safety data sheet heptaneprotective.ansell.com/global/protective-products/msds/1... ·...

SDS according to Regulation (EC) No. 1907/2006 concerning the Registration, Evaluation, Authorisation and Restrictionof Chemicals (REACH), Annex II-EU

SECTION 1: Identification of the substance / mixture and of the company /undertaking

1.1. Product identifier

1.2. Relevant identified uses of the substance or mixture and uses advised against

1.3. Details of the supplier of the safety data sheet

Foreign manufacturer

Distributor

SAFETY DATA SHEET

HEPTANE

26.04.2019

05.04.2019

HEPTANE

01-2119475515-33

927-510-4

601-008-00-2

HEPTANE--DR

No

Solvent.

Caldic Nederland B.V.

Westerlaan 1,

3016

CK Rotterdam

The Netherlands

+31 10 4136420

Algol Chemicals Oy

Karapellontie 6

02610

Espoo

Finland

Date issued

Revision date

Product name

REACH Reg. No.

EC No.

Index No.

Article no.

Extended SDS with ESincorporated

Use of the substance / preparation

Company name

Office address

Postcode

City

Country

Telephone number

Company name

Office address

Postcode

City

Country

HEPTANE - Version 3 of 12

This document is created with Publisher (EcoOnline) Revision date 05.04.2019

1.4. Emergency telephone number

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

2.2. Label elements

Hazard pictograms (CLP)

2.3. Other hazards

SECTION 3: Composition / information on ingredients

+358-9-50991

[email protected]

www.algolchemicals.fi

FI07774850

Description: Poison Information Centre, Tukholmankatu 17, P.O.Box 790, FI-00029HUS Helsinki), Finland tel. (24 h) / 09-4711 (exchange), 09-471977 (direct)

Flam. Liq. 2; H225

Skin Irrit. 2; H315

STOT SE 3; H336

Asp. tox. 1; H304

Aquatic Chronic 2; H411

Danger

H225 Highly flammable liquid and vapour.H315 Causes skin irritation.H336 May cause drowsiness or dizziness.H304 May be fatal if swallowed and enters airways.H411 Toxic to aquatic life with long lasting effects.

P210 Keep away from heat / sparks / open flames / hot surfaces. – No smoking.P243 Take action to prevent static discharge.P261 Avoid breathing dust / fume / gas / mist / vapours / spray.P301+P310 IF SWALLOWED: Immediately call a POISON CENTER / doctor / .P331 Do NOT induce vomiting.P405 Store locked up.

P501 Dispose of contents / container according to national and local regulations.

Not applicable.

Telephone number

Email

Website

Enterprise No.

Emergency telephone

Classification according toRegulation (EC) No 1272/2008[CLP / GHS]

Signal word

Hazard statements

Precautionary statements

Supplemental label information

PBT / vPvB



mailto:[email protected]

3.1. Substances

Substance Identification Classification ContentsHydrocarbons, C7, n-alkanes,isoalkanes, cyclics

EC No.: 927-510-4REACH Reg. No.:01-2119475515-33

~ 100 %

SECTION 4: First aid measures

4.1. Description of first aid measures

4.2. Most important symptoms and effects, both acute and delayed

4.3. Indication of any immediate medical attention and special treatment needed

SECTION 5: Firefighting measures

5.1. Extinguishing media

5.2. Special hazards arising from the substance or mixture

5.3. Advice for firefighters

SECTION 6: Accidental release measures

Immediately remove contaminated clothing.

Move into fresh air and keep at rest. If breathing stops, provide artificialrespiration. Consult a physician for specific advice.

Wash the skin immediately with soap and water.

IF IN EYES: Rinse cautiously with water for several minutes. Remove contactlenses, if present and easy to do. Continue rinsing. Consult a physician forspecific advice.

DO NOT induce vomiting. Get medical attention immediately.

Headache. Unconsciousness.

Pulmonary oedema, frothy sputum.Tachycardia, (excessively rapid heart beat, including rapid and weak pulse).

No other information noted.

Extinguish with dry sand. Foam. Water spray. Carbon dioxide or dry powder.

Do not use water jet as an extinguisher, as this will spread the fire.

Carbon monoxide (CO).

Self contained breathing apparatus and full protective clothing must be worn incase of fire.

Cool containers exposed to heat with water spray and remove container, if no riskis involved.

General

Inhalation

Skin contact

Eye contact

Ingestion

Acute symptoms and effects

Delayed symptoms and effects

Medical treatment

Suitable extinguishing media

Improper extinguishing media

Hazardous combustion products

Personal protective equipment

Other information



6.1. Personal precautions, protective equipment and emergency procedures

6.2. Environmental precautions

6.3. Methods and material for containment and cleaning up

6.4. Reference to other sections

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Protective safety measures

7.2. Conditions for safe storage, including any incompatibilities

Conditions for safe storage

7.3. Specific end use(s)

Provide adequate ventilation.

Use personal protective equipment as required.

Keep public away from danger area.

Prevent spillage entering a watercourse or sewer, contaminating soil orvegetation. If this is not possible notify police and appropriate authoritiesimmediately.

Provide adequate ventilation.

Dam and absorb spillage with sand, sawdust or other absorbent.Use mechanical handling equipment.Collect into suitable containers for recovery or disposal.For waste disposal, see section 13.

For personal protection, see section 8.For waste disposal, see section 13.

Handle and open container with care. Provide adequate ventilation. Vapours areheavier than air and may spread near ground to sources of ignition. Staticelectricity and formation of sparks must be prevented.

Keep away from sources of ignition - No smoking.Protect from heat and direct sunlight.Use spark-proof tools and explosion-proof equipment.Forms explosive mixtures with air.

Keep in an area equipped with solvent resistant flooring.Store in a cool place.

Store in tightly closed original container in a dry, cool and well-ventilated place.Protect from heat and direct sunlight.

No specific recommendations.

General measures

Protective equipment

Emergency procedures

Environmental precautionarymeasures

Containment

Clean up

Other instructions

Handling

Safety measures to prevent fire

Requirements for storage roomsand vessels

Additional information on storageconditions

Specific use(s)



SECTION 8: Exposure controls / personal protection

8.1. Control parameters

DNEL / PNEC

8.2. Exposure controls

Precautionary measures to prevent exposure

Eye / face protection

Hand protection

Skin protection

Respiratory protection

Hydrocarbons, C7, n-alkanes, isoalkanes, cyclics

Group: ConsumerRoute of exposure: Long-term oral (systemic)Value: 149 mg/kg bw/day

Group: ConsumerRoute of exposure: Long-term dermal (systemic)Value: 149 mg/kg bw/day

Group: ProfessionalRoute of exposure: Long-term dermal (systemic)Value: 300 mg/kg bw/day

Group: ConsumerRoute of exposure: Long-term inhalation (systemic)Value: 447 mg/m³

Group: ProfessionalRoute of exposure: Long-term inhalation (systemic)Value: 2085 mg/m³

Do not breathe gas/fumes/vapour/spray.

Wear tight-fitting goggles or face shield.

Use protective gloves, goggles and suitable protective clothing.

Nitrile. Neoprene. PVC gloves are recommended.

Value: 480 minute(s)

The most suitable glove must be chosen in consultation with the gloves supplier,who can inform about the breakthrough time of the glove material.

Wear full protective clothing.

Respiratory protection may be required.

Substance

DNEL

Appropriate engineering controls

Suitable eye protection

Skin- / hand protection, short termcontact

Suitable gloves type

Breakthrough time

Hand protection, comments

Suitable protective clothing

Respiratory protection necessaryat



Hygiene / environmental

Appropriate environmental exposure control

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

This product should not be used under conditions of poor ventilation unless aprotective mask with an appropriate gas filter (i.e. type A1 according to standardEN 14387) is used.

Keep separate from food, feedstuffs, fertilisers and other sensitive material.Remove contaminated clothing and wash the skin thoroughly with soap andwater after work.Wash hands before breaks and before smoking, eating or drinking.Avoid contact with skin and eyes.When using do not eat, drink or smoke.

Not available.

Fluid.

Not determined.

Characteristic.

Comments: Not determined.

Value: 83 - 105 °CMethod: (ASTM D1078)

Value: < 0 °CMethod: (ASTM D-56)

Value: 4,8Comments: (n-butylacetate = 1)

Value: 0,6 %

Value: 7 vol%

Value: 60 hPaTemperature: 20 °C

Value: 0,681 - 0,781 g/cm³Temperature: 20 °C

Medium: WaterComments: Insoluble in water.

Comments: Not determined.

Value: 0,5 - 1,2 mm2/sMethod: (ASTM D702)

None.

Recommended type of equipment

Specific hygiene measures

Environmental exposure controls

Physical state

Colour

Odour

Melting point / melting range

Boiling point / boiling range

Flash point

Evaporation rate

Lower explosion limit with unit ofmeasurement

Upper explosion limit with units ofmeasurement

Vapour pressure

Density

Solubility

Partition coefficient: n-octanol/water

Viscosity

Oxidising properties



9.2. Other information

Other physical and chemical properties

SECTION 10: Stability and reactivity

10.1. Reactivity

10.2. Chemical stability

10.3. Possibility of hazardous reactions

10.4. Conditions to avoid

10.5. Incompatible materials

10.6. Hazardous decomposition products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Molecular weight: 98 g/mol

Not determined.

There are no anticipated hazardous decomposition products associated with thismaterial.

Strong oxidising agents.

No information available.

Strong oxidising agents.

Carbon monoxide (CO). Carbon dioxide (CO2).

Effect tested: LD50Route of exposure: OralValue: > 5840 mg/kgSpecies: RatComments: (OECD 401)

Effect tested: LD50Route of exposure: DermalValue: > 2920 mg/kgSpecies: RabbitComments: (OECD 402)

Effect tested: LC50Route of exposure: Inhalation.Value: > 23,3 mg/lSpecies: RatComments: (OECD 403)

Physical and chemical properties

Reactivity

Stability

Possibility of hazardous reactions

Conditions to avoid

Materials to avoid

Hazardous decompositionproducts

Acute toxicity



Other information regarding health hazards

SECTION 12: Ecological information

12.1. Toxicity

Irritating to skin.

Based on available data the classification criteria are not met.

Based on available data, the classification criteria are not met.



Comments: Vapours may cause drowsiness and dizziness.

Comments: Based on available data the classification criteria are not met.

H304 May be fatal if swallowed and enters airways.

Value: > 1 ≤ 10 mg/lEffect dose concentration : LC50

Value: > 1 ≤ 10 mg/lEffect dose concentration : EC50

Value: > 1 ≤ 10 mg/lEffect dose concentration : IC50

Value: 1 - 10 mg/lEffect dose concentration : NOEC


Value: 1 -10 mg/lEffect dose concentration : LC50

Value: 1 -10 mg/lEffect dose concentration : EC50

Value: 1 -10 mg/lEffect dose concentration : IC50

Value: 1 -10 mg/lEffect dose concentration : NOEC

Value: > 1 ≤ 10 mg/lEffect dose concentration : LC50

Value: > 1 ≤ 10 mg/lEffect dose concentration : EC50

Value: > 1 ≤ 10 mg/lEffect dose concentration : IC50


Skin corrosion / irritation, otherinformation

General respiratory or skinsensitisation

Mutagenicity

Carcinogenicity, other information

Reproductive toxicity

STOT-single exposure, test results

Specific target organ toxicity - RE,test results

Assessment of aspiration hazard,classification

Acute aquatic, fish

Substance

Acute aquatic, fish

Acute aquatic, algae

Substance



12.2. Persistence and degradability

12.3. Bioaccumulative potential

12.4. Mobility in soil

12.5. Results of PBT and vPvB assessment

12.6. Other adverse effects


Value: 10 - 100 mg/l



Value: 10 -100 mg/lEffect dose concentration : EC50

Value: 10 -100 mg/lEffect dose concentration : IC50


Value: 1 -10 mg/lEffect dose concentration : EC50Species: Activated sludge.


Value: 1 -10 mg/lEffect dose concentration : IC50Species: Activated sludge.

Value: 0.1 -1 mg/lEffect dose concentration : NOECSpecies: Activated sludge.

TISBE Marine copepod - LC50 / IC50 / EC50 : 1 - 10 mg/l , NOEC : 0.1 - 1 mg/l

The product is easily biodegradable.



Not applicable.

Not applicable.

Very toxic to aquatic organisms.

Acute aquatic, algae

Toxicity to bacteria

Substance

Toxicity to bacteria

Substance

Impact on sewage treatment

Other ecotoxicologicalinformation, crustaceans

Persistence and degradabilitydescription

Bioaccumulative potential

Mobility

PBT assessment results

vPvB evaluation results

Additional ecological information



SECTION 13: Disposal considerations

13.1. Waste treatment methods

SECTION 14: Transport information

14.1. UN number

14.2. UN proper shipping name

14.3. Transport hazard class(es)

14.4. Packing group

14.5. Environmental hazards

14.6. Special precautions for user

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

Do not dispose of together with household waste. No emission to sewagetreatment plant. Dispose of waste and residues in accordance with localauthority requirements.

Yes

1206

1206

1206

HEPTANES

HEPTANES

HEPTANES

HEPTANES

3

F1

3

3

II

II

II

Yes

HEPTANES

Specify the appropriate methodsof disposal

Dangerous goods

ADR / RID / ADN

IMDG

ICAO / IATA

Proper shipping name english ADR/ RID / ADN

ADR / RID / ADN

IMDG

ICAO / IATA

ADR / RID / ADN

Classificaton code ADR / RID /ADN

IMDG

ICAO / IATA

ADR / RID / ADN

IMDG

ICAO / IATA

IMDG Marine pollutant

Product name



Additional information

ADR / RID - Other information

IMDG / ICAO / IATA Other information

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations / legislation specific for the substanceor mixture

15.2. Chemical safety assessment

SECTION 16: Other information

3

3

3

D/E

2

33

33

F-E, S-D

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of18 December 2006 concerning the Registration, Evaluation, Authorisation andRestriction of Chemicals (REACH), establishing a European Chemicals Agency,amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and2000/21/EC, including amendments.Regulation (EC) No 1272/2008 of the European Parliament and of the Council of16 December 2008 on classification, labelling and packaging of substances andmixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, andamending Regulation (EC) No 1907/2006 with amendments.

Yes

The information on this data sheet represents our current data and is reliableprovided that the product is used under the prescribed conditions and inaccordance with the application specified on the packaging and/or in thetechnical guidance literature. Any other use of the product which involves usingthe product in combination with any other product or any other process is theresponsibility of the user.

H225 Highly flammable liquid and vapour.H304 May be fatal if swallowed and enters airways.H315 Causes skin irritation.H336 May cause drowsiness or dizziness.

ADR / RID / ADN hazard label

IMDG Hazard label

ICAO / IATA Hazard label

Tunnel restriction code

Transport category

Hazard No.

RID other applicable information

EmS

Legislation and regulations

Chemical safety assessmentperformed

Supplier's notes

List of relevant H-phrases (Section2 and 3)



H411 Toxic to aquatic life with long lasting effects.

Classification according to supplier.Harmonized classification.

Material Safety Data Sheet 21.03.2018

3

CLP classification, notes

Key literature references andsources for data

Version



safety data sheet heptaneprotective.ansell.com/global/protective-products/msds/1... ·...

Documents