scientific notebook no. 864: radionuclide transport in the ... · this scientific notebook (sn) is...

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LABORATORY NOTEBOOK

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- TABLE OF CONTENTS

22 Afl&w2Z.o'd7 - BOOK

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TITLE

This notebook contains work for Radionuclide Transport in both the saturated zone and - -

concerned with identification of key geochemical processes that may control radionuclide -

hydrochemistry and mineralogy along the groundwater flow paths from the proposed - repository. Typical activities associated with these investigatlons would include

I unsaturated zone (ISIs 20.06002.02.242 and 20.06002.01.232 respectively). RT is

transport at Yucca Mountain. Radionuclide retardation is dependent on the

~ _ I _

~ - 1 -

PROJECT

Current experimental activities are fccused on laboratory batch sorption experiments that -~ incorporate materials (groundwater and sonic corings) from the Yucca Mountain region and materials (simulated groundwater) based on the chemistry of the Yucca Mountain region materials. The objective for the sorption experiment is to determine the sorption capability (Kd or sorption coefficient) for a particular radionuclide, solid material and solution typically over a range of pH values. Tasks typically include the following:

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~- bnontfnuuj Ftum Page

Initial Entry for Scientific Notebook 864 . . -

- Preparation of reference solutions ___

Preparation of experimental solutions

Cation (Div 01), inorganic carbon (GED) and pH analyses (GED) ofreference solutions

Liquid Scintillation Analyses (GED) of experimental solutions

__

__. Further details of these tasks are recorded in initial and in-process entries. _______-

-_ This scientific notebook (SN) is a continuation of SN 836. That notebook concludes with Div 01 chemistry results for 22PC Intervals used to Compose 22PC Sonic Core Composite.

__ ~ _ _ _ 30k---------

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PROJECT

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Continued To Page

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Z~,Ed&+& DISCLOSED TO AND UNDERSTOOD BY

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PROJECT

SOUTHWEST RESEARCH INSTITUTE SAMPLE ANALYSIS DATA SHEET

__ Sample ID

E 22PC-IC 1 Lab Name: Southwest Research Institute Client: Division 20

LabCode: SwRl Date Received: 02/12/07

Matrix: Water Projsct No.: 06002.01.242

Lab SystemID: 293151 SRR: 30363

Method: 6010B MOD, 6020 MOD Task Order: 0702 13-4

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PROJECT X ” .- - -


- - -

Sample ID 7 22PC-2c -J Client: Dnwsion 20

Date Received: 02/12/07

Rojea No.: 06002.01.242

SRR: 30363

Task Order: 07021 3-4 ]Method: 6010B MOD, 6020 MOD

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TITLE PROJECT

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Lab Name: Southwest Research Institute Client: Division 20

LabCode: SwRl Date R.eceived: 02/12/07

Matrix: Water Project No.: 06002.01.242

Lab System ID: 293 157

Method: 6010B MOD, 6020 MOD

SRR: 30363

Task Order: 0702134

- 6 BoOK PAGE

n M PROJECT


Sample ID

I 22PC-4C I Lab Name: S ~ ~ t h w t s t Research Institute

Labcode: SWRl

Matrix: Water



Client: Division 20


Project No.: 06002.01.242

SRR: 30363

Task Order: 070213-4

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TITLE

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PRn. IFCT 1

SOUTHWEST RESEARCH INSTITUTE

i SAMPLE ANALYSIS DATA SHEET Sample ID

c Client: Division 20 Lab Name: Southwest Research Institute

LabCode: SwKl

Matrix: Water


Method: 6010H MOD, 6020 MOD

Date Received 02/12/07

Ptoject No.: 06002.01.242

SRFt 30363


Reporting I r

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SIGNATURE

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T I T U PROJECT

SOUTHWEST RESEARCH INSTITUTE SAMPLE ANALYSIS DATA SHEE'T

Sample ID 22PC-6C -1 I

Client: Division 20 Lab N m : Southwest Research Institute

Labcode: SwRl Date Received 02/12/07

Matrix: Water Roject No.: 06002.01.242



SRR: 30363

Task Order: 07021 3 4

Condinucd To .................... ...

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SIGNATURE I DATE

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- 9 BOOK PAGE

SOUTHWEST RESEARCH INSTITUTE SAMPLE ANALYSIS DA.TA SHEET

Lab Name: Southwest Research Institute

LabCode: SwFU

Matrix: Water



Sample ID E 22PC-7c I Client: Division 20

Date A.eceived: 02/12/07

Project No.: 06002.01.242

SRR: 30363

Task Order: 0702 1 3 4

I I SamuIe I Reporting I

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-Tungsten <0.100 0.1 Uranium .rl .oo 1 Vanadium <0.0500 0.05 Yttrium <0.0500 0.05 Zinc <0.0500 0.05 Zirconium -4.0500 0.05

-- - 10 BOOK PAGE

TITLE

- Conthud To p.0. SKUlATulll 1 DATE

. ! & r n f i r d ~ ’ ............... ... 5w.

PROJECT


Sample ID

I 22PC-8C -1 Lab Name: southwest Research Institute

Labcode: SwRl Date Received: 02/12/07



Method: 601 OB MOD, 6020 MOD

Client: Division 20

SRR 30363


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TITLE BOOK

PROJECT


Sample ID 22PC-9c 1

Lab Name: Southwest Research Institute Client: I3ivision 20

LabCode: SwRl Date Received: 02/12/07

Matrix: Water


Project No.: 06002.01 242

SRR: 30363

Method: 60 1 OB MOD, 6020 MOD Task Order 070213-4

I Reporting I

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Continued To Page -- ........ -... ...... ...-.. .... -... ...................... .... ............ -. ......................... ..._. ...... ______ 3lGNATURE I DATE

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T1Tl.S PROJECT


Lab Name: SO~thwest Research Institute

Labcode: SWRI

Matrix: Water

Sample ID

I 22PC-1oc I Client: 13ivision 20

Date Received: OW1 2/07

Project No.: 06002.01.242

Lab System ID: 293131


SRR: 30363


___ .- - 1 Continued To Peg# SlGNATlJRE DATE ;

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___ SOUTHWEST RESEARCH INSTITUTE - __ SAMPLE ANALYSIS DATA SHEET

Sample ID 1- 22PC-llC I _- _. Lab Name: Southwest Research Institute

LabCode: SwRl -

Client: )Division 20


__ Matrix: Watn



___

__

Project No.: 06002.01.242

SRR: 30363

Task Orda: 070213-4

_.___ - _______ CtmtinW To Page

.............. ... SIGN% e&b I DATE

DISCLOSED TO AND UNDERSTOOD BY ....... ........................................................... ............. ................ ! / .. Jd .- <MdVg? ..........

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TITLO PRhISPT h - - SOUTHWEST RESEARCH INSTITUTE - - SAMPLE ANALYSIS DATA SHEET

- - LA Name: S o ~ t h ~ e s t Research Institute

- 11code: S W R l

- M x : Water

- LabSystemID: 293135

- Method. 6010B MOD, 6020 MOD

-

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Sample ID 22PC-12c -J

Client: Division 20


Project No.: 06002.01.242

SRR: 30363

Task Ordm: 0702 1 3-4

Conbhued To Page ... ....... ....... .......................... - ......... SIGNNURE : DATE

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PROJECT TITLE Contmuc F SOUTHWEST RESEARCH INSTITUTE -1

BOOK PAGE

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SAMPLE ANALYSIS DATA SHEET ._. _-


LabCode: SwRl

~ Matnx: Water

Sample ID

22PC-13c I Client: Division 20

Date IReceived: 02/12/07

Project No.: 06002.01.242



SRR: 30363

Task (Order: 0702 13-4

I I Sample I Reporting 1 15

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Analysis 1 Result (mg/L) I Limit (mg/L) Aluminum I <0.500 I 0.5

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TITLEI PROJECT IccnB


Sample ID

E 22Pc-14c-J

Name: southwest Research Institute Client: Division 20

Date Received 021 207 Labcode: SwRI




SRK: 30363


<0.0500 <0.0500

CondkrW To Page

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PROJECT

SOUTHWEST RESEARCH INSTITUTE SAMPLE, ANALYSIS DATA SHEEiT

Sample ID 1- 22PC-15C I Client: Division 20


Project No.: 06002.01.242

SRR: 30363

Task Order: 0702 13-4


LabCode: SwRl

Matrix: Water

Lab System ID: 291 1 4 1


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TITLE PROJECT


Sample ID

E 22PC-16C -1 Lab Name: Southwest Research Institute

Labcode: SwRI

Matrix: Water



Client: Division 20

Date Received 02/12/07

Project No.: 06002.01 2.42

SRR: 30363

Task. Order: 07021 3 4

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SOUTH WEST RESEARCH INSTITUTE SAMPLE ANALYSIS DATA SHEET


LabCode: SwRl

Matrix: Water



Client: Division 20

Date Received: OW1 2/07

Project No.: 06002.01.242

SRR: 30363


Analysis I Result ( m a ) I Limit ( m a ) Aluminum I c0.500 I 0.5

WII”,,””” .” ”.- Dnnr tn &.)A --.__.__ -

SIGNATURE --I ~*-E

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Tl7I.B PROJECT

__ SOUTH WEST RESEARCH INSTITUTE SAMPLE ANALYSIS DATA SHE;ET __

Lab N m : Southwest Research Institute

Sample ID ~

1 - I 22PC-18C

Client: Division 20 -

Labcode: SwRI Data Received: 02/12/07

Matrix: Water Project No.: 06002.01

Lab S e e m ID: 293 147


SRR.: 30363


Selenium <0.0500 Silicon Silver <0.0500 Sodium Strontium

'Thallium Thorium <O. 150 0.15 Tin <n nsnn n ns

9.75

Titanium <0.0500 0.05 Tungsten <o. loo 0.1 Uranium <1.00 1 Vanadium <n nsnn n ns Yttrium <0.0500 0.05 Zinc <0.0500 0.05 ,Zirconium <0.0500 0.05

242

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BOOK

TITLE PROJECT

SOUTH WEST RESEARCH INSTITUTE -

SAMPLE ANALYSIS DATA SHEET

- - Lab Name: Southwest Research Institute

LabCode: SwRl - -

- Matrix: Water

-. Lab System ID: 293 149


- --

Sample ID I 22PC- 1 9 c 1 Client: Division 20


Project No.: 06002.01.242

SRR: 30363

Task Order 0702 1 3-4

PAGE

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TITLE PROJECT

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SOUTHWEST RESEARCH INSTITUTE SAMPLE ANALYSIS DATA SHE:ET


LabCode: SwRl

Matrix: Water



Sample ID E 22Pc-2oc -1 Client: Division 20

Date Received: OU12/0;r

project No.: 06002.01 .;!42

SRR: 30363

Task Order. 07021 3-4

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= I 23 BOOK PAGE

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SOUTHWEST RESEARCH INSTlTUTE LABORATORY CONTROL SAMPLE

Sample ID i LCS 1 Client: Division 20

Date Received: NA


Labcode: SwRl


Lab System ID: NA


SRR: 30363

Task Order: 07021 3 4

wiiuiiuw iu roue . t . \I^. A-l:....Ll..

- 24 BOOK PAGE

TITLE PROJECT

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SOUTHWEST RESEARCH INSTITUTE -

BLANK SUMMARY - Sample ID

i PB 1 Lab Name: Southwest Research Institute Client: Division 20

LabCode: SwRl Date :Received: NA

Matrix: Water

LabSystemID: NA

Method: 60 I OB MOD, 6020 MOD

I Reporting I

Project No.: 06002.01.242

SRR: 30363

Task Order: 0702134

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TITLE PROJECT


LabCode: SwRl

Matrix: Water

LabSystemID: 2931318

Method: 60108 MOD, 6020 MOD

SOUTHWEST RESEARCH INSTITUTE MATRIX SPIKE SUMMARY

~

Sample ID ___ I 22PC-1oc

Client: Division 20


Project No.: 06002.01.242

SRR: 30363

Task Chder: 07021 3 4

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TITLE PROJECT

SOUTHWEST RESEARCH INSTITUTE - DUPLICATE SUMMARY

- Lab Name: Southwest Research Institute

- Labcode: SWN

Matrix: Water

Sample ID I 22PC-1oc

Client: Division 20

Date Receive& 02/1 2/07

Project No.: 06002.01.242

- LabSystemID: 2931311) -


SRR: 30363

Task Order: 0702134

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-8 27 BOOK PAGE

Potassium Calcium Sodium Silicon Maanesiurn

TITLE PROJECT

<0.250 19.9 '99.5

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- 16.7 20.4 . :j! I 'Potassium 17.5

Calcium 20.5 S o d i U . 17.8 17.7 Silicon e0.250 c0.250 Magnesium 19.9 20

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Normal' QA Standard

Table Comparing Cation Target and Div 01 Results for Blind QA Standard 22PC-IC

Species Target Conc

I (glmL)

Sourlce for target conc:: 836132 Sourlce for Div 01 results: 836/133

Table Comparing Cation Target and Div 01 Results for Blind QA Standard 22PC-2C

Species Target Conc Div 01 Conc Percent (glmL) (mglL) Recovery

I I

Source for target conc:: 836132 Sourlce for Div 01 results: 83611 33

Table Comparing Cation Div 01 Results of Duplicate Blind Standards 22PC-1 C and 22PC-2C

Species QA-Cation1 QA-Cation2 Percent Conc (mg/L) Conc (mg1L) Difference

Continued To Paoe

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Potassium 1.83 Calcium 15.30

45.9 Sodium .I---

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TITLE

- 1.95 ’ 6.6 15.30 0.0 45.1 -1.7 -

PROJECT

Silicon 11.3 11.3 -- Magnesium 1.02 j 1.01

Specfic Conc. QA Standard

0.0 -1 .o

.

........

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Species Target Conc Div 01 Conc Percent (g/mL) (mg/L) Recovery

I I I I I I lpotassium t 9 4 QQ I n I

I

ISiIicon I 10 I 11.3 1 113.0 I I I 1.02 I 102.0 I

Source for target conc: 836135 Source for Div 01 results: 83611 33


Species Target Conc Div 01 Conc Percent (g/mL) (mglL) Recovery

I I I Potassium Calcium 15.30 102.0 Sodium Silicon 11.3 113.0

Table Comparing Cation Div 01 Results of Duplicate Blind Standards 22PC-19C and 22PC-20C

Species QA-Cation1 QA-Cation2 Percent Conc (mg/L) Conc (mg/L) Difference

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Experiments

19PB and 22PC with and without Calcium Sorption Experimental Solutions Series 0

SN: 742 / 64-80 Np 237 61A-1 (3691100)

19 CAL Series 1 and 22 CAI, Series 1 with and without Calcite Sorption Experiments .- Np-237 on Consolidated Alluvium with 19PB Simulated Waters with Calcium over a pH range

SN: 800 / 14-46 Np Spike # 61A-1 (369/100)

19 CAL Series 2 and 22 CAI, Series 2 with and without Calcite Sorption Experiments - Np-237 on Consolidated Alluvium with 19PB Simulated Waters with Calcium over a pH range

SN: 81 1 / 2-26 Np Spike # 61A-2 (369//63 )

19PB and 22PC with and without Calcite Sorption Experiments .- Testing Repeatability of pH Targets using Np-237 on Consolidated Alluvium with 19PB Simulated Waters with Calcium

SN: 811 / 51-76 Np Spike # 61A-1 (369/100) and Np Spike # 61A (369195)

19PB and 22PC with and without Calcite Sorption Experiments -Using Np-237 on Consolidated Alluvium with 19PB Simulated Waters with Calcium Phase 2: Adjusting Initial Reference Solution pH 45

SN: 811 / 78- Np Spike # 61A (369/ 95)

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- __ - 0 19PB Intervals Comprising 19PB Sonic Core Composite - Np-237 on Consolidated - - Alluvium with 19PB Simulated Waters with Calcium over a :single pH -

SN: 836 12- 31 Np Spike # 61A (369195)

- 0 22PC Intervals Comprising 22PC Sonic Core Composite - Np-237 on Consolidated

Alluvium with 19PB Simulated Waters (19PB-5) over a single pH - - r

SN: 836 142- 77 Np Spike # 61A (369/95)

Continued To Page ...._.._.._......__-_.--..-.-....-i-.__---.-.._ I_

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OA PRXSSS:

Internal analytical ‘Itpndardr’ ne submmed as Mind saw *in the saw group. No k m XRD Standards are aVallaMe for complex mineral assemblages. Pnnrious XRD a n a w l results ham been critically examinad for quality acceptance by inspedion of results of indudad prepared standards with a known n\inaralmmpwitionshnilarb~ expected in the u n k m samples. The internal standards m e prepared using mineral standards with known chemical composition that had also been independently snam using XRD. Qusntitative mineral content was avaluated by mixing measured mass fradbm of several knorm mineral phases to create a known internal standard and by using resulk of previous XRD results of complex mineral mixtures lo examine ratios of measured charadehtic peaks of phases. Fw thk group of u n k m samples. the expected mineral compoeitii of the is not consistent with the available mineral phases used to emate a k m krtsmal standard. lndusbn of standards with mineral composltii (fenomagnesian silicates) awpeded in the samples is highly desired. Therefom. a new basalt rack pwdw standard will be generated for use in evaluating the quality of the XRD analyses. Thk new standard is aeated by aust-dng a basalt rock sample and independently analyzhg its mineral composition by XRD. The independent XRD pattern of the basalt sample along with a separate previously analyred complex mineral bemlcal standard (NBS 99a -sodium feldspar) will then be used in the CIA aaeptance evaluation.

For this analysts. QA accaptance criteria indude:

1. lnspedion of XRD patterns of standards to insure identifmlion of maim minerals cwnprising the standards. The XRD patterns of the standards should be compared to independently or previously produced XRD patlerns to insure consistency in the major mineral charadeW Peak.

2. Qualitative agreemant of peak pmpwtions. Charactefistic peak he!ghts and peak ra th ot the major minerals (e.g.. divine) in the known standards in the Independent XRD patterns should be similar to those in the XRD patterns of the known slamlards provided by the suppbr.

3. Quantitative resub of mharal content of the NBS 99a standard should be within 5% (fa each phase) ofthe mineral content identifii in previous quantitative XRD analyses of NBS 99a

4. Bulk XRD rewlts for the unknown samples should be checked to ensure lhat the major minerals Mentifisd in the samples are condstent with the daracteristic mineral peaks r e p m t e d in the XRD pattern. Jade software at CNWRA shouM be used to load the nsw pattern pmvided by the supplier to facilitate this beck.

characteristic peaks md tha pm8ana d pmvider intoma! standefd peaks (4).

-1

5. Results of theGbyfrectionmalyses rhaw be chedted benwre pcoperloclltioli of

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TITLE PROJECT

Sampk Prepration Samples submitted for whole-mck and clay-tiaction XRD m i d analyses M fm clesnad d obvious drilling contaminants and Ihm disaggregated in a mat.r and p e s k Appmximately fiw gram of each sample M transfcmd to isalnopyl alcohol and pulverized using a McCraPl micronizing mill. % rwul~ant powders uc dried, disaggmgatcd. and packed into aluminum sample holdas to produce random whok-rcrk mounts. A s e p ~ ~ t e split of each samph i~ dispersed in a dilute sodium phosphrce solution using a m i c probe. The suspensions are *a centrifugally size-fractionated to isolate clay-size (<4 micron ESD) materials for a sepsnte clay- fraction mount. The suspensions M then vacuumdeposiIed on silver mmhranc fillen I pmdufe oriented clay minml aggregates. Memhrane m n t s are attached to stainless steel r lup and exposed IO ethyletu glycol vapor for a minimum of 24 hours.

A u l y t i u l Roeedum XRD analyses of the samples m performed utilizing a Scintag or Philip automated poardr diffractomter equipped with a coppcr source (4OkV. 4OmA) and a d i d state or scintill.tioa detector. The whole ruck samples M analyzed over an angular range of 2-60 degrees 24heta u a swn rate of OM degrrelminute. The glycol-solvated clay-fraction m n t s are analyzed over M angular range of 2-50 degrees 2-theta at a rate of 1.5 degrecdminute.

Semiquantitative determinations of whole-rock and phylloailicate mincral amounts M' dom utilizing integrated peak press (derived from peakdecomposition I profile-fitting mehds) ud empirical reference intensity rauo (RIR) factors determined specifically for the diffractotma used in data collection. The toul clay mineral (including mica) abundmc of each sanlpb is duanined from the whole-mck XRD patterns using combined (001) and (hw] clay n i d d k c t i o n s and suimblc: empirical RIR factors.

XRD patterns from glycol-solvated clay-fraction samples are poalyzed using techniquea simila m thcw described above. Determinations of mixed-layer clay ordering and expandability m dom by comparing experimental diffraction dun from the glycol-solvated clay mineral aggregates with simulated one dimensional diffraction profiks generated using the program NEWMOD wrioar by R.C. Reynolds.

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PROJECT - TITLE ........ .................................... .- ............ ............................................................................... .___

Continued fmn, peg.

.............. ...____

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I O

15

Consolidation of Experimental Solutions Returned for Div 01 .

- ~ _ _

.........

____--

__ ...........

..................... -

Personnel Involved: Marla Roberts __

Procedure: samples returned by Division 01 are combined into a large HDPE waste - storage container. This container is labeled Np Waste 3.

The following experimental solutions are involved: --

0 @ @

NC-EWDP-19PB and 22PC With and Without Calcite (742/45)

19PB Intervals Comprising 19PB Sonic Core Composite (836/2)

22PC Intervals Comprising 22PC Composite (836/42)

. . . . . . . . ............................................................................

............................................................................................................................................................ ................................................... ._ ..............................................................................

___ - __-- 30

............. .......... ............ .............................................................. .......................................

---I--_____ __ ___.__

~ _ _ _ _ _

............................................................................................ - .............................. ^ .......... 35

... ~

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.-----1_--

... .... _-- . ......... ~ __

451. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . \ ....................................... --__ .. . __ ............................. _-_- __-_____ .... - __-___

Continued To Page

SIGNATURE DATE

DISCLOSED TO AND UNDERSTOOD BY DATE r F - 6 It I AHY

._

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'. 57 BOOK PAGE

TITLE PROJECT

5

10

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45

Conlinued F m Page _____-_ ____ _- - .___ Preparation for Aliquots from September 2007 NC-EWDP Groundwater Samples for Div -

--.01 Cation and Anion Analyses -

Task Initially Assigned To: Marla Roberts

Sample Collection: 333/ -

-_ . Background: In the field groundwater samples were collected directly from the well line due to _

___ the slow pumping rate. For filtered samples a 0.45pm pore size filter was attached directly to the - ____ well line (see 33#3/ for specifics on sampling parameters and conditions). __ __

Samples: - _ _ NC-EWDP-32P Intermediate-0907-FA NC-EWDP-32P Intermediate-0907-FUA NC-EWDP-32P Intermediate-0907-UFUA MC-EWDP-32P Deep-0907-FA NC-EWDP-32P Deep-0907-FUA NC-EWDP-32P Deep-0907-UFUA NC-EWDP-33P Intermediate-0907-FA NC-EWDP-33P Intermediate-0907-FUA NC-EWDP-33P Intermediate-0907-UFUA NC-EWDP-33P Deep-0907-UFUA

Supplies: 60mL pp bottles __ - ~

Procedure: From each of the 10 samples (represented 2 wells and 4 intervals) a cation and __

- anion aliquot will be taken and sent to Div -1 for analyses.

__ Approximately a 60mL aliquot was decanted in a labeled 60mL pp bottle. The bottle was - -- labeled with the sample ID, date and initials. The 60mL aliquot taken from each of the UFUA -- ~ samples was preserved with -1 80 pL of 1 : 1 nitric acid (5'42/74). The following table contaiins -

- ___ ___

sample IDS. - __ __

- CNWRAID Div 01 Cation Div 01 Anion

~ NC-EWDP-32P Intermediate-0907-FUA 321-0907C-2 321-0907A-2 ___ .- NC-EWDP-32P Intermediate-0907-UFUA 321-0907C-3 321-0907A-3

- ' NC-EWDP-32P Intermediate-0907-FA 321-0907C-1 321-0907A-1

- NC-EWDP-32P Deep-0907-FA 32D-0907C-4 32D-0907A-4 - __._. NC-EWDP-32P Deep-0907-FUA 32D-0907C-5 32D-0907A-5 ___ ' NC-EWDP-32P Deep-0907-UFUA 32D-0907C-6 32D-0907A-6 - _ ___ NC-EWDP-33P Intermediate-0907-FA 331-0907C-7 331-0907A-7 _- NC-EWDP-33P Intermediate-0907-FUA 331-0907C-8 331-0907A-8 - - - ' NC-EWDP-33P Intermediate-0907-UFUA 331-0907C-9 331-0907A-9 - NC-EWDP-33P Dem-0907-UFUA 33D-0907C-10 33D-0907A-10

- 58 BOOK PAGE

TITLE

__ - I Spex Std.

-_ - _ _ _ _ _ ~

._

- .

~~

__ __

__ __ ____

-

PROJECT

Dilution Factor Target Coinc. (ppm) of QA Std. 100 10 100 10 100 10 100 10 50 12 50 8 50 8 50 8 50 4 50 2

5

1c

1!

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25

3c

3c

4c

4f

Preparation of Cation and Anion QA Solutions ..

__

. - Objective: To prepare QA solutions to include with September 2007 NC-EWDP cation - and anion samples sent to Div 01 for analyses. __ _____

___- Reagents:

~ _ _ _

Spex Centiprep Instrument Calibration Standard 21 (cat # CL-CAL-3,

Spex Certiprep IC Instrument Check Standard 2 (cat # ICMIX2-100,

Type 1 water (BamsteadJThermolyne mode ID 1 1901 , sn

__

__ - Lot # )

Lot # )

_ _-- __

__ ___

_____ __

- _- 1190010979691) __

__ Supplies: Volumetric pipets _____ Volumetric flasks

__ HDPE bottles __-___ Squirt bottle for water __ ~ Kimwipes

___ . _- Procedure: __

.- _. _ _ __ ~ _ _ _ _ Add 1 OmL (volumetric pipet) of cation mix (Spex CL-CAL-3) into a 1 OOOmL volumetric __

-- flask and fill to mark with Type 1 water. Mix thoroughly. Decant into a 1L HDPE bottle _ _ _

________ and label Cation Std 1007A, date, initials and SN ref. The cation dilution factor is 100. ~

__ Add 1OmL (volumetric pipet) of anion mix (Spex ICMIX2-100) into a 500mL volumetric __

bottle and label Anion Std. 1007A, date, initials and SN ref. The anion dilution factor is ~

50.

- __ flask and fill to mark with 'Type 1 water. Mix thoroughly. Decant into a 500 mL HDPE ._.__

___- ____ - _ _ _ -

___

.............

................

..............

...............

Conbnued To Page

SIGNATURE DATE

DATE ZqZ4Jb /a/&irfl DISCLOSED TO AND UNDERSTOOD BY

I * *

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- 59 BOOK PAGE

TITLE PROJECT

I

5

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Confi

............................................................. ....... -. .................................... ._ ........ ................... ..... ............................. ......

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............ .................. ...................... .................. .............. ........ .............................. .........

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................... ................................................................................................... ...... .......

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......................... ........................................................... .......... .......................................................................... -. .~ ....... . SIGNATURE I DATE

1 ! / (/'L%u7 ................................................. D,sCl.osED To AND UNDERsTooD /Pd/A?fS BY ...................................................................... - .................................... 1 ...... 1 DATE

~ gl27!1f I@ - j & r '*

- 60 BOOK PAGE

TITLE PROJECT

5

I _.__ / J

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I

I Y ~ M X rypa: A -Air I-Biota D - Dust 1. - EmissionlStadc L - Liquid c - PmdUd Bd - Sol i B - son BED -Sediment

W - Water r - rim

FB - Fdd Bbnk (Sgnature) FD - Field Duplicate

TE-TfipBbnk Dsb

NS-Motr*Spi(ca Relbrquished by (PrinVSignature) Date r i wO-M.wISpyreDUp

I Tim -

-- The Relinquished by (PrintlSinature) Date

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samples Disposed by: I 1 I I I

- 65 BOOK PAGE

I T Objective: To characterize groundwater and collect aliquots for use in sorption

issues.

Samples: CNWRA personnel sampled a two wells (and two intervals per well) at the

experiments in the Yucca Mountain vicinity in order to investigate radionuclide transport

September 2007 sampling event. At the well, groundwater characterization will include field analyses of water temperature, air temperature, conductance, dissolved oxygen, oxidation-reduction potential, pH and alkalinity. Sample aliquots will be collected for

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TITLE PROJECT I c ~ n t / n m ~ ~ o m p e ~ e 1

-i . ___ I--- -+ Early Warning Drilling Program Groundwater Sampling Event September 2007

Personnel Involved: Miriam Juckett and Marla Roberts 5:

-~ F- 333’82-95. _- _-_. - -___ Equipment: Hydrolab minisonde 4A Water Quality Multiprobe (sn 41080)

Hydrolab Surveyor 4A Water Quality Data Display (sn S3 123) __

1 : 1 :Nitric Acid (742/74) Quinhydrone 98% (Acros Organics, Lot # A01 5 1 18301) Type 1 water

Millipore GWSC045 10 disposable groundwater sampling capsule 0.45 p -- 250 mL glass amber bottles (ICHEM 349-0250 certified 300 series) 40 mL glass amber VOA bottles (ICHEM T2146-00400 certified series) ~ _ _ _

Hach digital titrators with J-hooks Parafilm Labels Gloves Squirt bottle Sharpies Pens Pipetor and 5mL tips Scissors Kimwipes Trash bags Zip locks

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Table 1 : Sample Types and Volumes Colleted for Each Groundwater Zone During the September 2007 Early Warning Drilling Program Sampling Event

Sample Volume and Filtration Preservation Analyses Container Type Two 40mL Amber Glass Filtered, 0.45 None Inorganic Carbon (in

duplicate) 250 mL, Amber Glass Not Filtered None Anions and Cations,

Trace Metals 250 High Density Filtered, 0.45 None Anions and Cations, Polyethylene Pm Trace Metals 250 High Density Filtered, 0.45 1 : 1 HNO3 Trace Anions and Cations, Polyethylene pm Metal Grade Trace Metals

Pm

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Procedure:

The primary source for pH, OW, conductivity and dissolved oxygen field data is the inline probe. The probe was calibrated (333/82-95) and for pH was idso challenged (33/82-95). Due to the slow flow rate the inline probe recorded data at two distinct time periods. The resulting measurements for pH, OW, conductivity and. DO for each time slice were recorded in the field notebook.

Groundwater samples were collected directly from the well line. The Millipore groundwater filter was attached directly to the well and the outflow lkom the filter was decanted into each of the sample bottles. Sample types, quantities and treatments for subsequent laboratory analyses are listed in Table 1. The groundwater for the alkalinity tritration was filtered before analyses.

The bottles for sample collection for subsequent lab analyses were not rinsed with sample before filling because they were certified. Preservation consisted of 2 mL of 1 : 1 nitric acid into 250 mL of solution. Samples were labeled, parafilmed, ziplocked, and placed in cooler.

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Local Well Numbers: NC-EWDP-32P and NC-EWIDP-33P NC-EWDP-32P Intermediate: 463.7 ft -483.3 fi bgs NC-EWDP-32P Deep: 697.9 fi - 737.0 fi bgs NC-EWDP-33P Intermediate: 484.5 ft-523.6f bgs

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_____ - __ NC-EWDP-33P Deep: 600.9ft-64O.Oft bgs

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scientific notebook no. 864: radionuclide transport in the ... · this scientific notebook (sn) is...

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