shock absorption capability of a siimgle-crystal beta ... · technical iad-ao33

17
^D-AOS* <^$ TECHNICAL IAD-AO33 <.vg LIBRARY SHOCK ABSORPTION CAPABILITY OF A SIIMGLE-CRYSTAL BETA-ALUMINUM-BRONZE ROD ALBERT A. WARNAS MATERIALS SCIENCES DIVISION August 1976 Approved for public release; distribution unlimited. ARMY MATERIALS AND MECHANICS RESEARCH CENTER Watertown, Massachusetts 02172

Upload: others

Post on 18-Jul-2020

2 views

Category:

Documents


0 download

TRANSCRIPT

Page 1: SHOCK ABSORPTION CAPABILITY OF A SIIMGLE-CRYSTAL BETA ... · TECHNICAL IAD-AO33

^D-AOS* <^$

TECHNICAL IAD-AO33 <.vg LIBRARY

SHOCK ABSORPTION CAPABILITY

OF A SIIMGLE-CRYSTAL

BETA-ALUMINUM-BRONZE ROD

ALBERT A. WARNAS MATERIALS SCIENCES DIVISION

August 1976

Approved for public release; distribution unlimited.

ARMY MATERIALS AND MECHANICS RESEARCH CENTER Watertown, Massachusetts 02172

Page 2: SHOCK ABSORPTION CAPABILITY OF A SIIMGLE-CRYSTAL BETA ... · TECHNICAL IAD-AO33

The findings in this report are not to be construed as an official Department of the Army position, unless so designated by other authorized documents.

Mention of any trade names or manufacturers in this report shall not be construed as advertising nor as an official indorsement or approval of such products or companies by the United States Government.

DISPOSITION INSTRUCTIONS

Destroy this report when it is no longer needed. Do not return it to the originator.

Page 3: SHOCK ABSORPTION CAPABILITY OF A SIIMGLE-CRYSTAL BETA ... · TECHNICAL IAD-AO33

UNCLASSIFIED SECURtTV CLASSIFICATION OF THIS PAGE (When Dal* Entered)

REPORT DOCUMENTATION PAGE READ INSTRUCTIONS BEFORE COMPLETING FORM

t. REPORT NUMBER

AMMRC TR 76-24

2. GOVT ACCESSION NO. 3. RECIPIENT'S CATALOG NUMBER

4. TITLE (and Subtitle)

SHOCK ABSORPTION CAPABILITY OF A SINGLE-CRYSTAL BETA-ALUMINUM-BRONZE ROD

5. TYPE OF REPORT ft PERIOD COVERED

Final Report 6 PERFORMING ORG. REPORT NUMBER

7. AUTHORf»;

Albert A. Wamas

8. CONTRACT OR GRANT NUMBERCs.)

9. PERFORMING ORGANIZATION NAME AND ADDRESS

Army Materials and Mechanics Research Center Watertown, Massachusetts 02172 DRXMR-D

10. PROGRAM ELEMENT, PROJECT, TASK AREA ft WORK UNIT NUMBERS

D/A Project: 1T161101A91A mem Code: 611101.11.84400 \gencv Accession: DA 0F4717

11, CONTROLLING OFFICE NAME AND ADDRESS

U.S. Army Materiel Development and Readiness Command

Alexandria, Virginia 22333

12. REPORT DATE

August 1976 13. NUMBER OF PAGES

13 U. MONITORING AGENCY NAME ft ADORESSfiV d///eren( from Conrro/;yn« Ollice) 15. SECURITY CLASS, (ol this report)

Unclassified 15a. DECLASSIFI CATION.'DOWN GRADING

SCHEDULE

IS. DISTRIBUTION STATEMENT (ol this Report)

Approved for public release; distribution unlimited. •

17. DISTRIBUTION STATEMENT (ol the mbslract entered in Block 20. it dlllerent trom Report)

4

16. SUPPLEMENTARY NOTES

19. KEY WORDS (Continue on reverse aide il necessary and identify by block number)

Single crystal Martensitic transformation Beta-aluminum bronze Shock absorption Buckling Hysteresis

20. ABSTRACT (Continue on reverse side it necessary and identity by block number)

(SEE REVERSE SIDE)

DD I JAN 73 1473 EDITION OF 1 NOV 65 IS OBSOLETE UNCLASSIFIED

SECURITY CLASSIFICATION OF THIS PAGE (IChen Data Entered)

Page 4: SHOCK ABSORPTION CAPABILITY OF A SIIMGLE-CRYSTAL BETA ... · TECHNICAL IAD-AO33

UNCLASSIFIED KCUWITY CLAHIFICATION Of TMH Pk<il(Whm Dal* Knfnd)

Block NO. 20

ABSTRACT

Slender single-crystal beta-aluminum-bronze rods exhibited large recov- erable strains and large hysteresis upon buckling under static and dynamic cyclic loading conditions at room temperature. The cyclically buckled rods dissipated between 25 and 49 percent of the input energy which is comparable to that for cyclically stretched rubber.

During buckling only the regions at the bends, about two inches of the rod, were strained, participated in the energy dissipation process, and ex- perienced a reversible martensitic phase change. Both the static and dynam- ic tests were repeatable and reproducible with a given rod. The rod-end impacts showed no adverse effects on the rod material. After each impact the material reverted to its pre-impact condition.

The load-crosshead displacement curves of the statically buckled rods showed no changes in load level for crosshead speeds between 0.02 and 2 inches per minute.

The load-time curves of the dynamically buckled rods showed initial load oscillations which damped out in 12 milliseconds to constant input and output load levels. These constant load levels were comparable in magnitude to the static test load levels.

Because the loading cycle was repeatable and since a large amount of input energy was dissipated, the buckling slender single-crystal beta- aluminum-bronze rod shows capability of shock absorber application.

UNCLASSIFIED SECURITY CLASSIFICATION OF THIS PAGEfWhon Dml* Emertdi

Page 5: SHOCK ABSORPTION CAPABILITY OF A SIIMGLE-CRYSTAL BETA ... · TECHNICAL IAD-AO33

INTRODUCTION

Superelasticity is an effect whereby strain is attained, as in beta-aluminum- bronze, through a stress-induced martensitic transformation and such strain is completely recoverable upon unloading due to the reversibility of the transforma- tion. Loading curves of single-crystal beta-aluminum-bronze (SCBAB) material in tension, compression, and bending consist of large, recoverable strains and closed hysteresis loops reminiscent of the properties of rubber.

Oishi and Brown1 grew SCBAB specimens in the composition range Cu+14Al+3Ni (weight percent) and tested them in tension, getting recoverable strains of six percent and closed hysteresis loops. Shepard grew SCBAB rods of composition Cu+14Al+3Ni getting recoverable strains to eight percent and closed hysteresis loops in compression. The energy dissipated in cyclic compression was about a third of the input energy under a loading of 1000 pounds on a 0.2-inch-diameter, 0.5-inch-long SCBAB sample, while rubber with a one-inch-square cross section, cyclically stretched to several times its length, dissipates about 40% of the input energy under a loading of 15 pounds. Intermediate between these loading values is the 100 to 300-pound load needed to cyclically buckle a 0.2-inch- diameter, 6-inch-long SCBAB rod. During the cyclic buckling, the rod absorbs the input energy partly as elastic restoring energy and partly as mechanical work in overcoming the internal frictional forces of the material which is dissipated as heat.

This report investigates the energy absorbing and dissipating capability of a slender SCBAB rod in the superelastic range of the material when the rod is cyclically buckled under static and dynamic loading conditions at room temperature.

EXPERIMENTAL PROCEDURE ■

Ingots of alloy composition 82.9Cu-14.lAl-3Ni (weight percent) were vacuum induction melted and poured under argon, from which single-crystal rods were grown.2 The dimensions of the single-crystal rods were up to 6.5 inches long and 0.2 inch in diameter. The crystal [100] orientation lay within 16 degrees of the rod axis. The rods were finished by sanding, chemically polishing, and etching in two parts nitric acid, one part water.

Preliminary static buckling tests on a single-crystal rod, with the setup in Figure 1, resulted in a load-displacement curve like the one shown schematically in Figure 2. The area in the closed hysteresis loop is related to the dissipated energy; the rest of the area is related to the "elastic" restoring energy. The curve shows that a rod loaded in the buckling mode is suitable for energy absorption tests. Hence, this mode of loading was adopted for testing under both static and dynamic conditions in the present investigation.

The static buckling tests were performed at constant crosshead speeds between 0.02 and 2.0 inches/minute. Load-crosshead displacement curves were planimetered and the energies involved were calculated.

1. OISHI, K., and BROWN, L. C. Stress-Induced Martemite Formation in Cu-Al-Ni Alloys. Met. Trans., v. 2, 1971, p. 1971-1977. 2. SHEPARD, L. A. Compression of CuAINi Crystals in Shape Memory Effects in Alloys. AIME, Jeff Perkins, ed.. Plenum Press

New York, 1975, p. 419-429.

Page 6: SHOCK ABSORPTION CAPABILITY OF A SIIMGLE-CRYSTAL BETA ... · TECHNICAL IAD-AO33

Crosshead ^» \ Load

Displacement, Ai Crosshead

in End Plate

// // , Lateral Deflection

l-t l\2

/ ,„/ =A/v/i/2Ai-0.25 yr fo ■ Total Rod Length

'—| 1- i-0.25

vj Vortex Hole

" 0 End Plate

Base

Load Beta

Phase

Buckling Load

Beta + Gamma Prime Phases "Gamma Prime Increases with

Increasing A/(Loading) and Decreases with Decreasing A/ (Unloading)

-Loading

'Dissipated Energy,

' Unloading

Restoring Energy

Figure 1. Static buckling mode. Rod with ends in

vortex holes between end plates.

Crosshead Displacement, Ai

Figure 2. Schematic load versus crosshead displacement

curve for a SCBAB rod loaded in

the static buckling mode.

Several types of end-plate holes, for holding and positioning the rods during buckling, were tried. Figure 3a shows one of the steel end plates with one end of a crystal rod in a vortex-like hole in the plate. Also shown in Figure 3a is a straight, drilled hole and two shallow con^s of 30 and 45 degrees. The vortex hole was chosen over these because it gave rigid support to the rod, eliminated stress concentration on the side of the rod, and introduced the ends of the rod in the deformation so as to absorb more energy.

The dynamic buckling tests were performed with a fixture that accommodated a rod for impact by a Charpy impact machine. The main element of the fixture is a rigid frame for the buckling rod (see Figure 3bj. The left end of the frame con- sists of a ram and sliding block. The left end of a rod is held in position in a vortex hole in the sliding block. The right end of the frame has a compound screw by which rods of different lengths are accommodated in the fixture. The compound screw has a vortex hole in its end to hold a rod end.

The quantitative dynamic loading results were obtained in two ways. One was by measuring angles associated with the energies of impact and rebound of the tup. The difference in these energies is the dissipated energy. The other way was by photographing the impulse trace from an oscilloscope connected to electronically monitored strain gages calibrated to measure load in the tup. The dissipated energy was calculated from the areas under the curve.

Page 7: SHOCK ABSORPTION CAPABILITY OF A SIIMGLE-CRYSTAL BETA ... · TECHNICAL IAD-AO33

Figure 3. (A) A rod end-plate with a SCBAB rod in a vortex hole. (B) Impact fixture with a Revere 456 rod in a post-impact state.

■WSSm*

Static Tests

EXPERIMENTAL RESULTS

The results of the static tests are in Table 1. All tests in this table were on rods mounted between end plates except for Test 3 which was performed with a rod in the impact fixture. The tests are arranged according to a decrease in the rod length and an increase in the crosshead displacement for a given rod length.

Rod 1, which performed well in Tests la-le, had a gas hole in its surface about 0.1 inch in diameter and 0.1 inch deep, about two inches from one end. It broke, later to become the 4.5-inch rod used in Test 6.

Test 2 consisted of three tests, each at a different crosshead speed, result- ing in three load-crosshead displacement curves. In all three cases the crosshead displacement was 0.3 inch. Normalizing the crosshead displacements resulted in three identical load-displacement curves; therefore only one set of data, the continuous line curve, is shown in Figure 4a. As there was no change in the loading and unloading levels for the three different crosshead speeds, and indeed there were only slight differences between load levels for corresponding displacements beyond the buckling peak in all the static curves of Table 1, it was concluded that the strained regions of the buckling rod were insensitive to crosshead speeds between 0.02 and 2.0 inches/minute.

Test 3 is a repeat of Test 2, but with the same rod in the impact fixture (see Figure 4a, dashed-line curve). A static value for the friction of the impact fixture was obtained by comparing the ratio of the dissipated to input energy of Tests 2 and 3. The dissipated energy for Test 3 was found to be 26% higher than that of Test 2.

Page 8: SHOCK ABSORPTION CAPABILITY OF A SIIMGLE-CRYSTAL BETA ... · TECHNICAL IAD-AO33

Table 1. ROOM TEMPERATURE STATIC -BUCKLING, L0AD-CR0SSHEAD DISPLACEMENT TESTS ON SINGLE-CRYSTAL BETA-ALUMINUM-BRONZE RODS

Single-Crystal Crosshead

Buckling Load, lb

Energy/Load Cycle [TOO]

Length IQ, in.

Lateral Def1ection Input

ft-lb

Hysteresis Displacement

in. Speed

in./min Test Rod Rod Axis in. ft-lb Input, %

la 1 10° 6.5 0.92 0.28 0.10 212 2.50 0.83 33 lb 1 10° 6.5 1.00 0.33 1.00 230 2.80 1.11 40 lc 1 10° 6.5 1.10 0.40 0.10 230 3.33 1.21 36 Id 1 10° 6.5 1.15 0.44 2.00 185 3.07 1.32 43 le 1 10° 6.5 1.20 0.48 0.20 290 4.40 1.41 32 A 2 _ 6.0 1.05 0.40 0.10 300 3.87 1.41 36 2 3 go 5.5 0.87 0.30 0.02 355 4,23 1.69 40 2 3 9° 5.5 0.87 0.30 0.1 355 4.23 1.69 40 2 ■ 3 9° 5.5 0.87 0.30 1.0 355 4.23 1.69 40 3 3 go 5.5 0.87 0.30 0.02 315 4.39 2.37 54 3 3 go 5.5 0.87 0.30 0.1 315 4.39 2.37 54 3 3 g° 5.5 0.87 0.30 1.0 315 4.39 2.37 54 4a 4 - 5.0 0.86 0.32 0.10 510 7.60 3.28 43 4b 4 - 5.0 0.86 0.32 0.20 475. 7.58 3.70 49 4c 4 - 5.0 1.02 0.46 0.20 445 10.50 - - 5 3 _ 5.5 0.75 0.21 1.00 270 1.37 0.39 28 6 1 _ 4.5 0.71 0.23 1.00 230 1.30 0.56 43 7 Revere

456 - 5.5 0.87 0.30 1 .00 900 10.80 9.60 89

a. SCBAB Rod with Ends in Vortex Holes Between End Plates

n Impact Fixture

300

200

100

0 0.1 0.2 0.3

b. A SCBAB Rod with Ends in Shallow-Cone Rod-End Holders

Figure 4. Static buckling of SCBAB.rod 3,

5.5 inches long, at a crosshead speed of

1 inch/minute and room temperature.

0.1 0.2 Crosshead Displacement, Inch

Test A and Tests 4a-4c were performed on rods 2 and 4, whose angular deviation of the crystal [100] from the rod axis was unknown but is assumed to be less than 16 degrees, since these crystals resembled crystals 1 and 3 in both etching appear- ance and mechanical performance. In Test 4c, crystal 4 was buckled to destruction to obtain an idea of the limits of energy, lateral deflection, and crosshead displacement.

Tests 5 and 6 were done with shallow-cone, rod-end holders. The rods bent only in the middle. The rod ends were free to snap out of the shallow cones beyond

Page 9: SHOCK ABSORPTION CAPABILITY OF A SIIMGLE-CRYSTAL BETA ... · TECHNICAL IAD-AO33

a crosshead displacement o£ 0.2 inch. Figure 4b is typical for buckled rods with shallow cone holders supporting their ends. The energy dissipated is about 25% that o£ a rod tested with vortex hole rod-end holders as in Test 2.

Test 7 (see Figure 5) was strictly for purpose of comparison. It consisted of a Revere 456 welding rod, 0.19-inch diameter and 5 inches long, which, as expected, buckled with permanent deformation (see Figure 3b). The permanent deformation energy is listed under the hysteresis column in Table 1. The buckled shape of the brass rod is typical for any buckled slender metal rod and is representative of a buckled SCBAB rod.

The lateral deflection column in Table 1 was computed from the formula in Figure 1. The length l=lo-0.25 is used in the formula to correct for the tip ends of the rod deep in the shanks of the vortex holes. These tip ends participate in the energy absorption but not in the lateral deflection of the rod. The correction is about 0.125 inch at each end. It was assumed that the rod buckles at its mid- point, as a hinge, with no curvature at the bend. Actually, there is curvature which would make the lateral deflection values listed in Table 1 smaller by about 0.1 inch.

During the course of static buckling of rods, it was observed that if the loading is cycled on a buckled SCBAB rod in a region where the rod remained in a loaded and buckled state, small amounts of energy are dissipated. In Figure 6a three different loops with their maximum loop load h is shown on the main un- loading curve. These loops are reproducible. This is analogous to flexing a bent elastic rod without ever allowing it to become completely relaxed to its straight position. But with a SCBAB rod a certain amount of energy is absorbed and dissipated in each such flexing, as shown by the closed loops with each flexing in Figure 6a. Table 2 lists the energies and maximum loads for the three loops of Figure 6a. Figure 6b is a repeat of Figure 6a but with the rod in the impact fixture.

Some general observations may be made with regard to the static buckling of SCBAB rods with the [100] orientation near the rod axis from Table 1.

1. No strain rate effects were observed for crosshead speeds up to 2 inches/ minute where strain rate effects are recognized through load level changes.

.o

0.1 0.2 Crosshead Displacement, Inch

Figure 5. Static buckling of a 5.5-inches long

brass welding rod with rod ends in vortex holes

between end plates at a crosshead speed of 1 inch/minute and room temperature.

Page 10: SHOCK ABSORPTION CAPABILITY OF A SIIMGLE-CRYSTAL BETA ... · TECHNICAL IAD-AO33

2. For a given rod length and rod diameter, the energies (input and dissi- pated) as well as the lateral rod deflection increase with crosshead displacement.

3. For a given crosshead displacement and diameter, as the rod length de- creases, the energies increase but the lateral deflection decreases.

Table 2. ENERGIES AND MAXIMUM LOADS

Loop Input ft-lb

Heat ft-lb

Percent of Input

h, Max. Loop Load

lb

1 2 3

0.99 1.02 0.93

0.10 0.16 0.19

10 16 20

12 29 97

Dynamic Tests

The dynamic tests, using rod 3, were performed on a 240 foot-pound capacity Charpy impact machine. The results are given in Tables 3 and 4. Tests 1 through 6, Table 3, were performed with rod 3, 6.5 inches long. Tests 7 through 10, Table 4, were performed with rod 3, cut to 5.5 inches long. Figure 7 consists of three curves, data plots of the impact energy E. , versus the dissipated energy E, .

Curves 1 and 2, Figure 7, are from the E. versus E, data in Table 4, obtained by measuring angles of impact and rebound as shown in Figure 8. Curve 1 is the data of Tests 7 and 8 which were performed with a dry (unlubricated) fixture. Curve 2 is the data of Tests 9 and 10 which were done with the fixture's sliding parts lubricated with oil. A 14 percent dissipated energy decrease is achieved by lubricating the sliding parts. The dissipated energies in Curve 1 (5.5- inch rod) are higher than the corresponding dissipated energies in Curve 3 (6.5-inch

Table 3. ROOM TEMPERATURE DYNAMIC BUCKLING TESTS ON 6.5-INCH SCBAB ROD 3

(Data from Impulse Fraces)

Ein Eout Eheat /heat /o E. Lin

Vin V out AV

Test ft-lb ft-lb ft-lb ft/sec ft/sec ft/sec

1 2.2 1.55 0.65 30 1.62 1.36 0.26 ? 3.0 2.03 0.97 32 1.89 1.56 0.33 3 3.4 2.39 1.01 35 2.01 1.69 0.32 4 4.7 3.39 1.31 21 2.37 2.01 0.36 5 6.3 4.02 2.28 36 2.47 2.19 0.55 6 7.8 4.14 3.66 47 3.05 2.22 0.83

Table 4. ROOM TEMPERATURE DYNAMIC BUCKLING TESTS ON 5.5-INCH SCBAB ROD 3

(Data from Angles of Impact and Rebound)

Test

Ein ft-lb 81 82

Eheat ft-lb

Aeat 10 E. in

Vin ft/sec

Vout ft/sec

—•

AV ft/sec

7 8 9*

10*

3.4 7.48 3.4 7.48

76°45,

71012' 76045l

710^2,

SCMO1

76°45,

7903r 76031,

1.65 3.73 1.40 3.33

48.5 50 41.2 44.8

2.01 2.94 2.01 2.94

1.45 2.11 1.55 2.22

0.56 0.83 0.46 0.72

*Impact fixture lubricated

Page 11: SHOCK ABSORPTION CAPABILITY OF A SIIMGLE-CRYSTAL BETA ... · TECHNICAL IAD-AO33

350

250

150

- 50

8300

200

100

0

_ f\ a. SCBAB Rod in Vortex Holes Between End Plates

:l V

/

n- ^ ■) ~—■^- ; -__ (•IB ^-—^ A^—^=-—-^

n

;/ i i i

^f b. SCBAB Rod In Impact Fixture with Vortex Holes

r ^ ^ ^c=r-~V 1

l I r

0.1 0.2 Crosshead Displacement, Inch

0.3

4 -

2 -

1 -

Table A 4

Fixture Dry

4 Lubricated

3 Dry

SCBAB Rod Length 5.5 Inches

5.5 inches

6.5 Inches

~>> 4 ft-lb

Figure 7. Impact energy versus dissipated energy for SCBAB rod 3 buckled by impact in a Charpy impact machine at room temperature.

rod). Thus the dissipated energy increases static tests. In Tests 7 through 10, Table 4 ling rod with the fixture cavity wall was ob ratio between the input and dissipated energ

Figure 6. Static load cycling with buckled SCBAB rod 3, 5.5 inches long, at a crosshead speed of 1 inch/minute and room temperature.

heat Hysteresis RWIsinej-sinSj)

R • 2.625 feet W ■ 53.23 pounds

Impact Fixture with Buckled Rod ■ Rebound

ES2

Pendulum Arm with Tup

F^a^-^

Figure 8. Schematic of impact fixture with rod posi- tioned on Charpy impact machine. Dissipated energy of impact measured by angles of impact and rebound.

as the rod length decreases, as in the no interaction of the 5.5-inch buck-

served. Curves 1 and 2 show a constant ies.

The data for Table 3 was obtained with the Charpy impact machine electronically instrumented. Impulse traces from Tests 2 and 5 are shown in Figure 9. The initial shaded-in part of the impulse trace represents oscillations of the impact load which damp out with time. From the point where the load oscillations cease to the end of the impulse, the loads level off on two plateaus. At the end of the first (loading) plateau, at point R, the kinetic energy of the impact is zero. The velocity of the system (Charpy pendulum arm with tup, movable impact fixtures parts, and buckled rod) is also zero. On the lower (unloading) plateau, from R to the end of the impulse trace, the rod exerts a restoring force on the system. At the end of the impulse the rod is restored to its pre-impact state.

Page 12: SHOCK ABSORPTION CAPABILITY OF A SIIMGLE-CRYSTAL BETA ... · TECHNICAL IAD-AO33

The energy values in Table 3 were obtained by dividing the area under the impulse trace into two parts at R (see Figure 9). The area Ein (hatched region of impulse trace as represented in schematic in Figure 5) is proportional to the impact energy while the area Eout is proportional to the restoring or rebound energy. The ratio of the areas Eout to Ein times the energy value of Ej^, obtained from the Charpy pendulum free swing, results in the energy value Eout. The value o: the dissipated energy E^eat, is the difference between the energy values of Ein and

^out In Table 3, the velocities of the impact V^n and rebound Vout (of tup and impacted rod end) were calculated from the kinetic energy equation,

Curve 3 (dashed line). Figure 7, is from the E^n versus E^eat data in Table 3. It was observed that the 6.5-inch buckling rod interacted with the fixture cavity wall, thereby changing the ratio of dissipated energy to restoring energy. Since the impact energy data from Table 4 can be represented by straight lines (Curves 1 and 2, Figure 7) there is the question as to why Curve 3 deviates from a straight line. It is believed that the dashed line Curve 3 reflects the inter- action of the deflecting 6.5-inch rod with a fixture cavity wall. With this con- sideration, a straight line is proposed as the E^n versus E^at curve for the 6.5-inch rod undergoing buckling with unhindered lateral deflection (as drawn in Figure 7, Curve 3). The difference between the dashed and straight line curve is then explainable in terms of the interaction of rod and wall and the corresponding changes in the energy ratios of dissipated to restoring energy.

100 lb 1

i L JE—^- r

100 lb

r

-UOh- msec

E. ■ 3 ft-lb in Test 2

n E. =6.3 ft-lb in Test 5

Figure 9. Typical impulse traces for a

SCBAB rod dynamically buckled under

impact loads between 2.2 and 7.8

foot-pounds.

Schematic Time Impulse

Trace

Page 13: SHOCK ABSORPTION CAPABILITY OF A SIIMGLE-CRYSTAL BETA ... · TECHNICAL IAD-AO33

DISCUSSION

The primary purpose of this study was the determination of the energy absorbing and dissipating capability of a SCBAB rod for shock absorber applications. A SCBAB rod, upon buckling, deformed, transformed, and absorbed energy, and in so doing dissipated a large amount of the input energy as heat. The remainder, stored as elastic restoring energy, supplied the restoring force to the rod to return it to its original shape and structure. This loading cycle and the accom- panying energy absorption was repeatedly reproducible with a given test sample.

During the initial linear part of the loading curve for static buckling by a SCBAB rod, as represented in Figure 2, no rod buckling nor color change was observed in the beta phase. As the rod begins to buckle (in the vicinity of the dashed line), thin chevrons of gamma-prime orthorhombic martensite form in the beta phase, in a 1-inch region at the bend in the middle of the rod. The normally reddish-copper color of the beta-aluminum-bronze rod is observed to change to yellowish-brass in the gamma-prime chevrons. The load decreases but, with contin- uing crosshead motion, the rod continues to buckle with a widening of the gamma- prime chevrons. The change in color is more pronounced on the compression side of the bend than on the tension side. Upon unloading, the path of returns is the lower curve during which the gamma-prime phase decreases, disappearing at the lower peak (at the dashed line). From this point to unloading the material is beta phase and copper colored. At zero load the rod showed no permanent defor- mation.

Strain-rate effects were not observed in the load-crosshead deflection curves of statically buckled rods at crosshead speeds between 0.02 and 2 inches/minute. That is, with faster crosshead motion, the rods buckled sooner and the strained regions transformed sooner but the load levels remained constant for a given rod length.

In the dynamic tests the expected doubling of load was observed at the buckling peak in some of the impacts. In all impacts, the initially oscillating load damped out in 12 milliseconds to strain-rate-insensitive static-test load levels. The duration of the impulse, loading and unloading, was 90 milliseconds for the 7.8 ft-lb input. The loading-impulse duration (including oscillating load interval) was about 40 milliseconds.

From examination of all the impulse photos, the load levels are comparable to the strain-rate-insensitive static load levels beyond the peak of the load- crosshead displacement curve. Increases in impact energies (input and recovery) show up on an impulse trace as the application of strain-rate-insensitive static loads (input and recovery) over longer durations of time.

The pronounced hysteresis in the stress-strain curve for rubber3 shown in Figure 10 enables this material to convert large amounts of mechanical input energy into heat. This energy dissipating ability enhances the value of rubber as a shock absorber. The energy absorbed and dissipated by rubber in Figure 10 is 42

3. ANDREWS, E. H. Fracture in Polymers. American Elsevier Publishing Co., New York, 1968, p. 28.

Page 14: SHOCK ABSORPTION CAPABILITY OF A SIIMGLE-CRYSTAL BETA ... · TECHNICAL IAD-AO33

21.3

- 14.2'

7.1;

Figure 10. Mechanical hysteresis in rubber (after Andrews, Ref. 3).

percent of the input energy. Since a SCBAB rod absorbs energy in comparable ratios (between 25 and 49%), it has capability as shock absorber material in shock absorber devices. Indeed, the impact fixture with a SCBAB rod constitutes such a device. Mounting this device on a platform with four wheels (as was done by the author for demonstration purposes) and propelling it toward a wall with a velocity V. in the range of velocities of the Charpy rod-end impact tests, would result in energy exchanges like those given in Tables 3 and 4. Thus the fixture with SCBAB rod constitutes a vehicle bumper.

It is emphasized that the buckling rods, independent of their lengths, deformed and transformed only in the immediate regions of the bends, constituting 2 inches of the total rod length. Thus, the remainder of the rod not involved in absorbing energy can be considered as part of the shock absorber device, while the deformed and transformed regions of the rod constitute the shock absorber material in the present buckling mode.

Although the shape of the load-displacement curve, its load levels, strain distribution, and energy dissipation are governed by the mode of testing and the shape of the specimen, it is clear that when SCBAB material is deformed and trans- formed, it dissipates a large amount of energy. Also the energy absorption and dissipation cycle is reproducible and repeatable. Thus, this material warrants further investigation into its energy absorption properties for its use in shock absorber devices.

CONCLUSION

Single-crystal beta-aluminum-bronze (SCBAB) rods, 0.2 inch in diameter, be- tween 5 and 6.5 inches long, with the [100] within sixteen degrees of the rod axis, were buckled at room temperature under static and dynamic loading conditions. A rod buckled by hinging in the middle and the supported ends. Upon load removal the rod assumed its pre-impact condition. Both static and dynamic tests were repeatable and reproducible with a given rod.

In the static buckling tests, the rods dissipated between 32 and 49 percent of the input energy for inputs up to 7.45 foot-pounds. The load-crosshead displacement curves showed no change in load-levels (loading and unloading) for crosshead speeds between 0.02 and 2 inches/minute.

10

Page 15: SHOCK ABSORPTION CAPABILITY OF A SIIMGLE-CRYSTAL BETA ... · TECHNICAL IAD-AO33

Under dynamic loading conditions, the rods were buckled by rod-end impacts up to 7.8 foot-pound. Between 25 and 44.8 percent of the input energy was dissipated in the impact process. The impact-loading initially experienced oscillations. These loading oscillations damped out in 12 milliseconds to a constant loading level. The unloading (restoring) level, of lower magnitude than the loading level, also was constant. Thus, the rod, surviving the initial impact, can be described as under the influence of constant loadings (input and restoring), comparable to the static test load-levels in magnitude, which act over periods of time. Likewise, the input energies (from 2,2 to 7.8 foot- pounds) and corresponding restoring energies vary with the times over which the constant, static-load levels act. The total impulse, loading plus unloading, lasted up to 90 milliseconds with a time span for the loading impulse (including the loading oscillations) of 40 milliseconds.

Only the strained regions of the rod, at the midpoint bend and the bends at the ends, were involved in the energy absorption and phase transformation (about one inch in the middle bend and about one-half inch at each of the end bends).

The material transformed from the body-centered-cubic beta phase to an orthorhombic raartensitic gamma-prime phase during loading in the strained regions of the buckled rod. Part of the input energy was dissipated as heat during the phase transformation and straining. The rest was stored as "elastic" restoring energy in the strained and transformed regions of the rod.

* During unloading, "elastic" restoring forces in the strained material of

the rod restored the rod to its original pre-impact state. The strained material reverted to its beta phase and the rod returned to its straight shape with completely recovered strain.

Because the loading-unloading cycle was repeatable and reproducible, with a large amount of input energy dissipated in the cycle, the buckling, slender SCBAB rod shows capability in shock absorber applications.

ACKNOWLEDGMENTS

The author wishes to thank Dr. L. A. Shepard of the Materials Sciences Division for providing the single-crystal rods used in this report and for helpful discussions in the course of this work. The author also wishes to thank Mr. Charles Curll of the Materials Properties Division for the use of the instrumented Charpy impact machine, his operation thereof, and the impulse photos.

11

Page 16: SHOCK ABSORPTION CAPABILITY OF A SIIMGLE-CRYSTAL BETA ... · TECHNICAL IAD-AO33

DISTRIBUTION LIST

No. of Copies To

1 Office of the Director, Defense Research and Engineering, The Pentagon, Washington, D. C. 20301

12 Commander, Defense Documentation Center, Cameron Station, Building 5, 5010 Duke Street, Alexandria, Virginia 22314

1 Metals and Ceramics Information Center, Battelle Memorial Institute, 505 King Avenue, Columbus, Ohio 43201

1 Chemical Propulsion Information Agency, Applied Physics Laboratory, The Johns Hopkins University, 8621 Georgia Avenue, Silver Spring, Maryland 20910

Chief of Research and Development, Department of the Army, Washington, D. C. 20310

2 ATTN: Physical and Engineering Sciences Division

Commander, Army Research Office, P. 0. Box 12211, Research Triangle Park, North Carolina 27709

1 ATTN: Information Processing Office

Commander, U. S. Army Materiel Development and Readiness Command, 5001 Eisenhower Avenue, Alexandria, Virginia 22333

1 ATTN; DRCDE-TC 1 DRCSA-S, Dr. R. B. Dillaway, Chief Scientist

Commander, U. S. Army Electronics Command, Fort llonmouth, New Jersey 07703

1 ATTN: DRSEL-GG-DD 1 DRSEL-GG-DM

Commander, U. S. Army Missile Command, Redstone Arsenal, Alabama 35809

1 ATTN: Technical- Library 1 DRSHI-RSM, Mr. E. J. Wheelahan

Commander, U. S. Army Armament Command, Rock Island, Illinois 61201

2 ATTN: Technical Library

Commander, U. S. Army Research and Development Command, Natick, Massachusetts 01760

1 ATTN: Technical Library

Commander, U. S. Army Satellite Communications Agency, Fort Monmouth, New Jersey 07703

1 ATTN: Technical Document Center

Contnander, U. 5. Army Tank-Automotive Development Center, Warren, Michigan 48090

2 ATTN: DRDTA, Research Library Branch

Commander, White Sands Missile Range, New Mexico 88002 1 ATTN: STEWS-WS-VT

Commander, Aberdeen Proving Ground, Maryland 21005 1 ATTN: STEAP-TL, Bldg. 305

President, Airborne, Electronics and Special Warfare Board, Fort Bragg, North Carolina 28307

1 ATTN: Library

Commander, Dugway Proving Ground, Dugway, Utah 84022 1 ATTN: Technical Library, Technical Information Division

Commander, Edgewood Arsenal, Maryland 21010 1 ATTN: Mr. F. E. Thompson, Dir. of Eng. i Ind. Serv.,

Chem-Mun Br

Commander, Frankford Arsenal, Philadelphia, Pennsylvania 19137

1 ATTN: Library, H1300, Bl. 51-2 1 SARFA-L300, Mr. John Corrie

Commander, Harry Diamond Laboratories, 2800 Powder Mill Road, Adelphi, Maryland 20783

1 ATTN: Technical Information Office

Commander, Picatinny Arsenal, Dover, New Jersey 07801 1 ATTN: SARPA-RT-5

No. of Copies To

Commander, Redstone Scientific Information Center, U. S. Army Missile Command, Redstone Arsenal, Alabama 35809

4 ATTN: DRSMI-RBLD, Document Section

Commander, Watervliet Arsenal, Watervliet, New York 12189 1 ATTN: SARWV-RDT, Technical Information Services Office

Commander, U. S. Army Foreign Science and Technology Center, 220 7th Street, N. E., Charlottesville, Virginia 22901

1 ATTN: DRXST-SD3

Director, Eustis Directorate, U. S. Army Air Mobility Research and Development Laboratory, Fort Eustis, Virginia 23604

1 ATTN: Mr. J. Robinson, SAVDL-EU-SS

Librarian, U. S. Army Aviation School Library, Fort Rucker, Alabama 36360

1 ATTN: Building 5907

Commander, U. S. Army Engineer School, Fort Belvoir, Virginia 22060

1 ATTN: Library

Commandant, U. S. Army Quartermaster School, Fort Lee, Virginia 23801

1 ATTN: Quartermaster School Library

Naval Research Laboratory, Washington, D. C. 1 ATTN: Dr. J. M. Krafft - Code 8430 2 Dr. G. R. Yoder - Code 6382

20375

Chief of Naval Research, Arlington, Virginia 22217 1 ATTN: Code 471

Air Force Materials Laboratory, Wright-Patterson Air Force Base, Ohio 45433

2 ATTN: AFHL (MXE), E. Morrissey 1 AFML (LC) 1 AFML (LLP), D. M. Forney, Jr. 1 AFML (MBC), S. Schulman

National Aeronautics and Space Administration, Washington, D. C. 20546

1 ATTN: Mr. B. G. Achhammer 1 Mr. G. C. Deutsch - Code RR-l

National Aeronautics and Space Administration, Marshall Space Flight Center, Huntsville, Alabama 35812

1 ATTN: R-PJVE-M, R. J. Schwinghamer 1 SSE-ME-MM, Mr. W. A. Wilson, Building 4720

1 Ship Research Committee, Maritime Transportation Research Board, National Research Council, 2101 Constitution Ave., N. W., Washington, D. C. 20418

P. R. Mallory Company, Inc., 3029 East Washington Street, Indianapolis, Indiana 46206

1 ATTN: Technical Library

Wyman-Gordon Company, Worcester, Massachusetts 01601 1 ATTN: Technical Library

Lockheed-Georgia Company, Marietta, Georgia 30060 1 ATTN: Advanced Composites Information Center,

Dept. 72-34 - Zone 26

1 The Charles Stark Draper Laboratory, 68 Albany Street, Cambridge, Massachusetts 02139

1 Materials Sciences Corporation, Blue Bell Campus, Morion Towle Bldg., Blue Bell, Pennsylvania 19422

Director, Army Materials and Mechanics Research Center, Watertown, Massachusetts 02172

2 ATTN: DRXMR-PL 1 DRXMR-AG 1 Author

Page 17: SHOCK ABSORPTION CAPABILITY OF A SIIMGLE-CRYSTAL BETA ... · TECHNICAL IAD-AO33

_

O CD i— Ui •—" <D E t— OC 4J 5 lJ- t— in vi c

tO ►-. t. S- £ LO o o u 3 en < _ 3 ^ C I O 0) (0 •(- <J LU >> ^ I r-

" i— (U I I •M I "O QJ 0) ,C ■<- E

VlCt-OJIr- .|>+J|— O v)ca)3£:irtj2r-(n(u ^o C O UQ>i-C*»- (• yjf— M--r-

■t- -r- I_ id 0) o •,- O O E <u •O+^OJ t-4->3l.S--a i- l-'i-Q. •+Jt.'0(UL)(TJi/)C\jai +JT3 »-(/i(0O4->lOaJr-J

o ^t xi tu o. E ra JD t- OJ v o

: £ X .a O

3 *^ «—

Ct «J <—

I> UJ ra lO *

5 c^3 r^ < (hi- c z . f— en

0) H-.< «c CJ LTi -«-> P

•M U) CD x: «t i- 3 r- U CM (U o^<— i- r^u_ JD 3 lO (0 r— o>-r < >— OJ OJ < (— to o 5- , 0) J— 'S- o £ —i <NJ -M O

1 o ^ in -j a y) +J »-. o IO (D -a- O ■♦-> CT) CC I^ -^co

^e^- tZ VI O, UJ ra 3 < rvj h- CL -— x: x: oz (J u o <J «C "-^ a; *o ^ a: ac w o co

to 1—• 1

ex -^o

■o ra i— s: c XoT^) (A to ra D; z 4-> o; *o^-. i.r- (U i/i c to a: O XI X)

«?S3 cx ra o tU -M O

•r- +J ct OC 1 S- S- ^ 1 V. (/) 0) 01 o< r- 3 ^ -M +J OH- ra ro ni LU Z: 3t L0 CD •r- -^ d:

xi en c — racra -r-TJi-Qjtnajuaj *-•»- -a *inc .caiEOi— OTJUI (y-D L ra at \— cn-i- >rac\i^ipa) J: C+JTJTD o o (j£.>(U4-> ro i GJ ro Oi— C-M <U<— '.C-OQ-O QJ OJajojJ-xaccora E-— t-oeui-^ «oo ora

•p-S+J-Mra+J .f-Or--0+J ai«—4-»w) raw+Jc c: oi u QJ ^--oaj-tJ-i- atjzro t- >iJD >,o QJ a-u-o-oj; u-t-> rao ^- oajojcajt— *• wi

«— -CJ*— inEt<«-oj -CE u a ro cu QJ M-oo 20

"0-t-+Ju,C'i-ft>aj -c ■ u OJEra-^Ui-t. -tJyiOJW +J ra Q.1— c a <v aj u -ucaj •r-c-i-u-f-a-XmraiosOui XJ >> v> >, x 1_ Q-TJ c •.- 0) ■i-"Dwi(JOQJtnQJE 0-I-+J.C 4B E 3r +J>->-C.Era(— X-0-01.-P-OtnT3l •— <uc: o cajra<u-oi-r-

;■,-) un M- 4_) -rj 4-> S- OJ 1) -r- • V> TD ZJ O Q-r- O. U W T3004->0 *UC J* tA •— 0*t-l-ra^3t/)-f- l/)0(/)0(U i'+J x:ratrtE-o-i-»3(U >

raTD+j ajraa)'t--Qx:'ejaj tt)^j(U K Q C B urar- NtOf— OiflO>,00>>CO

^+>-0 l-TJx:-*->r— -r-i— TD

0) -o c c o

ra (/> ra s <J

cn-r- QJ C i—

t— -f- a. U f— Q. >,^ ra u o

3 »- cnxi a> |I I

TD x: o ra +J yi

r— * ra ■o

OJ OJ ^ *z ■*-* u +-> ra o

o-x:

u -a ai >,

CD (/) +•' ra -r- 5 p-

(/) >>xi r— en ra

QJ 1- O- > OJ ra QJ C U

-O ■!-> I/)

■ i- u

>, ra OJ ■ o ra

T3 ra CM i— o -i 1^ oi u ra r— . +J +J -^ "O •!- u &• -M c: -t-* ■(-> i

«~s_^4-» ura aj^ora-r- 7>f~ ra+3raT-a.>+J c c on

■r- C ra CL CL-IJ E OJ tAwm-w- E ■<- <-» E +^ •-- « -^ C o 3«— .^oratrt+J o) •■a f-J^^-U I/II/I^OI— X:OOJ rauu tn-r- cra-n j t s^i/icTsa^ajT- co raxjo-r-o x:is_ii-o>-c 4* -r-^-M-OajOOItrt Q>cQ;x:cntDi O-M i noj=L)Oii-x;i-rato-P(/i

O-l— -i-i-OJ+J s <u v -o

t +J o o ■ ro E s-

4-* ra xi

ro — O <U > XJ o ^ XOJOJCDxroiL. C n-

(n-r-aJ>>4->0> +JUTDT3-M >,(/)i_cn £• OJOIC L v 3 & >,*3 <u • +J +> at i— ra (J J- 4-» OJ •— CDTD (J B CL-iC -M

■ ajraccccoraajcAUi/) 0>+Ji-ajO'^rai-cLE 3c

<— WO) x: EOJTDXlO oi >, 0.+J enx) o c -r- u ra u ■ J^: E ZJ d Qj 01 ra0J>,

■r- oi o-r- -u OJ >jri—x:.— o WIO^-M ci— ra wi-i- u Q-wt—

en -f-^Q-raCTirai/ii/ira i-s-E u-i-x: oi-r-oow ajraoaj3UQ.ra TDI--.-TD

c C.4J +Jo^:Qj-a rao QJTD CTl--»--t->-MraS~CU

F- c-*->4- c ra-u •!-*+- OJ o >>aj co ra ro o -i- o.-r- x <: x: *+- "a to

r- E O 3 +J ra r- ra QJ 0) I -aura 3 C 4-)

o c QJ >,

xi u cu ra i

,— -M 0) JD ra «— ra a) en ' CL c ra o» -r- CL C in

- -\

>-> 00 -o >ve:

S5LJ 0 ^c i— c

O LU Z P 0) C ■»-> (J

t—< l/l CD CD

UJ ra

c!3

£ < 1- U CM 0) l- r^ LI_ JD ra i— O'rr' a> CM <r m o >-

i— en

tn o 3 I— Olr— 3 lO < F-

£ I in.

w - (J ■♦-> ag DC

■f- 0J ^ c tn Q, LU ra 3 <: rM JZ x: CJ z u o o OJ ra z a: £ m <=> CD

w •-< I ■o ra I- S C £ Q. ^ ra Di z

vt : oo ;

ra o< _j -^ +J < u i- ^ t a) OJ CJ <; +J 4J o i— ro ra DZ LU z: 3 oo co

CM +> CD I u^

to OJ ^a- r^, -i-^ao

I- Q-<—

O < r-'

iQP <£ -.—

m to

i~r~ OJ O XI "O o. ro o 0) 4<> u

ro >— CJ

tn c: i~ OJ in c OJ 3 c: c o u Q •!- •^ -^ j- « ra ■»-> OJ i- t- -r- o. • -M 4»'C J- in in C CTi O)

O O- XI QJ 01 U XI t-

I— "D 3 0J xi cn c i- i racra i~r- -a * OJ TJ to OJ "a > ra CM jr p o o u C

QJ OJ OJ OJ t. u OJ t. x:

■i- S ■♦J -^ OJ <— -M wi en u OJ 1-

rau r—^ •— TJ ■— tn

u QJ ro OJ -o -^ +J u ^ OJ E ra -f- u

4-> ro (D-r- c ■»- c -i- o -i- XJ >, trt >, ■r- T3 w (J O

X TD "5 I. -P OJ c o

ra tn 4- +J l/l "O 3 ■O O O 4-» O o T- i- ra JD u +J j- ra

ra -o ^ a* +J OJ M m i— O in c .* ■*-> -o O S- u c s- OJ 3 OJ a;

JD T3 X) ^- xa ' C JD e 3 >, ra OJ 5 »— i- x; c a>.— ra +-> •.- c ro a. E -^ u E +J 3 i—i- o ro

.— .*: r- (J ro CJ o to i 3 r^ i/i c

ra xi CJ -i- o -M •r- OJ c OJ x: en

E »- ra TJ ^ > a. E ra s-

QJ OJ O C 3 • ^ t. -o i— .^ o .Q O •^ TD S- QJ wi QJ in c j= QJ E >~ ra QJ f~ oi-"-

r- OJ i i OJ • 0) OJ -C -i- E "O c

IF- . t > +J ,_ O co in^r- oioj <— o OJ*"- c-r-ramf—4-T- w><—■*-> OJ(J->-O oEOjramra +J3i-l--CJ J-J o ^-aojoramCMOJ oi-*- m rt J_I i i-i m r~ 5 QJ C r—

r— T- Q. U) O r— Q. — >,.* ro OJ U U > 3 S-

_ OJ cnjD 0J O i— C X3

^,->- -^ QJ X w .t C-MTDTDTDJZO > QJ -*-J raiojrara-Mtn QJ<— -XITDD-OO JD s-jDccuraE"—>— "ra

ra o o ora TD rtj+j ..-oi—"O-MOJOJ^

rain-t->c c.c4-»(j T30i-i->-i- aj^ro-Mrao oi a.oT3T3^ (j ■*-> a..c <JOJ QJC QJt— •<- inOJ-i-m ct.M-oj ^zcintn QJ *t-oo X03tnl4-

■»- OJ QJ J= ■ o ra -r- o j,i. -MmOJin CIT? OJOJOJC) -MCOJOJ >■, CLX^/)roln30^ncDln■•-, x i-cLTDc-i-o* ra-^ QJinQjEO'i--i->JZ S p—

•»->>-r-S-Era(— « v ■n ui X) i ■— in >,Xi cOJraaj-os-'— r-enra ra-M l_OJOJ-i- ■ Of b a.

o Q-i— o. CJ m > OJ ra »CJC Jii Wi— OJCU

trt'r- tnuinOQj.— OJ en £ X7 4-J 3 CU > t/l OJ ra OJT-XJXTTD OJ-O-P 5 ocs CJror-ra30 o>,oo>»co o Q-x: u-axr-Mt— •i-r—-eji— c m

VI ro « ra CM f— O ■»-> T)

ccmOJU ra^m^-p Ora+J-P-r-TJ-i- QJOC

■r- (Jl~+JC4->+->4-> ■i->oroajrara'^3 +* QJ ra-'-CL>+J CD-UCN 0.+-» E 0J tnCMT--i-»T- 3 c

■r-nJ.,-!. 0 3+JQO in4-» Qj.-aoraEi- ininxJi— .COQJ •Mra^a

*i- c ra -M J TD in i T30J0J-<- coc OJE

x: i i-M-0J.craQJC7i3 s^+JTDiuoojin jrt-c en O+J 5 +J43re.^. t-Jzl-ratn-Ptn3 r— E

i-i-l— -r-j-QJ+J EQJ0J"OO-O 3 '—3 JZ COQJ >xioc-t->ro«— ro ^ojojoajroju tmt- ro 4Jtn* x: j—x:3in OJOJI in-i-OJ^-POJ +JC>T3-0+JTDCJro >^(rti-cn jr- OIOJC3C-U i-Qj3t->,+jaj •■4-»+JQJ<— ro-M-i-oi

— Q.^ ■!-> -r- in X3

QJ -t-= s^ OJ o -f ra i- CL E 3 c cnT) ■— EQjT3jDOracra

" E ra ■»-> en >, Q.+J en-o u c •. , ,, <=jz;E3caJ OJ rooi^,

■r- OJ CL-f- 4-> 0J>x:>— ^i— OC OJ >, m OJ+J ci— ra tn-i- o cxmr—4->T-r— t.

D> •r-^^a.roCTirammra ^30 S-l-E u-1-.c aj-^ouinojroi QjraoaJ30(D.ra T3i-'r-"a'—-MOJ "Or-oxrxi'^ i- oEcjDra»— C_£.+J +-»C)JIQJ-O rooroojen

■" ■ — +J 4_> (0 ' ^ "

i/> ra ro o • : ro+J-f-M- ai o ^-.aj ro OJ-I-

: x: M- TD tn o. C in i <C x: <

J