safety data sheet - crcorp...isobutyl acetate 110-19-0 1 - 2.5 xylene 1330-20-7 1 - 2.5 other...

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Product name: IHSP FIRE HYDRANT RED Issue date: 10-04-2016 SDS US 1 / 12 SAFETY DATA SHEET 1. Identification Product number Product identifier Company information Company phone Emergency telephone US Version # Recommended use Recommended restrictions 2. Hazard(s) identification Physical hazards Health hazards OSHA defined hazards Label elements n/a INHIBITAUR HighSolids FIRE HYDR. RED CONTINENTAL RESEARCH CORP. 1180 Central Industrial Dr ST LOUIS, MO 63110-0204 United States General Assistance 314-776-0410 1-888-255-3924 (CHEM-TEL) Coating None known. Flammable aerosols Serious eye damage/eye irritation Specific target organ toxicity, single exposure Not classified. Category 1 Category 2A Category 3 narcotic effects Signal word Danger Hazard statement Extremely flammable aerosol. Causes serious eye irritation. May cause drowsiness or dizziness. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing gas. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear eye protection/face protection. Response If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If exposed or concerned: Get medical advice/attention. Call a poison center/doctor if you feel unwell. If eye irritation persists: Get medical advice/attention. Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information None. 3. Composition/information on ingredients Mixtures Chemical name Acetone Propane Barium Sulfate, Natural Butane Common name and synonyms CAS number % 67-64-1 10 - 20 74-98-6 10 - 20 7727-43-7 2.5 - 10 106-97-8 2.5 - 10

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Page 1: SAFETY DATA SHEET - crcorp...Isobutyl Acetate 110-19-0 1 - 2.5 Xylene 1330-20-7 1 - 2.5 Other components below reportable levels 20 - 40 *Designates that a specific chemical identity

Product name: IHSP FIRE HYDRANT RED Issue date: 10-04-2016

SDS US

1 / 12

SAFETY DATA SHEET

1. Identification

Product number

Product identifier

Company information

Company phone

Emergency telephone US

Version #

Recommended use

Recommended restrictions

2. Hazard(s) identification

Physical hazards

Health hazards

OSHA defined hazards

Label elements

n/a

INHIBITAUR HighSolids FIRE HYDR. RED

CONTINENTAL RESEARCH CORP. 1180 Central Industrial Dr ST LOUIS, MO 63110-0204 United States

General Assistance 314-776-0410

1-888-255-3924 (CHEM-TEL)

Coating

None known.

Flammable aerosols

Serious eye damage/eye irritation

Specific target organ toxicity, single exposure

Not classified.

Category 1

Category 2A

Category 3 narcotic effects

Signal word Danger

Hazard statement Extremely flammable aerosol. Causes serious eye irritation. May cause drowsiness or dizziness.

Precautionary statement

Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open

flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing gas. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear eye protection/face protection.

Response If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse

cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If exposed or concerned: Get medical advice/attention. Call a poison center/doctor if you feel unwell. If eye irritation persists: Get medical advice/attention.

Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect from

sunlight. Do not expose to temperatures exceeding 50°C/122°F.

Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.

Hazard(s) not otherwise

classified (HNOC) None known.

Supplemental information None.

3. Composition/information on ingredients

Mixtures

Chemical name

Acetone

Propane

Barium Sulfate, Natural

Butane

Common name and synonyms CAS number %

67-64-1 10 - 20

74-98-6 10 - 20

7727-43-7 2.5 - 10

106-97-8 2.5 - 10

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Product name: IHSP FIRE HYDRANT RED Issue date: 10-04-2016

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Chemical name Common name and synonyms CAS number %

Ethylene Glycol Propyl Ether 2807-30-9 2.5 - 10

Methyl Isobutyl Ketone 108-10-1 2.5 - 10

Methyl Propyl Ketone 107-87-9 2.5 - 10

Propylene Glycol Monomethyl Ether Acetate

108-65-6 2.5 - 10

Isobutyl Acetate 110-19-0 1 - 2.5

Xylene 1330-20-7 1 - 2.5

Other components below reportable levels 20 - 40

*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures

Inhalation

Skin contact

Eye contact

Ingestion

Most important

symptoms/effects, acute and

delayed

Indication of immediate

medical attention and special

treatment needed

General information

5. Fire-fighting measures

Suitable extinguishing media

Unsuitable extinguishing

media

Specific hazards arising from

the chemical

Special protective equipment

and precautions for firefighters

Fire fighting

equipment/instructions

Specific methods

General fire hazards

Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON

CENTER or doctor/physician if you feel unwell.

Wash off with soap and water. Get medical attention if irritation develops and persists.

Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

In the unlikely event of swallowing contact a physician or poison control center. Rinse mouth.

May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision.

Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed.

Ensure that medical personnel are aware of the material(s) involved, and take precautions to

protect themselves.

Alcohol resistant foam. Powder. Carbon dioxide (CO2).

Do not use water jet as an extinguisher, as this will spread the fire.

Contents under pressure. Pressurized container may explode when exposed to heat or flame. During fire, gases hazardous to health may be formed.

Firefighters must use standard protective equipment including flame retardant coat, helmet with

face shield, gloves, rubber boots, and in enclosed spaces, SCBA.

Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose

holder or monitor nozzles, if possible. If not, withdraw and let fire burn out.

Use standard firefighting procedures and consider the hazards of other involved materials. Move

containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes.

Extremely flammable aerosol.

6. Accidental release measures

Personal precautions,

protective equipment and

emergency procedures

Methods and materials for

containment and cleaning up

Environmental precautions

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Avoid breathing gas. Do not touch

damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate

closed spaces before entering them. Local authorities should be advised if significant spillages

cannot be contained. For personal protection, see section 8 of the SDS.

Refer to attached safety data sheets and/or instructions for use. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has

dispersed. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Cover with plastic sheet to

prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following

product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to

remove residual contamination. For waste disposal, see section 13 of the SDS.

Avoid discharge into drains, water courses or onto the ground.

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7. Handling and storage

Precautions for safe handling

Conditions for safe storage,

including any incompatibilities

Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke

while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Avoid breathing gas. Avoid contact with eyes. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Observe good industrial hygiene practices.

Level 2 Aerosol.

Store locked up. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open

flame, heat or other sources of ignition. This material can accumulate static charge which may

cause spark and become an ignition source. Store away from incompatible materials (see Section 10 of the SDS).

8. Exposure controls/personal protection

Occupational exposure limits

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

Components Type Value Form

Acetone (CAS 67-64-1) PEL 2400 mg/m3

1000 ppm

Barium Sulfate, Natural (CAS 7727-43-7)

PEL 5 mg/m3 Respirable fraction.

15 mg/m3 Total dust.

Isobutyl Acetate (CAS

110-19-0) PEL 700 mg/m3

150 ppm

Methyl Isobutyl Ketone

(CAS 108-10-1) PEL 410 mg/m3

100 ppm

Methyl Propyl Ketone (CAS

107-87-9) PEL 700 mg/m3

200 ppm

Propane (CAS 74-98-6) PEL 1800 mg/m3

1000 ppm

Xylene (CAS 1330-20-7) PEL 435 mg/m3

100 ppm

US. ACGIH Threshold Limit Values

Components Type Value Form

Acetone (CAS 67-64-1) STEL 500 ppm

TWA 250 ppm

Barium Sulfate, Natural (CAS 7727-43-7)

TWA 5 mg/m3 Inhalable fraction.

Butane (CAS 106-97-8) STEL 1000 ppm

Isobutyl Acetate (CAS 110-19-0)

TWA 150 ppm

Methyl Isobutyl Ketone

(CAS 108-10-1) STEL 75 ppm

TWA 20 ppm

Methyl Propyl Ketone (CAS 107-87-9)

STEL 150 ppm

Xylene (CAS 1330-20-7) STEL 150 ppm

TWA 100 ppm

US. NIOSH: Pocket Guide to Chemical Hazards

Components Type Value Form

Acetone (CAS 67-64-1)

Barium Sulfate, Natural (CAS 7727-43-7)

TWA 590 mg/m3

250 ppm

TWA 5 mg/m3 Respirable.

10 mg/m3 Total

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US. NIOSH: Pocket Guide to Chemical Hazards

Components Type Value Form

Butane (CAS 106-97-8)

Isobutyl Acetate (CAS

110-19-0)

Methyl Isobutyl Ketone

(CAS 108-10-1)

Methyl Propyl Ketone (CAS

107-87-9)

Propane (CAS 74-98-6)

TWA 1900 mg/m3

800 ppm

TWA 700 mg/m3

150 ppm

STEL 300 mg/m3

75 ppm

TWA 205 mg/m3

50 ppm

TWA 530 mg/m3

150 ppm

TWA 1800 mg/m3

1000 ppm

US. Workplace Environmental Exposure Level (WEEL) Guides

Components Type

Value

Propylene Glycol Monomethyl Ether Acetate

(CAS 108-65-6)

Biological limit values

ACGIH Biological Exposure Indices

TWA 50 ppm

Components Value Determinant Specimen Sampling Time

Acetone (CAS 67-64-1) 25 mg/l Acetone Urine *

Methyl Isobutyl Ketone

(CAS 108-10-1) 1 mg/l Methyl isobutyl

ketone Urine *

Xylene (CAS 1330-20-7) 1.5 g/g Methylhippuric acids

Creatinine in urine

*

* - For sampling details, please see the source document.

Exposure guidelines

US - California OELs: Skin designation

Propylene Glycol Monomethyl Ether Acetate (CAS

108-65-6)

Can be absorbed through the skin.

Appropriate engineering

controls

Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide

eyewash station.

Individual protection measures, such as personal protective equipment

Eye/face protection

Skin protection

Hand protection

Other

Respiratory protection

Thermal hazards

General hygiene

considerations

Wear safety glasses with side shields (or goggles).

Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove

supplier.

Wear suitable protective clothing.

If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an

air-supplied respirator.

Wear appropriate thermal protective clothing, when necessary.

When using do not smoke. Always observe good personal hygiene measures, such as washing

after handling the material and before eating, drinking, and/or smoking. Routinely wash work

clothing and protective equipment to remove contaminants.

9. Physical and chemical properties

Appearance

Physical state

Form

Gas.

Aerosol.

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Product name: IHSP FIRE HYDRANT RED Issue date: 10-04-2016

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Color

Odor

Not available.

Not available.

Odor threshold Not available.

pH Not available.

Melting point/freezing point Not available.

Initial boiling point and boiling

range

-47.2 °F (-44 °C) supplier estimated

Flash point -2.2 °F (-19.0 °C) supplier

Evaporation rate Not available.

Flammability (solid, gas) Not available.

Upper/lower flammability or explosive limits

Flammability limit - lower

(%)

Flammability limit - upper

(%)

1.7 supplier

10.9 supplier

Explosive limit - lower (%) Not available.

Explosive limit - upper (%) Not available.

Vapor pressure Not available.

Vapor density Not available.

Relative density Not available.

Solubility(ies)

Solubility (water) Not available.

Partition coefficient

(n-octanol/water)

Not available.

Auto-ignition temperature Not available.

Decomposition temperature Not available.

Viscosity Not available.

Other information

Explosive properties

Oxidizing properties

Not explosive.

Not oxidizing.

Specific gravity 0.815 estimated

10. Stability and reactivity

Reactivity

Chemical stability

Possibility of hazardous

reactions

Conditions to avoid

Incompatible materials

Hazardous decomposition

products

The product is stable and non-reactive under normal conditions of use, storage and transport.

Material is stable under normal conditions.

Hazardous polymerization does not occur.

Avoid temperatures exceeding the flash point. Contact with incompatible materials.

Strong acids. Strong oxidizing agents. Nitrates. Aluminum. Halogens. Phosphorus. Fluorine. Chlorine.

No hazardous decomposition products are known.

11. Toxicological information

Information on likely routes of exposure

Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be

harmful.

Skin contact No adverse effects due to skin contact are expected.

Eye contact Causes serious eye irritation.

Ingestion Expected to be a low ingestion hazard.

Symptoms related to the

physical, chemical and

toxicological characteristics

May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision.

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Information on toxicological effects

Acute toxicity Narcotic effects.

Components Species

Acetone (CAS 67-64-1)

Acute

Dermal

Test Results

LD50 Guinea pig > 7426 mg/kg, 24 Hours

> 9.4 ml/kg, 24 Hours

Rabbit > 7426 mg/kg, 24 Hours

> 9.4 ml/kg, 24 Hours

Inhalation

LC50 Rat 55700 ppm, 3 Hours

132 mg/l, 3 Hours

50.1 mg/l

Oral

LD50 Rat 5800 mg/kg

2.2 ml/kg

Barium Sulfate, Natural (CAS 7727-43-7)

Acute

Oral

Ethylene Glycol Propyl Ether (CAS 2807-30-9)

Acute

Dermal

LD100

LD50

Butane (CAS 106-97-8)

Rat

Rat

564 g/kg

307 g/kg

Acute

Inhalation

LC50

Mouse

1237 mg/l, 120 Minutes

52 %, 120 Minutes

Rat 1355 mg/l

LD50 Guinea pig

Rabbit

5.6 g/kg, 4 Days

> 1 g/kg, 24 Hours

1337 ml/kg, 14 Days

Inhalation

LC50

Rat

> 2132 ppm, 6 Hours

> 1800 ppm

Oral

LD50

Guinea pig

2.2 g/kg

Mouse 1774 mg/kg

Rat 0.5 - 1 g/kg

Isobutyl Acetate (CAS 110-19-0)

Acute

Dermal

LD50

Rabbit

> 17400 mg/kg, 24 Hours

Inhalation

LC50

Rat

> 30 mg/l, 6 Hours

> 23.4 mg/l, 4 Hours

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Components Species

Oral

Test Results

LD50 Rat 13413 mg/kg

Methyl Isobutyl Ketone (CAS 108-10-1)

Acute

Inhalation

Methyl Propyl Ketone (CAS 107-87-9)

Acute

Inhalation

Vapor

LC50 Rat > 25.5 mg/l, 4 Hours

Oral

LD50 Mouse 1600 mg/kg

Rat 1600 - 3200 mg/kg

Propane (CAS 74-98-6)

Acute

Inhalation

LC50 Mouse 1237 mg/l, 120 Minutes

52 %, 120 Minutes

Rat 1355 mg/l

658 mg/l/4h

Propylene Glycol Monomethyl Ether Acetate (CAS 108-65-6)

Acute

Dermal

* Estimates for product may be based on additional component data not shown.

Skin corrosion/irritation

Serious eye damage/eye

irritation

Respiratory or skin sensitization

Prolonged skin contact may cause temporary irritation.

Causes serious eye irritation.

Respiratory sensitization Not a respiratory sensitizer.

Skin sensitization This product is not expected to cause skin sensitization.

LC50 Rat 2000 - 4000 ppm, 4 Hours

Oral

LD50

Rat

2.08 g/kg

LD50

Oral

Rat > 2000 mg/kg, 24 Hours

LD50 Rat > 5000 mg/kg

> 14.1 ml

Xylene (CAS 1330-20-7)

Acute

Dermal

LD50

Rabbit

> 5000 ml/kg, 4 Hours

12126 mg/kg, 24 Hours

Inhalation

LC50

Rat

5922 ppm, 4 Hours

Oral

LD50

Mouse

5251 mg/kg

Rat 3523 mg/kg

10 ml/kg

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Germ cell mutagenicity

No data available to indicate product or any components present at greater than 0.1% are

mutagenic or genotoxic.

Carcinogenicity Risk of cancer cannot be excluded with prolonged exposure.

IARC Monographs. Overall Evaluation of Carcinogenicity

Methyl Isobutyl Ketone (CAS 108-10-1) 2B Possibly carcinogenic to humans.

Xylene (CAS 1330-20-7) 3 Not classifiable as to carcinogenicity to humans.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not regulated.

US. National Toxicology Program (NTP) Report on Carcinogens

Not listed.

Reproductive toxicity

Specific target organ toxicity -

single exposure

Specific target organ toxicity -

repeated exposure

Components in this product have been shown to cause birth defects and reproductive disorders in laboratory animals.

May cause drowsiness and dizziness.

Not classified.

Aspiration hazard Not likely, due to the form of the product.

Chronic effects Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects.

12. Ecological information

Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

Components

Acetone (CAS 67-64-1)

Aquatic

Crustacea

Fish

EC50

LC50

Species

Water flea (Daphnia magna)

Rainbow trout,donaldson trout (Oncorhynchus mykiss)

Test Results

21.6 - 23.9 mg/l, 48 hours

4740 - 6330 mg/l, 96 hours

Barium Sulfate, Natural (CAS 7727-43-7)

Aquatic

Crustacea EC50 Tubificid worm (Tubifex tubifex) 28.61 - 38.03 mg/l, 48 hours

Methyl Isobutyl Ketone (CAS 108-10-1)

Aquatic

Fish LC50 Fathead minnow (Pimephales promelas) 492 - 593 mg/l, 96 hours

Methyl Propyl Ketone (CAS 107-87-9)

Aquatic

Fish LC50 Fathead minnow (Pimephales promelas) 1190 - 1290 mg/l, 96 hours

Propylene Glycol Monomethyl Ether Acetate (CAS 108-65-6)

Aquatic

Crustacea

Xylene (CAS 1330-20-7)

Aquatic

Fish

EC50

LC50

Daphnia

Bluegill (Lepomis macrochirus)

500.0001 mg/L, 48 Hours

7.711 - 9.591 mg/l, 96 hours

* Estimates for product may be based on additional component data not shown.

Persistence and degradability

Bioaccumulative potential

No data is available on the degradability of this product.

Partition coefficient n-octanol / water (log Kow)

Acetone -0.24

Butane 2.89

Isobutyl Acetate 1.78

Methyl Isobutyl Ketone 1.31

Methyl Propyl Ketone 0.91

Propane 2.36

Xylene 3.12 - 3.2

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Mobility in soil

No data available.

Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation

potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations

Disposal instructions

Local disposal regulations

Hazardous waste code

Waste from residues / unused

products

Contaminated packaging

14. Transport information

DOT

UN number

UN proper shipping name

Transport hazard class(es)

Class

Subsidiary risk

Label(s)

Packing group

Special precautions for user

Special provisions

Packaging exceptions

Packaging non bulk

Packaging bulk

Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Dispose of contents/container in accordance

with local/regional/national/international regulations.

Dispose in accordance with all applicable regulations.

The waste code should be assigned in discussion between the user, the producer and the waste

disposal company.

Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).

Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers.

UN1950

Aerosols, flammable, (each not exceeding 1 L capacity)

2.1

-

2.1

Not applicable.

Read safety instructions, SDS and emergency procedures before handling.

N82

306

None

None

This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond

mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20

and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently.

IATA

UN number

UN proper shipping name

Transport hazard class(es)

Class

Subsidiary risk

Label(s)

Packing group

Environmental hazards

ERG Code

Special precautions for user

Other information

Passenger and cargo

aircraft

Cargo aircraft only

Packaging Exceptions

IMDG

UN number

UN proper shipping name

Transport hazard class(es)

Class

Subsidiary risk

Label(s)

Packing group

UN1950

Aerosols, flammable

2.1

-

2.1

Not applicable.

No.

10L

Read safety instructions, SDS and emergency procedures before handling.

Allowed with restrictions.

Allowed with restrictions.

LTD QTY

UN1950

AEROSOLS

2.1

-

2.1

Not applicable.

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Environmental hazards

Marine pollutant

EmS

Special precautions for user

Packaging Exceptions

Transport in bulk according to

Annex II of MARPOL 73/78 and

the IBC Code

DOT

IATA; IMDG

15. Regulatory information

US federal regulations

No.

F-D, S-U

Read safety instructions, SDS and emergency procedures before handling.

LTD QTY

Not applicable.

This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication

Standard, 29 CFR 1910.1200.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

Not regulated.

CERCLA Hazardous Substance List (40 CFR 302.4)

Acetone (CAS 67-64-1) Listed.

Isobutyl Acetate (CAS 110-19-0) Listed.

Methyl Isobutyl Ketone (CAS 108-10-1) Listed.

Xylene (CAS 1330-20-7) Listed.

SARA 304 Emergency release notification

Not regulated.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not regulated.

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories Immediate Hazard - Yes

Delayed Hazard - No

Fire Hazard - Yes

Pressure Hazard - No

Reactivity Hazard - No

SARA 302 Extremely hazardous substance

Not listed.

SARA 311/312 Hazardous No

chemical

SARA 313 (TRI reporting)

Chemical name CAS number % by wt.

Methyl Isobutyl Ketone 108-10-1 2.5 - 10

Xylene 1330-20-7 1 - 2.5

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Other federal regulations

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List

Methyl Isobutyl Ketone (CAS 108-10-1)

Xylene (CAS 1330-20-7)

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)

Butane (CAS 106-97-8)

Propane (CAS 74-98-6)

Safe Drinking Water Act

(SDWA)

Not regulated.

Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and

Chemical Code Number

Acetone (CAS 67-64-1) 6532

Methyl Isobutyl Ketone (CAS 108-10-1) 6715

Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))

Acetone (CAS 67-64-1) 35 %WV

Methyl Isobutyl Ketone (CAS 108-10-1) 35 %WV

DEA Exempt Chemical Mixtures Code Number

Acetone (CAS 67-64-1) 6532

Methyl Isobutyl Ketone (CAS 108-10-1) 6715

US state regulations

US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)

Not listed.

US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd.

(a))

Acetone (CAS 67-64-1)

Butane (CAS 106-97-8)

Methyl Isobutyl Ketone (CAS 108-10-1)

Xylene (CAS 1330-20-7)

US. Massachusetts RTK - Substance List

Acetone (CAS 67-64-1)

Barium Sulfate, Natural (CAS 7727-43-7)

Butane (CAS 106-97-8)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Propane (CAS 74-98-6)

Xylene (CAS 1330-20-7)

US. New Jersey Worker and Community Right-to-Know Act

Acetone (CAS 67-64-1)

Barium Sulfate, Natural (CAS 7727-43-7)

Butane (CAS 106-97-8)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Propane (CAS 74-98-6)

Xylene (CAS 1330-20-7)

US. Pennsylvania Worker and Community Right-to-Know Law

Acetone (CAS 67-64-1)

Barium Sulfate, Natural (CAS 7727-43-7)

Butane (CAS 106-97-8)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Propane (CAS 74-98-6)

Xylene (CAS 1330-20-7)

US. Rhode Island RTK

Acetone (CAS 67-64-1)

Butane (CAS 106-97-8)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Propane (CAS 74-98-6)

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Xylene (CAS 1330-20-7)

US. California Proposition 65

WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm.

US - California Proposition 65 - CRT: Listed date/Carcinogenic substance

Methyl Isobutyl Ketone (CAS 108-10-1) Listed: November 4, 2011

US - California Proposition 65 - CRT: Listed date/Developmental toxin

Methyl Isobutyl Ketone (CAS 108-10-1) Listed: March 28, 2014

International Inventories

Country(s) or region Inventory name On inventory (yes/no)*

Australia Australian Inventory of Chemical Substances (AICS)

Canada Domestic Substances List (DSL)

Canada Non-Domestic Substances List (NDSL)

China Inventory of Existing Chemical Substances in China (IECSC)

Europe European Inventory of Existing Commercial Chemical Substances (EINECS)

Europe European List of Notified Chemical Substances (ELINCS)

Japan Inventory of Existing and New Chemical Substances (ENCS)

Korea Existing Chemicals List (ECL)

New Zealand New Zealand Inventory

Philippines Philippine Inventory of Chemicals and Chemical Substances

(PICCS)

United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)

No

Yes

No

No

No

No

No

No

No

Yes

Yes

A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing

country(s).

16. Other information, including date of preparation or last revision

Issue date 10-04-2016

Version # 01

Disclaimer

Revision information

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a

guidance for safe handling, use, processing, storage, transportation, disposal and release and is

not to be considered a warranty or quality specification. The information relates only to the specific

material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

Product and Company Identification: Alternate Trade Names

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SAFETY DATA SHEET

1. Identification

Product identifier INHIBITAUR High Solids FLAT BLACK

Company information CONTINENTAL RESEARCH CORPORATION P.O. Box 15204 St. Louis, MO 63110

Company phone 800-325-4869

Emergency telephone US 888-255-3924 (CHEM-TEL)

Version # 01

Recommended use COATING

Recommended restrictions None known.

2. Hazard(s) identification

Physical hazards

Health hazards

Environmental hazards

OSHA defined hazards

Label elements

Flammable aerosols

Serious eye damage/eye irritation

Carcinogenicity

Specific target organ toxicity, single exposure

Not classified.

Not classified.

Category 1

Category 2A

Category 2

Category 3 narcotic effects

Signal word Danger

Hazard statement Extremely flammable aerosol. Causes serious eye irritation. May cause drowsiness or dizziness. Suspected of causing cancer.

Precautionary statement

Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read

and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing gas. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection.

Response If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse

cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If exposed or concerned: Get medical advice/attention. Call a poison center/doctor if you feel unwell. If eye irritation persists: Get medical advice/attention.

Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect from

sunlight. Do not expose to temperatures exceeding 50°C/122°F.

Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.

Hazard(s) not otherwise

classified (HNOC) None known.

Supplemental information None.

3. Composition/information on ingredients

Mixtures

Chemical name Common name and synonyms

CAS number %

Acetone 67-64-1 20 - 40

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Chemical name Common name and synonyms CAS number %

Calcium Carbonate

Propane

Butane

Ethylene Glycol Propyl Ether

Methyl Isobutyl Ketone

Methyl Propyl Ketone

Propylene Glycol Monomethyl Ether Acetate

Solvent Naphtha (petroleum), Light Aliph.

Isobutyl Acetate

Carbon Black

1317-65-3

74-98-6

106-97-8

2807-30-9

108-10-1

107-87-9

108-65-6

64742-89-8

110-19-0

1333-86-4

10 - 20

10 - 20

2.5 - 10

2.5 - 10

2.5 - 10

2.5 - 10

2.5 - 10

2.5 - 10

1 - 2.5

0.1 - 1

Other components below reportable levels 10 - 20

*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures

Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON

CENTER or doctor/physician if you feel unwell.

Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists.

Eye contact Rinse with water. Get medical attention if irritation develops and persists.

Ingestion Rinse mouth. Get medical attention if symptoms occur.

Most important

symptoms/effects, acute and

delayed

Indication of immediate

medical attention and special

treatment needed

May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision.

Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed.

General information IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.

5. Fire-fighting measures

Suitable extinguishing media Powder. Alcohol resistant foam. Carbon dioxide (CO2).

Unsuitable extinguishing

media

Specific hazards arising from

the chemical

Special protective equipment

and precautions for firefighters

Fire-fighting

equipment/instructions

Do not use water jet as an extinguisher, as this will spread the fire.

Contents under pressure. Pressurized container may explode when exposed to heat or flame.

Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA.

Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out.

Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. Move

containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes.

General fire hazards Extremely flammable aerosol.

6. Accidental release measures

Personal precautions,

protective equipment and

emergency procedures

Methods and materials for

containment and cleaning up

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Avoid breathing gas. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.

Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Prevent entry into waterways, sewer, basements or confined areas. For waste disposal, see section 13 of the SDS.

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Environmental precautions Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage

Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read

and understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Avoid breathing gas. Avoid contact with eyes. Avoid prolonged exposure. Use only in well-ventilated areas. Should be handled in closed systems, if possible. Wear appropriate personal protective equipment. Observe good industrial hygiene practices.

Conditions for safe storage,

including any incompatibilities

Level 1 Aerosol.

Store locked up. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). Level 1 Aerosol (NFPA 30B)

8. Exposure controls/personal protection

Occupational exposure limits

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

Components Type Value Form

Acetone (CAS 67-64-1) PEL 2400 mg/m3 1000 ppm Calcium Carbonate (CAS 1317-65-3)

PEL 5 mg/m3 Respirable fraction.

15 mg/m3 Total dust.

Carbon Black (CAS 1333-86-4)

PEL 3.5 mg/m3

Isobutyl Acetate (CAS 110-19-0)

PEL 700 mg/m3

150 ppm Methyl Isobutyl Ketone (CAS 108-10-1)

PEL 410 mg/m3

100 ppm Methyl Propyl Ketone (CAS 107-87-9)

PEL 700 mg/m3

200 ppm Propane (CAS 74-98-6) PEL 1800 mg/m3

1000 ppm ACGIH Components Type Value

Solvent Naphtha (petroleum), Light Aliph. (CAS 64742-89-8)

TWA 400 ppm

US. ACGIH Threshold Limit Values Components Type Value Form

Acetone (CAS 67-64-1) STEL 750 ppm TWA 500 ppm Butane (CAS 106-97-8) STEL 1000 ppm Carbon Black (CAS 1333-86-4)

TWA 3 mg/m3 Inhalable fraction.

Isobutyl Acetate (CAS 110-19-0)

TWA 150 ppm

Methyl Isobutyl Ketone (CAS 108-10-1)

STEL 75 ppm

TWA 20 ppm Methyl Propyl Ketone (CAS 107-87-9)

STEL 150 ppm

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US. NIOSH: Pocket Guide to Chemical Hazards

Components Type Value Form

Acetone (CAS 67-64-1)

Butane (CAS 106-97-8)

Calcium Carbonate (CAS 1317-65-3)

Carbon Black (CAS 1333-86-4)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Propane (CAS 74-98-6)

TWA 590 mg/m3

250 ppm

TWA 1900 mg/m3

800 ppm

TWA 5 mg/m3 Respirable.

10 mg/m3 Total

TWA 0.1 mg/m3

TWA 700 mg/m3

150 ppm

STEL 300 mg/m3

75 ppm

TWA 205 mg/m3

50 ppm

TWA 530 mg/m3

150 ppm

TWA 1800 mg/m3

1000 ppm

US. Workplace Environmental Exposure Level (WEEL) Guides

Components Type

Value

Propylene Glycol Monomethyl Ether Acetate (CAS 108-65-6)

Biological limit values

ACGIH Biological Exposure Indices

TWA 50 ppm

Components Value Determinant Specimen Sampling Time

Acetone (CAS 67-64-1) 50 mg/l Acetone Urine *

Methyl Isobutyl Ketone (CAS 108-10-1)

1 mg/l Methyl isobutyl ketone

Urine *

* - For sampling details, please see the source document.

Exposure guidelines

US - California OELs: Skin designation

Propylene Glycol Monomethyl Ether Acetate (CAS 108-65-6)

Can be absorbed through the skin.

Appropriate engineering

controls

Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station.

Individual protection measures, such as personal protective equipment

Eye/face protection Wear safety glasses with side shields (or goggles).

Hand protection Wear appropriate chemical resistant gloves.

Skin protection

Other Wear suitable protective clothing. Use of an impervious apron is recommended.

Skin protection

Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator.

Thermal hazards Wear appropriate thermal protective clothing, when necessary.

General hygiene

considerations

When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.

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9. Physical and chemical properties

Appearance

Physical state Gas.

Form Aerosol.

Color Not available.

Odor Not available.

Odor threshold Not available.

pH Not available.

Melting point/freezing point Not available.

Initial boiling point and boiling

range

73.81 °F (23.23 °C) estimated

Flash point -2.2 °F (-19.0 °C) SUPPLIER

Evaporation rate Not available.

Flammability (solid, gas) Not available.

Upper/lower flammability or explosive limits

Flammability limit - lower (%)

Flammability limit - upper

(%)

Not available.

Not available.

Explosive limit - lower (%) Not available.

Explosive limit - upper (%) Not available.

Vapor pressure 2750 hPa SUPPLIER estimated

Vapor density Not available.

Relative density Not available.

Solubility(ies)

Solubility (water) Not available.

Partition coefficient

(n-octanol/water)

Not available.

Auto-ignition temperature Not available.

Decomposition temperature Not available.

Viscosity Not available.

Other information

Specific gravity 0.85 SUPPLIER estimated

10. Stability and reactivity

Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.

Chemical stability Material is stable under normal conditions.

Possibility of hazardous

reactions

Hazardous polymerization does not occur.

Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials.

Incompatible materials Strong oxidizing agents. Nitrates. Fluorine. Chlorine.

Hazardous decomposition

products

No hazardous decomposition products are known.

11. Toxicological information

Information on likely routes of exposure

Ingestion Expected to be a low ingestion hazard.

Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be harmful.

Skin contact No adverse effects due to skin contact are expected.

Eye contact Causes serious eye irritation.

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Symptoms related to the

physical, chemical and

toxicological characteristics

May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision.

Information on toxicological effects

Acute toxicity Narcotic effects.

Components Species

Acetone (CAS 67-64-1)

Acute

Dermal

LD50 Guinea pig

Test Results

> 7426 mg/kg, 24 Hours

> 9.4 ml/kg, 24 Hours

Inhalation

Rabbit > 7426 mg/kg, 24 Hours

> 9.4 ml/kg, 24 Hours

LC50 Rat

Oral

LD50 Rat

Butane (CAS 106-97-8)

Acute

Inhalation

LC50 Mouse

55700 ppm, 3 Hours

132 mg/l, 3 Hours

50.1 mg/l

5800 mg/kg

2.2 ml/kg

1237 mg/l, 120 Minutes

52 %, 120 Minutes

Carbon Black (CAS 1333-86-4)

Acute

Oral

Rat 1355 mg/l

LD50 Rat

Ethylene Glycol Propyl Ether (CAS 2807-30-9)

Acute

Dermal

LD50 Guinea pig

> 8000 mg/kg

5.6 g/kg, 4 Days

Inhalation

Rabbit > 1 g/kg, 24 Hours

1337 ml/kg, 14 Days

LC50 Rat

Oral

LD50 Guinea pig

> 2132 ppm, 6 Hours

> 1800 ppm

2.2 g/kg

Isobutyl Acetate (CAS 110-19-0)

Acute

Dermal

Mouse 1774 mg/kg

Rat 0.5 - 1 g/kg

LD50 Rabbit

Inhalation

LC50 Rat

> 17400 mg/kg, 24 Hours

> 30 mg/l, 6 Hours

> 23.4 mg/l, 4 Hours

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Components

Species

Oral

LD50 Rat

Methyl Isobutyl Ketone (CAS 108-10-1)

Acute

Inhalation

LC50 Rat

Oral

LD50 Rat

Propane (CAS 74-98-6)

Acute

Inhalation

LC50 Mouse

Test Results

13413 mg/kg

2000 - 4000 ppm, 4 Hours

2.08 g/kg

1237 mg/l, 120 Minutes

52 %, 120 Minutes

Rat 1355 mg/l

658 mg/l/4h

Propylene Glycol Monomethyl Ether Acetate (CAS 108-65-6)

Acute

Dermal

LD50 Rat

Oral

LD50 Rat

Solvent Naphtha (petroleum), Light Aliph. (CAS 64742-89-8)

Acute

Dermal

LD50 Rabbit

Inhalation

LC50 Rat

Oral

LD50 Rat

> 2000 mg/kg, 24 Hours

> 14.1 ml

5155 mg/kg

> 1900 mg/kg, 24 Hours

> 5020 mg/m3, 4 Hours

> 4980 mg/m3

> 4980 mg/m3, 4 Hours

> 4.96 mg/l, 4 Hours

4820 mg/kg

* Estimates for product may be based on additional component data not shown.

Skin corrosion/irritation Not applicable.

Serious eye damage/eye

irritation

Respiratory or skin sensitization

Causes serious eye irritation.

Respiratory sensitization Not available.

Skin sensitization This product is not expected to cause skin sensitization.

Germ cell mutagenicity Not applicable.

Carcinogenicity Suspected of causing cancer.

IARC Monographs. Overall Evaluation of Carcinogenicity

Carbon Black (CAS 1333-86-4) 2B Possibly carcinogenic to humans.

Methyl Isobutyl Ketone (CAS 108-10-1) 2B Possibly carcinogenic to humans.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.

Reproductive toxicity Not applicable.

Specific target organ toxicity -

single exposure

May cause drowsiness and dizziness.

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Specific target organ toxicity -

repeated exposure

Not classified.

Aspiration hazard Not likely, due to the form of the product.

Chronic effects Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects.

12. Ecological information

Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the

possibility that large or frequent spills can have a harmful or damaging effect on the environment.

Components

Acetone (CAS 67-64-1)

Aquatic

Crustacea

Fish

EC50

LC50

Species

Water flea (Daphnia magna)

Rainbow trout,donaldson trout (Oncorhynchus mykiss)

Test Results

21.6 - 23.9 mg/l, 48 hours

4740 - 6330 mg/l, 96 hours

Methyl Isobutyl Ketone (CAS 108-10-1)

Aquatic

Fish LC50 Fathead minnow (Pimephales promelas) 492 - 593 mg/l, 96 hours

Methyl Propyl Ketone (CAS 107-87-9)

Aquatic

Fish LC50 Fathead minnow (Pimephales promelas) 1190 - 1290 mg/l, 96 hours

Propylene Glycol Monomethyl Ether Acetate (CAS 108-65-6)

Aquatic

Crustacea EC50 Daphnia 500.0001 mg/L, 48 Hours

Solvent Naphtha (petroleum), Light Aliph. (CAS 64742-89-8)

Aquatic

Algae IC50 Algae 4700 mg/L, 72 Hours

* Estimates for product may be based on additional component data not shown.

Persistence and degradability No data is available on the degradability of this product.

Bioaccumulative potential No data available.

Partition coefficient n-octanol / water (log Kow) Acetone -0.24

Butane 2.89

Isobutyl Acetate 1.78

Methyl Isobutyl Ketone 1.31

Methyl Propyl Ketone 0.91

Propane 2.36

Mobility in soil No data available.

Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations

Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents

under pressure. Do not puncture, incinerate or crush. Dispose of contents/container in accordance with local/regional/national/international regulations.

Local disposal regulations Dispose in accordance with all applicable regulations.

Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste

disposal company.

US RCRA Hazardous Waste U List: Reference

Acetone (CAS 67-64-1) U002

Methyl Isobutyl Ketone (CAS 108-10-1) U161

Waste from residues / unused

products

Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).

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Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers.

14. Transport information

DOT

UN number

UN proper shipping name

Transport hazard class(es)

Class

Subsidiary risk

Label(s)

Packing group

UN1950

Aerosols, flammable

2.1

-

2.1

Not applicable.

Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling.

Special provisions

Packaging exceptions

Packaging non bulk

Packaging bulk

N82

306

None

None

This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond

mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently.

IATA

UN number

UN proper shipping name

Transport hazard class(es)

Class

Subsidiary risk

Label(s)

Packing group

Environmental hazards

ERG Code

UN1950

Aerosols, flammable

2.1

-

2.1

Not applicable.

No.

10L

Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling.

Other information

Passenger and cargo

aircraft

Cargo aircraft only

Packaging Exceptions

IMDG

UN number

UN proper shipping name

Transport hazard class(es)

Class

Subsidiary risk

Label(s)

Packing group

Environmental hazards

Marine pollutant

EmS

Allowed.

Allowed.

LTD QTY

UN1950

AEROSOLS

2.1

-

2.1

Not applicable.

No.

F-D, S-U

Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling.

Packaging Exceptions

Transport in bulk according to

Annex II of MARPOL 73/78 and

the IBC Code

LTD QTY

Not applicable.

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DOT

IATA; IMDG

15. Regulatory information

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication

Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

Not regulated.

CERCLA Hazardous Substance List (40 CFR 302.4)

Acetone (CAS 67-64-1) Listed.

Isobutyl Acetate (CAS 110-19-0) Listed.

Methyl Isobutyl Ketone (CAS 108-10-1) Listed.

SARA 304 Emergency release notification

Not regulated.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No

SARA 302 Extremely hazardous substance

Not listed.

SARA 311/312 Hazardous No

chemical

SARA 313 (TRI reporting)

Chemical name CAS number % by wt.

Methyl Isobutyl Ketone 108-10-1 2.5 - 10

Ethyl Benzene 100-41-4 0.1 - 1

Other federal regulations

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List

Methyl Isobutyl Ketone (CAS 108-10-1)

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)

Butane (CAS 106-97-8)

Propane (CAS 74-98-6)

Safe Drinking Water Act

(SDWA)

Not regulated.

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Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and

Chemical Code Number

Acetone (CAS 67-64-1) 6532

Methyl Isobutyl Ketone (CAS 108-10-1) 6715

Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))

Acetone (CAS 67-64-1) 35 %WV

Methyl Isobutyl Ketone (CAS 108-10-1) 35 %WV

DEA Exempt Chemical Mixtures Code Number

Acetone (CAS 67-64-1) 6532

Methyl Isobutyl Ketone (CAS 108-10-1) 6715

US state regulations

US. Massachusetts RTK - Substance List

Acetone (CAS 67-64-1)

Butane (CAS 106-97-8)

Calcium Carbonate (CAS 1317-65-3)

Carbon Black (CAS 1333-86-4)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Propane (CAS 74-98-6)

US. New Jersey Worker and Community Right-to-Know Act

Acetone (CAS 67-64-1)

Butane (CAS 106-97-8)

Calcium Carbonate (CAS 1317-65-3)

Carbon Black (CAS 1333-86-4)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Propane (CAS 74-98-6)

US. Pennsylvania Worker and Community Right-to-Know Law

Acetone (CAS 67-64-1)

Butane (CAS 106-97-8)

Calcium Carbonate (CAS 1317-65-3)

Carbon Black (CAS 1333-86-4)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Propane (CAS 74-98-6)

US. Rhode Island RTK

Acetone (CAS 67-64-1)

Butane (CAS 106-97-8)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Propane (CAS 74-98-6)

US. California Proposition 65

WARNING: This product contains a chemical known to the State of California to cause cancer.

US - California Proposition 65 - CRT: Listed date/Carcinogenic substance

Carbon Black (CAS 1333-86-4) Listed: February 21, 2003

Ethyl Benzene (CAS 100-41-4) Listed: June 11, 2004

Methyl Isobutyl Ketone (CAS 108-10-1) Listed: November 4, 2011

International Inventories

Country(s) or region Inventory name On inventory (yes/no)*

Australia Australian Inventory of Chemical Substances (AICS)

Canada Domestic Substances List (DSL)

Canada Non-Domestic Substances List (NDSL)

China Inventory of Existing Chemical Substances in China (IECSC)

Europe European Inventory of Existing Commercial Chemical Substances (EINECS)

Europe European List of Notified Chemical Substances (ELINCS)

No

No

Yes

No

No

No

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Country(s) or region Inventory name On inventory (yes/no)*

Japan Inventory of Existing and New Chemical Substances (ENCS)

Korea Existing Chemicals List (ECL)

New Zealand New Zealand Inventory

Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS)

United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)

No

No

No

Yes

Yes

A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s).

16. Other information, including date of preparation or last revision

Issue date 04-25-2016

Version # 01

Issued By: EHS Administrator

Disclaimer We cannot anticipate all conditions under which this information and its product, or the products of

other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

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SAFETY DATA SHEET

1. Identification

Product identifier INHIBITAUR High Solids FLAT WHITE

Revision date 04-25-2016

Company information CONTINENTAL RESEARCH CORPORATION P.O. Box 15204 ST LOUIS, MO 63110 United States

Company phone 800-325-4869

Emergency telephone US 888-255-3924 (CHEM-TEL)

Version # 02

Supersedes date 07-30-2015

Recommended use COATING

Recommended restrictions None known.

2. Hazard(s) identification

Physical hazards

Health hazards

Environmental hazards

OSHA defined hazards

Label elements

Flammable aerosols

Serious eye damage/eye irritation

Reproductive toxicity (the unborn child)

Specific target organ toxicity, repeated exposure

Not classified.

Not classified.

Category 1

Category 2A

Category 2

Category 2

Signal word Danger

Hazard statement Extremely flammable aerosol. Causes serious eye irritation. Suspected of damaging the unborn child. May cause damage to organs through prolonged or repeated exposure.

Precautionary statement

Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read

and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe gas. Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection.

Response If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and

easy to do. Continue rinsing. If exposed or concerned: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Collect spillage.

Storage Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.

Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.

Hazard(s) not otherwise

classified (HNOC) None known.

Supplemental information None.

3. Composition/information on ingredients

Mixtures

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Chemical name Common name and synonyms CAS number %

Acetone

Calcium Carbonate

Propane

Butane

Isobutyl Acetate

Propylene Glycol Monomethyl Ether Acetate

Titanium dioxide

Toluene

Trizinc Bis(orthophosphate)

Ethylene Glycol Propyl Ether

Methyl Isobutyl Ketone

Methyl Propyl Ketone

Xylene

67-64-1

1317-65-3

74-98-6

106-97-8

110-19-0

108-65-6

13463-67-7

108-88-3

7779-90-0

2807-30-9

108-10-1

107-87-9

1330-20-7

10 - 20

10 - 20

10 - 20

2.5 - 10

2.5 - 10

2.5 - 10

2.5 - 10

2.5 - 10

2.5 - 10

1 - 2.5

1 - 2.5

1 - 2.5

1 - 2.5

Other components below reportable levels 10 - 20

*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures

Inhalation Move to fresh air. Call a physician if symptoms develop or persist.

Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists.

Eye contact Rinse with water. Get medical attention if irritation develops and persists.

Ingestion Rinse mouth. Get medical attention if symptoms occur.

Most important

symptoms/effects, acute and

delayed

Indication of immediate

medical attention and special

treatment needed

Dizziness. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Prolonged exposure may cause chronic effects.

Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed.

General information IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice

(show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance.

5. Fire-fighting measures

Suitable extinguishing media Powder. Alcohol resistant foam. Carbon dioxide (CO2).

Unsuitable extinguishing

media

Specific hazards arising from

the chemical

Special protective equipment

and precautions for firefighters

Fire-fighting

equipment/instructions

Do not use water jet as an extinguisher, as this will spread the fire.

Contents under pressure. Pressurized container may explode when exposed to heat or flame.

Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA.

Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose

holder or monitor nozzles, if possible. If not, withdraw and let fire burn out.

Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. Move

containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes.

General fire hazards Extremely flammable aerosol.

6. Accidental release measures

Personal precautions,

protective equipment and

emergency procedures

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Do not breathe gas. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.

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Methods and materials for

containment and cleaning up

Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. For waste disposal, see section 13 of the SDS.

Environmental precautions Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all

environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage

Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read

and understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Do not breathe gas. Avoid contact with eyes. Avoid prolonged exposure. Use only in well-ventilated areas. Should be handled in closed systems, if possible. Pregnant or breastfeeding women must not handle this product. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices.

Conditions for safe storage,

including any incompatibilities

Level 1 Aerosol.

Store locked up. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS).

8. Exposure controls/personal protection

Occupational exposure limits

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

Components Type Value Form

Acetone (CAS 67-64-1) PEL 2400 mg/m3 1000 ppm Calcium Carbonate (CAS 1317-65-3)

PEL 5 mg/m3 Respirable fraction.

15 mg/m3 Total dust.

Isobutyl Acetate (CAS 110-19-0)

PEL 700 mg/m3

150 ppm Methyl Isobutyl Ketone (CAS 108-10-1)

PEL 410 mg/m3

100 ppm Methyl Propyl Ketone (CAS 107-87-9)

PEL 700 mg/m3

200 ppm Propane (CAS 74-98-6) PEL 1800 mg/m3

1000 ppm Titanium dioxide (CAS 13463-67-7)

PEL 15 mg/m3 Total dust.

Xylene (CAS 1330-20-7) PEL 435 mg/m3 100 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) Components Type Value

Toluene (CAS 108-88-3) Ceiling 300 ppm TWA 200 ppm US. ACGIH Threshold Limit Values Components Type Value

Acetone (CAS 67-64-1) STEL 750 ppm TWA 500 ppm Butane (CAS 106-97-8) STEL 1000 ppm

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US. ACGIH Threshold Limit Values

Components Type

Value

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Titanium dioxide (CAS 13463-67-7)

Toluene (CAS 108-88-3)

Xylene (CAS 1330-20-7)

TWA 150 ppm

STEL 75 ppm

TWA 20 ppm

STEL 150 ppm

TWA 10 mg/m3

TWA 20 ppm

STEL 150 ppm

TWA 100 ppm

US. NIOSH: Pocket Guide to Chemical Hazards

Components Type Value Form

Acetone (CAS 67-64-1)

Butane (CAS 106-97-8)

Calcium Carbonate (CAS 1317-65-3)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Propane (CAS 74-98-6)

Toluene (CAS 108-88-3)

TWA 590 mg/m3

250 ppm

TWA 1900 mg/m3

800 ppm

TWA 5 mg/m3 Respirable.

10 mg/m3 Total

TWA 700 mg/m3

150 ppm

STEL 300 mg/m3

75 ppm

TWA 205 mg/m3

50 ppm

TWA 530 mg/m3

150 ppm

TWA 1800 mg/m3

1000 ppm

STEL 560 mg/m3

150 ppm

TWA 375 mg/m3

100 ppm

US. Workplace Environmental Exposure Level (WEEL) Guides

Components Type

Value

Propylene Glycol Monomethyl Ether Acetate (CAS 108-65-6)

Biological limit values

ACGIH Biological Exposure Indices

TWA 50 ppm

Components Value Determinant Specimen Sampling Time

Acetone (CAS 67-64-1) 50 mg/l Acetone Urine *

Methyl Isobutyl Ketone (CAS 108-10-1)

1 mg/l Methyl isobutyl ketone

Urine *

Toluene (CAS 108-88-3) 0.3 mg/g o-Cresol, with hydrolysis

Creatinine in urine

*

0.03 mg/l Toluene Urine *

0.02 mg/l Toluene Blood *

Xylene (CAS 1330-20-7) 1.5 g/g Methylhippuric acids

Creatinine in urine

*

* - For sampling details, please see the source document.

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Exposure guidelines

US - California OELs: Skin designation

Propylene Glycol Monomethyl Ether Acetate (CAS 108-65-6)

Can be absorbed through the skin.

Toluene (CAS 108-88-3) Can be absorbed through the skin.

US - Minnesota Haz Subs: Skin designation applies

Toluene (CAS 108-88-3) Skin designation applies.

Appropriate engineering

controls

Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station.

Individual protection measures, such as personal protective equipment

Eye/face protection Wear safety glasses with side shields (or goggles).

Hand protection Wear appropriate chemical resistant gloves.

Skin protection

Other Wear suitable protective clothing. Use of an impervious apron is recommended.

Skin protection

Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an

air-supplied respirator.

Thermal hazards Wear appropriate thermal protective clothing, when necessary.

General hygiene

considerations

When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.

9. Physical and chemical properties

Appearance

Physical state Gas.

Form Aerosol.

Color Not available.

Odor Not available.

Odor threshold Not available.

pH Not available.

Melting point/freezing point Not available.

Initial boiling point and boiling

range

755.67 °F (402.04 °C) estimated

Flash point -2.2 °F (-19.0 °C) SUPPLIER

Evaporation rate Not available.

Flammability (solid, gas) Not available.

Upper/lower flammability or explosive limits

Flammability limit - lower

(%)

Flammability limit - upper

(%)

Not available.

Not available.

Explosive limit - lower (%) Not available.

Explosive limit - upper (%) Not available.

Vapor pressure 2750 hPa SUPPLIER estimated

Vapor density Not available.

Relative density Not available.

Solubility(ies)

Solubility (water) Not available.

Partition coefficient

(n-octanol/water)

Not available.

Auto-ignition temperature Not available.

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Decomposition temperature Not available.

Viscosity Not available.

Other information

Specific gravity 0.85 SUPPLIER estimated

10. Stability and reactivity

Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.

Chemical stability Material is stable under normal conditions.

Possibility of hazardous

reactions

Hazardous polymerization does not occur.

Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials.

Incompatible materials Strong acids. Strong oxidizing agents. Nitrates. Halogens. Fluorine. Chlorine.

Hazardous decomposition

products

No hazardous decomposition products are known.

11. Toxicological information

Information on likely routes of exposure

Ingestion Expected to be a low ingestion hazard.

Inhalation May cause damage to organs through prolonged or repeated exposure by inhalation. Prolonged inhalation may be harmful.

Skin contact No adverse effects due to skin contact are expected.

Eye contact Causes serious eye irritation.

Symptoms related to the

physical, chemical and

toxicological characteristics

Dizziness. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision.

Information on toxicological effects

Acute toxicity

Components Species

Acetone (CAS 67-64-1)

Acute

Dermal

LD50 Guinea pig

Test Results

> 7426 mg/kg, 24 Hours

> 9.4 ml/kg, 24 Hours

Inhalation

Rabbit > 7426 mg/kg, 24 Hours

> 9.4 ml/kg, 24 Hours

LC50 Rat

Oral

LD50 Rat

Butane (CAS 106-97-8)

Acute

Inhalation

LC50 Mouse

55700 ppm, 3 Hours

132 mg/l, 3 Hours

50.1 mg/l

5800 mg/kg

2.2 ml/kg

1237 mg/l, 120 Minutes

52 %, 120 Minutes

Rat 1355 mg/l

Ethylene Glycol Propyl Ether (CAS 2807-30-9)

Acute

Dermal

LD50 Guinea pig 5.6 g/kg, 4 Days

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Components Species Test Results

Inhalation

Rabbit > 1 g/kg, 24 Hours

1337 ml/kg, 14 Days

LC50 Rat

Oral

LD50 Guinea pig

> 2132 ppm, 6 Hours

> 1800 ppm

2.2 g/kg

Isobutyl Acetate (CAS 110-19-0)

Acute

Dermal

Mouse 1774 mg/kg

Rat 0.5 - 1 g/kg

LD50 Rabbit

Inhalation

LC50 Rat

Oral

LD50 Rat

Methyl Isobutyl Ketone (CAS 108-10-1)

Acute

Inhalation

LC50 Rat

Oral

LD50 Rat

Propane (CAS 74-98-6)

Acute

Inhalation

LC50 Mouse

> 17400 mg/kg, 24 Hours

> 30 mg/l, 6 Hours

> 23.4 mg/l, 4 Hours

13413 mg/kg

2000 - 4000 ppm, 4 Hours

2.08 g/kg

1237 mg/l, 120 Minutes

52 %, 120 Minutes

Rat 1355 mg/l

658 mg/l/4h

Propylene Glycol Monomethyl Ether Acetate (CAS 108-65-6)

Acute

Dermal

LD50 Rat

Oral

LD50 Rat

Titanium dioxide (CAS 13463-67-7)

Acute

Inhalation

LC50 Rat

Oral

LD50 Rat

Toluene (CAS 108-88-3)

Acute

Dermal

LD50 Rabbit

> 2000 mg/kg, 24 Hours

> 14.1 ml

5155 mg/kg

> 2.28 mg/l, 4 Hours

> 11000 mg/kg

> 5000 mg/kg, 24 Hours

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Components Species Test Results

Inhalation

LC50 Mouse

6405 - 7436 ppm, 6 Hours

5320 ppm, 8 Hours

Oral

Rat 5879 - 6281 ppm, 6 Hours

12.5 - 28.8 mg/l, 4 Hours

LD50 Rat

Trizinc Bis(orthophosphate) (CAS 7779-90-0)

Acute

Inhalation

LC50 Rat

Xylene (CAS 1330-20-7)

Acute

Dermal

LD50 Rabbit

Inhalation

LC50 Rat

Oral

LD50 Mouse

5000 mg/kg

> 5410 mg/m3

> 5000 ml/kg, 4 Hours

12126 mg/kg, 24 Hours

5922 ppm, 4 Hours

5251 mg/kg

Rat 3523 mg/kg

10 ml/kg

* Estimates for product may be based on additional component data not shown.

Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.

Serious eye damage/eye

irritation

Respiratory or skin sensitization

Causes serious eye irritation.

Respiratory sensitization Not available.

Skin sensitization This product is not expected to cause skin sensitization.

Germ cell mutagenicity Not applicable.

Carcinogenicity Risk of cancer cannot be excluded with prolonged exposure.

IARC Monographs. Overall Evaluation of Carcinogenicity

Methyl Isobutyl Ketone (CAS 108-10-1) 2B Possibly carcinogenic to humans.

Titanium dioxide (CAS 13463-67-7) 2B Possibly carcinogenic to humans.

Toluene (CAS 108-88-3) 3 Not classifiable as to carcinogenicity to humans.

Xylene (CAS 1330-20-7) 3 Not classifiable as to carcinogenicity to humans.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.

Reproductive toxicity Components in this product have been shown to cause birth defects and reproductive disorders in laboratory animals. Suspected of damaging the unborn child.

Specific target organ toxicity -

single exposure

Specific target organ toxicity -

repeated exposure

Not classified.

Respiratory system. Skin. Kidneys. Central nervous system. Eyes. Liver. May cause damage to organs through prolonged or repeated exposure.

Aspiration hazard Not likely, due to the form of the product.

Chronic effects Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects. May cause

damage to organs through prolonged or repeated exposure.

12. Ecological information

Ecotoxicity Toxic to aquatic life with long lasting effects.

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Components

Acetone (CAS 67-64-1)

Aquatic

Crustacea

Fish

EC50

LC50

Species

Water flea (Daphnia magna)

Rainbow trout,donaldson trout (Oncorhynchus mykiss)

Test Results

21.6 - 23.9 mg/l, 48 hours

4740 - 6330 mg/l, 96 hours

Methyl Isobutyl Ketone (CAS 108-10-1)

Aquatic

Fish LC50 Fathead minnow (Pimephales promelas) 492 - 593 mg/l, 96 hours

Methyl Propyl Ketone (CAS 107-87-9)

Aquatic

Fish LC50 Fathead minnow (Pimephales promelas) 1190 - 1290 mg/l, 96 hours

Propylene Glycol Monomethyl Ether Acetate (CAS 108-65-6)

Aquatic

Crustacea EC50 Daphnia 500.0001 mg/L, 48 Hours

Titanium dioxide (CAS 13463-67-7)

Aquatic

Crustacea

Fish

Toluene (CAS 108-88-3)

Aquatic

Algae

Crustacea

Fish

EC50

LC50

IC50

EC50

LC50

Water flea (Daphnia magna)

Mummichog (Fundulus heteroclitus)

Algae

Daphnia

Water flea (Daphnia magna)

Coho salmon,silver salmon (Oncorhynchus kisutch)

> 1000 mg/l, 48 hours

> 1000 mg/l, 96 hours

433.0001 mg/L, 72 Hours

7.645 mg/L, 48 Hours

5.46 - 9.83 mg/l, 48 hours

8.11 mg/l, 96 hours

Trizinc Bis(orthophosphate) (CAS 7779-90-0)

Aquatic

Fish

Xylene (CAS 1330-20-7)

Aquatic

Fish

LC50

LC50

Rainbow trout,donaldson trout (Oncorhynchus mykiss)

Bluegill (Lepomis macrochirus)

0.09 mg/l, 96 hours

7.711 - 9.591 mg/l, 96 hours

* Estimates for product may be based on additional component data not shown.

Persistence and degradability No data is available on the degradability of this product.

Bioaccumulative potential No data available.

Partition coefficient n-octanol / water (log Kow) Acetone -0.24

Butane 2.89

Isobutyl Acetate 1.78

Methyl Isobutyl Ketone 1.31

Methyl Propyl Ketone 0.91

Propane 2.36

Toluene 2.73

Xylene 3.12 - 3.2

Mobility in soil No data available.

Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation

potential, endocrine disruption, global warming potential) are expected from this component.

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13. Disposal considerations

Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents

under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations.

Local disposal regulations Dispose in accordance with all applicable regulations.

Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company.

US RCRA Hazardous Waste U List: Reference

Acetone (CAS 67-64-1) U002

Methyl Isobutyl Ketone (CAS 108-10-1) U161

Toluene (CAS 108-88-3) U220

Xylene (CAS 1330-20-7) U239

Waste from residues / unused

products

Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).

Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers.

14. Transport information

DOT

UN number

UN proper shipping name

Transport hazard class(es)

Class

Subsidiary risk

Label(s)

Packing group

UN1950

Aerosols, flammable

2.1

-

2.1

Not applicable.

Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling.

Special provisions

Packaging exceptions

Packaging non bulk

Packaging bulk

N82

306

None

None

This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently.

IATA

UN number

UN proper shipping name

Transport hazard class(es)

Class

Subsidiary risk

Label(s)

Packing group

Environmental hazards

ERG Code

UN1950

Aerosols, flammable

2.1

-

2.1

Not applicable.

Yes

10L

Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety

instructions, SDS and emergency procedures before handling.

Other information

Passenger and cargo

aircraft

Cargo aircraft only

Packaging Exceptions

IMDG

UN number

UN proper shipping name

Allowed.

Allowed.

LTD QTY

UN1950

AEROSOLS

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Transport hazard class(es)

Class

Subsidiary risk

Label(s)

Packing group

Environmental hazards

Marine pollutant

EmS

2.1

-

2.1

Not applicable.

Yes

F-D, S-U

Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety

instructions, SDS and emergency procedures before handling.

Packaging Exceptions

Transport in bulk according to

Annex II of MARPOL 73/78 and

the IBC Code

DOT

IATA; IMDG

Marine pollutant

LTD QTY

Not applicable.

General information IMDG Regulated Marine Pollutant.

15. Regulatory information

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication

Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

Not regulated.

CERCLA Hazardous Substance List (40 CFR 302.4)

Acetone (CAS 67-64-1) Listed.

Isobutyl Acetate (CAS 110-19-0) Listed.

Methyl Isobutyl Ketone (CAS 108-10-1) Listed.

Toluene (CAS 108-88-3) Listed.

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Xylene (CAS 1330-20-7) Listed.

SARA 304 Emergency release notification

Not regulated.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No

SARA 302 Extremely hazardous substance

Not listed.

SARA 311/312 Hazardous

chemical

No

SARA 313 (TRI reporting) Chemical name CAS number % by wt.

Toluene 108-88-3 2.5 - 10 Methyl Isobutyl Ketone 108-10-1 1 - 2.5

Xylene 1330-20-7 1 - 2.5

Ethyl Benzene 100-41-4 0.1 - 1

Other federal regulations

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List

Methyl Isobutyl Ketone (CAS 108-10-1)

Toluene (CAS 108-88-3)

Xylene (CAS 1330-20-7)

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)

Butane (CAS 106-97-8)

Propane (CAS 74-98-6)

Safe Drinking Water Act

(SDWA)

Not regulated.

Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and

Chemical Code Number

Acetone (CAS 67-64-1) 6532

Methyl Isobutyl Ketone (CAS 108-10-1) 6715

Toluene (CAS 108-88-3) 6594

Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))

Acetone (CAS 67-64-1) 35 %WV

Methyl Isobutyl Ketone (CAS 108-10-1) 35 %WV

Toluene (CAS 108-88-3) 35 %WV

DEA Exempt Chemical Mixtures Code Number

Acetone (CAS 67-64-1) 6532

Methyl Isobutyl Ketone (CAS 108-10-1) 6715

Toluene (CAS 108-88-3) 594

US state regulations

US. Massachusetts RTK - Substance List

Acetone (CAS 67-64-1)

Butane (CAS 106-97-8)

Calcium Carbonate (CAS 1317-65-3)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Propane (CAS 74-98-6)

Titanium dioxide (CAS 13463-67-7)

Toluene (CAS 108-88-3)

Xylene (CAS 1330-20-7)

US. New Jersey Worker and Community Right-to-Know Act

Acetone (CAS 67-64-1)

Butane (CAS 106-97-8)

Calcium Carbonate (CAS 1317-65-3)

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Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Propane (CAS 74-98-6)

Titanium dioxide (CAS 13463-67-7)

Toluene (CAS 108-88-3)

Xylene (CAS 1330-20-7)

US. Pennsylvania Worker and Community Right-to-Know Law

Acetone (CAS 67-64-1)

Butane (CAS 106-97-8)

Calcium Carbonate (CAS 1317-65-3)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Propane (CAS 74-98-6)

Titanium dioxide (CAS 13463-67-7)

Toluene (CAS 108-88-3)

Xylene (CAS 1330-20-7)

US. Rhode Island RTK

Acetone (CAS 67-64-1)

Butane (CAS 106-97-8)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Propane (CAS 74-98-6)

Toluene (CAS 108-88-3)

Xylene (CAS 1330-20-7)

US. California Proposition 65

WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm.

US - California Proposition 65 - CRT: Listed date/Carcinogenic substance

Ethyl Benzene (CAS 100-41-4) Listed: June 11, 2004

Methyl Isobutyl Ketone (CAS 108-10-1) Listed: November 4, 2011

Titanium dioxide (CAS 13463-67-7) Listed: September 2, 2011

US - California Proposition 65 - CRT: Listed date/Developmental toxin

Toluene (CAS 108-88-3) Listed: January 1, 1991

US - California Proposition 65 - CRT: Listed date/Female reproductive toxin

Toluene (CAS 108-88-3) Listed: August 7, 2009

International Inventories

Country(s) or region Inventory name On inventory (yes/no)*

Australia Australian Inventory of Chemical Substances (AICS)

Canada Domestic Substances List (DSL)

Canada Non-Domestic Substances List (NDSL)

China Inventory of Existing Chemical Substances in China (IECSC)

Europe European Inventory of Existing Commercial Chemical Substances (EINECS)

Europe European List of Notified Chemical Substances (ELINCS)

Japan Inventory of Existing and New Chemical Substances (ENCS)

Korea Existing Chemicals List (ECL)

New Zealand New Zealand Inventory

Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS)

United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)

No

No

Yes

No

No

No

No

No

No

Yes

Yes

A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s).

16. Other information, including date of preparation or last revision

Issue date 07-30-2015

Revision date 07-30-2015

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Issued By EHS Administrator

Version # 02

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge,

information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

Revision Information GHS: Classification

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SAFETY DATA SHEET

1. Identification

Product identifier INHIBITAUR High Solids GLOSS BLACK

Company information CONTINENTAL RESEARCH CORP. 1180 CENTRAL IND DRIVE ST LOUIS, MO 63110 United States

Company phone 800-325-4869

Emergency telephone US 888-255-3924 (CHEM-TEL)

Version # 01

Recommended use COATING

Recommended restrictions None known.

2. Hazard(s) identification

Physical hazards

Health hazards

Environmental hazards

OSHA defined hazards

Label elements

Flammable aerosols

Serious eye damage/eye irritation

Specific target organ toxicity, single exposure

Hazardous to the aquatic environment, acute hazard

Not classified.

Category 1

Category 2A

Category 3 narcotic effects

Category 3

Signal word Danger

Hazard statement Extremely flammable aerosol. Causes serious eye irritation. May cause drowsiness or dizziness.

Precautionary statement

Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open

flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing gas. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear eye/face protection.

Response If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse

cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If exposed or concerned: Get medical advice/attention. Call a poison center/doctor if you feel unwell. If eye irritation persists: Get medical advice/attention.

Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect from

sunlight. Do not expose to temperatures exceeding 50°C/122°F.

Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.

Hazard(s) not otherwise

classified (HNOC) None known.

Supplemental information None.

3. Composition/information on ingredients

Mixtures

Chemical name Common name and synonyms

CAS number %

Acetone

Propane

67-64-1

74-98-6

20 - 40

10 - 20

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Chemical name Common name and synonyms CAS number %

Barium Sulfate, Natural 7727-43-7 2.5 - 10

Butane 106-97-8 2.5 - 10

Ethylene Glycol Propyl Ether 2807-30-9 2.5 - 10

Methyl Isobutyl Ketone 108-10-1 2.5 - 10

Methyl Propyl Ketone 107-87-9 2.5 - 10

Xylene 1330-20-7 2.5 - 10

Isobutyl Acetate 110-19-0 1 - 2.5

Propylene Glycol Monomethyl Ether Acetate

108-65-6 1 - 2.5

Other components below reportable levels 20 - 40

*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures

Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON

CENTER or doctor/physician if you feel unwell.

Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists.

Eye contact Rinse with water. Get medical attention if irritation develops and persists.

Ingestion Rinse mouth. Get medical attention if symptoms occur.

Most important

symptoms/effects, acute and

delayed

Indication of immediate

medical attention and special

treatment needed

May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose and throat. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision.

Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed.

General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to

protect themselves.

5. Fire-fighting measures

Suitable extinguishing media Powder. Alcohol resistant foam. Carbon dioxide (CO2).

Unsuitable extinguishing

media

Specific hazards arising from

the chemical

Special protective equipment

and precautions for firefighters

Fire-fighting

equipment/instructions

Do not use water jet as an extinguisher, as this will spread the fire.

Contents under pressure. Pressurized container may explode when exposed to heat or flame.

Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA.

Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out.

Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. Move

containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes.

General fire hazards Extremely flammable aerosol.

6. Accidental release measures

Personal precautions,

protective equipment and

emergency procedures

Methods and materials for

containment and cleaning up

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Avoid breathing gas. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.

Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Prevent entry into waterways, sewer, basements or confined areas. For waste disposal, see section 13 of the SDS.

Environmental precautions Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all

environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground.

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7. Handling and storage

Precautions for safe handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing

or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Avoid breathing gas. Avoid contact with eyes. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices.

Conditions for safe storage,

including any incompatibilities

Level 2 Aerosol.

Store locked up. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). Level 2 Aerosol.

8. Exposure controls/personal protection

Occupational exposure limits

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

Components Type Value Form

Acetone (CAS 67-64-1) PEL 2400 mg/m3 1000 ppm Barium Sulfate, Natural (CAS 7727-43-7)

PEL 5 mg/m3 Respirable fraction.

15 mg/m3 Total dust.

Isobutyl Acetate (CAS 110-19-0)

PEL 700 mg/m3

150 ppm Methyl Isobutyl Ketone (CAS 108-10-1)

PEL 410 mg/m3

100 ppm Methyl Propyl Ketone (CAS 107-87-9)

PEL 700 mg/m3

200 ppm Propane (CAS 74-98-6) PEL 1800 mg/m3

1000 ppm Xylene (CAS 1330-20-7) PEL 435 mg/m3

100 ppm US. ACGIH Threshold Limit Values Components Type Value Form

Acetone (CAS 67-64-1) STEL 750 ppm TWA 500 ppm Barium Sulfate, Natural (CAS 7727-43-7)

TWA 5 mg/m3 Inhalable fraction.

Butane (CAS 106-97-8) STEL 1000 ppm Isobutyl Acetate (CAS 110-19-0)

TWA 150 ppm

Methyl Isobutyl Ketone (CAS 108-10-1)

STEL 75 ppm

TWA 20 ppm Methyl Propyl Ketone (CAS 107-87-9)

STEL 150 ppm

Xylene (CAS 1330-20-7) STEL 150 ppm TWA 100 ppm US. NIOSH: Pocket Guide to Chemical Hazards

Components Type Value Form

Acetone (CAS 67-64-1)

Barium Sulfate, Natural (CAS 7727-43-7)

TWA 590 mg/m3

250 ppm

TWA 5 mg/m3 Respirable.

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US. NIOSH: Pocket Guide to Chemical Hazards

Components Type Value Form

Butane (CAS 106-97-8)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Propane (CAS 74-98-6)

10 mg/m3 Total

TWA 1900 mg/m3

800 ppm

TWA 700 mg/m3

150 ppm

STEL 300 mg/m3

75 ppm

TWA 205 mg/m3

50 ppm

TWA 530 mg/m3

150 ppm

TWA 1800 mg/m3

1000 ppm

US. Workplace Environmental Exposure Level (WEEL) Guides

Components Type

Value

Propylene Glycol Monomethyl Ether Acetate (CAS 108-65-6)

Biological limit values

ACGIH Biological Exposure Indices

TWA 50 ppm

Components Value Determinant Specimen Sampling Time

Acetone (CAS 67-64-1) 50 mg/l Acetone Urine *

Methyl Isobutyl Ketone (CAS 108-10-1)

1 mg/l Methyl isobutyl ketone

Urine *

Xylene (CAS 1330-20-7) 1.5 g/g Methylhippuric acids

Creatinine in urine

*

* - For sampling details, please see the source document.

Exposure guidelines

US - California OELs: Skin designation

Propylene Glycol Monomethyl Ether Acetate (CAS 108-65-6)

Can be absorbed through the skin.

Appropriate engineering

controls

Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station.

Individual protection measures, such as personal protective equipment

Eye/face protection Wear safety glasses with side shields (or goggles).

Hand protection Wear appropriate chemical resistant gloves.

Skin protection

Other Wear suitable protective clothing.

Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an

air-supplied respirator.

Thermal hazards Wear appropriate thermal protective clothing, when necessary.

General hygiene

considerations

When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.

9. Physical and chemical properties

Appearance

Physical state Gas.

Form Aerosol.

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Color Not available.

Odor Not available.

Odor threshold Not available.

pH Not available.

Melting point/freezing point Not available.

Initial boiling point and boiling

range

94.36 °F (34.65 °C) estimated

Flash point -2.2 °F (-19.0 °C) SUPPLIER estimated

Evaporation rate Not available.

Flammability (solid, gas) Not available.

Upper/lower flammability or explosive limits

Flammability limit - lower

(%)

Flammability limit - upper

(%)

Not available.

Not available.

Explosive limit - lower (%) Not available.

Explosive limit - upper (%) Not available.

Vapor pressure 2750 hPa @70F estimated

Vapor density Not available.

Relative density Not available.

Solubility(ies)

Solubility (water) Not available.

Partition coefficient

(n-octanol/water)

Not available.

Auto-ignition temperature Not available.

Decomposition temperature Not available.

Viscosity Not available.

Other information

Specific gravity 0.861 estimated

10. Stability and reactivity

Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.

Chemical stability Material is stable under normal conditions.

Possibility of hazardous

reactions

Hazardous polymerization does not occur.

Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials.

Incompatible materials Strong acids. Strong oxidizing agents. Nitrates. Aluminum. Halogens. Phosphorus. Fluorine. Chlorine.

Hazardous decomposition

products

No hazardous decomposition products are known.

11. Toxicological information

Information on likely routes of exposure

Ingestion Expected to be a low ingestion hazard.

Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be

harmful.

Skin contact No adverse effects due to skin contact are expected.

Eye contact Causes serious eye irritation.

Symptoms related to the

physical, chemical and

toxicological characteristics

May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose and throat. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision.

Information on toxicological effects

Acute toxicity Narcotic effects.

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Components Species Test Results

Acetone (CAS 67-64-1)

Acute

Dermal

LD50 Guinea pig

> 7426 mg/kg, 24 Hours

> 9.4 ml/kg, 24 Hours

Inhalation

Rabbit > 7426 mg/kg, 24 Hours

> 9.4 ml/kg, 24 Hours

LC50 Rat

Oral

LD50 Rat

Barium Sulfate, Natural (CAS 7727-43-7)

Acute

Oral

LD100 Rat

55700 ppm, 3 Hours

132 mg/l, 3 Hours

50.1 mg/l

5800 mg/kg

2.2 ml/kg

564 g/kg

LD50 Rat 307 g/kg

Butane (CAS 106-97-8)

Acute

Inhalation

LC50 Mouse 1237 mg/l, 120 Minutes

52 %, 120 Minutes

Rat 1355 mg/l

Ethylene Glycol Propyl Ether (CAS 2807-30-9)

Acute

Dermal

LD50 Guinea pig 5.6 g/kg, 4 Days

Inhalation

Rabbit > 1 g/kg, 24 Hours

1337 ml/kg, 14 Days

LC50 Rat

Oral

LD50 Guinea pig

> 2132 ppm, 6 Hours

> 1800 ppm

2.2 g/kg

Isobutyl Acetate (CAS 110-19-0)

Acute

Dermal

Mouse 1774 mg/kg

Rat 0.5 - 1 g/kg

LD50 Rabbit

Inhalation

LC50 Rat

Oral

LD50 Rat

> 17400 mg/kg, 24 Hours

> 30 mg/l, 6 Hours

> 23.4 mg/l, 4 Hours

13413 mg/kg

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Components Species Test Results

Methyl Isobutyl Ketone (CAS 108-10-1)

Acute

Inhalation

LC50 Rat

Oral

LD50 Rat

Propane (CAS 74-98-6)

Acute

Inhalation

LC50 Mouse

2000 - 4000 ppm, 4 Hours

2.08 g/kg

1237 mg/l, 120 Minutes

52 %, 120 Minutes

Rat 1355 mg/l

658 mg/l/4h

Propylene Glycol Monomethyl Ether Acetate (CAS 108-65-6)

Acute

Dermal

LD50 Rat

Oral

LD50 Rat

Xylene (CAS 1330-20-7)

Acute

Dermal

LD50 Rabbit

Inhalation

LC50 Rat

Oral

LD50 Mouse

> 2000 mg/kg, 24 Hours

> 14.1 ml

5155 mg/kg

> 5000 ml/kg, 4 Hours

12126 mg/kg, 24 Hours

5922 ppm, 4 Hours

5251 mg/kg

Rat 3523 mg/kg

10 ml/kg

* Estimates for product may be based on additional component data not shown.

Skin corrosion/irritation Not applicable.

Serious eye damage/eye

irritation

Respiratory or skin sensitization

Causes serious eye irritation.

Respiratory sensitization Not available.

Skin sensitization This product is not expected to cause skin sensitization.

Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.

Carcinogenicity Risk of cancer cannot be excluded with prolonged exposure.

IARC Monographs. Overall Evaluation of Carcinogenicity

Methyl Isobutyl Ketone (CAS 108-10-1) 2B Possibly carcinogenic to humans.

Xylene (CAS 1330-20-7) 3 Not classifiable as to carcinogenicity to humans.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.

Reproductive toxicity Components in this product have been shown to cause birth defects and reproductive disorders in laboratory animals.

Specific target organ toxicity -

single exposure

May cause drowsiness and dizziness.

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Specific target organ toxicity -

repeated exposure

Not classified.

Aspiration hazard Not likely, due to the form of the product.

Chronic effects Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects.

12. Ecological information

Ecotoxicity Harmful to aquatic life with long lasting effects.

Components

Acetone (CAS 67-64-1)

Aquatic

Crustacea

Fish

EC50

LC50

Species

Water flea (Daphnia magna)

Rainbow trout,donaldson trout (Oncorhynchus mykiss)

Test Results

21.6 - 23.9 mg/l, 48 hours

4740 - 6330 mg/l, 96 hours

Barium Sulfate, Natural (CAS 7727-43-7)

Aquatic

Crustacea EC50 Tubificid worm (Tubifex tubifex) 28.61 - 38.03 mg/l, 48 hours

Methyl Isobutyl Ketone (CAS 108-10-1)

Aquatic

Fish LC50 Fathead minnow (Pimephales promelas) 492 - 593 mg/l, 96 hours

Methyl Propyl Ketone (CAS 107-87-9)

Aquatic

Fish LC50 Fathead minnow (Pimephales promelas) 1190 - 1290 mg/l, 96 hours

Propylene Glycol Monomethyl Ether Acetate (CAS 108-65-6)

Aquatic

Crustacea

Xylene (CAS 1330-20-7)

Aquatic

Fish

EC50

LC50

Daphnia

Bluegill (Lepomis macrochirus)

500.0001 mg/L, 48 Hours

7.711 - 9.591 mg/l, 96 hours

* Estimates for product may be based on additional component data not shown.

Persistence and degradability No data is available on the degradability of this product.

Bioaccumulative potential No data available.

Partition coefficient n-octanol / water (log Kow) Acetone -0.24

Butane 2.89

Isobutyl Acetate 1.78

Methyl Isobutyl Ketone 1.31

Methyl Propyl Ketone 0.91

Propane 2.36

Xylene 3.12 - 3.2

Mobility in soil No data available.

Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation

potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations

Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents

under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations.

Local disposal regulations Dispose in accordance with all applicable regulations.

Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company.

US RCRA Hazardous Waste U List: Reference

Acetone (CAS 67-64-1) U002

Methyl Isobutyl Ketone (CAS 108-10-1) U161

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Xylene (CAS 1330-20-7) U239

Waste from residues / unused

products

Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).

Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers.

14. Transport information

DOT

UN number

UN proper shipping name

Transport hazard class(es)

Class

Subsidiary risk

Label(s)

Packing group

UN1950

Aerosols, flammable

2.1

-

2.1

Not applicable.

Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling.

Special provisions

Packaging exceptions

Packaging non bulk

Packaging bulk

N82

306

None

None

This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently.

IATA

UN number

UN proper shipping name

Transport hazard class(es)

Class

Subsidiary risk

Label(s)

Packing group

Environmental hazards

ERG Code

UN1950

Aerosols, flammable

2.1

-

2.1

Not applicable.

No.

10L

Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling.

Other information

Passenger and cargo

aircraft

Cargo aircraft only

Packaging Exceptions

IMDG

UN number

UN proper shipping name

Transport hazard class(es)

Class

Subsidiary risk

Label(s)

Packing group

Environmental hazards

Marine pollutant

EmS

Allowed.

Allowed.

LTD QTY

UN1950

AEROSOLS

2.1

-

2.1

Not applicable.

No.

F-D, S-U

Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling.

Packaging Exceptions

Transport in bulk according to

Annex II of MARPOL 73/78 and

the IBC Code

LTD QTY

Not applicable.

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DOT

IATA; IMDG

15. Regulatory information

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication

Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

Not regulated.

CERCLA Hazardous Substance List (40 CFR 302.4)

Acetone (CAS 67-64-1) Listed.

Isobutyl Acetate (CAS 110-19-0) Listed.

Methyl Isobutyl Ketone (CAS 108-10-1) Listed.

Xylene (CAS 1330-20-7) Listed.

SARA 304 Emergency release notification

Not regulated.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No

SARA 302 Extremely hazardous substance

Not listed.

SARA 311/312 Hazardous No

chemical

SARA 313 (TRI reporting)

Chemical name CAS number % by wt.

Methyl Isobutyl Ketone 108-10-1 2.5 - 10

Xylene 1330-20-7 2.5 - 10

Other federal regulations

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List

Methyl Isobutyl Ketone (CAS 108-10-1)

Xylene (CAS 1330-20-7)

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)

Butane (CAS 106-97-8)

Propane (CAS 74-98-6)

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Safe Drinking Water Act

(SDWA)

Not regulated.

Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and

Chemical Code Number

Acetone (CAS 67-64-1) 6532

Methyl Isobutyl Ketone (CAS 108-10-1) 6715

Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))

Acetone (CAS 67-64-1) 35 %WV

Methyl Isobutyl Ketone (CAS 108-10-1) 35 %WV

DEA Exempt Chemical Mixtures Code Number

Acetone (CAS 67-64-1) 6532

Methyl Isobutyl Ketone (CAS 108-10-1) 6715

US state regulations

US. Massachusetts RTK - Substance List

Acetone (CAS 67-64-1)

Barium Sulfate, Natural (CAS 7727-43-7)

Butane (CAS 106-97-8)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Propane (CAS 74-98-6)

Xylene (CAS 1330-20-7)

US. New Jersey Worker and Community Right-to-Know Act

Acetone (CAS 67-64-1)

Barium Sulfate, Natural (CAS 7727-43-7)

Butane (CAS 106-97-8)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Propane (CAS 74-98-6)

Xylene (CAS 1330-20-7)

US. Pennsylvania Worker and Community Right-to-Know Law

Acetone (CAS 67-64-1)

Barium Sulfate, Natural (CAS 7727-43-7)

Butane (CAS 106-97-8)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Propane (CAS 74-98-6)

Xylene (CAS 1330-20-7)

US. Rhode Island RTK

Acetone (CAS 67-64-1)

Butane (CAS 106-97-8)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Propane (CAS 74-98-6)

Xylene (CAS 1330-20-7)

US. California Proposition 65

WARNING: This product contains a chemical known to the State of California to cause cancer.

US - California Proposition 65 - CRT: Listed date/Carcinogenic substance

Methyl Isobutyl Ketone (CAS 108-10-1) Listed: November 4, 2011

International Inventories

Country(s) or region Inventory name On inventory (yes/no)*

Australia Australian Inventory of Chemical Substances (AICS)

Canada Domestic Substances List (DSL)

Canada Non-Domestic Substances List (NDSL)

China Inventory of Existing Chemical Substances in China (IECSC)

Europe European Inventory of Existing Commercial Chemical Substances (EINECS)

No

Yes

No

No

No

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Country(s) or region Inventory name On inventory (yes/no)*

Europe European List of Notified Chemical Substances (ELINCS)

Japan Inventory of Existing and New Chemical Substances (ENCS)

Korea Existing Chemicals List (ECL)

New Zealand New Zealand Inventory

Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS)

United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)

No

No

No

No

Yes

Yes

A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s).

16. Other information, including date of preparation or last revision

Issue date 04-25-2016

Issued By EHS Administrator

Version # 01

Disclaimer We cannot anticipate all conditions under which this information and its product, or the products of

other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

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SAFETY DATA SHEET

1. Identification

Product identifier INHIBITAUR High Solids GLOSS WHITE

Company information CONTINENTAL RESEARCH CORP. P.O. Box 15204 St. Louis, MO 63110

Company phone 800-325-4869

Emergency telephone US 888-255-3924 (CHEM-TEL)

Version # 01

Recommended use Coating

Recommended restrictions None known.

2. Hazard(s) identification

Physical hazards

Health hazards

Environmental hazards

OSHA defined hazards

Label elements

Flammable aerosols

Serious eye damage/eye irritation

Not classified.

Not classified.

Category 1

Category 2A

Signal word Danger

Hazard statement Extremely flammable aerosol. Causes serious eye irritation.

Precautionary statement

Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open

flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Wear eye/face protection.

Response If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Storage Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.

Disposal Dispose of waste and residues in accordance with local authority requirements.

Hazard(s) not otherwise

classified (HNOC) None known.

Supplemental information None.

3. Composition/information on ingredients

Mixtures

Chemical name Common name and synonyms

CAS number %

Acetone

Propane

Titanium dioxide

Barium Sulfate, Natural

Butane

Ethylene Glycol Propyl Ether

67-64-1

74-98-6

13463-67-7

7727-43-7

106-97-8

2807-30-9

10 - 20

10 - 20

10 - 20

2.5 - 10

2.5 - 10

2.5 - 10

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Chemical name Common name and synonyms CAS number %

Isobutyl Acetate 110-19-0 2.5 - 10

Methyl Isobutyl Ketone 108-10-1 2.5 - 10

Methyl Propyl Ketone 107-87-9 2.5 - 10

Xylene 1330-20-7 1 - 2.5

Other components below reportable levels 20 - 40

*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures

Inhalation Move to fresh air. Call a physician if symptoms develop or persist.

Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists.

Eye contact Rinse with water. Get medical attention if irritation develops and persists.

Ingestion Rinse mouth. Get medical attention if symptoms occur.

Most important

symptoms/effects, acute and

delayed

Indication of immediate

medical attention and special

treatment needed

Dizziness. Headache. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision.

Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed.

General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to

protect themselves.

5. Fire-fighting measures

Suitable extinguishing media Powder. Alcohol resistant foam. Carbon dioxide (CO2).

Unsuitable extinguishing

media

Specific hazards arising from

the chemical

Special protective equipment

and precautions for firefighters

Fire-fighting

equipment/instructions

Do not use water jet as an extinguisher, as this will spread the fire.

Contents under pressure. Pressurized container may explode when exposed to heat or flame.

Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA.

Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out.

Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. Move

containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes.

General fire hazards Extremely flammable aerosol.

6. Accidental release measures

Personal precautions,

protective equipment and

emergency procedures

Methods and materials for

containment and cleaning up

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.

Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and

open area if the leak is irreparable. Isolate area until gas has dispersed. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. For waste disposal, see section 13 of the SDS.

Environmental precautions Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage

Precautions for safe handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing

or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Avoid contact with eyes. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Observe good industrial hygiene practices.

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Conditions for safe storage,

including any incompatibilities

Level 2 Aerosol.

Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). Level 2 Aerosol.

8. Exposure controls/personal protection

Occupational exposure limits

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

Components Type Value Form

Acetone (CAS 67-64-1) PEL 2400 mg/m3 1000 ppm Barium Sulfate, Natural (CAS 7727-43-7)

PEL 5 mg/m3 Respirable fraction.

15 mg/m3 Total dust.

Isobutyl Acetate (CAS 110-19-0)

PEL 700 mg/m3

150 ppm Methyl Isobutyl Ketone (CAS 108-10-1)

PEL 410 mg/m3

100 ppm Methyl Propyl Ketone (CAS 107-87-9)

PEL 700 mg/m3

200 ppm Propane (CAS 74-98-6) PEL 1800 mg/m3

1000 ppm Titanium dioxide (CAS 13463-67-7)

PEL 15 mg/m3 Total dust.

Xylene (CAS 1330-20-7) PEL 435 mg/m3 100 ppm US. ACGIH Threshold Limit Values Components Type Value Form

Acetone (CAS 67-64-1) STEL 750 ppm TWA 500 ppm Barium Sulfate, Natural (CAS 7727-43-7)

TWA 5 mg/m3 Inhalable fraction.

Butane (CAS 106-97-8) STEL 1000 ppm Isobutyl Acetate (CAS 110-19-0)

TWA 150 ppm

Methyl Isobutyl Ketone (CAS 108-10-1)

STEL 75 ppm

TWA 20 ppm Methyl Propyl Ketone (CAS 107-87-9)

STEL 150 ppm

Titanium dioxide (CAS 13463-67-7)

TWA 10 mg/m3

Xylene (CAS 1330-20-7) STEL 150 ppm TWA 100 ppm US. NIOSH: Pocket Guide to Chemical Hazards

Components Type Value Form

Acetone (CAS 67-64-1)

Barium Sulfate, Natural (CAS 7727-43-7)

Butane (CAS 106-97-8)

Isobutyl Acetate (CAS 110-19-0)

TWA 590 mg/m3

250 ppm

TWA 5 mg/m3 Respirable.

10 mg/m3 Total

TWA 1900 mg/m3

800 ppm

TWA 700 mg/m3

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US. NIOSH: Pocket Guide to Chemical Hazards

Components Type Value

150 ppm

Form

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Propane (CAS 74-98-6)

Biological limit values

ACGIH Biological Exposure Indices

STEL 300 mg/m3

75 ppm

TWA 205 mg/m3

50 ppm

TWA 530 mg/m3

150 ppm

TWA 1800 mg/m3

1000 ppm

Components Value Determinant Specimen Sampling Time

Acetone (CAS 67-64-1) 50 mg/l Acetone Urine *

Methyl Isobutyl Ketone (CAS 108-10-1)

1 mg/l Methyl isobutyl ketone

Urine *

Xylene (CAS 1330-20-7) 1.5 g/g Methylhippuric acids

Creatinine in urine

*

* - For sampling details, please see the source document.

Appropriate engineering

controls

Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station.

Individual protection measures, such as personal protective equipment

Eye/face protection Wear safety glasses with side shields (or goggles).

Hand protection Wear appropriate chemical resistant gloves.

Skin protection

Other Wear suitable protective clothing.

Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator.

Thermal hazards Wear appropriate thermal protective clothing, when necessary.

General hygiene

considerations

When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.

9. Physical and chemical properties

Appearance

Physical state Gas.

Form Aerosol.

Color Not available.

Odor Not available.

Odor threshold Not available.

pH Not available.

Melting point/freezing point Not available.

Initial boiling point and boiling

range

-47.2 °F (-44 °C) supplier estimated

Flash point -2.2 °F (-19.0 °C) supplier

Evaporation rate Not available.

Flammability (solid, gas) Not available.

Upper/lower flammability or explosive limits

Flammability limit - lower (%)

1.7 supplier

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Flammability limit - upper

(%)

10.9 supplier

Explosive limit - lower (%) Not available.

Explosive limit - upper (%) Not available.

Vapor pressure Not available.

Vapor density Not available.

Relative density Not available.

Solubility(ies)

Solubility (water) Not available.

Partition coefficient

(n-octanol/water)

Not available.

Auto-ignition temperature Not available.

Decomposition temperature Not available.

Viscosity Not available.

Other information

Specific gravity 1.163 estimated

10. Stability and reactivity

Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.

Chemical stability Material is stable under normal conditions.

Possibility of hazardous

reactions

Hazardous polymerization does not occur.

Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials.

Incompatible materials Strong acids. Strong oxidizing agents. Nitrates. Aluminum. Halogens. Phosphorus. Fluorine. Chlorine.

Hazardous decomposition

products

No hazardous decomposition products are known.

11. Toxicological information

Information on likely routes of exposure

Ingestion Expected to be a low ingestion hazard.

Inhalation Prolonged inhalation may be harmful.

Skin contact No adverse effects due to skin contact are expected.

Eye contact Causes serious eye irritation.

Symptoms related to the

physical, chemical and

toxicological characteristics

Dizziness. Headache. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision.

Information on toxicological effects

Acute toxicity

Components Species

Acetone (CAS 67-64-1)

Acute

Dermal

LD50 Guinea pig

Test Results

> 7426 mg/kg, 24 Hours

> 9.4 ml/kg, 24 Hours

Inhalation

Rabbit > 7426 mg/kg, 24 Hours

> 9.4 ml/kg, 24 Hours

LC50 Rat 55700 ppm, 3 Hours

132 mg/l, 3 Hours

50.1 mg/l

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Components Species Test Results

Oral

LD50 Rat

Barium Sulfate, Natural (CAS 7727-43-7)

Acute

Oral

LD100 Rat

5800 mg/kg

2.2 ml/kg

564 g/kg

LD50 Rat 307 g/kg

Butane (CAS 106-97-8)

Acute

Inhalation

LC50 Mouse 1237 mg/l, 120 Minutes

52 %, 120 Minutes

Rat 1355 mg/l

Ethylene Glycol Propyl Ether (CAS 2807-30-9)

Acute

Dermal

LD50 Guinea pig 5.6 g/kg, 4 Days

Inhalation

Rabbit > 1 g/kg, 24 Hours

1337 ml/kg, 14 Days

LC50 Rat

Oral

LD50 Guinea pig

> 2132 ppm, 6 Hours

> 1800 ppm

2.2 g/kg

Isobutyl Acetate (CAS 110-19-0)

Acute

Dermal

Mouse 1774 mg/kg

Rat 0.5 - 1 g/kg

LD50 Rabbit

Inhalation

LC50 Rat

Oral

LD50 Rat

Methyl Isobutyl Ketone (CAS 108-10-1)

Acute

Inhalation

LC50 Rat

Oral

LD50 Rat

Propane (CAS 74-98-6)

Acute

Inhalation

LC50 Mouse

> 17400 mg/kg, 24 Hours

> 30 mg/l, 6 Hours

> 23.4 mg/l, 4 Hours

13413 mg/kg

2000 - 4000 ppm, 4 Hours

2.08 g/kg

1237 mg/l, 120 Minutes

52 %, 120 Minutes

Rat 1355 mg/l

658 mg/l/4h

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Components Species Test Results

Titanium dioxide (CAS 13463-67-7)

Acute

Inhalation

LC50 Rat

Oral

LD50 Rat

Xylene (CAS 1330-20-7)

Acute

Dermal

LD50 Rabbit

Inhalation

LC50 Rat

Oral

LD50 Mouse

> 2.28 mg/l, 4 Hours

> 11000 mg/kg

> 5000 ml/kg, 4 Hours

12126 mg/kg, 24 Hours

5922 ppm, 4 Hours

5251 mg/kg

Rat 3523 mg/kg

10 ml/kg

* Estimates for product may be based on additional component data not shown.

Skin corrosion/irritation Not applicable.

Serious eye damage/eye

irritation

Respiratory or skin sensitization

Causes serious eye irritation.

Respiratory sensitization Not available.

Skin sensitization This product is not expected to cause skin sensitization.

Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are

mutagenic or genotoxic.

Carcinogenicity Risk of cancer cannot be excluded with prolonged exposure.

IARC Monographs. Overall Evaluation of Carcinogenicity

Methyl Isobutyl Ketone (CAS 108-10-1) 2B Possibly carcinogenic to humans.

Titanium dioxide (CAS 13463-67-7) 2B Possibly carcinogenic to humans.

Xylene (CAS 1330-20-7) 3 Not classifiable as to carcinogenicity to humans.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.

Reproductive toxicity Components in this product have been shown to cause birth defects and reproductive disorders in

laboratory animals.

Specific target organ toxicity -

single exposure

Specific target organ toxicity -

repeated exposure

Not classified.

Not classified.

Aspiration hazard Not likely, due to the form of the product.

Chronic effects Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects.

12. Ecological information

Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

Components

Acetone (CAS 67-64-1)

Aquatic

Crustacea

Fish

EC50

LC50

Species

Water flea (Daphnia magna)

Rainbow trout,donaldson trout (Oncorhynchus mykiss)

Test Results

21.6 - 23.9 mg/l, 48 hours

4740 - 6330 mg/l, 96 hours

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Components

Barium Sulfate, Natural (CAS 7727-43-7)

Aquatic

Species Test Results

Crustacea EC50 Tubificid worm (Tubifex tubifex) 28.61 - 38.03 mg/l, 48 hours

Methyl Isobutyl Ketone (CAS 108-10-1)

Aquatic

Fish LC50 Fathead minnow (Pimephales promelas) 492 - 593 mg/l, 96 hours

Methyl Propyl Ketone (CAS 107-87-9)

Aquatic

Fish LC50 Fathead minnow (Pimephales promelas) 1190 - 1290 mg/l, 96 hours

Titanium dioxide (CAS 13463-67-7)

Aquatic

Crustacea

Fish

Xylene (CAS 1330-20-7)

Aquatic

Fish

EC50

LC50

LC50

Water flea (Daphnia magna)

Mummichog (Fundulus heteroclitus)

Bluegill (Lepomis macrochirus)

> 1000 mg/l, 48 hours

> 1000 mg/l, 96 hours

7.711 - 9.591 mg/l, 96 hours

* Estimates for product may be based on additional component data not shown.

Persistence and degradability No data is available on the degradability of this product.

Bioaccumulative potential No data available.

Partition coefficient n-octanol / water (log Kow) Acetone -0.24

Butane 2.89

Isobutyl Acetate 1.78

Methyl Isobutyl Ketone 1.31

Methyl Propyl Ketone 0.91

Propane 2.36

Xylene 3.12 - 3.2

Mobility in soil No data available.

Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations

Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents

under pressure. Do not puncture, incinerate or crush. Dispose of contents/container in accordance with local/regional/national/international regulations.

Local disposal regulations Dispose in accordance with all applicable regulations.

Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company.

US RCRA Hazardous Waste U List: Reference

Acetone (CAS 67-64-1) U002

Methyl Isobutyl Ketone (CAS 108-10-1) U161

Xylene (CAS 1330-20-7) U239

Waste from residues / unused

products

Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).

Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers.

14. Transport information

DOT

UN number

UN proper shipping name

Transport hazard class(es)

Class

UN1950

Aerosols, flammable

2.1

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Subsidiary risk

Label(s)

Packing group

-

2.1

Not applicable.

Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling.

Special provisions

Packaging exceptions

Packaging non bulk

Packaging bulk

N82

306

None

None

This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently.

IATA

UN number

UN proper shipping name

Transport hazard class(es)

Class

Subsidiary risk

Label(s)

Packing group

Environmental hazards

ERG Code

UN1950

Aerosols, flammable

2.1

-

2.1

Not applicable.

No.

10L

Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety

instructions, SDS and emergency procedures before handling.

Other information

Passenger and cargo

aircraft

Cargo aircraft only

Packaging Exceptions

IMDG

UN number

UN proper shipping name

Transport hazard class(es)

Class

Subsidiary risk

Label(s)

Packing group

Environmental hazards

Marine pollutant

EmS

Allowed.

Allowed.

LTD QTY

UN1950

AEROSOLS

2.1

-

2.1

Not applicable.

No.

F-D, S-U

Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling.

Packaging Exceptions

Transport in bulk according to

Annex II of MARPOL 73/78 and

the IBC Code

DOT

LTD QTY

Not applicable.

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IATA; IMDG

15. Regulatory information

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication

Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

Not regulated.

CERCLA Hazardous Substance List (40 CFR 302.4)

Acetone (CAS 67-64-1) Listed.

Isobutyl Acetate (CAS 110-19-0) Listed.

Methyl Isobutyl Ketone (CAS 108-10-1) Listed.

Xylene (CAS 1330-20-7) Listed.

SARA 304 Emergency release notification

Not regulated.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No

SARA 302 Extremely hazardous substance

Not listed.

SARA 311/312 Hazardous No

chemical

SARA 313 (TRI reporting)

Chemical name CAS number % by wt.

Methyl Isobutyl Ketone 108-10-1 2.5 - 10

Xylene 1330-20-7 1 - 2.5

Other federal regulations

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List

Methyl Isobutyl Ketone (CAS 108-10-1)

Xylene (CAS 1330-20-7)

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)

Butane (CAS 106-97-8)

Propane (CAS 74-98-6)

Safe Drinking Water Act

(SDWA)

Not regulated.

Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and

Chemical Code Number

Acetone (CAS 67-64-1) 6532

Methyl Isobutyl Ketone (CAS 108-10-1) 6715

Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))

Acetone (CAS 67-64-1) 35 %WV

Methyl Isobutyl Ketone (CAS 108-10-1) 35 %WV

DEA Exempt Chemical Mixtures Code Number

Acetone (CAS 67-64-1) 6532

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Methyl Isobutyl Ketone (CAS 108-10-1) 6715

US state regulations

US. Massachusetts RTK - Substance List

Acetone (CAS 67-64-1)

Barium Sulfate, Natural (CAS 7727-43-7)

Butane (CAS 106-97-8)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Propane (CAS 74-98-6)

Titanium dioxide (CAS 13463-67-7)

Xylene (CAS 1330-20-7)

US. New Jersey Worker and Community Right-to-Know Act

Acetone (CAS 67-64-1)

Barium Sulfate, Natural (CAS 7727-43-7)

Butane (CAS 106-97-8)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Propane (CAS 74-98-6)

Titanium dioxide (CAS 13463-67-7)

Xylene (CAS 1330-20-7)

US. Pennsylvania Worker and Community Right-to-Know Law

Acetone (CAS 67-64-1)

Barium Sulfate, Natural (CAS 7727-43-7)

Butane (CAS 106-97-8)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Propane (CAS 74-98-6)

Titanium dioxide (CAS 13463-67-7)

Xylene (CAS 1330-20-7)

US. Rhode Island RTK

Acetone (CAS 67-64-1)

Butane (CAS 106-97-8)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Propane (CAS 74-98-6)

Xylene (CAS 1330-20-7)

US. California Proposition 65

WARNING: This product contains a chemical known to the State of California to cause cancer.

US - California Proposition 65 - CRT: Listed date/Carcinogenic substance

Methyl Isobutyl Ketone (CAS 108-10-1) Listed: November 4, 2011

Titanium dioxide (CAS 13463-67-7) Listed: September 2, 2011

International Inventories

Country(s) or region Inventory name On inventory (yes/no)*

Australia Australian Inventory of Chemical Substances (AICS)

Canada Domestic Substances List (DSL)

Canada Non-Domestic Substances List (NDSL)

China Inventory of Existing Chemical Substances in China (IECSC)

Europe European Inventory of Existing Commercial Chemical Substances (EINECS)

Europe European List of Notified Chemical Substances (ELINCS)

Japan Inventory of Existing and New Chemical Substances (ENCS)

Korea Existing Chemicals List (ECL)

New Zealand New Zealand Inventory

Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS)

No

Yes

No

No

No

No

No

No

No

Yes

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Country(s) or region Inventory name On inventory (yes/no)*

United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)

Yes

A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing

country(s).

16. Other information, including date of preparation or last revision

Issue date 04-25-2016

Version # 01

Issued By: EHS Administrator

Disclaimer We cannot anticipate all conditions under which this information and its product, or the products of

other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

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SAFETY DATA SHEET

1. Identification

Product identifier INHIBITAUR High Solids SAFETY ORANGE

Company information CONTINENTAL RESEARCH CORP. P.O. Box 15204 ST LOUIS, MO 63110 United States

Company phone 800-325-4869

Emergency telephone US 888-255-3924 (CHEM-TEL)

Version # 01

Recommended use Not available.

Recommended restrictions None known.

2. Hazard(s) identification

Physical hazards

Health hazards

Environmental hazards

OSHA defined hazards

Label elements

Flammable aerosols

Serious eye damage/eye irritation

Specific target organ toxicity, single exposure

Not classified.

Not classified.

Category 1

Category 2A

Category 3 narcotic effects

Signal word Danger

Hazard statement Extremely flammable aerosol. Causes serious eye irritation. May cause drowsiness or dizziness.

Precautionary statement

Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open

flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing mist or vapor. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear eye/face protection.

Response If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison

center/doctor if you feel unwell. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect from

sunlight. Do not expose to temperatures exceeding 50°C/122°F.

Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.

Hazard(s) not otherwise

classified (HNOC) None known.

Supplemental information None.

3. Composition/information on ingredients

Mixtures

Chemical name Common name and synonyms

CAS number %

Acetone

Propane

Barium Sulfate, Natural

67-64-1

74-98-6

7727-43-7

10 - 20

10 - 20

2.5 - 10

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Chemical name Common name and synonyms CAS number %

Butane 106-97-8 2.5 - 10

Ethylene Glycol Propyl Ether 2807-30-9 2.5 - 10

Methyl Isobutyl Ketone 108-10-1 2.5 - 10

Methyl Propyl Ketone 107-87-9 2.5 - 10

Propylene Glycol Monomethyl Ether Acetate

108-65-6 2.5 - 10

Isobutyl Acetate 110-19-0 1 - 2.5

Xylene 1330-20-7 1 - 2.5

Other components below reportable levels 20 - 40

*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures

Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON

CENTER or doctor/physician if you feel unwell.

Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists.

Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Ingestion In the unlikely event of swallowing contact a physician or poison control center. Rinse mouth.

Most important

symptoms/effects, acute and

delayed

Indication of immediate

medical attention and special

treatment needed

May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose and throat. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision.

Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed.

General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.

5. Fire-fighting measures

Suitable extinguishing media Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).

Unsuitable extinguishing

media

Specific hazards arising from

the chemical

Special protective equipment

and precautions for firefighters

Fire-fighting

equipment/instructions

Do not use water jet as an extinguisher, as this will spread the fire.

Contents under pressure. Pressurized container may explode when exposed to heat or flame.

Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA.

Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out.

Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. Move

containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes.

General fire hazards Extremely flammable aerosol.

6. Accidental release measures

Personal precautions,

protective equipment and

emergency procedures

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.

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Methods and materials for

containment and cleaning up

Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS.

Environmental precautions Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all

environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage

Precautions for safe handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing

or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Avoid breathing mist or vapor. Avoid contact with eyes. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices.

Conditions for safe storage,

including any incompatibilities

Level 3 Aerosol.

Store locked up. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). Level 3 Aerosol.

8. Exposure controls/personal protection

Occupational exposure limits

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

Components Type Value Form

Acetone (CAS 67-64-1) PEL 2400 mg/m3 1000 ppm Barium Sulfate, Natural

(CAS 7727-43-7) PEL 5 mg/m3 Respirable fraction.

15 mg/m3 Total dust.

Isobutyl Acetate (CAS 110-19-0)

PEL 700 mg/m3

150 ppm Methyl Isobutyl Ketone

(CAS 108-10-1) PEL 410 mg/m3

100 ppm Methyl Propyl Ketone (CAS

107-87-9) PEL 700 mg/m3

200 ppm Propane (CAS 74-98-6) PEL 1800 mg/m3 1000 ppm Xylene (CAS 1330-20-7) PEL 435 mg/m3 100 ppm US. ACGIH Threshold Limit Values Components Type Value Form

Acetone (CAS 67-64-1) STEL 750 ppm TWA 500 ppm Barium Sulfate, Natural

(CAS 7727-43-7) TWA 5 mg/m3 Inhalable fraction.

Butane (CAS 106-97-8) STEL 1000 ppm Isobutyl Acetate (CAS

110-19-0) TWA 150 ppm

Methyl Isobutyl Ketone (CAS 108-10-1)

STEL 75 ppm

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US. ACGIH Threshold Limit Values

Components

Type

Value

Form

Methyl Propyl Ketone (CAS 107-87-9)

Xylene (CAS 1330-20-7)

TWA 20 ppm

STEL 150 ppm

STEL 150 ppm

TWA 100 ppm

US. NIOSH: Pocket Guide to Chemical Hazards

Components Type Value Form

Acetone (CAS 67-64-1)

Barium Sulfate, Natural (CAS 7727-43-7)

Butane (CAS 106-97-8)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Propane (CAS 74-98-6)

TWA 590 mg/m3

250 ppm

TWA 5 mg/m3 Respirable.

10 mg/m3 Total

TWA 1900 mg/m3

800 ppm

TWA 700 mg/m3

150 ppm

STEL 300 mg/m3

75 ppm

TWA 205 mg/m3

50 ppm

TWA 530 mg/m3

150 ppm

TWA 1800 mg/m3

1000 ppm

US. Workplace Environmental Exposure Level (WEEL) Guides

Components Type

Value

Propylene Glycol Monomethyl Ether Acetate (CAS 108-65-6)

Biological limit values

ACGIH Biological Exposure Indices

TWA 50 ppm

Components Value Determinant Specimen Sampling Time

Acetone (CAS 67-64-1) 50 mg/l Acetone Urine *

Methyl Isobutyl Ketone (CAS 108-10-1)

1 mg/l Methyl isobutyl ketone

Urine *

Xylene (CAS 1330-20-7) 1.5 g/g Methylhippuric acids

Creatinine in urine

*

* - For sampling details, please see the source document.

Exposure guidelines

US - California OELs: Skin designation

Propylene Glycol Monomethyl Ether Acetate (CAS 108-65-6)

Can be absorbed through the skin.

Appropriate engineering

controls

Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates

should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station.

Individual protection measures, such as personal protective equipment

Eye/face protection Chemical respirator with organic vapor cartridge and full facepiece.

Hand protection Wear appropriate chemical resistant gloves.

Skin protection

Other Wear suitable protective clothing.

Respiratory protection Chemical respirator with organic vapor cartridge and full facepiece.

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Thermal hazards Wear appropriate thermal protective clothing, when necessary.

General hygiene

considerations

When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.

9. Physical and chemical properties

Appearance

Physical state Liquid.

Form Aerosol.

Color Not available.

Odor Not available.

Odor threshold Not available.

pH Not available.

Melting point/freezing point Not available.

Initial boiling point and boiling

range

-47.2 °F (-44 °C) estimated

Flash point 1.4 °F (-17.0 °C) estimated

Evaporation rate > 1 BuAc

Flammability (solid, gas) Not available.

Upper/lower flammability or explosive limits

Explosive limit - lower (%) Not available.

Explosive limit - upper (%) Not available.

Vapor pressure 40 psig @70F estimated

Vapor density Not available.

Relative density Not available.

Solubility(ies)

Solubility (water) Not available.

Auto-ignition temperature Not available.

Decomposition temperature Not available.

Viscosity Not available.

Other information

Flammability class Flammable IA estimated

Specific gravity 0.81 estimated

10. Stability and reactivity

Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.

Chemical stability Material is stable under normal conditions.

Possibility of hazardous

reactions

Hazardous polymerization does not occur.

Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials.

Incompatible materials Strong acids. Strong oxidizing agents. Nitrates. Aluminum. Halogens. Phosphorus. Fluorine. Chlorine.

Hazardous decomposition

products

No hazardous decomposition products are known.

11. Toxicological information

Information on likely routes of exposure

Ingestion Expected to be a low ingestion hazard.

Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be harmful.

Skin contact No adverse effects due to skin contact are expected.

Eye contact Causes serious eye irritation.

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Symptoms related to the

physical, chemical and

toxicological characteristics

May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose and throat. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision.

Information on toxicological effects

Acute toxicity Narcotic effects.

Components Species

Acetone (CAS 67-64-1)

Acute

Dermal

LD50 Guinea pig

Test Results

> 7426 mg/kg, 24 Hours

> 9.4 ml/kg, 24 Hours

Inhalation

Rabbit > 7426 mg/kg, 24 Hours

> 9.4 ml/kg, 24 Hours

LC50 Rat

Oral

LD50 Rat

Barium Sulfate, Natural (CAS 7727-43-7)

Acute

Oral

LD100 Rat

55700 ppm, 3 Hours

132 mg/l, 3 Hours

50.1 mg/l

5800 mg/kg

2.2 ml/kg

564 g/kg

LD50 Rat 307 g/kg

Butane (CAS 106-97-8)

Acute

Inhalation

LC50 Mouse 1237 mg/l, 120 Minutes

52 %, 120 Minutes

Rat 1355 mg/l

Ethylene Glycol Propyl Ether (CAS 2807-30-9)

Acute

Dermal

LD50 Guinea pig 5.6 g/kg, 4 Days

Inhalation

Rabbit > 1 g/kg, 24 Hours

1337 ml/kg, 14 Days

LC50 Rat

Oral

LD50 Guinea pig

> 2132 ppm, 6 Hours

> 1800 ppm

2.2 g/kg

Isobutyl Acetate (CAS 110-19-0)

Acute

Dermal

Mouse 1774 mg/kg

Rat 0.5 - 1 g/kg

LD50 Rabbit > 17400 mg/kg, 24 Hours

Rat 5000 mg/kg

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Components

Species

Inhalation

LC50 Rat

Oral

LD50 Rat

Methyl Isobutyl Ketone (CAS 108-10-1)

Acute

Inhalation

LC50 Rat

Oral

LD50 Rat

Propane (CAS 74-98-6)

Acute

Inhalation

LC50 Mouse

Test Results

> 30 mg/l, 6 Hours

> 23.4 mg/l, 4 Hours

13413 mg/kg

2000 - 4000 ppm, 4 Hours

2.08 g/kg

1237 mg/l, 120 Minutes

52 %, 120 Minutes

Rat 1355 mg/l

658 mg/l/4h

Propylene Glycol Monomethyl Ether Acetate (CAS 108-65-6)

Acute

Dermal

LD50 Rat

Oral

LD50 Rat

Xylene (CAS 1330-20-7)

Acute

Dermal

LD50 Rabbit

Inhalation

LC50 Rat

Oral

LD50 Mouse

> 2000 mg/kg, 24 Hours

> 14.1 ml

5155 mg/kg

> 5000 ml/kg, 4 Hours

12126 mg/kg, 24 Hours

5922 ppm, 4 Hours

5251 mg/kg

Rat 3523 mg/kg

10 ml/kg

* Estimates for product may be based on additional component data not shown.

Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.

Serious eye damage/eye

irritation

Respiratory or skin sensitization

Causes serious eye irritation.

Respiratory sensitization Not available.

Skin sensitization This product is not expected to cause skin sensitization.

Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are

mutagenic or genotoxic.

Carcinogenicity Risk of cancer cannot be excluded with prolonged exposure.

IARC Monographs. Overall Evaluation of Carcinogenicity

Methyl Isobutyl Ketone (CAS 108-10-1) 2B Possibly carcinogenic to humans.

Xylene (CAS 1330-20-7) 3 Not classifiable as to carcinogenicity to humans.

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OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.

Reproductive toxicity Components in this product have been shown to cause birth defects and reproductive disorders in laboratory animals.

Specific target organ toxicity -

single exposure

Specific target organ toxicity -

repeated exposure

May cause drowsiness and dizziness.

Not classified.

Aspiration hazard Not available.

Chronic effects Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects.

12. Ecological information

Ecotoxicity Harmful to aquatic life with long lasting effects.

Components

Acetone (CAS 67-64-1)

Aquatic

Crustacea

Fish

EC50

LC50

Species

Water flea (Daphnia magna)

Rainbow trout,donaldson trout (Oncorhynchus mykiss)

Test Results

21.6 - 23.9 mg/l, 48 hours

4740 - 6330 mg/l, 96 hours

Barium Sulfate, Natural (CAS 7727-43-7)

Aquatic

Crustacea EC50 Tubificid worm (Tubifex tubifex) 28.61 - 38.03 mg/l, 48 hours

Isobutyl Acetate (CAS 110-19-0)

Aquatic

Fish LC50 Fish 100, 96 Hours

Methyl Isobutyl Ketone (CAS 108-10-1)

Aquatic

Fish LC50 Fathead minnow (Pimephales promelas) 492 - 593 mg/l, 96 hours

Methyl Propyl Ketone (CAS 107-87-9)

Aquatic

Fish LC50 Fathead minnow (Pimephales promelas) 1190 - 1290 mg/l, 96 hours

Propylene Glycol Monomethyl Ether Acetate (CAS 108-65-6)

Aquatic

Crustacea

Xylene (CAS 1330-20-7)

Aquatic

Fish

EC50

LC50

Daphnia

Bluegill (Lepomis macrochirus)

500.0001 mg/L, 48 Hours

7.711 - 9.591 mg/l, 96 hours

* Estimates for product may be based on additional component data not shown.

Persistence and degradability No data is available on the degradability of this product.

Bioaccumulative potential No data available.

Partition coefficient n-octanol / water (log Kow) Acetone -0.24

Butane 2.89

Isobutyl Acetate 1.78

Methyl Isobutyl Ketone 1.31

Methyl Propyl Ketone 0.91

Propane 2.36

Xylene 3.12 - 3.2

Mobility in soil No data available.

Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation

potential, endocrine disruption, global warming potential) are expected from this component.

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13. Disposal considerations

Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents

under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations.

Local disposal regulations Dispose in accordance with all applicable regulations.

Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company.

US RCRA Hazardous Waste U List: Reference

Acetone (CAS 67-64-1) U002

Methyl Isobutyl Ketone (CAS 108-10-1) U161

Xylene (CAS 1330-20-7) U239

Waste from residues / unused

products

Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).

Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers.

14. Transport information

DOT

UN number

UN proper shipping name

Transport hazard class(es)

Class

Subsidiary risk

Label(s)

Packing group

UN1950

Aerosols, flammable

2.1

-

2.1

Not applicable.

Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling.

Special provisions

Packaging exceptions

Packaging non bulk

Packaging bulk

N82

306

None

None

This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently.

IATA

UN number

UN proper shipping name

Transport hazard class(es)

Class

Subsidiary risk

Label(s)

Packing group

Environmental hazards

ERG Code

UN1950

Aerosols, flammable

2.1

-

2.1

Not applicable.

No.

10L

Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety

instructions, SDS and emergency procedures before handling.

Other information

Passenger and cargo

aircraft

Cargo aircraft only

Packaging Exceptions

IMDG

UN number

UN proper shipping name

Transport hazard class(es)

Class

Allowed.

Allowed.

LTD QTY

UN1950

AEROSOLS

2.1

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Subsidiary risk

Label(s)

Packing group

Environmental hazards

Marine pollutant

EmS

-

2.1

Not applicable.

No.

F-D, S-U

Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety

instructions, SDS and emergency procedures before handling.

Packaging Exceptions

Transport in bulk according to

Annex II of MARPOL 73/78 and

the IBC Code

DOT

IATA; IMDG

LTD QTY

Not applicable.

15. Regulatory information

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication

Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

Not regulated.

CERCLA Hazardous Substance List (40 CFR 302.4)

Acetone (CAS 67-64-1) Listed.

Isobutyl Acetate (CAS 110-19-0) Listed.

Methyl Isobutyl Ketone (CAS 108-10-1) Listed.

Xylene (CAS 1330-20-7) Listed.

SARA 304 Emergency release notification

Not regulated.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No

SARA 302 Extremely hazardous substance

Not listed.

SARA 311/312 Hazardous No

chemical

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SARA 313 (TRI reporting) Chemical name CAS number % by wt.

Methyl Isobutyl Ketone 108-10-1 2.5 - 10 Xylene 1330-20-7 1 - 2.5

Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List

Methyl Isobutyl Ketone (CAS 108-10-1)

Xylene (CAS 1330-20-7)

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)

Butane (CAS 106-97-8)

Propane (CAS 74-98-6)

Safe Drinking Water Act

(SDWA)

Not regulated.

Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and

Chemical Code Number

Acetone (CAS 67-64-1) 6532

Methyl Isobutyl Ketone (CAS 108-10-1) 6715

Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))

Acetone (CAS 67-64-1) 35 %WV

Methyl Isobutyl Ketone (CAS 108-10-1) 35 %WV

DEA Exempt Chemical Mixtures Code Number

Acetone (CAS 67-64-1) 6532

Methyl Isobutyl Ketone (CAS 108-10-1) 6715

US state regulations

US. Massachusetts RTK - Substance List

Acetone (CAS 67-64-1)

Barium Sulfate, Natural (CAS 7727-43-7)

Butane (CAS 106-97-8)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Propane (CAS 74-98-6)

Xylene (CAS 1330-20-7)

US. New Jersey Worker and Community Right-to-Know Act

Acetone (CAS 67-64-1)

Barium Sulfate, Natural (CAS 7727-43-7)

Butane (CAS 106-97-8)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Propane (CAS 74-98-6)

Xylene (CAS 1330-20-7)

US. Pennsylvania Worker and Community Right-to-Know Law

Acetone (CAS 67-64-1)

Barium Sulfate, Natural (CAS 7727-43-7)

Butane (CAS 106-97-8)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Propane (CAS 74-98-6)

Xylene (CAS 1330-20-7)

US. Rhode Island RTK

Acetone (CAS 67-64-1)

Butane (CAS 106-97-8)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Propane (CAS 74-98-6)

Xylene (CAS 1330-20-7)

US. California Proposition 65

WARNING: This product contains a chemical known to the State of California to cause cancer.

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US - California Proposition 65 - CRT: Listed date/Carcinogenic substance

Methyl Isobutyl Ketone (CAS 108-10-1) Listed: November 4, 2011

International Inventories

Country(s) or region Inventory name On inventory (yes/no)*

Australia Australian Inventory of Chemical Substances (AICS)

Canada Domestic Substances List (DSL)

Canada Non-Domestic Substances List (NDSL)

China Inventory of Existing Chemical Substances in China (IECSC)

Europe European Inventory of Existing Commercial Chemical Substances (EINECS)

Europe European List of Notified Chemical Substances (ELINCS)

Japan Inventory of Existing and New Chemical Substances (ENCS)

Korea Existing Chemicals List (ECL)

New Zealand New Zealand Inventory

Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS)

United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)

No

Yes

No

No

No

No

No

No

No

Yes

Yes

A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s).

16. Other information, including date of preparation or last revision

Issue date 04-25-2016

Issued By EHS Administrator

Version # 01

Disclaimer Manufacturer cannot anticipate all conditions under which this information and its product, or the

products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

Revision Information Product and Company Identification: Alternate Trade Names

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SAFETY DATA SHEET

1. Identification

Product identifier INHIBITAUR High Solids Paint – Safety Yellow

Company information CONTINENTAL RESEARCH CORP. P.O. Box 15204 ST LOUIS, MO 63110 United States

Company phone 800-325-4869

Emergency telephone US 888-255-3924 (CHEM-TEL)

Version # 01

Recommended use Not available.

Recommended restrictions None known.

2. Hazard(s) identification

Physical hazards

Health hazards

Environmental hazards

OSHA defined hazards

Label elements

Flammable aerosols

Acute toxicity, inhalation

Serious eye damage/eye irritation

Specific target organ toxicity, single exposure

Not classified.

Not classified.

Category 1

Category 4

Category 2A

Category 3 narcotic effects

Signal word Danger

Hazard statement Extremely flammable aerosol. Causes serious eye irritation. Harmful if inhaled. May cause drowsiness or dizziness.

Precautionary statement

Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open

flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing mist or vapor. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear eye/face protection.

Response If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison

center/doctor if you feel unwell. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect from

sunlight. Do not expose to temperatures exceeding 50°C/122°F.

Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.

Hazard(s) not otherwise

classified (HNOC) None known.

Supplemental information None.

3. Composition/information on ingredients

Mixtures

Chemical name Common name and synonyms

CAS number %

Acetone 67-64-1 10 - 20

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Chemical name Common name and synonyms CAS number %

Propane

Barium Sulfate, Natural

Butane

Ethylene Glycol Propyl Ether

Isobutyl Acetate

Methyl Isobutyl Ketone

Methyl Propyl Ketone

Titanium dioxide

Propylene Glycol Monomethyl Ether Acetate

Xylene

74-98-6

7727-43-7

106-97-8

2807-30-9

110-19-0

108-10-1

107-87-9

13463-67-7

108-65-6

1330-20-7

10 - 20

2.5 - 10

2.5 - 10

2.5 - 10

2.5 - 10

2.5 - 10

2.5 - 10

2.5 - 10

1 - 2.5

1 - 2.5

Other components below reportable levels 20 - 40

*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures

Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or artificial respiration if needed. Call a POISON CENTER or doctor/physician if you feel unwell.

Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists.

Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.

Ingestion In the unlikely event of swallowing contact a physician or poison control center. Rinse mouth.

Most important

symptoms/effects, acute and

delayed

Indication of immediate

medical attention and special

treatment needed

May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose and throat. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision.

Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victim under observation. Symptoms may be delayed.

General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to

protect themselves.

5. Fire-fighting measures

Suitable extinguishing media Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).

Unsuitable extinguishing

media

Specific hazards arising from

the chemical

Special protective equipment

and precautions for firefighters

Fire-fighting

equipment/instructions

Do not use water jet as an extinguisher, as this will spread the fire.

Contents under pressure. Pressurized container may explode when exposed to heat or flame.

Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA.

Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out.

Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. Move

containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes.

General fire hazards Extremely flammable aerosol.

6. Accidental release measures

Personal precautions,

protective equipment and

emergency procedures

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Avoid inhalation of vapors and spray mists. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.

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Methods and materials for

containment and cleaning up

Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS.

Environmental precautions Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all

environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage

Precautions for safe handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing

or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Avoid inhalation of vapors and spray mists. Avoid contact with eyes. Avoid prolonged exposure. Use only outdoors or in a well-ventilated area. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices.

Conditions for safe storage,

including any incompatibilities

Level 3 Aerosol.

Store locked up. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Store in a well-ventilated place. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). Level 3 Aerosol.

8. Exposure controls/personal protection

Occupational exposure limits

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

Components Type Value Form

Acetone (CAS 67-64-1) PEL 2400 mg/m3 1000 ppm Barium Sulfate, Natural

(CAS 7727-43-7) PEL 5 mg/m3 Respirable fraction.

15 mg/m3 Total dust.

Isobutyl Acetate (CAS 110-19-0)

PEL 700 mg/m3

150 ppm Methyl Isobutyl Ketone

(CAS 108-10-1) PEL 410 mg/m3

100 ppm Methyl Propyl Ketone (CAS

107-87-9) PEL 700 mg/m3

200 ppm Propane (CAS 74-98-6) PEL 1800 mg/m3 1000 ppm Titanium dioxide (CAS

13463-67-7) PEL 15 mg/m3 Total dust.

Xylene (CAS 1330-20-7) PEL 435 mg/m3 100 ppm US. ACGIH Threshold Limit Values Components Type Value Form

Acetone (CAS 67-64-1) STEL 750 ppm TWA 500 ppm Barium Sulfate, Natural

(CAS 7727-43-7) TWA 5 mg/m3 Inhalable fraction.

Butane (CAS 106-97-8) STEL 1000 ppm Isobutyl Acetate (CAS

110-19-0) TWA 150 ppm

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US. ACGIH Threshold Limit Values

Components

Type

Value

Form

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Titanium dioxide (CAS 13463-67-7)

Xylene (CAS 1330-20-7)

STEL 75 ppm

TWA 20 ppm

STEL 150 ppm

TWA 10 mg/m3

STEL 150 ppm

TWA 100 ppm

US. NIOSH: Pocket Guide to Chemical Hazards

Components Type Value Form

Acetone (CAS 67-64-1)

Barium Sulfate, Natural (CAS 7727-43-7)

Butane (CAS 106-97-8)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Propane (CAS 74-98-6)

TWA 590 mg/m3

250 ppm

TWA 5 mg/m3 Respirable.

10 mg/m3 Total

TWA 1900 mg/m3

800 ppm

TWA 700 mg/m3

150 ppm

STEL 300 mg/m3

75 ppm

TWA 205 mg/m3

50 ppm

TWA 530 mg/m3

150 ppm

TWA 1800 mg/m3

1000 ppm

US. Workplace Environmental Exposure Level (WEEL) Guides

Components Type

Value

Propylene Glycol Monomethyl Ether Acetate (CAS 108-65-6)

Biological limit values

ACGIH Biological Exposure Indices

TWA 50 ppm

Components Value Determinant Specimen Sampling Time

Acetone (CAS 67-64-1) 50 mg/l Acetone Urine *

Methyl Isobutyl Ketone (CAS 108-10-1)

1 mg/l Methyl isobutyl ketone

Urine *

Xylene (CAS 1330-20-7) 1.5 g/g Methylhippuric acids

Creatinine in urine

*

* - For sampling details, please see the source document.

Exposure guidelines

US - California OELs: Skin designation

Propylene Glycol Monomethyl Ether Acetate (CAS 108-65-6)

Can be absorbed through the skin.

Appropriate engineering

controls

Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station.

Individual protection measures, such as personal protective equipment

Eye/face protection Chemical respirator with organic vapor cartridge and full facepiece.

Hand protection Wear appropriate chemical resistant gloves.

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Skin protection

Other Wear suitable protective clothing.

Respiratory protection Chemical respirator with organic vapor cartridge and full facepiece.

Thermal hazards Wear appropriate thermal protective clothing, when necessary.

General hygiene

considerations

When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.

9. Physical and chemical properties

Appearance

Physical state Liquid.

Form Aerosol.

Color Not available.

Odor Not available.

Odor threshold Not available.

pH Not available.

Melting point/freezing point Not available.

Initial boiling point and boiling

range

-47.2 °F (-44 °C) estimated

Flash point 1.4 °F (-17.0 °C) estimated

Evaporation rate > 1 BuAc estimated

Flammability (solid, gas) Not available.

Upper/lower flammability or explosive limits

Explosive limit - lower (%) 1.7 estimated

Explosive limit - upper (%) 10.9 estimated

Vapor pressure 40 psig @70F estimated

Vapor density Not available.

Relative density Not available.

Solubility(ies)

Solubility (water) Not available.

Auto-ignition temperature Not available.

Decomposition temperature Not available.

Viscosity Not available.

Other information

Flammability class Flammable IA estimated

Specific gravity 0.81 estimated

10. Stability and reactivity

Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.

Chemical stability Material is stable under normal conditions.

Possibility of hazardous

reactions

Hazardous polymerization does not occur.

Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials.

Incompatible materials Strong acids. Strong oxidizing agents. Nitrates. Aluminum. Halogens. Phosphorus. Fluorine. Chlorine.

Hazardous decomposition

products

No hazardous decomposition products are known.

11. Toxicological information

Information on likely routes of exposure

Ingestion Expected to be a low ingestion hazard.

Inhalation Harmful if inhaled. May cause drowsiness and dizziness. Headache. Nausea, vomiting.

Skin contact No adverse effects due to skin contact are expected.

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Eye contact Causes serious eye irritation.

Symptoms related to the

physical, chemical and

toxicological characteristics

May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose and throat. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision.

Information on toxicological effects

Acute toxicity Harmful if inhaled. Narcotic effects.

Components Species

Acetone (CAS 67-64-1)

Acute

Dermal

LD50 Guinea pig

Test Results

> 7426 mg/kg, 24 Hours

> 9.4 ml/kg, 24 Hours

Inhalation

Rabbit > 7426 mg/kg, 24 Hours

> 9.4 ml/kg, 24 Hours

LC50 Rat

Oral

LD50 Rat

Barium Sulfate, Natural (CAS 7727-43-7)

Acute

Oral

LD100 Rat

55700 ppm, 3 Hours

132 mg/l, 3 Hours

50.1 mg/l

5800 mg/kg

2.2 ml/kg

564 g/kg

LD50 Rat 307 g/kg

Butane (CAS 106-97-8)

Acute

Inhalation

LC50 Mouse 1237 mg/l, 120 Minutes

52 %, 120 Minutes

Rat 1355 mg/l

Ethylene Glycol Propyl Ether (CAS 2807-30-9)

Acute

Dermal

LD50 Guinea pig 5.6 g/kg, 4 Days

Inhalation

Rabbit > 1 g/kg, 24 Hours

1337 ml/kg, 14 Days

LC50 Rat

Oral

LD50 Guinea pig

> 2132 ppm, 6 Hours

> 1800 ppm

2.2 g/kg

Isobutyl Acetate (CAS 110-19-0)

Acute

Dermal

Mouse 1774 mg/kg

Rat 0.5 - 1 g/kg

LD50 Rabbit > 17400 mg/kg, 24 Hours

Rat 5000 mg/kg

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Components

Species

Inhalation

LC50 Rat

Oral

LD50 Rat

Methyl Isobutyl Ketone (CAS 108-10-1)

Acute

Inhalation

LC50 Rat

Oral

LD50 Rat

Propane (CAS 74-98-6)

Acute

Inhalation

LC50 Mouse

Test Results

> 30 mg/l, 6 Hours

> 23.4 mg/l, 4 Hours

13413 mg/kg

2000 - 4000 ppm, 4 Hours

2.08 g/kg

1237 mg/l, 120 Minutes

52 %, 120 Minutes

Rat 1355 mg/l

658 mg/l/4h

Propylene Glycol Monomethyl Ether Acetate (CAS 108-65-6)

Acute

Dermal

LD50 Rat

Oral

LD50 Rat

Titanium dioxide (CAS 13463-67-7)

Acute

Inhalation

LC50 Rat

Oral

LD50 Rat

Xylene (CAS 1330-20-7)

Acute

Dermal

LD50 Rabbit

Inhalation

LC50 Rat

Oral

LD50 Mouse

> 2000 mg/kg, 24 Hours

> 14.1 ml

5155 mg/kg

> 2.28 mg/l, 4 Hours

> 11000 mg/kg

> 5000 ml/kg, 4 Hours

12126 mg/kg, 24 Hours

5922 ppm, 4 Hours

5251 mg/kg

Rat 3523 mg/kg

10 ml/kg

* Estimates for product may be based on additional component data not shown.

Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.

Serious eye damage/eye

irritation

Respiratory or skin sensitization

Causes serious eye irritation.

Respiratory sensitization Not available.

Skin sensitization This product is not expected to cause skin sensitization.

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Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.

Carcinogenicity Risk of cancer cannot be excluded with prolonged exposure.

IARC Monographs. Overall Evaluation of Carcinogenicity

Methyl Isobutyl Ketone (CAS 108-10-1) 2B Possibly carcinogenic to humans.

Titanium dioxide (CAS 13463-67-7) 2B Possibly carcinogenic to humans.

Xylene (CAS 1330-20-7) 3 Not classifiable as to carcinogenicity to humans.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.

Reproductive toxicity Components in this product have been shown to cause birth defects and reproductive disorders in laboratory animals.

Specific target organ toxicity -

single exposure

Specific target organ toxicity -

repeated exposure

May cause drowsiness and dizziness.

Not classified.

Aspiration hazard Not available.

Chronic effects Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects.

12. Ecological information

Ecotoxicity Harmful to aquatic life with long lasting effects.

Components

Acetone (CAS 67-64-1)

Aquatic

Crustacea

Fish

EC50

LC50

Species

Water flea (Daphnia magna)

Rainbow trout,donaldson trout (Oncorhynchus mykiss)

Test Results

21.6 - 23.9 mg/l, 48 hours

4740 - 6330 mg/l, 96 hours

Barium Sulfate, Natural (CAS 7727-43-7)

Aquatic

Crustacea EC50 Tubificid worm (Tubifex tubifex) 28.61 - 38.03 mg/l, 48 hours

Isobutyl Acetate (CAS 110-19-0)

Aquatic

Fish LC50 Fish 100, 96 Hours

Methyl Isobutyl Ketone (CAS 108-10-1)

Aquatic

Fish LC50 Fathead minnow (Pimephales promelas) 492 - 593 mg/l, 96 hours

Methyl Propyl Ketone (CAS 107-87-9)

Aquatic

Fish LC50 Fathead minnow (Pimephales promelas) 1190 - 1290 mg/l, 96 hours

Propylene Glycol Monomethyl Ether Acetate (CAS 108-65-6)

Aquatic

Crustacea EC50 Daphnia 500.0001 mg/L, 48 Hours

Titanium dioxide (CAS 13463-67-7)

Aquatic

Crustacea

Fish

Xylene (CAS 1330-20-7)

Aquatic

Fish

EC50

LC50

LC50

Water flea (Daphnia magna)

Mummichog (Fundulus heteroclitus)

Bluegill (Lepomis macrochirus)

> 1000 mg/l, 48 hours

> 1000 mg/l, 96 hours

7.711 - 9.591 mg/l, 96 hours

* Estimates for product may be based on additional component data not shown.

Persistence and degradability No data is available on the degradability of this product.

Bioaccumulative potential No data available.

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Partition coefficient n-octanol / water (log Kow) Acetone -0.24

Butane 2.89

Isobutyl Acetate 1.78

Methyl Isobutyl Ketone 1.31

Methyl Propyl Ketone 0.91

Propane 2.36

Xylene 3.12 - 3.2

Mobility in soil No data available.

Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation

potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations

Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents

under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations.

Local disposal regulations Dispose in accordance with all applicable regulations.

Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company.

US RCRA Hazardous Waste U List: Reference

Acetone (CAS 67-64-1) U002

Methyl Isobutyl Ketone (CAS 108-10-1) U161

Xylene (CAS 1330-20-7) U239

Waste from residues / unused

products

Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).

Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers.

14. Transport information

DOT

UN number

UN proper shipping name

Transport hazard class(es)

Class

Subsidiary risk

Label(s)

Packing group

UN1950

Aerosols, flammable

2.1

-

2.1

Not applicable.

Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling.

Special provisions

Packaging exceptions

Packaging non bulk

Packaging bulk

N82

306

None

None

This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently.

IATA

UN number

UN proper shipping name

Transport hazard class(es)

Class

Subsidiary risk

Label(s)

Packing group

Environmental hazards

ERG Code

UN1950

Aerosols, flammable

2.1

-

2.1

Not applicable.

No.

10L

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Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling.

Other information

Passenger and cargo

aircraft

Cargo aircraft only

Packaging Exceptions

IMDG

UN number

UN proper shipping name

Transport hazard class(es)

Class

Subsidiary risk

Label(s)

Packing group

Environmental hazards

Marine pollutant

EmS

Allowed.

Allowed.

LTD QTY

UN1950

AEROSOLS

2.1

-

2.1

Not applicable.

No.

F-D, S-U

Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling.

Packaging Exceptions

Transport in bulk according to

Annex II of MARPOL 73/78 and

the IBC Code

DOT

IATA; IMDG

LTD QTY

Not applicable.

15. Regulatory information

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication

Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

Not regulated.

CERCLA Hazardous Substance List (40 CFR 302.4)

Acetone (CAS 67-64-1) Listed.

Isobutyl Acetate (CAS 110-19-0) Listed.

Methyl Isobutyl Ketone (CAS 108-10-1) Listed.

Xylene (CAS 1330-20-7) Listed.

SARA 304 Emergency release notification

Not regulated.

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OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No

SARA 302 Extremely hazardous substance

Not listed.

SARA 311/312 Hazardous No

chemical

SARA 313 (TRI reporting)

Chemical name CAS number % by wt.

Methyl Isobutyl Ketone 108-10-1 2.5 - 10

Xylene 1330-20-7 1 - 2.5

Other federal regulations

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List

Methyl Isobutyl Ketone (CAS 108-10-1)

Xylene (CAS 1330-20-7)

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)

Butane (CAS 106-97-8)

Propane (CAS 74-98-6)

Safe Drinking Water Act

(SDWA)

Not regulated.

Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and

Chemical Code Number

Acetone (CAS 67-64-1) 6532

Methyl Isobutyl Ketone (CAS 108-10-1) 6715

Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))

Acetone (CAS 67-64-1) 35 %WV

Methyl Isobutyl Ketone (CAS 108-10-1) 35 %WV

DEA Exempt Chemical Mixtures Code Number

Acetone (CAS 67-64-1) 6532

Methyl Isobutyl Ketone (CAS 108-10-1) 6715

US state regulations

US. Massachusetts RTK - Substance List

Acetone (CAS 67-64-1)

Barium Sulfate, Natural (CAS 7727-43-7)

Butane (CAS 106-97-8)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Propane (CAS 74-98-6)

Titanium dioxide (CAS 13463-67-7)

Xylene (CAS 1330-20-7)

US. New Jersey Worker and Community Right-to-Know Act

Acetone (CAS 67-64-1)

Barium Sulfate, Natural (CAS 7727-43-7)

Butane (CAS 106-97-8)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Propane (CAS 74-98-6)

Titanium dioxide (CAS 13463-67-7)

Xylene (CAS 1330-20-7)

US. Pennsylvania Worker and Community Right-to-Know Law

Acetone (CAS 67-64-1)

Barium Sulfate, Natural (CAS 7727-43-7)

Butane (CAS 106-97-8)

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Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Methyl Propyl Ketone (CAS 107-87-9)

Propane (CAS 74-98-6)

Titanium dioxide (CAS 13463-67-7)

Xylene (CAS 1330-20-7)

US. Rhode Island RTK

Acetone (CAS 67-64-1)

Butane (CAS 106-97-8)

Isobutyl Acetate (CAS 110-19-0)

Methyl Isobutyl Ketone (CAS 108-10-1)

Propane (CAS 74-98-6)

Xylene (CAS 1330-20-7)

US. California Proposition 65

WARNING: This product contains a chemical known to the State of California to cause cancer.

US - California Proposition 65 - CRT: Listed date/Carcinogenic substance

Methyl Isobutyl Ketone (CAS 108-10-1) Listed: November 4, 2011

Titanium dioxide (CAS 13463-67-7) Listed: September 2, 2011

International Inventories

Country(s) or region Inventory name On inventory (yes/no)*

Australia Australian Inventory of Chemical Substances (AICS)

Canada Domestic Substances List (DSL)

Canada Non-Domestic Substances List (NDSL)

China Inventory of Existing Chemical Substances in China (IECSC)

Europe European Inventory of Existing Commercial Chemical Substances (EINECS)

Europe European List of Notified Chemical Substances (ELINCS)

Japan Inventory of Existing and New Chemical Substances (ENCS)

Korea Existing Chemicals List (ECL)

New Zealand New Zealand Inventory

Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS)

United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)

No

Yes

No

No

No

No

No

No

No

Yes

Yes

A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s).

16. Other information, including date of preparation or last revision

Issue date 04-25-2016

Issued By EHS Administrator

Version # 01

Disclaimer The manufacturer cannot anticipate all conditions under which this information and its product, or

the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

Revision Information Product and Company Identification: Alternate Trade Names GHS: Classification

Page 87: SAFETY DATA SHEET - crcorp...Isobutyl Acetate 110-19-0 1 - 2.5 Xylene 1330-20-7 1 - 2.5 Other components below reportable levels 20 - 40 *Designates that a specific chemical identity

Product name: INHIBITAUR High Solids SAFETY YELLOW

Issue date: 04-25-2016

SDS US

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