A wettable powder containing 50% dimethomorph.

A fungicide for use against crown rot (Phytophthora cactorum)in strawberries and root rot (Phytophthora spp.) in raspberries and

blackberries.

Supplied by:Servem Limited,Maxboley,Duncormick,Co. Wexford,Ireland

Office Tel+353 51 563530, Fax:+353 51 563531Emergency Information (24 hours freephone): Telephone +353 51 563530

SAFETY PRECAUTIONSOperator protectionEngineering control of operator exposure must be used where reasonably practicable in addition to the following personal protective equipment.WEAR SUITABLE PROTECTIVE GLOVES AND SUITABLE RESPIRATORY PROTECTIVEEQUIPMENT (disposable filtering facepiece respirator to at least EN149 FFP2 or equivalent) when handling the product.WEAR SUITABLE PROTECTIVE GLOVES when handling contaminated surfaces.WASH ALL PROTECTIVE CLOTHING thoroughly after use, especially the insides of gloves.Environmental protectionDo not contaminate water with the product or its container. Do not clean application equipment near surface water. Avoid contamination via drains from farmyards and roads.Do not allow direct spray from ground crop sprayers to fall withn 5m of the top of the bank of a static or flowing waterbody or within 1m of the top of a ditch which is dry at the time of application.Storage and disposalSTORE IN ORIGINAL CONTAINER tightly closed, in a safe place. WASH OUT CONTAINER THOROUGHLY and dispose of safely.This product is approved under the S.I. No 159 of 2012.

RIGEL

Risk and Safety InformationHarmful to aquatic life with long lasting effects.

To avoid risks to human health and the environment, comply with the instructions for use.

Dispose of contents/container to a licensed waste disposal contractor or collection site except for triple rinsed empty containers which may be disposed of as non-hazardous waste

To protect aquatic organisms respect an unsprayed buffer one of 5m to surface water bodies

PCS NO 05280

1kgSPECIMEN -

2015

to da

te

DIRECTIONS FOR USEIMPORTANT: This information is approved as part of the Product Label. All instructions within this section must be read carefully in order to obtain safe and successful use of this product.1. Restrictions/Warnings For professional use only. 1.1 Processed cropsConsult processor before use on crops for processing2. Disease controlRigel is a fungicide with protectant activity against crown rot (Phytophthora cactorum) in strawberries and root rot (Phytophthora spp.) in raspberries and blackberries. Rigel will be most effective when applied as a protectant treatment immediately after planting, before disease symptoms appear.2.1 ResistanceRigel contains dimethomorph, a CAA fungicide. It should be used in accordance with FRAC resistance management advice for CAA fungicides.In outdoor and protected crops of strawberries, no more than one application of Rigel per year may be made for moderate control of crown rot (Phytophthora cactorum). Applications should be made preventatively after planting.In raspberries and blackberries, no more than one application of Rigel per year may be made for moderate control of root rot (Phytophthora spp.). Applications should be made preventatively immediately after planting in the spring or autumn. Alternation with fungicides with different modes of

action to Rigel is recommended as part of a resistance management programme. CAA fungicides should not make up more than 50% of the intended number of fungicide applications for Phytophthora disease control in strawberries, raspberries and blackberries.Use Rigel as part of an Integrated Crop Management (ICM) strategy incorporating other methods of control, including where appropriate fungicides with a different mode of action.3. Crops3.1 Outdoor strawberries Time of applicationFor the moderate control of crown rot (Phytophthora cactorum) apply Rigel as a preventative treatment immediately after planting.Rate of applicationApply Rigel at 3.0 kg/ha as a high volume spray of 600–1000 litres of water per hectare, ensuring good coverage around the base of the plant.3.2 Protected strawberries Time of applicationFor the moderate control of crown rot (Phytophthora cactorum), apply Rigel as a preventative treatment immediately after planting.Rate of applicationApply Rigel as a drip irrigation or root drench treatment of 0.1 gram of product per plant, not exceeding 3.0 kg of product/ha.Rigel may be used at the following dilutions and water volumes: 1g Rigel/litre of water - use 100 ml/plant0.5g Rigel/litre of water - use 200 ml/plant 0.25g Rigel/litre of

IMPORTANT INFORMATION

FOR USE ONLY AS A HORTICULTURAL FUNGICIDE, as directed below:

Crop Maximum individual Dose (kg product/ha) 3.0 3.0 See ‘Other Specific Restriction (1)’ for details. 3.0 See ‘Other Specific Restriction (2)’ for details.

Maximum number of applications (per year) 1 1

Latest Time of Application

Strawberry (outdoor) Strawberry (protected)

35 days before harvest 35 days before harvest

Raspberries, blackberries (outdoor and protected qualified minor use)

1 90 days before harvest

Other Specific Restrictions: (1) For use on protected strawberry as a drip irrigation or root drench the concentration of

the diluted product must not exceed 1 g product per litre water. If using the maximum concentration do not apply more than 100 ml of diluted product/solution per plant. Do not exceed the maximum individual dose or exceed 0.1 g product per plant.

(2) For the use on protected and outdoor raspberries and blackberries as a drip irrigation or root drench the concentration of the diluted product must not exceed 5 g product per litre water. If using the maximum concentration do not apply more than 200 ml of the diluted product/ solution per plant. Do not exceed the maximum individual dose or exceed 1.0g product per plant.

READ THE LABEL BEFORE USE. USING THIS PRODUCT IN A MANNER THAT IS INCONSISTENT WITH THE LABEL MAY BE AN OFFENCE. FOLLOW THE CODE OF PRACTICE FOR USING PLANT PROTECTION PRODUCTS.

water - use 400 ml/plant

3.3 Raspberries and blackberries (outdoor and protected) – qualified minor use recommendation Time of applicationFor the moderate control of root rot (Phytophthora spp.) apply Riigel as a preventative treatment immediately after planting in the spring or autumn.Rate of applicationApply as a drip irrigation or root drench treatment delivering 1.0 g of Rigel per plant, not exceeding 3.0 kg of product/ha.Rigel may be used at the following dilutions and water volumes: 5g Rigel/litre of water - use 200 ml/plant2.5g Rigel/litre of water - use 400 ml/plant*There is limited evidence of crop safety and/or product efficacy available for Qualified Minor uses and the commercial risk of using this product under this Qualified Minor use is borne entirely by the grower.

4. Succeeding CropsFollowing application of Rigel, allow 10 months before sowing clover.5. Mixing and ApplicationIn outdoor strawberries, Rigel should be applied as a COARSE spray as defined by BCPC, using a high volume drenching spray of 600–1000 litres of water per hectare, using hydraulic nozzles and ensuring good coverage around the base of the plant. In protected crops of strawberries, Rigel should be applied via drip irrigation or as a root drench delivering at least 100 ml of water per plant. In outdoor or protected raspberries and blackberries, Rigel should be applied via drip irrigation or as a root drench delivering at least 200 ml of water per plant.Half fill the sprayer, drench or irrigation tank with clean water and start agitation.Steadily add the required quantity of Rigel direct to the spray, drench or irrigation tank (pre-mixing is not necessary). Empty product container thoroughly and dispose of safely.Add the remainder of the water.Apply immediately and continue agitation until spraying, irrigation or drenching is complete.Wash sprayer or flush out drench or irrigation equipment thoroughly immediately after use, using clean water and following best practice advice and the guidance provided by the equipment manufacturer.Do not apply via knapsack sprayers.

The following does not form part of the product label under the UK Plant Protection Products Regulations or the Irish S.I. No. 159 of 2012.

With many products there is a general risk of resistance developing to the active ingredients. For this reason a change in activity cannot be ruled out. It is generally impossible to predict with certainty how resistance may develop because there are so many crop and use connected ways of

influencing this. We therefore have to exclude liability for damage or loss attributable to any such resistance that may develop. To help minimise any loss in activity the BASF recommended rate should in all events be adhered to.

Numerous, particularly regional or regionally attributable, factors can influence the activity of the product. Examples include weather and soil conditions, crop plant varieties, crop rotation, treatment times, application amounts, admixture with other products, appearance of organisms resistant to active ingredients and spraying techniques. Under particular conditions a change in activity or damage to plants cannot be ruled out. The manufacturer or supplier is therefore unable to accept any liability in such circumstances. All goods supplied by us are of high grade and we believe them to be suitable, but as we cannot exercise control over their mixing or use or the weather conditions during and after application, which may affect the performance of the material, all conditions and warranties, statutory or otherwise, as to the quality or fitness for any purpose of our goods are excluded and no responsibility will be accepted by us for any damage or injury whatsoever arising from their storage, handling, application or use; but nothing should be deemed to exclude or restrict any liability upon us which cannot be excluded or restricted under the provisions of the Unfair Contract Terms Act 1977 or any similar applicable law.

Section 6 of the Health and Safety at Work Act Additional Product Safety InformationThe product label provides information on a specific pesticidal use of the product; do not use otherwise, unless you have assessed any potential hazard involved, the safety measures required and that the particular use has ‚off-label‘ approval or is otherwise permitted under the Plant Protection Products Regulations.The information on this label is based on the best available information including data from test results

Safety Data Sheet

1. Identification of the substance/mixture and of the company/undertakingProduct identifier RIGELRelevant identified uses of the substance or mixture and uses advised againstRelevant identified uses: crop protection product, fungicideDetails of the supplier of the safety data sheetCompany: Servem LtdContact address: Maxboley Duncormick.Wexford IrelandTelephone: +35351563530E-mail address:info@servemlimited.comEmergency telephone numberInternational emergency number: Telephone: +35351563531

2. Hazards Identification

Label elementsGlobally Harmonized System, EU (GHS) Hazard Statement:H412 Harmful to aquatic life with long lasting effects.EUH401 To avoid risks to human health and the environment, comply with the instructions for use.According to Directive 67/548/EEC or 1999/45/EC EEC DirectivesR-phrase(s)R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s)S2 Keep out of the reach of children.S13 Keep away from food, drink and animal feeding stuffs.S20/21 When using do not eat, drink or smoke.Classification/labelling in accordance with Irish regulations. Hazard symbol(s)N Dangerous for the environment.R-phrase(s)R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s)S2 Keep out of the reach of children.S13 Keep away from food, drink and animal feeding stuffs.S20/21 When using do not eat, drink or smoke.S35 This material and its container must be disposed of in a safe way.S57 Use appropriate container to avoid environmental contamination.Classification of the substance or mixture According to Regulation (EC) No 1272/2008 [CLP] Aquatic Chronic 3According to Directive 67/548/EEC or 1999/45/EC Possible Hazards:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. For the classifications not written out in full in this section the full text can be found in section 16.Other hazardsAccording to Regulation (EC) No 1272/2008 [CLP]See section 12 - Results of PBT and vPvB assessment.

If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture.

3. Composition/Information on Ingredients MixturesChemical naturecrop protection product, fungicide, Wettable powder (WP)

Hazardous ingredients (GHS)according to Regulation (EC) No. 1272/2008

Dimethomorph

Content (W/W): 50 % Aquatic Chronic 2CAS Number: 110488-70-5 H411EC-Number: 404-200-2INDEX-Number: 613-102-00-0KaoliniteContent (W/W): < 45 % CAS Number: 1318-74-7EC-Number: 215-286-4 Sodium diisopropylnaphthalenesulphonateContent (W/W): < 5 % CAS Number: 1322-93-6EC-Number: 215-343-3 Hazardous ingredientsaccording to Directive 1999/45/ECDimethomorphContent (W/W): 50 %CAS Number: 110488-70-5EC-Number: 404-200-2INDEX-Number: 613-102-00-0Hazard symbol(s): N R-phrase(s): 51/53KaoliniteContent (W/W): < 45 % CAS Number: 1318-74-7EC-Number: 215-286-4 Sodium diisopropylnaphthalenesulphonateContent (W/W): < 5 % CAS Number: 1322-93-6EC-Number: 215-343-3For the classifications not written out in full in this section, including the indication of danger, the hazard symbols, the R phrases, and the hazard statements, the full text is listed in section 16.

4. First-Aid MeasuresDescription of first aid measuresRemove contaminated clothing.If inhaled: Keep patient calm, remove to fresh air.On skin contact: Wash thoroughly with soap and water.On contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open. On ingestion: Rinse mouth and then drink plenty of water.Most important symptoms and effects, both acute and delayedSymptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known.Indication of any immediate medical attention and special treatment neededTreatment: Symptomatic treatment (decontamination, vital functions).

5. Fire-Fighting Measures Extinguishing mediaSuitable extinguishing media: dry powder, foam, water spray Unsuitable extinguishing media for safety reasons: carbon dioxideSpecial hazards arising from the substance or mixturecarbon monoxide, hydrogen chloride, Carbon dioxide, nitrogen oxides, organochloric compounds The

substances/groups of substances mentioned can be released in case of fire.Advice for fire-fightersSpecial protective equipment:Wear self-contained breathing apparatus and chemical-protective clothing.Further information:In case of fire and/or explosion do not breathe fumes. Keep containers cool by spraying with water if exposed to fire. Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.

6. Accidental Release MeasuresPersonal precautions, protective equipment and emergency proceduresUse personal protective clothing. Avoid contact with the skin, eyes and clothing. Avoid dust formation.Environmental precautionsDo not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater.Do not allow contamination of public drains or surface or ground waters. Inform local water plc if spillage enters drains and the Environmental Protection Agency if it enters surface or ground waters. Keep people and animals away.Methods and material for containment and cleaning upFor small amounts: Contain with dust binding material and dispose of. For large amounts: Sweep/shovel up.Dispose of absorbed material in accordance with regulations. Collect waste in suitable containers, which can be labeled and sealed.Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Avoid raising dust.Reference to other sectionsInformation regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.7. Handling and Storage Precautions for safe handlingNo special measures necessary if stored and handled correctly. Ensure thorough ventilation of stores and work areas. When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift.Protection against fire and explosion:Dust can form an explosive mixture with air. Avoid dust formation. Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.Conditions for safe storage, including any incompatibilitiesSegregate from foods and animal feeds.Further information on storage conditions: Keep away from heat. Protect against moisture. Protect from direct sunlight. Protect from temperatures above: 40 °CChanges in the properties of the product may occur if substance/product is stored above indicated temperature for extended periods of time.

Specific end use(s)For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed.

8. Exposure Controls/Personal Protection Control parametersComponents with workplace control parametersFor normal use and handling refer to the product label/leaflet. In all other cases the following apply. Refer to the current schedule of occupational exposure standards published by the Irish HSA.Exposure controlsPersonal protective equipmentRespiratory protection: Respiratory protection not required.Hand protection: Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) and otherEye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166)

Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical- protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).General safety and hygiene measuresThe statements on personal protective equipment in the instructions for use apply when handling crop-protection agents in final- consumer packing. Wearing of closed work clothing is recommended. Keep away from food, drink and animal feeding stuffs. Store work clothing separately.

9. Physical and Chemical PropertiesInformation on basic physical and chemical propertiesForm: powderColour: whiteOdour: slight odour, sweetishOdour threshold: not determinedpH value: approx. 4 - 6 (10 g/l, 20 °C)Melting point: approx. 125 - 149 °CThe values mentioned are those of the active ingredient.Boiling point: The product has not been tested.Flash point: not applicableEvaporation rate: not applicableFlammability: not highly flammable (Directive 92/69/EEC, A.10)Lower explosion limit: not determinedUpper explosion limit: not determinedVapour pressure: negligibleDensity: approx. 1.72 g/cm3 (20 °C) (OECD Guideline 109) Relative vapour density (air): not determinedSolubility in water: dispersibleInformation on: Dimethomorph Partitioning coefficientn-octanol/water (log Kow): 2.63 - 2.73 (20 °C)----------------------------------

Self ignition: Temperature: 371 °C (Method: Directive 92/69/EEC, A.16) Thermal decomposition: not determinedViscosity, dynamic: not applicableExplosion hazard: Based on the chemical structure there is no indicating of explosive properties. Fire promoting properties: Based on its structural properties the product is not classified as oxidizing.Other informationIf necessary, information on other physical and chemical parameters is indicated in this section.10. Stability and Reactivity ReactivityNo hazardous reactions if stored and handled as prescribed/indicated.Chemical stabilityThe product is stable if stored and handled as prescribed/indicated.Possibility of hazardous reactionsNo hazardous reactions if stored and handled as prescribed/indicated.Conditions to avoidSee MSDS section 7 - Handling and storage.Incompatible materialsSubstances to avoid: strong acids, strong bases, strong oxidizing agentsHazardous decomposition productsHazardous decomposition products:No hazardous decomposition products if stored and handled as prescribed/indicated.

11. Toxicological Information Information on toxicological effectsAcute toxicityAssessment of acute toxicity:Of low toxicity after single ingestion. Virtually nontoxic after a single skin contact. Virtually nontoxic by inhalation.Experimental/calculated data:LD50 rat (oral): 2,939 mg/kg (OECD Guideline 401)LC50 rat (by inhalation): > 2.0 mg/l 4 h (OECD Guideline 403)No mortality was observed. Highest concentration available for testing. Tested as dust aerosol. LD50 rat (dermal): > 2,000 mg/kg (OECD Guideline 402)IrritationAssessment of irritating effects:Not irritating to the eyes. Not irritating to the skin. Experimental/calculated data:Skin corrosion/irritation rabbit: non-irritant (OECD Guideline 404) Serious eye damage/irritation rabbit: non-irritant (OECD Guideline 405)Respiratory/Skin sensitization Assessment of sensitization:There is no evidence of a skin-sensitizing potential.Experimental/calculated data:Buehler test guinea pig: Non-sensitizing. (OECD Guideline 406)Germ cell mutagenicity Assessment of mutagenicity:The product has not been tested. The statement has been derived from the properties of the individual components.

Mutagenicity tests revealed no genotoxic potential.CarcinogenicityAssessment of carcinogenicity:The product has not been tested. The statement has been derived from the properties of the individual components. The results of various animal studies gave no indication of a carcinogenic effect.Reproductive toxicityAssessment of reproduction toxicity:The product has not been tested. The statement has been derived from the properties of the individual components. The results of animal studies gave no indication of a fertility impairing effect.Developmental toxicity Assessment of teratogenicity:The product has not been tested. The statement has been derived from the properties of the individual components. Animal studies gave no indication of a developmental toxic effect at doses that were not toxic to the parental animals.Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity:The product has not been tested. The statement has been derived from the properties of the individual components. No substance- specific organotoxicity was observed after repeated administration of high doses to animals.Other relevant toxicity information Misuse can be harmful to health.

12. Ecological Information ToxicityAssessment of aquatic toxicity:Acutely harmful for aquatic organisms. May cause long-term adverse effects in the aquatic environment.Toxicity to fish:LC50 (96 h) 15.3 mg/l, Oncorhynchus mykiss (OECD Guideline 203, static)Aquatic invertebrates:EC50 (48 h) 14.2 mg/l, Daphnia magna (OECD Guideline 202, part 1, static)Aquatic plants:EC50 (72 h) 60.2 mg/l (growth rate), Desmodesmus subspicatus (OECD Guideline 201, static)Persistence and degradabilityAssessment biodegradation and elimination (H2O):The product has not been tested. The statement has been derived from the properties of the individual components.Information on: DimethomorphAssessment biodegradation and elimination (H2O): Not readily biodegradable (by OECD criteria).----------------------------------Bioaccumulative potentialAssessment bioaccumulation potential:The product has not been tested. The statement has been derived from the properties of the individual components.Information on: Dimethomorph Bioaccumulation potential:No significant accumulation in organisms is expected as a result of the distribution coefficient of n-octanol/water (log Pow).----------------------------------

Mobility in soil (and other compartments if available)Assessment transport between environmental compartments:The product has not been tested. The statement has been derived from the properties of the individual components.Information on: DimethomorphAssessment transport between environmental compartments:Following exposure to soil, adsorption to solid soil particles is probable, therefore contamination of groundwater is not expected.----------------------------------Results of PBT and vPvB assessmentThe product does not contain a substance fullfilling the PBT (persistent/bioaccumulative/toxic) criteria or the vPvB (very persistent/ very bioaccumulative) criteria.Other adverse effectsThe product does not contain substances that are listed in Annex I of Regulation (EC) 2037/2000 on substances that deplete the ozone layer.Additional informationOther ecotoxicological advice:Do not discharge product into the environment without control.

13. Disposal Considerations Waste treatment methodsMust be sent to a suitable incineration plant, observing local regulations. Contaminated packaging:Contaminated packaging should be emptied as far as possible and disposed of in the same manner as the substance/product.

14. Transport Information Land transportADR Not classified as a dangerous good under transport regulations RID Not classified as a dangerous good under transport regulationsInland waterway transportADN Not classified as a dangerous good under transport regulationsSea transportIMDG Not classified as a dangerous good under transport regulationsAir transportIATA/ICAO Not classified as a dangerous good under transport regulations

15. Regulatory InformationSafety, health and environmental regulations/legislation specific for the substance or mixtureFor the user of this plant-protective product applies: ‚To avoid risks to man and the environment, comply with the instructions for use.‘ (Directive 1999/45/EC, Article 10, No. 1.2)This product may be subject to the Seveco II Directive and amendments if specific treshold tonnages are exceeded. For further medical advice Doctors should contact the National Poison Information Centre at Beaumont Hospital, Dublin.Chemical Safety AssessmentAdvice on product handling can be found in sections 7 and 8

of this safety data sheet.16. Other InformationFor proper and safe use of this product, please refer to the approval conditions laid down on the product label.Full text of the classifications, including the indication of danger, the hazard symbols, the R phrases, and the hazard statements, if mentioned in section 2 or 3:N Dangerous for the environment.51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Aquatic Chronic Hazardous to the aquatic environment - chronicH411 Toxic to aquatic life with long lasting effects.The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product‘s properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.

Version: 1.0)

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2015

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DIRECTIONS FOR USEIMPORTANT: This information is approved as part of the Product Label. All instructions within this section must be read carefully in order to obtain safe and successful use of this product.1. Restrictions/Warnings For professional use only. 1.1 Processed cropsConsult processor before use on crops for processing2. Disease controlRigel is a fungicide with protectant activity against crown rot (Phytophthora cactorum) in strawberries and root rot (Phytophthora spp.) in raspberries and blackberries. Rigel will be most effective when applied as a protectant treatment immediately after planting, before disease symptoms appear.2.1 ResistanceRigel contains dimethomorph, a CAA fungicide. It should be used in accordance with FRAC resistance management advice for CAA fungicides.In outdoor and protected crops of strawberries, no more than one application of Rigel per year may be made for moderate control of crown rot (Phytophthora cactorum). Applications should be made preventatively after planting.In raspberries and blackberries, no more than one application of Rigel per year may be made for moderate control of root rot (Phytophthora spp.). Applications should be made preventatively immediately after planting in the spring or autumn. Alternation with fungicides with different modes of

action to Rigel is recommended as part of a resistance management programme. CAA fungicides should not make up more than 50% of the intended number of fungicide applications for Phytophthora disease control in strawberries, raspberries and blackberries.Use Rigel as part of an Integrated Crop Management (ICM) strategy incorporating other methods of control, including where appropriate fungicides with a different mode of action.3. Crops3.1 Outdoor strawberries Time of applicationFor the moderate control of crown rot (Phytophthora cactorum) apply Rigel as a preventative treatment immediately after planting.Rate of applicationApply Rigel at 3.0 kg/ha as a high volume spray of 600–1000 litres of water per hectare, ensuring good coverage around the base of the plant.3.2 Protected strawberries Time of applicationFor the moderate control of crown rot (Phytophthora cactorum), apply Rigel as a preventative treatment immediately after planting.Rate of applicationApply Rigel as a drip irrigation or root drench treatment of 0.1 gram of product per plant, not exceeding 3.0 kg of product/ha.Rigel may be used at the following dilutions and water volumes: 1g Rigel/litre of water - use 100 ml/plant0.5g Rigel/litre of water - use 200 ml/plant 0.25g Rigel/litre of

water - use 400 ml/plant

3.3 Raspberries and blackberries (outdoor and protected) – qualified minor use recommendation Time of applicationFor the moderate control of root rot (Phytophthora spp.) apply Riigel as a preventative treatment immediately after planting in the spring or autumn.Rate of applicationApply as a drip irrigation or root drench treatment delivering 1.0 g of Rigel per plant, not exceeding 3.0 kg of product/ha.Rigel may be used at the following dilutions and water volumes: 5g Rigel/litre of water - use 200 ml/plant2.5g Rigel/litre of water - use 400 ml/plant*There is limited evidence of crop safety and/or product efficacy available for Qualified Minor uses and the commercial risk of using this product under this Qualified Minor use is borne entirely by the grower.

4. Succeeding CropsFollowing application of Rigel, allow 10 months before sowing clover.5. Mixing and ApplicationIn outdoor strawberries, Rigel should be applied as a COARSE spray as defined by BCPC, using a high volume drenching spray of 600–1000 litres of water per hectare, using hydraulic nozzles and ensuring good coverage around the base of the plant. In protected crops of strawberries, Rigel should be applied via drip irrigation or as a root drench delivering at least 100 ml of water per plant. In outdoor or protected raspberries and blackberries, Rigel should be applied via drip irrigation or as a root drench delivering at least 200 ml of water per plant.Half fill the sprayer, drench or irrigation tank with clean water and start agitation.Steadily add the required quantity of Rigel direct to the spray, drench or irrigation tank (pre-mixing is not necessary). Empty product container thoroughly and dispose of safely.Add the remainder of the water.Apply immediately and continue agitation until spraying, irrigation or drenching is complete.Wash sprayer or flush out drench or irrigation equipment thoroughly immediately after use, using clean water and following best practice advice and the guidance provided by the equipment manufacturer.Do not apply via knapsack sprayers.

The following does not form part of the product label under the UK Plant Protection Products Regulations or the Irish S.I. No. 159 of 2012.

With many products there is a general risk of resistance developing to the active ingredients. For this reason a change in activity cannot be ruled out. It is generally impossible to predict with certainty how resistance may develop because there are so many crop and use connected ways of

influencing this. We therefore have to exclude liability for damage or loss attributable to any such resistance that may develop. To help minimise any loss in activity the BASF recommended rate should in all events be adhered to.

Numerous, particularly regional or regionally attributable, factors can influence the activity of the product. Examples include weather and soil conditions, crop plant varieties, crop rotation, treatment times, application amounts, admixture with other products, appearance of organisms resistant to active ingredients and spraying techniques. Under particular conditions a change in activity or damage to plants cannot be ruled out. The manufacturer or supplier is therefore unable to accept any liability in such circumstances. All goods supplied by us are of high grade and we believe them to be suitable, but as we cannot exercise control over their mixing or use or the weather conditions during and after application, which may affect the performance of the material, all conditions and warranties, statutory or otherwise, as to the quality or fitness for any purpose of our goods are excluded and no responsibility will be accepted by us for any damage or injury whatsoever arising from their storage, handling, application or use; but nothing should be deemed to exclude or restrict any liability upon us which cannot be excluded or restricted under the provisions of the Unfair Contract Terms Act 1977 or any similar applicable law.

Section 6 of the Health and Safety at Work Act Additional Product Safety InformationThe product label provides information on a specific pesticidal use of the product; do not use otherwise, unless you have assessed any potential hazard involved, the safety measures required and that the particular use has ‚off-label‘ approval or is otherwise permitted under the Plant Protection Products Regulations.The information on this label is based on the best available information including data from test results

Safety Data Sheet

1. Identification of the substance/mixture and of the company/undertakingProduct identifier RIGELRelevant identified uses of the substance or mixture and uses advised againstRelevant identified uses: crop protection product, fungicideDetails of the supplier of the safety data sheetCompany: Servem LtdContact address: Maxboley Duncormick.Wexford IrelandTelephone: +35351563530E-mail address:info@servemlimited.comEmergency telephone numberInternational emergency number: Telephone: +35351563531

2. Hazards Identification

Label elementsGlobally Harmonized System, EU (GHS) Hazard Statement:H412 Harmful to aquatic life with long lasting effects.EUH401 To avoid risks to human health and the environment, comply with the instructions for use.According to Directive 67/548/EEC or 1999/45/EC EEC DirectivesR-phrase(s)R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s)S2 Keep out of the reach of children.S13 Keep away from food, drink and animal feeding stuffs.S20/21 When using do not eat, drink or smoke.Classification/labelling in accordance with Irish regulations. Hazard symbol(s)N Dangerous for the environment.R-phrase(s)R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s)S2 Keep out of the reach of children.S13 Keep away from food, drink and animal feeding stuffs.S20/21 When using do not eat, drink or smoke.S35 This material and its container must be disposed of in a safe way.S57 Use appropriate container to avoid environmental contamination.Classification of the substance or mixture According to Regulation (EC) No 1272/2008 [CLP] Aquatic Chronic 3According to Directive 67/548/EEC or 1999/45/EC Possible Hazards:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. For the classifications not written out in full in this section the full text can be found in section 16.Other hazardsAccording to Regulation (EC) No 1272/2008 [CLP]See section 12 - Results of PBT and vPvB assessment.

If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture.

3. Composition/Information on Ingredients MixturesChemical naturecrop protection product, fungicide, Wettable powder (WP)

Hazardous ingredients (GHS)according to Regulation (EC) No. 1272/2008

Dimethomorph

Content (W/W): 50 % Aquatic Chronic 2CAS Number: 110488-70-5 H411EC-Number: 404-200-2INDEX-Number: 613-102-00-0KaoliniteContent (W/W): < 45 % CAS Number: 1318-74-7EC-Number: 215-286-4 Sodium diisopropylnaphthalenesulphonateContent (W/W): < 5 % CAS Number: 1322-93-6EC-Number: 215-343-3 Hazardous ingredientsaccording to Directive 1999/45/ECDimethomorphContent (W/W): 50 %CAS Number: 110488-70-5EC-Number: 404-200-2INDEX-Number: 613-102-00-0Hazard symbol(s): N R-phrase(s): 51/53KaoliniteContent (W/W): < 45 % CAS Number: 1318-74-7EC-Number: 215-286-4 Sodium diisopropylnaphthalenesulphonateContent (W/W): < 5 % CAS Number: 1322-93-6EC-Number: 215-343-3For the classifications not written out in full in this section, including the indication of danger, the hazard symbols, the R phrases, and the hazard statements, the full text is listed in section 16.

4. First-Aid MeasuresDescription of first aid measuresRemove contaminated clothing.If inhaled: Keep patient calm, remove to fresh air.On skin contact: Wash thoroughly with soap and water.On contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open. On ingestion: Rinse mouth and then drink plenty of water.Most important symptoms and effects, both acute and delayedSymptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known.Indication of any immediate medical attention and special treatment neededTreatment: Symptomatic treatment (decontamination, vital functions).

5. Fire-Fighting Measures Extinguishing mediaSuitable extinguishing media: dry powder, foam, water spray Unsuitable extinguishing media for safety reasons: carbon dioxideSpecial hazards arising from the substance or mixturecarbon monoxide, hydrogen chloride, Carbon dioxide, nitrogen oxides, organochloric compounds The

substances/groups of substances mentioned can be released in case of fire.Advice for fire-fightersSpecial protective equipment:Wear self-contained breathing apparatus and chemical-protective clothing.Further information:In case of fire and/or explosion do not breathe fumes. Keep containers cool by spraying with water if exposed to fire. Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.

6. Accidental Release MeasuresPersonal precautions, protective equipment and emergency proceduresUse personal protective clothing. Avoid contact with the skin, eyes and clothing. Avoid dust formation.Environmental precautionsDo not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater.Do not allow contamination of public drains or surface or ground waters. Inform local water plc if spillage enters drains and the Environmental Protection Agency if it enters surface or ground waters. Keep people and animals away.Methods and material for containment and cleaning upFor small amounts: Contain with dust binding material and dispose of. For large amounts: Sweep/shovel up.Dispose of absorbed material in accordance with regulations. Collect waste in suitable containers, which can be labeled and sealed.Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Avoid raising dust.Reference to other sectionsInformation regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.7. Handling and Storage Precautions for safe handlingNo special measures necessary if stored and handled correctly. Ensure thorough ventilation of stores and work areas. When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift.Protection against fire and explosion:Dust can form an explosive mixture with air. Avoid dust formation. Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.Conditions for safe storage, including any incompatibilitiesSegregate from foods and animal feeds.Further information on storage conditions: Keep away from heat. Protect against moisture. Protect from direct sunlight. Protect from temperatures above: 40 °CChanges in the properties of the product may occur if substance/product is stored above indicated temperature for extended periods of time.

Specific end use(s)For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed.

8. Exposure Controls/Personal Protection Control parametersComponents with workplace control parametersFor normal use and handling refer to the product label/leaflet. In all other cases the following apply. Refer to the current schedule of occupational exposure standards published by the Irish HSA.Exposure controlsPersonal protective equipmentRespiratory protection: Respiratory protection not required.Hand protection: Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) and otherEye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166)

Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical- protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).General safety and hygiene measuresThe statements on personal protective equipment in the instructions for use apply when handling crop-protection agents in final- consumer packing. Wearing of closed work clothing is recommended. Keep away from food, drink and animal feeding stuffs. Store work clothing separately.

9. Physical and Chemical PropertiesInformation on basic physical and chemical propertiesForm: powderColour: whiteOdour: slight odour, sweetishOdour threshold: not determinedpH value: approx. 4 - 6 (10 g/l, 20 °C)Melting point: approx. 125 - 149 °CThe values mentioned are those of the active ingredient.Boiling point: The product has not been tested.Flash point: not applicableEvaporation rate: not applicableFlammability: not highly flammable (Directive 92/69/EEC, A.10)Lower explosion limit: not determinedUpper explosion limit: not determinedVapour pressure: negligibleDensity: approx. 1.72 g/cm3 (20 °C) (OECD Guideline 109) Relative vapour density (air): not determinedSolubility in water: dispersibleInformation on: Dimethomorph Partitioning coefficientn-octanol/water (log Kow): 2.63 - 2.73 (20 °C)----------------------------------

Self ignition: Temperature: 371 °C (Method: Directive 92/69/EEC, A.16) Thermal decomposition: not determinedViscosity, dynamic: not applicableExplosion hazard: Based on the chemical structure there is no indicating of explosive properties. Fire promoting properties: Based on its structural properties the product is not classified as oxidizing.Other informationIf necessary, information on other physical and chemical parameters is indicated in this section.10. Stability and Reactivity ReactivityNo hazardous reactions if stored and handled as prescribed/indicated.Chemical stabilityThe product is stable if stored and handled as prescribed/indicated.Possibility of hazardous reactionsNo hazardous reactions if stored and handled as prescribed/indicated.Conditions to avoidSee MSDS section 7 - Handling and storage.Incompatible materialsSubstances to avoid: strong acids, strong bases, strong oxidizing agentsHazardous decomposition productsHazardous decomposition products:No hazardous decomposition products if stored and handled as prescribed/indicated.

11. Toxicological Information Information on toxicological effectsAcute toxicityAssessment of acute toxicity:Of low toxicity after single ingestion. Virtually nontoxic after a single skin contact. Virtually nontoxic by inhalation.Experimental/calculated data:LD50 rat (oral): 2,939 mg/kg (OECD Guideline 401)LC50 rat (by inhalation): > 2.0 mg/l 4 h (OECD Guideline 403)No mortality was observed. Highest concentration available for testing. Tested as dust aerosol. LD50 rat (dermal): > 2,000 mg/kg (OECD Guideline 402)IrritationAssessment of irritating effects:Not irritating to the eyes. Not irritating to the skin. Experimental/calculated data:Skin corrosion/irritation rabbit: non-irritant (OECD Guideline 404) Serious eye damage/irritation rabbit: non-irritant (OECD Guideline 405)Respiratory/Skin sensitization Assessment of sensitization:There is no evidence of a skin-sensitizing potential.Experimental/calculated data:Buehler test guinea pig: Non-sensitizing. (OECD Guideline 406)Germ cell mutagenicity Assessment of mutagenicity:The product has not been tested. The statement has been derived from the properties of the individual components.

Mutagenicity tests revealed no genotoxic potential.CarcinogenicityAssessment of carcinogenicity:The product has not been tested. The statement has been derived from the properties of the individual components. The results of various animal studies gave no indication of a carcinogenic effect.Reproductive toxicityAssessment of reproduction toxicity:The product has not been tested. The statement has been derived from the properties of the individual components. The results of animal studies gave no indication of a fertility impairing effect.Developmental toxicity Assessment of teratogenicity:The product has not been tested. The statement has been derived from the properties of the individual components. Animal studies gave no indication of a developmental toxic effect at doses that were not toxic to the parental animals.Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity:The product has not been tested. The statement has been derived from the properties of the individual components. No substance- specific organotoxicity was observed after repeated administration of high doses to animals.Other relevant toxicity information Misuse can be harmful to health.

12. Ecological Information ToxicityAssessment of aquatic toxicity:Acutely harmful for aquatic organisms. May cause long-term adverse effects in the aquatic environment.Toxicity to fish:LC50 (96 h) 15.3 mg/l, Oncorhynchus mykiss (OECD Guideline 203, static)Aquatic invertebrates:EC50 (48 h) 14.2 mg/l, Daphnia magna (OECD Guideline 202, part 1, static)Aquatic plants:EC50 (72 h) 60.2 mg/l (growth rate), Desmodesmus subspicatus (OECD Guideline 201, static)Persistence and degradabilityAssessment biodegradation and elimination (H2O):The product has not been tested. The statement has been derived from the properties of the individual components.Information on: DimethomorphAssessment biodegradation and elimination (H2O): Not readily biodegradable (by OECD criteria).----------------------------------Bioaccumulative potentialAssessment bioaccumulation potential:The product has not been tested. The statement has been derived from the properties of the individual components.Information on: Dimethomorph Bioaccumulation potential:No significant accumulation in organisms is expected as a result of the distribution coefficient of n-octanol/water (log Pow).----------------------------------

Mobility in soil (and other compartments if available)Assessment transport between environmental compartments:The product has not been tested. The statement has been derived from the properties of the individual components.Information on: DimethomorphAssessment transport between environmental compartments:Following exposure to soil, adsorption to solid soil particles is probable, therefore contamination of groundwater is not expected.----------------------------------Results of PBT and vPvB assessmentThe product does not contain a substance fullfilling the PBT (persistent/bioaccumulative/toxic) criteria or the vPvB (very persistent/ very bioaccumulative) criteria.Other adverse effectsThe product does not contain substances that are listed in Annex I of Regulation (EC) 2037/2000 on substances that deplete the ozone layer.Additional informationOther ecotoxicological advice:Do not discharge product into the environment without control.

13. Disposal Considerations Waste treatment methodsMust be sent to a suitable incineration plant, observing local regulations. Contaminated packaging:Contaminated packaging should be emptied as far as possible and disposed of in the same manner as the substance/product.

14. Transport Information Land transportADR Not classified as a dangerous good under transport regulations RID Not classified as a dangerous good under transport regulationsInland waterway transportADN Not classified as a dangerous good under transport regulationsSea transportIMDG Not classified as a dangerous good under transport regulationsAir transportIATA/ICAO Not classified as a dangerous good under transport regulations

15. Regulatory InformationSafety, health and environmental regulations/legislation specific for the substance or mixtureFor the user of this plant-protective product applies: ‚To avoid risks to man and the environment, comply with the instructions for use.‘ (Directive 1999/45/EC, Article 10, No. 1.2)This product may be subject to the Seveco II Directive and amendments if specific treshold tonnages are exceeded. For further medical advice Doctors should contact the National Poison Information Centre at Beaumont Hospital, Dublin.Chemical Safety AssessmentAdvice on product handling can be found in sections 7 and 8

of this safety data sheet.16. Other InformationFor proper and safe use of this product, please refer to the approval conditions laid down on the product label.Full text of the classifications, including the indication of danger, the hazard symbols, the R phrases, and the hazard statements, if mentioned in section 2 or 3:N Dangerous for the environment.51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Aquatic Chronic Hazardous to the aquatic environment - chronicH411 Toxic to aquatic life with long lasting effects.The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product‘s properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.

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DIRECTIONS FOR USEIMPORTANT: This information is approved as part of the Product Label. All instructions within this section must be read carefully in order to obtain safe and successful use of this product.1. Restrictions/Warnings For professional use only. 1.1 Processed cropsConsult processor before use on crops for processing2. Disease controlRigel is a fungicide with protectant activity against crown rot (Phytophthora cactorum) in strawberries and root rot (Phytophthora spp.) in raspberries and blackberries. Rigel will be most effective when applied as a protectant treatment immediately after planting, before disease symptoms appear.2.1 ResistanceRigel contains dimethomorph, a CAA fungicide. It should be used in accordance with FRAC resistance management advice for CAA fungicides.In outdoor and protected crops of strawberries, no more than one application of Rigel per year may be made for moderate control of crown rot (Phytophthora cactorum). Applications should be made preventatively after planting.In raspberries and blackberries, no more than one application of Rigel per year may be made for moderate control of root rot (Phytophthora spp.). Applications should be made preventatively immediately after planting in the spring or autumn. Alternation with fungicides with different modes of

action to Rigel is recommended as part of a resistance management programme. CAA fungicides should not make up more than 50% of the intended number of fungicide applications for Phytophthora disease control in strawberries, raspberries and blackberries.Use Rigel as part of an Integrated Crop Management (ICM) strategy incorporating other methods of control, including where appropriate fungicides with a different mode of action.3. Crops3.1 Outdoor strawberries Time of applicationFor the moderate control of crown rot (Phytophthora cactorum) apply Rigel as a preventative treatment immediately after planting.Rate of applicationApply Rigel at 3.0 kg/ha as a high volume spray of 600–1000 litres of water per hectare, ensuring good coverage around the base of the plant.3.2 Protected strawberries Time of applicationFor the moderate control of crown rot (Phytophthora cactorum), apply Rigel as a preventative treatment immediately after planting.Rate of applicationApply Rigel as a drip irrigation or root drench treatment of 0.1 gram of product per plant, not exceeding 3.0 kg of product/ha.Rigel may be used at the following dilutions and water volumes: 1g Rigel/litre of water - use 100 ml/plant0.5g Rigel/litre of water - use 200 ml/plant 0.25g Rigel/litre of

water - use 400 ml/plant

3.3 Raspberries and blackberries (outdoor and protected) – qualified minor use recommendation Time of applicationFor the moderate control of root rot (Phytophthora spp.) apply Riigel as a preventative treatment immediately after planting in the spring or autumn.Rate of applicationApply as a drip irrigation or root drench treatment delivering 1.0 g of Rigel per plant, not exceeding 3.0 kg of product/ha.Rigel may be used at the following dilutions and water volumes: 5g Rigel/litre of water - use 200 ml/plant2.5g Rigel/litre of water - use 400 ml/plant*There is limited evidence of crop safety and/or product efficacy available for Qualified Minor uses and the commercial risk of using this product under this Qualified Minor use is borne entirely by the grower.

4. Succeeding CropsFollowing application of Rigel, allow 10 months before sowing clover.5. Mixing and ApplicationIn outdoor strawberries, Rigel should be applied as a COARSE spray as defined by BCPC, using a high volume drenching spray of 600–1000 litres of water per hectare, using hydraulic nozzles and ensuring good coverage around the base of the plant. In protected crops of strawberries, Rigel should be applied via drip irrigation or as a root drench delivering at least 100 ml of water per plant. In outdoor or protected raspberries and blackberries, Rigel should be applied via drip irrigation or as a root drench delivering at least 200 ml of water per plant.Half fill the sprayer, drench or irrigation tank with clean water and start agitation.Steadily add the required quantity of Rigel direct to the spray, drench or irrigation tank (pre-mixing is not necessary). Empty product container thoroughly and dispose of safely.Add the remainder of the water.Apply immediately and continue agitation until spraying, irrigation or drenching is complete.Wash sprayer or flush out drench or irrigation equipment thoroughly immediately after use, using clean water and following best practice advice and the guidance provided by the equipment manufacturer.Do not apply via knapsack sprayers.

The following does not form part of the product label under the UK Plant Protection Products Regulations or the Irish S.I. No. 159 of 2012.

With many products there is a general risk of resistance developing to the active ingredients. For this reason a change in activity cannot be ruled out. It is generally impossible to predict with certainty how resistance may develop because there are so many crop and use connected ways of

influencing this. We therefore have to exclude liability for damage or loss attributable to any such resistance that may develop. To help minimise any loss in activity the BASF recommended rate should in all events be adhered to.

Numerous, particularly regional or regionally attributable, factors can influence the activity of the product. Examples include weather and soil conditions, crop plant varieties, crop rotation, treatment times, application amounts, admixture with other products, appearance of organisms resistant to active ingredients and spraying techniques. Under particular conditions a change in activity or damage to plants cannot be ruled out. The manufacturer or supplier is therefore unable to accept any liability in such circumstances. All goods supplied by us are of high grade and we believe them to be suitable, but as we cannot exercise control over their mixing or use or the weather conditions during and after application, which may affect the performance of the material, all conditions and warranties, statutory or otherwise, as to the quality or fitness for any purpose of our goods are excluded and no responsibility will be accepted by us for any damage or injury whatsoever arising from their storage, handling, application or use; but nothing should be deemed to exclude or restrict any liability upon us which cannot be excluded or restricted under the provisions of the Unfair Contract Terms Act 1977 or any similar applicable law.

Section 6 of the Health and Safety at Work Act Additional Product Safety InformationThe product label provides information on a specific pesticidal use of the product; do not use otherwise, unless you have assessed any potential hazard involved, the safety measures required and that the particular use has ‚off-label‘ approval or is otherwise permitted under the Plant Protection Products Regulations.The information on this label is based on the best available information including data from test results

Safety Data Sheet

1. Identification of the substance/mixture and of the company/undertakingProduct identifier RIGELRelevant identified uses of the substance or mixture and uses advised againstRelevant identified uses: crop protection product, fungicideDetails of the supplier of the safety data sheetCompany: Servem LtdContact address: Maxboley Duncormick.Wexford IrelandTelephone: +35351563530E-mail address:info@servemlimited.comEmergency telephone numberInternational emergency number: Telephone: +35351563531

2. Hazards Identification

Label elementsGlobally Harmonized System, EU (GHS) Hazard Statement:H412 Harmful to aquatic life with long lasting effects.EUH401 To avoid risks to human health and the environment, comply with the instructions for use.According to Directive 67/548/EEC or 1999/45/EC EEC DirectivesR-phrase(s)R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s)S2 Keep out of the reach of children.S13 Keep away from food, drink and animal feeding stuffs.S20/21 When using do not eat, drink or smoke.Classification/labelling in accordance with Irish regulations. Hazard symbol(s)N Dangerous for the environment.R-phrase(s)R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s)S2 Keep out of the reach of children.S13 Keep away from food, drink and animal feeding stuffs.S20/21 When using do not eat, drink or smoke.S35 This material and its container must be disposed of in a safe way.S57 Use appropriate container to avoid environmental contamination.Classification of the substance or mixture According to Regulation (EC) No 1272/2008 [CLP] Aquatic Chronic 3According to Directive 67/548/EEC or 1999/45/EC Possible Hazards:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. For the classifications not written out in full in this section the full text can be found in section 16.Other hazardsAccording to Regulation (EC) No 1272/2008 [CLP]See section 12 - Results of PBT and vPvB assessment.

If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture.

3. Composition/Information on Ingredients MixturesChemical naturecrop protection product, fungicide, Wettable powder (WP)

Hazardous ingredients (GHS)according to Regulation (EC) No. 1272/2008

Dimethomorph

Content (W/W): 50 % Aquatic Chronic 2CAS Number: 110488-70-5 H411EC-Number: 404-200-2INDEX-Number: 613-102-00-0KaoliniteContent (W/W): < 45 % CAS Number: 1318-74-7EC-Number: 215-286-4 Sodium diisopropylnaphthalenesulphonateContent (W/W): < 5 % CAS Number: 1322-93-6EC-Number: 215-343-3 Hazardous ingredientsaccording to Directive 1999/45/ECDimethomorphContent (W/W): 50 %CAS Number: 110488-70-5EC-Number: 404-200-2INDEX-Number: 613-102-00-0Hazard symbol(s): N R-phrase(s): 51/53KaoliniteContent (W/W): < 45 % CAS Number: 1318-74-7EC-Number: 215-286-4 Sodium diisopropylnaphthalenesulphonateContent (W/W): < 5 % CAS Number: 1322-93-6EC-Number: 215-343-3For the classifications not written out in full in this section, including the indication of danger, the hazard symbols, the R phrases, and the hazard statements, the full text is listed in section 16.

4. First-Aid MeasuresDescription of first aid measuresRemove contaminated clothing.If inhaled: Keep patient calm, remove to fresh air.On skin contact: Wash thoroughly with soap and water.On contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open. On ingestion: Rinse mouth and then drink plenty of water.Most important symptoms and effects, both acute and delayedSymptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known.Indication of any immediate medical attention and special treatment neededTreatment: Symptomatic treatment (decontamination, vital functions).

5. Fire-Fighting Measures Extinguishing mediaSuitable extinguishing media: dry powder, foam, water spray Unsuitable extinguishing media for safety reasons: carbon dioxideSpecial hazards arising from the substance or mixturecarbon monoxide, hydrogen chloride, Carbon dioxide, nitrogen oxides, organochloric compounds The

substances/groups of substances mentioned can be released in case of fire.Advice for fire-fightersSpecial protective equipment:Wear self-contained breathing apparatus and chemical-protective clothing.Further information:In case of fire and/or explosion do not breathe fumes. Keep containers cool by spraying with water if exposed to fire. Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.

6. Accidental Release MeasuresPersonal precautions, protective equipment and emergency proceduresUse personal protective clothing. Avoid contact with the skin, eyes and clothing. Avoid dust formation.Environmental precautionsDo not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater.Do not allow contamination of public drains or surface or ground waters. Inform local water plc if spillage enters drains and the Environmental Protection Agency if it enters surface or ground waters. Keep people and animals away.Methods and material for containment and cleaning upFor small amounts: Contain with dust binding material and dispose of. For large amounts: Sweep/shovel up.Dispose of absorbed material in accordance with regulations. Collect waste in suitable containers, which can be labeled and sealed.Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Avoid raising dust.Reference to other sectionsInformation regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.7. Handling and Storage Precautions for safe handlingNo special measures necessary if stored and handled correctly. Ensure thorough ventilation of stores and work areas. When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift.Protection against fire and explosion:Dust can form an explosive mixture with air. Avoid dust formation. Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.Conditions for safe storage, including any incompatibilitiesSegregate from foods and animal feeds.Further information on storage conditions: Keep away from heat. Protect against moisture. Protect from direct sunlight. Protect from temperatures above: 40 °CChanges in the properties of the product may occur if substance/product is stored above indicated temperature for extended periods of time.

Specific end use(s)For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed.

8. Exposure Controls/Personal Protection Control parametersComponents with workplace control parametersFor normal use and handling refer to the product label/leaflet. In all other cases the following apply. Refer to the current schedule of occupational exposure standards published by the Irish HSA.Exposure controlsPersonal protective equipmentRespiratory protection: Respiratory protection not required.Hand protection: Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) and otherEye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166)

Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical- protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).General safety and hygiene measuresThe statements on personal protective equipment in the instructions for use apply when handling crop-protection agents in final- consumer packing. Wearing of closed work clothing is recommended. Keep away from food, drink and animal feeding stuffs. Store work clothing separately.

9. Physical and Chemical PropertiesInformation on basic physical and chemical propertiesForm: powderColour: whiteOdour: slight odour, sweetishOdour threshold: not determinedpH value: approx. 4 - 6 (10 g/l, 20 °C)Melting point: approx. 125 - 149 °CThe values mentioned are those of the active ingredient.Boiling point: The product has not been tested.Flash point: not applicableEvaporation rate: not applicableFlammability: not highly flammable (Directive 92/69/EEC, A.10)Lower explosion limit: not determinedUpper explosion limit: not determinedVapour pressure: negligibleDensity: approx. 1.72 g/cm3 (20 °C) (OECD Guideline 109) Relative vapour density (air): not determinedSolubility in water: dispersibleInformation on: Dimethomorph Partitioning coefficientn-octanol/water (log Kow): 2.63 - 2.73 (20 °C)----------------------------------

Self ignition: Temperature: 371 °C (Method: Directive 92/69/EEC, A.16) Thermal decomposition: not determinedViscosity, dynamic: not applicableExplosion hazard: Based on the chemical structure there is no indicating of explosive properties. Fire promoting properties: Based on its structural properties the product is not classified as oxidizing.Other informationIf necessary, information on other physical and chemical parameters is indicated in this section.10. Stability and Reactivity ReactivityNo hazardous reactions if stored and handled as prescribed/indicated.Chemical stabilityThe product is stable if stored and handled as prescribed/indicated.Possibility of hazardous reactionsNo hazardous reactions if stored and handled as prescribed/indicated.Conditions to avoidSee MSDS section 7 - Handling and storage.Incompatible materialsSubstances to avoid: strong acids, strong bases, strong oxidizing agentsHazardous decomposition productsHazardous decomposition products:No hazardous decomposition products if stored and handled as prescribed/indicated.

11. Toxicological Information Information on toxicological effectsAcute toxicityAssessment of acute toxicity:Of low toxicity after single ingestion. Virtually nontoxic after a single skin contact. Virtually nontoxic by inhalation.Experimental/calculated data:LD50 rat (oral): 2,939 mg/kg (OECD Guideline 401)LC50 rat (by inhalation): > 2.0 mg/l 4 h (OECD Guideline 403)No mortality was observed. Highest concentration available for testing. Tested as dust aerosol. LD50 rat (dermal): > 2,000 mg/kg (OECD Guideline 402)IrritationAssessment of irritating effects:Not irritating to the eyes. Not irritating to the skin. Experimental/calculated data:Skin corrosion/irritation rabbit: non-irritant (OECD Guideline 404) Serious eye damage/irritation rabbit: non-irritant (OECD Guideline 405)Respiratory/Skin sensitization Assessment of sensitization:There is no evidence of a skin-sensitizing potential.Experimental/calculated data:Buehler test guinea pig: Non-sensitizing. (OECD Guideline 406)Germ cell mutagenicity Assessment of mutagenicity:The product has not been tested. The statement has been derived from the properties of the individual components.

Mutagenicity tests revealed no genotoxic potential.CarcinogenicityAssessment of carcinogenicity:The product has not been tested. The statement has been derived from the properties of the individual components. The results of various animal studies gave no indication of a carcinogenic effect.Reproductive toxicityAssessment of reproduction toxicity:The product has not been tested. The statement has been derived from the properties of the individual components. The results of animal studies gave no indication of a fertility impairing effect.Developmental toxicity Assessment of teratogenicity:The product has not been tested. The statement has been derived from the properties of the individual components. Animal studies gave no indication of a developmental toxic effect at doses that were not toxic to the parental animals.Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity:The product has not been tested. The statement has been derived from the properties of the individual components. No substance- specific organotoxicity was observed after repeated administration of high doses to animals.Other relevant toxicity information Misuse can be harmful to health.

12. Ecological Information ToxicityAssessment of aquatic toxicity:Acutely harmful for aquatic organisms. May cause long-term adverse effects in the aquatic environment.Toxicity to fish:LC50 (96 h) 15.3 mg/l, Oncorhynchus mykiss (OECD Guideline 203, static)Aquatic invertebrates:EC50 (48 h) 14.2 mg/l, Daphnia magna (OECD Guideline 202, part 1, static)Aquatic plants:EC50 (72 h) 60.2 mg/l (growth rate), Desmodesmus subspicatus (OECD Guideline 201, static)Persistence and degradabilityAssessment biodegradation and elimination (H2O):The product has not been tested. The statement has been derived from the properties of the individual components.Information on: DimethomorphAssessment biodegradation and elimination (H2O): Not readily biodegradable (by OECD criteria).----------------------------------Bioaccumulative potentialAssessment bioaccumulation potential:The product has not been tested. The statement has been derived from the properties of the individual components.Information on: Dimethomorph Bioaccumulation potential:No significant accumulation in organisms is expected as a result of the distribution coefficient of n-octanol/water (log Pow).----------------------------------

Mobility in soil (and other compartments if available)Assessment transport between environmental compartments:The product has not been tested. The statement has been derived from the properties of the individual components.Information on: DimethomorphAssessment transport between environmental compartments:Following exposure to soil, adsorption to solid soil particles is probable, therefore contamination of groundwater is not expected.----------------------------------Results of PBT and vPvB assessmentThe product does not contain a substance fullfilling the PBT (persistent/bioaccumulative/toxic) criteria or the vPvB (very persistent/ very bioaccumulative) criteria.Other adverse effectsThe product does not contain substances that are listed in Annex I of Regulation (EC) 2037/2000 on substances that deplete the ozone layer.Additional informationOther ecotoxicological advice:Do not discharge product into the environment without control.

13. Disposal Considerations Waste treatment methodsMust be sent to a suitable incineration plant, observing local regulations. Contaminated packaging:Contaminated packaging should be emptied as far as possible and disposed of in the same manner as the substance/product.

14. Transport Information Land transportADR Not classified as a dangerous good under transport regulations RID Not classified as a dangerous good under transport regulationsInland waterway transportADN Not classified as a dangerous good under transport regulationsSea transportIMDG Not classified as a dangerous good under transport regulationsAir transportIATA/ICAO Not classified as a dangerous good under transport regulations

15. Regulatory InformationSafety, health and environmental regulations/legislation specific for the substance or mixtureFor the user of this plant-protective product applies: ‚To avoid risks to man and the environment, comply with the instructions for use.‘ (Directive 1999/45/EC, Article 10, No. 1.2)This product may be subject to the Seveco II Directive and amendments if specific treshold tonnages are exceeded. For further medical advice Doctors should contact the National Poison Information Centre at Beaumont Hospital, Dublin.Chemical Safety AssessmentAdvice on product handling can be found in sections 7 and 8

of this safety data sheet.16. Other InformationFor proper and safe use of this product, please refer to the approval conditions laid down on the product label.Full text of the classifications, including the indication of danger, the hazard symbols, the R phrases, and the hazard statements, if mentioned in section 2 or 3:N Dangerous for the environment.51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Aquatic Chronic Hazardous to the aquatic environment - chronicH411 Toxic to aquatic life with long lasting effects.The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product‘s properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.

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DIRECTIONS FOR USEIMPORTANT: This information is approved as part of the Product Label. All instructions within this section must be read carefully in order to obtain safe and successful use of this product.1. Restrictions/Warnings For professional use only. 1.1 Processed cropsConsult processor before use on crops for processing2. Disease controlRigel is a fungicide with protectant activity against crown rot (Phytophthora cactorum) in strawberries and root rot (Phytophthora spp.) in raspberries and blackberries. Rigel will be most effective when applied as a protectant treatment immediately after planting, before disease symptoms appear.2.1 ResistanceRigel contains dimethomorph, a CAA fungicide. It should be used in accordance with FRAC resistance management advice for CAA fungicides.In outdoor and protected crops of strawberries, no more than one application of Rigel per year may be made for moderate control of crown rot (Phytophthora cactorum). Applications should be made preventatively after planting.In raspberries and blackberries, no more than one application of Rigel per year may be made for moderate control of root rot (Phytophthora spp.). Applications should be made preventatively immediately after planting in the spring or autumn. Alternation with fungicides with different modes of

action to Rigel is recommended as part of a resistance management programme. CAA fungicides should not make up more than 50% of the intended number of fungicide applications for Phytophthora disease control in strawberries, raspberries and blackberries.Use Rigel as part of an Integrated Crop Management (ICM) strategy incorporating other methods of control, including where appropriate fungicides with a different mode of action.3. Crops3.1 Outdoor strawberries Time of applicationFor the moderate control of crown rot (Phytophthora cactorum) apply Rigel as a preventative treatment immediately after planting.Rate of applicationApply Rigel at 3.0 kg/ha as a high volume spray of 600–1000 litres of water per hectare, ensuring good coverage around the base of the plant.3.2 Protected strawberries Time of applicationFor the moderate control of crown rot (Phytophthora cactorum), apply Rigel as a preventative treatment immediately after planting.Rate of applicationApply Rigel as a drip irrigation or root drench treatment of 0.1 gram of product per plant, not exceeding 3.0 kg of product/ha.Rigel may be used at the following dilutions and water volumes: 1g Rigel/litre of water - use 100 ml/plant0.5g Rigel/litre of water - use 200 ml/plant 0.25g Rigel/litre of

water - use 400 ml/plant

3.3 Raspberries and blackberries (outdoor and protected) – qualified minor use recommendation Time of applicationFor the moderate control of root rot (Phytophthora spp.) apply Riigel as a preventative treatment immediately after planting in the spring or autumn.Rate of applicationApply as a drip irrigation or root drench treatment delivering 1.0 g of Rigel per plant, not exceeding 3.0 kg of product/ha.Rigel may be used at the following dilutions and water volumes: 5g Rigel/litre of water - use 200 ml/plant2.5g Rigel/litre of water - use 400 ml/plant*There is limited evidence of crop safety and/or product efficacy available for Qualified Minor uses and the commercial risk of using this product under this Qualified Minor use is borne entirely by the grower.

4. Succeeding CropsFollowing application of Rigel, allow 10 months before sowing clover.5. Mixing and ApplicationIn outdoor strawberries, Rigel should be applied as a COARSE spray as defined by BCPC, using a high volume drenching spray of 600–1000 litres of water per hectare, using hydraulic nozzles and ensuring good coverage around the base of the plant. In protected crops of strawberries, Rigel should be applied via drip irrigation or as a root drench delivering at least 100 ml of water per plant. In outdoor or protected raspberries and blackberries, Rigel should be applied via drip irrigation or as a root drench delivering at least 200 ml of water per plant.Half fill the sprayer, drench or irrigation tank with clean water and start agitation.Steadily add the required quantity of Rigel direct to the spray, drench or irrigation tank (pre-mixing is not necessary). Empty product container thoroughly and dispose of safely.Add the remainder of the water.Apply immediately and continue agitation until spraying, irrigation or drenching is complete.Wash sprayer or flush out drench or irrigation equipment thoroughly immediately after use, using clean water and following best practice advice and the guidance provided by the equipment manufacturer.Do not apply via knapsack sprayers.

The following does not form part of the product label under the UK Plant Protection Products Regulations or the Irish S.I. No. 159 of 2012.

With many products there is a general risk of resistance developing to the active ingredients. For this reason a change in activity cannot be ruled out. It is generally impossible to predict with certainty how resistance may develop because there are so many crop and use connected ways of

influencing this. We therefore have to exclude liability for damage or loss attributable to any such resistance that may develop. To help minimise any loss in activity the BASF recommended rate should in all events be adhered to.

Numerous, particularly regional or regionally attributable, factors can influence the activity of the product. Examples include weather and soil conditions, crop plant varieties, crop rotation, treatment times, application amounts, admixture with other products, appearance of organisms resistant to active ingredients and spraying techniques. Under particular conditions a change in activity or damage to plants cannot be ruled out. The manufacturer or supplier is therefore unable to accept any liability in such circumstances. All goods supplied by us are of high grade and we believe them to be suitable, but as we cannot exercise control over their mixing or use or the weather conditions during and after application, which may affect the performance of the material, all conditions and warranties, statutory or otherwise, as to the quality or fitness for any purpose of our goods are excluded and no responsibility will be accepted by us for any damage or injury whatsoever arising from their storage, handling, application or use; but nothing should be deemed to exclude or restrict any liability upon us which cannot be excluded or restricted under the provisions of the Unfair Contract Terms Act 1977 or any similar applicable law.

Section 6 of the Health and Safety at Work Act Additional Product Safety InformationThe product label provides information on a specific pesticidal use of the product; do not use otherwise, unless you have assessed any potential hazard involved, the safety measures required and that the particular use has ‚off-label‘ approval or is otherwise permitted under the Plant Protection Products Regulations.The information on this label is based on the best available information including data from test results

Safety Data Sheet

1. Identification of the substance/mixture and of the company/undertakingProduct identifier RIGELRelevant identified uses of the substance or mixture and uses advised againstRelevant identified uses: crop protection product, fungicideDetails of the supplier of the safety data sheetCompany: Servem LtdContact address: Maxboley Duncormick.Wexford IrelandTelephone: +35351563530E-mail address:info@servemlimited.comEmergency telephone numberInternational emergency number: Telephone: +35351563531

2. Hazards Identification

Label elementsGlobally Harmonized System, EU (GHS) Hazard Statement:H412 Harmful to aquatic life with long lasting effects.EUH401 To avoid risks to human health and the environment, comply with the instructions for use.According to Directive 67/548/EEC or 1999/45/EC EEC DirectivesR-phrase(s)R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s)S2 Keep out of the reach of children.S13 Keep away from food, drink and animal feeding stuffs.S20/21 When using do not eat, drink or smoke.Classification/labelling in accordance with Irish regulations. Hazard symbol(s)N Dangerous for the environment.R-phrase(s)R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s)S2 Keep out of the reach of children.S13 Keep away from food, drink and animal feeding stuffs.S20/21 When using do not eat, drink or smoke.S35 This material and its container must be disposed of in a safe way.S57 Use appropriate container to avoid environmental contamination.Classification of the substance or mixture According to Regulation (EC) No 1272/2008 [CLP] Aquatic Chronic 3According to Directive 67/548/EEC or 1999/45/EC Possible Hazards:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. For the classifications not written out in full in this section the full text can be found in section 16.Other hazardsAccording to Regulation (EC) No 1272/2008 [CLP]See section 12 - Results of PBT and vPvB assessment.

If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture.

3. Composition/Information on Ingredients MixturesChemical naturecrop protection product, fungicide, Wettable powder (WP)

Hazardous ingredients (GHS)according to Regulation (EC) No. 1272/2008

Dimethomorph

Content (W/W): 50 % Aquatic Chronic 2CAS Number: 110488-70-5 H411EC-Number: 404-200-2INDEX-Number: 613-102-00-0KaoliniteContent (W/W): < 45 % CAS Number: 1318-74-7EC-Number: 215-286-4 Sodium diisopropylnaphthalenesulphonateContent (W/W): < 5 % CAS Number: 1322-93-6EC-Number: 215-343-3 Hazardous ingredientsaccording to Directive 1999/45/ECDimethomorphContent (W/W): 50 %CAS Number: 110488-70-5EC-Number: 404-200-2INDEX-Number: 613-102-00-0Hazard symbol(s): N R-phrase(s): 51/53KaoliniteContent (W/W): < 45 % CAS Number: 1318-74-7EC-Number: 215-286-4 Sodium diisopropylnaphthalenesulphonateContent (W/W): < 5 % CAS Number: 1322-93-6EC-Number: 215-343-3For the classifications not written out in full in this section, including the indication of danger, the hazard symbols, the R phrases, and the hazard statements, the full text is listed in section 16.

4. First-Aid MeasuresDescription of first aid measuresRemove contaminated clothing.If inhaled: Keep patient calm, remove to fresh air.On skin contact: Wash thoroughly with soap and water.On contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open. On ingestion: Rinse mouth and then drink plenty of water.Most important symptoms and effects, both acute and delayedSymptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known.Indication of any immediate medical attention and special treatment neededTreatment: Symptomatic treatment (decontamination, vital functions).

5. Fire-Fighting Measures Extinguishing mediaSuitable extinguishing media: dry powder, foam, water spray Unsuitable extinguishing media for safety reasons: carbon dioxideSpecial hazards arising from the substance or mixturecarbon monoxide, hydrogen chloride, Carbon dioxide, nitrogen oxides, organochloric compounds The

substances/groups of substances mentioned can be released in case of fire.Advice for fire-fightersSpecial protective equipment:Wear self-contained breathing apparatus and chemical-protective clothing.Further information:In case of fire and/or explosion do not breathe fumes. Keep containers cool by spraying with water if exposed to fire. Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.

6. Accidental Release MeasuresPersonal precautions, protective equipment and emergency proceduresUse personal protective clothing. Avoid contact with the skin, eyes and clothing. Avoid dust formation.Environmental precautionsDo not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater.Do not allow contamination of public drains or surface or ground waters. Inform local water plc if spillage enters drains and the Environmental Protection Agency if it enters surface or ground waters. Keep people and animals away.Methods and material for containment and cleaning upFor small amounts: Contain with dust binding material and dispose of. For large amounts: Sweep/shovel up.Dispose of absorbed material in accordance with regulations. Collect waste in suitable containers, which can be labeled and sealed.Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Avoid raising dust.Reference to other sectionsInformation regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.7. Handling and Storage Precautions for safe handlingNo special measures necessary if stored and handled correctly. Ensure thorough ventilation of stores and work areas. When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift.Protection against fire and explosion:Dust can form an explosive mixture with air. Avoid dust formation. Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.Conditions for safe storage, including any incompatibilitiesSegregate from foods and animal feeds.Further information on storage conditions: Keep away from heat. Protect against moisture. Protect from direct sunlight. Protect from temperatures above: 40 °CChanges in the properties of the product may occur if substance/product is stored above indicated temperature for extended periods of time.

Specific end use(s)For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed.

8. Exposure Controls/Personal Protection Control parametersComponents with workplace control parametersFor normal use and handling refer to the product label/leaflet. In all other cases the following apply. Refer to the current schedule of occupational exposure standards published by the Irish HSA.Exposure controlsPersonal protective equipmentRespiratory protection: Respiratory protection not required.Hand protection: Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) and otherEye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166)

Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical- protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).General safety and hygiene measuresThe statements on personal protective equipment in the instructions for use apply when handling crop-protection agents in final- consumer packing. Wearing of closed work clothing is recommended. Keep away from food, drink and animal feeding stuffs. Store work clothing separately.

9. Physical and Chemical PropertiesInformation on basic physical and chemical propertiesForm: powderColour: whiteOdour: slight odour, sweetishOdour threshold: not determinedpH value: approx. 4 - 6 (10 g/l, 20 °C)Melting point: approx. 125 - 149 °CThe values mentioned are those of the active ingredient.Boiling point: The product has not been tested.Flash point: not applicableEvaporation rate: not applicableFlammability: not highly flammable (Directive 92/69/EEC, A.10)Lower explosion limit: not determinedUpper explosion limit: not determinedVapour pressure: negligibleDensity: approx. 1.72 g/cm3 (20 °C) (OECD Guideline 109) Relative vapour density (air): not determinedSolubility in water: dispersibleInformation on: Dimethomorph Partitioning coefficientn-octanol/water (log Kow): 2.63 - 2.73 (20 °C)----------------------------------

Self ignition: Temperature: 371 °C (Method: Directive 92/69/EEC, A.16) Thermal decomposition: not determinedViscosity, dynamic: not applicableExplosion hazard: Based on the chemical structure there is no indicating of explosive properties. Fire promoting properties: Based on its structural properties the product is not classified as oxidizing.Other informationIf necessary, information on other physical and chemical parameters is indicated in this section.10. Stability and Reactivity ReactivityNo hazardous reactions if stored and handled as prescribed/indicated.Chemical stabilityThe product is stable if stored and handled as prescribed/indicated.Possibility of hazardous reactionsNo hazardous reactions if stored and handled as prescribed/indicated.Conditions to avoidSee MSDS section 7 - Handling and storage.Incompatible materialsSubstances to avoid: strong acids, strong bases, strong oxidizing agentsHazardous decomposition productsHazardous decomposition products:No hazardous decomposition products if stored and handled as prescribed/indicated.

11. Toxicological Information Information on toxicological effectsAcute toxicityAssessment of acute toxicity:Of low toxicity after single ingestion. Virtually nontoxic after a single skin contact. Virtually nontoxic by inhalation.Experimental/calculated data:LD50 rat (oral): 2,939 mg/kg (OECD Guideline 401)LC50 rat (by inhalation): > 2.0 mg/l 4 h (OECD Guideline 403)No mortality was observed. Highest concentration available for testing. Tested as dust aerosol. LD50 rat (dermal): > 2,000 mg/kg (OECD Guideline 402)IrritationAssessment of irritating effects:Not irritating to the eyes. Not irritating to the skin. Experimental/calculated data:Skin corrosion/irritation rabbit: non-irritant (OECD Guideline 404) Serious eye damage/irritation rabbit: non-irritant (OECD Guideline 405)Respiratory/Skin sensitization Assessment of sensitization:There is no evidence of a skin-sensitizing potential.Experimental/calculated data:Buehler test guinea pig: Non-sensitizing. (OECD Guideline 406)Germ cell mutagenicity Assessment of mutagenicity:The product has not been tested. The statement has been derived from the properties of the individual components.

Mutagenicity tests revealed no genotoxic potential.CarcinogenicityAssessment of carcinogenicity:The product has not been tested. The statement has been derived from the properties of the individual components. The results of various animal studies gave no indication of a carcinogenic effect.Reproductive toxicityAssessment of reproduction toxicity:The product has not been tested. The statement has been derived from the properties of the individual components. The results of animal studies gave no indication of a fertility impairing effect.Developmental toxicity Assessment of teratogenicity:The product has not been tested. The statement has been derived from the properties of the individual components. Animal studies gave no indication of a developmental toxic effect at doses that were not toxic to the parental animals.Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity:The product has not been tested. The statement has been derived from the properties of the individual components. No substance- specific organotoxicity was observed after repeated administration of high doses to animals.Other relevant toxicity information Misuse can be harmful to health.

12. Ecological Information ToxicityAssessment of aquatic toxicity:Acutely harmful for aquatic organisms. May cause long-term adverse effects in the aquatic environment.Toxicity to fish:LC50 (96 h) 15.3 mg/l, Oncorhynchus mykiss (OECD Guideline 203, static)Aquatic invertebrates:EC50 (48 h) 14.2 mg/l, Daphnia magna (OECD Guideline 202, part 1, static)Aquatic plants:EC50 (72 h) 60.2 mg/l (growth rate), Desmodesmus subspicatus (OECD Guideline 201, static)Persistence and degradabilityAssessment biodegradation and elimination (H2O):The product has not been tested. The statement has been derived from the properties of the individual components.Information on: DimethomorphAssessment biodegradation and elimination (H2O): Not readily biodegradable (by OECD criteria).----------------------------------Bioaccumulative potentialAssessment bioaccumulation potential:The product has not been tested. The statement has been derived from the properties of the individual components.Information on: Dimethomorph Bioaccumulation potential:No significant accumulation in organisms is expected as a result of the distribution coefficient of n-octanol/water (log Pow).----------------------------------

Mobility in soil (and other compartments if available)Assessment transport between environmental compartments:The product has not been tested. The statement has been derived from the properties of the individual components.Information on: DimethomorphAssessment transport between environmental compartments:Following exposure to soil, adsorption to solid soil particles is probable, therefore contamination of groundwater is not expected.----------------------------------Results of PBT and vPvB assessmentThe product does not contain a substance fullfilling the PBT (persistent/bioaccumulative/toxic) criteria or the vPvB (very persistent/ very bioaccumulative) criteria.Other adverse effectsThe product does not contain substances that are listed in Annex I of Regulation (EC) 2037/2000 on substances that deplete the ozone layer.Additional informationOther ecotoxicological advice:Do not discharge product into the environment without control.

13. Disposal Considerations Waste treatment methodsMust be sent to a suitable incineration plant, observing local regulations. Contaminated packaging:Contaminated packaging should be emptied as far as possible and disposed of in the same manner as the substance/product.

14. Transport Information Land transportADR Not classified as a dangerous good under transport regulations RID Not classified as a dangerous good under transport regulationsInland waterway transportADN Not classified as a dangerous good under transport regulationsSea transportIMDG Not classified as a dangerous good under transport regulationsAir transportIATA/ICAO Not classified as a dangerous good under transport regulations

15. Regulatory InformationSafety, health and environmental regulations/legislation specific for the substance or mixtureFor the user of this plant-protective product applies: ‚To avoid risks to man and the environment, comply with the instructions for use.‘ (Directive 1999/45/EC, Article 10, No. 1.2)This product may be subject to the Seveco II Directive and amendments if specific treshold tonnages are exceeded. For further medical advice Doctors should contact the National Poison Information Centre at Beaumont Hospital, Dublin.Chemical Safety AssessmentAdvice on product handling can be found in sections 7 and 8

of this safety data sheet.16. Other InformationFor proper and safe use of this product, please refer to the approval conditions laid down on the product label.Full text of the classifications, including the indication of danger, the hazard symbols, the R phrases, and the hazard statements, if mentioned in section 2 or 3:N Dangerous for the environment.51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Aquatic Chronic Hazardous to the aquatic environment - chronicH411 Toxic to aquatic life with long lasting effects.The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product‘s properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.

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DIRECTIONS FOR USEIMPORTANT: This information is approved as part of the Product Label. All instructions within this section must be read carefully in order to obtain safe and successful use of this product.1. Restrictions/Warnings For professional use only. 1.1 Processed cropsConsult processor before use on crops for processing2. Disease controlRigel is a fungicide with protectant activity against crown rot (Phytophthora cactorum) in strawberries and root rot (Phytophthora spp.) in raspberries and blackberries. Rigel will be most effective when applied as a protectant treatment immediately after planting, before disease symptoms appear.2.1 ResistanceRigel contains dimethomorph, a CAA fungicide. It should be used in accordance with FRAC resistance management advice for CAA fungicides.In outdoor and protected crops of strawberries, no more than one application of Rigel per year may be made for moderate control of crown rot (Phytophthora cactorum). Applications should be made preventatively after planting.In raspberries and blackberries, no more than one application of Rigel per year may be made for moderate control of root rot (Phytophthora spp.). Applications should be made preventatively immediately after planting in the spring or autumn. Alternation with fungicides with different modes of

action to Rigel is recommended as part of a resistance management programme. CAA fungicides should not make up more than 50% of the intended number of fungicide applications for Phytophthora disease control in strawberries, raspberries and blackberries.Use Rigel as part of an Integrated Crop Management (ICM) strategy incorporating other methods of control, including where appropriate fungicides with a different mode of action.3. Crops3.1 Outdoor strawberries Time of applicationFor the moderate control of crown rot (Phytophthora cactorum) apply Rigel as a preventative treatment immediately after planting.Rate of applicationApply Rigel at 3.0 kg/ha as a high volume spray of 600–1000 litres of water per hectare, ensuring good coverage around the base of the plant.3.2 Protected strawberries Time of applicationFor the moderate control of crown rot (Phytophthora cactorum), apply Rigel as a preventative treatment immediately after planting.Rate of applicationApply Rigel as a drip irrigation or root drench treatment of 0.1 gram of product per plant, not exceeding 3.0 kg of product/ha.Rigel may be used at the following dilutions and water volumes: 1g Rigel/litre of water - use 100 ml/plant0.5g Rigel/litre of water - use 200 ml/plant 0.25g Rigel/litre of

water - use 400 ml/plant

3.3 Raspberries and blackberries (outdoor and protected) – qualified minor use recommendation Time of applicationFor the moderate control of root rot (Phytophthora spp.) apply Riigel as a preventative treatment immediately after planting in the spring or autumn.Rate of applicationApply as a drip irrigation or root drench treatment delivering 1.0 g of Rigel per plant, not exceeding 3.0 kg of product/ha.Rigel may be used at the following dilutions and water volumes: 5g Rigel/litre of water - use 200 ml/plant2.5g Rigel/litre of water - use 400 ml/plant*There is limited evidence of crop safety and/or product efficacy available for Qualified Minor uses and the commercial risk of using this product under this Qualified Minor use is borne entirely by the grower.

4. Succeeding CropsFollowing application of Rigel, allow 10 months before sowing clover.5. Mixing and ApplicationIn outdoor strawberries, Rigel should be applied as a COARSE spray as defined by BCPC, using a high volume drenching spray of 600–1000 litres of water per hectare, using hydraulic nozzles and ensuring good coverage around the base of the plant. In protected crops of strawberries, Rigel should be applied via drip irrigation or as a root drench delivering at least 100 ml of water per plant. In outdoor or protected raspberries and blackberries, Rigel should be applied via drip irrigation or as a root drench delivering at least 200 ml of water per plant.Half fill the sprayer, drench or irrigation tank with clean water and start agitation.Steadily add the required quantity of Rigel direct to the spray, drench or irrigation tank (pre-mixing is not necessary). Empty product container thoroughly and dispose of safely.Add the remainder of the water.Apply immediately and continue agitation until spraying, irrigation or drenching is complete.Wash sprayer or flush out drench or irrigation equipment thoroughly immediately after use, using clean water and following best practice advice and the guidance provided by the equipment manufacturer.Do not apply via knapsack sprayers.

The following does not form part of the product label under the UK Plant Protection Products Regulations or the Irish S.I. No. 159 of 2012.

With many products there is a general risk of resistance developing to the active ingredients. For this reason a change in activity cannot be ruled out. It is generally impossible to predict with certainty how resistance may develop because there are so many crop and use connected ways of

influencing this. We therefore have to exclude liability for damage or loss attributable to any such resistance that may develop. To help minimise any loss in activity the BASF recommended rate should in all events be adhered to.

Numerous, particularly regional or regionally attributable, factors can influence the activity of the product. Examples include weather and soil conditions, crop plant varieties, crop rotation, treatment times, application amounts, admixture with other products, appearance of organisms resistant to active ingredients and spraying techniques. Under particular conditions a change in activity or damage to plants cannot be ruled out. The manufacturer or supplier is therefore unable to accept any liability in such circumstances. All goods supplied by us are of high grade and we believe them to be suitable, but as we cannot exercise control over their mixing or use or the weather conditions during and after application, which may affect the performance of the material, all conditions and warranties, statutory or otherwise, as to the quality or fitness for any purpose of our goods are excluded and no responsibility will be accepted by us for any damage or injury whatsoever arising from their storage, handling, application or use; but nothing should be deemed to exclude or restrict any liability upon us which cannot be excluded or restricted under the provisions of the Unfair Contract Terms Act 1977 or any similar applicable law.

Section 6 of the Health and Safety at Work Act Additional Product Safety InformationThe product label provides information on a specific pesticidal use of the product; do not use otherwise, unless you have assessed any potential hazard involved, the safety measures required and that the particular use has ‚off-label‘ approval or is otherwise permitted under the Plant Protection Products Regulations.The information on this label is based on the best available information including data from test results

Safety Data Sheet

1. Identification of the substance/mixture and of the company/undertakingProduct identifier RIGELRelevant identified uses of the substance or mixture and uses advised againstRelevant identified uses: crop protection product, fungicideDetails of the supplier of the safety data sheetCompany: Servem LtdContact address: Maxboley Duncormick.Wexford IrelandTelephone: +35351563530E-mail address:info@servemlimited.comEmergency telephone numberInternational emergency number: Telephone: +35351563531

2. Hazards Identification

Label elementsGlobally Harmonized System, EU (GHS) Hazard Statement:H412 Harmful to aquatic life with long lasting effects.EUH401 To avoid risks to human health and the environment, comply with the instructions for use.According to Directive 67/548/EEC or 1999/45/EC EEC DirectivesR-phrase(s)R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s)S2 Keep out of the reach of children.S13 Keep away from food, drink and animal feeding stuffs.S20/21 When using do not eat, drink or smoke.Classification/labelling in accordance with Irish regulations. Hazard symbol(s)N Dangerous for the environment.R-phrase(s)R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s)S2 Keep out of the reach of children.S13 Keep away from food, drink and animal feeding stuffs.S20/21 When using do not eat, drink or smoke.S35 This material and its container must be disposed of in a safe way.S57 Use appropriate container to avoid environmental contamination.Classification of the substance or mixture According to Regulation (EC) No 1272/2008 [CLP] Aquatic Chronic 3According to Directive 67/548/EEC or 1999/45/EC Possible Hazards:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. For the classifications not written out in full in this section the full text can be found in section 16.Other hazardsAccording to Regulation (EC) No 1272/2008 [CLP]See section 12 - Results of PBT and vPvB assessment.

If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture.

3. Composition/Information on Ingredients MixturesChemical naturecrop protection product, fungicide, Wettable powder (WP)

Hazardous ingredients (GHS)according to Regulation (EC) No. 1272/2008

Dimethomorph

Content (W/W): 50 % Aquatic Chronic 2CAS Number: 110488-70-5 H411EC-Number: 404-200-2INDEX-Number: 613-102-00-0KaoliniteContent (W/W): < 45 % CAS Number: 1318-74-7EC-Number: 215-286-4 Sodium diisopropylnaphthalenesulphonateContent (W/W): < 5 % CAS Number: 1322-93-6EC-Number: 215-343-3 Hazardous ingredientsaccording to Directive 1999/45/ECDimethomorphContent (W/W): 50 %CAS Number: 110488-70-5EC-Number: 404-200-2INDEX-Number: 613-102-00-0Hazard symbol(s): N R-phrase(s): 51/53KaoliniteContent (W/W): < 45 % CAS Number: 1318-74-7EC-Number: 215-286-4 Sodium diisopropylnaphthalenesulphonateContent (W/W): < 5 % CAS Number: 1322-93-6EC-Number: 215-343-3For the classifications not written out in full in this section, including the indication of danger, the hazard symbols, the R phrases, and the hazard statements, the full text is listed in section 16.

4. First-Aid MeasuresDescription of first aid measuresRemove contaminated clothing.If inhaled: Keep patient calm, remove to fresh air.On skin contact: Wash thoroughly with soap and water.On contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open. On ingestion: Rinse mouth and then drink plenty of water.Most important symptoms and effects, both acute and delayedSymptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known.Indication of any immediate medical attention and special treatment neededTreatment: Symptomatic treatment (decontamination, vital functions).

5. Fire-Fighting Measures Extinguishing mediaSuitable extinguishing media: dry powder, foam, water spray Unsuitable extinguishing media for safety reasons: carbon dioxideSpecial hazards arising from the substance or mixturecarbon monoxide, hydrogen chloride, Carbon dioxide, nitrogen oxides, organochloric compounds The

substances/groups of substances mentioned can be released in case of fire.Advice for fire-fightersSpecial protective equipment:Wear self-contained breathing apparatus and chemical-protective clothing.Further information:In case of fire and/or explosion do not breathe fumes. Keep containers cool by spraying with water if exposed to fire. Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.

6. Accidental Release MeasuresPersonal precautions, protective equipment and emergency proceduresUse personal protective clothing. Avoid contact with the skin, eyes and clothing. Avoid dust formation.Environmental precautionsDo not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater.Do not allow contamination of public drains or surface or ground waters. Inform local water plc if spillage enters drains and the Environmental Protection Agency if it enters surface or ground waters. Keep people and animals away.Methods and material for containment and cleaning upFor small amounts: Contain with dust binding material and dispose of. For large amounts: Sweep/shovel up.Dispose of absorbed material in accordance with regulations. Collect waste in suitable containers, which can be labeled and sealed.Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Avoid raising dust.Reference to other sectionsInformation regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.7. Handling and Storage Precautions for safe handlingNo special measures necessary if stored and handled correctly. Ensure thorough ventilation of stores and work areas. When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift.Protection against fire and explosion:Dust can form an explosive mixture with air. Avoid dust formation. Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.Conditions for safe storage, including any incompatibilitiesSegregate from foods and animal feeds.Further information on storage conditions: Keep away from heat. Protect against moisture. Protect from direct sunlight. Protect from temperatures above: 40 °CChanges in the properties of the product may occur if substance/product is stored above indicated temperature for extended periods of time.

Specific end use(s)For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed.

8. Exposure Controls/Personal Protection Control parametersComponents with workplace control parametersFor normal use and handling refer to the product label/leaflet. In all other cases the following apply. Refer to the current schedule of occupational exposure standards published by the Irish HSA.Exposure controlsPersonal protective equipmentRespiratory protection: Respiratory protection not required.Hand protection: Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) and otherEye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166)

Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical- protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).General safety and hygiene measuresThe statements on personal protective equipment in the instructions for use apply when handling crop-protection agents in final- consumer packing. Wearing of closed work clothing is recommended. Keep away from food, drink and animal feeding stuffs. Store work clothing separately.

9. Physical and Chemical PropertiesInformation on basic physical and chemical propertiesForm: powderColour: whiteOdour: slight odour, sweetishOdour threshold: not determinedpH value: approx. 4 - 6 (10 g/l, 20 °C)Melting point: approx. 125 - 149 °CThe values mentioned are those of the active ingredient.Boiling point: The product has not been tested.Flash point: not applicableEvaporation rate: not applicableFlammability: not highly flammable (Directive 92/69/EEC, A.10)Lower explosion limit: not determinedUpper explosion limit: not determinedVapour pressure: negligibleDensity: approx. 1.72 g/cm3 (20 °C) (OECD Guideline 109) Relative vapour density (air): not determinedSolubility in water: dispersibleInformation on: Dimethomorph Partitioning coefficientn-octanol/water (log Kow): 2.63 - 2.73 (20 °C)----------------------------------

Self ignition: Temperature: 371 °C (Method: Directive 92/69/EEC, A.16) Thermal decomposition: not determinedViscosity, dynamic: not applicableExplosion hazard: Based on the chemical structure there is no indicating of explosive properties. Fire promoting properties: Based on its structural properties the product is not classified as oxidizing.Other informationIf necessary, information on other physical and chemical parameters is indicated in this section.10. Stability and Reactivity ReactivityNo hazardous reactions if stored and handled as prescribed/indicated.Chemical stabilityThe product is stable if stored and handled as prescribed/indicated.Possibility of hazardous reactionsNo hazardous reactions if stored and handled as prescribed/indicated.Conditions to avoidSee MSDS section 7 - Handling and storage.Incompatible materialsSubstances to avoid: strong acids, strong bases, strong oxidizing agentsHazardous decomposition productsHazardous decomposition products:No hazardous decomposition products if stored and handled as prescribed/indicated.

11. Toxicological Information Information on toxicological effectsAcute toxicityAssessment of acute toxicity:Of low toxicity after single ingestion. Virtually nontoxic after a single skin contact. Virtually nontoxic by inhalation.Experimental/calculated data:LD50 rat (oral): 2,939 mg/kg (OECD Guideline 401)LC50 rat (by inhalation): > 2.0 mg/l 4 h (OECD Guideline 403)No mortality was observed. Highest concentration available for testing. Tested as dust aerosol. LD50 rat (dermal): > 2,000 mg/kg (OECD Guideline 402)IrritationAssessment of irritating effects:Not irritating to the eyes. Not irritating to the skin. Experimental/calculated data:Skin corrosion/irritation rabbit: non-irritant (OECD Guideline 404) Serious eye damage/irritation rabbit: non-irritant (OECD Guideline 405)Respiratory/Skin sensitization Assessment of sensitization:There is no evidence of a skin-sensitizing potential.Experimental/calculated data:Buehler test guinea pig: Non-sensitizing. (OECD Guideline 406)Germ cell mutagenicity Assessment of mutagenicity:The product has not been tested. The statement has been derived from the properties of the individual components.

Mutagenicity tests revealed no genotoxic potential.CarcinogenicityAssessment of carcinogenicity:The product has not been tested. The statement has been derived from the properties of the individual components. The results of various animal studies gave no indication of a carcinogenic effect.Reproductive toxicityAssessment of reproduction toxicity:The product has not been tested. The statement has been derived from the properties of the individual components. The results of animal studies gave no indication of a fertility impairing effect.Developmental toxicity Assessment of teratogenicity:The product has not been tested. The statement has been derived from the properties of the individual components. Animal studies gave no indication of a developmental toxic effect at doses that were not toxic to the parental animals.Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity:The product has not been tested. The statement has been derived from the properties of the individual components. No substance- specific organotoxicity was observed after repeated administration of high doses to animals.Other relevant toxicity information Misuse can be harmful to health.

12. Ecological Information ToxicityAssessment of aquatic toxicity:Acutely harmful for aquatic organisms. May cause long-term adverse effects in the aquatic environment.Toxicity to fish:LC50 (96 h) 15.3 mg/l, Oncorhynchus mykiss (OECD Guideline 203, static)Aquatic invertebrates:EC50 (48 h) 14.2 mg/l, Daphnia magna (OECD Guideline 202, part 1, static)Aquatic plants:EC50 (72 h) 60.2 mg/l (growth rate), Desmodesmus subspicatus (OECD Guideline 201, static)Persistence and degradabilityAssessment biodegradation and elimination (H2O):The product has not been tested. The statement has been derived from the properties of the individual components.Information on: DimethomorphAssessment biodegradation and elimination (H2O): Not readily biodegradable (by OECD criteria).----------------------------------Bioaccumulative potentialAssessment bioaccumulation potential:The product has not been tested. The statement has been derived from the properties of the individual components.Information on: Dimethomorph Bioaccumulation potential:No significant accumulation in organisms is expected as a result of the distribution coefficient of n-octanol/water (log Pow).----------------------------------

Mobility in soil (and other compartments if available)Assessment transport between environmental compartments:The product has not been tested. The statement has been derived from the properties of the individual components.Information on: DimethomorphAssessment transport between environmental compartments:Following exposure to soil, adsorption to solid soil particles is probable, therefore contamination of groundwater is not expected.----------------------------------Results of PBT and vPvB assessmentThe product does not contain a substance fullfilling the PBT (persistent/bioaccumulative/toxic) criteria or the vPvB (very persistent/ very bioaccumulative) criteria.Other adverse effectsThe product does not contain substances that are listed in Annex I of Regulation (EC) 2037/2000 on substances that deplete the ozone layer.Additional informationOther ecotoxicological advice:Do not discharge product into the environment without control.

13. Disposal Considerations Waste treatment methodsMust be sent to a suitable incineration plant, observing local regulations. Contaminated packaging:Contaminated packaging should be emptied as far as possible and disposed of in the same manner as the substance/product.

14. Transport Information Land transportADR Not classified as a dangerous good under transport regulations RID Not classified as a dangerous good under transport regulationsInland waterway transportADN Not classified as a dangerous good under transport regulationsSea transportIMDG Not classified as a dangerous good under transport regulationsAir transportIATA/ICAO Not classified as a dangerous good under transport regulations

15. Regulatory InformationSafety, health and environmental regulations/legislation specific for the substance or mixtureFor the user of this plant-protective product applies: ‚To avoid risks to man and the environment, comply with the instructions for use.‘ (Directive 1999/45/EC, Article 10, No. 1.2)This product may be subject to the Seveco II Directive and amendments if specific treshold tonnages are exceeded. For further medical advice Doctors should contact the National Poison Information Centre at Beaumont Hospital, Dublin.Chemical Safety AssessmentAdvice on product handling can be found in sections 7 and 8

of this safety data sheet.16. Other InformationFor proper and safe use of this product, please refer to the approval conditions laid down on the product label.Full text of the classifications, including the indication of danger, the hazard symbols, the R phrases, and the hazard statements, if mentioned in section 2 or 3:N Dangerous for the environment.51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Aquatic Chronic Hazardous to the aquatic environment - chronicH411 Toxic to aquatic life with long lasting effects.The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product‘s properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.

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DIRECTIONS FOR USEIMPORTANT: This information is approved as part of the Product Label. All instructions within this section must be read carefully in order to obtain safe and successful use of this product.1. Restrictions/Warnings For professional use only. 1.1 Processed cropsConsult processor before use on crops for processing2. Disease controlRigel is a fungicide with protectant activity against crown rot (Phytophthora cactorum) in strawberries and root rot (Phytophthora spp.) in raspberries and blackberries. Rigel will be most effective when applied as a protectant treatment immediately after planting, before disease symptoms appear.2.1 ResistanceRigel contains dimethomorph, a CAA fungicide. It should be used in accordance with FRAC resistance management advice for CAA fungicides.In outdoor and protected crops of strawberries, no more than one application of Rigel per year may be made for moderate control of crown rot (Phytophthora cactorum). Applications should be made preventatively after planting.In raspberries and blackberries, no more than one application of Rigel per year may be made for moderate control of root rot (Phytophthora spp.). Applications should be made preventatively immediately after planting in the spring or autumn. Alternation with fungicides with different modes of

action to Rigel is recommended as part of a resistance management programme. CAA fungicides should not make up more than 50% of the intended number of fungicide applications for Phytophthora disease control in strawberries, raspberries and blackberries.Use Rigel as part of an Integrated Crop Management (ICM) strategy incorporating other methods of control, including where appropriate fungicides with a different mode of action.3. Crops3.1 Outdoor strawberries Time of applicationFor the moderate control of crown rot (Phytophthora cactorum) apply Rigel as a preventative treatment immediately after planting.Rate of applicationApply Rigel at 3.0 kg/ha as a high volume spray of 600–1000 litres of water per hectare, ensuring good coverage around the base of the plant.3.2 Protected strawberries Time of applicationFor the moderate control of crown rot (Phytophthora cactorum), apply Rigel as a preventative treatment immediately after planting.Rate of applicationApply Rigel as a drip irrigation or root drench treatment of 0.1 gram of product per plant, not exceeding 3.0 kg of product/ha.Rigel may be used at the following dilutions and water volumes: 1g Rigel/litre of water - use 100 ml/plant0.5g Rigel/litre of water - use 200 ml/plant 0.25g Rigel/litre of

water - use 400 ml/plant

3.3 Raspberries and blackberries (outdoor and protected) – qualified minor use recommendation Time of applicationFor the moderate control of root rot (Phytophthora spp.) apply Riigel as a preventative treatment immediately after planting in the spring or autumn.Rate of applicationApply as a drip irrigation or root drench treatment delivering 1.0 g of Rigel per plant, not exceeding 3.0 kg of product/ha.Rigel may be used at the following dilutions and water volumes: 5g Rigel/litre of water - use 200 ml/plant2.5g Rigel/litre of water - use 400 ml/plant*There is limited evidence of crop safety and/or product efficacy available for Qualified Minor uses and the commercial risk of using this product under this Qualified Minor use is borne entirely by the grower.

4. Succeeding CropsFollowing application of Rigel, allow 10 months before sowing clover.5. Mixing and ApplicationIn outdoor strawberries, Rigel should be applied as a COARSE spray as defined by BCPC, using a high volume drenching spray of 600–1000 litres of water per hectare, using hydraulic nozzles and ensuring good coverage around the base of the plant. In protected crops of strawberries, Rigel should be applied via drip irrigation or as a root drench delivering at least 100 ml of water per plant. In outdoor or protected raspberries and blackberries, Rigel should be applied via drip irrigation or as a root drench delivering at least 200 ml of water per plant.Half fill the sprayer, drench or irrigation tank with clean water and start agitation.Steadily add the required quantity of Rigel direct to the spray, drench or irrigation tank (pre-mixing is not necessary). Empty product container thoroughly and dispose of safely.Add the remainder of the water.Apply immediately and continue agitation until spraying, irrigation or drenching is complete.Wash sprayer or flush out drench or irrigation equipment thoroughly immediately after use, using clean water and following best practice advice and the guidance provided by the equipment manufacturer.Do not apply via knapsack sprayers.

The following does not form part of the product label under the UK Plant Protection Products Regulations or the Irish S.I. No. 159 of 2012.

With many products there is a general risk of resistance developing to the active ingredients. For this reason a change in activity cannot be ruled out. It is generally impossible to predict with certainty how resistance may develop because there are so many crop and use connected ways of

influencing this. We therefore have to exclude liability for damage or loss attributable to any such resistance that may develop. To help minimise any loss in activity the BASF recommended rate should in all events be adhered to.

Numerous, particularly regional or regionally attributable, factors can influence the activity of the product. Examples include weather and soil conditions, crop plant varieties, crop rotation, treatment times, application amounts, admixture with other products, appearance of organisms resistant to active ingredients and spraying techniques. Under particular conditions a change in activity or damage to plants cannot be ruled out. The manufacturer or supplier is therefore unable to accept any liability in such circumstances. All goods supplied by us are of high grade and we believe them to be suitable, but as we cannot exercise control over their mixing or use or the weather conditions during and after application, which may affect the performance of the material, all conditions and warranties, statutory or otherwise, as to the quality or fitness for any purpose of our goods are excluded and no responsibility will be accepted by us for any damage or injury whatsoever arising from their storage, handling, application or use; but nothing should be deemed to exclude or restrict any liability upon us which cannot be excluded or restricted under the provisions of the Unfair Contract Terms Act 1977 or any similar applicable law.

Section 6 of the Health and Safety at Work Act Additional Product Safety InformationThe product label provides information on a specific pesticidal use of the product; do not use otherwise, unless you have assessed any potential hazard involved, the safety measures required and that the particular use has ‚off-label‘ approval or is otherwise permitted under the Plant Protection Products Regulations.The information on this label is based on the best available information including data from test results

Safety Data Sheet

1. Identification of the substance/mixture and of the company/undertakingProduct identifier RIGELRelevant identified uses of the substance or mixture and uses advised againstRelevant identified uses: crop protection product, fungicideDetails of the supplier of the safety data sheetCompany: Servem LtdContact address: Maxboley Duncormick.Wexford IrelandTelephone: +35351563530E-mail address:info@servemlimited.comEmergency telephone numberInternational emergency number: Telephone: +35351563531

2. Hazards Identification

Label elementsGlobally Harmonized System, EU (GHS) Hazard Statement:H412 Harmful to aquatic life with long lasting effects.EUH401 To avoid risks to human health and the environment, comply with the instructions for use.According to Directive 67/548/EEC or 1999/45/EC EEC DirectivesR-phrase(s)R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s)S2 Keep out of the reach of children.S13 Keep away from food, drink and animal feeding stuffs.S20/21 When using do not eat, drink or smoke.Classification/labelling in accordance with Irish regulations. Hazard symbol(s)N Dangerous for the environment.R-phrase(s)R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s)S2 Keep out of the reach of children.S13 Keep away from food, drink and animal feeding stuffs.S20/21 When using do not eat, drink or smoke.S35 This material and its container must be disposed of in a safe way.S57 Use appropriate container to avoid environmental contamination.Classification of the substance or mixture According to Regulation (EC) No 1272/2008 [CLP] Aquatic Chronic 3According to Directive 67/548/EEC or 1999/45/EC Possible Hazards:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. For the classifications not written out in full in this section the full text can be found in section 16.Other hazardsAccording to Regulation (EC) No 1272/2008 [CLP]See section 12 - Results of PBT and vPvB assessment.

If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture.

3. Composition/Information on Ingredients MixturesChemical naturecrop protection product, fungicide, Wettable powder (WP)

Hazardous ingredients (GHS)according to Regulation (EC) No. 1272/2008

Dimethomorph

Content (W/W): 50 % Aquatic Chronic 2CAS Number: 110488-70-5 H411EC-Number: 404-200-2INDEX-Number: 613-102-00-0KaoliniteContent (W/W): < 45 % CAS Number: 1318-74-7EC-Number: 215-286-4 Sodium diisopropylnaphthalenesulphonateContent (W/W): < 5 % CAS Number: 1322-93-6EC-Number: 215-343-3 Hazardous ingredientsaccording to Directive 1999/45/ECDimethomorphContent (W/W): 50 %CAS Number: 110488-70-5EC-Number: 404-200-2INDEX-Number: 613-102-00-0Hazard symbol(s): N R-phrase(s): 51/53KaoliniteContent (W/W): < 45 % CAS Number: 1318-74-7EC-Number: 215-286-4 Sodium diisopropylnaphthalenesulphonateContent (W/W): < 5 % CAS Number: 1322-93-6EC-Number: 215-343-3For the classifications not written out in full in this section, including the indication of danger, the hazard symbols, the R phrases, and the hazard statements, the full text is listed in section 16.

4. First-Aid MeasuresDescription of first aid measuresRemove contaminated clothing.If inhaled: Keep patient calm, remove to fresh air.On skin contact: Wash thoroughly with soap and water.On contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open. On ingestion: Rinse mouth and then drink plenty of water.Most important symptoms and effects, both acute and delayedSymptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known.Indication of any immediate medical attention and special treatment neededTreatment: Symptomatic treatment (decontamination, vital functions).

5. Fire-Fighting Measures Extinguishing mediaSuitable extinguishing media: dry powder, foam, water spray Unsuitable extinguishing media for safety reasons: carbon dioxideSpecial hazards arising from the substance or mixturecarbon monoxide, hydrogen chloride, Carbon dioxide, nitrogen oxides, organochloric compounds The

substances/groups of substances mentioned can be released in case of fire.Advice for fire-fightersSpecial protective equipment:Wear self-contained breathing apparatus and chemical-protective clothing.Further information:In case of fire and/or explosion do not breathe fumes. Keep containers cool by spraying with water if exposed to fire. Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.

6. Accidental Release MeasuresPersonal precautions, protective equipment and emergency proceduresUse personal protective clothing. Avoid contact with the skin, eyes and clothing. Avoid dust formation.Environmental precautionsDo not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater.Do not allow contamination of public drains or surface or ground waters. Inform local water plc if spillage enters drains and the Environmental Protection Agency if it enters surface or ground waters. Keep people and animals away.Methods and material for containment and cleaning upFor small amounts: Contain with dust binding material and dispose of. For large amounts: Sweep/shovel up.Dispose of absorbed material in accordance with regulations. Collect waste in suitable containers, which can be labeled and sealed.Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Avoid raising dust.Reference to other sectionsInformation regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.7. Handling and Storage Precautions for safe handlingNo special measures necessary if stored and handled correctly. Ensure thorough ventilation of stores and work areas. When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift.Protection against fire and explosion:Dust can form an explosive mixture with air. Avoid dust formation. Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.Conditions for safe storage, including any incompatibilitiesSegregate from foods and animal feeds.Further information on storage conditions: Keep away from heat. Protect against moisture. Protect from direct sunlight. Protect from temperatures above: 40 °CChanges in the properties of the product may occur if substance/product is stored above indicated temperature for extended periods of time.

Specific end use(s)For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed.

8. Exposure Controls/Personal Protection Control parametersComponents with workplace control parametersFor normal use and handling refer to the product label/leaflet. In all other cases the following apply. Refer to the current schedule of occupational exposure standards published by the Irish HSA.Exposure controlsPersonal protective equipmentRespiratory protection: Respiratory protection not required.Hand protection: Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) and otherEye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166)

Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical- protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).General safety and hygiene measuresThe statements on personal protective equipment in the instructions for use apply when handling crop-protection agents in final- consumer packing. Wearing of closed work clothing is recommended. Keep away from food, drink and animal feeding stuffs. Store work clothing separately.

9. Physical and Chemical PropertiesInformation on basic physical and chemical propertiesForm: powderColour: whiteOdour: slight odour, sweetishOdour threshold: not determinedpH value: approx. 4 - 6 (10 g/l, 20 °C)Melting point: approx. 125 - 149 °CThe values mentioned are those of the active ingredient.Boiling point: The product has not been tested.Flash point: not applicableEvaporation rate: not applicableFlammability: not highly flammable (Directive 92/69/EEC, A.10)Lower explosion limit: not determinedUpper explosion limit: not determinedVapour pressure: negligibleDensity: approx. 1.72 g/cm3 (20 °C) (OECD Guideline 109) Relative vapour density (air): not determinedSolubility in water: dispersibleInformation on: Dimethomorph Partitioning coefficientn-octanol/water (log Kow): 2.63 - 2.73 (20 °C)----------------------------------

Self ignition: Temperature: 371 °C (Method: Directive 92/69/EEC, A.16) Thermal decomposition: not determinedViscosity, dynamic: not applicableExplosion hazard: Based on the chemical structure there is no indicating of explosive properties. Fire promoting properties: Based on its structural properties the product is not classified as oxidizing.Other informationIf necessary, information on other physical and chemical parameters is indicated in this section.10. Stability and Reactivity ReactivityNo hazardous reactions if stored and handled as prescribed/indicated.Chemical stabilityThe product is stable if stored and handled as prescribed/indicated.Possibility of hazardous reactionsNo hazardous reactions if stored and handled as prescribed/indicated.Conditions to avoidSee MSDS section 7 - Handling and storage.Incompatible materialsSubstances to avoid: strong acids, strong bases, strong oxidizing agentsHazardous decomposition productsHazardous decomposition products:No hazardous decomposition products if stored and handled as prescribed/indicated.

11. Toxicological Information Information on toxicological effectsAcute toxicityAssessment of acute toxicity:Of low toxicity after single ingestion. Virtually nontoxic after a single skin contact. Virtually nontoxic by inhalation.Experimental/calculated data:LD50 rat (oral): 2,939 mg/kg (OECD Guideline 401)LC50 rat (by inhalation): > 2.0 mg/l 4 h (OECD Guideline 403)No mortality was observed. Highest concentration available for testing. Tested as dust aerosol. LD50 rat (dermal): > 2,000 mg/kg (OECD Guideline 402)IrritationAssessment of irritating effects:Not irritating to the eyes. Not irritating to the skin. Experimental/calculated data:Skin corrosion/irritation rabbit: non-irritant (OECD Guideline 404) Serious eye damage/irritation rabbit: non-irritant (OECD Guideline 405)Respiratory/Skin sensitization Assessment of sensitization:There is no evidence of a skin-sensitizing potential.Experimental/calculated data:Buehler test guinea pig: Non-sensitizing. (OECD Guideline 406)Germ cell mutagenicity Assessment of mutagenicity:The product has not been tested. The statement has been derived from the properties of the individual components.

Mutagenicity tests revealed no genotoxic potential.CarcinogenicityAssessment of carcinogenicity:The product has not been tested. The statement has been derived from the properties of the individual components. The results of various animal studies gave no indication of a carcinogenic effect.Reproductive toxicityAssessment of reproduction toxicity:The product has not been tested. The statement has been derived from the properties of the individual components. The results of animal studies gave no indication of a fertility impairing effect.Developmental toxicity Assessment of teratogenicity:The product has not been tested. The statement has been derived from the properties of the individual components. Animal studies gave no indication of a developmental toxic effect at doses that were not toxic to the parental animals.Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity:The product has not been tested. The statement has been derived from the properties of the individual components. No substance- specific organotoxicity was observed after repeated administration of high doses to animals.Other relevant toxicity information Misuse can be harmful to health.

12. Ecological Information ToxicityAssessment of aquatic toxicity:Acutely harmful for aquatic organisms. May cause long-term adverse effects in the aquatic environment.Toxicity to fish:LC50 (96 h) 15.3 mg/l, Oncorhynchus mykiss (OECD Guideline 203, static)Aquatic invertebrates:EC50 (48 h) 14.2 mg/l, Daphnia magna (OECD Guideline 202, part 1, static)Aquatic plants:EC50 (72 h) 60.2 mg/l (growth rate), Desmodesmus subspicatus (OECD Guideline 201, static)Persistence and degradabilityAssessment biodegradation and elimination (H2O):The product has not been tested. The statement has been derived from the properties of the individual components.Information on: DimethomorphAssessment biodegradation and elimination (H2O): Not readily biodegradable (by OECD criteria).----------------------------------Bioaccumulative potentialAssessment bioaccumulation potential:The product has not been tested. The statement has been derived from the properties of the individual components.Information on: Dimethomorph Bioaccumulation potential:No significant accumulation in organisms is expected as a result of the distribution coefficient of n-octanol/water (log Pow).----------------------------------

Mobility in soil (and other compartments if available)Assessment transport between environmental compartments:The product has not been tested. The statement has been derived from the properties of the individual components.Information on: DimethomorphAssessment transport between environmental compartments:Following exposure to soil, adsorption to solid soil particles is probable, therefore contamination of groundwater is not expected.----------------------------------Results of PBT and vPvB assessmentThe product does not contain a substance fullfilling the PBT (persistent/bioaccumulative/toxic) criteria or the vPvB (very persistent/ very bioaccumulative) criteria.Other adverse effectsThe product does not contain substances that are listed in Annex I of Regulation (EC) 2037/2000 on substances that deplete the ozone layer.Additional informationOther ecotoxicological advice:Do not discharge product into the environment without control.

13. Disposal Considerations Waste treatment methodsMust be sent to a suitable incineration plant, observing local regulations. Contaminated packaging:Contaminated packaging should be emptied as far as possible and disposed of in the same manner as the substance/product.

14. Transport Information Land transportADR Not classified as a dangerous good under transport regulations RID Not classified as a dangerous good under transport regulationsInland waterway transportADN Not classified as a dangerous good under transport regulationsSea transportIMDG Not classified as a dangerous good under transport regulationsAir transportIATA/ICAO Not classified as a dangerous good under transport regulations

15. Regulatory InformationSafety, health and environmental regulations/legislation specific for the substance or mixtureFor the user of this plant-protective product applies: ‚To avoid risks to man and the environment, comply with the instructions for use.‘ (Directive 1999/45/EC, Article 10, No. 1.2)This product may be subject to the Seveco II Directive and amendments if specific treshold tonnages are exceeded. For further medical advice Doctors should contact the National Poison Information Centre at Beaumont Hospital, Dublin.Chemical Safety AssessmentAdvice on product handling can be found in sections 7 and 8

of this safety data sheet.16. Other InformationFor proper and safe use of this product, please refer to the approval conditions laid down on the product label.Full text of the classifications, including the indication of danger, the hazard symbols, the R phrases, and the hazard statements, if mentioned in section 2 or 3:N Dangerous for the environment.51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Aquatic Chronic Hazardous to the aquatic environment - chronicH411 Toxic to aquatic life with long lasting effects.The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product‘s properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.

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