reservoir characterization of coals in the powder river ... that on average one injection well was...

1
mD 16m 800m N 48 44 39 34 29 25 20 15 10 6 1 mD 48 44 39 34 29 25 20 15 10 6 1 152 138 123 109 94 80 65 51 36 21 mD a) b) c) 7 Reservoir Characterization of Coals in the Powder River Basin, Wyoming, USA, to Test the Feasibility of CO 2 Sequestration Hannah E. Ross 1* and Mark D. Zoback 1 1 Department of Geophysics, Stanford University, Stanford, CA 94305-2215, *[email protected] The aim of this study is to investigate the feasibility of sequestering CO 2 in unmineable coalbeds of the Powder River Basin (PRB), Wyoming, through geomechanical and geologic reservoir characterization and simulations. We are particularly interested in whether hydraulically fracturing the coal will increase injectivity and improve sequestration capacity, and whether enhanced coalbed methane recovery (ECBM) will offset the cost of sequestration. We found that gravity and buoyancy were the major driving forces behind gas flow within the coal, and that coal matrix swelling resulted in a slight reduction in injectivity. However, hydraulically fracturing the coal close to its base helped mitigate the negative effect of permeability reduction on injection rate. Our simulations show that after 6 years of CO 2 injection, ~95% of the total CO 2 injected into the Big George coal would be sequestered and that CH 4 production would be ~7 times greater with CO 2 injection than without. We found that on average one injection well was able to sequester ~23 kt of CO 2 a year. Based on this injection rate, it would take ~2,300 injection wells (each with a lifetime of ~6 years) to sequester the current CO 2 emissions for the State of Wyoming. Since there have already been ~15,000 CBM wells drilled in the PRB, and ~50,000 more projected to be drilled in the next decade, utilization of 2,300 wells for CO 2 sequestration is quite feasible, especially in light of the potential for significant cost recovery through enhanced methane production. Summary Reservoir Characterization Preliminary Results for CO 2 Injection and CH 4 Production 2) 3D Model Our 3D model was built in an area where Colmenares and Zoback (AAPG, in press) found horizontal hydraulic fractures. Vertical hydraulic fractures may penetrate the overlying strata creating potential leakage points for CO 2 . We used 5 PRB CBM wells to construct our model. We used the Computer Modelling Group’s ECBM simulator GEM. Cleat spacing = 10 cm. Initial reservoir pressure gradient = 7.12 kPa/m (0.315 psi/ft) (ARI, 2002). All simulations were run with and without matrix shrinkage and swelling modeling. Base case: primary production for 11 years. Injection case: injection begins at 1800 days. Simulations were run with an injector BHP constraint of 4000 kPa (580 psi). This is set below S 3 (6200 kPa (900 psi)) so no hydraulic fractures are created. Injection with hydraulic fracture case: a horizontal hydraulic fracture was placed at the base of the injection well. The hydraulic fracture has a radius of 60 m, permeability of 1000 mD, and porosity of 30%. If S 3 = S v then horizontal hydraulic fractures form Simulation Setup 0 200 400 600 800 1000 1200 1400 1600 1800 0 200 400 600 800 1000 1200 CO 2 adsorption CO 2 desorption CH 4 adsorption CH 4 desorption N 2 adsorption N 2 desorption T=22°C Gas Adsorption (SCF/Ton) Pressure (psia) CO 2 CH 4 N 2 Adsorption/Desorption Isotherms for Dry Coal 0 200 400 600 800 1000 1200 1400 1600 0 200 400 600 800 1000 1200 1400 1600 CO2, Swi=0 CO2, Swi=8.47% CH4, Swi=0 CH4, Swi=8.67% N2, Swi=0 N2, Swi=8.54% Gas Adsorption (SCF/Ton) Pressure (psia) T=22°C N 2 CH 4 CO 2 Adsorption Isotherms for Moist Coal Closed symbols = dry coal Open symbols = moist coal 0 200 400 600 800 1000 1200 1400 1600 0 200 400 600 800 1000 1200 1400 1600 1800 Pressure (psi) Depth (feet) S v P hyd S 3 Big George Coal nx dx 20 m ny dy 20 m nz 6 dz 3x4 m a n d 3x1.3 m 42 41 CBM wells in the PRB are routinely hydraulically fractured through water enhancement tests. In some areas the hydraulic fractures propagate horizontally, whereas in other areas they grow vertically (Colmenares and Zoback, AAPG, in press). 4) Adsorption Isotherms We used adsorption/desorption isotherms from lab experiments conducted on dry and moist PRB coal samples by the SUPRI-A group, Department of Petroleum Engineering, Stanford University (courtesy of A. Kovscek and T. Tang). The initial cleat permeability and porosity values came from the literature, and we used geostatistical techniques to populate our model with multiple, equiprobable cleat permeability distributions. We further constrained the cleat permeability and porosity values through history-matching the water production from CBM wells in our study area (WOGCC). 1) State of Stress a) Horizontal face cleat permeability. b) Horizontal butt cleat permeability. c) Vertical face cleat permeability. This figure shows our 3D model populated with cleat permeability values for realization 1. The heterogeneity and anisotropy in coal cleat permeability is modeled using geostatistical techniques. The horizontal face cleat permeability is higher than in the butt cleat and vertical directions (Laubrach et al., 1998). Depth to the top of the coal varies from 315-360 m. The PRB contains the fastest growing CBM play in the United States (there are currently ~15,000 CBM wells in the PRB and ~50,000 more to be drilled). Wyoming has a number of point sources for CO 2 capture, which emitted 52 megatons of CO 2 in 2000 (EPA, 2005). Wyoming has a CO 2 pipeline network, with a proposed extension to the PRB (Nummedal et al., 2003). We focused our study on the Big George Coal, part of the Wyodak-Anderson coal zone of the Paleocene Fort Union Formation. The average depth of the coal is 335 m and coal thickness varies from 14 to 62 m (Flores and Bader, 1999). Powder River Basin Big George Coal 109W 109W 108W 108W 107W 107W 106W 106W 105W 105W 104W 104W 103W 103W 42N 42N 43N 43N 44N 44N 45N 45N 46N 46N 47N 47N Big Horn Mountains Buffalo Sheridan Gillette Montana Wyoming Wyoming North Dakota South Dakota Black Hills N Douglas Casper Belle Fourche River Powder River Tongue River Existing CO 2 pipelines Possible future extension To Shute Creek Plant 0 50 100 km Coal Bed Methane Development Area Study Area Powder River Basin Location map of the Powder River Basin, Wyoming, and our study area. Our 3D model is located in the southern part of our study area. Sensitivity Analysis Injection well (inject pure CO 2 ) Production well CH 4 /CO 2 front Five Spot Pattern Total Volume of CO 2 Injected (tonne) 0 20000 40000 60000 80000 100000 120000 140000 160000 180000 Injection, no S&S Injection with hydrofrac, no S&S Injection, with S&S Injection with hydrofrac, with S&S Total Volume of CO 2 Injected Total Volume of CH 4 Produced 0 100000 200000 300000 400000 500000 600000 700000 95% of CO sequestered Injection, no S&S Injection with hydrofrac, no S&S Injection, with S&S Injection with hydrofrac, with S&S Total Volume of CH 4 Produced (MSCF) Total Volume of CO 2 Injected 0 20000 40000 60000 80000 100000 120000 140000 160000 180000 95% of CO sequestered Injection, no S&S Injection with hydrofrac, no S&S Injection, with S&S Injection with hydrofrac, with S&S Total Volume of CO 2 Injected (tonne) Total volume of CO 2 injected and total volume of CH 4 produced after 11 years. Hydraulically fracturing the coal at the base of the injection well increased the total volume of injected CO 2 by ~30%. With ECBM there was a ~7 fold increase in CH 4 production. Hydrofrac stands for hydraulic fracture and S&S stands for matrix shrinkage and swelling. ECBM Primary Production Total Volume of CH 4 Produced Total Volume of CH 4 Produced (MSCF) 0 100000 200000 300000 400000 500000 600000 700000 Primary Production Only Injection, no S&S Injection with hydrofrac, no S&S Injection, with S&S Injection with hydrofrac, with S&S Cleat spacing, cm Injector BHP, kPa Cleat compressibility, 1/kPa Young’s modulus, kPa Poisson’s ratio Volumetric strain for CH 4 Volumetric strain for CO 2 Exponent Total Volumes Injected and Produced from Sensitivity Analysis 0 50000 100000 150000 200000 250000 300000 Base Half Double Homogeneous High vert Half Double 0.1 5.0 200 in vert 3000.0 5000.0 1.00E-08 1.00E-04 0.1 8.0 Hydrostatic 1.45E-07 6.50E-06 1.45E-05 5.80E-05 8.70E-05 1.10E-04 1.380E+06 5.510E+06 0.23 0.30 0.43 CH4 0.001 CH4 0.01 CH4 0.05 CH4 0.1 CO2 0.001 CO2 0.007 CO2 0.05 CO2 0.1 1.0 2.0 4.0 0 100000 200000 300000 400000 500000 600000 700000 800000 Base Half Double Homogeneous High vert Half Double 0.1 5.0 200 in vert 3000.0 5000.0 1.00E-08 1.00E-04 0.1 8.0 Hydrostatic 1.45E-07 6.50E-06 1.45E-05 5.80E-05 8.70E-05 1.10E-04 1.380E+06 5.510E+06 0.23 0.30 0.43 CH4 0.001 CH4 0.01 CH4 0.05 CH4 0.1 CO2 0.001 CO2 0.007 CO2 0.05 CO2 0.1 1.0 2.0 4.0 Cleat porosity Cleat permeability Gas diffusion, cm 2 /s Thickness, m Pressure, kPa Total Volume of CO 2 Injected (tonne) Total Volume of CH 4 Produced (MSCF) Total volumes of CO 2 injected and CH 4 produced due to changes in the model and input parameters for the fluid flow simulations. Cleat compressibility, Young’s modulus, Poisson’s ratio, matrix volumetric strain and the exponent used to relate cleat porosity and permeability are all included in the Palmer and Mansoori (1996; 1998; GEM 2005) equation. The dark blue boxes correspond to the base case, and the values used for the parameters in the base case are listed in Table 1 of our GHGT-8 paper. All of these simulations incorporate matrix shrinkage and swelling, but no hydraulic fracture. 95% of CO 2 sequestered 100% of CO 2 sequestered 95% of CO 2 sequestered 100% of CO 2 sequestered Total volumes of CO 2 injected and CH 4 produced if injection is stopped at the first sign of CO 2 breakthrough (100% of the total CO 2 injected is sequestered), compared to the total volumes at the end of 6 years of injection, where only 95% of the total CO 2 injected is sequestered. In our simulations, the first sign of CO 2 breakthrough is at ~3,000 days, after ~3 years of injection. ECBM would still be profitable after only 3 years of CO 2 injection, with CH 4 production increasing by a factor of 5 over primary production. The CO 2 injection rate would drop to ~21 kt per year compared with ~23 kt. And the number of injection wells needed to sequester the current CO 2 emissions for the state of Wyoming would increase to ~2,500 wells, each with a lifetime of 3 years, compared to ~2,300 wells, each with a lifetime of 6 years. 3) Geostatistical Characterization and History-match of Cleat Permeability and Porosity Powder River Basin, Wyoming CO2/CH4 front 315 330 0 10 200 CO2/CH4 front Production Well Injection Well CH 4 CO 2 Coal Depth (m) CO2/CH4 front Horizontal hydraulic fracture (Modified from Colmenares and Zoback, 2004)

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mD

16m

800m

N

48443934292520151061

mD

48443934292520151061

152138123109948065513621

mD

a) b) c)

7

Reservoir Characterization of Coals in the Powder River Basin, Wyoming, USA, to Test the Feasibility of CO2 SequestrationHannah E. Ross1* and Mark D. Zoback11Department of Geophysics, Stanford University, Stanford, CA 94305-2215, *[email protected]

The aim of this study is to investigate the feasibility of sequestering CO2 in unmineable coalbeds of the Powder River Basin (PRB), Wyoming, through geomechanical and geologic reservoir characterization and simulations. We are particularly interested in whether hydraulically fracturing the coal will increase injectivity and improve sequestration capacity, and whether enhanced coalbed methane recovery (ECBM) will offset the cost of sequestration.

We found that gravity and buoyancy were the major driving forces behind gas flow within the coal, and that coal matrix swelling resulted in a slight reduction in injectivity. However, hydraulically fracturing the coal close to its base helped mitigate the negative effect of permeability reduction on injection rate.

Our simulations show that after 6 years of CO2 injection, ~95% of the total CO2 injected into the Big George coal would be sequestered and that CH4 production would be ~7 times greater with CO2 injection than without. We found that on average one injection well was able to sequester ~23 kt of CO2 a year. Based on this injection rate, it would take ~2,300 injection wells (each with a lifetime of ~6 years) to sequester the current CO2 emissions for the State of Wyoming. Since there have already been ~15,000 CBM wells drilled in the PRB, and ~50,000 more projected to be drilled in the next decade, utilization of 2,300 wells for CO2 sequestration is quite feasible, especially in light of the potential for significant cost recovery through enhanced methane production.

Summary

Reservoir Characterization Preliminary Results for CO2 Injection and CH4 Production

2) 3D ModelOur 3D model was built in an area where Colmenares and Zoback (AAPG, in press) found horizontal hydraulic fractures. Vertical hydraulic fractures may penetrate the overlying strata creating potential leakage points for CO2. We used 5 PRB CBM wells to construct our model.

We used the Computer Modelling Group’s ECBM simulator GEM.Cleat spacing = 10 cm.Initial reservoir pressure gradient = 7.12 kPa/m (0.315 psi/ft) (ARI, 2002). All simulations were run with and without matrix shrinkage and swelling modeling. Base case: primary production for 11 years.Injection case: injection begins at 1800 days. Simulations were run with an injector BHP constraint of 4000 kPa (580 psi). This is set below S3 (6200 kPa (900 psi)) so no hydraulic fractures are created.Injection with hydraulic fracture case: a horizontal hydraulic fracture was placed at the base of the injection well. The hydraulic fracture has a radius of 60 m, permeability of 1000 mD, and porosity of 30%.

If S3 = Sv then horizontal hydraulic fractures form

Simulation Setup

0

200

400

600

800

1000

1200

1400

1600

1800

0 200 400 600 800 1000 1200

CO2 adsorptionCO2 desorptionCH4 adsorptionCH4 desorptionN2 adsorptionN2 desorption

T=22°C

Gas

Ads

orpt

ion

(SC

F/To

n)

Pressure (psia)

CO2

CH4

N2

Adsorption/Desorption Isotherms for Dry Coal

0

200

400

600

800

1000

1200

1400

1600

0 200 400 600 800 1000 1200 1400 1600

CO2, Swi=0 CO2, Swi=8.47%CH4, Swi=0 CH4, Swi=8.67%N2, Swi=0 N2, Swi=8.54%

Gas

Ads

orpt

ion

(SC

F/To

n)

Pressure (psia)

T=22°C

N2

CH4

CO2

Adsorption Isotherms for Moist CoalClosed symbols = dry coalOpen symbols = moist coal

0

200

400

600

800

1000

1200

1400

1600

0 200 400 600 800 1000 1200 1400 1600 1800Pressure (psi)

Dep

th (f

eet)

SvPhyd

S3 Big George Coal

nx dx 20 m ny dy 20 m nz 6 dz 3x4 m a n d 3x1.3 m

4241

CBM wells in the PRB are routinely hydraulically fractured through water enhancement tests. In some areas the hydraulic fractures propagate horizontally, whereas in other areas they grow vertically (Colmenares and Zoback, AAPG, in press).

4) Adsorption IsothermsWe used adsorption/desorption isotherms from lab experiments conducted on dry and moist PRB coal samples by the SUPRI-A group, Department of Petroleum Engineering, Stanford University (courtesy of A. Kovscek and T. Tang).

The initial cleat permeability and porosity values came from the literature, and we used geostatistical techniques to populate our model with multiple, equiprobable cleat permeability distributions. We further constrained the cleat permeability and porosity values through history-matching the water production from CBM wells in our study area (WOGCC).

1) State of Stress

a) Horizontal face cleat permeability. b) Horizontal butt cleat permeability. c) Vertical face cleat permeability. This figure shows our 3D model populated with cleat permeability values for realization 1. The heterogeneity and anisotropy in coal cleat permeability is modeled using geostatistical techniques. The horizontal face cleat permeability is higher than in the butt cleat and vertical directions (Laubrach et al., 1998). Depth to the top of the coal varies from 315-360 m.

The PRB contains the fastest growing CBM play in the United States (there are currently ~15,000 CBM wells in the PRB and ~50,000 more to be drilled).Wyoming has a number of point sources for CO2 capture, which emitted 52 megatons of CO2 in 2000 (EPA, 2005). Wyoming has a CO2 pipeline network, with a proposed extension to the PRB (Nummedal et al., 2003).

We focused our study on the Big George Coal, part of the Wyodak-Anderson coal zone of the Paleocene Fort Union Formation.The average depth of the coal is 335 m and coal thickness varies from 14 to 62 m (Flores and Bader, 1999).

Powder River Basin

Big George Coal

Source for CO2 pipelines location: http://www.corporateir.net/ireye/ir_site.zhtml?ticker=apc&script=411&layout=0&item_id=439732

109W

109W

108W

108W

107W

107W

106W

106W

105W

105W

104W

104W

103W

103W

42N 42N

43N 43N

44N 44N

45N 45N

46N 46N

47N 47N

0 50 100

km

Big Horn Mountains

Buffalo

Sheridan

Gillette

MontanaWyoming

Wyo

min

g

North Dakota

Sout

h D

akot

a

Black Hills

N

DouglasCasper

Belle F

ourch

e Rive

r

Powde

r Rive

r

Tong

ue R

iver

Existing CO2 pipelines

Possible future extension

To Shute Creek Plant

0 50 100

km

Coal Bed MethaneDevelopment Area

Study Area

Powder River Basin

Location map of the Powder River Basin, Wyoming, and our study area. Our 3D model is located in the southern part of our study area.

Sensitivity Analysis

Injection well (inject pure CO2)

Production well

CH4/CO2 front

Five Spot Pattern

Tota

l Vol

ume

of C

O2

Inje

cted

(ton

ne)

020000400006000080000

100000120000140000160000180000

Injection, no S&S

Injection withhydrofrac, no

S&S

Injection,with S&S

Injection withhydrofrac,with S&S

Total Volume of CO2 Injected

Total Volume of CH4 Produced

0

100000

200000

300000400000

500000

600000

700000

95% of CO2 sequestered100% of CO2 sequestered

Injection, no S&S

Injection withhydrofrac, no

S&S

Injection,with S&S

Injection withhydrofrac,with S&S

Tota

l Vol

ume

of C

H4

Pro

duce

d (M

SC

F)

Total Volume of CO2 Injected

020000400006000080000

100000120000140000160000180000

95% of CO2 sequestered100% of CO2 sequestered

Injection, no S&S

Injection withhydrofrac, no

S&S

Injection,with S&S

Injection withhydrofrac,with S&S

Tota

l Vol

ume

of C

O2

Inje

cted

(ton

ne)

Total volume of CO2 injected and total volume of CH4 produced after 11 years. Hydraulically fracturing the coal at the base of the injection well increased the total volume of injected CO2 by ~30%. With ECBM there was a ~7 fold increase in CH4 production. Hydrofrac stands for hydraulic fracture and S&S stands for matrix shrinkage and swelling.

ECBMPrimaryProduction

Total Volume of CH4 Produced

Tota

l Vol

ume

of C

H4

Pro

duce

d (M

SC

F)0

100000200000300000400000500000600000700000

PrimaryProduction

Only

Injection, no S&S

Injection withhydrofrac, no

S&S

Injection,with S&S

Injection withhydrofrac,with S&S

Cleat spacing,cm

InjectorBHP, kPa

Cleat compressibility,

1/kPa

Young’smodulus,

kPa

Poisson’sratio

Volumetric strain

for CH4

Volumetricstrain

for CO2

Exponent

Total Volumes Injected and Produced from Sensitivity Analysis

050000

100000150000200000250000300000

Base

Half

Double

Hom

ogeneous

High vert

Half

Double

0.1

5.0

200 in vert

3000.0

5000.0

1.00E-08

1.00E-04

0.1

8.0

Hydrostatic

1.45E-07

6.50E-06

1.45E-05

5.80E-05

8.70E-05

1.10E-04

1.380E+06

5.510E+06

0.23

0.30

0.43

CH

4 0.001

CH

4 0.01

CH

4 0.05

CH

4 0.1

CO

2 0.001

CO

2 0.007

CO

2 0.05

CO

2 0.1

1.0

2.0

4.0

0100000200000300000400000500000600000700000800000

Base

Half

Double

Hom

ogeneous

High vert

Half

Double

0.1

5.0

200 in vert

3000.0

5000.0

1.00E-08

1.00E-04

0.1

8.0

Hydrostatic

1.45E-07

6.50E-06

1.45E-05

5.80E-05

8.70E-05

1.10E-04

1.380E+06

5.510E+06

0.23

0.30

0.43

CH

4 0.001

CH

4 0.01

CH

4 0.05

CH

4 0.1

CO

2 0.001

CO

2 0.007

CO

2 0.05

CO

2 0.1

1.0

2.0

4.0

CleatporosityCleat permeability

Gas diffusion,cm2/s

Thickness, m

Pressure, kPa

Tota

l Vol

ume

of C

O2

Inje

cted

(ton

ne)

Tota

l Vol

ume

of C

H4

Pro

duce

d (M

SC

F)

Total volumes of CO2 injected and CH4 produced due to changes in the model and input parameters for the fluid flow simulations. Cleat compressibility, Young’s modulus, Poisson’s ratio, matrix volumetric strain and the exponent used to relate cleat porosity and permeability are all included in the Palmer and Mansoori (1996; 1998; GEM 2005) equation. The dark blue boxes correspond to the base case, and the values used for the parameters in the base case are listed in Table 1 of our GHGT-8 paper. All of these simulations incorporate matrix shrinkage and swelling, but no hydraulic fracture.

95% of CO2 sequestered100% of CO2 sequestered

95% of CO2 sequestered100% of CO2 sequestered

Total volumes of CO2 injected and CH4 produced if injection is stopped at the first sign of CO2 breakthrough (100% of the total CO2 injected is sequestered), compared to the total volumes at the end of 6 years of injection, where only 95% of the total CO2 injected is sequestered. In our simulations, the first sign of CO2 breakthrough is at ~3,000 days, after ~3 years of injection. ECBM would still be profitable after only 3 years of CO2 injection, with CH4 production increasing by a factor of 5 over primary production. The CO2 injection rate would drop to ~21 kt per year compared with ~23 kt. And the number of injection wells needed to sequester the current CO2 emissions for the state of Wyoming would increase to ~2,500 wells, each with a lifetime of 3 years, compared to ~2,300 wells, each with a lifetime of 6 years.

3) Geostatistical Characterization and History-match of Cleat Permeability and Porosity

Powder River Basin, Wyoming

CO2/CH4 front

315

330

0

10

200

CO2/CH4 front

Production Well Injection Well

CH4 CO2Coal

Dep

th (m

)

CO2/CH4 front

Horizontal hydraulic fracture

(Modified from Colmenares and Zoback, 2004)