1/5 Creation Date : September 28, 2001

Revision Date : November 7, 2011

Safety data sheet for chemical products

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: UB-205 Black [ uni-ball VISION ELITE ]

Manufacture's name : MITSUBISHI PENCIL CO.,LTD.Address : 5-23-37, HIGASHIOHI, SHINAGAWA, TOKYO, JAPANTelephone number : 03-3458-6281 Telefax number : 03-3450-0363Telex number : 2422337 MBPENC J.

Creation Date : September 28, 2001Revision Date : November 7, 2011File No. : 066133A Rev. 2.5.02.05

2. COMPOSITION/INFORMATION ON INGREDIENTS

The chemical product is a substance or a preparation : Preparation

Chemical nature: Component parts : Ink

Other parts : Other parts are excluded from 'chemical substances'.

3. HAZARDS IDENTIFICATION

Most important hazards : Not available.

Specific hazards : Information of components.

<Ethylene glycol>

<Carbon Black>

4. FIRST-AID MEASURES

Inhalation:

Skin contact:

Eye contact:

10- 30

Registered 2034733

Registered Polymer

10- 30107-21-1

CAS No.range (wt%)

TSCA EINECSNo.

Resins Registered

Concentration

Water 7732-18-5 Registered 2317912 50- 80

Chemical or generic name

Ethylene glycol

< 10

Additive Registered Registered Registered < 10

Carbon Black 1333-86-4 Registered 2156099

MAJOR HEALTH HAZARDS: respiratory tract irritation, skin irritation, eye

irritation, central nervous system depression, nerve damage, kidney damage

MAJOR HEALTH HAZARDS: suspect cancer hazard (in animals)

PHYSICAL HAZARDS: Dust/air mixtures may ignite or explode.

Not applicable.

(Due to its low vapor pressure. Inhalation is unlikely at room temperature.)

Wash skin with soap and water for at least 15 minutes while removing contaminated

clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry

contaminated clothing and shoes before reuse.

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.

-UB-205 Black-

2/5 Creation Date : September 28, 2001

Revision Date : November 7, 2011

Ingestion:

[Ink quantity of refill(UBR-95) : about 1.6g]

5. FIRE-FIGHTING MEASURES

Fire and explosion measures : Slight fire hazard.

Exitinguishing media:Suitable : regular dry chemical, carbon dioxide, water, regular foam.

Large fires : Use regular foam or flood with fine water spray.

Fire fighting : The Products is no flammable.Use extinguishing agents appropriate for surrounding fire.

Avoid inhalation of material or combustion by-products.

Stay upwind and keep out of low areas.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Not available.

Environmental precautions : Do not wash away into shower or water way.

Methods for cleaning up : Wipe off by dry cloth and wash with water.

: In accordance with national, state and local regulations.

7. HANDLING AND STORAGE

Store and handle in accordance with all current regulations and standards.Keep separated from incompatible substances.

Handling:Technical measures : Don't swallow ink.

: Recap after use.

: Don't shake.

: Keep out of the reach of children.

: Avoid contact with skin and eyes.

Precautions : Not available.

Safe handling advice : Not available.

Storage:Technical measures : Keep away from oxidizing materials, ignition sources and

high temperature.

Storage condition : Avoid direct sunlight.

: Do not leave the products in high temperature space.

: Recommended temperature: 0-30 C.

Incompatible products : (Information of components.)

Ethylene glycol

Resin

Carbon Black

Packaging materials : Not applicable.

If swallowed, seek medical advice, and show the MSDS to the physician then.

oxidizing materials, bases, acids, reducing agents, metals

strong acids, alkalies, oxidizers, oxidizing materials,

reducing agents

oxidizing materials, halogens

-UB-205 Black-

3/5 Creation Date : September 28, 2001

Revision Date : November 7, 2011

8. EXPOSURE CONTROL / PERSONAL PROTECTION

Engineering measures : Not required.

Control parameters (Information of components.)

OSHAACGIH

EC

Personal protective equipment : Not required.

9. PHYSICAL AND CHEMICAL PROPERTIES

[ ] : Information of components.

Physical state and form : Low viscous liquid.

Colour : Black.

Odour : None odour.

pH : about 7.5

Boiling point : Not available. [Water/ 100 C]

Melting point : <-10 C

Flash point : Not applicable. [Ethylene glycol/ 111 C(CC)]

Autoignition temperature : Not applicable. [Ethylene glycol/ 398 C]

Explosion limits : Not applicable.

[ Lower flammable limit / 3.2% , Upper flammable limit / 15.3% <Ethylene glycol> ]

Density : about 1.1 / 25 C

Vapour density (air=1) : Not available. [Ethylene glycol/ 2.1]

Solubulity in water : Soluble.

Evaporation rate : Not available.

Volatile : 69-72%

10. STABILITY AND REACTIVITY

Stability : Stability.

Hazardous reactions : Will not occur.

Conditions to avoid : Avoid heat, flames, sparks and other sources of ignition.

Avoid contact with incompatible materials.

Materials to avoid : (Information of components.)

Ethylene glycol

Resin

Carbon Black

Hazardous decomposition products : (Information of components.)

common decomposition products

Resin

Additive

100mg/m3 ceiling (particulate)(aerosol) Ethylene glycol

3.5mg/m3 Carbon Black

52mg/m3(20ppm) TWA,

104mg/m3(40ppm) STEL(skin)Ethylene glycol

3.5mg/m3(total dust) TWA Carbon Black15mg/m3 (Total dust) Additive

3.5mg/m3 Carbon Black

oxidizing materials, bases, acids, reducing agents, metals

strong acids, alkalies, oxidizers, oxidizing materials,

reducing agents

oxides of carbon, water

oxidizing materials, halogens

oxides of nitrogen.

miscellaneous decomposition products.

-UB-205 Black-

4/5 Creation Date : September 28, 2001

Revision Date : November 7, 2011

11.TOXICOLOGICAL INFORMATION

(Information of components)

Acute toxicity

Ingestion LD50

Inhalation LC50Skin LD50

Local effects

Chronic toxicity and long term toxicity

Signs and Symptos of overexposure and aggravated by exposure

Inhalation

Skin contact

Eye contact

Ingestion

Specific effects

12. ECOLOGICAL INFORMATION

Not available.

13. DISPOSAL CONSIDERATIONS

Waste from residues : Disposal in accordance with all current regulations and standards.

Contaminated packaging : Not applicable.

14. TRANSPORT INFORMATION

HS Code : 960810

1650mg/kg-Cat,

4700mg/kg-Rat

Ethylene glycol

1040mg/kg-Rabbit,

>40000mg/kg-Mouse

Resin

>8000mg/kg-Rat Carbon Black

9530uL/kg-Rabbit Ethylene glycol

Not available.

Irritant;inhalation, skin Carbon Black

Irritant;inhalation, skin, eye Ethylene glycol

The substance may have effects on the central nervous

system, resulting in abnormal eye movements (nystagmus).Ethylene glycol

Respiratory disorders. Carbon Black

irritation Carbon Black / Additive

irritation,cough Ethylene glycol

irritation,pneumonitis Resin

irritation Carbon Black / Additive

irritation,dry Ethylene glycol

irritation,sensitization Resin

mechanical irritation,

discoloration of lids

Carbon Black

irritation,redness Ethylene glycol

irritation Resin / Additive

nausea,vomiting Ethylene glycol

diarrhea,pneumonitis Resin

IARC Group 2B Carbon Black

IARC Group 3 Resin

-UB-205 Black-

5/5 Creation Date : September 28, 2001

Revision Date : November 7, 2011

15. REGULATORY INFORMATION

Regulations (Information of components)Hazardous chemicals (OSHA HCS) : Ethylene glycol / Carbon Black

EU labeling25%<=Xn;R22 : Ethylene glycol

R22 : Harmful if swallowed.

CANADA Hazardous Products Act - Ingredient Disclosure List1%over : Ethylene glycol / Carbon Black

Hazard and safety informationProducts are manufactured in accordance with ISO 8124-3 " Safety of Toys - Part 3"

16. OTHER INFORMATION

This sheet completes the technical sheet of use but it doesn't replace it.

The information contained in this sheet are based knowledge of the products

at the data : (November 7, 2011). They are given quite sincerely.

Moreover the attention of the users is drawn on the risks possibly taken,

when a product is used for other utilization than these which it is intended.

-UB-205 Black-

1/5 Creation Date : September 28, 2001

Revision Date : November 7, 2011

Safety data sheet for chemical products

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: UB-205 Blue [ uni-ball VISION ELITE ]

Manufacture's name : MITSUBISHI PENCIL CO.,LTD.Address : 5-23-37, HIGASHIOHI, SHINAGAWA, TOKYO, JAPANTelephone number : 03-3458-6281 Telefax number : 03-3450-0363Telex number : 2422337 MBPENC J.

Creation Date : September 28, 2001Revision Date : November 7, 2011File No. : 066134A Rev. 2.5.03.05

2. COMPOSITION/INFORMATION ON INGREDIENTS

The chemical product is a substance or a preparation : Preparation

Chemical nature: Component parts : Ink

Other parts : Other parts are excluded from 'chemical substances'.

3. HAZARDS IDENTIFICATION

Most important hazards : Not available.

Specific hazards : Information of components.

<Ethylene glycol>

4. FIRST-AID MEASURES

Inhalation:

Skin contact:

Eye contact:

Ingestion:

[Ink quantity of refill(UBR-95) : about 1.6g]

Ethylene glycol 107-21-1 Registered 2034733

range (wt%)TSCA EINECSNo.

< 10

2317912 50- 80

ConcentrationChemical or generic name

Resins Registered Registered

CAS No.

Coloring agent Registered

Water 7732-18-5 Registered

Polymer

Registered Registered

10- 30

< 10

< 10Additive Registered Registered Registered

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.

If swallowed, seek medical advice, and show the MSDS to the physician then.

MAJOR HEALTH HAZARDS: respiratory tract irritation, skin irritation, eye

irritation, central nervous system depression, nerve damage, kidney damage

Not applicable.

(Due to its low vapor pressure. Inhalation is unlikely at room temperature.)

Wash skin with soap and water for at least 15 minutes while removing contaminated

clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry

contaminated clothing and shoes before reuse.

-UB-205 Blue-

2/5 Creation Date : September 28, 2001

Revision Date : November 7, 2011

5. FIRE-FIGHTING MEASURES

Fire and explosion measures : Slight fire hazard.

Exitinguishing media:Suitable : regular dry chemical, carbon dioxide, water, regular foam.

Large fires : Use regular foam or flood with fine water spray.

Fire fighting : The Products is no flammable.Use extinguishing agents appropriate for surrounding fire.

Avoid inhalation of material or combustion by-products.

Stay upwind and keep out of low areas.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Not available.

Environmental precautions : Do not wash away into shower or water way.

Methods for cleaning up : Wipe off by dry cloth and wash with water.

: In accordance with national, state and local regulations.

7. HANDLING AND STORAGE

Store and handle in accordance with all current regulations and standards.Keep separated from incompatible substances.

Handling:Technical measures : Don't swallow ink.

: Recap after use.

: Don't shake.

: Keep out of the reach of children.

: Avoid contact with skin and eyes.

Precautions : Not available.

Safe handling advice : Not available.

Storage:Technical measures : Keep away from oxidizing materials, ignition sources and

high temperature.

Storage condition : Avoid direct sunlight.

: Do not leave the products in high temperature space.

: Recommended temperature: 0-30 C.

Incompatible products : (Information of components.)

Ethylene glycol

Coloring agent

Resin

Packaging materials : Not applicable.

oxidizing materials, bases, acids, reducing agents, metals

oxidizing materials, reducing agents

oxidizing materials

-UB-205 Blue-

3/5 Creation Date : September 28, 2001

Revision Date : November 7, 2011

8. EXPOSURE CONTROL / PERSONAL PROTECTION

Engineering measures : Not required.

Control parameters (Information of components.)

OSHA

ACGIH

EC

Personal protective equipment : Not required.

9. PHYSICAL AND CHEMICAL PROPERTIES

[ ] : Information of components.

Physical state and form : Low viscous liquid.

Colour : Blue.

Odour : None odour.

pH : about 7.5

Boiling point : Not available. [Water/ 100 C]

Melting point : <-10 C

Flash point : Not applicable. [Ethylene glycol/ 111 C(CC)]

Autoignition temperature : Not applicable. [Ethylene glycol/ 398 C]

Explosion limits : Not applicable.

[ Lower flammable limit / 3.2% , Upper flammable limit / 15.3% <Ethylene glycol> ]

Density : about 1.1 / 25 C

Vapour density (air=1) : Not available. [Ethylene glycol/ 2.1]

Solubulity in water : Soluble.

Evaporation rate : Not available.

Volatile : 83-86%

10. STABILITY AND REACTIVITY

Stability : Stability.

Hazardous reactions : Will not occur.

Conditions to avoid : Avoid heat, flames, sparks and other sources of ignition.

Avoid contact with incompatible materials.

Materials to avoid : (Information of components.)

Ethylene glycol

Coloring agent

Resin

Hazardous decomposition products : (Information of components.)

common decomposition products

Coloring agent / Resin

Additive

oxidizing materials, bases, acids, reducing agents, metals

oxides of nitrogen.

miscellaneous decomposition products.

oxidizing materials, reducing agents

oxides of carbon, water

oxidizing materials

15mg/m3 (Total dust) Additive52mg/m3(20ppm) TWA,

104mg/m3(40ppm) STEL(skin)Ethylene glycol

100mg/m3 ceiling (particulate)(aerosol) Ethylene glycol10mg/m3(Nuisance particulate) Coloring agent

5mg/m3(Respirable flaction),

15mg/m3(Total dust) [Nuisance Dust]Coloring agent

-UB-205 Blue-

4/5 Creation Date : September 28, 2001

Revision Date : November 7, 2011

11.TOXICOLOGICAL INFORMATION

(Information of components)

Acute toxicity

Ingestion LD50

Inhalation LC50Skin LD50

Local effects

Chronic toxicity and long term toxicity

Signs and Symptos of overexposure and aggravated by exposure

Inhalation

Skin contact

Eye contact

Ingestion

Specific effects

12. ECOLOGICAL INFORMATION

Not available.

13. DISPOSAL CONSIDERATIONS

Waste from residues : Disposal in accordance with all current regulations and standards.

Contaminated packaging : Not applicable.

14. TRANSPORT INFORMATION

HS Code : 960810

IARC Group 3 Resin

diarrhea,pneumonitis Resin

gastric disturbances Coloring agent

irritation Coloring agent / Resin / Additive

nausea,vomiting Ethylene glycol

irritation Additive

irritation,redness Ethylene glycol

irritation,dry Ethylene glycol

irritation,sensitization Resin

irritation Coloring agent / Additive

irritation,pneumonitis Resin

The substance may have effects on the central nervous

system, resulting in abnormal eye movements (nystagmus).Ethylene glycol

irritation,cough Ethylene glycol

9530uL/kg-Rabbit Ethylene glycol

Irritant;inhalation, skin, eye Ethylene glycol

1040mg/kg-Rabbit,

>40000mg/kg-Mouse

Resin

Not available.

1650mg/kg-Cat,

4700mg/kg-Rat

Ethylene glycol

>=5000mg/kg-Rat Coloring agent

-UB-205 Blue-

5/5 Creation Date : September 28, 2001

Revision Date : November 7, 2011

15. REGULATORY INFORMATION

Regulations (Information of components)Hazardous chemicals (OSHA HCS) : Ethylene glycol

EU labeling25%<=Xn;R22 : Ethylene glycol

R22 : Harmful if swallowed.

CANADA Hazardous Products Act - Ingredient Disclosure List1%over : Ethylene glycol

Hazard and safety informationProducts are manufactured in accordance with ISO 8124-3 " Safety of Toys - Part 3"

16. OTHER INFORMATION

This sheet completes the technical sheet of use but it doesn't replace it.

The information contained in this sheet are based knowledge of the products

at the data : (November 7, 2011). They are given quite sincerely.

Moreover the attention of the users is drawn on the risks possibly taken,

when a product is used for other utilization than these which it is intended.

-UB-205 Blue-

1/5 Creation Date : September 28, 2001

Revision Date : November 7, 2011

Safety data sheet for chemical products

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: UB-205 Red [ uni-ball VISION ELITE ]

Manufacture's name : MITSUBISHI PENCIL CO.,LTD.Address : 5-23-37, HIGASHIOHI, SHINAGAWA, TOKYO, JAPANTelephone number : 03-3458-6281 Telefax number : 03-3450-0363Telex number : 2422337 MBPENC J.

Creation Date : September 28, 2001Revision Date : November 7, 2011File No. : 066135A Rev. 2.5.02.05

2. COMPOSITION/INFORMATION ON INGREDIENTS

The chemical product is a substance or a preparation : Preparation

Chemical nature: Component parts : Ink

Other parts : Other parts are excluded from 'chemical substances'.

3. HAZARDS IDENTIFICATION

Most important hazards : Not available.

Specific hazards : Information of components.

<Ethylene glycol>

4. FIRST-AID MEASURES

Inhalation:

Skin contact:

Eye contact:

Ingestion:

[Ink quantity of refill(UBR-95) : about 1.6g]

range (wt%)TSCA EINECSNo.

< 10

Registered 2034733

Concentration

Polymer

Registered Registered

10- 30

< 10

Chemical or generic name

Resins Registered Registered

Ethylene glycol 107-21-1

CAS No.

Coloring agent Registered

Water 7732-18-5 Registered 2317912 50- 80

< 10Additive Registered Registered Registered

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.

If swallowed, seek medical advice, and show the MSDS to the physician then.

MAJOR HEALTH HAZARDS: respiratory tract irritation, skin irritation, eye

irritation, central nervous system depression, nerve damage, kidney damage

Not applicable.

(Due to its low vapor pressure. Inhalation is unlikely at room temperature.)

Wash skin with soap and water for at least 15 minutes while removing contaminated

clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry

contaminated clothing and shoes before reuse.

-UB-205 Red-

2/5 Creation Date : September 28, 2001

Revision Date : November 7, 2011

5. FIRE-FIGHTING MEASURES

Fire and explosion measures : Slight fire hazard.

Exitinguishing media:Suitable : regular dry chemical, carbon dioxide, water, regular foam.

Large fires : Use regular foam or flood with fine water spray.

Fire fighting : The Products is no flammable.Use extinguishing agents appropriate for surrounding fire.

Avoid inhalation of material or combustion by-products.

Stay upwind and keep out of low areas.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Not available.

Environmental precautions : Do not wash away into shower or water way.

Methods for cleaning up : Wipe off by dry cloth and wash with water.

: In accordance with national, state and local regulations.

7. HANDLING AND STORAGE

Store and handle in accordance with all current regulations and standards.Keep separated from incompatible substances.

Handling:Technical measures : Don't swallow ink.

: Recap after use.

: Don't shake.

: Keep out of the reach of children.

: Avoid contact with skin and eyes.

Precautions : Not available.

Safe handling advice : Not available.

Storage:Technical measures : Keep away from oxidizing materials, ignition sources and

high temperature.

Storage condition : Avoid direct sunlight.

: Do not leave the products in high temperature space.

: Recommended temperature: 0-30 C.

Incompatible products : (Information of components.)

Ethylene glycol

Coloring agent

Resin

Packaging materials : Not applicable.

oxidizing materials, bases, acids, reducing agents, metals

oxidizing materials, reducing agents

oxidizing materials

-UB-205 Red-

3/5 Creation Date : September 28, 2001

Revision Date : November 7, 2011

8. EXPOSURE CONTROL / PERSONAL PROTECTION

Engineering measures : Not required.

Control parameters (Information of components.)

OSHAACGIH

EC

JAIH

Personal protective equipment : Not required.

9. PHYSICAL AND CHEMICAL PROPERTIES

[ ] : Information of components.

Physical state and form : Low viscous liquid.

Colour : Red.

Odour : None odour.

pH : about 7.5

Boiling point : Not available. [Water/ 100 C]

Melting point : <-10 C

Flash point : Not applicable. [Ethylene glycol/ 111 C(CC)]

Autoignition temperature : Not applicable. [Ethylene glycol/ 398 C]

Explosion limits : Not applicable.

[ Lower flammable limit / 3.2% , Upper flammable limit / 15.3% <Ethylene glycol> ]

Density : about 1.1 / 25 C

Vapour density (air=1) : Not available. [Ethylene glycol/ 2.1]

Solubulity in water : Soluble.

Evaporation rate : Not available.

Volatile : 83-86%

10. STABILITY AND REACTIVITY

Stability : Stability.

Hazardous reactions : Will not occur.

Conditions to avoid : Avoid heat, flames, sparks and other sources of ignition.

Avoid contact with incompatible materials.

Materials to avoid : (Information of components.)

Ethylene glycol

Coloring agent

Resin

Hazardous decomposition products : (Information of components.)

common decomposition products

Coloring agent / Resin

Additive

oxidizing materials, bases, acids, reducing agents,

metals

oxides of nitrogen.

miscellaneous decomposition products.

oxidizing materials, reducing agents

oxides of carbon, water

oxidizing materials

52mg/m3(20ppm) TWA,

104mg/m3(40ppm) STEL(skin)Ethylene glycol

2mg/m3(Respirable fraction),

8mg/m3(Total dust)Coloring agent

100mg/m3 ceiling (particulate)(aerosol) Ethylene glycol15mg/m3 (Total dust) Additive

Not available.

-UB-205 Red-

4/5 Creation Date : September 28, 2001

Revision Date : November 7, 2011

11.TOXICOLOGICAL INFORMATION

(Information of components)

Acute toxicity

Ingestion LD50

Inhalation LC50Skin LD50

Local effects

Chronic toxicity and long term toxicity

Signs and Symptos of overexposure and aggravated by exposure

Inhalation

Skin contact

Eye contact

Ingestion

Specific effects

12. ECOLOGICAL INFORMATION

Not available.

13. DISPOSAL CONSIDERATIONS

Waste from residues : Disposal in accordance with all current regulations and standards.

Contaminated packaging : Not applicable.

14. TRANSPORT INFORMATION

HS Code : 960810

IARC Group 3 Resin

nausea,vomiting Ethylene glycol / Coloring agent

diarrhea,pneumonitis Resin

irritation,redness Ethylene glycol

irritation Resin / Additive

irritation,sensitization Resin

irritation Additive

irritation,dry Ethylene glycol

redness,swelling Coloring agent

irritation Coloring agent / Additive

irritation,pneumonitis Resin

The substance may have effects on the central nervous

system, resulting in abnormal eye movements (nystagmus).Ethylene glycol

irritation,cough Ethylene glycol

9530uL/kg-Rabbit Ethylene glycol

Irritant;inhalation, skin, eye Ethylene glycol

1040mg/kg-Rabbit,

>40000mg/kg-Mouse

Resin

Not available.

1650mg/kg-Cat,

4700mg/kg-Rat

Ethylene glycol

>=5000mg/kg-Rat Coloring agent

-UB-205 Red-

5/5 Creation Date : September 28, 2001

Revision Date : November 7, 2011

15. REGULATORY INFORMATION

Regulations (Information of components)Hazardous chemicals (OSHA HCS) : Ethylene glycol

EU labeling25%<=Xn;R22 : Ethylene glycol

R22 : Harmful if swallowed.

CANADA Hazardous Products Act - Ingredient Disclosure List1%over : Ethylene glycol

Hazard and safety informationProducts are manufactured in accordance with ISO 8124-3 " Safety of Toys - Part 3"

16. OTHER INFORMATION

This sheet completes the technical sheet of use but it doesn't replace it.

The information contained in this sheet are based knowledge of the products

at the data : (November 7, 2011). They are given quite sincerely.

Moreover the attention of the users is drawn on the risks possibly taken,

when a product is used for other utilization than these which it is intended.

-UB-205 Red-

1/5 Creation Date : September 28, 2001

Revision Date : November 7, 2011

Safety data sheet for chemical products

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: UB-205 Blue-black [ uni-ball VISION ELITE ]

Manufacture's name : MITSUBISHI PENCIL CO.,LTD.Address : 5-23-37, HIGASHIOHI, SHINAGAWA, TOKYO, JAPANTelephone number : 03-3458-6281 Telefax number : 03-3450-0363Telex number : 2422337 MBPENC J.

Creation Date : September 28, 2001Revision Date : November 7, 2011File No. : 066136A Rev. 2.5.02.05

2. COMPOSITION/INFORMATION ON INGREDIENTS

The chemical product is a substance or a preparation : Preparation

Chemical nature: Component parts : Ink

Other parts : Other parts are excluded from 'chemical substances'.

3. HAZARDS IDENTIFICATION

Most important hazards : Not available.

Specific hazards : Not available.

4. FIRST-AID MEASURES

Inhalation:

Skin contact:

Eye contact:

Ingestion:

[Ink quantity of refill(UBR-95) : about 1.6g]

CAS No.Concentration

Chemical or generic namerange (wt%)

TSCA EINECSNo.

If swallowed, seek medical advice, and show the MSDS to the physician then.

Not applicable.

(Due to its low vapor pressure. Inhalation is unlikely at room temperature.)

Wash skin with soap and water for at least 15 minutes while removing contaminated

clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry

contaminated clothing and shoes before reuse.

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.

< 10

Triethanolamine 102-71-6 Registered 2030498 < 10

Additive Registered Registered Polymer

< 10Resins Registered Registered Polymer

< 10Coloring agents Registered Registered Registered

50- 80

Glycerine 56-81-5 Registered 2002895 10- 30

Water 7732-18-5 Registered 2317912

-UB-205 Blue-black-

2/5 Creation Date : September 28, 2001

Revision Date : November 7, 2011

5. FIRE-FIGHTING MEASURES

Fire and explosion measures : Slight fire hazard.

Exitinguishing media:Suitable : regular dry chemical, carbon dioxide, water, regular foam.

Large fires : Use regular foam or flood with fine water spray.

Fire fighting : The Products is no flammable.Use extinguishing agents appropriate for surrounding fire.

Avoid inhalation of material or combustion by-products.

Stay upwind and keep out of low areas.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Not available.

Environmental precautions : Do not wash away into shower or water way.

Methods for cleaning up : Wipe off by dry cloth and wash with water.

: In accordance with national, state and local regulations.

7. HANDLING AND STORAGE

Store and handle in accordance with all current regulations and standards.Keep separated from incompatible substances.

Handling:Technical measures : Don't swallow ink.

: Recap after use.

: Don't shake.

: Keep out of the reach of children.

: Avoid contact with skin and eyes.

Precautions : Not available.

Safe handling advice : Not available.

Storage:Technical measures : Keep away from oxidizing materials, ignition sources and

high temperature.

Storage condition : Avoid direct sunlight.

: Do not leave the products in high temperature space.

: Recommended temperature: 0-30 C.

Incompatible products : (Information of components.)

Glycerine

Coloring agent

Resin

Additive

Triethanolamine

Packaging materials : Not applicable.

acids, bases, oxidizing materials, metal oxides, peroxides,

reducing agents

acids, metals, oxidizing materials

oxidizing materials, reducing agents

strong oxidizers

oxidizing materials

-UB-205 Blue-black-

3/5 Creation Date : September 28, 2001

Revision Date : November 7, 2011

8. EXPOSURE CONTROL / PERSONAL PROTECTION

Engineering measures : Not required.

Control parameters (Information of components.)

OSHA

ACGIH

EC

Personal protective equipment : Not required.

9. PHYSICAL AND CHEMICAL PROPERTIES

[ ] : Information of components.

Physical state and form : Low viscous liquid.

Colour : Blue-black.

Odour : None odour.

pH : about 8.6

Boiling point : Not available. [Water/ 100 C]

Melting point : <-10 C

Flash point : Not applicable. [Glycerine/ 160 C]

Autoignition temperature : Not applicable. [Triethanolamine/ 315.5 C]

Explosion limits : Not applicable. [ Lower flammable limit / 0.9% <Glycerine>]

Density : about 1.05 / 25 C

Vapour density (air=1) : Not available. [Glycerine/ 3.1]

Solubulity in water : Soluble.

Evaporation rate : Not available.

Volatile : 81-84%

10. STABILITY AND REACTIVITY

Stability : Stability.

Hazardous reactions : Will not occur.

Conditions to avoid : Avoid heat, flames, sparks and other sources of ignition.

Avoid contact with incompatible materials.

Materials to avoid : (Information of components.)

Glycerine

Coloring agent

Resin

Additive

Triethanolamine

Hazardous decomposition products : (Information of components.)

common decomposition products

Glycerine / Additive

Coloring agent

Resin / Triethanolamine

acids, bases, oxidizing materials, metal oxides,

peroxides, reducing agents

oxides of nitrogen, sulfur.

oxides of nitrogen.

oxides of carbon, water

corrosive acrolein.

strong oxidizers

acids, metals, oxidizing materials

oxidizing materials

oxidizing materials, reducing agents

Not available.

10mg/m3 (Nuisance particulate) Coloring agent5mg/m3 TWA Triethanolamine

5mg/m3(Respirable flaction),

15mg/m3(Total dust) [Nuisance Dust]Coloring agent

10mg/m3 TWA Glycerine

5mg/m3 TWA(Respirable dust fraction),

15mg/m3 TWA (Total dust)Glycerine

-UB-205 Blue-black-

4/5 Creation Date : September 28, 2001

Revision Date : November 7, 2011

11.TOXICOLOGICAL INFORMATION

(Information of components)

Acute toxicity

Ingestion LD50

Inhalation LC50Skin LD50

Local effects

Chronic toxicity and long term toxicity

Signs and Symptos of overexposure and aggravated by exposure

Inhalation

Skin contact

Eye contact

Ingestion

Specific effects

12. ECOLOGICAL INFORMATION

Not available.

13. DISPOSAL CONSIDERATIONS

Waste from residues : Disposal in accordance with all current regulations and standards.

Contaminated packaging : Not applicable.

14. TRANSPORT INFORMATION

HS Code : 960810

IARC Group 3 Resin / Triethanolamine

burns,gastrointestinal irritation Triethanolamine

gastric disturbances Coloring agent

diarrhea,pneumonitis Resin

irritation,corneal swelling Triethanolamine

nausea,vomiting Glycerine

tearing,stinging Glycerine

irritation Coloring agent / Resin

irritation,sensitization Resin

sensitization Additive

irritation,redness Glycerine / Triethanolamine

irritation Coloring agent

irritation,pneumonitis Resin

sore throat,difficulty breathing Triethanolamine

irritation,difficulty breathing Glycerine

irritation Coloring agent

Irritant;skin, eye Triethanolamine

Repeated or prolonged contact may cause skin sensitization. Triethanolamine

>16mL/kg-Rat Triethanolamine

dehydration Additive

>570mg/m3-1H-Rat Glycerine

>10000mg/kg-Rabbit Glycerine

1040mg/kg-Rabbit,

>40000mg/kg-Mouse

Resin

2200mg/kg-Rabbit,

5846mg/kg-Mouse

Triethanolamine

4090mg/kg-Mouse Glycerine

>5000mg/kg-Rat Coloring agent

-UB-205 Blue-black-

5/5 Creation Date : September 28, 2001

Revision Date : November 7, 2011

15. REGULATORY INFORMATION

Regulations (Information of components)Hazardous chemicals (OSHA HCS) : Glycerine / Triethanolamine

EU labeling : Not restricted.

CANADA Hazardous Products Act - Ingredient Disclosure List1%over : Triethanolamine

Hazard and safety informationProducts are manufactured in accordance with ISO 8124-3 " Safety of Toys - Part 3"

16. OTHER INFORMATION

This sheet completes the technical sheet of use but it doesn't replace it.

The information contained in this sheet are based knowledge of the products

at the data : (November 7, 2011). They are given quite sincerely.

Moreover the attention of the users is drawn on the risks possibly taken,

when a product is used for other utilization than these which it is intended.

-UB-205 Blue-black-

1/5 Creation Date : March 30, 2004

Revision Date : November 7, 2011

Safety data sheet for chemical products

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: UB-205 Violet [ uni-ball VISION ELITE ]

Manufacture's name : MITSUBISHI PENCIL CO.,LTD.Address : 5-23-37, HIGASHIOHI, SHINAGAWA, TOKYO, JAPANTelephone number : 03-3458-6281 Telefax number : 03-3450-0363Telex number : 2422337 MBPENC J.

Creation Date : March 30, 2004Revision Date : November 7, 2011File No. : 066172A Rev. 2.5.04.03

2. COMPOSITION/INFORMATION ON INGREDIENTS

The chemical product is a substance or a preparation : Preparation

Chemical nature: Component parts : Ink

Other parts : Other parts are excluded from 'chemical substances'.

3. HAZARDS IDENTIFICATION

Most important hazards : Not available.

Specific hazards : Not available.

4. FIRST-AID MEASURES

Inhalation:

Skin contact:

Eye contact:

Ingestion:

[Ink quantity of product : about 1.6g]

Water 7732-18-5 Registered 2317912 50- 80

Glycerine 56-81-5 Registered 2002895 10- 30

Coloring agent Registered Registered Registered < 10

< 10Resins Registered Registered Registered

Polymer

Not applicable.

(Due to its low vapor pressure. Inhalation is unlikely at room temperature.)

Wash skin with soap and water for at least 15 minutes while removing contaminated

clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry

contaminated clothing and shoes before reuse.

< 101,2-Propanediol 57-55-6 Registered 2003380

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.

If swallowed, seek medical advice, and show the MSDS to the physician then.

CAS No.Concentration

Chemical or generic namerange (wt%)

TSCA EINECSNo.

-UB-205 Violet-

2/5 Creation Date : March 30, 2004

Revision Date : November 7, 2011

5. FIRE-FIGHTING MEASURES

Fire and explosion measures : Slight fire hazard.

Exitinguishing media:Suitable : regular dry chemical, carbon dioxide, water, regular foam.

Large fires : Use regular foam or flood with fine water spray.

Fire fighting : The Products is no flammable.Use extinguishing agents appropriate for surrounding fire.

Avoid inhalation of material or combustion by-products.

Stay upwind and keep out of low areas.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Not available.

Environmental precautions : Do not wash away into shower or water way.

Methods for cleaning up : Wipe off by dry cloth and wash with water.

: In accordance with national, state and local regulations.

7. HANDLING AND STORAGE

Store and handle in accordance with all current regulations and standards.Keep separated from incompatible substances.

Handling:Technical measures : Don't swallow ink.

: Recap after use.

: Don't shake.

: Keep out of the reach of children.

: Avoid contact with skin and eyes.

Precautions : Not available.

Safe handling advice : Not available.

Storage:Technical measures : Keep away from oxidizing materials, ignition sources and

high temperature.

Storage condition : Avoid direct sunlight.

: Do not leave the products in high temperature space.

: Recommended temperature: 0-30 C.

Incompatible products : (Information of components.)

Glycerine

Coloring agent

Resin

1,2-Propanediol

Packaging materials : Not applicable.

oxidizing materials

acids, bases, oxidizing materials, metal oxides, peroxides,

reducing agents

oxidizing materials, reducing agents

acids, bases, combustible materials, halo carbons, metals,

metal salts, oxidizing materials, reducing agents

-UB-205 Violet-

3/5 Creation Date : March 30, 2004

Revision Date : November 7, 2011

8. EXPOSURE CONTROL / PERSONAL PROTECTION

Engineering measures : Not required.

Control parameters (Information of components.)

OSHA

ACGIHECJAIH

UK

Personal protective equipment : Not required.

9. PHYSICAL AND CHEMICAL PROPERTIES

[ ] : Information of components.

Physical state and form : Low viscous liquid.

Colour : Violet.

Odour : None odour.

pH : about 8.7

Boiling point : Not available. [Water/ 100 C]

Melting point : <-10 C

Flash point : Not applicable. [1,2-Propanediol/ 99 C(CC)]

Autoignition temperature : Not applicable. [Glycerine/ 370 C]

Explosion limits : Not applicable.

[ Lower flammable limit / 2.6% , Upper flammable limit / 12.5% <1,2-Propanediol> ]

Density : about 1.05-1.10 / 25 C

Vapour density (air=1) : Not available. [1,2-Propanediol/ 2.60-2.62]

Solubulity in water : Soluble.

Evaporation rate : Not available.

Volatile : 88-91%

10. STABILITY AND REACTIVITY

Stability : Stability.

Hazardous reactions : Will not occur.

Conditions to avoid : Avoid heat, flames, sparks and other sources of ignition.

Avoid contact with incompatible materials.

Materials to avoid : (Information of components.)

Glycerine

Coloring agent

Resin

1,2-Propanediol

Hazardous decomposition products : (Information of components.)

common decomposition products

Glycerine

Coloring agent

Resin

5mg/m3 TWA(Respirable dust fraction),

15mg/m3 TWA (Total dust)Glycerine

10mg/m3 TWA GlycerineNot available.

oxidizing materials, reducing agents

oxidizing materials

2mg/m3(Respirable fraction),

8mg/m3(Total dust)Coloring agent

150ppm(474mg/m3) TWA(total(vapor and

pariclulates)), 10mg/m3 TWA(particlulates)1,2-Propanediol

miscellaneous decomposition products.

oxides of nitrogen.

oxides of carbon, water

corrosive acrolein.

acids, bases, oxidizing materials, metal oxides,

peroxides, reducing agents

acids, bases, combustible materials, halo carbons,

metals, metal salts, oxidizing materials, reducing

-UB-205 Violet-

4/5 Creation Date : March 30, 2004

Revision Date : November 7, 2011

11.TOXICOLOGICAL INFORMATION

(Information of components)

Acute toxicity

Ingestion LD50

Inhalation LC50Skin LD50

Local effects

Chronic toxicity and long term toxicity

Signs and Symptos of overexposure and aggravated by exposure

Inhalation

Skin contact

Eye contact

Ingestion

Specific effects

12. ECOLOGICAL INFORMATION

Not available.

13. DISPOSAL CONSIDERATIONS

Waste from residues : Disposal in accordance with all current regulations and standards.

Contaminated packaging : Not applicable.

14. TRANSPORT INFORMATION

HS Code : 960810

IARC Group 3 Resin

4090mg/kg-Mouse Glycerine

>=5000mg/kg-Rat Coloring agent

1040mg/kg-Rabbit,

>40000mg/kg-Mouse

Resin

20000mg/kg-Rat 1,2-Propanediol

>570mg/m3-1H-Rat Glycerine

>10000mg/kg-Rabbit Glycerine

20800mg/kg-Rabbit 1,2-Propanediol

Not available.

Repeated or prolonged contact may cause skin sensitization. 1,2-Propanediol

irritation,difficulty breathing Glycerine

irritation Coloring agent

irritation,pneumonitis Resin

nausea,headache 1,2-Propanediol

irritation,redness Glycerine

Glycerine

irritation Resin

irritation,sensitization Resin

irritation,allergic reaction 1,2-Propanediol

Resin

irritation,pain 1,2-Propanediol

tearing,stinging

allergic reaction,vomiting 1,2-Propanediol

nausea,vomiting Glycerine

diarrhea,pneumonitis

-UB-205 Violet-

5/5 Creation Date : March 30, 2004

Revision Date : November 7, 2011

15. REGULATORY INFORMATION

Regulations (Information of components)Hazardous chemicals (OSHA HCS) : Glycerine

EU labeling : Not restricted.

CANADA Hazardous Products Act - Ingredient Disclosure List1%over : 1,2-Propanediol

Hazard and safety informationProducts are manufactured in accordance with ISO 8124-3 " Safety of Toys - Part 3"

16. OTHER INFORMATION

This sheet completes the technical sheet of use but it doesn't replace it.

The information contained in this sheet are based knowledge of the products

at the data : (November 7, 2011). They are given quite sincerely.

Moreover the attention of the users is drawn on the risks possibly taken,

when a product is used for other utilization than these which it is intended.

-UB-205 Violet-

1/5 Creation Date : March 30, 2004

Revision Date : November 7, 2011

Safety data sheet for chemical products

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: UB-205 Green [ uni-ball VISION ELITE ]

Manufacture's name : MITSUBISHI PENCIL CO.,LTD.Address : 5-23-37, HIGASHIOHI, SHINAGAWA, TOKYO, JAPANTelephone number : 03-3458-6281 Telefax number : 03-3450-0363Telex number : 2422337 MBPENC J.

Creation Date : March 30, 2004Revision Date : November 7, 2011File No. : 066173A Rev. 2.5.04.03

2. COMPOSITION/INFORMATION ON INGREDIENTS

The chemical product is a substance or a preparation : Preparation

Chemical nature: Component parts : Ink

Other parts : Other parts are excluded from 'chemical substances'.

3. HAZARDS IDENTIFICATION

Most important hazards : Not available.

Specific hazards : Not available.

4. FIRST-AID MEASURES

Inhalation:

Skin contact:

Eye contact:

Ingestion:

[Ink quantity of product : about 1.6g]

102-71-6 Registered 2030498

50- 80

10- 30

< 10

< 10

Glycerine 56-81-5 Registered 2002895

Water 7732-18-5 Registered 2317912

Coloring agent Registered Registered Registered

Resins Registered Registered Registered

Polymer

Not applicable.

(Due to its low vapor pressure. Inhalation is unlikely at room temperature.)

Wash skin with soap and water for at least 15 minutes while removing contaminated

clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry

contaminated clothing and shoes before reuse.

< 101,2-Propanediol 57-55-6 Registered 2003380

< 10Triethanolamine

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.

If swallowed, seek medical advice, and show the MSDS to the physician then.

range (wt%)TSCA EINECSNo.

ConcentrationChemical or generic name CAS No.

-UB-205 Green-

2/5 Creation Date : March 30, 2004

Revision Date : November 7, 2011

5. FIRE-FIGHTING MEASURES

Fire and explosion measures : Slight fire hazard.

Exitinguishing media:Suitable : regular dry chemical, carbon dioxide, water, regular foam.

Large fires : Use regular foam or flood with fine water spray.

Fire fighting : The Products is no flammable.Use extinguishing agents appropriate for surrounding fire.

Avoid inhalation of material or combustion by-products.

Stay upwind and keep out of low areas.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Not available.

Environmental precautions : Do not wash away into shower or water way.

Methods for cleaning up : Wipe off by dry cloth and wash with water.

: In accordance with national, state and local regulations.

7. HANDLING AND STORAGE

Store and handle in accordance with all current regulations and standards.Keep separated from incompatible substances.

Handling:Technical measures : Don't swallow ink.

: Recap after use.

: Don't shake.

: Keep out of the reach of children.

: Avoid contact with skin and eyes.

Precautions : Not available.

Safe handling advice : Not available.

Storage:Technical measures : Keep away from oxidizing materials, ignition sources and

high temperature.

Storage condition : Avoid direct sunlight.

: Do not leave the products in high temperature space.

: Recommended temperature: 0-30 C.

Incompatible products : (Information of components.)

Glycerine

Coloring agent

Resin

1,2-Propanediol

Triethanolamine

Packaging materials : Not applicable.

acids, metals, oxidizing materials

oxidizing materials

acids, bases, oxidizing materials, metal oxides, peroxides,

reducing agents

oxidizing materials, reducing agents

acids, bases, combustible materials, halo carbons, metals,

metal salts, oxidizing materials, reducing agents

-UB-205 Green-

3/5 Creation Date : March 30, 2004

Revision Date : November 7, 2011

8. EXPOSURE CONTROL / PERSONAL PROTECTION

Engineering measures : Not required.

Control parameters (Information of components.)

OSHA

ACGIH

ECUK

Personal protective equipment : Not required.

9. PHYSICAL AND CHEMICAL PROPERTIES

[ ] : Information of components.

Physical state and form : Low viscous liquid.

Colour : Green.

Odour : None odour.

pH : about 8.7

Boiling point : Not available. [Water/ 100 C]

Melting point : <-10 C

Flash point : Not applicable. [1,2-Propanediol/ 99 C(CC)]

Autoignition temperature : Not applicable. [Triethanolamine/ 315.5 C]

Explosion limits : Not applicable.

[ Lower flammable limit / 2.6% , Upper flammable limit / 12.5% <1,2-Propanediol> ]

Density : about 1.05-1.10 / 25 C

Vapour density (air=1) : Not available. [1,2-Propanediol/ 2.60-2.62]

Solubulity in water : Soluble.

Evaporation rate : Not available.

Volatile : 86-89%

10. STABILITY AND REACTIVITY

Stability : Stability.

Hazardous reactions : Will not occur.

Conditions to avoid : Avoid heat, flames, sparks and other sources of ignition.

Avoid contact with incompatible materials.

Materials to avoid : (Information of components.)

Glycerine

Coloring agent

Resin

1,2-Propanediol

Triethanolamine

5mg/m3 TWA(Respirable dust fraction),

15mg/m3 TWA (Total dust)Glycerine

5mg/m3(Respirable flaction),

15mg/m3(Total dust) [Nuisance Dust]Coloring agent

10mg/m3 TWA Glycerine10mg/m3 (Nuisance particulate) Coloring agent

1,2-Propanediol

5mg/m3 TWA TriethanolamineNot available.

acids, metals, oxidizing materials

oxidizing materials

oxidizing materials, reducing agents

150ppm(474mg/m3) TWA(total(vapor and

pariclulates)), 10mg/m3 TWA(particlulates)

acids, bases, oxidizing materials, metal oxides, peroxides,

reducing agents

acids, bases, combustible materials, halo carbons,

metals, metal salts, oxidizing materials, reducing

-UB-205 Green-

4/5 Creation Date : March 30, 2004

Revision Date : November 7, 2011

Hazardous decomposition products : (Information of components.)

common decomposition products

Glycerine

Coloring agent

Resin / Triethanolamine

11.TOXICOLOGICAL INFORMATION

(Information of components)

Acute toxicity

Ingestion LD50

Inhalation LC50Skin LD50

Local effects

Chronic toxicity and long term toxicity

Signs and Symptos of overexposure and aggravated by exposure

Inhalation

Skin contact

Eye contact

Ingestion

Specific effects

12. ECOLOGICAL INFORMATION

Not available.

cyanide, oxides of nitrogen.

oxides of nitrogen.

oxides of carbon, water

corrosive acrolein.

4090mg/kg-Mouse Glycerine

>=5000mg/kg-Rat Coloring agent

1040mg/kg-Rabbit,

>40000mg/kg-Mouse

Resin

20000mg/kg-Rat 1,2-Propanediol

2200mg/kg-Rabbit,

5846mg/kg-Mouse

Triethanolamine

>570mg/m3-1H-Rat Glycerine

>10000mg/kg-Rabbit Glycerine

20800mg/kg-Rabbit 1,2-Propanediol

Repeated or prolonged contact may cause skin sensitization.

>16mL/kg-Rat Triethanolamine

Irritant;skin, eye Triethanolamine

irritation,difficulty breathing Glycerine

irritation Coloring agent

irritation,pneumonitis Resin

nausea,headache 1,2-Propanediol

sore throat,difficulty breathing Triethanolamine

irritation,redness Glycerine / Triethanolamine

irritation Coloring agent

irritation,sensitization Resin

irritation,allergic reaction 1,2-Propanediol

tearing,stinging Glycerine

irritation Coloring agent / Resin

irritation,pain 1,2-Propanediol

diarrhea,pneumonitis Resin

irritation,corneal swelling Triethanolamine

nausea,vomiting Glycerine

allergic reaction,vomiting 1,2-Propanediol

gastric disturbances Coloring agent

IARC Group 3 Resin / Triethanolamine

1,2-Propanediol / Triethanolamine

burns,gastrointestinal irritation Triethanolamine

-UB-205 Green-

5/5 Creation Date : March 30, 2004

Revision Date : November 7, 2011

13. DISPOSAL CONSIDERATIONS

Waste from residues : Disposal in accordance with all current regulations and standards.

Contaminated packaging : Not applicable.

14. TRANSPORT INFORMATION

HS Code : 960810

15. REGULATORY INFORMATION

Regulations (Information of components)Hazardous chemicals (OSHA HCS) : Glycerine / Triethanolamine

EU labeling : Not restricted.

CANADA Hazardous Products Act - Ingredient Disclosure List1%over : 1,2-Propanediol / Triethanolamine

Hazard and safety informationProducts are manufactured in accordance with ISO 8124-3 " Safety of Toys - Part 3"

16. OTHER INFORMATION

This sheet completes the technical sheet of use but it doesn't replace it.

The information contained in this sheet are based knowledge of the products

at the data : (November 7, 2011). They are given quite sincerely.

Moreover the attention of the users is drawn on the risks possibly taken,

when a product is used for other utilization than these which it is intended.

-UB-205 Green-

1/5 Creation Date : March 30, 2004

Revision Date : November 7, 2011

Safety data sheet for chemical products

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: UB-205 Orange [ uni-ball VISION ELITE ]

Manufacture's name : MITSUBISHI PENCIL CO.,LTD.Address : 5-23-37, HIGASHIOHI, SHINAGAWA, TOKYO, JAPANTelephone number : 03-3458-6281 Telefax number : 03-3450-0363Telex number : 2422337 MBPENC J.

Creation Date : March 30, 2004Revision Date : November 7, 2011File No. : 066174A Rev. 2.5.02.03

2. COMPOSITION/INFORMATION ON INGREDIENTS

The chemical product is a substance or a preparation : Preparation

Chemical nature: Component parts : Ink

Other parts : Other parts are excluded from 'chemical substances'.

3. HAZARDS IDENTIFICATION

Most important hazards : Not available.

Specific hazards : Not available.

4. FIRST-AID MEASURES

Inhalation:

Skin contact:

Eye contact:

Ingestion:

[Ink quantity of product : about 1.6g]

102-71-6 Registered 2030498

50- 80

10- 30

< 10

< 10

Glycerine 56-81-5 Registered 2002895

Water 7732-18-5 Registered 2317912

Coloring agent Registered Registered Registered

Resins Registered Registered Registered

Polymer

Not applicable.

(Due to its low vapor pressure. Inhalation is unlikely at room temperature.)

Wash skin with soap and water for at least 15 minutes while removing contaminated

clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry

contaminated clothing and shoes before reuse.

< 101,2-Propanediol 57-55-6 Registered 2003380

< 10Triethanolamine

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.

If swallowed, seek medical advice, and show the MSDS to the physician then.

Chemical or generic namerange (wt%)

TSCA EINECSNo.CAS No.Concentration

-UB-205 Orange-

2/5 Creation Date : March 30, 2004

Revision Date : November 7, 2011

5. FIRE-FIGHTING MEASURES

Fire and explosion measures : Slight fire hazard.

Exitinguishing media:Suitable : regular dry chemical, carbon dioxide, water, regular foam.

Large fires : Use regular foam or flood with fine water spray.

Fire fighting : The Products is no flammable.Use extinguishing agents appropriate for surrounding fire.

Avoid inhalation of material or combustion by-products.

Stay upwind and keep out of low areas.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Not available.

Environmental precautions : Do not wash away into shower or water way.

Methods for cleaning up : Wipe off by dry cloth and wash with water.

: In accordance with national, state and local regulations.

7. HANDLING AND STORAGE

Store and handle in accordance with all current regulations and standards.Keep separated from incompatible substances.

Handling:Technical measures : Don't swallow ink.

: Recap after use.

: Don't shake.

: Keep out of the reach of children.

: Avoid contact with skin and eyes.

Precautions : Not available.

Safe handling advice : Not available.

Storage:Technical measures : Keep away from oxidizing materials, ignition sources and

high temperature.

Storage condition : Avoid direct sunlight.

: Do not leave the products in high temperature space.

: Recommended temperature: 0-30 C.

Incompatible products : (Information of components.)

Glycerine

Coloring agent

Resin

1,2-Propanediol

Triethanolamine

Packaging materials : Not applicable.

acids, metals, oxidizing materials

oxidizing materials

oxidizing materials, reducing agents

acids, bases, oxidizing materials, metal oxides, peroxides,

reducing agents

acids, bases, combustible materials, halo carbons, metals,

metal salts, oxidizing materials, reducing agents

-UB-205 Orange-

3/5 Creation Date : March 30, 2004

Revision Date : November 7, 2011

8. EXPOSURE CONTROL / PERSONAL PROTECTION

Engineering measures : Not required.

Control parameters (Information of components.)

OSHA

ACGIH

ECUK

Personal protective equipment : Not required.

9. PHYSICAL AND CHEMICAL PROPERTIES

[ ] : Information of components.

Physical state and form : Low viscous liquid.

Colour : Orange.

Odour : None odour.

pH : about 8.7

Boiling point : Not available. [Water/ 100 C]

Melting point : <-10 C

Flash point : Not applicable. [1,2-Propanediol/ 99 C(CC)]

Autoignition temperature : Not applicable. [Triethanolamine/ 315.5 C]

Explosion limits : Not applicable.

[ Lower flammable limit / 2.6% , Upper flammable limit / 12.5% <1,2-Propanediol> ]

Density : about 1.05-1.10 / 25 C

Vapour density (air=1) : Not available. [1,2-Propanediol/ 2.60-2.62]

Solubulity in water : Soluble.

Evaporation rate : Not available.

Volatile : 84-87%

10. STABILITY AND REACTIVITY

Stability : Stability.

Hazardous reactions : Will not occur.

Conditions to avoid : Avoid heat, flames, sparks and other sources of ignition.

Avoid contact with incompatible materials.

Materials to avoid : (Information of components.)

Glycerine

Coloring agent

Resin

1,2-Propanediol

Triethanolamine

5mg/m3 TWA(Respirable dust fraction),

15mg/m3 TWA (Total dust)Glycerine

5mg/m3(Respirable flaction),

15mg/m3(Total dust) [Nuisance Dust]Coloring agent

10mg/m3 TWA Glycerine10mg/m3 (Nuisance particulate) Coloring agent

1,2-Propanediol

5mg/m3 TWA TriethanolamineNot available.

acids, metals, oxidizing materials

oxidizing materials

oxidizing materials, reducing agents

150ppm(474mg/m3) TWA(total(vapor and

pariclulates)), 10mg/m3 TWA(particlulates)

acids, bases, oxidizing materials, metal oxides,

peroxides, reducing agents

acids, bases, combustible materials, halo carbons,

metals, metal salts, oxidizing materials, reducing

-UB-205 Orange-

4/5 Creation Date : March 30, 2004

Revision Date : November 7, 2011

Hazardous decomposition products : (Information of components.)

11.TOXICOLOGICAL INFORMATION

(Information of components)

Acute toxicity

Ingestion LD50

Inhalation LC50Skin LD50

Local effects

Chronic toxicity and long term toxicity

Signs and Symptos of overexposure and aggravated by exposure

Inhalation

Skin contact

Eye contact

Ingestion

Specific effects

12. ECOLOGICAL INFORMATION

Not available.

oxides of carbon, water common decomposition products

corrosive acrolein. Glycerine

oxides of nitrogen. Coloring agent / Resin / Triethanolamine

4090mg/kg-Mouse Glycerine

>=5000mg/kg-Rat Coloring agent

1040mg/kg-Rabbit,

>40000mg/kg-Mouse

Resin

20000mg/kg-Rat 1,2-Propanediol

2200mg/kg-Rabbit,

5846mg/kg-Mouse

Triethanolamine

>570mg/m3-1H-Rat Glycerine

>10000mg/kg-Rabbit Glycerine

20800mg/kg-Rabbit 1,2-Propanediol

>16mL/kg-Rat Triethanolamine

irritation,difficulty breathing Glycerine

Irritant;skin, eye Triethanolamine

Repeated or prolonged contact may cause skin sensitization.

irritation Coloring agent

irritation,pneumonitis Resin

nausea,headache 1,2-Propanediol

sore throat,difficulty breathing Triethanolamine

irritation,redness Glycerine / Triethanolamine

redness,swelling of skin Coloring agent

irritation,sensitization Resin

irritation,allergic reaction 1,2-Propanediol

tearing,stinging Glycerine

irritation Resin

allergic reaction,vomiting 1,2-Propanediol

nausea,vomiting Glycerine / Coloring agent

diarrhea,pneumonitis Resin

irritation,pain 1,2-Propanediol

irritation,corneal swelling

IARC Group 3 Resin / Triethanolamine

1,2-Propanediol / Triethanolamine

burns,gastrointestinal irritation Triethanolamine

Triethanolamine

-UB-205 Orange-

5/5 Creation Date : March 30, 2004

Revision Date : November 7, 2011

13. DISPOSAL CONSIDERATIONS

Waste from residues : Disposal in accordance with all current regulations and standards.

Contaminated packaging : Not applicable.

14. TRANSPORT INFORMATION

HS Code : 960810

15. REGULATORY INFORMATION

Regulations (Information of components)Hazardous chemicals (OSHA HCS) : Glycerine / Triethanolamine

EU labeling : Not restricted.

CANADA Hazardous Products Act - Ingredient Disclosure List1%over : 1,2-Propanediol / Triethanolamine

Hazard and safety informationProducts are manufactured in accordance with ISO 8124-3 " Safety of Toys - Part 3"

16. OTHER INFORMATION

This sheet completes the technical sheet of use but it doesn't replace it.

The information contained in this sheet are based knowledge of the products

at the data : (November 7, 2011). They are given quite sincerely.

Moreover the attention of the users is drawn on the risks possibly taken,

when a product is used for other utilization than these which it is intended.

-UB-205 Orange-

1/5 Creation Date : March 30, 2004

Revision Date : November 7, 2011

Safety data sheet for chemical products

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: UB-205 Wine [ uni-ball VISION ELITE ]

Manufacture's name : MITSUBISHI PENCIL CO.,LTD.Address : 5-23-37, HIGASHIOHI, SHINAGAWA, TOKYO, JAPANTelephone number : 03-3458-6281 Telefax number : 03-3450-0363Telex number : 2422337 MBPENC J.

Creation Date : March 30, 2004Revision Date : November 7, 2011File No. : 066175A Rev. 2.5.03.03

2. COMPOSITION/INFORMATION ON INGREDIENTS

The chemical product is a substance or a preparation : Preparation

Chemical nature: Component parts : Ink

Other parts : Other parts are excluded from 'chemical substances'.

3. HAZARDS IDENTIFICATION

Most important hazards : Not available.

Specific hazards : Not available.

4. FIRST-AID MEASURES

Inhalation:

Skin contact:

Eye contact:

Ingestion:

[Ink quantity of product : about 1.6g]

(Due to its low vapor pressure. Inhalation is unlikely at room temperature.)

Wash skin with soap and water for at least 15 minutes while removing contaminated

clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry

contaminated clothing and shoes before reuse.

< 10Triethanolamine 102-71-6 Registered 2030498

50- 80

Glycerine 56-81-5 Registered 2002895

Water 7732-18-5 Registered 2317912

10- 30

< 10

< 10Resins Registered Registered Registered

Polymer

Coloring agent Registered Registered Registered

< 10

If swallowed, seek medical advice, and show the MSDS to the physician then.

1,2-Propanediol 57-55-6 Registered 2003380

Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.

Not applicable.

CAS No.Concentration

Chemical or generic namerange (wt%)

TSCA EINECSNo.

-UB-205 Wine-

2/5 Creation Date : March 30, 2004

Revision Date : November 7, 2011

5. FIRE-FIGHTING MEASURES

Fire and explosion measures : Slight fire hazard.

Exitinguishing media:Suitable : regular dry chemical, carbon dioxide, water, regular foam.

Large fires : Use regular foam or flood with fine water spray.

Fire fighting : The Products is no flammable.Use extinguishing agents appropriate for surrounding fire.

Avoid inhalation of material or combustion by-products.

Stay upwind and keep out of low areas.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Not available.

Environmental precautions : Do not wash away into shower or water way.

Methods for cleaning up : Wipe off by dry cloth and wash with water.

: In accordance with national, state and local regulations.

7. HANDLING AND STORAGE

Store and handle in accordance with all current regulations and standards.Keep separated from incompatible substances.

Handling:Technical measures : Don't swallow ink.

: Recap after use.

: Don't shake.

: Keep out of the reach of children.

: Avoid contact with skin and eyes.

Precautions : Not available.

Safe handling advice : Not available.

Storage:Technical measures : Keep away from oxidizing materials, ignition sources and

high temperature.

Storage condition : Avoid direct sunlight.

: Do not leave the products in high temperature space.

: Recommended temperature: 0-30 C.

Incompatible products : (Information of components.)

Glycerine

Coloring agent

Resin

1,2-Propanediol

Triethanolamine

Packaging materials : Not applicable.

acids, metals, oxidizing materials

oxidizing materials

acids, bases, oxidizing materials, metal oxides, peroxides,

reducing agents

oxidizing materials, reducing agents

acids, bases, combustible materials, halo carbons, metals,

metal salts, oxidizing materials, reducing agents

-UB-205 Wine-

3/5 Creation Date : March 30, 2004

Revision Date : November 7, 2011

8. EXPOSURE CONTROL / PERSONAL PROTECTION

Engineering measures : Not required.

Control parameters (Information of components.)

OSHA

ACGIH

ECUK

Personal protective equipment : Not required.

9. PHYSICAL AND CHEMICAL PROPERTIES

[ ] : Information of components.

Physical state and form : Low viscous liquid.

Colour : Wine.

Odour : None odour.

pH : about 8.7

Boiling point : Not available. [Water/ 100 C]

Melting point : <-10 C

Flash point : Not applicable. [1,2-Propanediol/ 99 C(CC)]

Autoignition temperature : Not applicable. [Triethanolamine/ 315.5 C]

Explosion limits : Not applicable.

[ Lower flammable limit / 2.6% , Upper flammable limit / 12.5% <1,2-Propanediol> ]

Density : about 1.05-1.10 / 25 C

Vapour density (air=1) : Not available. [1,2-Propanediol/ 2.60-2.62]

Solubulity in water : Soluble.

Evaporation rate : Not available.

Volatile : 81-84%

10. STABILITY AND REACTIVITY

Stability : Stability.

Hazardous reactions : Will not occur.

Conditions to avoid : Avoid heat, flames, sparks and other sources of ignition.

Avoid contact with incompatible materials.

Materials to avoid : (Information of components.)

Glycerine

Coloring agent

Resin

1,2-Propanediol

Triethanolamine

5mg/m3 TWA(Respirable dust fraction),

15mg/m3 TWA (Total dust)Glycerine

5mg/m3(Respirable flaction),

15mg/m3(Total dust) [Nuisance Dust]Coloring agent

10mg/m3 TWA Glycerine10mg/m3 (Nuisance particulate) Coloring agent

1,2-Propanediol

5mg/m3 TWA TriethanolamineNot available.

acids, metals, oxidizing materials

oxidizing materials

oxidizing materials, reducing agents

150ppm(474mg/m3) TWA(total(vapor and

pariclulates)), 10mg/m3 TWA(particlulates)

acids, bases, oxidizing materials, metal oxides,

peroxides, reducing agents

acids, bases, combustible materials, halo carbons,

metals, metal salts, oxidizing materials, reducing

-UB-205 Wine-

4/5 Creation Date : March 30, 2004

Revision Date : November 7, 2011

Hazardous decomposition products : (Information of components.)

11.TOXICOLOGICAL INFORMATION

(Information of components)

Acute toxicity

Ingestion LD50

Inhalation LC50Skin LD50

Local effects

Chronic toxicity and long term toxicity

Signs and Symptos of overexposure and aggravated by exposure

Inhalation

Skin contact

Eye contact

Ingestion

Specific effects

12. ECOLOGICAL INFORMATION

Not available.

oxides of carbon, water common decomposition products

corrosive acrolein. Glycerine

oxides of nitrogen. Coloring agent / Resin / Triethanolamine

4090mg/kg-Mouse Glycerine

>=5000mg/kg-Rat Coloring agent

1040mg/kg-Rabbit,

>40000mg/kg-Mouse

Resin

20000mg/kg-Rat 1,2-Propanediol

2200mg/kg-Rabbit,

5846mg/kg-Mouse

Triethanolamine

>570mg/m3-1H-Rat Glycerine

>10000mg/kg-Rabbit Glycerine

>3000mg/kg-Rabbit Coloring agent

20800mg/kg-Rabbit 1,2-Propanediol

Repeated or prolonged contact may cause skin sensitization. 1,2-Propanediol / Triethanolamine

>16mL/kg-Rat Triethanolamine

Irritant;skin, eye Triethanolamine

irritation,difficulty breathing Glycerine

irritation,pneumonitis Resin

nausea,headache 1,2-Propanediol

sore throat,difficulty breathing Triethanolamine

irritation,redness Glycerine / Triethanolamine

irritation,sensitization Resin

irritation,allergic reaction 1,2-Propanediol

tearing,stinging Glycerine

irritation Resin

irritation,pain 1,2-Propanediol

Resin

allergic reaction,vomiting 1,2-Propanediol

irritation,corneal swelling Triethanolamine

nausea,vomiting Glycerine

IARC Group 3 Resin / Triethanolamine

burns,gastrointestinal irritation Triethanolamine

diarrhea,pneumonitis

-UB-205 Wine-

5/5 Creation Date : March 30, 2004

Revision Date : November 7, 2011

13. DISPOSAL CONSIDERATIONS

Waste from residues : Disposal in accordance with all current regulations and standards.

Contaminated packaging : Not applicable.

14. TRANSPORT INFORMATION

HS Code : 960810

15. REGULATORY INFORMATION

Regulations (Information of components)Hazardous chemicals (OSHA HCS) : Glycerine / Triethanolamine

EU labeling : Not restricted.

CANADA Hazardous Products Act - Ingredient Disclosure List1%over : 1,2-Propanediol / Triethanolamine

Hazard and safety informationProducts are manufactured in accordance with ISO 8124-3 " Safety of Toys - Part 3"

16. OTHER INFORMATION

This sheet completes the technical sheet of use but it doesn't replace it.

The information contained in this sheet are based knowledge of the products

at the data : (November 7, 2011). They are given quite sincerely.

Moreover the attention of the users is drawn on the risks possibly taken,

when a product is used for other utilization than these which it is intended.

-UB-205 Wine-