reclassifying chemical relics of the cold war

1
government & policy Reclassifying chemical relics of the Cold War Among the detritus of the Cold War are tens of thousands of chemical agent identification sets (CAIS) that the Army used from 1928 to 1969 to train soldiers to defend themselves against chemical weapons attacks. These kits now need to be destroyed. How to do so—a prob- lem complicated by technical, legal, en- vironmental, and societal issues—is the gist of a recent National Research Coun- cil study called for by Congress. Most of the approximately 10,000 kits—more are expected to surface as Army bases close—contain glass vials of small quantities of the blister agents sulfur mustard (C1CH 2 CH 2 SCH 2 CH 2 C1) and lewisite (Cl 2 AsCHCHCl). The Army has classified the kits as chemical war- fare matériel, which precludes their dis- posal at commercial hazardous waste fa- cilities. Because they are considered nonstockpile matériel, the Army, by law, is not allowed to incinerate them at the eight U.S. installations slated to de- stroy the nation's arsenal of chemical weapons. The Army's solution, which it docu- mented in a report to Congress, is to employ what it dubs the Rapid Re- sponse System (RRS). This system is a mobile trailer unit that incompletely neutralizes a chemical agent. The Army then has to treat the remaining waste, usually via incineration. RRS is now un- dergoing testing. The NRC committee has recom- mended that the Army rethink its classi- fication of CAIS as chemical warfare ma- tériel. If the Army determines that it cannot reclassify CAIS, then it should go to Congress and ask for legislation that will allow CAIS to be regulated as hazardous waste under the Resource Conservation & Recovery Act. The En- vironmental Protection Agency has evaluated CAIS chemicals and has con- cluded that they may be treated as haz- ardous waste under RCRA. Reclassification, the committee con- cludes, would substantially reduce transportation and disposal costs and in- crease the likelihood and feasibility of New Intermediates! 6-Mercapto-l -hexanol PhCH 2 0 Methyl 2-(n-Hexyl]acetoocetate Useful for Aq and Pharma CF3CH2CH2CH2CI 4-Chloro-1,1,1 -trifluorobutane CF3CH2CH2CH2I 4-lodo-1,1,1 -trifluorobutane CF3CH2CH2CI 3-Chloro-l, 1, 1-trifluoropropane CF3CH2CH2Br 3-Bromo-1,1,1 -trifluoropropane CF3CH2NH2 2,2,2-Trifluoroethylamine ΒΛ/ SO 2 CI 5-Bromothiophene-2- sulfonyl Chloride Ο II CF 3 CH 2 0 - S - C F 3 II ο 2,2,2-Trifluoroethyl triflate A global resource for custom chemistry & process development Davos Chemical Corporation • 464 Hudson Terr. • Englewood Cliffs, NJ 07632 (201) 569-2200 • FAX (201) 569-2201 • E-Mail: [email protected] • Website: www.davos.com CIRCLE 11 ON READER SERVICE CARD CAIS disposal. Worker and public safety would not be compromised. Chemical warfare agents in the kits are present in such small quantities that they are likely to pose less risk than do the much larger volumes of sometimes highly toxic industrial chemicals now being treated by the chemical industry and commercial hazardous waste treat- ment plants, the committee concludes. But the committee adds that the Army still needs to do a more complete risk assessment to document the anticipated safety of disposing of the kits. Earlier, the Army had estimated that commercial incineration of the kits would cost substantially less than if it disposed of them. But the NRC committee found several problems with the Army's esti- mates and called for a more comprehen- sive cost analysis. And because of strong public opposition to incineration, the committee also urged the Army to con- sider other disposal options at either commercial or Army facilities. In those states with a chemical weap- ons disposal facility, the Army should en- gage the public in discussions of CAIS disposal options, including the possible use of the stockpile incineration facility for the destruction of the kits. If an affect- ed community agrees to the use of the fa- cility for kit disposal, the Army should in- volve the community thoroughly in estab- lishing specific conditions for the kits' destruction. Such community acquies- cence may be more likely at the two U.S. sites that will employ neutralization rath- er than incineration as the destruction technology, the committee says. Even with community agreement, the Army would still have to get Congress to amend the law prohibiting the use of the eight stockpile destruction facilities from destroying material other than chemical weapons, the committee emphasizes. Few commercial firms may be willing to take on the Army's business even if fur- ther analyses find the commercial route to be the disposal avenue of choice, the committee warns. The amount of busi- ness would be relatively small, the firms may have to add equipment to handle ar- senic-based lewisite, and public outrage over the disposal of chemical warfare ma- tériel may ward off commercial takers. Robert Jones, a spokesman for the Army's Non-Stockpile Program, tells C&EN that his group has just "received the NRC report and has not had the op- portunity to review it in its entirety to provide a quality comment." Lois Ember ffAVff 2,3,5-Tri-0-benzyl-l-0-{4-nitrobenzoyl) -D-arabinofuranoside 44 JANUARY 17,2000 C&EN

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Page 1: Reclassifying chemical relics of the Cold War

g o v e r n m e n t & p o l i c y

Reclassifying chemical relics of the Cold War Among the detritus of the Cold War are tens of thousands of chemical agent identification sets (CAIS) that the Army used from 1928 to 1969 to train soldiers to defend themselves against chemical weapons attacks. These kits now need to be destroyed. How to do so—a prob­lem complicated by technical, legal, en­vironmental, and societal issues—is the gist of a recent National Research Coun­cil study called for by Congress.

Most of the approximately 10,000 kits—more are expected to surface as Army bases close—contain glass vials of small quantities of the blister agents sulfur mustard (C1CH2CH2SCH2CH2C1) and lewisite (Cl2AsCHCHCl). The Army has classified the kits as chemical war­fare matériel, which precludes their dis­posal at commercial hazardous waste fa­cilities. Because they are considered nonstockpile matériel, the Army, by law, is not allowed to incinerate them at the eight U.S. installations slated to de­

stroy the nation's arsenal of chemical weapons.

The Army's solution, which it docu­mented in a report to Congress, is to employ what it dubs the Rapid Re­sponse System (RRS). This system is a mobile trailer unit that incompletely neutralizes a chemical agent. The Army then has to treat the remaining waste, usually via incineration. RRS is now un­dergoing testing.

The NRC committee has recom­mended that the Army rethink its classi­fication of CAIS as chemical warfare ma­tériel. If the Army determines that it cannot reclassify CAIS, then it should go to Congress and ask for legislation that will allow CAIS to be regulated as hazardous waste under the Resource Conservation & Recovery Act. The En­vironmental Protection Agency has evaluated CAIS chemicals and has con­cluded that they may be treated as haz­ardous waste under RCRA.

Reclassification, the committee con­cludes, would substantially reduce transportation and disposal costs and in­crease the likelihood and feasibility of

New Intermediates! 6-Mercapto-l -hexanol

P h C H 2 0

Methyl 2-(n-Hexyl]acetoocetate

Useful fo r A q a n d P h a r m a

CF3CH2CH2CH2CI 4-Chloro-1,1,1 -trifluorobutane

CF3CH2CH2CH2I 4-lodo-1,1,1 -trifluorobutane

CF3CH2CH2CI 3-Chloro-l, 1, 1-trifluoropropane

CF3CH2CH2Br 3-Bromo-1,1,1 -trifluoropropane

CF3CH2NH2 2,2,2-Trifluoroethylamine

ΒΛ/ SO2CI 5-Bromothiophene-2-

sulfonyl Chloride

Ο II

C F 3 C H 2 0 - S - CF 3

II ο

2,2,2-Trifluoroethyl triflate

A global resource for custom chemistry

& process development

Davos Chemical Corporation • 464 Hudson Terr. • Englewood Cliffs, NJ 07632 (201) 569-2200 • FAX (201) 569-2201 • E-Mail: [email protected] • Website: www.davos.com

CIRCLE 11 ON READER SERVICE CARD

CAIS disposal. Worker and public safety would not be compromised.

Chemical warfare agents in the kits are present in such small quantities that they are likely to pose less risk than do the much larger volumes of sometimes highly toxic industrial chemicals now being treated by the chemical industry and commercial hazardous waste treat­ment plants, the committee concludes. But the committee adds that the Army still needs to do a more complete risk assessment to document the anticipated safety of disposing of the kits.

Earlier, the Army had estimated that commercial incineration of the kits would cost substantially less than if it disposed of them. But the NRC committee found several problems with the Army's esti­mates and called for a more comprehen­sive cost analysis. And because of strong public opposition to incineration, the committee also urged the Army to con­sider other disposal options at either commercial or Army facilities.

In those states with a chemical weap­ons disposal facility, the Army should en­gage the public in discussions of CAIS disposal options, including the possible use of the stockpile incineration facility for the destruction of the kits. If an affect­ed community agrees to the use of the fa­cility for kit disposal, the Army should in­volve the community thoroughly in estab­lishing specific conditions for the kits' destruction. Such community acquies­cence may be more likely at the two U.S. sites that will employ neutralization rath­er than incineration as the destruction technology, the committee says.

Even with community agreement, the Army would still have to get Congress to amend the law prohibiting the use of the eight stockpile destruction facilities from destroying material other than chemical weapons, the committee emphasizes.

Few commercial firms may be willing to take on the Army's business even if fur­ther analyses find the commercial route to be the disposal avenue of choice, the committee warns. The amount of busi­ness would be relatively small, the firms may have to add equipment to handle ar­senic-based lewisite, and public outrage over the disposal of chemical warfare ma­tériel may ward off commercial takers.

Robert Jones, a spokesman for the Army's Non-Stockpile Program, tells C&EN that his group has just "received the NRC report and has not had the op­portunity to review it in its entirety to provide a quality comment."

Lois Ember

ffAVff

2,3,5-Tri-0-benzyl-l-0-{4-nitrobenzoyl) -D-arabinofuranoside

4 4 JANUARY 17,2000 C&EN