1.1 Product identification

Product ID Portland-slag cement EN 197-1 - CEM II/B-S 42.5 NProduct description Portland-slag cement

1.2 Referred use of the substance or mixture and contraindicated usage

Production of concrete, reinforced concrete, mortar, plaster and other building materials.

SECTION 1: IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND THE COMPANY/UNDERTAKING

SAFE

TY D

ATA

SH

EET

PORTLAND-SLAG CEMENTEN 197-1 CEM II/B-S 42,5 N

Safety Data Sheet of the REACH Regulation1907/2006/EC according to the first

amendment of 453/2010/ECDate of publication: 1 December 2015Date of last review: 1 December 2015

Version: 7.00

Királyegyháza Cement Plant

BLUE1/15

CEMENT

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PROC Identified Uses - Use Description

Manufacture/ Formulation of

Professional/ Industrial use of

building and construction materials

2 Use in closed, continuous process with occasional controlled exposure X X

3 Use in closed batch process X X

5Mixing or blending in batch process for formulation

of mixtures and articlesX X

7 Industrial spraying X

8aTransfer of substance or mixture from/to vessels/large

containers at non-dedicated facilitiesX

8bTransfer of substance or mixture from/to vessels/large

containers a dedicated facilitiesX X

9 Transfer of substance or mixture into small containers X X

10 Roller application or brushing X

11 Non-Industrial spraying X

13 Treatment of articles by dipping and pouring X

14Production of mixtures or articles by tabletting,

compression extrusion, pelletisationX X

19 Hand-mixing with intimate contact and only PPE available X

22Potentially closed processing operations with minerals/metals

at elevated temperature in industrial settingX

26 Handling of solid inorganic substances at ambient temperature X X

1.3 Data about the supplier of the Safety Data Sheet

Manufacturer / Supplier LAFARGE Cement Hungary Ltd.Address 7953 Királyegyháza, 041/29 hrsz.Postal correspondence 7940 Szentlőrinc, Pf.: 54Name of manufacturer’s site LAFARGE Cement Magyarország Kft.Address of manufacturer’s site 7953 Királyegyháza, 041/29 hrsz.Telefon/fax +36 73 500 900 / +36 73 500 958 Name of assembler Dorottya TamásiHis/her email address dorottya.tamasi@lafargeholcim.comNational contact person Mátyás Kovács

1.4 Emergency phoneEgészségügyi Toxikológiai Tájékoztató Szolgálat (ETTSZ) 1096 Budapest, Nagyvárad tér 2.Language of information: hungarianService hours: 24/7 on-call serviceEmergency phone number: +36 80 201 199

SECTION 2: HAZARD CLASSIFICATION

2.1 Classification of the substance/mixture

Product definition: mixture

2.1.1. Hazard rates and categories, warnings as per 1272/2008/EC

Hazard rate Hazard category Classification process

Skin irritation Skin Irrit. 2 According to test results

Severe eye impairment Eye Dam. 1 According to test results

Skin irritability Skin Sens. 1 Based on a literature review

Toxicity on target organ – single exposure STOT SE 3 Based on a literature review

H315 Causes skin irritation.H317 May cause an allergic skin reaction.H318 Causes serious eye damage.H335 May cause respiratory irritation.

2.2 Labelling elements

2.2.1. According to Regulation (EC) No 1272/2008

H315 Causes skin irritation.H317 May cause an allergic skin reaction.H318 Causes serious eye damage.H335 May cause respiratory irritation.P280 Wear protective gloves/protective clothing/eye protection/face protection.

P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.

P302 + P352 + P333 + P313 IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. P261 + P304 + P340 + P312 Avoid breathing dust/fume/gas/mist/vapours/spray. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.

GHS07 GHS05

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2.3 Additional hazardsIn accordance with Appendix XIII of the REACH Regulation 1907/2006/EC, the cement does not comply with the criteria for PBT or vPvB materials.

SECTION 3: INFORMATION ON COMPOUND OR SUBSTANCE

3.1 Mixture

Description Portland cement-clinker

Contents (% by weight) 60-72%

EINECS 266-043-4

CAS 65997-15-1

Classification as perDirective 1272/2008/EEC

Skin irritation Skin Irrit. 2

Severe eye impairment Eye Dam. 1

Skin irritability Skin Sens. 1

Toxicity on target organ – single exposure STOT SE 3

H315, H317, H318, H335

SECTION 4: FIRST AID MEASURES

4.1 First aid measures

General informationWearing any specific personal protection equipment is not required when providing first aid but should avoid contact with wet cement.

In case of contact with eyesDo not rub eye, should be rinsed with open eyelids under running water for at least 45 minutes. If possible,use isotonic eye wash (0.9% NaCl). Consult with your occupational health physician and/or eye specialist.

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GHS07 GHS05

In case of skin contactDry cement powder must to be removed, then rinse thoroughly with water. In case of contact with wet cement the skin should be washed withplenty of water. Contaminated clothing, shoes, watch, etc. should be removed and thoroughly cleaned before next use.If symptoms appear (irritation), contact your doctor.

In case of inhalationGo to fresh air, breathe heavily to release dust from respiratory system as soon as possible.If symptoms appear (nausea, coughing, permanent irritation), contact your doctor.

After ingestionDo not make the injured person puke! If conscious, rinse mouth thoroughly and sip plenty of water, contact your doctor or the toxicologyinformation centre for help.

4.2 Most important symptoms and effects, both acute and delayed EyesCement (both dry and wet) may cause serious and permanent damage in case of contact with eyes.

Skin Prolonged contact with cement is irritating to the wet skin (due to sweating or humidity).Contact with wet skin may cause irritation, and might lead to dermatitis or severe skin lesions.For more information see (1).

InhalationRepeated and continuous inhalation over a longer period of time increases the risk of lung disease.

Environment Cement is environment friendly if used properly.

4.3 Indication in case of medical emergency or special treatmentTake this safety data sheet with you if contacting your doctor.

SECTION 5:FIRE SAFETY MEASURES

This product is not flammable or explosive neither as delivered nor as a ready-mix.

5.1 Fire extinguishing agentsFire extinguishing agents need to be chosen according to the surrounding fire.Unsuitable extinguishing agents for safety reasons: none.

5.2 Special hazards derived from the substance or mixtureNot available.

5.3 Advice for firefightersNo special measures needed, as cement poses no risk in terms of fire hazard.

SECTION 6:EMERGENCY MEASURES IN CASE OF ACCIDENTAL EXPOSURE

6.1 Personal precautionary measures, protective equipment and emergency proceduresWear protective clothing (see 8.2). Consider section 7.1 regarding safety procedures. Emergency management plan not required.

6.1.1. Non-emergency personnelWear protective clothing as described in Section 8. Follow the instructions regarding safety procedures as described in Section 7.

6.1.2. Rescue teamContingency plan not required. In case of high exposure to cement dust breathing apparatus must be worn.

6.2 Environmental precautionsAvoid contamination of draining system, surface water or groundwater.

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6.3 Measures and materials for containment and cleaningSpillage should be cleaned up using dry methods.

Dry cementPrefer dry clean-up methods and avoid spreading the dust (for example use an industrial vacuum cleaner equipped with appropriate filters (EPAand HEPA), or make it wet and remove applying wet cement techniques.

Wet cementWet cement should be removed mechanically, wait until it sets and hardens on a plastic foil or in a special container and dispose as described in Section 13.

6.4 Reference to Sections7., 8. and 13. for further information.

SECTION 7:HANDLING AND STORAGE

7.1 Precautions for safe handlingCannot be stored or used around food, beverages or tobacco products.Additionally, the regulations of Section 8 must be followed. Avoid formation of dust. In case of bagged product or open mixing equipment alwaysadd water first, and mix in cement carefully. Keep the filling height as low as possible. Slowly speed up the mixer. Please see section 6.3 regarding clean-up methods for spillage. Lifting cement bags may increase muscle rigidity, and may lead to muscle strain in your lower back, arms, shoulders and legs. Be careful at all times, lift in an adequate and suitable manner.

7.2 Conditions for safe storageStore in the original package.Bulk cement should be stored in a silo, which is dry (internal condensation to be minimized), waterproof, clean and protected against dirt.Entering a place used for bulk cement storage, like a silo, a tanker truck or other container without adequate safety preparations is prohibited,since there is a risk of burial and suffocation. Cement might form barricades and sludges, which can slide unexpectedly. To preserve the product,unopened bags should be stored on the floor in a dry and cold place protected from wind. The bags should be stored securely.

7.3 Specific end-use Checking of water soluble chromium (VI) content:Please keep in mind that in case of cements treated with chromium-reducing agents the effect of the agent decreases with time. For this reason, there is a best before date indicated on the cement bags / delivery documents. Until this date, the water soluble chromium (VI) content remains under 0.0002% (in accordance with the provisions of the REACH Regulation). The manufacturer’s instructions for storage must be observed. Inadequate (wet) or too long storage might decrease or terminate the effect of the chromium-reducing agent, which might result in irritation in case of skin contact.

SECTION 8:EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1 Control parameters

Description Threshold limit Exposure Frequency Note

Water soluble chromium (VI) 2 ppm Skin contactShort term (acute)

long term (repetitive)1907/2006/EC

Portland cement (powder) 10 mg/m3 Inhalation 8 hOn the basis of Annex 1 of

joint RegulationACGIH TLV 25/2000. (IX. 30.)

8.2 Exposure restrictions and control

8.2.1. Technical inspection

Measures to prevent dust formation or spreading, like the use of appropriate ventilation systems andcleaning methods which prevent dusting.

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UsePROC

(PROC’s are identified uses and defined in section 1.2.)

Exposure Localised controls Efficiency

Industrial manufacture/ formulation of hydraulic building and construction materials

2, 3

Dura

tion i

s not

restr

icted

(up t

o 480

minu

tes p

er sh

ift, 5

shift

s a w

eek)

Not required -

14, 26 A) not required or B) generic local exhaust ventilation

-

78%

5, 8b, 9 A) general ventilation or B) generic local exhaust ventilation

17%

78%

Industrial uses of dry hydraulic building and construction materials (indoor, outdoor)

2 Not required -

14, 22, 26 A) not required or B) generic local exhaust ventilation

-

78%

5,8b, 9 A) general ventilation or B) generic local exhaust ventilation

17%

78%

Industrial uses of wet suspension of hydraulic building and construction materials

2, 5, 8b, 9, 10, 13, 14 Not required -

7 A) not required or B) generic local exhaust ventilation

-

78%

Professional use of dry hydraulic building and construction material (indoor, outdoor)

2 Not required -

9, 26 A) not required or B) generic local exhaust ventilation

-

78%

5, 8a, 8b, 14 A) not required or B) integrated local exhaust ventilation

-

87%

19 Localised controls are not applicable, process only in good ventilated rooms or outdoor

50%

Professional uses of wet suspensions of hydraulic building and construction materials

11 A) not required or B) generic local exhaust ventilation

-

78%

2, 5, 8a, 8b, 9, 10, 13, 14, 19 Not required -

For each individual PROC, users can choose from either option A) or B) in the table, according to what is best suited to their specific situation. If one option is chosen, then the same option has to be chosen in the table from section “8.2.2 Individual protection measures such as personal protection equipment” - Specification of respiratory protective equipment. Only combinations between A) – A) and B) – B) are possible.

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8.2.2 Personal precautions, personal protective equipment

General safety and hygiene recommendations:

Avoid skin and eye contact. If possible, do not stand / kneel in fresh concrete or mortar during processing.

If necessary, wearing of alkaline resistant, waterproof protective clothing (e.g. Type C TYCHEM protective clothingcomplying with standards EN 368, EN 369, EN 463, EN 468, EN 1073-2 and EN 14126). Waterlogged or soiledclothing should be replaces immediately.

Eating, drinking or smoking is prohibited during work.

Hands should be washed during breaks and after work, and taking a shower in order to remove the adhering cement ishighly recommended. Contaminated clothing, footwear, watches, etc. to be cleaned before re-use.

Respiratory protection (S22 Do not breathe dust):

In case exposure limits are exceeded (e.g. by mixing) particle mask equipped with special filter should be worn (e.g.FFP-1 respirator complying with standard EN 149:2002 or 3M Half Facepiece reusable respirator equipped with 3M2135 filter which complies with standard EN 143:2000.

Eye protection (S25 Avoid contact with eyes):

In dusty working conditions or in case of splash hazard wear protective eyewear with a wide panoramic field of vision(complying with standard EN 166).

Skin protection (S24 Avoid contact with skin):

Wear waterproof, alkaline resistant gloves (complying with standards AQL 1,5 EN 374, EN 420:2003). Wear closedprotective clothing and closed footwear. Make sure, that you keep fresh mortar or concrete out of your shoes or boots.Using skincare after work is highly recommended.

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UsePROC

(PROC’s are identified uses and defined in section 1.2)

ExposureSpecification of

respiratory protective equipment (RPE)

RPE efficiency -assigned

protection factor (APF)

Industrial manufacture/ formulation of hydraulic building and construction materials

2, 3

Dura

tion i

s not

restr

icted

(up t

o 480

minu

tes p

er sh

ift, 5

shift

s a w

eek)

Not required -

14, 26 A) P1 mask (FF, FM) or B) not required

APF = 4

-

5, 8b, 9 A) P2 mask (FF, FM) or B) P1 mask (FF, FM)

APF = 10

APF = 4

Industrial uses of dry hydraulic building and construction materials (indoor, outdoor)

2 Not required -

14, 22, 26 A) P1 mask (FF, FM) or B) not required

APF = 4

-

5, 8b, 9 A) P2 mask (FF, FM) or B) P1 mask (FF, FM)

APF = 10

APF = 4

Industrial uses of wet suspension of hydraulic building and construction materials

2, 5, 8b, 9, 10, 13, 14 Not required -

7 A) P1 mask (FF, FM) or B) not required

APF = 4

-

Professional use of dry hydraulic building and construction material (indoor, outdoor)

2 P1 mask (FF, FM) APF = 4

9, 26 A) P2 mask (FF, FM) or B) P1 mask (FF, FM)

APF = 10

APF = 4

5, 8a, 8b, 14 A) P3 mask (FF, FM) or B) P1 mask (FF, FM)

APF = 20

APF = 4

19 P2 mask (FF, FM) APF = 10

Professional uses of wet suspensions of hydraulic building and construction materials

11 A) P2 mask (FF, FM) or B) P1 mask (FF, FM)

APF = 10

APF = 4

2, 5, 8a, 8b, 9, 10, 13, 14, 19 Not required -

A For each individual PROC, users can choose from either option A) or B) in the table, according to what is best suited to their specific situation. If one option is chosen, then the same option has to be chosen in the table from section “8.2.2 Individual protection measures such as personal protection equipment” - Specification of respiratory protective equipment.

An overview of the APFs of different RPE (according to EN 529:2005) can be found in the glossary of MEASE (16). Any RPE as defined above shall only be worn if the following principles are implemented in parallel: The duration of work (compare with “duration of exposure” above) should reflect the additional physiological stress for the worker due to the breathing resistance and mass of the RPE itself, due to the increased thermal stress by enclosing the head. In addition, it shall be considered that the worker’s capability of using tools and of communicating are reduced during the wearing of RPE. For reasons as given above, the worker should therefore be (i) healthy (especially in view of medical problems that may affect the use of RPE), (ii) have suitable facial characteristics reducing leakages between face and mask (in view of scars and facial hair). The recommended devices above which rely on a tight face seal will not provide the required protection unless they fit the contours of the face properly and securely. The employer and self-employed persons have legal responsibilities for the maintenance and issue of respiratory protective devices and the management of their correct use in the workplace. Therefore, they should define and document a suitable policy for a respiratory protective device programme including training of the workers.

8.3 Environmental exposure controls

Emissions from the work process equipment should be checked to ensure compliance with environmental regulations. Technicalmodifications to the process equipment will be necessary in some cases in order to reduce emissions to acceptable levels.

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SECTION 9:PHYSICAL AND CHEMICAL PARAMETERS

9.1 Information on basic physical and chemical characteristics

Appearance / form Inorganic, solid, fine powder (grey or white powder)

Odour Odourless

Odour threshold None, because odourless

pH (at T=20°C in water , water-solid ratio 1:2 ) 11 to 13.5

Meeting point > 1250 °C

Boiling point or boiling range Not applicable because its meeting point is about 1250°C

Flash point Not applicable, since not liquid

Evaporation rate Not applicable, since not liquid

Flammability (solid, gas) Not applicable, since solid substance non-flammable

Upper/lower inflammation or explosion limits Not applicable, since not gaseous

Vapour pressure Not applicable, since melting point >1250°C

Vapour density Not applicable, since melting point >1250°C

Relative density Density: 2.75-3.20 g/cm³; bulk density: 0.9-1.5 g/cm³

Solubility in water (T=20°C) Low (0.1-1.5 g / l)

Partition coefficient (n-octane/water) Not applicable, since inorganic substance

Auto-ignition temperature Not applicable (not self-igniting, not organometallic compound)

Decomposition temperature Not applicable, since does not contain inorganic peroxides

Viscosity Not applicable, since not liquid

Explosion characteristicsNot explosive, non-pyrotechnic product, no gas emission or self-sustaining exothermicchemical reaction

Oxidizing characteristics Not applicable, cement has no oxidizing characteristics

9.2 Other characteristicsNot applicable.

SECTION 10:STABILITY AND REACTIVITY

10.1 ReactivityIf properly mixed with water, cement hardens and forms a solid material that does not react with the environment.

10.2 Chemical stabilityDry cement is stable, as long as properly stored (Section 7).

10.3 Possibility of hazardous reactionsNot applicable.

10.4 Circumstances to avoidMoisture during storage may cause caking and quality loss.

10.5 Incompatible materialsUncontrolled use of aluminium in wet cement should be avoided, since it results in hydrogen emission.

10.6 Hazardous decomposition productsNo known dangerous decomposition products.

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SECTION 11:TOXICOLOGICAL DATA

Hazard rate Category Effect Reference

Acute toxicity – skin -Threshold limit test, rabbit, 24 hours, 2000mg/kg weight – no lethality.Based on available data, classification criteria not met.

(2)

Acute toxicity – inhalation -Threshold limit test, rat, 5g/m3 – no acute toxicity.The study was made using portland cement clinker, the main component of cement.Based on available data, classification criteria not met.

(4)

Acute toxicity – ingestion -No acute oral toxicity experienced during animal studies.Based on available data, classification criteria not met.

Literature

Skin irritation/skin damage

2

The cement is skin- and mucous membrane irritant. Dry cement contacting wet skin, or skin contacting damp or wet cement can lead to various inflammatory and irritant skin reactions, e.g. redness and roughness. Long-term contact along with abrasive influences can lead to serious skin damage.

(2) and humanexperience

also

Severity of eye damage/skin irritation

1

In vitro studies showed that the Portland cement clinker (main component of cement) hasvarious serious effects on cornea. Irritation index of 128 calculated. Direct contact withcement might cause corneal damage or Scleritis; partly due to mechanical effect, and partlybecause of immediate or delayed inflammation.

(5), (6) and humanexperience

also

Skin sensibility 1

Contact with wet cement may cause eczema for some people. These cases might be caused by pH level (irritant contact dermatitis) or by immunological reactions from water soluble chromium (VI) content (allergic contact dermatitis). The skin reacts in different ways from mild rushes to severe dermatitis, which can be derived from the combination of the two mechanisms. Accurate diagnosis is often difficult to find. Therefore the water soluble chromium content has to be reduced under 0.0002% using suitable reducing agent. There should be no increased sensibility as long as the best before date of the chromium reducing agent has not been exceeded.

(3), (7)

Sensibility of the respiratory system

- No signs of over-sensibility in the respiratory system caused by cement. (1)

Germ cell mutagenicity -No evidence of mutagenic effects of cement.Based on available data, classification criteria not met.

(8), (9)

Carcinogenesis -

No causal relationship found between cement and cancer. Epidemiological studies indicateno link between cancer and exposure to cement. Portland cement is not considered to be ahuman carcinogen according to ACGIH A4. In vitro studies and animal tests do not providesufficient evidence to demonstrate a carcinogenic effect.Based on available data, classification criteria not met.

(1), (10)

Reproductive toxicity - Based on available data, classification criteria not met.No evidence

based on humanexperience

Specific target organtoxicity in case ofsingle exposure

3

Exposure to cement dust may lead to irritation of the respiratory tract (mouth, throat, lungs). Meeting or exceeding the occupational exposure limit may result in coughing, wheezing, and shortness of breath. Long term occupational exposure may damage the respiratory system. However there is no sufficient information available to allow an estimation of the doseresponse relationship.

(1)

Specific target organtoxicity in case of

repetitive exposure-

Exceeding the occupational exposure limit may result in coughing, shortness of breath andchronic obstructive lesions in the respiratory tract. No chronic effects observed at lowconcentrations. Based on available data, classification criteria not met.

(11)

Aspiration - Not relevant, not present as aerosol.

Inhalation of cement may intensify existing respiratory disease, for example asthma or pulmonary emphysema.Contact with cement dust may aggravate existing skin diseases or sicknesses affecting the organs of sight.

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SECTION 12:ECOLOGICAL INFORMATION

12.1 ToxicityThis product does not threaten the environment. Bio-toxicological analysis of Portland cement using Daphnia magna (U.S. EPA, 1994a) (12) andSelenastrum coli (U.S. EPA, 1993) (13) showed slight toxic effects. Therefore LC50 and EC50 values could not be determined. Large quantitiesof cement disposed into water might shift the pH values, which might have a toxic effect on aquatic life in some circumstances.

12.2 Persistence and degradabilityNot applicable, as cement is an inorganic mineral product. After hydration the cement residues do not represent a toxicological risk.

12.3 Bioaccumulative capabilityNot applicable, as it is an inorganic mineral product.

12.4 Mobility in soilNot applicable, as cement is an inorganic mineral product. After hydration the cement residues do not represent a toxicological risk.

12.5 Results of the PBT and vPvB assessmentNot applicable, as cement is an inorganic mineral product. After hydration the cement residues do not represent a toxicological risk.

12.6 Other adverse effectsNot applicable.

SECTION 13:DISPOSAL CONSIDERATIONS

13.1 Waste management systems

13.1.1. Expired products containing reducing agent, if water soluble chromium (VI) content exceeds 0.0002%The product cannot be marketed or used, except in the case where a controlled, closed, and fully automated technology is used, or chromiumreducing agent is added.

13.1.2. Remaining unused dry productGather dry product. Select container. Use it before the expiry date keeping in mind to avoid making dust. In case of disposal, add water and waituntil it becomes solid, and then proceed with waste management as described in section 13.1.4.

13.1.3. Wet, silty productLet the wet, muddy product to become solid, keeping in mind to avoid leakage to sewage system or surrounding waters. Disposal as described in section 13.1.4.

13.1.4. If hardened after water addedTo be treated as waste. Do not dispose to sewage system. It becomes solid after 5 to 6 hours and can be treated as concrete waste or concrete silt.

13.1.5. Contaminated packagingPackaging should be emptied completely and recycled.

SECTION 14:TRANSPORT INFORMATION

Cement is not subject to international regulations on the transport of hazardous materials (IMDG, IATA, ADR / RID). Therefore no respectiveclassification and labelling needed.

14.1 UN numberNot applicable.

14.2 Proper shipping name for UNNot applicable.

14.3 Transport hazard classNot applicable.

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14.4 Packing groupsNot applicable.

14.5 Environmental hazardsNot applicable.

14.6 Special precautions affecting userNot applicable.

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC codexNot applicable.

SECTION 15:REGULATORY INFORMATION

15.1 Mixture specific safety, health and environmental regulations / legislationThe cement is a mixture, therefore not subject to compulsory notification according to Regulation 1907/2006/EC (REACH).

In accordance with Article 47, Appendix XVII of the REACH Regulation 1907/2006/EC; marketing of cement and cement containing products isprohibited, in case its chromium (VI) content after hydration exceeds 0.0002% per equivalent dry substance. Only exception being the casewhere a controlled, closed, and fully automated technology is used, which allows entirely avoiding skin contact along the process.

National regulationsPublic Act No XXV. of the year 2000 on chemical safety44/2000. (XII.27.) EüM (Ministry of Health) Regulation of hazardous materials and arrangements of processes and activities related to hazardous products41/2000. (XII.20.) EüM (Ministry of Health) and KöM (Ministry of Public Administration) joint Regulation about the restriction of certain dangerous substances and certain activities related to hazardous products.25/2000. (IX.30.) EüM (Ministry of Health)-SzCsM (Ministry of Social and Family Affairs) joint Regulation about workplace safety regulations regarding chemical exposure.442/2012. (XII. 29)Decree about the detailed rules for packaging and waste management of packaging.16/2001. (VII. 18.) KöM (Ministry of Public Administration) Regulation about the Catalogue for wastePublic Act No XCIII of the year 1993 about workplace safety

15.2. Chemical safety assessmentChemical Safety Assessment has not been carried out.

SECTION 16:ADDITIONAL INFORMATION

16.1. Changes compared to the previous versionThe following points of the Material Safety Data Sheet has changed:

Brand name removed from header

2.1.1. Hazard rates and categories, warnings as per 1272/2008/EC

3.1. Mixture

16.6 Warnings as per 1272/2008/EC

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16.2 Abbreviations and acronyms

ACGIH American Conference of Industrial HygienistsADR/RID European Agreements on the transport of Dangerous goods by Road/Railway CAS Chemical Abstracts ServiceCLP Classification, labelling and packagingEC50 Half maximal effective concentration EINECS European Inventory of Existing Commercial chemical SubstancesEPA Type of high efficiency air filter HEPA Type of high efficiency air filterIATA International Air Transport Association IMDG International agreement on the Maritime transport of Dangerous GoodsLC50 Median lethal dose PBT Persistent, bio-accumulative and toxic (perzisztents, bioakkumulatív, toxikus)REACH Registration, Evaluation and Authorisation of ChemicalsvPvB Very persistent, very bioaccumulativeMEASE Metals estimation and assessment of substance exposure, EBRC Consulting GmbH for Eurometaux

16.3 Literature and data sources

(1) Portland Cement Dust - Hazard assessment document EH75/7, UK Health and Safety Executive, 2006. Available from:http://www.hse.gov.uk/pubns/web/portlandcement.pdf

(2) Observations on the effects of skin irritation caused by cement, Kietzman et al, Dermatosen, 47, 5, 184-189 (1999).

(3) Epidemiological assessment of the occurrence of allergic dermatitis in workers in the construction industry related to the content of Cr (VI) in cement, NIOH, Page 11, 2003.

(4) TNO report V8801/02, An acute (4-hour) inhalation toxicity study with Portland Cement Clinker CLP/GHS 03-2010-fine in rats, August 2010.

(5) TNO report V8815/09, Evaluation of eye irritation potential of cement clinker G in vitro using the isolated chicken eye test, April 2010.

(6) TNO report V8815/10, Evaluation of eye irritation potential of cement clinker W in vitro using the isolated chicken eye test, April 2010.

(7) European Commission’s Scientific Committee on Toxicology, Ecotoxicology and the Environment (SCTEE) opinion of the risks to health from Cr (VI) in cement (European Commission, 2002). http://ec.europa.eu/health/archive/ph_risk/committees/sct/documents/out158_en.pdf

(8) Investigation of the cytotoxic and proinflammatory effects of cement dusts in rat alveolar macrophages, Van Berlo et al, Chem. Res. Toxicol., September 2009. 22(9):1548-58.

(9) Cytotoxicity and genotoxicity of cement dusts in A549 human epithelial lung cells in vitro; Gminski et al, Abstract DGPT conference Mainz, 2008.

(10) Comments on a recommendation from the American Conference of governmental industrial Hygienists to change the threshold limit value for Portland cement, Patrick A. Hessel and John F. Gamble, EpiLung Consulting, June 2008.

(11) Prospective monitoring of exposure and lung function among cement workers, Interim report of the study after the data collection of Phase I-II 2006-2010, Hilde Notø, Helge Kjuus, Marit Skogstad and Karl-Christian Nordby, National Institute of Occupational Health, Oslo, Norway, March 2010.

(12) U.S. EPA, Short-term Methods for Estimating the Chronic Toxicity of Effluents and Receiving Waters to Freshwater Organisms, 3rd ed. EPA/600/7-91/002, Environmental Monitoring and Support Laboratory, U.S. EPA, Cincinnati, OH (1994a).

(13) U.S. EPA, Methods for Measuring the Acute Toxicity of Effluents and Receiving Waters to Freshwater and Marine Organisms, 4th ed. EPA/600/4-90/027F, Environmental Monitoring and Support Laboratory, U.S. EPA, Cincinnati, OH (1993).

(14) Environmental Impact of Construction and Repair Materials on Surface and Ground Waters. Summary of Methodology, Laboratory Results, and Model Development. NCHRP report 448, National Academy Press, Washington, D.C., 2001.

16.4 Training advicesAlthough training programs are essential for the workers to be able to properly understand Health & Safety or environment protection; itis the company’s responsibility to ensure that employees read, understand and implement all the safety requirements.

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16.5 According to 1999/45/EC

Xi Irritant (stimulant, irritating effect).R 37 Irritating to respiratory system.R 38 Irritating to skin.R 41 Risk of serious damage to eyes.R 43 May cause sensitization by skin contact (oversensitivity).S 22 Do not breathe dust.S 24/25 Avoid contact with skin or eyes.S 26 In case of contact with eyes; rinse immediately with plenty of water and seek medical advice.S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection.

16.6 Warnings as per 1272/2008/EC

H315 Causes skin irritation.H317 May cause an allergic skin reaction.H318 Causes serious eye damage.H335 May cause respiratory irritation.

Legal disclaimer

This safety data sheet has been assembled according to the amendment of Appendix II., Article 31. of the REACH Regulation 1907/2006/EC. All information and warnings in this document are based on current information of science and technology available at the time of preparation. All the information contained in this data sheet is correct, and valid in case the given product has been properly used according to the recommendations on the packaging and relevant literature. Any deviancy from the above, including utilization along with other products, will be the sole responsibility of the user or the recipient of this data sheet. The recipient of this form is respon-sible to explain the data, information and warnings included in this data sheet to the user. In case the recipient of the sheet itself establishes provisions after receiving this data sheet, it is his or her responsibility to include all the relevant data contained in this data sheet as per the amendment of Appendix II., Article 31. of the REACH Regulation 1907/2006/EC. This safety data sheet is an identical translation of the Hungarian document with the same version number. In case of dispute the Hungarian version must be considered as a valid document.

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