red bed paleoclimate.pdf
TRANSCRIPT
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upon which to base paleoclimatic interpretations.
Early research on modern red deserts supported the
and related to earlier paleoenvironmental conditions.
More recently, Parrish (1998, p. 192) stated that ter-
restrial red beds, b. . .appear to be indicative of cli-
Palaeogeography, Palaeoclimatology, Palaeoeinterpretation that ancient red beds formed in hot, dry1. Introduction
A long held dogma is that widespread Triassic
terrestrial red beds indicate a global transition to warm-
er and drier conditions than those that characterized the
Permian (Parrish, 1995). This new climatic system has
been termed the Pangean mega-monsoon (Kutzbach
and Gallimore, 1989). The question to be addressed
herein is whether red color alone is sufficient evidence
climates (Walker, 1976). However, modern red deserts
of Arizona and Australia are red because of sediments
recycled from paleosols of Triassic and Miocene age,
respectively, and most deserts of North and South
America, Asia, and the Middle East are grey like
their weathering source rocks. Further, many red
soils in semi-arid areas such as New Mexico derived
their red color from well-drained, warm conditions
during Pleistocene pluvials, so the red color is relictAbstract
Terrestrial red beds have long been interpreted as desert deposits by comparison with modern red deserts. More recently red
beds have been interpreted as evidence of seasonally dry conditions and a PermoTriassic Pangean monsoon. Red beds of Cala
Viola, Sardinia are identified as paleosols and used to reconstruct Late Permian paleoclimatic conditions. Reconstruction of
paleoenvironmental conditions based on the paleosols of the Cala Viola indicates warm, humid conditions with no evidence of
dry conditions, as in a desert, or of extreme seasonality as in a monsoon. Instead, it is suggested that the red color of the
paleosols is a result of former good drainage, and that red color in general does not indicate specific paleoclimatic conditions.
D 2005 Elsevier B.V. All rights reserved.
Keywords: Permian; Sardinia; Paleosols; Paleoclimate; MonsoonDo red beds indicate p
A Permian
Nathan D
Department of Geology, Royal Holloway University
Received 27 September 2004; received in revis0031-0182/$ - see front matter D 2005 Elsevier B.V. All rights reserved.
doi:10.1016/j.palaeo.2005.06.009
* Tel.: +44 1784 443615.
E-mail address: [email protected] conditions?:
ase study
heldon*
ndon, Egham, Surrey TW20 0EX, United Kingdom
rm 25 February 2005; accepted 16 June 2005
cology 228 (2005) 305319
www.elsevier.com/locate/palaeoeasonal with respectmates that are warm and dry or sto rainfall.Q A model put forth by Dubiel and Smoot(1994) suggests that continental red bed formation is
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favored by warm climates with alternating wet-and-
dry seasons (monsoons) and open, desert to savanna
vegetation. However, it is not an exact analog because
a true savanna requires grasslands, which did not
evolve until the Cenozoic (Retallack, 2001a; Terry,
2001). Monsoonal tropical Pakistan and India include
both grey and red soils and paleosols (Retallack,
1991a). Wynn (2000) and Wynn and Retallack
(2001) describe reconstructed savanna ecosystems
from Cenozoic paleosols in Africa that are not signi-
ficantly reddened. Furthermore, numerous examples
have been published of diagenetic reddening of non-
desert paleosols by dehydration of iron oxyhydroxides
(Retallack, 1991a, 1997, 2001b; see also the review of
older literature in Blodgett et al., 1993).
Taken together, these various factors suggest that
the origin of red color may not be well-understood or
well-explained by existing models. Work presented
here on Late Permian red beds in Sardinia offers an
alternative explanation to pronounced aridity or sea-
sonality. It is suggested that the red color is indicative
of well-drained conditions and that it provides no
unequivocal information on the paleoclimatic condi-
tions at the time of paleosol formation. Instead, paleo-
climatic conditions are reconstructed on the basis of
other proxies, such as the degree of chemical weath-
ering, nature and extent of pedogenic carbonate and
salts, and patterns of root traces and trace fossils.
2. Geologic context
Basin-and-Range topography was a result of the
CarboniferousPermian Hercynian orogeny from eastern
Europe to the southern coast of the United States
(Cortesogno et al., 1998). Collision of South Europe
with North America and Africa during the Late De-
vonian and Carboniferous (Condie, 1989) was fol-
lowed, through Triassic time, by local rifting and
formation of continental basins in Spain, Southern
n for
f the
N.D. Sheldon / Palaeogeography, Palaeoclimatology, Palaeoecology 228 (2005) 305319306Fig. 1. Map showing the location of field sites and stratigraphic colum
sample numbers, and Munsell colour of the sample is to the right oMosca Pesca and Lago di Baratz paleosols and the overlying Macchia pale
X) rather than at the first logged Macchia Rossa paleosol.the Lago di Baratz section, Verrucano Sardo Formation. LB01-15 are
sample number. The exact transition between the lesser developedosols is unknown and may lie in the covered interval (shown with an
-
Fig. 2. Stratigraphic column for the Cala Viola Nord section
Verrucano Sardo Formation. Symbols and conventions are as in
Fig. 1. Asterisks next to sample numbers indicate samples that were
weakly reactive to dilute acid. The thicknesses of the conglomerate
that caps the Cala Viola Nord and Sud sections are variable, so the
average thickness is portrayed. Where multiple lithologies are
shown, there is significant variability along strike and additiona
limatology, Palaeoecology 228 (2005) 305319 307France, Italy, Corsica, and Sardinia (Cassinis and
Ronchi, 1997). These basins were filled with clastic
red beds derived from the orogenic belt.
In Sardinia, those sediments are part of the Verru-
cano Sardo Formation exposed on the Cala Viola
(bviolet bayQ) (Fig. 1), and are divided it into fourinformal units (Gasperi and Gelmini, 1979). The red
beds described in this paper are from bUnit 2,Q a 150m package of sediments composed of sandy conglom-
erates, grey sandstones, and red sandstones and mud-
stones. The Cala Viola Nord section is capped by a
thick, quartz cobble conglomerate that is also exposed
near the base of the Cala Viola Sud section (Fig. 1).
The rocks exhibit fluvial paleochannels, tetrapod foot-
prints, and fossil plants indicating subaerial deposition
on alluvial fans and floodplains. Gasperi and Gelmini
(1979) examined the limited available fossil assem-
blages and found Autunian (Early Permian) non-ma-
rine strata near the base of the sequence and Triassic
red claystones and sandstones near the top [Units 3
and 4], overlain by Middle Triassic (AnisianEarly
Ladinian) limestone (Cassinis and Ronchi, 1997; Cas-
sinis et al., 1992). The red beds described here are
located near the top of the sequence (top of Unit 2),
and are thus Late Permian in age (Cassinis et al.,
1992).
The Lago di Baratz area (Fig. 1) is well vegetated
and exposure is generally poor. Three of the four
pedotypes are exposed in this section (Fig. 1), includ-
ing the Lago di Baratz and Mosca Pesca pedotypes,
which are not preserved in either of the Cala Viola
sections. In contrast, the Cala Viola sections, with
localized gentle folding, are well-exposed in sea cliffs
and rock platforms, and are continuous and conform-
able with significant lateral variability difficult to
capture adequately in single stratigraphic sections
(Figs. 2 and 3). The Lago di Baratz section lies
stratigraphically below the Cala Viola sections by an
unknown thickness of mudstones and sandstones in
Unit 2 of Gasperi and Gelmini (1979). However,
given that only the middle and upper portions of
Unit 2 are red and the lower portion is primarily
grey, it is possible that the red Macchia paleosols of
the Lago di Baratz section (Fig. 1) represent the first
red beds. If this is the case, given the 7585 m
exposed in the Cala Viola sections (Figs. 2 and 3)
N.D. Sheldon / Palaeogeography, Palaeocand a total thickness of 150 m for Unit 2 (Gasperi and
Gelmini, 1979), there can be no more than a few tenssymbols apply to the right column, which represents the dominan
lithology.,
lt
-
limatoN.D. Sheldon / Palaeogeography, Palaeoc308of meters between the top of the Lago di Baratz
section and the bottom of the Cala Viola Nord section.
3. Methods
Paleosols were recognized in the field on the basis
of ped morphology, horizonation, root traces, and
and in contrast to the fluvially-derived sandstones
(Fig. 4B). Many of the paleosols also preserve drab-
Fig. 3. Stratigraphic column for the Cala Viola Sud section, Verru-
cano Sardo Formation. Symbols and conventions are as in Fig. 1.
See Fig. 2 caption for additional information.haloed root traces (Fig. 4C,F) and rarely, vertical
burrows (Fig. 4C,D). Burrows range up to one cm
in diameter and show some internal structure consis-
tent with backfilling by an arthropod. Non-calcareous
rhizoliths are well-preserved in some of the paleosols,
both in hand specimen and thin section (Fig. 4H).
Both root traces and burrows penetrate deeply into
paleosol profiles (Fig. 4C), indicating that the paleo-
water table was substantially below the surface. Point
counts of thin sections (e.g., Fig. 4E,H) are consistent
with the field observation that paleosols are more fine-
grained than interfluve sandstones, siltstones, and
mudstones. Some of the Cala Viola paleosols have
an observed clay bulge (Fig. 5) and illuviation argil-
lans observable in thin section consistent with subsur-
face accumulation of clay in a Bt horizon. A and B
horizons of paleosols have 8097% clay and phyllo-
silicate minerals and 320% quartz and lithics (includ-grain size changes (Retallack, 1997). Munsell color
was recorded as well as the qualitative degree of
calcareousness on the basis of reaction with dilute
hydrochloric acid (Retallack, 1997). Samples were
collected for petrography and geochemical analysis
from three sites north of Alghero, near Lago di Baratz
and at two localities on the Cala Viola (Fig. 1).
Geochemical data were obtained from a commercial
laboratory (Intertek of Vancouver, B.C.) using XRF,
ICP-MS, and titration (FeO) and are compiled in
Table 1. Paleosols were classified into pedotypes
(Retallack, 1997; Retallack, 2001b) on the basis of
physical and chemical characteristics (Sheldon and
Retallack, 2001; Sheldon et al., 2002), and analyzed
using the factor function approach (Jenny, 1941).
Bulk density (q) was measured by the clod methodusing paraffin; analysis of 10 replicates of a single
sample gave an uncertainty of 0.09 g cm3.
4. Evidence of pedogenesis
Paleosols in the Cala Viola sections fine up-profile
and are notably finer grained than the succession as a
whole (Figs. 2 and 3). This difference shows up in the
weathering profile of the sections as well (Fig. 4A)
logy, Palaeoecology 228 (2005) 305319ing feldspars) with an average of less than 10%,
whereas C horizons and other fluvial sediments all
-
Table 1
Geochemical data
Sample Level
(m)
Reacta Horizon SiO2 TiO2 Al2O3 Feb FeO Fe2O3 MnO MgO CaO Na2O K2O P2O5 LOI Total
LB02 3.6 N 77.98 0.37 12.64 1.80 0.45 1.30 0.02 0.27 0.07 n/a 1.85 0.07 4.03 99.1
LB03 4.4 N A/Bwc 78.63 0.30 9.62 4.81 0.39 4.37 0.03 0.21 0.08 n/a 0.97 0.12 4.16 99.3
LB04A 5.9 N C 66.80 0.70 14.89 7.30 0.51 6.73 0.05 0.60 0.16 0.10 2.75 0.15 5.79 99.8
LB04B 6.0 N C 70.08 0.81 17.22 1.68 0.45 1.19 0.01 0.74 0.09 0.19 3.40 0.05 5.31 100.0
LB04C 6.2 N A/Bw 69.27 0.84 17.08 1.73 0.51 1.16 0.02 0.66 0.06 0.20 3.56 0.05 5.08 99.1
LB04D 6.4 N A 67.22 0.70 15.35 6.52 0.58 5.88 0.05 0.59 0.09 0.08 2.88 0.11 5.66 99.8
LB11 13.0 N C 75.11 0.52 14.21 2.83 0.45 2.33 0.03 0.62 0.11 0.03 2.48 0.07 4.29 100.8
LB12 13.2 N C 66.15 0.72 16.84 5.58 0.71 4.79 0.02 1.14 0.12 0.14 3.95 0.08 4.99 100.4
LB13 13.5 N C 61.17 0.80 18.76 6.54 0.71 5.75 0.02 1.40 0.08 0.17 4.82 0.06 5.27 99.8
LB14 13.7 N Bw 62.34 0.79 18.84 5.15 0.90 4.15 0.02 1.30 0.10 0.21 4.69 0.06 5.93 100.3
LB15 13.9 N A 61.20 0.78 18.63 7.02 0.64 6.31 0.02 1.32 0.08 0.15 4.70 0.08 5.30 99.9
CV03 1.7 N Bw 58.00 0.92 19.18 6.61 0.84 5.68 0.05 1.81 0.90 0.16 5.22 0.06 6.67 100.4
CV06 4.2 N 56.05 0.84 16.17 6.06 1.61 4.27 0.13 2.60 3.50 0.23 4.05 0.07 9.78 101.1
CV07 5.5 N C 48.79 0.72 16.40 6.19 0.71 5.40 0.46 4.30 5.26 0.22 4.41 0.09 12.5 100.0
CV08 5.8 N Bt 54.82 0.87 19.81 6.40 1.03 5.26 0.07 2.21 1.50 0.17 5.47 0.12 7.92 100.4
CV09 6.1 N Bt 56.93 0.91 20.65 6.49 0.90 5.49 0.02 1.67 0.28 0.15 5.72 0.12 6.27 100.1
CV10 6.5 N A 57.71 0.91 20.21 6.98 0.77 6.12 0.02 1.57 0.20 0.18 5.27 0.08 6.12 100.0
CV13 10.1 N 56.05 0.91 19.22 6.32 0.90 5.32 0.07 2.00 1.31 0.16 5.30 0.08 7.39 99.7
CV16 12.4 N C 55.56 0.78 14.59 6.55 1.74 4.62 0.18 3.03 4.20 0.32 3.79 0.04 10.7 101.4
CV19 14.1 Y C 56.24 0.86 16.04 3.47 1.87 1.40 0.17 3.12 4.47 0.18 3.87 0.09 11.1 101.5
CV22 17.2 Y Bt 30.48 0.47 9.25 3.30 1.03 1.51 0.91 10.6 15.5 0.29 2.26 0.06 26.7 100.8
CV24 19.15 N C 56.12 0.59 13.94 4.64 1.42 3.07 0.18 3.27 5.08 0.26 3.58 0.05 11.4 100.5
CV25 19.85 N Bt 51.90 0.63 11.69 4.83 0.51 4.26 0.34 4.77 7.67 0.19 2.89 0.07 14.2 99.7
CV26 20.65 Y A 14.89 0.25 4.99 2.98 0.26 2.69 0.91 15.1 22.6 0.22 1.10 0.07 35.4 98.8
CV27 22.05 Y Bt 56.94 0.89 19.69 7.98 0.77 7.12 0.02 1.44 0.29 0.09 5.79 0.14 5.82 99.9
CV28 23.2 N C 53.35 0.83 15.45 5.58 0.77 4.72 0.06 1.50 1.90 0.22 4.24 0.09 6.61 90.6
CV29 24.2 N Bt 59.56 0.89 19.87 6.59 0.64 5.88 0.03 1.24 0.19 0.17 4.95 0.12 5.43 99.7
CV30 24.9 N Bt 57.89 0.93 20.01 8.35 0.58 7.71 0.03 1.20 0.14 0.12 4.77 0.11 5.75 99.9
CV31 26.15 N 55.13 0.61 11.67 4.29 0.51 3.72 0.15 1.18 6.57 0.56 2.41 0.05 11.5 94.6
CV45 46.5 N C 58.99 0.40 6.22 1.26 0.32 0.90 0.12 6.17 9.31 0.25 1.57 0.03 14.5 99.1
CV46 48.0 N BC 58.65 0.71 12.04 3.43 0.45 2.93 0.09 4.28 5.56 0.59 2.85 0.04 9.89 98.6
CV47 49.25 N Bw 83.50 0.26 8.57 1.23 0.45 0.73 0.01 0.28 0.22 0.05 1.57 0.03 2.75 99.0
Sample Rho
(g cm3)CIAK Clayeynessd (Pbases/Al)d Salin.d Gleyd MAP MAT Bae Sr Y Nb Zr Rb
LB02 2.52 0.095 0.22 0.16 0.77 132 66 25 28 164 112
LB03 2.39 98.51 0.07 0.18 0.11 0.198 1540 15.3 76 36 18 18 141 72
LB04A 2.58 0.13 0.33 0.21 0.17 351 92 31 21 257 137
LB04B 2.49 0.15 0.35 0.23 0.84 362 127 42 28 312 194
LB04C 2.50 97.49 0.15 0.35 0.24 0.98 1509 12.8 377 116 37 22 281 180
LB04D 2.55 98.11 0.13 0.32 0.21 0.22 1528 13.4 293 95 29 22 260 151
LB11 2.59 0.11 0.32 0.19 0.43 208 61 23 22 229 159
LB12 2.59 0.15 0.45 0.27 0.33 358 107 36 28 280 240
LB13 2.64 0.18 0.49 0.29 0.27 423 121 34 21 215 292
LB14 2.53 97.28 0.18 0.47 0.29 0.48 1503 12.0 405 123 33 28 229 293
LB15 2.54 97.94 0.18 0.47 0.29 0.23 1522 12.0 398 128 38 23 225 276
CV03 2.71 90.99 0.195 0.63 0.31 0.33 1328 11.6 622 117 37 23 171 266
CV06 2.70 0.17 1.095 0.29 0.84 1636 134 34 21 284 195
CV07 2.71 0.20 1.56 0.31 0.29 544 122 34 16 144 210
CV08 2.81 86.82 0.21 0.73 0.31 0.44 1223 11.5 998 105 30 22 114 262
(continued on next page)
N.D. Sheldon / Palaeogeography, Palaeoclimatology, Palaeoecology 228 (2005) 305319 309
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Sample Rho
(g cm3)CIAK Clayeynessd (Pbases/Al)d Salin.d Gleyd MAP MAT Bae Sr Y Nb Zr Rb
CV09 2.77 96.47 0.21 0.54 0.31 0.36 1479 11.5 449 98 33 24 120 280
30
31
32
28
32
31
29
31
33
32
28
27
30
34
34
21
MgO
Table 1 (continued)
N.D. Sheldon / Palaeogeography, Palaeoclimatology, Palaeoecology 228 (2005) 305319310CV10 2.74 96.84 0.21 0.51 0.
CV13 2.74 0.20 0.70 0.
CV16 2.64 0.15 1.37 0.
CV19 2.65 0.17 1.28 0.
CV22 2.76 0.18 6.26 0.
CV24 2.67 0.15 1.56 0.
CV25 2.58 0.13 2.52 0.
CV26 2.82 0.20 16.2 0.
CV27 2.74 96.68 0.21 0.54 0.
CV28 2.54 0.18 0.79 0.
CV29 2.70 96.95 0.20 0.46 0.
CV30 2.72 97.79 0.20 0.43 0.
CV31 2.60 0.13 1.58 0.
CV45 2.69 0.06 5.57 0.
CV46 2.75 0.12 2.08 0.
CV47 2.60 94.67 0.07 0.37 0.
a Reactive with dilute HCl.b Total iron as Fe2O3.c Refers to samples at the boundary between two horizons.d Molar ratios: clayeyness=(Al2O3 /SiO2);
Pbases /Al= (CaO+
tion=(FeO/Fe2O3).e All trace element compositions.have 1535% quartz and lithics, with an average of
about 20%. Many of the fluvial sediments, and two of
the paleosols, have non-calcareous sandy concretions
ranging in size from mm-scale (Fig. 4E) to decimeter
scale. Typically these are grey-green, fine- to medium-
grained sand in otherwise red sediments. Grey-green
color in iron-bearing paleosols is typically associated
with unoxidized iron. These apparent micro-reducing
conditions may be attributable to the former presence
of decaying organic matter, and may have been
formed in a fashion similar to the drab-haloed root
traces.
Bulk rock geochemical properties of fluvial rocks
may also be used to identify paleosols and to separate
paleosol orders (Sheldon et al., 2002). Net gains and
losses of different elements may be calculated by
examining the mobility of the element of interest
relative to some assumed immobile element (Chad-
Fig. 4. Field and petrographic photos. A) Outcrop photo of the Cala Viola N
the section (arrow). B) Outcrop photo showing the complex fluvial characte
the light colored vertical streaks are rhizoliths and drab-haloed root traces
horizon (arrow). E) mm-scale quartz concretion (sample CV-20). F) Root t
to into the A horizon of the underlying paleosol. G) Laterally discontinuo
ephemerally closer to the surface. H) Thin section of a root trace (sample0.28 1490 11.8 418 94 30 21 153 270
0.38 1081 125 27 25 147 260
0.84 951 92 36 19 237 184
2.97 959 113 42 19 301 196
1.52 537 87 43 10 93 94
1.03 2439 136 33 16 195 163
0.27 2434 142 41 12 306 124
0.22 9654 272 29 nd 31 40
0.24 1485 11.3 507 158 33 24 125 270
0.36 51,452 1017 22 nd 151 178
0.24 1493 12.0 3292 262 32 22 159 244
0.17 1518 12.3 367 179 47 21 173 241
0.31 34,767 688 30 9 269 95
0.79 275 73 34 20 202 79
0.34 303 107 32 22 390 138
1.37 1428 13.4 144 78 17 23 133 102
+Na2O+K2O) /Al2O3; salinization (Na2O+K2O) /Al2O3; gleiza-wick et al., 1990; e.g., Driese et al., 2000). Elements
that are typically considered as immobile during
weathering include Ti, Zr, Nb, Hf, and under some
pH conditions, Al. Ti, Zr, and Nb were considered and
Ti was selected both because it was immobile relative
to Zr and Nb and because it is the most abundant of
the three elements. The open system mass-transport
function for element j in the weathered sample (w)
is defined as follows (e.g., Chadwick et al., 1990):
sj;w qwCj;w
= qpCj;p
ei;w 1 1 1
where qw is the density of the weathered material,Cj,w is the chemical concentration (weight percentage)
of element j in the weathered material, qp is thedensity of the parent material, and Cj,p is the chemical
concentration (weight percentage) of element j in the
parent material. If sj,w=0 (i.e., element w was immo-
ord section; paleosols sit on top of the coarser, horizontal benches in
r of Verrucano Sardo Formation. C) Profile of a Cala Viola paleosol;
(arrows). D) Close-up of vertically oriented burrows in a paleosol A
races (arrow) deep in the C horizon of a paleosol, penetrating nearly
us ground water gleying (arrow) features where the water table was
CV-12).
-
N.D. Sheldon / Palaeogeography, Palaeoclimatology, Palaeoecology 228 (2005) 305319 311
-
limatoN.D. Sheldon / Palaeogeography, Palaeoc312bile), then ei,w can be solved for separately allowingus to bypass volume (as in the classical definition of
strain) as follows (e.g., Chadwick et al., 1990):
ei;w qpCj;p
= qwCj;w 1 2
where ei,w is the strain on immobile element i in theweathered sample. The parent materials for the profiles
were overbank mudstones and sandstones as appropri-
Fig. 5. Chemical degree of weathering. A) Ca and Sr loss in the type Macch
1 represents 100% loss of Ca relative to the parent material, and a tau vthe Cala Viola type profile showing greater Ca loss, consistent with a grea
more complicated changes, but are still consistent with a greater degree o
geochemistry (CIAK (Maynard, 1992) and clayeyness (molar ratio of alsignificant offset between values low in the profile and high in profile is evi
bbulgeQ consistent with the field identification of a Bt horizon.logy, Palaeoecology 228 (2005) 305319ate, with separate geochemical analyses for each of the
paleosol profiles (Table 1; lowermost C horizon anal-
yses). Fig. 6 shows the losses or gains of Ca and Sr
(which occupy the same sites in most minerals) in the
type Macchia and Cala Viola paleosols assuming Ti
was immobile during weathering (calculated following
Chadwick et al. (1990)). Although both pedotypes have
lost much of their Ca relative to their parent material,
the Cala Viola paleosol has clearly been more weath-
ia and Cala Viola paleosols assuming Ti is immobile. A tau value of
alue of 0 represents the parent material. Both paleosols lost Ca, with
ter degree of chemical weathering. Other elements such as Sr show
f chemical weathering in the type Cala Viola profile. B) Additional
umina to silica; Retallack, 1997)). of the type Cala Viola profile The
dence of intense chemical weathering. The clayeyness index shows a
-
Fig. 6. Gleization for the type profiles of the Cala Viola and Macchia p
(Fe3+) iron.
N.D. Sheldon / Palaeogeography, Palaeoclimatoered, a finding consistent with the field classification of
the paleosols (Table 2). Paleosols generally exhibit the
highest degree of chemical weathering within their A
and B horizons, with a decrease in weathering down
profile. Fig. 5B shows the chemical index of alteration
without potash (Maynard, 1992) for the type Cala Viola
paleosol. This pattern is consistent with pedogenesis
rather than fluvial sedimentation where one would
predict a more erratic variation from bed to bed, but
where most values would cluster around a btypicalQvalue for the whole sedimentary succession.
4.1. Pedotypes
Four pedotypes (sensu Retallack, 1994) were
identified and given names in Italian from their
field localities or reconstructed similarity to a given
environment.
4.1.1. Cala Viola (bviolet bayQ)The type Cala Viola paleosol crops out in the
northern Cala Viola section. Cala Viola paleosols areTable 2
Cala Viola pedotypes
Pedotype Diagnosis FAO USDA
Cala Viola Thick and red with clayey
subsurface (Bt) on alluvium
Luvisol Alfisol
Lago di
Baratz
Grey-green silty soil with
some relict bedding and no
diagnostic subsurface horizons
Fluvisol Entisol
Macchia Variable thickness red
sometimes with scattered
drab haloed root traces and
no subsurface Bt or Bk
Cambisol Inceptisol
Mosca
Pesca
Sandy, relict bedding,
without horizonation
Fluvisol Entisolcomparable to modern Alfisols (Soil Survey Staff,
1998) in the USDA soil classification scheme (Table
2). They are moderately developed (see Retallack
(1988) for definitions of the degree of development),
with no relict bedding, blocky peds, and subsurface Bt
or Bw horizons. Cala Viola profiles are typically A
BtC, and represent a fairly stable landscape (i.e.,
infrequently flooded; Table 3).
4.1.2. Lago di Baratz (bBaratzs lakeQ)The type Lago di Baratz paleosol crops out in the
Lago di Baratz section. Lago di Baratz paleosols are
comparable to modern Entisols (Soil Survey Staff,
1998) in the USDA soil classification scheme (Table
2). They are very weakly developed, with some relict
bedding and no diagnostic subsurface horizons. Lago
di Baratz profiles are AC and represent a frequently
disturbed landscape (i.e., flooded; Table 3).
4.1.3. Macchia (bunderbrushQ)The type Macchia paleosol crops out in the Lago di
Baratz section, and Macchia paleosols are found in
edotypes. Gleization is the molar ratio of ferrous (Fe2+) to ferric
logy, Palaeoecology 228 (2005) 305319 313both field areas. Macchia paleosols are comparable to
modern Inceptisols (Soil Survey Staff, 1998) in the
USDA soil classification scheme (Table 2). They are
weakly developed with little relict bedding or ped
structure. Macchia profiles are A(Bw)C and repre-
sent a fairly stable landscape (Table 3).
4.1.4. Mosca Pesca (bfly fishingQ)The type Mosca Pesca paleosol outcrops in the
Lago di Baratz section. Mosca Pesca paleosols are
comparable to modern Entisols (Soil Survey Staff,
1998) in the USDA soil classification scheme (Table
2). They are very weakly developed, preserve relict
bedding, lack ped structure, and lack diagnostic sub-
-
Viola preserve essentially no organic matter (b1%by volume in thin section point counts). Studies of
6. Paleoclimatic reconstruction
tation
ous
es th
limatoQuaternary (Stevenson, 1969) and older (Retallack,
2001b) paleosols have shown that buried paleosolssurface horizons. Mosca Pesca profiles are ACC and
represent a frequently disturbed landscape (Table 3).
5. Diagenesis
Paleosols typically undergo a number of diagenetic
changes including loss of organic matter, burial red-
dening due to dehydration of oxyhydroxides (e.g.,
conversion of goethite [Fe(OH)3] to hematite
[Fe2O3]), and compaction due to burial beneath an
overburden (Retallack, 1991b). Paleosols of the Cala
Table 3
Paleoenvironmental interpretation
Pedotype Paleoclimate Former vegetation
Cala Viola Humid (13001500 mm/yr)
temperate
Eutrophic forest
Lago di Baratz Insufficiently developed to
determine, but probably
humid
Stream-side early
successional woody
and herbaceous vege
Macchia Humid (13001500 mm/yr)
temperate
Eutrophic forest
Mosca Pesca Insufficiently developed to
determine
Stream-side early
successional herbace
vegetation
a Estimated semi-quantitatively after Retallack (1997) and referenc
N.D. Sheldon / Palaeogeography, Palaeoc314lose up to an order of magnitude of organic carbon
soon after burial in well-drained soils, whereas water-
logged (hydromorphic) or peaty paleosols show sig-
nificantly less to no loss of organic matter (Stevenson,
1969). Given their red color and low ferrous to ferric
ratios (see Fig. 6), much of the iron in these paleosols
has been oxidized, indicating at least a moderate
degree of aeration post-burial, and oxygen promotes
the breakdown of organic matter. This likely accounts
for the dearth of detectable organic matter.
Sheldon and Retallack (2001) showed that the
degree of compactibility varies according to the initial
physical properties of the soil. Regional stratigraphic
relationships indicate a burial depth of 24 km, so the
paleosols have been compacted to between 61.2% and
87.8% of their original thickness depending on burial
depth and soil order (see Sheldon and Retallack,A number of means have been devised to recon-
struct paleoclimate from paleosols. Retallack (1994)
has suggested that the depth to the Bk horizon can be
related to mean annual precipitation (see Royer (1999,
2000) and Retallack (2000) for discussion of this
approach). Although a couple of the Sardinian paleo-2001). Given that all of these paleosols are developed
on alluvium, an estimate based on inorganic flood-
plain silts and muds (see Sheldon and Retallack,
2001) of 78.686.4% of the original thickness is a
good first order generalization for the sedimentary
succession as a whole.
Paleotopography Parent material Timea
Negligible, but
well-drained siltstones
Alluvial sandstones,
and mud-stones
100010000 years
Negligible, but poorly
drained
Coarse sandstone 1005000 years
Negligible,
but moderately
to well-drained
Alluvial sandstones,
siltstones, and
mud-stones
5005000 years
Negligible Coarse sandstone b100 years
erein.
logy, Palaeoecology 228 (2005) 305319sols effervesce slightly when hydrochloric acid is
applied, there is nothing that would qualify Bk ho-
rizons (Soil Survey Staff, 1998). Royer (1999) sug-
gested that soil carbonate is absent in regions
receiving precipitation N760 mm per year, althoughthis value varies with seasonality and local evapo-
transpiration (Retallack, 2000; Royer, 2000). This
value for the western US may be applicable to the
Sardinian paleosols given their formation within a
continental interior montane basin.
A more quantitative approach is to compare the
precipitation regimes of modern soils with indices of
chemical weathering (Sheldon et al., 2002; Sheldon,
2003). Climatic transfer functions applied to a set of
paleosols spanning the EoceneOligocene boundary
produced results that were consistent with indepen-
dent estimates of mean annual precipitation and mean
-
annual temperature (Retallack et al., 2000; Sheldon et
al., 2002; Sheldon and Retallack, 2004). Although the
paleosols in this study are much older, bulk rock
geochemical data for the Sardinian paleosols can
also be used to reconstruct the paleoenvironmental
conditions under with they formed, because the pres-
ence of root traces, rhizoliths, and burrows indicates a
formerly vegetated landscape for which modern ana-
logues can be identified. Mean annual precipitation
can be related to the chemical index of alteration
without potash as follows (Sheldon et al., 2002):
MAP in mm 221:12e:0197 CIAK 3with an R2=0.72 where CIAK is 100 times themolar ratio of aluminum to aluminum, calcium, and
sodium (Maynard, 1992). Mean annual temperature
At the present time, soils forming under conditions
of N1200 mm/year mean annual precipitation and 1114 8C mean annual temperature are found in Mexicoon the eastern side of the Gulf of California, in the
United States on the eastern side of the Appalachians,
northern India, Greece, and southern Italy (FAO,
19711981). Given the proximity of the Sardinian
paleosols to the Hercynian chain and their low paleo-
latitude (10F5 degrees), northern India is probablythe best modern analogue. Such comparisons are im-
perfect modern analogues because PermoTriassic
CO2 levels far exceeded present levels (Berner and
Kothavala, 2001; Retallack, 2001c). Nevertheless, it is
clear that these soils did not form in desert conditions.
Could they have instead formed in a monsoonal
paleoenvironment?
N.D. Sheldon / Palaeogeography, Palaeoclimatology, Palaeoecology 228 (2005) 305319 315can be related to salinization (Retallack, 1997) where
MAT 8C 18:5 S 17:3 4with a somewhat low R2=0.37 (Sheldon et al.,
2002). As shown in Fig. 7, mean annual precipitation
increased slightly from 1300 mm/year to about 1500
mm/year, while mean annual temperature increased
slightly but held fairly steady at 1114 8C. Thatresult is consistent with the general lack of soil
carbonate. Two analyses (CV22 and CV25 on
Table 1) of Bt horizons are excluded from the anal-
ysis because of extremely low oxide totals owing to
high volatile contents (LOI on Table 1; 26.7 and
14.2%, respectively).Fig. 7. Paleoprecipitation and paleotemperature estimates using transfer fun
of Quaternary soils. The standard error on the precipitation estimate is F18Modern monsoonal environments are characterized
by extreme seasonal variation, with a pronounced dry
season or seasons, and a short, very wet season or
seasons. There are two main varieties, namely, wet
monsoons as in Southeast Asia, Indonesia, northeast-
ern Australia, and some of India, and dry monsoons as
in central Asia, parts of India, northwestern Australia,
the Arabian peninsula, and the southwestern United
States, however, there is a spectrum of conditions
between the main end-members. Soils forming under
dry monsoonal conditions are most often Vertisols,
Aridisols, and rarely, Mollisols (FAO, 19711981).
Soils forming under wet monsoonal conditions are
most often Ultisols or Vertisols (FAO, 19711981).ctions from regression of climatic data against chemical composition
2 mm and the standard error on the temperature estimate is F4.4 8C.
-
difference is in base saturation. Alfisols are base-rich
soils that typically have forest vegetation, while Ulti-
sols are base-poor forest soils. Because of this diffe-
rence, modern Alfisols and Ultisols are distinguished
on the basis of their base status (e.g., percentage base
saturation), which is not always recorded (or measur-
able) in paleosols. A statistically significant method of
differentiating Alfisols from Ultisols has been derived
for paleosols. The B horizons of Alfisols have molar
ratio of bases (CaO, Na2O, MgO, K2O) to alumina
(Al2O3) greater that 0.5, whereas the B horizons of
Ultisols have base / alumina ratios less than 0.5, typi-
cally much less (Sheldon et al., 2002). Fig. 8 shows
the base /alumina ratios of paleosols in the Cala Viola
section; most have base /alumina ratios greater than
0.5, thereby confirming the field diagnosis of these
paleosols as Inceptisol-like (Macchia) and Alfisol-like
(Cala Viola) rather than Ultisol-like. Only one of Cala
limatology, Palaeoecology 228 (2005) 305319Only the Cala Viola and Macchia pedotypes are
sufficiently developed to use in comparisons with
modern environments. Both pedotypes developed
on areas of little or no topographic relief, had similar
parent material, and indicate similar paleoclimatic
conditions (Table 3). The primary differences were
formation time and vegetative covering (Table 3),
though it could be argued that Cala Viola pedotypes
represent later stage succession of Macchia pedo-
types, however there is not sufficient evidence to
conclude this robustly.
A dry monsoon is considered first. In Vertisols,
large precipitation differences or seasonal soil mois-
ture deficits between wet and dry seasons change the
physical volume of smectite clay minerals in soils.
During the wet season, clays swell with the addi-
Table 4
Paleoclimates compared
Features Desert Wet
monsoon
Dry
monsoon
Cala viola
Salts Yes No No No
CaCO3 nodules Yes No Yes No
MAP (13001500 mm) No Yes Maybe Yes
MAT (11148) No Maybe Maybe YesSoil Types Aridisols Ultisols Vertisols Alfisols
Vertisols Aridisols Inceptisols
Mollisols Entisols
Layered
Fe(OH)3CaCO3
No Yes Yes No
Mukkara/gilgai
gilgai
No Yes Yes No
N.D. Sheldon / Palaeogeography, Palaeoc316tional water. In the dry season, the clays lose the
water that they have gained and the parting between
layers shrinks. These shrink-swell cycles lead to
deep cracks in the soil. The behavior of the clay
minerals and colloids also gives rise to mukkara
structure and gilgai microrelief that readily distin-
guishes Vertisols (Coulombe et al., 1996; Coulombe,
1997; Retallack, 1997; Driese et al., 2000, 2003).
None of these features (deep vertical to sub-vertical
cracks, mukkara structure, gilgai microrelief) are
present in any of the Sardinian paleosols (Table 4).
Nor do the Sardinian paleosols have pedogenic cal-
crete and salts of Aridisols, or the abundant crumb
peds, organic matter, and fine root traces of Molli-
sols (Table 4).
Wet monsoons are characterized by Vertisols and
Ultisols. Ultisols are similar to Alfisols; the primaryViola paleosols plots within the Ultisols field, though
others are bnear-Ultic,Q perhaps indicating some weakmonsoonal influence (Fig. 8).
Retallack (1991a) studied Miocene monsoonal
paleosols and soils of Pakistan and found that they
typically have concretions (rather than nodules) of
hematite, calcite, or interlayered calcite and hematite,
and diffuse carbonate in small nodules throughout the
profile, including the A horizon. There is essentially
no carbonate in the Sardinian paleosols and the rare
Fig. 8. Molar ratio of total bases to alumina for Cala Viola paleosols.Only one Cala Viola paleosol (at 24.9 m) plots within the Ultiso
field, though others are bnear-Ultic.Q
l
-
of these paleosols appears to be primarily related to
the hydrological conditions in which they formed.
diagnostic. Paleoclimatic reconstruction of Late Perm-
ian paleosols on the basis of the degree of chemical
Retallack, and this version has benefited from two
anonymous reviews and a review by Lee Nordt.
limatoobserved nodules are unlayered, and silica- or iron-
oxyhydroxide cemented. There are no nodules or
concretions consistent with a monsoonal paleoclimate.
Taken together, these various lines of evidence sug-
gest that the Sardinian paleosols were not subject to a
strongly monsoonal paleoclimate, either wet or dry
(Table 4).
Although the Lago di Baratz and Mosca Pesca
paleosols of the Lago di Baratz section show little
significant reddening, the Macchia and Cala Viola
paleosols of both the Lago di Baratz and Cala Viola
sections are both characterized by very red color.
Intensity of color and degree of clay remobilization
are two-fold indicators of development, and can be
supported with chemical and petrographic data. Degree
of drainage also plays a role in soil color and can be
inferred from the degree of chemical gleization (molar
ratio of Fe2+ /Fe3+), soil redoximorphic features (e.g.,
reduction spots, grey/green paleosols with red mot-
tles), and trace fossils of organisms requiring oxygen
(animal burrows and root traces). The red paleosol
types (Macchia and Cala Viola) are characterized by
low gleization ratios (e.g., Fig. 6) and nearly uniform
red color, with the exception of rare drab-haloed root
traces. Drab-haloed root traces are commonly created
by micro-reducing conditions, which occur around
decaying organic matter shortly after burial (Retal-
lack, 1991b), and as such, would be unrelated to the
past water table depth. There are no other soil re-
doximorphic features (iron-manganese nodules, ferric
nodules) and the deeply penetrating root traces and
burrows (Fig. 4CD) indicate good drainage as does
the degree of chemical weathering and clay illuviation
into subsurface horizons. The root traces are drab
from the inside out, as in surface water gley, rather
than groundwater gley, yet there is no high density or
impermeable layer within the paleosols that would
perch the water table.
The sequence, as a whole, goes from weakly de-
veloped grey paleosols to more strongly developed
red paleosols, which is consistent with a dropping
base level or increased distance from a stream
(Kraus, 1999), and has no evidence significant paleo-
topography (Table 3). The Cala Viola Nord section of
red paleosols is capped by a thick, areally extensive
conglomerate with centimeter-sized, well-rounded
N.D. Sheldon / Palaeogeography, Palaeoccobbles that may represent a sequence boundary be-
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N.D. Sheldon / Palaeogeography, Palaeoclimatology, Palaeoecology 228 (2005) 305319 319
Do red beds indicate paleoclimatic conditions?: A Permian case studyIntroductionGeologic contextMethodsEvidence of pedogenesisPedotypesCala Viola (violet bay)Lago di Baratz (Baratz's lake)Mcchia (underbrush)Mosca Pesca (fly fishing)
DiagenesisPaleoclimatic reconstructionConclusionsAcknowledgementsReferences