reference standards

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REFERENCE STANDARDS

Single Component Solutions

*Volume is 1mL/ampul unless otherwise noted. Concentration is µg/mL unlessotherwise noted.

SSoollvveenntt ccooddee::A = acetoneACN = acetonitrileC = carbon disulfideCy = cyclohexaneD = methylene chlorideDEA = diethylamineDMSO = dimethyl sulfoxideEA = ethyl acetateH = hexane

I = isooctaneIp = isopropanolM = methanolMTBE = methyl tert-butyl etherPTM = purge & trap grade methanolT = tolueneTO = transformer oilW = water (DI)

CCoommppoouunndd SSoollvveenntt IInnddiivviidduuaallPPaacckkaaggeedd 11mmLL//aammppuull** CCAASS## CCooddee µµgg//mmLL** ccaatt..## pprriicceeacenaphthene 83-32-9 M 1,000 31267acenaphthylene 208-96-8 M 1,000 31268acetaldehyde-2,4-DNPH 1019-57-4 ACN 100 33074acetochlor 34256-82-1 M 100 33208acetochlor ESA sodium salt 187022-11-3 M 100 33092acetochlor OA 184992-44-4 M 100 33094acetone 67-64-1 PTM 5,000 30245acetone-2,4-DNPH 1567-89-1 ACN 100 33075acetonitrile 75-05-8 DMSO 2.05mg/mL 36281acetonitrile 75-05-8 PTM 1,000 30495acetophenone 98-86-2 PTM 5,000 30621acifluorfen 50594-66-6 M 1,000 32255acifluorfen methyl ester 50594-67-7 M 1,000 32256acrolein 107-02-8 PTM 5,000 30645acrolein 107-02-8 W 5,000 30646acrylamide 79-06-1 M 1,000 30494acrylonitrile 107-13-1 PTM 2,000 30246alachlor 15972-60-8 M 1,000 32204alachlor 15972-60-8 M 100 33207alachlor ESA sodium salt 142363-53-9 M 100 33096alachlor OA 171262-17-2 M 100 33099aldrin 309-00-2 M 1,000 32205allyl chloride 107-05-1 PTM 2,000 30248alprazolam 28981-97-7 PTM 1,000 340422-amino-4,6-dinitrotoluene 35572-78-2 ACN 1,000 316704-amino-2,6-dinitrotoluene 19406-51-0 ACN 1,000 31671aminomethyl phosphonic acid

(AMPA) 1066-51-9 W 100 32428ammelide 645-93-2 DEA:W 1,000 33249ammeline 645-92-1 DEA:W 1,000 33250ammonium picrate** 131-74-8 ACN 2,000 31890amobarbital 64-43-7 PTM 1,000 34028d-amphetamine 51-63-8 PTM 1,000 34020tert-amyl alcohol 75-85-4 PTM 10,000 30631tert-amyl ethyl ether (TAEE) 919-94-8 PTM 2,000 30617tert-amyl methyl ether (TAME) 994-05-8 PTM 2,000 306295-α-androstane 438-22-2 D 2,000 31065aniline 62-53-3 M 1,000 31470anthracene 120-12-7 A 1,000 31269anthracene-d10 1719-06-08 D 2,000 31037anthracene 120-12-7 ACN 100 33264antifoam agent for purge & trap N/A Neat 1mL 31822aprobarbital 77-02-1 PTM 1,000 34029Aramite 140-57-8 H 2,000 31624Aroclor 1016 12674-11-2 H 1,000 32006Aroclor 1016 12674-11-2 I 200 32064Aroclor 1016 12674-11-2 TO 500mg/kg 32076Aroclor 1016 12674-11-2 TO 50mg/kg 32075Aroclor 1221 11104-28-2 H 1,000 32007Aroclor 1221 11104-28-2 I 200 32065Aroclor 1221 11104-28-2 TO 500mg/kg 32078Aroclor 1221 11104-28-2 TO 50mg/kg 32077Aroclor 1232 11141-16-5 H 1,000 32008Aroclor 1232 11141-16-5 I 200 32066Aroclor 1232 11141-16-5 TO 500mg/kg 32080Aroclor 1232 11141-16-5 TO 50mg/kg 32079Aroclor 1242 53469-21-9 H 1,000 32009Aroclor 1242 53469-21-9 I 200 32067Aroclor 1242 53469-21-9 TO 500mg/kg 32082Aroclor 1242 53469-21-9 TO 50mg/kg 32081Aroclor 1248 12672-29-6 H 1,000 32010Aroclor 1248 12672-29-6 I 200 32068Aroclor 1248 12672-29-6 TO 500mg/kg 32084Aroclor 1248 12672-29-6 TO 50mg/kg 32083Aroclor 1254 11097-69-1 H 1,000 32011Aroclor 1254 11097-69-1 I 200 32069Aroclor 1254 11097-69-1 TO 500mg/kg 32086Aroclor 1254 11097-69-1 TO 50mg/kg 32085Aroclor 1260 11096-82-5 H 1,000 32012Aroclor 1260 11096-82-5 I 200 32070Aroclor 1260 11096-82-5 TO 500mg/kg 32088Aroclor 1260 11096-82-5 TO 50mg/kg 32087

CCoommppoouunndd SSoollvveenntt IInnddiivviidduuaallPPaacckkaaggeedd 11mmLL//aammppuull** CCAASS## CCooddee µµgg//mmLL** ccaatt..## pprriicceeAroclor 1262 37324-23-5 H 1,000 32409Aroclor 1268 11100-14-4 H 1,000 32410atrazine 1912-24-9 A 1,000 32208aviation gas 8006-69-1 PTM 2,500 30094aviation gas 8006-69-1 PTM 50,000 30207aviation gas (5mL) 8006-69-1 PTM 50,000 30208azobenzene 103-33-3 D 1,000 31496barbital 57-44-3 PTM 1,000 34030bentazon 25057-89-0 M 1,000 32257benzaldehyde 100-52-7 D 2,000 33017benzaldehyde-2,4-DNPH 1157-84-2 ACN 100 33077benzene 71-43-2 DMSO 10mg/mL 36282benzene 71-43-2 D 250 35262benzene 71-43-2 PTM 2,000 30249benzene-d6 1076-43-3 PTM 2,000 30025benzidine 92-87-5 M 1,000 31441benzo(a)anthracene 56-55-3 M 1,000 31270benzo(a)pyrene 50-32-8 A 1,000 31271benzo(b)fluoranthene 205-99-2 A 1,000 31272benzo(ghi)perylene 191-24-2 D 1,000 31273benzo(k)fluoranthene 207-08-9 A 1,000 31274benzoguanamine 91-76-9 DEA:W 1,000 33251benzoguanamine (5mL) 91-76-9 DEA:W 1,000 33252benzoic acid 65-85-0 D 2,000 31879benzoic acid 65-85-0 M 1,000 31415benzoylecgonine 519-09-5 PTM 1,000 34016benzphetamine 5411-22-3 PTM 1,000 34022benzyl benzoate 120-51-4 H 5,000 31847α-BHC 319-84-6 M 1,000 32206β-BHC 319-85-7 A 1,000 32209δ-BHC 319-86-8 M 1,000 32217γ-BHC (lindane) 58-89-9 M 1,000 32226bis(2-ethylhexyl)adipate 103-23-1 M 1,000 31449bis(2-ethylhexyl)phthalate 117-81-7 D 1,000 31420bromazepam 1812-30-2 PTM 1,000 34043bromobenzene 108-86-1 PTM 2,000 302502-bromobutanoic acid 80-58-0 MTBE 2,000 318812-bromobutyrate 3196-15-4 MTBE 2,000 318822-bromochlorobenzene 694-80-4 PTM 2,000 302284-bromochlorobenzene 106-39-8 PTM 2,000 302301-bromo-2-chloroethane 107-04-0 PTM 2,000 30469bromochloromethane 74-97-5 PTM 2,000 302252-bromo-1-chloropropane 3017-95-6 PTM 2,000 30226bromodichloromethane 75-27-4 PTM 2,000 302514-bromo-3,5-dimethylphenyl-

N-methylcarbamate (BDMC) 3766-81-2 M 100 322741-bromo-4-fluorobenzene 460-00-4 A 1,000 318544-bromofluorobenzene 460-00-4 PTM 2,000 300264-bromofluorobenzene 460-00-4 PTM 2,500 300674-bromofluorobenzene 460-00-4 PTM 5,000 300034-bromofluorobenzene 460-00-4 PTM 10,000 30082bromoform 75-25-2 PTM 2,000 30252bromomethane 74-83-9 PTM 2,000 302531-bromo-2-nitrobenzene 577-19-5 A 1,000 322792-bromopropionic acid 598-72-1 MTBE 1,000 31653butabarbital 125-40-6 PTM 1,000 34031butachlor ESA sodium salt M 100 332021,3-butadiene 106-99-0 PTM 2,000 30622butalbital 77-26-9 PTM 1,000 340321,4-butanediol 110-63-4 M 1,000 34078(s)-(-)-1,2,4-butanetriol 42890-76-6 pyridine 1,000 33024(s)-(-)-1,2,4-butanetriol (5mL) 42890-76-6 pyridine 1,000 330321-butanol 71-36-3 PTM 50,000 30474tert-butanol 75-65-0 PTM 50,000 30470tert-butanol-d9 25725-11-5 PTM 20,000 306182-butanone (MEK) 78-93-3 PTM 5,000 30254n-butyraldehyde-2,4-DNPH 1527-98-6 ACN 100 33079γ-butyrolactone (GBL) 96-48-0 ACN 1,000 34077

**Meets all DOT requirements. Available only to customers or distributors insidethe 48 contiguous United States; item may not be resold for export.

442-449_ARM_singles.qxp 11/22/2010 8:22 PM Page 443

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REFERENCE STANDARDS


*Volume is 1mL/ampul unless otherwise noted. Concentration is µg/mL unless otherwise noted.

CCoommppoouunndd SSoollvveenntt IInnddiivviidduuaallPPaacckkaaggeedd 11mmLL//aammppuull** CCAASS## CCooddee µµgg//mmLL** ccaatt..## pprriicceecaffeine 74051-80-2 W 5 31804caffeine 74051-80-2 W 25 31803caffeine 74051-80-2 W 125 31802caffeine 74051-80-2 W 250 31801caffeine 74051-80-2 W 500 31800caffeine 58-08-2 M 1,000 34084cannabidiol 13956-24-1 PTM 1,000 34011cannabinol 521-35-7 PTM 1,000 34010ε-caprolactam 105-60-2 D 2,000 31833carbazole 86-74-8 D 1,000 31836carbazole 86-74-8 M 1,000 31430carbon disulfide 75-15-0 PTM 2,000 30258carbon tetrachloride 56-23-5 DMSO 20mg/mL 36283carbon tetrachloride 56-23-5 PTM 2,000 30259chloral hydrate 302-17-0 ACN 1,000 30609chlordane (technical) 57-74-9 H 1,000 32021chlordane (technical) 57-74-9 I 5,000 32072chlordane (technical) 57-74-9 M 2,000 32016α-chlordane 5103-71-9 M 1,000 32207γ-chlordane 5566-34-7 M 1,000 32227chlordiazepoxide 438-41-5 PTM 1,000 340444-chloroaniline 106-47-8 D 2,000 31211chlorobenzene 108-90-7 DMSO 1.8mg/mL 36284chlorobenzene 108-90-7 PTM 2,000 30261chlorobenzene-d5 3114-55-4 PTM 2,000 30223chlorobenzilate 510-15-6 M 1,000 32211chloroethane 75-00-3 PTM 2,000 302632-chloroethanol 107-07-3 PTM 2,000 302642-chloroethyl vinyl ether 110-75-8 PTM 2,000 302651-chloro-2-fluorobenzene 348-51-6 PTM 2,000 300401-chloro-4-fluorobenzene 352-33-0 PTM 2,500 30066chloroform 67-66-3 DMSO 0.3mg/mL 36285chloroform 67-66-3 PTM 2,000 30266chloromethane 74-87-3 PTM 2,000 302672-chloronaphthalene 91-58-7 M 1,000 312844-chloro-3-nitrobenzotrifluoride 121-17-5 A 1,000 322821-chlorooctadecane 3386-33-2 D 10,000 310981-chlorooctane 111-85-3 PTM 10,000 30084chloroprene 126-99-8 PTM 5,000 30238chlorpyrifos 2921-88-2 M 1,000 32212chrysene 218-01-9 A 1,000 31275clobazam 22316-47-8 PTM 1,000 34045clonazepam 1622-61-3 PTM 1,000 34046cocaethylene 529-38-4 ACN 1,000 34066cocaine 53-21-4 PTM 1,000 34015codeine 76-57-3 PTM 1,000 34000continine 486-56-6 M 1,000 34086creosote oil 8001-58-9 D 50,000 31838crotonaldehyde-2,4-DNPH 1527-96-4 ACN 100 33080cyanazine 21725-46-2 A 1,000 32215cyanuric acid 108-80-5 DEA:W 1,000 33248cyclohexane 110-82-7 DMSO 19.4mg/mL 36286

CCoommppoouunndd SSoollvveenntt IInnddiivviidduuaallPPaacckkaaggeedd 11mmLL//aammppuull** CCAASS## CCooddee µµgg//mmLL** ccaatt..## pprriiccee2,4-D

(2,4-dichlorophenylacetic acid) 94-75-7 M 1,000 322392,4-D methyl ester 1928-38-7 M 1,000 32240Dacthal (DCPA dimethyl ester) 1861-32-1 M 1,000 32216dalapon 75-99-0 ACN 1,000 32432dalapon 75-99-0 M 1,000 32253dalapon 75-99-0 M 2,000 32056dalapon methyl ester 17640-02-7 H 2,000 32057dalapon methyl ester 17640-02-7 M 1,000 322542,4-DB 94-82-6 M 1,000 32241DCPA diacid 2136-79-0 M 200 322612,4'-DDD 53-19-0 M 1,000 320984,4'-DDD 72-54-8 M 1,000 322012,4'-DDE 3424-82-6 M 1,000 320994,4'-DDE 72-55-9 M 1,000 322022,4'-DDT 789-02-6 M 1,000 322004,4'-DDT 50-29-3 M 1,000 32203decachlorobiphenyl (BZ #209) 2051-24-3 A 200 32029decachlorobiphenyl (BZ #209) 2051-24-3 I 10 32289decachlorobiphenyl

(BZ #209) (5mL) 2051-24-3 A 200 32030decafluorobiphenyl 434-90-2 A 1,000 31855decafluorobiphenyl 434-90-2 D 2,000 31041decafluorobiphenyl 434-90-2 ACN 1,000 31842decafluorotriphenylphosphine

(DFTPP) 5074-71-5 D 2,500 31001n-decane 124-18-5 Neat 1mL 31858desethyl-atrazine 6190-65-4 A 1,000 32445desisopropylatrazine 1007-28-9 A 1,000 32446dextromethorphan HBr

monohydrate 125-69-9 M 1,000 34081dextro-propoxyphene 1639-60-7 PTM 1,000 34008diazepam 439-14-5 PTM 1,000 34047dibenzo(a,h)anthracene 53-70-3 D 1,000 312764,4'-dibromobiphenyl 92-86-4 D 2,000 310394,4'-dibromobiphenyl 92-86-4 EA 500 32092dibromochloromethane

(chlorodibromochloromethane) 124-48-1 PTM 2,000 302711,2-dibromo-3-chloropropane

(DBCP) 96-12-8 PTM 2,000 302701,2-dibromoethane 106-93-4 PTM 2,000 30272dibromofluoromethane 1868-53-7 Neat 100mg 30634dibromomethane 74-95-3 PTM 2,000 304304,4'-dibromooctafluorobiphenyl 10386-84-2 D 2,000 310404,4'-dibromooctafluorobiphenyl 10386-84-2 H 250 320534,4'-dibromooctafluorobiphenyl 10386-84-2 MTBE 2,000 318562,3-dibromopropionic acid 600-05-5 MTBE 1,000 316552,5-dibromotoluene 615-59-8 PTM 1,000 304352,5-dibromotoluene 615-59-8 PTM 10,000 30453dibutylchlorendate 1770-80-5 A 200 32025dicamba 1918-00-9 M 1,000 32247dicamba methyl ester 6597-78-0 M 1,000 32248

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REFERENCE STANDARDS



CCoommppoouunndd SSoollvveenntt IInnddiivviidduuaallPPaacckkaaggeedd 11mmLL//aammppuull** CCAASS## CCooddee µµgg//mmLL** ccaatt..## pprriiccee1,2-dichlorobenzene 95-50-1 M 1,000 314421,3-dichlorobenzene 541-73-1 M 1,000 314431,4-dichlorobenzene 106-46-7 ACN 1,000 304981,4-dichlorobenzene 106-46-7 M 1,000 314441,2-dichlorobenzene-d4 2199-69-1 PTM 2,000 300493,3'-dichlorobenzidine 91-94-1 D 2,000 318353,3'-dichlorobenzidine 91-94-1 M 2,000 310263,5-dichlorobenzoic acid 51-36-5 MTBE 1,000 316523,5-dichlorobenzoic acid

methyl ester 2905-67-1 M 1,000 322643,5-dichlorobenzoic acid

methyl ester 2905-67-1 MTBE 1,000 316491,4-dichlorobutane 110-56-5 PTM 2,000 30227trans-1,4-dichloro-2-butene 110-57-6 PTM 2,000 30274dichlorodifluoromethane

(CFC-12) 75-71-8 PTM 2,000 302751,1-dichloroethane 75-34-3 PTM 2,000 302761,2-dichloroethane 107-06-2 DMSO 25mg/mL 362881,2-dichloroethane 107-06-2 PTM 2,000 302771,2-dichloroethane-d4 17060-07-0 PTM 2,000 300271,1-dichloroethene 75-35-4 DMSO 40mg/mL 362871,1-dichloroethene 75-35-4 PTM 2,000 30278cis-1,2-dichloroethene 156-59-2 PTM 2,000 30279trans-1,2-dichloroethene 156-60-5 PTM 2,000 30280cis-1,2-dichloroethylene 156-59-2 DMSO 4.67mg/mL 36289trans-1,2-dichloroethylene 156-60-5 DMSO 4.67mg/mL 362902,6-dichlorophenol 87-65-0 M 1,000 314092,4-dichlorophenylacetic acid 19719-28-9 M 200 320492,4-dichlorophenylacetic acid 19719-28-9 A 1,000 324392,4-dichlorophenyl acetic acid

methyl ester 55954-23-9 H 200 320501,2-dichloropropane 78-87-5 PTM 2,000 302812,2-dichloropropane 594-20-7 PTM 2,000 30283cis-1,3-dichloropropene 10061-01-5 PTM 2,000 30284trans-1,3-dichloropropene 10061-02-6 PTM 2,000 302852,3-dichloropropionic acid 565-64-0 MTBE 1,000 316502,3-dichloropropionic acid

methyl ester 3674-09-7 MTBE 1,000 316511,2-dichlorotetrafluoroethane

(CFC-114) 76-14-2 PTM 2,000 30476dichlorprop 120-36-5 M 1,000 32249dichlorprop methyl ester 57153-17-0 M 1,000 32250dieldrin 60-57-1 M 1,000 32218diesel fuel #2 composite 68334-30-5 D 5,000 31093diesel fuel #2 composite 68334-30-5 D 50,000 31258diesel fuel #2 composite (5mL) 68334-30-5 D 50,000 31259diesel fuel #2: 25% weathered 68334-30-5 D 5,000 31234diesel fuel #2: 50% weathered 68334-30-5 D 5,000 31235diesel fuel #2: 75% weathered 68334-30-5 D 5,000 31236diesel fuel #2: unweathered 68334-30-5 D 5,000 31233diesel/biodiesel 80:20 67784-80-9 D 5,000 31880diethyl ether (ethyl ether) 60-29-7 PTM 2,000 302861,4-difluorobenzene 540-36-3 PTM 2,000 30032diisopropyl ether (DIPE) 108-20-3 PTM 2,000 30627dimethachlor ESA sodium salt M 100 33203

CCoommppoouunndd SSoollvveenntt IInnddiivviidduuaallPPaacckkaaggeedd 11mmLL//aammppuull** CCAASS## CCooddee µµgg//mmLL** ccaatt..## pprriiccee1,2-dimethoxyethane 173201-80-4 DMSO 0.5mg/mL 36291N,N-dimethylacetamide 127-19-5 DMSO 5.45mg/mL 36292dimethyldichlorosilane

(DMDCS) (20mL) 75-78-5 Neat 20mL 31840N,N-dimethylformamide 68-12-2 DMSO 4.4mg/mL 362933,5-dinitroaniline 618-87-1 ACN 1,000 316611,2-dinitrobenzene 528-29-0 M 1,000 314531,3-dinitrobenzene 99-65-0 ACN 1,000 316621,4-dinitrobenzene 100-25-4 ACN 2,000 332052,4-dinitrophenol 51-28-5 M 1,000 312912,4-dinitrotoluene 121-14-2 ACN 1,000 316632,6-dinitrotoluene 606-20-2 ACN 1,000 316643,4-dinitrotoluene 610-39-9 EA 2,000 339013,4-dinitrotoluene 610-39-9 M 1,000 31452di-n-octyl phthalate 117-84-0 M 1,000 31426dinoseb 88-85-7 M 1,000 32251dinoseb methyl ether 6099-79-2 M 1,000 32252diolein (1,3-di[cis-octadecenoyl]

glycerol) 2465-32-9 pyridine 5,000 330221,4-dioxane 123-91-1 DMSO 1.9mg/mL 362941,4-dioxane 123-91-1 D 2,000 318531,4-dioxane 123-91-1 PTM 2,000 302871,4-dioxane-d8 17647-74-4 PTM 2,000 306141,2-diphenylhydrazine 122-66-7 M 1,000 31497diuron 330-54-1 ACN 200 32450ecgonine 5796-31-6 PTM 1,000 34017ecgonine methyl ester 38969-40-3 PTM 1,000 34018EDDP perchlorate 66729-78-0 M 1,000 34069EGDN** 628-96-6 M 1,000 31601endosulfan I 959-98-8 M 1,000 32221endosulfan II 33213-65-9 M 1,000 32222endosulfan sulfate 1031-07-8 M 1,000 32223endrin 72-20-8 M 1,000 32219endrin aldehyde 7421-93-4 M 1,000 32224endrin ketone 53494-70-5 M 1,000 32220ethanol 64-17-5 PTM 2,000 30288ethanol 64-17-5 W 10,000 304662-ethoxyethanol 110-80-5 DMSO 0.8mg/mL 36295ethylbenzene 100-41-4 DMSO 1.84mg/mL 36296ethylbenzene 100-41-4 PTM 2,000 30290ethylbenzene-d10 25837-05-2 PTM 2,000 30029ethylbenzene-d5 20302-26-5 PTM 2,000 30028ethyl-tert-butyl ether (ETBE) 637-92-3 PTM 2,000 30628ethylenediamine 107-15-3 M 540 35222ethylene glycol 3775-85-7 DMSO 3.1mg/mL 36297ethylene oxide 75-21-8 DMSO 500 36005ethyl methacrylate 97-63-2 PTM 2,000 30289fentanyl 437-38-7 M 1,000 34082nor-fentanyl oxalate 1609-66-1 M 1,000 34083

**Meets all DOT requirements. Available only to customers or distributors inside the 48 contiguous United States; item may not be resold for export.



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CCoommppoouunndd SSoollvveenntt IInnddiivviidduuaallPPaacckkaaggeedd 11mmLL//aammppuull** CCAASS## CCooddee µµgg//mmLL** ccaatt..## pprriicceeflunitrazepam 1622-62-4 PTM 1,000 34049fluoranthene 206-44-0 M 1,000 31277fluorene 86-73-7 M 1,000 31278fluorobenzene 462-06-6 PTM 2,000 300302-fluorobiphenyl 321-60-8 D 2,000 310912-fluorobiphenyl 321-60-8 D 10,000 310961-fluoronaphthalene 321-38-0 D 2,000 310922-fluorophenol 367-12-4 D 2,000 31047flurazepam 1172-18-5 PTM 1,000 34050formaldehyde-DNPH 1081-15-8 ACN 500 31837formaldehyde-2,4-DNPH 1081-15-8 ACN 100 33082formaldehyde oxazoladine T 2,000 33004formamide 75-12-7 DMSO 1.1mg/mL 36298fuel oil # 4 68476-31-3 D 5,000 31216fuel oil # 4 68476-31-3 D 50,000 31244fuel oil # 5 70892-11-4 D 5,000 31217fuel oil # 5 70892-11-4 D 50,000 31246fuel oil # 6 68553-00-4 D 5,000 31218fuel oil # 6 68553-00-4 D 50,000 31248fuel oil # 6 (5mL) 68553-00-4 D 50,000 31249DL-glutethimide 18389-24-7 PTM 1,000 34058glycerin 56-81-5 pyridine 500 33020glycolaldehyde-2,4-DNPH ACN 100 33091glyphosate 1071-83-6 W 1,000 32426glyphosate (5mL) 1071-83-6 W 1,000 324271,6-HDIP 72375-27-0 DMSO 1,000 33002heptachlor 76-44-8 M 1,000 32228heptachlor epoxide (isomer B) 1024-57-3 M 1,000 322302,2',3,4,4',5,5'-heptachlorobiphenyl

(BZ #180) 35065-29-3 I 10 32288hexachlorobenzene 118-74-1 A 1,000 322312,2',3,4,4',5'-hexachlorobiphenyl

(BZ #138) 35065-28-2 I 10 322862,2',4,4',5,5'-hexachlorobiphenyl

(BZ #153) 35065-27-1 I 10 32287hexachloro-1,3-butadiene 87-68-3 M 1,000 31435hexachlorocyclopentadiene 77-47-4 M 1,000 32232hexachloroethane 67-72-1 M 1,000 31436hexachlorophene 70-30-4 D 2,000 31811hexaldehyde-2,4-DNPH 1527-97-5 ACN 100 33083hexane 8031-34-3 DMSO 1.45mg/mL 36299hexobarbital 56-29-1 PTM 1,000 34033hexyl 2-ethylhexyl phthalate 75673-16-4 H:A 1,000 33228HMX** 2691-41-0 ACN 1,000 31665hydraulic oil 64741-89-5 D 50,000 31839hydrocodone 34195-34-1 PTM 1,000 34002hydromorphone 71-68-1 PTM 1,000 34063indeno(1,2,3-cd)pyrene 193-39-5 D 1,000 31279iodomethane 74-88-4 PTM 2,000 30292isobutyl alcohol 78-83-1 PTM 2,000 30293isobutylbenzene M 1,000 30613isobutyraldehyde-2,4-DNPH 2057-82-1 ACN 100 33084isopropylbenzene 98-82-8 PTM 2,000 30294jet fuel A 64742-47-8 D 5,000 31215jet fuel A 64742-47-8 D 50,000 31242jet fuel A (5mL) 64742-47-8 D 50,000 31243JP-4 military fuel 8008-20-6 D 5,000 31219JP-4 military fuel 8008-20-6 D 50,000 31250JP-4 military fuel 8008-20-6 PTM 50,000 30472

CCoommppoouunndd SSoollvveenntt IInnddiivviidduuaallPPaacckkaaggeedd 11mmLL//aammppuull** CCAASS## CCooddee µµgg//mmLL** ccaatt..## pprriicceeJP-5 military fuel 8008-20-6 D 5,000 31220JP-5 military fuel 8008-20-6 D 50,000 31252JP-8 military fuel 8008-20-6 D 5,000 31262JP-8 military fuel 8008-20-6 D 50,000 31254kerosene composite 84742-81-0 D 5,000 31094kerosene composite 84742-81-0 D 50,000 31256kerosene composite (5mL) 84742-81-0 D 50,000 31257kerosene: 25% weathered 84742-81-0 D 5,000 31230kerosene: 50% weathered 84742-81-0 D 5,000 31231kerosene: 75% weathered 84742-81-0 D 5,000 31232kerosene: unweathered 84742-81-0 D 5,000 31229levorphanol 5985-38-6 PTM 1,000 34003lorazepam 846-49-1 PTM 1,000 34051MCPA 94-74-6 M 1,000 32269MCPP 93-65-2 M 1,000 322713,4-MDA HCl 4764-17-4 M 1,000 340703,4-MDEA HCl 82801-81-8 M 1,000 340724,4'-MDIP 72375-24-7 DMSO 1,000 330033,4-MDMA HCl 42542-10-9 M 1,000 34071melamine 108-78-1 DEA:W 1,000 33247meperidine 50-13-5 PTM 1,000 34004mephobarbital 115-38-8 PTM 1,000 34034meprobamate 57-53-4 PTM 1,000 34059methacrolein-2,4-DNPH 5077-73-6 ACN 100 33095methacrylonitrile 126-98-7 PTM 2,000 30297methadone 1095-90-5 PTM 1,000 34005(+)methamphetamine 51-57-0 PTM 1,000 34021methanol 67-56-1 DMSO 15mg/mL 36401methanol 67-56-1 W 10,000 30467methaqualone 340-56-7 PTM 1,000 34064methohexital 151-83-7 PTM 1,000 34035methoxychlor 72-43-5 M 1,000 322332-methoxyethanol 109-86-4 DMSO 0.25mg/mL 364021-(methylamino)anthraquinone 82-38-3 D 100 31823methyl arachidate 1120-28-1 Neat 35056methyl arachidonate 2566-89-4 Neat 35060methyl behenate 929-77-1 Neat 35062methyl 2-bromopropionate 5445-17-0 MTBE 1,000 31654methyl tert-butyl ether (MTBE) 1634-04-4 PTM 2,000 30402methylbutylketone 591-78-6 DMSO 0.25mg/mL 36400methyl caprate 110-42-9 Neat 35041methyl caproate 106-70-7 Neat 35037methyl caprylate 111-11-5 Neat 35039methylcyclohexane 108-87-2 DMSO 5.9mg/mL 36403methyl-2,3-dibromopropionate 1729-67-5 MTBE 1,000 316562-methyl-4,6-dinitrophenol 534-52-1 M 1,000 31292methyl eicosadienoate 2463-02-7 Neat 35058methyl eicosatrienoate 55682-88-7 Neat 35059methyl eicosenoate 2390-09-2 Neat 35057methyl erucate 1120-34-9 Neat 35063methyl heneicosanoate 6064-90-0 Neat 35061methyl heptadecanoate 1731-92-6 Neat 35050methyl heptanoate 106-73-0 Neat 35038


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REFERENCE STANDARDS


*Volume is 1mL/ampul unless otherwise noted. Concentration is µg/mL unlessotherwise noted.

CCoommppoouunndd SSoollvveenntt IInnddiivviidduuaallPPaacckkaaggeedd 11mmLL//aammppuull** CCAASS## CCooddee µµgg//mmLL** ccaatt..## pprriicceemethyl laurate 111-82-0 Neat 35043methyl lignocerate 2442-49-1 Neat 35064methyl linoleate 112-63-0 Neat 35053methyl linolenate 301-00-8 Neat 35054methyl methacrylate 80-62-6 PTM 2,000 30299methyl myristate 124-10-7 Neat 35045methyl myristoleate 56219-06-8 Neat 350461-methylnaphthalene 90-12-0 M 1,000 312832-methylnaphthalene 91-57-6 D 1,000 31285methyl nervonate 2733-88-2 Neat 350652-methyl-4-nitroaniline 99-55-8 M 1,000 31612methyl nonadecanoate 1731-94-8 Neat 350552-methylnonane D 1,000 31870methyl nonanoate 1731-84-6 Neat 35040methyl oleate 112-62-9 Neat 35052methyl palmitate 112-39-0 Neat 35048methyl palmitoleate 1120-25-8 Neat 35049methyl pentadecanoate 7132-64-1 Neat 350474-methyl-2-pentanone (MIBK) 108-10-1 PTM 5,000 304003-methylphenol 108-39-4 M 1,000 31403N-methylpyrrolidone 872-50-4 DMSO 2.65mg/mL 36405methyl stearate 112-61-8 Neat 35051methyl tridecanoate 1731-88-0 Neat 35044methyl undecanoate 1731-86-8 Neat 35042α-methylene-γ-butyrolactone

(AMGBL) 547-65-9 ACN 1,000 34079methylene chloride

(dichloromethane) 75-09-2 DMSO 3mg/mL 36404methylene chloride

(dichloromethane) 75-09-2 PTM 2,000 30401methyprylon 125-64-4 PTM 1,000 34060metolachlor 51218-45-2 M 100 33209metolachlor ESA sodium salt 171118-09-5 M 100 33200metolachlor OA 152019-73-3 M 100 33201metribuzin 21087-64-9 A 1,000 32436mineral spirits: 25% weathered 8030-30-6 D 5,000 31226mineral spirits: 50% weathered 8030-30-6 D 5,000 31227mineral spirits: 75% weathered 8030-30-6 D 5,000 31228mineral spirits: unweathered 8030-30-6 D 5,000 31225mineral spirits: unweathered 8030-30-6 D 50,000 31260mineral spirits: unweathered

(5mL) 8030-30-6 D 50,000 31261monolein (1-mono[cis-9-octadecenoyl]-

rac-glycerol) 111-03-5 pyridine 5,000 33021monopalmitin 524-44-9 pyridine 5,000 33026morphine 6211-15-0 PTM 1,000 34006motor oil composite 64742-47-8 D 50,000 31464naphthalene 91-20-3 M 1,000 31280naphthalene-d8 1146-65-2 D 2,000 31043nicarbazin (bis-nitrophenol urea) 330-95-0 ACN 10 33261nicotine 54-11-5 M 1,000 34085nitrazepam 146-22-5 PTM 1,000 34053nitrobenzene 99-95-3 ACN 1,000 31657nitrobenzene-d5 4165-60-0 D 2,000 31044nitroglycerin** 55-63-0 M 1,000 31498nitroguanidine** 556-88-7 M 1,000 316022-nitromesitylene 603-71-4 M 2,000 33902nitromethane 75-52-5 DMSO 0.25mg/mL 364064-nitrophenol 100-02-7 M 1,000 312962-nitropropane 79-46-9 PTM 2,000 30403N-nitrosodimethylamine 62-75-9 M 1,000 31427N-nitrosodimethylamine-d6 17829-05-9 D 1,000 33910N-nitrosodiphenylamine 86-30-6 M 1,000 31429N-nitroso-di-n-propylamine 621-64-7 M 1,000 31428N-nitrosodi-n-propylamine-d14 93951-96-3 D 1,000 33911

CCoommppoouunndd SSoollvveenntt IInnddiivviidduuaallPPaacckkaaggeedd 11mmLL//aammppuull** CCAASS## CCooddee µµgg//mmLL** ccaatt..## pprriiccee2-nitrotoluene 88-72-2 ACN 1,000 316593-nitrotoluene 99-08-1 ACN 1,000 316604-nitrotoluene 99-99-0 ACN 1,000 31658n-nonatriacontane (C39) 7194-86-7 C 3,000 31456n-nonatriacontane (C39) (10mL) 7194-86-7 C 3,000 31877n-octacosane (C28) 630-02-4 D 10,000 31672oxazepam 604-75-1 PTM 1,000 34054oxycodone 124-90-3 PTM 1,000 34007oxymorphone 76-41-5 PTM 1,000 34065PCB 18 (5mL) 37680-65-2 ACN 50 33255PCB 28 (5mL) 7012-37-5 ACN 50 33256PCB 52 (5mL) 35693-99-3 ACN 50 33257PCB 138 (5mL) 35065-28-2 ACN 50 33262PCB 153 (5mL) 35065-27-1 ACN 50 33263pentachloroanisole 1825-21-4 M 1,000 322682,2',4,5,5'-pentachlorobiphenyl

(BZ #101) 37680-73-2 I 10 322852,3',4,4',5-pentachlorobiphenyl

(BZ #118) 31508-00-6 I 10 32293pentachloroethane 76-01-7 PTM 2,000 30404pentachloronitrobenzene 82-68-8 EA 100 32091pentachlorophenol 87-86-5 M 1,000 31297n-pentacontane (C50) 6596-40-3 T 10 31685pentacosane (C25) 629-99-2 D 10,000 31487pentafluorobenzene 363-72-4 PTM 2,000 30031pentafluorophenol 771-61-9 D 2,000 31048pentazocine 64024-15-3 PTM 1,000 34062pentobarbital 76-74-4 PTM 1,000 34036perfluorotributylamine (PFTBA) 311-89-7 Neat 1mL 30482perfluorotributylamine (PFTBA) 311-89-7 Neat 1g 33027PETN

(pentaerythritol tetranitrate)** 78-11-5 M 1,000 31600phenanthrene 85-01-8 M 1,000 31281phenanthrene-d10 1517-22-2 D 2,000 31045phencyclidine 956-90-1 PTM 1,000 34027phendimetrazine 50-58-8 PTM 1,000 34025phenmetrazine 1707-14-8 PTM 1,000 34026phenobarbital 50-06-6 PTM 1,000 34037phenol 108-95-2 M 1,000 31298phenol-d6 13127-88-3 D 2,000 31049phentermine 1197-21-3 PTM 1,000 34024phenylpropanolamine HCl 154-41-6 M 1,000 34073picloram 1918-02-1 M 1,000 32265picloram methyl ester 14143-55-6 M 1,000 32266picric acid** 88-89-1 M 1,000 31499Polywax 500 9002-88-4 Neat 1g 36224Polywax 655 9002-88-4 Neat 1g 36225Polywax 850 9002-88-4 Neat 1g 36226Polywax 1000 9002-88-4 Neat 1g 36227prazepam 2955-38-6 PTM 1,000 34055prometryne 7287-19-6 A 1,000 32449propachlor 1918-16-7 M 1,000 322352-propanol 67-63-0 W 50,000 30473propazine 139-40-2 A 1,000 32448propionaldehyde-2,4-DNPH 725-00-8 ACN 100 33086propionitrile 107-12-0 PTM 2,000 30407propylene glycol dinitrate

(PGDN) 6423-43-4 M 1,000 31821pyrene 129-00-0 M 1,000 31282pyridine 110-86-1 DMSO 1mg/mL 36407pyridine 110-86-1 PTM 2,000 30409pyridine-d5 7291-22-7 D 2,000 31046

**Meets all DOT requirements. Available only to customers or distributors insidethe 48 contiguous United States; item may not be resold for export.




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REFERENCE STANDARDS



CCoommppoouunndd SSoollvveenntt IInnddiivviidduuaallPPaacckkaaggeedd 11mmLL//aammppuull** CCAASS## CCooddee µµgg//mmLL** ccaatt..## pprriicceeRDX** 121-82-4 ACN 1,000 31666secobarbital 29071-21-4 PTM 1,000 34038simazine 122-34-9 A 1,000 32236stearyl stearate (10mL) 2778-96-3 Cy 2,000 31636stearyl stearate (10mL) 2778-96-3 H 2,000 31681stearyl stearate 2778-96-3 Neat 100mg 31860Stoddard solvent 8052-41-3 PTM 10,000 30487styrene 100-42-5 PTM 2,000 30410sulfolane 126-33-0 DMSO 0.8mg/mL 364132,4,5-T 93-76-5 M 200 322432,4,5-T methyl ester 1928-37-6 M 1,000 32244talbutal 115-44-6 PTM 1,000 340392,4-TDIP 72375-21-4 DMSO 1,000 330012,6-TDIP 195625-39-9 DMSO 1,000 33000temazepam 896-50-4 PTM 1,000 34056terbuthylazine 5915-41-3 A 1,000 32447o-terphenyl 84-15-1 A 2,000 31066o-terphenyl 84-15-1 D 10,000 31097p-terphenyl 92-94-4 D 10,000 31095p-terphenyl-d14 1718-51-0 D 1,000 31828α-terpineol 98-55-5 D 2,000 339122,2',5,5'-tetrachlorobiphenyl

(BZ #52) 35693-99-3 I 10 322841,1,1,2-tetrachloroethane 630-20-6 PTM 2,000 304111,1,2,2-tetrachloroethane 79-34-5 PTM 2,000 30412tetrachloroethene 127-18-4 PTM 2,000 304132,3,4,6-tetrachlorophenol 58-90-2 M 1,000 314022,4,5,6-tetrachloro-m-xylene 877-09-8 A 200 320272,4,5,6-tetrachloro-m-xylene (5mL) 877-09-8 A 200 32028n-tetracontane (C40) 4181-95-7 Neat 100mg 31859tetrahydrofuran (THF) 109-99-9 DMSO 3.6mg/mL 36408tetrahydrofuran (THF) 109-99-9 PTM 2,000 30414tetralin 119-64-2 DMSO 0.5mg/mL 36409tetrapentyltin 3765-65-9 D 2,000 31475tetra-n-propyltin 2176-98-9 D 2,000 31474tetryl** 479-45-8 ACN 1,000 31667Δ9-THC 1972-08-3 M 1,000 34067(±)11-nor-9-carboxy-Δ9-THC 104874-50-2 M 100 34068thebaine 115-37-7 PTM 1,000 34009thiopental 71-73-8 PTM 1,000 34041Tinuvin P 2440-22-4 Ip 51.8 31629toluene 108-88-3 DMSO 4.45mg/mL 36410toluene 108-88-3 PTM 2,000 30415toluene-d8 2037-26-5 PTM 2,000 30224toxaphene 8001-35-2 H 1,000 32005toxaphene 8001-35-2 I 5,000 32071toxaphene 8001-35-2 M 2,000 320152,4,5-TP (Silvex) 93-72-1 M 1,000 322452,4,5-TP (Silvex) methyl ester 4841-20-7 M 1,000 32246transformer oil (PCB-free) 64742-53-6 Neat 50mL 32425transformer oil (PCB-free) 64742-53-6 Neat 5mL 32424n-triacontane-d62 (C30) 638-68-6 D 500 31816triazolam 28911-01-5 PTM 1,000 340572,4,6-tribromophenol 118-79-6 M 1,000 31401tributylphosphate 126-73-8 A 1,000 32280tributyltin chloride 1461-22-9 D 2,000 31478tricaprin

(1,2,3-tricaprinoylglycerol) 621-71-6 pyridine 8,000 33025tricaprin

(1,2,3-tricaprinoylglycerol) (5mL) 621-71-6 pyridine 8,000 33033

CCoommppoouunndd SSoollvveenntt IInnddiivviidduuaallPPaacckkaaggeedd 11mmLL//aammppuull** CCAASS## CCooddee µµgg//mmLL** ccaatt..## pprriiccee1,2,3-trichlorobenzene 87-61-6 PTM 2,000 304161,2,4-trichlorobenzene 120-82-1 M 1,000 314392,4,4'-trichlorobiphenyl (BZ #28) 7012-37-5 I 10 322831,1,1-trichloroethane 71-55-6 DMSO 50mg/mL 364111,1,1-trichloroethane 71-55-6 PTM 2,000 304181,1,2-trichloroethane 79-00-5 PTM 2,000 30419trichloroethene 79-01-6 DMSO 0.4mg/mL 36412trichloroethene 79-01-6 PTM 2,000 30420trichlorofluoromethane (CFC-11) 75-69-4 PTM 2,000 304212,4,5-trichlorophenol 95-95-4 A 1,000 320172,4,5-trichlorophenol 95-95-4 M 1,000 312992,4,6-trichlorophenol 88-06-2 M 1,000 314001,2,3-trichloropropane 96-18-4 MTBE 1,000 316481,2,3-trichloropropane 96-18-4 PTM 2,000 304291,1,2-trichlorotrifluoroethane

(CFC-113) 76-13-1 PTM 2,000 30462α,α,α-trifluorotoluene 98-08-8 PTM 2,000 30048α,α,α-trifluorotoluene 98-08-8 PTM 2,500 30068α,α,α-trifluorotoluene 98-08-8 PTM 10,000 30083trifluralin 1582-09-8 M 1,000 322381,2,4-trimethylbenzene 95-63-6 PTM 2,000 304221,3,5-trimethylbenzene 108-67-8 PTM 2,000 304231,2,4-trimethyl-5-nitrobenzene 610-91-3 M 2,000 339032,2,4-trimethylpentane (isooctane) 540-84-1 nonane 5% vol/vol 306711,3,5-trinitrobenzene** 99-35-4 ACN 1,000 316682,4,6-trinitrotoluene** 118-96-7 ACN 1,000 31669triolein (1,2,3-Tri[cis-octadecenoyl]

glycerol) 122-32-7 pyridine 5,000 33023tripentyltin chloride 3342-67-4 D 2,000 31477triphenylmethane (5mL) 519-73-3 ACN 10 33260triphenylphosphate 115-86-6 A 1,000 32281triphenylphosphate (5mL) 115-86-6 ACN 20 33258tri-n-propyltin chloride 995-25-5 D 2,000 31476tris(1,3-dichloroisopropyl)

phosphate (5mL) 13674-87-8 ACN 50 33259n-undecane (C11) D 1,000 30612unleaded gasoline composite 8006-61-9 PTM 2,500 30081unleaded gasoline composite 8006-61-9 PTM 50,000 30205unleaded gasoline composite

(5mL) 8006-61-9 PTM 50,000 30206unleaded gasoline:

25% weathered 8006-61-9 PTM 5,000 30097unleaded gasoline:




unweathered 8006-61-9 PTM 5,000 30096used motor oil composite 64742-65-0 D 50,000 31465γ-valerolactone 108-29-2 ACN 1,000 34080vinyl acetate 108-05-4 PTM 2,000 30216vinyl chloride 75-01-4 PTM 2,000 30089vinyl chloride 75-01-4 PTM 2,500 30093m-xylene 108-38-3 DMSO 6.51mg/mL 36414m-xylene 108-38-3 PTM 2,000 30424o-xylene 95-47-6 DMSO 0.97mg/mL 36415o-xylene 95-47-6 PTM 2,000 30425p-xylene 106-42-3 DMSO 1.52mg/mL 36416p-xylene 106-42-3 PTM 2,000 30426


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REFERENCE STANDARDS

ENVIRONMENTAL MATERIALS500 Series Drinking Water Analyses . . . . . . . . . . . . . . . .451-463

600 Series Wastewater Analyses . . . . . . . . . . . . . . . . . . . .464-469

Method 418.1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .470

Method 1311 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .470

Method 1664 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .470

Method 3500 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .470

8000 Series Solid Waste Analyses . . . . . . . . . . . . . . . . . . .471-485

Contract Lab Program . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .486-495

PCBs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .495-496

Organotins . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .496

Minnesota Dept. of Agriculture Pesticides . . . . . . . . . . . . . . .497

International Environmental Mixes . . . . . . . . . . . . . . . . .498-500

Underground Storage Tank Monitoring . . . . . . . . . . . .501-512

ASTM Methods . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .513E1387 and E1618 (Fire Debris Analysis); 5197 (Formaldehyde andOther Carbonyl Compounds in Air); D5836-03/OSHA 42, OSHA 47, NIOSH 5522 (Analysis of Isocyanates in Indoor Air by HPLC)

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REFERENCE STANDARDS | ENVIRONMENTAL MATERIALS

500 Series Methods

UUSS EEPPAA MMeetthhoodd NNoo.. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. ..CCoommppoouunndd CCllaassss

501.1, 501.2, 501.3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Trihalomethanes

502.1, 502.2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Volatile Halogenated Organics

504.1 . . . . . . . . . . . . . . . . . . . . . . . .Ethylene Dibromide/Dibromochloropropane

505 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Organohalide Pesticides & PCBs

506 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Phthalate & Adipate Esters

507 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Nitrogen & Phosphorus Pesticides

508, 508.1, 508A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Chlorinated Pesticides

515, 515.4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Chlorinated Acid Herbicides

521 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Nitrosamines

524.1, 524.2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Volatile Organics

525, 525.1, 525.2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Semivolatile Organics

526 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Semivolatile Organics

UUSS EEPPAA MMeetthhoodd NNoo.. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. ..CCoommppoouunndd CCllaassss

527 . . . . . . . . . . . . . . . . . . . . . . . . . . . .Pesticides & Flame Retardants (GC/MS)

528 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Phenols

529 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Nitroaromatics & Nitramines

531.1, 531.2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Carbamates

532 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Phenylurea Pesticides

535 . . . . . . . . . . . . . . . . . . . . . . . . . . . .Chloroacetanilide Herbicide Degradates

547 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Glyphosate

549.2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Paraquat/Diquat

551.1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Chlorinated Pesticides & Herbicides

552, 552.1, 552.2, 552.3 . . . . . . . . . . . . . . . . . . . .Haloacetic Acids and Dalapon

555 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Chlorinated Acids

— . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Drinking Water Odor Standard

500 Series Methods - US EPA Safe Drinking Water Act (SDWA)

Method 501.1, 501.2, 501.3 (Trihalomethanes)

chlorobenzene1,2-dichlorobenzenecis-1,2-dichloroethenetrans-1,2-dichloroethene1,2-dichloropropaneethylbenzene

styrenetetrachloroethenetoluenem-xyleneo-xylenep-xylene

DW-VOC Mix #2 (12 components)

200µg/mL each in P&T methanol, 1mL/ampulcat. # 30038 (ea.)

2,000µg/mL each in P&T methanol, 1mL/ampulcat. # 30220 (ea.)

methylene chloride1,2,4-trichlorobenzene

1,1,2-trichloroethaneDW-VOC Mix #3 (3 components)



also availableRtx®-502.2 GC Columns

See page 102 for details.

bromodichloromethanebromoform

chloroformdibromochloromethane

501 Trihalomethane Mix (4 components)



benzenecarbon tetrachloride1,4-dichlorobenzene1,2-dichloroethane

1,1-dichloroethene1,1,1-trichloroethanetrichloroethenevinyl chloride

DW-VOC Mix #1 (8 components)



Contains 1mL each of these mixtures.30036: 501 Trihalomethane Mix30037: DW-VOC Mix #130038: DW-VOC Mix #230209: DW-VOC Mix #3

Quantity discounts not available.

Revised DW-VOC Kit (200μg/mL)

cat. # 30210 (kit)

kit

Contains 1mL each of these mixtures.30211: 501 Trihalomethane Mix30219: DW-VOC Mix #130220: DW-VOC Mix #230235: DW-VOC Mix #3


DW-VOC Kit #2 (2,000μg/mL)

cat. # 30221 (kit)

kit


452 www.restek.com 800-356-1688 or 814-353-1300


500 Series MethodsMethod 502.1, 502.2 (Volatile Halogenated Organics)

benzenebromobenzenebromochloromethanebromodichloromethanebromoformbromomethane (methyl bromide)n-butylbenzenesec-butylbenzenetert-butylbenzenecarbon tetrachloridechlorobenzenechloroethane (ethyl chloride)chloroformchloromethane (methyl chloride)2-chlorotoluene4-chlorotoluenedibromochloromethane1,2-dibromo-3-chloropropane (DBCP)1,2-dibromoethane (EDB)dibromomethane1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzenedichlorodifluoromethane (CFC-12)1,1-dichloroethane1,2-dichloroethane1,1-dichloroethenecis-1,2-dichloroethenetrans-1,2-dichloroethene1,2-dichloropropane1,3-dichloropropane2,2-dichloropropane1,1-dichloropropenecis-1,3-dichloropropenetrans-1,3-dichloropropeneethylbenzenehexachloro-1,3-butadiene

(hexachlorobutadiene)

isopropylbenzene (cumene)4-isopropyltoluene (p-cymene)methylene chloride (dichloromethane)naphthalenen-propylbenzenestyrene1,1,1,2-tetrachloroethane1,1,2,2-tetrachloroethanetetrachloroethenetoluene1,2,3-trichlorobenzene1,2,4-trichlorobenzene1,1,1-trichloroethane1,1,2-trichloroethanetrichloroethenetrichlorofluoromethane (CFC-11)1,2,3-trichloropropane1,2,4-trimethylbenzene1,3,5-trimethylbenzenevinyl chloridem-xyleneo-xylenep-xylene

Volatiles MegaMix® with Gases(60 components)


1-chloro-2-fluorobenzene502.2 Internal Standard #1

2,000µg/mL in P&T methanol, 1mL/ampulcat. # 30040 (ea.)

2-bromo-1-chloropropane fluorobenzene502.2 Internal Standard Mix #2 (2 components)


1-bromo-2-chloroethane1-chloro-3-fluorobenzene

fluorobenzene

8021/502.2 Surrogate Mix #1 (3 components)


1-bromo-2-chloroethane4-bromochlorobenzene

1-chloro-3-fluorobenzenefluorobenzene



benzenebromobenzenebromochloromethanebromodichloromethanebromoformn-butylbenzenesec-butylbenzenetert-butylbenzenecarbon tetrachloridechlorobenzenechloroform2-chlorotoluene4-chlorotoluenedibromochloromethane1,2-dibromo-3-chloropropane (DBCP)1,2-dibromoethanedibromomethane1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzene1,1-dichloroethane1,2-dichloroethane1,1-dichloroethenecis-1,2-dichloroethenetrans-1,2-dichloroethene1,2-dichloropropane1,3-dichloropropane2,2-dichloropropane

1,1-dichloropropenecis-1,3-dichloropropenetrans-1,3-dichloropropeneethylbenzenehexachloro-1,3-butadiene (hexa-

chlorobutadiene)isopropylbenzene (cumene)4-isopropyltoluene (p-cymene)methylene chloride (dichloromethane)naphthalenen-propylbenzenestyrene1,1,1,2-tetrachloroethane1,1,2,2-tetrachloroethanetetrachloroethenetoluene1,2,3-trichlorobenzene1,2,4-trichlorobenzene1,1,1-trichloroethane1,1,2-trichloroethanetrichloroethene1,2,3-trichloropropane1,2,4-trimethylbenzene1,3,5-trimethylbenzenem-xyleneo-xylenep-xylene

502.2 MegaMix® (54 components)

Includes all target analytes except the six gases, which are avail-able separately as 502.2 Calibration Mix #1.



bromomethanechloroethanechloromethane

dichlorodifluoromethane (CFC-12)trichlorofluoromethane (CFC-11)vinyl chloride

502.2 Calibration Mix #1 (gases) (6 components)



bromodichloromethanebromoformcarbon tetrachloridechloroform1,1-dichloroethane1,1-dichloroethenetrans-1,2-dichloroethene

1,3-dichloropropane2,2-dichloropropanecis-1,3-dichloropropenetrans-1,3-dichloropropenemethylene chloride1,1,1-trichloroethanetrichloroethene

502.2 Calibration Mix #2 (14 components)


No data pack available.

Antifoam Agent for Purge & Trap Samples

Foam generated as purge gas passes through a sample can enter theanalytical trap, and possibly the GC column. Our silica-containingantifoam agent is effective over a wide pH range, and will not conflictwith chromatography of target analytes.

Neat, 1mL/ampulcat. # 31822 (ea.)


800-356-1688 or 814-353-1300 www.restek.com 453


500 Series Methods

bromochloromethanedibromochloromethane1,2-dibromo-3-chloropropane1,2-dibromoethanedibromomethane1,2-dichloroethanecis-1,2-dichloroethene

1,2-dichloropropane1,1-dichloropropene1,1,1,2-tetrachloroethane1,1,2,2-tetrachloroethanetetrachloroethene1,1,2-trichloroethane1,2,3-trichloropropane



benzenetert-butylbenzenechlorobenzeneisopropylbenzenen-propylbenzene

styrenetoluene1,3,5-trimethylbenzenem-xylene



bromobenzenen-butylbenzenesec-butylbenzene2-chlorotoluene1,3-dichlorobenzene

ethylbenzene1,2,4-trichlorobenzene1,2,4-trimethylbenzeneo-xylenep-xylene



4-chlorotoluene1,2-dichlorobenzene1,4-dichlorobenzenehexachlorobutadiene

4-isopropyltoluenenaphthalene1,2,3-trichlorobenzene



Method 502.1, 502.2 (Volatile Halogenated Organics),cont'd

Method 505 (Organohalide Pesticides & PCBs)

Method 504.1 (Ethylene Dibromide/Dibromochloropropane)

Method 506 (Phthalate & Adipate Esters)

1,2-dibromo-3-chloropropane1,2-dibromoethane

1,2,3-trichloropropane504.1 Calibration Mix (3 components)


aldrinalachloratrazineγ-BHC (lindane)α-chlordaneγ-chlordanedieldrinendrin

heptachlorheptachlor epoxide (isomer B)hexachlorobenzenehexachlorocyclopentadienemethoxychlorcis-nonachlortrans-nonachlorsimazine

505 Organohalide Pesticide Mix (16 components)

200µg/mL each in methanol, 1mL/ampulcat. # 32024 (ea.)

Toxaphene Solutions

1,000µg/mL in hexane, 1mL/ampulcat. # 32005 (ea.)

2,000µg/mL in methanol, 1mL/ampulcat. # 32015 (ea.)

5,000µg/mL in isooctane, 1mL/ampulcat. # 32071 (ea.)

benzyl butyl phthalatebis(2-ethylhexyl)adipatebis(2-ethylhexyl)phthalatedi-n-butylphthalate

di-n-octyl phthalatediethylphthalatedimethylphthalate

506 Calibration Mix (7 components)

1,000µg/mL in isooctane, 1mL/ampulcat. # 31845 (ea.)

benzyl butyl phthalate 250µg/mLbis(2-ethylhexyl)adipate 1,200bis(2-ethylhexyl)phthalate 250di-n-butylphthalate 100

di-n-octyl phthalate 650diethylphthalate 100dimethylphthalate 100

506 Laboratory Performance Check Mix (7 components)

In P&T methanol, 1mL/ampulcat. # 31844 (ea.)

Contains 1mL each of these mixtures.30042: 502.2 Calibration Mix #130043: 502.2 Calibration Mix #230044: 502.2 Calibration Mix #330045: 502.2 Calibration Mix #430046: 502.2 Calibration Mix #530047: 502.2 Calibration Mix #6


502.2 VOA Calibration Kit #1 (2,000μg/mL)

cat. # 30444 (kit)

kit

Contains 1mL each of these mixtures.30042: 502.2 Calibration Mix #130431: 502.2 MegaMix


502.2 VOA Calibration Kit #2 (2,000μg/mL)

cat. # 30445 (kit)

kit

Contains 1mL each of these mixtures.30439: 502.2 Calibration Mix #130432: 502.2 MegaMix


502.2 VOA Calibration Kit #3 (200μg/mL)

cat. # 30446 (kit)

kit



and/or lot number)



454 www.restek.com 800-356-1688 or 814-353-1300


500 Series Methods

Method 507 (Nitrogen & Phosphorus Pesticides)

Method 508, 508.1, 508A (Chlorinated Pesticides)

alachlorametrynatratonatrazinebromacilbutachlorbutylatechlorprophamcyanazine (Bladex)cycloatediphenamidEPTCetridiazole (Terrazole)fenarimolfluridone (Sonar)hexazinone (Velpar)metolachlormetribuzinMGK-264

molinatenapropamide (Devrinol)norflurazonpebulateprometonprometrynepronamide (propyzamide)propachlorpropazinesimazinesimetryntebuthiuronterbacilterbutryntriadimefontricyclazole (Beam)trifluralinvernolate

Organonitrogen Pesticide Mix #1 (Rev), Method 525.2(37 components)

500µg/mL each in acetone, 1mL/ampulcat. # 33012 (ea.)

chlorpyrifos (Dursban)dichlorvos (DDVP)disulfoton sulfoneethoprop (ethoprophos)

methyl paraoxon (parathion methyl-O-analog)

mevinphos (phosdrin)stirofos (tetrachlorvinphos)

Organophosphorus Pesticide Mix #1 (Rev), Method 525.2(7 components)


carboxindiazinondisulfoton

fenamiphosmerphosterbufos

Method 525.2 Nitrogen/Phosphorus Pesticide Mix #2(6 components)

1,000µg/mL each in acetone, 1mL/ampulcat. # 32423 (ea.)

pentachloronitrobenzene508.1 Internal Standard

100µg/mL in ethyl acetate, 1mL/ampulcat. # 32091 (ea.)

4,4'-dibromobiphenyl508.1 Surrogate

500µg/mL in ethyl acetate, 1mL/ampulcat. # 32092 (ea.)

4,4'-DDT endrin508.1 GC Degradation Check Mix

100µg/mL each in ethyl acetate, 1mL/ampulcat. # 32093 (ea.)

Method 508, 508.1, 508A (Chlorinated Pesticides)cont'd

δ-BHC 0.4µg/mLchlorothalonil 0.5

chlorpyrifos 0.02DCPA (Dacthal) 0.5

508 Performance Check Mix (4 components)

In methyl tert-butyl ether, 1mL/ampulcat. # 32045 (ea.)

aldrinα-BHCβ-BHCδ-BHCγ-BHC (lindane)4,4'-DDD4,4'-DDE4,4'-DDTdieldrin

endosulfan Iendosulfan IIendosulfan sulfateendrinendrin aldehydeheptachlorheptachlor epoxide (isomer B)methoxychlor



chlorobenzilateα-chlordaneγ-chlordanechlornebDCPA (Dacthal)etridiazole

hexachlorobenzenecis-permethrin*trans-permethrin*propachlortrifluralin

*1,000µg/mL total permethrin. Exact content of each isomer listed on certificateof analysis.



alachloratrazinechlorthalonilcyanazine

hexachlorocyclopentadienemetolachlormetribuzinsimazine



4,4'-DDT 200µg/mLendrin 100µg/mL

Organochlorine Pesticide System Evaluation Mix (2 components)


Decachlorobiphenyl, 508A

200µg/mL in acetone, 1mL/ampulcat. # 32029 (ea.)


10µg/mL in isooctane, 1mL/ampulcat. # 32289 (ea.)

Toxaphene Solutions1,000µg/mL in hexane, 1mL/ampul

cat. # 32005 (ea.)2,000µg/mL in methanol, 1mL/ampul

cat. # 32015 (ea.) 5,000µg/mL in isooctane, 1mL/ampul

cat. # 32071 (ea.)



800-356-1688 or 814-353-1300 www.restek.com 455


500 Series MethodsMethod 508, 508.1, 508A (Chlorinated Pesticides)cont'd

Method 515, 515.4 (Chlorinated Acid Herbicides)

4,4'-dibromooctafluorobiphenylHerbicide Internal Standard

250µg/mL in hexane, 1mL/ampulcat. # 32053 (ea.)

2,000µg/mL in methyl tert-butyl ether, 1mL/ampulcat. # 31856 (ea.)

2,4-dichlorophenylacetic acid (DCAA)

Herbicide Surrogate

FFrreeee AAcciidd FFoorrmm

200µg/mL in methanol, 1mL/ampulcat. # 32049 (ea.)

1,000µg/mL in acetone, 1mL/ampulcat. # 32439 (ea.)

2,4-dichlorophenyl acetic acid methyl ester (DCAA methyl ester)DDeerriivvaattiizzeedd FFoorrmm


dinoseb methyl ether 4µg/mLDCAA methyl ester 5004,4'-dibromooctafluorobiphenyl 2503,5-dichlorobenzoic acid methyl ester 6004-nitroanisole 1,600

Herbicide Lab Performance Check Mix (5 components)


2,4-D2,4-DB2,4,5-T2,4,5-TP

dicambadichlorpropdinoseb

Herbicide Mix #1 (7 components)



2,4-D methyl ester2,4-DB methyl ester2,4,5-T methyl ester2,4,5-TP methyl ester

dicamba methyl esterdichlorprop methyl esterdinoseb methyl ether

DDeerriivvaattiizzeedd FFoorrmm

200µg/mL each in hexane, 1mL/ampulcat. # 32055 (ea.)

Method 515, 515.4 (Chlorinated Acid Herbicides)cont'd

dalapon

Herbicide Mix #2



dalapon methyl esterDDeerriivvaattiizzeedd FFoorrmm


acifluorfenbentazonchlorambenDCPA diacid

3,5-dichlorobenzoic acid4-nitrophenolpentachlorophenolpicloram




acifluorfen methyl esterbentazon methyl esterchloramben methyl esterDCPA (Dacthal)

3,5-dichlorobenzoic acid methyl ester4-nitroanisolepentachloroanisolepicloram methyl ester



acifluorfen methyl ester 50µg/mLbentazon methyl ester 100chloramben methyl ester 50dalapon methyl ester 1002,4-D methyl ester 1002,4-DB methyl ester 100DCPA (Dacthal) 100dicamba methyl ester 503,5-dichlorobenzoic acid

methyl ester 50

dichlorprop methyl ester 100dinoseb methyl ether 100pentachloroanisole 10picloram methyl ester 50quinclorac methyl ester 502,4,5-T methyl ester 252,4,5-TP (Silvex) methyl ester 25

515.4 Methylated Chlorinated Acids Mix (16 components)


acifluorfen (Blazer) 50µg/mLbentazon 100chloramben 502,4-D 100dalapon 1002,4-DB 100DCPA diacid (tetrachloro

terephthalic acid) 50dicamba 50

3,5-dichlorobenzoic acid 50dichlorprop 100dinoseb 100pentachlorophenol 10picloram 50quinclorac 502,4,5-T 252,4,5-TP (Silvex) 25

515.4 Calibration Mix (16 components)

In acetone, 1mL/ampulcat. # 32443 (ea.)

also availableAdditional chlorinated acid herbicides mixes:

see Method 555, page 463.

and Method 8321, page 484.

Contains 1mL each of these mixtures.32045: 508 Performance Check Mix32091: 508.1 Internal Standard Mix32092: 508.1 Surrogate Mix32093: 508.1 GC Degradation Check Mix32094: 508.1 Calibration Mix #132095: 508.1 Calibration Mix #232096: 508.1 Calibration Mix #3


508.1 Pesticide Kit

cat. # 32097 (kit)

kit


456 www.restek.com 800-356-1688 or 814-353-1300


500 Series MethodsMethod 521 (Nitrosamines)

N-nitrosodiethylamineN-nitrosodimethylamineN-nitrosodi-n-butylamineN-nitrosodi-n-propylamine

N-nitrosomethylethylamineN-nitrosopiperidineN-nitrosopyrrolidine

Nitrosamine Calibration Mix, Method 521 (7 components)

1,000µg/mL each in methylene chloride, 1mL/ampulcat. # 31898 (ea.)

N-nitrosodimethylamine-d6N-Nitrosodimethylamine-d6

1,000µg/mL in methylene chloride, 1mL/ampulcat. # 33910 (ea.)

N-nitrosodi-n-propylamine-d14N-Nitrosodi-n-propylamine-d14


4-bromofluorobenzene1,2-dichlorobenzene-d4

fluorobenzene524 Internal Standard/Surrogate Mix (3 components)


4-bromofluorobenzene α,α,α-trifluorotoluene

Surrogate Standard (2 components)


1-bromo-4-fluorobenzene 1,2-dichlorobenzene-d4

524.2 Surrogate Standard (2 components)


perfluorotributylamine (PFTBA)


PFTBA (MS Tuning Compound)


Neat, 1gcat. # 33027 (ea.)

Method 524.1, 524.2 (Volatile Organics)

benzenebromobenzenebromochloromethanebromodichloromethanebromoformbromomethane (methyl bromide)n-butylbenzenesec-butylbenzenetert-butylbenzenecarbon tetrachloridechlorobenzenechloroethane (ethyl chloride)chloroformchloromethane (methyl chloride)2-chlorotoluene4-chlorotoluenedibromochloromethane1,2-dibromo-3-chloropropane (DBCP)1,2-dibromoethane (EDB)dibromomethane1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzenedichlorodifluoromethane (CFC-12)1,1-dichloroethane1,2-dichloroethane1,1-dichloroethenecis-1,2-dichloroethenetrans-1,2-dichloroethene1,2-dichloropropane1,3-dichloropropane

2,2-dichloropropane1,1-dichloropropenecis-1,3-dichloropropenetrans-1,3-dichloropropeneethylbenzenehexachloro-1,3-butadiene

(hexachlorobutadiene)isopropylbenzene (cumene)4-isopropyltoluene (p-cymene)methylene chloride (dichloromethane)naphthalenen-propylbenzenestyrene1,1,1,2-tetrachloroethane1,1,2,2-tetrachloroethanetetrachloroethenetoluene1,2,3-trichlorobenzene1,2,4-trichlorobenzene1,1,1-trichloroethane1,1,2-trichloroethanetrichloroethenetrichlorofluoromethane (CFC-11)1,2,3-trichloropropane1,2,4-trimethylbenzene1,3,5-trimethylbenzenevinyl chloridem-xyleneo-xylenep-xylene

Volatiles MegaMix® with Gases (60 components)





Neat, 1mL/ampul cat. # 31822 (ea.)

• Activated charcoal for extraction of nitrosamines and dioxane in drinking water.

• Batch tested to ensure low background and consistent recoveries.

• High quality polypropylene tubes and frits to minimize interference.

• Specially treated charcoal and frits to minimize fines that result in inconsistent recoveries.

EPA 521 & 522Cartridge

See page 394.

Disks are also available on page 397.


800-356-1688 or 814-353-1300 www.restek.com 457


500 Series MethodsMethod 524.1, 524.2 (Volatile Organics) cont'd

acetone2-butanone (MEK)1,1-dichloro-2-propanone

2-hexanone4-methyl-2-pentanone (MIBK)

Ketones Mix, 524.2 Rev. 4.1 (5 components)

5,000µg/mL each in 90% P&T methanol:10% water, 1mL/ampulcat. # 30602 (ea.)

diisopropyl ether (DIPE) 2,000µg/mLethyl-tert-butyl ether (ETBE) 2,000tert-amyl ethyl ether (TAEE) 2,000tert-amyl methyl ether (TAME) 2,000tert-butyl alcohol (TBA) 10,000

Oxygenates Standard (5 components)


carbon disulfidechloroacetonitrile1-chlorobutanetrans-1,4-dichloro-2-butene1,1-dichloro-2-propanonediethyl ether

hexachloroethaneiodomethane (methyl iodide)methacrylonitrilemethyl tert-butyl ether2-nitropropanepropionitrile

524 Calibration Mix #8 (12 components)


acrylonitrileallyl chloridebenzenebromobenzenebromochloromethanebromodichloromethanebromoformn-butylbenzenesec-butylbenzenetert-butylbenzenecarbon disulfidecarbon tetrachloridechloroacetonitrilechlorobenzene1-chlorobutanechlorodibromomethane

(dibromochloromethane)chloroform2-chlorotoluene4-chlorotoluene1,2-dibromo-3-chloropropane (DBCP)1,2-dibromoethane (ethylene

dibromide)dibromomethane1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzenetrans-1,4-dichloro-2-butene1,1-dichloroethane1,2-dichloroethane1,1-dichloroethenecis-1,2-dichloroethenetrans-1,2-dichloroethene1,2-dichloropropane1,3-dichloropropane2,2-dichloropropane1,1-dichloropropenecis-1,3-dichloropropenetrans-1,3-dichloropropenediethyl ether (ethyl ether)ethylbenzeneethyl methacrylatehexachloro-1,3-butadienehexachloroethaneiodomethane (methyl iodide)

isopropylbenzene (cumene)4-isopropyltoluene (p-cymene)methacrylonitrilemethyl acrylatemethyl tert-butyl ether (MTBE)methylene chloride (dichloromethane)methyl methacrylatenaphthalenenitrobenzene2-nitropropanepentachloroethanepropionitrile (ethylcyanide)n-propylbenzenestyrene1,1,1,2-tetrachloroethane1,1,2,2-tetrachloroethanetetrachloroethenetetrahydrofurantoluene1,2,3-trichlorobenzene1,2,4-trichlorobenzene1,1,1-trichloroethane1,1,2-trichloroethanetrichloroethene1,2,3-trichloropropane1,2,4-trimethylbenzene1,3,5-trimethylbenzenem-xyleneo-xylenep-xylene

Drinking Water VOA MegaMix®,

524.2 Rev. 4.1 (73 components)







Note: For a listing of additional individual VOA surrogate and internal standards,see page 467.

Contains 1mL each of these mixtures.30300: 524 Calibration Mix #7A30304: 524 Calibration Mix #7B


524 Calibration Mix #7 Kit

cat. # 30202 (kit)

kit

acetone2-butanone (MEK)2-hexanone

4-methyl-2-pentanone (MIBK)tetrahydrofuran

524 Calibration Mix #7A (5 components)


acrylonitrileallyl chloride (3-chloropropene)ethyl methacrylatemethyl acrylate

methyl methacrylatenitrobenzenepentachloroethane

524 Calibration Mix #7B (7 components)


Contains 1mL each of these mixtures.30201: 524 Internal Standard/Surrogate Mix30042: 502.2 Calibration Mix #130043: 502.2 Calibration Mix #230044: 502.2 Calibration Mix #330045: 502.2 Calibration Mix #430046: 502.2 Calibration Mix #530047: 502.2 Calibration Mix #630300: 524 Calibration Mix #7A30304: 524 Calibration Mix #7B30203: 524 Calibration Mix #8


524 Rev. 4.0 Volatile Organics Kit (2,000μg/mL)

kit

cat. # 30204 (kit)

Contains 1mL each of these mixtures.30042: 502.2 Calibration Mix #130431: 502.2 MegaMix30300: 524 Calibration Mix #7A30304: 524 Calibration Mix #7B30203: 524 Calibration Mix #830201: 524 Surrogate/Internal Standard Mix


524 Rev. 4.0 VOA Kit #2 (2,000μg/mL)

cat. # 30447 (kit)

kit


458 www.restek.com 800-356-1688 or 814-353-1300


500 Series Methods

also availableSee pages 452-453 for 502.2 MegaMix® and 502.2 calibration mixes.

aldrinα-BHCβ-BHCδ-BHCγ-BHC (lindane)α-chlordaneγ-chlordane4,4'-DDD4,4'-DDE4,4'-DDT

dieldrinendosulfan Iendosulfan IIendosulfan sulfateendrinendrin aldehydeendrin ketoneheptachlorheptachlor epoxide (isomer B)methoxychlor

Organochlorine Pesticide Mix AB # 3 (20 components)

2,000µg/mL each in hexane:toluene (1:1), 1mL/ampulcat. # 32415 (ea.)

acenaphthene-d10chrysene-d12

phenanthrene-d10Method 525.2 Internal Standard Mix (3 components)


2-nitro-m-xyleneperylene-d12

pyrene-d10triphenylphosphate

Method 525.2 Surrogate Standard Mix (4 components)


2-chlorobiphenyl (BZ#1)2,3-dichlorobiphenyl (BZ#5)2,4,5-trichlorobiphenyl (BZ#29)2,2',4,4'-tetrachlorobiphenyl (BZ#47)2,2',3',4,6-pentachlorobiphenyl (BZ#98)2,2',4,4',5,6'-hexachlorobiphenyl (BZ#154)2,2',3,3',4,4',6-heptachlorobiphenyl (BZ#171)2,2',3,3',4,5',6,6'-octachlorobiphenyl (BZ#200)

Method 525.2 PCB Congener Mix (8 components)


Method 525, 525.1, 525.2 (Semivolatile Organics)

acetochloralachlor

metolachlorMethod 525.2 Herbicide Mix (3 components)


CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceeacetochlor M 100 33208alachlor M 100 33207metolachlor M 100 33209M = methanol

Method 525.2 Herbicide AnalytesVolume is 1mL/ampul. Concentration is µg/mL.

acenaphthyleneanthracenebenzo(a)anthracenebenzo(a)pyrenebenzo(b)fluoranthenebenzo(ghi)perylenebenzo(k)fluoranthenebenzylbutylphthalatebis(2-ethylhexyl)adipatebis(2-ethylhexyl)phthalatechrysenedibenzo(a,h)anthracenediethylphthalatedimethylphthalate

di-n-butylphthalate2,4-dinitrotoluene2,6-dinitrotoluenedi-n-octylphthalatefluoranthenefluorenehexachlorobenzenehexachlorocyclopentadieneindeno(1,2,3-cd)pyreneisophoronenaphthalenepentachlorophenol*phenanthrenepyrene

Method 525.2 Semivolatile Mix (revised) (28 components)

1,000µg/mL each in acetone, 1mL/ampul*cat. # 31899 (ea.)

*pentachlorophenol at 4,000µg/mL.

alachlorametrynatratonatrazinebromacilbutachlorbutylatechlorprophamcyanazine (Bladex)cycloatediphenamidEPTCetridiazole (Terrazole)fenarimolfluridone (Sonar)hexazinone (Velpar)metolachlormetribuzinMGK-264

molinatenapropamide (Devrinol)norflurazonpebulateprometonprometrynepronamide (propyzamide)propachlorpropazinesimazinesimetryntebuthiuronterbacilterbutryntriadimefontricyclazole (Beam)trifluralinvernolate

Organonitrogen Pesticide Mix #1 (Rev), Method 525.2(37 components)


chlorpyrifos (Dursban)dichlorvos (DDVP)disulfoton sulfoneethoprop (ethoprophos)

methyl paraoxon (parathion methyl-O-analog)

mevinphos (phosdrin)stirofos (tetrachlorvinphos)

Organophosphorus Pesticide Mix #1 (Rev), Method 525.2(7 components)

500µg/mL each in acetone, 1mL/ampulcat. # 33013 (ea.)also available

Try our CLPesticides columns for theseapplications.

See pages 88-90 for details.carboxindiazinondisulfoton

fenamiphosmerphosterbufos

Method 525.2 Nitrogen/Phosphorus Pesticide Mix #2

(6 components)



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500 Series Methods

chlorobenzilatechloronebchlorothalonilDCPA (Dacthal)

heptachlor epoxide (isomer A)trans-nonachlorcis-permethrintrans-permethrin

Organochlorine Pesticide Mix #2 (Rev), Method 525.2(8 components)


p-terphenyl-d14Method 525.2 Fortification Recovery Standard


4,4'-DDTDFTPP (decafluorotriphenylphosphine)endrin

Method 525.2 GC/MS Performance Check Mix (3 components)


Method 526 (Semivolatile Organics)

Method 527 (Pesticides & Flame Retardants-GC/MS)

acetochlorcyanazinediazinon2,4-dichlorophenol1,2-diphenylhydrazinedisulfoton

fonofosnitrobenzeneprometonterbufos2,4,6-trichlorophenol

Semivolatile Calibration Mix, EPA 526 (11 components)



phenanthrene-d10

Internal Standard Mix, EPA 526 (3 components)


2-nitro-m-xylene triphenylphosphate

Surrogate Standard Mix, EPA 526 (2 components)


atrazinebifenthrinesbiol (Bioallethrin, S-cyclopentyl

isomer)bromacilesfenvalaratefenvalaratehexazinonekepone

mirexnitrofennorflurazonoxychlordaneprometrynepropazinethiobencarbvinclozolin

Pesticides Mix #1, Method 527 (16 components)


chloropyrifos (Dursban)dimethoatemalathion

parathionterbufos sulfone

Pesticides Mix #2, Method 527 (5 components)


1,3-dimethyl-2-nitrobenzeneperylene-d12

triphenylphosateSurrogate Standard, Method 527 (3 components)


2,2',4,4',5-pentabromodiphenyl ether (BDE-99)2,2',4,4',5,5'-hexabromobiphenyl2,2',4,4',5,5'-hexabromodiphenyl ether (BDE-153)2,2',4,4',6-pentabromodiphenyl ether (BDE-100)2,2',4,4'-tetrabromodiphenyl ether (BDE-47)


PBDE Mix (5 components)

50µg/mL each in isooctane:ethyl acetate (4:1), 1mL/ampulcat. # 33098 (ea.)


phenanthrene-d10Internal Standard, Method 527 (3 components)


Method 525, 525.1, 525.2 (Semivolatile Organics)cont'd

2-nitro-m-xyleneperylene-d12

pyrene-d10triphenylphosphate

Method 525.2 Surrogate Standard Mix (4 components)



phenanthrene-d10Method 525.2 Internal Standard Mix (3 components)


quantity discountsOrder 3 or 4 of any one reference standard and receive a 10% discount!

Order 5 or more of any one reference standard and receive a 20% discount!

Quantity discounts are not available on all reference standards. Reference Standards SearchSearch by compound name, synonym, or CAS #.



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500 Series MethodsMethod 529 (Nitroaromatics & Nitramines)

3,5-dinitroaniline1,3-dinitrobenzene2-amino-4,6-dinitrotoluene4-amino-2,6-dinitrotoluene2,4-dinitrotoluene2,6-dinitrotoluenenitrobenzene

2-nitrotoluene3-nitrotoluene4-nitrotolueneRDXtetryl1,3,5-trinitrobenzene2,4,6-trinitrotoluene

Nitroaromatics and Nitramine Explosives in Drinking Water(14 components)

1,000µg/mL each in acetonitrile, 1mL/ampulcat. # 33900 (ea.)

3,4-dinitrotoluene529 Internal Standard Mix

2,000µg/mL in ethyl acetate, 1mL/ampulcat. # 33901 (ea.)

2-nitromesitylene529 Surrogate Standard #1


1,2,4-trimethyl-5-nitrobenzene529 Surrogate Standard #2


nitrobenzene-d5529 Surrogate Standard #3


Method 528 (Phenols)

4-chloro-3-methylphenol2-chlorophenolo-cresol2,4-dichlorophenol2,4-dimethylphenol2,4-dinitrophenol

2-methyl-4,6-dinitrophenol2-nitrophenol4-nitrophenolpentachlorophenolphenol2,4,6-trichlorophenol

Phenol Calibration Mix, EPA 528 (12 components)


3-nitro-o-xylene 1,000µg/mL2,3,4,5-tetrachlorophenol 2,000

Internal Standard Mix, EPA 528 (2 components)

In methylene chloride, 1mL/ampulcat. # 31696 (ea.)

4-chloro-3-methylphenol 100µg/mL2-chlorophenol 100o-cresol 1002,4-dichlorophenol 1002,4-dimethylphenol 1002,4-dinitrophenol 500

2-methyl-4,6-dinitrophenol 5002-nitrophenol 1004-nitrophenol 500pentachlorophenol 500phenol 1002,4,6-trichlorophenol 100

Phenols Fortification Mix, EPA 528 (12 components)

In methanol, 1mL/ampulcat. # 31695 (ea.)

Surrogate Standard Mix, EPA 528 (3 components)

2-chlorophenol-d4 1,000µg/mL2,4-dimethylphenol-3,5,6-d3 1,0002,4,6-tribromophenol 2,000


Meets all DOT requirements. Available only to customers or distributors insidethe 48 contiguous United States; item may not be resold for export.

• Low bleed for lower detection limits of late eluting PAHs.• Excellent resolution of benzo(b)fluoranthene and

benzo(k)fluoranthene • Engineered to assure column-to-column reproducibility.

Exceptionally Inert Columns for GC/MS

and Trace Level Analyses

-5Sil MS

Find Out More about Rxi® 3-in-1

Technology at www.restek.com/rxi


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500 Series MethodsMethod 531.1, 531.2 (Carbamates)

Method 532 (Phenylurea Pesticides)

4-bromo-3,5-dimethylphenyl-N-methylcarbamate (BDMC)Internal Standard


aldicarb sulfoxide 100µg/mLBDMC 10

3-hydroxycarbofuran 2methiocarb 20

531.1 Performance Check Mix (4 components)


aldicarbaldicarb sulfonealdicarb sulfoxidecarbaryl (Sevin)carbofuran

3-hydroxycarbofuranmethiocarbmethomyloxamylpropoxur (Baygon)

531.1 Carbamate Pesticide Calibration Mixture (10 components)


aldicarbaldicarb sulfonealdicarb sulfoxidecarbaryl (Sevin)carbofuran3-hydroxycarbofuran

methiocarbmethomyl1-naphtholoxamylpropoxur (Baygon)

531.2 Carbamate Pesticide Calibration Mixture (11 components)

100µg/mL in acetonitrile, 1mL/ampulcat. # 32435 (ea.)

carbazole monuronPhenylurea Surrogate Mixture (2 components)

500µg/mL each in methanol:acetonitrile (50:50), 1mL/ampulcat. # 32433 (ea.)

diflubenzurondiuronfluometuronlinuron

propanilsidurontebuthiuronthidiazuron

Phenylurea Pesticide Mixture (8 components)

200µg/mL each in acetonitrile:acetone (90:10), 1mL/ampulcat. # 32434 (ea.)

Method 535 (Chloroacetanilide Herbicide Degradates)

butachlor ESA sodium saltMethod 535 Internal Standard


dimethachlor ESA sodium saltMethod 535 Surrogate Standard


CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceeacetochlor ESA sodium salt M 100 33092acetochlor OA M 100 33094alachlor ESA sodium salt M 100 33096alachlor OA M 100 33099metolachlor ESA sodium salt M 100 33200metolachlor OA M 100 33201

M = methanol

Method 535 Individual Compounds

Volume is 1mL/ampul. Concentration is µg/mL.

Method 547 (Glyphosate)

Method 549.2 (Paraquat/Diquat)

glyphosateGlyphosate Standard

1,000µg/mL in DI water, 1mL/ampulcat. # 32426 (ea.)

1,000µg/mL in DI water, 5mL/ampulcat. # 32427 (ea.)

aminomethyl phosphonic acid (AMPA)AMPA (glyphosate metabolite)

100µg/mL in DI water, 1mL/ampulcat. # 32428 (ea.)

diquat dibromide paraquat dichlorideParaquat & Diquat Calibration Mix (2 components)

1,000µg/mL each in water, 1mL/ampulcat. # 32437 (ea.)

Ultra Quat Reagent Solution

Use with Ultra Quat HPLC column. Dilute to 1 liter, per instructions.In water, 20mL/bottle

cat. # 32441 (ea.)

Chromatogram Search ToolSearch by compound name, synonym,CAS # or keywordwww.restek.com/chromatograms


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500 Series MethodsMethods 552, 552.1, 552.2, 552.3 (Haloacetic Acidsand Dalapon)

Method 551.1 (Chlorinated Pesticides & Herbicides)

1-bromo-4-fluorobenzene551.1 Internal Standard


decafluorobiphenyl551.1 Surrogate Standard


alachloratrazinebromacilcyanazine (Bladex)endrinendrin aldehydeendrin ketoneγ-BHC (lindane)

heptachlorheptachlor epoxide (isomer B)hexachlorobenzenehexachlorocyclopentadienemethoxychlormetolachlorsimazinetrifluralin

Method 551.1 Pesticide/Herbicide Mix (16 components)


bromochloroacetonitrilebromodichloromethanebromoformcarbon tetrachloridechloroformchloropicrindibromoacetonitriledibromochloromethane1,2-dibromo-3-chloropropane (DBCP)1,2-dibromoethane (EDB)

dichloroacetonitrile1,1-dichloro-2-propanonetetrachloroethylenetrichloroacetonitrile1,1,1-trichloroethane1,1,2-trichloroethanetrichloroethylene1,2,3-trichloropropane1,1,1-trichloro-2-propanone

Disinfection By-Product and Chlorinated Solvents Mix(19 components)


chloral hydrateChloral Hydrate

1,000µg/mL in acetonitrile, 1mL/ampulcat. # 30609 (ea.)

bromochloroacetonitrilechloropicrindibromoacetonitriledichloroacetonitrile

1,1-dichloro-2-propanonetrichloroacetonitrile1,1,1-trichloro-2-propanone

Disinfection By-Product Mix (7 components)


bromochloroacetic acidbromodichloroacetic acidchlorodibromoacetic aciddibromoacetic aciddichloroacetic acid

monobromoacetic acidmonochloroacetic acidtribromoacetic acidtrichloroacetic acid

Haloacetic Acid Mix (9 components)

1,000µg/mL each in methyl tert-butyl ether, 1mL/ampulcat. # 31896 (ea.)

methyl bromochloroacetatemethyl bromodichloroacetatemethyl chlorodibromoacetatemethyl dibromoacetatemethyl dichloroacetate

methyl monobromoacetatemethyl monochloroacetatemethyl tribromoacetatemethyl trichloroacetate

Haloacetic Acid Methyl Ester Mix (9 components)


bromochloroacetic aciddibromoacetic aciddichloroacetic acid

monobromoacetic acidmonochloroacetic acidtrichloroacetic acid

Haloacetic Acid Mix #1 (6 components)


methyl bromochloroacetatemethyl dibromoacetatemethyl dichloroacetate

methyl monobromoacetatemethyl monochloroacetatemethyl trichloroacetate

Haloacetic Acid Methyl Ester Mix #1 (6 components)




and/or lot number)



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500 Series MethodsMethod 555 (Chlorinated Acids)Methods 552, 552.1, 552.2, 552.3 (Haloacetic Acids

and Dalapon) cont'd

Drinking Water Odor Standard

bromochloroacetic acid 400µg/mLbromodichloroacetic acid 400chlorodibromoacetic acid 1,000dibromoacetic acid 200dichloroacetic acid 600

monobromoacetic acid 400monochloroacetic acid 600tribromoacetic acid 2,000trichloroacetic acid 200

Haloacetic Acid Mix #2 (9 components)


methyl bromochloroacetate 400µg/mLmethyl bromodichloroacetate 400methyl chlorodibromoacetate 1,000methyl dibromoacetate 200methyl dichloroacetate 600

methyl monobromoacetate 400methyl monochloroacetate 600methyl tribromoacetate 2,000methyl trichloroacetate 200

Haloacetic Acid Methyl Ester Mix #2 (9 components)


dalaponDalapon (2,2-dichloropropionic acid)




dalapon methyl esterDalapon Methyl Ester



acifluorfen (Blazer)bentazonchloramben2,4-D

dicambadichlorproppicloram2,4,5-TP (Silvex)

Chlorinated Acids by HPLC, Mix A (8 components)


2,4-DB3,5-dichlorobenzoic aciddinosebMCPA

MCPP (mecoprop)4-nitrophenolpentachlorophenol2,4,5-T

Chlorinated Acids by HPLC, Mix B (8 components)


2,4-dichlorophenoxyacetic acid (2,4-D)2,4,5-TP (Silvex)

Chlorinated Acid Herbicide Mix (2 components)


(+/-)-geosmin 2-methylisoborneol

Unpleasant odor in drinking water is associated with the growthand decay of microorganisms. The threshold value for thesecompounds is low (10 ppt) and purge and trap analyses usuallyare used to quantify them.

100µg/mL in P&T methanol, 1mL/ampulcat. # 30608 (ea.)

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceeIInntteerrnnaall SSttaannddaarrdd::1,2,3-trichloropropane MTBE 1,000 31648

SSuurrrrooggaatteess ffoorr MMeetthhoodd 555522,, 555522..11::2,3-dichloropropionic acid MTBE 1,000 316503,5-dichlorobenzoic acid MTBE 1,000 316523,5-dichlorobenzoic acid methyl ester MTBE 1,000 316492,3-dichloropropionic acid methyl ester MTBE 1,000 31651

SSuurrrrooggaatteess ffoorr MMeetthhoodd 555522..22::2-bromopropionic acid MTBE 1,000 316532,3-dibromopropionic acid MTBE 1,000 31655methyl-2,3-dibromopropionate MTBE 1,000 31656

SSuurrrrooggaatteess ffoorr MMeetthhoodd 555522..33::2-bromobutanoic acid MTBE 2,000 318812-bromobutyrate MTBE 2,000 31882

MTBE = methyl tert-butyl ether

Internal Standards and Surrogates


Get More!Environmental Solutions Online

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600 Series Methods

UUSS EEPPAA MMeetthhoodd NNoo.. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. ..CCoommppoouunndd CCllaassss

601 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Purgeable Hydrocarbons

602 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Purgeable Aromatics

603 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Acrolein/Acrylonitrile

604 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Phenols

605 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Benzidine/3,3'-Dichlorobenzidine

606 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Phthalate Esters

607 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Nitrosamines

608 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Organochlorine Pesticides and PCBs


609 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Nitroaromatics/Isophorone

610 . . . . . . . . . . . . . . . . . . . . . . . . . . .Polycyclic Aromatic Hydrocarbons (PAHs)

611 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Haloethers

612 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Chlorinated Hydrocarbons

615 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Chlorinated Acid Herbicides

624 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Purgeable Halocarbons

625 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Semivolatiles

600 Series Methods - US EPA Clean Water Act (CWA)

Method 602 (Purgeable Aromatics)

Method 603 (Acrolein/Acrylonitrile)


Method 606 (Phthalate Esters)

Method 605 (Benzidine/3,3’-Dichlorobenzidine)

benzenechlorobenzene1,2-dichlorobenzene1,3-dichlorobenzene

1,4-dichlorobenzeneethylbenzenetoluene

602 Purgeable Aromatics Calibration Mix (7 components)


acrolein acrylonitrile

Acrolein/Acrylonitrile (2 components)

2,000µg/mL each in DI water, 1mL/ampulcat. # 30600 (ea.)

Acrylonitrile2,000µg/mL in P&T methanol, 1mL/ampul

cat. # 30246 (ea.)

4-chloro-3-methylphenol2-chlorophenol2,4-dichlorophenol2,4-dimethylphenol2,4-dinitrophenol2-methyl-4,6-dinitrophenol

2-nitrophenol4-nitrophenolpentachlorophenolphenol2,4,6-trichlorophenol

604 Phenols Calibration Mix (11 components)

2,000µg/mL each in methanol, 1mL/ampulcat. # 31029 (ea.)

bis(2-ethylhexyl)phthalatebutyl benzyl phthalatediethyl phthalate

dimethyl phthalatedi-n-butyl phthalatedi-n-octyl phthalate

606 Phthalate Esters Calibration Mix (6 components)


benzidine 3,3'-dichlorobenzidine605 Benzidines Calibration Mix (2 components)



Method 601 (Purgeable Hydrocarbons)

bromodichloromethanebromoformcarbon tetrachloridechlorobenzene2-chloroethyl vinyl etherchloroformdibromochloromethane1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzene1,1-dichloroethane1,2-dichloroethane

1,1-dichloroethenetrans-1,2-dichloroethene1,2-dichloropropanecis-1,3-dichloropropenetrans-1,3-dichloropropenemethylene chloride1,1,2,2-tetrachloroethanetetrachloroethene1,1,1-trichloroethane1,1,2-trichloroethanetrichloroethene

VOA Purgeable Halocarbon Mix #1 (23 components)


Acrolein


5,000µg/mL in water, 1mL/ampulcat. # 30646 (ea.)

Must ship overnight on ice. Reference Standards SearchSearch by compound name, synonym, or CAS #.



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600 Series MethodsMethod 610 (Polycyclic Aromatic Hydrocarbons[PAHs])

Method 609 (Nitroaromatics/Isophorone)

Method 608 (Organochlorine Pesticides & PCBs)

aldrinα-BHCβ-BHCδ-BHCγ-BHC (lindane)4,4'-DDD4,4'-DDE4,4'-DDT

dieldrinendosulfan Iendosulfan IIendosulfan sulfateendrinendrin aldehydeheptachlorheptachlor epoxide (isomer B)

608 Calibration Mix (16 components)

200µg/mL each in hexane:toluene (1:1), 1mL/ampulcat. # 32022 (ea.)

2,4-dinitrotolueneisophorone

2,6-dinitrotoluenenitrobenzene

609 Nitroaromatics & Isophorone Calibration Mix (4 components)

2,000µg/mL each in hexane, 1mL/ampulcat. # 31033 (ea.)

acenaphtheneacenaphthyleneanthracenebenzo(a)anthracenebenzo(a)pyrenebenzo(b)fluoranthenebenzo(k)fluoranthenebenzo(ghi)perylene

chrysenedibenzo(a,h)anthracenefluoranthenefluoreneindeno(1,2,3-cd)pyrenenaphthalenephenanthrenepyrene

SV Calibration Mix #5 / 610 PAH Mix (16 components)


Method 607 (Nitrosamines)

N-nitrosodimethylamineN-nitroso-di-n-propylamine

N-nitrosodiphenylamine607 Nitrosamines Calibration Mix (3 components)


acenaphthene 1,000µg/mLacenaphthylene 1,000anthracene 1,000benzo(a)anthracene 500benzo(a)pyrene 500benzo(b)fluoranthene 500benzo(k)fluoranthene 500benzo(ghi)perylene 500

chrysene 500dibenzo(a,h)anthracene 500fluoranthene 500fluorene 1,000indeno(1,2,3-cd)pyrene 500naphthalene 1,000phenanthrene 500pyrene 500

610 PAH Calibration Mix A (16 components)For HPLC/fluorescence detection.


acenaphthene 1,000µg/mLacenaphthylene 2,000anthracene 100benzo(a)anthracene 100benzo(a)pyrene 100benzo(b)fluoranthene 200benzo(k)fluoranthene 100benzo(ghi)perylene 200

chrysene 100dibenzo(a,h)anthracene 200fluoranthene 200fluorene 200indeno(1,2,3-cd)pyrene 100naphthalene 1,000phenanthrene 100pyrene 100

610 PAH Calibration Mix B (16 components)For HPLC/UV detection.

In methylene chloride:methanol (1:1), 1mL/ampulcat. # 31455 (ea.)

Method 612 (Chlorinated Hydrocarbons)

2-chloronaphthalene1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzenehexachlorobenzene

hexachlorobutadienehexachlorocyclopentadienehexachloroethane1,2,4-trichlorobenzene

612 Chlorinated Hydrocarbons Calibration Mix (9 components)

2,000µg/mL each in isooctane, 1mL/ampulcat. # 31035 (ea.)

bis(2-chloroethoxy)methanebis(2-chloroethyl)etherbis(2-chloroisopropyl)ether

4-bromophenyl phenyl ether4-chlorophenyl phenyl ether

611 Haloethers Calibration Mix (5 components)


Method 611 (Haloethers)

Please see page 469 for individual Aroclor, toxaphene, and chlordane information.

4,4'-DDT 200µg/mL endrin 100µg/mL

Organochlorine Pesticide System Evaluation Mix (2 components)


Contains 1mL each of these mixtures.32022: 608 Calibration Mix32006: Aroclor 101632007: Aroclor 122132008: Aroclor 123232009: Aroclor 124232010: Aroclor 124832011: Aroclor 125432012: Aroclor 126032005: toxaphene32021: chlordane (technical)


608 Complete Kit

cat. # 32060 (kit)

kit


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600 Series Methods


see Method 555, page 463

and Method 8321, page 484

benzenebromodichloromethanebromoformcarbon tetrachloridechlorobenzene2-chloroethyl vinyl etherchloroformdibromochloromethane1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzene1,1-dichloroethane1,2-dichloroethane

1,1-dichloroethenetrans-1,2-dichloroethene1,2-dichloropropanecis-1,3-dichloropropenetrans-1,3-dichloropropeneethylbenzenemethylene chloride1,1,2,2-tetrachloroethanetetrachloroethenetoluene1,1,1-trichloroethane1,1,2-trichloroethanetrichloroethene

Volatiles MegaMix®, EPA Method 624 (26 components)


bromochloromethane2-bromo-1-chloropropane

1,4-dichlorobutane624 Internal Standard Mix (3 components)


4-bromofluorobenzenefluorobenzene

pentafluorobenzene624 Surrogate Standard Mix (3 components)



trichlorofluoromethane (CFC-11)vinyl chloride

624 Calibration Mix #1 (gases) (5 components)


benzenecarbon tetrachloridechlorobenzene2-chloroethyl vinyl etherdibromochloromethane1,1-dichloroethane

1,1-dichloroethene1,2-dichloropropanemethylene chloridetetrachloroethene1,1,2-trichloroethanetrichloroethene



bromodichloromethanebromoformchloroform1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzene1,2-dichloroethane

trans-1,2-dichloroethenecis-1,3-dichloropropenetrans-1,3-dichloropropeneethylbenzene1,1,2,2-tetrachloroethanetoluene1,1,1-trichloroethane



Method 615 (Chlorinated Acid Herbicides)

MCPA MCPP




MCPA methyl ester MCPP methyl esterDDeerriivvaattiizzeedd FFoorrmm


Method 624 (Purgeable Halocarbons)

2,4-dichlorophenylacetic acid (DCAA)200µg/mL in methanol, 1mL/ampul

cat. # 32049 (ea.) 1,000µg/mL in acetone, 1mL/ampul

cat. # 32439 (ea.)



Herbicide Surrogate


2,4-D2,4-DB2,4,5-T2,4,5-TP









dalapon

Herbicide Mix #2





dalapon methyl ester2,000µg/mL in hexane, 1mL/ampul

cat. # 32057 (ea.) 1,000µg/mL in methanol, 1mL/ampul

cat. # 32254 (ea.)


4-bromofluorobenzene α,α,α-trifluorotolueneSurrogate Standard (2 components)



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600 Series Methods

EPA Method 624 on an Rtx®-VMS column.

Method 624 (Purgeable Halocarbons) cont'd Individual VOA Surrogate and Internal Standardsfor EPA Methods

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceebenzene-d6 PTM 2,000 300252-bromochlorobenzene PTM 2,000 302284-bromochlorobenzene PTM 2,000 30230bromochloromethane PTM 2,000 302252-bromo-1-chloropropane PTM 2,000 302264-bromofluorobenzene PTM 2,000 30026chlorobenzene-d5 PTM 2,000 302231-chloro-2-fluorobenzene PTM 2,000 300401,2-dichlorobenzene-d4 PTM 2,000 300491,4-dichlorobutane PTM 2,000 302271,2-dichloroethane-d4 PTM 2,000 300271,4-difluorobenzene PTM 2,000 30032ethylbenzene-d5 PTM 2,000 30028ethylbenzene-d10 PTM 2,000 30029fluorobenzene PTM 2,000 30030pentafluorobenzene PTM 2,000 30031toluene-d8 PTM 2,000 30224α,α,α-trifluorotoluene PTM 2,000 30048

PTM = Purge & trap grade methanol


Our Rtx®-VMS capillary GC column

is optimized for EPA Method 624!

See page 100 for more information.1. chloromethane2. vinyl chloride3. bromomethane4. chloroethane5. trichlorofluoromethane6. 1,1-dichloroethene7. methylene chloride8. trans-1,2-dichloroethene9. 1,1-dichloroethane

10. bromochloromethane11. chloroform12. carbon tetrachloride13. 1,1,1-trichloroethane14. benzene15. pentafluorobenzene16. 1,2-dichloroethane17. fluorobenzene18. trichloroethene19. 1,2-dichloropropane

20. bromodichloromethane21. 2-chloroethyl vinyl ether22. cis-1,3-dichloropropene23. toluene24. tetrachloroethene25. trans-1,3-dichloropropene26. 2-bromo-1-chloropropane27. 1,1,2-trichloroethane28. dibromochloromethane29. ethylbenzene30. chlorobenzene31. bromoform32. 4-bromofluorobenzene33. 1,4-dichlorobutane34. 1,1,2,2-tetrachloroethane35. 1,3-dichlorobenzene36. 1,4-dichlorobenzene37. 1,2-dichlorobenzene

1.00 2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00

Column: Rtx®-VMS, 30m, 0.25mm ID, 1.40µm (cat#19915)Conc.: 20 ppb in 5mL of RO waterConcentrator: Tekmar LSC-3000 Purge and TrapTrap: Vocarb 3000 (type K)Purge: 11 min. @ 40mL/min. (ambient temperature)Dry purge: 1 min. @ 40mL/min. (MCS bypassed using

Silcosteel® tubing)Desorb preheat: 245°CDesorb: 250°C for 2 min., Flow 10mL/min.Bake: 260°C for 8 min.

GC Interface: 1:10 split at injection port. 1mm ID liner.GC: Agilent 6890 Oven temp.: 40°C (hold 4 min.) to 95°C @ 24°C/min. (hold 3 min.), to

210°C @ 40°C/min. (hold 6 min.)Carrier gas: helium @ ~1mL/min. constant flow

Adjust dichlorodifluoromethane to a retention time of 2.54 min. @ 40°C

Detector: Agilent 5973 MSDScan range: 25-300 amu

1

23

4

5

6

78

910

1112

13

14

15

16

17 18

19

20

21 22

23 24,25

27

2628

29 30

31

32

33,34 3536

37

GC_EV00425

Contains 1mL each of these mixtures.30020: 624 Calibration Mix #130021: 624 Calibration Mix #230022: 624 Calibration Mix #330023: 624 Internal Standard Mix30243: 624 Surrogate Standard Mix


624 Complete Kit

cat. # 30244 (kit)

kit

Contains 1mL each of these mixtures.30020: 624 Calibration Mix #130021: 624 Calibration Mix #230022: 624 Calibration Mix #330023: 624 Internal Standard Mix


624 Kit

cat. # 30055 (kit)

kit


468 www.restek.com 800-356-1688 or 814-353-1300


600 Series Methods

Method 625 (Semivolatiles)

acenaphtheneacenaphthyleneanthracenebenzo(a)anthracenebenzo(a)pyrenebenzo(b)fluoranthenebenzo(ghi)perylenebenzo(k)fluoranthenebenzyl butyl phthalatebis(2-chloroethoxy)methanebis(2-chloroethyl)etherbis(2-chloroisopropyl)etherbis(2-ethylhexyl)phthalate4-bromophenyl phenyl ether4-chloro-3-methylphenol2-chloronaphthalene2-chlorophenol4-chlorophenyl phenyl etherchrysenedibenzo(a,h)anthracene1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzene2,4-dichlorophenoldiethylphthalate2,4-dimethylphenoldimethylphthalatedi-n-butylphthalate4,6-dinitro-2-methylphenol2,4-dinitrophenol2,4-dinitrotoluene2,6-dinitrotoluenedi-n-octylphthalatediphenylamine*

fluoranthenefluorenehexachlorobenzenehexachloro-1,3-butadienehexachlorocyclopentadiene*hexachloroethaneindeno(1,2,3-cd)pyreneisophoronenaphthalenenitrobenzene2-nitrophenol4-nitrophenolN-nitrosodimethylamine*N-nitroso-di-n-propylaminepentachlorophenolphenanthrenephenolpyrene1,2,4-trichlorobenzene2,4,6-trichlorophenol

Semivolatiles MegaMix®, EPA

Method 625 (54 components)


*Listed as an “additional compound” in Method 625 (listed compound N-nitrosodiphenylamine decomposes to MegaMix component diphenylamine). The six other “additional compounds” are components in other Restek referencemixes used for Method 625: benzidine is included in cat.# 31030 (page 464); β-BHC, δ-BHC, endosulfan I, endosulfan II, endrin are in cat.# 32291 (page 472)and cat.# 32415 (page 473).

also availableTry Restek’s Rxi®-5Sil MS columns for EPAMethods 625 and 8270. Guaranteed for lowGC/MS bleed, excellent phenol response, andthe resolution needed to quantify critical pairsand structural isomers.

See page 87 for more information.

acenaphthene-d10chrysene-d121,4-dichlorobenzene-d4

naphthalene-d8perylene-d12phenanthrene-d10

SV Internal Standard Mix (6 components)

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceeanthracene-d10 D 2,000 31037decafluorobiphenyl D 2,000 31041decafluorobiphenyl A 1,000 318554,4'-dibromobiphenyl D 2,000 310394,4'-dibromooctafluorobiphenyl D 2,000 310402-fluorobiphenyl D 2,000 310911-fluoronaphthalene D 2,000 310922-fluorophenol D 2,000 31047naphthalene-d8 D 2,000 31043nitrobenzene-d5 D 2,000 31044pentafluorophenol D 2,000 31048phenanthrene-d10 D 2,000 31045phenol-d6 D 2,000 31049pyridine-d5 D 2,000 31046p-terphenyl-d14 D 1,000 318282,4,6-tribromophenol M 1,000 31401

A = acetone; D = methylene chloride; M = methanol

Individual Semivolatile Surrogate and InternalStandards for EPA MethodsVolume is 1mL/ampul. Concentration is µg/mL.

Kit components described on pages 464–465.

Contains 1mL each of these mixtures.31029: 604 Phenols Mix31030: 605 Benzidines Mix31031: 606 Phthalate Esters Mix31032: 607 Nitrosamines Mix31033: 609 Nitroaromatics/Isophorone Mix31011: 610 PAH Mix (SV Calibration Mix #5)31034: 611 Haloethers Mix31035: 612 Chlorinated Hydrocarbons Mix


625 Kit

Because most laboratories do not routinely analyze pesticides, PCBs, toxaphene, andchlordane in their calibration mixtures for Method 625, these mixtures are not includedin the 625 Kit. They may be purchased separately or in the 608 Complete Kit. See page 465.

cat. # 31036 (kit)

kit





EEaacchh 1155--ppkk.. 2255--ppkk..2,000µg/mL each in methylene chloride, 1mL/ampul

31206 31206.15 31206.254,000µg/mL each in methylene chloride, 1mL/ampul

31006 31006.15 31006.25


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600 Series Methods

also availableFor a complete listing of solutions of individual environmentalcompounds, please see pages 443-448.

Aroclor Solutions

4-bromofluorobenzeneVOA Tuning Compound


decafluorotriphenylphosphine (DFTPP)SV Tuning Compound


Tuning Mixtures

benzidine4,4'-DDT

decafluorotriphenylphosphine (DFTPP)pentachlorophenol

GC/MS Tuning Mixture (4 components)


Technical Chlordane, Toxaphene Solutions





Neat, 1gcat. # 33027 (ea.)

A = acetone; H = hexane; I = isooctane; TO = transformer oil (PCB-free)

Volume is 1mL/ampul. Concentration is µg/mL unless otherwise noted.

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceechlordane (technical) H 1,000 32021chlordane (technical) I 5,000 32072chlordane (technical) M 2,000 32016toxaphene H 1,000 32005toxaphene I 5,000 32071toxaphene M 2,000 32015H = hexane; I = isooctane; M = methanol


CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceeAroclor 1016 H 1,000 32006Aroclor 1016 I 200 32064Aroclor 1016 TO 50mg/kg 32075Aroclor 1016 TO 500mg/kg 32076Aroclor 1221 H 1,000 32007Aroclor 1221 I 200 32065Aroclor 1221 TO 50mg/kg 32077Aroclor 1221 TO 500mg/kg 32078Aroclor 1232 H 1,000 32008Aroclor 1232 I 200 32066Aroclor 1232 TO 50mg/kg 32079Aroclor 1232 TO 500mg/kg 32080Aroclor 1242 H 1,000 32009Aroclor 1242 I 200 32067Aroclor 1242 TO 50mg/kg 32081Aroclor 1242 TO 500mg/kg 32082Aroclor 1248 H 1,000 32010Aroclor 1248 I 200 32068Aroclor 1248 TO 50mg/kg 32083Aroclor 1248 TO 500mg/kg 32084Aroclor 1254 H 1,000 32011Aroclor 1254 I 200 32069Aroclor 1254 TO 50mg/kg 32085Aroclor 1254 TO 500mg/kg 32086Aroclor 1260 H 1,000 32012Aroclor 1260 I 200 32070Aroclor 1260 TO 50mg/kg 32087Aroclor 1260 TO 500mg/kg 32088Aroclor 1262 H 1,000 32409Aroclor 1268 H 1,000 32410Aroclor 1016/1260 H 1,000 32039Aroclor 1016/1260 I 200 32299Aroclor 1016/1260 A 400 32456


Restek’s Learning NetworkSign up for our widely acclaimed seminars today!

Visit www.restek.com/seminars

Restek training seminars are full-day courses presented inan engaging multimedia format. They are equally valuable tobeginning chromatographers, those who have moderateexperience and want a better understanding of the subjectmatter, and those interested in the “best practices” and latesttechnologies. No sales pitch is presented, just the facts onhow to make your chromatography results better. Visitwww.restek.com/seminars for more information.


470 www.restek.com 800-356-1688 or 814-353-1300


8000 Series Methods


418.1 . . . . . . . . . . . . . . . . . .Total Recoverable Petroleum Hydrocarbons (TRPH)

1311 . . . . . . . . . . . . . . . . . .Toxicity Characteristics Leaching Procedure (TCLP)

1664 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Oil & Grease

3500 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Organic Extraction Surrogates

8010 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Halogenated Volatile Organics

8011 . . . . . . . . . . . . . . . . . . .1,2-Dibromoethane, 1,2-Dibromo-3-Chloropropane

8020 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Aromatic Volatile Organics

8021 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Volatile Organics

8040 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Phenols

8061A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Phthalate Esters

8080, 8081 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Chlorinated Pesticides

8082, 8082A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .PCBs


8095 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Explosives by GC

8100 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Polycyclic Aromatic Hydrocarbons

8140, 8141 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Organophosphorus Pesticides

8150, 8151, 8151A . . . . . . . . . . . . . . . . . . . . . . . . . .Chlorinated Acid Herbicides

8240 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Volatile Organic Compounds (VOC)

8260, 8260A, 8260B . . . . . . . . . . . . . . . . . . .Volatile Organic Compounds (VOC)

8270D, 8270C . . . . . . . . . . . . . . . . . . . . . . . . . .Semivolatile Organic Compounds

8310 . . . . . . . . . . . . . . . . . . . . . . . . . .Polycyclic Aromatic Hydrocarbons (PAHs)

8315 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Aldehydes/Ketones-DNPH by HPLC

8321 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Chlorinated Acids by HPLC

8330 . . . . . . . . . . . . . . . . . . . . . . . . . . .Nitroaromatics and Nitramines by HPLC

8000 Series Methods - Resource Conservation and Recovery Act (RCRA)

Method 418.1 (Total Recoverable PetroleumHydrocarbons [TRPH])

Method 1311 (Toxicity Characteristics LeachingProcedure [TCLP]) cont'd

Method 1311 (Toxicity Characteristics LeachingProcedure [TCLP])

benzene2-butanone (MEK)carbon tetrachloridechlorobenzenechloroform1,4-dichlorobenzene

1,2-dichloroethane1,1-dichloroethenetetrachloroethenetrichloroethenevinyl chloride

TCLP VOA Mix (11 components)

2,000µg/mL each in P&T methanol:water (90:10), 1mL/ampulcat. # 30024 (ea.)

2-methylphenol3-methylphenol4-methylphenol

pentachlorophenol2,4,5-trichlorophenol2,4,6-trichlorophenol

TCLP Acid Mix (6 components)


1,4-dichlorobenzene2,4-dinitrotoluenehexachlorobenzenehexachlorobutadiene

hexachloroethanenitrobenzenepyridine

TCLP B/N Mix (7 components)


γ-BHC (lindane)endrinheptachlor

heptachlor epoxide (isomer B)methoxychlor

TCLP Pesticide Mix (5 components)


2,4-D (free acid) Silvex (free acid)TCLP Herbicide Mix (2 components)


toxapheneTCLP Toxaphene Mix


chlordane (technical)TCLP Chlordane Mix


Method 1664 (Oil & Grease)

hexadecane stearic acid1664 Oil & Grease Mix (2 components)


Method 3500 (Organic Extraction Surrogates)

High-Concentration Surrogates and

Matrix Spike Mixtures for SW-846

• Highest concentrations commercially available—reduces costper sample extract.

• Convenient 1mL and 5mL packaging.

See Method 8270, pages 479-482.

Resprep Oil & Grease SPE Disks also available. See page 397.

chlorobenzene 25.0% (v/v)n-hexadecane 37.5%

isooctane 37.5%418.1 Calibration Mix (3 components)

1mL/ampulcat. # 30080 (ea.)

470-478_ARM_8000series1.qxp 11/22/2010 8:32 PM Page 470

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8000 Series MethodsMethod 8010 (Halogenated Volatile Organics)

benzyl chloridebromodichloromethanebromoformcarbon tetrachloridechlorobenzene1,2-dichlorobenzene1,3-dichlorobenzene1,1-dichloroethene

trans-1,2-dichloroethenecis-1,3-dichloropropenetrans-1,3-dichloropropenemethylene chloridetetrachloroethenetrichloroethene1,2,3-trichloropropane

8010A Calibration Mix #2 (15 components)


bromobenzene2-chloroethyl vinyl etherchloroformdibromochloromethanedibromomethane1,4-dichlorobenzene1,1-dichloroethane

1,2-dichloroethane1,2-dichloropropane1,1,1,2-tetrachloroethane1,1,2,2-tetrachloroethane1,1,1-trichloroethane1,1,2-trichloroethane

8010A Calibration Mix #3 (13 components)


benzeneethylbenzenetoluene

m-xyleneo-xylenep-xylene

BTEX Standard (6 components)



2,000µg/mL each in P&T methanol (m-xylene and p-xylene at 1,000µg/mL), 1mL/ampulcat. # 30488 (ea.)

Method 8010 (Halogenated Volatile Organics) cont'd

Method 8011 (1,2-Dibromoethane, 1,2-Dibromo-3-chloropropane)

1,2-dibromo-3-chloropropane (DBCP)1,2-dibromoethane (EDB)

8011 Calibration Mix—EDB/DBCP (2 components)


Method 8020 (Aromatic Volatile Organics)

benzenechlorobenzene1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzene

ethylbenzenetoluenem-xyleneo-xylenep-xylene

8020A Calibration Mix (10 components)







bromochloromethane2-bromo-1-chloropropane

1,4-dichlorobutane624 Internal Standard Mix (3 components)




Requires a high-purity VOC single-stage regulator. See page 433. No data pack available.Quantity discounts not available.

BTEX Gas Mix (6 components)

CCyylliinnddeerr CCoonnssttrruuccttiioonn:: aluminumCCyylliinnddeerr FFiittttiinngg:: CGA-180 outlet

1ppm in nitrogen, 104 liters @ 1,800psicat. # 34414 (ea.)

100ppb in nitrogen, 104 liters @ 1,800psicat. # 34428 (ea.)

1ppm in nitrogen, 110 liters @ 1,800psi (Pi-marked Cylinder)cat. # 34414-PI (ea.)

100ppb in nitrogen, 110 liters @ 1,800psi (Pi-marked Cylinder)cat. # 34428-PI (ea.)

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriiccee4-bromofluorobenzene PTM 2,000 300261,4-difluorobenzene PTM 2,000 30032fluorobenzene PTM 2,000 30030α,α,α-trifluorotoluene PTM 2,000 30048


Internal and Surrogate Standards


Spectra 104L Cylinders:

Size: 8 x 24 cm Volume/Pressure: 104 liters of gas @ 1,800 psiWeight: 1.5 lbs/0.7 kg

Scotty 110L Cylinders

(Pi-marked Cylinders for

EU Regulations):

Size: 8.3 x 29.5 cm Volume/Pressure: 110 liters of gas @ 1,800 psiWeight: 2.2 lbs/1 kgUS DOT Specs: 3AL2216

tech tipTo analyze compounds listed in Methods 8010 and 8020 concurrently,add BTEX Standard to the calibration curve mix.

Note: Method 8010 does not specify internal standards to be used. The analystmust select appropriate internal standards based on the particular samples beinganalyzed. Potential internal standards are available. See page 467.



and/or lot number)



472 www.restek.com 800-356-1688 or 814-353-1300


8000 Series MethodsMethod 8021 (Volatile Organics)


2-fluorophenol 2,4,6-tribromophenol8040 Surrogate Mix (2 components)

2,000µg/mL each in isopropanol, 1mL/ampulcat. # 31090 (ea.)

4-chloro-3-methylphenol2,4-dichlorophenol2-methyl-4,6-dinitrophenol3-methylphenol2-nitrophenol

4-nitrophenolpentachlorophenolphenol2,4,6-trichlorophenol

8040 Phenols Mix #1 (9 components)


sec-butyl-4,6-dinitrophenol (dinoseb)2-chlorophenol2,6-dichlorophenol2,4-dimethylphenol2,4-dinitrophenol

2-methylphenol4-methylphenol2,3,4,6-tetrachlorophenol2,4,5-trichlorophenol

8040 Phenols Mix #2 (9 components)


Method 8061A (Phthalate Esters)

benzyl butyl phthalate bis(2-ethylhexyl)phthalate8061A Matrix Spike Solution (2 components)


Benzyl Benzoate (Internal Standard)


dibenzyl phthalatediphenyl isophthalate

diphenyl phthalate8061A Surrogate Standard (3 components)


Method 8080, 8081 (Chlorinated Pesticides)



Organochlorine Pesticide Mix AB #1 (20 components)


Method 8061A (Phthalate Esters) cont'd

1-bromo-2-chloroethane1-chloro-3-fluorobenzene

fluorobenzene8021/502.2 Surrogate Mix #1 (3 components)


1-bromo-2-chloroethane4-bromochlorobenzene

1-chloro-3-fluorobenzenefluorobenzene



2-bromochlorobenzene 1,4-dichlorobutane8021 Surrogate Mix (2 components)


2-bromo-1-chloropropane fluorobenzene502.2 Internal Standard Mix #2 (2 components)


benzyl butyl phthalatebis(2-n-butoxyethyl)phthalatebis(2-ethoxyethyl)phthalatebis(2-ethylhexyl)phthalatebis(2-methoxyethyl)phthalatebis(4-methyl-2-pentyl)phthalatedi-n-butylphthalatediethylphthalate

di-n-hexyl phthalatedimethylphthalatedi-nonyl phthalatedi-n-octyl phthalatedipentylphthalatephthalic acid dicyclohexyl esterphthalic acid diisobutyl ester

EPA 8061A Phthalate Esters Mixture (15 components)

1,000µg/mL each in hexane:acetone (80:20), 1mL/ampulcat. # 33227 (ea.)

hexyl 2-ethylhexyl phthalateEPA 8061A Hexyl 2-Ethylhexyl Phthalate Standard

1,000µg/mL in hexane:acetone (80:20), 1mL/ampulcat. # 33228 (ea.)

Contains 1mL each of these mixtures.33227: EPA 8061A Phthalate Esters Mixture33228: EPA 8061A Hexyl 2-Ethylhexyl Phthalate Standard


EPA 8061A Phthalate Esters Kit

cat. # 33229 (kit)

kit




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8000 Series Methods

aldrin 8µg/mLα-BHC 8β-BHC 8δ-BHC 8γ-BHC (lindane) 8α-chlordane 8γ-chlordane 84,4'-DDD 164,4'-DDE 164,4'-DDT 16

dieldrin 16endosulfan I 8endosulfan II 16endosulfan sulfate 16endrin 16endrin aldehyde 16endrin ketone 16heptachlor 8heptachlor epoxide (isomer B) 8methoxychlor 80


In hexane:toluene (1:1), 1mL/ampulcat. # 32292 (ea.)

Method 8080, 8081 (Chlorinated Pesticides) cont'd

Method 8082, 8082A (PCBs)

2-chlorobiphenyl (BZ #1)2,3-dichlorobiphenyl (BZ #5)2,2',5-trichlorobiphenyl (BZ #18)2,4',5-trichlorobiphenyl (BZ #31)2,2',3,5'-tetrachlorobiphenyl (BZ #44)2,2',5,5'-tetrachlorobiphenyl (BZ #52)2,3',4,4'-tetrachlorobiphenyl (BZ #66)2,2',3,4,5'-pentachlorobiphenyl (BZ #87)2,2',4,5,5'-pentachlorobiphenyl (BZ #101)2,3,3',4',6-pentachlorobiphenyl (BZ #110)2,2',3,4,4',5'-hexachlorobiphenyl (BZ #138)2,2',3,4,5,5'-hexachlorobiphenyl (BZ #141)2,2',3,5,5',6-hexachlorobiphenyl (BZ #151)2,2',4,4',5,5'-hexachlorobiphenyl (BZ #153)2,2',3,3',4,4',5-heptachlorobiphenyl (BZ #170)2,2',3,4,4',5,5'-heptachlorobiphenyl (BZ #180)2,2',3,4,4',5',6-heptachlorobiphenyl (BZ #183)2,2',3,4',5,5',6-heptachlorobiphenyl (BZ #187)2,2',3,3',4,4',5,5',6-nonachlorobiphenyl (BZ #206)

PCB Congener Mix, Method 8082A (19 components)

100µg/mL each in isooctane, 1mL/ampulcat. # 32416 (ea.)

Method 8095 (Explosives by GC)

3,4-dinitrotoluene8095 Surrogate


2-methyl-4-nitroaniline8095 Surrogate


3,5-dinitroaniline*nitrobenzenenitroglycerine2-nitrotoluene

3-nitrotoluene4-nitrotoluenePETN

8095 Matrix Spike Mix B (7 components)**

1,000µg/mL each in acetonitrile (*3,5-dinitroaniline at 200µg/mL), 1mL/ampulcat. # 31610 (ea.)

2-amino-4,6-dinitrotoluene4-amino-2,6-dinitrotoluene1,3-dinitrobenzene2,4-dinitrotoluene2,6-dinitrotoluene

HMXRDXtetryl1,3,5-trinitrobenzene2,4,6-trinitrotoluene

8095 Calibration Mix A (10 components)**


3,5-dinitroaniline*nitrobenzenenitroglycerine2-nitrotoluene

3-nitrotoluene4-nitrotoluenePETN

8095 Calibration Mix B (7 components)**

5,000µg/mL each in acetonitrile (*3,5-dinitroaniline at 1,000µg/mL), 1mL/ampulcat. # 31608 (ea.)

These materials support nitroaromatic, nitramine, andnitroester analyses by GC/ECD (Method 8095).1,2 Compoundslisted are explosives, manufacturing intermediates, or degrada-tion products. Method 8095 mixtures contain the componentsat concentration ratios appropriate for ECD.

RReeffeerreenncceess ((NNoott aavvaaiillaabbllee ffrroomm RReesstteekk..))1US Environmental Protection Agency. Test Methods for Evaluating Solid Waste,Physical/Chemical Methods. SW-846, Proposed Draft Update IVB, Office of SolidWaste, Washington, DC, 1999.2M. E. Walsh, T. Ranney, J. Chromatogr. Sci., Vol. 36, pp. 406-416, August 1998.

decachlorobiphenyl 2,4,5,6-tetrachloro-m-xylene

Pesticide Surrogate Mix (2 components)






decachlorobiphenyl 200µg/mL 2,4,5,6-tetrachloro-m-xylene 100Pesticide Surrogate Mix (2 components)


also availableMethod 8095 single-component explosives solutions. See next page.


2-amino-4,6-dinitrotoluene4-amino-2,6-dinitrotoluene1,3-dinitrobenzene2,4-dinitrotoluene2,6-dinitrotoluene

HMX*RDXtetryl1,3,5-trinitrobenene2,4,6-trinitrotoluene

8095 Matrix Spike Mix A (10 components)**

200µg/mL each in acetonitrile (*HMX at 2,000µg/mL), 1mL/ampulcat. # 31609 (ea.)

**Meet all DOT requirements. Available only to customers or distributors insidethe 48 contiguous United States; items may not be resold for export.


474 www.restek.com 800-356-1688 or 814-353-1300


8000 Series MethodsMethods 8140, 8141 (Organophosphorus Pesticides)

azinphos methylbolstar (sulprofos)chlorpyrifoscoumaphosdemeton, O & Sdiazinondichlorvosdisulfotonethopropfensulfothion

fenthionmerphosmethyl parathionmevinphosnaledphorateronnelstirofostokuthion (prothiofos)trichloronate

8140/8141 OP Pesticide Calibration Mix A (20 components)

200µg/mL each in hexane:acetone (95:5), 1mL/ampulcat. # 32277 (ea.)

dimethoateEPNmalathionmonocrotophos

parathionsulfoteppTEPP

8141 OP Pesticide Calibration Mix B (7 components)

200µg/mL each in hexane:acetone (95:5), 1mL/ampulcat. # 32278 (ea.)

8140/8141 Internal Standards & Surrogates



also availableAdditional nitrogen/phosphorus pesticide mixes are listed on page 458.





Method 8100 (Polycyclic Aromatic Hydrocarbons)

benzo(j)fluoranthenedibenzo(a,h)acridinedibenzo(a,j)acridine7H-dibenzo(c,g)carbazole

dibenzo(a,e)pyrenedibenzo(a,h)pyrenedibenzo(a,i)pyrene3-methylcholanthrene

PAH Supplement Mix for Method 8100 (8 components)


NNPPDD DDeetteeccttoorr::Internal Standard: 1-bromo-2-nitrobenzene (cat.# 32279)Surrogate: 4-chloro-3-nitrobenzotrifluoride (cat.# 32282)

FFPPDD DDeetteeccttoorr::Internal Standard: none recommendedSurrogate: tributylphosphate (cat.# 32280) and triphenylphosphate (cat.# 32281)



ACN = acetonitrile; EA = ethyl acetate; M = methanol

Single-Component Explosives Solutions


Method 8095 (Explosives by GC) cont'd

also availableOur 30 m, 0.32 mm ID, 0.50 μm Rtx®-OPPesticidescolumn provides fast analyses, low bleed, and better resolution than alternative choices.


*Meet all DOT requirements. Available only to customers or distributors insidethe 48 contiguous United States; items may not be resold for export.

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriiccee2-amino-4,6-dinitrotoluene ACN 1,000 316704-amino-2,6-dinitrotoluene ACN 1,000 31671ammonium picrate* ACN 2,000 318903,5-dinitroaniline ACN 1,000 316611,2-dinitrobenzene M 1,000 314531,3-dinitrobenzene ACN 1,000 316622,4-dinitrotoluene ACN 1,000 316632,6-dinitrotoluene ACN 1,000 316643,4-dinitrotoluene EA 2,000 339013,4-dinitrotoluene M 1,000 31452EGDN* M 1,000 31601HMX* ACN 1,000 316652-methyl-4-nitroaniline M 1,000 31612nitrobenzene ACN 1,000 31657nitroglycerin* M 1,000 31498nitroguanidine* M 1,000 316022-nitrotoluene ACN 1,000 316593-nitrotoluene ACN 1,000 316604-nitrotoluene ACN 1,000 31658PETN (pentaerythritol tetranitrate)* M 1,000 31600picric acid* M 1,000 31499propylene glycol dinitrate

(PGDN) M 1,000 31821RDX* ACN 1,000 31666tetryl* ACN 1,000 316671,3,5-trinitrobenzene* ACN 1,000 316682,4,6-trinitrotoluene* ACN 1,000 31669

The preparation of accurate and stable OP standards is compli-cated by their sensitivity to light, pH, heat, and water. Restek hasspent more than four years researching OP pesticide mixtures.Our research results:

• OP standards have a maximum of 12 months shelf life due totheir volatility. It is our policy to ship standards with no lessthan 3 months shelf life remaining.

• Solvents are assayed to ensure low water content.• Reference mixtures are stored in deactivated amber ampules,

under an inert atmosphere.• Purity is determined by a combination of methods: GC/FID,

GC/FPD, GC/NPD, DSC, and HPLC/UV.


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8000 Series Methods


see Method 555, page 463

and Method 8321, page 484

Method 8150, 8151, 8151A (Chlorinated Acid Herbicides)

Picloram


3,5-dichlorobenzoic acid methyl ester

3,5-Dichlorobenzoic Acid Methyl Ester Surrogate Standard



3,5-dichlorobenzoic acid3,5-Dichlorobenzoic Acid Surrogate Standard


MCPA


MCPP


4,4'-dibromooctafluorobiphenylHerbicide Internal Standard




2,4-dichlorophenylacetic acid (DCAA)

Herbicide Surrogate






2,4-D2,4-DB2,4,5-T2,4,5-TP









dalapon

Herbicide Mix #2





dalapon methyl esterDDeerriivvaattiizzeedd FFoorrmm



MCPA MCPP




MCPA methyl ester MCPP methyl esterDDeerriivvaattiizzeedd FFoorrmm


acifluorfenbentazonchlorambenDCPA diacid

3,5-dichlorobenzoic acid4-nitrophenolpentachlorophenolpicloram




acifluorfen methyl esterbentazon methyl esterchloramben methyl esterDCPA (Dacthal)

3,5-dichlorobenzoic acid methyl ester4-nitroanisolepentachloroanisolepicloram methyl ester






476 www.restek.com 800-356-1688 or 814-353-1300


8000 Series Methods




(Pi-marked Cylinders

for EU Regulations):


bromodichloromethanebromoformcarbon tetrachloridechlorobenzene2-chloroethyl vinyl etherchloroformdibromochloromethane1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzene1,1-dichloroethane1,2-dichloroethane

1,1-dichloroethenetrans-1,2-dichloroethene1,2-dichloropropanecis-1,3-dichloropropenetrans-1,3-dichloropropenemethylene chloride1,1,2,2-tetrachloroethanetetrachloroethene1,1,1-trichloroethane1,1,2-trichloroethanetrichloroethene

VOA Purgeable Halocarbon Mix #1 (23 components)


allyl alcohol2-chloroethanolethanol

isobutyl alcoholpropargyl alcohol

8240 Alcohols Mix (5 components)


allyl chloridebenzyl chloride1,2-dibromo-3-chloropropane1,2-dibromoethanedibromomethanecis-1,4-dichloro-2-butene

trans-1,4-dichloro-2-butene1,4-dioxaneiodomethanepentachloroethane1,1,1,2-tetrachloroethane1,2,3-trichloropropane

8240 Volatiles Mix #1A (12 components)


carbon disulfide2-picoline

pyridine8240 Volatiles Mix #2A (3 components)


acrylonitrileethyl methacrylatemalononitrilemethacrylonitrile

methyl methacrylatepropionitrilestyrene

8240 Nitriles Mix (7 components)


restek innovation!Xylene-Free, Highly-Purified Chloroprene Standard

The R&D chemists at Restek developed a novel procedure that producesa pure, quantitative chloroprene solution specially stabilized in purge &trap-grade methanol. The entire procedure is performed under carefullymonitored conditions to prevent any contamination or polymerizationof the highly reactive, neat chloroprene. The final solution is specially

stabilized, allowing analysts to make dilutions for working standards inunmodified purge & trap-grade methanol.

Note: Because chloroprene is not analyzed by many laboratories, it is notincluded in our 8240 VOA mixes. Chloroprene is included in our 8260BMegaMix® Calibration Mix. Refer to page 477.

acetone2-butanone (MEK)


VOA Calibration Mix #1 (ketones) (4 components)


Method 8240 (Volatile Organic Compounds [VOC])

ethylene glycol propylene glycolGlycols Standard (2 components)















Requires a high-purity VOC single-stage regulator. See page 433.No data pack available.Quantity discounts not available.






100ppb in nitrogen, 110 liters @ 1,800psi (Pi-marked Cylinder)cat. # 34428-PI (ea.)


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8000 Series Methods

chlorobenzene-d51,4-dichlorobenzene-d4

fluorobenzene8260A Internal Standard Mix (3 components)


4-bromofluorobenzenedibromofluoromethane

1,2-dichloroethane-d4toluene-d8

8260A Surrogate Mix (4 components)


benzenechlorobenzene1,1-dichloroethene

toluenetrichloroethylene

8260B Matrix Spike Mix (5 components)



1,4-difluorobenzenepentafluorobenzene

8260 Internal Standard Mix (4 components)


4-bromofluorobenzenedibromofluoromethane

toluene-d88260 Surrogate Mix (3 components)


bromoformchlorobenzenechloromethane

1,1-dichloroethane1,1,2,2-tetrachloroethane

8240/8260 System Performance Check Mix (5 components)


chloroform1,1-dichloroethene1,2-dichloropropane

ethylbenzenetoluenevinyl chloride

8240/8260 Calibration Check Mix (6 components)


Method 8260, 8260A, 8260B (Volatile Organic Compounds [VOC])

acetonitrileacrylonitrileallyl chloridebenzenebromobenzenebromochloromethanebromodichloromethanebromoformn-butylbenzenesec-butylbenzenetert-butylbenzenecarbon disulfidecarbon tetrachloridechlorobenzene2-chloroethanolchloroformchloroprene2-chlorotoluene4-chlorotoluenedibromochloromethane1,2-dibromo-3-chloropropane (DBCP)1,2-dibromoethane (EDB)dibromomethane1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzenecis-1,4-dichloro-2-butenetrans-1,4-dichloro-2-butene1,1-dichloroethane1,2-dichloroethane1,1-dichloroethenecis-1,2-dichloroethenetrans-1,2-dichloroethene1,2-dichloropropane1,3-dichloropropane2,2-dichloropropane1,1-dichloropropenecis-1,3-dichloropropene

trans-1,3-dichloropropenediethyl ether (ethyl ether)1,4-dioxaneethylbenzeneethyl methacrylatehexachloro-1,3-butadieneiodomethaneisobutyl alcoholisopropylbenzene (cumene)4-isopropyl toluene (p-cymene)methacrylonitrilemethyl acrylatemethyl methacrylatemethylene chloride (dichloromethane)naphthalenenitrobenzene2-nitropropanepentachloroethanepropionitrilen-propylbenzenestyrene1,1,1,2-tetrachloroethane1,1,2,2-tetrachloroethanetetrachloroethenetetrahydrofurantoluene1,2,3-trichlorobenzene1,2,4-trichlorobenzene1,1,1-trichloroethane1,1,2-trichloroethanetrichloroethene1,2,3-trichloropropane1,1,2-trichlorotrifluororethane (CFC-113)1,2,4-trimethylbenzene1,3,5-trimethylbenzenem-xyleneo-xylenep-xylene

8260B MegaMix® Calibration Mix (76 components)


2-Chloroethyl Vinyl Ether


1,4-Dioxane-d8


4-Bromofluorobenzene







Neat, 1gcat. # 33027 (ea.)






Contains 1mL each of these mixtures.30633: 8260B MegaMix30265: 2-chlorethyl vinyl ether


8260B MegaMix® Calibration Mix Kit

cat. # 30475 (kit)

kit


478 www.restek.com 800-356-1688 or 814-353-1300


8000 Series Methods

also availableOur Rtx®-VMS column is your best choice for EPAMethod 8260.

• Fastest cycle times for VOCs. • Tuned selectivity for VOCs.• Excellent separation of gases.


Chloroprene


Vinyl Acetate


Method 8260, 8260A, 8260B (Volatile Organic Compounds [VOC]) cont'd

1,2-Dichlorotetrafluoroethane (CFC-114)


CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceeethanol W 10,000 30466methanol W 10,000 30467tert-amyl alcohol PTM 10,000 30631ethanol PTM 2,000 30288methyl tert-butyl ether (MTBE) PTM 2,000 30402tert-amyl ethyl ether (TAEE) PTM 2,000 30617diisopropyl ether (DIPE) PTM 2,000 30627ethyl-tert-butyl ether (ETBE) PTM 2,000 30628tert-amyl methyl ether (TAME) PTM 2,000 30629tert-butanol-d9 PTM 20,000 30618tert-butanol PTM 50,000 30470

PTM = purge & trap grade methanol; W = DI water

Single-Component Oxygenates Solutions


diisopropyl ether (DIPE) 2,000µg/mLethyl-tert-butyl ether (ETBE) 2,000tert-amyl methyl ether (TAME) 2,000

tert-butyl alcohol 10,000methyl tert-butyl ether (MTBE) 2,000

California Oxygenates Mix (5 components)


tert-amyl ethyl ether (TAEE) 2,000µg/mL

tert-amyl methyl ether (TAME) 2,000tert-butyl alcohol (TBA) 10,000

diisopropyl ether (DIPE) 2,000ethyl-tert-butyl ether (ETBE) 2,000methyl tert-butyl ether (MTBE) 2,000

Oxygenates (6 components)


vinyl acetateethyl acetateisopropyl acetate

n-propyl acetaten-butyl acetate

8260B Acetate Mix (5 components)


n-amyl acetatebutyl acetateethyl acetateisopropyl acetate

methyl acetatepropyl acetatevinyl acetate

8260B Acetate Mix (Revised) (7 components)






Components are listed on pages 452, 453, 477, and 486.

Components are listed on pages 452, 453, 477, and 486.

Acrolein5,000µg/mL in P&T methanol, 1mL/ampul

cat. # 30645 (ea.) 5,000µg/mL in water, 1mL/ampul

cat. # 30646 (ea.)

Contains 1mL each of these mixtures.30042: 502.2 Calibration Mix #130043: 502.2 Calibration Mix #230044: 502.2 Calibration Mix #330045: 502.2 Calibration Mix #430046: 502.2 Calibration Mix #530047: 502.2 Calibration Mix #630067: 4-bromofluorobenzene (2,500µg/mL)30240: 8260A Surrogate Mix (2,500µg/mL)30241: 8260A Internal Standard Mix (2,500µg/mL)30075: 8240/8260 System Performance Check Mix30005: VOA Matrix Spike Mix (2,500µg/mL)


8260A Volatile Organics Kit (2,000μg/mL)

Changes in this revision of the method include modification ofthe recommended internal standard and surrogate solutions.

cat. # 30242 (kit)

kit

Contains 1mL each of these mixtures.30042: 502.2 Calibration Mix #130043: 502.2 Calibration Mix #230044: 502.2 Calibration Mix #330045: 502.2 Calibration Mix #430046: 502.2 Calibration Mix #530047: 502.2 Calibration Mix #630067: 4-bromofluorobenzene (2,500µg/mL)30073: 8260 Surrogate Mix (2,500µg/mL)30074: 8260 Internal Standard Mix (2,500µg/mL)30075: 8240/8260 System Performance Check Mix30005: VOA Matrix Spike Mix (2,500µg/mL)


8260 Volatile Organics Kit (2,000μg/mL)

cat. # 30076 (kit)

kit

ChromaBLOGraphyTopical and timely insights from top chromatographers.

Visit us at blog.restek.com


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8000 Series Methods

Method 8270D, 8270C (Semivolatile Organic Compounds)

benzidine4,4'-DDT

DFTPPpentachlorophenol

GC/MS Tuning Mixture (4 components)






Neat, 1gcat. # 33027 (ea.)


2,500µg/mL in methylene chloride, 1mL/ampulcat. # 31001






31006 31006.15 31006.25

acenaphthene-d10chrysene-d121,4-dichlorobenzene-d41,4-dioxane-d8


Revised SV Internal Standard Mix (7 components)



31886 31886.15 31886.25

2-fluorobiphenylnitrobenzene-d5

p-terphenyl-d14B/N Surrogate Mix (4/89 SOW) (3 components)





33028 33028.15 33028.25


p-terphenyl-d14pyrene-d10

Revised B/N Surrogate Mix (4 components)




31889 31889.15 31889.25

2-fluorophenolphenol-d6

2,4,6-tribromophenolAcid Surrogate Mix (4/89 SOW) (3 components)

EEaacchh 1155--ppkk.. 2255--ppkk..2,000µg/mL each in methanol, 1mL/ampul

31025 31025.15 31025.2510,000µg/mL each in methanol, 1mL/ampul



33029 33029.15 33029.25

acenaphthene1,4-dichlorobenzene2,4-dinitrotoluene

N-nitroso-di-n-propylaminepyrene1,2,4-trichlorobenzene

B/N Matrix Spike Mix (6 components)





33030 33030.15 33030.25

4-chloro-3-methylphenol2-chlorophenol4-nitrophenol

pentachlorophenolphenol

Acid Matrix Spike Mix (5 components)





33031 33031.15 33031.25

Special pricing on

multi-packs of 15 & 25!

EPA 8270 Internal,Surrogate & Spike Mixes!

up to

40%OFFlist price

• 8270 Matrix Spike Mix

• SV Internal Standard Mix

• Revised SV Internal Standard Mix

• B/N Surrogate Mix (4/89 SOW)

• Revised B/N Surrogate Mix

• Acid Surrogate Mix (4/89 SOW)

• B/N Matrix Spike Mix


480 www.restek.com 800-356-1688 or 814-353-1300


8000 Series MethodsMethod 8270D, 8270C (Semivolatile Organic Compounds) cont'd

acenaphtheneacenaphthyleneanilineanthraceneazobenzene1

benzo(a)anthracenebenzo(a)pyrenebenzo(b)fluoranthenebenzo(ghi)perylenebenzo(k)fluoranthenebenzyl alcoholbenzyl butyl phthalatebis(2-chloroethoxy)methanebis(2-chloroethyl)etherbis(2-chloroisopropyl)etherbis(2-ethylhexyl)adipatebis(2-ethylhexyl)phthalate4-bromophenyl phenyl ethercarbazole4-chloroaniline4-chloro-3-methylphenol2-chloronaphthalene2-chlorophenol4-chlorophenyl phenyl etherchrysenedibenzo(a,h)anthracenedibenzofuran1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzene2,4-dichlorophenoldiethyl phthalate2,4-dimethylphenoldimethyl phthalatedi-n-butyl phthalate1,2-dinitrobenzene1,3-dinitrobenzene1,4-dinitrobenzene4,6-dinitro-2-methylphenol2,4-dinitrophenol2,4-dinitrotoluene2,6-dinitrotoluenedi-n-octyl phthalatediphenylamine2

fluoranthenefluorene

hexachlorobenzenehexachlorobutadienehexachlorocyclopentadienehexachloroethaneindeno(1,2,3-cd)pyreneisophorone1-methylnaphthalene2-methylnaphthalene2-methylphenol3-methylphenol4-methylphenolnaphthalene2-nitroaniline3-nitroaniline4-nitroanilinenitrobenzene2-nitrophenol4-nitrophenolN-nitrosodimethylamineN-nitroso-di-n-propylaminepentachlorophenolphenanthrenephenolpyrenepyridine2,3,4,6-tetrachlorophenol2,3,5,6-tetrachlorophenol1,2,4-trichlorobenzene2,4,5-trichlorophenol2,4,6-trichlorophenol

*3-methylphenol and 4-methylphenol concentration is 500µg/mL.

8270 MegaMix® (76 components)

1,000µg/mL each in methylene chloride, 1mL/ampul*cat. # 31850 (ea.)

Same list as 8270 MegaMix above.

8270 MegaMix® and 8270 Matrix Spike Mix include 3-methylphenol and 4-methylphenol at 1/2 x concentrationof other components.

8270 Matrix Spike Mix (76 components)

11,2-diphenylhydrazine (8270-listed analyte) decomposes to azobenzene (mixcomponent) in the injector.2N-nitrosodiphenylamine (8270-listed analyte) decomposes to diphenylamine(mix component) in the injector.

acenaphthenebenzo(a)pyrene1,4-dichlorobenzenedi-n-octyl phthalate

diphenylaminefluoranthenehexachlorobutadiene

8270 B/N Calibration Check Mix (7 components)


4-chloro-3-methylphenol2,4-dichlorophenol2-nitrophenol

pentachlorophenolphenol2,4,6-trichlorophenol

8270 Acid Calibration Check Mix (6 components)


2,4-dinitrophenolhexachlorocyclopentadiene

4-nitrophenolN-nitroso-di-n-propylamine

SV System Performance Check Mix (SPCC) (4 components)


benzidine3,3'-dichlorobenzidine

3,3'-dimethylbenzidine8270 Benzidines Mix (3 components)



also availableOur Rxi®-5Sil MS columns provide high response for 2,4-dinitrophenol, show excellent peak shapeof pyridine, and produce outstanding resolutionof PAHs.

See page 87.

EASIERcalibration




**3-methylphenol and 4-methylphenol concentration is 100µg/mL.

EEaacchh 1155--ppkk.. 2255--ppkk..200µg/mL each in methanol:methylene chloride (80:20), 5mL/ampul**

31687 31687.15 31687.25200µg/mL each in methanol:methylene chloride (80:20), 10mL/ampul**

33073 33073.15 33073.25


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8000 Series Methods


2-acetylaminofluorene4-aminobiphenylp-dimethylaminoazobenzene3,3'-dimethylbenzidineα,α,-dimethylphenethylamine

(free base)methapyrilene (free base)1-naphthylamine2-naphthylamine5-nitro-o-toluidine

N-nitrosodibutylamineN-nitrosodiethylamineN-nitrosomethylethylamineN-nitrosomorpholineN-nitrosopiperidineN-nitrosopyrrolidine1,4-phenylenediamine2-picolineo-toluidine

Appendix IX Mix #1 (18 components)


acetophenoneAramiteatrazinebenzaldehydebiphenylε-caprolactamchlorobenzilate1-chloronaphthalenediallatedibenzo(a,j)acridine2,6-dichlorophenol7,12-dimethylbenz(a)anthracene1,4-dioxanediphenyl etherethyl methacrylateethyl methanesulfonate

hexachloropropeneisodrinisosafrole (cis & trans)kepone3-methylcholanthrenemethyl methanesulfonate1,4-naphthoquinone4-nitroquinoline-N-oxidepentachlorobenzenepentachloroethanepentachloronitrobenzenephenacetinpronamidesafrole1,2,4,5-tetrachlorobenzene1,3,5-trinitrobenzene

Appendix IX Mix #2 (32 components)


dimethoatedisulfotonfamphurmethyl parathionO,O,O-triethyl phosphorothioate

parathion (ethyl parathion)phoratesulfoteppzinophos (thionazine)

Organophosphorus Pesticide Mix, 8270/Appendix IX

(9 components)


Method 8270D, 8270C (Semivolatile Organic Compounds) cont'd

benzoic acid4-chloro-3-methylphenol2-chlorophenol2,4-dichlorophenol2,6-dichlorophenol2,4-dimethylphenol4,6-dinitro-2-methylphenol2,4-dinitrophenoldinoseb2-methylphenol

3-methylphenol4-methylphenol2-nitrophenol4-nitrophenolpentachlorophenolphenol2,3,4,6-tetrachlorophenol2,4,5-trichlorophenol2,4,6-trichlorophenol



anilinebenzidine4-chloroaniline3,3'-dichlorobenzidinediphenylamine*2-nitroaniline

3-nitroaniline4-nitroanilineN-nitrosodimethylamineN-nitrosodi-n-propylaminepyridine

*N-nitrosodiphenylamine (8270-listed analyte) decomposes to diphenylamine(mix component) in the injector.


2,000µg/mL each in methylene chloride:methanol (85:15), 1mL/ampulcat. # 31619 (ea.)

Benzoic Acid





Aramitebis(2-chloroethyl)etherbis(2-chloroethoxy)methanebis(2-chloroisopropyl)ether4-bromophenyl phenyl etherchlorobenzilate2-chloronaphthalene4-chlorophenyl phenyl ether1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzene1,3-dinitrobenzene

hexachlorobenzenehexachlorobutadienehexachlorocyclopentadienehexachloroethanehexachloropropeneisodrinkeponepentachlorobenzenepentachloronitrobenzene1,2,4,5-tetrachlorobenzene1,2,4-trichlorobenzene



Contains 1mL each of these mixtures.31850: 8270 MegaMix31834: 605 Benzidines Calibration Mix31625: Appendix IX Mix #131806: Appendix IX Mix #2


8270/Appendix IX Kit

cat. # 31815 (kit)

kit




482 www.restek.com 800-356-1688 or 814-353-1300


8000 Series Methods

Aroclor Solutions



acenaphtheneacenaphthyleneanthracenebenzo(a)anthracenebenzo(a)pyrenebenzo(b)fluoranthenebenzo(ghi)perylenebenzo(k)fluoranthenechrysenedibenzo(a,h)anthracene

fluoranthenefluoreneideno(1,2,3-cd)pyrene3-methylcholanthrene1-methylnaphthalene2-methylnaphthalenenaphthalenephenanthrenepyrene



diallate (cis & trans)dimethoatedisulfotonfamphurmethyl parathion

parathionphoratepronamidethionazine (zinophos)O,O,O-triethyl phosphorothioate



Aramite


Method 8270D, 8270C (Semivolatile Organic Compounds) cont'd


acetophenoneazobenzene*benzyl alcoholbis(2-ethylhexyl)phthalatebutyl benzyl phthalatedibenzofurandiethyl phthalatedimethyl phthalatedi-n-butyl phthalatedi-n-octyl phthalate2,4-dinitrotoluene

2,6-dinitrotolueneethyl methanesulfonateisophoroneisosafrole (cis & trans)methyl methanesulfonate1,4-naphthoquinonenitrobenzene4-nitroquinoline-1-oxidephenacetinsafrole1,3,5-trinitrobenzene

*1,2-diphenylhydrazine (8270-listed analyte) decomposes to azobenzene(mix component) in the injector.



Contains 1mL each of these mixtures.31618: 8270 Calibration Mix #131619: 8270 Calibration Mix #231620: 8270 Calibration Mix #331621: 8270 Calibration Mix #431622: 8270 Calibration Mix #531623: 8270 Calibration Mix #631625: Appendix IX Mix #1


8270/Appendix IX Calibration Kit (2,000μg/mL)

cat. # 31627 (kit)

kit

Contains 1mL each of these mixtures.31618: 8270 Calibration Mix #131619: 8270 Calibration Mix #231620: 8270 Calibration Mix #331621: 8270 Calibration Mix #431622: 8270 Calibration Mix #5


8270 Calibration Kit (2,000μg/mL)

cat. # 31626 (kit)

kit



and/or lot number)



800-356-1688 or 814-353-1300 www.restek.com 483


8000 Series Methods

acenaphthene 100µg/mLacenaphthylene 100anthracene 100benzo(a)anthracene 10benzo(a)pyrene 10benzo(b)fluoranthene 10benzo(ghi)perylene 10benzo(k)fluoranthene 5chrysene 10

dibenzo(a,h)anthracene 10fluoranthene 10fluorene 100indeno(1,2,3-cd)pyrene 101-methylnaphthalene 1002-methylnaphthalene 100naphthalene 100phenanthrene 100pyrene 10

EPA Method 8310 Quality Control Check (18 components)

Method 8315 (Aldehydes/Ketones-DNPH by HPLC)Method 8310 (Polycyclic Aromatic Hydrocarbons[PAHs])

acenaphtheneacenaphthyleneanthracenebenzo(a)anthracenebenzo(a)pyrenebenzo(b)fluoranthenebenzo(ghi)perylenebenzo(k)fluoranthenechrysene

dibenzo(a,h)anthracenefluoranthenefluoreneindeno(1,2,3-cd)pyrene1-methylnaphthalene2-methylnaphthalenenaphthalenephenanthrenepyrene

EPA Method 8310 PAH Mixture (18 components)

500µg/mL each in acetonitrile, 1mL/ampulcat. # 31841 (ea.)

decafluorobiphenylEPA Method 8310 Surrogate Standard


In acetonitrile, 1mL/ampulcat. # 31843 (ea.)

acetaldehyde-DNPHacetone-DNPHacrolein-DNPHbenzaldehyde-DNPHn-butyraldehyde-DNPHcrotonaldehyde-DNPH2,5-dimethylbenzaldehyde-DNPHformaldehyde-DNPH

hexaldehyde-DNPHisovaleraldehyde-DNPHpropionaldehyde-DNPHm-tolualdehyde-DNPHo-tolualdehyde-DNPHp-tolualdehyde-DNPHvaleraldehyde-DNPH

Aldehyde-Ketone-DNPH TO-11A Calibration Mix

(15 components)

15µg/mL each in acetonitrile, 1mL/ampul*cat. # 31808 (ea.)

formaldehyde-DNPHFormaldehyde-DNPH Mix

500µg/mL in acetonitrile, 1mL/ampul*cat. # 31837 (ea.)

*Concentration calculated as the aldehyde/ketone.

*Concentration calculated as the aldehyde/ketone.Quantity discounts not available.

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceeacetaldehyde-2,4-DNPH ACN 100 33074acetone-2,4-DNPH ACN 100 33075benzaldehyde-2,4-DNPH ACN 100 33077n-butyraldehyde-2,4-DNPH ACN 100 33079crotonaldehyde-2,4-DNPH ACN 100 33080formaldehyde-2,4-DNPH ACN 100 33082glycolaldehyde-2,4-DNPH ACN 100 33091hexaldehyde-2,4-DNPH ACN 100 33083isobutyraldehyde-2,4-DNPH ACN 100 33084methacrolein-2,4-DNPH ACN 100 33095propionaldehyde-2,4-DNPH ACN 100 33086m-tolualdehyde-2,4-DNPH ACN 100 33088

ACN = acetonitrile*Concentration calculated as the aldehyde/ketone.

DNPH Reference Materials

Volume is 1mL/ampul. Concentration is µg/mL.*

acetaldehyde-2,4-DNPHacetone-2,4-DNPHacrolein-2,4-DNPHbenzaldehyde-2,4-DNPHn-butyraldehyde-2,4-DNPHcrotonaldehyde-2,4-DNPHformaldehyde-2,4-DNPH

hexaldehyde-2,4-DNPHmethacrolein-2,4-DNPHmethyl ethyl ketone-2,4-DNPHpropionaldehyde-2,4-DNPHm-tolualdehyde-2,4-DNPHvaleraldehyde-2,4-DNPH

CARB 1004 Aldehyde/Ketone-DNPH Calibration Standard

(13 components)

3µg/mL each in acetonitrile, 1mL/ampul*cat. # 33093 (ea.)


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8000 Series Methods

Method 8321 (Chlorinated Acids by HPLC)

3,4-dinitrotoluene

8330 Internal Standards

EPA Method 8330 is used to measure explosives residues in waterand soil samples, using HPLC with UV detection. Target analytesare nitroaromatic and nitramine explosives and their degrada-tion products.


1,2-dinitrobenzene

8330 Surrogate


1,3-dinitrobenzene2,4-dinitrotolueneHMXnitrobenzene

RDX1,3,5-trinitrobenzene2,4,6-trinitrotoluene

8330 Calibration Mix #1 (7 components)**


2-amino-4,6-dinitrotoluene4-amino-2,6-dinitrotoluene2,6-dinitrotoluene2-nitrotoluene

3-nitrotoluene4-nitrotoluenetetryl

8330 Calibration Mix #2 (7 components)**


also availableSee page 469 for chlordane and toxaphene reference materials.

1,3-dinitrobenzene2-amino-4,6-dinitrotoluene4-amino-2,6-dinitrotoluene2,4-dinitrotoluene2,6-dinitrotolueneHMXnitrobenzene

2-nitrotoluene3-nitrotoluene4-nitrotolueneRDXtetryl1,3,5-trinitrobenzene2,4,6-trinitrotoluene

Nitroaromatics and Nitramine Explosives by HPLC(14 components)**


did you know?When you order reference materials for Method 8330, be aware thatobtaining pure, neat compounds for standards can be very difficult.Some of these commercial-grade materials contain desensitizing agentssuch as beeswax, water, or other manufacturing by-products. Many areshipped wet and must be carefully dried before preparation.

To ensure the highest quality standards, Restek chemists use multipleanalytical techniques including GC, HPLC, GC/MS, or DSC to verify rawmaterial purity. All compounds are 98% pure or higher.

acifluorfen (Blazer)bentazonchloramben2,4-D

dicambadichlorproppicloram2,4,5-TP (Silvex)

Chlorinated Acids by HPLC, Mix A (8 components)


2,4-DB3,5-dichlorobenzoic aciddinosebMCPA

MCPP (mecoprop)4-nitrophenolpentachlorophenol2,4,5-T

Chlorinated Acids by HPLC, Mix B (8 components)


2,4-dichlorophenoxyacetic acid (2,4-D)2,4,5-TP (Silvex)

Chlorinated Acid Herbicide Mix (2 components)


Dalapon (2,2-dichloropropionic acid)




2-amino-4,6-dinitrotoluene4-amino-2,6-dinitrotoluene3,5-dinitroaniline1,3-dinitrobenzene2,4-dinitrotoluene2,6-dinitrotolueneHMXnitrobenzenenitroglycerin

2-nitrotoluene3-nitrotoluene4-nitrotoluenePETNRDXtetryl1,3,5-trinitrobenzene2,4,6-trinitrotoluene

8330B Nitroaromatics and Nitramine Mix (17 components)**


1,4-dinitrobenzene2,000µg/mL in acetonitrile, 1mL/ampul

cat. # 33205 (ea.)

Method 8330 (Nitroaromatics and Nitramines by HPLC)

Method 8330 (Nitroaromatics and Nitramines by HPLC) cont'd

**Meet all DOT requirements. Available only to customers or distributors insidethe 48 contiguous United States; items may not be resold for export.


800-356-1688 or 814-353-1300 www.restek.com 485


8000 Series Methods

Ultra II® Aromax columns separate all 17 target compounds and can be used alone (MS) or with a

confirmation column (UV).

Method 8330 (Nitroaromatics and Nitramines by HPLC) cont'd

also availableSee materials for GC Method 8095 on pages 473-474.

also available

Ultra II®Aromax HPLCcolumns, page 161

Ultra C18 HPLC columns, page 182

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriiccee2-amino-4,6-dinitrotoluene ACN 1,000 316704-amino-2,6-dinitrotoluene ACN 1,000 31671ammonium picrate* ACN 2,000 318903,5-dinitroaniline ACN 1,000 316611,2-dinitrobenzene M 1,000 314531,3-dinitrobenzene ACN 1,000 316622,4-dinitrotoluene ACN 1,000 316632,6-dinitrotoluene ACN 1,000 316643,4-dinitrotoluene EA 2,000 339013,4-dinitrotoluene M 1,000 31452EGDN* M 1,000 31601HMX* ACN 1,000 316652-methyl-4-nitroaniline M 1,000 31612nitrobenzene ACN 1,000 31657nitroglycerin* M 1,000 31498nitroguanidine* M 1,000 316022-nitrotoluene ACN 1,000 316593-nitrotoluene ACN 1,000 316604-nitrotoluene ACN 1,000 31658PETN (pentaerythritol tetranitrate)* M 1,000 31600picric acid* M 1,000 31499propylene glycol dinitrate (PGDN) M 1,000 31821RDX* ACN 1,000 31666tetryl* ACN 1,000 316671,3,5-trinitrobenzene* ACN 1,000 316682,4,6-trinitrotoluene* ACN 1,000 31669





Contains 1mL each of these mixtures.31450: 8330 Calibration Mix #131451: 8330 Calibration Mix #231452: 8330 Internal Standard Mix31453: 8330 Surrogate Mix


8330 Nitroaromatics Kit (1,000μg/mL)

cat. # 31454 (kit)

kit

1. HMX2. RDX3. nitroglycerin4. nitrobenzene5. 4-amino-2,6-dinitrotoluene6. 3,5-dinitroaniline7. 2-nitrotoluene8. 2-amino-4,6-dinitrotoluene9. 3-nitrotoluene

10. PETN11. 4-nitrotoluene12. 1,3-dinitrobenzene13. 2,6-dinitrotoluene14. tetryl15. 2,4-dinitrotoluene16. 1,3,5-trinitrobenzene17. 2,4,6-trinitrotoluene

SSaammppllee:: 8330B Nitroaromatics and Nitramine Mix (cat.# 33204)

Inj.: 10µLConc.: 10µg/mL each componentSample diluent: methanol

CCoolluummnn:: Ultra II® AromaxCat.#: 9607575Dimensions: 250mm x 4.6mmParticle size: 5µmPore size: 100Å

CCoonnddiittiioonnss::Instrument: Shimadzu Prominence UFLCXRMobile phase: water:methanol, 35:65 (v/v)Flow: 1.2mL/min.Temp.: 30°CDet.: UV @ 254nm and 210nm

LC_EV0484

free literatureFor more information, download our Analysis ofExplosives by Liquid Chromatography applicationsnote from www.restek.com

lit. cat.# EVAN1176


486 www.restek.com 800-356-1688 or 814-353-1300


EPA Super fund Contract Lab Program (CLP)

UUSS EEPPAA MMeetthhoodd NNoo.. CCoommppoouunndd CCllaassss

SOM01.1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Volatiles

04.2 and 04.1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Volatiles

10/92 SOW . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Volatiles

3/90 SOW . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Volatiles

03.2 OLC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Volatiles

UUSS EEPPAA MMeetthhoodd NNoo.. CCoommppoouunndd CCllaassss

SOM01.1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Semivolatiles

03.2 OLC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Semivolatiles

04.2 and 04.1 SOW . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Semivolatiles

4/89 and 3/90 SOW . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Semivolatiles

SOM01.1, 04.1, 3/90, 4/89 and 2/88 SOW . . . . . . . . . .Pesticides, Aroclor PCBs

EPA Superfund Contract Lab Program (CLP)

04.2, 04.1, and 10/92 SOW (Volatiles), QA Mixes

bromochloromethane4-bromofluorobenzenechlorobenzene-d5

1,2-dichloroethane-d41,4-difluorobenzenetoluene-d8

CLP 04.1 VOA Internal Standard/SMC Spike Mix (6 components)


bromochloromethane1,4-difluorobenzene

chlorobenzene-d5VOA Internal Standard Mix (3 components)


4-bromofluorobenzene1,2-dichloroethane-d4

toluene-d8VOA Surrogate Spike Mix (3 components)


benzenechlorobenzene1,1-dichloroethene

toluenetrichloroethene

VOA Matrix Spike Mix (5 components)



o-xylenep-xylene

VOA Screening Mix #1 (5 components)


n-dodecane n-nonaneVOA Screening Mix #2 (2 components)


4-bromofluorobenzeneVOA Tuning Compound



1,4-difluorobenzeneL/C VOA Internal Standard Mix (3 components)


benzenebromoformcarbon tetrachloride1,2-dibromoethane1,4-dichlorobenzene1,2-dichloroethane

1,2-dichloropropanecis-1,3-dichloropropenetetrachloroethene1,1,2-trichloroethanetrichloroethene

L/C VOA Lab Control Sample #1 (11 components)


vinyl chlorideL/C VOA Lab Control Sample #2


04.2, 04.1, and 10/92 SOW (Volatiles), QA Mixes cont'dSOM01.1 (Volatiles), QA Mixes

benzene-d6chloroethane-d5chloroform-d1,2-dichlorobenzene-d41,2-dichloroethane-d41,1-dichloroethene-d2

1,2-dichloropropane-d61,3-dichloropropene-d4*1,1,2,2-tetrachloroethane-d2toluene-d8vinyl chloride-d3

*Mix of cis and trans isomers. Exact proportions will be reported on the datasheet.

SOM01.1 VOA Non-Ketone Deuterated Monitoring

Compounds (11 components)

500µg/mL each in deuterated methanol (MeOD), 1mL/ampulcat. # 30624 (ea.)

2-butanone-d5 2-hexanone-d5

SOM01.1 VOA Ketone Deuterated Monitoring Compounds

(2 components)

500µg/mL each in deuterium oxide (D2O), 1mL/ampulcat. # 30625 (ea.)

500µg/mL. 1mL each of these mixtures.30624: Non-Ketones30625: Ketones


SOM01.1 VOA DMC Kit

cat. # 30630 (kit)

kit





Neat, 1gcat. # 33027 (ea.)

486-497_ARM_clp.qxp 11/22/2010 8:37 PM Page 486

800-356-1688 or 814-353-1300 www.restek.com 487


EPA Super fund Contract Lab Program (CLP)3/90 SOW (Volatiles), Calibration Mixes04.2 and 04.1 (Volatiles), Calibration Mixes

benzenebromodichloromethanebromoformcarbon disulfidecarbon tetrachloridechlorobenzenechloroformcyclohexanedibromochloromethane1,2-dibromo-3-chloropropane (DBCP)1,2-dibromoethane1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzene1,1-dichloroethane1,2-dichloroethane1,1-dichloroethenecis-1,2-dichloroethenetrans-1,2-dichloroethene1,2-dichloropropanecis-1,3-dichloropropenetrans-1,3-dichloropropeneethylbenzeneisopropylbenzenemethyl acetatemethyl tert-butyl ether (MTBE)methylcyclohexanemethylene chloride

styrene1,1,2,2-tetrachloroethanetetrachloroethenetoluene1,2,4-trichlorobenzene1,1,1-trichloroethane1,1,2-trichloroethanetrichloroethene1,1,2-trichloro-1,2,2-trifluoroethane

(CFC-113)m-xyleneo-xylenep-xylene







benzenecarbon disulfideethylbenzenetoluene

vinyl acetateo-xylenep-xylene

VOA Calibration Mix #2 (7 components)


carbon tetrachloridechlorobenzenechloroform1,1-dichloroethane1,1-dichloroethene

1,2-dichloropropanemethylene chloride1,1,2-trichloroethanetrichloroethenem-xylene



bromodichloromethanebromoformdibromochloromethane1,2-dichloroethanecis-1,2-dichloroethenetrans-1,2-dichloroethene

cis-1,3-dichloropropenetrans-1,3-dichloropropenestyrene1,1,2,2-tetrachloroethanetetrachloroethene1,1,1-trichloroethane



bromomethanechloroethane

chloromethanevinyl chloride

VOA Calibration Mix #5 (gases) (4 components)


CLP 04.1 VOA CAL2000

MegaMix® (40 components)benzenebromodichloromethanebromoformcarbon disulfidecarbon tetrachloridechlorobenzenechloroformdibromochloromethane1,1-dichloroethane1,2-dichloroethane1,1-dichloroethenecis-1,2-dichloroethenetrans-1,2-dichloroethene1,2-dichloropropane

cis-1,3-dichloropropenetrans-1,3-dichloropropeneethylbenzenemethylene chloridestyrene1,1,2,2-tetrachloroethanetetrachloroethenetoluene1,1,1-trichloroethane1,1,2-trichloroethanetrichloroethenem-xyleneo-xylenep-xylene

CLP VOA CAL2000 MegaMix® (28 components)


Vinyl Acetate






Contains 1mL each of these mixtures.30006: VOA Calibration Mix #1 (ketones)30042: 502.2 Calibration Mix #1 (gases)30456: CLP 04.1 VOA CAL2000 MegaMix


CLP 04.1 VOA Kit #3

cat. # 30460 (kit)

kit

Contains 1mL each of these mixtures.30632: CLP VOA CAL2000 MegaMix30216: vinyl acetate


CLP VOA CAL2000 MegaMix® Kit

cat. # 30438 (kit)

kit

Contains 1mL each of these mixtures.30006: VOA Calibration Mix #1 (ketones)30010: VOA Calibration Mix #5 (gases)30632: CLP VOA CAL2000 MegaMix30216: vinyl acetate


CLP VOA Calibration Kit #2

cat. # 30442 (kit)

kitChromaBLOGraphyTopical and timely insights from top chromatographers.



488 www.restek.com 800-356-1688 or 814-353-1300


EPA Super fund Contract Lab Program (CLP)04.2, 04.1, 4/89, and 3/90 SOW (Semivolatiles),QA Mixes

OLC 03.2 (Volatiles), Calibration Mixes

benzenebromochloromethanebromodichloromethanebromoformcarbon disulfidecarbon tetrachloridechlorobenzenechloroformcyclohexanedibromochloromethane

(chlorodibromomethane)1,2-dibromo-3-chloropropane (DBCP)1,2-dibromoethane (EDB)1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzene1,1-dichloroethane1,2-dichloroethane1,1-dichloroethenecis-1,2-dichloroethenetrans-1,2-dichloroethene1,2-dichloropropanecis-1,3-dichloropropenetrans-1,3-dichloropropeneethylbenzeneisopropylbenzene (cumene)methyl acetatemethylcyclohexanemethyl tert-butyl ether (MTBE)

methylene chloride (dichloromethane)styrene1,1,2,2-tetrachloroethanetetrachloroethenetoluene1,2,3-trichlorobenzene1,2,4-trichlorobenzene1,1,1-trichloroethane1,1,2-trichloroethanetrichloroethene1,1,2-trichlorotrifluoroethane

(CFC-113)m-xylene*o-xylenep-xylene*

OLC 03.2 VOA MegaMix®

(42 components)

2,000µg/mL each (*m- & p-xylene at 1,000µg/mL) in P&T methanol, 1mL/ampulcat. # 30492 (ea.)

2-chlorophenol-d42-fluorophenol

phenol-d62,4,6-tribromophenol

Acid Surrogate Standard Mix (3/90 SOW) (4 components)




bromochloromethane1,2-dibromo-3-chloropropane (DBCP)1,2-dibromoethane

1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzene

L/C VOA Calibration Mix #6 (6 components)


30006: VOA Calibration Mix #130007: VOA Calibration Mix #230008: VOA Calibration Mix #3

30009: VOA Calibration Mix #430010: VOA Calibration Mix #530003: VOA Tuning Compound

See pages 486–487 for mix compositions.

Additional VOA Calibration Mixes Required:

SOM01.1 (Semivolatiles), QA Mixes

fluoranthene-d10 2-methylnaphthalene-d10

SOM01.1 Deuterated Monitoring Compound Mix

SIM Compounds (2 components)


2-methylnonaneCCME F2 Surrogate Standard







31006 31006.15 31006.25

acenaphthene-d10chrysene-d121,4-dichlorobenzene-d41,4-dioxane-d8


Revised SV Internal Standard Mix (7 components)



31886 31886.15 31886.25

2-fluorophenolphenol-d6

2,4,6-tribromophenol

Acid Surrogate Mix (4/89 SOW) (3 components)





33029 33029.15 33029.25


p-terphenyl-d14pyrene-d10

Revised B/N Surrogate Mix (4 components)




31889 31889.15 31889.25

Chromatogram Search ToolSearch by compound name, synonym,CAS # or keywordwww.restek.com/chromatograms


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EPA Super fund Contract Lab Program (CLP)04.2, 04.1, 4/89, and 3/90 SOW (Semivolatiles),QA Mixes cont'd

2-chlorophenol-d4 1,500µg/mL1,2-dichlorobenzene-d4 1,0002-fluorobiphenyl 1,0002-fluorophenol 1,500

nitrobenzene-d5 1,000phenol-d6 1,500p-terphenyl-d14 1,0002,4,6-tribromophenol 1,500

CLP 04.1 BNA Surrogate Mix (8 components)


acenaphthene2,4-dinitrotoluene

N-nitroso-di-n-propylaminepyrene

CLP 04.1 B/N Matrix Spike Mix (4 components)


4-chloro-3-methylphenol2-chlorophenol4-nitrophenol

pentachlorophenolphenol

Acid Matrix Spike Mix (5 components)




1,2-dichlorobenzene-d42-fluorobiphenyl

nitrobenzene-d5p-terphenyl-d14

B/N Surrogate Standard Mix (3/90 SOW) (4 components)




Low Concentration Semivolatiles, QA Mixes

2-chlorophenolphenol

2,4,6-trichlorophenolL/C Acid Lab Control Sample (3 components)





p-terphenyl-d14B/N Surrogate Mix (4/89 SOW) (3 components)





33028 33028.15 33028.25

acenaphthene1,4-dichlorobenzene2,4-dinitrotoluene

N-nitroso-di-n-propylaminepyrene1,2,4-trichlorobenzene

B/N Matrix Spike Mix (6 components)





33030 33030.15 33030.25

benzo(a)pyrenebis(2-chloroethyl)etherdiethylphthalate2,4-dinitrotoluenehexachlorobenzenehexachloroethane

isophoronenaphthaleneN-nitrosodiphenylamineN-nitroso-di-n-propylamine1,2,4-trichlorobenzene

L/C B/N Lab Control Sample Mix A (11 components)

1,000µg/mL each in methylene chloride:methanol (85:15), 1mL/ampulcat. # 30310 (ea.)

4-chloroanilineL/C Aniline Mix B


Contains 1mL each of these mixtures.30310: L/C B/N Lab Control Sample Mix A31211: L/C Aniline Mix B


L/C B/N Lab Control Sample Kit

cat. # 31241 (kit)

kit





Neat, 1gcat. # 33027 (ea.)

Special pricing on

multi-packs of 15 & 25!

EPA 8270 Internal,Surrogate & Spike Mixes!

up to

40%OFFlist price

• 8270 Matrix Spike Mix

• SV Internal Standard Mix

• Revised SV Internal Standard Mix

• B/N Surrogate Mix (4/89 SOW)

• Revised B/N Surrogate Mix

• Acid Surrogate Mix (4/89 SOW)

• B/N Matrix Spike Mix

486-497_ARM_clp.qxp 11/22/2010 8:38 PM 9

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CLP Semivolatiles Dilution Tip

Atrazine and benzaldehyde react quickly with the methanol stabilizerused in most brands and grades of methylene chloride. This reaction willprevent you from obtaining stable, working-level calibration standards.We prepare our CLP semivolatiles standards from methylene chloridethat is stabilized with amylene and is completely free of methanol. Westrongly recommend screening the methylene chloride used to dilutethese mixtures and confirming that it is free of methanol.

04.2 and 04.1 (Semivolatiles), Calibration Mixes

4-chloro-3-methylphenol2-chlorophenol2,4-dichlorophenol2,4-dimethylphenol2,4-dinitrophenol2-methyl-4,6-dinitrophenol2-methylphenol

4-methylphenol2-nitrophenol4-nitrophenolpentachlorophenolphenol2,4,5-trichlorophenol2,4,6-trichlorophenol

CLP 04.1 Phenols Calibration Mix (14 components)


benzidine 3,3'-dichlorobenzidineBenzidine Mix (2 components)


SOM01.1 (Semivolatiles), Calibration Mixes

also availableFor details on our Rxi®-5Sil MS capillarycolumns for semivolatiles analysis, seepage 87.

tech tip

acenaphtheneacenaphthyleneacetophenoneanthracenebenzo(a)anthracenebenzo(a)pyrenebenzo(b)fluoranthenebenzo(ghi)perylenebenzo(k)fluoranthenebenzyl butyl phthalatebiphenylbis(2-chloroethoxy)methanebis(2-chloroethyl)etherbis(2-chloroisopropyl)ether

(2,2'-oxybis(1-chloropropane))bis(2-ethylhexyl)phthalate4-bromophenyl-phenylethercarbazole4-chloroaniline4-chloro-3-methylphenol2-chloronaphthalene2-chlorophenol4-chlorophenyl-phenyletherchrysenedibenzo(a,h)anthracenedibenzofuran3,3'-dichlorobenzidine2,4-dichlorophenoldiethylphthalate2,4-dimethylphenoldimethylphthalatedi-n-butylphthalate4,6-dinitro-2-methylphenol2,4-dinitrophenol2,4-dinitrotoluene2,6-dinitrotoluenedi-n-octyl phthalatediphenylamine1

fluoranthenefluorenehexachlorobenzene

hexachloro-1,3-butadiene (hexachlorobutadiene)

hexachlorocyclopentadienehexachloroethaneindeno(1,2,3-cd)pyreneisophorone2-methylnaphthalene2-methylphenol (o-cresol)3-methylphenol (m-cresol)*4-methylphenol (p-cresol)*naphthalene2-nitroaniline3-nitroaniline4-nitroanilinenitrobenzene2-nitrophenol4-nitrophenolN-nitroso-di-n-propylaminepentachlorophenolphenanthrenephenolpyrene1,2,4,5-tetrachlorobenzene2,3,4,6-tetrachlorophenol2,4,5-trichlorophenol2,4,6-trichlorophenol

*3-methylphenol and 4-methylphenol concentration is 500µg/mL.1 N-nitrosodiphenylamine (CLP-listed analyte) decomposes to diphenylamine(mix component) in the injector.

SOM01.1 SVOA MegaMix®,

Revised (65 components)


atrazinebenzaldehyde

ε-caprolactamCLP/SVOA Additions Mix (3 components)


acenaphtheneacenaphthyleneacetophenoneanthracenebenzo(a)anthracenebenzo(a)pyrenebenzo(b)fluoranthenebenzo(ghi)perylenebenzo(k)fluoranthenebenzyl butyl phthalatebiphenylbis(2-chloroethoxy)methanebis(2-chloroethyl)etherbis(2-chloroisopropyl)ether

(2,2'-oxybis(1-chloropropane))bis(2-ethylhexyl)phthalate4-bromophenyl phenyl ethercarbazole4-chloroaniline2-chloronaphthalene4-chlorophenyl phenyl etherchrysenedibenzo(a,h)anthracenedibenzofurandiethylphthalate

dimethylphthalatedi-n-butyl phthalate2,4-dinitrotoluene2,6-dinitrotoluenedi-n-octyl phthalatediphenylamine1

fluoranthenefluorenehexachlorobenzenehexachloro-1,3-butadiene

(hexachlorobutadiene)hexachlorocyclopentadienehexachloroethaneindeno(1,2,3-cd)pyreneisophorone2-methylnaphthalenenaphthalene2-nitroaniline3-nitroaniline4-nitroanilinenitrobenzeneN-nitroso-di-n-propylaminephenanthrenepyrene

1 N-nitrosodiphenylamine (CLP-listed analyte) decomposes to diphenylamine(mix component) in the injector.

CLP 04.1 B/N MegaMix®, Revision 2 (47 components)


Contains 1mL each of these mixtures.31900: SOM01.1 SVOA MegaMix, Revised31902: CLP/SVOA Additions Mix


SOM01.1 SVOA MegaMix® Kit

cat. # 31904 (kit)

kit

Contains 1mL each of these mixtures.31903: CLP 04.1 B/N MegaMix, Revision 231902: CLP/SVOA Additions Mix


CLP 04.1 B/N MegaMix® Kit

cat. # 31905 (kit)

kit

atrazinebenzaldehyde

ε-caprolactamCLP/SVOA Additions Mix (3 components)


NEW!

NEW!

NEW!

NEW!

NEW!

NEW!

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EPA Super fund Contract Lab Program (CLP)4/89 and 3/90 SOW (Semivolatiles), Calibration Mixes

benzyl alcohol4-chloroaniline2-nitroaniline

3-nitroaniline4-nitroaniline

SV Calibration Mix #1 (5 components)


benzoic acid4-chloro-3-methylphenol2-chlorophenol2,4-dichlorophenol2,4-dimethylphenol2,4-dinitrophenol2-methyl-4,6-dinitrophenol2-methylphenol

4-methylphenol2-nitrophenol4-nitrophenolpentachlorophenolphenol2,4,5-trichlorophenol2,4,6-trichlorophenol



bis(2-chloroethoxy)methanebis(2-chloroethyl)etherbis(2-chloroisopropyl)etherbis(2-ethylhexyl)phthalate4-bromophenyl phenyl etherbutyl benzyl phthalate2-chloronaphthalene

4-chlorophenyl phenyl etherdimethylphthalatedi-n-butylphthalatedi-n-octylphthalate N-nitrosodimethylamineN-nitroso-di-n-propylamineN-nitrosodiphenylamine



carbazoledibenzofurandiethyl phthalate2,4-dinitrotoluene2,6-dinitrotoluenehexachlorobenzenehexachlorobutadiene

hexachlorocyclopentadienehexachloroethaneisophorone2-methylnaphthalenenitrobenzene1,2,4-trichlorobenzene



aldrinα-BHCβ-BHCδ-BHCγ-BHC (lindane)4,4'-DDD4,4'-DDE4,4'-DDTdieldrin

endosulfan Iendosulfan IIendosulfan sulfateendrinendrin aldehydeendrin ketoneheptachlorheptachlor epoxide (isomer B)methoxychlor


2,000µg/mL each in toluene:hexane (1:1), 1mL/ampulcat. # 31012 (ea.)

1,2-dichlorobenzene1,3-dichlorobenzene

1,4-dichlorobenzeneSV Calibration Mix #7 (3 components)


3,3'-Dichlorobenzidine2,000µg/mL in methanol, 1mL/ampul

cat. # 31026 (ea.) 2,000µg/mL in methylene chloride, 1mL/ampul

cat. # 31835 (ea.)

benzidine3,3'-dichlorobenzidine

3,3'-dimethylbenzidine8270 Benzidines Mix (3 components)










Contains 1mL each of these mixtures.31007: SV Calibration Mix #1 (anilines)31008: SV Calibration Mix #2 (phenols)31009: SV Calibration Mix #3 (base neutrals)31010: SV Calibration Mix #4 (base neturals)31011: SV Calibration Mix #5 (PAHs)31013: SV Calibration Mix #7 (dichlorobenzenes)31026: 3,3'-dichlorobenzidine


CLP Semivolatile Calibration Kit #2 (without pesticides)

cat. # 31462 (kit)

kit

Contains 1mL each of these mixtures.31007: SV Calibration Mix #1 (anilines)31008: SV Calibration Mix #2 (phenols)31009: SV Calibration Mix #3 (base neutrals)31010: SV Calibration Mix #4 (base neturals)31011: SV Calibration Mix #5 (PAHs)31013: SV Calibration Mix #7 (dichlorobenzenes)31030: 605 Benzidines Calibration Mix (benzidine & 3,3'-dichlorobenzidine)


Semivolatile Calibration Kit #3 (with benzidine)

cat. # 31463 (kit)

kit




492 www.restek.com 800-356-1688 or 814-353-1300



03.2 (Semivolatiles), Calibration Mixes

acenaphthylene-d8 anthracene-d10 benzo(a)pyrene-d12 4-chloroaniline-d4 bis-(2-chloroethyl)ether-d8 2-chlorophenol-d4 2,4-dichlorophenol-d3 dimethylphthalate-d6

4,6-dinitro-methylphenol-d2 fluorene-d10 4-methylphenol-d8 nitrobenzene-d5 2-nitrophenol-d4 4-nitrophenol-d4 phenol-d5 pyrene-d10

OLC 03.2 SVOA Deuterated Monitoring Compounds (DMC)

(16 components)


3,3'-Dichlorobenzidine2,000µg/mL in methylene chloride, 1mL/ampul

cat. # 31835 (ea.)

Low Concentration Semivolatiles, Calibration Mixes

4,6-dinitro-2-methylphenol2,4-dinitrophenol2-nitroaniline3-nitroaniline

4-nitroaniline4-nitrophenol2,4,5-trichlorophenol

Fortification Mix (7 components)


Hexachlorophene2,000µg/mL in methylene chloride, 1mL/ampul

cat. # 31811 (ea.)

2,4-dinitrophenol*2-methyl-4,6-dinitrophenol*4-nitrophenol*

pentachlorophenol*2,4,6-tribromophenol (SS)*2,4,5-trichlorophenol*

*Must be calibrated at a level different from the other listed semivolatilecompounds.

L/C Phenol Mix A (6 components)


4-chloro-3-methylphenol2-chlorophenol2,4-dichlorophenol2,4-dimethylphenol2-fluorophenol2-methylphenol

4-methylphenol2-nitrophenolphenolphenol-d6 (SS)2,4,6-trichlorophenol

L/C Phenol Mix B (11 components)


2-nitroaniline*3-nitroaniline*

4-nitroaniline*

*Must be calibrated at a level different from the other listed semivolatilecompounds.

L/C Aniline Mix A (3 components)


4-chloroanilineL/C Aniline Mix B


31024: B/N Surrogate Mix (4/89 SOW)31009: SV Calibration Mix #331010: SV Calibration Mix #431011: SV Calibration Mix #531026: 3,3'-dichlorobenzidine31001: SV Tuning Compound (DFTPP)

Additional Required SV Calibration Mixes:

See pages 489 and 491 for mix compositions.

GPC Calibration Mix

bis(2-ethylhexyl) phthalate 10mg/mLcorn oil 250methoxychlor 2.0

perylene 0.2sulfur 0.8

CLP GPC Calibration Mix (5 components)

Qualitative mixture useful for determining GPC dump/collecttimes. The compounds are dissolved in methylene chloride at theconcentrations listed.



bis(2-ethylhexyl) phthalate 5mg/mLcorn oil 250methoxychlor 1.0

perylene 0.2sulfur 0.8

Revised GPC Calibration Mix (5 components)



did you know?Our Pesticide Matrix Spike Mix (cat.# 32018, page 494) can be usedas a GPC calibration verification solution.





and/or lot number)



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04.2, 04.1, 03.2, 3/90, 4/89, and 2/88 SOW (Pesticides),QA Mixes

Working with solutions containing decachlorobiphenyl

Decachlorobiphenyl has poor solubility in most organic solvents. Themaximum concentration that can be prepared in acetone, hexane, orisooctane is 200 μg/mL. Temperature will affect the solubility as well.Storing solutions at reduced temperatures will cause decachlorobiphenylto precipitate.

Products containing decachlorobiphenyl must be sonicated for a minimum of 10 minutes prior to opening the ampul. Because each ultrasonic bath operates at a different energy level, 10 minutes is aguideline only. Longer sonication time will not affect product quality.

These precautions apply to working solutions prepared in your laboratory as well. The amount of compound that precipitates dependson concentration AND temperature. If you store your standards at a temperature lower than 4°C (even dilute solutions), allow extra sonication time.

decachlorobiphenyl 2,4,5,6-tetrachloro-m-xylene



2,4,5,6-Tetrachloro-m-xylene



Decachlorobiphenyl (BZ #209)



10µg/mL in isooctane, 1mL/ampulcat. # 32289 (ea.)

Dibutylchlorendate


2,4,5-trichlorophenolFlorisil® Cartridge Check Standard


γ-chlordane 1µg/mL4,4'-DDE 2dieldrin 2endosulfan I 1

endosulfan sulfate 2endrin ketone 2methoxychlor 10

Pesticide Resolution Check Mix (7 components)

In hexane, 1mL/ampulcat. # 32001 (ea.)

γ-chlordane 1µg/mL4,4'-DDE 2decachlorobiphenyl (SS) 2dieldrin 2endosulfan I 1

endosulfan sulfate 2endrin ketone 2methoxychlor 102,4,5,6-tetrachloro-m-xylene (SS) 2

Pesticide Resolution Check Mix w/Surrogates (9 components)


α-BHC 1µg/mLβ-BHC 1γ-BHC (lindane) 1

4,4'-DDT 10endrin 5methoxychlor 25

Pesticide Performance Evaluation Mix (6 components)


α-BHC 1µg/mLβ-BHC 1γ-BHC (lindane) 14,4'-DDT 10

decachlorobiphenyl (SS) 2endrin 5methoxychlor 252,4,5,6-tetrachloro-m-xylene (SS) 2

Pesticide Performance Evaluation Mix w/Surrogates

(8 components)


04.2, 04.1, 03.2, 3/90, 4/89, and 2/88 SOW (Pesticides),QA Mixes cont'd

SOM01.1 (Pesticides), QA Mixes

decachlorobiphenyl 200µg/mL2,4,5,6-tetrachloro-m-xylene 100



aldrin 10µg/mLα-BHC 10β-BHC 10δ-BHC 10γ-BHC (lindane) 10α-chlordane 10γ-chlordane 10decachlorobiphenyl (SS) 20dieldrin 204,4'-DDD 204,4'-DDE 204,4'-DDT 20

endosulfan I 10endosulfan II 20endosulfan sulfate 20endrin 20endrin aldehyde 20endrin ketone 20heptachlor 10heptachlor epoxide (isomer B) 10methoxychlor 1002,4,5,6-tetrachloro-m-xylene (SS) 10

Organochlorine Pesticide Resolution Check Mix

(with surrogates) (22 components)


tech tip

4,4'-DDT 200µg/mL endrin 100µg/mL

Organochlorine Pesticide System Evaluation Mix

(2 components)



494 www.restek.com 800-356-1688 or 814-353-1300



aldrin 10µg/mLα-BHC 5β-BHC 10δ-BHC 10α-chlordane 10γ-chlordane 10

4,4'-DDD 204,4'-DDE 10endosulfan sulfate 20endrin 10endrin ketone 20

Pesticide Standard Mix B (2/88 SOW) (11 components)


α-BHC 5µg/mLγ-BHC (lindane) 54,4'-DDD 104,4'-DDT 10dieldrin 10

endosulfan I 5endrin 10heptachlor 5methoxychlor 50

Pesticide Standard Mix A (9 components)


aldrin 5µg/mLβ-BHC 5δ-BHC 5α-chlordane 5γ-chlordane 54,4'-DDE 10

endosulfan II 10endosulfan sulfate 10endrin aldehyde 10endrin ketone 10heptachlor epoxide (isomer B) 5

Pesticide Standard Mix B (11 components)


CLP Pesticides Mixtures, Calibration Mixes

CLP Pesticides Mixtures, Calibration Mixes cont'd

aldrin 10µg/mLγ-BHC (lindane) 54,4'-DDT 20dieldrin 10endosulfan I 10

endosulfan II 20endrin aldehyde 25heptachlor 10heptachlor epoxide (isomer B) 10methoxychlor 100

Pesticide Standard Mix A (2/88 SOW) (10 components)


Low Concentration Pesticides Mixtures, QA Mixes

γ-BHC (lindane) 10µg/mLγ-chlordane 104,4'-DDE 20dieldrin 20

endosulfan sulfate 20endrin 20heptachlor epoxide (isomer B) 10

L/C Pesticide Lab Control Sample (7 components)


CLP Pesticides Mixtures, QA Mixes

aldrin 25µg/mLγ-BHC (lindane) 254,4'-DDT 50

dieldrin 50endrin 50heptachlor 25

Pesticide Matrix Spike Mix (6 components)


aldrin 200µg/mLγ-BHC (lindane) 2004,4'-DDT 500

dieldrin 500endrin 500heptachlor 200

Pesticide Matrix Spike Mix (2/88 SOW) (6 components)


aldrindibutylchlorendate (SS)

4,4'-DDTendrin

Pesticide Evaluation Mix (2/88 SOW) (4 components)


also availableUse our Rtx®-CLPesticides/Rtx®-CLPesticides2 capillary column pair to analyze all twentyorganochlorine pesticides and their surrogatessimultaneously. See pages 88-89.

See page 496 for our complete listing of PCBs and congeners.

See complete listing of PCBs, pages 495-496.





aldrin 8µg/mLα-BHC 8β-BHC 8δ-BHC 8γ-BHC (lindane) 8α-chlordane 8γ-chlordane 84,4'-DDD 164,4'-DDE 164,4'-DDT 16

dieldrin 16endosulfan I 8endosulfan II 16endosulfan sulfate 16endrin 16endrin aldehyde 16endrin ketone 16heptachlor 8heptachlor epoxide (isomer B) 8methoxychlor 80








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Pesticides Calibration Mixtures

Technical Chlordane, Toxaphene Solutions

Aroclor Solutions

α-BHC 8µg/mLγ-BHC (lindane) 84,4'-DDD 164,4'-DDT 16decachlorobiphenyl (SS) 16dieldrin 16

endosulfan I 8endrin 16heptachlor 8methoxychlor 802,4,5,6-tetrachloro-m-xylene (SS) 8

Pesticide Standard Mix A w/Surrogates (11 components)


aldrin 8µg/mLβ-BHC 8δ-BHC 8α-chlordane 8γ-chlordane 84,4'-DDE 16decachlorobiphenyl (SS) 16

endosulfan II 16endosulfan sulfate 16endrin aldehyde 16endrin ketone 16heptachlor epoxide (isomer B) 82,4,5,6-tetrachloro-m-xylene (SS) 8

Pesticide Standard Mix B w/Surrogates (13 components)


Components of these products are at 16x the Contract RequiredQuantitation Level (CRQL) and can be used to prepare calibra-tion mixes at 4x CRQL and at 1x CRQL by serial dilution.

please noteWe test our transformer oil solvent to ensure that it is PCB-free.

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceechlordane (technical) H 1,000 32021chlordane (technical) I 5,000 32072chlordane (technical) M 2,000 32016toxaphene H 1,000 32005toxaphene I 5,000 32071toxaphene M 2,000 32015

H = hexane; I = isooctane; M = methanol





Achieving the Best Results from Gas Standards

In order to achieve the best results from gas standards, proper handlingand storage of gas solutions is of vital importance. Use the following tipsto help ensure trouble-free performance:

• Before opening the sealed ampul, warm it to room temperature andinvert the ampul several times. This will redissolve any gases that mayhave migrated into the headspace of the ampul.

• When diluting a gas standard, always add it to a solvent. Adding thegas standard to an empty vessel prior to adding solvent will result inthe loss of gas compounds.

• When diluting a gas standard in solvent, make sure the pipette or needle tip is directly above, or immersed below, the solvent surface.

• We recommend that any unused portion of gas standard be disposedof after it has been removed from the sealed ampul. If it is necessary tostore the unused portion, place it into a tightly capped vial and store itin the freezer.

• We recommend that any gas solutions that have been stored outsideof a sealed ampul be disposed of after 7 days.

tech tip

Contains 1mL each of these mixtures.32003: Pesticide Standard Mix A w/Surrogates32004: Pesticide Standard Mix B w/Surrogates32005: Toxaphene32007: Aroclor 122132008: Aroclor 123232009: Aroclor 124232010: Aroclor 124832011: Aroclor 125432039: Aroclor 1016/1260


Pesticide Kit #3

Calibration mixes only for CLP 04.1. Includes pesticide standard mixes A & Bat 16x CRQL with surrogates.

cat. # 32404 (kit)

kit


496 www.restek.com 800-356-1688 or 814-353-1300

ANALYTICAL REFERENCE MATERIALS | ENVIRONMENTAL MATERIALS

PCBs, Organotin

also availableAdditional PCB congener mixes:

See EPA Method 8082: cat.# 32416 page 473.

See EPA Method 525: cat.# 32420 page 458.

2,4,4'-trichlorobiphenyl (BZ #28)2,2',5,5'-tetrachlorobiphenyl (BZ #52)2,2',4,5,5'-pentachlorobiphenyl (BZ #101)2,2',3,4,4',5'-hexachlorobiphenyl (BZ #138)2,2',4,4',5,5'-hexachlorobiphenyl (BZ #153)2,2',3,4,4',5,5'-heptachlorobiphenyl (BZ #180)

PCB Congener Standard #1 (6 components)


2,4,4'-trichlorobiphenyl (BZ #28)2,2',5,5'-tetrachlorobiphenyl (BZ #52)2,2',4,5,5'-pentachlorobiphenyl (BZ #101)2,3',4,4',5-pentachlorobiphenyl (BZ #118)2,2',3,4,4',5'-hexachlorobiphenyl (BZ #138)2,2',4,4',5,5'-hexachlorobiphenyl (BZ #153)2,2',3,4,4',5,5'-heptachlorobiphenyl (BZ #180)



butyltin trichloridedibutyltin dichloride

tetrabutyltintributyltin chloride

Butyltin Chloride Calibration Mixture (4 components)


Tributyltin Chloride Calibration Mixture


diphenyltin dichloridephenyltin trichloride

tetraphenyltintriphenyltin chloride

Phenyltin Chloride Calibration Mixture (4 components)


Tri-n-propyltin Chloride Surrogate


Tripentyltin Chloride Surrogate


Tetra-n-propyltin Internal Standard2,000µg/mL in methylene chloride, 1mL/ampul

cat. # 31474 (ea.)

Tetrapentyltin Internal Standard


Organotin Mixes

PCB Congeners

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriiccee2,4,4'-trichlorobiphenyl (BZ #28) I 10 322832,2',5,5'-tetrachlorobiphenyl (BZ #52) I 10 322842,2',4,5,5'-pentachlorobiphenyl (BZ #101) I 10 322852,3',4,4',5-pentachlorobiphenyl (BZ #118) I 10 322932,2',3,4,4',5'-hexachlorobiphenyl (BZ #138) I 10 322862,2',4,4',5,5'-hexachlorobiphenyl (BZ #153) I 10 322872,2',3,4,4',5,5'-heptachlorobiphenyl (BZ #180) I 10 32288decachlorobiphenyl (BZ #209) I 10 32289

I = isooctane


PCB Congeners cont'dPCB Kits

1,000µg/mL each in hexane, 1mL/ampul32006: Aroclor 101632007: Aroclor 122132008: Aroclor 123232009: Aroclor 124232010: Aroclor 124832011: Aroclor 125432012: Aroclor 1260


PCB Kit #1

cat. # 32089 (kit)

kit

200µg/mL each in isooctane, 1mL/ampul32064: Aroclor 101632065: Aroclor 122132066: Aroclor 123232067: Aroclor 124232068: Aroclor 124832069: Aroclor 125432070: Aroclor 1260


PCB Kit #2

cat. # 32090 (kit)

kit

1,000µg/mL each in hexane, 1mL/ampul32007: Aroclor 122132008: Aroclor 123232009: Aroclor 124232010: Aroclor 124832011: Aroclor 125432039: Aroclor 1016/1260


PCB Kit #3

cat. # 32400 (kit)

kit

200µg/mL each in isooctane, 1mL/ampul32065: Aroclor 122132066: Aroclor 123232067: Aroclor 124232068: Aroclor 124832069: Aroclor 125432299: Aroclor 1016/1260


PCB Kit #4

cat. # 32401 (kit)

kit


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ANALYTICAL REFERENCE MATERIALS | ENVIRONMENTAL MATERIALS

Minnesota Dept. of Agriculture Pesticides

Minnesota Dept. of Agriculture List 1 Pesticides on an Rxi®-1ms column.

acetochloralachloratrazinecyanazinedesethylatrazinedesisopropylatrazinedimethenamid*ethalfluralin

metolachlormetribuzinpendimethalinprometonpropachlorpropazinesimazinetrifluralin

*Added to Minnesota Department of Agriculture List 1 pesticide (neutrals) inci-dent investigation requirements, effective January 1, 2000.¹ CAS # 87674-68-8manufactured by several companies under various trade names.¹Analytical Lists for Pesticide Incident Investigations, Minnesota Department ofAgriculture, Guidance Document 26 (3/99), St. Paul, MN. For a copy, visit theirweb site at: www.mda.state.mn.us

Minnesota Ag List 1 Pesticides Mix A (16 components)

200ppm each in acetone, 1mL/ampulcat. # 32406 (ea.)

chlorpyrifosEPTCfonofos

phorateterbufostriallate

Minnesota Ag List 1 Pesticides Mix B (6 components)

200ppm each in acetone, 1mL/ampulcat. # 32407 (ea.)

Minnesota Department of Agriculture List 1 Pesticides

GC_EV00837

1. 2-fluorophenol (SS)2. phenol-d6 (SS)3. 1,4-dichlorobenzene-d4 (IS)4. nitrobenzene-d5 (SS)5. naphthalene-d8 (IS)6. EPTC7. 2-fluorobiphenyl (SS)8. acenaphthene-d10 (IS)9. propachlor

10. desisopropyl atrazine11. desethyl atrazine12. 2,4,6-tribromophenol (SS)13. ethalfluralin14. trifluralin15. phorate16. simazine17. prometon18. atrazine

19. propazine20. terbufos21. fonofos22. phenanthrene-d10 (IS)23. triallate24. metribuzin25. dimethenamid26. acetochlor27. alachlor28. cyanazine29. metolachlor30. chlorpyrifos31. pendimethalin32. p-terphenyl-d14 (SS)33. chrysene-d12 (IS)34. perylene-d12 (IS)

Column: Rxi®-1ms, 30m, 0.25mm ID, 0.25µm (cat.# 13323)

Sample: Minnesota Ag List 1 Pesticides Mix A (cat.# 32406), Minnesota Ag List 1 Pesticides Mix B (cat.# 32407), SV Internal Standard Mix (cat.# 31206), B/N Surrogate Mix (4/89 SOW) (cat.# 31024), Acid Surrogate Mix (4/89 SOW) (cat.# 31025)

Inj.: 1.0µL, 10µg/mL each analyte (internal standards 25µg/mL), split (10:1)4mm Drilled Uniliner® inlet liner (hole near bottom) (cat.# 20771)

Instrument: Agilent 6890Inj. temp.: 250°CCarrier gas: helium, constant flowFlow rate: 1.2mL/min.Oven temp.: 70°C (hold 1 min.) to 180°C @ 20°C/min.,

to 230°C @ 5°C/min., to 325°C @ 40°C/min. (hold 3.5 min.)

Det.: Agilent 5973 MSDTransfer line

temp.: 280°CScan range: 35-550amuSolvent delay: 2.50 min.Tune: DFTPPIonization: EI

Contains 1mL each of these mixtures.32406: Minnesota Ag List Pesticides Mix A32407: Minnesota Ag List Pesticides Mix B


Minnesota Ag List 1 Pesticide Kit

cat. # 32408 (kit)

kit

also availableSee page 41 for our Rxi®-1ms capillary columns.


498 www.restek.com 800-356-1688 or 814-353-1300


International Mixes

aldicarbbendiocarbcarbaryl (Sevin)

carbofurantriallate

Canadian Drinking Water Carbamates Mix (5 components)


aldrinγ-BHC (lindane)α-chlordaneγ-chlordane2,4'-DDE4,4'-DDE2,4'-DDT

4,4'-DDTdieldrinheptachlorheptachlor epoxide (isomer B)methoxychloroxychlordanetrifluralin

Canadian Drinking Water Chlorinated Pesticides Mix

(14 components)

200µg/mL each in hexane:toluene, 1mL/ampulcat. # 31866 (ea.)

azinphos methyl (Guthion)chlorpyrifos (Dursban)Diazinondimethoatemalathion

parathion (ethyl)phoratetemephos (Abate)terbufos

Canadian Drinking Water OP Pesticides Mix (9 components)


Canada cont'd

Canada

n-pentacontane (C50)C50 in Toluene

10µg/mL in toluene, 1mL/ampulcat. # 31685 (ea.)

n-undecane (C11)CCME F1 Surrogate Standard


2-methylnonaneCCME F2 Surrogate Standard


n-decane (C10)n-hexane (C6)

tolueneCCME F1 Retention Time Marker (3 components)


n-decane (C10)n-hexadecane (C16)

n-tetratriacontane (C34)CCME PHC Calibration Mix (3 components)

5,000µg/mL each in toluene, 1mL/ampulcat. # 31684 (ea.)

alachloratrazinecyanazine (Bladex)metolachlor

metribuzinprometrynesimazine

Canadian Drinking Water Triazine Herbicides Mix

(7 components)


bromoxynil2,4-Ddicamba2,4-dichlorophenoldiclofop methyldinoseb

pentachlorophenolpicloram2,4,5-T2,3,4,6-tetrachlorophenol2,4,6-trichlorophenol

Canadian Drinking Water Phenoxyacid Herbicides Mix

(11 components)


CCoouunnttrryy//MMiisscceellllaanneeoouuss CCoommppoouunndd CCllaassss

Canada: CCME . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Alkanes; PAHs

Canada: Drinking Water . . . . . . . . . . . . . . . . . . . . . . . . . . . .Volatiles; Pesticides

Canada: RBCA - Atlantic Provinces . . . . . . . . . . . . .Aromatics; Aliphatics; PAHs

European Union . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Pesticides

Japan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Odor Compounds

ISO/DIS-9377 Water Quality Testing . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

International Environmental Mixes

RESTEK REFINEDPetroleum & Sulfur Standards!

See pages 518-521 for more information.Documentation Search


and/or lot number)


498-500_ARM_intnl.qxp 11/22/2010 8:39 PM Page 498

800-356-1688 or 814-353-1300 www.restek.com 499


International MixesCanada - Atlantic Provinces

acenaphtheneanthracenebenzo(a)pyrenechrysenen-decane (C10)n-dodecane (C12)

n-dotriacontane (C32)n-heneicosane (C21)n-hexadecane (C16)n-octacosane (C28)naphthalene

Atlantic RBCA EPH Mix (11 components)

1,000µg/mL each in hexane:methylene chloride, 1mL/ampulcat. # 31872 (ea.)

n-dotriacontane (C32) isobutylbenzeneAtlantic RBCA EPH Surrogate Standard (2 components)


benzenen-decane (C10)ethylbenzenen-heptane (C7)n-hexane (C6)1-methyl-3-ethylbenzene

n-octane (C8)toluene1,2,4-trimethylbenzene1,3,5-trimethylbenzeneo-xylenep-xylene

Atlantic RBCA VPH Mix (12 components)


isobutylbenzeneAtlantic RBCA VPH Surrogate Standard


Europe

acephate 200µg/mLazinphos methyl (Guthion) 400chlorpyrifos 100demeton-s-methyl 200dichlorvos (DDVP) 500dimethoate 200ethion 200malathion 200

methamidophos 500methidathion 200omethoate 1,000pirimiphos methyl 100profenfos 200pyrazophos 500tokuthion (prothiofos) 200tolclofos-methyl 100

Organophosphorus Pesticide Mix, European Formulation

(16 components)


Desethyl-atrazine1,000µg/mL in acetone, 1mL/ampul

cat. # 32445 (ea.)

Desisopropylatrazine1,000µg/mL in acetone, 1mL/ampul

cat. # 32446 (ea.)

Terbuthylazine1,000µg/mL in acetone, 1mL/ampul

cat. # 32447 (ea.)

Propazine1,000µg/mL in acetone, 1mL/ampul

cat. # 32448 (ea.)

Prometryne1,000µg/mL in acetone, 1mL/ampul

cat. # 32449 (ea.)

Japan

(+/-)-geosmin 2-methylisoborneol

Drinking Water Odor Standard (2 components)

Unpleasant odor in drinking water is associated with the growthand decay of microorganisms. The threshold value for thesecompounds is low (10 ppt) and purge and trap analyses usuallyare used to quantify them.


Europe cont'd

also availableEP 2.4.22 Composition of Fatty Acids by GC Mixes





(Pi-marked Cylinders for

EU Regulations):


2,4,4'-trichlorobiphenyl (BZ #28)2,2',5,5'-tetrachlorobiphenyl (BZ #52)2,2',4,5,5'-pentachlorobiphenyl (BZ #101)2,2',3,4,4',5'-hexachlorobiphenyl (BZ #138)2,2',4,4',5,5'-hexachlorobiphenyl (BZ #153)2,2',3,4,4',5,5'-heptachlorobiphenyl (BZ #180)



2,4,4'-trichlorobiphenyl (BZ #28)2,2',5,5'-tetrachlorobiphenyl (BZ #52)2,2',4,5,5'-pentachlorobiphenyl (BZ #101)2,3',4,4',5-pentachlorobiphenyl (BZ #118)2,2',3,4,4',5'-hexachlorobiphenyl (BZ #138)2,2',4,4',5,5'-hexachlorobiphenyl (BZ #153)2,2',3,4,4',5,5'-heptachlorobiphenyl (BZ #180)



acrylonitrilebenzene1,3-butadienechloroform1,2-dichloroethane

dichloromethanetetrachloroethylenetrichloroethylenevinyl chloride

No data pack available.Quantity discounts not available.

Japan Calibration Mix (9 components)




Requires a high-purity VOC single-stage regulator. See page 433.


500 www.restek.com 800-356-1688 or 814-353-1300


International Mixes

stearyl stearateStearyl Stearate Test Solution


2,000µg/mL in cyclohexane, 10mL/ampul (enough to check one Florisil cartridge)cat. # 31636 (ea.)

diesel fuel #2 composite mineral oil

Florisil® Cartridge Quality Control Standard Mixture, Rev.2

(2 components)


n-Tetracontane (C40)Neat, 100mg

cat. # 31859 (ea.)

n-Decane (C10)Neat, 1mL/ampul

cat. # 31858 (ea.)

Stearyl StearateNeat, 100mg

cat. # 31860 (ea.)

n-decane (C10) 20µL/L n-tetracontane (C40) 20mg/LExtraction Solvent Stock Solution #2 (2 components)


ISO/DIS 9377 Water Quality Testing

• For GC analysis of total petroleum hydrocarbons (TPH) in water.

• Calibration standard available as Diesel #2/ motor oil andDiesel #2/mineral oil.

Reference mixtures for ISO/DIS 9377 (German H-53), a gaschromatography/flame ionization detection (GC/FID) method.

diesel fuel #2 composite motor oilDiesel #2/Motor Oil (2 components)


diesel fuel #2 composite mineral oilDiesel #2/Mineral Oil (2 components)


diesel #2 (additive-free)mineral oil (additive-free [i.e., USP grade] bp 325-460

or C18-C32 retention time range)

Standard Mixture Stock Solution (2 components)

5,000µg/mL each in cyclohexane, 1mL/ampul (prepares 8mL of 1.25µg/µL calibrationcurve high point) Total hydrocarbon concentration is 10,000µg/mL.

cat. # 31630 (ea.)

diesel #2 (additive-free)motor oil (additive-free bp 325–460 or C18–C32 retention time range)

Quality Control Standard Mixture, Revised (2 components)

500µg/mL each in acetone, 1mL/ampul (1mL is enough mix to spike one 900mL qualitycontrol sample). Total hydrocarbon concentration is 1,000µg/mL.

cat. # 31641 (ea.)

Quality Control Standard Mixture (2 components)

diesel #2 (additive-free)mineral oil (additive-free [i.e., USP grade] bp 391–522

or C24–C40 retention time range)500µg/mL each in acetone, 1mL/ampul (1mL is enough mix to spike one quality control sample). Total hydrocarbon concentration is 1,000µg/mL.

cat. # 31631 (ea.)

n-decane (C10)n-dodecane (C12)n-tetradecane (C14)n-hexadecane (C16)n-octadecane (C18)n-eicosane (C20)n-docosane (C22)n-tetracosane (C24)

n-hexacosane (C26)n-octacosane (C28)n-triacontane (C30)n-dotriacontane (C32)n-tetratriacontane (C34)n-hexatriacontane (C36)n-octatriacontane (C38)n-tetracontane (C40)

System Performance Test Standard Mixture of n-Alkanes

(16 components)


n-decane (C10) 20µL/L n-tetracontane (C40) 20mg/LExtraction Solvent Stock Solution #1 (2 components)


ISO/DIS 9377 Water Quality Testing cont'd




800-356-1688 or 814-353-1300 www.restek.com 501


UST Monitoring

Retention Time StandardsUsed during initial sample screening, to determine retentiontime windows for each petroleum product. Gasoline generallyelutes in the window from C6 to C10 (or C12), and diesel fuelfrom C10 (or C12) to C24 (or C28). Retention above C24 (orC28) indicates oil or lubricant contamination.

n-decane (C10)n-pentacosane (C25)

n-hexatriacontane (C36)Retention Time Marker Standard (3 components)


n-hexane (C6)n-decane (C10)

n-dodecane (C12)Retention Time Marker (3 components)


n-hexane (C6)n-dodecane (C12)

n-octacosane (C28)n-pentatriacontane (C35)

TNRCC 1005 Retention Time Markers Mix (4 components)

200µg/mL each in pentane, 1mL/ampulcat. # 31698 (ea.)


n-pentacosane (C25)n-hexatriacontane (C36)

Retention Time Marker - Alaska (4 components)


Fuel Composite Standards

Unleaded Gasoline Composite Standard




Diesel Fuel #2 Composite Standard




Kerosene Composite Standard




Motor Oil Composite Standards

Motor Oil Composite Standard

Prepared from an equal volume blend of 5W30, 10W30, 10W40,and 20W50 motor oils. After blending, a precisely weighedamount of the composite is added to a volumetric flask to pro-duce the standard.


Used Motor Oil Composite Standard

Prepared from an equal volume blend from five gasoline pow-ered vehicles (belonging to Restek employees). After blending, aprecisely weighed amount of the composite is added to a volu-metric flask to produce the standard.


also availableOther fuels, oils and lubricant oils available on request as custom products.

Underground Storage Tank Monitoring (UST):General

CCaatteeggoorryy CCoommppoouunndd CCllaassss

Retention Time Standards . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Fuel Composite Standards . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Motor Oil Composite Standards . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Single Source Fuel Standards . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Military Fuels (Jet Propellant) . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Fuel Oil Degradation Test . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Mineral Spirits . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

PVOC, GRO and BTEX . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Gasoline Surrogate and Internal Standards . . . . . . . . . . . . . . . . . . . . . .Volatiles

Diesel Surrogate and Internal Standards . . . . . . . . . . . . . . . . . . .Hydrocarbons

Diesel/Biodiesel Blend . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

n-hexane (C6)n-decane (C10)n-dodecane (C12)n-tetracosane (C24)

n-octacosane (C28)n-triacontane (C30)n-tetracontane (C40)

Leaking Underground Storage Tank Retention Time Standard

(7 components)

25µg/mL each in methylene chloride, 1mL/ampulcat. # 31200 (ea.)

501-504_ARM_USTintro.qxp 11/22/2010 8:40 PM Page 501

502 www.restek.com 800-356-1688 or 814-353-1300


UST MonitoringSingle Source Fuels Single Source Fuels cont'd

Military Fuels (Jet Propellant)

Unleaded Gasoline Standard

Prepared from a single source (one refinery) product.5,000µg/mL in P&T methanol, 1mL/ampul

cat. # 30096 (ea.)

Kerosene Standard

Prepared from a single source (one refinery) product.5,000µg/mL in methylene chloride, 1mL/ampul

cat. # 31229 (ea.)

Diesel Fuel #2 Standard

Prepared from a single source (one refinery) product.5,000µg/mL in methylene chloride, 1mL/ampul

cat. # 31233 (ea.)

Fuel Oil #4 Standard

Fuel oil #4 is typically used in limited applications in which thefuel cannot be preheated prior to burning. The fuel is a blend ofdistillate (fuel oil #2) and residual (fuel oil #6) to meet ASTM vis-cosity specifications. Fuel oil #4 used to prepare this mixture hasa kinematic viscosity of 21.9 at 38°C (100°F), measured usingASTM D-445.5,000µg/mL in methylene chloride, 1mL/ampul


cat. # 31244 (ea.)


Fuel oil #5 is typically used in applications in which there is littleor no preheating of the fuel prior to burning. A blend of distillate(fuel oil #2) and residual (fuel oil #6), the fuel oil #5 used to pre-pare this mixture has a kinematic viscosity of 106.5 at 38°C(100°F), measured using ASTM D-445.




This fuel, sometimes called bunker C or residual, is a black vis-cous oil. Applications in which it may be used require the abilityto preheat the fuel prior to pumping and burning.




Aviation Gas Standard

100-octane low-lead fuel currently used in piston-type aircraft.




Jet Fuel A Standard

Commercial jet fuel A.5,000µg/mL in methylene chloride, 1mL/ampul



cat. # 31243 (ea.)

Creosote Oil Standard

Creosote oil, a widely used wood preservative produced by dis-tilling coal tar, contains chemicals that are classified as carcino-gens (e.g., benzo(a)pyrene). We offer this high concentrationstandard.


Hydraulic Oil Standard


JP-4 Military Fuel Standard











diesel/biodiesel 80:20

Diesel/Biodiesel 80:20 Blend Standard

The biodiesel component is methyl soyate.



800-356-1688 or 814-353-1300 www.restek.com 503


UST MonitoringFuel Oil Degradation Test

heptadecane (C17)octadecane (C18)pristane (2,6,10,14-tetramethylpentadecane)phytane (2,6,10,14-tetramethylhexadecane)

1Interpretation of Gas Chromatographic Data in Subsurface HydrocarbonInvestigations, R. Senn and M. Johnson, Ground Water Monitoring Review, Winter1987.

Fuel Oil Degradation Mix (4 components)

Subsurface degradation of fuel oil spills can be estimated byexamining the ratios of C17/pristane and C18/phytane.1 To assistin identifying these four compounds from the complex fuel oilanalysis, we offer a product that contains these compounds forretention time determination.


Mineral Spirits

Mineral Spirits Standards (Unweathered)




There are four general types of mineral spirits, classified accord-ing to boiling point range (BPR):

• Type I (Stoddard solvent) BPR 149–182°C • Type II (high flash point) BPR 177–196°C • Type III (odorless) BPR 149–196°C• Type IV (low dry point) BPR 149–174°C

We prepare our solutions from an equal volume blend of Type I,II, and III mineral spirits.

Stoddard Solvent Standard

Stoddard solvent is also known as Type I mineral spirits, TexsolveS, or Varsol® 1 mineral spirits. We offer this reference material forthose who need to calibrate Stoddard solvent separately. Thisstandard is dissolved in methanol for analysis by either directinjection or purge and trap.


Petroleum Volatile Organic Compounds (PVOC),Gasoline Range Organics (GRO), & Benzene-Toluene-Ethylbenzene-Xylenes (BTEX)

benzeneethylbenzenemethyl tert-butyl ether (MTBE)toluene


PVOC Mix (California) (7 components)


benzeneethylbenzenemethyl tert-butyl ether (MTBE)naphthalenetoluene

1,2,4-trimethylbenzene1,3,5-trimethylbenzenem-xyleneo-xylenep-xylene

PVOC/GRO Mix (Wisconsin) (10 components)


benzeneethylbenzene3-methylpentanenaphthalenetoluene

1,2,4-trimethylbenzene2,2,4-trimethylpentane (isooctane)m-xyleneo-xylene

GRO Mix (9 components)


benzene 500µg/mLethylbenzene 500heptane 5002-methylpentane 1,500toluene 1,500

1,2,4-trimethylbenzene 1,0002,2,4-trimethylpentane 1,500m-xylene 1,000o-xylene 1,000

GRO Mix (EPA) (9 components)



Aluminum construction.Size: 8 x 24 cm Volume/Pressure: 104 liters of gas @ 1,800 psiCGA-180 outlet fitting.Weight: 1.5 lbs/0.7 kg

Scotty 110L Cylinders:

Aluminum construction.Size: 8.3 x 29.5 cm Volume/Pressure: 110 liters of gas @ 1,800 psiCGA-180 outlet fitting.Weight: 2.2 lbs/1 kgUS DOT Specs: 3AL2216

cylinder design









Requires a high-purity VOC single-stageregulator. See page 433.No data pack available.Quantity discounts not available.




1ppm in nitrogen, 110 liters @ 1,800psi (Pi-marked Cylinder)

cat. # 34414-PI (ea.) 100ppb in nitrogen, 110 liters @ 1,800psi (Pi-marked Cylinder)

cat. # 34428-PI (ea.)



504 www.restek.com 800-356-1688 or 814-353-1300


UST MonitoringGasoline Surrogate and Internal Standards

Diesel Surrogate and Internal Standards

Petroleum Volatile Organic Compounds (PVOC),Gasoline Range Organics (GRO), & Benzene-Toluene-Ethylbenzene-Xylenes (BTEX) cont'd


1,2,4-trimethylbenzene 1,0002,2,4-trimethylpentane 1,500m-xylene 1,000o-xylene 1,000p-xylene 1,000

Gasoline Component Standard (10 components)

10,000µg/mL total in P&T methanol, 1mL/ampulcat. # 30486 (ea.)

CCeerrttiiffiieedd ffoorr::benzene*ethylbenzene*isopropyl benzene*methyl tert-butyl ether (MTBE)*naphthalene*

toluene*m-xylene*o-xylene*p-xylene*

*Concentration differs lot-to-lot. See on-line Certificate of Analysis for certifiedconcentrations.

Certified BTEX in Unleaded Gas Composite Standard

(9 components)

5,500ppm gasoline in P&T methanol, 1mL/ampulcat. # 30237 (ea.)

CCeerrttiiffiieedd ffoorr::benzene*ethylbenzene*m-ethyltoluene*o-ethyltoluene*p-ethyltoluene*isopropylbenzene*methyl tert-butyl ether (MTBE)*naphthalene*

n-propylbenzene*toluene*1,2,3-trimethylbenzene*1,2,4-trimethylbenzene*1,3,5-trimethylbenzene*m-xylene*o-xylene*p-xylene*


Certified Aromatics in Gasoline (16 components)

5,500ppm gasoline in P&T methanol, 1mL/ampulcat. # 30485 (ea.)

CCeerrttiiffiieedd PPAAHHssacenaphthene*acenaphthylene*fluorene*1-methylnaphthalene*

2-methylnaphthalene*naphthalene*phenanthrene*


Certified PAHs in Diesel (7 components)

50,000ppm diesel #2 in methylene chloride, 1mL/ampulcat. # 31673 (ea.)

Diesel/Biodiesel Standard

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriiccee4-bromofluorobenzene PTM 2,500 300674-bromofluorobenzene PTM 10,000 300821-chlorooctane PTM 10,000 30084α,α,α-trifluorotoluene PTM 2,500 30068α,α,α-trifluorotoluene PTM 10,000 30083

Recommended Internal Standard (PID) for EPA GRO Method

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriiccee1-chloro-4-fluorobenzene PTM 2,500 30066



CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriiccee1-chlorooctadecane D 10,000 310982-fluorobiphenyl D 10,000 31096o-terphenyl D 10,000 31097p-terphenyl D 10,000 31095

Recommended Internal Standards

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriiccee5-α-androstane D 2,000 31065o-terphenyl A 2,000 31066

A = acetone; D = methylene chloride



The biodiesel component is methyl soyate.5,000µg/mL in methylene chloride, 1mL/ampul

cat. # 31880 (ea.)

also availableASTM Method D6584-00 and EN14105 Biodiesel Standards.

See page 516.


800-356-1688 or 814-353-1300 www.restek.com 505


UST Monitoring

Alaska

AK101

Method for determination of aromatic and aliphatic hydrocarbonsin gasoline range organics.

Alaska Department of Environmental Conservation (ADEC) regulations indicate which products and indicator compounds areto be tested for each petroleum range. The analyst must use thefollowing Alaska Series Methods or appropriate SW-846 methodfor the indicator compounds. The Alaska UST procedurals man-ual indicates which products are to be tested for each petroleumrange.

benzeneethylbenzene1-ethyl-2-methylbenzene1-ethyl-3-methylbenzene1-ethyl-4-methylbenzeneisopropylbenzenen-propylbenzene

toluene1,2,3-trimethylbenzene1,2,4-trimethylbenzene1,3,5-trimethylbenzenem-xyleneo-xylenep-xylene

Alaska UST Method AK101AA (14 components)


Alaska cont'd

Unleaded Gasoline Composite Standard




1-Chloro-4-fluorobenzene Mix


4-Bromofluorobenzene Mix


αα,αα,αα-Trifluorotoluene




for more infoState of Alaska

Method and regulatory information is available from:

Alaska Department of Environmental Conservation410 Willoughby AvenueJuneau, AK 99801-1795Phone: (907) 465-5203Fax: (907) 465-5218

www.dec.state.ak.us/regulations/index.htm

SSttaattee CCoommppoouunndd CCllaassss

Alaska . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Arizona . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

California/Los Angeles . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Connecticut . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Florida . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Massachusetts . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Michigan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Mississippi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

New Jersey . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Northwest (Oregon & Washington) . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Pennsylvania . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Tennessee/Mississippi . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Texas . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Washington . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Wisconsin . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Hydrocarbons

Underground Storage Tank Monitoring (UST):State Specific Methods


n-pentacosane (C25)n-hexatriacontane (C36)

Retention Time Marker - Alaska (4 components)




and/or lot number)


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UST Monitoring

AK103

Diesel Fuel #2 Composite Standard




5-αα-androstane


Alaska cont'd

o-Terphenyl



Method for determination of aromatic and aliphatichydrocarbons in residual range organics.

SAE30 motor oil:SAE40 motor oil (1:1)Residual Range Calibration Standard (RCS)


SAE30 motor oil:SAE40 motor oil (1:1)Residual Range Calibration Verification Standard (CVS)



This fuel, sometimes called bunker C or residual, is a black vis-cous oil. Applications in which it may be used require the abilityto preheat the fuel prior to pumping and burning.




n-Triacontane-d62

500µg/mL in methylene chloride, 1mL/ampulcat. # 31816 (ea.)

squalaneo-terphenyl

tetrahydronaphtholSurrogate Standard Mixture (3 components)


AK102

Method for determination of aromatic and aliphatichydrocarbons in diesel range organics.

n-decane (C10)n-undecane (C11)n-dodecane (C12)n-tridecane (C13)n-tetradecane (C14)n-pentadecane (C15)n-hexadecane (C16)n-heptadecane (C17)

n-octadecane (C18)n-nonadecane (C19)n-eicosane (C20)n-heneicosane (C21)n-docosane (C22)n-tricosane (C23)n-tetracosane (C24)n-pentacosane (C25)

DRO Mix (Tennessee/Mississippi) (16 components)


Kerosene Composite Standard






Motor Oil Composite Standard50,000µg/mL in methylene chloride, 1mL/ampul

cat. # 31464 (ea.)


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UST MonitoringArizona

*For samples suspected of gasoline contamination, Los Angeles County requireslaboratories to calibrate and report these compounds.

California

Los Angeles County, CAWell Investigation Program (WIP)*

Connecticut

Florida


n-docosane (C22)n-dotriacontane (C32)

Extraction Retention Time Standard (4 components)


10W30 motor oil:diesel fuel #2 (1:1 blend)DRO/GRO Calibration Standard


n-decane (C10)n-dodecane (C12)n-tetradecane (C14)n-hexadecane (C16)n-octadecane (C18)n-eicosane (C20)

n-docosane (C22)n-tetracosane (C24)n-hexacosane (C26)n-octacosane (C28)n-triacontane (C30)n-dotriacontane (C32)

DRO/GRO Range Calibration Standard (12 components)


benzene naphthaleneGRO P&T Retention Time Standard (2 components)


diisopropyl ether (DIPE) 2,000µg/mLethyl-tert-butyl ether (ETBE) 2,000tert-amyl methyl ether (TAME) 2,000tert-butyl alcohol 10,000methyl tert-butyl ether (MTBE) 2,000

California Oxygenates Mix (5 components)


Methanol10,000µg/mL in DI Water, 1mL/ampul

cat. # 30467 (ea.)

Ethanol10,000µg/mL in DI Water, 1mL/ampul

cat. # 30466 (ea.)



benzenechlorobenzene1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzeneethylbenzene

methyl tert-butyl ether (MTBE)toluenem-xyleneo-xylenep-xylene

CA WIP VOA Standard (11 components)


n-nonane (C9)n-decane (C10)n-dodecane (C12)n-tetradecane (C14)n-hexadecane (C16)n-octadecane (C18)n-eicosane (C20)n-docosane (C22)

n-tetracosane (C24)n-hexacosane (C26)n-octacosane (C28)n-triacontane (C30)n-dotriacontane (C32)n-tetratriacontane (C34)n-hexatriacontane (C36)

Connecticut ETPH Calibration Mixture (15 components)


n-nonatriacontane (C39)

*Ground transportation shipments only.

Florida TRPH Surrogate Mix

3,000µg/mL in carbon disulfide, 1mL/ampul*cat. # 31456 (ea.)

3,000µg/mL in carbon disulfide, 10mL/ampul*cat. # 31877 (ea.)

n-octane (C8)n-decane (C10)n-dodecane (C12)n-tetradecane (C14)n-hexadecane (C16)n-octadecane (C18)n-eicosane (C20)n-docosane (C22)n-tetracosane (C24)

n-hexacosane (C26)n-octacosane (C28)n-triacontane (C30)n-dotriacontane (C32)n-tetratriacontane (C34)n-hexatriacontane (C36)n-octatriacontane (C38)n-tetracontane (C40)

Florida TRPH Standard (17 components)


2,000µg/mL each in carbon disulfide, 1mL/ampul*cat. # 31878 (ea.)

o-Terphenyl2,000µg/mL in acetone, 1mL/ampul


cat. # 31097 (ea.)

benzeneethylbenzenemethyl tert-butyl ether (MTBE)toluene


PVOC Mix (California) (7 components)





508 www.restek.com 800-356-1688 or 814-353-1300


UST Monitoring

n-pentane (C5)n-nonane (C9)benzene2,5-dibromotoluene (SS)ethylbenzeneisooctane2-methylpentane

methyl tert-butyl ether (MTBE)naphthalenetoluene1,2,4-trimethylbenzenem-xyleneo-xylenep-xylene

MA VPH Matrix Spike Mix with Surrogate (14 components)


acenaphtheneacenaphthyleneanthracenebenzo(a)anthracenebenzo(a)pyrenebenzo(b)fluoranthenebenzo(k)fluoranthenebenzo(ghi)perylenechrysene

dibenzo(a,h)anthracenefluoranthenefluoreneindeno(1,2,3-cd)pyrene2-methylnaphthalenenaphthalenephenanthrenepyrene

MA EPH Aromatic Hydrocarbon Standard (17 components)


n-nonane (C9)n-decane (C10)n-dodecane (C12)n-tetradecane (C14)n-hexadecane (C16)n-octadecane (C18)n-nonadecane (C19)

n-eicosane (C20)n-docosane (C22)n-tetracosane (C24)n-hexacosane (C26)n-octacosane (C28)n-triacontane (C30)n-hexatriacontane (C36)

MA EPH Aliphatic Hydrocarbon Standard (14 components)


n-nonane (C9)n-tetradecane (C14)n-nonadecane (C19)n-eicosane (C20)n-octacosane (C28)

acenaphtheneanthracenechrysenenaphthalenepyrene

MA EPH Matrix Spike Mix (10 components)


MA VPH Standard with Surrogate (14 components)

n-pentane (C5) 1,000µg/mLn-nonane (C9) 1,000benzene 5002,5-dibromotoluene (SS) 1,000ethylbenzene 500isooctane 1,5002-methylpentane 1,500

methyl tert-butyl ether (MTBE) 1,500naphthalene 1,000toluene 1,5001,2,4-trimethylbenzene 1,000m-xylene 1,000o-xylene 1,000p-xylene 1,000


2,5-dibromotoluene

MA VPH Surrogate Standard



Massachusetts

n-pentane (C5) 1,000µg/mLn-nonane (C9) 1,000benzene 500ethylbenzene 500isooctane 1,5002-methylpentane 1,500methyl tert-butyl ether (MTBE) 1,500

naphthalene 1,000toluene 1,5001,2,4-trimethylbenzene 1,000m-xylene 1,000o-xylene 1,000p-xylene 1,000

MA Volatile Petroleum Hydrocarbon (VPH) Standard

(13 components)


benzenen-butylcyclohexanen-decane (C10)2,5-dibromotoluene (SS)ethylbenzene2-methylpentanemethyl tert-butyl ether (MTBE)naphthalene

n-nonane (C9)n-pentane (C5)toluene1,2,4-trimethylbenzene2,2,4-trimethylpentane (isooctane)m-xyleneo-xylenep-xylene

MA VPH Standard with Surrogate Rev. 1.1 (July 2004)

(16 components)


benzenen-butylcyclohexanen-decane (C10)2,5-dibromotoluene (SS)ethylbenzene2-methylpentanemethyl tert-butyl ether (MTBE)naphthalene

n-nonane (C9)n-pentane (C5)toluene1,2,4-trimethylbenzene2,2,4-trimethylpentane (isooctane)m-xyleneo-xylenep-xylene

MA VPH Matrix Spike Mix with Surrogate Rev. 1.1 (July 2004)

(16 components)



benzene1,3-butadienebutylcyclohexanecyclohexanen-decane2,3-dimethylheptane2,3-dimethylpentanen-dodecaneethylbenzenen-heptanen-hexaneisopentaneisopropylbenzene

p-isopropyltoluenemethyl tert-butyl ether1-methyl-3-ethylbenzenenaphthalenen-nonanen-octanetoluene1,2,3-trimethylbenzene1,3,5-trimethylbenzenen-undecaneo-xylenem/p-xylene (combined)

Requires a high-purity VOC single-stage regulator. See page 433.No data pack available.Quantity discounts not available.

Massachusetts APH Mix (26 components)


cat. # 34540-PI (ea.)

Now with

Naphthalene!


140-450ppb in nitrogen, 90 liters @ 1,500psig (Pi-marked Cylinder)

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UST MonitoringMichigan

Mississippi

1-chlorooctadecane o-terphenylMA EPH Surrogate Spike Mix (2 components)


2-bromonaphthalene 2-fluorobiphenyl

MA Fractionation Surrogate Spike Mix (2 components)


PPAAHHss::acenaphtheneacenaphthyleneanthracenebenzo(a)anthracenebenzo(a)pyrenebenzo(b)fluoranthenebenzo(k)fluoranthenebenzo(ghi)perylenechrysenedibenzo(a,h)anthracenefluoranthenefluoreneindeno(1,2,3-cd)pyrene2-methylnaphthalenenaphthalenephenanthrenepyrene

HHyyddrrooccaarrbboonnss::n-nonane (C9)n-decane (C10)n-dodecane (C12)n-tetradecane (C14)n-hexadecane (C16)n-octadecane (C18)n-nonadecane (C19)n-eicosane (C20)n-docosane (C22)n-tetracosane (C24)n-hexacosane (C26)n-octacosane (C28)n-triacontane (C30)n-hexatriacontane (C36)

MA Fractionation Check Mix (31 components)


Massachusetts cont'd

benzene1,2-dibromoethane1,2-dichloroethaneethylbenzeneisopropylbenzene2-methylnaphthalenemethyl tert-butyl-ether (MTBE)

naphthalenetoluene1,2,4-trimethylbenzene1,3,5-trimethylbenzenem-xyleneo-xylenep-xylene

Michigan GRO Mix (14 components)


1-chlorooctadecane1-Chlorooctadecane Mix


Naphthalene-d8


5-α-androstaneMA EPH Internal Standard










Save time with prepackedsample prep cartridges!

MA EPH Tubes

See page 394.


510 www.restek.com 800-356-1688 or 814-353-1300


UST Monitoring

Northwest USA Regional Method(Oregon & Washington)also see Washington, page 512

n-dodecane (C12)n-tetracosane (C24)

tolueneNW TPH-HCID Retention Time Mix (3 components)


n-pentacosane (C25) 4-bromofluorobenzeneNW TPH-HCID Surrogate Mix (2 components)


CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriiccee2-fluorobiphenyl D 10,000 31096o-terphenyl D 10,000 31097p-terphenyl D 10,000 31095pentacosane (C25) D 10,000 31487D = methylene choride

NW TPH-Dx Surrogate Mix Standards




New Jersey

n-nonane (C9)n-decane (C10)n-dodecane (C12)n-tetradecane (C14)n-hexadecane (C16)n-octadecane (C18)n-eicosane (C20)n-heneicosane (C21)n-docosane (C22)n-tetracosane (C24)

n-hexacosane (C26)n-octacosane (C28)n-triacontane (C30)n-dotriacontane (C32)n-tetratriacontane (C34)n-hexatriacontane (C36)n-octatriacontane (C38)n-tetracontane (C40)2-methylnaphthalenenaphthalene

NJDEP EPH 10/08 Rev.2 Aliphatics Calibration

Standard (20 components)

2,000µg/mL each in hexane:carbon disulfide (80:20), 1mL/ampulcat. # 30540 (ea.)


dibenzo(a,h)anthracenefluoranthenefluoreneindeno(1,2,3-cd)pyrene2-methylnaphthalenenaphthalenephenanthrenepyrene1,2,3-trimethylbenzene

NJDEP EPH 10/08 Rev.2 Aromatics Calibration

Standard (18 components)


n-nonane (C9)n-decane (C10)n-dodecane (C12)n-tetradecane (C14)n-hexadecane (C16)n-octadecane (C18)n-eicosane (C20)n-heneicosane (C21)n-docosane (C22)

n-tetracosane (C24)n-hexacosane (C26)n-octacosane (C28)n-triacontane (C30)n-dotriacontane (C32)n-tetratriacontane (C34)n-hexatriacontane (C36)n-octatriacontane (C38)n-tetracontane (C40)

NJDEP EPH 10/08 Rev.2 Aliphatics Matrix Spike Mix

(18 components)




NJDEP EPH 10/08 Rev.2 Aromatics Matrix Spike Mix

(18 components)

200µg/mL each in acetone:toluene (50:50), 5mL/ampulcat. # 30543 (ea.)

n-nonane (C9)n-decane (C10)n-dodecane (C12)n-tetradecane (C14)n-hexadecane (C16)n-octadecane (C18)n-eicosane (C20)n-heneicosane (C21)n-docosane (C22)

n-tetracosane (C24)n-hexacosane (C26)n-octacosane (C28)n-triacontane (C30)n-dotriacontane (C32)n-tetratriacontane (C34)n-hexatriacontane (C36)n-octatriacontane (C38)n-tetracontane (C40)

NJDEP EPH 10/08 Rev.2 Aliphatics Fractionation

Check Mix (18 components)


acenaphtheneacenaphthyleneanthracenebenzo(a)anthracenebenzo(a)pyrenebenzo(b)fluoranthenebenzo(ghi)perylenebenzo(k)fluoranthene

chrysenedibenzo(a,h)anthracenefluoranthenefluoreneindeno(1,2,3-cd)pyrenephenanthrenepyrene1,2,3-trimethylbenzene

NJDEP EPH 10/08 Rev.2 Aromatics Fractionation

Check Mix (16 components)


New Jersey cont'd

NEW!

NEW!

NEW!

NEW!

NEW!

NEW!


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UST Monitoring

Texas TNRCC Method 1006

1-Chlorooctane10,000µg/mL in P&T methanol, 1mL/ampul

cat. # 30084 (ea.)

n-hexane (C6)n-heptane (C7)n-octane (C8)n-decane (C10)n-dodecane (C12)

n-hexadecane (C16)n-heneicosane (C21)n-octacosane (C28)n-pentatriacontane (C35)

TNRCC 1006 Retention Time Marker Mix (9 components)

200µg/mL in pentane, 1mL/ampulcat. # 31814 (ea.)

Texas

Texas TNRCC Method 1005


n-octacosane (C28)TX TPH Locator Mix (3 components)


diesel fuel #2 composite unleaded gasoline compositeTX TPH Calibration Mix (2 components)

10,000µg/mL each in pentane, 1mL/ampulcat. # 31483 (ea.)

diesel fuel #2 composite unleaded gasoline compositeTX TPH Matrix Spike Mix (2 components)


Alternate Boiling Point/Carbon Number Distribution Marker

Stock Standard (9 components)

n-hexane (C6)n-octane (C8)n-decane (C10)n-dodecane (C12)n-hexadecane (C16)

n-heneicosane (C21)n-octacosane (C28)n-pentatriacontane (C35)n-hexatriacontane (C36)


Don’t see the UST mix you need? We can custom blend a UST mix to meet therequirements of your method. Visit our web site at www.restek.com/solutions

Pennsylvania

Tennessee/Mississippi

benzene1,2-dibromoethane1,2-dichloroethaneethylbenzeneisopropyl benzenemethyl tert-butyl ether (MTBE)

naphthalenetoluenem-xyleneo-xylenep-xylene

PA DEP UST Standard (11 components)


αα,αα,αα-Trifluorotoluene2,000µg/mL in P&T methanol, 1mL/ampul

cat. # 30048 (ea.) 2,500µg/mL in P&T methanol, 1mL/ampul

cat. # 30068 (ea.) 10,000µg/mL in P&T methanol, 1mL/ampul

cat. # 30083 (ea.)

1-Chlorooctadecane










n-hexane (C6)n-dodecane (C12)

n-octacosane (C28)n-pentatriacontane (C35)

TNRCC 1005 Retention Time Markers Mix (4 components)


Texas cont'd


512 www.restek.com 800-356-1688 or 814-353-1300


UST Monitoring

Wisconsin

Washingtonalso see Northwest USA Regional Method, page 510

n-pentane (C5)n-hexane (C6)n-octane (C8)n-decane (C10)n-dodecane (C12)

1-methylnaphthalenenaphthalenetoluene1,2,3-trimethylbenzene

WA VPH Marker Standard (9 components)


n-pentane (C5)n-hexane (C6)n-octane (C8)n-decane (C10)n-dodecane (C12)benzeneethylbenzene1-methylnaphthalene

methyl tert-butyl ether (MTBE)naphthalenetoluene1,2,3-trimethylbenzenem-xyleneo-xylenep-xylene

WA VPH Standard (15 components)


acenaphthenebenzo(ghi)perylenenaphthalene

pyrenetoluene1,2,3-trimethylbenzene

WA EPH Aromatic Hydrocarbon Mix (6 components)


n-octane (C8)n-decane (C10)n-dodecane (C12)

n-hexadecane (C16)n-heneicosane (C21)n-tetratriacontane (C34)

WA EPH Aliphatic Hydrocarbon Mix (6 components)


Washington cont'd

acenaphtheneacenaphthyleneanthracenebenzo(a)anthracenebenzo(a)pyrenebenzo(b)fluoranthenebenzo(k)fluoranthenebenzo(ghi)perylenechrysene


WA EPH Aromatic Hydrocarbon Standard (18 components)


n-decane (C10)n-dodecane (C12)n-hexadecane (C16)n-heneicosane (C21)acenaphthene

anthracenebenzo(a)pyrenebenzo(ghi)perylenenaphthalenepyrene

WA EPH Matrix Spike Mix (10 components)


n-octane (C8)n-decane (C10)n-dodecane (C12)n-hexadecane (C16)n-heneicosane (C21)n-tetratriacontane (C34)acenaphtheneacenaphthyleneanthracenebenzo(a)anthracenebenzo(a)pyrene

benzo(b)fluoranthenebenzo(k)fluoranthenebenzo(ghi)perylenechrysenedibenzo(a,h)anthracenefluoranthenefluoreneindeno(1,2,3-cd)pyrenenaphthalenephenanthrenepyrene

WA EPH Fractionation Check Mix (22 components)


n-decane (C10)n-dodecane (C12)n-tetradecane (C14)n-hexadecane (C16)n-octadecane (C18)

n-eicosane (C20)n-docosane (C22)n-tetracosane (C24)n-hexacosane (C26)n-octacosane (C28)

DRO Mix (EPA/Wisconsin) (10 components)


benzeneethylbenzenemethyl tert-butyl ether (MTBE)naphthalenetoluene

1,2,4-trimethylbenzene1,3,5-trimethylbenzenem-xyleneo-xylenep-xylene

PVOC/GRO Mix (Wisconsin) (10 components)





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ASTM Methods

acetaldehyde-2,4-DNPHacetone-2,4-DNPHacrolein-2,4-DNPHbenzaldehyde-2,4-DNPHn-butyraldehyde-2,4-DNPHcrotonaldehyde-2,4-DNPHformaldehyde-2,4-DNPH

hexaldehyde-2,4-DNPHmethacrolein-2,4-DNPHmethyl ethyl ketone-2,4-DNPHpropionaldehyde-2,4-DNPHm-tolualdehyde-2,4-DNPHvaleraldehyde-2,4-DNPH

CARB 1004 Aldehyde/Ketone-DNPH Calibration Standard

(13 components)


ASTM Method 5197 (Formaldehyde and OtherCarbonyl Compounds in Air)

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceeacetaldehyde-2,4-DNPH ACN 100 33074acetone-2,4-DNPH ACN 100 33075benzaldehyde-2,4-DNPH ACN 100 33077n-butyraldehyde-2,4-DNPH ACN 100 33079crotonaldehyde-2,4-DNPH ACN 100 33080formaldehyde-2,4-DNPH ACN 100 33082glycolaldehyde-2,4-DNPH ACN 100 33091hexaldehyde-2,4-DNPH ACN 100 33083isobutyraldehyde-2,4-DNPH ACN 100 33084methacrolein-2,4-DNPH ACN 100 33095propionaldehyde-2,4-DNPH ACN 100 33086m-tolualdehyde-2,4-DNPH ACN 100 33088

ACN = acetonitrile*Concentration calculated as the aldehyde/ketone.

DNPH Reference Materials


CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriiccee2,6-TDIP DMSO 1,000 330002,4-TDIP DMSO 1,000 330011,6-HDIP DMSO 1,000 330024,4'-MDIP DMSO 1,000 33003

DMSO = dimethyl sulfoxide

Isocyanates Singles

ASTM D5836 and OSHA 42 are test methods for determining2,4-toluene diisocyanate (2,4-TDI) and 2,6-TDI in the workplace atmosphere. OSHA 47 is for 4,4'-methylenediphenylisocyanate (4,4'-MDI) in indoor air, and NIOSH Method 5522 isan analysis for 2,4-TDI, 2,6-TDI, 4,4'-MDI, and 1,6-hexamethyl-ene diisocyanate (1,6-HDI) in air. Restek offers the 1,-(2-pyridyl)piperzine (1-2pp) derivative.


ASTM Method D5836-03/OSHA 42, OSHA 47, NIOSH5522 (Analysis of Isocyanates in Indoor Air by HPLC)

formaldehyde oxazoladineFormaldehyde Oxazoladine

2,000µg/mL in toluene, 1mL/ampulcat. # 33004 (ea.)

n-hexane (C6)n-octane (C8)n-decane (C10)n-dodecane (C12)n-tetradecane (C14)n-hexadecane (C16)n-octadecane (C18)

n-eicosane (C20)2-ethyltoluene3-ethyltoluenetoluene1,2,4-trimethylbenzenep-xylene

E1387 Column Resolution Check Mix (13 components)


These materials also can be used for underground storage tankmonitoring.

ASTM E1387 and E1618 (Fire Debris Analysis)




E1618 Test Mix (13 components)

Components in this mix (0.5µL/mL or 0.05% volume/volumeeach) are at 10x the concentration of the final test solution spec-ified in ASTM 1618 and ASTM 1387.

0.05% volume/volume each in methylene chloride, 1mL/ampulcat. # 31613 (ea.)



REFERENCE STANDARDS

PETROLEUM &PETROCHEMICAL MATERIALSASTM Methods

D2887-01 and D3710-95 (Simulated Distillation) . . . . . .515

D3606-07 (Benzene & Toluene in Finished

Motor & Aviation Gasoline) . . . . . . . . . . . . . . . . . . . . . . . . . .515

D4059-96 (PCB Standards in Oil) . . . . . . . . . . . . . . . . . . . . . .516

D6352-98 (Polywax® Standards) . . . . . . . . . . . . . . . . . . . . . . .516

D6584-00 (Biodiesel) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .516

D6730-01 (Individual Components in Spark

Ignition Engine Fuels) . . . . . . . . . . . . . . . . . . . . . . . . . .516-517

Petroleum & Sulfur Standards . . . . . . . . . . . . . . . . . . . . . .518-521

What’sNEW?


514-529_ARM_pet_cft_ph.qxp 11/9/2010 7:53 PM Page 514

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REFERENCE STANDARDS | PETROLEUM & PETROCHEMICAL MATERIALS

ASTM Methods

ASTM Simulated Distillation Petrochemical Mixtures

American Society for Testing and Materials (ASTMInternational) Method D2887-01 is used to determine the boil-ing range distribution of petroleum products and fractions hav-ing a final boiling point of 538°C (1,000°F) or lower; a boilingrange greater than 55°C (131°F) and a vapor pressure sufficient-ly low to permit sampling at ambient temperature.

n-pentane (C5)n-hexane (C6)n-heptane (C7)n-octane (C8)n-nonane (C9)n-decane (C10)n-undecane (C11)n-dodecane (C12)n-tetradecane (C14)n-pentadecane (C15)

n-hexadecane (C16)n-heptadecane (C17)n-octadecane (C18)n-eicosane (C20)n-tetracosane (C24)n-octacosane (C28)n-dotriacontane (C32)n-hexatriacontane (C36)n-tetracontane (C40)n-tetratetracontane (C44)

No data pack available.*Orders in the US ship FedEx only. Call for options when shipping outside the US.

ASTM D2887-01 Calibration Mix (20 components)

1% w/w in carbon disulfide, 1g solution/ampul*cat. # 31674 (ea.)

5% w/w, Neat, 1g /ampulcat. # 31675 (ea.)

ASTM Methods D2887 and D3710-95

These calibration mixtures are made with pure, highly character-ized neat material, and prepared using NIST-traceable balancesand weights. Each ampul is supplied with a data sheet indicatingthe exact concentration, and a sample chromatogram.

CCoommppoouunndd CCoonncc..((%% ww//ww))

n-hexane (C6) 6n-heptane (C7) 6n-octane (C8) 8n-nonane (C9) 8n-decane (C10) 12n-undecane (C11) 12n-dodecane (C12) 12n-tetradecane (C14) 12n-hexadecane (C16) 10

CCoommppoouunndd CCoonncc..((%% ww//ww))

n-octadecane (C18) 5n-eicosane (C20) 2n-tetracosane (C24) 2n-octacosane (C28) 1n-dotriacontane (C32) 1n-hexatriacontane (C36) 1n-tetracontane (C40) 1n-tetratetracontane (C44) 1

D2887 Calibration Mix (17 components)

Packaged 1mL/ampulcat. # 31222 (ea.)

CCoommppoouunndd CCoonncc..((%% vvooll//vvooll))

n-pentane (C5) 8n-hexane (C6) 6n-heptane (C7) 10n-octane (C8) 5n-decane (C10) 4n-dodecane (C12) 4n-tridecane (C13) 2n-tetradecane (C14) 2

CCoommppoouunndd CCoonncc..((%% vvooll//vvooll))

n-pentadecane (C15) 22-methylbutane 102-methylpentane 62,4-dimethylpentane 6toluene 12p-xylene 14n-propylbenzene 5n-butylbenzene 4

D3710-95 Calibration Mix (16 components)

Packaged 1mL/ampulcat. # 31223 (ea.)



ASTM D3606-07 (Determination of Benzene &Toluene in Finished Motor & Aviation Gasoline by GC)

Contains 25mL each of these mixtures.30647: ASTM D3606 Calibration Standard #1 without Internal Standard30648: ASTM D3606 Calibration Standard #2 without Internal Standard30649: ASTM D3606 Calibration Standard #3 without Internal Standard30650: ASTM D3606 Calibration Standard #4 without Internal Standard30651: ASTM D3606 Calibration Standard #5 without Internal Standard30652: ASTM D3606 Calibration Standard #6 without Internal Standard30653: ASTM D3606 Calibration Standard #7 without Internal Standard


ASTM D3606 Calibration Kit

without Internal Standard

cat. # 30672 (kit)

kit

Contains 1mL each of these mixtures.30654: ASTM D3606 Calibration Standard #1 with MEK Internal Standard30655: ASTM D3606 Calibration Standard #2 with MEK Internal Standard30656: ASTM D3606 Calibration Standard #3 with MEK Internal Standard30657: ASTM D3606 Calibration Standard #4 with MEK Internal Standard30658: ASTM D3606 Calibration Standard #5 with MEK Internal Standard30659: ASTM D3606 Calibration Standard #6 with MEK Internal Standard30660: ASTM D3606 Calibration Standard #7 with MEK Internal Standard



with MEK Internal Standard

cat. # 30673 (kit)

kit

Contains 1mL each of these mixtures.30661: ASTM D3606 Calibration Standard #1 with sec-Butanol Internal Standard30662: ASTM D3606 Calibration Standard #2 with sec-Butanol Internal Standard30663: ASTM D3606 Calibration Standard #3 with sec-Butanol Internal Standard30664: ASTM D3606 Calibration Standard #4 with sec-Butanol Internal Standard30665: ASTM D3606 Calibration Standard #5 with sec-Butanol Internal Standard30666: ASTM D3606 Calibration Standard #6 with sec-Butanol Internal Standard30667: ASTM D3606 Calibration Standard #7 with sec-Butanol Internal Standard



with sec-Butanol Internal Standard

cat. # 30674 (kit)

kit

2,2,4-trimethylpentane (isooctane)ASTM D3606 Backflush Standard

5% vol/vol in nonane, 1mL/ampulcat. # 30671 (ea.)

NEW!

also availableD3606 Application Column (2 column set)


NEW!

NEW!

NEW!

ASTM D3606 StandardsVisit us at www.restek.com/astm


516 www.restek.com 800-356-1688 or 814-353-1300

REFERENCE STANDARDS| PETROLEUM & PETROCHEMICAL MATERIALS

ASTM Methods

ASTM Method D6352-98 (Polywax® Standards)These high molecular weight hydrocarbon waxes are useful forsimulated distillation and other high-temperature GC work.

Volume is 1mL/ampul.CCoommppoouunndd qqttyy.. ccaatt..## ((eeaa..)) pprriicceePolywax 500 1g 36224Polywax 655 1g 36225Polywax 850 1g 36226Polywax 1000 1g 36227


ASTM Method D6584-00 and EN14105 (Biodiesel)Determining Free and Total Glycerin in B100 Biodiesel

Methyl Esters by GC

In the manufacture of biodiesel fuel, triglycerides are split intotheir monoalkyl ester components via transesterification. Thefatty acid monoalkyl esters can be used as fuel in diesel engines.Amounts of free glycerin and total glycerin indicate the quality ofthe conversion of the oil or fat to monoalkyl esters. D6584-00 isa test method for quantitative determination of free glycerin,total glycerin, and mono-, di-, and triglycerides in biodiesel fuelmethyl esters by GC, after silylation of the sample with N-methyl-N-(trimethylsilyl) trifluoroacetamide (MSTFA).

(s)-(-)-1,2,4-Butanetriol

1,000µg/mL in pyridine, 1mL/ampulcat. # 33024 (ea.)


Diolein (1,3-di[cis-octadecenoyl]glycerol)5,000µg/mL in pyridine, 1mL/ampul

cat. # 33022 (ea.)

Glycerin500µg/mL in pyridine, 1mL/ampul

cat. # 33020 (ea.)

Monolein (1-mono[cis-9-octadecenoyl]-rac-glycerol)5,000µg/mL in pyridine, 1mL/ampul

cat. # 33021 (ea.)

Monopalmitin


Tricaprin8,000µg/mL in pyridine, 1mL/ampul

cat. # 33025 (ea.) 8,000µg/mL in pyridine, 5mL/ampul

cat. # 33033 (ea.)

Triolein



The biodiesel component is methyl soyate.


benzene 1.00%tert-butanol 0.50%cyclohexane 28.9%n-decane 1.00%2,3-dimethylbutane 0.50%trans-1,2-dimethylcyclopentane 0.50%2,3-dimethylheptane 0.20%dodecane 0.25%ethanol 8.00%ethylbenzene 25.0%3-ethylpentane 0.20%n-heptane 2.00%n-hexane 2.00%2-methyl-2-butene 2.50%methyl tert-butyl ether 10.0%

1-methylcyclopentene 0.50%1-methyl-2-ethylbenzene 0.50%1-methylnaphthalene 0.25%5-methylnonane 0.20%naphthalene 0.50%n-nonane 2.00%n-octane 2.00%n-pentane 2.00%1,2,3,5-tetramethylbenzene 0.25%toluene 7.00%tridecane 0.25%2,2,3-trimethylpentane 0.52%2,3,3-trimethylpentane 0.50%undecane 0.50%p-xylene 1.00%

2mL prescored ampulcat. # 33034 (ea.)

ASTM Method D6730-01 (Determination of IndividualComponents in Spark Ignition Engine Fuels)

ASTM Method D4059-96 is used for determining PCB concen-trations in various types of transformer oil, using GC/ECDdetection. The analyst must dilute transformer oil samples in asolvent prior to injection. The oil in the sample has been shownto quench the ECD. Calibration mixtures of PCBs in transformeroil must be prepared and diluted identically to eliminate thedetector quenching bias resulting when samples are analyzed.

We prepare these solutions in a mineral oil-based transformer oil(Exxon® Univolt® N-61), which has been tested to ensure it isPCB-free.


PCB-Free Transformer Oil

Neat, 5mL cat. # 32424 (ea.) Neat, 50mL cat. # 32425 (ea.)

Aroclor Standards

ASTM Method D4059-96 (PCB Standards in Oil)

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceeAroclor 1016 TO 50mg/kg 32075Aroclor 1016 TO 500mg/kg 32076Aroclor 1221 TO 50mg/kg 32077Aroclor 1221 TO 500mg/kg 32078Aroclor 1232 TO 50mg/kg 32079Aroclor 1232 TO 500mg/kg 32080Aroclor 1242 TO 50mg/kg 32081Aroclor 1242 TO 500mg/kg 32082Aroclor 1248 TO 50mg/kg 32083Aroclor 1248 TO 500mg/kg 32084Aroclor 1254 TO 50mg/kg 32085Aroclor 1254 TO 500mg/kg 32086Aroclor 1260 TO 50mg/kg 32087Aroclor 1260 TO 500mg/kg 32088TO = transformer oil (PCB-free)

Volume is 1mL/ampul.

ASTM Method D6584-00 and EN14105(Biodiesel) cont'd

Oxy Set-Up Blend (30 components)

Gravimetrically prepared and NIST-traceable.

ASTM method D6730-01 is specifically designed for the deter-mination of the individual hydrocarbons present in spark igni-tion fuels, as well as fuel blends containing oxygenates such asmethyl tert-butyl ether, ethyl tert-butyl ether, tert-butanol,ethanol, etc.


800-356-1688 or 814-353-1300 www.restek.com 517


ASTM Methods

also availableRtx®-DHA Columns. See page 75.

ASTM Method D6730-01 (Determination of Individual Components in Spark Ignition Engine Fuels) cont'd

Contact us for component listing.


DHA PONA VI Mix

PONA-VI (PONA 6) is a qualitative mixture of various gasolineand refinery materials prepared to provide nearly every compo-nent that may be encountered in feedstock and finished gaso-lines. Some oxygenates have been added to allow this blend to beused for DHA method setup.

Neat, 0.1mL in Autosampler Vialcat. # 30723 (ea.)

Neat, 0.1mL in Vial with Mininert Valvecat. # 30724 (ea.)

DHA PIANO Blend (136 components)

PIANO StandardsThe PIANO blends are standards used for calibrating complexhydrocarbon analyses and provide the greatest number of gravi-metrically determined values for quantitative calibration.

Contact us for component listing.




decane 9.11%dodecane 9.13%heptane 9.08%hexane 9.11%nonane 9.08%octane 9.10%

pentadecane 9.09%pentane 9.06%tetradecane 9.14%tridecane 9.05%undecane 9.05%


DHA Paraffins Mix (11 components)



3,3-diethylpentane 1.87%2,3-dimethylbutane 2.27%2,3-dimethylheptane 1.12%2,5-dimethylheptane 3.64%3,3-dimethylheptane 1.71%3,4-dimethylheptane 0.80%3,5-dimethylheptane 2.27%2,2-dimethylhexane 0.76%2,3-dimethylhexane 3.29%2,4-dimethylhexane 1.40%2,5-dimethylhexane 5.69%2,2-dimethyloctane 2.05%3,3-dimethyloctane 0.78%2,2-dimethylpentane 2.36%2,3-dimethylpentane 4.54%2,4-dimethylpentane 5.77%3,3-dimethylpentane 2.23%

3-ethylhexane 0.29%3-ethyloctane 1.04%3-ethylpentane 0.85%isopentane 1.53%3-methylcycloheptane 5.73%4-methylcycloheptane 1.41%2-methylheptane 4.54%2-methylhexane 4.54%3-methylhexane 2.28%2-methylnonane 1.53%3-methylnonane 5.10%2-methyloctane 1.20%3-methyloctane 6.81%2-methylpentane 6.17%3-methylpentane 10.23%2,2,3-trimethylbutane 0.64%2,2,3-trimethylpentane 3.56%


DHA Isoparaffins Mix (34 components)



benzene 8.20%n-butylbenzene 2.06%sec-butylbenzene 3.07%tert-butylbenzene 2.04%tert-1-butyl-3,5-dimethyl

benzene 3.31%1-tert-butyl-4-ethylbenzene 2.05%1-tert-butyl-2-methylbenzene 2.05%1,2-diethylbenzene 0.84%1,2-dimethyl-3-ethylbenzene 2.13%1,2-dimethyl-4-ethylbenzene 0.90%1,3-dimethyl-2-ethylbenzene 0.79%1,3-dimethyl-5-ethylbenzene 0.39%1,4-dimethyl-2-ethylbenzene 2.05%ethylbenzene 8.18%1-ethyl-2-methylbenzene 1.55%1-ethyl-3-methylbenzene 2.77%1-ethyl-4-methylbenzene 2.05%hexylbenzene 5.11%isobutylbenzene 3.08%

isopropylbenzene 2.07%2-methylbutylbenzene 0.11%1-methyl-2-isopropylbenzene 2.76%1-methyl-3-isopropylbenzene 1.05%1-methyl-4-isopropylbenzene 4.09%1-methyl-2-n-propylbenzene 2.13%1-methyl-3-n-propylbenzene 2.06%1-methyl-4-n-propylbenzene 2.06%pentylbenzene 2.05%n-propylbenzene 3.07%1,2,4,5-tetramethylbenzene 0.85%toluene 12.36%1,2,4-triethylbenzene 1.02%1,3,5-triethylbenzene 2.04%1,2,4-trimethylbenzene 2.05%1,3,5-trimethylbenzene 0.41%m-xylene 3.08%p-xylene 1.03%o-xylene 3.10%


DHA Aromatics Mix (38 components)



ctc-123-TMCYC6 3.40%cyclohexane 4.41%cyclopentane 8.75%cis-1,2-dimethylcyclohexane 7.74%trans-1,2-dimethylcyclohexane 3.29%trans-1,4-dimethylcyclohexane 4.38%trans-1,2-dimethylcyclopentane 3.37%cis-1,3-dimethylcyclopentane 3.39%trans-1,3-dimethylcyclopentane 5.36%ethylcyclopentane 7.25%1-ethyl-1-methylcyclopentane 1.35%isobutylcyclohexane 3.28%isobutylcyclopentane 1.23%isopropylcyclohexane 4.37%isopropylcyclopentane 1.20%

methylcyclohexane 3.39%methylcyclopentane 5.48%trans-1-methyl-2-(4MP)

cyclopentane 3.31%trans-1-methyl-2-propyl

cyclohexane 4.43%n-propylcyclopentane 4.06%1,1,2-trimethylcyclohexane 1.69%1,1,4-trimethylcyclohexane 5.83%ctc-1,2,4-trimethylcyclohexane 0.98%ctt-1,2,4-trimethylcyclohexane 1.70%ccc-1,3,5-trimethylcyclohexane 2.16%ccc-1,2,3-trimethylcyclopentane 0.73%ctc-1,2,3-trimethylcyclopentane 3.48%


DHA Naphthenes Mix (27 components)



1-decene 2.27%1-heptene 6.81%cis-2-heptene 3.42%trans-2-heptene 0.52%cis-3-heptene 3.41%trans-3-heptene 1.37%1-hexene 11.30%cis-2-hexene 2.30%trans-2-hexene 2.26%2-methyl-1,3-butadiene 3.69%2-methyl-1-butene 2.18%3-methyl-1-butene 1.48%2-methyl-1-nonene 3.42%

2-methyl-2-pentene 3.43%4-methyl-1-pentene 3.41%1-nonene 6.94%trans-2-nonene 2.29%cis-3-nonene 3.02%trans-3-nonene 2.29%cis-4-nonene 4.38%1-octene 11.37%cis-2-octene 2.32%trans-2-octene 3.42%1-pentene 8.76%cis-2-pentene 2.01%trans-2-pentene 1.94%


DHA Olefins Mix (26 components)



NEW!

NEW!

NEW!

NEW!

NEW!

NEW!

NEW!


518 www.restek.com 800-356-1688 or 814-353-1300


Petroleum Standards

Petroleum StandardsThese petroleum standards are gravimetrically prepared,NIST-traceable by weight, and verified by one or more analyticalmethods.

Sulfur Simulated Distillation Standard

Speciated Sulfur System Suitability CheckoutStandard

EPA Ultra Low & Low Sulfur Diesel Standards andSamples in Diesel Fuel to Meet EPA Requirements forLab Qualification

30 ppm total sulfur by weight from ethanethiol60 ppm total sulfur by weight from 1-propanethiol30 ppm total sulfur by weight from 1-butanethiol60 ppm total sulfur by weight from 1-pentanethiol30 ppm total sulfur by weight from 1-hexanethiol60 ppm total sulfur by weight from 1-heptanethiol30 ppm total sulfur by weight from 3,5-dimethlybenzenethiol60 ppm total sulfur by weight from 1-octanethiol30 ppm total sulfur by weight from 1-nonanethiol60 ppm total sulfur by weight from 1-decanethiol30 ppm total sulfur by weight from 1-pentadecanethiolol60 ppm total sulfur by weight from 1-hexadecanethiol30 ppm total sulfur by weight from 1-octadecanethiolBalance: toluene/isooctane 1/15


Sulfur Simulated Distillation Standard (SSDS)

1mL pre-scored amber ampul.cat. # 33049 (ea.)

0.50 ppm total sulfur by weight from dimethylsulfide35.0 ppm total sulfur by weight from tertiary butyl mercaptan50.0 ppm total sulfur by weight from thiopene15.0 ppm total sulfur by weight from dimethyl disulfide25.0 ppm total sulfur by weight from benzothiopeneBalance: isooctane


Speciated Sulfur System Suitability Checkout Standard

(SSSSCS)

1mL pre-scored amber ampul.cat. # 33050 (ea.)


EPA Ultra Low Sulfur Diesel Accuracy Standard # 1

EPA Section 80.520(a)(1) and 80.510(b)1-10 ppm total sulfur in a diesel fuel matrix for motor vehicle diesel and diesel

additives subject to the 15 ppm sulfur standard. 1 x 200mL amber bottle.

cat. # 33053 (ea.)


EPA Ultra Low Sulfur Diesel Accuracy Standard # 2

EPA Section 80.520(a)(1) and 80.510(b)10-20 ppm total sulfur in a diesel fuel matrix for motor vehicle diesel and diesel


cat. # 33054 (ea.)


EPA Ultra Low Sulfur Diesel Precision Sample # 1

EPA Section 80.580-80.585 Title 40, Chapter 1, Part 80

Homogenous commercially available diesel fuel with sulfur content of 5-15 ppm. 1 x 200mL amber bottle.

cat. # 33051 (ea.)


EPA Low Sulfur Diesel Precision Sample # 2

EPA Section 80.580-80.585 Title 40, Chapter 1, Part 80Homogenous commercially available diesel fuel with sulfur content of 200-500 ppm.1 x 200mL amber bottle.

cat. # 33052 (ea.)


EPA Low Sulfur Diesel Accuracy Standard # 3

EPA Section 80.520(c) and 80.510(c)100-200 ppm total sulfur in a diesel fuel matrix for motor vehicle diesel and diesel


cat. # 33055 (ea.)


EPA Low Sulfur Diesel Accuracy Standard # 4

EPA Section 80.520(c) and 80.510(c)400-500 ppm total sulfur in a diesel fuel matrix for motor vehicle diesel and diesel


cat. # 33056 (ea.)

also availableCustom ULSD and LSD calibration standards are also available in 100mL,200mL, 500mL, and 1 liter bottles.

Call our Analytical Reference Department at 800-356-1688 or814-353-1300, or your Restek representative for details.

Gas

Calibration

Standards

See pages 427-432 orvisit www. restek.com/air

Regulators available too!

See pages 433-434


800-356-1688 or 814-353-1300 www.restek.com 519


Petroleum Standards

Low Sulfur in Gasoline Calibration Standards cont'd

Low Sulfur in Gasoline Calibration Standards

Ultra Low & Low Sulfur in Diesel Fuel Calibration Kits

Sulfur in Isooctane Calibration Kits and CheckStandards


Blank100 ppm total sulfur from di-n-butylsulfide in diesel fuel200 ppm total sulfur from di-n-butylsulfide in diesel fuel300 ppm total sulfur from di-n-butylsulfide in diesel fuel400 ppm total sulfur from di-n-butylsulfide in diesel fuel500 ppm total sulfur from di-n-butylsulfide in diesel fuel


Cal Kit LSD 100 - 500

Set of six 20mL bottles.cat. # 33062 (kit)

Blank1.0 ppm total sulfur from di-n-butylsulfide in diesel fuel2.5 ppm total sulfur from di-n-butylsulfide in diesel fuel5.0 ppm total sulfur from di-n-butylsulfide in diesel fuel10.0 ppm total sulfur from di-n-butylsulfide in diesel fuel15.0 ppm total sulfur from di-n-butylsulfide in diesel fuel20.0 ppm total sulfur from di-n-butylsulfide in diesel fuel


Cal Kit ULSD 1 - 20

Set of seven 20mL bottles.cat. # 33060 (kit)

Blank20.0 ppm total sulfur from di-n-butylsulfide in diesel fuel35.0 ppm total sulfur from di-n-butylsulfide in diesel fuel50.0 ppm total sulfur from di-n-butylsulfide in diesel fuel75.0 ppm total sulfur from di-n-butylsulfide in diesel fuel100 ppm total sulfur from di-n-butylsulfide in diesel fuel


Cal Kit ULSD 20 - 100

Set of six 20mL bottles.cat. # 33061 (kit)

Blank10 ppm sulfur from di-n-butylsulfide in gasoline by weight20 ppm sulfur from di-n-butylsulfide in gasoline by weight30 ppm sulfur from di-n-butylsulfide in gasoline by weight40 ppm sulfur from di-n-butylsulfide in gasoline by weight50 ppm sulfur from di-n-butylsulfide in gasoline by weight


Cal Kit SG 10 - 50


Set of six 5mL amber bottles.cat. # 33043 (kit)

Blank50 ppm sulfur from di-n-butylsulfide in gasoline by weight65 ppm sulfur from di-n-butylsulfide in gasoline by weight80 ppm sulfur from di-n-butylsulfide in gasoline by weight95 ppm sulfur from di-n-butylsulfide in gasoline by weight110 ppm sulfur from di-n-butylsulfide in gasoline by weight125 ppm sulfur from di-n-butylsulfide in gasoline by weight


Cal Kit SG 50 - 125

Set of seven 5mL amber bottles.cat. # 33045 (kit)

Blank110 ppm sulfur from di-n-butylsulfide200 ppm sulfur from di-n-butylsulfide300 ppm sulfur from di-n-butylsulfide400 ppm sulfur from di-n-butylsulfide500 ppm sulfur from di-n-butylsulfide


Cal Kit SG 110 - 500

Set of six 5mL amber bottles.cat. # 33047 (kit)


Check Standard SG 25

25 ppm sulfur from di-n-butylsulfide in gasoline by weight. Set of five 5mL amber bottles.

cat. # 33044 (ea.)


Check Standard SG 75

75 ppm sulfur from di-n-butylsulfide in gasoline by weight. Set of five 5mL amber bottles.

cat. # 33046 (ea.)


Check Standard SG 175175 ppm sulfur from di-n-butylsulfide in gasoline by weight. Set of five 5mL amber bottles.

cat. # 33048 (ea.)

Blank0.125 w/w ppm total sulfur from di-n-butylsulfide in isooctane0.25 w/w ppm total sulfur from di-n-butylsulfide in isooctane0.50 w/w ppm total sulfur from di-n-butylsulfide in isooctane1.00 w/w ppm total sulfur from di-n-butylsulfide in isooctane2.50 w/w ppm total sulfur from di-n-butylsulfide in isooctane


Cal Kit SISO 0.125 - 2.5ppm

ASTM Methods D3120, D4045, D5453, D6920

Calibration kit for total sulfur by weight from di-n-butylsulfide in isooctane 0.125–2.5ppm range. Set of six 1mL pre-scored ampuls.

cat. # 33035 (kit)


Check Standard SISO 0.75

0.75ppm total sulfur by weight from di-n-butylsulfide in isooctane. Set of five 1mL pre-scored ampuls.

cat. # 33036 (ea.)

please noteThese petroleum standards are gravimetrically prepared, NIST-traceableby weight, and verified by one or more analytical methods.

kit

kit

kit

kit

kit

kit

kit




520 www.restek.com 800-356-1688 or 814-353-1300


Petroleum Standards

Total Sulfur & Total Nitrogen in IsooctaneCalibration Kits

Sulfur in Isooctane Calibration Kits and CheckStandards cont'd

also availableCustom total sulfur & total nitrogen in isooctane check standards alsoavailable.

Call our Analytical Reference Department at 800-356-1688 or814-353-1300, or your Restek representative for details.

Blank2.50 w/w ppm total sulfur from di-n-butylsulfide in isooctane5.00 w/w ppm total sulfur from di-n-butylsulfide in isooctane10.00 w/w ppm total sulfur from di-n-butylsulfide in isooctane15.00 w/w ppm total sulfur from di-n-butylsulfide in isooctane20.00 w/w ppm total sulfur from di-n-butylsulfide in isooctane25.00 w/w ppm total sulfur from di-n-butylsulfide in isooctane50.00 w/w ppm total sulfur from di-n-butylsulfide in isooctane


Cal Kit SISO 2.5 - 50 ppm

Calibration kit for total sulfur by weight from di-n-butylsulfide in isooctane 2.5–50 ppm range. Set of eight 1mL pre-scored ampuls.

cat. # 33037 (kit)

Blank50 w/w ppm total sulfur from di-n-butylsulfide in isooctane75 w/w ppm total sulfur from di-n-butylsulfide in isooctane100 w/w ppm total sulfur from di-n-butylsulfide in isooctane250 w/w ppm total sulfur from di-n-butylsulfide in isooctane500 w/w ppm total sulfur from di-n-butylsulfide in isooctane1000 w/w ppm total sulfur from di-n-butylsulfide in isooctane


Cal Kit SISO 50 - 1000 ppm

Calibration kit for total sulfur by weight from di-n-butylsulfide in isooctane 50–100 ppm range. Set of seven 1mL pre-scored ampuls.

cat. # 33039 (kit)

Blank1000 w/w ppm total sulfur from di-n-butylsulfide in isooctane1500 w/w ppm total sulfur from di-n-butylsulfide in isooctane2000 w/w ppm total sulfur from di-n-butylsulfide in isooctane4000 w/w ppm total sulfur from di-n-butylsulfide in isooctane6000 w/w ppm total sulfur from di-n-butylsulfide in isooctane


Cal Kit SISO 1000 - 6000

Calibration kit for total sulfur by weight from di-n-butylsulfide in isooctane 1000–6000 ppm range. Set of six 1mL pre-scored ampuls.

cat. # 33041 (kit)


Check Standard SISO 3030 ppm total sulfur by weight from di-n-butylsulfide in isooctane. Set of five 1mL pre-scored ampuls.

cat. # 33038 (ea.)


Check Standard SISO 300300 ppm total sulfur by weight from di-n-butylsulfide in isooctane. Set of five 1mL pre-scored ampuls.

cat. # 33040 (ea.)


Check Standard SISO 30003000 pm total sulfur by weight from di-n-butylsulfide in isooctane. Set of five 1mL pre-scored ampuls.

cat. # 33042 (ea.)

Blank0.125 w/w ppm total sulfur from thiophene & total nitrogen

from pyridine in isooctane0.25 w/w ppm total sulfur from thiophene & total nitrogen





from pyridine in isooctane


Cal Kit SNISO 0.125 - 5.0

ASTM Methods D3120, D4045, D4629, D5453, D5762,D6069, D6920

Set of seven 1mL pre-scored amber ampuls.cat. # 33057 (kit)







Cal Kit SNISO 5.0 - 50.0

Set of five 1mL pre-scored amber ampuls.cat. # 33058 (kit)



from pyridine in isooctane100 w/w ppm total sulfur from thiophene & total nitrogen






Cal Kit SNISO 50.0 - 1000

Set of seven 1mL pre-scored amber ampuls.cat. # 33059 (kit)

kit

kit

kit

kit

kit

kit



and/or lot number)



800-356-1688 or 814-353-1300 www.restek.com 521


Petroleum StandardsSulfur in Mineral Oil Calibration Kits and Check Standards

Blank2.00 w/w ppm total sulfur from di-n-butylsulfide in mineral oil5.00 w/w ppm total sulfur from di-n-butylsulfide in mineral oil7.00 w/w ppm total sulfur from di-n-butylsulfide in mineral oil10.00 w/w ppm total sulfur from di-n-butylsulfide in mineral oil15.00 w/w ppm total sulfur from di-n-butylsulfide in mineral oil20.00 w/w ppm total sulfur from di-n-butylsulfide in mineral oil


Cal Kit SMO 2 - 20

ASTM Methods D2622, D3120, D4045, D4294, D5453, D6212, D6313, D6428, D6445, D7039


Blank10.0 w/w ppm total sulfur from di-n-butylsulfide in mineral oil25.0 w/w ppm total sulfur from di-n-butylsulfide in mineral oil50.0 w/w ppm total sulfur from di-n-butylsulfide in mineral oil100 w/w ppm total sulfur from di-n-butylsulfide in mineral oil


Cal Kit SMO 10 - 100

Set of five 100mL bottles.cat. # 33065 (kit)

Blank100 w/w ppm total sulfur from di-n-butylsulfide in mineral oil200 w/w ppm total sulfur from di-n-butylsulfide in mineral oil300 w/w ppm total sulfur from di-n-butylsulfide in mineral oil400 w/w ppm total sulfur from di-n-butylsulfide in mineral oil500 w/w ppm total sulfur from di-n-butylsulfide in mineral oil600 w/w ppm total sulfur from di-n-butylsulfide in mineral oil750 w/w ppm total sulfur from di-n-butylsulfide in mineral oil1000 w/w ppm total sulfur from di-n-butylsulfide in mineral oil


Cal Kit SMO 100 - 1000

Set of nine 100mL bottles.cat. # 33067 (kit)

Blank1000 w/w ppm total sulfur from di-n-butylsulfide in mineral oil2500 w/w ppm total sulfur from di-n-butylsulfide in mineral oil5000 w/w ppm total sulfur from di-n-butylsulfide in mineral oil1.00% total sulfur by weight from di-n-butylsulfide in mineral oil1.50% total sulfur by weight from di-n-butylsulfide in mineral oil2.00% total sulfur by weight from di-n-butylsulfide in mineral oil2.50% total sulfur by weight from di-n-butylsulfide in mineral oil


Cal Kit SMO 1000 - 25000

Set of eight 100mL bottles.cat. # 33069 (kit)

Blank2.50% total sulfur by weight from di-n-butylsulfide in mineral oil3.00% total sulfur by weight from di-n-butylsulfide in mineral oil3.50% total sulfur by weight from di-n-butylsulfide in mineral oil4.00% total sulfur by weight from di-n-butylsulfide in mineral oil4.50% total sulfur by weight from di-n-butylsulfide in mineral oil5.00% total sulfur by weight from di-n-butylsulfide in mineral oil


Cal Kit SMO 25000 - 50000



Check Standard SMO 11

11.0 w/w ppm total sulfur from di-n-butylsulfide in mineral oil. 1 liter bottle.

cat. # 33064 (ea.)



30.0 w/w ppm total sulfur from di-n-butylsulfide in mineral oil. 1 liter bottle.

cat. # 33066 (ea.)


Check Standard SMO 350350 w/w ppm total sulfur from di-n-butylsulfide in mineral oil. 1 liter bottle.

cat. # 33068 (ea.)


Check Standard SMO 30003000 w/w ppm total sulfur from di-n-butylsulfide. 1 liter bottle.

cat. # 33070 (ea.)



3.70% total sulfur by weight from di-n-butylsulfide in mineral oil. 1 liter bottle.

cat. # 33072 (ea.)

please noteThese petroleum standards are gravimetrically prepared, NIST-traceableby weight, and verified by one or more analytical methods.

kit

kit

kit

kit

kit

Get More!Petroleum &Petrochemical Solutions Online

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REFERENCE STANDARDS

CLINICAL, FORENSIC &TOXICOLOGY MATERIALSFire Debris Analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .523

Blood Alcohol Standards . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .524

Bank Dye Standard . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .524

Explosives Solutions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .524

Exempted Drugs of Abuse Standards . . . . . . . . . . . . . . . . . . .525

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REFERENCE STANDARDS | CLINICAL, FORENSIC & TOXICOLOGY MATERIALS

Fire Debris Analysis

Weathered Petrochemical Standards

• Type I (Stoddard solvent) BPR 149–182°C • Type II (high flash point) BPR 177–196°C • Type III (odorless) BPR 149–196°C• Type IV (low dry point) BPR 149–174°C

We prepare our mineral spirits solutions from an equal volumeblend of Type I, II, and III mineral spirits.

These solutions are prepared from a single source (one refinery)product. The weathered materials indicate the percent weightloss from the original material. Samples of regular and premiumgrade unleaded gasoline were blended in equal volumes.

There are four general types of mineral spirits, classifiedaccording to boiling point range (BPR):

please noteWe can custom prepare weathered accelerants for fire debris analysis.

Please complete the custom reference material request form atwww.restek.com/solutions.

We’ll be glad to work with you!

Weathered Petrochemical Standards cont'd

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceeunleaded gasoline: unweathered PTM 5,000 30096unleaded gasoline: 25% weathered PTM 5,000 30097unleaded gasoline: 50% weathered PTM 5,000 30098unleaded gasoline: 75% weathered PTM 5,000 30099unleaded gasoline: 99% weathered PTM 5,000 30436

PTM = P&T methanol

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceekerosene: unweathered D 5,000 31229kerosene: 25% weathered D 5,000 31230kerosene: 50% weathered D 5,000 31231kerosene: 75% weathered D 5,000 31232

D = methylene chloride

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceediesel fuel #2: unweathered D 5,000 31233diesel fuel #2: 25% weathered D 5,000 31234diesel fuel #2: 50% weathered D 5,000 31235diesel fuel #2: 75% weathered D 5,000 31236CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceemineral spirits: unweathered D 5,000 31225mineral spirits: unweathered D 50,000 31260mineral spirits: unweathered (5mL) D 50,000 31261mineral spirits: 25% weathered D 5,000 31226mineral spirits: 50% weathered D 5,000 31227mineral spirits: 75% weathered D 5,000 31228

Concentration is µg/mL. Volume is 1mL/ampul unless otherwise noted.

Stoddard Solvent Standard


Contains 1mL each of these mixtures.30096: Unleaded Gasoline Standard30097: Unleaded Gas Standard: 25% Weathered 30098: Unleaded Gas Standard: 50% Weathered30099: Unleaded Gas Standard: 75% Weathered


Weathered Gasoline Kit

cat. # 30100 (kit)

kit

Contains 1mL each of these mixtures.31229: Kerosene Standard31230: Kerosene Standard: 25% Weathered31231: Kerosene Standard: 50% Weathered31232: Kerosene Standard: 75% Weathered


Weathered Kerosene Kit

cat. # 31238 (kit)

kit

Contains 1mL each of these mixtures.31233: Diesel Fuel #2 Standard31234: Diesel Fuel #2 Standard: 25% Weathered31235: Diesel Fuel #2 Standard: 50% Weathered31236: Diesel Fuel #2 Standard: 75% Weathered


Weathered Diesel Fuel #2 Kit

cat. # 31239 (kit)

kit

Contains 1mL each of these mixtures.31225: Mineral Spirits Standard31226: Mineral Spirits Standard: 25% Weathered31227: Mineral Spirits Standard: 50% Weathered31228: Mineral Spirits Standard: 75% Weathered


Weathered Mineral Spirits Kit

cat. # 31237 (kit)

kit

Contains 1mL each of these mixtures.30096: Unleaded Gasoline Standard30097: Unleaded Gas Standard: 25% Weathered 30098: Unleaded Gas Standard: 50% Weathered30099: Unleaded Gas Standard: 75% Weathered30436: Unleaded Gas Standard: 99% Weathered


Weathered Gasoline Kit #2

cat. # 30437 (kit)

kit

ASTM E1387 and E1618 (Fire Debris Analysis)

These materials also can be used for underground storage tankmonitoring.



E1387 Column Resolution Check Mix (13 components)





E1618 Test Mix (13 components)

Components in this mix (0.5µL/mL or 0.05% volume/volumeeach) are at 10X the concentration of the final test solution spec-ified in ASTM 1618 and ASTM 1387.

0.05% volume/volume each in methylene chloride, 1mL/ampulcat. # 31613 (ea.)


524 www.restek.com 800-356-1688 or 814-353-1300


Blood Alcohols, Bank Dye, Explosives

1-N-(methylamino)anthraquinone (MAAQ)

Bank Dye Standard (MAAQ)Restek offers this qualitative standard (red dye used in bank“Security Pack”) to help investigators in municipal police stations and criminal laboratories fight crime.

100µg/mL in methylene chloride, 1mL/ampulcat. # 31823 (ea.)

We have developed calibration mixtures for performing multi-point instrument calibrations so that laboratories can constructcalibration curves. The data pack (which can be downloadedfrom our website at www.restek.com/documents) includes aCertificate of Analysis, raw material testing results, statistical QAresults, analytical balance printout, and gravimetric weight ofeach analyte. Ethanol in these mixes is National Institute ofStandards and Technology (NIST)-traceable.


Blood Alcohol Standards

did you know?Resolve blood alcohol samples in less than 3 minutes with our Rtx®-BAC1 and Rtx®-BAC2 columns. Visit www.restek.com/CFT for more information on these columns or to find out what's new for clinical/forensic analyses.


These materials support nitroaromatic, nitramine, andnitroester analyses by GC/ECD (Method 8095).1,2 Compoundslisted are explosives, manufacturing intermediates, or degrada-tion products. Method 8095 mixtures contain the components atconcentration ratios appropriate for ECD.


RReeffeerreenncceess ((NNoott aavvaaiillaabbllee ffrroomm RReesstteekk..))1US Environmental Protection Agency. Test Methods for Evaluating Solid Waste,Physical/Chemical Methods. SW-846, Proposed Draft Update IVB, Office of SolidWaste, Washington, DC, 1999.2M. E. Walsh, T. Ranney, J. Chromatogr. Sci., Vol. 36, pp. 406-416, August 1998.

Explosives Solutions

CCoommppoouunndd qqttyy.. ccaatt..## pprriiccee0.010g/dL forensic ethanol solution1mL/ampul 5-pk. 362761mL/ampul 10-pk. 362785mL/ampul ea. 362770.015g/dL forensic ethanol solution1mL/ampul 5-pk. 362321mL/ampul 10-pk. 3633220mL/ampul ea. 362480.02g/dL forensic ethanol solution1mL/ampul 5-pk. 362331mL/ampul 10-pk. 3633320mL/ampul ea. 362490.025g/dL forensic ethanol solution1mL/ampul 5-pk. 362341mL/ampul 10-pk. 363345mL/ampul ea. 362420.04g/dL forensic ethanol solution1mL/ampul 5-pk. 362351mL/ampul 10-pk. 363355mL/ampul ea. 3624320mL/ampul ea. 362510.05g/dL forensic ethanol solution1mL/ampul 5-pk. 362571mL/ampul 10-pk. 362595mL/ampul ea. 3625820mL/ampul ea. 362600.08g/dL forensic ethanol solution1mL/ampul 5-pk. 362621mL/ampul 10-pk. 362645mL/ampul ea. 3626320mL/ampul ea. 362650.1g/dL forensic ethanol solution1mL/ampul 5-pk. 362361mL/ampul 10-pk. 363365mL/ampul ea. 3624420mL/ampul ea. 362520.15g/dL forensic ethanol solution1mL/ampul 5-pk. 362371mL/ampul 10-pk. 363375mL/ampul ea. 3624520mL/ampul ea. 362530.16g/dL forensic ethanol solution1mL/ampul 5-pk. 364171mL/ampul 10-pk. 364185mL/ampul ea. 3641920mL/ampul ea. 364200.2g/dL forensic ethanol solution1mL/ampul 5-pk. 362381mL/ampul 10-pk. 363385mL/ampul ea. 3624620mL/ampul ea. 362540.3g/dL forensic ethanol solution1mL/ampul 5-pk. 362391mL/ampul 10-pk. 363395mL/ampul ea. 3624720mL/ampul ea. 362550.4g/dL forensic ethanol solution1mL/ampul 5-pk. 362661mL/ampul 10-pk. 362685mL/ampul ea. 3626720mL/ampul ea. 36269

CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriiccee2-amino-4,6-dinitrotoluene ACN 1,000 316704-amino-2,6-dinitrotoluene ACN 1,000 31671ammonium picrate* ACN 2,000 318903,5-dinitroaniline ACN 1,000 316611,2-dinitrobenzene M 1,000 314531,3-dinitrobenzene ACN 1,000 316622,4-dinitrotoluene ACN 1,000 316632,6-dinitrotoluene ACN 1,000 316643,4-dinitrotoluene EA 2,000 339013,4-dinitrotoluene M 1,000 31452EGDN* M 1,000 31601HMX* ACN 1,000 316652-methyl-4-nitroaniline M 1,000 31612nitrobenzene ACN 1,000 31657nitroglycerin* M 1,000 31498nitroguanidine* M 1,000 316022-nitrotoluene ACN 1,000 316593-nitrotoluene ACN 1,000 316604-nitrotoluene ACN 1,000 31658PETN (pentaerythritol tetranitrate)* M 1,000 31600picric acid* M 1,000 31499propylene glycol dinitrate (PGDN) M 1,000 31821RDX* ACN 1,000 31666tetryl* ACN 1,000 316671,3,5-trinitrobenzene* ACN 1,000 316682,4,6-trinitrotoluene* ACN 1,000 31669



Blood Alcohol Standards cont'd

acetaldehydeacetoneacetonitrileethanol (NIST certified value)

ethyl acetateisopropanolmethanolmethyl ethyl ketone

Blood Alcohol Mix Resolution Control Standard (8 components)

Use to verify the retention time for each compound normallyincluded in a blood alcohol test, and to verify that the compounds are resolved from and do not interfere with oneanother. Concentration of ethanol is NIST-traceable.

0.100g/dL each in water, 1mL/ampulcat. # 36256 (ea.)


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Drugs of Abuse

CCoommppoouunndd CCAASS## SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceeBBeennzzooddiiaazzeeppiinneessalprazolam 28981-97-7 PTM 1,000 34042bromazepam 1812-30-2 PTM 1,000 34043chlordiazepoxide 438-41-5 PTM 1,000 34044clobazam 22316-47-8 PTM 1,000 34045clonazepam 1622-61-3 PTM 1,000 34046diazepam 439-14-5 PTM 1,000 34047flunitrazepam 1622-62-4 PTM 1,000 34049flurazepam 1172-18-5 PTM 1,000 34050lorazepam 846-49-1 PTM 1,000 34051nitrazepam 146-22-5 PTM 1,000 34053oxazepam 604-75-1 PTM 1,000 34054prazepam 2955-38-6 PTM 1,000 34055temazepam 896-50-4 PTM 1,000 34056triazolam 28911-01-5 PTM 1,000 34057CCooccaaiinnee && MMeettaabboolliitteesscocaethylene 529-38-4 ACN 1,000 34066cocaine 53-21-4 PTM 1,000 34015benzoylecgonine 519-09-5 PTM 1,000 34016ecgonine 5796-31-6 PTM 1,000 34017ecgonine methyl ester 38969-40-3 PTM 1,000 34018MMeetthhaaddoonnee && MMeettaabboolliitteessEDDP perchlorate 66729-78-0 M 1,000 34069methadone 1095-90-5 PTM 1,000 34005AAmmpphheettaammiinneess && MMeettaabboolliitteessd-amphetamine 51-63-8 PTM 1,000 34020(+)methamphetamine 51-57-0 PTM 1,000 340213,4-MDA HCl 4764-17-4 M 1,000 340703,4-MDEA HCl 82801-81-8 M 1,000 340723,4-MDMA HCl 42542-10-9 M 1,000 34071phenylpropanolamine HCl 154-41-6 M 1,000 34073OOppiiaatteess && MMeettaabboolliitteesscodeine 76-57-3 PTM 1,000 34000dextromethorphan HBr

monohydrate 125-69-9 M 1,000 34081hydrocodone 34195-34-1 PTM 1,000 34002hydromorphone 71-68-1 PTM 1,000 34063morphine 6211-15-0 PTM 1,000 34006oxycodone 124-90-3 PTM 1,000 34007oxymorphone 76-41-5 PTM 1,000 34065CCaannnnaabbiinnooiidd && MMeettaabboolliitteesscannabidiol 13956-24-1 PTM 1,000 34011cannabinol 521-35-7 PTM 1,000 34010Δ9-THC 1972-08-3 M 1,000 34067(±)11-nor-9-carboxy-Δ9-THC 104874-50-2 M 100 34068BBaarrbbiittuurraatteessamobarbital 64-43-7 PTM 1,000 34028aprobarbital 77-02-1 PTM 1,000 34029barbital 57-44-3 PTM 1,000 34030butabarbital 125-40-6 PTM 1,000 34031butalbital 77-26-9 PTM 1,000 34032DL-glutethimide 18389-24-7 PTM 1,000 34058hexobarbital 56-29-1 PTM 1,000 34033mephobarbital 115-38-8 PTM 1,000 34034methohexital 151-83-7 PTM 1,000 34035pentobarbital 76-74-4 PTM 1,000 34036phenobarbital 50-06-6 PTM 1,000 34037secobarbital 29071-21-4 PTM 1,000 34038talbutal 115-44-6 PTM 1,000 34039thiopental 71-73-8 PTM 1,000 34041

GGHHBB1,4-butanediol 110-63-4 M 1,000 34078γ-butyrolactone (GBL) 96-48-0 ACN 1,000 34077α-methylene-γ-butyrolactone

(AMGBL) 547-65-9 ACN 1,000 34079γ-valerolactone 108-29-2 ACN 1,000 34080OOtthheerrbenzphetamine 5411-22-3 PTM 1,000 34022caffeine 58-08-2 M 1,000 34084continine 486-56-6 M 1,000 34086fentanyl 437-38-7 M 1,000 34082nor-fentanyl oxalate 1609-66-1 M 1,000 34083levorphanol 5985-38-6 PTM 1,000 34003meperidine 50-13-5 PTM 1,000 34004meprobamate 57-53-4 PTM 1,000 34059methaqualone 340-56-7 PTM 1,000 34064methyprylon 125-64-4 PTM 1,000 34060nicotine 54-11-5 M 1,000 34085pentazocine 64024-15-3 PTM 1,000 34062phencyclidine 956-90-1 PTM 1,000 34027phendimetrazine 50-58-8 PTM 1,000 34025phenmetrazine 1707-14-8 PTM 1,000 34026phentermine 1197-21-3 PTM 1,000 34024dextro-propoxyphene 1639-60-7 PTM 1,000 34008thebaine 115-37-7 PTM 1,000 34009

Exempted Drug of Abuse Reference MaterialsConcentration is µg/mL. Volume is 1mL/ampul.

CCoommppoouunndd CCAASS## SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriiccee

Quantity discounts not available.ACN = acetonitrile; M = methanol; PTM = purge & trap grade methanol

amiodarone 10µg/mLamphetamine 10caffeine 10codeine 10

diazepam 10doxepine 10haloperidol 1morphine 10

Forensic Drug Screen Test Mixture (8 components)


D5-diazepam D5-doxepineForensic Drug Screen Internal Standard (2 components)


DerivatizationReagents• Reagents available for acylation,

alkylation, and silylation.• Packaged in 10 x 1 g vials or 25 g vials.• High purity for accurate results.

See page 537.

Get More!Clinical, Forensic &ToxicologySolutions Online

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REFERENCE STANDARDS

PHARMACEUTICAL MATERIALSUSP . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .527-528

Limit of Diethylene and Ethylene Glycol Standards . . . . . .528

European Pharmacopoeia . . . . . . . . . . . . . . . . . . . . . . . . . .528-529

Composition of Fatty Acids by GC . . . . . . . . . . . . . . . . . . . . . . .529

ASTM Methods . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .529

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REFERENCE STANDARDS | PHARMACEUTICAL MATERIALS

USP

USP <467>

acetonitrile 2.05mg/mLchlorobenzene 1.80cyclohexane 19.40cis-1,2-dichloroethene 4.70trans-1,2-dichloroethene 4.701,4-dioxane 1.90ethylbenzene 1.84methanol 15.00

methylcyclohexane 5.90methylene chloride 3.00tetrahydrofuran 3.45toluene 4.45m-xylene 6.51o-xylene 0.98p-xylene 1.52

Residual Solvents Class 2 - Mix A (15 components)

In dimethyl sulfoxide, 1mL/ampulcat. # 36271 (ea.)

2-ethoxyethanol 800µg/mLethylene glycol 3,100formamide 1,100N,N-dimethylacetamide 5,450N,N-dimethylformamide 4,400

2-methoxyethanol (methyl Cellosolve) 250

N-methylpyrrolidone 2,650sulfolane 800

Residual Solvents Class 2 - Mix C (8 components)


CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceeacetonitrile DMSO 2.05mg/mL 36281benzene DMSO 10mg/mL 36282carbon tetrachloride DMSO 20mg/mL 36283chlorobenzene DMSO 1.8mg/mL 36284chloroform DMSO 0.3mg/mL 36285cyclohexane DMSO 19.4mg/mL 362861,1-dichloroethene DMSO 40mg/mL 362871,2-dichloroethane DMSO 25mg/mL 36288cis-1,2-dichloroethylene DMSO 4.67mg/mL 36289trans-1,2-dichloroethylene DMSO 4.67mg/mL 362901,2-dimethoxyethane DMSO 0.5mg/mL 36291N,N-dimethylacetamide DMSO 5.45mg/mL 36292N,N-dimethylformamide DMSO 4.4mg/mL 362931,4-dioxane DMSO 1.9mg/mL 362942-ethoxyethanol DMSO 0.8mg/mL 36295ethylbenzene DMSO 1.84mg/mL 36296ethylene glycol DMSO 3.1mg/mL 36297formamide DMSO 1.1mg/mL 36298hexane DMSO 1.45mg/mL 36299methanol DMSO 15mg/mL 364012-methoxyethanol DMSO 0.25mg/mL 36402methylbutylketone DMSO 0.25mg/mL 36400methylcyclohexane DMSO 5.9mg/mL 36403methylene chloride (dichloromethane) DMSO 3mg/mL 36404N-methylpyrrolidone DMSO 2.65mg/mL 36405nitromethane DMSO 0.25mg/mL 36406pyridine DMSO 1mg/mL 36407sulfolane DMSO 0.8mg/mL 36413tetrahydrofuran (THF) DMSO 3.6mg/mL 36408tetralin DMSO 0.5mg/mL 36409toluene DMSO 4.45mg/mL 364101,1,1-trichloroethane DMSO 50mg/mL 36411trichloroethene DMSO 0.4mg/mL 36412m-xylene DMSO 6.51mg/mL 36414o-xylene DMSO 0.97mg/mL 36415p-xylene DMSO 1.52mg/mL 36416

DMSO = dimethyl sulfoxide

USP <467> Singles

Volume is 1mL/ampul.

benzene 10mg/mLcarbon tetrachloride 201,2-dichloroethane 25

1,1-dichloroethene 401,1,1-trichloroethane 50

Residual Solvents - Class 1 (5 components)


chloroform 60µg/mL1,2-dimethoxyethane 100n-hexane (C6) 2902-hexanone 50

nitromethane 50pyridine 200tetralin 100trichloroethene 80

Residual Solvents Class 2 - Mix B (8 components)


free literatureResidual Solvent Analysis

Download your free copy fromwww.restek.com

Flyer lit. cat.# PHFL1018A

These mixtures reflect the changes made in USP30/NF25effective July 1, 2008.

OVI retention indexFor a list of OVI retention times, see pages 693 and 696.

The United States Pharmacopeia (USP) general chapter <467> Residual Solvents is a widely used compendial method intended foridentifying and quantifying residual solvents in drug substances, drug products, and excipients. In an attempt to better mirror theInternational Conference on Harmonization (ICH) guidelines, the USP has adopted a more comprehensive methodology in residualsolvent testing—the current USP30/NF25. The ICH publishes a guideline (Q3C) listing the acceptable amounts of solvent residuesthat can be present. In the ICH guideline, residual solvents are summarized by class, according to their toxicity. Class 1 compoundsare carcinogenic compounds that pose a risk to both the consumer and the environment. The use of these solvents is to be avoided,but if they are used, they must be tightly controlled. Class 2 compounds are nongenotoxic animal carcinogens, and concentrations ofthese compounds should be limited. Chromatographic analysis is needed for both the Class 1 and Class 2 residual solvents.

A perfect match for validated residualsolvent methods!

Save time and money with mixes prepared toyour specific solvent set and concentrations.The more you buy the less you pay per ampul!

Easy online order form:www.restek.com/customusp

Custom ResidualSolvent Mixes


528 www.restek.com 800-356-1688 or 814-353-1300

REFERENCE STANDARDS| PHARMACEUTICAL MATERIALS

USP, European Pharmacopoeia

benzene 2µg/mLcarbon tetrachloride 41,2-dichloroethane 5


European Pharmacopoeia/ICH Class 1 Mix (5 components)

Prepared in water:dimethyl sulfoxide (90:10), 1mL/ampulcat. # 36228 (ea.)

European Pharmacopoeia MethodThe analysis of residual solvents in pharmaceutical products haschanged, particularly for products being sold into Europe. TheInternational Conference on Harmonization (ICH) Guidelinesfor Residual Solvents is becoming the international standard andis being adopted by more pharmacopoeias, including the UnitedStates Pharmacopeia, every year. The ICH method and com-pound list is more extensive than any method previously usedand poses new challenges. Compounds in Class 1 are solventsconsidered to be of highest risk and to be avoided in pharma-ceutical manufacturing. Use of Class 2 compounds is to be lim-ited, as they pose a lower, but present, threat to health.Compounds in Class 3 pose the lowest toxic potential and maybe used routinely in manufacturing.

benzene 2µg/mLcarbon tetrachloride 41,2-dichloroethane 5


European Pharmacopoeia/ICH Class 1 Mix (revised)

(5 components)

In water:dimethyl sulfoxide (90:10), 1mL/ampulcat. # 36261 (ea.)

These Class 1 mixtures reflect the changes made in USP24/NF19effective January 1, 2000, and USP23/NF18 effective January 1,1995 to December 31, 1999. While these mixtures do not meetthe current USP guidelines, many labs still use these mixtures toobtain a detectable benzene peak for the direct injection meth-ods, Method I and Method V.

chloroform 60µg/mL1,4-dioxane 380

methylene chloride 600trichloroethene 80

USP <467> Calibration Mix #6 (4 components)


chloroform 60µg/mL1,4-dioxane 380


USP <467> Calibration Mix #7 (4 components)


benzene 2µg/mLchloroform 601,4-dioxane 380


USP <467> Calibration Mixture #4 (5 components)














Ethylene oxide is available in other solvents and concentrations. Request yourcustom formulation at [email protected].

Ethylene Oxide

500µg/mL in dimethyl sulfoxide, 1mL/ampulcat. # 36005 (ea.)

USP <467> cont'd

Get More!Pharmaceutical Solutions Online

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diethylene glycol 0.5mg/mLethylene glycol 0.5

glycerin 20Glycerin Standard Mix (3 components)


Limit of Diethylene & Ethylene Glycol StandardsMeet new FDA Guidance for Industry: Testing of Glycerin forDiethylene Glycol with our new diethylene glycol (DEG) andethylene glycol limit standards. This Guidance emphasizes theimportance of screening raw material for the presence of dieth-ylene glycol. Under cGMPs, drug manufacturers—not just glycerin manufacturers—must now test glycerin prior to use toprevent DEG-contamination in finished products. FDA hasworked extensively with USP to modify the glycerin monographand these standards support the revised USP method.

diethylene glycol 0.5mg/mLethylene glycol 0.5

propylene glycol 20Propylene Glycol Standard Mix (3 components)


diethylene glycol ethylene glycolSorbitol Standard Mix (2 components)

0.8mg/mL each in acetone:water (90:10), 1mL/ampulcat. # 31893 (ea.)

2,2,2-trichloroethanolLimit of Diethylene & Ethylene Glycol Internal Standard Mix

10mg/mL in P&T methanol, 1mL/ampulcat. # 31894 (ea.)

NEW!

NEW!

NEW!

NEW!


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REFERENCE STANDARDS | PHARMACEUTICAL MATERIALS

European Pharmacopoeia, Fatty Acids, ASTM MethodsASTM Method D6042-96 (Plastic Container Testing)

BHTerucamide slipvitamin EIrgafos 168

Irganox 3114Irganox 1010Irganox 1076


50µg/mL each in isopropanol, 1mL/ampulcat. # 31628 (ea.)

Tinuvin PASTM D6042-96 Internal Standard Mix

51.8µg/mL in isopropanol, 1mL/ampulcat. # 31629 (ea.)



Other Additives—Available from Restek as Custom

FormulationsSimilar methods for extractables in plastic pharmaceutical containers are cited inthe United States Pharmacopeia (USP), British Pharmacopoeia (BP), EuropeanPharmacopoeia (EP), and Japanese Pharmacopoeia (JP). Customers may alsohave formulation-specific or product-specific test mixtures. Please contact us fora custom mixture. Our current inventory of raw materials includes these popularantioxidants. We have many more not listed and can obtain most compounds youmay need.• Ethanox 323• Ethanox 330• Ethanox 702• Ethanox 703• Irganox L06• Irganox L57

• Irganox L64• Irganox L109• Irganox L134• Irganox L135• Irganox 1035• Santanox R

• Ultranox 626• Vanlube 81• Vanlube 848• Vanlube 7723• Vanlube AZ• Vanlube NA

• Vanlube PCX• Vanlube SL• Vanlube SS

chlorobenzene 360µg/mLcyclohexane 3,880cis-1,2-dichloroethene 1,870N,N-dimethylformamide 880ethylbenzene 369n-hexane (C6) 290methylcyclohexane 1,180

methylene chloride 600tetrahydrofuran 720toluene 890trichloroethene 80m-xylene 1,302o-xylene 195p-xylene 304

European Pharmacopoeia/ICH Q3C(M) Class 2 Mix A, Revised

(14 components)


2-ethoxyethanol 160µg/mLethylene glycol 620formamide 2202-methoxyethanol

(methyl Cellosolve) 50

N-methylpyrrolidone 530sulfolane 160

European Pharmacopoeia/ICH Q3C(M) Class 2 Mix C, Revised

(6 components)


acetonitrile 410µg/mLchloroform 601,2-dimethoxyethane 100N,N-dimethylacetamide 1,090 1,4-dioxane 380

2-hexanone 50methanol 3,000nitromethane 50pyridine 200tetralin 100

European Pharmacopoeia/ICH Class 2 Mix B, Revised

(10 components)

Prepared in water:dimethyl sulfoxide (80:20), 1mL/ampulcat. # 36270 (ea.)

DDeessccrriippttiioonn %% bbyy WWeeiigghhttmethyl arachidate (C20:0) 40methyl dodecanoate (C12:0) 5methyl myristate (C14:0) 5

DDeessccrriippttiioonn %% bbyy WWeeiigghhttmethyl oleate (C18:1[cis9]) 20methyl palmitate (C16:0) 10methyl stearate (C18:0) 20


EP 2.4.22 Composition of Fatty Acids by GC Mix 1

(6 components)

100mg totalcat. # 35100 (ea.)

DDeessccrriippttiioonn %% bbyy WWeeiigghhttmethyl caproate (C6:0) 10methyl caprylate (C8:0) 10methyl decanoate (C10:0) 20

DDeessccrriippttiioonn %% bbyy WWeeiigghhttmethyl dodecanoate (C12:0) 20methyl myristate (C14:0) 40



(5 components)


European Pharmacopoeia Method cont'd

NEW!

NEW!

American Society for Testing and Materials (ASTM International)Method D6042-96—Test Method for Determination of PhenolicAntioxidants and Erucamide Slip Additives in PolypropyleneHomopolymer Formulations Using Liquid Chromatography—is a “consensus” or “referee” method used among plastic manu-facturers and the pharmaceutical companies that purchase plas-tic containers. Plastic container manufacturers use this test toensure the quality of their product to their pharmaceutical customers. Pharmaceutical companies also specify this test andprovide their own lists of target compounds and concentrationlimits in purchase agreements.

This test calls for isopropanol extraction, HPLC separation, andUV detection. Restek offers a variety of reversed phase HPLCcolumns suitable for these separations. Restek also designed ananalytical reference material to validate this method. This mix-ture contains the common antioxidants and slips listed in ASTMD6042-96, along with BHT.

NEW!

Keep up with advances in melamineanalysis at www.restek.com/melamine

Melamine Analysis Kit.........cat. # 33254

(see page 535)Detect melamine and related compounds byGC/MS with a complete analysis kit. Consistentwith FDA procedure and new guidance for at-risk pharmaceutical components.

At Risk for MelamineMeet new FDA guidance for

melamine contamination in at-risk

pharmaceutical components.

Composition of Fatty Acids by GC


REFERENCE STANDARDS

FOODS, FLAVORS &FRAGRANCES MATERIALSFlavors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .531

Fragrances . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .531

Nutritional Analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .531-533

Composition of Fatty Acids by GC . . . . . . . . . . . . . . . . . . . . . . .533

Food Safety . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .534-535

Food Testing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .536

Derivatization Reagents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .537

What’sNEW?


530-539_ARM_fff_testmix.qxp 11/22/2010 8:51 PM Page 530

800-356-1688 or 814-353-1300 www.restek.com 531

REFERENCE STANDARDS | FOODS, FLAVORS & FRAGRANCES MATERIALS

Flavors & Fragrances, Nutritional Analysis

Organic acids on an Allure® Organic Acids HPLC

column.

Flavors

citric acid 2,000µg/mlfumaric acid 10*malic acid 2,000

quinic acid 2,000tartaric acid 2,000

Fruit Juice Organic Acid Standard (5 components)

In water, 1mL/ampulcat. # 35080 (ea.)

In water, 5mL/ampulcat. # 35081 (ea.)

PPeeaakk LLiisstt:: CCoonncc.. ((mmgg//mmLL))1. tartaric acid 12. quinic acid 13. malic acid 14. citric acid 15. fumaric acid 0.005

SSaammppllee::Inj.: 10µL standard solutionSolvent: water

CCoolluummnn:: AAlllluurree®® OOrrggaanniicc AAcciiddssCat.#: 9165585Dimensions: 300mm x 4.6mmParticle size: 5µmPore size: 60Å

CCoonnddiittiioonnss::Mobile phase: 100mM phosphate buffer, pH 2.5Flow: 0.5mL/min.Temp.: ambientDet.: UV @ 226nm

LC_0238

*Fumaric acid is a trace impurity in malic acid, as well as an added componentof the mix. The amount of fumaric acid in malic acid will not affect the statedconcentration of malic acid, but can represent a significant and variable devia-tion from the low concentration of fumaric acid stated to be in the mix. All othercomponents of the mix are at the specified concentration.Quantity discounts not available.

Fatty Acid Methyl Esters (FAMEs)

CChhaaiinn DDeessccrriippttiioonn %% bbyy WWeeiigghhttC14:0 methyl myristate 6.0C14:1 methyl myristoleate 1.0C16:0 methyl palmitate 16.0C16:1 methyl palmitoleate 5.0C18:0 methyl stearate 8.0C18:1 methyl oleate 13.0C18:1 methyl vaccenate 4.0C18:2 methyl linoleate 2.0C18:3 methyl linolenate 2.0C20:0 methyl arachidate 1.0C20:1 methyl 11-eicosenoate 9.0C20:2 methyl 11-14-eicosadienoate 1.0C20:4 methyl arachidonate 3.0C20:3 methyl 11-14-17-eicosatrienoate 1.0C20:5 methyl eicosapentaenoate 10.0C22:0 methyl behenate 1.0C22:1 methyl erucate 3.0C22:6 methyl docosahexaenoate 12.0C24:0 methyl lingnocerate 1.0C24:1 methyl nervonate 1.0

Marine Oil FAME Mix (20 components)

cat. # 35066 (100mg)

DDeessccrriippttiioonn %% bbyy WWeeiigghhttmethyl elaidate (C18:1 trans-9) 10.0methyl linoleate (C18:2 cis-9,12) 20.0methyl oleate (C18:1 cis-9) 10.0methyl petroselinate (C18:1cis-6) 8.0methyl petroselaidate (C18:1trans-6) 8.0methyl stearate (C18:0) 20.0methyl transvaccenate (C18:1 trans-11) 12.0methyl vaccenate (C18:1 cis-11) 12.0

cis/trans FAME Mix (8 components)

10mg/mL total in methylene chloride, 1mL/ampulcat. # 35079 (ea.)

No data pack available. Quantity discounts not available.


acetic acidbutyric acid (C4:0)isobutyric acid

isovaleric acidpropionic acidvaleric acid

Free Fatty Acids Test Standard (6 components)

1,000µg/mL each in water, 1mL/ampulcat. # 35272 (ea.)

Standard Methods for the Examination of Water andWastewater Method 5560: Organic and Volatile AcidsThe measurement of organic acids, either by adsorption and elu-tion from a chromatographic column or by distillation, can beused as a control test for anaerobic digestion. The chromato-graphic separation method is presented for organic acids(5560B), while a method using distillation (5560C) is presentedfor volatile acids. A new method using gas chromatography isincluded for the determination of acetic, propionic, butyric,isobutyric, valeric, and isovaleric acids (5560D).

benzoic acid 1.0%benzyl salicylate 36.2%1,8-cineole (eucalyptol) 0.5%trans cinnamaldehyde 0.5%cinnamyl acetate 0.3%cinnamyl alcohol 0.3%ethyl butyrate 36.2%

geraniol 0.6%hydroxycitronellal (3,7-dimethyl-

7-hydroxyoctanal) 5.0%d-limonene 20.0%thymol 0.3%vanillin 0.1%

Fragrance Materials Test Mix (12 components)

The Fragrance Materials Association (FMA) has proposed a methodfor analyzing essential oils on polar and nonpolar capillary GCcolumns. A performance evaluation mixture should be used to aid indetecting inlet problems, stationary phase degradation, loss of reso-lution, changes in sensitivity, and the presence of reactive sites in thesample pathway. Our test mix is consistent with the mixture pro-posed by the FMA. The required 5% test solution is made by dilut-ing the 0.5mL of neat mixture to 10mL with acetone. The workingsolution will be stable for up to one week if transferred to a dark container and stored refrigerated.

Neat, 0.5mL in an amber ampulcat. # 31807 (ea.)


Fragrances


ordering noteCustom fatty acid methyl ester mixtures also are available. Call 800-356-1688 or 814-353-1300, or contact your Restek representative for details.

532 www.restek.com 800-356-1688 or 814-353-1300


Nutritional Analysis

CChhaaiinn %% bbyy WWeeiigghhttC4:0 4.0C6:0 4.0C8:0 4.0C10:0 4.0C11:0 2.0C12:0 4.0C13: 2.0C14:0 4.0C14:1(cis-9) 2.0C15:0 2.0C15:1(cis-10) 2.0C16:0 6.0C16;1(cis-9) 2.0C17:0 2.0C17:1(cis-10) 2.0C18:0 4.0C18:1(trans-9) 2.0C18:1(cis-9) 4.0C18:2(all-trans-9,12) 2.0

CChhaaiinn %% bbyy WWeeiigghhttC18:2(all-cis-9,12) 2.0C18:3(all-cis-6,9,12) 2.0C18:3(all-cis-9,12,15) 2.0C20:0 4.0C20:1(cis-11) 2.0C20:2(all-cis-11,14,) 2.0C20:3(all-cis-8,11,14) 2.0C20:3(all-cis-11,14,17) 2.0C20:4(all-cis-5,8,11,14) 2.0C20:5(all-cis-5,8,11,14,17) 2.0C21:0 2.0C22:0 4.0C22:1(cis-13) 2.0C22:2(all-cis-13,16) 2.022:6 (all-cis-4,7,10,13,16,19) 2.0C23:0 2.0C24:0 4.0C24:1(cis-15) 2.0

Food Industry FAME Mix (37 components)


CChhaaiinn %% bbyy WWeeiigghhttC4:0 1.5C6:0 1.5C8:0 2.0C10:0 2.5C11:0 2.5C12:0 5.0C13: 2.5C14:0 2.5C14:1(cis-9) 1.5C15:0 1.5C16:0 10.0C16:1(cis-9) 5.0C17:0 2.5C18:0 5.0

CChhaaiinn %% bbyy WWeeiigghhttC18:1(trans-9) 2.5C18:1(cis-9) 15.0C18:2(all-trans-9,12) 2.5C18:2(all-cis-9,12) 10.0C18:3(all-cis-9,12,15) 5.0C20:0 2.5C20:1(cis-11) 1.5C20:5(all-cis-5,8,11,14,17) 2.5C22:0 2.5C22:1(cis-13) 1.5C22:6(all-cis-4,7,10,13,16,19) 2.5C23:0 1.5C24:0 2.5C24:1(cis-15) 2.5

NLEA FAME Mix (28 components)


Neat Fatty Acid Methyl Esters

Fatty Acid Methyl Esters (FAMEs) cont'd




CChhaaiinn DDeessccrriippttiioonn CCAASS ## qqttyy.. ccaatt..## pprriicceeC6:0 methyl caproate 106-70-7 100mg 35037C7:0 methyl heptanoate 106-73-0 100mg 35038C8:0 methyl caprylate 111-11-5 100mg 35039C9:0 methyl nonanoate 1731-84-6 100mg 35040C10:0 methyl caprate 110-42-9 100mg 35041C11:0 methyl undecanoate 1731-86-8 100mg 35042C12:0 methyl laurate 111-82-0 100mg 35043C13:0 methyl tridecanoate 1731-88-0 100mg 35044C14:0 methyl myristate 124-10-7 100mg 35045C14:1 Δ 9 cis methyl myristoleate 56219-06-8 100mg 35046C15:0 methyl pentadecanoate 7132-64-1 100mg 35047C16:0 methyl palmitate 112-39-0 100mg 35048C16:1 Δ 9 cis methyl palmitoleate 1120-25-8 100mg 35049C17:0 methyl heptadecanoate 1731-92-6 100mg 35050C18:0 methyl stearate 112-61-8 100mg 35051C18:1 Δ 9 cis methyl oleate 112-62-9 100mg 35052C18:2 Δ 9,12 cis methyl linoleate 112-63-0 100mg 35053C18:3 Δ 9,12,15 cis methyl linolenate 301-00-8 100mg 35054C19:0 methyl nonadecanoate 1731-94-8 100mg 35055C20:0 methyl arachidate 1120-28-1 100mg 35056C20:1 Δ 11 cis methyl eicosenoate 2390-09-2 100mg 35057C20:2 Δ 11,14 cis methyl eicosadienoate 2463-02-7 100mg 35058C20:3 Δ 11,14,17 cis methyl eicosatrienoate 55682-88-7 100mg 35059C20:4 Δ 5,8,11,14 cis methyl arachidonate 2566-89-4 100mg 35060C21:0 methyl heneicosanoate 6064-90-0 100mg 35061C22:0 methyl behenate 929-77-1 100mg 35062C22:1 Δ 13 cis methyl erucate 1120-34-9 100mg 35063C24:0 methyl lignocerate 2442-49-1 100mg 35064C24:1 Δ 15 cis methyl nervonate 2733-88-2 100mg 35065



800-356-1688 or 814-353-1300 www.restek.com 533


Nutritional Analysis, Composition of Fatty Acids by GCQuantitative Fatty Acid Methyl Ester (FAME) MixturesThese mixtures can be used for quantification (AOCS Method CE 1-62) and approximate the compositions of the followingtypes of oils:AOCS #1: corn, poppy seed, cotton seed, soybean, walnut,

safflower, sunflower, rice, bran, and sesame oilAOCS #2: linseed, perilla, hempseed, and rubberseed oilAOCS #3: peanut, rapeseed, and mustard seed oilAOCS #4: olive, teaseed, and neatsfoot oilAOCS #5: coconut, palm kernel, babassu, and ouri-curi oilAOCS #6: lard, beef or mutton tallow, and palm oilFAME #1: oils of mid-range chain lengths (C16 - C18)FAME #2: oils of short to mid-range chain lengths (C6 - C14)FAME #3: oils of short to mid-range chain lengths (C8 - C16)

FAME #4: oils of mid-range to long chain lengths (C16 - C24)FAME #5: oils of mid-range to long chain lengths (C16 - C24)FAME #6: oils of long chain lengths (C20 - C21)FAME #7: oils of short chain lengths (C6 - C10)FAME #8: oils of short to mid-range chain lengths (C11 - C15)FAME #9: oils of mid-range to long chain lengths (C16 - C20)FAME #12: oils of mid-range to long chain lengths (C13 - C21)FAME #13: mustard seed oilFAME #14: cocoa butterFAME #15: peanut oil

methyl nervonate (24:1)

methyl lignocerate (24:0)

methyl docosadienoate (22:2)

methyl erucate (22:1)

methyl behenate (22:0)

methyl heneicosanoate (21:0)

methyl arachidonate (20:4)

methyl hom

o γlinolenate (20:3)

methyl eicosadienoate (20:2)

methyl eicosenoate (20:1)

methyl arachidate (20:0)

methyl nonadecanoate (19:0)

methyl linolenate (18:3)

methyl linoleate (18:2)

methyl oleate (18:1)

methyl stearate (18:0)

methyl heptadecanoate (17:0)

methyl palm

itoleate (16:1)

methyl palm

itate (16:0)

methyl pentadecanoate (15:0)

methyl m

yristate (14:0)

methyl tridecanoate (13:0)

methyl laurate (12:0)

methyl undecanoate (11:0)

methyl caprate (10:0)

methyl nonanoate (9:0)

methyl caprylate (8:0)

methyl heptanoate (7:0)

methyl caproate (6:0)

MMiixx ccaatt.. ## pprriiccee CCoommppoossiittiioonn ooff eeaacchh mmiixxttuurree lliisstteedd aass aa wweeiigghhtt//wweeiigghhtt %% bbaassiiss ((mmiinniimmuumm 5500mmgg//aammppuull))AOCS #1 35022 6.0 3.0 35.0 50.0 3.0 3.0AOCS #2 35023 7.0 5.0 18.0 36.0 34.0AOCS #3 35024 1.0 4.0 3.0 45.0 15.0 3.0 3.0 3.0 20.0 3.0AOCS #4 35025 11.0 3.0 80.0 6.0AOCS #5 35026 7.0 5.0 48.0 15.0 7.0 3.0 12.0 3.0AOCS #6 35027 2.0 30.0 3.0 14.0 41.0 7.0 3.0FAME #1 35010 20.0 20.0 20.0 20.0 20.0FAME #2 35011 20.0 20.0 20.0 20.0 20.0FAME #3 35012 20.0 20.0 20.0 20.0 20.0FAME #4 35013 20.0 20.0 20.0 20.0 20.0FAME #5 35014 20.0 20.0 20.0 20.0 20.0FAME #6 35015 20.0 20.0 20.0 20.0 20.0FAME #7 35016 20.0 20.0 20.0 20.0 20.0FAME #8 35017 20.0 20.0 20.0 20.0 20.0FAME #9 35018 20.0 20.0 20.0 20.0 20.0FAME #12 35021 20.0 20.0 20.0 20.0 20.0FAME #13 35034 3.0 1.0 2.0 20.0 15.0 10.0 1.0 10.0 2.0 1.0 30.0 2.0 1.0 2.0FAME #14 35035 0.1 26.3 0.4 0.3 33.7 34.3 3.1 0.2 1.3 0.1 0.2FAME #15 35036 10.0 3.0 50.0 30.0 1.5 1.5 3.0 1.0


DDeessccrriippttiioonn %% bbyy WWeeiigghhttmethyl arachidate (C20:0) 40methyl dodecanoate (C12:0) 5methyl myristate (C14:0) 5

DDeessccrriippttiioonn %% bbyy WWeeiigghhttmethyl oleate (C18:1[cis9]) 20methyl palmitate (C16:0) 10methyl stearate (C18:0) 20



(6 components)


DDeessccrriippttiioonn %% bbyy WWeeiigghhttmethyl caproate (C6:0) 10methyl caprylate (C8:0) 10methyl decanoate (C10:0) 20

DDeessccrriippttiioonn %% bbyy WWeeiigghhttmethyl dodecanoate (C12:0) 20methyl myristate (C14:0) 40



(5 components)


NEW! NEW!

Composition of Fatty Acids by GC


534 www.restek.com 800-356-1688 or 814-353-1300


Food Safety

PCB 18PCB 28

PCB 52tris-(1,3-dichloroisopropyl)phosphate

QuEChERS Internal Standard Mix for GC/ECD Analysis

(4 components)


QuEChERS Standards• Ready to use for QuEChERS extractions—no dilutions necessary.• Support for GC and HPLC with MS, MS/MS, and selective detectors.

Pesticide analysis is fast and simple using QuEChERS methods. Use these cost-effective QuEChERS standards for even greater labefficiency. Standards are compatible with all major methods, including mini-multiresidue, AOAC, and European procedures. Savetime with convenient mixes or make your own blend using our full line of single component solutions.

triphenyl phosphate 20µg/mLtris-(1,3-dichloroisopropyl)phosphate 50µg/mL

QuEChERS Internal Standard Mix for GC/NPD and LC/MS/MS

Analysis (2 components)


PCB 18 50µg/mLPCB 28 50PCB 52 50triphenyl phosphate 20

tris-(1,3-dichloroisopropyl)phosphate 50

triphenylmethane 10

QuEChERS Internal Standard Mix for GC/MS Analysis

(6 components)


nicarbazinQuEChERS Internal Standard Mix for LC/MS/MS Analysis


CCaatt..## 3333226688::PCB 138PCB 153

CCaatt..## 3333226644::anthracene

QuEChERS Quality Control Standards for GC/MS Analysis



CCoommppoouunndd SSoollvveenntt CCoonncc.. ccaatt..## ((eeaa..)) pprriicceePCB 18 (5mL) ACN 50 33255PCB 28 (5mL) ACN 50 33256PCB 52 (5mL) ACN 50 33257PCB 138 (5mL) ACN 50 33262PCB 153 (5mL) ACN 50 33263triphenylmethane (5mL) ACN 10 33260triphenylphosphate (5mL) ACN 20 33258tris(1,3-dichloroisopropyl)phosphate (5mL) ACN 50 33259

ACN = acetonitrile

QuEChERS Single-Component Reference Standards

Concentration is µg/mL.

Complete Product Offering

to support AOAC (2007.01)

& European (EN 15662)

QuEChERS Methods

• Comprehensive portfolio of QuEChERS tubes. • Method-specific internal and QC standards.• Rxi®-5Sil MS capillary column • Ultra Aqueous C18 LC column• Q-sep™ 3000 Centrifuge

www.restek.com/quechers

NEW!


800-356-1688 or 814-353-1300 www.restek.com 535


Food Safety

Quantity discounts not available.cat. # 33254 (kit)

Kit includes:CCoolluummnn:: Rxi-5Sil MS w/5 meter Integra-GuardSSttaannddaarrddss::33247: 1mL Melamine Stock Standard (1,000µg/mL)33248: 1mL Cyanuric Acid Stock Standard (1,000µg/mL)33249: 1mL Ammelide Stock Standard (1,000µg/mL)33250: 1mL Ammeline Stock Standard (1,000µg/mL)33251: 1mL Benzoguanamine Internal Standard (1,000µg/mL)33253: 1mL Melamine Mix Standard (1,000µg/mL)DDeerriivvaattiizzaattiioonn RReeaaggeenntt::35607: BSTFA w/1% TMCS, 25g vialAAcccceessssoorriieess::50mL centrifuge tubes, 5-pk.13mm, 0.45µm nylon syringe filters, 5-pk.EEaassyy--ttoo--ffoollllooww iinnssttrruuccttiioonnss with procedural check lists to assist with laboratorydocumentation.

Melamine Analysis Kitkit melamine

Melamine Stock Standard

1,000µg/mL in diethylamine:water (20:80), 1mL/ampulcat. # 33247 (ea.)

cyanuric acidCyanuric Acid Stock Standard


ammelideAmmelide Stock Standard


ammelineAmmeline Stock Standard


benzoguanamineBenzoguanamine Internal Standard



ammelideammeline

cyanuric acidmelamine

Melamine and Related Analogs Stock Standard (4 components)

1,000µg/mL each in diethylamine:water (20:80), 1mL/ampulcat. # 33253 (ea.)

Keep up with advances in melamine analysis atwww.restek.com/melamine

Full GC/MSmethod kit

available withinstructions!

Easily detect 1 μg/gmelamine with our

complete kit for GC/MS

NEW!


536 www.restek.com 800-356-1688 or 814-353-1300


Food Testing

Equal concentration of all compounds. Suitable for GC/MS analysis.

Varied concentrations. Suitable for GC/ECD analysis.

Equal concentration of all compounds. Suitable for GC/FPD, GC/NPD,& GC/MS analysis.

FAPAS-registered trademark of Central Science Laboratory, Sand Hutton, York,YO41, UK.

FAPAS® Food Testing Program*Laboratories testing food quality and safety are encouraged toroutinely perform proficiency tests. Proficiency testing is anexternal check of quality. It provides an independent and unbi-ased assessment of the performance of all aspects of the labora-tory, both human and hardware. Each participating laboratory isencouraged to use its normal analytical method, thereby simu-lating the testing of a routine laboratory sample as closely as pos-sible. While the outcome of the analysis may depend on thechoice of method, it also could be affected by the performance ofthe laboratory equipment or the competence of the analyst.Using proficiency testing, those laboratories performing well canensure high standards are maintained and those performingunsatisfactorily can implement corrective action rapidly. In anenvironment in which analytical laboratories compete intensive-ly for work, proficiency testing provides the means by whichexternal customers can compare competence in carrying outspecific tests. Together with laboratory accreditation and the useof validated methods, proficiency tests are an important require-ment of the EU Additional Measures Directive 93/99/EEC apply-ing to laboratories entrusted with the official control of food.

aldrinα-BHCβ-BHCγ-BHC (lindane)α-chlordane (cis)γ-chlordane (trans)4,4'-DDD4,4'-DDE2,4'-DDT4,4'-DDT

dieldrinα-endosulfan (I)β-endosulfan (II)endosulfan sulfateendrinheptachlorheptachlor epoxide (isomer B)hexachlorobenzeneoxychlordane

*Use of Restek calibration mixtures by laboratories participating in the FAPASprogram is voluntary and no endorsement of any Restek product has been madeby the Central Science Laboratory. To obtain further information regarding theFAPAS program, or to participate, contact [email protected].

FAPAS® Series 5 OC Pesticide Mix 1 (19 components)


aldrin 10µg/mLα-BHC 10β-BHC 10γ-BHC (lindane) 10α-chlordane (cis) 10γ-chlordane (trans) 104,4'-DDD 204,4'-DDE 202,4'-DDT 204,4'-DDT 20

dieldrin 20α-endosulfan (I) 10β-endosulfan (II) 20endosulfan sulfate 20endrin 20heptachlor 10heptachlor epoxide (isomer B) 10hexachlorobenzene 10oxychlordane 10

FAPAS® Series 5 OC Pesticide Mix 2 (19 components)


chlorpyriphoschlorpyriphos-methyldiazinondichlorvosetrimphos

fenitrothionmalathionmethacriphosphosphamidonpirimiphos-methyl

FAPAS® Series 9 OP Pesticide Mix 1 (10 components)


Get More!Foods, Flavors & Fragrances

Solutions Onlinewww.restek.com/FFF

BHTerucamide slipvitamin EIrgafos 168

Irganox 3114Irganox 1010Irganox 1076



50µg/mL each in isopropanol, 1mL/ampulcat. # 31628 (ea.)

Other Additives Available From Restek on a Custom Basis Similar methods for extractables in plastic pharmaceutical containers are cited inthe United States Pharmacopeia (USP), British Pharmacopoeia (BP), EuropeanPharmacopoeia (EP), and Japanese Pharmacopoeia (JP). Customers may alsohave formulation-specific or product-specific test mixtures. Please contact us fora custom mixture. Our current inventory of raw materials includes these popularantioxidants. We have many more not listed and can obtain most compounds youmay need.

ASTM Method D6042-96 (Plastic Container Testing)American Society for Testing and Materials (ASTM International)Method D6042-96—Test Method for Determination of PhenolicAntioxidants and Erucamide Slip Additives in PolypropyleneHomopolymer Formulations Using Liquid Chromatography—is a “consensus” or “referee” method used among plastic manu-facturers and the pharmaceutical companies that purchase plas-tic containers. Plastic container manufacturers use this test toensure the quality of their product to their pharmaceutical customers. Pharmaceutical companies also specify this test andprovide their own lists of target compounds and concentrationlimits in purchase agreements.

This test calls for isopropanol extraction, HPLC separation, andUV detection. Restek offers a variety of reversed phase HPLCcolumns suitable for these separations. Restek also designed ananalytical reference material to validate this method. This mix-ture contains the common antioxidants and slips listed in ASTMD6042-96, along with BHT.

Tinuvin P


ASTM D6042-96 Internal Standard Mix

51.8µg/mL in isopropanol, 1mL/ampulcat. # 31629 (ea.)

• Ethanox 323• Ethanox 330• Ethanox 702• Ethanox 703• Irganox L06• Irganox L57

• Irganox L64• Irganox L109• Irganox L134• Irganox L135• Irganox 1035• Santanox R

• Ultranox 626• Vanlube 81• Vanlube 848• Vanlube 7723• Vanlube AZ• Vanlube NA

• Vanlube PCX• Vanlube SL• Vanlube SS


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REFERENCE STANDARDS| FOODS, FLAVORS & FRAGRANCES MATERIALS

Derivatization Reagents

CCoommppoouunndd CCAASS## ccaatt..## pprriicceeMBTFA (N-methyl-bis-trifluoroacetamide)10-pk. (10x1g) 685-27-8 3561625g vial 685-27-8 35617TFAA (trifluoroacetic acid anhydride)10-pk. (10x1g) 407-25-0 3561825g vial 407-25-0 35619PFAA (pentafluoropropionic acid anhydride)10-pk. (10x1g) 356-42-3 3562025g vial 356-42-3 35621HFAA (heptafluorobutyric acid anhydride)10-pk. (10x1g) 336-59-4 3562225g vial 336-59-4 35623PFPOH (pentafluoropropanol)10-pk. (10x1g) 422-05-9 3562425g vial 422-05-9 35625

Acylation Derivatization Reagents

Acylation reagents offer the same types of advantages availablefrom silylation reagents: creating less polar, more volatile deriva-tives. In comparison to silylating reagents, the acylating reagentscan more readily target highly polar multi-functional com-pounds, such as carbohydrates and amino acids. In addition,acylating reagents offer the distinct advantage of introducingelectron-capturing groups, thus enhancing detectability duringanalysis.

• Most commonly used for electron capture detection.• React with alcohols, amines and phenols.• Frequently used for drugs of abuse confirmation.

CCoommppoouunndd CCAASS## ccaatt..## pprriicceeTMPAH10-pk. (10x1g) 1899-02-1 3561425g vial 1899-02-1 35615

Alkylation Derivatization Reagents

Alkylation reagents reduce molecular polarity by replacing activehydrogens, such as carboxylic acids and phenols. Alkylationreagents can be used alone to form esters and amides or they canbe used in conjunction with acylation or silylation reagents. Atwo-step approach is commonly used in the derivatization ofamino acids, where multiple functional groups of these com-pounds may necessitate protection during derivatization.

Esterification is the reaction of an acid with an alcohol in thepresence of a catalyst. It is the most popular method of alkylationdue to the availability of reagents and ease of use. Alkyl esters arestable, and can be formed quickly and quantitatively. Retentionof the derivative can be varied by altering the length of the sub-stituted alkyl group. In addition to the formation of simpleesters, alkylation reagents can be used in extraction procedureswhere biological matrices are present.

• Adds alkyl groups to functional hydrogens (H).• Decreases polarity on compounds containing acidic

hydrogens, i.e., phenols, carboxylic acids.• Forms an ester.

• Replaces active hydrogen, reducing polarity and making thecompounds more volatile.

• Increases stability of derivatives.

CCoommppoouunndd CCAASS## ccaatt..## pprriicceeMSTFA (N-methyl-N-trimethylsilytrifluoroacetamide)10-pk. (10x1g) 24589-78-4 3560025g vial 24589-78-4 35601MSTFA w/1% TMCS (N-methyl-N-trimethylsilytrifluoroacetamide w/1%trimethylchlorosilane)10-pk. (10x1g) 24589-78-4 3560225g vial 24589-78-4 35603BSTFA (N,O-bis[trimethylsilyl]trifluoroacetamide)10-pk. (10x1g) 25561-30-2 3560425g vial 25561-30-2 35605BSTFA w/1% TMCS (N,O-bis[trimethylsilyltrifluoroacetamide] w/1% trimethylchlorosilane)10-pk. (10x1g) 25561-30-2 3560625g vial 25561-30-2 35607MTBSTFA w/1% TBDMCS (N-methyl-N[tert-butyldimethylsilyl trifluoroacetamide] w/1% tert-butyldimethylchlorosilane)10-pk. (10x1g) 77377-52-7 3560825g vial 77377-52-7 35610TMCS (trimethylchlorosilane)10-pk. (10x1g) 75-77-4 3561125g vial 75-77-4 35612

Silylation Derivatization Reagents

Silylation is the most widely used derivatization procedure forsample analysis by GC. In silylation, an active hydrogen isreplaced by an alkylsilyl group such as trimethylsilyl (TMS) ortert-butyldimethylsilyl (tert-BDMS). Silyl derivatives are morevolatile, less polar, and more thermally stable. As a result, GCseparation is improved and detection is enhanced.

Both TMS and tert-BDMS reagents are suitable for a wide vari-ety of compounds and can be used for many GC applications.Note that silylation reagents are generally moisture sensitive andmust be sealed to prevent deactivation.

DerivatizationReagents• Reagents available for acylation,

alkylation, and silylation.• Packaged in 10 x 1 g vials or 25 g vials.• High purity for accurate results.


n C 10-FAME 0.42mg/mLn C 11-FAME 0.42n C 12-FAME 0.412,3-butanediol 0.53dicyclohexylamine 0.312,6-dimethylaniline 0.32

2,6-dimethylphenol 0.322-ethylhexanoic acid 0.38nonanal 0.401-octanol 0.36undecane (C11) 0.29decane (C10) 0.28

Grob Test Mix (12 components)


1,2-butanediol 0.60mg/mLpyridine 0.60decane (C10) 0.60diethylenetriamine 1.20

diethanolamine 1.202-nonanol 0.602,6-dimethylaniline 0.60dodecane (C12) 0.60

Amine Column Test Mix (8 components)

In methylene chloride:methanol (1:1), 1mL/ampulcat. # 35002 (ea.)

1,2-hexanediol 0.46mg/mLdecane (C10) 0.29undecane (C11) 0.29dodecane (C12) 0.29tridecane 0.29

1-octanol 0.36nonanal 0.402,6-dimethylaniline 0.322,6-dichlorophenol 0.57naphthalene 0.32

Isothermal Column Test Mix (10 components)





For use with temperature programmed conditions.

For Stabilwax®-DB, Rtx®-5Amine, and Rtx®-35Amine columns.

For Restek’s complete line of columntest mixes, visit our website at:www.restek.com/testmixes

REFERENCE

STANDARDS

COLUMN TESTMIXES

GC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .538-539

HPLC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .539

Deactivating Agent . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .539

4-chlorophenoldicyclohexylamine2-ethylhexanoic acid1,6-hexanediol

1-methylnaphthalenen-tetradecane (C14)n-tridecane (C13)1-undecanol

Rxi®-5Sil MS/XLB Column Test Mix (8 components)

350µg/mL each in methylene chloride, 1mL/ampulcat. # 35226 (ea.)

acetonediethyl ether (ethyl ether)ethanolethyl acetate

n-hexane (C6)methanoln-pentane (C5)

Q-BOND and U-BOND Column Test Mix (7 components)

0.1% vol/vol each in heptane, 1mL/ampulcat. # 35202 (ea.)

GC

NEW!

NEW!


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REFERENCE STANDARDS | COLUMN TEST MIXES

GC, HPLC

benzene 1.00mg/mLbenzaldehyde 0.04

benzyl alcohol 3.004-methoxybenzyl alcohol 2.00

HPLC Normal Phase Test Mix #1 (4 components)


benzene 3.00mg/mLuracil 0.02

naphthalene 0.50biphenyl 0.06

HPLC Reversed Phase Test Mix #1 (4 components)

In methanol:water (75:25), 1mL/ampulcat. # 35005 (ea.)

Caffeine at 5, 25, 125, 250, 500µg/mL in water in a five ampul kit.

HPLC OQ Linearity Test Mix Kit

Linear detector responses to concentration variations are animportant part of operation qualification (OQ) for HPLCinstruments. Our kit of five aqueous solutions of caffeine can beused to generate simple plots of UV response versus concentra-tion. Certificate of Analysis includes caffeine concentration,calculated variance in preparing each mixture, a linearity plot,and coefficient of determination (r²) for the linear plot.

1mL each of these mixtures.cat. # 31805 (kit)

glucose 2.0mgfructose 2.1lactose 4.4

maltose 4.5sucrose 4.0

Carbohydrate HPLC Performance Check Mix (5 components)

Performance qualification (PQ) determines the precision of theHPLC system. Our performance check mix for HPLC/RI consistsof five simple sugars in varied concentrations. We prepare thereference material in water, lyophilize it, and pack it dry forenhanced stability.

Dry components in 4mL screw-cap vial. Reconstitute in 1mL acetonitrile:water (75:25)to 2.0, 2.1, 4.4, 4.5, 4.0mg/mL, respectively.

cat. # 31809 (ea.)

amitriptyline hydrochloride 2,800µg/mL

ethylbenzene 1,700

quinizarin 94toluene 1,400uracil 28

HPLC Performance Test Mix (5 components)

The National Institute of Standards and Technology (NIST) hasformulated a mixture that is highly effective for characterizingHPLC columns for efficiency, void volume, methylene selectivi-ty, retentiveness, and activity toward chelators and organic bases.Results can be used for column classification, for column selec-tion, for monitoring column performance over time, or for qual-ity control. We test our material against the NIST 870 standard.






dimethyldichlorosilane (DMDCS)

Dimethyldichlorosilane (DMDCS) Deactivating Agent

Restek offers dimethyldichlorosilane (DMDCS), for deactivatingliners and other glassware. Simply dilute the neat material to a 5%solution in toluene, soak the glass item(s) in the solution for 15minutes, and rinse with toluene and methanol. DMDCS reactswith active hydroxyl groups on the glass surface to produce a deac-tivated surface. A detailed procedure is included with the product.


n-heptadecane (C17) 1.5µg/mLn-octadecane (C18) 10n-nonadecane (C19) 2n-eicosane (C20) 100

n-docosane (C22) 1,000n-tetracosane (C24) 10,000

OQ Response Linearity Test Standard (6 components)

In isooctane, 1mL/ampulcat. # 33906 (ea.)

n-tetradecane (C14)n-pentadecane (C15)

n-hexadecane (C16)FID Performance Evaluation Standard (3 components)

0.03 w/w% each in hexane, 1mL/ampulcat. # 33908 (ea.)

1,2-dichlorobenzenenitrobenzene

tert-butyl disulfideOQ/PV Headspace Standard (3 components)

2,000µg/mL each in ethanol, 1mL/ampulcat. # 33909 (ea.)

also availableIndividual ampuls of caffeine are available on page 444.

GC cont'd HPLC cont'd

HPLC

Deactivating Agent

kit



and/or lot number)



reference standards

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