red bed paleoclimate.pdf

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Do red beds indicate paleoclimatic conditions?: A Permian case study Nathan D. Sheldon * Department of Geology, Royal Holloway University of London, Egham, Surrey TW20 0EX, United Kingdom Received 27 September 2004; received in revised form 25 February 2005; accepted 16 June 2005 Abstract Terrestrial red beds have long been interpreted as desert deposits by comparison with modern red deserts. More recently red beds have been interpreted as evidence of seasonally dry conditions and a Permo–Triassic Pangean monsoon. Red beds of Cala Viola, Sardinia are identified as paleosols and used to reconstruct Late Permian paleoclimatic conditions. Reconstruction of paleoenvironmental conditions based on the paleosols of the Cala Viola indicates warm, humid conditions with no evidence of dry conditions, as in a desert, or of extreme seasonality as in a monsoon. Instead, it is suggested that the red color of the paleosols is a result of former good drainage, and that red color in general does not indicate specific paleoclimatic conditions. D 2005 Elsevier B.V. All rights reserved. Keywords: Permian; Sardinia; Paleosols; Paleoclimate; Monsoon 1. Introduction A long held dogma is that widespread Triassic terrestrial red beds indicate a global transition to warm- er and drier conditions than those that characterized the Permian (Parrish, 1995). This new climatic system has been termed the Pangean mega-monsoon (Kutzbach and Gallimore, 1989). The question to be addressed herein is whether red color alone is sufficient evidence upon which to base paleoclimatic interpretations. Early research on modern red deserts supported the interpretation that ancient red beds formed in hot, dry climates (Walker, 1976). However, modern red deserts of Arizona and Australia are red because of sediments recycled from paleosols of Triassic and Miocene age, respectively, and most deserts of North and South America, Asia, and the Middle East are grey like their weathering source rocks. Further, many red soils in semi-arid areas such as New Mexico derived their red color from well-drained, warm conditions during Pleistocene pluvials, so the red color is relict and related to earlier paleoenvironmental conditions. More recently, Parrish (1998, p. 192) stated that ter- restrial red beds, b...appear to be indicative of cli- mates that are warm and dry or seasonal with respect to rainfall.Q A model put forth by Dubiel and Smoot (1994) suggests that continental red bed formation is 0031-0182/$ - see front matter D 2005 Elsevier B.V. All rights reserved. doi:10.1016/j.palaeo.2005.06.009 * Tel.: +44 1784 443615. E-mail address: [email protected]. Palaeogeography, Palaeoclimatology, Palaeoecology 228 (2005) 305– 319 www.elsevier.com/locate/palaeo

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    upon which to base paleoclimatic interpretations.

    Early research on modern red deserts supported the

    and related to earlier paleoenvironmental conditions.

    More recently, Parrish (1998, p. 192) stated that ter-

    restrial red beds, b. . .appear to be indicative of cli-

    Palaeogeography, Palaeoclimatology, Palaeoeinterpretation that ancient red beds formed in hot, dry1. Introduction

    A long held dogma is that widespread Triassic

    terrestrial red beds indicate a global transition to warm-

    er and drier conditions than those that characterized the

    Permian (Parrish, 1995). This new climatic system has

    been termed the Pangean mega-monsoon (Kutzbach

    and Gallimore, 1989). The question to be addressed

    herein is whether red color alone is sufficient evidence

    climates (Walker, 1976). However, modern red deserts

    of Arizona and Australia are red because of sediments

    recycled from paleosols of Triassic and Miocene age,

    respectively, and most deserts of North and South

    America, Asia, and the Middle East are grey like

    their weathering source rocks. Further, many red

    soils in semi-arid areas such as New Mexico derived

    their red color from well-drained, warm conditions

    during Pleistocene pluvials, so the red color is relictAbstract

    Terrestrial red beds have long been interpreted as desert deposits by comparison with modern red deserts. More recently red

    beds have been interpreted as evidence of seasonally dry conditions and a PermoTriassic Pangean monsoon. Red beds of Cala

    Viola, Sardinia are identified as paleosols and used to reconstruct Late Permian paleoclimatic conditions. Reconstruction of

    paleoenvironmental conditions based on the paleosols of the Cala Viola indicates warm, humid conditions with no evidence of

    dry conditions, as in a desert, or of extreme seasonality as in a monsoon. Instead, it is suggested that the red color of the

    paleosols is a result of former good drainage, and that red color in general does not indicate specific paleoclimatic conditions.

    D 2005 Elsevier B.V. All rights reserved.

    Keywords: Permian; Sardinia; Paleosols; Paleoclimate; MonsoonDo red beds indicate p

    A Permian

    Nathan D

    Department of Geology, Royal Holloway University

    Received 27 September 2004; received in revis0031-0182/$ - see front matter D 2005 Elsevier B.V. All rights reserved.

    doi:10.1016/j.palaeo.2005.06.009

    * Tel.: +44 1784 443615.

    E-mail address: [email protected] conditions?:

    ase study

    heldon*

    ndon, Egham, Surrey TW20 0EX, United Kingdom

    rm 25 February 2005; accepted 16 June 2005

    cology 228 (2005) 305319

    www.elsevier.com/locate/palaeoeasonal with respectmates that are warm and dry or sto rainfall.Q A model put forth by Dubiel and Smoot(1994) suggests that continental red bed formation is

  • favored by warm climates with alternating wet-and-

    dry seasons (monsoons) and open, desert to savanna

    vegetation. However, it is not an exact analog because

    a true savanna requires grasslands, which did not

    evolve until the Cenozoic (Retallack, 2001a; Terry,

    2001). Monsoonal tropical Pakistan and India include

    both grey and red soils and paleosols (Retallack,

    1991a). Wynn (2000) and Wynn and Retallack

    (2001) describe reconstructed savanna ecosystems

    from Cenozoic paleosols in Africa that are not signi-

    ficantly reddened. Furthermore, numerous examples

    have been published of diagenetic reddening of non-

    desert paleosols by dehydration of iron oxyhydroxides

    (Retallack, 1991a, 1997, 2001b; see also the review of

    older literature in Blodgett et al., 1993).

    Taken together, these various factors suggest that

    the origin of red color may not be well-understood or

    well-explained by existing models. Work presented

    here on Late Permian red beds in Sardinia offers an

    alternative explanation to pronounced aridity or sea-

    sonality. It is suggested that the red color is indicative

    of well-drained conditions and that it provides no

    unequivocal information on the paleoclimatic condi-

    tions at the time of paleosol formation. Instead, paleo-

    climatic conditions are reconstructed on the basis of

    other proxies, such as the degree of chemical weath-

    ering, nature and extent of pedogenic carbonate and

    salts, and patterns of root traces and trace fossils.

    2. Geologic context

    Basin-and-Range topography was a result of the

    CarboniferousPermian Hercynian orogeny from eastern

    Europe to the southern coast of the United States

    (Cortesogno et al., 1998). Collision of South Europe

    with North America and Africa during the Late De-

    vonian and Carboniferous (Condie, 1989) was fol-

    lowed, through Triassic time, by local rifting and

    formation of continental basins in Spain, Southern

    n for

    f the

    N.D. Sheldon / Palaeogeography, Palaeoclimatology, Palaeoecology 228 (2005) 305319306Fig. 1. Map showing the location of field sites and stratigraphic colum

    sample numbers, and Munsell colour of the sample is to the right oMosca Pesca and Lago di Baratz paleosols and the overlying Macchia pale

    X) rather than at the first logged Macchia Rossa paleosol.the Lago di Baratz section, Verrucano Sardo Formation. LB01-15 are

    sample number. The exact transition between the lesser developedosols is unknown and may lie in the covered interval (shown with an

  • Fig. 2. Stratigraphic column for the Cala Viola Nord section

    Verrucano Sardo Formation. Symbols and conventions are as in

    Fig. 1. Asterisks next to sample numbers indicate samples that were

    weakly reactive to dilute acid. The thicknesses of the conglomerate

    that caps the Cala Viola Nord and Sud sections are variable, so the

    average thickness is portrayed. Where multiple lithologies are

    shown, there is significant variability along strike and additiona

    limatology, Palaeoecology 228 (2005) 305319 307France, Italy, Corsica, and Sardinia (Cassinis and

    Ronchi, 1997). These basins were filled with clastic

    red beds derived from the orogenic belt.

    In Sardinia, those sediments are part of the Verru-

    cano Sardo Formation exposed on the Cala Viola

    (bviolet bayQ) (Fig. 1), and are divided it into fourinformal units (Gasperi and Gelmini, 1979). The red

    beds described in this paper are from bUnit 2,Q a 150m package of sediments composed of sandy conglom-

    erates, grey sandstones, and red sandstones and mud-

    stones. The Cala Viola Nord section is capped by a

    thick, quartz cobble conglomerate that is also exposed

    near the base of the Cala Viola Sud section (Fig. 1).

    The rocks exhibit fluvial paleochannels, tetrapod foot-

    prints, and fossil plants indicating subaerial deposition

    on alluvial fans and floodplains. Gasperi and Gelmini

    (1979) examined the limited available fossil assem-

    blages and found Autunian (Early Permian) non-ma-

    rine strata near the base of the sequence and Triassic

    red claystones and sandstones near the top [Units 3

    and 4], overlain by Middle Triassic (AnisianEarly

    Ladinian) limestone (Cassinis and Ronchi, 1997; Cas-

    sinis et al., 1992). The red beds described here are

    located near the top of the sequence (top of Unit 2),

    and are thus Late Permian in age (Cassinis et al.,

    1992).

    The Lago di Baratz area (Fig. 1) is well vegetated

    and exposure is generally poor. Three of the four

    pedotypes are exposed in this section (Fig. 1), includ-

    ing the Lago di Baratz and Mosca Pesca pedotypes,

    which are not preserved in either of the Cala Viola

    sections. In contrast, the Cala Viola sections, with

    localized gentle folding, are well-exposed in sea cliffs

    and rock platforms, and are continuous and conform-

    able with significant lateral variability difficult to

    capture adequately in single stratigraphic sections

    (Figs. 2 and 3). The Lago di Baratz section lies

    stratigraphically below the Cala Viola sections by an

    unknown thickness of mudstones and sandstones in

    Unit 2 of Gasperi and Gelmini (1979). However,

    given that only the middle and upper portions of

    Unit 2 are red and the lower portion is primarily

    grey, it is possible that the red Macchia paleosols of

    the Lago di Baratz section (Fig. 1) represent the first

    red beds. If this is the case, given the 7585 m

    exposed in the Cala Viola sections (Figs. 2 and 3)

    N.D. Sheldon / Palaeogeography, Palaeocand a total thickness of 150 m for Unit 2 (Gasperi and

    Gelmini, 1979), there can be no more than a few tenssymbols apply to the right column, which represents the dominan

    lithology.,

    lt

  • limatoN.D. Sheldon / Palaeogeography, Palaeoc308of meters between the top of the Lago di Baratz

    section and the bottom of the Cala Viola Nord section.

    3. Methods

    Paleosols were recognized in the field on the basis

    of ped morphology, horizonation, root traces, and

    and in contrast to the fluvially-derived sandstones

    (Fig. 4B). Many of the paleosols also preserve drab-

    Fig. 3. Stratigraphic column for the Cala Viola Sud section, Verru-

    cano Sardo Formation. Symbols and conventions are as in Fig. 1.

    See Fig. 2 caption for additional information.haloed root traces (Fig. 4C,F) and rarely, vertical

    burrows (Fig. 4C,D). Burrows range up to one cm

    in diameter and show some internal structure consis-

    tent with backfilling by an arthropod. Non-calcareous

    rhizoliths are well-preserved in some of the paleosols,

    both in hand specimen and thin section (Fig. 4H).

    Both root traces and burrows penetrate deeply into

    paleosol profiles (Fig. 4C), indicating that the paleo-

    water table was substantially below the surface. Point

    counts of thin sections (e.g., Fig. 4E,H) are consistent

    with the field observation that paleosols are more fine-

    grained than interfluve sandstones, siltstones, and

    mudstones. Some of the Cala Viola paleosols have

    an observed clay bulge (Fig. 5) and illuviation argil-

    lans observable in thin section consistent with subsur-

    face accumulation of clay in a Bt horizon. A and B

    horizons of paleosols have 8097% clay and phyllo-

    silicate minerals and 320% quartz and lithics (includ-grain size changes (Retallack, 1997). Munsell color

    was recorded as well as the qualitative degree of

    calcareousness on the basis of reaction with dilute

    hydrochloric acid (Retallack, 1997). Samples were

    collected for petrography and geochemical analysis

    from three sites north of Alghero, near Lago di Baratz

    and at two localities on the Cala Viola (Fig. 1).

    Geochemical data were obtained from a commercial

    laboratory (Intertek of Vancouver, B.C.) using XRF,

    ICP-MS, and titration (FeO) and are compiled in

    Table 1. Paleosols were classified into pedotypes

    (Retallack, 1997; Retallack, 2001b) on the basis of

    physical and chemical characteristics (Sheldon and

    Retallack, 2001; Sheldon et al., 2002), and analyzed

    using the factor function approach (Jenny, 1941).

    Bulk density (q) was measured by the clod methodusing paraffin; analysis of 10 replicates of a single

    sample gave an uncertainty of 0.09 g cm3.

    4. Evidence of pedogenesis

    Paleosols in the Cala Viola sections fine up-profile

    and are notably finer grained than the succession as a

    whole (Figs. 2 and 3). This difference shows up in the

    weathering profile of the sections as well (Fig. 4A)

    logy, Palaeoecology 228 (2005) 305319ing feldspars) with an average of less than 10%,

    whereas C horizons and other fluvial sediments all

  • Table 1

    Geochemical data

    Sample Level

    (m)

    Reacta Horizon SiO2 TiO2 Al2O3 Feb FeO Fe2O3 MnO MgO CaO Na2O K2O P2O5 LOI Total

    LB02 3.6 N 77.98 0.37 12.64 1.80 0.45 1.30 0.02 0.27 0.07 n/a 1.85 0.07 4.03 99.1

    LB03 4.4 N A/Bwc 78.63 0.30 9.62 4.81 0.39 4.37 0.03 0.21 0.08 n/a 0.97 0.12 4.16 99.3

    LB04A 5.9 N C 66.80 0.70 14.89 7.30 0.51 6.73 0.05 0.60 0.16 0.10 2.75 0.15 5.79 99.8

    LB04B 6.0 N C 70.08 0.81 17.22 1.68 0.45 1.19 0.01 0.74 0.09 0.19 3.40 0.05 5.31 100.0

    LB04C 6.2 N A/Bw 69.27 0.84 17.08 1.73 0.51 1.16 0.02 0.66 0.06 0.20 3.56 0.05 5.08 99.1

    LB04D 6.4 N A 67.22 0.70 15.35 6.52 0.58 5.88 0.05 0.59 0.09 0.08 2.88 0.11 5.66 99.8

    LB11 13.0 N C 75.11 0.52 14.21 2.83 0.45 2.33 0.03 0.62 0.11 0.03 2.48 0.07 4.29 100.8

    LB12 13.2 N C 66.15 0.72 16.84 5.58 0.71 4.79 0.02 1.14 0.12 0.14 3.95 0.08 4.99 100.4

    LB13 13.5 N C 61.17 0.80 18.76 6.54 0.71 5.75 0.02 1.40 0.08 0.17 4.82 0.06 5.27 99.8

    LB14 13.7 N Bw 62.34 0.79 18.84 5.15 0.90 4.15 0.02 1.30 0.10 0.21 4.69 0.06 5.93 100.3

    LB15 13.9 N A 61.20 0.78 18.63 7.02 0.64 6.31 0.02 1.32 0.08 0.15 4.70 0.08 5.30 99.9

    CV03 1.7 N Bw 58.00 0.92 19.18 6.61 0.84 5.68 0.05 1.81 0.90 0.16 5.22 0.06 6.67 100.4

    CV06 4.2 N 56.05 0.84 16.17 6.06 1.61 4.27 0.13 2.60 3.50 0.23 4.05 0.07 9.78 101.1

    CV07 5.5 N C 48.79 0.72 16.40 6.19 0.71 5.40 0.46 4.30 5.26 0.22 4.41 0.09 12.5 100.0

    CV08 5.8 N Bt 54.82 0.87 19.81 6.40 1.03 5.26 0.07 2.21 1.50 0.17 5.47 0.12 7.92 100.4

    CV09 6.1 N Bt 56.93 0.91 20.65 6.49 0.90 5.49 0.02 1.67 0.28 0.15 5.72 0.12 6.27 100.1

    CV10 6.5 N A 57.71 0.91 20.21 6.98 0.77 6.12 0.02 1.57 0.20 0.18 5.27 0.08 6.12 100.0

    CV13 10.1 N 56.05 0.91 19.22 6.32 0.90 5.32 0.07 2.00 1.31 0.16 5.30 0.08 7.39 99.7

    CV16 12.4 N C 55.56 0.78 14.59 6.55 1.74 4.62 0.18 3.03 4.20 0.32 3.79 0.04 10.7 101.4

    CV19 14.1 Y C 56.24 0.86 16.04 3.47 1.87 1.40 0.17 3.12 4.47 0.18 3.87 0.09 11.1 101.5

    CV22 17.2 Y Bt 30.48 0.47 9.25 3.30 1.03 1.51 0.91 10.6 15.5 0.29 2.26 0.06 26.7 100.8

    CV24 19.15 N C 56.12 0.59 13.94 4.64 1.42 3.07 0.18 3.27 5.08 0.26 3.58 0.05 11.4 100.5

    CV25 19.85 N Bt 51.90 0.63 11.69 4.83 0.51 4.26 0.34 4.77 7.67 0.19 2.89 0.07 14.2 99.7

    CV26 20.65 Y A 14.89 0.25 4.99 2.98 0.26 2.69 0.91 15.1 22.6 0.22 1.10 0.07 35.4 98.8

    CV27 22.05 Y Bt 56.94 0.89 19.69 7.98 0.77 7.12 0.02 1.44 0.29 0.09 5.79 0.14 5.82 99.9

    CV28 23.2 N C 53.35 0.83 15.45 5.58 0.77 4.72 0.06 1.50 1.90 0.22 4.24 0.09 6.61 90.6

    CV29 24.2 N Bt 59.56 0.89 19.87 6.59 0.64 5.88 0.03 1.24 0.19 0.17 4.95 0.12 5.43 99.7

    CV30 24.9 N Bt 57.89 0.93 20.01 8.35 0.58 7.71 0.03 1.20 0.14 0.12 4.77 0.11 5.75 99.9

    CV31 26.15 N 55.13 0.61 11.67 4.29 0.51 3.72 0.15 1.18 6.57 0.56 2.41 0.05 11.5 94.6

    CV45 46.5 N C 58.99 0.40 6.22 1.26 0.32 0.90 0.12 6.17 9.31 0.25 1.57 0.03 14.5 99.1

    CV46 48.0 N BC 58.65 0.71 12.04 3.43 0.45 2.93 0.09 4.28 5.56 0.59 2.85 0.04 9.89 98.6

    CV47 49.25 N Bw 83.50 0.26 8.57 1.23 0.45 0.73 0.01 0.28 0.22 0.05 1.57 0.03 2.75 99.0

    Sample Rho

    (g cm3)CIAK Clayeynessd (Pbases/Al)d Salin.d Gleyd MAP MAT Bae Sr Y Nb Zr Rb

    LB02 2.52 0.095 0.22 0.16 0.77 132 66 25 28 164 112

    LB03 2.39 98.51 0.07 0.18 0.11 0.198 1540 15.3 76 36 18 18 141 72

    LB04A 2.58 0.13 0.33 0.21 0.17 351 92 31 21 257 137

    LB04B 2.49 0.15 0.35 0.23 0.84 362 127 42 28 312 194

    LB04C 2.50 97.49 0.15 0.35 0.24 0.98 1509 12.8 377 116 37 22 281 180

    LB04D 2.55 98.11 0.13 0.32 0.21 0.22 1528 13.4 293 95 29 22 260 151

    LB11 2.59 0.11 0.32 0.19 0.43 208 61 23 22 229 159

    LB12 2.59 0.15 0.45 0.27 0.33 358 107 36 28 280 240

    LB13 2.64 0.18 0.49 0.29 0.27 423 121 34 21 215 292

    LB14 2.53 97.28 0.18 0.47 0.29 0.48 1503 12.0 405 123 33 28 229 293

    LB15 2.54 97.94 0.18 0.47 0.29 0.23 1522 12.0 398 128 38 23 225 276

    CV03 2.71 90.99 0.195 0.63 0.31 0.33 1328 11.6 622 117 37 23 171 266

    CV06 2.70 0.17 1.095 0.29 0.84 1636 134 34 21 284 195

    CV07 2.71 0.20 1.56 0.31 0.29 544 122 34 16 144 210

    CV08 2.81 86.82 0.21 0.73 0.31 0.44 1223 11.5 998 105 30 22 114 262

    (continued on next page)

    N.D. Sheldon / Palaeogeography, Palaeoclimatology, Palaeoecology 228 (2005) 305319 309

  • Sample Rho

    (g cm3)CIAK Clayeynessd (Pbases/Al)d Salin.d Gleyd MAP MAT Bae Sr Y Nb Zr Rb

    CV09 2.77 96.47 0.21 0.54 0.31 0.36 1479 11.5 449 98 33 24 120 280

    30

    31

    32

    28

    32

    31

    29

    31

    33

    32

    28

    27

    30

    34

    34

    21

    MgO

    Table 1 (continued)

    N.D. Sheldon / Palaeogeography, Palaeoclimatology, Palaeoecology 228 (2005) 305319310CV10 2.74 96.84 0.21 0.51 0.

    CV13 2.74 0.20 0.70 0.

    CV16 2.64 0.15 1.37 0.

    CV19 2.65 0.17 1.28 0.

    CV22 2.76 0.18 6.26 0.

    CV24 2.67 0.15 1.56 0.

    CV25 2.58 0.13 2.52 0.

    CV26 2.82 0.20 16.2 0.

    CV27 2.74 96.68 0.21 0.54 0.

    CV28 2.54 0.18 0.79 0.

    CV29 2.70 96.95 0.20 0.46 0.

    CV30 2.72 97.79 0.20 0.43 0.

    CV31 2.60 0.13 1.58 0.

    CV45 2.69 0.06 5.57 0.

    CV46 2.75 0.12 2.08 0.

    CV47 2.60 94.67 0.07 0.37 0.

    a Reactive with dilute HCl.b Total iron as Fe2O3.c Refers to samples at the boundary between two horizons.d Molar ratios: clayeyness=(Al2O3 /SiO2);

    Pbases /Al= (CaO+

    tion=(FeO/Fe2O3).e All trace element compositions.have 1535% quartz and lithics, with an average of

    about 20%. Many of the fluvial sediments, and two of

    the paleosols, have non-calcareous sandy concretions

    ranging in size from mm-scale (Fig. 4E) to decimeter

    scale. Typically these are grey-green, fine- to medium-

    grained sand in otherwise red sediments. Grey-green

    color in iron-bearing paleosols is typically associated

    with unoxidized iron. These apparent micro-reducing

    conditions may be attributable to the former presence

    of decaying organic matter, and may have been

    formed in a fashion similar to the drab-haloed root

    traces.

    Bulk rock geochemical properties of fluvial rocks

    may also be used to identify paleosols and to separate

    paleosol orders (Sheldon et al., 2002). Net gains and

    losses of different elements may be calculated by

    examining the mobility of the element of interest

    relative to some assumed immobile element (Chad-

    Fig. 4. Field and petrographic photos. A) Outcrop photo of the Cala Viola N

    the section (arrow). B) Outcrop photo showing the complex fluvial characte

    the light colored vertical streaks are rhizoliths and drab-haloed root traces

    horizon (arrow). E) mm-scale quartz concretion (sample CV-20). F) Root t

    to into the A horizon of the underlying paleosol. G) Laterally discontinuo

    ephemerally closer to the surface. H) Thin section of a root trace (sample0.28 1490 11.8 418 94 30 21 153 270

    0.38 1081 125 27 25 147 260

    0.84 951 92 36 19 237 184

    2.97 959 113 42 19 301 196

    1.52 537 87 43 10 93 94

    1.03 2439 136 33 16 195 163

    0.27 2434 142 41 12 306 124

    0.22 9654 272 29 nd 31 40

    0.24 1485 11.3 507 158 33 24 125 270

    0.36 51,452 1017 22 nd 151 178

    0.24 1493 12.0 3292 262 32 22 159 244

    0.17 1518 12.3 367 179 47 21 173 241

    0.31 34,767 688 30 9 269 95

    0.79 275 73 34 20 202 79

    0.34 303 107 32 22 390 138

    1.37 1428 13.4 144 78 17 23 133 102

    +Na2O+K2O) /Al2O3; salinization (Na2O+K2O) /Al2O3; gleiza-wick et al., 1990; e.g., Driese et al., 2000). Elements

    that are typically considered as immobile during

    weathering include Ti, Zr, Nb, Hf, and under some

    pH conditions, Al. Ti, Zr, and Nb were considered and

    Ti was selected both because it was immobile relative

    to Zr and Nb and because it is the most abundant of

    the three elements. The open system mass-transport

    function for element j in the weathered sample (w)

    is defined as follows (e.g., Chadwick et al., 1990):

    sj;w qwCj;w

    = qpCj;p

    ei;w 1 1 1

    where qw is the density of the weathered material,Cj,w is the chemical concentration (weight percentage)

    of element j in the weathered material, qp is thedensity of the parent material, and Cj,p is the chemical

    concentration (weight percentage) of element j in the

    parent material. If sj,w=0 (i.e., element w was immo-

    ord section; paleosols sit on top of the coarser, horizontal benches in

    r of Verrucano Sardo Formation. C) Profile of a Cala Viola paleosol;

    (arrows). D) Close-up of vertically oriented burrows in a paleosol A

    races (arrow) deep in the C horizon of a paleosol, penetrating nearly

    us ground water gleying (arrow) features where the water table was

    CV-12).

  • N.D. Sheldon / Palaeogeography, Palaeoclimatology, Palaeoecology 228 (2005) 305319 311

  • limatoN.D. Sheldon / Palaeogeography, Palaeoc312bile), then ei,w can be solved for separately allowingus to bypass volume (as in the classical definition of

    strain) as follows (e.g., Chadwick et al., 1990):

    ei;w qpCj;p

    = qwCj;w 1 2

    where ei,w is the strain on immobile element i in theweathered sample. The parent materials for the profiles

    were overbank mudstones and sandstones as appropri-

    Fig. 5. Chemical degree of weathering. A) Ca and Sr loss in the type Macch

    1 represents 100% loss of Ca relative to the parent material, and a tau vthe Cala Viola type profile showing greater Ca loss, consistent with a grea

    more complicated changes, but are still consistent with a greater degree o

    geochemistry (CIAK (Maynard, 1992) and clayeyness (molar ratio of alsignificant offset between values low in the profile and high in profile is evi

    bbulgeQ consistent with the field identification of a Bt horizon.logy, Palaeoecology 228 (2005) 305319ate, with separate geochemical analyses for each of the

    paleosol profiles (Table 1; lowermost C horizon anal-

    yses). Fig. 6 shows the losses or gains of Ca and Sr

    (which occupy the same sites in most minerals) in the

    type Macchia and Cala Viola paleosols assuming Ti

    was immobile during weathering (calculated following

    Chadwick et al. (1990)). Although both pedotypes have

    lost much of their Ca relative to their parent material,

    the Cala Viola paleosol has clearly been more weath-

    ia and Cala Viola paleosols assuming Ti is immobile. A tau value of

    alue of 0 represents the parent material. Both paleosols lost Ca, with

    ter degree of chemical weathering. Other elements such as Sr show

    f chemical weathering in the type Cala Viola profile. B) Additional

    umina to silica; Retallack, 1997)). of the type Cala Viola profile The

    dence of intense chemical weathering. The clayeyness index shows a

  • Fig. 6. Gleization for the type profiles of the Cala Viola and Macchia p

    (Fe3+) iron.

    N.D. Sheldon / Palaeogeography, Palaeoclimatoered, a finding consistent with the field classification of

    the paleosols (Table 2). Paleosols generally exhibit the

    highest degree of chemical weathering within their A

    and B horizons, with a decrease in weathering down

    profile. Fig. 5B shows the chemical index of alteration

    without potash (Maynard, 1992) for the type Cala Viola

    paleosol. This pattern is consistent with pedogenesis

    rather than fluvial sedimentation where one would

    predict a more erratic variation from bed to bed, but

    where most values would cluster around a btypicalQvalue for the whole sedimentary succession.

    4.1. Pedotypes

    Four pedotypes (sensu Retallack, 1994) were

    identified and given names in Italian from their

    field localities or reconstructed similarity to a given

    environment.

    4.1.1. Cala Viola (bviolet bayQ)The type Cala Viola paleosol crops out in the

    northern Cala Viola section. Cala Viola paleosols areTable 2

    Cala Viola pedotypes

    Pedotype Diagnosis FAO USDA

    Cala Viola Thick and red with clayey

    subsurface (Bt) on alluvium

    Luvisol Alfisol

    Lago di

    Baratz

    Grey-green silty soil with

    some relict bedding and no

    diagnostic subsurface horizons

    Fluvisol Entisol

    Macchia Variable thickness red

    sometimes with scattered

    drab haloed root traces and

    no subsurface Bt or Bk

    Cambisol Inceptisol

    Mosca

    Pesca

    Sandy, relict bedding,

    without horizonation

    Fluvisol Entisolcomparable to modern Alfisols (Soil Survey Staff,

    1998) in the USDA soil classification scheme (Table

    2). They are moderately developed (see Retallack

    (1988) for definitions of the degree of development),

    with no relict bedding, blocky peds, and subsurface Bt

    or Bw horizons. Cala Viola profiles are typically A

    BtC, and represent a fairly stable landscape (i.e.,

    infrequently flooded; Table 3).

    4.1.2. Lago di Baratz (bBaratzs lakeQ)The type Lago di Baratz paleosol crops out in the

    Lago di Baratz section. Lago di Baratz paleosols are

    comparable to modern Entisols (Soil Survey Staff,

    1998) in the USDA soil classification scheme (Table

    2). They are very weakly developed, with some relict

    bedding and no diagnostic subsurface horizons. Lago

    di Baratz profiles are AC and represent a frequently

    disturbed landscape (i.e., flooded; Table 3).

    4.1.3. Macchia (bunderbrushQ)The type Macchia paleosol crops out in the Lago di

    Baratz section, and Macchia paleosols are found in

    edotypes. Gleization is the molar ratio of ferrous (Fe2+) to ferric

    logy, Palaeoecology 228 (2005) 305319 313both field areas. Macchia paleosols are comparable to

    modern Inceptisols (Soil Survey Staff, 1998) in the

    USDA soil classification scheme (Table 2). They are

    weakly developed with little relict bedding or ped

    structure. Macchia profiles are A(Bw)C and repre-

    sent a fairly stable landscape (Table 3).

    4.1.4. Mosca Pesca (bfly fishingQ)The type Mosca Pesca paleosol outcrops in the

    Lago di Baratz section. Mosca Pesca paleosols are

    comparable to modern Entisols (Soil Survey Staff,

    1998) in the USDA soil classification scheme (Table

    2). They are very weakly developed, preserve relict

    bedding, lack ped structure, and lack diagnostic sub-

  • Viola preserve essentially no organic matter (b1%by volume in thin section point counts). Studies of

    6. Paleoclimatic reconstruction

    tation

    ous

    es th

    limatoQuaternary (Stevenson, 1969) and older (Retallack,

    2001b) paleosols have shown that buried paleosolssurface horizons. Mosca Pesca profiles are ACC and

    represent a frequently disturbed landscape (Table 3).

    5. Diagenesis

    Paleosols typically undergo a number of diagenetic

    changes including loss of organic matter, burial red-

    dening due to dehydration of oxyhydroxides (e.g.,

    conversion of goethite [Fe(OH)3] to hematite

    [Fe2O3]), and compaction due to burial beneath an

    overburden (Retallack, 1991b). Paleosols of the Cala

    Table 3

    Paleoenvironmental interpretation

    Pedotype Paleoclimate Former vegetation

    Cala Viola Humid (13001500 mm/yr)

    temperate

    Eutrophic forest

    Lago di Baratz Insufficiently developed to

    determine, but probably

    humid

    Stream-side early

    successional woody

    and herbaceous vege

    Macchia Humid (13001500 mm/yr)

    temperate

    Eutrophic forest

    Mosca Pesca Insufficiently developed to

    determine

    Stream-side early

    successional herbace

    vegetation

    a Estimated semi-quantitatively after Retallack (1997) and referenc

    N.D. Sheldon / Palaeogeography, Palaeoc314lose up to an order of magnitude of organic carbon

    soon after burial in well-drained soils, whereas water-

    logged (hydromorphic) or peaty paleosols show sig-

    nificantly less to no loss of organic matter (Stevenson,

    1969). Given their red color and low ferrous to ferric

    ratios (see Fig. 6), much of the iron in these paleosols

    has been oxidized, indicating at least a moderate

    degree of aeration post-burial, and oxygen promotes

    the breakdown of organic matter. This likely accounts

    for the dearth of detectable organic matter.

    Sheldon and Retallack (2001) showed that the

    degree of compactibility varies according to the initial

    physical properties of the soil. Regional stratigraphic

    relationships indicate a burial depth of 24 km, so the

    paleosols have been compacted to between 61.2% and

    87.8% of their original thickness depending on burial

    depth and soil order (see Sheldon and Retallack,A number of means have been devised to recon-

    struct paleoclimate from paleosols. Retallack (1994)

    has suggested that the depth to the Bk horizon can be

    related to mean annual precipitation (see Royer (1999,

    2000) and Retallack (2000) for discussion of this

    approach). Although a couple of the Sardinian paleo-2001). Given that all of these paleosols are developed

    on alluvium, an estimate based on inorganic flood-

    plain silts and muds (see Sheldon and Retallack,

    2001) of 78.686.4% of the original thickness is a

    good first order generalization for the sedimentary

    succession as a whole.

    Paleotopography Parent material Timea

    Negligible, but

    well-drained siltstones

    Alluvial sandstones,

    and mud-stones

    100010000 years

    Negligible, but poorly

    drained

    Coarse sandstone 1005000 years

    Negligible,

    but moderately

    to well-drained

    Alluvial sandstones,

    siltstones, and

    mud-stones

    5005000 years

    Negligible Coarse sandstone b100 years

    erein.

    logy, Palaeoecology 228 (2005) 305319sols effervesce slightly when hydrochloric acid is

    applied, there is nothing that would qualify Bk ho-

    rizons (Soil Survey Staff, 1998). Royer (1999) sug-

    gested that soil carbonate is absent in regions

    receiving precipitation N760 mm per year, althoughthis value varies with seasonality and local evapo-

    transpiration (Retallack, 2000; Royer, 2000). This

    value for the western US may be applicable to the

    Sardinian paleosols given their formation within a

    continental interior montane basin.

    A more quantitative approach is to compare the

    precipitation regimes of modern soils with indices of

    chemical weathering (Sheldon et al., 2002; Sheldon,

    2003). Climatic transfer functions applied to a set of

    paleosols spanning the EoceneOligocene boundary

    produced results that were consistent with indepen-

    dent estimates of mean annual precipitation and mean

  • annual temperature (Retallack et al., 2000; Sheldon et

    al., 2002; Sheldon and Retallack, 2004). Although the

    paleosols in this study are much older, bulk rock

    geochemical data for the Sardinian paleosols can

    also be used to reconstruct the paleoenvironmental

    conditions under with they formed, because the pres-

    ence of root traces, rhizoliths, and burrows indicates a

    formerly vegetated landscape for which modern ana-

    logues can be identified. Mean annual precipitation

    can be related to the chemical index of alteration

    without potash as follows (Sheldon et al., 2002):

    MAP in mm 221:12e:0197 CIAK 3with an R2=0.72 where CIAK is 100 times themolar ratio of aluminum to aluminum, calcium, and

    sodium (Maynard, 1992). Mean annual temperature

    At the present time, soils forming under conditions

    of N1200 mm/year mean annual precipitation and 1114 8C mean annual temperature are found in Mexicoon the eastern side of the Gulf of California, in the

    United States on the eastern side of the Appalachians,

    northern India, Greece, and southern Italy (FAO,

    19711981). Given the proximity of the Sardinian

    paleosols to the Hercynian chain and their low paleo-

    latitude (10F5 degrees), northern India is probablythe best modern analogue. Such comparisons are im-

    perfect modern analogues because PermoTriassic

    CO2 levels far exceeded present levels (Berner and

    Kothavala, 2001; Retallack, 2001c). Nevertheless, it is

    clear that these soils did not form in desert conditions.

    Could they have instead formed in a monsoonal

    paleoenvironment?

    N.D. Sheldon / Palaeogeography, Palaeoclimatology, Palaeoecology 228 (2005) 305319 315can be related to salinization (Retallack, 1997) where

    MAT 8C 18:5 S 17:3 4with a somewhat low R2=0.37 (Sheldon et al.,

    2002). As shown in Fig. 7, mean annual precipitation

    increased slightly from 1300 mm/year to about 1500

    mm/year, while mean annual temperature increased

    slightly but held fairly steady at 1114 8C. Thatresult is consistent with the general lack of soil

    carbonate. Two analyses (CV22 and CV25 on

    Table 1) of Bt horizons are excluded from the anal-

    ysis because of extremely low oxide totals owing to

    high volatile contents (LOI on Table 1; 26.7 and

    14.2%, respectively).Fig. 7. Paleoprecipitation and paleotemperature estimates using transfer fun

    of Quaternary soils. The standard error on the precipitation estimate is F18Modern monsoonal environments are characterized

    by extreme seasonal variation, with a pronounced dry

    season or seasons, and a short, very wet season or

    seasons. There are two main varieties, namely, wet

    monsoons as in Southeast Asia, Indonesia, northeast-

    ern Australia, and some of India, and dry monsoons as

    in central Asia, parts of India, northwestern Australia,

    the Arabian peninsula, and the southwestern United

    States, however, there is a spectrum of conditions

    between the main end-members. Soils forming under

    dry monsoonal conditions are most often Vertisols,

    Aridisols, and rarely, Mollisols (FAO, 19711981).

    Soils forming under wet monsoonal conditions are

    most often Ultisols or Vertisols (FAO, 19711981).ctions from regression of climatic data against chemical composition

    2 mm and the standard error on the temperature estimate is F4.4 8C.

  • difference is in base saturation. Alfisols are base-rich

    soils that typically have forest vegetation, while Ulti-

    sols are base-poor forest soils. Because of this diffe-

    rence, modern Alfisols and Ultisols are distinguished

    on the basis of their base status (e.g., percentage base

    saturation), which is not always recorded (or measur-

    able) in paleosols. A statistically significant method of

    differentiating Alfisols from Ultisols has been derived

    for paleosols. The B horizons of Alfisols have molar

    ratio of bases (CaO, Na2O, MgO, K2O) to alumina

    (Al2O3) greater that 0.5, whereas the B horizons of

    Ultisols have base / alumina ratios less than 0.5, typi-

    cally much less (Sheldon et al., 2002). Fig. 8 shows

    the base /alumina ratios of paleosols in the Cala Viola

    section; most have base /alumina ratios greater than

    0.5, thereby confirming the field diagnosis of these

    paleosols as Inceptisol-like (Macchia) and Alfisol-like

    (Cala Viola) rather than Ultisol-like. Only one of Cala

    limatology, Palaeoecology 228 (2005) 305319Only the Cala Viola and Macchia pedotypes are

    sufficiently developed to use in comparisons with

    modern environments. Both pedotypes developed

    on areas of little or no topographic relief, had similar

    parent material, and indicate similar paleoclimatic

    conditions (Table 3). The primary differences were

    formation time and vegetative covering (Table 3),

    though it could be argued that Cala Viola pedotypes

    represent later stage succession of Macchia pedo-

    types, however there is not sufficient evidence to

    conclude this robustly.

    A dry monsoon is considered first. In Vertisols,

    large precipitation differences or seasonal soil mois-

    ture deficits between wet and dry seasons change the

    physical volume of smectite clay minerals in soils.

    During the wet season, clays swell with the addi-

    Table 4

    Paleoclimates compared

    Features Desert Wet

    monsoon

    Dry

    monsoon

    Cala viola

    Salts Yes No No No

    CaCO3 nodules Yes No Yes No

    MAP (13001500 mm) No Yes Maybe Yes

    MAT (11148) No Maybe Maybe YesSoil Types Aridisols Ultisols Vertisols Alfisols

    Vertisols Aridisols Inceptisols

    Mollisols Entisols

    Layered

    Fe(OH)3CaCO3

    No Yes Yes No

    Mukkara/gilgai

    gilgai

    No Yes Yes No

    N.D. Sheldon / Palaeogeography, Palaeoc316tional water. In the dry season, the clays lose the

    water that they have gained and the parting between

    layers shrinks. These shrink-swell cycles lead to

    deep cracks in the soil. The behavior of the clay

    minerals and colloids also gives rise to mukkara

    structure and gilgai microrelief that readily distin-

    guishes Vertisols (Coulombe et al., 1996; Coulombe,

    1997; Retallack, 1997; Driese et al., 2000, 2003).

    None of these features (deep vertical to sub-vertical

    cracks, mukkara structure, gilgai microrelief) are

    present in any of the Sardinian paleosols (Table 4).

    Nor do the Sardinian paleosols have pedogenic cal-

    crete and salts of Aridisols, or the abundant crumb

    peds, organic matter, and fine root traces of Molli-

    sols (Table 4).

    Wet monsoons are characterized by Vertisols and

    Ultisols. Ultisols are similar to Alfisols; the primaryViola paleosols plots within the Ultisols field, though

    others are bnear-Ultic,Q perhaps indicating some weakmonsoonal influence (Fig. 8).

    Retallack (1991a) studied Miocene monsoonal

    paleosols and soils of Pakistan and found that they

    typically have concretions (rather than nodules) of

    hematite, calcite, or interlayered calcite and hematite,

    and diffuse carbonate in small nodules throughout the

    profile, including the A horizon. There is essentially

    no carbonate in the Sardinian paleosols and the rare

    Fig. 8. Molar ratio of total bases to alumina for Cala Viola paleosols.Only one Cala Viola paleosol (at 24.9 m) plots within the Ultiso

    field, though others are bnear-Ultic.Q

    l

  • of these paleosols appears to be primarily related to

    the hydrological conditions in which they formed.

    diagnostic. Paleoclimatic reconstruction of Late Perm-

    ian paleosols on the basis of the degree of chemical

    Retallack, and this version has benefited from two

    anonymous reviews and a review by Lee Nordt.

    limatoobserved nodules are unlayered, and silica- or iron-

    oxyhydroxide cemented. There are no nodules or

    concretions consistent with a monsoonal paleoclimate.

    Taken together, these various lines of evidence sug-

    gest that the Sardinian paleosols were not subject to a

    strongly monsoonal paleoclimate, either wet or dry

    (Table 4).

    Although the Lago di Baratz and Mosca Pesca

    paleosols of the Lago di Baratz section show little

    significant reddening, the Macchia and Cala Viola

    paleosols of both the Lago di Baratz and Cala Viola

    sections are both characterized by very red color.

    Intensity of color and degree of clay remobilization

    are two-fold indicators of development, and can be

    supported with chemical and petrographic data. Degree

    of drainage also plays a role in soil color and can be

    inferred from the degree of chemical gleization (molar

    ratio of Fe2+ /Fe3+), soil redoximorphic features (e.g.,

    reduction spots, grey/green paleosols with red mot-

    tles), and trace fossils of organisms requiring oxygen

    (animal burrows and root traces). The red paleosol

    types (Macchia and Cala Viola) are characterized by

    low gleization ratios (e.g., Fig. 6) and nearly uniform

    red color, with the exception of rare drab-haloed root

    traces. Drab-haloed root traces are commonly created

    by micro-reducing conditions, which occur around

    decaying organic matter shortly after burial (Retal-

    lack, 1991b), and as such, would be unrelated to the

    past water table depth. There are no other soil re-

    doximorphic features (iron-manganese nodules, ferric

    nodules) and the deeply penetrating root traces and

    burrows (Fig. 4CD) indicate good drainage as does

    the degree of chemical weathering and clay illuviation

    into subsurface horizons. The root traces are drab

    from the inside out, as in surface water gley, rather

    than groundwater gley, yet there is no high density or

    impermeable layer within the paleosols that would

    perch the water table.

    The sequence, as a whole, goes from weakly de-

    veloped grey paleosols to more strongly developed

    red paleosols, which is consistent with a dropping

    base level or increased distance from a stream

    (Kraus, 1999), and has no evidence significant paleo-

    topography (Table 3). The Cala Viola Nord section of

    red paleosols is capped by a thick, areally extensive

    conglomerate with centimeter-sized, well-rounded

    N.D. Sheldon / Palaeogeography, Palaeoccobbles that may represent a sequence boundary be-

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    Do red beds indicate paleoclimatic conditions?: A Permian case studyIntroductionGeologic contextMethodsEvidence of pedogenesisPedotypesCala Viola (violet bay)Lago di Baratz (Baratz's lake)Mcchia (underbrush)Mosca Pesca (fly fishing)

    DiagenesisPaleoclimatic reconstructionConclusionsAcknowledgementsReferences