section ii...section ii common trade name manufacturer/supplier name abs pipe & fittings...

SECTION II

Common Trade Name Manufacturer/Supplier Name ABS Pipe & Fittings Charlotte Pipe Adhesive Lubricant Jones / Blair AV-202 Multigrout Avanti Casting, Gray Iron Charlotte Pipe Chlorinating Tablets Arch Systems Concrete/Concrete Products Rinker Concrete Pipe County Materials Corp. Concrete, Ready-Mixed Carew Ductile Iron Neenah Foundry Ease-on Pipe Lubricant Seacord Gray Iron Neenah Foundry Pipe Dope Black Swan Pipe Joint Compound Black Swan Pipe Stick Black Swan Purple PVC Primer Black Swan PVC Cement Black Swan PVC Cement Oatley PVC Pipe & Fittings Charlotte Pipe Re-Crete Dayton Superior Speed Crete Blue Line Euclid Water-Base Coating PCT White Masonry Cement Rinerk White Portland Cement Rinker

ABS Pipe and Fittings

Date updated: 10/27/14

SAFETY DATA SHEET

Revision Date: 10/27/2014 Page 1 of 8

1. PRODUCT AND COMPANY IDENTIFICATION

COMMON NAME: ABS Pipe and Fittings

CHEMICAL NAME: Not Applicable. Formulation, see section 3.

FORMULA: Mixture

PRODUCT CAS NO.: Mixture, see section 3.

Recommended Use: Drain Waste and Vent Pipe and Fittings

SUPPLIER: Charlotte Pipe and Foundry Company (Plastics Division)

ADDRESS: 4210 Old Charlotte Highway

CITY, STATE, ZIP: Monroe, NC 28110

PHONE: +1-704-372-3650 EMERGENCY PHONE: +1-704-372-3650

2. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW Toxic and irritating gases and fumes may be given off during burning or thermal decomposition. Avoid generating dust. Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard.

GHS Status This material is hazardous in accordance with the hazard communication standard, 29 CFR

1910.1200 Classification of the substance or mixture

Skin irritation – Category 2

Eye irritation – Category 2 B Carcinogenicity – Category 2 GHS label pictogram Health hazard. Signal word Warning Hazard statements Causes eye irritation.



SAFETY DATA SHEET


Causes skin irritation. Suspected of causing cancer if inhaled. Precautionary statements Prevention Obtain special instructions before use. Do not handle until all safety precautions have been

read and understood. Wear protective breathing gear, such as an N95 or P95 respirator. Wash skin thoroughly after handling.

Response If on skin: wash with plenty of water. If in eyes. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse.

Storage Keep away from intense heat, flames. Store locked up. Disposal Dispose of in accordance with local regulations. Hazards not otherwise classified

None known.

Relevant routes of exposure

Skin, eyes, inhalation.

Inhalation Melted product is flammable and produces intense heat and dense smoke during burning. Irritating gases and fumes may be given off during burning or thermal decomposition.

Skin contact May cause allergic reaction. Eye contact No data available. Ingestion No data available.

3. HAZARDOUS INGREDIENTS: COMPOSITION/INFORMATION

INGREDIENT %

WEIGHT

PEL-OSHA

TLV-ACGIH

NIOSH REL

Acrylonitrile Butadiene Styrene CAS 9003-56-9

95 - 100 None established for ABS Particulates not otherwise classified: 15 mg/m3

None Established for ABS Particulates not otherwise classified: 10 mg/m3 (inhalable fraction)

None established

Corn oil CAS 8001-30-7

0 - 3 Vegetable oil: 5 mg/m3 (PEL, respirable fraction) 15 mg/m3 (PEL, total dust)

10 mg/m3 (8-hour TWA)

Vegetable oil mist: 10 mg/m3 (total TWA)

Carbon black CAS 1333-86-4

0 - 2 3.5 mg/m3 (TWA) 3.0 mg/m3 (TWA)

3.5 mg/m3 (TWA)

Polyvinyl chloride CAS 9002-86-2

<4% None established Particulates not otherwise classified: 15 mg/m3

1 mg/m3 (respirable fraction) Particulates not otherwise

None established



SAFETY DATA SHEET


classified: 10 mg/m3 (inhalable fraction)

Titanium dioxide CAS 13463-67-7

Less than 0.5%

15 mg/m3, total dust 10 mg/m3 TWA None established

4. FIRST AID MEASURES EYE CONTACT: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. SKIN CONTACT: Rinse with water. Remove contaminated clothing and shoes. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes before reuse. INHALATION: If vapors from excessive heating, burning or decomposition products are inhaled: remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular, or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing, such as collar, tie, belt, or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance. INGESTION: Wash out mouth with water. Remove dentures, if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Loosen tight clothing, such as collar, tie, belt, or waistband. Notes to physician: In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under surveillance for 48 hours Specific treatments: None known

5. FIRE FIGHTING MEASURES

FLAMMABLE PROPERTIES FLASH POINT: 388-400°C (730-752°F) Decomposition products may be combustible. FLAMMABLE LIMITS: LEL: No Data UEL: No data EXTINGUISHING MEDIA: Use media appropriate for surrounding fire. FIRE AND EXPLOSION HAZARDS: Thermal decomposition may produce carbon dioxide, carbon monoxide, nitrogen oxides, sulfur oxides, halogenated compounds, and metal oxide/oxides. PROTECTIVE MEASURES FOR FIRE FIGHTERS: Firefighters must wear a NIOSH-approved, full-face piece self-contained breathing apparatus (SCBA) operated in positive pressure mode and full turnout or bunker gear with additional chemical protective clothing as necessary to protect against thermal decomposition products. SPECIAL PROTECTIVE ACTIONS FOR FIRE FIGHTERS: If there is a fire, promptly isolate the scene by removing all persons from the vicinity of the incident. No action shall be taken involving any personal risk or without suitable training.



SAFETY DATA SHEET


6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment, and emergency measures For non-emergency personnel

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

For emergency responders If specialized clothing is required to deal with decomposition products or fumes from burning or excessive heating, take note of information in Section 8 on suitable and unsuitable materials. See also information in “for non-emergency personnel.”

Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains, and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil, or air).

Methods and materials for containment and clean-up Small spill Avoid dust generation. Vacuum dust with equipment fitted with a HEPA filter

and place in a closed, labeled waste container. See Section 1 for emergency contact information.

Large spill Move containers from spill area. Approach release from upwind. Prevent entry into sewers, waterways, basements, and confined areas. Avoid dust generation. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. See Section 1 for emergency contact information.

7. HANDLING AND STORAGE Conditions for safe storage, including any incompatibilities

Store in a dry place away from direct sunlight, heat, and incompatible materials. Avoid intense heat and flames.

Precautions for safe handling Protective measures Put on appropriate personal protective equipment (see Section 8). Do not

handle until all safety precautions have been read and understood. Do not get particles, vapors or fumes in eyes, on skin, or on clothing. Do not ingest. If during normal use, the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator.

Advice on general occupational hygiene

Employees must wash hands and face before eating, drinking, or smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also section 8 for additional information on hygiene measures.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation, or other engineering controls to keep worker exposure to airborne contaminants below recommended and statutory limits. RESPIRATORY PROTECTION: Cutting or sanding this product can generate dust. Used a properly fitted particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product, and the safe working limits of the respirator. A NIOSH-approved N95 single use or P95 multiple use respirator will protect the employee from at least 95% of airborne particles. Follow the respirator manufacture’s instructions for proper use. If adhesives or other substances are used with this



SAFETY DATA SHEET


product, refer to the product manufacturer’s safety data sheet for applicable respiratory protective measures. SKIN PROTECTION: Chemical-resistant, impervious gloves complying with an approved standard should be worn when handling this or any chemical product, if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures containing several substances, the protection time of the gloves cannot be accurately estimated. If adhesives or other substances are used with this product, refer to the product manufacturer’s safety data sheet for applicable skin protective measures. BODY PROTECTION: Personal protective equipment for the body should be selected on the task being performed and the risks involved, and should be approved by a specialist before handling this product. If adhesives or other substances are used with this product, refer to the product manufacturer’s safety data sheet for applicable skin protective measures. EYE/FACE PROTECTION: Safety eyewear complying with an approved standard must be used when a risk assessment indicates this is necessary to avoid exposure to dust. Particulates and dust can be formed when cutting, grinding or sanding this product. If contact with dust or particulates is possible, the following should be worn unless the assessment indicates a higher degree of protection: safety glasses with side shields. If adhesives or other substances are used with this product, refer to the product manufacturer’s safety data sheet for applicable eye and face protective measures.

9. PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE: Solid. Black. ODOR: Slight, sweet, aromatic. ODOR THRESHOLD: Not available BOILING POINT: Not available FLASH POINT: 388-400°C (730-752°F) FLAMMABILITY: Melted product is flammable. AUTOIGNITION TEMPERATURE: 495-510°C (923-950°F) DECOMPOSITION TEMPERATURE: Approximately 260°C (500°F) LOWER/UPPER EXPLOSION LIMITS: Not available VAPOR PRESSURE: Not available LIQUID DENSITY: Not available SPECIFIC GRAVITY: Approximately 1.05 MELTING POINT: Not available pH: Not available SOLUBILITY: Insoluble % VOLATILE: Not available VISCOSITY: Not available

10. STABILITY AND REACTIVITY Stability: Stable at normal temperatures and pressures.



SAFETY DATA SHEET


Reactivity: Stable at normal temperatures and pressures.

Conditions to avoid: Heat, flames, sparks and other sources of ignition.

Incompatible materials/conditions: Consult the Charlotte Pipe and Foundry chemical resistance guide.

Hazardous decomposition products: Hydrogen chloride, carbon oxides, small amounts of benzene and aromatic and aliphatic hydrocarbons, phosgene.

Hazardous polymerization: Not available.

11. TOXICOLOGICAL INFORMATION ACUTE TOXICITY: No toxicological data is available for the finished product. SENSITIZATION: No data available.

MUTAGENICITY: No data available.

DEVELEPMENTAL: No data available.

Fertility: No data available.

CARCINOGENICITY: This product contains Carbon Black, which is classified by the International Agency for Research on Cancer as 2B: possibly carcinogenic to humans. Not listed on the National Toxicology Program Report on Carcinogens or OSHA Subpart Z. REPRODUCTIVE TOXICITY: Not available

TERATOGENICITY: Not available

SPECIFIC TARGET ORGANS – SINGLE EXPOSURE: Not available

SPECIFIC TARGET ORGANS – REPEATED EXPOSURE: Not available

ASPIRATION HAZARD: Not available

INFORMATION ON THE LIKELY ROUTES OF EXPOSURE: Potential acute health effects

Eye contact No known significant effects or critical hazards. Dust can cause eye irritation. Inhalation Exposure to decomposition products may cause a health hazard. Serious effects

may be delayed following exposure. Skin contact Skin irritant. Ingestion No known significant effects or critical hazards.

Symptoms related to the physical, chemical, and toxicological characteristics

Eye contact No data available. Inhalation No data available Skin contact Adverse symptoms may include irritation. Ingestion No data available



SAFETY DATA SHEET


Immediate, delayed and chronic effects from short term exposure

Short term exposure

Potential immediate effects No data available. Potential delayed effects No data available

Long term exposure


Potential chronic effects

General No data available. Carcinogenicity May cause cancer. Risk of cancer depends on duration and level of exposure.

12. ECOLOGICAL INFORMATION

Numerical measures of toxicity No data available Persistence and degradability Does not biodegrade over time. Bioaccumulative potential No data available Mobility in soil No data available. Other adverse effects: No known significant or critical hazards.

13. DISPOSAL CONSIDERATIONS

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, and by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste should not be disposed of to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material must be disposed of in a safe way.

14. TRANSPORT INFORMATION

PROPER SHIPPING NAME: Not Regulated HAZARD CLASS: Not Regulated



SAFETY DATA SHEET


IDENTIFICATION NUMBER: Not Regulated SHIPPING LABEL: Not Regulated PACKING GROUP: Not Regulated

15. REGULATORY INFORMATION United States

TSCA 8(b): All ingredients are listed on the U.S. Toxic Substances Control Act inventory.

Airborne unbound particles of carbon black of respirable size are listed as being carcinogenic per California Proposition 65.

16. OTHER INFORMATION Date of Preparation: 23 October 2014 Key To Acronyms: CAS: Chemical Abstracts Service CFR: Code of Federal Regulations HEPA High-Efficiency Particulate Air (filter) IARC: International Agency for Research on Cancer LD50 Lethal dose to 50% of exposed laboratory animals LC50 Lethal concentration to 50% of exposed laboratory animals LEL: Lower Explosive Limit mg/l Milligrams per liter NIOSH: National Institute for Occupational Safety and Health (US) NTP: National Toxicology Program OSHA: Occupational Safety and Health Administration (US) PEL: Permissible Exposure Limit TSCA Toxic Substances Control Act TLV: Threshold Limit Value – American Conference of Governmental Industrial Hygienists (ACGIH) TWA: Time Weighted Average UEL: Upper Explosive Limit ug/ m3 Micrograms per cubic meter

DISCLAIMER NO WARRANTY OF MERCHANTABILITY OR OF FITNESS FOR A PARTICULAR PURPOSE, OR WARRANTY OR GUARANTY OF ANY OTHER KIND, EXPRESS OR IMPLIED, IS MADE REGARDING PERFORMANCE, SAFETY, SUITABILITY, STABILITY OR OTHERWISE FOR THE ABS MATERIALS AS REPRESENTED IN THIS MSDS SHEET. Charlotte Pipe and Foundry assumes no liability whatsoever for the use of or reliance upon this information. The information and data contained in this MSDS has been compiled from information believed to be accurate and is offered for your consideration, investigation and verification. Buyer assumes all risk of use, storage, handling and disposal of the product in compliance with applicable



SAFETY DATA SHEET


federal, state, and local laws and regulations.

Material Safety Data Sheet Revision Date: 04-17-2015

Product Code: 8510

Page 1 of 6

I. PRODUCT AND COMPANY IDENTIFICATION Product Name: ADHESIVE LUBRICANT BLACK 5-B-1Product Code: 8510 Document ID: M8510 Company: JONES-BLAIR® Company

2728 Empire Central Dallas, TX 75235 1-214-353-1600

Revision Number: 2 Prior Version Date: 09-01-2009 Chemical Family: LUBRICANT Intended use: Adhesion Promoter for Paint Emergency Contact: ChemTrec Center Emergency Phone: 1-800-424-9300 International: 703-527-3887

II. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW: WARNING! Flammable liquid and vapor. Causes eye irritation. Vapor harmful. Harmful or fatal if swallowed.

Routes of Entry: • Inhalation • Skin contact • Eye contact

Target Organs Potentially Affected by Exposure:

• Central nervous system • Skin • Respiratory Tract • Eyes • Kidneys • Liver • Blood

Medical Conditions Aggravated by Exposure:

• Skin disorders. • Respiratory disorders, including but not limited to asthma and bronchitis. • Eye disorders. • Liver disease • Kidney disease •

Immediate (Acute) Health Effects by Route of Exposure: Inhalation Toxicity: Vapor harmful. May affect the brain or nervous system causing dizziness, headache or

nausea. Skin Contact: Can cause moderate skin irritation. Skin Absorption: May be harmful if absorbed through skin. Eye Contact: Causes eye irritation. Ingestion Toxicity: Aspiration of material into the lungs can cause chemical pneumonitis which can be fatal. Long-Term (Chronic) Health Effects: Carcinogenicity: Possible cancer hazard. Contains ethylbenzene which may cause cancer based on animal

data. (Risk of cancer depends on duration and level of exposure.) Possible cancer hazard. Contains carbon black which may cause cancer based on animal


Product Code: 8510

Page 2 of 6

data. (Risk of cancer depends on duration and level of exposure.) Reproductive and Developmental Toxicity:

Xylene may cause adverse reproductive and/or developmental effects. Pregnant women may be at an increased risk from exposure.

Mutagenicity: Xylene has been shown to be positive in mutagenicity assays. Inhalation: NOTICE: Reports have associated repeated and prolonged occupational overexposure to

solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.

III. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name % CAS # Xylene 40 - 60 1330-20-7 Heavy aromatic solvent naphtha (Petroleum) 10 - 30 64742-94-5 Ethylbenzene 5 - 10 100-41-4 Phenolic Resin 1 - 5 Not Available Carbon black 1 - 5 1333-86-4 Naphthalene 1 - 5 91-20-3

IV. FIRST-AID MEASURES

Inhalation: Remove to fresh air. If breathing is difficult, have a trained individual administer oxygen. Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get

medical attention immediately. Skin Contact: Wash with soap and water. Remove contaminated clothing and launder. Get medical attention if

irritation develops or persists. Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately. Induce vomiting as a

last measure. Induced vomiting may lead to aspiration of the material into the lungs potentially causing chemical pneumonitis that may be fatal.

Notes to Doctor: No additional first aid information available V. FIRE FIGHTING MEASURES

Flammability Summary: Flammable liquid and vapor. Extinguishing Media: Use alcohol resistant foam, carbon dioxide, or dry chemical extinguishing

agents. Water spray or fog may also be effective for extinguishing if swept across the base of the fire. Water can also be used to absorb heat and minimize fire damage.

Fire and/or Explosion Hazards: Vapors may be ignited by sparks, flames or other sources of ignition if material is above the flash point giving rise to a fire (Class B). Vapors are heavier than air and may travel to a source of ignition and flash back. Container may explode in heat of fire. Empty containers that retain product residue (liquid, solid/sludge, or vapor) can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Any of these actions can potentially cause an explosion that may lead to injury or death.

Fire Fighting Methods and Protection: Do not enter fire area without proper protection including self-contained breathing apparatus and full protective equipment. Fight fire from a safe distance and a protected location due to the potential of hazardous vapors and decomposition products. Flammable component(s) of this material may be lighter than water and burn while floating on the surface.

Hazardous Combustion Products: Carbon dioxide, Carbon monoxide, Sulfur containing gases Flash Point (°F/°C): 83 / 28 Autoignition Temperature (°F/°C): 810.0 / 432.0 Lower Flammable/Explosive Limit, % in air: 0.9 Upper Flammable/Explosive Limit, % in air: 7.0


Product Code: 8510

Page 3 of 6

VI. ACCIDENTAL RELEASE MEASURES

Personal Precautions and Equipment: Exposure to the spilled material may be irritating or harmful. Follow personal protective equipment recommendations found in Section VIII of this MSDS. Additional precautions may be necessary based on special circumstances created by the spill including the material spilled, the quantity of the spill, the area in which the spill occurred. Also consider the expertise of employees in the area responding to the spill.

Methods for Clean-up: Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so. Dike with suitable absorbent material. Gather and store in a sealed container pending disposal.

VII. HANDLING AND STORAGE

Handling Technical Measures and Precautions: Harmful or irritating material. Avoid contacting and avoid breathing the material. Use only in a well ventilated area. Follow all protective equipment recommendations provided in Section VIII. Use spark-proof tools and explosion-proof equipment.

Storage Technical Measures and Conditions: Store in a cool dry place. Keep container(s) closed. Keep away from sources of ignition.

VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Measures: Local exhaust ventilation or other engineering controls may be required when handling or using this product to avoid overexposure.

Respiratory Protection: General or local exhaust ventilation is the preferred means of protection. In cases where ventilation is inadequate, respiratory protection may be required to avoid overexposure. Follow respirator manufacturer's directions for respirator use.

Eye Protection: Wear safety glasses with side shields when handling this product. Wear additional eye protection such as chemical splash goggles and/or face shield when the possibility exists for eye contact with splashing or spraying liquid, or airborne material. Have an eye wash station available.

Skin Protection: Where use can result in skin contact, practice good personal hygiene. Wash hands and other exposed areas with mild soap and water before eating, drinking, and when leaving work. Clothing suitable to prevent skin contact. Wear chemical resistant gloves.

Control Parameters: Chemical Name ACGIH TLV-TWA ACGIH STEL OSHA PEL-TWA Xylene 100 ppm TWA; 434

mg/m³ TWA 150 ppm STEL; 651 mg/m3 STEL

100 ppm TWA; 435 mg/m³ TWA

Ethylbenzene 100 ppm TWA; 434 mg/m³ TWA

125 ppm STEL; 543 mg/m³ STEL

100 ppm TWA; 435 mg/m³ TWA

Carbon black 3.5 mg/m3 TWA 3.5 mg/m3 TWA Naphthalene 10 ppm TWA; 52 mg/m3

TWA 15 ppm STEL; 79 mg/m3 STEL

10 ppm TWA; 50 mg/m3 TWA

IX. PHYSICAL AND CHEMICAL PROPERTIES

Color: Black Physical State: LiquidBoiling Point - Low (°F): 276.8 Boiling Point - High (°F): 380.0Evaporation Rate: 116.00 Ethyl Ether Odor: No data available pH (target): No data available


Product Code: 8510

Page 4 of 6

Vapor Density: 4.00 (air = 1)Vapor Pressure: 68° F 10.00 MM HG VOC (g/l) (Regulatory, Calculated): 734.36

(Actual, Calculated): 734.36 Solubility in Water: Negligible; 0-1% Octanol/Water Partition Coefficient: No data available Volatiles, % by Volume (Calculated): 84.36 Volatiles, % by weight (Calculated): 78.82Density: 7.65 - 7.85 lbs./Gal. Physical and Chemical Properties are calculated target or range values for single packaged items and do not represent compliance values for multi-component (mixed) systems. X. STABILITY AND REACTIVITY

Stability: Stable under normal conditions. Conditions to Avoid: Sparks, open flame, other ignition sources, and elevated

temperatures. Contamination. Materials to Avoid/Chemical Incompatibility: Oxidizing agents Polymerization: Will not occur.Hazardous Decomposition Products: Carbon dioxide, Carbon monoxide, Sulfur containing gases XI. TOXICOLOGICAL INFORMATION

Component Toxicology Data: Chemical Name CAS Number LD50/LC50Xylene 1330-20-7 Oral LD50 Rat 3523 mg/kg

Dermal LD50 Rabbit 1100 mg/kg Inhalation LC50 (4h) Rat 11.00 mg/L

Ethylbenzene 100-41-4 Oral LD50 Rat 3500 mg/kg Dermal LD50 Rabbit 5510 mg/kg Inhalation LC50 (4h) Rat 17.00 mg/L

Carbon black 1333-86-4 Oral LD50 Rat > 8000 mg/kg Dermal LD50 Rabbit > 2000 mg/kg

Naphthalene 91-20-3 Dermal LD50 Rabbit > 20 g/kg Inhalation LC50 Rat > 340.00 mg/m³

Carcinogens: Chemical Name CAS Number IARC NTP OSHAEthylbenzene 100-41-4 2B Carbon black 1333-86-4 2B Naphthalene 91-20-3 2B 2

XII. ECOLOGICAL INFORMATION

Toxicity data, if available, are listed below.Overview: No data available Mobility: No data available XIII. DISPOSAL CONSIDERATIONS

Disposal Methods: Refer to other sections of this MSDS to determine the toxicity and physical characteristics of the material to determine the proper waste identification and disposal in compliance with applicable regulations.

XIV. TRANSPORTATION INFORMATION

This section provides basic shipping classification information and does not contain all regulatory transportation


Product Code: 8510

Page 5 of 6

details. Refer to all applicable regulations for domestic, international, air, vessel and ground transportation requirements and restrictions. DOT Basic Description: Adhesive Hazard Class: 3 UN Number: UN1133 Packing Group: III Other: This product qualifies for a limited quantity exception per CFR173.150(b)(3) for inner

containers <= 1.3 gallons (5L) and total gross package wt <= 66 lbs (30kg). IATA Air Shipping Name: Adhesive IATA Hazard Class: 3 IATA UN Number: UN1133 IATA Packing Group: III Marine Pollutant: No

XV. REGULATORY INFORMATION

United States Federal Regulations: TSCA Status All components of this product are either listed on the TSCA Inventory; or, are not subject to the

inventory notification requirements. SARA EHS Chemicals CAS # %Formaldehyde 50-00-0 0.001- 0.01

CERCLA Xylene (mixed isomers) 1330-20-7 40 - 60Ethyl Benzene 100-41-4 5 - 10 Naphthalene 91-20-3 1 - 5

SARA 313 Xylene (mixed isomers) 1330-20-7 40 - 60Ethylbenzene 100-41-4 5 - 10 Naphthalene 91-20-3 1 - 5

SARA 311/312 Health (Acute): Y Health (chronic): Y Fire (Flammable): Y Pressure: N Reactivity: N

U. S. State Regulations: California Prop 65 Chemicals Cancer CAS # %Ethyl Benzene 100-41-4 5 - 10Carbon Black 1333-86-4 1 - 5 Naphthalene 91-20-3 1 - 5Benzene 71-43-2 0.001- 0.01 Formaldehyde 50-00-0 0.001- 0.01Lead 7439-92-1 < 1 ppm

Reproductive Toluene 108-88-3 0.1 - 1 Benzene 71-43-2 0.001- 0.01Lead 7439-92-1 < 1 ppm


Product Code: 8510

Page 6 of 6

Canadian Regulations: CEPA DSL: The components of this product ARE listed on the Canadian Domestic Substances

List. WHMIS Hazard Class: B2 D2A

XVI. ADDITIONAL INFORMATION

Prepared By: Regulatory DepartmentDisclaimer: This MSDS has been prepared in accordance with the OSHA Hazard Communication

Standard (29 CFR 1910.1200) and Canada's Controlled Product Regulations (CPR). To the best of our knowledge the information contained herein is accurate. Determination of safe handling, application and use of this material is the responsibility of the end user. This information is furnished without warranty, expressed or implied.

Print Date: April 17, 2015

AV-202 Multigrout Page 1 of 7

AV-202 MULTIGROUT® SAFETY DATA SHEET

Rev. 09/13/2016

GHS Product Identifier: AV-202 Multigrout Classification: Hydrophilic Foam Product Use: Industrial Use Only Supplier 24 HR. EMERGENCY TELEPHONE NUMBER Avanti International Chemtrec: 800.424.9300 1100 Hercules Ave., Suite 320 Houston, TX 77058 Phone: 800.877.2570 Fax: 281.486.7300

GHS Classification

Hazard Class Category Resp. sens. 1 Respiratory sensitization Skin sens. 1 Skin sensitization

GHS Label Elements Hazard pictograms:

Signal Word: Danger Hazards Statements: H315 Causes skin irritation. H317 May cause an allergic skin reaction. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Precautionary Statements: Prevention: P261 Avoid breathing vapors, spray or mist. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear eye protection, protective clothing and protective gloves.

P284

In case of inadequate ventilation wear respiratory protection. The type of respiratory protection selected must comply with the requirements set forth in OSHA's Respiratory Protection Standard (29 CFR 1910.134) or regional standards. For additional details, see Section 8 of the SDS.

P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P333 + P313 If skin irritation or rash occurs, get medical advice/attention. P362 + P364 Take off contaminated clothing and wash it before reuse. P501 Dispose of contents/container according to local, regional, national, and international

regulations.

Other hazards not contributing to classification: Exposure may aggravate those with pre-existing eye, skin, or respiratory conditions. Unknown Acute Toxicity (GHS-US): No data available

Section 1: Identification

Section 2: Hazards Identification


Labeling of special preparations (GHS): Contains isocyanates. Inhalation of isocyanate mists/vapors may cause respiratory irritation, breathlessness, chest discomfort and reduced pulmonary functions. Overexposure well above the PEL may result in bronchitis, bronchial spasms and pulmonary edema. Long-term exposure to isocyanates has been reported to cause lung damage, including reduced lung function which may be permanent. Acute or chronic overexposure to isocyanates may cause sensitization in some individuals, resulting in allergic respiratory reactions including wheezing, shortness of breath and difficulty breathing. Animal tests indicate that skin contact may play a role in causing respiratory sensitization.

Weight % Components CAS-No. Classification 45 - 55%

Oxirane, methyl-, polymer with oxirane, ether with 1,2,3-propanetriol (3:1), polymer with 1,1'-methylenebis[4-isocyanatobenzene]

(CAS #) 59675-67-1 Resp. Sens. 1, H334 Skin Sens. 1, H317

45 - 55%

Poly[oxy(methyl-1,2-thanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,3-diisocyanato-2-methylbenzene and 2,4-diisicyanato-1-methylbenzene

(CAS #) 64814-10-4 Not Classified

Full text of H-phrases: See section 16

Description of First-Aid Measures First-aid Measures General Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid Measures After Inhalation When symptoms occur: go into open air and ventilate suspected area. Remove to fresh air and keep at rest in a position comfortable for breathing. Obtain medical attention if breathing difficulty persists. First-aid Measures After Skin Contact Remove contaminated clothing. Gently wash with plenty of soap and water followed by rinsing with water for at least 15 minutes. Call a Poison Center or doctor/physician if you feel unwell. Wash contaminated clothing before reuse. First-aid Measures After Eye Contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention. First-aid Measures After Ingestion Rinse mouth. Do not induce vomiting. Immediately call a Poison Center or doctor/physician. Most Important Symptoms and Effects, Both Acute and Delayed Symptoms/Injuries: Causes skin irritation. May be fatal if swallowed and enters airways. May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Symptoms/Injuries After Inhalation: MDI vapors or mist at concentrations above the TLV can irritate (burning sensation) the mucous membranes in the respiratory tract (nose, throat, and lungs) causing runny nose, sore throat, coughing, chest discomfort, shortness of breath and reduced lung function (breathing obstruction). Persons with a preexisting, nonspecific bronchial hyperactivity can respond to concentrations below the TLV with similar symptoms as well as asthma attack. Exposure well above the TLV may lead to bronchitis, bronchial spasm and pulmonary edema (fluid in lungs). These effects are usually reversible. Chemical or hypersensitive pneumonitis, with flu-like symptoms (e.g., fever and chills) has also been reported. These symptoms can be delayed up to several hours after exposure. Symptoms/Injuries After Skin Contact: Isocyanates react with skin protein and moisture, and can cause irritation, which may include the following symptoms; reddening, swelling, rash, scaling or blistering. Cured material is difficult to remove. Symptoms/Injuries After Eye Contact: liquid, aerosols or vapors are irritating and can cause tearing, reddening and

Section 3: Composition/Information on Ingredients

Section 4: First-Aid Measures


swelling. If left untreated, corneal damage can occur and injury is slow to heal. However, damage is usually reversible (see Emergency and first aid procedures). Symptoms/Injuries After Ingestion: can result in irritation and corrosive action in the mouth, stomach tissue and digestive tract. Symptoms can include sore throat, abdominal pain, nausea, vomiting and diarrhea. Chronic Symptoms: As a result of previous repeated overexposures, or single large dose, certain individuals develop symptoms to isocyanates at levels way below TLV. These symptoms, which can include chest tightness, wheezing, cough; shortness of breath, or asthma attack could be immediate or delayed up to several hours after exposure, similar to many non-specific asthmatic responses. There are reports that once sensitized an individual can experience these symptoms upon exposure to dust, cold air or other irritants. This increased lung sensitivity can persist for weeks and in severe cases for several years. Overexposure to isocyanates has also been reported to cause lung damage, including decrease in lung function), which may be permanent. Sensitization can either be temporary or permanent. If exposed or concerned, get medical advice and attention.

Suitable Extinguishing Media: Water spray, fog, alcohol-resistant foam, carbon dioxide (CO2), dry

chemical powder. Unsuitable Extinguishing Media: Do not use a heavy water stream. A heavy water stream may spread

burning liquid. Special Hazards Arising from Substance or Mixture

Fire Hazard: Not flammable but will support combustion. Explosion Hazard: Product is not explosive. Reactivity: Hazardous reactions will not occur under normal conditions.

Fire-fighting Procedure Exercise caution when fighting any chemical fire. Use water spray or fog for cooling exposed containers. In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. Do not enter fire area without proper protective equipment, including respiratory protection.

Other information Do not allow run-off from firefighting to enter drains or water sources. Do not allow the product to be released into the environment.

Personal Precautions, Protective Equipment and Emergency Procedures General Measures Avoid all contact with skin, eyes, or clothing. Avoid breathing (vapor, mist, spray). For Non-emergency Personnel Protective Equipment: Use appropriate personal protection equipment (PPE). Emergency Procedures: Evacuate unnecessary personnel. For Emergency Responders Protective Equipment: Equip cleanup crew with proper protection. Emergency Procedures: Stop leak if safe to do so. Eliminate ignition sources. Ventilate area. Environmental Precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Methods and Material for Containment and Cleaning-Up For Containment: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. Methods for Cleaning Up: Clear up spills immediately and dispose of waste safely. Spills should be contained with mechanical barriers. Transfer spilled material to a suitable container for disposal. Contact competent authorities after a spill. Reference to Other Sections See Section 8. Exposure controls and personal protection.

Section 5: Fire-Fighting Measures

Section 6: Accidental Release Measures


Precautions for Safe Handling Any proposed use of this product in elevated-temperature processes should be thoroughly evaluated to assure that safe operating conditions are established and maintained. Avoid contact with skin and eyes. Hygiene Measures Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Conditions for Safe Storage (Including any incompatibilities) Technical Measures: Comply with applicable regulations. Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Keep/Store away from direct sunlight, extremely high or low temperatures and incompatible materials. Incompatible Products: Water, amines, strong bases, and alcohols. Incompatible Materials: Sources of ignition. Direct sunlight. Heat sources. Storage Temperature: 45˚F - 95°F Specific End Use(s): No additional information available.

Control Parameters For substances listed in section 3 that are not listed here, there are no established exposure limits from the manufacturer, supplier, importer, or the appropriate advisory agency including: ACGIH (TLV), NIOSH (REL), or OSHA (PEL). Exposure Controls Appropriate Engineering Controls: Ensure adequate ventilation, especially in confined areas. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure all national/local regulations are observed. Personal Protective Equipment: Protective goggles. Gloves. Protective clothing. Insufficient ventilation: wear respiratory protection.

Personal Protective Equipment Respiratory Protection: Use a NIOSH-approved respirator or self-contained breathing apparatus whenever exposure may exceed established Occupational Exposure Limits. Hand Protection: Wear chemically resistant protective gloves. Eye Protection: Chemical goggles or safety glasses Skin and Body Protection Wear suitable protective clothing. Environmental Exposure Controls Do not allow the product to be released into the environment. Consumer Exposure Controls Do not eat, drink or smoke during use.

Section 7: Handling and Storage

Section 8: Exposure Controls/Personal Protection


Appearance: Transparent, brown liquid Odor: Slightly musty odor Odor Threshold: No data available pH: No data available Freezing Point: <32˚F (<0˚C) Boiling Point: 406°F @ 5 mmHg for MDI (207.78°C) Flashpoint: higher than 212°F (100°C) Pensky-Martens closed cup (ASTM-D-93) Evaporation Rate: No data available Flammability: No data available Lower Explosion Limits: No data available Upper explosion limits: No data available Vapor Pressure: less than 10-5 mm Hg at 77° F (25°C) for MDI Vapor Density: 8.5 (MDI) (air – 1) Relative Density: No data available Solubility in Water: Not soluble. Reacts slowly with water to liberate CO2 gases Partition Coefficient n-octanol/water: No data available Auto-ignition Temperature: No data available Decomposition Temperature: No data available Specific Gravity: 1.147 @ 72°F (22°C) Viscosity: 3,200-6,000 cP @ 72°F (22°C)

Reactivity Hazardous reactions will not occur under normal conditions. Chemical stability Stable under recommended handling and storage conditions (see Section 7). Possibility of hazardous reactions May occur; contact with moisture, other materials, which react with isocyanates, or temperatures about 400˚F (204˚C) may cause polymerization. Conditions to avoid Contamination with water and high temperatures above 400°F (204°C). Incompatible materials Water, amines, strong bases, alcohols. Hazardous decomposition products By high heat and fire; carbon monoxide, oxides of nitrogen, traces of HCN, MDI vapors or aerosols

Acute Toxicity/Effects Not classified

Skin Corrosion/Irritation Causes skin irritation. Serious Eye Damage/Irritation Not classified Respiratory or Skin Sensitization May cause allergy or asthma symptoms or breathing

difficulties if inhaled. May cause an allergic skin reaction. Germ Cell Mutagenicity Not classified Carcinogenicity Not classified

Section 9: Physical and Chemical Properties

Section 10: Stability and Reactivity

Section 11: Toxicological Information


Reproductive Toxicity Not classified STOT (Single Exposure) Not classified STOT (Repeated Exposure) Not classified Aspiration Hazard May be fatal if swallowed and enters airways.

Toxicity Harmful to aquatic life when exposure exceeds 1 cm2/L Persistence and degradability May cause long-term adverse effects in the environment. Bioaccumulative potential Not established. Mobility in soil No additional information available. Other adverse effects Avoid release to the environment.

Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national, & international regulations. Sewage Waste Recommendations: Do not dispose of waste into sewer.

DOT (Department of Transportation) Proper Shipping Name: Liquid Resin (Non-Regulated) Hazard Class: Non-regulated UN Number: None Packing Group: None Label: Not applicable Placard: Not applicable NMFC (National Motor Freight Carriers) Freight Class: 55 IMO / IMDG CODE (OCEAN) HAZARD CLASS DIVISION NUMBER: Non-regulated/Not dangerous goods ICAO / IATA (AIR) HAZARD CLASS DIVISION NUMBER: Non-regulated/Not dangerous goods

US Federal Regulations SARA Section 311/312 Hazard Classes: Immediate (acute) health hazard Oxirane, methyl-, polymer with oxirane, ether with 1,2,3-propanetriol (3:1), polymer with 1,1'-methylenebis[4-isocyanatobenzene] (59675-67-1)

Listed on the United States TSCA (Toxic Substances Control Act) inventory

Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,3-diisocyanato-2

Section 12: Ecological Information

Section 13: Disposal Considerations

Section 14: Transport Information

Section 15: Regulatory Information


methylbenzene and 2,4-diisocyanato-1-methylbenzene (64814-10-4) Listed on the United States TSCA (Toxic Substances Control Act) inventory

US State Regulations Neither this product nor its chemical components appear on any US state lists.

Skin Sens. 1 H317 Skin sensitization Category 1 Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. NFPA 704M ratings:

Health

Flammability 1

Reactivity 1

Other

HMIS ratings: 0-Insignificate 1-Slight 2-Moderate 3-High 4-Extreme

Health 3

Flammability 1

Physical Hazard 1

Personal Protection H

The information provided in this Safety Data Sheet is correct to the best of Avanti International’s knowledge, information and belief at the date of this publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any other process, unless specified in the text. AVANTI INTERNATIONAL MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. Given the variety of factors that can affect the use and application of this product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. Each user is also responsible for evaluating the conditions of use and designing the appropriate protective mechanisms to prevent employee exposures, property damage, or release to the environment. Avanti International assumes no responsibility for injury to the recipient or third persons or for any damage to any property resulting from misuse of the product.

Section 16: Other Information

SDS-CI (1-12-15) Gray Iron Castings (SDS SC-000-041 Rev 12) Page 1 of 6

© 2013 American Foundry Society

Meets the Requirements of OSHA Standard 29 CFR 1910.1200 Hazard Communication and EPA Supplier Notification Requirements under Section 313 of the Emergency Planning and Community Right-to-Know Act.

SAFETY DATA SHEET (SDS)

GRAY IRON CASTINGS SDS SC-000-041 Rev. 12 DATE ISSUED 10/13

SECTION 1—PRODUCT IDENTIFICATION & COMPANY INFORMATION PRODUCT NAME

GRAY IRON CASTINGS OTHER DESIGNATIONS: ASTM (American Society for Testing & Materials) Specification No’s., (ACI (Alloy Casting Institute) Alloy Designations—

Grades)

ASTM: A48, A74, A126, A159, A278, A319, A667, A748, A823, A942 PRODUCT IDENTIFICATION (Label Identifier)

MANUFACTURER’S NAME

STREET ADDRESS

EMERGENCY TELEPHONE NO.

MAILING ADDRESS

TELEPHONE NO.

CITY, STATE, ZIP CODE, COUNTRY

FAX NO.

E-MAIL ADDRESS/WEBSITE

RECOMMENDED USE OF CHEMICAL AND RESTRICTIONS ON USE Solid casting; no restrictions

SECTION 2—HAZARD IDENTIFICATION CLASSIFICATION

Castings are metallic articles that do not present hazards in their original form. OTHER INFORMATION

1. Grinding castings that have not been cleaned or that contain embedded sand may generate significant amounts of dust containing crystalline silica.

2. Fumes from hot processes may contain other compounds with different exposure limits. Dust or fumes generated by machining, grinding, welding or thermal cutting of the casting may produce airborne contaminants. Consult Sections 3 & 8 for further information.

SECTION 3—COMPOSITION/INFORMATION ON INGREDIENTS

CHEMICAL NAME/COMMON NAME/SYNONYM Wt % CAS NUMBER Carbon (C) 2.5‒4.0 7440-44-0 Chromium (Cr) 0.01‒1.5 7440-47-3 Copper (Cu) 0.01‒1.00 7440-50-8 Iron (Fe) 86.3‒96.2 7439-89-6 Manganese (Mn) 0.2‒1.1 7439-96-5 Nickel (Ni) 0.01‒1.5 7440-02-0 Silicon (Si) 1.0‒3.5 7440-21-3 Tin (Sn) 0.1‒0.15 7440-31-5

Gray Iron Castings (SDS SC-000-041 Rev 12) Page 2 of 6

SECTION 4—FIRST AID MEASURES EYE CONTACT: Not applicable SKIN CONTACT: No special requirements INGESTION: Not applicable INHALATION: Not applicable

SECTION 5—FIREFIGHTING MEASURES FLAMMABLE PROPERTIES: Not applicable EXTINGUISHING MEDIA: Not applicable PROTECTION OF FIREFIGHTERS: Not applicable

SECTION 6—ACCIDENTAL RELEASE MEASURES

Not applicable

SECTION 7—HANDLING & STORAGE RECOMMENDED STORAGE

No special requirements PROCEDURES FOR HANDLING

Proper hand and foot protection is recommended.

SECTION 8—EXPOSURE CONTROLS/ PERSONAL PROTECTION ENGINEERING CONTROLS

None Required. There are no health hazards from castings in solid form.

SUBSTANCE ACGIH TLV

mg/m3 OSHA PEL

mg/m3 Carbon (C) N/E N/E Chromium (Cr) 0.5 1 Copper (Cu) 1 1 Iron (Fe) N/E N/E Manganese (Mn) 0.02 (R); 0.1 (I) 5 (C) Nickel (Ni) 1.5 (I) 1 Silicon (Si)

Total dust Respirable dust

N/E N/E

15 5

Tin (Sn) 2 2 SUPPLEMENTAL INFORMATION

Grinding castings that have not been cleaned or that contain embedded sand may generate significant amounts of dust containing crystalline silica. Fumes from hot processes may contain other compounds with different exposure limits than those listed above. Dust or fumes generated by machining, grinding, welding or thermal cutting of the casting may produce airborne contaminants. Exposure limits for the most common contaminants are offered as reference. Please consult a competent person for guidance on exposure assessment and controls. In particular, Hexavalent Chromium is an OSHA Expanded Health Standard; refer to OSHA 29 CFR 1910.1026-Chromium (VI) for complete requirements.


SUBSTANCE ACGIH TLV

mg/m3 OSHA PEL

mg/m3 Chromium Compounds (as Cr)

Chromium (II) inorganic compounds Chromium (III) inorganic compounds Chromium (VI) inorganic compounds, certain water insoluble Chromium (VI) inorganic compounds, water soluble Chromium (VI) all forms and compounds

N/E 0.5 0.01 0.05 N/E

0.5 0.5

0.005 0.005 0.005

Copper Compounds (as Cu) Fume, as Cu Dusts and mists, as Cu

0.2 1

0.1 1

Iron Compounds Iron oxide (Fe2O3) fume Iron oxide (Fe2O3)

N/E 5 (R)

10 N/E

Nickel Compounds (as Ni) Insoluble, inorganic compounds Soluble, inorganic compounds Nickel oxide

0.2(I) 0.1(I) 0.2(I)

1 1 1

Tin compounds (as Sn) Tin Oxide & inorganic compounds, except SnH4 Inorganic compounds, except oxides, as Sn Tin Oxides, as Sn

2

N/E 2

N/E

2 N/E

TERMS All exposure limits referenced above are 8 hour time weighted averages (TWA) unless otherwise noted.

N/E = None Established C = Ceiling I = Inhalable fraction R = Respirable fraction TLV = Threshold Limit Value/American Conference of Industrial Hygienists (ACGIH) PEL = Permissible Exposure Limit / OSHA mg/m3 = milligrams per cubic meter

PERSONAL PROTECTION: Proper hand and foot protection is recommended.

SECTION 9—PHYSICAL & CHEMICAL PROPERTIES APPEARANCE /PHYSICAL STATE

Solid, silver gray in color ODOR/ODOR THRESHOLD

None VAPOR DENSITY

Not applicable MELTING POINT/FREEZING POINT

Approximately 2350°F (1300°C) SPECIFIC GRAVITY (relative density)

7.85 g/cm3 for iron BOILING POINT

5000°F (2750°C) for iron VAPOR PRESSURE

Not applicable FLASH POINT

Not applicable for solid castings EVAPORATION RATE

Not applicable FLAMMABILITY

Not flammable SOLUBILITY IN WATER

Insoluble UPPER AND LOWER FLAMMABILITY LIMITS

Not applicable for solid castings pH

Not applicable AUTO IGNITION TEMPERATURE

Not applicable VISCOSITY

Not applicable


DECOMPOSITION TEMPERATURE Not applicable

PARTITION COEFFICIENT Not applicable

SECTION 10—STABILITY & REACTIVITY CHEMICAL STABILITY

Stable CONDITIONS TO AVOID

None REACTIVITY

Not reactive INCOMPATIBLE MATERIALS

None HAZARDOUS DECOMPOSITION PRODUCTS

None POSSIBILITY OF HAZARDOUS REACTIONS

Not applicable

SECTION 11—TOXICOLOGICAL INFORMATION POTENTIAL HEALTH EFFECTS EYE CONTACT: None SKIN: None INGESTION: None INHALATION: None

Carcinogen Classification of Ingredients INGREDIENT OSHA NTP IARC TARGET ORGAN

Nickel (metal) NL K 2B Lung, Nose

TERMS OSHA—Occupational Safety & Health Administration

Y = Listed as a Human Carcinogen NTP—National Toxicology Program

K = Known to be a Human Carcinogen R = Reasonably Anticipated to be a Human Carcinogen (RAHC)

IARC—International Agency for Research on Cancer 1 = Carcinogen to Humans 2A = Probably Carcinogenic to Humans 2B = Possibly Carcinogenic to Humans 3 = Unclassifiable as to Carcinogenicity in Humans 4 = Probably not Carcinogenic to Humans

Other NL = Not Listed

SECTION 12—ECOLOGICAL INFORMATION

ECOTOXICITY Not applicable

PERSISTENCE AND DEGRADABILITY Not applicable

BIOACCUMULATION POTENTIAL Not applicable

MOBILITY IN SOIL Not applicable

OTHER ADVERSE EFFECTS Not applicable

SECTION 13—DISPOSAL CONSIDERATIONS Recover or recycle if possible. Dispose of according to federal, state and local regulations. Dust collected from machining, welding, etc. may be classified as a hazardous waste. Consult federal, state and local regulations.

SECTION 14—TRANSPORT INFORMATION US DEPARTMENT OF TRANSPORTATION (DOT)-HMR (Hazardous Materials Registration)

Not Regulated

CANADIAN TRANSPORTATION OF DANGEROUS GOODS (TDG)

Not regulated UN SHIPPING NAME

Not regulated UN NUMBER

Not regulated


TRANSPORT HAZARD CLASS Not regulated

PACKING GROUP Not regulated

ENVIRONMENTAL HAZARDS None

LABEL(S) REQUIRED? No

TRANSPORT IN BULK Not applicable

SPECIAL SHIPPING INFORMATION Not applicable

SECTION 15—REGULATORY INFORMATION US-OSHA (Hazard Communication Standard)

Reference 29 CFR 1910.1200 and 1910.1000. A finished casting is an article as defined in the OSHA Hazard Communication Standard 29CFR 1910.1200 (c). Dust or fumes generated by cleaning, machining, grinding, or welding of the casting may produce airborne contaminants, such as chromium, copper, iron, manganese, nickel, silicon, tin and silica. For hexavalent chromium references see 29 CFR 1910.1026.

US-EPA (Toxic Substances Control Act–TSCA) All components of these products are on the TSCA inventory list or are excluded from listing.

US-EPA (SARA Title III) Releases to the environment of Chromium, Copper, Manganese and Nickel, may be subject to reporting under Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.

CANADA-WHMIS (Workplace Hazardous Materials Information System) This SDS has been prepared according to the hazard criteria of the Controlled Product Regulations (CPR) and the SDS contains the information required by the CPR.

CANADA DSL (Domestic Substance List) Inventory Status All components of these products are on the DSL Inventory.

CEPA (Canadian Environmental Protection Act) Chromium and nickel are on the CEPA Priorities Substances Lists

EINECS No. (European Inventory of Existing Commercial Chemical Substances) All components of these products are on the EINECS list.

RoHS (Restriction of Certain Hazardous Substances) Compliance Castings comply with RoHS

CALIFORNIA PROPOSITION 65 Compliance WARNING: This product contains or produces chemicals known to the State of California to cause cancer and birth defects (or other reproductive harm). (California Health & Safety Code 25248.5 et seq.)

US STATE REGULATORY INFORMATION Some of the components listed in Section 3 may be covered under specific state regulations.

SECTION 16—OTHER INFORMATION SDS SHEET PREPARED BY

American Foundry Society, Inc. Occupational Safety & Health Committee (10-Q)

DATE 10/13

NOTE: This data and label information is offered in good faith as typical values and not as a product specification. No warranty either expressed or implied is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review the recommendations in specific context of the intended use and determine if they are appropriate.


Addendum: Label Information

PRODUCT IDENTIFIER

SC-000-041 Rev. 12

GRAY IRON CASTINGS

SUPPLIER IDENTIFICATION

Company Name____________________________

Street Address ____________________________

Mailing Address: ___________________________

City ____________________________ State ____

Zip/Postal Code ___________ Country _________

Emergency Phone Number___________________

Other Info ________________________________

HAZARD PICTOGRAMS

None*

SIGNAL WORD

None*

PRECAUTIONARY STATEMENTS

None*

HAZARD STATEMENTS

None*

*Castings do not present hazards in their original form. OTHER INFORMATION

1. Grinding castings that have not been cleaned or that contain embedded sand may generate significant amounts of dust containing crystalline silica.

2. Fumes from hot processes may contain other compounds with different exposure limits. Dust or fumes generated by machining, grinding, welding or thermal cutting of the casting may produce airborne contaminants. Consult Sections 3 & 8 of the SDS for further information.

MATERIAL SAFETY DATA SHEET

HTH® SUPER 3" CHLORINATING TABLETS REVISION DATE : 02/13/2012 Page 1 of 13

FOR ANY EMERGENCY, 24 HOURS / 7 DAYS, CALL: FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC®: FOR ALL MSDS QUESTIONS & REQUESTS, CALL:

1-800-654-6911 (OUTSIDE USA: 1-423-780-2970) 1-800-424-9300 (OUTSIDE USA: 1-703-527-3887) 1-800-511-MSDS (OUTSIDE USA: 1-423-780-2347)

PRODUCT NAME: HTH® SUPER 3" CHLORINATING TABLETS

EPA Registration Number: 1258-1338

1. PRODUCT AND COMPANY IDENTIFICATION Arch Chemicals, Inc. 501 Merritt 7 PO Box 5204 Norwalk, CT 06856-5204

REVISION DATE: 02/13/2012 SUPERCEDES: 07/05/2011

MSDS Number: 000000013279 SYNONYMS: Trichloroisocyanuric Acid, TCCA,

Trichlor CHEMICAL FAMILY: Chloroisocyanurates DESCRIPTION / USE Swimming pool water treatment FORMULA: NOT APPLICABLE/MIXTURE


OSHA Hazard Classification:

Corrosive to eyes and skin, Lung toxin, Toxic by ingestion, Toxic by inhalation (dust)., Oxidizer

Routes of Entry: Inhalation, skin, eyes, ingestion Chemical Interactions: No known or reported interactions. Medical Conditions Aggravated: Asthma, respiratory and cardiovascular disease Human Threshold Response Data

Odor Threshold Not established for product.

Irritation Threshold Not established for product.



Hazardous Materials Identification System / National Fire Protection Association Classifications

Hazard Ratings : Health Flammability Physical / Instability PPI / Special hazard.

HMIS 3 0 2 NFPA 2 0 2 Oxidizer

Immediate (Acute) Health Effects Inhalation Toxicity: This product in the form of solid tablets is not an inhalation hazard.

However, if dust is created and inhaled, inhalation of this material in dust or vapor form is irritating to the nose, mouth, throat and lungs. It may also cause burns to the respiratory tract with the production of lung edema which can result in shortness of breath, wheezing, choking, chest pain, and impairment of lung function. Inhalation of high concentrations can result in permanent lung damage. Toxic by inhalation (dust).

Skin Toxicity: DRY MATERIAL CAUSES MODERATE SKIN IRRITATION. WET MATERIAL CAUSES SKIN BURNS. Dermal exposure to dry material causes moderate skin irritation characterized by redness and swelling. Dermal exposure to wet material can cause severe irritation and/or burns characterized by redness, swelling and scab formation. Prolonged skin exposure may cause permanent damage.

Eye Toxicity: CAUSES BURNS TO EYES. Severe irritation and/or burns can occur following eye exposure. Direct contact may cause impairment of vision and corneal damage.

Ingestion Toxicity: Toxic if swallowed. CAUSES BURNS TO DIGESTIVE TRACT. Irritation and/or burns can occur to the entire gastrointestinal tract, including the stomach and intestines, characterized by nausea, vomiting, diarrhea, abdominal pain, bleeding, and/or tissue ulceration. Ingestion may cause severe damage to the gastrointestinal tract with the potential to cause perforation.

Acute Target Organ Toxicity: This product is corrosive to all tissues contacted and upon inhalation, may cause irritation to mucous membranes and respiratory tract., The dry material is irritating to the skin. However when wet, it will produce burns to the skin.

Prolonged (Chronic) Health Effects Carcinogenicity: This product is not known or reported to be carcinogenic by any

reference source including IARC, OSHA, NTP or EPA. Reproductive and Developmental Toxicity:

Not known or reported to cause reproductive or developmental toxicity.

Inhalation: There are no known or reported effects from chronic exposure except for effects similar to those experienced from acute exposure.

Skin Contact: Effects similar to those from acute exposure. In addition, chronic exposure to wet material may cause effects secondary to tissue destruction.



Ingestion: There are no known or reported effects from chronic ingestion except for effects similar to those experienced from single exposure. The acute corrosivity of this product, makes chronic ingestion of significant amounts unlikely.

Sensitization: This material tested negative for skin sensitization in animals. Chronic Target Organ Toxicity: There are no known or reported target organ effects from chronic

exposure., Toxicological investigation indicates it does not produce significant effects from chronic exposure.

Supplemental Health Hazard Information :

No additional health information available.

3. COMPOSITION / INFORMATION ON INGREDIENTS

CAS OR CHEMICAL NAME CAS # % RANGE TRICHLORO-S-TRIAZINETRIONE

87-90-1

94.5

ZINC SULFATE

7446-19-7

3.5

filter aid

PROPRIETARY 1.5

4. FIRST AID MEASURES General Advice: Call a poison control center or doctor for treatment advice. For 24-hour

emergency medical assistance, call Arch Chemical Emergency Action Network at 1-800-654-6911. Have the product container or label with you when calling a poison control center or doctor, or going for treatment.

Inhalation: IF INHALED: Move person to fresh air. If person is not breathing, call 911 or an

ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice.

Skin Contact: IF ON SKIN OR CLOTHING: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice.

Eye Contact: IF IN EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.



Ingestion: IF SWALLOWED: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person.

Notes to Physician: Probable mucosal damage may contraindicate the use of gastric lavage.

5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is not known to be flammable, combustible or pyrophoric.,

NFPA Oxidizer Class: Meets the criteria of an NFPA Class 1 Oxidizer

Flammable Properties Flash Point: Not applicable Autoignition Temperature: Not applicable Fire / Explosion Hazards: During a fire, irritating and highly toxic gases may be generated by

thermal decomposition or combustion. Closed containers may explode (due to the build up of steam pressure) when exposed to extreme heat.

Extinguishing Media: Water only. Fire Fighting Instructions: Use water to cool containers exposed to fire. On small fires, use

water spray or fog. On large fires, use heavy deluge or fog streams. Flooding amounts of water may be required before extinguishment can be accomplished. Do not use dry extinguishers containing ammonium compounds.

Upper Flammable / Explosive Limit, % in air: Not applicable Lower Flammable / Explosive Limit, % in air: Not applicable

6. ACCIDENTAL RELEASE MEASURES Personal Protection for Emergency Situations:

Response to a large quantity spill (100 pounds or greater) or when dusting or decomposition gas exposure could occur requires the use of a positive pressure full face supplied air repirator or self contained breathing apparatus (SCBA), chemical resistant gloves, coveralls and boots. In case of fire, this personal protective equipment should be used in addition to normal fire fighter equipment.Compatible materials for response to this material are: neoprene.Protection concerns must also address the following: If this material becomes damp/wet or contaminated in a container, the formation of nitrogen trichloride gas may occur and an explosive condition may exist.

Spill Mitigation Procedures Air Release: Vapors may be suppressed by the use of water fog.



Water Release: This material is heavier than water. This material is soluble in water. Stop water flow or divert water flow around spill if possible and safe to do so. Begin monitoring for available chlorine and pH immediately.

Land Release: Do not contaminate spill material with any organic materials, ammonia, ammonium salts or urea. Clean up all spill material with clean, dry dedicated equipment and place in a clean dry container.

Additional Spill Information : FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC: 1-800-424-9300 REPORTABLE QUANTITY: Not Applicable (Per 40 CFR 302.4) Hazardous concentrations in air may be found in local spill area and immediately downwind. If spill material is still dry, do not put water directly on this product as a gas evolution may occur. If material is wet, contact 1-800-654-6911 for proper stabilization procedures. Dispose of spill residues per guidelines under Section 13, Disposal Consideration. This material may be neutralized for disposal; you are requested to contact Arch Chemicals at 1-800-654-6911 before beginning any such procedure.

7. HANDLING AND STORAGE Handling: Do not take internally. Avoid contact with skin, eyes and clothing.

Upon contact with skin or eyes, wash off with water. Avoid breathing dust, mist, vapor or gas.

Storage: Store in a cool dry ventilated location, away from sources of ignition or other incompatible conditions and chemicals. Keep container(s) closed. Avoid creating dusts.

Shelf Life Limitations: Indefinite. Available chlorine loss can be as little as 0.1% per year at ambient temperatures.

Incompatible Materials for Storage: organic materials Reducing agents nitrogen containing materials oxidizers acids Bases (Incompatible materials for packaging: paper, cardboard)

Do Not Store At temperatures Above: 60 DEG°C / 140 DEG°F

8. EXPOSURE CONTROLS / PERSONAL PROTECTION Ventilation: Local exhaust ventilation or other engineering controls are normally required

when handling or using this product to keep airborne exposures below the TLV, PEL or other recommended exposure limit.

Protective Equipment for Routine Use of Product



Respiratory Protection : Wear a NIOSH approved respirator if levels above the exposure limits are possible.

Respirator Type : A NIOSH approved full-face air purifying respirator equipped with combination chlorine/P100 cartridges. Air purifying respirators should not be used in oxygen deficient or IDLH atmospheres or if exposure concentrations exceed ten (10) times the published limit.

Skin Protection : Wear impervious gloves to avoid skin contact. A full impervious suit is recommended if exposure is possible to a large portion of the body.

Eye Protection: Use chemical goggles. Protective Clothing Type: Nitrile, Natural rubber, Neoprene (This includes: gloves, boots, apron,

protective suit) General Protective Measures:

An eye wash and safety shower should be provided in the immediate work area.

Exposure Limit Data CHEMICAL NAME CAS # Name of Limit Exposure TRICHLORO-S-TRIAZINETRIONE 87-90-1 ARCH-ROEG* 0.5 mg/m3 TWA

*ARCH-ROEG: Arch Recommended Occupational Exposure Guideline.


Physical State: solid Form Tablet Color: white Odor: Strong chlorine Molecular Weight: 232.41 Specific Gravity : >1 (@ 20 Deg. C) pH : 2.6 1% solution Boiling Point: Not applicable Freezing Point: Not applicable Melting Point: Not applicable Density: 1.79g/cc Vapor Pressure: Not available Vapor Density: Not applicable Viscosity: Not applicable Fat Solubility: No data Solubility in Water: 1.2 % (@ 25 Deg. C)

Partition coefficient n-octanol/water:

Not available.

Evaporation Rate: Not applicable Oxidizing: Oxidizer Volatiles, % by vol.: Not applicable VOC Content Not applicable HAP Content Not applicable



10. STABILITY AND REACTIVITY Stability and Reactivity Summary: May be unstable at temperatures above 225 Deg. C (437 Deg. F)

Not sensitive to mechanical shock. Not sensitive to static discharge. Product will not undergo hazardous polymerization. Product is an oxidizer.

Conditions to Avoid: Sparks, open flame, other ignition sources, and elevated temperatures., Contact with small amounts of water may result in an exothermic reaction with the liberation of toxic fumes., Damp or slightly wet product (will evolve nitrogen trichloride), May be unstable at temperatures above 225 Deg. C (437 Deg. F)

Chemical Incompatibility: Organic materials, Oils, Grease, Sawdust, Reducing agents, nitrogen-containing compounds, oxidizers, acids, Bases, Dry fire extinguishers containing ammonium compounds

Hazardous Decomposition Products: Nitrogen trichloride, Chlorine, nitrous oxides, cyanates, Carbon monoxide, Carbon dioxide

Decomposition Temperature: 225 DEG°C - , 437 DEG°F-

11. TOXICOLOGICAL INFORMATION Component Animal Toxicology Oral LD50 value: TRICHLORO-S-TRIAZINETRIONE

LD50 = 490 mg/kg Rat

ZINC SULFATE LD50 > 2,949 mg/kg rat filter aid LD50 anhydrous substance = 6,207 mg/kg Mouse filter aid LD50 anhydrous substance = 1,930 mg/kg Rat Component Animal Toxicology Dermal LD50 value: TRICHLORO-S-TRIAZINETRIONE

LD50 > 2,000 mg/kg Rabbit

ZINC SULFATE LD50 Believed to be > 2,000 mg/kg rat filter aid LD50 anhydrous substance Believed to be > 2,000 mg/kg Rabbit Component Animal Toxicology Inhalation LC50 value: TRICHLORO-S-TRIAZINETRIONE

LC50 1 h (aerosol dust), (Nose Only) Approximately 2.16 MG/L Rat

TRICHLORO-S-TRIAZINETRIONE

LC50 4 h (aerosol dust), (Nose Only) Approximately 0.54 MG/L Rat

ZINC SULFATE no data available filter aid No data



Product Animal Toxicity Oral LD50 value: LD50 490 mg/kg Rat Dermal LD50 value: LD50 > 2,000 mg/kg Rabbit Inhalation LC50 value:

LC50 4 h (aerosol dust), (Nose Only) Approximately 0.54 MG/L Rat LC50 1 h (aerosol dust), (Nose Only) Approximately 2.16 MG/L Rat

Skin Irritation: DRY MATERIAL CAUSES MODERATE SKIN IRRITATION., WET MATERIAL CAUSES SKIN BURNS.

Eye Irritation: Corrosive to eyes. Skin Sensitization: Negative skin sensitizer, guinea pig - Buehler Method Acute Toxicity: This product is corrosive to all tissues contacted and upon inhalation, may cause

irritation to mucous membranes and respiratory tract.The dry material is irritating to the skin. However when wet, it will produce burns to the skin.

Subchronic / Chronic Toxicity:

There are no known or reported effects from repeated exposure., Toxicological investigation indicates it does not produce significant effects from chronic exposure.

Reproductive and Developmental Toxicity:

Not known or reported to cause reproductive or developmental toxicity.

TRICHLORO-S-TRIAZINETRIONE Not known or reported to cause reproductive or

developmental toxicity. A similar product has been tested and it did not produce teratogenic or fetotoxic effects in laboratory animals.

Mutagenicity: This product was determined to be non-mutagenic in the Ames assay.

TRICHLORO-S-TRIAZINETRIONE This product was determined to be non-mutagenic in the Ames assay.

Carcinogenicity: This product is not known or reported to be carcinogenic by any reference

source including IARC, OSHA, NTP or EPA. TRICHLORO-S-TRIAZINETRIONE This chemical is not known or reported to be

carcinogenic by any reference source including IARC, OSHA, NTP, or EPA.

12. ECOLOGICAL INFORMATION Overview: Highly toxic to fish and other aquatic organisms. Ecological Toxicity Values - Product:



Rainbow trout (Salmo gairdneri), - 96 h LC50 0.32 mg/l Bluegill sunfish - 96 h LC50 0.30 mg/l

Daphnia magna, - 48 h LC50 0.21 mg/l Mallard duck - 8 DAYS Dietary LC50 > 10,000 ppm

Mallard duck - Acute Oral LD50 1,600 mg/kg Bobwhite quail - 8 DAYS Dietary LC50 7,422 ppm

Ecological Toxicity Values for: TRICHLORO-S-TRIAZINETRIONE

Rainbow trout (Salmo gairdneri), - 96 h LC50 0.32 mg/l Bluegill sunfish - 96 h LC50 0.30 mg/l

Daphnia magna, - 48 h LC50 0.21 mg/l Mallard duck - 8 DAYS Dietary LC50 > 10,000 ppm

Mallard duck - Acute Oral LD50 1,600 mg/kg Bobwhite quail - 8 DAYS Dietary LC50 7,422 ppm

Ecological Toxicity Values for: ZINC SULFATE

Rainbow trout (Oncorhynchus mykiss)

- 96 h LC50 = 2.4 mg/l

Fathead minnow (Pimephales promelas),

- (static). 96 h LC50 = 3.1 mg/l

Daphnia magna, - (static). 48 h LC50= 0.690 mg/l Ecological Toxicity Values for: filter aid

Largemouth bass - 96 h LC50 = 250 mg/l (anhydrous aluminum sulfate) Mosquito fish - 96 h LC50 = 235 mg/l (anhydrous aluminum sulfate)

13. DISPOSAL CONSIDERATIONS CARE MUST BE TAKEN TO PREVENT ENVIRONMENTAL CONTAMINATION FROM THE USE OF THE MATERIAL. THE USER OF THE MATERIAL HAS THE RESPONSIBILITY TO DISPOSE OF UNUSED MATERIAL, RESIDUES AND CONTAINERS IN COMPLIANCE WITH ALL RELEVANT LOCAL, STATE AND FEDERAL LAWS AND REGULATIONS REGARDING TREATMENT, STORAGE AND DISPOSAL FOR HAZARDOUS AND NONHAZARDOUS WASTES. Waste Disposal Summary : If this product becomes a waste, it DOES NOT meet the criteria of a



hazardous waste as defined under 40 CFR 261, in that it does not exhibit the characteristics of hazardous waste of Subpart C, nor is it listed as a hazardous waste under Subpart D.

Disposal Methods : As a nonhazardous solid waste it should be disposed of in

accordance with local, state and federal regulations. Potential US EPA Waste Codes : Not applicable

14. TRANSPORT INFORMATION Land (US DOT): UN3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.

(TRICHLORO-S-TRIAZINETRIONE, ZINC SULFATE) 9 III Water (IMDG): UN3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.,

(TRICHLORO-S-TRIAZINETRIONE, ZINC SULFATE) 9 III MARINE POLLUTANT Flash Point: Not applicable

Air (IATA): UN3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., (TRICHLORO-S-TRIAZINETRIONE, ZINC SULFATE) 9 III

Emergency Response Guide Number: ERG # 171

Transportation Notes: Material is not regulated for ground transportation within the US if shipped in non-bulk packages. Material is not regulated as a marine pollutant for ground, rail car, or aircraft transportation within the USA if shipped in non bulk packages per marine pollutant exception 49 CFR 171.4(c).

EMS: F-A, S-F

15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA): This is an EPA registered pesticide. EPA Pesticide Registration Number: 1258-1338 FIFRA Listing of Pesticide Chemicals (40 CFR 180):

This product is regulated under the Federal Insecticide, Fungicide and Rodenticide Act. It must be used for purposes consistent with its labeling.

Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311 / 312 (40 CFR 370.2): Health Immediate (Acute) Health Hazard Physical Fire Hazard



Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity:

ZUS_SAR302 TPQ (threshold planning quantity)

None established

Reportable Quantity (49 CFR 172.101, Appendix):

ZUS_CERCLA Reportable quantity ZINC AND COMPOUNDS Value:

ZUS_SAR302 Reportable quantity None established

Supplier Notification Requirements (40 CFR 372.45), 313 Reportable Components

ZUS_SAR313 De minimis concentration None established

Clean Air Act Toxic ARP Section 112r: CAA 112R None established Clean Air Act Socmi: HON SOC None established Clean Air Act VOC Section 111: CAA 111 None established Clean Air Act Haz. Air Pollutants Section 112: ZUS_CAAHAP None established ZUS_CAAHRP None established CAA AP None established State Right-to-Know Regulations Status of Ingredients Pennsylvania:CAS # COMPONENT NAME 87-90-1 TRICHLORO-S-TRIAZINETRIONE 7446-19-7 ZINC SULFATE ZUSPA_RTK Pennsylvania: Hazardous substance list

1989-08-11 1,3,5-TRIAZINE-2,4,6(1H,3H,5H)-TRIONE, 1,3,5-TRICHLORO-



Pennsylvania: Hazardous substance list 1990-01-01 ZINC COMPOUNDS Environmental hazard, hazardous substance

New Jersey:CAS # COMPONENT NAME 87-90-1 TRICHLORO-S-TRIAZINETRIONE 7446-19-7 ZINC SULFATE ZUSNJ_RTK New Jersey Right to Know Hazardous Substance List (RTK-HSL)

2007-03-01 TRICHLOROISOCYANURIC ACID SYMCLOSENE 1,3,5-TRIAZINE-2,4,6(1H,3H,5H)-TRIONE, 1,3,5-TRICHLORO- Special Health Hazard - Reactive - Second Degree

New Jersey Right to Know Hazardous Substance List (RTK-HSL)

1989-12-01 ZINC compounds hazardous substance

Massachusetts:CAS # COMPONENT NAME 87-90-1 TRICHLORO-S-TRIAZINETRIONE ZUSMA_RTK Massachusetts Right to Know List of Chemicals and Hazard Classifications

1993-04-24 TRICHLORO-S-TRIAZINETRIONE

California Proposition 65: CAS # COMPONENT NAME ZUSCA_P65

None established

WHMIS Hazard Classification: : : : : :



Ingredient Disclosure List (WHMIS) 2007-08-24 Threshold limits: 1 Weight percent 148 Trichloroisocyanuric acid

16. OTHER INFORMATION MSDS REVISION STATUS : SECTIONS REVISED: 1 Major References : Available upon request. THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN PREPARED IN COMPLIANCE WITH THE FEDERAL OSHA HAZARD COMMUNICATION STANDARD, 29 CFR 1910.1200. THE INFORMATION IN THIS MSDS SHOULD BE PROVIDED TO ALL WHO WILL USE, HANDLE, STORE, TRANSPORT, OR OTHERWISE BE EXPOSED TO THIS PRODUCT. THIS INFORMATION HAS BEEN PREPARED FOR THE GUIDANCE OF PLANT ENGINEERING, OPERATIONS AND MANAGEMENT AND FOR PERSONS WORKING WITH OR HANDLING THIS PRODUCT. ARCH CHEMICALS BELIEVES THIS INFORMATION TO BE RELIABLE AND UP TO DATE AS OF THE DATE OF PUBLICATION BUT, MAKES NO WARRANTY THAT IT IS. ADDITIONALLY, IF THIS MSDS IS MORE THAN THREE YEARS OLD, YOU SHOULD CONTACT ARCH CHEMICALS MSDS CONTROL AT THE PHONE NUMBER ON THE FRONT PAGE TO MAKE CERTAIN THAT THIS DOCUMENT IS CURRENT. .

MATERIAL SAFETY DATA SHEET (MSDS) FOR READY MIXED CONCRETE

(Complies with OSHA's Hazard Communication Standard, 29 CFR 1910.1200)

CEMEX, INC. 840 GESSNER, SUITE 1400 HOUSTON, TEXAS 77024

Section 1 - IDENTIFICATION Supplier/Manufacturer Emergency Contact Information CEMEX, Inc. Kevin Keegan (713) 722-5991 840 Gessner, Suite 1400 Michael Tilton (713) 722-1728 Houston, Texas 77024 Chemical name and synonyms Product name Hydrated Portland Cement (CAS #65997-15-1) Ready Mixed Concrete Chemical family Formula Calcium salts. 3CaO.SiO2 (CAS #12168-85-3)

2CaO.SiO2 (CAS #10034-77-2) 3CaO.Al2O2 (CAS #12042-78-3) 4CaO..Al2O3Fe2O3 (CAS #12068-35-8) CaSO2.2H2O (CAS #13397-24-5)

Section 2 - COMPONENTS Hazardous Ingredients Portland cement (CAS# 65997-15- 1) - approximately 10.0-20.0 % by weight

ACGIH TLV-TWA (2000) = 10 mg total dust/m3 OSHA PEL (8-hour TWA) = 50 million particles/ft3

Respirable quartz (CAS# 14808-60-7) – greater than 0.1% by weight

ACGIH TLV-TWA (2000) = 0.05 mg respirable quartz dust/m3 OSHA PEL (8-hour TWA) = (10 mg respirable dust/m3)/(percent silica + 2)

Trace Ingredients Concrete Aggregates: Inert sand, gravel, and stone

Concrete Additives and Admixtures: May include flyash, and very amounts of organic and inorganic materials which have no effect on the hazards associated with the use of this product such as air entrained agents, water reducers, superplasticizers, fiberous reinforcement, pigments, ect.

Section 3 - HAZARD IDENTIFICATION Emergency Overview

Exposure of sufficient duration to ready mixed concrete can cause serious, potentially irreversible tissue (skin or eye) destruction in the form of chemical (caustic) burns.

Potential Health Effects Relevant Routes of Exposure:

Eye contact, skin contact, and ingestion. Effects Resulting from Eye Contact:

Eye contact by splashes of concrete may cause effects ranging from moderate eye irritation to chemical burns or blindness. Such exposures require immediate first aid (see Section 4) and medical attention to prevent significant damage to the eye.

Effects Resulting from Skin Contact: Discomfort or pain cannot be relied upon to alert a person to hazardous skin exposure. Consequently, the only effective means of avoiding skin injury or illness involves minimizing skin contact, with concrete. Exposed persons may not feel discomfort until hours after the exposure has ended and significant injury has occurred.

Exposure to concrete may cause more severe skin effects including thickening, cracking or fissuring of the skin. Prolonged exposure can cause severe skin damage in the form of (alkali) chemical burns.

Some individuals may exhibit an allergic response upon exposure to concrete, possibly due to trace elements of chromium. The response may appear in a variety of forms ranging from a mild rash to severe skin ulcers. Persons already sensitized may react to their first contact with the product. Other persons may first experience this effect after years of contact with concrete products.

Effects Resulting from Ingestion:

Although small quantities of concrete are not known to be harmful, ill effects are possible if larger quantities are consumed. Concrete should not be eaten.

Carcinogenic potential:

Concrete is not listed as a carcinogen by NTP, OSHA, or IARC. It may however, contain trace amounts of substances listed as carcinogens by these organizations.

Crystalline silica, a potential component in concrete, is now classified by IARC as known human carcinogen (Group I). NTP has characterized respirable silica as "reasonably anticipated to be [a] carcinogen".

Medical conditions which may be aggravated by dermal exposure:

Unusual (hyper) sensitivity to hexavalent chromium (chromium+6) salts. Section 4 - FIRST AID Eyes

Immediately flush eyes thoroughly with water. Continue flushing eye for at least 15 minutes, including under lids, to remove all material. Call physician immediately.

Skin

Wash skin with cool water and pH-neutral soap or a mild detergent. Seek medical treatment in all cases of prolonged exposure to concrete or fresh cconcrete products.

Ingestion

Do not induce vomiting. If conscious, have the victim drink plenty of water and call a physician immediately. Section 5 - FIRE AND EXPLOSION DATA

Flash point ...................................None Lower Explosive Limit.......................None Upper Explosive Limit.................None Auto ignition temperature..............….Not Combustible Extinguishing media.....................Not Combustible Special fire fighting Procedures.........None Hazardous combustion products...None Unusual fire and explosion hazards...None

Section 6 - ACCIDENTAL RELEASE MEASURES Wear appropriate personal protective equipment as described in Section 8. Scrape up wet material and place in an appropriate container. Allow the material to "dry" before disposal. Do not attempt to wash concrete down drains. Dispose of waste material according to local, state and federal regulations.

Section 7 - HANDLING AND STORAGE Normal temperatures and pressures do not affect the material. Promptly remove clothing that is wet with concrete or its fluids and launder before reuse. Wash thoroughly after exposure to concrete or its fluids. Section 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION Skin Protection

Prevention is essential to avoiding potentially severe skin injury. Avoid contact with unhardened concrete. If contact occurs, promptly wash affected area with soap and water. Where prolonged exposure to unhardened concrete products might occur, wear impervious clothing and gloves to eliminate skin contact. Wear sturdy boots that are impervious to water to eliminate foot and ankle exposure.

Do not rely on barrier creams: barrier creams should not be used in place of gloves.

Periodically wash areas contacted by concrete or concrete fluids with a pH neutral soap. Wash again at the end of work. If irritation occurs, immediately wash the affected area and seek treatment. If clothing becomes saturated with wet concrete, it should be removed and replaced with clean dry clothing.

Respiratory Protection

If any cutting, grinding, scarifying, or any other procedures are employed to hardened Portland cement concrete, dusting may occur. If possible, avoid actions that cause dust to become airborne. Use local or general exhaust ventilation to control exposures below applicable exposure limits.

Use NIOSH/MSHA approved (under 30 CFR 11) or NIOSH approved (under 42 CFR 84) respirators in poorly ventilated areas, if an applicable exposure limit is exceeded, or when dust causes discomfort or irritation. (Advisory: Respirators and filters purchased after June 10, 1998 must be certified under 42 CFR 84.)

Ventilation

Use local exhaust or general dilution ventilation to control exposure within applicable limits, if involved in dust generating activities associated with hardened Portland cement concrete.

Eye Protection

Where potentially subject to splashes of concrete, wear safety glasses with side shields or goggles. Contact lenses should not be worn when working with concrete.

Section 9 - PHYSICAL AND CHEMICAL, PROPERTIES Appearance.............Gray granular mud Odor.............................No distinct odor Physical state...........Fluid pH (in water)................12 to 13 Solubility in water...Slightly soluble (0.1 to 1.0%) Vapor pressure.............Not applicable Vapor density..........Not applicable Boiling point.................Not applicable (i.e., > 1000 C) Melting point...........Not applicable Specific gravity (H20 = 1.0).......Greater than 3.0 Evaporation rate......Not applicable Section 10 - STABILITY AND REACTIVITY Stability

Stable. Conditions to avoid

None known. Incompatibility

Concrete is alkaline. As such it is incompatible with acids, ammonium salts and phosphorous. Hazardous decomposition Will not spontaneously occur. Adding water produces (caustic) calcium hydroxide

Hazardous Polymerization

Will not occur. Section 11 - TOXICOLOGICAL INFORMATION For a description of available, more detailed toxicological information contact the supplier or manufacturer. Section 12 - ECOLOGICAL INFORMATION Ecotoxicity

No recognized unusual toxicity to plants or animals Relevant physical and chemical properties

(See Sections 9 and 10.) Section 13 - DISPOSAL Dispose of waste material according to local, state and federal regulations. Dispose of bags in an approved landfill or incinerator. Section 14 - TRANSPORTATION DATA Hazardous materials description/proper shipping name

Ready mixed concrete is not hazardous under U.S. Department of Transportation (DOT) regulations. Hazard class

Not applicable Identification number

Not applicable. Required label text

Not applicable. Hazardous substances/reportable quantities (RQ)

Not applicable. Section 15 - OTHER REGULATORY INFORMATION Status under USDOL-OSHA Hazard Communication Rule, 29 CFR 1910.1200

Concrete is considered a "hazardous chemical" under this regulation, and should be part of any hazard communication program. Status under CERCLA/SUPERFUND 40 CFR 117 and 302

Not listed. Hazard Category under SARA(Title III), Sections 311 and 312

Concrete qualifies as a "hazardous substance" with delayed health effects. Status under SARA (Title III), Section 313

Not subject to reporting requirements under Section 313. Status under TSCA (as of May 1997)

Some substances in ready mixed concrete are on the TSCA inventory list. Status under the Federal Hazardous Substances Act

Concrete is a "hazardous substance" subject to statutes promulgated under the subject act. Status under California Proposition 65

This product contains up to 0.05 percent of chemicals (trace elements) known to the State of California to cause cancer, birth

defects or other reproductive harm. California law requires the manufacturer to give the above warning in the absence of definitive testing to prove that the defined risks do not exist.

Section 16 - OTHER INFORMATION Prepared by

Kevin Keegan Director - Health and Safety CEMEX, Inc. Houston, Texas

Approval date or Revision date

Approved: September, 1998 Revised: March, 2001

Other important information While the information provided in this material safety data sheet is believed to provide a useful summary of the hazards of ready mixed concrete as it is commonly used, the sheet cannot anticipate and provide the all of the information that might be needed in every situation. Inexperienced product users should obtain proper training before using this product. SELLER MAKES NO WARRANTY, EXPRESSED OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE OR CONCERNING THE ACCURACY OF ANY INFORMATION PROVIDED BY CEMEX, Inc. except that the product shall conform to contracted specifications. The information provided herein was believed by CEMEX, Inc. to be accurate at the time of preparation or prepared from sources believed to be reliable, but it is the responsibility of the user to investigate and understand other pertinent sources of information to comply with all laws and procedures applicable to the safe handling and use of product and to determine the suitability of the product for its intended use. Buyer's exclusive remedy shall be for damages and no claim of any kind, whether as to product delivered or for non-delivery of product, and whether based on contract, breach of warranty, negligence, or otherwise shall be greater in amount than the purchase price of the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty, negligence or otherwise. In particular, the data furnished in this sheet do not address hazards that may be posed by other materials mixed with portland cement concrete to produce portland cement products. Users should review other relevant material safety data sheets before working with portland cement concrete.

Safety Data Sheet (SDS)

Prepared to comply with GHS (Globally Harmonized System) and OSHA-Hazard Communication Standard 29 CFR.1910.1200, System of Classifying and Labeling of Chemicals

Material Name: Pre-Cast / Pre-Stressed Concrete Products

Section 1: Identification 1.1 Product trade names: Concrete Pipe, Pre-cast and Pre-stressed Concrete Products

1.2 Product Class: Concrete / Stone Products

Product Codes: N/A

CAS/EC Number: Mixture (composition detailed in Section 3)

Intended Use: Used for construction and civil engineering projects for residential, commercial, industrial, agricultural, and transportation, including but not limited to; septic tanks, risers, boxes, parking curbs, bridge girders, building floors and hollow core planks.

1.3 Supplier: County Materials Corp. 205 North St., P.O. Box 100 Marathon, WI 54448-0100 General Information Telephone: (800) 289-2569 Email: [email protected]

1.4 Emergency telephone:

715-223-7788 Section 2: Hazard(s) Identification 2.1 Classification:

Skin Sensitizer – Category 1 Carcinogenicity – Category 1A Specific Target Organ Toxicity (Single Exposure-Respiratory System) – Category 3 Specific Target Organ Toxicity (Repeat Exposure-Respiratory System) – Category 1

2.2 Labeling: Pictograms:

Signal Word: DANGER Hazard Statements H317 – May cause an allergic skin reaction H335 – May cause respiratory irritation H351 – Suspected of causing cancer H372 – Causes damage to the organs (respiratory system) through prolonged or repeated exposure. Precautionary Statements P102 – Keep out of the reach of children. P201 – Obtain special instructions before use. P202 – Do not handle until all safety precautions have been read and understood. P260 – Do not breathe dusts. P264 – Wash exposed areas of face and body with water thoroughly after handling. P270 – Do not eat, drink, or smoke when using this product. P272 – Contaminated work clothing should not be allowed out of the workplace. P280 – Wear protective gloves/protective clothing/eye protection/face protection.

Issue Date: 01/05/16 | Revision 1.0 Page 1 of 10

mailto:[email protected]




Section 2: Hazard(s) Identification Response P302 + P352 – IF ON SKIN: Wash with plenty of water. P304 + P340 + P312 – IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a doctor if you feel unwell. P308 + P313 – IF exposed or concerned: Get medical advice/attention. P333 + P313 – If skin irritation or rash occurs: Get medical advice/attention. P362 + P364 – Take off contaminated clothing. And wash before reuse. Storage P403 – Store in a well-ventilated place. P405 – Store locked up. Disposal P501 – Dispose of contents in accordance with local/regional/national/international regulations.

2.3 Other Hazards: This product is classified based on the dust/particulate generated during cutting, crushing, drilling or grinding of the product. Hazards occur from dust exposure. Exposure to entrained dusts can cause acute and chronic health problems. Outside manufacturers provide steel components for this reinforced concrete pipe. Observe PELs and TLVs for particulates of these components: Iron, Carbon, Silicon, Aluminum, Arsenic, Boron, Calcium, Chromium, Cobalt, Copper, Lead, Manganese, Molybdenum, and Nickel. Dusts may be generated during cutting or grinding of the products.

Section 3: Composition/Information on Ingredients (1,2) Chemical Name EINECS/EC CAS Percent Classification Fine Aggregate-Silica Dioxide (Silica, Quartz, Sands, Crystalline Silica)(3)

231‐545‐4 14808-60-7 55-75% Carcinogenicity – Category 1A Specific Target Organ Toxicity (Single Exposure-Respiratory System) – Category 3 Specific Target Organ Toxicity (Repeat Exposure-Respiratory System) – Category 1

Course Aggregate (pea stone and limestone)

207-439-9 1317-65-3 20-28% Specific Target Organ Toxicity (Single Exposure-Respiratory System) – Category 3 Specific Target Organ Toxicity (Repeat Exposure-Respiratory System) – Category 1

Portland Cement 266-043-4 65997-15-1 6-10% Skin Sensitizer – Category 1 Carcinogenicity – Category 1A Specific Target Organ Toxicity (Single Exposure-Respiratory System) – Category 3 Specific Target Organ Toxicity (Repeat Exposure-Respiratory System) – Category 1

Fly Ash 268-627-4 68131-74-8 0-4% Skin Sensitizer – Category 1 Carcinogenicity – Category 1A Specific Target Organ Toxicity (Single Exposure-Respiratory System) – Category 3 Specific Target Organ Toxicity (Repeat Exposure-Respiratory System) – Category 1





Section 2: Hazard(s) Identification Amorphous Silica (fused)

231-545-4 (4) 7631-86-9 0-5%

Ferric Oxide 215-168-2 1309-37-1 0-5% Specific Target Organ Toxicity (Single Exposure-Respiratory System) – Category 3

Calcium Hydroxide 215-137-3 1305-62-0 0-5% 1. Portland Cement and Fly Ash. These products may contain trace amounts of chemicals including

silicates and metals which may be toxic in some forms. These ingredients may include, but are not limited to, Aluminum, Arsenic, Barium, Beryllium, Cadmium, Chromium, Iron, Lead, Manganese, Mercury, Nickel, Selenium, Vanadium and Zinc, along with other trace constituents.

2. May include 0-1% inorganics for reinforcement. Steel reinforcements may be added for physical stability. During dust/fume generating activities, observe PELs and TLVs for the following components: Iron, Carbon, Silicon, Aluminum, Arsenic, Boron, Calcium, Chromium, Cobalt, Copper, Lead, Manganese, Molybdenum, and Nickel.

3. This product’s composition varies naturally. Quartz and silica sand may contain variable amounts of crystalline silica (i.e. quartz) which is classified as a carcinogen.

4. EINECS/EC number for Amorphous silica is a general silica number.

Section 4: First-Aid Measures 4.1 Description of first aid measures:

Inhalation: Dust from cutting, grinding, sawing, or drilling product may be inhaled. If inhaled remove person immediately to fresh air. If breathing is difficult, give oxygen. SEEK MEDICAL ATTENTION IMMEDIATELY if person is unconscious or unable to breathe.

Skin Contact: Treat symptomatically. Cuts and abrasions should be cleaned and bandaged. Dust exposed skin should be rinsed with clean potable water. If irritation persists or develops later seek medical attention.

Eye Contact: Rinse eyes thoroughly with potable water for at least 15 minutes and remove contact lenses if easy to do. Rinse under eyelids to remove any particles. Seek medical attention for abrasions and burns.

Ingestion: Highly improbable. If the person is conscious and aware, give large amounts of water. Never attempt to make an unconscious person drink or vomit. If the person is choking due to blocked airway it may be necessary to perform the Heimlich maneuver. If the person is unconscious it may be necessary to sweep the blockage out of the mouth using a finger. CPR chest compressions may also dislodge any blockage. Seek emergency medical attention from a physician immediately.

4.2 Most important symptoms and effects: Inhalation: Inhalation of dust may cause irritation of the respiratory tract and pulmonary edema. May cause allergic or asthma like respiratory reactions if inhaled. Skin Contact: Projectile fragments may cause cuts or abrasions when in contact with skin. Dusts may irritate the skin. Eye Contact: Projectile fragments may cause cuts or abrasions when in contact with eyes. Dusts may cause severe irritation, abrasions, burns, redness, tissue destruction and permanent eye damage including blindness. Ingestion: Expected to be virtually nontoxic. Ingestion of large amounts of dust may cause gastrointestinal irritation, choking/blockage.

4.3 Indication of any immediate medical attention and special treatment needed: See Section 4.1.





Section 5: Fire-Fighting Measures 5.1 Extinguishing media: Product is not flammable. Use appropriate media for fire adjacent to product.

5.2 Special hazards arising from the substance or mixture: None.

5.3 Advice to firefighters: None.

Section 6: Accidental Release Measures 6.1 Personal precautions: Highly improbable. Wear appropriate protective equipment and clothing

during clean-up as recommended in Section 8. Use caution and avoid breathing dust. Wear dust-mask or respirator if required and qualified. Respirable crystalline silica dust particles may be generated by clean-up of crushed product, or with cutting, grinding, and drilling activities.

6.2 Environmental precautions: Product, when intact, is not an environmental hazard.

6.3 Methods and materials for containment and cleaning up: Avoid cutting, sawing, drilling or grinding to decrease generation of dusts.

6.4 Reference to other sections: Use information obtained throughout this SDS to be fully prepared in case of accidental release.

Section 7: Handling and Storage 7.1 Precautions for safe handling: Avoid contact with skin, eyes, and clothing. Persons handling the

product should wear recommended personal protective equipment (PPE) as noted in Section 8. Wash thoroughly with potable water and mild soap after handling. Avoid breathing dusts. Ensure adequate ventilation (or a respirator should be worn if PELs are exceeded) during drilling, cutting, crushing, and grinding. Use local exhaust or perform activities in well-ventilated areas. Water suppression may be used to limit airborne dusts. Most hazards are related to physical properties (including size and weight). Use mechanical devices to lift or move.

7.2 Conditions for safe storage, including any incompatibilities: Store on flat level ground. Avoid incompatible materials that may break down product such as strong oxidizers or acids.

7.3 Specific end uses: See Section 1 for intended uses.

Section 8: Exposure Controls/Personal Protection 8.1 Control parameters: Note the limits shown below are for guidance only. Follow applicable regulations

in your jurisdiction. Substance Name Source Exposure Limit Portland Cement ACGIH 1 mg/m3 (R)

OSHA 15 mg/m3 (T) / 5 mg/m3 (R) NIOSH 10 mg/m3 (T) / 5 mg/m3 (R) IDLH 5000 mg/m3

Calcium Carbonate ACGIH Removed TLV due to insufficient data. Use PNOC for exposure limit.

OSHA 15 mg/m3 (T) / 5 mg/m3 (R)

NIOSH 10 mg/m3 (T) / 5 mg/m3 (R) Fly Ash -- *Fly Ash is a byproduct from combustion of coal and thus may

contain a number of trace chemicals including silicates and metals. No exposure limit is available for Fly Ash. Use proper ventilation or

approved respirator to avoid breathing dusts.





Section 8: Exposure Controls/Personal Protection Quartz, Silica (Crystalline Silica)

ACGIH 0.025 mg/m3 OSHA (30 mg/m3 ÷ (%SiO2+2)) (T)

(10 mg/m3 ÷ (%SiO2+2)) (R) NIOSH 0.05 mg/m3 / 0.025 mg/m3

Total Dust (or Particulates Not Otherwise Classified)

ACGIH None OSHA 15 mg/m3 (T) / 5 mg/m3 (R) NIOSH 10 mg/m3 (T) / 5 mg/m3 (R)

Amorphous Silica (fumed) ACGIH Removed TLV due to insufficient data. Use PNOC for exposure limit.

OSHA 80 mg/m3 / %SiO2 or 20 mppcf NIOSH 6 mg/m3 IDLH 3000 mg/m3

Iron Oxide ACGIH 5 mg/m3 (R) OSHA 10 mg/m3 NIOSH 5 mg/m3 IDLH 2500 mg/m3

Calcium Hydroxide ACGIH 5 mg/m3 (R) OSHA 15 mg/m3 (T) / 5 mg/m3 (R) NIOSH 5 mg/m3

8.1.1 Currently recommended monitoring procedures: No recommendations.

8.1.2 Exposure guidelines for air contaminants, if any: See Section 8.1

8.1.3 DNELS and PNECS for exposure scenarios: Information not available at this time.

8.1.4 Control banding for risk management: Use good industrial hygiene practice, where appropriate PPE and use local ventilation.

8.2 Exposure Controls:

8.2.1 Appropriate engineering controls: Use local exhaust ventilation when possible to remove and prevent buildup of any dusts generated from the handling of this product. Water suppression may also be considered to limit airborne dusts during grinding, cutting, drilling or crushing activities.

8.2.2 Individual protection methods: Use good industrial hygiene practices in handling this material. Eye wash stations should be available. Wash exposed skin thoroughly with potable water and mild soap after use. If any irritation or redness is noted, treat symptomatically or consult a doctor immediately. Wear gloves, safety glasses and protective clothing. Safety shoes (steel toe) should be worn when handling heavy materials that could be dropped on the feet. In case of eye contact with projectile debris or dust, flush with plenty of clean, potable water for at least 15 minutes. Remove contacts if easy to do so. Seek medical attention immediately. Avoid dust inhalation and direct contact with skin and eyes. Wash contaminated skin before eating, drinking or smoking.

Eye/Face: Use appropriate eye protection: glasses with side shields or googles. Dust googles or a face shield (preferred) should be worn during cutting, grinding crushing, or drilling activities.

Skin: Avoid contact by covering skin with protective clothing or protective suit. Wear leather heavy-duty gloves when handling the product. Wear eye protection. Wash exposed skin thoroughly with potable water and mild soap.

Respiratory: If airborne concentrations are above the applicable exposure limits, use NIOSH-approved respirator if qualified.





Section 9: Physical and Chemical Properties Physical State: Solid Concrete

Color: Varying gray shades

Odor: Odorless

Odor Threshold: Not applicable

Melting Point: Not applicable

Freezing Point: Not applicable

Initial Boiling Point: Not applicable

Flammability (solid, gas): Lower and Upper Explosion Limits/Flammability Limit:

Not applicable Not applicable

Flash Point: Non-flammable Auto-Ignition Temperature: Not applicable

Decomposition Temperature: Not evaluated

pH: Not-applicable (powdered product may be caustic when in contact with water)

Kinematic Viscosity: Not applicable

Solubility: Non-soluble

Partition Coefficient: Not applicable

Vapor Pressure Not applicable

Density (and/or Relative Density): Not evaluated

Relative Vapor Density: Not applicable

Particle Characteristics: Variable (when broken) Section 10: Stability and Reactivity 10.1 Reactivity: Ingredients may react with incompatible materials. Product may react with strong

oxidizers, reducing agents, and acids.

10.2 Chemical stability: Stable

10.3 Possibility of hazardous reactions: Possible release of gases when ingredients come into contact with incompatible materials. Avoid dust created by agitation. Avoid contact or storage of dusty materials near incompatible substances. Avoid contact with strong oxidizing agents such as fluorine, boron trifluoride, chlorine trifluoride, manganese trifluoride, and oxygen difluoride as reactions may occur. Silica dissolves readily in hydrofluoric acid producing a corrosive gas, silicon tetrafluoride.

10.4 Conditions to avoid: Avoid excessive handling, cutting, drilling, or grinding of hardened material which may generate dust levels above permissible exposure limits.

10.5 Incompatible materials: Some ingredients have incompatible materials as detailed in Section 10.3.

10.6 Hazardous decomposition or byproducts: Highly improbable. Decomposition through thermal oxidation of limestone can produce lime. Hazardous polymerization will not occur.





Section 11: Toxicological Information 11.1 Information on toxicological effects:

Acute Exposure and Symptoms: Inhalation: Dust may cause irritation of the respiratory tract and pulmonary edema. May cause allergic or asthma-like respiratory reactions if inhaled. Skin Contact: Projectile fragments may cause cuts or abrasions when in contact with skin. Dusts may irritate the skin. Eye Contact: Projectile fragments may cause cuts or abrasions when in contact with eyes. Dusts may cause severe irritation, abrasions, burns, redness, tissue destruction and permanent eye damage including blindness (in extreme cases). Ingestion: Highly improbable. Virtually nontoxic. Ingestion of large amounts may cause gastrointestinal irritation, choking/blockage. Chronic Exposure: Prolonged inhalation of dusts may cause damage to the respiratory tract.

Repeated inhalation of high concentrations of dusts, especially respirable crystalline silica (quartz) for periods as short as six months have caused acute silicosis. Acute silicosis is a rapidly progressive, incurable lung disease that may be fatal. Not all individuals with silicosis will exhibit symptoms (signs) of the disease. However, silicosis can be progressive, and symptoms can appear at any time, even years after exposure has ceased. Symptoms of silicosis may include, but are not limited to, the following: shortness of breath; difficulty breathing with or without exertion; coughing; diminished work capacity; diminished chest expansion; reduction of lung volume; right heart enlargement and/or failure. Smoking may increase the risk of developing lung disorders, including emphysema and lung cancer. Persons with silicosis have an increased risk of pulmonary tuberculosis infection.

Several studies of persons with silicosis also indicate an increased risk of developing lung cancer, a risk that increases with the duration of exposure. Many of these studies do not account for confounding variables for lung cancer, especially smoking.

Acute and Chronic Toxicity Component Analysis: LD50/LC50 for exposure to particulate forms of the product’s components. Portland Cement (65997-15-1): No data available Calcium Carbonate (1317-65-3): No data available Fly Ash (68131-74-8): Oral LD50 Rat >2000 mg/kg (toxicity presented is for Ashes, residues (CAS no. 68131-74-8)) Silica, Quartz (Crystalline, Silica) (14808-60-7): LD50 oral rat >500 mg/kg.

Component Carcinogenicity Concrete is not listed as a carcinogen by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP), or the Occupational Safety and Health Administration (OSHA), the American Conference of Governmental Industrial Hygienists (ACGIH), or the State of California. In October 1996, an IARC Working Group re-assessing crystalline silica, a component of this product, designated crystalline silica as a carcinogen (Group 1). The NTP, ACGIH, and the State of California have listed crystalline silica (respirable size) as a known human carcinogen. This information is based on sufficient evidence of carcinogenicity in certain experimental animals and on selected epidemiological studies of workers exposed to crystalline silica.





Section 11: Toxicological Information

Substance Name IARC NTP ACGIH OSHA NIOSH Cal. Prop. 65

Portland Cement (65997-15-1) -- -- A4 -- -- -- Calcium Carbonate (1317-65-3) -- -- -- -- -- -- Fly Ash (68131-74-8) (6) -- -- -- -- -- -- Amorphous Silica (fumed) (7631-86-9) -- -- -- -- -- -- Iron Oxide (1309-37-1) -- -- A4 -- -- -- Calcium Hydroxide (1305-62-0) -- -- -- -- -- -- Silica, Quartz (Crystalline, Silica) (14808-60-7) G1 G2 A2 GS Listed YES (7)

1. ‘’--“ – Not Listed 2. OSHA - Group S: OSHA Select Carcinogen 3. IARC - Group 1: Carcinogenic to humans 4. NTP - Group 2: Reasonably Anticipated to be Human Carcinogens (R) 5. ACGIH –A2: Suspected Human Carcinogen, A4: Not Classifiable as Human Carcinogen 6. Fly Ash is a byproduct from combustion of coal and thus may contain a number of trace chemicals

including silicates and metals. Some of the components may be suspected or known carcinogens. 7. California Prop. 65 Components: WARNING! This product contains a chemical known to the State of

California to cause cancer: Crystalline Silica.

Specific Target Organ Toxicity Repeat Exposure – Respiratory System Repeated inhalation of high concentrations of dusts, especially respirable crystalline silica (quartz), for periods as short as six months has been known to cause acute silicosis. Silicosis is a rapidly progressive, incurable lung disease that can be fatal. Symptoms of silicosis may include, but are not limited to, the following: shortness of breath; difficulty breathing with or without exertion; coughing; diminished work capacity; diminished chest expansion; reduction of lung volume; right heart enlargement and/or failure. Skin Sensitizer Some components of this product may cause skin sensitization: Portland Cement and Trace metals found in fly ash.

Section 12: Ecological Information (non-mandatory) 12.1 Ecotoxicity:

General Product Information: Product when used as intended is not anticipated to pose and environmental impact. Component Analysis - Ecotoxicity : No ecotoxicity data are available for this product's components. Environmental Fate: No information available for the product.

Section 13: Disposal Considerations (non-mandatory) 13.1 Waste treatment methods:

General Product Information: Whatever cannot be saved or recovered for recycling should be disposed of according to state and local regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.





Section 14: Tranport Information (non-mandatory) US DOT Information Not Regulated

IMDG Not Regulated

IATA Not Regulated

Section 15: Regulatory Information (non-mandatory) 15.1 Safety, health, and environmental regulation:

US Federal Regulations General Product Information: All components are on the U.S. EPA TSCA Inventory List. Portland Cement and crystalline silica are exempt from reporting under the inventory update rule. Component Analysis: Some ingredients within components of this product are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65), or CERCLA (40 CFR 302.4). SARA 311/312 Tier II Hazard Ratings: Crystalline Silica

Acute Health Hazard Chronic Health Hazard Fire Hazard Reactivity Hazard

Sudden Release of Pressure

No Yes No No No State Regulations General Product Information: Other state regulations may apply. Check individual state requirements. California Prop. 65 Components: WARNING! This product contains a chemical known to the State of California to cause Cancer: Crystalline Silica

Component Analysis – WHMISIDL:

Component EINECS/EC CAS Minimum Concentration

Silica, Quartz (Crystalline, Silica) 231‐545‐4 14808-60-7 1%

Additional Regulatory Information General Product Information: No additional information available. Component Analysis – Inventory:

Component EINECS/EC CAS TSCA CAN EC Portland Cement 266-043-4 65997-15-1 Yes DSL EINECS Calcium Carbonate 207-439-9 1317-65-3 Yes DSL EINECS Fly Ash (1) 268-627-4 68131-74-8 Yes DSL EINECS Amorphous Silica (fumed) 231-545-4 (2) 7631-86-9 Yes DSL EINECS Ferric Oxide 215-168-2 1309-37-1 Yes DSL EINECS Calcium Hydroxide 215-137-3 1305-62-0 Yes DSL EINECS Silica, Quartz (Crystalline, Silica) 231‐545‐4 14808-60-7 Yes DSL EINECS 1. Information presented is for Ash residues 68131-74-8. Fly ash contains many components that may or

may not be listed in these inventories. 2. EINECS/EC number for Amorphous silica is a general silica number.


SAFETY DATA SHEET (SDS)

Ready Mixed Concrete

Section 1. Identification Product identifier: Ready Mixed Concrete

Other means of identification:

Concrete, Ready Mix Concrete, Concrete Ready Mix, Portland Cement Concrete, Ready Mix Grout, Permeable Concrete, Shotcrete, Gunite, Colored Concrete, Flowable Fill, Roller- Compacted Concrete, Fiber Reinforced Concrete

Identified uses: Concrete is widely used as a structural component in many construction applications.

Supplier's details: Carew Concrete & Supply Co., Inc 1811 West Edgewood Drive Appleton, WI 54913 920-731-9771

Emergency telephone number:

Poison Help line: 1-800-222-1222 (24 hours/day)

Section 2. Hazards Identification Classification of mixture: Skin Corrosion/Irritation: Category 1

Eye Damage/Irritation: Category 1 Sensitization – Skin: Category 1 Specific Target Organ Toxicity (Single Exposure) (Respiratory tract irritation): Category 3

Signal word: Danger

Pictograms:

Hazard statements: May cause severe skin burns and serious eye damage. May cause an allergic skin reaction. May cause respiratory irritation.

Precautionary statements:

Wear protective gloves. Wear eye and/or face protection. Avoid breathing dust. Wash hands thoroughly after handling. May cause eye and skin burns. See Section 4 for additional details. May present risk of engulfment. See Section 7 for additional details. Overexposure to wet concrete can cause severe, potentially irreversible tissue (skin, eye, respiratory tract)

Continued…

damage in the form of chemical burns, including third degree burns. The same severe injury can occur if wet or moist skin is exposed to dry Ready Mixed Concrete dust. Clothing wet with moisture from concrete can transmit the caustic effects to the skin, causing chemical burns. Ready Mixed Concrete may cause skin burns with little warning; discomfort or pain cannot be relied upon to alert a person to a serious injury. Pain or the severity of the burn may not be felt or known until hours after the exposure. Medical conditions which may be aggravated by exposure: Contact with wet concrete may aggravate existing skin conditions. Sensitivity to hexavalent chromium can be aggravated by exposure.

Hazards not otherwise classified: Not applicable.

Section 3. Composition/Information on Ingredients Substance/mixture: Mixture (Portland Cement, Coarse Aggregate, Fine Aggregate, Water, Admixtures)

CAS number: Not applicable.

Product code: Not applicable.

Ingredient name (Structure of Ready Mixed Concrete may contain the following in some concentration ranges):

% CAS Number

Quartz (Aggregates) 0-80 14808-60-7

Limestone (Aggregates) 0-80 131 7-65-3

Portland cement 0-20 65997-15-1

Slag cement 0-15 N/A

Fly ash 0-10 68131-74-8

Any concentration shown as a range is to protect confidentiality or is due to batch variation. Chemical admixtures may be present in ranges of less than 1%. Individual composition of hazardous constituents may vary between types/different mix designs of Ready Mixed Concrete. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8.

Section 4. First-aid Measures Inhalation: Seek medical help if coughing or other symptoms persist. Inhalation of large

amounts of Ready Mixed Concrete requires immediate medical attention. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If the individual is not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.

Skin contact: Continued…

Get medical attention immediately. Heavy exposure to Ready Mixed Concrete dust, wet concrete or associated water requires prompt attention. Quickly remove contaminated clothing, shoes, and leather goods such as watchbands and belts. Quickly wash or brush away Ready Mixed Concrete. Immediately wash thoroughly with gently flowing water and non-abrasive pH neutral soap. Seek medical attention for rashes, burns, irritation, dermatitis and prolonged unprotected exposures to wet concrete, concrete mixtures or liquids from wet concrete. Burns should be treated as caustic burns. Ready Mixed Concrete may cause skin burns with little warning. Discomfort or pain cannot be relied upon to alert a person to a serious injury. You may not feel pain or the severity of the burn until hours after the exposure. Chemical burns must be treated promptly by a physician. In the event of any complaints or symptoms, avoid further exposure.

Eye contact: Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Chemical burns must be treated promptly by a physician.

Ingestion: Get medical attention immediately. Call a poison center or physician. Have victim rinse mouth thoroughly with water. Do not induce vomiting unless directed to do so by medical personnel. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop giving water if the exposed person feels sick as vomiting may be dangerous. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.

Important symptoms/effects, acute and delayed:

Inhalation: May cause respiratory irritation. Adverse symptoms may include the following: respiratory tract irritation, coughing

Skin contact: May cause severe burns. May cause an allergic skin reaction. Adverse symptoms may include the following: pain or irritation, redness, blistering may occur

Eye contact: May cause serious eye damage. Adverse symptoms may include the following: pain, watering, redness

Ingestion: May cause burns to mouth, throat and stomach. Adverse symptoms may include the following: stomach pains

Indication of immediate medical attention and special treatment, if necessary:

If inhaled: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Prolonged and repeated inhalation of respirable crystalline silica-containing dust in excess of appropriate exposure limits has caused silicosis, fibrosis or scar tissue formations in the lungs. Call a poison center or physician if you feel unwell.

If on skin:

Wash with plenty of pH neutral soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. If skin irritation or rash occurs: get

Continued…

medical attention. Ready Mixed Concrete may contain trace amounts of hexavalent chromium. Hexavalent chromium is associated with allergic skin reactions which may appear as contact dermatitis and skin ulcerations. Persons already sensitized may react to their first exposure to concrete. Other individuals may develop allergic dermatitis after repeated exposure to concrete. The symptoms of allergic reactions may include reddening of the skin, rash, and irritation. Symptoms of chronic exposure to wet concrete may include reddening, irritation, and eczematous rashes. Drying, thickening, and cracking of the skin and nails may also occur.

If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Exposure to dust may cause immediate or delayed irritation or inflammation. Eye contact by larger amount of dry power or splashes of wet Ready Mixed Concrete may cause effects ranging from moderate eye irritation to chemical burns or blindness. Immediately call a poison center or physician.

If ingested: Irritating to mouth, throat and stomach. Ingestion of large quantities may cause severe irritation and chemical burns of the mouth, throat, stomach and digestive tract. Do not ingest Ready Mixed Concrete. Get immediate medical attention.

Notes to physician: Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Protection of first-aiders: No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wear gloves when removing contaminated clothing.

See toxicological information listed in Section 11.

Section 5. Fire-fighting Measures Suitable extinguishing media: Use an extinguishing agent suitable for the surrounding fire.

Unsuitable extinguishing media: None known.

Specific hazards arising from the product:

No specific fire or explosion hazard.

Hazardous thermal decomposition products may include:

Carbon dioxide, carbon monoxide, sulfur oxides, metal oxide/oxides

Special protective equipment and precautions for fire-fighters:

Fire-fighters should wear appropriate protective equipment.

Section 6. Accidental Release Measures For non-emergency personnel: Personnel involved with the handling of wet unhardened concrete

should take steps to avoid contact with the eyes and skin, through the use of gloves and suitable clothing as described in Section 8. Silica-containing respirable dust particles may be generated by crushing, cutting, grinding, or drilling hardened concrete or concrete products, and should always be avoided. Follow protective controls defined in Section 8 when handling these products. When cutting, grinding, crushing or drilling hardened concrete, use local exhaust or general

dilution ventilation or other suppression methods to maintain dust levels below exposure limits.

For emergency responders : For personal protective clothing and equipment requirements, please see Section 8.

Environmental precautions: Wet unhardened concrete should be recycled or allowed to harden and disposed. Do not wash concrete down sewage and drainage systems or into bodies of water (e.g. lakes, streams, wetlands, etc.).

Methods and materials for containment and cleaning up spills:

Place spilled material into a contained area and allow wet unhardened concrete to harden and dispose in a landfill as common solid waste. Follow applicable Federal, State, and local regulations for disposal. Uncontaminated ready mixed concrete is neither a listed nor a characteristic hazardous waste under designations by the USEPA or USDOT.

USDOT Class: Uncontaminated ready mixed concrete does not meet any hazardous material class definition found in Title 49 Code of Federal Regulations Part 173.

Section 7. Handling and Storage Precautions for safe handling: When required use appropriate personal protective equipment (see

Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure by obtaining and following special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe dust. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Conditions for safe storage, including any incompatibilities:

A key to using the product safely requires the user to recognize that Ready Mixed Concrete reacts chemically with water to produce calcium hydroxide which can cause severe chemical burns. Every attempt should be made to avoid skin and eye contact with concrete. Do not get Ready Mixed Concrete inside boots, shoes or gloves. Do not allow wet, saturated clothing to remain against the skin. Promptly remove clothing and shoes that are dusty or wet with concrete mixtures. Launder/clean clothing and shoes before reuse.

Section 8. Exposure Controls/Personal Protection Ingredient name:

Exposure limits:

OSHA PEL: ACGIH TLV: NIOSH REL: MSHA PEL:

Quartz* Continued…

TWA: 10 mg/m3 / (%SiO2+2) 8 hours. Form: Respirable TWA: 250 MPPCF / (%SiO2+5) 8 hours. Form: Respirable

TWA: 0.025 mg/m3 8 hours. Form: Respirable fraction

TWA: 0.05 mg/m3 10 hours. Form: respirable dust

N/A

Portland cement

TWA: 5 mg/m3 8 hours. Form: Respirable fraction TWA: 15 mg/m3 8 hours. Form: Total dust

TWA: 1 mg/m3 8 hours. Form: Respirable fraction

TWA: 5 mg/m3 10 hours. Form: Respirable fraction TWA: 10 mg/m3 10 hours. Form: Total

N/A

Limestone*

TWA: 5 mg/m3 8 hours. Form: Respirable fraction TWA: 15 mg/m3 8 hours. Form: Total dust

N/A TWA: 5 mg/m3 10 hours. Form: Respirable fraction TWA: 10 mg/m3 10 hours. Form: Total

N/A

Fly ash* TWA: 5 mg/m3 8 hours. Form: Respirable fraction TWA: 15 mg/m3 8 hours. Form: Total dust

TWA: 10 mg/m3 10 hours. Form: Total

N/A N/A

Slag cement N/A N/A N/A N/A

*Each of these ingredients may have crystalline silica (quartz) as a component. The percent of silica varies greatly from product to product and also within the same product. Silica exposure may occur when respirable dust is present. Dust is not present in freshly mixed unhardened Ready Mixed Concrete. Admixtures may be present in quantities of less than 1%.

Appropriate engineering controls:

Use only with adequate ventilation. If user operations generate dust, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.

Individual protection measures (including Personal Protective Equipment):

Clean water should always be readily available for skin and (emergency) eye washing. Periodically wash areas contacted by Ready Mixed Concrete with a pH neutral soap and clean, uncontaminated water. If clothing becomes saturated with Ready Mixed Concrete, it should be removed and replaced with clean, dry clothing. To prevent eye contact, wear safety glasses with side shields, safety goggles or face shields when handling dust or wet concrete. Wearing contact lenses when working with concrete is not recommended. Use impervious, waterproof, abrasion and alkali-resistant gloves. Do not rely on barrier creams in place of impervious gloves. Do not get Ready Mixed Concrete inside gloves. Use impervious, waterproof, abrasion and alkali-resistant boots and long-sleeved and long-legged clothing to protect the skin from contact with wet Ready Mixed Concrete. To reduce foot and ankle exposure, wear impervious boots that are high enough to prevent Ready Mixed Concrete from getting inside them. If finishing concrete, wear waterproof knee pads to protect knees. Do not get Ready Mixed Concrete inside boots, shoes, or gloves. Remove clothing and protective equipment that becomes saturated with concrete and immediately wash exposed areas of the body. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved. Footwear and other gear to protect the skin should be approved by a specialist before handling this product. Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. (See OSHA Respiratory Protection Standard 29 CFR 1910.134)

Section 9. Physical and Chemical Properties Appearance (physical state, color, etc.)

Solid, semi-fluid, flowable, granular paste, varying Gray color, varying

Upper/lower flammability or explosive limits:

N/A

Odor: Odorless Vapor pressure: N/A

Odor threshold: N/A Vapor density: N/A

pH: Pour solution: 12+ Relative density: Normal weight concrete: 2.2 to 2.6

Melting point/freezing point:

N/A Solubility: N/A

Initial boiling and boiling range:

N/A Partition coefficient: n-octanol/water:

N/A

Flash point: Not flammable. Not combustible.

Auto-ignition temperature:

N/A

Evaporation rate: N/A Decomposition temperature:

N/A

Flammability (solid, gas): N/A Viscosity: N/A

Section 10. Stability and Reactivity Reactivity: Cementitious materials react slowly with water forming hydrated compounds,

releasing heat and producing a strong alkaline solution.

Chemical stability: The product is stable.

Possibility of hazardous reactions:

Under normal conditions of storage and use, hazardous reactions will not occur.

Conditions to avoid: No specific data.

Incompatible materials: Reactive or incompatible with the following materials: oxidizing materials, acids, aluminum and ammonium salt. Ready Mixed Concrete is highly alkaline and will react with acids to produce a violent, heat-generating reaction. Toxic gases or vapors may be given off depending on the acid involved. Reacts with acids, aluminum metals and ammonium salts. Aluminum powder and other alkali and alkaline earth elements will react in wet mortar or concrete, liberating hydrogen gas. Limestone ignites on contact with fluorine and is incompatible with acids, alum, ammonium salts, and magnesium. Silica reacts violently with powerful oxidizing agents such as fluorine, boron trifluoride, chlorine trifluoride, manganese trifluoride, and oxygen difluoride yielding possible fire and/or explosions. Silicates dissolve readily in hydrofluoric acid producing a corrosive gas - silicon tetrafluoride.

Hazardous decomposition products:

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Section 11. Toxicological Information Likely routes of exposure: Dermal contact. Eye contact. Inhalation. Ingestion.

Symptoms:

Inhalation: May cause respiratory irritation. Adverse symptoms may include the following: respiratory tract irritation, coughing

Skin contact: May cause severe burns. May cause an allergic skin reaction. Adverse symptoms may include the following: pain or irritation, redness, blistering may occur

Eye contact: May cause serious eye damage. Adverse symptoms may include the following: pain, watering, redness

Ingestion: May cause burns to mouth, throat and stomach. Adverse symptoms may include the following: stomach pains

Delayed and immediate effects:

Repeated or prolonged inhalation of dust may lead to chronic respiratory irritation. If sensitized to hexavalent chromium, a severe allergic dermal reaction may occur when subsequently exposed to very low levels.

Numerical measures of toxicity:

No data available.

Ingredient name: NPT IARC OSHA MSHA NIOSH EPA ACGIH

Portland cement Known to be a human carcinogen.

N/A N/A N/A N/A N/A A4

Quartz Known to be a human carcinogen.

1 N/A N/A N/A N/A A2

Section 12. Ecological Information Ecotoxicity: Only relevant in accidental spillages of fresh unhardened concrete. If it

reaches water, it can result in a slight rise in pH. Hardened concrete is inert.

Persistence and degradability: No data available.

Bioaccumulative potential : No data available.

Mobility in soil: No data available.

Other adverse effects: No known significant effects or critical hazards.

Section 13. Disposal Considerations If disposing Ready Mixed Concrete, it should be done in accordance with local, regional, and national regulations. The generation of waste should be avoided or minimized wherever possible. If disposing this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Process water should not be released to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Landfill should only be considered when recycling is not feasible. This material must be disposed of in a safe manner. Avoid dispersal of spilled material and runoff in waterways, drains and sewers.

Section 14. Transport Information UN number: Not regulated.

UN proper shipping name: N/A

Transport hazard class(es): N/A

Packing group: N/A

Environmental hazards: None.

Transport in bulk: Annex II of MARPOL 73/78 and the IBC Code

Special precautions: Ensure that persons transporting the product know what to do in the event of an accident or spillage.

Section 15. Regulatory Information OSHA Hazard Communication: This product is considered by OSHA to be a hazardous material and should be included in the employer’s hazard communication program. CERCLA/SUPERFUND: This product is not listed as a CERCLA hazardous substance. EPCRA SARA Title III: This product has been reviewed according to the EPA Hazard Categories promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 and is considered a hazardous and a delayed health hazard. EPCRA SARA Section 313: This product may contain substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. RCRA: If discarded in its hardened form, this product would not be a hazardous waste either by listing characteristic. However, under RCRA, it is the responsibility of the product user to determine at the time of disposal, whether a material containing the product or derived from the product should be classified as a hazardous waste. TSCA: Portland Cement and crystalline silica are exempt from reporting under the inventory update rule. California Proposition 65: Crystalline silica (airborne particulates of respirable size) and Chromium (hexavalent compounds) are substances known by the State of California to cause cancer. WHMIS/DSL: Products containing crystalline silica and calcium carbonate are classified as D2A, E and are subject to WHMIS requirements.

Section 16. Other Information Date of last revision: January 2017




Section 16: Other Information Other Information Disclaimer: Supplier gives no warranty of merchantability or of fitness for a particular purpose. Any

product purchased is sold on the assumption the purchaser will make his own tests to determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental and/or consequential property damage arising out of the use of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. Read the Safety Data Sheet before handling product.

Key to Abbreviations and Acronyms: ACGIH: ADR:

American Conference of Governmental Industrial Hygienists European Agreement concerning the International Carriage of Dangerous Goods by Road

CLP: Classification, Labelling, and Packaging DNEL: Derived no effect level DSL: EC:

Canada’s Domestic Substances List European Community

EEC: EINECS: EPA: EU:

European Economic Community European Inventory of Existing Commercial Chemical Substances Environmental Protection Agency European Union

GHS Globally Harmonized System of classification and labelling of chemicals IARC: IATA:

International Agency for Research on Cancer International Air Transport Association

ATA-DGR: Dangerous Goods Regulations by the International Air Transport Association ICAO: International Civil Aviation Organization ICAO-TI: Technical Instructions by the International Civil Aviation Organization (ICAO) IMDG: International Maritime Code for Dangerous Goods IP: Inhalable Particles LC50: Lethal concentration in air fatal to 50 percent of test animals LD50: Lethal dose by mouth or other route to 50 percent of test animals LDLo: Lowest lethal dose MPPCF: Million particles per cubic foot NIOSH: NJTSR: NOEC: NOS:

National Institute for Occupational Safety and Health New Jersey Trade Secret Registry No observed effects Not Otherwise Specified

NTP: OSHA:

National Toxicology Program Occupational Safety and Health Administration (USA)

PNEC: Predicted no effect concentration PPM: Parts per million R: Respirable Particles RID: Regulations Concerning the International Transport of Goods by Rail STEL: Short term exposure limit T: Total Dust TLV: Threshold Limit Value TSCA: TWA:

Toxic Substance Control Act Time weighted average

** This is the end of SDS – Pre-Cast / Pre-Stressed Concrete Products **


ENV.MSDSGI Page 1 of 3 11/05/2009

MATERIAL SAFETY DATA SHEET (MSDS)

SC-000-042 REV. 6 Vendor name and address: NEENAH FOUNDRY COMPANY

DATE: 10/97 PO BOX 729

NEENAH WI 54956

(920) 725-7000

Conforms to requirements of OSHA standard 1910.1200

“

INGREDIENT CAS NO. % TLV PEL

SECTION I PRODUCT (mg/m3) (mg/m

3)

Nickel* (as Ni) 7440-02-0 0.01-1.5

This MSDS supplied for: GRAY IRON Metal 1.5 1.0

Insoluble Compounds (as Ni) 0.2 1.0

ASTM ALLOY DESIGNATION Soluble Compounds (as Ni) 0.1 1.0

Silicon (as Si) 7440-21-3 1.0-3.5

Total Dust 10.0 15.0

Respirable Dust N/E 5.0 N/E = none established. N/A = not applicable. N/D = no data available.

INGREDIENT CAS NO. % TLV PEL TLV = American Conference of Governmental Industrial Hygienists (ACGIH) Threshold

(mg/m3) (mg/m

3) Limit Value (8-hour time weighted average).

Carbon (as C) 7440-44-0 2.5-4.0 N/E N/E PEL = OSHA Permissible Exposure Limit.

mg/m3 = Milligrams per cubic meter of air.

Chromium* (as Cr) 7440-47-3 0.01-0.9 NTP = National Toxicology Program.

Chromium (II) Compounds (as Cr) N/E 0.5 C = Ceiling limit

Chromium (III) Compounds (as Cr) 0.5 0.5 STEL = Short Term Exposure Limit.

Chromium Metal (as Cr) 0.5 1.0 SARA Title III Information

Chromium (VI) Insoluble Compounds 0.01 N/E *This constituent, a toxic chemical, makes this product subject to the reporting requirements of

Chromic Acid & Chromates (as CrO3) N/E 1.0 mg/10 m3(C) Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR

Chromium, (VI) Compounds Water Part 372. Quantity threshold amounts are 25,000 pounds for manufacturing, importing or processing

Soluble (as Cr) 0.05 N/E and 10,000 pounds for otherwise using the listed chemical. Chemicals marked ** are reportable only

if in the form of dust or fume.

Iron (as Fe2O3) 1309-37-1 86.3-96.2

Iron Oxide Fume (Fe2O3) N/E 10.0 CARCINOGEN CLASSIFICATION

Iron Oxide Dust & Fume (Fe2O3) 5.0 N/E INGREDIENT OSHA NTP IARC EPA TARGET ORGAN

Carbon N N N N -

Manganese* (as Mn) 7439-96-5 0.2-1.1 Chromium (Hexavalent) N K 1 A-K Lung

Fume (as Mn) N/E 5.0 (C) Iron N N 3 N Lung

Elemental & Inorganic Compounds Manganese N N N D Central Nervous System

Compounds (as Mn) 0.2 5.0 (C) Nickel R 2B N Lung, Nasal

Silicon N N N N -

MATERIAL SAFETY DATA SHEET (MSDS) DOC NAME: GRAY IRON MSDS

DOC #: ENV.MSDSGI Vendor name and address: ADVANTAGE TACTILE

DATE REVIEWED: 11/05/2009 241 Main Street, Suite 100

Buffalo, NY 14203

PH: 800-679-4022

Conforms to requirements of OSHA standard 1910.1200 FAX: 800-679-4023

“Hazard Communication” and to various state “Employee Right to Know” Laws Emergency Number: CHEMTREC (800) 424-9300

GRAY IRON SECTION II – HAZARDOUS COMPONENTS (cont’d)

SECTION II – HAZARDOUS COMPONENTS

SECTION I– PRODUCT IDENTIFICATION


OSHA-OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION N= Not listed as a Human Carcinogen Y= Listed as a Human Carcinogen insoluble hexavalent (carcinogenic) form, but the chromium content of the casting

NTP-NATIONAL TOXICOLOGY PROGRAM is so low that over exposure is not likely. K= Known to be a Human Carcinogen R= Reasonably anticipated to be a Human Carcinogen (RAHC)

N= Not listed as a Human Carcinogen Nickel has been shown to cause cancer in laboratory animals. However its potential

IARC-INTERNATIONAL AGENCY FOR RESEARCH ON CANCER to cause cancer in humans has not been determined. The nickel content of the casting 1= Carcinogen to Humans is so low that over-exposure is not likely. 2B= Possibly Carcinogenic to Humans 3= Unclassified as Carcinogenicity in Humans

N= Not listed as a Carcinogen Grinding castings that have not been cleaned or that contain embedded sand will generate

EPA-U.S. ENVIRONMENTAL PROTECTION AGENCY significant amounts of dust containing free silica, which can cause silicosis. Good local

A= Human Carcinogen ventilation is frequently required to prevent over-exposure in this situation. K= Known to be a Human Carcinogen D= Not classified as to Human Carcinogenicity. No data available If good ventilation is not available, use a NIOSH-approved dust respirator. IARC has listed

B1= Probable Human Carcinogen. Sufficient evidence from Epidemiologic Studies crystalline silica as Class 2A, probably can cause lung cancer. L= Likely to produce Cancer in humans B2= Probable Human Carcinogen. Sufficient evidence from Animal Studies Other toxic metals in the alloy are present in small amounts that will not represent a hazard

N= Not listed as a Human Carcinogen if iron dust and fume are adequately controlled.

There are no chemical hazards from these castings in solid form.

PHYSICAL DESCRIPTION: Solid, silver gray in color, no odor

Dust or fumes generated by machining, grinding, or welding of the casting will put BOILING POINT: 2750C for iron

contaminants in the air. Since the casting is over 85% iron, most of the dust or fume VAPOR PRESSURE: N/A

will be iron or iron oxide. There is no TLV for iron dust, but available information VAPOR DENSITY: N/A

indicates that a concentration of 10 mg/m3, as if it were a nuisance dust, will serve SOLUBILITY IN WATER: N/A

as a guideline until a TLV is established. SPECIFIC GRAVITY: 7.86 for iron

PERCENT VOLATILE BY VOLUME: N/A

High production dry machining of gray iron castings usually requires local exhaust EVAPORATION RATE: N/A

ventilation.

Flame cutting, arc gouging, or welding of the casting generates iron oxide fume.

Inhalation of too much iron oxide fume over a long time can cause siderosis, some-

times called “iron pigmentation” of the lung. It can be seen on a chest x-ray but Castings will not burn or explode.

causes little or no disability. Also see the MSDS for the welding rod being used.

Welding or flame cutting may convert a fraction of the chromium to the water EYES: Metal particles in the eyes may cause irritation if not removed. Contact lenses

should be worn with caution in a metalcasting environment. Obey work rules concerning

contact lenses.

SKIN: Carbon: Skin irritation; Nickel: Dermatitis; Silicon: Skin irritation.

SECTION III - OVERVIEW

SECTION II – HAZARDOUS COMPONENTS (cont’d)

SECTION V – FIRE AND EXPLOSION DATA

SECTION VI – HEALTH HAZARD DATA

SECTION IV – PHYSICAL DATA

SECTION III – OVERVIEW (cont’d)


BREATHING: Prolonged or repeated overexposure to dust or fumes from

these castings may cause the following health effects: STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:

Carbon: Respiratory irritation. If damaged, return castings to vendor or scrap reclaimer.

Chromium, Hexavalent: Lung cancer.

Iron: Iron pigmentation of the lung, which can be seen in a chest x-ray but Collected dust from machining, welding, etc., may be classed as a “hazardous

causes little or no disability. Siderosis-inflammation of the lungs. waste” depending on circumstances. Consult local authorities regarding disposal.

Manganese: Central nervous system effects are: sleepiness, weakness in legs,

spastic gait, emotional disturbances.

Nickel: Lung and nasal cancer.

Silicon: Skin, eye and nose irritation. RESPIRATORY PROTECTION: Wear a NOISH approved respirator for dusts

Breathing excessive amounts of silica dust for a long time can cause silicosis. or fume if concentrations exceed the TLV or PEL.

Silicosis causes shortness of breath, reduced capacity to do work, and weakens

the defenses against other lung diseases. VENTILATION: Provide general ventilation and/or local exhaust if necessary

INGESTION: Hand, clothing, food and drink contact with metal dust, fume to maintain concentrations below the TLVs.

or powder can cause ingestion of particulate during hand to mouth activities

such as eating, drinking, smoking, nail biting, etc. PROTECTIVE GLOVES: Work gloves advisable for handling castings.

NOISE: Grinding or machining castings is noisy. The OSHA limit for noise

averaged over 8 hours is 90 decibels (dBA). A hearing conservation program is EYE PROTECTION: Safety glasses with side shields and/or face shields for

required if exposure is over 85 dBA. If noise is at or above 90 dBA. You should particles (grinding). Welding goggles or helmet for welding.

wear earmuffs or earplugs.

OTHER PROTECTIVE EQUIPMENT: Wear a protective apron and gauntlets if

FIRST AID arc-air gouging or cutting, or welding castings. Safety shoes may be required during

IF IN EYES: Metal particles should be removed by a trained individual such as certain operations.

a nurse or physician.

IF ON SKIN: Use a mild hand cream if irritation develops. If noise is at or above 90 dBA, you should wear earmuffs or earplugs.

IF BREATHED: (Fumes from welding): Move to fresh air.

IF INGESTED: Consult local physician.

STORAGE: Keep dry to reduce rusting.

THE INFORMATION CONTAINED HEREIN IS BASED ON THE VENDOR’S

HAZARDOUS POLYMERIZATION: Will not occur. MSDS WITH ADDITIONS AS NECESSARY TO COMPLY WITH CURRENT

STABILITY: Stable. REGULATIONS. THE INFORMATION IS BELIEVED TO BE ACCURATE

INCOMPATIBILITY: Metal dust can burn or explode and must be protected BUT UNDER THE CIRCUMSTANCES IS NOT WARRANTED TO BE.

from ignition sources such as grinding sparks, etc. Under some conditions,

metal dust is incompatible with some oxidizing conditions and may be

incompatible with oxidizers, acids and water and may ignite or explode.

SECTION VI – HEALTH HAZARD DATE (cont’d)

SECTION VII – REACTIVITY DATA

SECTION VIII – SPILL OR LEAK PROCEDURES

SECTION IX – PROTECTIVE EQUIPMENT TO BE USED

SECTION X – SPECIAL PRECAUTIONS OR OTHER COMMENTS

Hazard Communication Label

The following hazard information is required for labels under OSHA Standard

1910.1200 and applicable instructions. Other label information may be added.

CAUTION

Grinding , welding, or arc gouging of this casting creates dust or fumes containing

substances listed below with corresponding possible health effects after prolonged or

repeated overexposure.

Carbon: Respiratory and skin irritation.

Chromium, Hexavalent: Lung cancer.

Iron: Iron pigmentation of the lung, which can be seen in a chest x-ray but causes

little or no disability. Siderosis-inflammation of the lungs

Manganese: Central nervous system effects are: sleepiness, weakness in legs,

spastic gait, and emotional disturbances.

Nickel: Dermatitis, lung and nasal cancer.

Silicon: Skin, eye and nose irritation.

Wear eye protection. Wear approved dust and fume respirator if exposures exceed

safe limits.

GRAY IRON

BLACK SWAN MFG. CO.

GHS

SECTION 1

Manufacturer:

Black Swan Mfg. Co.

4540 W. Thomas St.

Chicago, IL 60651-3318

Tel.: 800-252-5796

Fax: 773-227-3705

Web Site : www.blackswanmfg.com

E-mail : [email protected]

Product Name: All Purpose Pipe Dope

SECTION 2

Labels

Irritant

NFPA

HEALTH HAZARD FIRE 4 – Deadly

3 - Extreme Danger

2 – Hazardous

1 - Slight Hazardous

0 - Normal Material

SPECIFIC HAZARD Oxidizer OX 4

Acid ACID 3

Alkali ALK may detonateCorrosive COR 2

Use NO WATER W

Radioactive

Signal Word Warning

HMIS

Hazardous Statements H303: May be harmful if swallowed.

H313: May be harmful in contact with skin.

H335 + H336: May cause respiratory irritation and drowsiness or dizziness.

SECTION 3 – COMPOSITION / INFORMATION ON INGREDIENTS

Chemicals CAS#

2-BUTOXYETHANOL 111-76-2

OXIDIZED CASTOR OIL 68187-84

CALCIUM CARBONATE 1317-65

SILICONE DIOXIDE,

CHEMICALLY PREPARED 112945-

*Unlisted ingredients are not classified as hazardous according to OSHA 1910.1200.

SECTION

Inhalation: Move into fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen and call physician

Skin: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water.

Eyes: Flush with water for 15 minutes. If irritation persists, get medical attention.

Ingestion: Give 1 or 2 glasses of water. DO NOT INDUCE VOMITING. Contact physician im

21

HEALTH

FLAMMABILITY

REACTIVITY

1

2

0

`

BLACK SWAN MFG. CO.

GHS SAFETY DATA SHEET

SECTION 1 - IDENTIFICATION

www.blackswanmfg.com

For any Transportation or Medical Chemical Emergencies call:

INFOTRAC

(800) 535-5053 OR

24 hours per day -

Recommended Use: To seal threaded pipes on metal and plastic

connections.

SECTION 2 – HAZARD(S) IDENTIFICATION

NFPA

AZARD FIRE HAZARD Flash Points

4 – Below 73°F

3 – Below 100°F

2 – Above 100°F, Not

exceeding 200°F

1 – Above 200°F 0 – Will not burn

REACTIVITY Oxidizer OX 4 – May detonate

Acid ACID 3 – Shock and heat

ALK may detonate Corrosive COR 2 – Violent chemical

change

1 – Unstable if heated

0 – Stable

GHS Classification

Health Acute Toxicity: Not Established

Skin Irritation: Cat. 3 Acute Aquatic Toxicity: Not Established

Eye Irritation: Cat. 2B Chronic Aquatic Toxicity: Not Est

Skin Sensitization: NO

Physical None

H335 + H336: May cause respiratory irritation and drowsiness or dizziness.

Precautionary StatementsP102: Keep out of reach of children

P233: Keep container tightly closed

P262: Do not get in eyes, on skin or on clothing

P271: Use only outdoors or in well-ventilated area

COMPOSITION / INFORMATION ON INGREDIENTS

CAS# EINECS# REACH

Pre-registration Number

2 N/A N/A 13

84-8 269-128-4 N/A

65-3 N/A N/A

-52-2 N/A N/A

according to OSHA 1910.1200.

SECTION 4 – FIRST- AID MEASURES

Move into fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen and call physician

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water.

Flush with water for 15 minutes. If irritation persists, get medical attention.

Give 1 or 2 glasses of water. DO NOT INDUCE VOMITING. Contact physician immediately.

Page 1 of 3

2 0

any Transportation or Medical Chemical Emergencies call:

INFOTRAC

(352) 323-3500

7 days a week

To seal threaded pipes on metal and plastic

GHS Classification

Environmental

Acute Aquatic Toxicity: Not Established

Chronic Aquatic Toxicity: Not Established

Precautionary Statements

not get in eyes, on skin or on clothing

ventilated area


REACH Approx %

registration Number

N/A N/A 13-18%

N/A 5-10%

N/A N/A 60-80 %

N/A N/A 1-2 %

Move into fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen and call physician.

`


SECTION 5 – FIRE-FIGHTING MEASURES

Fire Hazard: Combustible-Moderate flash point. Vapors heavier than air and may travel along the ground or to low spots at considerable

distances to a source of ignition resulting in potential flashback. Burning liquid may float on water. Heat may build up pressure and rupture

containers.

Combustion Products: None known.

Extinguishing Media: Carbon Dioxide Gas, Dry Chemical Powder, and Water.

Unsuitable Extinguishing Media: None known.

Protective Equipment: Self-contained breathing apparatus {(SCBA), MSHA/NIOSH}. Full protective gear.

Special Fire Fighting Procedures: As appropriate for combustibles in area.

SECTION 6 – ACCIDENTAL RELEASE MEASURES

Personal Precautions: None.

Protective Equipment: None.

Emergency Procedures: None.

Environmental Precautions: Avoid runoff into storm sewers, ditches and waterways.

Methods for Cleaning Up: Soak up spill with an inert absorbent such as sand, earth or other noncombusting material. Transfer absorbent

material to a covered, labeled, metal container. Do not use plastic or aluminum containers.

SECTION 7 – HANDLING AND STORAGE

Handling Avoid prolonged or repeated contact with skin or clothing. Empty

containers may contain residues; treat as if full and observe all

product precautions. Do not reuse empty containers.

Storage Keep container closed and upright when not in use. Do not store

near heat, sparks, or open flames.

SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Limits

Hazardous Chemicals ACGIH-TLV ACGIH-STEL OSHA-PEL 2-BUTOXYETHANOL 25 ppm N/A 50 ppm

Engineering Controls: A source of running water to flush or wash the eyes and skin in case of contact. Use local exhaust as needed.

Ventilation: Local ventilation is adequate.

Personal Protective Equipment – Respiratory: Avoid breathing of fumes. If used in a confined area, a respirator may be necessary.

Personal Protective Equipment – Skin: Protective Gloves.

Personal Protective Equipment – Eyes: Protective Goggles.

SECTION 9 – PHYSICAL & CHEMICAL PROPERTIES Appearance: Light Yellowish Paste Flash Point: 82°F Vapor Pressure: 0.88mm Hg @25°C

Odor: Mild Specific Gravity: 1.41 Flammability: 921°F

pH: Not Established Solubility (H2O): Slight Flammability Limits: LEL - 1.1%

Melting Point: Not Established Evaporation Rate: 0.6 (BUAC=1) UEL – 10.6%

Freezing Point: Not Established Vapor Density: >1.00 (AIR=1)

Boiling Point: 180°F VOC: 190 g/l

SECTION 10 – STABILITY AND REACTIVITY

Stability: Stable.

Hazardous polymerization: Will not occur.

Conditions to avoid: Heat, sparks, open flames and strong oxidizing.

Incompatible materials: Liquid Oxygen Systems, Liquid Sodium, Gaseous Fluorine, Strong Oxidizers.

Hazardous decomposition products: None.

Page 2 of 3

`


SECTION 11 – TOXICOLOGICAL INFORMATION

Toxicity

Hazardous Chemicals LD50 LC50

2-BUTOXYETHANOL N/A N/A

Likely Routes of Exposure: Skin Contact and Eye Contact.

Symptoms and Effect - Inhalation: Possible dizziness if used in confined area. Skin Contact: May cause mild irritation to sensitive skin.

Eye Contact: May cause eye irritation. Ingestion: None.

Long-Term Effect: None known.

Pre-Existing Conditions: None known.

SECTION 12 – ECOLOGICAL INFORMATION

Ecotoxicity: None known.

Persistance & Degradability: None known.

Bioaccumulative Potential: None known.

Mobility in soil: None known.

SECTION 13 – DISPOSAL CONSIDERATION

Dispose of product or container in accordance with federal, state or local regulations.

SECTION 14 – TRANSPORTATION INFORMATION

D.O.T. (U.S.): Not Regulated.

SECTION 15 – REGULATORY INFORMATION

Precautionary Label Information: Irritant.

Risk Phrases: R36/38-Irritant to eyes and skin.

Safety Phrases: S2-Keep out of reach of children. S3-Keep in a cool place. S7-Keep container tightly closed when not in use. S24/25-Avoid

contact with skin and eyes. S29-Do not empty into drains, storm drains or watercourses. S35-Dispose of material and container in a safe way.

S37/39-Wear suitable gloves and eye protection. S51-Use in well ventilated area.

SECTION 16 – OTHER INFORMATION Information on this form is furnished solely for the purpose of compliance with the Occupational Safety and Health Act and shall not be used for any other purpose. Black

Swan Mfg. Co. urges the customers receiving this Material Safety Data Sheet to study it carefully to become aware of the hazards, if any, of the product involved. In the

interest of safety, you should notify your employees, agents and contractors of the information on the sheets. DATE: 01/01/2017

Page 3 of 3

BLACK SWAN MFG. CO.

GHS

SECTION 1

Manufacturer:

Black Swan Mfg. Co.

4540 W. Thomas St.


Tel.: 800-252-5796

Fax: 773-227-3705



Product Name: Pipe Joint Compound

SECTION 2

Labels None

NFPA

HEALTH HAZARD FIRE HAZARD4 – Deadly

3 - Extreme Danger

2 – Hazardous


0 - Normal Material


Acid ACID 3


Use NO WATER W

Radioactive

Signal Word None

HMIS


Chemicals

LIMESTONE CALCIUM CARBONATE 1317

DISTILLATES, HYDROTREATED LIGHT NAPHTHENIC 64742


SECTION

Inhalation: None.

Skin: Wash skin thoroughly with soap and water.


Ingestion: DO NOT INDUCE VOMITING. Contact physician immediately.

SECTION

Fire Hazard: None.

Combustion Products: None.

Extinguishing Media: Carbon Dioxide Gas, Dry Chemical



Special Fire Fighting Procedures: As appropriate for combustibles in area.

00

HEALTH

FLAMMABILITY

REACTIVITY

0

0

0

`

BLACK SWAN MFG. CO.





INFOTRAC

(800) 535-5053 OR

24 hours per day -

Recommended Use: To seal threaded pipes on all types of metal

connections.


NFPA


4 – Below 73°F

3 – Below 100°F


exceeding 200°F


REACTIVITY OX 4 – May detonate


Alkali ALK may detonate orrosive COR 2 – Violent chemical

change


0 – Stable

GHS Classification

Health Acute Toxicity:Not Established

Skin Irritation: Not Established Acute Aquatic Toxicity:

Eye Irritation: Not Established Chronic Aquatic Toxicity: Not Established


Physical None

Hazardous Statements

None

P102 : Keep out of reach of children


CAS# EINECS# REACH

Pre-registration Number LIMESTONE CALCIUM CARBONATE 1317-65-3 N/A N/A 60

DISTILLATES, HYDROTREATED LIGHT NAPHTHENIC 64742-53-6 N/A N/A 10

not classified as hazardous according to OSHA 1910.1200.

SECTION 4 – FIRST-AID MEASURES


DO NOT INDUCE VOMITING. Contact physician immediately.


Carbon Dioxide Gas, Dry Chemical.

As appropriate for combustibles in area.

Page 1 of 3

0 0


INFOTRAC

(352) 323-3500

7 days a week

To seal threaded pipes on all types of metal

GHS Classification

Environmental

cute Aquatic Toxicity: Not Established

ye Irritation: Not Established Chronic Aquatic Toxicity: Not Established




REACH Approx %

registration Number N/A N/A 60-80%

6 N/A N/A 10-20%

`



Personal Precautions: None.



Environmental Precautions: None.

Methods for Cleaning Up: Clean up by scrapping and put in a container for disposal.


Handling

Wash thoroughly after handling.

Storage

Store in a dry/cool place.


Exposure Limits

This product is not classified as hazardous according to OSHA 1910.1200.



Personal Protective Equipment – Respiratory: None. Skin: Rubber Gloves. Eyes: Safety Glasses.

SECTION 9 – PHYSICAL & CHEMICAL PROPERTIES Appearance: Gray Paste Flash Point: Not Established Vapor Pressure: Not Established

Odor: Odorless Specific Gravity: 1.87 Flammability: Not Established

pH: Not Established Solubility (H2O): Insoluble Flammability Limits: LEL – Not Established

Melting Point: Not Established Evaporation Rate: Not Established UEL – Not Established

Freezing Point: Not Established Vapor Density: Not Established

Boiling Point: Not Established VOC: 108 g/l


Stability: Stable.


Conditions to avoid: Direct contact with open flame.

Incompatible materials: None known.

Hazardous decomposition products: Carbon Dioxide and Carbon Monoxide may be released on burning.


Toxicity This product is not classified as hazardous according to OSHA 1910.1200.

Likely Routes of Exposure: Skin Contact.

Symptoms and Effect - Inhalation: None. Skin Contact: None. Eye Contact: None. Ingestion: None.












Page 2 of 3

`



Precautionary Label Information: None.

Risk Phrases: None.

Safety Phrases: S2-Keep out of reach of children.




Page 3 of 3

BLACK SWAN MFG. CO.

GHS

SECTION 1

Manufacturer:

Black Swan Mfg. Co.

4540 W. Thomas St.


Tel.: 800-252-5796

Fax: 773-227-3705



Product Name: Pipe-Lube

SECTION 2

Labels None

NFPA


3 - Extreme Danger

2 – Hazardous


0 - Normal Material


Acid ACID 3


Use NO WATER W

Radioactive

Signal Word None

HMIS


Chemicals

POTASSIUM HYDROXIDE 1310

FATTY ACIDS -

C16-18 AND C18-UNSATD 67701

DISTILLATES HYDROTREATED

LIGHT NAPHTHENIC 64742

1,2-PROPANEDIOL 57


SECTION

Inhalation: Not expected to be a normal route of exposure.


advice/attention.

Eyes: Do not rub eyes. Flush eyes with large amounts of water for at least 15 minutes, holding eyelids open. Consult a physician if

persists.

Ingestion: If swallowed, immediately call a poison center or

anything by mouth to an unconscious person.

11

HEALTH

FLAMMABILITY

REACTIVITY

1

0

0

`

BLACK SWAN MFG. CO.





INFOTRAC

(800) 535-5053 OR

24 hours per day -

Recommended Use: For lubrication of slip

joints with rubber or synthetic rubber type gaskets.


NFPA


4 – Below 73°F

3 – Below 100°F


exceeding 200°F





change


0 – Stable

GHS Classification

Health Acute Toxicity: Not Established




Physical None


None

P


P262: Do not get in eyes, on skin or on

clothing

P

P280: Wear protective gloves/protective

clothing/eye protection/face


CAS# EINECS# REACH

Pre-registration Number1310-58-3 215-181-3 N/A

UNSATD 67701-08-0 N/A N/A

EATED

LIGHT NAPHTHENIC 64742-53-6 265-156-6 N/A

PROPANEDIOL 57-55-6 N/A N/A



: Not expected to be a normal route of exposure.

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water. If skin irritation occurs get medical

Do not rub eyes. Flush eyes with large amounts of water for at least 15 minutes, holding eyelids open. Consult a physician if

poison center or physician. Rinse mouth. DO NOT INDUCE VOMITING

Page 1 of 3

1 0


INFOTRAC

(352) 323-3500

7 days a week

For lubrication of slip-on or “O” ring type

joints with rubber or synthetic rubber type gaskets.

GHS Classification

Environmental



Precautionary Statements P102: Keep out of reach of children


P262: Do not get in eyes, on skin or on

clothing

P264: Wash thoroughly after handling

P280: Wear protective gloves/protective

clothing/eye protection/face protection


REACH Approx %

registration Number N/A 5-15%

N/A 30-60%

6 N/A 15-25%

N/A 3-7%

If skin irritation occurs get medical

Do not rub eyes. Flush eyes with large amounts of water for at least 15 minutes, holding eyelids open. Consult a physician if irritation

DO NOT INDUCE VOMITING. Never give

`



Fire Hazard: None.


Extinguishing Media: Carbon Dioxide, Dry Chemical, Water, Foam.


Protective Equipment: Wear a self-contained breathing apparatus & protective clothing.

Special Fire Fighting Procedures: Evacuate enclosed areas, stay upwind. Closed or confined quarters require self-contained breathing

apparatus, positive pressure hose masks or airline masks.


Personal Precautions: Wear appropriate shoes to avoid slips.



Environmental Precautions: This is a biodegradable soap. Avoid runoff into storm sewers, ditches, and waterways.

Methods for Cleaning Up: Scrape up or use absorbing material to pick up. Place in a clean, dry, leak proof container.


Handling Keep out of reach of children. Avoid contact with eyes, skin and

clothing. Wash thoroughly after handling. Do not eat, drink or

smoke in the work area.

Storage Keep container tightly closed when not in use. Empty containers

may contain residue; treat as if full and observe all product

precautions. Do not reuse empty containers. Incompatible

Materials: Strong oxidizing agents.


Exposure Limits This product is not classified as hazardous according to OSHA 1910.1200.


Ventilation: None needed.

Personal Protective Equipment – Respiratory: None. Skin: Rubber gloves. Eyes: Glasses recommended.

SECTION 9 – PHYSICAL & CHEMICAL PROPERTIES Appearance: Amber Flash Point: >250°F (121°C) Vapor Pressure: Negligible

Odor: Odorless Specific Gravity: >1.0 Flammability: Not Established

pH: 11 Solubility (H2O): Insoluble Flammability Limits: LEL – Not Established

Melting Point: <32°F Evaporation Rate: Not Established UEL – Not Established


Boiling Point: >220°F VOC: 50 g/l


Stability: Stable.


Conditions to avoid: Reactive alloys like aluminum, brass, bronze.

Incompatible materials: Strong oxidizing agents.

Hazardous decomposition products: Thermal oxidative decomposition can produce oxides of Carbon and Nitrogen.


Toxicity


Likely Routes of Exposure: Skin Contact and Eye Contact.

Symptoms and Effect – Inhalation: Not a likely route of entry. Skin Contact: Slight skin irritant if allowed to remain in contact. Eye

Contact: Slight eye irritant. Ingestion: Not a likely route of entry.



Page 2 of 3

`






Mobility in soil: In normal use, emission of Volatile Organic Compounds (VOC’s) to the air takes place, typically at a rate of 50 g/l.







Risk Phrases: None.





.

Page 3 of 3

BLACK SWAN MFG. CO.

GHS

SECTION 1

Manufacturer:

Black Swan Mfg. Co.

4540 W. Thomas St.


Tel.: 800-252-5796

Fax: 773-227-3705



Product Name: Pipe Stick

SECTION 2

Labels None

NFPA

HEALTH HAZARD FIRE 4 – Deadly

3 - Extreme Danger

2 – Hazardous


0 - Normal Material


Acid ACID 3

Alkali ALK Corrosive COR 2

Use NO WATER W

Radioactive

Signal Word None

HMIS


Chemicals

LINSEED OIL, POLYMERIZED 67746

NAPTHETIC ACIDS, COBALT SALTS 263

ALIPHATIC HYDROCARBONS (STODDARD TYPE) 232

LIMESTONE CALCIUM CARBONATE

HEAVY HYDROTREATED NAPHTHENIC

DISTILLATES (PETROLEUM) 64742


SECTION

Inhalation: None.

Skin: Wash skin thoroughly with soap and water.


Ingestion: DO NOT INDUCE VOMITING. Contact physician immediately.

SECTION

Fire Hazard: Water soaked with this product may spontaneously catch fire if improperly discarded. Rags and waste paper containing this

product may burn spontaneously. Store wiping rags containing this product in metal containers with tight lids.


Extinguishing Media: Carbon Dioxide Gas, Dry Chemical


Protective Equipment: Wear full firefighting turn

Special Fire Fighting Procedures: As appropriate for combu

11

HEALTH

FLAMMABILITY

REACTIVITY

1

1

0

`

BLACK SWAN MFG. CO.





INFOTRAC

(800) 535-5053 OR

24 hours per day -

Recommended Use: Pipe Joint Compound in stick form for sealing

threaded pipe on metal or plastic connections.


NFPA


4 – Below 73°F

3 – Below 100°F


exceeding 200°F




may detonate Corrosive COR 2 – Violent chemical

change


0 – Stable

GHS Classification

Health Acute Toxicity:Not Established




Physical None


None



CAS# EINECS# REACH

Pre-registration Number SEED OIL, POLYMERIZED 67746-08-1 N/A N/A

NAPTHETIC ACIDS, COBALT SALTS 263-064-0 N/A N/A

ALIPHATIC HYDROCARBONS (STODDARD TYPE) 232-489-3 N/A N/A

LIMESTONE CALCIUM CARBONATE 1317-65-3 N/A N/A

DISTILLATES (PETROLEUM) 64742-53-6 N/A N/A




DO NOT INDUCE VOMITING. Contact physician immediately.


: Water soaked with this product may spontaneously catch fire if improperly discarded. Rags and waste paper containing this


: Carbon Dioxide Gas, Dry Chemical, Foam.

: Wear full firefighting turn-out gear & respiratory protection.

As appropriate for combustibles in area.

Page 1 of 3

1 0


INFOTRAC

(352) 323-3500

7 days a week

Pipe Joint Compound in stick form for sealing

threaded pipe on metal or plastic connections.

GHS Classification

Environmental


ye Irritation: Not Established Chronic Aquatic Toxicity: Not Established




REACH Approx %

registration Number 1 N/A N/A 10-15%

N/A 0-1%

3 N/A N/A 15-25%

3 N/A N/A 40-70%

N/A 5-10%

: Water soaked with this product may spontaneously catch fire if improperly discarded. Rags and waste paper containing this


`



Personal Precautions: Use recommended personal protective equipment.



Environmental Precautions: None.

Methods for Cleaning Up: Sweep or scrape up. If large quantities are exposed to excessive heat, this product may melt. Allow melted

material to cool and then scrape up.


Handling Wash thoroughly after handling.

Storage Store in a dry/cool place. Store away from incompatible materials.


Exposure Limits




Personal Protective Equipment – Respiratory: NIOSH approved respirator. Skin: Oil Resistant Gloves. Eyes: Safety Glasses/Chemical Goggles.

SECTION 9 – PHYSICAL & CHEMICAL PROPERTIES Appearance: Cylindrical Crayon/Solid Flash Point: 400°F Vapor Pressure: Not Established

Odor: Linseed Oil Specific Gravity: >1 Flammability: Not Established

pH: Not Established Solubility (H2O): Water:Insoluble; Fat:Soluble Flammability Limits: LEL – Not Established

Melting Point: 150°F Evaporation Rate: Not Established UEL – Not Established


Boiling Point: Not Established VOC: 0 g/l


Stability: Stable.


Conditions to avoid: High surface area exposure can result in release of heat while product is polymerizing (drying).

Incompatible materials: Oxidizers.

Hazardous decomposition products: Alderhudes (including acrolein) may be produced from atmospheric oxidation (drying).


Toxicity This product is not classified as hazardous according to OSHA 1910.1200.

Likely Routes of Exposure: Inhalation, Eye Contact and Ingestion.

Symptoms and Effect - Inhalation: Irritating fumes may be produced during the products drying process if exposed to large surface area.

Skin Contact: None. Eye Contact: May cause mild eye irritation including stinging, watering and redness. Ingestion: Possible nausea or

diarrhea if large amounts are ingested.










Page 2 of 3

`






Risk Phrases: None.





Page 3 of 3

SAFETY DATA SHEET

1. IdentificationOatey Purple Primer CleanerProduct identifier

Other means of identification1401EProduct codePart Numbers: 30780, 30783, 30796, 30768, 30806, 30769SynonymsJoining PVC PipesRecommended useNone known.Recommended restrictions

Manufacturer/Importer/Supplier/Distributor informationCompany Name Oatey Co.Address 4700 West 160th St.

Cleveland, OH 44135

Telephone 216-267-7100E-mail [email protected] Emergency Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887)Emergency First Aid 1-877-740-5015Contact person MSDS Coordinator

2. Hazard(s) identificationCategory 2Flammable liquidsPhysical hazards

Category 2ASerious eye damage/eye irritationHealth hazardsCategory 3 respiratory tract irritationSpecific target organ toxicity, single exposureCategory 3 narcotic effectsSpecific target organ toxicity, single exposureCategory 1Aspiration hazard

Not classified.OSHA defined hazards

Label elements

Signal word DangerHazard statement Highly flammable liquid and vapor. Harmful if swallowed. May be fatal if swallowed and enters

airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Maycause drowsiness or dizziness.

Precautionary statementPrevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly

closed. Ground/bond container and receiving equipment. Use explosion-proofelectrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionarymeasures against static discharge. Avoid breathing mist or vapor. Wash thoroughly afterhandling. Do not eat, drink or smoke when using this product. Use only outdoors or in awell-ventilated area. Wear eye protection/face protection. Wear protective gloves/protectiveclothing/eye protection/face protection.

Response If swallowed: Immediately call a poison center/doctor. If on skin (or hair): Take off immediately allcontaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air andkeep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor ifyou feel unwell. Rinse mouth. Do NOT induce vomiting. If skin irritation occurs: Get medicaladvice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminatedclothing and wash before reuse. In case of fire: Use appropriate media to extinguish.

Storage Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up.

Oatey Purple Primer Cleaner SDS US927429 Version #: 01 Revision date: - Issue date: 27-May-2015 1 / 9

Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.Hazard(s) not otherwiseclassified (HNOC)

Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.

Supplemental informationNot applicable.

3. Composition/information on ingredientsMixtures

67-64-1 70-100Acetone

CAS number %Chemical name

108-94-1 1-5Cyclohexanone

*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measuresRemove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISONCENTER or doctor/physician if you feel unwell.

Inhalation

Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skinirritation occurs: Get medical advice/attention.

Skin contact

Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Eye contact

Call a physician or poison control center immediately. Do not induce vomiting. Aspiration maycause pulmonary edema and pneumonitis. If vomiting occurs, keep head low so that stomachcontent doesn't get into the lungs.

Ingestion

Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms mayinclude stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation.Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Skinirritation. May cause redness and pain.

Most importantsymptoms/effects, acute anddelayed

Provide general supportive measures and treat symptomatically. Thermal burns: Flush with waterimmediately. While flushing, remove clothes which do not adhere to affected area. Call anambulance. Continue flushing during transport to hospital. In case of shortness of breath, giveoxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed.

Indication of immediatemedical attention and specialtreatment needed

Take off all contaminated clothing immediately. Ensure that medical personnel are aware of thematerial(s) involved, and take precautions to protect themselves. Wash contaminated clothingbefore reuse.

General information

5. Fire-fighting measuresAlcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing mediaDo not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing

mediaVapors may form explosive mixtures with air. Vapors may travel considerable distance to a sourceof ignition and flash back. During fire, gases hazardous to health may be formed.

Specific hazards arising fromthe chemical

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipmentand precautions for firefighters

In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can doso without risk.

Fire fightingequipment/instructions

Use standard firefighting procedures and consider the hazards of other involved materials.Specific methodsHighly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosiveorganic peroxide when exposed to air or light or with age.

General fire hazards

6. Accidental release measuresKeep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out oflow areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist orvapor. Do not touch damaged containers or spilled material unless wearing appropriate protectiveclothing. Ventilate closed spaces before entering them. Local authorities should be advised ifsignificant spillages cannot be contained. For personal protection, see section 8 of the SDS.

Personal precautions,protective equipment andemergency procedures


Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Takeprecautionary measures against static discharge. Use only non-sparking tools. Keep combustibles(wood, paper, oil, etc.) away from spilled material. This product is miscible in water.

Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors ordivert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet toprevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up theproduct and place into a container for later disposal. Prevent entry into waterways, sewer,basements or confined areas. Following product recovery, flush area with water.

Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containersfor later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.

Methods and materials forcontainment and cleaning up

Avoid discharge into drains, water courses or onto the ground.Environmental precautions

7. Handling and storageVapors may form explosive mixtures with air. Do not handle, store or open near an open flame,sources of heat or sources of ignition. Protect material from direct sunlight. Explosion-proofgeneral and local exhaust ventilation. Take precautionary measures against static discharges. Allequipment used when handling the product must be grounded. Use non-sparking tools andexplosion-proof equipment. Avoid breathing mist or vapor. Avoid prolonged exposure. Do not tasteor swallow. When using, do not eat, drink or smoke. Wear appropriate personal protectiveequipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices.

Precautions for safe handling

Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic chargebuild-up by using common bonding and grounding techniques. Store in a cool, dry place out ofdirect sunlight. Store in original tightly closed container. Store in a well-ventilated place. Storeaway from incompatible materials (see Section 10 of the SDS).

Conditions for safe storage,including any incompatibilities

8. Exposure controls/personal protectionOccupational exposure limits

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

ValueTypeComponentsPEL 2400 mg/m3Acetone (CAS 67-64-1)

1000 ppmPEL 200 mg/m3Cyclohexanone (CAS

108-94-1)50 ppm

US. ACGIH Threshold Limit Values

ValueTypeComponentsSTEL 750 ppmAcetone (CAS 67-64-1)TWA 500 ppmSTEL 50 ppmCyclohexanone (CAS

108-94-1)TWA 20 ppm

US. NIOSH: Pocket Guide to Chemical Hazards

ValueTypeComponentsTWA 590 mg/m3Acetone (CAS 67-64-1)

250 ppmTWA 100 mg/m3Cyclohexanone (CAS

108-94-1)25 ppm

Biological limit valuesACGIH Biological Exposure Indices

Value Sampling TimeDeterminant SpecimenComponents50 mg/l Acetone Urine *Acetone (CAS 67-64-1)


ACGIH Biological Exposure Indices

Value Sampling TimeDeterminant SpecimenComponents80 mg/l 1,2-Cyclohexan

ediol, withhydrolysis

Urine *Cyclohexanone (CAS108-94-1)

8 mg/l Cyclohexanol,with hydrolysis

Urine *

* - For sampling details, please see the source document.Exposure guidelines

US - California OELs: Skin designationCyclohexanone (CAS 108-94-1) Can be absorbed through the skin.

US - Minnesota Haz Subs: Skin designation appliesCyclohexanone (CAS 108-94-1) Skin designation applies.

US - Tennessee OELs: Skin designationCyclohexanone (CAS 108-94-1) Can be absorbed through the skin.

US ACGIH Threshold Limit Values: Skin designationCyclohexanone (CAS 108-94-1) Can be absorbed through the skin.

US. NIOSH: Pocket Guide to Chemical HazardsCyclohexanone (CAS 108-94-1) Can be absorbed through the skin.

Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 airchanges per hour) should be used. Ventilation rates should be matched to conditions. Ifapplicable, use process enclosures, local exhaust ventilation, or other engineering controls tomaintain airborne levels below recommended exposure limits. If exposure limits have not beenestablished, maintain airborne levels to an acceptable level. Eye wash facilities and emergencyshower must be available when handling this product.

Appropriate engineeringcontrols

Individual protection measures, such as personal protective equipmentChemical respirator with organic vapor cartridge and full facepiece.Eye/face protection

Skin protectionWear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glovesupplier.

Hand protection

Wear appropriate chemical resistant clothing.OtherChemical respirator with organic vapor cartridge and full facepiece.Respiratory protectionWear appropriate thermal protective clothing, when necessary.Thermal hazardsWhen using, do not eat, drink or smoke. Always observe good personal hygiene measures, suchas washing after handling the material and before eating, drinking, and/or smoking. Routinelywash work clothing and protective equipment to remove contaminants.

General hygieneconsiderations

9. Physical and chemical properties AppearanceLiquid.Physical stateTranslucent liquid.FormPurpleColorSolvent.Odor

Odor threshold Not available.

pH Not available.

Melting point/freezing point Not available.

Initial boiling point and boilingrange

133 °F (56.11 °C)

Flash point -4.0 °F (-20.0 °C)

Evaporation rate Not available.Not applicable.Flammability (solid, gas)

Upper/lower flammability or explosive limitsFlammability limit - lower(%)

Not available.


Flammability limit - upper(%)

Not available.

Explosive limit - lower (%) Not available.

Explosive limit - upper (%) Not available.

Vapor pressure 145 mm Hg @ 20 C

Vapor density 2.5

Relative density 0.79 +/- 0.02

Solubility(ies)Solubility (water) Miscible

Partition coefficient(n-octanol/water)

Not available.

Auto-ignition temperature Not available.

Decomposition temperature Not available.

Viscosity < 10 cP

Other informationBulk density 7 lb/gal

Not explosive.Explosive propertiesNot oxidizing.Oxidizing properties

VOC (Weight %) 180 g/l SQACMD Method 24

10. Stability and reactivityThe product is stable and non-reactive under normal conditions of use, storage and transport.ReactivityMaterial is stable under normal conditions.Chemical stabilityNo dangerous reaction known under conditions of normal use.Possibility of hazardous

reactionsAvoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding theflash point. Contact with incompatible materials.

Conditions to avoid

Acids. Strong oxidizing agents. Ammonia. Amines. Isocyanates. Caustics.Incompatible materialsNo hazardous decomposition products are known.Hazardous decomposition

products

11. Toxicological informationInformation on likely routes of exposure

Inhalation May be fatal if swallowed and enters airways. Headache. Nausea, vomiting. May cause irritationto the respiratory system. Vapors have a narcotic effect and may cause headache, fatigue,dizziness and nausea. Prolonged inhalation may be harmful.

Skin contact No adverse effects due to skin contact are expected.

Eye contact Causes serious eye irritation.

Ingestion May be fatal if swallowed and enters airways. Harmful if swallowed. Droplets of the productaspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia.

Symptoms related to thephysical, chemical andtoxicological characteristics

Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms mayinclude stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation.Skin irritation. Symptoms of overexposure may be headache, dizziness, tiredness, nausea andvomiting. May cause redness and pain.

Information on toxicological effectsAcute toxicity May be fatal if swallowed and enters airways. Narcotic effects. May cause respiratory irritation.

Test ResultsComponents SpeciesAcetone (CAS 67-64-1)

LD50 RabbitDermalAcute

20 ml/kg

LC50 RatInhalation

50 mg/l, 8 Hours


Test ResultsComponents Species

LD50 RatOral

5800 mg/kg

Cyclohexanone (CAS 108-94-1)


948 mg/kg

LC50 RatInhalation

8000 ppm, 4 hours

LD50 RatOral

1540 mg/kg

* Estimates for product may be based on additional component data not shown.Causes skin irritation.Skin corrosion/irritationCauses serious eye irritation.Serious eye damage/eye

irritationRespiratory or skin sensitization

Respiratory sensitization Not a respiratory sensitizer.This product is not expected to cause skin sensitization.Skin sensitizationNo data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.

Germ cell mutagenicity

Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.

IARC Monographs. Overall Evaluation of CarcinogenicityCyclohexanone (CAS 108-94-1) 3 Not classifiable as to carcinogenicity to humans.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.

This product is not expected to cause reproductive or developmental effects.Reproductive toxicitySpecific target organ toxicity -single exposure

Narcotic effects. May cause drowsiness and dizziness. Respiratory tract irritation.

Specific target organ toxicity -repeated exposure

Not classified.

Aspiration hazard May be fatal if swallowed and enters airways.

Chronic effects Prolonged inhalation may be harmful.

12. Ecological informationThe product is not classified as environmentally hazardous. However, this does not exclude thepossibility that large or frequent spills can have a harmful or damaging effect on the environment.

Ecotoxicity

Components Test ResultsSpeciesAcetone (CAS 67-64-1)

AquaticLC50Fish > 100 mg/l, 96 hoursFathead minnow (Pimephales promelas)

* Estimates for product may be based on additional component data not shown.

Cyclohexanone (CAS 108-94-1)Aquatic

LC50Fish 481 - 578 mg/l, 96 hoursFathead minnow (Pimephales promelas)

No data is available on the degradability of this product.Persistence and degradabilityNo data available.Bioaccumulative potential

Partition coefficient n-octanol / water (log Kow)Acetone (CAS 67-64-1) -0.24Cyclohexanone (CAS 108-94-1) 0.81

No data available.Mobility in soilOther adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation

potential, endocrine disruption, global warming potential) are expected from this component.


13. Disposal considerationsCollect and reclaim or dispose in sealed containers at licensed waste disposal site. This materialand its container must be disposed of as hazardous waste. Do not allow this material to drain intosewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or usedcontainer. Dispose of contents/container in accordance with local/regional/national/internationalregulations.

Disposal instructions

Dispose in accordance with all applicable regulations.Local disposal regulationsThe waste code should be assigned in discussion between the user, the producer and the wastedisposal company.

Hazardous waste code

Dispose of in accordance with local regulations. Empty containers or liners may retain someproduct residues. This material and its container must be disposed of in a safe manner (see:Disposal instructions).

Waste from residues / unusedproducts

Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied.

Contaminated packaging

14. Transport informationDOT

UN1993UN numberFlammable liquids, n.o.s. (Acetone RQ = 5128 LBS)UN proper shipping name

3ClassTransport hazard class(es)

-Subsidiary risk3Label(s)IIPacking groupRead safety instructions, SDS and emergency procedures before handling.Special precautions for userIB2, T7, TP1, TP8, TP28Special provisions150Packaging exceptions202Packaging non bulk242Packaging bulk

IATAUN1993UN numberFlammable liquid, n.o.s. (Acetone)UN proper shipping name


-Subsidiary riskIIPacking groupNo.Environmental hazards3HERG CodeRead safety instructions, SDS and emergency procedures before handling.Special precautions for user

IMDGUN1993UN numberFLAMMABLE LIQUID, N.O.S. (Acetone)UN proper shipping name


-Subsidiary riskIIPacking group

No.Marine pollutantEnvironmental hazards

F-E, S-EEmSRead safety instructions, SDS and emergency procedures before handling.Special precautions for userNot established.Transport in bulk according to

Annex II of MARPOL 73/78 andthe IBC Code

15. Regulatory informationThis product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.

US federal regulations


TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Not listed.

CERCLA Hazardous Substance List (40 CFR 302.4)Acetone (CAS 67-64-1) LISTEDCyclohexanone (CAS 108-94-1) LISTED

Superfund Amendments and Reauthorization Act of 1986 (SARA)Immediate Hazard - YesDelayed Hazard - NoFire Hazard - YesPressure Hazard - NoReactivity Hazard - No

Hazard categories

SARA 302 Extremely hazardous substanceNot listed.

NoSARA 311/312 HazardouschemicalSARA 313 (TRI reporting)

Not regulated.

Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List

Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)

Not regulated.Not regulated.Safe Drinking Water Act

(SDWA)Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) andChemical Code Number

Acetone (CAS 67-64-1) 6532Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))

Acetone (CAS 67-64-1) 35 %WVDEA Exempt Chemical Mixtures Code Number

Acetone (CAS 67-64-1) 6532US state regulations

US. Massachusetts RTK - Substance ListAcetone (CAS 67-64-1)Cyclohexanone (CAS 108-94-1)

US. New Jersey Worker and Community Right-to-Know ActAcetone (CAS 67-64-1)Cyclohexanone (CAS 108-94-1)

US. Pennsylvania Worker and Community Right-to-Know LawAcetone (CAS 67-64-1)Cyclohexanone (CAS 108-94-1)

US. Rhode Island RTKAcetone (CAS 67-64-1)Cyclohexanone (CAS 108-94-1)

US. California Proposition 65California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to containany chemicals currently listed as carcinogens or reproductive toxins.

International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*

Australian Inventory of Chemical Substances (AICS) YesAustraliaDomestic Substances List (DSL) YesCanadaNon-Domestic Substances List (NDSL) NoCanadaInventory of Existing Chemical Substances in China (IECSC) YesChina


Country(s) or region Inventory name On inventory (yes/no)*European Inventory of Existing Commercial ChemicalSubstances (EINECS)

YesEurope

European List of Notified Chemical Substances (ELINCS) NoEuropeInventory of Existing and New Chemical Substances (ENCS) YesJapanExisting Chemicals List (ECL) YesKoreaNew Zealand Inventory YesNew ZealandPhilippine Inventory of Chemicals and Chemical Substances(PICCS)

YesPhilippines

*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).

Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico

16. Other information, including date of preparation or last revision27-May-2015Issue date-Revision date

Version # 01Health: 2Flammability: 3Physical hazard: 0

HMIS® ratings

The information in the sheet was written based on the best knowledge and experience currentlyavailable. Oatey Co. cannot anticipate all conditions under which this information and its product,or the products of other manufacturers in combination with its product, may be used. It is theuser’s responsibility to ensure safe conditions for handling, storage and disposal of the product,and to assume liability for loss, injury, damage or expense due to improper use.

Disclaimer


BLACK SWAN MFG. CO.

GHS

SECTION 1

Manufacturer:

Black Swan Mfg. Co.

4540 W. Thomas St.


Tel.: 800-252-5796

Fax: 773-227-3705



Product Name: PVC Cement (Clear) – Regular Bodied

SECTION 2

Labels

Health Hazard Flammable

NFPA


3 - Extreme Danger

2 – Hazardous


0 - Normal Material


Acid ACID 3


Use NO WATER W

Radioactive

Signal Word Danger

HMIS

Hazardous Statements H225: Highly flammable liquid and vapor

H304: May be fatal if swallowed and enters airways

H312: Harmful in contact with skin

H319: Causes serious eye irritation

H332: Harmful if inhaled

H335: May cause respiratory irritation

H336: May cause drowsiness or dizziness


Hazardous Chemicals CAS#

TETRAHYDROFURAN 109-99-9

METHYL ETHYL KETONE 78-93-3

CYCLOHEXANONE 108-94-1 203

ACETONE 67-64-1 20All of the constituents of this adhesive product are listed on the TSCA inventory of chemical substances

SECTION

Inhalation: Move into fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen and call physician



Ingestion: Give 1 or 2 glasses of water. DO NOT INDUCE VOMITING. Contact physician immediately.

32

HEALTH

FLAMMABILITY

REACTIVITY

2

3

0

`

BLACK SWAN MFG. CO.





INFOTRAC

(800) 535-5053 OR

24 hours per day -

Regular Bodied

Recommended Use: For connecting PVC pipe and fittings.


NFPA


4 – Below 73°F

3 – Below 100°F


exceeding 200°F





change


0 – Stable

GHS Classification

Health Acute Toxicity: Cat. 4

Skin Irritation: Cat. 3 Acute Aquatic Toxicity: Not Established

Eye Irritation: Cat. 2B Chronic Aquatic Toxicity: Not Estab


Physical Flammability: Cat. 2

Precautionary StatementsP102: Keep out of reach of children

P210: Keep away from heat/sparks/open flames/hot surfaces

P233/P235: Keep container tightly closed

P243: Take precautionary measures against static discharge

P261: Avoid breathing dust/fume/gas/mist/vapo

P262: Do not get in eyes, on skin, or on clothing

P264: Wash thoroughly after handling

P270: Do not eat, drink or smoke when using this product

P271: Use only outdoors or in a well-ventilated area

P280/P284: Wear protective gloves/protective clothing/eye protection/face

protection. Wear a NIOSH approved respirator for organic solvents.


EINECS# REACH

Pre-registration Number

203-726-8 05-2116297729-22-0000 20

201-159-0 05-2116297728-24-0000 10

1 203-631-1 05-2116297718-25-0000 10

1 200-662-2 05-2116297713-35-0000 20All of the constituents of this adhesive product are listed on the TSCA inventory of chemical substances maintained by the US EPA, or are


Move into fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen and call physician

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water.

water for 15 minutes. If irritation persists, get medical attention.

Give 1 or 2 glasses of water. DO NOT INDUCE VOMITING. Contact physician immediately.

Page 1 of 3

3 0


INFOTRAC

(352) 323-3500

7 days a week

connecting PVC pipe and fittings.

GHS Classification

Environmental

Acute Aquatic Toxicity: Not Established


Flammability: Cat. 2


P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking

: Keep container tightly closed and cooled

P243: Take precautionary measures against static discharge

eathing dust/fume/gas/mist/vapors/spray

P262: Do not get in eyes, on skin, or on clothing

P270: Do not eat, drink or smoke when using this product

ventilated area

P284: Wear protective gloves/protective clothing/eye protection/face

protection. Wear a NIOSH approved respirator for organic solvents.


REACH Approx %

0000 20-30%

0000 10-20%

0000 10-20%

0000 20-30% maintained by the US EPA, or are exempt from that listing.

Move into fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen and call physician.

`



Fire Hazard: Highly flammable liquid and vapor. Keep away from heat and all sources of ignition including sparks, flames, lighted

cigarettes and pilot lights. Containers may rupture or explode in the heat of a fire. Vapors are heavier than air and may travel to a remote

ignition source and flash back.

Combustion Products: Combustion will produce toxic and irritating vapors including carbon monoxide, carbon dioxide and hydrogen

chloride.

Extinguishing Media: Carbon Dioxide Gas, Dry Chemical Powder, Foam.

Unsuitable Extinguishing Media: Water Spray, Water Stream.

Protective Equipment: Self-contained breathing apparatus {(SCBA), MSHA/NIOSH}. Full protective gear.

Special Fire Fighting Procedures: Evacuate enclosed areas, stay upwind. Closed or confined quarters require self-contained breathing

apparatus, positive pressure hose masks or airline masks. Use water spray to cool containers, to flush spills from sources of ignition and to

disperse vapors.


Personal Precautions: Prevent contact with skin or eyes. Personnel cleaning up the spill should wear appropriate personal protective

equipment, including respirators if vapor concentrations are high.

Protective Equipment: Wear suitable respiratory protective equipment.

Emergency Procedures: Remove all sources of ignition and ventilate area. For leaks, stop leak if it can be done safely. Evacuate area and

keep unnecessary and unprotected personnel from entering the spill area.

Environmental Precautions: Avoid runoff into storm sewers, ditches and waterways.

Methods for Cleaning Up: Soak up spill with an inert absorbent such as sand, earth or other noncombusting material. Transfer absorbent

material to a covered, labeled, metal container. Do not use plastic or aluminum containers.


Handling Avoid contact with eyes, skin and clothing. Avoid prolonged

breathing of vapor and mist. Use with adequate ventilation. Wash

thoroughly after handling. Do not eat, drink or smoke in the work

area. Keep products away from heat, sparks, flames and all other

sources of ignition. Keep containers closed when not in use.

Storage Store in a cool, dry, well-ventilated area away from incompatible

materials. Store in shade between 40°F – 110°F. Keep container

closed when not in use. Keep away from heat, sparks, open flame

and other sources of ignition. Incompatible Materials: caustics,

ammonia, inorganic acids, chlorinated compounds, amines, strong

oxidizers and isocyanates.


Exposure Limits

Hazardous Chemicals ACGIH-TLV ACGIH-STEL OSHA-PEL TETRAHYDROFURAN 50 ppm 100 ppm 200 ppm

METHYL ETHYL KETONE 200 ppm 300 ppm 200 ppm

CYCLOHEXANONE 20 ppm 50 ppm 50 ppm

ACETONE 500 ppm 750 ppm 1000 ppm


Ventilation: Local ventilation is adequate. Use only explosion proof ventilation equipment.

Personal Protective Equipment – Respiratory: Atmospheric levels should be maintained below established exposure limits. If airborne

concentrations exceed those limits, use of a NIOSH approved organic vapor cartridge respirator with full face-piece is recommended. The

effectiveness of an air purifying respirator is limited. Use it only for a single short-term exposure. For emergency and other conditions

where short term exposure guidelines may be exceeded, use an approved positive pressure self-contained breathing apparatus.

Personal Protective Equipment – Skin: Prevent contact with skin. Butyl rubber gloves should be used.

Personal Protective Equipment – Eyes: Use glasses with side shield or splash proof goggles.

SECTION 9 – PHYSICAL & CHEMICAL PROPERTIES Appearance: Clear Liquid Flash Point: 6°F Vapor Pressure: 143mm Hg @20°C

Odor: Ketone Specific Gravity: 0.95 + 0.02 @ 20°C Flammability: Category 2

pH: Not Established Solubility (H2O): Solvent-Complete, Resin-Precipitates Flammability Limits: LEL - 1.8%

Melting Point: Not Established Evaporation Rate: 8 (BUAC=1) UEL – 11.8%

Freezing Point: Not Established Vapor Density: >2.00 (AIR=1)

Boiling Point: 151°F (66°C) VOC: 510 g/l

Page 2 of 3

`



Stability: Stable.


Conditions to avoid: Keep away from heat, sparks, open flame and other sources of ignition.

Incompatible materials: Caustics, ammonia, inorganic acids, chlorinated compounds, amines, strong oxidizers and isocyanates.

Hazardous decomposition products: When forced to burn, this product gives out carbon monoxide, carbon dioxide, hydrogen chloride

and smoke.


Toxicity

Hazardous Chemicals LD50 LC50

TETRAHYDROFURAN Oral: 2842 mg/kg (rat) Inhalation: 3 hrs., 21000 mg/m3 (rat)

METHYL ETHYL KETONE Oral: 2737 mg/kg (rat), Dermal: 6480 mg/kg (rabbit) Inhalation: 8 hrs., 23500 mg/m3 (rat)

CYCLOHEXANONE Oral: 1535 mg/kg (rat), Dermal: 948 mg/kg (rabbit) Inhalation: 4 hrs., 8000 ppm (rat)

ACETONE Oral: 5800 mg/kg (rat) Inhalation: 50100 mg/m3 (rat)

Likely Routes of Exposure: Inhalation, Skin Contact and Eye Contact.

Symptoms and Effect - Inhalation: Severe overexposure may result in nausea, dizziness, and headaches. Can cause drowsiness, irritation

of eyes and nasal passages. Skin Contact: Liquid contact may remove natural skin oils resulting in irritation. Dermatitis may occur with

prolonged contact. Eye Contact: Vapors slightly uncomfortable. Overexposure may result in severe eye injury with corneal or conjunctival

inflammation on contact with the liquid. Ingestion: May cause nausea, vomiting, diarrhea and mental sluggishness.


Pre-Existing Conditions: Individuals with pre-existing diseases of the eyes, skin or respiratory system may have increased susceptibility

to the toxicity of excessive exposure.



Persistance & Degradability: Biodegradable.


Mobility in soil: In normal use, emission of Volatile Organic Compounds (VOC’s) to the air takes place, typically at a rate of <510 g/l.




Shipping Information Shipping Name: Adhesives, Containing a Flammable Liquid Exception to the rule: If the package that contains the hazardous

Hazardous Class: 3 material is in a small consumer size (Less than 1L), then the rules

I.D. Number: UN1133 that apply to shipping hazardous materials do not apply. This is

Packing Group: II called an “Exception”.

Label Required: Flammable Liquid This is classified as Consumer Commodity ORM-D.

Marine Pollutant: No


Precautionary Label Information: Highly Flammable, Irritant and Health Hazard.

Risk Phrases: R11-Highly Flammable. R36/37-Irritant to eyes and respiratory system. R66-Repeated exposure may cause skin dryness or

cracking. R67-Vapors may cause drowsiness and dizziness.

Safety Phrases: S2-Keep out of reach of children. S9-Keep container in a well-ventilated place. S16-Keep away from sources of ignition-No

smoking. S25-Avoid contact with eyes. S26-In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S33-

Take precautionary measures against static discharges.




Page 3 of 3

SAFETY DATA SHEET

1. IdentificationPVC All Weather Clear CementProduct identifier

Other means of identification1105EProduct codePart Numbers: 31132, 31133, 31135, 31136SynonymsJoining PVC PipesRecommended useNone known.Recommended restrictions

Manufacturer/Importer/Supplier/Distributor informationCompany Name Oatey Co.Address 4700 West 160th St.

Cleveland, OH 44135

Telephone 216-267-7100E-mail [email protected] Emergency Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887)Emergency First Aid 1-877-740-5015Contact person MSDS Coordinator

2. Hazard(s) identificationCategory 2Flammable liquidsPhysical hazards

Category 4Acute toxicity, oralHealth hazardsCategory 2Skin corrosion/irritationCategory 2ASerious eye damage/eye irritationCategory 3 respiratory tract irritationSpecific target organ toxicity, single exposureCategory 3 narcotic effectsSpecific target organ toxicity, single exposureCategory 1Aspiration hazard

Not classified.OSHA defined hazards

Label elements

Signal word DangerHazard statement Highly flammable liquid and vapor. Harmful if swallowed. May be fatal if swallowed and enters

airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Maycause drowsiness or dizziness.

Precautionary statementPrevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly

closed. Ground/bond container and receiving equipment. Use explosion-proofelectrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionarymeasures against static discharge. Avoid breathing mist or vapor. Wash thoroughly afterhandling. Do not eat, drink or smoke when using this product. Use only outdoors or in awell-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection.

Response If swallowed: Immediately call a poison center/doctor. If on skin (or hair): Take off immediately allcontaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air andkeep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor ifyou feel unwell. Rinse mouth. Do NOT induce vomiting. If skin irritation occurs: Get medicaladvice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminatedclothing and wash before reuse. In case of fire: Use appropriate media to extinguish.

PVC All Weather Clear Cement SDS US927288 Version #: 01 Revision date: - Issue date: 27-May-2015 1 / 10

Storage Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up.

Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.Hazard(s) not otherwiseclassified (HNOC)

Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.May form explosive peroxides. Contains a chemical classified by the US EPA as a suspectedpossible carcinogen.

Supplemental informationNot applicable.

3. Composition/information on ingredientsMixtures

109-99-9 35-55Furan, Tetrahydro-

CAS number %Chemical name

67-64-1 10-25Acetone

9002-86-2 12-20Polyvinyl chloride

108-94-1 10-20Cyclohexanone

112945-52-5 1-5Silica, amorphous, fumed

*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measuresRemove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISONCENTER or doctor/physician if you feel unwell.

Inhalation

Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skinirritation occurs: Get medical advice/attention.

Skin contact

Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Eye contact

Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs,keep head low so that stomach content doesn't get into the lungs. Aspiration may causepulmonary edema and pneumonitis.

Ingestion

Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eyeirritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Maycause respiratory irritation. Vapors have a narcotic effect and may cause headache, fatigue,dizziness and nausea. Skin irritation. May cause redness and pain.

Most importantsymptoms/effects, acute anddelayed

Provide general supportive measures and treat symptomatically. Thermal burns: Flush with waterimmediately. While flushing, remove clothes which do not adhere to affected area. Call anambulance. Continue flushing during transport to hospital. In case of shortness of breath, giveoxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed.

Indication of immediatemedical attention and specialtreatment needed

Take off all contaminated clothing immediately. Ensure that medical personnel are aware of thematerial(s) involved, and take precautions to protect themselves. Wash contaminated clothingbefore reuse.

General information

5. Fire-fighting measuresAlcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing mediaDo not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing

mediaVapors may form explosive mixtures with air. Vapors may travel considerable distance to a sourceof ignition and flash back. During fire, gases hazardous to health may be formed.

Specific hazards arising fromthe chemical

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipmentand precautions for firefighters

In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can doso without risk.

Fire fightingequipment/instructions

Use standard firefighting procedures and consider the hazards of other involved materials.Specific methodsHighly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosiveorganic peroxide when exposed to air or light or with age.

General fire hazards


6. Accidental release measuresKeep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out oflow areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist orvapor. Do not touch damaged containers or spilled material unless wearing appropriate protectiveclothing. Ventilate closed spaces before entering them. Local authorities should be advised ifsignificant spillages cannot be contained. For personal protection, see section 8 of the SDS.

Personal precautions,protective equipment andemergency procedures

Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Takeprecautionary measures against static discharge. Use only non-sparking tools. Keep combustibles(wood, paper, oil, etc.) away from spilled material. This product is miscible in water.

Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors ordivert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet toprevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up theproduct and place into a container for later disposal. Prevent entry into waterways, sewer,basements or confined areas. Following product recovery, flush area with water.

Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containersfor later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.

Methods and materials forcontainment and cleaning up

Avoid discharge into drains, water courses or onto the ground.Environmental precautions

7. Handling and storageVapors may form explosive mixtures with air. Do not handle, store or open near an open flame,sources of heat or sources of ignition. Protect material from direct sunlight. Explosion-proofgeneral and local exhaust ventilation. Take precautionary measures against static discharges. Allequipment used when handling the product must be grounded. Use non-sparking tools andexplosion-proof equipment. Avoid breathing mist or vapor. Avoid contact with eyes, skin, andclothing. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink orsmoke. Wear appropriate personal protective equipment. Wash hands thoroughly after handling.Observe good industrial hygiene practices.

Precautions for safe handling

Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic chargebuild-up by using common bonding and grounding techniques. Store in a cool, dry place out ofdirect sunlight. Store in original tightly closed container. Store in a well-ventilated place. Storeaway from incompatible materials (see Section 10 of the SDS).

Conditions for safe storage,including any incompatibilities

8. Exposure controls/personal protectionOccupational exposure limits

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

ValueTypeComponentsSTEL 5 ppmPolyvinyl chloride (CAS

9002-86-2)TWA 1 ppm

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

ValueType FormComponentsPEL 2400 mg/m3Acetone (CAS 67-64-1)

1000 ppmPEL 200 mg/m3Cyclohexanone (CAS

108-94-1)50 ppm

PEL 590 mg/m3Furan, Tetrahydro- (CAS109-99-9)

200 ppmPEL 5 mg/m3 Respirable fraction.Polyvinyl chloride (CAS

9002-86-2)15 mg/m3 Total dust.


US. OSHA Table Z-3 (29 CFR 1910.1000)

ValueTypeComponentsTWA 0.8 mg/m3Silica, amorphous, fumed

(CAS 112945-52-5)20 mppcf

US. ACGIH Threshold Limit Values

ValueType FormComponentsSTEL 750 ppmAcetone (CAS 67-64-1)TWA 500 ppmSTEL 50 ppmCyclohexanone (CAS

108-94-1)TWA 20 ppmSTEL 100 ppmFuran, Tetrahydro- (CAS

109-99-9)TWA 50 ppmTWA 1 mg/m3 Respirable fraction.Polyvinyl chloride (CAS

9002-86-2)US. NIOSH: Pocket Guide to Chemical Hazards

ValueTypeComponentsTWA 590 mg/m3Acetone (CAS 67-64-1)

250 ppmTWA 100 mg/m3Cyclohexanone (CAS

108-94-1)25 ppm

STEL 735 mg/m3Furan, Tetrahydro- (CAS109-99-9)

250 ppmTWA 590 mg/m3

200 ppmTWA 6 mg/m3Silica, amorphous, fumed

(CAS 112945-52-5)Biological limit values

ACGIH Biological Exposure Indices

Value Sampling TimeDeterminant SpecimenComponents50 mg/l Acetone Urine *Acetone (CAS 67-64-1)80 mg/l 1,2-Cyclohexan

ediol, withhydrolysis

Urine *Cyclohexanone (CAS108-94-1)

8 mg/l Cyclohexanol,with hydrolysis

Urine *

2 mg/l Tetrahydrofuran

Urine *Furan, Tetrahydro- (CAS109-99-9)* - For sampling details, please see the source document.

Exposure guidelinesUS - California OELs: Skin designation

Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin.US - Minnesota Haz Subs: Skin designation applies

Cyclohexanone (CAS 108-94-1) Skin designation applies.US - Tennessee OELs: Skin designation

Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin.US ACGIH Threshold Limit Values: Skin designation

Cyclohexanone (CAS 108-94-1) Can be absorbed through the skin.Furan, Tetrahydro- (CAS 109-99-9) Can be absorbed through the skin.


US. NIOSH: Pocket Guide to Chemical HazardsCyclohexanone (CAS 108-94-1) Can be absorbed through the skin.

Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 airchanges per hour) should be used. Ventilation rates should be matched to conditions. Ifapplicable, use process enclosures, local exhaust ventilation, or other engineering controls tomaintain airborne levels below recommended exposure limits. If exposure limits have not beenestablished, maintain airborne levels to an acceptable level. Eye wash facilities and emergencyshower must be available when handling this product.

Appropriate engineeringcontrols

Individual protection measures, such as personal protective equipmentFace shield is recommended. Wear safety glasses with side shields (or goggles).Eye/face protection

Skin protectionWear appropriate chemical resistant gloves.Hand protectionWear appropriate chemical resistant clothing.OtherIf engineering controls do not maintain airborne concentrations below recommended exposurelimits (where applicable) or to an acceptable level (in countries where exposure limits have notbeen established), an approved respirator must be worn.

Respiratory protection

Wear appropriate thermal protective clothing, when necessary.Thermal hazardsWhen using, do not eat, drink or smoke. Always observe good personal hygiene measures, suchas washing after handling the material and before eating, drinking, and/or smoking. Routinely washwork clothing and protective equipment to remove contaminants.

General hygieneconsiderations

9. Physical and chemical propertiesAppearance

Liquid.Physical stateTranslucent liquid.FormGray.ColorSolvent.Odor

Odor threshold Not available.

pH Not available.

Melting point/freezing point Not available.

Initial boiling point and boilingrange

151 °F (66.11 °C)

Flash point -4.0 °F (-20.0 °C)

Evaporation rate 5.5 - 8Not available.Flammability (solid, gas)

Upper/lower flammability or explosive limitsFlammability limit - lower(%)

1.8

Flammability limit - upper(%)

11.8

Explosive limit - lower (%) Not available.

Explosive limit - upper (%) Not available.

Vapor pressure 145 mm Hg @ 20 C

Vapor density 2.5

Relative density 0.95 +/- 0.02

Solubility(ies)Solubility (water) Negligible

Partition coefficient(n-octanol/water)

Not available.

Auto-ignition temperature Not available.

Decomposition temperature Not available.

Viscosity 600 - 1500 cP

Other informationVOC (Weight %) 423 g/l SCAQMD 1168/M316A


10. Stability and reactivityThe product is stable and non-reactive under normal conditions of use, storage and transport.ReactivityMaterial is stable under normal conditions.Chemical stabilityNo dangerous reaction known under conditions of normal use.Possibility of hazardous

reactionsAvoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding theflash point. Contact with incompatible materials.

Conditions to avoid

Acids. Strong oxidizing agents. Ammonia. Amines. Isocyanates. Caustics.Incompatible materialsNo hazardous decomposition products are known.Hazardous decomposition

products

11. Toxicological informationInformation on likely routes of exposure

Inhalation May be fatal if swallowed and enters airways. Headache. Nausea, vomiting. May cause irritationto the respiratory system. Vapors have a narcotic effect and may cause headache, fatigue,dizziness and nausea. Prolonged inhalation may be harmful.

Skin contact Causes skin irritation.

Eye contact Causes serious eye irritation.

Ingestion May be fatal if swallowed and enters airways. Harmful if swallowed. Harmful if swallowed. Dropletsof the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.

Symptoms related to thephysical, chemical andtoxicological characteristics

Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severeeye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Maycause respiratory irritation. Skin irritation. May cause redness and pain. Symptoms ofoverexposure may be headache, dizziness, tiredness, nausea and vomiting.

Information on toxicological effectsAcute toxicity May be fatal if swallowed and enters airways. Narcotic effects. May cause respiratory irritation.

Test ResultsComponents SpeciesAcetone (CAS 67-64-1)


20 ml/kg

LC50 RatInhalation

50 mg/l, 8 Hours

LD50 RatOral

5800 mg/kg

Cyclohexanone (CAS 108-94-1)


948 mg/kg

LC50 RatInhalation

8000 ppm, 4 hours

LD50 RatOral

1540 mg/kg

* Estimates for product may be based on additional component data not shown.Causes skin irritation.Skin corrosion/irritationCauses serious eye irritation.Serious eye damage/eye

irritationRespiratory or skin sensitization

Respiratory sensitization Not available.This product is not expected to cause skin sensitization.Skin sensitizationNo data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.

Germ cell mutagenicity


Carcinogenicity In 2012 USEPA Integrated Risk Information System (IRIS) reviewed a two species inhalationlifetime study on THF conducted by NTP (1998). Male rats developed renal tumors and femalemice developed liver tumors while neither the female rats nor the male mice showed similarresults. Because the carcinogenic mechanisms could not be identified clearly in either species foreither tumor, the EPA determined that the male rat and female mouse findings are relevant to theassessment of carcinogenic potential in humans. Therefore, the IRIS review concludes that thesedata in aggregate indicate that there is "suggestive evidence of carcinogenic potential" followingexposure to THF by all routes of exposure.

IARC Monographs. Overall Evaluation of CarcinogenicityCyclohexanone (CAS 108-94-1) 3 Not classifiable as to carcinogenicity to humans.Polyvinyl chloride (CAS 9002-86-2) 3 Not classifiable as to carcinogenicity to humans.Silica, amorphous, fumed (CAS 112945-52-5) 3 Not classifiable as to carcinogenicity to humans.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Polyvinyl chloride (CAS 9002-86-2) Cancer

This product is not expected to cause reproductive or developmental effects.Reproductive toxicitySpecific target organ toxicity -single exposure

Narcotic effects. May cause drowsiness and dizziness. Respiratory tract irritation.

Specific target organ toxicity -repeated exposure

Not classified.

Aspiration hazard May be fatal if swallowed and enters airways.

Chronic effects Prolonged inhalation may be harmful.

12. Ecological informationThe product is not classified as environmentally hazardous. However, this does not exclude thepossibility that large or frequent spills can have a harmful or damaging effect on the environment.

Ecotoxicity

Components Test ResultsSpeciesAcetone (CAS 67-64-1)

AquaticLC50Fish > 100 mg/l, 96 hoursFathead minnow (Pimephales promelas)

* Estimates for product may be based on additional component data not shown.

Cyclohexanone (CAS 108-94-1)Aquatic

LC50Fish 481 - 578 mg/l, 96 hoursFathead minnow (Pimephales promelas)

No data is available on the degradability of this product.Persistence and degradabilityNo data available.Bioaccumulative potential

Partition coefficient n-octanol / water (log Kow)Acetone (CAS 67-64-1) -0.24Cyclohexanone (CAS 108-94-1) 0.81Furan, Tetrahydro- (CAS 109-99-9) 0.46

No data available.Mobility in soilOther adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation

potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerationsCollect and reclaim or dispose in sealed containers at licensed waste disposal site. This materialand its container must be disposed of as hazardous waste. Do not allow this material to drain intosewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or usedcontainer. Dispose of contents/container in accordance with local/regional/national/internationalregulations.

Disposal instructions

Dispose in accordance with all applicable regulations.Local disposal regulationsThe waste code should be assigned in discussion between the user, the producer and the wastedisposal company.

Hazardous waste code

Dispose of in accordance with local regulations. Empty containers or liners may retain someproduct residues. This material and its container must be disposed of in a safe manner (see:Disposal instructions).

Waste from residues / unusedproducts

Empty containers should be taken to an approved waste handling site for recycling or disposal.Since emptied containers may retain product residue, follow label warnings even after container isemptied.

Contaminated packaging


14. Transport informationDOT

UN1993UN numberFlammable liquids, n.o.s. (Acetone RQ = 25934 LBS)UN proper shipping name


-Subsidiary risk3Label(s)IIPacking groupRead safety instructions, SDS and emergency procedures before handling.Special precautions for userIB2, T7, TP1, TP8, TP28Special provisions150Packaging exceptions202Packaging non bulk242Packaging bulk

IATAUN1993UN numberFlammable liquid, n.o.s. (Acetone)UN proper shipping name


-Subsidiary riskIIPacking groupNo.Environmental hazards3HERG CodeRead safety instructions, SDS and emergency procedures before handling.Special precautions for user

IMDGUN1993UN numberFLAMMABLE LIQUID, N.O.S. (Acetone)UN proper shipping name


-Subsidiary riskIIPacking group

No.Marine pollutantEnvironmental hazards

F-E, S-EEmSRead safety instructions, SDS and emergency procedures before handling.Special precautions for userNot available.Transport in bulk according to

Annex II of MARPOL 73/78 andthe IBC Code

15. Regulatory informationThis product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.

US federal regulations

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)Polyvinyl chloride (CAS 9002-86-2) Cancer

Central nervous systemLiverBloodFlammability

CERCLA Hazardous Substance List (40 CFR 302.4)Acetone (CAS 67-64-1) LISTEDCyclohexanone (CAS 108-94-1) LISTEDFuran, Tetrahydro- (CAS 109-99-9) LISTED


Superfund Amendments and Reauthorization Act of 1986 (SARA)Immediate Hazard - YesDelayed Hazard - NoFire Hazard - YesPressure Hazard - NoReactivity Hazard - No

Hazard categories

SARA 302 Extremely hazardous substanceNot listed.

NoSARA 311/312 HazardouschemicalSARA 313 (TRI reporting)

Not regulated.

Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List

Not regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)

Not regulated.Not regulated.Safe Drinking Water Act

(SDWA)Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) andChemical Code Number

Acetone (CAS 67-64-1) 6532Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))

Acetone (CAS 67-64-1) 35 %WVDEA Exempt Chemical Mixtures Code Number

Acetone (CAS 67-64-1) 6532US state regulations

US. Massachusetts RTK - Substance ListAcetone (CAS 67-64-1)Cyclohexanone (CAS 108-94-1)Furan, Tetrahydro- (CAS 109-99-9)Silica, amorphous, fumed (CAS 112945-52-5)

US. New Jersey Worker and Community Right-to-Know ActAcetone (CAS 67-64-1)Cyclohexanone (CAS 108-94-1)Furan, Tetrahydro- (CAS 109-99-9)Polyvinyl chloride (CAS 9002-86-2)

US. Pennsylvania Worker and Community Right-to-Know LawAcetone (CAS 67-64-1)Cyclohexanone (CAS 108-94-1)Furan, Tetrahydro- (CAS 109-99-9)Silica, amorphous, fumed (CAS 112945-52-5)

US. Rhode Island RTKAcetone (CAS 67-64-1)Cyclohexanone (CAS 108-94-1)Furan, Tetrahydro- (CAS 109-99-9)

US. California Proposition 65California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to containany chemicals currently listed as carcinogens or reproductive toxins.

International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*

Domestic Substances List (DSL) YesCanada

*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).

Toxic Substances Control Act (TSCA) Inventory NoUnited States & Puerto Rico


16. Other information, including date of preparation or last revision27-May-2015Issue date-Revision date

Version # 01Health: 2Flammability: 3Physical hazard: 0

HMIS® ratings

NFPA ratings

023

The information in the sheet was written based on the best knowledge and experience currentlyavailable. Oatey Co. cannot anticipate all conditions under which this information and its product,or the products of other manufacturers in combination with its product, may be used. It is theuser’s responsibility to ensure safe conditions for handling, storage and disposal of the product,and to assume liability for loss, injury, damage or expense due to improper use.

Disclaimer


PVC Pipe and Fittings Date updated: 1/14/14

SAFETY DATA SHEET


1. PRODUCT AND COMPANY IDENTIFICATION

COMMON NAME: PVC Pipe and Fittings

CHEMICAL NAME: Not Applicable. Formulation, see section 3.

FORMULA: Mixture

PRODUCT CAS NO.: Mixture, see section 3.

Recommended Use: Drain Waste Vent and Pressure Pipe and Fittings

SUPPLIER: Charlotte Pipe and Foundry Company (Plastics Division)

ADDRESS: 4210 Old Charlotte Highway

CITY, STATE, ZIP: Monroe, NC 28110

PHONE: +1-704-372-3650 EMERGENCY PHONE: +1-704-372-3650


EMERGENCY OVERVIEW Toxic and irritating gases and fumes may be given off during burning or thermal decomposition. Avoid generating dust. Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard.

GHS Status This material is hazardous in accordance with the hazard communication standard, 29 CFR

1910.1200 Classification of the substance or mixture

Skin irritation – Category 2

Eye irritation – Category 2 A Specific target organ toxicity – single exposure – Category 3 GHS label pictogram Warning Signal word Warning Hazard statements Causes serious eye irritation.


SAFETY DATA SHEET


Causes skin irritation. May cause respiratory irritation Precautionary statements Prevention Avoid breathing dust/fume/gas/mist. Response If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present

and easy to do. Continue rinsing. Storage Keep away from intense heat, flames. Disposal Dispose of in accordance with local regulations. Hazards not otherwise classified

None known.

Relevant routes of exposure

Skin, eyes, inhalation.

Inhalation Melted product is flammable and produces intense heat and dense smoke during burning. Irritating gases and fumes may be given off during burning or thermal decomposition.

Skin contact Gases and fumes evolved during thermal processing or decomposition can cause skin irritation.

Eye contact Dust can cause eye irritation. Gases and fumes evolved during thermal processing or decomposition can cause eye irritation.

Ingestion No data available.

3. HAZARDOUS INGREDIENTS: COMPOSITION/INFORMATION

INGREDIENT %

WEIGHT

PEL-OSHA

TLV-ACGIH

NIOSH REL

Polyvinyl chloride CAS 9002-86-2

>80% None established Particulates not otherwise classified: 15 mg/m3

1 mg/m3 (respirable fraction) Particulates not otherwise classified: 10 mg/m3 (inhalable fraction)

None established

Titanium dioxide CAS 13463-67-7

0-5% 15 mg/m3, total dust 10 mg/m3 TWA None established

4. FIRST AID MEASURES EYE CONTACT: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 15 minutes. Consult a physician. SKIN CONTACT: Rinse with water. Remove contaminated clothing and shoes. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes before reuse. INHALATION: If vapors from excessive heating, burning or decomposition products are inhaled: remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular, or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing, such as collar, tie, belt, or waistband. In case of inhalation of decomposition


SAFETY DATA SHEET


products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance.

INGESTION: Wash out mouth with water. Remove dentures, if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Loosen tight clothing, such as collar, tie, belt, or waistband. Consult a physician. Notes to physician: In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under surveillance for 48 hours Specific treatments: None known

5. FIRE FIGHTING MEASURES

FLAMMABLE PROPERTIES FLASH POINT: No data. Decomposition products may be combustible. FLAMMABLE LIMITS: LEL: No Data UEL: No data EXTINGUISHING MEDIA: Water, foam, dry chemical. Do not use CO2 on Class A fires, as a lack of cooling capacity may result in re-ignition. FIRE AND EXPLOSION HAZARDS: Solid does not readily release flammable vapors. Thermoplastic polymers can burn. Smoke, Carbon Monoxide, Carbon Dioxide, Aldehydes, Hydrogen Chloride, Tin. Irritating and/or toxic substances will be emitted during burning, combustion, or decomposition. Run-off water from firefighting may have corrosive effects. PROTECTIVE MEASURES FOR FIRE FIGHTERS: Firefighters must wear a NIOSH-approved, full-facepiece self-contained breathing apparatus (SCBA) operated in positive pressure mode and full turnout or bunker gear with additional chemical protective clothing as necessary to protect against thermal decomposition products. SPECIAL PROTECTIVE ACTIONS FOR FIRE FIGHTERS: If there is a fire, promptly isolate the scene by removing all persons from the vicinity of the incident. No action shall be taken involving any personal risk or without suitable training

6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment, and emergency measures For non-emergency personnel

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

For emergency responders If specialized clothing is required to deal with decomposition products or fumes from burning or excessive heating, take note of information in Section 8 on suitable and unsuitable materials. See also information in “for non-emergency personnel.”

Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains, and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil, or air).


SAFETY DATA SHEET


Methods and materials for containment and clean-up Small spill Avoid dust generation. Vacuum dust with equipment fitted with a HEPA filter

and place in a closed, labeled waste container. See Section 1 for emergency contact information.

Large spill Move containers from spill area. Approach release from upwind. Prevent entry into sewers, waterways, basements, and confined areas. Avoid dust generation. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. See Section 1 for emergency contact information.

7. HANDLING AND STORAGE Conditions for safe storage, including any incompatibilities

Store in a dry place away from direct sunlight, heat, and incompatible materials. Avoid intense heat and flames.

Precautions for safe handling Protective measures Put on appropriate personal protective equipment (see Section 8). Do not

handle until all safety precautions have been read and understood. Do not get particles, vapors or fumes in eyes, on skin, or on clothing. Do not ingest. If during normal use, the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator.

Advice on general occupational hygiene

Employees must wash hands and face before eating, drinking, or smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also section 8 for additional information on hygiene measures.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation, or other engineering controls to keep worker exposure to airborne contaminants below recommended and statutory limits. RESPIRATORY PROTECTION: Cutting or sanding this product can generate dust. Used a properly fitted particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product, and the safe working limits of the respirator. A NIOSH-approved N95 single use or P95 multiple use respirator will protect the employee from at least 95% of airborne particles. Follow the respirator manufacture’s instructions for proper use. If adhesives or other substances are used with this product, refer to the product manufacturer’s safety data sheet for applicable respiratory protective measures. SKIN PROTECTION: Chemical-resistant, impervious gloves complying with an approved standard should be worn when handling this or any chemical product, if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures containing several substances, the protection time of the gloves cannot be accurately estimated. If adhesives or other substances are used with this product, refer to the product manufacturer’s safety data sheet for applicable skin protective measures. BODY PROTECTION: Personal protective equipment for the body should be selected on the task being performed and the risks involved, and should be approved by a specialist before handling this product. If adhesives or other substances are used with this product, refer to the product manufacturer’s safety data sheet for applicable skin protective measures. EYE/FACE PROTECTION: Safety eyewear complying with an approved standard must be used when a risk assessment indicates this is necessary to avoid exposure to dust. Particulates and dust can be formed when cutting, grinding or sanding this product. If contact with dust or particulates is possible, the following should be worn unless the assessment indicates a


SAFETY DATA SHEET


higher degree of protection: safety glasses with side shields. If adhesives or other substances are used with this product, refer to the product manufacturer’s safety data sheet for applicable eye and face protective measures.


APPEARANCE: Solid. White/grey ODOR: Not applicable. ODOR THRESHOLD: Not available BOILING POINT: Not available FLASH POINT: Not applicable FLAMMABILITY: Melted product is flammable. AUTOIGNITION TEMPERATURE: Not applicable DECOMPOSITION TEMPERATURE: Not available LOWER/UPPER EXPLOSION LIMITS: Not available VAPOR PRESSURE: Not available LIQUID DENSITY: Not available SPECIFIC GRAVITY: Approximately 1.4 MELTING POINT: Not available pH: Not available SOLUBILITY: Insoluble % VOLATILE: Not available VISCOSITY: Not available

10. STABILITY AND REACTIVITY Stability: Stable at normal temperatures and pressures.

Reactivity: Stable at normal temperatures and pressures.

Conditions to avoid: Heat, flames, sparks and other sources of ignition.

Incompatible materials/conditions: Consult the Charlotte Pipe and Foundry chemical resistance guide.

Hazardous decomposition products: Hydrogen chloride, carbon oxides, small amounts of benzene and aromatic and aliphatic hydrocarbons, phosgene.

Hazardous polymerization: Not available.

11. TOXICOLOGICAL INFORMATION

ACUTE TOXICITY: No toxicological data is available for the finished product.


SAFETY DATA SHEET


SENSITIZATION: No data available.

MUTAGENICITY: No data available.

DEVELEPMENTAL: No data available.

Fertility: No data available.

CARCINOGENICITY: On the date of preparation of this SDS, this product does not contain ingredients classified by the International Agency for Research on Cancer, National Toxicology Program Report, or OSHA at 29 CFR 1910, Subpart Z, as a carcinogen. REPRODUCTIVE TOXICITY: Not available

TERATOGENICITY: Not available

SPECIFIC TARGET ORGANS – SINGLE EXPOSURE: Not available

SPECIFIC TARGET ORGANS – REPEATED EXPOSURE: Not available

ASPIRATION HAZARD: Not available

INFORMATION ON THE LIKELY ROUTES OF EXPOSURE: Potential acute health effects

Eye contact No known significant effects or critical hazards. Dust can cause eye irritation. Inhalation Exposure to decomposition products may cause a health hazard. Serious effects

may be delayed following exposure. Skin contact Skin irritant. Ingestion No known significant effects or critical hazards.

Symptoms related to the physical, chemical, and toxicological characteristics

Eye contact No data available. Inhalation No data available Skin contact Adverse symptoms may include irritation. Ingestion No data available

Immediate, delayed and chronic effects from short term exposure

Short term exposure


Long term exposure


Potential chronic effects

General No data available. Carcinogenicity Not listed by OSHA, IARC or NTP. See section 11.


SAFETY DATA SHEET


12. ECOLOGICAL INFORMATION

Numerical measures of toxicity No data available Persistence and degradability Does not biodegrade over time. Bioaccumulative potential No data available Mobility in soil No data available. Other adverse effects: No known significant or critical hazards.

13. DISPOSAL CONSIDERATIONS

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, and by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste should not be disposed of to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste and packaging should be recycled when possible. Incineration or landfill should only be considered when recycling is not feasible. This material must be disposed of in a safe way.

14. TRANSPORT INFORMATION

PROPER SHIPPING NAME: Not Regulated HAZARD CLASS: Not Regulated IDENTIFICATION NUMBER: Not Regulated SHIPPING LABEL: Not Regulated PACKING GROUP: Not Regulated

15. REGULATORY INFORMATION United States

TSCA 8(b): All ingredients are listed on the U.S. Toxic Substances Control Act inventory.

Airborne unbound particles of titanium dioxide of respirable size are listed as being carcinogenic per California Proposition 65.

16. OTHER INFORMATION

Date of Preparation: 11 December 2013 Key To Acronyms: CAS: Chemical Abstracts Service


SAFETY DATA SHEET


CFR: Code of Federal Regulations HEPA High-Efficiency Particulate Air (filter) IARC: International Agency for Research on Cancer LD50 Lethal dose to 50% of exposed laboratory animals LC50 Lethal concentration to 50% of exposed laboratory animals LEL: Lower Explosive Limit mg/l Milligrams per liter NIOSH: National Institute for Occupational Safety and Health (US) NTP: National Toxicology Program OSHA: Occupational Safety and Health Administration (US) PEL: Permissible Exposure Limit TSCA Toxic Substances Control Act TLV: Threshold Limit Value – American Conference of Governmental Industrial Hygienists (ACGIH) TWA: Time Weighted Average UEL: Upper Explosive Limit ug/ m3 Micrograms per cubic meter

DISCLAIMER NO WARRANTY OF MERCHANTABILITY OR OF FITNESS FOR A PARTICULAR PURPOSE, OR WARRANTY OR GUARANTY OF ANY OTHER KIND, EXPRESS OR IMPLIED, IS MADE REGARDING PERFORMANCE, SAFETY, SUITABILITY, STABILITY OR OTHERWISE FOR THE ABS MATERIALS AS REPRESENTED IN THIS MSDS SHEET. Charlotte Pipe and Foundry assumes no liability whatsoever for the use of or reliance upon this information. The information and data contained in this MSDS has been compiled from information believed to be accurate and is offered for your consideration, investigation and verification. Buyer assumes all risk of use, storage, handling and disposal of the product in compliance with applicable federal, state, and local laws and regulations.

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Safety Data Sheetacc. to OSHA HCS

Printing date 01/05/2015 Reviewed on 01/05/2015

39.0

1 Identification

· Product identifier

· Trade name: Recrete™ 5 Minute

· Article number: 83-67305

· Relevant identified uses of the substance or mixture and uses advised against No further relevant information available.

· Application of the substance / the mixture

· Details of the supplier of the safety data sheet· Manufacturer/Supplier:

Dayton® Superior

4226 Kansas Avenue Tel.: (866) 329-8724

Kansas City, KS 66106

Emergency Telephone Number: Use only in the event of an emergency involving a spill, leak, fire, exposure, or accident

involving chemicals. Within the U.S., Canada, or the U.S. Virgin Islands, call ChemTrec at (800) 424-9300, 24 hours a day.

Or, outside these areas, call international number, +1 703 741-5970. Collect calls are accepted.

· Information department: Environmental, Health, and Safety department.

2 Hazard(s) identification

· Classification of the substance or mixture

Carc. 1A H350 May cause cancer.

· Classification according to Directive 67/548/EEC or Directive 1999/45/ECMay cause eye and skin irritation. Prolonged contact may cause sensitization.

· Information concerning particular hazards for human and environment:The product has to be labelled due to internationally acknowledged calculation procedures using the latest valid versions.

· Classification system:The classification was made according to the latest editions of international substances lists, and expanded upon from

company and literature data.

· Label elements· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).

· Hazard pictograms

GHS08

· Signal word Danger

· Hazard-determining components of labeling:Quartz (SiO2)

· Hazard statementsMay cause cancer.

· Precautionary statementsIf medical advice is needed, have product container or label at hand.

Keep out of reach of children.

Read label before use.

Use personal protective equipment as required.

Obtain special instructions before use.

Do not handle until all safety precautions have been read and understood.

IF exposed or concerned: Get medical advice/attention.

Store locked up.

Dispose of contents/container in accordance with local/regional/national/international regulations.(Contd. on page 2)

USA

/9



Trade name: Recrete™ 5 Minute

(Contd. of page 1)

39.0

· Classification system:· NFPA ratings (scale 0 - 4)

10

0Health = 1

Fire = 0

Reactivity = 0

· HMIS-ratings (scale 0 - 4)

HEALTH

FIRE

PHYSICAL HAZARD

1

0

0

Health = 1

Fire = 0

Reactivity = 0

· Other hazards· Results of PBT and vPvB assessment· PBT: Not applicable.

· vPvB: Not applicable.

3 Composition/information on ingredients

· Chemical characterization: Mixtures· Description: Mixture of the substances listed below with nonhazardous additions.

· Dangerous components:

14808-60-7 Quartz (SiO2) 25-50%

1317-65-3 Limestone 10-25%

65997-15-1 Cement, portland, chemicals 10-25%

8050-09-7 Rosin ≤ 5%

26499-65-0 Calcium sulfate ≤ 5%

7778-18-9 calcium sulphate, natural ≤ 2.5%

· Additional information: For the wording of the listed risk phrases refer to section 16.

4 First-aid measures

· Description of first aid measures· After inhalation:

Supply fresh air and to be sure call for a doctor.

In case of unconsciousness place patient stably in side position for transportation.

· After skin contact: If skin irritation continues, consult a doctor.

· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.

· After swallowing: Seek medical treatment.

· Most important symptoms and effects, both acute and delayed No further relevant information available.

· Indication of any immediate medical attention and special treatment needed No further relevant information available.

5 Fire-fighting measures

· Extinguishing media· Suitable extinguishing agents:

CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

· Special hazards arising from the substance or mixture No further relevant information available.(Contd. on page 3)

USA

/9




(Contd. of page 2)

39.0

· Advice for firefighters· Protective equipment:

Because fire may produce thermal decomposition products, wear a self-contained breathing apparatus (SCBA) with a full face

piece operated in pressure-demand or positive-pressure mode.

6 Accidental release measures

· Personal precautions, protective equipment and emergency proceduresWear protective equipment. Keep unprotected persons away.

· Environmental precautions: No special measures required.

· Methods and material for containment and cleaning up: Ensure adequate ventilation.

· Reference to other sectionsSee Section 7 for information on safe handling.

See Section 8 for information on personal protection equipment.

See Section 13 for disposal information.

7 Handling and storage

· Precautions for safe handlingWear appropriate personal protective clothing to prevent eye and skin contact. Avoid breathing vapors or mists of this

product. Use with adequate ventilation. Do not take internally.

· Information about protection against explosions and fires: No special measures required.

· Conditions for safe storage, including any incompatibilities· Storage:· Requirements to be met by storerooms and receptacles: No special requirements.

· Information about storage in one common storage facility: Not required.

· Further information about storage conditions: Keep receptacle tightly sealed.

· Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection

· Additional information about design of technical systems: No further data; see item 7.

· Control parameters

· Components with limit values that require monitoring at the workplace:

14808-60-7 Quartz (SiO2)

PEL see Quartz listing

REL Long-term value: 0.05* mg/m³

*respirable dust; See Pocket Guide App. A

TLV Long-term value: 0.025* mg/m³

*as respirable fraction

65997-15-1 Cement, portland, chemicals

PEL Long-term value: 50 mppcf or 15* 5** mg/m³

*total dust **respirable fraction

REL Long-term value: 10* 5** mg/m³


TLV Long-term value: 1* mg/m³

E; *as respirable fraction

(Contd. on page 4) USA

/9




(Contd. of page 3)

39.0

26499-65-0 Calcium sulfate

PEL Long-term value: 15* 5** mg/m³




7778-18-9 calcium sulphate, natural

PEL Long-term value: 15* 5** mg/m³




TLV Long-term value: 10* mg/m³

*as inhalable fraction

· Additional information: The lists that were valid during the creation were used as basis.

· Exposure controls· Personal protective equipment:· General protective and hygienic measures:

Keep away from foodstuffs, beverages and feed.

Immediately remove all soiled and contaminated clothing.

Wash hands before breaks and at the end of work.

Avoid contact with the eyes and skin.

· Breathing equipment: Suitable respiratory protective device recommended.

· Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.

· Material of glovesThe selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from

manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can

not be calculated in advance and has therefore to be checked prior to the application.

· Penetration time of glove materialThe exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.

· Eye protection: Wear appropriate eye protection to prevent eye contact.

9 Physical and chemical properties

· Information on basic physical and chemical properties· General Information· Appearance:

Form: Solid

Color: According to product specification

· Odor: Characteristic

· Odour threshold: Not determined.

· pH-value: Not applicable.

· Change in conditionMelting point/Melting range: Undetermined.

Boiling point/Boiling range: > 999 °C (> 1830 °F)


/9




(Contd. of page 4)

39.0

· Flash point: Not applicable.

· Flammability (solid, gaseous): Not determined.

· Ignition temperature:

Decomposition temperature: Not determined.

· Auto igniting: Product is not selfigniting.

· Danger of explosion: Product does not present an explosion hazard.

· Explosion limits:Lower: Not determined.

Upper: Not determined.

· Vapor pressure: Not applicable.

· Density at 20 °C (68 °F): 2.73374 g/cm³ (22.813 lbs/gal)

· Relative density Not determined.

· Vapour density Not applicable.

· Evaporation rate Not applicable.

· Solubility in / Miscibility withWater: Soluble.

· Partition coefficient (n-octanol/water): Not determined.

· Viscosity:Dynamic: Not applicable.

Kinematic: Not applicable.

· Solvent content:Organic solvents: 0.0 %

Solids content: 99.9 %

· Other information No further relevant information available.

· Volatile Organic Compounds: Not determined

10 Stability and reactivity

· Reactivity· Chemical stability· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.

· Possibility of hazardous reactions No dangerous reactions known.

· Conditions to avoid No further relevant information available.

· Incompatible materials: No further relevant information available.

· Hazardous decomposition products: No dangerous decomposition products known.

11 Toxicological information

· Information on toxicological effects· Acute toxicity:· Primary irritant effect:· on the skin: May cause skin irritation.

· on the eye: Irritating effect.

· Sensitization: Sensitization possible through skin contact.(Contd. on page 6)

USA

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(Contd. of page 5)

39.0

· Additional toxicological information:The product shows the following dangers according to internally approved calculation methods for preparations:

Irritant

· Carcinogenic categories

· IARC (International Agency for Research on Cancer)

14808-60-7 Quartz (SiO2) 1

13463-67-7 titanium dioxide 2B

7631-86-9 silicon dioxide, chemically prepared 3

1309-37-1 diiron trioxide 3

50-00-0 formaldehyde 1

· NTP (National Toxicology Program)

14808-60-7 Quartz (SiO2) K

50-00-0 formaldehyde R

· OSHA-Ca (Occupational Safety & Health Administration)

50-00-0 formaldehyde

12 Ecological information

· Toxicity· Aquatic toxicity: No further relevant information available.

· Persistence and degradability No further relevant information available.

· Bioaccumulative potential No further relevant information available.

· Mobility in soil No further relevant information available.

· Additional ecological information:· General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water

· Results of PBT and vPvB assessment· PBT: Not applicable.

· vPvB: Not applicable.

· Other adverse effects No further relevant information available.

13 Disposal considerations

· Waste treatment methods· Recommendation:

Must not be disposed of as normal garbage. Do not allow product to reach sewage system.

It is the generator's responsibility to determine if the waste meets applicable definitions of hazardous waste. State and local

regulations may differ from federal disposal regulations. Dispose of waste material according to local, state, federal, and

provincial environmental regulations.

· Uncleaned packagings:· Recommendation: Disposal must be made according to Federal, State, and Local regulations.

· Recommended cleansing agent: Water, if necessary with cleansing agents.

14 Transport information

· UN-Number· DOT, ADR, IMDG, IATA Not Regulated


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(Contd. of page 6)

39.0

· UN proper shipping name· ADR Not Regulated

· Transport hazard class(es)

· DOT, ADR, IMDG, IATA· Class N/A

· Packing group· DOT, ADR, IMDG, IATA III

· Environmental hazards:· Marine pollutant: No

· Transport in bulk according to Annex II of MARPOL73/78and the IBC Code Not applicable.

· Transport/Additional information:

· ADR· U.S. Domestic Ground Shipments: Same as listed for Standard Shipments above.

· U.S. Domestic Ground Non-Bulk (119 gal or less percontainer) Shipments: Same as listed for Standard Shipments above.

· Emergency Response Guide (ERG) Number: Not determine

· UN "Model Regulation": UN-, -, N/A, III

15 Regulatory information

· Safety, health and environmental regulations/legislation specific for the substance or mixture· Sara

· Section 355 (extremely hazardous substances):


· Section 313 (Specific toxic chemical listings):This product may contain 1 or more toxic chemicals subject to the reporting requirements of Section 313 of Title III of the

Superfund Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR part 372. If so, the chemicals are listed below.

1344-28-1 aluminium oxide ≤1%

554-13-2 lithium carbonate ≤0.1%

50-00-0 formaldehyde ≤0.01%

· TSCA (Toxic Substances Control Act):

14808-60-7 Quartz (SiO2)

1317-65-3 Limestone

65997-15-1 Cement, portland, chemicals

65997-16-2 Cement, alumina, chemicals

7778-18-9 calcium sulphate, natural

1310-73-2 sodium hydroxide

13463-67-7 titanium dioxide

1344-28-1 aluminium oxide

99999-99-9 Non-hazardous material

7631-86-9 silicon dioxide, chemically prepared


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(Contd. of page 7)

39.0

554-13-2 lithium carbonate

144-55-8 sodium hydrogencarbonate

1309-37-1 diiron trioxide

21645-51-2 aluminium hydroxide


· Proposition 65

· Chemicals known to the State of California (Prop. 65) to cause cancer:

14808-60-7 Quartz (SiO2)



· Chemicals known to cause reproductive toxicity for females:

None of the ingredients is listed.

· Chemicals known to cause reproductive toxicity for males:

None of the ingredients is listed.

· Chemicals known to cause developmental toxicity:

554-13-2 lithium carbonate

· Cancerogenity categories

· EPA (Environmental Protection Agency)

50-00-0 formaldehyde B1

· TLV (Threshold Limit Value established by ACGIH)

14808-60-7 Quartz (SiO2) A2

13463-67-7 titanium dioxide A4

1344-28-1 aluminium oxide A4

1309-37-1 diiron trioxide A4

50-00-0 formaldehyde A2

· MAK (German Maximum Workplace Concentration)

14808-60-7 Quartz (SiO2) 1

13463-67-7 titanium dioxide 3A

1344-28-1 aluminium oxide 2

50-00-0 formaldehyde 4

· NIOSH-Ca (National Institute for Occupational Safety and Health)

14808-60-7 Quartz (SiO2)



· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).

· Hazard pictograms

GHS08

· Signal word Danger(Contd. on page 9)

USA

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(Contd. of page 8)

39.0

· Hazard-determining components of labeling:Quartz (SiO2)

· Hazard statementsMay cause cancer.

· Precautionary statementsIf medical advice is needed, have product container or label at hand.

Keep out of reach of children.

Read label before use.

Use personal protective equipment as required.

Obtain special instructions before use.

Do not handle until all safety precautions have been read and understood.

IF exposed or concerned: Get medical advice/attention.

Store locked up.

Dispose of contents/container in accordance with local/regional/national/international regulations.

· National regulations:

· Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.

· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information

The provided information is based on our present knowledge. However, this shall not constitute a guarantee for any specific

product features and shall not establish a legally valid contractual relationship.

This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product

features and shall not establish a legally valid contractual relationship.

· Department issuing MSDS: Environmental, Health & Safety Department

· Contact: Environmental, Health & Safety Manager

· Date of preparation / last revision 01/05/2015 / 19

· Abbreviations and acronyms:ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of

Dangerous Goods by Road)

IMDG: International Maritime Code for Dangerous Goods

DOT: US Department of Transportation

IATA: International Air Transport Association

ACGIH: American Conference of Governmental Industrial Hygienists

EINECS: European Inventory of Existing Commercial Chemical Substances

ELINCS: European List of Notified Chemical Substances

CAS: Chemical Abstracts Service (division of the American Chemical Society)

NFPA: National Fire Protection Association (USA)

HMIS: Hazardous Materials Identification System (USA)

Carc. 1A: Carcinogenicity, Hazard Category 1A

USA

Version: 2.0 Revision Date: 01/30/2017

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SAFETY DATA SHEET

1. Identification

Material name: SPEED CRETE BLUE LINE Material: TR5102650

Recommended use and restriction on use

Recommended use: Cement, Portland, chemicals Restrictions on use: Not known.

Manufacturer/Importer/Supplier/Distributor Information EUCLID CHEMICAL COMPANY 19218 REDWOOD ROAD CLEVELAND OH 44110 US Contact person: EH&S Department Telephone: 216-531-9222 Emergency telephone number: 1-800-424-9300 (US); 1-613-996-6666 (Canada)

2. Hazard(s) identification

Hazard Classification

Health Hazards

Skin Corrosion/Irritation Category 2

Serious Eye Damage/Eye Irritation Category 1

Skin sensitizer Category 1

Carcinogenicity Category 1A

Specific Target Organ Toxicity - Single Exposure

Category 31.

Target Organs

1. Respiratory tract irritation.

Unknown toxicity - Health

Acute toxicity, oral 90.93 %

Acute toxicity, dermal 92.25 %

Acute toxicity, inhalation, vapor 100 %

Acute toxicity, inhalation, dust or mist

100 %

Hazard Symbol:

Label Elements


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Signal Word: Danger

Hazard Statement: Causes skin irritation. May cause an allergic skin reaction. Causes serious eye damage. May cause respiratory irritation. May cause cancer.


Prevention: Wash thoroughly after handling. Wear protective gloves/protective

clothing/eye protection/face protection. Avoid breathing dust/fume/gas/mist/vapors/spray. Contaminated work clothing must not be allowed out of the workplace. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Use only outdoors or in a well-ventilated area.

Response: IF INHALED: Remove person to fresh air and keep comfortable for

breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice/attention. Immediately call a POISON CENTER/doctor. Specific treatment (see this label). Wash contaminated clothing before reuse.

Storage: Store locked up. Store in well-ventilated place. Keep container tightly

closed.

Disposal: Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

Hazard(s) not otherwise classified (HNOC):

None.

3. Composition/information on ingredients

Mixtures

Chemical Identity CAS number Content in percent (%)*


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Portland cement 65997-15-1 50 - <100%

Crystalline Silica (Quartz)/ Silica Sand

14808-60-7 20 - <50%

Kaolin Clay 1332-58-7 5 - <10%

Gypsum (Calcium Sulfate) 10034-76-1 5 - <10%

Calcium salt 7778-18-9 1 - <5%

Titanium dioxide 13463-67-7 0.1 - <1%

Ammonium Chloride 12125-02-9 0.1 - <1% * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

4. First-aid measures

Ingestion: Call a POISON CENTER/doctor/.../if you feel unwell. Rinse mouth.

Inhalation: Move to fresh air.

Skin Contact: Get medical attention. Destroy or thoroughly clean contaminated shoes.

Immediately remove contaminated clothing and shoes and wash skin with soap and plenty of water. If skin irritation or an allergic skin reaction develops, get medical attention.

Eye contact: Immediately flush with plenty of water for at least 15 minutes. If easy to do,

remove contact lenses. Call a physician or poison control center immediately.

Most important symptoms/effects, acute and delayed

Symptoms: Prolonged or repeated contact with skin may cause redness, itching,

irritation and eczema/chapping. Extreme irritation of eyes and mucous membranes, including burning and tearing. Respiratory tract irritation.

Indication of immediate medical attention and special treatment needed

Treatment: Symptoms may be delayed.

5. Fire-fighting measures

General Fire Hazards: No unusual fire or explosion hazards noted.

Suitable (and unsuitable) extinguishing media

Suitable extinguishing media:

Use fire-extinguishing media appropriate for surrounding materials.

Unsuitable extinguishing media:

Do not use water jet as an extinguisher, as this will spread the fire.

Specific hazards arising from

the chemical: During fire, gases hazardous to health may be formed.

Special protective equipment and precautions for firefighters


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Special fire fighting procedures:

No data available.

Special protective equipment for fire-fighters:

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

6. Accidental release measures

Personal precautions,

protective equipment and emergency procedures:

See Section 8 of the SDS for Personal Protective Equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep unauthorized personnel away.

Methods and material for

containment and cleaning up:

Collect spillage in containers, seal securely and deliver for disposal according to local regulations.

Notification Procedures: In the event of a spill or accidental release, notify relevant authorities in

accordance with all applicable regulations. Environmental Precautions: Do not contaminate water sources or sewer. Prevent further leakage or

spillage if safe to do so.

7. Handling and storage

Precautions for safe handling: Ventilate well, avoid breathing vapors. Use approved respirator if air

contamination is above accepted level. Use mechanical ventilation in case of handling which causes formation of dust. Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Use personal protective equipment as required. Do not get in eyes. Wash hands thoroughly after handling. Avoid contact with skin. Avoid contact with eyes, skin, and clothing.

Conditions for safe storage,

including any incompatibilities:

Store locked up.

8. Exposure controls/personal protection

Control Parameters

Occupational Exposure Limits

Chemical Identity type Exposure Limit Values Source

Portland cement - Respirable fraction.

TWA 1 mg/m3 US. ACGIH Threshold Limit Values (2011)

Portland cement - Total dust. PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006)


PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006)

Portland cement TWA 50 millions of particles per cubic foot of

air

US. OSHA Table Z-3 (29 CFR 1910.1000) (2000)

Crystalline Silica (Quartz)/ Silica Sand - Respirable fraction.

TWA 0.025 mg/m3 US. ACGIH Threshold Limit Values (2011)

Crystalline Silica (Quartz)/ PEL 0.05 mg/m3 US. OSHA Table Z-1 Limits for Air


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Silica Sand Contaminants (29 CFR 1910.1000) (03 2016)

Crystalline Silica (Quartz)/ Silica Sand - Respirable.

TWA 2.4 millions of particles

per cubic foot of air

US. OSHA Table Z-3 (29 CFR 1910.1000) (2000)

TWA 0.1 mg/m3 US. OSHA Table Z-3 (29 CFR 1910.1000) (2000)

Kaolin Clay - Respirable fraction.



Kaolin Clay - Total dust. PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006)

TWA 50 millions of particles per cubic foot of

air

US. OSHA Table Z-3 (29 CFR 1910.1000) (03 2016)



air


TWA 5 mg/m3 US. OSHA Table Z-3 (29 CFR 1910.1000) (03 2016)

Kaolin Clay - Total dust. TWA 15 mg/m3 US. OSHA Table Z-3 (29 CFR 1910.1000) (03 2016)

Gypsum (Calcium Sulfate) - Inhalable fraction.


Gypsum (Calcium Sulfate) - Total dust.


Gypsum (Calcium Sulfate) - Respirable fraction.





Calcium salt - Total REL 10 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2010)

Calcium salt - Respirable. REL 5 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2010)

Calcium salt - Total dust. TWA 15 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)

Calcium salt - Respirable fraction.

TWA 5 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)

Calcium salt - Total dust. TWA 15 mg/m3 US. Tennessee. OELs. Occupational Exposure Limits, Table Z1A (06 2008)


TWA 5 mg/m3 US. Tennessee. OELs. Occupational Exposure Limits, Table Z1A (06 2008)

Calcium salt AN ESL 5 µg/m3 US. Texas. Effects Screening Levels (Texas Commission on Environmental Quality) (03 2014)

ST ESL 50 µg/m3 US. Texas. Effects Screening Levels (Texas Commission on Environmental Quality) (03 2014)

Calcium salt - Inhalable fraction.


Calcium salt - Total dust. PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006)



Titanium dioxide TWA 10 mg/m3 US. ACGIH Threshold Limit Values (2011)

Titanium dioxide - Total dust. PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006)

Titanium dioxide - Respirable fraction.


air


Titanium dioxide - Total dust. TWA 15 mg/m3 US. OSHA Table Z-3 (29 CFR 1910.1000) (03


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2016)



Titanium dioxide - Total dust. TWA 50 millions of particles per cubic foot of

air


Ammonium Chloride - Fume. TWA 10 mg/m3 US. ACGIH Threshold Limit Values (2011)

STEL 20 mg/m3 US. ACGIH Threshold Limit Values (2011)

Ammonium Chloride - Total dust.


air


Ammonium Chloride - Respirable fraction.


air



Ammonium Chloride - Total dust.


Chemical name type Exposure Limit Values Source

Portland cement - Total dust. TWA 10 mg/m3 Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007)


TWA 3 mg/m3 Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007)


TWA 1 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (06 2015)

Portland cement - Total dust. TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) (12 2008)

Portland cement - Respirable dust.

TWA 5 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) (12 2008)


TWA 0.025 mg/m3 Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007)


TWA 0.10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (06 2015)

Crystalline Silica (Quartz)/ Silica Sand - Respirable dust.

TWA 0.1 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) (12 2008)

Kaolin Clay - Respirable. TWA 2 mg/m3 Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007)



Kaolin Clay - Respirable dust. TWA 5 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) (12 2008)


STEL 20 mg/m3 Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007)

TWA 10 mg/m3 Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances,


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Occupational Health and Safety Regulation 296/97, as amended) (07 2007)

Gypsum (Calcium Sulfate) - Respirable fraction.


Gypsum (Calcium Sulfate) - Inhalable


Gypsum (Calcium Sulfate) - Inhalable fraction.





Gypsum (Calcium Sulfate) - Respirable dust.



Calcium salt TWA 10 mg/m3 Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2) (07 2009)

Calcium salt - Inhalable TWA 10 mg/m3 Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007)

Calcium salt - Inhalable fraction.


Calcium salt - Total dust. TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) (12 2008)

Calcium salt - Respirable dust.


Titanium dioxide - Total dust. TWA 10 mg/m3 Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007)



Titanium dioxide TWA 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (11 2010)

Titanium dioxide - Total dust. TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) (12 2008)

Appropriate Engineering

Controls Mechanical ventilation or local exhaust ventilation may be required. Observe good industrial hygiene practices. Observe occupational exposure limits and minimize the risk of inhalation of dust.


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Individual protection measures, such as personal protective equipment

General information: Provide easy access to water supply and eye wash facilities. Good general

ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.

Eye/face protection: Wear a full-face respirator, if needed. Wear safety glasses with side shields

(or goggles) and a face shield.

Skin Protection Hand Protection: Use suitable protective gloves if risk of skin contact.

Other: Wear chemical-resistant gloves, footwear, and protective clothing

appropriate for the risk of exposure. Contact health and safety professional or manufacturer for specific information.

Respiratory Protection: In case of inadequate ventilation use suitable respirator. Seek advice from

local supervisor.

Hygiene measures: Observe good industrial hygiene practices. Wash hands before breaks and immediately after handling the product. Do not get in eyes. Wash contaminated clothing before reuse. Avoid contact with skin. Contaminated work clothing should not be allowed out of the workplace.

9. Physical and chemical properties

Appearance

Physical state: solid

Form: Powder

Color: Gray

Odor: Odorless

Odor threshold: No data available.

pH: No data available.

Melting point/freezing point: No data available.

Initial boiling point and boiling range: No data available.

Flash Point: No data available.

Evaporation rate: No data available.

Flammability (solid, gas): No

Upper/lower limit on flammability or explosive limits

Flammability limit - upper (%): No data available.

Flammability limit - lower (%): No data available.

Explosive limit - upper (%): No data available.

Explosive limit - lower (%): No data available.

Vapor pressure: No data available.

Vapor density: No data available.


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Relative density: 3.0

Solubility(ies)

Solubility in water: Miscible with water.

Solubility (other): No data available.

Partition coefficient (n-octanol/water): No data available.

Auto-ignition temperature: No data available.

Decomposition temperature: No data available.

Viscosity: No data available.

10. Stability and reactivity

Reactivity: No data available.

Chemical Stability: Material is stable under normal conditions. Possibility of hazardous

reactions: No data available.

Conditions to avoid: Avoid heat or contamination.

Incompatible Materials: No data available.

Hazardous Decomposition

Products: Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapors.

11. Toxicological information

Information on likely routes of exposure

Inhalation: In high concentrations, vapors, fumes or mists may irritate nose, throat and mucus membranes.

Skin Contact: Causes skin irritation. May cause an allergic skin reaction.

Eye contact: Causes serious eye damage.

Ingestion: May be ingested by accident. Ingestion may cause irritation and malaise.

Symptoms related to the physical, chemical and toxicological characteristics

Inhalation: No data available.

Skin Contact: No data available.

Eye contact: No data available.

Ingestion: No data available.


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Information on toxicological effects

Acute toxicity (list all possible routes of exposure)

Oral

Product: ATEmix: 12,277.17 mg/kg

Dermal Product: Not classified for acute toxicity based on available data.

Inhalation

Product:

Repeated dose toxicity Product: No data available.

Skin Corrosion/Irritation Product: No data available.

Serious Eye Damage/Eye Irritation

Product: No data available.

Respiratory or Skin Sensitization Product: No data available.

Carcinogenicity


IARC Monographs on the Evaluation of Carcinogenic Risks to Humans:

Crystalline Silica (Quartz)/ Silica Sand

Overall evaluation: Carcinogenic to humans.

Titanium dioxide Overall evaluation: Possibly carcinogenic to humans.

US. National Toxicology Program (NTP) Report on Carcinogens: Crystalline Silica (Quartz)/ Silica Sand

Known To Be Human Carcinogen.

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050):

No carcinogenic components identified


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Germ Cell Mutagenicity

In vitro


In vivo Product: No data available.

Reproductive toxicity


Specific Target Organ Toxicity - Single Exposure Product: No data available.

Specific Target Organ Toxicity - Repeated Exposure Product: No data available.

Target Organs Specific Target Organ Toxicity - Single Exposure: Respiratory tract irritation.

Aspiration Hazard


Other effects: No data available.

12. Ecological information

Ecotoxicity:

Acute hazards to the aquatic environment:

Fish Product: No data available.

Aquatic Invertebrates


Chronic hazards to the aquatic environment:

Fish Product: No data available.

Aquatic Invertebrates


Toxicity to Aquatic Plants Product: No data available.

Persistence and Degradability

Biodegradation


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BOD/COD Ratio Product: No data available.

Bioaccumulative potential

Bioconcentration Factor (BCF) Product: No data available.

Partition Coefficient n-octanol / water (log Kow)

Product: No data available. Mobility in soil: No data available.

Other adverse effects: No data available.

13. Disposal considerations

Disposal instructions: Dispose of waste at an appropriate treatment and disposal facility in

accordance with applicable laws and regulations, and product characteristics at time of disposal.

Contaminated Packaging: No data available.

14. Transport information

TDG:

Not Regulated

CFR / DOT: Not Regulated

IMDG: Not Regulated

15. Regulatory information

US Federal Regulations

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

None present or none present in regulated quantities.

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) None present or none present in regulated quantities.


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CERCLA Hazardous Substance List (40 CFR 302.4):

Chemical Identity Reportable quantity

Ammonium Chloride 5000 lbs.

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories

Immediate (Acute) Health Hazards Delayed (Chronic) Health Hazard

SARA 302 Extremely Hazardous Substance


SARA 304 Emergency Release Notification Chemical Identity Reportable quantity Ammonium Chloride 5000 lbs.

SARA 311/312 Hazardous Chemical Chemical Identity Threshold Planning Quantity

Portland cement 10000 lbs Crystalline Silica (Quartz)/ Silica Sand

10000 lbs

Kaolin Clay 10000 lbs Gypsum (Calcium Sulfate) 10000 lbs Calcium salt 10000 lbs Titanium dioxide 10000 lbs Ammonium Chloride 10000 lbs

SARA 313 (TRI Reporting)


Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) None present or none present in regulated quantities.

Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3)

None present or none present in regulated quantities. US State Regulations

US. California Proposition 65 This product contains chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm. Crystalline Silica (Quartz)/ Silica Sand

Carcinogenic. 09 2011

Titanium dioxide Carcinogenic. 09 2011

US. New Jersey Worker and Community Right-to-Know Act

Chemical Identity Portland cement Crystalline Silica (Quartz)/ Silica Sand Kaolin Clay Gypsum (Calcium Sulfate) Calcium salt


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US. Massachusetts RTK - Substance List

Chemical Identity

Portland cement Crystalline Silica (Quartz)/ Silica Sand Kaolin Clay Gypsum (Calcium Sulfate) Calcium salt

US. Pennsylvania RTK - Hazardous Substances

Chemical Identity Portland cement Crystalline Silica (Quartz)/ Silica Sand Kaolin Clay Gypsum (Calcium Sulfate) Calcium salt

US. Rhode Island RTK

Chemical Identity Portland cement Crystalline Silica (Quartz)/ Silica Sand Kaolin Clay

International regulations

Montreal protocol

not applicable

Stockholm convention

not applicable

Rotterdam convention

not applicable

Kyoto protocol not applicable

VOC: Regulatory VOC (less water and exempt solvent)

: 0 g/l

VOC Method 310 : 0.00 %


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Inventory Status:

Australia AICS: All components in this product are listed on or exempt from the Inventory.

EINECS, ELINCS or NLP: One or more components in this product are

not listed on or exempt from the Inventory.

Japan (ENCS) List: One or more components in this product are


China Inv. Existing Chemical Substances: All components in this product are listed on or

exempt from the Inventory.

Korea Existing Chemicals Inv. (KECI): One or more components in this product are


Canada NDSL Inventory: One or more components in this product are


Philippines PICCS: One or more components in this product are


New Zealand Inventory of Chemicals: All components in this product are listed on or


Japan ISHL Listing: One or more components in this product are


Japan Pharmacopoeia Listing: One or more components in this product are


Canada DSL Inventory List: All components in this product are listed on or


US TSCA Inventory: All components in this product are listed on or


16.Other information, including date of preparation or last revision

Revision Date: 01/30/2017

Version #: 2.0

Further Information: No data available.


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16/16

Disclaimer: For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the consideration of the user, subject to their own investigation of compliance with applicable regulations, including the safe use of the product under every foreseeable condition.

MATERIAL SAFETY DATA SHEET REV. DATE 6/23/04

QUICK IDENTIFIER: WATER-BASE PIPE & FITTING COATING

MANUFACTURER’S NAME: PROFESSIONAL COATING TECHNOLOGIES, INC. (P.C.T.) ADDRESS: 1001 MT. LEBANON RD.

CEDAR HILL, TX 75104 EMERGENCY 24 HR. TELEPHONE NUMBER: (972) 291-7474

OTHER INFORMATION CALLS: (972) 291-7474

SECTION 1 - IDENTIFY

TRADE NAME AND SYNONYMS: MPFC-D 8 C.A.S. NUMBER: NONE, MIXTURE

CHEMICAL NAME: EMULSIFIED ASPHALT CHEMICAL FAMILY: PETROLEUM HYDROCARBON

FORMULA: VARIABLE MIXTURE

SECTION 2 - INGREDIENTS

PRINCIPAL HAZARDOUS COMPONENTS % THRESHOLD LIMIT VALUE

(CHEMICAL & COMMON NAMES) (UNITS) NONE KNOWN

OTHER INGREDIENTS ASPHALT, PETROLEUM 008052-42-4 50-62 5.00 mg/m 3 PETROLEUM DISTILLATE LESS THAN . 9lb.per gal

SECTION 3 - PHYSICAL & CHEMICAL CHARACTERISTICS

BOILING POINT: 212 DEG. F. SPECIFIC GRAVITY (H20-1.00):1.02 VAPOR PRESSURE (mmHg): N/D VAPOR DENSITY (AIR @ 1): > 1

PERCENT SOLVENT BY VOLUME: <6% EVAP. RATE (H20 = 1.00): ND APPEARANCE AND ODOR: LOW VISCOSITY, SMOOTH BROWN LIQUID, SLIGHT PETROLEUM ODOR

SECTION 4 - FIRE AND EXPLOSION

FLASH POINT: N/A IN EMULSION STATE AUTO IGNITION TEMP: N/A FLAMMABLE LIMITS IN AIR % BY VOLUME: LOWER: N/A UPPER: N/A

EXTINGUISHER MEDIA: NON-FLAMMABLE IN EMULSION STATE *NOTE* IN ASPHALT STATE: SMALL FIRES USE DRY CHEMICAL, CO2, HALON, WATER SPRAY OR STANDARD FOAM. LARGE

FIRES USE WATER SPRAY, FOG OR STANDARD FOAM. (1987 EMERGENCY RESPONSE GUIDEBOOK, D.O.T. P5800.4 GUIDE NO. 27)

SPECIAL FIRE FIGHTING PROCEDURES: NON-FLAMMABLE IN EMULSION STATE. *NOTE* IN ASPHALT STATE: MOVE VESSEL FROM FIRE AREA IF YOU CAN DO IT WITHOUT RISK. COOL CONTAINERS

THAT ARE EXPOSED TO FLAMES WITH WATER FROM THE SIDE UNTIL WELL AFTER THE FIRE IS OUT. STAY AWAY FROM ENDS OF TANK. FOR MASSIVE FIRE IN CARGO AREA, USE UNMANNED HOSE HOLDER OR MONITOR NOZZLES; IF THIS IS IMPOSSIBLE, WITHDRAW FROM AREA AND LET FIRE BURN. WITHDRAW IMMEDIATELY IN CASE OF RISING SOUND FROM VENTING SAFETY DEVICE OR ANY DISCOLORATION OF TANK DUE TO FIRE.(1987 EMERGENCY RESPONSE GUIDEBOOK,

D.O.T. P5800.4 GUIDE NO. 27)

SECTION 5 - PHYSICAL HAZARDS

MATERIAL IS: STABLE CONDITIONS TO AVOID: NONE

INCOMPATIBILITY (MATERIALS TO AVOID): NONE HAZARDOUS POLYMERIZATION WILL: NOT OCCUR

_____________________________________________________

SECTION 6 - HEALTH HAZARDS

CHEMICAL LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN.

ASPHALT EMULSIONS HAVE NOT BEEN INVESTIGATED AS POSSIBLE CARCINOGENS. PETROLEUM ASPHALT WOULD BE AS

FOLLOWS: NAT. TOXICOLOGY PROGRAM NO OSHA YES

I.A.R.C. *UNDETERMINED

*EXPLANATION: IARC MONOGRAPHS - JAN. 1985 - THE STUDY INDICATES THERE IS SUFFICIENT EVIDENCE FOR

CARCINOGENICITY IN ANIMALS FROM EXPOSURE TO EXTRACTS OF STEAM-REFINED BITUMENS, AIR-REFINED BITUMENS AND

MIXTURES OF STEAM-REFINED AND AIR-DEFINED BITUMENS. DUE TO INADEQUATE EVIDENCE IN HUMANS, BUT SUFFICIENT EVIDENCE IN ANIMALS, BITUMEN IS CONSIDERED BY OSHA AS IF IT PRESENTS A CARCINOGENIC RISK TO HUMANS. THERE

IS INADEQUATE EVIDENCE THAT BITUMENS ALONE ARE CARCINOGENIC TO HUMANS.

OSHA PERMISSIBLE EXPOSURE LIMIT: N/A FOR EMULSION (ASPHALT FUMES: 5mg/m3 MAX CEILING) ACGIH THRESHOLD LIMIT VALUE: N/A FOR EMULSION (ASPHALT FUMES: 5mg/m3 TWA)

OTHER EXPOSURE LIMIT USED: NONE ROUTES OF EXPOSURE: PRIMARY - SKIN CONTACT

SECONDARY - INGESTION OR INHALATION SIGNS AND SYMPTOMS OF EXPOSURE: SKIN - CONTACT WITH HOT PRODUCT MAY CAUSE THERMAL BURNS. PROLONGED

OR REPEATED CONTACT WITH COOL PRODUCT MAY CAUSE IRRITATION. ASPHALT EMULSIONS HAVE NOT BEEN INVESTIGATED FOR POSSIBLE CARCINOGENICITY.

INGESTION - EMULSIONS MAY CAUSE NAUSEA AND IRRITATION OF GASTROINTESTINAL TRACT. INHALATION - EXCESSIVE EXPOSURE TO FUMES, VAPORS OR MISTS MAY CAUSE SOME RESPIRATORY DISCOMFORT OF THE

MUCOUS MEMBRANES. ASPHALT, WHEN HEATED, RELEASES VARIOUS CONCENTRATIONS OF HYDROGEN SULFIDE (H2S) GAS. H2S IS AN EXTREMELY TOXIC AND FLAMMABLE GAS THAT AT LOW CONCENTRATIONS IS IRRITATING TO THE

RESPIRATORY TRACT AND HAS A ROTTEN EGG ODOR. ODOR CAN NOT BE RELIED ON AS A MEANS OF DETECTION BECAUSE AT HIGHER CONCENTRATIONS OF 500 - 1000 ppm MAY LEAD TO UNCONSCIOUS, RESPIRATORY PARALYSIS AND DEATH.

EMERGENCY AND FIRST AID PROCEDURES: INHALATION - IF OVEREXPOSURE OCCURS, REMOVE INDIVIDUAL TO FRESH AIR. IF DISCOMFORT CONTINUES, SEEK MEDICAL ATTENTION.

EYES - FLUSH EYES IMMEDIATELY WITH COPIOUS AMOUNTS OF WATER AT LEAST 15 MINUTES OCCASIONALLY LIFTING THE UPPER AND LOWER EYE LIDS. GET MEDICAL ATTENTION IMMEDIATELY.

SKIN - HOT PRODUCT SHOULD BE COOLED WITH WATER. CLEAN SKIN WATERLESS TYPE HAND CLEANER FOLLOWED BY SOAP AND WATER. IF IRRITATION OR BURN DEVELOPS, SEEK MEDICAL ATTENTION. COOL PRODUCT MAY BE CLEANED

WITH WATERLESS TYPE HAND CLEANER. INGESTION: IF MATERIAL IS SWALLOWED, DO NOT INDUCE VOMITING. TREAT SYMPTOMATICALLY AND GET MEDICAL

ATTENTION. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: UNKNOWN

SECTION 7 - SPECIAL PROTECTION INFORMATION

RESPIRATORY PROTECTION: NORMALLY NOT NEEDED, BUT IF CONDITIONS WARRANT USE ORGANIC VAPOR RESPIRATORS. VENTILATION LOCAL EXHAUST: AS NEEDED TO REMOVE MISTS OR VAPORS.

PROTECTIVE GLOVES: IMPERVIOUS COATING EYE PROTECTION: CHEMICAL GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS.

OTHER PROTECTIVE CLOTHING OR EQUIPMENT: APPROPRIATE CLOTHING TO PREVENT REPEATED OR PROLONGED

CONTACT WITH SKIN.

SECTION 8 - SPECIAL PRECAUTIONS AND SPILL/LEAK PROCEDURES

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: AVOID HEATED PRODUCT FUMES. OTHER PRECAUTIONS: OBSERVE GOOD PERSONAL HYGIENE. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. DO

NOT WEAR LEATHER SHOES OR BOOTS THAT HAVE BECOME SATURATED WITH PRODUCT.

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: CREATE DIKES OR PONDS AS SOON AS POSSIBLE. USE EARTH, SAWDUST OR SAND TO MAKE DIKES OR TO USE AS ABSORBENT. UPON ABSORPTION, MATERIAL WILL REVERT

TO ASPHALT STATE AND CAN BE REMOVED WITH ABSORPTION MATERIAL. WASTE DISPOSAL METHODS: EMULSION CAN BE MIXED WITH ANY STABILIZING MATTER (e.g., ROCK, GRAVEL OR SAND) IN

ORDER TO CHANGE ITS STATE FROM A LIQUID INTO A SOLID. THIS MATERIAL CAN THEN BE DISPOSED OF AT AN APPROVED LANDFILL

EXPLANATION OF ABBREVIATIONS: N/D - NOT DETERMINED: N/A - NOT APPLICABLE: TLV - THRESHOLD LIMIT VALUE :

TWA - TIME WEIGHTED AVERAGE

P.C.T. DISCLAIMER OF LIABILITY

THE INFORMATION IN THIS MSDS WAS OBTAINED FROM SOURCES WHICH WE BELIEVE ARE RELIABLE. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY REPRESENTATION OR WARRANTY, EXPRESS OR IMPLIED, REGARDING ITS ACCURACY OR CORRECTNESS. THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE AND DISPOSAL OF THE

PRODUCT BY OTHERS ARE BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME ANY RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH THE HANDLING, STORAGE, USE OR DISPOSAL OF THE

PRODUCT. NOTE THAT SOME MATERIAL IDENTIFIERS MAY OR MAY NOT CONTAIN HYPHENS. A MATERIAL NAME THAT DOES NO CONTAIN A HYPHEN SHOULD BE CONSIDERED THE SAME AS THE NAME WITH A HYPHEN.

section ii...section ii common trade name manufacturer/supplier name abs pipe & fittings...

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