rec’d digitally by caroline rieger at 10:51 am, feb 13, 2019 · ftn no. r04469-1767-001 dear ms....

341
5LHJHU &DUROLQH 7R .LOEXUQ 'LDQQD 6XEMHFW 5( &UDLJKHDG &RXQW\ /HJDF\ &ODVV /DQGILOO 3HUPLW 1R 65 6HFRQG KDOI JURXQGZDWHU PRQLWRULQJ UHSRUW QRWLFH RI 66,V )URP 0HOLVVD 9DXJKW >PDLOWRPPY#IWQDVVRFFRP@ 6HQW 7XHVGD\ )HEUXDU\ 30 7R .LOEXUQ 'LDQQD &F 'DQD 'HUULQJWRQ UKHQGUL[#FFVZGDFRP DQJHOD#FFVZGDFRP 6XEMHFW &UDLJKHDG &RXQW\ /HJDF\ &ODVV /DQGILOO 3HUPLW 1R 65 6HFRQG KDOI JURXQGZDWHU PRQLWRULQJ UHSRUW QRWLFH RI 66,V ŝĂŶŶĂ ʹ 'ŽŽĚ ĂĨƚĞƌŶŽŽŶ KŶ ďĞŚĂůĨ ŽĨ ƚŚĞ ƌĂŝŐŚĞĂĚ ŽƵŶƚLJ >ĞŐĂĐLJ >ĂŶĚĨŝůů &dE ŚĂƐ ƉƌĞƉĂƌĞĚ ƚŚĞ ĂƚƚĂĐŚĞĚ ƐĞĐŽŶĚ ŚĂůĨ ϮϬϭϴ ŐƌŽƵŶĚǁĂƚĞƌ ƌĞƉŽƌƚ ĂŶĚ ŶŽƚŝĐĞ ŽĨ ƐƚĂƚŝƐƚŝĐĂůůLJ ƐŝŐŶŝĨŝĐĂŶƚ ŝŶĐƌĞĂƐĞƐ ĨŽƌ ƚŚĞ ůĂŶĚĨŝůů WůĞĂƐĞ ĐŽŶƚĂĐƚ ĂŶĂ ĞƌƌŝŶŐƚŽŶ Žƌ ŵĞ ŝĨ LJŽƵ ŚĂǀĞ ĂŶLJ ƋƵĞƐƚŝŽŶƐ ǁŝƚŚ ƚŚŝƐ ƐƵďŵŝƚƚĂů dŚĂŶŬ LJŽƵ DĞůŝƐƐĂ sĂƵŐŚƚ WΎ &dE ƐƐŽĐŝĂƚĞƐ ŶǀŝƌŽŶŵĞŶƚĂů ŶŐŝŶĞĞƌ ϭϮϰ t ^ƵŶďƌŝĚŐĞ ƌŝǀĞ ^ƵŝƚĞ ηϯ &ĂLJĞƚƚĞǀŝůůĞ ƌŬĂŶƐĂƐ ϳϮϳϬϯ KĨĨŝĐĞ ;ϰϳϵͿ ϱϳϭͲϯϯϯϰ &Ădž ;ϰϳϵͿ ϱϳϭͲϯϯϯϴ ΎƌŬĂŶƐĂƐ ĂŶĚ KŬůĂŚŽŵĂ Rec’d Digitally AFIN:_________________________ PMT#:_________________________ S W DOC ID#:______________________ M D TO:___________________________ By Caroline Rieger at 10:51 am, Feb 13, 2019 16-00199 0254-S1-R4 DK>File <CR 75546

Upload: others

Post on 27-Jul-2020

0 views

Category:

Documents


0 download

TRANSCRIPT

Page 1: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Rec’d Digitally

AFIN:_________________________

PMT#:_________________________S

W DOC ID#:______________________ M

DTO:___________________________

By Caroline Rieger at 10:51 am, Feb 13, 2019

16-00199

0254-S1-R4

DK>File <CR

75546

Page 2: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Regional Offices: Fayetteville, Arkansas; Baton Rouge, Louisiana; Chesterfield, Mo • www.ftn-assoc.com • [email protected]

February 12, 2019

Ms. Dianna Kilburn

Groundwater Branch Manager

Assessment and Remediation

Office of Land Resources

Arkansas Department of Environmental Quality

5301 Northshore Drive

North Little Rock, AR 72118-5317

RE: Submittal of Second Half 2018 Groundwater Monitoring Report and Notice of Statistically

Significant Increases,

Craighead County Legacy Class 1 Landfill, Jonesboro, Arkansas,

Permit No. 0254-S1-R4, AFIN: 16-00199

FTN No. R04469-1767-001

Dear Ms. Kilburn:

On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates, Ltd. is pleased to

submit the second half 2018 groundwater monitoring report for the Craighead County Legacy Class 1

Landfill.

FTN is also submitting the attached notice of statistically significant increases to satisfy the notification

requirements of Arkansas Pollution Control and Ecology Commission (APCEC) Regulation No. 22,

§22.1204(c).

If you have any questions regarding the submittal of this report, please do not hesitate to contact me

at (314) 786-5855 or Melissa Vaught, PE at (479) 571-3334.

Respectfully submitted,

FTN ASSOCIATES, LTD.

Dana Derrington, PE, PG

Project Manager

DLD/kae

Enclosure

CC: Mr. Robert Hendrix; Craighead County Solid Waste Disposal Authority (with enclosure)

Ms. Angela Sparks; Craighead County Solid Waste Disposal Authority (with enclosure)

R:\WP_FILES\04469-1767-001\CORRESPONDENCE\2019-02-12 L-D KILBURN 2H2018 GWMR AND NOTICE OF SSIS\2019-02-12 L-D KILBURN.DOCX

Page 3: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

NOTICE OF STATISTICALLY SIGNIFICANT EXCEEDANCES

SECOND HALF 2018 GROUNDWATER DETECTION MONITORING

CRAIGHEAD COUNTY SOLID WASTE DISPOSAL AUTHORITY

LEGACY CLASS 1 LANDFILL

JONESBORO, ARKANSAS

PERMIT NO. 0254-S1-R4, AFIN 16-00199

An intrawell prediction limit evaluation of the second half of 2018 identified a confirmed

statistically significant increase for chloride at upgradient MW-14R.

A Mann-Kendall/Sen’s Slope test for trends of the second half of 2018 data identified a

statistically significant increasing trend for iron at upgradient MW-14R.

Page 4: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

SECOND HALF 2018 SEMIANNUAL

GROUNDWATER MONITORING REPORT CRAIGHEAD COUNTY

LEGACY CLASS 1 LANDFILL JONESBORO, ARKANSAS

PERMIT NO. 0254-S1-R4

AFIN: 16-00199

FEBRUARY 12, 2019

Page 5: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

SECOND HALF 2018 SEMIANNUAL GROUNDWATER MONITORING REPORT

CRAIGHEAD COUNTY LEGACY CLASS 1 LANDFILL

JONESBORO, ARKANSAS PERMIT NO. 0254-S1-R4

AFIN: 16-00199

Prepared for

Craighead County Solid Waste Disposal Authority Craighead County Landfill

238 County Road 476 Jonesboro, AR 72404

Prepared by

FTN Associates, Ltd. 3 Innwood Circle, Suite 220

Little Rock, AR 72211

FTN No. R04469-1767-001

February 12, 2019

Page 6: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 7: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

February 12, 2019

ii

TABLE OF CONTENTS

PROFESSIONAL GEOLOGIST’S CERTIFICATION .................................................................. i

1.0 INTRODUCTION ........................................................................................................... 1-1

2.0 GROUNDWATER MONITORING PROGRAM ........................................................... 2-1

2.1 Monitoring Well System ...................................................................................... 2-1

2.2 Sampling Schedule............................................................................................... 2-3

2.3 Sampling Methodology ........................................................................................ 2-4

2.4 Laboratory Analyses ............................................................................................ 2-4

3.0 WATER LEVEL DATA.................................................................................................. 3-1

3.1 Water Level Measurements and Groundwater Flow Direction ........................... 3-1

3.2 Hydraulic Gradient and Rate of Groundwater Flow ............................................ 3-3

4.0 GROUNDWATER QUALITY DATA ........................................................................... 4-1

4.1 Review of Laboratory Quality Control Samples ................................................. 4-1

4.2 Review of Field Quality Control Samples ........................................................... 4-1

4.3 Review of Field Documentation .......................................................................... 4-2

4.4 Summary of Groundwater Quality Results .......................................................... 4-2

5.0 STATISTICAL EVALUATION ..................................................................................... 5-1

5.1 Statistical Program Design ................................................................................... 5-1

5.2 Site-Wide False Positive Rate and Power ............................................................ 5-2

5.3 Statistical Evaluation Results ............................................................................... 5-3

5.3.1 Outlier Identification ................................................................................ 5-4

5.3.2 Prediction Limit Evaluation ..................................................................... 5-4

5.3.3 Mann-Kendall Test/Sen’s Estimate of Slope Evaluation ......................... 5-5

5.3.4 Notifications of Statistically Significant Results ..................................... 5-6

6.0 CONCLUSIONS.............................................................................................................. 6-1

7.0 SELECTED REFERENCES ........................................................................................... 7-1

Page 8: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

February 12, 2019

TABLE OF CONTENTS (CONTINUED)

iii

LIST OF APPENDICES

APPENDIX A: Field Sampling Forms APPENDIX B: Laboratory Data APPENDIX C: Historical Database APPENDIX D: Background Used for Statistics APPENDIX E: Distributional Plots APPENDIX F: Statistical Evaluation Results

LIST OF TABLES

Table 2.1 Monitoring well construction data ....................................................................... 2-3 Table 2.2 Constituents for detection monitoring ................................................................. 2-5 Table 3.1 Water level data and potentiometric surface elevations,

November 9, 2018 ................................................................................................ 3-1 Table 4.1 Groundwater quality, second half of 2018 ........................................................... 4-4 Table 5.1 Per-test alpha and power curve criteria, 2018 semiannual detection

monitoring ............................................................................................................ 5-2

Table 5.2 SSI based on prediction limit analysis, second half of 2018 ............................... 5-5

LIST OF FIGURES

Figure 2.1 Site map, Legacy Class 1 Landfill ....................................................................... 2-2 Figure 3.1 Potentiometric surface, November 9, 2018.......................................................... 3-2 Figure 5.1 Power curve, 2018 semiannual detection monitoring .......................................... 5-3

Page 9: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

February 12, 2019

1-1

1.0 INTRODUCTION

The Craighead County Solid Waste Disposal Authority (CCSWDA) owns and operates

the Legacy Class 1 landfill, located approximately 5 miles south of Jonesboro in Craighead

County, Arkansas. The landfill began accepting waste in 1991 and currently operates under

Permit No. 0254-S1-R4, which was issued on May 2, 2012, by the Arkansas Department of

Environmental Quality (ADEQ). Groundwater detection monitoring is conducted semiannually

at the site in accordance with the permit and Arkansas Pollution Control and Ecology

Commission (APCEC) Regulation No. 22 requirements.

This report presents the results of semiannual detection monitoring performed during the

second half of 2018. Section 2.0 describes the groundwater monitoring system and the sampling

schedule, sampling methods, and required laboratory analyses; Section 3.0 presents groundwater

level data and the rate and direction of groundwater flow; Section 4.0 presents groundwater

quality data; Section 5.0 presents the statistical approach and evaluation of groundwater data,

Section 6.0 summarizes conclusions based on the results from this monitoring period; and

Section 7.0 provides selected references for the report.

Page 10: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

February 12, 2019

2-1

2.0 GROUNDWATER MONITORING PROGRAM

This section describes the groundwater monitoring program at the landfill. Included is a

discussion of the monitoring well system, sampling schedule, sampling methodology, and

required laboratory analyses.

2.1 Monitoring Well System The monitoring well system was modified and expanded during September and

October 2017 and is now comprised of the nine wells shown on Figure 2.1. As described in

previous reports, wells MW-6R and MW-9R were unable to produce sufficient quantities of

water for groundwater quality analysis as required by §22.1202(a) and were removed from the

system in accordance with the ADEQ approved work plan (ADEQ document identification

numbers [DINs] 72457 and 72603). Monitoring well MW-9R was replaced with MW-9R2. No

replacement well was installed for former well MW-6R due to its distance from the active

disposal area. A second new well, MW-22, was installed north and upgradient of the active

disposal area to serve as an additional background well. A monitoring well installation and

decommissioning report was submitted to ADEQ on January 8, 2018 (DIN 73025).

Each monitoring well is installed within the uppermost saturated sands of the Mississippi

River Valley alluvial aquifer and Quaternary outwash associated with the erosion of Crowley’s

Ridge. A summary of well construction details is included as Table 2.1. More detailed

information regarding well construction can be found in the landfill’s groundwater sampling and

analysis plan (GWSAP) (Terracon 2012; DIN 61939) and the well installation report for MW-

9R2 and MW-22 (DIN 73025). Monitoring wells MW-14R, MW-17R, and MW-22 are located

upgradient of the waste mass, while the remaining wells are located side-gradient or

downgradient.

Page 11: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
KAE
Typewritten Text
KAE
Typewritten Text
2-2
KAE
Typewritten Text
KAE
Typewritten Text
KAE
Typewritten Text
KAE
Typewritten Text
KAE
Typewritten Text
KAE
Typewritten Text
Figure 2.1 Site map, Legacy Class 1 Landfill.
KAE
Typewritten Text
Page 12: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

February 12, 2019

2-3

Table 2.1. Monitoring well construction data.

Well ID Installation Date

Measuring Point

(MP) Elevation(1)

(ft NAVD*)

Total Depth(2)

(ft below MP)

Screened

Interval(2)

(ft below MP)

MW-8 6/6/1990 250.83 101.8 71.8 to 101.8 MW-9R2 9/26/2017 252.85(3) 133.9(3) 119.1 to 139.1(3) MW-14R 6/15/2004 265.77 122.6 102.6 to 122.6 MW-16R 5/27/2010 259.59 113.0 92.7 to 113.0 MW-17R 6/17/2004 282.20 138.6 118.6 to 138.6 MW-19 5/28/2010 264.50 118.5 98.2 to 118.5 MW-20 5/27/2010 258.06 108.0 87.7 to 108.0 MW-21 5/26/2010 253.10 102.9 82.6 to 102.9 MW-22 9/30/2017 260.60(3) 134.2(3) 126.5 to 146.5(3)

Notes: NAVD = North American Datum of 1988. 1. Except as otherwise noted, MP elevations are based on a December 2013 survey. 2. As reported in the approved GWSAP (Terracon 2012). 3. Based on October 2017 survey (DIN 73025).

2.2 Sampling Schedule In accordance with the landfill’s permit, the groundwater monitoring program consists of

semiannual sampling at all monitoring wells except MW-8, which is required to be sampled once

every 18 months. MW-8 was not accessible during the second half of 2018 due to wet site

conditions. An attempt will be made to sample MW-8 during the first half of 2019 sampling

event. New well MW-22 is scheduled to be sampled quarterly for the purpose of background

data collection in accordance with §22.1203(e). Quarterly sampling at MW-22 began during the

fourth quarter of 2017 and will continue until the third quarter of 2019.

During the second half of 2018, quarterly sampling of MW-22 was performed during the

months of August and November and semiannual detection monitoring was performed during

November 2018. Verification sampling for unconfirmed SSIs identified by statistical evaluation

in the first half of 2018 data set was performed during August. Those results were discussed in

the first half 2018 groundwater monitoring report. Verification sampling for unconfirmed SSIs

during the second half of 2018 was performed in January 2019, and the results are discussed in

Section 5.3.2.

Page 13: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

February 12, 2019

2-4

2.3 Sampling Methodology FTN Associates, Ltd. (FTN) provided groundwater sampling services during this

monitoring period. Sampling was performed using low-flow sampling techniques in accordance

with US Environmental Protection Agency (EPA) guidelines (Puls and Barcelona 1996) and the

facility’s approved GWSAP (Terracon 2012). Groundwater was sampled utilizing the new

dedicated bladder pumps installed during October 2017. Field parameters were measured during

purging and sampling using a Hach 2100P portable turbidity meter and a handheld YSI 556 MPS

and a flow-through cell. Field sampling forms for both events are provided in Appendix A.

2.4 Laboratory Analyses Per the requirements of §22.1204(d) and the facility’s permit, groundwater and leachate

samples were analyzed for the list of parameters included in Table 2.2. Laboratory analyses

adhered to methods described in EPA’s Test Methods for Evaluating Solid

Waste -Physical/Chemical Methods (SW-846), or equivalent, and other guidelines established by

EPA. Pace Analytical (Pace) of Mt. Juliet, Tennessee, provided laboratory services during this

monitoring period. Laboratory reports are included as Appendix B.

Page 14: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

February 12, 2019

2-5

Table 2.2. Constituents for detection monitoring.

Regulation 22 Appendix 1 Metals and General Water Quality Parameters

Antimony pH* Arsenic Selenium Barium Silver

Beryllium Specific Conductance* Cadmium Sulfate Chloride Temperature*

Chromium Thallium Cobalt Total Dissolved Solids (TDS) Copper Total Organic Carbon

Iron Turbidity* Lead Vanadium

Manganese Zinc Nickel

Regulation 22 Appendix 1 VOCs Acetone trans-1,3-Dichloropropene

Acrylonitrile Ethylbenzene Benzene 2-Hexanone

Bromochloromethane Methyl bromide Bromodichloromethane Methyl chloride

Bromoform; tribromomethane Methylene bromide Carbon disulfide Methylene chloride

Carbon tetrachloride Methyl ethyl ketone (MEK) Chlorobenzene Methyl iodide Chloroethane 4-Methyl-2-pentanone Chloroform Styrene

Dibromochloromethane 1,1,1,2-Tetrachloroethane 1,2-Dibromo-3-chloropropane (DBCP) 1,1,2,2-Tetrachloroethane

1,2-Dibromoethane (EDB) Tetrachloroethylene 1,2-Dichlorobenzene Toluene

1,4-Dichlorobenzene (1,4-DCB) 1,1,1-Trichloroethane trans-1,4-Dichloro-2-butene 1,1,2-Trichloroethane

1,1-Dichloroethane (1,1-DCA) Trichloroethylene 1,2-Dichloroethane (1,2-DCA) Trichlorofluoromethane

1,1-Dichloroethylene 1,2,3-Trichloropropane cis-1,2-Dichloroethylene (cis-1,2-DCE) Vinyl acetate

trans-1,2-Dichloroethylene Vinyl chloride 1,2-Dichloropropane Xylene

cis-1,3-Dichloropropene *Field parameter.

Page 15: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

February 12, 2019

3-1

3.0 WATER LEVEL DATA

This section presents water level data collected during the second half of 2018 and

discusses the rate and direction of groundwater flow.

3.1 Water Level Measurements and Groundwater Flow Direction FTN performed a round of water levels measurements on November 9, 2018, prior to

sampling activities. These data were used to contour the potentiometric surface and to determine

the hydraulic gradient. Depths to water were measured to the nearest 0.01 ft from the MP on the

top of casing and are tabulated in Table 3.1. Depth-to-water measurements were converted to

potentiometric surface elevations (in ft NAVD) and contoured to construct the potentiometric

surface map included as Figure 3.1. Groundwater flow was to the southwest during this sampling

event, which is consistent with the historical direction of groundwater flow across the landfill.

Table 3.1. Water level data and potentiometric surface elevations, November 9, 2018.

Well ID

MP Elevation

(ft NAVD)

Depth to Water

(ft below MP)

Groundwater Elevation

(ft NAVD)

MW-8 250.83 Not measured Not measured MW-9R2 252.85 95.98 156.87 MW-14R 265.77 107.36 158.44 MW-16R 259.59 101.80 157.81 MW-17R 282.20 123.36 158.75 MW-19 264.50 106.37 158.01 MW-20 258.06 100.89 157.16 MW-21 253.10 95.93 157.17 MW-22 260.60 101.42 159.17

Page 16: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

157.0

Figure 3.1. Potentiometric surface,

November 9, 2018.

KAE
Typewritten Text
3-2
Page 17: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

February 12, 2019

3-3

3.2 Hydraulic Gradient and Rate of Groundwater Flow The hydraulic gradient across the active disposal area during the second half of 2018 was

estimated to be 1.4 x 10-3 ft/ft using the flow line between monitoring wells MW-17R and MW-

9R2 shown on Figure 3.1. This estimated gradient is generally consistent with previously

reported values. The linear groundwater velocity, or rate of flow, was calculated using the

following equation:

Vx = -K/ne(dh/dl) Where: Vx = linear velocity, K = hydraulic conductivity, ne = effective porosity, and dh/dl = hydraulic gradient.

Grubbs, Garner & Hoskyn, Inc. (GG&H) reported a K-value of 142 to 283 ft/day, based

on grain size analyses of the underlying alluvial aquifer sands at the landfill (GG&H 1989

[DIN 16377]). In 1995, Genesis Environmental Consulting, Inc. (GEC) conducted slug tests on

five onsite monitoring wells and reported site-specific K-values ranging from 1 to 6 ft/day

(DIN 4172). Published K-values range from about 120 to 390 ft/day (Krinitzsky and Wire 1964,

Ackerman 1989, Renken 1998). The disparity between reported hydraulic conductivities may be

due to the variability of water-bearing lithologies screened by wells at this site. Well logs show

that some wells are screened across silty and/or clayey sands while some are screened in clean,

fine-to medium-grained sands.

For the purpose of this report, K-values of 1 ft/day and 280 ft/day are used to represent

the range of reported values discussed above. Using an average effective porosity (ne) of 20%

(GEC 1995), Vx is calculated to range from approximately 3 ft/year to 710 ft/year. Actual values

will differ by location due to the variability of the uppermost saturated sediments beneath the

landfill.

Page 18: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

February 12, 2019

4-1

4.0 GROUNDWATER QUALITY DATA

This section presents analytical results for groundwater sampling conducted for the

second half of 2018 detection monitoring period. Field and laboratory quality assurance (QA)

and quality control (QC) measures for this sampling event are also presented.

4.1 Review of Laboratory Quality Control Samples According to documentation provided by Pace included in Appendix B, samples were

received by the laboratory in good condition, properly preserved, and at the correct temperature,

and were analyzed within holding times.

4.2 Review of Field Quality Control Samples Field QA/QC samples include sample duplicates and field equipment rinsate blanks.

Sample duplicates are taken as an assessment of the reproducibility of sampling methods. To

verify that results for a duplicate pair show reasonable precision for analyzed parameters, the

relative percent difference (RPD) is calculated when the detected level is at least five times the

laboratory reporting detection limit (RDL) and where neither result is qualified or suspected of

blank contamination. The RPD quality control limit is 20%. Equipment rinsate blanks are taken

to assess the effectiveness of field decontamination procedures. When a detection occurs in a

laboratory quality control blank or above the RDL in an equipment rinsate blank, associated

groundwater data for the detected parameter are flagged with a “B” in the historical database if

the measured levels in the groundwater samples are less than ten times the measured level in the

equipment blank. EPA guidance (1986) recommends that detections in quality control blanks not

be used to correct groundwater data.

Field QA/QC samples were collected in conjunction with each groundwater sampling

activities performed during the second half of 2018 and the verification sampling event

performed in January 2019. All QA/QC samples were handled in the same manner as

groundwater samples with respect to sample collection, packaging, shipping, preservation, and

Page 19: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

February 12, 2019

4-2

chain-of-custody (COC) procedures. A review of the QA/QC samples was performed upon

receipt of the data from the laboratory. Results are summarized below.

• Calculated RPDs were below the quality control limit of 20% for all duplicate-

pairs evaluated indicating that field methods produced samples with an acceptable

level of reproducibility.

• Results for the equipment rinsate blanks were all below their respective laboratory

RDLs, with the exception of copper in the November 2018 sample EB-1,

indicating field decontamination methods were effective. The measured levels for

copper in the November 2018 groundwater samples were less than ten times the

measured level in the equipment blank and were flagged with a “B” in the

groundwater database.

• Trip blanks were nondetect for all analyzed parameters.

4.3 Review of Field Documentation Field sampling forms for sampling performed during the months of August 2018,

November 2018, and January 2019 are included in Appendix A. Based on a review of these

records, the following observations were made:

• Criteria for low-flow, minimal drawdown purging, and sampling were generally

met for all sampled wells during each sampling event. Flow rates were maintained at 500 mL/min or less and total drawdown was less than 0.3 ft at all wells.

• Field-measured turbidity was below 10 nephelometric turbidity units (NTUs) as required by §22.1103(a) for all samples except MW-14R, which had a turbidity level of 20 NTUs despite the well being purged at a rate of 100 mL/min for 3 hours and 10 minutes. Elevated sample turbidity may cause the total metals results in the sample to be biased high.

4.4 Summary of Groundwater Quality Results The laboratory reports provided by Pace for the second half of 2018 sampling events are

included in Appendix B. A review of the laboratory quality control information is provided in

Page 20: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

February 12, 2019

4-3

Section 4.1. Data from these monitoring events are compiled in the landfill’s historical

groundwater database, included in Appendix C.

Laboratory results detected above the RDL in one or more groundwater samples from the

second half of 2018 monitoring period are summarized in Table 4.1 along with field-measured

pH and turbidity. Water quality standards promulgated by EPA are included for comparison

purposes, where applicable.

As shown in Table 4.1, measured levels for pH, TDS, iron, and manganese were

measured at levels above the secondary drinking water standard (SDWS) at several well

locations during this monitoring period. Elevated levels for these parameters are consistent

historical measurements at this site and are consistent with published values for this aquifer

(Gonthier 2013). SDWSs are non-enforceable EPA guidelines based on cosmetic or aesthetic

effects and do not have enforceable limits established by the federal National Primary Drinking

Water Regulations (NPDWRs).

Page 21: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

February 12, 2019

4-4

Table 4.1. Groundwater quality, second half of 2018.

Well ID

Date

Collected

Arsenic

(mg/L)

Barium

(mg/L)

Chloride

(mg/L)

Iron

(mg/L)

Manganese

(mg/L)

Sulfate

(mg/L)

TDS

(mg/L)

pH

(su)

Turbidity

(NTUs)

Quarterly Background Monitoring (August 2018)

MW-22 8/20/2018 0.00217 0.0606 4.78 0.499 0.222 11.7 236 7.3 1.9 MW-31(a) 8/20/2018 <0.00200 <0.00500 --- <0.100 <0.00500 --- --- --- --- MW-32(b) 8/20/2018 0.00209 0.0626 4.91 0.464 0.213 11.6 241 --- --- Semiannual Detection Monitoring (November 2018) MW-9R2 11/13/2018 0.00114 J 0.140 7.02 1.71 0.396 17.2 277 6.9 0.6 MW-14R 11/12/2018 0.00117 J 0.254 44.7 5.54 0.355 64.1 533 6.9 20.1 MW-16R 11/12/2018 0.000940 J 0.0908 6.88 0.519 0.567 17.3 276 7.1 1.9 MW-17R 11/9/2018 0.00111 J 0.105 7.32 2.24 0.0510 30.1 349 6.8 5.1 MW-19 11/12/2018 0.000815 J 0.188 12.2 1.42 0.619 34.1 387 7.0 0.9

MW-20 11/13/2018 0.000335 J 0.230(d) 9.43 3.72 0.732 26.0 392 6.4 0.6 1/29/2019(c) --- 0.185 --- --- --- --- 373 6.5 0.8

MW-21 11/13/2018 0.00128 J 0.127 6.93 0.964 0.491 10.1 290 6.7 0.6 MW-22 11/9/2018 0.00199 J 0.0533 4.11 0.392 0.234 7.22 212 7.5 0.5 MW-16R DUP(b) 11/12/2018 0.000654 J 0.0917 6.88 0.302 0.535 17.3 280 --- --- EB-1(a) 11/13/2018 <0.00200 J 0.000726 J <1.00 <0.100 0.000523 J <5.00 <10.0 --- --- EPA Water Quality Standards 0.01(e) 2.0(e) 250(f) 0.3(f) 0.05(f) 250(f) 500(f) 6.5-8.5(f) ---

Notes: Values shown in bold type exceed an EPA SDWS. Values shown in bold red type exceed an EPA MCL. “B” flag indicates a detection in an associated quality control sample. “J” flag indicates the parameter was detected below the RDL; the reported value is an estimate. a. MW-31 and EB-1 were field equipment rinsate blanks during the sampling events. b. MW-32 was a duplicate of MW-22 for the August 2018 sampling event; MW-16R DUP was a duplicate of MW-16R for the November 2018 sampling event. c. Verification sampling results. d. Measurement shown represents retested sample results. e. EPA MCL. f. EPA SDWS.

Page 22: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

February 12, 2019

5-1

5.0 STATISTICAL EVALUATION

This section describes the statistical approach and evaluation of the second half of 2018

data.

5.1 Statistical Program Design This section outlines the statistical program design, which adheres to recommendations in

EPA’s Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities Unified

Guidance (Unified Guidance) and the facility’s GWSAP (Terracon 2012). In summary, detected

parameters are evaluated using either intrawell prediction limits with a "1 of 2" retesting strategy

or the Mann-Kendall/Sen’s Slope test for trends to detect statistically significant changes in

groundwater quality. Appendix D identifies which statistical test is applied to each

well-parameter pair in the landfill’s monitoring program. Each test is briefly described below.

Intrawell prediction limits are applied to well-parameter combinations with background

populations containing a minimum of 8 to 10 independent data points that have a stationary

statistical distribution (i.e., the data do not change over time). The “1 of 2” retesting strategy

requires one verification sample be obtained within the same monitoring period as the initial

exceedance. If the measured value in the verification sample also exceeds the prediction limit,

then an SSI (or SSD in the case of pH) is declared. Background data sets used to calculate

prediction limits are identified in Appendix D.

If background data characteristics do not meet the requirements for a prediction limit test,

the well-parameter pair is tested using the Mann-Kendall/Sen’s Slope test for trends, as

recommended by the Unified Guidance. If a statistically significant increasing trend (or

statistically significant decreasing trend in the case of pH) is indicated, then this is evidence of

possible deteriorating groundwater quality. While there is no explicit retesting strategy for the

Mann-Kendall/Sen’s Slope test (as there is for prediction limits), retesting can be applied

(Cameron 2015).

Page 23: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

February 12, 2019

5-2

5.2 Site-Wide False Positive Rate and Power The Unified Guidance recommends that detection monitoring programs have adequate

statistical power and a site-wide false positive rate (SWFPR, or α) value of 10% over a one-year

period of testing. As a result, the semiannual target rate is fixed at 0.05 (5%). The magnitude of

the per-test alpha will vary depending on how many statistical tests are required per semiannual

evaluation. Input criteria for the per-test alpha calculations are included in Table 5.1 for intrawell

prediction limit analyses.

Table 5.1. Per-test alpha and power curve criteria, 2018 semiannual detection monitoring.

Criteria for Per-Test Alpha and Power Curve Generation Statistical Test Intrawell Prediction Limit Number of Downgradient Monitoring Wells 5 Background Sample Size (n) 9 (based on minimum background size) Number of Constituents 12(a) Re-Sample Strategy 1 of 2(b) Per-Evaluation SWFPR 0.05

Notes: a. Estimated number of detected parameters evaluated by prediction limit tests. b. The “1 of 2” re-sample strategy includes one verification sampling event within the same monitoring period.

Statistical power is inversely related to the SWFPR and is an estimate of the rate at which

false negative results will occur. To gauge statistical power, the Unified Guidance recommends

the use of the EPA Reference Power Curve (ERPC) to estimate the ability of any individual test

to identify an exceedance above background. Any single statistical test should have the ability to

detect an exceedance 55% to 60% of the time at three standard deviations (3σ) above background

and 80% to 85% of the time at 4σ above background. Input criteria used to construct the power

curve for the 2018 statistical program are included in Table 5.1. Figure 5.1 depicts the facility’s

power curve plotted against the ERPC.

Page 24: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

February 12, 2019

5-3

Based on the input criteria used, the power curve shows that any single test is estimated

to detect exceedances above background approximately 50% of the time at 3σ, and

approximately 90% of the time at 4σ. This curve indicates that the landfill’s program meets the

EPA target rates for SSI detections at levels of 4σ above background but is slightly lower than

the EPA recommended rate at levels 3σ above background.

5.3 Statistical Evaluation Results Detected constituents during the second half of 2018 were evaluated using the Sanitas

software program. No statistical evaluations were conducted for results detected below the RDL,

Figure 5.1. Power curve, 2018 semiannual detection monitoring.

Page 25: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

February 12, 2019

5-4

per §22.1203(h)(5). Results detected below the RDL are flagged with a “J” in the historical

database included as Appendix C.

Distributional analyses including time-series plots, box-and-whiskers diagrams, and

outlier tests were applied to period-of-record data on currently detected parameters to identify

apparent trends or excursions from normal ranges. Results from these analyses are included in

Appendix E, and outliers identified in the current data set are summarized in Section 5.3.1.

Background data sets used for statistical analysis are discussed in Appendix D. Statistical

evaluation plots for detection monitoring are included in Appendix F.

5.3.1 Outlier Identification Dixon's, Rosner's, or Tukey's outlier tests were applied to period-of-record data to

identify possible outliers in the current dataset. Dixon’s outlier test is used for small, normally

distributed data populations (generally containing less than 25 data values). For large and

normally distributed data populations with 20 or more data points, the Rosner's outlier test is

applied. Tukey's outlier test is used to detect outliers in non-normal data distributions. Based on

the outlier screening for this reporting period, no statistical outliers were identified in the second

half 2018 data.

5.3.2 Prediction Limit Evaluation Detected data from the second half of 2018 sampling event were tested using intrawell

prediction limits (except as noted in Table D.1 of Appendix D) to determine if the data were

representative of background. Graphical plots for the statistical analyses are included in

Appendix F. Results are summarized in Table 5.2.

Page 26: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

February 12, 2019

5-5

Table 5.2. SSIs and potential exceedances based on prediction limit analysis, second half of 2018.

Well ID Parameter

Prediction

Limit

(mg/L)

Initial Observation,

November 2018

(mg/L)

Verification Sample,

January 2019

(mg/L)

SSI

Confirmed?

MW-20 Barium 0.2219 0.230 0.185 No MW-14R Chloride 38.77 44.7 NA(b) Yes(a)

MW-20 TDS 391.1 392 373 No Note: Well-parameter pairs shown in bold-faced type are confirmed SSIs. a. SSI was confirmed during a previous monitoring period, so verification sampling was not performed.

The SSI for chloride at upgradient MW-14R is confirmed and has been addressed in five

ADEQ-approved alternate source demonstrations (ASDs) (DINs 70470, 72108, 72776, 73764,

and 74831). The measured level of chloride at MW-14R during this monitoring period is lower

than those presented in the ASDs.

Verification sampling was performed on January 29, 2019, for the potential exceedances

for barium and TDS at MW-20. As shown in Table 5.2, the potential exceedances were

disconfirmed. A plot of the prediction limit analysis result from the verification sampling data is

provided in Appendix F.

5.3.3 Mann-Kendall Test/Sen’s Estimate of Slope Evaluation The Mann-Kendall/Sen’s Slope test for trends was applied to well-parameter pairs where

statistically significant trends were identified in background data sets (Table D.1 in

Appendix D). Period-of-record data were evaluated and results indicated one SSI: iron data at

MW-14R are increasing at a statistically significant level (98% confidence). The trend for iron at

MW-14R was previously confirmed and addressed in the ADEQ-approved ASDs (DINs 70470,

72108, 72776, 73764, and 74831). The detected level during the second half of 2018 is within

levels discussed in the approved ASDs. Graphical plots are included in Appendix F.

Page 27: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

February 12, 2019

5-6

5.3.4 Notifications of Statistically Significant Results Per the requirements of §22.1204(c)(1), a notice will be placed in the operating record

that chloride and iron at MW-14R were indicated as SSIs during the second half of 2018 and the

ADEQ director will be notified that the notice was placed.

As allowed by §22.1204(c)(3), an ASD for confirmed SSIs will be submitted to ADEQ

within 90 days of the submittal of this report.

Page 28: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

February 12, 2019

6-1

6.0 CONCLUSIONS

The following conclusions are based on a review of data for the landfill from the current

monitoring period:

1. Based on water level measurements taken during the second half of 2018,

groundwater flow across the landfill is to the southwest, consistent with the historically observed groundwater flow direction.

2. Analytical results from the second half of 2018 showed measured levels of iron, manganese, pH, and TDS above recommended SDWS at several wells. Published literature shows that regional groundwater quality in the alluvial aquifer has characteristically high levels of these parameters. Measured levels during the current monitoring period are consistent with historical data at the facility. SDWSs are non-enforceable EPA guidelines based on cosmetic or aesthetic effects and do not have enforceable limits established by the federal NPDWRs.

3. The landfill’s statistical power curve indicates that the groundwater program meets the EPA target rates to identify SSIs at 4σ above background but is slightly lower than the EPA-recommended target rate for 3σ above background. The statistical power will likely improve the next time background data sets are updated.

4. The intrawell prediction limit evaluation of the second half of 2018 data set identified a confirmed SSI for chloride at upgradient MW-14R. The SSI for chloride at upgradient MW-14R has been addressed in previously submitted ASDs.

5. The Mann-Kendall/Sen’s Slope evaluation identified an SSI for iron at MW-14R. This SSI has been confirmed and addressed in previously submitted ASDs.

6. Per the requirements of §22.1204(c)(1), a notice will be placed in the landfill’s operating record identifying the confirmed SSIs from the second half of 2018. A letter will be sent to ADEQ notifying the director that the notice was placed.

7. As allowed by §22.1204(c)(3), an ASD will be submitted to ADEQ within 90 days of the submittal of this report for the SSIs identified during this monitoring period.

8. Results from the second half of 2018 monitoring period are generally consistent with historical data observed at the landfill.

Page 29: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

February 12, 2019

7-1

7.0 SELECTED REFERENCES

Ackerman, D.J. 1989. Hydrology of the Mississippi River Valley Alluvial Aquifer, South-Central United States—A Preliminary Assessment of the Regional Flow System [US Geological Survey Water-Resources Investigation Report 88-4028]. 74p.

EPA [US Environmental Protection Agency]. 1986. RCRA Ground-Water Monitoring Technical Enforcement Guidance Document [EC-G-2002-130, EPA/530/SW-86/055]. Washington, DC: US Environmental Protection Agency, Office of Waste Programs Enforcement, Office of Solid Waste and Emergency Response. [Also published in EPA/NWWA series by National Water Well Association, Dublin, OH.] 328 pp.

———. 2009. Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Unified Guidance [EPA 530-R-09-007]. Washington, DC: US Environmental Protection Agency, Office of Resource Conservation and Recovery, Program Implementation and Information Division.

Cameron, K. 2015. “Modern Groundwater Statistics” [presentation/training]. Texas Commission on Environmental Quality, October 27-28, 2015, Austin, TX.

GEC [Genesis Environmental Consulting, Inc.]. 1995. Groundwater Monitoring System Evaluation and Certification for Craighead County Solid Waste Disposal Authority Landfill, Permit Number 0254-SR-2 [ADEQ DIN 4172]. Little Rock, AR: Genesis Environmental Consulting, Inc.

GG&H [Grubbs, Garner & Hoskyn, Inc.]. 1989. Geotechnical and Hydrogeologic Study, Proposed Sanitary Landfill/Whitlatch Property, Craighead County, Arkansas, May 31, 1989 [ADEQ DIN 16377]. Little Rock, AR: Grubbs, Garner & Hoskyn, Inc.

Gibbons, R.D. 1994. Statistical Methods for Groundwater Monitoring. New York: John Wiley & Sons, Inc.

Gonthier, G.J. 2003. Quality of Groundwater in Pleistocene and Holocene Subunits of the Mississippi River Alluvial Aquifer, 1998 [Water-Resources Investigations Report 03-4202]. Jackson, MS: US Geological Survey, National Water-Quality Assessment Program.

Krinitzsky, E.L., and J.C. Wire. 1964. Groundwater in Alluvium of Lower Mississippi Valley (Upper and Central Area) [USACE WES Technical Report 3-658, vol. 1 and 2]. Vicksburg, MS: US Army Corps of Engineers, Waterways Experiment Station. 400 p.

Renken, R.A. 1998. Ground Water Atlas of the United States, Segment 5, Arkansas, Louisiana, Mississippi [Hydrologic Investigations Atlas 730-F]. Reston, VA: US Geological Survey.

Puls, R.W., and M.J. Barcelona. 1996. Low-Flow (Minimal Drawdown) Ground-Water Sampling Procedures [EPA 540/S-95/504]. Washington, DC: US Environmental Protection Agency, Office of Solid Waste and Emergency Response.

Page 30: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

February 12, 2019

7-2

Sanitas Technologies. 2014. Sanitas Statistical Software, User Guide, version 9.5. Shawnee, KS: Sanitas Technologies.

Terracon Consultants, Inc. 2012. Groundwater Sampling and Analysis Plan, Craighead County Solid Waste Disposal Authority, Legacy Class 1 Landfill, second revision [ADEQ DIN 61939]. February 2013.

Page 31: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

APPENDIX A Field Sampling Forms

Page 32: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

August 2018 Sampling Event

Page 33: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 34: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 35: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 36: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 37: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 38: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

November 2018 Sampling Event

Page 39: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 40: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 41: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 42: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 43: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 44: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 45: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 46: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 47: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 48: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 49: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 50: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 51: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 52: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 53: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 54: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 55: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

January 2019 Sampling Event

Page 56: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 57: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

APPENDIX B Laboratory Data

Page 58: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

August 2018 Sampling Event

Page 59: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ANALYTICAL REPORTAugust 27, 2018

Legacy Landfill

Sample Delivery Group: L1019503

Samples Received: 08/21/2018

Project Number: 04469-1767-001

Description: Craighead County - Legacy Landfill

Report To: Angela Sparks

P.O. Box 16777

Jonesboro, AR 72403

Entire Report Reviewed By:

August 27, 2018

[Preliminary Report]

Mark W. BeasleyPro ject Manager

Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace Nationalis performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304.

12065 Lebanon Rd Mount Jul iet , TN 37122 615-758-5858 800-767-5859 www.pacenational .com

August 27, 2018

Mark W. BeasleyPro ject Manager

Page 60: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.TABLE OF CONTENTS

Cp: Cover Page 1

Tc: Table of Contents 2

Ss: Sample Summary 3

Cn: Case Narrative 4

Sr: Sample Results 5

MW-22 L1019503-01 5

MW-32 L1019503-02 7

MW-17R L1019503-03 9

TRIP BLANK L1019503-04 10

MW-31 L1019503-05 11

Qc: Quality Control Summary 12

Gravimetric Analysis by Method 2540 C-2011 12

Wet Chemistry by Method 9056A 13

Wet Chemistry by Method 9060A 15

Metals (ICPMS) by Method 6020 16

Volatile Organic Compounds (GC/MS) by Method 8260B 18

Gl: Glossary of Terms 21

Al: Accreditations & Locations 22

Sc: Sample Chain of Custody 23

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 14:38 2 of 23

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 17:10 2 of 23

Page 61: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE SUMMARY

Collected by Collected date/time Received date/time

MW-22 L1019503-01 GW 08/20/18 11:10 08/21/18 08:45

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Gravimetric Analysis by Method 2540 C-2011 WG1157019 1 08/24/18 19:44 08/24/18 20:28 MCG

Wet Chemistry by Method 9056A WG1155784 1 08/22/18 23:46 08/22/18 23:46 ELN

Wet Chemistry by Method 9060A WG1155930 1 08/23/18 14:32 08/23/18 14:32 EEM

Metals (ICPMS) by Method 6020 WG1155542 1 08/23/18 17:16 08/23/18 22:31 LD

Volatile Organic Compounds (GC/MS) by Method 8260B WG1155515 1 08/22/18 04:17 08/22/18 04:17 JSD

Collected by Collected date/time Received date/time

MW-32 L1019503-02 GW 08/20/18 11:15 08/21/18 08:45

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Gravimetric Analysis by Method 2540 C-2011 WG1157019 1 08/24/18 19:44 08/24/18 20:28 MCG

Wet Chemistry by Method 9056A WG1155784 1 08/23/18 01:09 08/23/18 01:09 ELN

Wet Chemistry by Method 9060A WG1155930 1 08/23/18 14:43 08/23/18 14:43 EEM

Metals (ICPMS) by Method 6020 WG1155542 1 08/23/18 17:16 08/23/18 22:36 LD

Volatile Organic Compounds (GC/MS) by Method 8260B WG1155515 1 08/22/18 04:37 08/22/18 04:37 JSD

Collected by Collected date/time Received date/time

MW-17R L1019503-03 GW 08/20/18 14:05 08/21/18 08:45

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Metals (ICPMS) by Method 6020 WG1155542 1 08/23/18 17:16 08/23/18 22:40 LD

Collected by Collected date/time Received date/time

TRIP BLANK L1019503-04 GW 08/20/18 11:05 08/21/18 08:45

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Volatile Organic Compounds (GC/MS) by Method 8260B WG1155515 1 08/21/18 22:40 08/21/18 22:40 JSD

Collected by Collected date/time Received date/time

MW-31 L1019503-05 GW 08/20/18 14:15 08/21/18 08:45

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Metals (ICPMS) by Method 6020 WG1155542 1 08/23/18 17:16 08/23/18 22:54 LD

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 14:38 3 of 23

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 17:10 3 of 23

Page 62: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.CASE NARRATIVE

All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated withinthe report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental sampleshave been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data.

[Preliminary Report]

Mark W. BeasleyPro jec t Manager

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 14:38 4 of 23

Mark W. BeasleyPro jec t Manager

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 17:10 4 of 23

Page 63: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 01L 1 0 1 9 5 0 3

MW-22C o l l e c t e d d a t e / t i m e : 0 8 / 2 0 / 1 8 1 1 : 1 0

Gravimetric Analysis by Method 2540 C-2011

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Dissolved Solids 236000 2820 10000 1 08/24/2018 20:28 WG1157019

Wet Chemistry by Method 9056A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Chloride 4780 51.9 1000 1 08/22/2018 23:46 WG1155784

Sulfate 11700 77.4 5000 1 08/22/2018 23:46 WG1155784

Wet Chemistry by Method 9060A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

TOC (Total Organic Carbon) 631 B J 102 1000 1 08/23/2018 14:32 WG1155930

Metals (ICPMS) by Method 6020

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Antimony U 0.754 2.00 1 08/23/2018 22:31 WG1155542

Arsenic 2.17 0.250 2.00 1 08/23/2018 22:31 WG1155542

Barium 60.6 0.360 5.00 1 08/23/2018 22:31 WG1155542

Beryllium U 0.120 2.00 1 08/23/2018 22:31 WG1155542

Cadmium U 0.160 1.00 1 08/23/2018 22:31 WG1155542

Chromium U 0.540 2.00 1 08/23/2018 22:31 WG1155542

Copper U 0.520 5.00 1 08/23/2018 22:31 WG1155542

Cobalt U 0.260 2.00 1 08/23/2018 22:31 WG1155542

Iron 499 15.0 100 1 08/23/2018 22:31 WG1155542

Lead U 0.240 2.00 1 08/23/2018 22:31 WG1155542

Manganese 222 0.250 5.00 1 08/23/2018 22:31 WG1155542

Nickel U 0.350 2.00 1 08/23/2018 22:31 WG1155542

Selenium U 0.380 2.00 1 08/23/2018 22:31 WG1155542

Silver U 0.310 2.00 1 08/23/2018 22:31 WG1155542

Thallium U 0.190 2.00 1 08/23/2018 22:31 WG1155542

Vanadium U 0.180 5.00 1 08/23/2018 22:31 WG1155542

Zinc U 2.56 25.0 1 08/23/2018 22:31 WG1155542

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Acetone U 10.0 50.0 1 08/22/2018 04:17 WG1155515

Acrylonitrile U 1.87 10.0 1 08/22/2018 04:17 WG1155515

Benzene U 0.331 1.00 1 08/22/2018 04:17 WG1155515

Bromochloromethane U 0.520 1.00 1 08/22/2018 04:17 WG1155515

Bromodichloromethane U 0.380 1.00 1 08/22/2018 04:17 WG1155515

Bromoform U 0.469 1.00 1 08/22/2018 04:17 WG1155515

Bromomethane U 0.866 5.00 1 08/22/2018 04:17 WG1155515

Carbon disulfide 0.315 J 0.275 1.00 1 08/22/2018 04:17 WG1155515

Carbon tetrachloride U 0.379 1.00 1 08/22/2018 04:17 WG1155515

Chlorobenzene U 0.348 1.00 1 08/22/2018 04:17 WG1155515

Chlorodibromomethane U 0.327 1.00 1 08/22/2018 04:17 WG1155515

Chloroethane U 0.453 5.00 1 08/22/2018 04:17 WG1155515

Chloroform U 0.324 5.00 1 08/22/2018 04:17 WG1155515

Chloromethane U 0.276 2.50 1 08/22/2018 04:17 WG1155515

Dibromomethane U 0.346 1.00 1 08/22/2018 04:17 WG1155515

1,2-Dibromoethane U 0.381 1.00 1 08/22/2018 04:17 WG1155515

1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 08/22/2018 04:17 WG1155515

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 14:38 5 of 23

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 17:10 5 of 23

Page 64: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 01L 1 0 1 9 5 0 3

MW-22C o l l e c t e d d a t e / t i m e : 0 8 / 2 0 / 1 8 1 1 : 1 0

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

1,2-Dichlorobenzene U 0.349 1.00 1 08/22/2018 04:17 WG1155515

1,4-Dichlorobenzene U 0.274 1.00 1 08/22/2018 04:17 WG1155515

trans-1,4-Dichloro-2-butene U 0.866 2.50 1 08/22/2018 04:17 WG1155515

1,1-Dichloroethane U 0.259 1.00 1 08/22/2018 04:17 WG1155515

1,2-Dichloroethane U 0.361 1.00 1 08/22/2018 04:17 WG1155515

1,1-Dichloroethene U 0.398 1.00 1 08/22/2018 04:17 WG1155515

cis-1,2-Dichloroethene U 0.260 1.00 1 08/22/2018 04:17 WG1155515

trans-1,2-Dichloroethene U 0.396 1.00 1 08/22/2018 04:17 WG1155515

1,2-Dichloropropane U 0.306 1.00 1 08/22/2018 04:17 WG1155515

cis-1,3-Dichloropropene U 0.418 1.00 1 08/22/2018 04:17 WG1155515

trans-1,3-Dichloropropene U 0.419 1.00 1 08/22/2018 04:17 WG1155515

Ethylbenzene U 0.384 1.00 1 08/22/2018 04:17 WG1155515

2-Hexanone U 3.82 10.0 1 08/22/2018 04:17 WG1155515

Iodomethane U 1.71 10.0 1 08/22/2018 04:17 WG1155515

2-Butanone (MEK) U 3.93 15.0 1 08/22/2018 04:17 WG1155515

Methylene Chloride U 1.00 5.00 1 08/22/2018 04:17 WG1155515

4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 08/22/2018 04:17 WG1155515

Styrene U 0.307 1.00 1 08/22/2018 04:17 WG1155515

1,1,1,2-Tetrachloroethane U 0.385 1.00 1 08/22/2018 04:17 WG1155515

1,1,2,2-Tetrachloroethane U 0.130 1.00 1 08/22/2018 04:17 WG1155515

Tetrachloroethene U 0.372 1.00 1 08/22/2018 04:17 WG1155515

Toluene U 0.412 1.00 1 08/22/2018 04:17 WG1155515

1,1,1-Trichloroethane U 0.319 1.00 1 08/22/2018 04:17 WG1155515

1,1,2-Trichloroethane U 0.383 1.00 1 08/22/2018 04:17 WG1155515

Trichloroethene U 0.398 1.00 1 08/22/2018 04:17 WG1155515

Trichlorofluoromethane U 1.20 5.00 1 08/22/2018 04:17 WG1155515

1,2,3-Trichloropropane U 0.807 2.50 1 08/22/2018 04:17 WG1155515

Vinyl acetate U 1.63 10.0 1 08/22/2018 04:17 WG1155515

Vinyl chloride U 0.259 1.00 1 08/22/2018 04:17 WG1155515

Xylenes, Total U 1.06 3.00 1 08/22/2018 04:17 WG1155515

(S) Toluene-d8 97.2 80.0-120 08/22/2018 04:17 WG1155515

(S) Dibromofluoromethane 104 76.0-123 08/22/2018 04:17 WG1155515

(S) 4-Bromofluorobenzene 98.3 80.0-120 08/22/2018 04:17 WG1155515

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 14:38 6 of 23

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 17:10 6 of 23

Page 65: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 02L 1 0 1 9 5 0 3

MW-32C o l l e c t e d d a t e / t i m e : 0 8 / 2 0 / 1 8 1 1 : 1 5

Gravimetric Analysis by Method 2540 C-2011

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Dissolved Solids 241000 2820 10000 1 08/24/2018 20:28 WG1157019

Wet Chemistry by Method 9056A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Chloride 4910 51.9 1000 1 08/23/2018 01:09 WG1155784

Sulfate 11600 77.4 5000 1 08/23/2018 01:09 WG1155784

Wet Chemistry by Method 9060A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

TOC (Total Organic Carbon) 530 B J 102 1000 1 08/23/2018 14:43 WG1155930

Metals (ICPMS) by Method 6020

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Antimony U 0.754 2.00 1 08/23/2018 22:36 WG1155542

Arsenic 2.09 0.250 2.00 1 08/23/2018 22:36 WG1155542

Barium 62.6 0.360 5.00 1 08/23/2018 22:36 WG1155542

Beryllium U 0.120 2.00 1 08/23/2018 22:36 WG1155542

Cadmium U 0.160 1.00 1 08/23/2018 22:36 WG1155542

Chromium U 0.540 2.00 1 08/23/2018 22:36 WG1155542

Copper U 0.520 5.00 1 08/23/2018 22:36 WG1155542

Cobalt U 0.260 2.00 1 08/23/2018 22:36 WG1155542

Iron 464 15.0 100 1 08/23/2018 22:36 WG1155542

Lead U 0.240 2.00 1 08/23/2018 22:36 WG1155542

Manganese 213 0.250 5.00 1 08/23/2018 22:36 WG1155542

Nickel U 0.350 2.00 1 08/23/2018 22:36 WG1155542

Selenium U 0.380 2.00 1 08/23/2018 22:36 WG1155542

Silver U 0.310 2.00 1 08/23/2018 22:36 WG1155542

Thallium U 0.190 2.00 1 08/23/2018 22:36 WG1155542

Vanadium U 0.180 5.00 1 08/23/2018 22:36 WG1155542

Zinc U 2.56 25.0 1 08/23/2018 22:36 WG1155542

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Acetone U 10.0 50.0 1 08/22/2018 04:37 WG1155515

Acrylonitrile U 1.87 10.0 1 08/22/2018 04:37 WG1155515

Benzene U 0.331 1.00 1 08/22/2018 04:37 WG1155515

Bromochloromethane U 0.520 1.00 1 08/22/2018 04:37 WG1155515

Bromodichloromethane U 0.380 1.00 1 08/22/2018 04:37 WG1155515

Bromoform U 0.469 1.00 1 08/22/2018 04:37 WG1155515

Bromomethane U 0.866 5.00 1 08/22/2018 04:37 WG1155515

Carbon disulfide 0.317 J 0.275 1.00 1 08/22/2018 04:37 WG1155515

Carbon tetrachloride U 0.379 1.00 1 08/22/2018 04:37 WG1155515

Chlorobenzene U 0.348 1.00 1 08/22/2018 04:37 WG1155515

Chlorodibromomethane U 0.327 1.00 1 08/22/2018 04:37 WG1155515

Chloroethane U 0.453 5.00 1 08/22/2018 04:37 WG1155515

Chloroform U 0.324 5.00 1 08/22/2018 04:37 WG1155515

Chloromethane U 0.276 2.50 1 08/22/2018 04:37 WG1155515

Dibromomethane U 0.346 1.00 1 08/22/2018 04:37 WG1155515

1,2-Dibromoethane U 0.381 1.00 1 08/22/2018 04:37 WG1155515

1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 08/22/2018 04:37 WG1155515

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 14:38 7 of 23

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 17:10 7 of 23

Page 66: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 02L 1 0 1 9 5 0 3

MW-32C o l l e c t e d d a t e / t i m e : 0 8 / 2 0 / 1 8 1 1 : 1 5

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

1,2-Dichlorobenzene U 0.349 1.00 1 08/22/2018 04:37 WG1155515

1,4-Dichlorobenzene U 0.274 1.00 1 08/22/2018 04:37 WG1155515

trans-1,4-Dichloro-2-butene U 0.866 2.50 1 08/22/2018 04:37 WG1155515

1,1-Dichloroethane U 0.259 1.00 1 08/22/2018 04:37 WG1155515

1,2-Dichloroethane U 0.361 1.00 1 08/22/2018 04:37 WG1155515

1,1-Dichloroethene U 0.398 1.00 1 08/22/2018 04:37 WG1155515

cis-1,2-Dichloroethene U 0.260 1.00 1 08/22/2018 04:37 WG1155515

trans-1,2-Dichloroethene U 0.396 1.00 1 08/22/2018 04:37 WG1155515

1,2-Dichloropropane U 0.306 1.00 1 08/22/2018 04:37 WG1155515

cis-1,3-Dichloropropene U 0.418 1.00 1 08/22/2018 04:37 WG1155515

trans-1,3-Dichloropropene U 0.419 1.00 1 08/22/2018 04:37 WG1155515

Ethylbenzene U 0.384 1.00 1 08/22/2018 04:37 WG1155515

2-Hexanone U 3.82 10.0 1 08/22/2018 04:37 WG1155515

Iodomethane U 1.71 10.0 1 08/22/2018 04:37 WG1155515

2-Butanone (MEK) U 3.93 15.0 1 08/22/2018 04:37 WG1155515

Methylene Chloride U 1.00 5.00 1 08/22/2018 04:37 WG1155515

4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 08/22/2018 04:37 WG1155515

Styrene U 0.307 1.00 1 08/22/2018 04:37 WG1155515

1,1,1,2-Tetrachloroethane U 0.385 1.00 1 08/22/2018 04:37 WG1155515

1,1,2,2-Tetrachloroethane U 0.130 1.00 1 08/22/2018 04:37 WG1155515

Tetrachloroethene U 0.372 1.00 1 08/22/2018 04:37 WG1155515

Toluene U 0.412 1.00 1 08/22/2018 04:37 WG1155515

1,1,1-Trichloroethane U 0.319 1.00 1 08/22/2018 04:37 WG1155515

1,1,2-Trichloroethane U 0.383 1.00 1 08/22/2018 04:37 WG1155515

Trichloroethene U 0.398 1.00 1 08/22/2018 04:37 WG1155515

Trichlorofluoromethane U 1.20 5.00 1 08/22/2018 04:37 WG1155515

1,2,3-Trichloropropane U 0.807 2.50 1 08/22/2018 04:37 WG1155515

Vinyl acetate U 1.63 10.0 1 08/22/2018 04:37 WG1155515

Vinyl chloride U 0.259 1.00 1 08/22/2018 04:37 WG1155515

Xylenes, Total U 1.06 3.00 1 08/22/2018 04:37 WG1155515

(S) Toluene-d8 99.1 80.0-120 08/22/2018 04:37 WG1155515

(S) Dibromofluoromethane 101 76.0-123 08/22/2018 04:37 WG1155515

(S) 4-Bromofluorobenzene 98.5 80.0-120 08/22/2018 04:37 WG1155515

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 14:38 8 of 23

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 17:10 8 of 23

Page 67: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 03L 1 0 1 9 5 0 3

MW-17RC o l l e c t e d d a t e / t i m e : 0 8 / 2 0 / 1 8 1 4 : 0 5

Metals (ICPMS) by Method 6020

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Arsenic 0.788 J 0.250 2.00 1 08/23/2018 22:40 WG1155542

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 14:38 9 of 23

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 17:10 9 of 23

Page 68: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 04L 1 0 1 9 5 0 3

TRIP BLANKC o l l e c t e d d a t e / t i m e : 0 8 / 2 0 / 1 8 1 1 : 0 5

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Acetone U 10.0 50.0 1 08/21/2018 22:40 WG1155515

Acrylonitrile U 1.87 10.0 1 08/21/2018 22:40 WG1155515

Benzene U 0.331 1.00 1 08/21/2018 22:40 WG1155515

Bromochloromethane U 0.520 1.00 1 08/21/2018 22:40 WG1155515

Bromodichloromethane U 0.380 1.00 1 08/21/2018 22:40 WG1155515

Bromoform U 0.469 1.00 1 08/21/2018 22:40 WG1155515

Bromomethane U 0.866 5.00 1 08/21/2018 22:40 WG1155515

Carbon disulfide U 0.275 1.00 1 08/21/2018 22:40 WG1155515

Carbon tetrachloride U 0.379 1.00 1 08/21/2018 22:40 WG1155515

Chlorobenzene U 0.348 1.00 1 08/21/2018 22:40 WG1155515

Chlorodibromomethane U 0.327 1.00 1 08/21/2018 22:40 WG1155515

Chloroethane U 0.453 5.00 1 08/21/2018 22:40 WG1155515

Chloroform U 0.324 5.00 1 08/21/2018 22:40 WG1155515

Chloromethane U 0.276 2.50 1 08/21/2018 22:40 WG1155515

Dibromomethane U 0.346 1.00 1 08/21/2018 22:40 WG1155515

1,2-Dibromoethane U 0.381 1.00 1 08/21/2018 22:40 WG1155515

1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 08/21/2018 22:40 WG1155515

1,2-Dichlorobenzene U 0.349 1.00 1 08/21/2018 22:40 WG1155515

1,4-Dichlorobenzene U 0.274 1.00 1 08/21/2018 22:40 WG1155515

trans-1,4-Dichloro-2-butene U 0.866 2.50 1 08/21/2018 22:40 WG1155515

1,1-Dichloroethane U 0.259 1.00 1 08/21/2018 22:40 WG1155515

1,2-Dichloroethane U 0.361 1.00 1 08/21/2018 22:40 WG1155515

1,1-Dichloroethene U 0.398 1.00 1 08/21/2018 22:40 WG1155515

cis-1,2-Dichloroethene U 0.260 1.00 1 08/21/2018 22:40 WG1155515

trans-1,2-Dichloroethene U 0.396 1.00 1 08/21/2018 22:40 WG1155515

1,2-Dichloropropane U 0.306 1.00 1 08/21/2018 22:40 WG1155515

cis-1,3-Dichloropropene U 0.418 1.00 1 08/21/2018 22:40 WG1155515

trans-1,3-Dichloropropene U 0.419 1.00 1 08/21/2018 22:40 WG1155515

Ethylbenzene U 0.384 1.00 1 08/21/2018 22:40 WG1155515

2-Hexanone U 3.82 10.0 1 08/21/2018 22:40 WG1155515

Iodomethane U 1.71 10.0 1 08/21/2018 22:40 WG1155515

2-Butanone (MEK) U 3.93 15.0 1 08/21/2018 22:40 WG1155515

Methylene Chloride U 1.00 5.00 1 08/21/2018 22:40 WG1155515

4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 08/21/2018 22:40 WG1155515

Styrene U 0.307 1.00 1 08/21/2018 22:40 WG1155515

1,1,1,2-Tetrachloroethane U 0.385 1.00 1 08/21/2018 22:40 WG1155515

1,1,2,2-Tetrachloroethane U 0.130 1.00 1 08/21/2018 22:40 WG1155515

Tetrachloroethene U 0.372 1.00 1 08/21/2018 22:40 WG1155515

Toluene U 0.412 1.00 1 08/21/2018 22:40 WG1155515

1,1,1-Trichloroethane U 0.319 1.00 1 08/21/2018 22:40 WG1155515

1,1,2-Trichloroethane U 0.383 1.00 1 08/21/2018 22:40 WG1155515

Trichloroethene U 0.398 1.00 1 08/21/2018 22:40 WG1155515

Trichlorofluoromethane U 1.20 5.00 1 08/21/2018 22:40 WG1155515

1,2,3-Trichloropropane U 0.807 2.50 1 08/21/2018 22:40 WG1155515

Vinyl acetate U 1.63 10.0 1 08/21/2018 22:40 WG1155515

Vinyl chloride U 0.259 1.00 1 08/21/2018 22:40 WG1155515

Xylenes, Total U 1.06 3.00 1 08/21/2018 22:40 WG1155515

(S) Toluene-d8 103 80.0-120 08/21/2018 22:40 WG1155515

(S) Dibromofluoromethane 106 76.0-123 08/21/2018 22:40 WG1155515

(S) 4-Bromofluorobenzene 97.4 80.0-120 08/21/2018 22:40 WG1155515

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 14:38 10 of 23

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 17:10 10 of 23

Page 69: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 05L 1 0 1 9 5 0 3

MW-31C o l l e c t e d d a t e / t i m e : 0 8 / 2 0 / 1 8 1 4 : 1 5

Metals (ICPMS) by Method 6020

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Antimony U 0.754 2.00 1 08/23/2018 22:54 WG1155542

Arsenic U 0.250 2.00 1 08/23/2018 22:54 WG1155542

Barium U 0.360 5.00 1 08/23/2018 22:54 WG1155542

Beryllium U 0.120 2.00 1 08/23/2018 22:54 WG1155542

Cadmium U 0.160 1.00 1 08/23/2018 22:54 WG1155542

Chromium U 0.540 2.00 1 08/23/2018 22:54 WG1155542

Copper 1.34 J 0.520 5.00 1 08/23/2018 22:54 WG1155542

Cobalt U 0.260 2.00 1 08/23/2018 22:54 WG1155542

Iron U 15.0 100 1 08/23/2018 22:54 WG1155542

Lead U 0.240 2.00 1 08/23/2018 22:54 WG1155542

Manganese U 0.250 5.00 1 08/23/2018 22:54 WG1155542

Nickel U 0.350 2.00 1 08/23/2018 22:54 WG1155542

Selenium U 0.380 2.00 1 08/23/2018 22:54 WG1155542

Silver U 0.310 2.00 1 08/23/2018 22:54 WG1155542

Thallium U 0.190 2.00 1 08/23/2018 22:54 WG1155542

Vanadium U 0.180 5.00 1 08/23/2018 22:54 WG1155542

Zinc U 2.56 25.0 1 08/23/2018 22:54 WG1155542

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 14:38 11 of 23

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 17:10 11 of 23

Page 70: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1157019G r a v i m e t r i c A n a l y s i s b y M e t h o d 2 5 4 0 C - 2 0 1 1 L 1 0 1 9 5 0 3 - 0 1 , 0 2

Method Blank (MB)

(MB) R3336676-1 08/24/18 20:28

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

Dissolved Solids U 2820 10000

L1019178-01 Original Sample (OS) • Duplicate (DUP)

(OS) L1019178-01 08/24/18 20:28 • (DUP) R3336676-4 08/24/18 20:28

Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits

Analyte ug/l ug/l % %

Dissolved Solids 119000 109000 1 8.77 J3 5

Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)

(LCS) R3336676-2 08/24/18 20:28 • (LCSD) R3336676-3 08/24/18 20:28

Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l % % % % %

Dissolved Solids 8800000 8670000 8850000 98.5 101 85.0-115 2.05 10

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 14:38 12 of 23

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 17:10 12 of 23

Page 71: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1155784W e t C h e m i s t r y b y M e t h o d 9 0 5 6 A L 1 0 1 9 5 0 3 - 0 1 , 0 2

Method Blank (MB)

(MB) R3336193-1 08/22/18 17:41

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

Chloride U 51.9 1000

Sulfate U 77.4 5000

L1019503-01 Original Sample (OS) • Duplicate (DUP)

(OS) L1019503-01 08/22/18 23:46 • (DUP) R3336193-4 08/23/18 00:27

Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits

Analyte ug/l ug/l % %

Chloride 4780 4710 1 1.39 15

Sulfate 11700 11600 1 0.903 15

L1019600-01 Original Sample (OS) • Duplicate (DUP)

(OS) L1019600-01 08/23/18 02:19 • (DUP) R3336193-7 08/23/18 02:33

Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits

Analyte ug/l ug/l % %

Chloride 3660 3640 1 0.646 15

Sulfate 16600 16600 1 0.137 15

Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)

(LCS) R3336193-2 08/22/18 17:55 • (LCSD) R3336193-3 08/22/18 18:09

Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l % % % % %

Chloride 40000 39400 38900 98.4 97.4 80.0-120 1.04 15

Sulfate 40000 39000 38900 97.5 97.4 80.0-120 0.116 15

L1019503-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)

(OS) L1019503-01 08/22/18 23:46 • (MS) R3336193-5 08/23/18 00:41 • (MSD) R3336193-6 08/23/18 00:55

Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l ug/l % % % % %

Chloride 50000 4780 55400 55000 101 101 1 80.0-120 0.676 15

Sulfate 50000 11700 61600 60600 99.8 97.9 1 80.0-120 1.56 15

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 14:38 13 of 23

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 17:10 13 of 23

Page 72: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1155784W e t C h e m i s t r y b y M e t h o d 9 0 5 6 A L 1 0 1 9 5 0 3 - 0 1 , 0 2

L1019600-01 Original Sample (OS) • Matrix Spike (MS)

(OS) L1019600-01 08/23/18 02:19 • (MS) R3336193-8 08/23/18 03:14

Spike Amount Original Result MS Result MS Rec. Dilution Rec. Limits MS Qualifier

Analyte ug/l ug/l ug/l % %

Chloride 50000 3660 54000 101 1 80.0-120

Sulfate 50000 16600 65800 98.4 1 80.0-120

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 14:38 14 of 23

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 17:10 14 of 23

Page 73: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1155930W e t C h e m i s t r y b y M e t h o d 9 0 6 0 A L 1 0 1 9 5 0 3 - 0 1 , 0 2

Method Blank (MB)

(MB) R3336327-1 08/23/18 09:30

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

TOC (Total Organic Carbon) 243 J 102 1000

Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)

(LCS) R3336327-2 08/23/18 10:15 • (LCSD) R3336327-5 08/23/18 12:46

Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l % % % % %

TOC 75000 72600 73100 96.8 97.4 85.0-115 0.673 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 14:38 15 of 23

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 17:10 15 of 23

Page 74: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1155542M e t a l s ( I C P M S ) b y M e t h o d 6 0 2 0 L 1 0 1 9 5 0 3 - 0 1 , 0 2 , 0 3 , 0 5

Method Blank (MB)

(MB) R3336304-1 08/23/18 21:04

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

Antimony U 0.754 2.00

Arsenic U 0.250 2.00

Barium 2.27 J 0.360 5.00

Beryllium U 0.120 2.00

Cadmium U 0.160 1.00

Chromium U 0.540 2.00

Copper U 0.520 5.00

Cobalt U 0.260 2.00

Iron U 15.0 100

Lead U 0.240 2.00

Manganese U 0.250 5.00

Nickel U 0.350 2.00

Selenium U 0.380 2.00

Silver U 0.310 2.00

Thallium U 0.190 2.00

Vanadium U 0.180 5.00

Zinc U 2.56 25.0

Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)

(LCS) R3336304-2 08/23/18 21:09 • (LCSD) R3336304-3 08/23/18 21:13

Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l % % % % %

Antimony 50.0 55.0 54.9 110 110 80.0-120 0.163 20

Arsenic 50.0 46.3 46.4 92.7 92.8 80.0-120 0.0725 20

Barium 50.0 52.8 48.1 106 96.3 80.0-120 9.25 20

Beryllium 50.0 45.0 45.2 90.0 90.4 80.0-120 0.508 20

Cadmium 50.0 47.0 46.9 94.0 93.8 80.0-120 0.242 20

Chromium 50.0 45.5 45.0 90.9 90.0 80.0-120 1.04 20

Copper 50.0 48.2 49.1 96.3 98.1 80.0-120 1.87 20

Cobalt 50.0 47.5 46.7 95.0 93.5 80.0-120 1.62 20

Iron 5000 4710 4720 94.2 94.3 80.0-120 0.104 20

Lead 50.0 47.2 47.0 94.3 93.9 80.0-120 0.435 20

Manganese 50.0 44.7 43.8 89.4 87.6 80.0-120 2.07 20

Nickel 50.0 46.8 46.0 93.7 92.0 80.0-120 1.77 20

Selenium 50.0 46.1 44.0 92.1 88.1 80.0-120 4.50 20

Silver 50.0 46.9 46.7 93.7 93.3 80.0-120 0.399 20

Thallium 50.0 48.1 47.5 96.2 95.1 80.0-120 1.21 20

Vanadium 50.0 44.7 44.5 89.4 89.0 80.0-120 0.432 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 14:38 16 of 23

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 17:10 16 of 23

Page 75: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1155542M e t a l s ( I C P M S ) b y M e t h o d 6 0 2 0 L 1 0 1 9 5 0 3 - 0 1 , 0 2 , 0 3 , 0 5

Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)

(LCS) R3336304-2 08/23/18 21:09 • (LCSD) R3336304-3 08/23/18 21:13

Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l % % % % %

Zinc 50.0 47.8 46.9 95.7 93.8 80.0-120 2.01 20

L1019087-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)

(OS) L1019087-03 08/23/18 21:18 • (MS) R3336304-5 08/23/18 21:27 • (MSD) R3336304-6 08/23/18 21:31

Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l ug/l % % % % %

Antimony 50.0 U 54.6 55.2 109 110 1 75.0-125 1.15 20

Arsenic 50.0 1.08 44.6 45.4 87.1 88.6 1 75.0-125 1.67 20

Barium 50.0 135 180 181 90.8 92.9 1 75.0-125 0.605 20

Beryllium 50.0 0.176 45.8 46.0 91.3 91.6 1 75.0-125 0.382 20

Cadmium 50.0 U 46.1 46.7 92.2 93.4 1 75.0-125 1.27 20

Chromium 50.0 U 42.4 43.5 84.9 86.9 1 75.0-125 2.39 20

Copper 50.0 0.571 46.0 47.6 90.9 94.0 1 75.0-125 3.27 20

Cobalt 50.0 4.27 48.7 49.4 88.9 90.3 1 75.0-125 1.40 20

Iron 5000 46.2 4450 4610 88.2 91.3 1 75.0-125 3.51 20

Lead 50.0 U 45.9 46.7 91.7 93.3 1 75.0-125 1.72 20

Manganese 50.0 331 365 368 67.5 74.4 1 75.0-125 V V 0.934 20

Nickel 50.0 4.19 48.4 48.9 88.4 89.4 1 75.0-125 1.01 20

Selenium 50.0 U 47.6 46.6 95.3 93.2 1 75.0-125 2.16 20

Silver 50.0 U 46.6 47.1 93.2 94.1 1 75.0-125 1.00 20

Thallium 50.0 0.276 46.9 47.8 93.2 95.0 1 75.0-125 1.85 20

Vanadium 50.0 U 42.1 43.2 84.1 86.3 1 75.0-125 2.57 20

Zinc 50.0 U 45.8 47.3 91.5 94.7 1 75.0-125 3.43 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 14:38 17 of 23

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 17:10 17 of 23

Page 76: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1155515V o l a t i l e O r g a n i c C o m p o u n d s ( G C / M S ) b y M e t h o d 8 2 6 0 B L 1 0 1 9 5 0 3 - 0 1 , 0 2 , 0 4

Method Blank (MB)

(MB) R3336570-2 08/21/18 20:56

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

Acetone U 10.0 50.0

Acrylonitrile U 1.87 10.0

Benzene U 0.331 1.00

Bromodichloromethane U 0.380 1.00

Bromochloromethane U 0.520 1.00

Bromoform U 0.469 1.00

Bromomethane U 0.866 5.00

Carbon disulfide U 0.275 1.00

Carbon tetrachloride U 0.379 1.00

Chlorobenzene U 0.348 1.00

Chlorodibromomethane U 0.327 1.00

Chloroethane U 0.453 5.00

Chloroform U 0.324 5.00

Chloromethane U 0.276 2.50

1,2-Dibromo-3-Chloropropane U 1.33 5.00

1,2-Dibromoethane U 0.381 1.00

Dibromomethane U 0.346 1.00

1,2-Dichlorobenzene U 0.349 1.00

1,4-Dichlorobenzene U 0.274 1.00

trans-1,4-Dichloro-2-butene U 0.866 2.50

1,1-Dichloroethane U 0.259 1.00

1,2-Dichloroethane U 0.361 1.00

1,1-Dichloroethene U 0.398 1.00

cis-1,2-Dichloroethene U 0.260 1.00

trans-1,2-Dichloroethene U 0.396 1.00

1,2-Dichloropropane U 0.306 1.00

cis-1,3-Dichloropropene U 0.418 1.00

trans-1,3-Dichloropropene U 0.419 1.00

Ethylbenzene U 0.384 1.00

2-Hexanone U 3.82 10.0

Iodomethane U 1.71 10.0

2-Butanone (MEK) U 3.93 15.0

Methylene Chloride U 1.00 5.00

4-Methyl-2-pentanone (MIBK) U 2.14 10.0

Styrene U 0.307 1.00

1,1,1,2-Tetrachloroethane U 0.385 1.00

1,1,2,2-Tetrachloroethane U 0.130 1.00

Tetrachloroethene U 0.372 1.00

Toluene U 0.412 1.00

1,1,1-Trichloroethane U 0.319 1.00

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 14:38 18 of 23

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 17:10 18 of 23

Page 77: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1155515V o l a t i l e O r g a n i c C o m p o u n d s ( G C / M S ) b y M e t h o d 8 2 6 0 B L 1 0 1 9 5 0 3 - 0 1 , 0 2 , 0 4

Method Blank (MB)

(MB) R3336570-2 08/21/18 20:56

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

1,1,2-Trichloroethane U 0.383 1.00

Trichloroethene U 0.398 1.00

Trichlorofluoromethane U 1.20 5.00

1,2,3-Trichloropropane U 0.807 2.50

Vinyl acetate U 1.63 10.0

Vinyl chloride U 0.259 1.00

Xylenes, Total U 1.06 3.00

(S) Toluene-d8 104 80.0-120

(S) Dibromofluoromethane 98.1 76.0-123

(S) 4-Bromofluorobenzene 98.6 80.0-120

Laboratory Control Sample (LCS)

(LCS) R3336570-1 08/21/18 20:17

Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier

Analyte ug/l ug/l % %

Acetone 125 123 98.2 10.0-160

Acrylonitrile 125 132 106 60.0-142

Benzene 25.0 26.6 107 69.0-123

Bromodichloromethane 25.0 23.2 92.9 76.0-120

Bromochloromethane 25.0 26.2 105 76.0-122

Bromoform 25.0 24.8 99.4 67.0-132

Bromomethane 25.0 27.0 108 18.0-160

Carbon disulfide 25.0 26.3 105 55.0-127

Carbon tetrachloride 25.0 24.4 97.6 63.0-122

Chlorobenzene 25.0 25.7 103 79.0-121

Chlorodibromomethane 25.0 25.2 101 75.0-125

Chloroethane 25.0 27.8 111 47.0-152

Chloroform 25.0 25.5 102 72.0-121

Chloromethane 25.0 27.5 110 48.0-139

1,2-Dibromo-3-Chloropropane 25.0 28.4 114 64.0-127

1,2-Dibromoethane 25.0 26.7 107 77.0-123

Dibromomethane 25.0 26.4 105 78.0-120

1,2-Dichlorobenzene 25.0 26.3 105 80.0-120

1,4-Dichlorobenzene 25.0 25.5 102 77.0-120

trans-1,4-Dichloro-2-butene 25.0 24.8 99.3 55.0-134

1,1-Dichloroethane 25.0 26.3 105 70.0-126

1,2-Dichloroethane 25.0 25.2 101 67.0-126

1,1-Dichloroethene 25.0 26.0 104 64.0-129

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 14:38 19 of 23

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 17:10 19 of 23

Page 78: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1155515V o l a t i l e O r g a n i c C o m p o u n d s ( G C / M S ) b y M e t h o d 8 2 6 0 B L 1 0 1 9 5 0 3 - 0 1 , 0 2 , 0 4

Laboratory Control Sample (LCS)

(LCS) R3336570-1 08/21/18 20:17

Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier

Analyte ug/l ug/l % %

cis-1,2-Dichloroethene 25.0 26.1 104 73.0-120

trans-1,2-Dichloroethene 25.0 26.1 104 71.0-121

1,2-Dichloropropane 25.0 25.8 103 75.0-125

cis-1,3-Dichloropropene 25.0 25.6 103 79.0-123

trans-1,3-Dichloropropene 25.0 25.2 101 74.0-127

Ethylbenzene 25.0 25.8 103 77.0-120

2-Hexanone 125 138 110 58.0-147

Iodomethane 125 122 97.6 57.0-140

2-Butanone (MEK) 125 149 119 37.0-158

Methylene Chloride 25.0 23.3 93.1 66.0-121

4-Methyl-2-pentanone (MIBK) 125 130 104 59.0-143

Styrene 25.0 25.0 100 78.0-124

1,1,1,2-Tetrachloroethane 25.0 24.1 96.3 75.0-122

1,1,2,2-Tetrachloroethane 25.0 27.1 108 71.0-122

Tetrachloroethene 25.0 24.9 99.7 70.0-127

Toluene 25.0 24.4 97.7 77.0-120

1,1,1-Trichloroethane 25.0 26.3 105 68.0-122

1,1,2-Trichloroethane 25.0 25.7 103 78.0-120

Trichloroethene 25.0 25.1 100 78.0-120

Trichlorofluoromethane 25.0 25.9 104 56.0-137

1,2,3-Trichloropropane 25.0 26.4 106 72.0-124

Vinyl acetate 125 124 99.2 46.0-160

Vinyl chloride 25.0 28.7 115 64.0-133

Xylenes, Total 75.0 76.8 102 77.0-120

(S) Toluene-d8 98.4 80.0-120

(S) Dibromofluoromethane 98.2 76.0-123

(S) 4-Bromofluorobenzene 99.4 80.0-120

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 14:38 20 of 23

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 17:10 20 of 23

Page 79: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.GLOSSARY OF TERMS

Guide to Reading and Understanding Your Laboratory Report

The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative.

Abbreviations and Definitions

MDL Method Detection Limit.

RDL Reported Detection Limit.

Rec. Recovery.

RPD Relative Percent Difference.

SDG Sample Delivery Group.

(S)Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be detected in all environmental media.

U Not detected at the Reporting Limit (or MDL where applicable).

Analyte The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported.

Dilution

If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor.

LimitsThese are the target % recovery ranges or % difference value that the laboratory has historically determined as normal for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or duplicated within these ranges.

Original Sample The non-spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control sample. The Original Sample may not be included within the reported SDG.

QualifierThis column provides a letter and/or number designation that corresponds to additional information concerning the resultreported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable.

Result

The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state “ND” (Not Detected) or “BDL” (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte.

Case Narrative (Cn)A brief discussion about the included sample results, including a discussion of any non-conformances to protocol observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.

Quality Control Summary (Qc)

This section of the report includes the results of the laboratory quality control analyses required by procedure or analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material.

Sample Chain of Custody (Sc)

This is the document created in the field when your samples were initially collected. This is used to verify the time and date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis.

Sample Results (Sr)This section of your report will provide the results of all testing performed on your samples. These results are provided by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section foreach sample will provide the name and method number for the analysis reported.

Sample Summary (Ss) This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates andtimes of preparation and/or analysis.

Qualifier Description

B The same analyte is found in the associated blank.

J The identification of the analyte is acceptable; the reported value is an estimate.

J3 The associated batch QC was outside the established quality control range for precision.

V The sample concentration is too high to evaluate accurate spike recoveries.

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 14:38 21 of 23

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 17:10 21 of 23

Page 80: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.

Pace National is the only environmental laboratory accredited/certified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as accessible or prepared to handle your needs throughout the country. Our capacity and capability from our single location laboratory is comparable to the collective totals of the network laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing turn-around time, and preventing cross contamination, thus protecting sample integrity. Our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE. * Not all certifications held by the laboratory are applicable to the results reported in the attached report. * Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace National.

State AccreditationsAlabama 40660 Nebraska NE-OS-15-05

Alaska 17-026 Nevada TN-03-2002-34

Arizona AZ0612 New Hampshire 2975

Arkansas 88-0469 New Jersey–NELAP TN002

California 2932 New Mexico ¹ n/a

Colorado TN00003 New York 11742

Connecticut PH-0197 North Carolina Env375

Florida E87487 North Carolina ¹ DW21704

Georgia NELAP North Carolina ³ 41

Georgia ¹ 923 North Dakota R-140

Idaho TN00003 Ohio–VAP CL0069

Illinois 200008 Oklahoma 9915

Indiana C-TN-01 Oregon TN200002

Iowa 364 Pennsylvania 68-02979

Kansas E-10277 Rhode Island LAO00356

Kentucky ¹ ⁶ 90010 South Carolina 84004

Kentucky ² 16 South Dakota n/a

Louisiana AI30792 Tennessee ¹ ⁴ 2006

Louisiana ¹ LA180010 Texas T 104704245-17-14

Maine TN0002 Texas ⁵ LAB0152

Maryland 324 Utah TN00003

Massachusetts M-TN003 Vermont VT2006

Michigan 9958 Virginia 460132

Minnesota 047-999-395 Washington C847

Mississippi TN00003 West Virginia 233

Missouri 340 Wisconsin 9980939910

Montana CERT0086 Wyoming A2LA

Third Party Federal AccreditationsA2LA – ISO 17025 1461.01 AIHA-LAP,LLC EMLAP 100789

A2LA – ISO 17025 ⁵ 1461.02 DOD 1461.01

Canada 1461.01 USDA P330-15-00234

EPA–Crypto TN00003

ACCREDITATIONS & LOCATIONS

¹ Drinking Water ² Underground Storage Tanks ³ Aquatic Toxicity ⁴ Chemical/Microbiological ⁵ Mold ⁶ Wastewater n/a Accreditation not applicable

Our LocationsPace National has sixty-four client support centers that provide sample pickup and/or the delivery of sampling supplies. If you would like assistance from one of our support offices, please contactour main office. Pace National performs all testing at our central laboratory.

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 14:38 22 of 23

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1019503 08/27/18 17:10 22 of 23

Page 81: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 82: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

November 2018 Sampling Event

Page 83: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ANALYTICAL REPORTNovember 20, 2018

Legacy Landfill

Sample Delivery Group: L1043691

Samples Received: 11/13/2018

Project Number: 04469-1767-001

Description: Craighead County - Legacy Landfill

Report To: Angela Sparks

P.O. Box 16777

Jonesboro, AR 72403

Entire Report Reviewed By:

November 20, 2018

[Preliminary Report]

Mark W. BeasleyPro ject Manager

Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace Nationalis performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304.

12065 Lebanon Rd Mount Jul iet , TN 37122 615-758-5858 800-767-5859 www.pacenational .com

November 21 , 2018

Mark W. BeasleyPro ject Manager

Page 84: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.TABLE OF CONTENTS

Cp: Cover Page 1

Tc: Table of Contents 2

Ss: Sample Summary 3

Cn: Case Narrative 5

Sr: Sample Results 6

TRIPBLANK L1043691-01 6

MW-14R L1043691-02 7

MW-16R L1043691-03 9

MW-17R L1043691-04 11

MW-19 L1043691-05 13

MW-22 L1043691-06 15

MW-16R DUP L1043691-07 17

Qc: Quality Control Summary 19

Gravimetric Analysis by Method 2540 C-2011 19

Wet Chemistry by Method 9056A 20

Wet Chemistry by Method 9060A 22

Metals (ICPMS) by Method 6020 24

Volatile Organic Compounds (GC/MS) by Method 8260B 26

Gl: Glossary of Terms 29

Al: Accreditations & Locations 30

Sc: Sample Chain of Custody 31

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 2 of 31

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 2 of 31

Page 85: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE SUMMARY

Collected by Collected date/time Received date/time

TRIPBLANK L1043691-01 GW Michael Clayton 11/12/18 00:00 11/13/18 08:45

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Volatile Organic Compounds (GC/MS) by Method 8260B WG1195901 1 11/13/18 15:09 11/13/18 15:09 PP

Collected by Collected date/time Received date/time

MW-14R L1043691-02 GW Michael Clayton 11/12/18 11:50 11/13/18 08:45

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Gravimetric Analysis by Method 2540 C-2011 WG1197217 1 11/16/18 13:38 11/16/18 14:25 MMF

Wet Chemistry by Method 9056A WG1196256 1 11/15/18 01:55 11/15/18 01:55 ELN

Wet Chemistry by Method 9060A WG1197777 1 11/16/18 22:49 11/16/18 22:49 SJM

Metals (ICPMS) by Method 6020 WG1196345 1 11/14/18 10:19 11/15/18 02:25 LAT

Volatile Organic Compounds (GC/MS) by Method 8260B WG1195901 1 11/13/18 15:48 11/13/18 15:48 PP

Collected by Collected date/time Received date/time

MW-16R L1043691-03 GW Michael Clayton 11/12/18 14:25 11/13/18 08:45

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Gravimetric Analysis by Method 2540 C-2011 WG1197217 1 11/16/18 13:38 11/16/18 14:25 MMF

Wet Chemistry by Method 9056A WG1196256 1 11/15/18 02:13 11/15/18 02:13 ELN

Wet Chemistry by Method 9060A WG1197777 1 11/16/18 23:09 11/16/18 23:09 SJM

Metals (ICPMS) by Method 6020 WG1196345 1 11/14/18 10:19 11/15/18 02:29 LAT

Volatile Organic Compounds (GC/MS) by Method 8260B WG1195901 1 11/13/18 16:07 11/13/18 16:07 PP

Collected by Collected date/time Received date/time

MW-17R L1043691-04 GW Michael Clayton 11/09/18 15:30 11/13/18 08:45

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Gravimetric Analysis by Method 2540 C-2011 WG1197217 1 11/16/18 13:38 11/16/18 14:25 MMF

Wet Chemistry by Method 9056A WG1196256 1 11/15/18 02:32 11/15/18 02:32 ELN

Wet Chemistry by Method 9060A WG1197777 1 11/17/18 00:55 11/17/18 00:55 SJM

Metals (ICPMS) by Method 6020 WG1196345 1 11/14/18 10:19 11/15/18 02:46 LAT

Volatile Organic Compounds (GC/MS) by Method 8260B WG1195901 1 11/13/18 16:26 11/13/18 16:26 PP

Collected by Collected date/time Received date/time

MW-19 L1043691-05 GW Michael Clayton 11/12/18 13:05 11/13/18 08:45

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Gravimetric Analysis by Method 2540 C-2011 WG1197217 1 11/16/18 13:38 11/16/18 14:25 MMF

Wet Chemistry by Method 9056A WG1196256 1 11/15/18 02:50 11/15/18 02:50 ELN

Wet Chemistry by Method 9060A WG1198811 1 11/19/18 14:02 11/19/18 14:02 SJM

Metals (ICPMS) by Method 6020 WG1196345 1 11/14/18 10:19 11/15/18 02:51 LAT

Volatile Organic Compounds (GC/MS) by Method 8260B WG1195901 1 11/13/18 16:46 11/13/18 16:46 PP

Collected by Collected date/time Received date/time

MW-22 L1043691-06 GW Michael Clayton 11/09/18 10:45 11/13/18 08:45

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Gravimetric Analysis by Method 2540 C-2011 WG1197217 1 11/16/18 13:38 11/16/18 14:25 MMF

Wet Chemistry by Method 9056A WG1196256 1 11/15/18 03:08 11/15/18 03:08 ELN

Wet Chemistry by Method 9060A WG1197777 1 11/17/18 01:34 11/17/18 01:34 SJM

Metals (ICPMS) by Method 6020 WG1196345 1 11/14/18 10:19 11/15/18 02:03 LAT

Volatile Organic Compounds (GC/MS) by Method 8260B WG1195901 1 11/13/18 17:05 11/13/18 17:05 PP

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 3 of 31

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 3 of 31

Page 86: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE SUMMARY

Collected by Collected date/time Received date/time

MW-16R DUP L1043691-07 GW Michael Clayton 11/12/18 14:30 11/13/18 08:45

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Gravimetric Analysis by Method 2540 C-2011 WG1197217 1 11/16/18 13:38 11/16/18 14:25 MMF

Wet Chemistry by Method 9056A WG1196256 1 11/15/18 03:26 11/15/18 03:26 ELN

Wet Chemistry by Method 9060A WG1197777 1 11/17/18 01:53 11/17/18 01:53 SJM

Metals (ICPMS) by Method 6020 WG1196345 1 11/14/18 10:19 11/15/18 02:55 LAT

Volatile Organic Compounds (GC/MS) by Method 8260B WG1195901 1 11/13/18 17:24 11/13/18 17:24 PP

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 4 of 31

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 4 of 31

Page 87: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.CASE NARRATIVE

All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated withinthe report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental sampleshave been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data.

[Preliminary Report]

Mark W. BeasleyPro jec t Manager

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 5 of 31

Mark W. BeasleyPro jec t Manager

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 5 of 31

Page 88: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 01L 1 0 4 3 6 9 1

TRIPBLANKC o l l e c t e d d a t e / t i m e : 1 1 / 1 2 / 1 8 0 0 : 0 0

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Acetone U 10.0 50.0 1 11/13/2018 15:09 WG1195901

Acrylonitrile U 1.87 10.0 1 11/13/2018 15:09 WG1195901

Benzene U 0.331 1.00 1 11/13/2018 15:09 WG1195901

Bromochloromethane U 0.520 1.00 1 11/13/2018 15:09 WG1195901

Bromodichloromethane U 0.380 1.00 1 11/13/2018 15:09 WG1195901

Bromoform U 0.469 1.00 1 11/13/2018 15:09 WG1195901

Bromomethane U 0.866 5.00 1 11/13/2018 15:09 WG1195901

Carbon disulfide 0.460 J 0.275 1.00 1 11/13/2018 15:09 WG1195901

Carbon tetrachloride U 0.379 1.00 1 11/13/2018 15:09 WG1195901

Chlorobenzene U 0.348 1.00 1 11/13/2018 15:09 WG1195901

Chlorodibromomethane U 0.327 1.00 1 11/13/2018 15:09 WG1195901

Chloroethane U 0.453 5.00 1 11/13/2018 15:09 WG1195901

Chloroform U 0.324 5.00 1 11/13/2018 15:09 WG1195901

Chloromethane U 0.276 2.50 1 11/13/2018 15:09 WG1195901

Dibromomethane U 0.346 1.00 1 11/13/2018 15:09 WG1195901

1,2-Dibromoethane U 0.381 1.00 1 11/13/2018 15:09 WG1195901

1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 11/13/2018 15:09 WG1195901

1,2-Dichlorobenzene U 0.349 1.00 1 11/13/2018 15:09 WG1195901

1,4-Dichlorobenzene U 0.274 1.00 1 11/13/2018 15:09 WG1195901

trans-1,4-Dichloro-2-butene U 0.866 2.50 1 11/13/2018 15:09 WG1195901

1,1-Dichloroethane U 0.259 1.00 1 11/13/2018 15:09 WG1195901

1,2-Dichloroethane U 0.361 1.00 1 11/13/2018 15:09 WG1195901

1,1-Dichloroethene U 0.398 1.00 1 11/13/2018 15:09 WG1195901

cis-1,2-Dichloroethene U 0.260 1.00 1 11/13/2018 15:09 WG1195901

trans-1,2-Dichloroethene U 0.396 1.00 1 11/13/2018 15:09 WG1195901

1,2-Dichloropropane U 0.306 1.00 1 11/13/2018 15:09 WG1195901

cis-1,3-Dichloropropene U 0.418 1.00 1 11/13/2018 15:09 WG1195901

trans-1,3-Dichloropropene U 0.419 1.00 1 11/13/2018 15:09 WG1195901

Ethylbenzene U 0.384 1.00 1 11/13/2018 15:09 WG1195901

2-Hexanone U 3.82 10.0 1 11/13/2018 15:09 WG1195901

Iodomethane U 1.71 10.0 1 11/13/2018 15:09 WG1195901

2-Butanone (MEK) U 3.93 15.0 1 11/13/2018 15:09 WG1195901

Methylene Chloride U 1.00 5.00 1 11/13/2018 15:09 WG1195901

4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 11/13/2018 15:09 WG1195901

Styrene U 0.307 1.00 1 11/13/2018 15:09 WG1195901

1,1,1,2-Tetrachloroethane U 0.385 1.00 1 11/13/2018 15:09 WG1195901

1,1,2,2-Tetrachloroethane U 0.130 1.00 1 11/13/2018 15:09 WG1195901

Tetrachloroethene U 0.372 1.00 1 11/13/2018 15:09 WG1195901

Toluene U 0.412 1.00 1 11/13/2018 15:09 WG1195901

1,1,1-Trichloroethane U 0.319 1.00 1 11/13/2018 15:09 WG1195901

1,1,2-Trichloroethane U 0.383 1.00 1 11/13/2018 15:09 WG1195901

Trichloroethene U 0.398 1.00 1 11/13/2018 15:09 WG1195901

Trichlorofluoromethane U 1.20 5.00 1 11/13/2018 15:09 WG1195901

1,2,3-Trichloropropane U 0.807 2.50 1 11/13/2018 15:09 WG1195901

Vinyl acetate U 1.63 10.0 1 11/13/2018 15:09 WG1195901

Vinyl chloride U 0.259 1.00 1 11/13/2018 15:09 WG1195901

Xylenes, Total U 1.06 3.00 1 11/13/2018 15:09 WG1195901

(S) Toluene-d8 110 80.0-120 11/13/2018 15:09 WG1195901

(S) Dibromofluoromethane 90.4 75.0-120 11/13/2018 15:09 WG1195901

(S) 4-Bromofluorobenzene 96.6 77.0-126 11/13/2018 15:09 WG1195901

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 6 of 31

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 6 of 31

Page 89: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 02L 1 0 4 3 6 9 1

MW-14RC o l l e c t e d d a t e / t i m e : 1 1 / 1 2 / 1 8 1 1 : 5 0

Gravimetric Analysis by Method 2540 C-2011

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Dissolved Solids 533000 2820 10000 1 11/16/2018 14:25 WG1197217

Wet Chemistry by Method 9056A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Chloride 44700 51.9 1000 1 11/15/2018 01:55 WG1196256

Sulfate 64100 77.4 5000 1 11/15/2018 01:55 WG1196256

Wet Chemistry by Method 9060A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

TOC (Total Organic Carbon) 937 J 102 1000 1 11/16/2018 22:49 WG1197777

Metals (ICPMS) by Method 6020

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Antimony U 0.754 2.00 1 11/15/2018 02:25 WG1196345

Arsenic 1.17 J 0.250 2.00 1 11/15/2018 02:25 WG1196345

Barium 254 0.360 5.00 1 11/15/2018 02:25 WG1196345

Beryllium U 0.120 2.00 1 11/15/2018 02:25 WG1196345

Cadmium U 0.160 1.00 1 11/15/2018 02:25 WG1196345

Chromium U 0.540 2.00 1 11/15/2018 02:25 WG1196345

Copper 7.78 0.520 5.00 1 11/15/2018 02:25 WG1196345

Cobalt 0.644 J 0.260 2.00 1 11/15/2018 02:25 WG1196345

Iron 5540 15.0 100 1 11/15/2018 02:25 WG1196345

Lead 0.288 J 0.240 2.00 1 11/15/2018 02:25 WG1196345

Manganese 355 0.250 5.00 1 11/15/2018 02:25 WG1196345

Nickel 0.463 J 0.350 2.00 1 11/15/2018 02:25 WG1196345

Selenium U 0.380 2.00 1 11/15/2018 02:25 WG1196345

Silver U 0.310 2.00 1 11/15/2018 02:25 WG1196345

Thallium U 0.190 2.00 1 11/15/2018 02:25 WG1196345

Vanadium U 0.180 5.00 1 11/15/2018 02:25 WG1196345

Zinc U 2.56 25.0 1 11/15/2018 02:25 WG1196345

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Acetone U 10.0 50.0 1 11/13/2018 15:48 WG1195901

Acrylonitrile U 1.87 10.0 1 11/13/2018 15:48 WG1195901

Benzene U 0.331 1.00 1 11/13/2018 15:48 WG1195901

Bromochloromethane U 0.520 1.00 1 11/13/2018 15:48 WG1195901

Bromodichloromethane U 0.380 1.00 1 11/13/2018 15:48 WG1195901

Bromoform U 0.469 1.00 1 11/13/2018 15:48 WG1195901

Bromomethane U 0.866 5.00 1 11/13/2018 15:48 WG1195901

Carbon disulfide U 0.275 1.00 1 11/13/2018 15:48 WG1195901

Carbon tetrachloride U 0.379 1.00 1 11/13/2018 15:48 WG1195901

Chlorobenzene U 0.348 1.00 1 11/13/2018 15:48 WG1195901

Chlorodibromomethane U 0.327 1.00 1 11/13/2018 15:48 WG1195901

Chloroethane U 0.453 5.00 1 11/13/2018 15:48 WG1195901

Chloroform U 0.324 5.00 1 11/13/2018 15:48 WG1195901

Chloromethane U 0.276 2.50 1 11/13/2018 15:48 WG1195901

Dibromomethane U 0.346 1.00 1 11/13/2018 15:48 WG1195901

1,2-Dibromoethane U 0.381 1.00 1 11/13/2018 15:48 WG1195901

1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 11/13/2018 15:48 WG1195901

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 7 of 31

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 7 of 31

Page 90: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 02L 1 0 4 3 6 9 1

MW-14RC o l l e c t e d d a t e / t i m e : 1 1 / 1 2 / 1 8 1 1 : 5 0

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

1,2-Dichlorobenzene U 0.349 1.00 1 11/13/2018 15:48 WG1195901

1,4-Dichlorobenzene U 0.274 1.00 1 11/13/2018 15:48 WG1195901

trans-1,4-Dichloro-2-butene U 0.866 2.50 1 11/13/2018 15:48 WG1195901

1,1-Dichloroethane U 0.259 1.00 1 11/13/2018 15:48 WG1195901

1,2-Dichloroethane U 0.361 1.00 1 11/13/2018 15:48 WG1195901

1,1-Dichloroethene U 0.398 1.00 1 11/13/2018 15:48 WG1195901

cis-1,2-Dichloroethene U 0.260 1.00 1 11/13/2018 15:48 WG1195901

trans-1,2-Dichloroethene U 0.396 1.00 1 11/13/2018 15:48 WG1195901

1,2-Dichloropropane U 0.306 1.00 1 11/13/2018 15:48 WG1195901

cis-1,3-Dichloropropene U 0.418 1.00 1 11/13/2018 15:48 WG1195901

trans-1,3-Dichloropropene U 0.419 1.00 1 11/13/2018 15:48 WG1195901

Ethylbenzene U 0.384 1.00 1 11/13/2018 15:48 WG1195901

2-Hexanone U 3.82 10.0 1 11/13/2018 15:48 WG1195901

Iodomethane U 1.71 10.0 1 11/13/2018 15:48 WG1195901

2-Butanone (MEK) U 3.93 15.0 1 11/13/2018 15:48 WG1195901

Methylene Chloride U 1.00 5.00 1 11/13/2018 15:48 WG1195901

4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 11/13/2018 15:48 WG1195901

Styrene U 0.307 1.00 1 11/13/2018 15:48 WG1195901

1,1,1,2-Tetrachloroethane U 0.385 1.00 1 11/13/2018 15:48 WG1195901

1,1,2,2-Tetrachloroethane U 0.130 1.00 1 11/13/2018 15:48 WG1195901

Tetrachloroethene U 0.372 1.00 1 11/13/2018 15:48 WG1195901

Toluene U 0.412 1.00 1 11/13/2018 15:48 WG1195901

1,1,1-Trichloroethane U 0.319 1.00 1 11/13/2018 15:48 WG1195901

1,1,2-Trichloroethane U 0.383 1.00 1 11/13/2018 15:48 WG1195901

Trichloroethene U 0.398 1.00 1 11/13/2018 15:48 WG1195901

Trichlorofluoromethane U 1.20 5.00 1 11/13/2018 15:48 WG1195901

1,2,3-Trichloropropane U 0.807 2.50 1 11/13/2018 15:48 WG1195901

Vinyl acetate U 1.63 10.0 1 11/13/2018 15:48 WG1195901

Vinyl chloride U 0.259 1.00 1 11/13/2018 15:48 WG1195901

Xylenes, Total U 1.06 3.00 1 11/13/2018 15:48 WG1195901

(S) Toluene-d8 107 80.0-120 11/13/2018 15:48 WG1195901

(S) Dibromofluoromethane 91.4 75.0-120 11/13/2018 15:48 WG1195901

(S) 4-Bromofluorobenzene 97.0 77.0-126 11/13/2018 15:48 WG1195901

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 8 of 31

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 8 of 31

Page 91: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 03L 1 0 4 3 6 9 1

MW-16RC o l l e c t e d d a t e / t i m e : 1 1 / 1 2 / 1 8 1 4 : 2 5

Gravimetric Analysis by Method 2540 C-2011

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Dissolved Solids 276000 2820 10000 1 11/16/2018 14:25 WG1197217

Wet Chemistry by Method 9056A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Chloride 6880 51.9 1000 1 11/15/2018 02:13 WG1196256

Sulfate 17300 77.4 5000 1 11/15/2018 02:13 WG1196256

Wet Chemistry by Method 9060A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

TOC (Total Organic Carbon) 702 J 102 1000 1 11/16/2018 23:09 WG1197777

Metals (ICPMS) by Method 6020

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Antimony U 0.754 2.00 1 11/15/2018 02:29 WG1196345

Arsenic 0.940 J 0.250 2.00 1 11/15/2018 02:29 WG1196345

Barium 90.8 0.360 5.00 1 11/15/2018 02:29 WG1196345

Beryllium U 0.120 2.00 1 11/15/2018 02:29 WG1196345

Cadmium U 0.160 1.00 1 11/15/2018 02:29 WG1196345

Chromium U 0.540 2.00 1 11/15/2018 02:29 WG1196345

Copper 0.948 J 0.520 5.00 1 11/15/2018 02:29 WG1196345

Cobalt U 0.260 2.00 1 11/15/2018 02:29 WG1196345

Iron 519 15.0 100 1 11/15/2018 02:29 WG1196345

Lead 0.344 J 0.240 2.00 1 11/15/2018 02:29 WG1196345

Manganese 567 0.250 5.00 1 11/15/2018 02:29 WG1196345

Nickel U 0.350 2.00 1 11/15/2018 02:29 WG1196345

Selenium U 0.380 2.00 1 11/15/2018 02:29 WG1196345

Silver 0.470 J 0.310 2.00 1 11/15/2018 02:29 WG1196345

Thallium U 0.190 2.00 1 11/15/2018 02:29 WG1196345

Vanadium 0.214 J 0.180 5.00 1 11/15/2018 02:29 WG1196345

Zinc U 2.56 25.0 1 11/15/2018 02:29 WG1196345

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Acetone U 10.0 50.0 1 11/13/2018 16:07 WG1195901

Acrylonitrile U 1.87 10.0 1 11/13/2018 16:07 WG1195901

Benzene U 0.331 1.00 1 11/13/2018 16:07 WG1195901

Bromochloromethane U 0.520 1.00 1 11/13/2018 16:07 WG1195901

Bromodichloromethane U 0.380 1.00 1 11/13/2018 16:07 WG1195901

Bromoform U 0.469 1.00 1 11/13/2018 16:07 WG1195901

Bromomethane U 0.866 5.00 1 11/13/2018 16:07 WG1195901

Carbon disulfide U 0.275 1.00 1 11/13/2018 16:07 WG1195901

Carbon tetrachloride U 0.379 1.00 1 11/13/2018 16:07 WG1195901

Chlorobenzene U 0.348 1.00 1 11/13/2018 16:07 WG1195901

Chlorodibromomethane U 0.327 1.00 1 11/13/2018 16:07 WG1195901

Chloroethane U 0.453 5.00 1 11/13/2018 16:07 WG1195901

Chloroform U 0.324 5.00 1 11/13/2018 16:07 WG1195901

Chloromethane U 0.276 2.50 1 11/13/2018 16:07 WG1195901

Dibromomethane U 0.346 1.00 1 11/13/2018 16:07 WG1195901

1,2-Dibromoethane U 0.381 1.00 1 11/13/2018 16:07 WG1195901

1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 11/13/2018 16:07 WG1195901

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 9 of 31

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 9 of 31

Page 92: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 03L 1 0 4 3 6 9 1

MW-16RC o l l e c t e d d a t e / t i m e : 1 1 / 1 2 / 1 8 1 4 : 2 5

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

1,2-Dichlorobenzene U 0.349 1.00 1 11/13/2018 16:07 WG1195901

1,4-Dichlorobenzene U 0.274 1.00 1 11/13/2018 16:07 WG1195901

trans-1,4-Dichloro-2-butene U 0.866 2.50 1 11/13/2018 16:07 WG1195901

1,1-Dichloroethane U 0.259 1.00 1 11/13/2018 16:07 WG1195901

1,2-Dichloroethane U 0.361 1.00 1 11/13/2018 16:07 WG1195901

1,1-Dichloroethene U 0.398 1.00 1 11/13/2018 16:07 WG1195901

cis-1,2-Dichloroethene U 0.260 1.00 1 11/13/2018 16:07 WG1195901

trans-1,2-Dichloroethene U 0.396 1.00 1 11/13/2018 16:07 WG1195901

1,2-Dichloropropane U 0.306 1.00 1 11/13/2018 16:07 WG1195901

cis-1,3-Dichloropropene U 0.418 1.00 1 11/13/2018 16:07 WG1195901

trans-1,3-Dichloropropene U 0.419 1.00 1 11/13/2018 16:07 WG1195901

Ethylbenzene U 0.384 1.00 1 11/13/2018 16:07 WG1195901

2-Hexanone U 3.82 10.0 1 11/13/2018 16:07 WG1195901

Iodomethane U 1.71 10.0 1 11/13/2018 16:07 WG1195901

2-Butanone (MEK) U 3.93 15.0 1 11/13/2018 16:07 WG1195901

Methylene Chloride U 1.00 5.00 1 11/13/2018 16:07 WG1195901

4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 11/13/2018 16:07 WG1195901

Styrene U 0.307 1.00 1 11/13/2018 16:07 WG1195901

1,1,1,2-Tetrachloroethane U 0.385 1.00 1 11/13/2018 16:07 WG1195901

1,1,2,2-Tetrachloroethane U 0.130 1.00 1 11/13/2018 16:07 WG1195901

Tetrachloroethene U 0.372 1.00 1 11/13/2018 16:07 WG1195901

Toluene U 0.412 1.00 1 11/13/2018 16:07 WG1195901

1,1,1-Trichloroethane U 0.319 1.00 1 11/13/2018 16:07 WG1195901

1,1,2-Trichloroethane U 0.383 1.00 1 11/13/2018 16:07 WG1195901

Trichloroethene U 0.398 1.00 1 11/13/2018 16:07 WG1195901

Trichlorofluoromethane U 1.20 5.00 1 11/13/2018 16:07 WG1195901

1,2,3-Trichloropropane U 0.807 2.50 1 11/13/2018 16:07 WG1195901

Vinyl acetate U 1.63 10.0 1 11/13/2018 16:07 WG1195901

Vinyl chloride U 0.259 1.00 1 11/13/2018 16:07 WG1195901

Xylenes, Total U 1.06 3.00 1 11/13/2018 16:07 WG1195901

(S) Toluene-d8 110 80.0-120 11/13/2018 16:07 WG1195901

(S) Dibromofluoromethane 91.8 75.0-120 11/13/2018 16:07 WG1195901

(S) 4-Bromofluorobenzene 95.1 77.0-126 11/13/2018 16:07 WG1195901

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 10 of 31

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 10 of 31

Page 93: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 04L 1 0 4 3 6 9 1

MW-17RC o l l e c t e d d a t e / t i m e : 1 1 / 0 9 / 1 8 1 5 : 3 0

Gravimetric Analysis by Method 2540 C-2011

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Dissolved Solids 349000 2820 10000 1 11/16/2018 14:25 WG1197217

Wet Chemistry by Method 9056A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Chloride 7320 51.9 1000 1 11/15/2018 02:32 WG1196256

Sulfate 30100 77.4 5000 1 11/15/2018 02:32 WG1196256

Wet Chemistry by Method 9060A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

TOC (Total Organic Carbon) 713 J 102 1000 1 11/17/2018 00:55 WG1197777

Metals (ICPMS) by Method 6020

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Antimony U 0.754 2.00 1 11/15/2018 02:46 WG1196345

Arsenic 1.11 J 0.250 2.00 1 11/15/2018 02:46 WG1196345

Barium 105 0.360 5.00 1 11/15/2018 02:46 WG1196345

Beryllium U 0.120 2.00 1 11/15/2018 02:46 WG1196345

Cadmium U 0.160 1.00 1 11/15/2018 02:46 WG1196345

Chromium U 0.540 2.00 1 11/15/2018 02:46 WG1196345

Copper 1.39 J 0.520 5.00 1 11/15/2018 02:46 WG1196345

Cobalt U 0.260 2.00 1 11/15/2018 02:46 WG1196345

Iron 2240 15.0 100 1 11/15/2018 02:46 WG1196345

Lead 0.401 J 0.240 2.00 1 11/15/2018 02:46 WG1196345

Manganese 51.0 0.250 5.00 1 11/15/2018 02:46 WG1196345

Nickel U 0.350 2.00 1 11/15/2018 02:46 WG1196345

Selenium U 0.380 2.00 1 11/15/2018 02:46 WG1196345

Silver U 0.310 2.00 1 11/15/2018 02:46 WG1196345

Thallium U 0.190 2.00 1 11/15/2018 02:46 WG1196345

Vanadium U 0.180 5.00 1 11/15/2018 02:46 WG1196345

Zinc U 2.56 25.0 1 11/15/2018 02:46 WG1196345

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Acetone U 10.0 50.0 1 11/13/2018 16:26 WG1195901

Acrylonitrile U 1.87 10.0 1 11/13/2018 16:26 WG1195901

Benzene U 0.331 1.00 1 11/13/2018 16:26 WG1195901

Bromochloromethane U 0.520 1.00 1 11/13/2018 16:26 WG1195901

Bromodichloromethane U 0.380 1.00 1 11/13/2018 16:26 WG1195901

Bromoform U 0.469 1.00 1 11/13/2018 16:26 WG1195901

Bromomethane U 0.866 5.00 1 11/13/2018 16:26 WG1195901

Carbon disulfide U 0.275 1.00 1 11/13/2018 16:26 WG1195901

Carbon tetrachloride U 0.379 1.00 1 11/13/2018 16:26 WG1195901

Chlorobenzene U 0.348 1.00 1 11/13/2018 16:26 WG1195901

Chlorodibromomethane U 0.327 1.00 1 11/13/2018 16:26 WG1195901

Chloroethane U 0.453 5.00 1 11/13/2018 16:26 WG1195901

Chloroform U 0.324 5.00 1 11/13/2018 16:26 WG1195901

Chloromethane U 0.276 2.50 1 11/13/2018 16:26 WG1195901

Dibromomethane U 0.346 1.00 1 11/13/2018 16:26 WG1195901

1,2-Dibromoethane U 0.381 1.00 1 11/13/2018 16:26 WG1195901

1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 11/13/2018 16:26 WG1195901

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 11 of 31

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 11 of 31

Page 94: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 04L 1 0 4 3 6 9 1

MW-17RC o l l e c t e d d a t e / t i m e : 1 1 / 0 9 / 1 8 1 5 : 3 0

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

1,2-Dichlorobenzene U 0.349 1.00 1 11/13/2018 16:26 WG1195901

1,4-Dichlorobenzene U 0.274 1.00 1 11/13/2018 16:26 WG1195901

trans-1,4-Dichloro-2-butene U 0.866 2.50 1 11/13/2018 16:26 WG1195901

1,1-Dichloroethane U 0.259 1.00 1 11/13/2018 16:26 WG1195901

1,2-Dichloroethane U 0.361 1.00 1 11/13/2018 16:26 WG1195901

1,1-Dichloroethene U 0.398 1.00 1 11/13/2018 16:26 WG1195901

cis-1,2-Dichloroethene U 0.260 1.00 1 11/13/2018 16:26 WG1195901

trans-1,2-Dichloroethene U 0.396 1.00 1 11/13/2018 16:26 WG1195901

1,2-Dichloropropane U 0.306 1.00 1 11/13/2018 16:26 WG1195901

cis-1,3-Dichloropropene U 0.418 1.00 1 11/13/2018 16:26 WG1195901

trans-1,3-Dichloropropene U 0.419 1.00 1 11/13/2018 16:26 WG1195901

Ethylbenzene U 0.384 1.00 1 11/13/2018 16:26 WG1195901

2-Hexanone U 3.82 10.0 1 11/13/2018 16:26 WG1195901

Iodomethane U 1.71 10.0 1 11/13/2018 16:26 WG1195901

2-Butanone (MEK) U 3.93 15.0 1 11/13/2018 16:26 WG1195901

Methylene Chloride U 1.00 5.00 1 11/13/2018 16:26 WG1195901

4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 11/13/2018 16:26 WG1195901

Styrene U 0.307 1.00 1 11/13/2018 16:26 WG1195901

1,1,1,2-Tetrachloroethane U 0.385 1.00 1 11/13/2018 16:26 WG1195901

1,1,2,2-Tetrachloroethane U 0.130 1.00 1 11/13/2018 16:26 WG1195901

Tetrachloroethene U 0.372 1.00 1 11/13/2018 16:26 WG1195901

Toluene U 0.412 1.00 1 11/13/2018 16:26 WG1195901

1,1,1-Trichloroethane U 0.319 1.00 1 11/13/2018 16:26 WG1195901

1,1,2-Trichloroethane U 0.383 1.00 1 11/13/2018 16:26 WG1195901

Trichloroethene U 0.398 1.00 1 11/13/2018 16:26 WG1195901

Trichlorofluoromethane U 1.20 5.00 1 11/13/2018 16:26 WG1195901

1,2,3-Trichloropropane U 0.807 2.50 1 11/13/2018 16:26 WG1195901

Vinyl acetate U 1.63 10.0 1 11/13/2018 16:26 WG1195901

Vinyl chloride U 0.259 1.00 1 11/13/2018 16:26 WG1195901

Xylenes, Total U 1.06 3.00 1 11/13/2018 16:26 WG1195901

(S) Toluene-d8 110 80.0-120 11/13/2018 16:26 WG1195901

(S) Dibromofluoromethane 90.5 75.0-120 11/13/2018 16:26 WG1195901

(S) 4-Bromofluorobenzene 94.6 77.0-126 11/13/2018 16:26 WG1195901

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 12 of 31

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 12 of 31

Page 95: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 05L 1 0 4 3 6 9 1

MW-19C o l l e c t e d d a t e / t i m e : 1 1 / 1 2 / 1 8 1 3 : 0 5

Gravimetric Analysis by Method 2540 C-2011

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Dissolved Solids 387000 2820 10000 1 11/16/2018 14:25 WG1197217

Wet Chemistry by Method 9056A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Chloride 12200 51.9 1000 1 11/15/2018 02:50 WG1196256

Sulfate 34100 77.4 5000 1 11/15/2018 02:50 WG1196256

Wet Chemistry by Method 9060A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

TOC (Total Organic Carbon) 975 J 102 1000 1 11/19/2018 14:02 WG1198811

Metals (ICPMS) by Method 6020

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Antimony U 0.754 2.00 1 11/15/2018 02:51 WG1196345

Arsenic 0.815 J 0.250 2.00 1 11/15/2018 02:51 WG1196345

Barium 188 0.360 5.00 1 11/15/2018 02:51 WG1196345

Beryllium U 0.120 2.00 1 11/15/2018 02:51 WG1196345

Cadmium U 0.160 1.00 1 11/15/2018 02:51 WG1196345

Chromium U 0.540 2.00 1 11/15/2018 02:51 WG1196345

Copper 0.618 J 0.520 5.00 1 11/15/2018 02:51 WG1196345

Cobalt U 0.260 2.00 1 11/15/2018 02:51 WG1196345

Iron 1420 15.0 100 1 11/15/2018 02:51 WG1196345

Lead 0.254 J 0.240 2.00 1 11/15/2018 02:51 WG1196345

Manganese 619 0.250 5.00 1 11/15/2018 02:51 WG1196345

Nickel U 0.350 2.00 1 11/15/2018 02:51 WG1196345

Selenium U 0.380 2.00 1 11/15/2018 02:51 WG1196345

Silver U 0.310 2.00 1 11/15/2018 02:51 WG1196345

Thallium U 0.190 2.00 1 11/15/2018 02:51 WG1196345

Vanadium U 0.180 5.00 1 11/15/2018 02:51 WG1196345

Zinc U 2.56 25.0 1 11/15/2018 02:51 WG1196345

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Acetone U 10.0 50.0 1 11/13/2018 16:46 WG1195901

Acrylonitrile U 1.87 10.0 1 11/13/2018 16:46 WG1195901

Benzene U 0.331 1.00 1 11/13/2018 16:46 WG1195901

Bromochloromethane U 0.520 1.00 1 11/13/2018 16:46 WG1195901

Bromodichloromethane U 0.380 1.00 1 11/13/2018 16:46 WG1195901

Bromoform U 0.469 1.00 1 11/13/2018 16:46 WG1195901

Bromomethane U 0.866 5.00 1 11/13/2018 16:46 WG1195901

Carbon disulfide U 0.275 1.00 1 11/13/2018 16:46 WG1195901

Carbon tetrachloride U 0.379 1.00 1 11/13/2018 16:46 WG1195901

Chlorobenzene U 0.348 1.00 1 11/13/2018 16:46 WG1195901

Chlorodibromomethane U 0.327 1.00 1 11/13/2018 16:46 WG1195901

Chloroethane U 0.453 5.00 1 11/13/2018 16:46 WG1195901

Chloroform U 0.324 5.00 1 11/13/2018 16:46 WG1195901

Chloromethane U 0.276 2.50 1 11/13/2018 16:46 WG1195901

Dibromomethane U 0.346 1.00 1 11/13/2018 16:46 WG1195901

1,2-Dibromoethane U 0.381 1.00 1 11/13/2018 16:46 WG1195901

1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 11/13/2018 16:46 WG1195901

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 13 of 31

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 13 of 31

Page 96: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 05L 1 0 4 3 6 9 1

MW-19C o l l e c t e d d a t e / t i m e : 1 1 / 1 2 / 1 8 1 3 : 0 5

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

1,2-Dichlorobenzene U 0.349 1.00 1 11/13/2018 16:46 WG1195901

1,4-Dichlorobenzene U 0.274 1.00 1 11/13/2018 16:46 WG1195901

trans-1,4-Dichloro-2-butene U 0.866 2.50 1 11/13/2018 16:46 WG1195901

1,1-Dichloroethane U 0.259 1.00 1 11/13/2018 16:46 WG1195901

1,2-Dichloroethane U 0.361 1.00 1 11/13/2018 16:46 WG1195901

1,1-Dichloroethene U 0.398 1.00 1 11/13/2018 16:46 WG1195901

cis-1,2-Dichloroethene U 0.260 1.00 1 11/13/2018 16:46 WG1195901

trans-1,2-Dichloroethene U 0.396 1.00 1 11/13/2018 16:46 WG1195901

1,2-Dichloropropane U 0.306 1.00 1 11/13/2018 16:46 WG1195901

cis-1,3-Dichloropropene U 0.418 1.00 1 11/13/2018 16:46 WG1195901

trans-1,3-Dichloropropene U 0.419 1.00 1 11/13/2018 16:46 WG1195901

Ethylbenzene U 0.384 1.00 1 11/13/2018 16:46 WG1195901

2-Hexanone U 3.82 10.0 1 11/13/2018 16:46 WG1195901

Iodomethane U 1.71 10.0 1 11/13/2018 16:46 WG1195901

2-Butanone (MEK) U 3.93 15.0 1 11/13/2018 16:46 WG1195901

Methylene Chloride U 1.00 5.00 1 11/13/2018 16:46 WG1195901

4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 11/13/2018 16:46 WG1195901

Styrene U 0.307 1.00 1 11/13/2018 16:46 WG1195901

1,1,1,2-Tetrachloroethane U 0.385 1.00 1 11/13/2018 16:46 WG1195901

1,1,2,2-Tetrachloroethane U 0.130 1.00 1 11/13/2018 16:46 WG1195901

Tetrachloroethene U 0.372 1.00 1 11/13/2018 16:46 WG1195901

Toluene U 0.412 1.00 1 11/13/2018 16:46 WG1195901

1,1,1-Trichloroethane U 0.319 1.00 1 11/13/2018 16:46 WG1195901

1,1,2-Trichloroethane U 0.383 1.00 1 11/13/2018 16:46 WG1195901

Trichloroethene U 0.398 1.00 1 11/13/2018 16:46 WG1195901

Trichlorofluoromethane U 1.20 5.00 1 11/13/2018 16:46 WG1195901

1,2,3-Trichloropropane U 0.807 2.50 1 11/13/2018 16:46 WG1195901

Vinyl acetate U 1.63 10.0 1 11/13/2018 16:46 WG1195901

Vinyl chloride U 0.259 1.00 1 11/13/2018 16:46 WG1195901

Xylenes, Total U 1.06 3.00 1 11/13/2018 16:46 WG1195901

(S) Toluene-d8 107 80.0-120 11/13/2018 16:46 WG1195901

(S) Dibromofluoromethane 90.8 75.0-120 11/13/2018 16:46 WG1195901

(S) 4-Bromofluorobenzene 94.9 77.0-126 11/13/2018 16:46 WG1195901

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 14 of 31

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 14 of 31

Page 97: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 06L 1 0 4 3 6 9 1

MW-22C o l l e c t e d d a t e / t i m e : 1 1 / 0 9 / 1 8 1 0 : 4 5

Gravimetric Analysis by Method 2540 C-2011

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Dissolved Solids 212000 2820 10000 1 11/16/2018 14:25 WG1197217

Wet Chemistry by Method 9056A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Chloride 4110 51.9 1000 1 11/15/2018 03:08 WG1196256

Sulfate 7220 77.4 5000 1 11/15/2018 03:08 WG1196256

Wet Chemistry by Method 9060A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

TOC (Total Organic Carbon) 726 J 102 1000 1 11/17/2018 01:34 WG1197777

Metals (ICPMS) by Method 6020

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Antimony U 0.754 2.00 1 11/15/2018 02:03 WG1196345

Arsenic 1.99 J 0.250 2.00 1 11/15/2018 02:03 WG1196345

Barium 53.3 0.360 5.00 1 11/15/2018 02:03 WG1196345

Beryllium U 0.120 2.00 1 11/15/2018 02:03 WG1196345

Cadmium U 0.160 1.00 1 11/15/2018 02:03 WG1196345

Chromium U 0.540 2.00 1 11/15/2018 02:03 WG1196345

Copper U 0.520 5.00 1 11/15/2018 02:03 WG1196345

Cobalt U 0.260 2.00 1 11/15/2018 02:03 WG1196345

Iron 392 15.0 100 1 11/15/2018 02:03 WG1196345

Lead 0.535 J 0.240 2.00 1 11/15/2018 02:03 WG1196345

Manganese 234 0.250 5.00 1 11/15/2018 02:03 WG1196345

Nickel U 0.350 2.00 1 11/15/2018 02:03 WG1196345

Selenium U 0.380 2.00 1 11/15/2018 02:03 WG1196345

Silver U 0.310 2.00 1 11/15/2018 02:03 WG1196345

Thallium U 0.190 2.00 1 11/15/2018 02:03 WG1196345

Vanadium U 0.180 5.00 1 11/15/2018 02:03 WG1196345

Zinc U 2.56 25.0 1 11/15/2018 02:03 WG1196345

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Acetone U 10.0 50.0 1 11/13/2018 17:05 WG1195901

Acrylonitrile U 1.87 10.0 1 11/13/2018 17:05 WG1195901

Benzene U 0.331 1.00 1 11/13/2018 17:05 WG1195901

Bromochloromethane U 0.520 1.00 1 11/13/2018 17:05 WG1195901

Bromodichloromethane U 0.380 1.00 1 11/13/2018 17:05 WG1195901

Bromoform U 0.469 1.00 1 11/13/2018 17:05 WG1195901

Bromomethane U 0.866 5.00 1 11/13/2018 17:05 WG1195901

Carbon disulfide 0.415 J 0.275 1.00 1 11/13/2018 17:05 WG1195901

Carbon tetrachloride U 0.379 1.00 1 11/13/2018 17:05 WG1195901

Chlorobenzene U 0.348 1.00 1 11/13/2018 17:05 WG1195901

Chlorodibromomethane U 0.327 1.00 1 11/13/2018 17:05 WG1195901

Chloroethane U 0.453 5.00 1 11/13/2018 17:05 WG1195901

Chloroform U 0.324 5.00 1 11/13/2018 17:05 WG1195901

Chloromethane U 0.276 2.50 1 11/13/2018 17:05 WG1195901

Dibromomethane U 0.346 1.00 1 11/13/2018 17:05 WG1195901

1,2-Dibromoethane U 0.381 1.00 1 11/13/2018 17:05 WG1195901

1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 11/13/2018 17:05 WG1195901

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 15 of 31

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 15 of 31

Page 98: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 06L 1 0 4 3 6 9 1

MW-22C o l l e c t e d d a t e / t i m e : 1 1 / 0 9 / 1 8 1 0 : 4 5

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

1,2-Dichlorobenzene U 0.349 1.00 1 11/13/2018 17:05 WG1195901

1,4-Dichlorobenzene U 0.274 1.00 1 11/13/2018 17:05 WG1195901

trans-1,4-Dichloro-2-butene U 0.866 2.50 1 11/13/2018 17:05 WG1195901

1,1-Dichloroethane U 0.259 1.00 1 11/13/2018 17:05 WG1195901

1,2-Dichloroethane U 0.361 1.00 1 11/13/2018 17:05 WG1195901

1,1-Dichloroethene U 0.398 1.00 1 11/13/2018 17:05 WG1195901

cis-1,2-Dichloroethene U 0.260 1.00 1 11/13/2018 17:05 WG1195901

trans-1,2-Dichloroethene U 0.396 1.00 1 11/13/2018 17:05 WG1195901

1,2-Dichloropropane U 0.306 1.00 1 11/13/2018 17:05 WG1195901

cis-1,3-Dichloropropene U 0.418 1.00 1 11/13/2018 17:05 WG1195901

trans-1,3-Dichloropropene U 0.419 1.00 1 11/13/2018 17:05 WG1195901

Ethylbenzene U 0.384 1.00 1 11/13/2018 17:05 WG1195901

2-Hexanone U 3.82 10.0 1 11/13/2018 17:05 WG1195901

Iodomethane U 1.71 10.0 1 11/13/2018 17:05 WG1195901

2-Butanone (MEK) U 3.93 15.0 1 11/13/2018 17:05 WG1195901

Methylene Chloride U 1.00 5.00 1 11/13/2018 17:05 WG1195901

4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 11/13/2018 17:05 WG1195901

Styrene U 0.307 1.00 1 11/13/2018 17:05 WG1195901

1,1,1,2-Tetrachloroethane U 0.385 1.00 1 11/13/2018 17:05 WG1195901

1,1,2,2-Tetrachloroethane U 0.130 1.00 1 11/13/2018 17:05 WG1195901

Tetrachloroethene U 0.372 1.00 1 11/13/2018 17:05 WG1195901

Toluene U 0.412 1.00 1 11/13/2018 17:05 WG1195901

1,1,1-Trichloroethane U 0.319 1.00 1 11/13/2018 17:05 WG1195901

1,1,2-Trichloroethane U 0.383 1.00 1 11/13/2018 17:05 WG1195901

Trichloroethene U 0.398 1.00 1 11/13/2018 17:05 WG1195901

Trichlorofluoromethane U 1.20 5.00 1 11/13/2018 17:05 WG1195901

1,2,3-Trichloropropane U 0.807 2.50 1 11/13/2018 17:05 WG1195901

Vinyl acetate U 1.63 10.0 1 11/13/2018 17:05 WG1195901

Vinyl chloride U 0.259 1.00 1 11/13/2018 17:05 WG1195901

Xylenes, Total U 1.06 3.00 1 11/13/2018 17:05 WG1195901

(S) Toluene-d8 105 80.0-120 11/13/2018 17:05 WG1195901

(S) Dibromofluoromethane 90.7 75.0-120 11/13/2018 17:05 WG1195901

(S) 4-Bromofluorobenzene 98.1 77.0-126 11/13/2018 17:05 WG1195901

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 16 of 31

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 16 of 31

Page 99: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 07L 1 0 4 3 6 9 1

MW-16R DUPC o l l e c t e d d a t e / t i m e : 1 1 / 1 2 / 1 8 1 4 : 3 0

Gravimetric Analysis by Method 2540 C-2011

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Dissolved Solids 280000 2820 10000 1 11/16/2018 14:25 WG1197217

Wet Chemistry by Method 9056A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Chloride 6880 51.9 1000 1 11/15/2018 03:26 WG1196256

Sulfate 17300 77.4 5000 1 11/15/2018 03:26 WG1196256

Wet Chemistry by Method 9060A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

TOC (Total Organic Carbon) 827 J 102 1000 1 11/17/2018 01:53 WG1197777

Metals (ICPMS) by Method 6020

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Antimony U 0.754 2.00 1 11/15/2018 02:55 WG1196345

Arsenic 0.654 J 0.250 2.00 1 11/15/2018 02:55 WG1196345

Barium 91.7 0.360 5.00 1 11/15/2018 02:55 WG1196345

Beryllium U 0.120 2.00 1 11/15/2018 02:55 WG1196345

Cadmium U 0.160 1.00 1 11/15/2018 02:55 WG1196345

Chromium U 0.540 2.00 1 11/15/2018 02:55 WG1196345

Copper 0.865 J 0.520 5.00 1 11/15/2018 02:55 WG1196345

Cobalt U 0.260 2.00 1 11/15/2018 02:55 WG1196345

Iron 302 15.0 100 1 11/15/2018 02:55 WG1196345

Lead 0.359 J 0.240 2.00 1 11/15/2018 02:55 WG1196345

Manganese 535 0.250 5.00 1 11/15/2018 02:55 WG1196345

Nickel 0.564 J 0.350 2.00 1 11/15/2018 02:55 WG1196345

Selenium U 0.380 2.00 1 11/15/2018 02:55 WG1196345

Silver 0.406 J 0.310 2.00 1 11/15/2018 02:55 WG1196345

Thallium U 0.190 2.00 1 11/15/2018 02:55 WG1196345

Vanadium 0.276 J 0.180 5.00 1 11/15/2018 02:55 WG1196345

Zinc U 2.56 25.0 1 11/15/2018 02:55 WG1196345

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Acetone U 10.0 50.0 1 11/13/2018 17:24 WG1195901

Acrylonitrile U 1.87 10.0 1 11/13/2018 17:24 WG1195901

Benzene U 0.331 1.00 1 11/13/2018 17:24 WG1195901

Bromochloromethane U 0.520 1.00 1 11/13/2018 17:24 WG1195901

Bromodichloromethane U 0.380 1.00 1 11/13/2018 17:24 WG1195901

Bromoform U 0.469 1.00 1 11/13/2018 17:24 WG1195901

Bromomethane U 0.866 5.00 1 11/13/2018 17:24 WG1195901

Carbon disulfide U 0.275 1.00 1 11/13/2018 17:24 WG1195901

Carbon tetrachloride U 0.379 1.00 1 11/13/2018 17:24 WG1195901

Chlorobenzene U 0.348 1.00 1 11/13/2018 17:24 WG1195901

Chlorodibromomethane U 0.327 1.00 1 11/13/2018 17:24 WG1195901

Chloroethane U 0.453 5.00 1 11/13/2018 17:24 WG1195901

Chloroform U 0.324 5.00 1 11/13/2018 17:24 WG1195901

Chloromethane U 0.276 2.50 1 11/13/2018 17:24 WG1195901

Dibromomethane U 0.346 1.00 1 11/13/2018 17:24 WG1195901

1,2-Dibromoethane U 0.381 1.00 1 11/13/2018 17:24 WG1195901

1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 11/13/2018 17:24 WG1195901

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 17 of 31

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 17 of 31

Page 100: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 07L 1 0 4 3 6 9 1

MW-16R DUPC o l l e c t e d d a t e / t i m e : 1 1 / 1 2 / 1 8 1 4 : 3 0

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

1,2-Dichlorobenzene U 0.349 1.00 1 11/13/2018 17:24 WG1195901

1,4-Dichlorobenzene U 0.274 1.00 1 11/13/2018 17:24 WG1195901

trans-1,4-Dichloro-2-butene U 0.866 2.50 1 11/13/2018 17:24 WG1195901

1,1-Dichloroethane U 0.259 1.00 1 11/13/2018 17:24 WG1195901

1,2-Dichloroethane U 0.361 1.00 1 11/13/2018 17:24 WG1195901

1,1-Dichloroethene U 0.398 1.00 1 11/13/2018 17:24 WG1195901

cis-1,2-Dichloroethene U 0.260 1.00 1 11/13/2018 17:24 WG1195901

trans-1,2-Dichloroethene U 0.396 1.00 1 11/13/2018 17:24 WG1195901

1,2-Dichloropropane U 0.306 1.00 1 11/13/2018 17:24 WG1195901

cis-1,3-Dichloropropene U 0.418 1.00 1 11/13/2018 17:24 WG1195901

trans-1,3-Dichloropropene U 0.419 1.00 1 11/13/2018 17:24 WG1195901

Ethylbenzene U 0.384 1.00 1 11/13/2018 17:24 WG1195901

2-Hexanone U 3.82 10.0 1 11/13/2018 17:24 WG1195901

Iodomethane U 1.71 10.0 1 11/13/2018 17:24 WG1195901

2-Butanone (MEK) U 3.93 15.0 1 11/13/2018 17:24 WG1195901

Methylene Chloride U 1.00 5.00 1 11/13/2018 17:24 WG1195901

4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 11/13/2018 17:24 WG1195901

Styrene U 0.307 1.00 1 11/13/2018 17:24 WG1195901

1,1,1,2-Tetrachloroethane U 0.385 1.00 1 11/13/2018 17:24 WG1195901

1,1,2,2-Tetrachloroethane U 0.130 1.00 1 11/13/2018 17:24 WG1195901

Tetrachloroethene U 0.372 1.00 1 11/13/2018 17:24 WG1195901

Toluene U 0.412 1.00 1 11/13/2018 17:24 WG1195901

1,1,1-Trichloroethane U 0.319 1.00 1 11/13/2018 17:24 WG1195901

1,1,2-Trichloroethane U 0.383 1.00 1 11/13/2018 17:24 WG1195901

Trichloroethene U 0.398 1.00 1 11/13/2018 17:24 WG1195901

Trichlorofluoromethane U 1.20 5.00 1 11/13/2018 17:24 WG1195901

1,2,3-Trichloropropane U 0.807 2.50 1 11/13/2018 17:24 WG1195901

Vinyl acetate U 1.63 10.0 1 11/13/2018 17:24 WG1195901

Vinyl chloride U 0.259 1.00 1 11/13/2018 17:24 WG1195901

Xylenes, Total U 1.06 3.00 1 11/13/2018 17:24 WG1195901

(S) Toluene-d8 110 80.0-120 11/13/2018 17:24 WG1195901

(S) Dibromofluoromethane 90.8 75.0-120 11/13/2018 17:24 WG1195901

(S) 4-Bromofluorobenzene 95.5 77.0-126 11/13/2018 17:24 WG1195901

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 18 of 31

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 18 of 31

Page 101: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1197217G r a v i m e t r i c A n a l y s i s b y M e t h o d 2 5 4 0 C - 2 0 1 1 L 1 0 4 3 6 9 1 - 0 2 , 0 3 , 0 4 , 0 5 , 0 6 , 0 7

Method Blank (MB)

(MB) R3361697-1 11/16/18 14:25

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

Dissolved Solids U 2820 10000

L1043597-01 Original Sample (OS) • Duplicate (DUP)

(OS) L1043597-01 11/16/18 14:25 • (DUP) R3361697-3 11/16/18 14:25

Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits

Analyte ug/l ug/l % %

Dissolved Solids 872000 908000 1 4.04 5

Laboratory Control Sample (LCS)

(LCS) R3361697-2 11/16/18 14:25

Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier

Analyte ug/l ug/l % %

Dissolved Solids 8800000 8630000 98.1 85.0-115

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 19 of 31

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 19 of 31

Page 102: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1196256W e t C h e m i s t r y b y M e t h o d 9 0 5 6 A L 1 0 4 3 6 9 1 - 0 2 , 0 3 , 0 4 , 0 5 , 0 6 , 0 7

Method Blank (MB)

(MB) R3360117-1 11/14/18 22:17

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

Chloride U 51.9 1000

Sulfate U 77.4 5000

L1043249-31 Original Sample (OS) • Duplicate (DUP)

(OS) L1043249-31 11/14/18 23:12 • (DUP) R3360117-3 11/14/18 23:30

Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits

Analyte ug/l ug/l % %

Chloride 67.2 0.000 1 200 P1 15

Sulfate U 0.000 1 0.000 15

L1043793-05 Original Sample (OS) • Duplicate (DUP)

(OS) L1043793-05 11/15/18 07:22 • (DUP) R3360117-6 11/15/18 07:40

Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits

Analyte ug/l ug/l % %

Chloride 12100 12100 1 0.239 15

Sulfate 85800 85800 1 0.0572 15

Laboratory Control Sample (LCS)

(LCS) R3360117-2 11/14/18 22:35

Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier

Analyte ug/l ug/l % %

Chloride 40000 39600 98.9 80.0-120

Sulfate 40000 40200 101 80.0-120

L1043249-31 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)

(OS) L1043249-31 11/14/18 23:12 • (MS) R3360117-4 11/14/18 23:48 • (MSD) R3360117-5 11/15/18 00:06

Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l ug/l % % % % %

Chloride 50000 67.2 49100 50400 98.0 101 1 80.0-120 2.58 15

Sulfate 50000 U 50100 50800 100 102 1 80.0-120 1.31 15

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 20 of 31

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 20 of 31

Page 103: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1196256W e t C h e m i s t r y b y M e t h o d 9 0 5 6 A L 1 0 4 3 6 9 1 - 0 2 , 0 3 , 0 4 , 0 5 , 0 6 , 0 7

L1043793-05 Original Sample (OS) • Matrix Spike (MS)

(OS) L1043793-05 11/15/18 07:22 • (MS) R3360117-7 11/15/18 07:59

Spike Amount Original Result MS Result MS Rec. Dilution Rec. Limits MS Qualifier

Analyte ug/l ug/l ug/l % %

Chloride 50000 12100 62000 99.8 1 80.0-120

Sulfate 50000 85800 132000 92.5 1 80.0-120 E

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 21 of 31

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 21 of 31

Page 104: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1197777W e t C h e m i s t r y b y M e t h o d 9 0 6 0 A L 1 0 4 3 6 9 1 - 0 2 , 0 3 , 0 4 , 0 6 , 0 7

Method Blank (MB)

(MB) R3360734-1 11/16/18 13:17

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

TOC (Total Organic Carbon) U 102 1000

L1043223-14 Original Sample (OS) • Duplicate (DUP)

(OS) L1043223-14 11/16/18 18:56 • (DUP) R3360734-5 11/16/18 19:17

Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits

Analyte ug/l ug/l % %

TOC 3360 3590 1 6.65 20

Laboratory Control Sample (LCS)

(LCS) R3360734-2 11/16/18 13:57

Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier

Analyte ug/l ug/l % %

TOC 75000 83400 111 85.0-115

L1043223-10 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)

(OS) L1043223-10 11/16/18 17:56 • (MS) R3360734-3 11/16/18 18:18 • (MSD) R3360734-4 11/16/18 18:39

Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l ug/l % % % % %

TOC 50000 1590 53700 54100 104 105 1 80.0-120 0.853 20

L1043639-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)

(OS) L1043639-02 11/16/18 21:47 • (MS) R3360734-6 11/16/18 22:09 • (MSD) R3360734-7 11/16/18 22:31

Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l ug/l % % % % %

TOC 50000 842 55900 55800 110 110 1 80.0-120 0.215 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 22 of 31

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 22 of 31

Page 105: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1198811W e t C h e m i s t r y b y M e t h o d 9 0 6 0 A L 1 0 4 3 6 9 1 - 0 5

Method Blank (MB)

(MB) R3361193-1 11/19/18 09:57

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

TOC (Total Organic Carbon) U 102 1000

L1044902-01 Original Sample (OS) • Duplicate (DUP)

(OS) L1044902-01 11/19/18 11:18 • (DUP) R3361193-3 11/19/18 11:31

Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits

Analyte ug/l ug/l % %

TOC ND 967 1 0.000 20

L1043765-09 Original Sample (OS) • Duplicate (DUP)

(OS) L1043765-09 11/19/18 20:24 • (DUP) R3361193-6 11/19/18 20:44

Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits

Analyte ug/l ug/l % %

TOC 2750 2780 1 1.01 20

Laboratory Control Sample (LCS)

(LCS) R3361193-2 11/19/18 10:40

Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier

Analyte ug/l ug/l % %

TOC 75000 83500 111 85.0-115

L1043765-05 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)

(OS) L1043765-05 11/19/18 17:11 • (MS) R3361193-4 11/19/18 18:53 • (MSD) R3361193-5 11/19/18 19:13

Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l ug/l % % % % %

TOC 50000 2880 55600 55900 105 106 1 80.0-120 0.502 20

L1043850-07 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)

(OS) L1043850-07 11/19/18 23:58 • (MS) R3361193-7 11/20/18 00:24 • (MSD) R3361193-8 11/20/18 00:46

Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l ug/l % % % % %

TOC 50000 2010 57900 57500 112 111 1 80.0-120 0.780 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 23 of 31

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 23 of 31

Page 106: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1196345M e t a l s ( I C P M S ) b y M e t h o d 6 0 2 0 L 1 0 4 3 6 9 1 - 0 2 , 0 3 , 0 4 , 0 5 , 0 6 , 0 7

Method Blank (MB)

(MB) R3360006-1 11/15/18 01:50

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

Antimony U 0.754 2.00

Arsenic U 0.250 2.00

Barium 0.361 J 0.360 5.00

Beryllium U 0.120 2.00

Cadmium U 0.160 1.00

Chromium U 0.540 2.00

Copper U 0.520 5.00

Cobalt U 0.260 2.00

Iron U 15.0 100

Lead U 0.240 2.00

Manganese 0.336 J 0.250 5.00

Nickel U 0.350 2.00

Selenium U 0.380 2.00

Silver U 0.310 2.00

Thallium U 0.190 2.00

Vanadium U 0.180 5.00

Zinc U 2.56 25.0

Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)

(LCS) R3360006-2 11/15/18 01:54 • (LCSD) R3360006-3 11/15/18 01:59

Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l % % % % %

Antimony 50.0 48.7 48.3 97.4 96.7 80.0-120 0.729 20

Arsenic 50.0 46.6 46.6 93.1 93.2 80.0-120 0.101 20

Barium 50.0 42.9 44.1 85.8 88.2 80.0-120 2.76 20

Beryllium 50.0 43.5 45.5 87.1 91.0 80.0-120 4.48 20

Cadmium 50.0 48.6 49.2 97.2 98.3 80.0-120 1.19 20

Chromium 50.0 48.4 49.2 96.8 98.4 80.0-120 1.64 20

Copper 50.0 49.2 50.0 98.3 100 80.0-120 1.75 20

Cobalt 50.0 49.4 50.2 98.9 100 80.0-120 1.48 20

Iron 5000 4910 4930 98.2 98.6 80.0-120 0.412 20

Lead 50.0 46.2 46.9 92.3 93.8 80.0-120 1.60 20

Manganese 50.0 49.0 49.1 97.9 98.1 80.0-120 0.224 20

Nickel 50.0 49.5 50.7 98.9 101 80.0-120 2.37 20

Selenium 50.0 55.8 56.0 112 112 80.0-120 0.369 20

Silver 50.0 47.5 47.8 95.0 95.6 80.0-120 0.662 20

Thallium 50.0 46.6 47.8 93.3 95.6 80.0-120 2.40 20

Vanadium 50.0 46.9 47.5 93.9 95.1 80.0-120 1.27 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 24 of 31

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 24 of 31

Page 107: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1196345M e t a l s ( I C P M S ) b y M e t h o d 6 0 2 0 L 1 0 4 3 6 9 1 - 0 2 , 0 3 , 0 4 , 0 5 , 0 6 , 0 7

Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)

(LCS) R3360006-2 11/15/18 01:54 • (LCSD) R3360006-3 11/15/18 01:59

Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l % % % % %

Zinc 50.0 47.7 48.3 95.5 96.6 80.0-120 1.18 20

L1043691-06 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)

(OS) L1043691-06 11/15/18 02:03 • (MS) R3360006-5 11/15/18 02:12 • (MSD) R3360006-6 11/15/18 02:16

Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l ug/l % % % % %

Antimony 50.0 U 49.0 49.5 97.9 99.1 1 75.0-125 1.14 20

Arsenic 50.0 1.99 47.5 48.6 91.0 93.3 1 75.0-125 2.39 20

Barium 50.0 53.3 99.0 97.1 91.4 87.7 1 75.0-125 1.86 20

Beryllium 50.0 U 44.7 44.4 89.4 88.8 1 75.0-125 0.639 20

Cadmium 50.0 U 48.6 49.4 97.3 98.7 1 75.0-125 1.46 20

Chromium 50.0 U 47.6 48.0 95.1 96.1 1 75.0-125 0.988 20

Copper 50.0 U 47.6 47.5 95.3 95.0 1 75.0-125 0.266 20

Cobalt 50.0 U 47.9 48.4 95.9 96.9 1 75.0-125 1.05 20

Iron 5000 392 5220 5230 96.5 96.7 1 75.0-125 0.236 20

Lead 50.0 0.535 46.5 46.7 91.9 92.3 1 75.0-125 0.426 20

Manganese 50.0 234 284 281 100 94.4 1 75.0-125 1.05 20

Nickel 50.0 U 47.7 49.1 95.5 98.1 1 75.0-125 2.79 20

Selenium 50.0 U 56.3 55.9 113 112 1 75.0-125 0.782 20

Silver 50.0 U 47.6 48.5 95.1 97.0 1 75.0-125 1.95 20

Thallium 50.0 U 48.2 47.3 96.5 94.6 1 75.0-125 1.93 20

Vanadium 50.0 U 46.1 47.2 92.3 94.4 1 75.0-125 2.21 20

Zinc 50.0 U 46.9 47.2 93.8 94.3 1 75.0-125 0.623 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 25 of 31

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 25 of 31

Page 108: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1195901V o l a t i l e O r g a n i c C o m p o u n d s ( G C / M S ) b y M e t h o d 8 2 6 0 B L 1 0 4 3 6 9 1 - 0 1 , 0 2 , 0 3 , 0 4 , 0 5 , 0 6 , 0 7

Method Blank (MB)

(MB) R3360590-4 11/13/18 12:54

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

Acetone U 10.0 50.0

Acrylonitrile U 1.87 10.0

Benzene U 0.331 1.00

Bromodichloromethane U 0.380 1.00

Bromochloromethane U 0.520 1.00

Bromoform U 0.469 1.00

Bromomethane U 0.866 5.00

Carbon disulfide U 0.275 1.00

Carbon tetrachloride U 0.379 1.00

Chlorobenzene U 0.348 1.00

Chlorodibromomethane U 0.327 1.00

Chloroethane U 0.453 5.00

Chloroform U 0.324 5.00

Chloromethane U 0.276 2.50

1,2-Dibromo-3-Chloropropane U 1.33 5.00

1,2-Dibromoethane U 0.381 1.00

Dibromomethane U 0.346 1.00

1,2-Dichlorobenzene U 0.349 1.00

1,4-Dichlorobenzene U 0.274 1.00

trans-1,4-Dichloro-2-butene U 0.866 2.50

1,1-Dichloroethane U 0.259 1.00

1,2-Dichloroethane U 0.361 1.00

1,1-Dichloroethene U 0.398 1.00

cis-1,2-Dichloroethene U 0.260 1.00

trans-1,2-Dichloroethene U 0.396 1.00

1,2-Dichloropropane U 0.306 1.00

cis-1,3-Dichloropropene U 0.418 1.00

trans-1,3-Dichloropropene U 0.419 1.00

Ethylbenzene U 0.384 1.00

2-Hexanone U 3.82 10.0

Iodomethane U 1.71 10.0

2-Butanone (MEK) U 3.93 15.0

Methylene Chloride U 1.00 5.00

4-Methyl-2-pentanone (MIBK) U 2.14 10.0

Styrene U 0.307 1.00

1,1,1,2-Tetrachloroethane U 0.385 1.00

1,1,2,2-Tetrachloroethane U 0.130 1.00

Tetrachloroethene U 0.372 1.00

Toluene U 0.412 1.00

1,1,1-Trichloroethane U 0.319 1.00

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 26 of 31

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 26 of 31

Page 109: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1195901V o l a t i l e O r g a n i c C o m p o u n d s ( G C / M S ) b y M e t h o d 8 2 6 0 B L 1 0 4 3 6 9 1 - 0 1 , 0 2 , 0 3 , 0 4 , 0 5 , 0 6 , 0 7

Method Blank (MB)

(MB) R3360590-4 11/13/18 12:54

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

1,1,2-Trichloroethane U 0.383 1.00

Trichloroethene U 0.398 1.00

Trichlorofluoromethane U 1.20 5.00

1,2,3-Trichloropropane U 0.807 2.50

Vinyl acetate U 1.63 10.0

Vinyl chloride U 0.259 1.00

Xylenes, Total U 1.06 3.00

(S) Toluene-d8 108 80.0-120

(S) Dibromofluoromethane 90.7 75.0-120

(S) 4-Bromofluorobenzene 97.6 77.0-126

Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)

(LCS) R3360590-1 11/13/18 11:37 • (LCSD) R3360590-2 11/13/18 11:56

Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l % % % % %

Acetone 125 137 134 109 107 19.0-160 2.36 27

Acrylonitrile 125 166 164 133 131 55.0-149 1.07 20

Benzene 25.0 22.5 21.5 90.2 86.1 70.0-123 4.60 20

Bromodichloromethane 25.0 24.3 23.8 97.4 95.3 75.0-120 2.16 20

Bromochloromethane 25.0 23.0 22.2 92.0 89.0 76.0-122 3.34 20

Bromoform 25.0 26.4 25.9 106 104 68.0-132 1.80 20

Bromomethane 25.0 13.4 14.1 53.4 56.2 10.0-160 5.12 25

Carbon disulfide 25.0 20.8 20.8 83.2 83.1 61.0-128 0.0705 20

Carbon tetrachloride 25.0 23.6 23.0 94.5 91.9 68.0-126 2.72 20

Chlorobenzene 25.0 27.2 27.0 109 108 80.0-121 0.712 20

Chlorodibromomethane 25.0 26.7 26.7 107 107 77.0-125 0.105 20

Chloroethane 25.0 25.2 25.9 101 104 47.0-150 2.59 20

Chloroform 25.0 21.2 20.8 84.9 83.2 73.0-120 2.08 20

Chloromethane 25.0 23.4 23.2 93.8 92.7 41.0-142 1.20 20

1,2-Dibromo-3-Chloropropane 25.0 27.2 25.8 109 103 58.0-134 5.46 20

1,2-Dibromoethane 25.0 26.4 25.8 106 103 80.0-122 2.38 20

Dibromomethane 25.0 23.7 23.0 94.9 92.0 80.0-120 3.08 20

1,2-Dichlorobenzene 25.0 24.3 24.2 97.2 97.0 79.0-121 0.243 20

1,4-Dichlorobenzene 25.0 22.6 22.3 90.6 89.3 79.0-120 1.46 20

trans-1,4-Dichloro-2-butene 25.0 29.5 27.9 118 111 33.0-144 5.65 20

1,1-Dichloroethane 25.0 24.9 24.5 99.5 98.1 70.0-126 1.47 20

1,2-Dichloroethane 25.0 23.7 22.4 95.0 89.7 70.0-128 5.73 20

1,1-Dichloroethene 25.0 22.1 21.7 88.5 86.8 71.0-124 1.93 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 27 of 31

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 27 of 31

Page 110: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1195901V o l a t i l e O r g a n i c C o m p o u n d s ( G C / M S ) b y M e t h o d 8 2 6 0 B L 1 0 4 3 6 9 1 - 0 1 , 0 2 , 0 3 , 0 4 , 0 5 , 0 6 , 0 7

Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)

(LCS) R3360590-1 11/13/18 11:37 • (LCSD) R3360590-2 11/13/18 11:56

Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l % % % % %

cis-1,2-Dichloroethene 25.0 19.8 20.1 79.1 80.5 73.0-120 1.81 20

trans-1,2-Dichloroethene 25.0 21.3 21.4 85.0 85.5 73.0-120 0.487 20

1,2-Dichloropropane 25.0 27.3 26.7 109 107 77.0-125 1.99 20

cis-1,3-Dichloropropene 25.0 26.7 26.6 107 107 80.0-123 0.378 20

trans-1,3-Dichloropropene 25.0 27.7 27.1 111 108 78.0-124 2.21 20

Ethylbenzene 25.0 26.9 26.9 108 108 79.0-123 0.0646 20

2-Hexanone 125 182 177 146 141 67.0-149 2.94 20

Iodomethane 125 95.5 114 76.4 91.3 33.0-147 17.8 26

2-Butanone (MEK) 125 156 147 124 118 44.0-160 5.51 20

Methylene Chloride 25.0 19.6 18.7 78.4 74.6 67.0-120 4.88 20

4-Methyl-2-pentanone (MIBK) 125 165 162 132 129 68.0-142 2.08 20

Styrene 25.0 24.8 24.7 99.3 98.6 73.0-130 0.676 20

1,1,1,2-Tetrachloroethane 25.0 27.8 28.0 111 112 75.0-125 0.536 20

1,1,2,2-Tetrachloroethane 25.0 22.9 22.5 91.4 90.0 65.0-130 1.60 20

Tetrachloroethene 25.0 28.1 28.0 112 112 72.0-132 0.571 20

Toluene 25.0 26.5 26.3 106 105 79.0-120 0.921 20

1,1,1-Trichloroethane 25.0 23.7 23.4 94.7 93.5 73.0-124 1.29 20

1,1,2-Trichloroethane 25.0 24.4 24.7 97.5 98.8 80.0-120 1.33 20

Trichloroethene 25.0 26.5 26.0 106 104 78.0-124 1.87 20

Trichlorofluoromethane 25.0 25.0 24.0 99.9 96.1 59.0-147 3.93 20

1,2,3-Trichloropropane 25.0 26.5 26.0 106 104 73.0-130 2.12 20

Vinyl acetate 125 133 127 106 101 11.0-160 4.63 20

Vinyl chloride 25.0 26.5 25.4 106 102 67.0-131 4.19 20

Xylenes, Total 75.0 81.0 80.7 108 108 79.0-123 0.371 20

(S) Toluene-d8 108 109 80.0-120

(S) Dibromofluoromethane 90.9 90.9 75.0-120

(S) 4-Bromofluorobenzene 95.2 95.9 77.0-126

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 28 of 31

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 28 of 31

Page 111: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.GLOSSARY OF TERMS

Guide to Reading and Understanding Your Laboratory Report

The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative.

Abbreviations and Definitions

MDL Method Detection Limit.

ND Not detected at the Reporting Limit (or MDL where applicable).

RDL Reported Detection Limit.

Rec. Recovery.

RPD Relative Percent Difference.

SDG Sample Delivery Group.

(S)Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be detected in all environmental media.

U Not detected at the Reporting Limit (or MDL where applicable).

Analyte The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported.

Dilution

If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor.

LimitsThese are the target % recovery ranges or % difference value that the laboratory has historically determined as normal for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or duplicated within these ranges.

Original Sample The non-spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control sample. The Original Sample may not be included within the reported SDG.

QualifierThis column provides a letter and/or number designation that corresponds to additional information concerning the resultreported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable.

Result

The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state “ND” (Not Detected) or “BDL” (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte.

Case Narrative (Cn)A brief discussion about the included sample results, including a discussion of any non-conformances to protocol observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.

Quality Control Summary (Qc)

This section of the report includes the results of the laboratory quality control analyses required by procedure or analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material.

Sample Chain of Custody (Sc)

This is the document created in the field when your samples were initially collected. This is used to verify the time and date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis.

Sample Results (Sr)This section of your report will provide the results of all testing performed on your samples. These results are provided by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section foreach sample will provide the name and method number for the analysis reported.

Sample Summary (Ss) This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates andtimes of preparation and/or analysis.

Qualifier Description

E The analyte concentration exceeds the upper limit of the calibration range of the instrument established by the initial calibration (ICAL).

J The identification of the analyte is acceptable; the reported value is an estimate.

P1 RPD value not applicable for sample concentrations less than 5 times the reporting limit.

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 29 of 31

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 29 of 31

Page 112: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.

Pace National is the only environmental laboratory accredited/certified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as accessible or prepared to handle your needs throughout the country. Our capacity and capability from our single location laboratory is comparable to the collective totals of the network laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing turn-around time, and preventing cross contamination, thus protecting sample integrity. Our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE. * Not all certifications held by the laboratory are applicable to the results reported in the attached report. * Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace National.

State AccreditationsAlabama 40660 Nebraska NE-OS-15-05

Alaska 17-026 Nevada TN-03-2002-34

Arizona AZ0612 New Hampshire 2975

Arkansas 88-0469 New Jersey–NELAP TN002

California 2932 New Mexico ¹ n/a

Colorado TN00003 New York 11742

Connecticut PH-0197 North Carolina Env375

Florida E87487 North Carolina ¹ DW21704

Georgia NELAP North Carolina ³ 41

Georgia ¹ 923 North Dakota R-140

Idaho TN00003 Ohio–VAP CL0069

Illinois 200008 Oklahoma 9915

Indiana C-TN-01 Oregon TN200002

Iowa 364 Pennsylvania 68-02979

Kansas E-10277 Rhode Island LAO00356

Kentucky ¹ ⁶ 90010 South Carolina 84004

Kentucky ² 16 South Dakota n/a

Louisiana AI30792 Tennessee ¹ ⁴ 2006

Louisiana ¹ LA180010 Texas T 104704245-17-14

Maine TN0002 Texas ⁵ LAB0152

Maryland 324 Utah TN00003

Massachusetts M-TN003 Vermont VT2006

Michigan 9958 Virginia 460132

Minnesota 047-999-395 Washington C847

Mississippi TN00003 West Virginia 233

Missouri 340 Wisconsin 9980939910

Montana CERT0086 Wyoming A2LA

Third Party Federal AccreditationsA2LA – ISO 17025 1461.01 AIHA-LAP,LLC EMLAP 100789

A2LA – ISO 17025 ⁵ 1461.02 DOD 1461.01

Canada 1461.01 USDA P330-15-00234

EPA–Crypto TN00003

ACCREDITATIONS & LOCATIONS

¹ Drinking Water ² Underground Storage Tanks ³ Aquatic Toxicity ⁴ Chemical/Microbiological ⁵ Mold ⁶ Wastewater n/a Accreditation not applicable

Our LocationsPace National has sixty-four client support centers that provide sample pickup and/or the delivery of sampling supplies. If you would like assistance from one of our support offices, please contactour main office. Pace National performs all testing at our central laboratory.

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/20/18 18:17 30 of 31

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1043691 11/21/18 15:46 30 of 31

Page 113: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 114: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ANALYTICAL REPORTNovember 23, 2018

Legacy Landfill

Sample Delivery Group: L1044753

Samples Received: 11/15/2018

Project Number: 04469-1767-001

Description: Craighead County - Legacy Landfill

Report To: Angela Sparks

P.O. Box 16777

Jonesboro, AR 72403

Entire Report Reviewed By:

November 23, 2018

[Preliminary Report]

Mark W. BeasleyPro ject Manager

Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace Nationalis performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304.

12065 Lebanon Rd Mount Jul iet , TN 37122 615-758-5858 800-767-5859 www.pacenational .com

November 26, 2018

Mark W. BeasleyPro ject Manager

Page 115: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.TABLE OF CONTENTS

Cp: Cover Page 1

Tc: Table of Contents 2

Ss: Sample Summary 3

Cn: Case Narrative 5

Sr: Sample Results 6

MW-9R2 L1044753-01 6

MW-20 L1044753-02 8

MW-21 L1044753-03 10

EB-1 L1044753-04 12

LEACHATE BLDG A L1044753-05 14

LEACHATE BLDG B L1044753-06 16

LEACHATE BLDG C L1044753-07 18

TRIP BLANK L1044753-08 20

Qc: Quality Control Summary 21

Gravimetric Analysis by Method 2540 C-2011 21

Wet Chemistry by Method 9056A 23

Wet Chemistry by Method 9060A 28

Metals (ICPMS) by Method 6020 30

Volatile Organic Compounds (GC/MS) by Method 8260B 32

Gl: Glossary of Terms 37

Al: Accreditations & Locations 38

Sc: Sample Chain of Custody 39

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 2 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 2 of 40

Page 116: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE SUMMARY

Collected by Collected date/time Received date/time

MW-9R2 L1044753-01 GW Michael Clayton 11/13/18 13:50 11/15/18 13:15

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Gravimetric Analysis by Method 2540 C-2011 WG1198057 1 11/18/18 11:13 11/18/18 11:45 MMF

Wet Chemistry by Method 9056A WG1197480 1 11/17/18 07:53 11/17/18 07:53 ELN

Wet Chemistry by Method 9060A WG1199249 1 11/20/18 21:59 11/20/18 21:59 SJM

Metals (ICPMS) by Method 6020 WG1197586 1 11/16/18 11:21 11/19/18 18:58 LD

Volatile Organic Compounds (GC/MS) by Method 8260B WG1197903 1 11/16/18 15:31 11/16/18 15:31 BMB

Collected by Collected date/time Received date/time

MW-20 L1044753-02 GW Michael Clayton 11/13/18 10:15 11/15/18 13:15

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Gravimetric Analysis by Method 2540 C-2011 WG1198057 1 11/18/18 11:13 11/18/18 11:45 MMF

Wet Chemistry by Method 9056A WG1197480 1 11/17/18 08:09 11/17/18 08:09 ELN

Wet Chemistry by Method 9060A WG1199249 1 11/20/18 22:15 11/20/18 22:15 SJM

Metals (ICPMS) by Method 6020 WG1197586 1 11/16/18 11:21 11/19/18 19:16 LD

Volatile Organic Compounds (GC/MS) by Method 8260B WG1197903 1 11/16/18 16:15 11/16/18 16:15 BMB

Collected by Collected date/time Received date/time

MW-21 L1044753-03 GW Michael Clayton 11/13/18 12:10 11/15/18 13:15

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Gravimetric Analysis by Method 2540 C-2011 WG1198057 1 11/18/18 11:13 11/18/18 11:45 MMF

Wet Chemistry by Method 9056A WG1198004 1 11/17/18 16:54 11/17/18 16:54 MAJ

Wet Chemistry by Method 9060A WG1199249 1 11/20/18 22:38 11/20/18 22:38 SJM

Metals (ICPMS) by Method 6020 WG1197586 1 11/16/18 11:21 11/19/18 19:20 LD

Volatile Organic Compounds (GC/MS) by Method 8260B WG1197903 1 11/16/18 16:37 11/16/18 16:37 BMB

Collected by Collected date/time Received date/time

EB-1 L1044753-04 GW Michael Clayton 11/13/18 15:00 11/15/18 13:15

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Gravimetric Analysis by Method 2540 C-2011 WG1198057 1 11/18/18 11:13 11/18/18 11:45 MMF

Wet Chemistry by Method 9056A WG1198004 1 11/17/18 17:59 11/17/18 17:59 MAJ

Wet Chemistry by Method 9060A WG1199249 1 11/21/18 00:13 11/21/18 00:13 SJM

Metals (ICPMS) by Method 6020 WG1197586 1 11/16/18 11:21 11/19/18 19:25 LD

Volatile Organic Compounds (GC/MS) by Method 8260B WG1197903 1 11/16/18 16:59 11/16/18 16:59 BMB

Collected by Collected date/time Received date/time

LEACHATE BLDG A L1044753-05 GW Michael Clayton 11/14/18 10:30 11/15/18 13:15

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Gravimetric Analysis by Method 2540 C-2011 WG1198284 1 11/18/18 14:38 11/18/18 15:12 MMF

Wet Chemistry by Method 9056A WG1198004 50 11/17/18 18:16 11/17/18 18:16 MAJ

Wet Chemistry by Method 9056A WG1199280 1 11/20/18 17:49 11/20/18 17:49 ELN

Wet Chemistry by Method 9060A WG1199249 20 11/21/18 00:40 11/21/18 00:40 SJM

Metals (ICPMS) by Method 6020 WG1197586 1 11/18/18 17:58 11/19/18 20:51 LD

Metals (ICPMS) by Method 6020 WG1197586 1 11/18/18 17:58 11/19/18 23:13 LD

Volatile Organic Compounds (GC/MS) by Method 8260B WG1197903 1 11/16/18 17:21 11/16/18 17:21 BMB

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 3 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 3 of 40

Page 117: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE SUMMARY

Collected by Collected date/time Received date/time

LEACHATE BLDG B L1044753-06 GW Michael Clayton 11/14/18 11:00 11/15/18 13:15

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Gravimetric Analysis by Method 2540 C-2011 WG1198284 1 11/18/18 14:38 11/18/18 15:12 MMF

Wet Chemistry by Method 9056A WG1198004 1 11/17/18 18:32 11/17/18 18:32 MAJ

Wet Chemistry by Method 9056A WG1198004 20 11/17/18 18:49 11/17/18 18:49 MAJ

Wet Chemistry by Method 9060A WG1199249 2 11/21/18 01:10 11/21/18 01:10 SJM

Metals (ICPMS) by Method 6020 WG1197586 1 11/16/18 11:21 11/19/18 19:48 LD

Volatile Organic Compounds (GC/MS) by Method 8260B WG1197903 1 11/16/18 17:43 11/16/18 17:43 BMB

Collected by Collected date/time Received date/time

LEACHATE BLDG C L1044753-07 GW Michael Clayton 11/14/18 11:30 11/15/18 13:15

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Gravimetric Analysis by Method 2540 C-2011 WG1198284 1 11/18/18 14:38 11/18/18 15:12 MMF

Wet Chemistry by Method 9056A WG1198004 1 11/17/18 19:05 11/17/18 19:05 MAJ

Wet Chemistry by Method 9056A WG1198004 20 11/17/18 19:54 11/17/18 19:54 MAJ

Wet Chemistry by Method 9060A WG1199834 2 11/21/18 16:39 11/21/18 16:39 SJM

Metals (ICPMS) by Method 6020 WG1197586 1 11/16/18 11:21 11/19/18 19:53 LD

Volatile Organic Compounds (GC/MS) by Method 8260B WG1197903 1 11/16/18 18:04 11/16/18 18:04 BMB

Collected by Collected date/time Received date/time

TRIP BLANK L1044753-08 GW Michael Clayton 11/13/18 00:00 11/15/18 13:15

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Volatile Organic Compounds (GC/MS) by Method 8260B WG1197903 1 11/16/18 15:09 11/16/18 15:09 BMB

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 4 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 4 of 40

Page 118: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.CASE NARRATIVE

All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated withinthe report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental sampleshave been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data.

[Preliminary Report]

Mark W. BeasleyPro jec t Manager

Sample Handl ing and Receiving

The following analysis were performed from an unpreserved, insufficiently or inadequately preserved sample.

Lab Sample ID Project Sample ID Method

L1044753-05 LEACHATE BLDG A 9060A

L1044753-06 LEACHATE BLDG B 9060A

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 5 of 40

Mark W. BeasleyPro jec t Manager

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 5 of 40

Page 119: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 01L 1 0 4 4 7 5 3

MW-9R2C o l l e c t e d d a t e / t i m e : 1 1 / 1 3 / 1 8 1 3 : 5 0

Gravimetric Analysis by Method 2540 C-2011

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Dissolved Solids 277000 2820 10000 1 11/18/2018 11:45 WG1198057

Wet Chemistry by Method 9056A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Chloride 7020 51.9 1000 1 11/17/2018 07:53 WG1197480

Sulfate 17200 77.4 5000 1 11/17/2018 07:53 WG1197480

Wet Chemistry by Method 9060A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

TOC (Total Organic Carbon) 649 J 102 1000 1 11/20/2018 21:59 WG1199249

Metals (ICPMS) by Method 6020

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Antimony U 0.754 2.00 1 11/19/2018 18:58 WG1197586

Arsenic 1.14 J 0.250 2.00 1 11/19/2018 18:58 WG1197586

Barium 140 0.360 5.00 1 11/19/2018 18:58 WG1197586

Beryllium U 0.120 2.00 1 11/19/2018 18:58 WG1197586

Cadmium U 0.160 1.00 1 11/19/2018 18:58 WG1197586

Chromium U 0.540 2.00 1 11/19/2018 18:58 WG1197586

Copper U 0.520 5.00 1 11/19/2018 18:58 WG1197586

Cobalt U 0.260 2.00 1 11/19/2018 18:58 WG1197586

Iron 1710 15.0 100 1 11/19/2018 18:58 WG1197586

Lead 0.643 J 0.240 2.00 1 11/19/2018 18:58 WG1197586

Manganese 396 0.250 5.00 1 11/19/2018 18:58 WG1197586

Nickel U 0.350 2.00 1 11/19/2018 18:58 WG1197586

Selenium U 0.380 2.00 1 11/19/2018 18:58 WG1197586

Silver U 0.310 2.00 1 11/19/2018 18:58 WG1197586

Thallium U 0.190 2.00 1 11/19/2018 18:58 WG1197586

Vanadium U 0.180 5.00 1 11/19/2018 18:58 WG1197586

Zinc U 2.56 25.0 1 11/19/2018 18:58 WG1197586

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Acetone U 10.0 50.0 1 11/16/2018 15:31 WG1197903

Acrylonitrile U 1.87 10.0 1 11/16/2018 15:31 WG1197903

Benzene U 0.331 1.00 1 11/16/2018 15:31 WG1197903

Bromochloromethane U 0.520 1.00 1 11/16/2018 15:31 WG1197903

Bromodichloromethane U 0.380 1.00 1 11/16/2018 15:31 WG1197903

Bromoform U 0.469 1.00 1 11/16/2018 15:31 WG1197903

Bromomethane U 0.866 5.00 1 11/16/2018 15:31 WG1197903

Carbon disulfide U 0.275 1.00 1 11/16/2018 15:31 WG1197903

Carbon tetrachloride U 0.379 1.00 1 11/16/2018 15:31 WG1197903

Chlorobenzene U 0.348 1.00 1 11/16/2018 15:31 WG1197903

Chlorodibromomethane U 0.327 1.00 1 11/16/2018 15:31 WG1197903

Chloroethane U 0.453 5.00 1 11/16/2018 15:31 WG1197903

Chloroform U 0.324 5.00 1 11/16/2018 15:31 WG1197903

Chloromethane U 0.276 2.50 1 11/16/2018 15:31 WG1197903

Dibromomethane U 0.346 1.00 1 11/16/2018 15:31 WG1197903

1,2-Dibromoethane U 0.381 1.00 1 11/16/2018 15:31 WG1197903

1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 11/16/2018 15:31 WG1197903

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 6 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 6 of 40

Page 120: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 01L 1 0 4 4 7 5 3

MW-9R2C o l l e c t e d d a t e / t i m e : 1 1 / 1 3 / 1 8 1 3 : 5 0

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

1,2-Dichlorobenzene U 0.349 1.00 1 11/16/2018 15:31 WG1197903

1,4-Dichlorobenzene U 0.274 1.00 1 11/16/2018 15:31 WG1197903

trans-1,4-Dichloro-2-butene U J4 0.866 2.50 1 11/16/2018 15:31 WG1197903

1,1-Dichloroethane U 0.259 1.00 1 11/16/2018 15:31 WG1197903

1,2-Dichloroethane U 0.361 1.00 1 11/16/2018 15:31 WG1197903

1,1-Dichloroethene U 0.398 1.00 1 11/16/2018 15:31 WG1197903

cis-1,2-Dichloroethene U 0.260 1.00 1 11/16/2018 15:31 WG1197903

trans-1,2-Dichloroethene U 0.396 1.00 1 11/16/2018 15:31 WG1197903

1,2-Dichloropropane U 0.306 1.00 1 11/16/2018 15:31 WG1197903

cis-1,3-Dichloropropene U 0.418 1.00 1 11/16/2018 15:31 WG1197903

trans-1,3-Dichloropropene U 0.419 1.00 1 11/16/2018 15:31 WG1197903

Ethylbenzene U 0.384 1.00 1 11/16/2018 15:31 WG1197903

2-Hexanone U 3.82 10.0 1 11/16/2018 15:31 WG1197903

Iodomethane U 1.71 10.0 1 11/16/2018 15:31 WG1197903

2-Butanone (MEK) U 3.93 15.0 1 11/16/2018 15:31 WG1197903

Methylene Chloride U 1.00 5.00 1 11/16/2018 15:31 WG1197903

4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 11/16/2018 15:31 WG1197903

Styrene U 0.307 1.00 1 11/16/2018 15:31 WG1197903

1,1,1,2-Tetrachloroethane U 0.385 1.00 1 11/16/2018 15:31 WG1197903

1,1,2,2-Tetrachloroethane U 0.130 1.00 1 11/16/2018 15:31 WG1197903

Tetrachloroethene U 0.372 1.00 1 11/16/2018 15:31 WG1197903

Toluene U 0.412 1.00 1 11/16/2018 15:31 WG1197903

1,1,1-Trichloroethane U 0.319 1.00 1 11/16/2018 15:31 WG1197903

1,1,2-Trichloroethane U 0.383 1.00 1 11/16/2018 15:31 WG1197903

Trichloroethene U 0.398 1.00 1 11/16/2018 15:31 WG1197903

Trichlorofluoromethane U 1.20 5.00 1 11/16/2018 15:31 WG1197903

1,2,3-Trichloropropane U 0.807 2.50 1 11/16/2018 15:31 WG1197903

Vinyl acetate U 1.63 10.0 1 11/16/2018 15:31 WG1197903

Vinyl chloride U 0.259 1.00 1 11/16/2018 15:31 WG1197903

Xylenes, Total U 1.06 3.00 1 11/16/2018 15:31 WG1197903

(S) Toluene-d8 90.9 80.0-120 11/16/2018 15:31 WG1197903

(S) Dibromofluoromethane 114 75.0-120 11/16/2018 15:31 WG1197903

(S) 4-Bromofluorobenzene 105 77.0-126 11/16/2018 15:31 WG1197903

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 7 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 7 of 40

Page 121: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 02L 1 0 4 4 7 5 3

MW-20C o l l e c t e d d a t e / t i m e : 1 1 / 1 3 / 1 8 1 0 : 1 5

Gravimetric Analysis by Method 2540 C-2011

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Dissolved Solids 392000 2820 10000 1 11/18/2018 11:45 WG1198057

Wet Chemistry by Method 9056A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Chloride 9430 51.9 1000 1 11/17/2018 08:09 WG1197480

Sulfate 26000 77.4 5000 1 11/17/2018 08:09 WG1197480

Wet Chemistry by Method 9060A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

TOC (Total Organic Carbon) 863 J 102 1000 1 11/20/2018 22:15 WG1199249

Metals (ICPMS) by Method 6020

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Antimony U 0.754 2.00 1 11/19/2018 19:16 WG1197586

Arsenic 0.335 J 0.250 2.00 1 11/19/2018 19:16 WG1197586

Barium 227 0.360 5.00 1 11/19/2018 19:16 WG1197586

Beryllium U 0.120 2.00 1 11/19/2018 19:16 WG1197586

Cadmium U 0.160 1.00 1 11/19/2018 19:16 WG1197586

Chromium U 0.540 2.00 1 11/19/2018 19:16 WG1197586

Copper 0.554 J 0.520 5.00 1 11/19/2018 19:16 WG1197586

Cobalt U 0.260 2.00 1 11/19/2018 19:16 WG1197586

Iron 3720 15.0 100 1 11/19/2018 19:16 WG1197586

Lead U 0.240 2.00 1 11/19/2018 19:16 WG1197586

Manganese 732 0.250 5.00 1 11/19/2018 19:16 WG1197586

Nickel U 0.350 2.00 1 11/19/2018 19:16 WG1197586

Selenium U 0.380 2.00 1 11/19/2018 19:16 WG1197586

Silver U 0.310 2.00 1 11/19/2018 19:16 WG1197586

Thallium U 0.190 2.00 1 11/19/2018 19:16 WG1197586

Vanadium U 0.180 5.00 1 11/19/2018 19:16 WG1197586

Zinc U 2.56 25.0 1 11/19/2018 19:16 WG1197586

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Acetone U 10.0 50.0 1 11/16/2018 16:15 WG1197903

Acrylonitrile U 1.87 10.0 1 11/16/2018 16:15 WG1197903

Benzene U 0.331 1.00 1 11/16/2018 16:15 WG1197903

Bromochloromethane U 0.520 1.00 1 11/16/2018 16:15 WG1197903

Bromodichloromethane U 0.380 1.00 1 11/16/2018 16:15 WG1197903

Bromoform U 0.469 1.00 1 11/16/2018 16:15 WG1197903

Bromomethane U 0.866 5.00 1 11/16/2018 16:15 WG1197903

Carbon disulfide U 0.275 1.00 1 11/16/2018 16:15 WG1197903

Carbon tetrachloride U 0.379 1.00 1 11/16/2018 16:15 WG1197903

Chlorobenzene U 0.348 1.00 1 11/16/2018 16:15 WG1197903

Chlorodibromomethane U 0.327 1.00 1 11/16/2018 16:15 WG1197903

Chloroethane U 0.453 5.00 1 11/16/2018 16:15 WG1197903

Chloroform U 0.324 5.00 1 11/16/2018 16:15 WG1197903

Chloromethane U 0.276 2.50 1 11/16/2018 16:15 WG1197903

Dibromomethane U 0.346 1.00 1 11/16/2018 16:15 WG1197903

1,2-Dibromoethane U 0.381 1.00 1 11/16/2018 16:15 WG1197903

1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 11/16/2018 16:15 WG1197903

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 8 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 8 of 40

Page 122: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 02L 1 0 4 4 7 5 3

MW-20C o l l e c t e d d a t e / t i m e : 1 1 / 1 3 / 1 8 1 0 : 1 5

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

1,2-Dichlorobenzene U 0.349 1.00 1 11/16/2018 16:15 WG1197903

1,4-Dichlorobenzene U 0.274 1.00 1 11/16/2018 16:15 WG1197903

trans-1,4-Dichloro-2-butene U J4 0.866 2.50 1 11/16/2018 16:15 WG1197903

1,1-Dichloroethane 0.964 J 0.259 1.00 1 11/16/2018 16:15 WG1197903

1,2-Dichloroethane U 0.361 1.00 1 11/16/2018 16:15 WG1197903

1,1-Dichloroethene U 0.398 1.00 1 11/16/2018 16:15 WG1197903

cis-1,2-Dichloroethene U 0.260 1.00 1 11/16/2018 16:15 WG1197903

trans-1,2-Dichloroethene U 0.396 1.00 1 11/16/2018 16:15 WG1197903

1,2-Dichloropropane U 0.306 1.00 1 11/16/2018 16:15 WG1197903

cis-1,3-Dichloropropene U 0.418 1.00 1 11/16/2018 16:15 WG1197903

trans-1,3-Dichloropropene U 0.419 1.00 1 11/16/2018 16:15 WG1197903

Ethylbenzene U 0.384 1.00 1 11/16/2018 16:15 WG1197903

2-Hexanone U 3.82 10.0 1 11/16/2018 16:15 WG1197903

Iodomethane U 1.71 10.0 1 11/16/2018 16:15 WG1197903

2-Butanone (MEK) U 3.93 15.0 1 11/16/2018 16:15 WG1197903

Methylene Chloride U 1.00 5.00 1 11/16/2018 16:15 WG1197903

4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 11/16/2018 16:15 WG1197903

Styrene U 0.307 1.00 1 11/16/2018 16:15 WG1197903

1,1,1,2-Tetrachloroethane U 0.385 1.00 1 11/16/2018 16:15 WG1197903

1,1,2,2-Tetrachloroethane U 0.130 1.00 1 11/16/2018 16:15 WG1197903

Tetrachloroethene U 0.372 1.00 1 11/16/2018 16:15 WG1197903

Toluene U 0.412 1.00 1 11/16/2018 16:15 WG1197903

1,1,1-Trichloroethane U 0.319 1.00 1 11/16/2018 16:15 WG1197903

1,1,2-Trichloroethane U 0.383 1.00 1 11/16/2018 16:15 WG1197903

Trichloroethene U 0.398 1.00 1 11/16/2018 16:15 WG1197903

Trichlorofluoromethane U 1.20 5.00 1 11/16/2018 16:15 WG1197903

1,2,3-Trichloropropane U 0.807 2.50 1 11/16/2018 16:15 WG1197903

Vinyl acetate U 1.63 10.0 1 11/16/2018 16:15 WG1197903

Vinyl chloride 0.350 J 0.259 1.00 1 11/16/2018 16:15 WG1197903

Xylenes, Total U 1.06 3.00 1 11/16/2018 16:15 WG1197903

(S) Toluene-d8 92.9 80.0-120 11/16/2018 16:15 WG1197903

(S) Dibromofluoromethane 118 75.0-120 11/16/2018 16:15 WG1197903

(S) 4-Bromofluorobenzene 110 77.0-126 11/16/2018 16:15 WG1197903

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 9 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 9 of 40

Page 123: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 03L 1 0 4 4 7 5 3

MW-21C o l l e c t e d d a t e / t i m e : 1 1 / 1 3 / 1 8 1 2 : 1 0

Gravimetric Analysis by Method 2540 C-2011

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Dissolved Solids 290000 2820 10000 1 11/18/2018 11:45 WG1198057

Wet Chemistry by Method 9056A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Chloride 6930 51.9 1000 1 11/17/2018 16:54 WG1198004

Sulfate 10100 77.4 5000 1 11/17/2018 16:54 WG1198004

Wet Chemistry by Method 9060A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

TOC (Total Organic Carbon) 562 J 102 1000 1 11/20/2018 22:38 WG1199249

Metals (ICPMS) by Method 6020

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Antimony U 0.754 2.00 1 11/19/2018 19:20 WG1197586

Arsenic 1.28 J 0.250 2.00 1 11/19/2018 19:20 WG1197586

Barium 127 0.360 5.00 1 11/19/2018 19:20 WG1197586

Beryllium U 0.120 2.00 1 11/19/2018 19:20 WG1197586

Cadmium U 0.160 1.00 1 11/19/2018 19:20 WG1197586

Chromium U 0.540 2.00 1 11/19/2018 19:20 WG1197586

Copper U 0.520 5.00 1 11/19/2018 19:20 WG1197586

Cobalt U 0.260 2.00 1 11/19/2018 19:20 WG1197586

Iron 964 15.0 100 1 11/19/2018 19:20 WG1197586

Lead U 0.240 2.00 1 11/19/2018 19:20 WG1197586

Manganese 491 0.250 5.00 1 11/19/2018 19:20 WG1197586

Nickel U 0.350 2.00 1 11/19/2018 19:20 WG1197586

Selenium U 0.380 2.00 1 11/19/2018 19:20 WG1197586

Silver U 0.310 2.00 1 11/19/2018 19:20 WG1197586

Thallium U 0.190 2.00 1 11/19/2018 19:20 WG1197586

Vanadium U 0.180 5.00 1 11/19/2018 19:20 WG1197586

Zinc U 2.56 25.0 1 11/19/2018 19:20 WG1197586

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Acetone U 10.0 50.0 1 11/16/2018 16:37 WG1197903

Acrylonitrile U 1.87 10.0 1 11/16/2018 16:37 WG1197903

Benzene U 0.331 1.00 1 11/16/2018 16:37 WG1197903

Bromochloromethane U 0.520 1.00 1 11/16/2018 16:37 WG1197903

Bromodichloromethane U 0.380 1.00 1 11/16/2018 16:37 WG1197903

Bromoform U 0.469 1.00 1 11/16/2018 16:37 WG1197903

Bromomethane U 0.866 5.00 1 11/16/2018 16:37 WG1197903

Carbon disulfide U 0.275 1.00 1 11/16/2018 16:37 WG1197903

Carbon tetrachloride U 0.379 1.00 1 11/16/2018 16:37 WG1197903

Chlorobenzene U 0.348 1.00 1 11/16/2018 16:37 WG1197903

Chlorodibromomethane U 0.327 1.00 1 11/16/2018 16:37 WG1197903

Chloroethane U 0.453 5.00 1 11/16/2018 16:37 WG1197903

Chloroform U 0.324 5.00 1 11/16/2018 16:37 WG1197903

Chloromethane U 0.276 2.50 1 11/16/2018 16:37 WG1197903

Dibromomethane U 0.346 1.00 1 11/16/2018 16:37 WG1197903

1,2-Dibromoethane U 0.381 1.00 1 11/16/2018 16:37 WG1197903

1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 11/16/2018 16:37 WG1197903

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 10 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 10 of 40

Page 124: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 03L 1 0 4 4 7 5 3

MW-21C o l l e c t e d d a t e / t i m e : 1 1 / 1 3 / 1 8 1 2 : 1 0

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

1,2-Dichlorobenzene U 0.349 1.00 1 11/16/2018 16:37 WG1197903

1,4-Dichlorobenzene U 0.274 1.00 1 11/16/2018 16:37 WG1197903

trans-1,4-Dichloro-2-butene U J4 0.866 2.50 1 11/16/2018 16:37 WG1197903

1,1-Dichloroethane 0.299 J 0.259 1.00 1 11/16/2018 16:37 WG1197903

1,2-Dichloroethane U 0.361 1.00 1 11/16/2018 16:37 WG1197903

1,1-Dichloroethene U 0.398 1.00 1 11/16/2018 16:37 WG1197903

cis-1,2-Dichloroethene U 0.260 1.00 1 11/16/2018 16:37 WG1197903

trans-1,2-Dichloroethene U 0.396 1.00 1 11/16/2018 16:37 WG1197903

1,2-Dichloropropane U 0.306 1.00 1 11/16/2018 16:37 WG1197903

cis-1,3-Dichloropropene U 0.418 1.00 1 11/16/2018 16:37 WG1197903

trans-1,3-Dichloropropene U 0.419 1.00 1 11/16/2018 16:37 WG1197903

Ethylbenzene U 0.384 1.00 1 11/16/2018 16:37 WG1197903

2-Hexanone U 3.82 10.0 1 11/16/2018 16:37 WG1197903

Iodomethane U 1.71 10.0 1 11/16/2018 16:37 WG1197903

2-Butanone (MEK) U 3.93 15.0 1 11/16/2018 16:37 WG1197903

Methylene Chloride U 1.00 5.00 1 11/16/2018 16:37 WG1197903

4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 11/16/2018 16:37 WG1197903

Styrene U 0.307 1.00 1 11/16/2018 16:37 WG1197903

1,1,1,2-Tetrachloroethane U 0.385 1.00 1 11/16/2018 16:37 WG1197903

1,1,2,2-Tetrachloroethane U 0.130 1.00 1 11/16/2018 16:37 WG1197903

Tetrachloroethene U 0.372 1.00 1 11/16/2018 16:37 WG1197903

Toluene U 0.412 1.00 1 11/16/2018 16:37 WG1197903

1,1,1-Trichloroethane U 0.319 1.00 1 11/16/2018 16:37 WG1197903

1,1,2-Trichloroethane U 0.383 1.00 1 11/16/2018 16:37 WG1197903

Trichloroethene U 0.398 1.00 1 11/16/2018 16:37 WG1197903

Trichlorofluoromethane U 1.20 5.00 1 11/16/2018 16:37 WG1197903

1,2,3-Trichloropropane U 0.807 2.50 1 11/16/2018 16:37 WG1197903

Vinyl acetate U 1.63 10.0 1 11/16/2018 16:37 WG1197903

Vinyl chloride U 0.259 1.00 1 11/16/2018 16:37 WG1197903

Xylenes, Total U 1.06 3.00 1 11/16/2018 16:37 WG1197903

(S) Toluene-d8 92.8 80.0-120 11/16/2018 16:37 WG1197903

(S) Dibromofluoromethane 113 75.0-120 11/16/2018 16:37 WG1197903

(S) 4-Bromofluorobenzene 106 77.0-126 11/16/2018 16:37 WG1197903

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 11 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 11 of 40

Page 125: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 04L 1 0 4 4 7 5 3

EB-1C o l l e c t e d d a t e / t i m e : 1 1 / 1 3 / 1 8 1 5 : 0 0

Gravimetric Analysis by Method 2540 C-2011

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Dissolved Solids U 2820 10000 1 11/18/2018 11:45 WG1198057

Wet Chemistry by Method 9056A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Chloride U 51.9 1000 1 11/17/2018 17:59 WG1198004

Sulfate U 77.4 5000 1 11/17/2018 17:59 WG1198004

Wet Chemistry by Method 9060A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

TOC (Total Organic Carbon) 244 J 102 1000 1 11/21/2018 00:13 WG1199249

Metals (ICPMS) by Method 6020

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Antimony U 0.754 2.00 1 11/19/2018 19:25 WG1197586

Arsenic U 0.250 2.00 1 11/19/2018 19:25 WG1197586

Barium 0.726 J 0.360 5.00 1 11/19/2018 19:25 WG1197586

Beryllium U 0.120 2.00 1 11/19/2018 19:25 WG1197586

Cadmium U 0.160 1.00 1 11/19/2018 19:25 WG1197586

Chromium 0.702 J 0.540 2.00 1 11/19/2018 19:25 WG1197586

Copper 6.84 0.520 5.00 1 11/19/2018 19:25 WG1197586

Cobalt U 0.260 2.00 1 11/19/2018 19:25 WG1197586

Iron U 15.0 100 1 11/19/2018 19:25 WG1197586

Lead U 0.240 2.00 1 11/19/2018 19:25 WG1197586

Manganese 0.523 J 0.250 5.00 1 11/19/2018 19:25 WG1197586

Nickel U 0.350 2.00 1 11/19/2018 19:25 WG1197586

Selenium U 0.380 2.00 1 11/19/2018 19:25 WG1197586

Silver U 0.310 2.00 1 11/19/2018 19:25 WG1197586

Thallium U 0.190 2.00 1 11/19/2018 19:25 WG1197586

Vanadium U 0.180 5.00 1 11/19/2018 19:25 WG1197586

Zinc 2.73 J 2.56 25.0 1 11/19/2018 19:25 WG1197586

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Acetone U 10.0 50.0 1 11/16/2018 16:59 WG1197903

Acrylonitrile U 1.87 10.0 1 11/16/2018 16:59 WG1197903

Benzene U 0.331 1.00 1 11/16/2018 16:59 WG1197903

Bromochloromethane U 0.520 1.00 1 11/16/2018 16:59 WG1197903

Bromodichloromethane U 0.380 1.00 1 11/16/2018 16:59 WG1197903

Bromoform U 0.469 1.00 1 11/16/2018 16:59 WG1197903

Bromomethane U 0.866 5.00 1 11/16/2018 16:59 WG1197903

Carbon disulfide U 0.275 1.00 1 11/16/2018 16:59 WG1197903

Carbon tetrachloride U 0.379 1.00 1 11/16/2018 16:59 WG1197903

Chlorobenzene U 0.348 1.00 1 11/16/2018 16:59 WG1197903

Chlorodibromomethane U 0.327 1.00 1 11/16/2018 16:59 WG1197903

Chloroethane U 0.453 5.00 1 11/16/2018 16:59 WG1197903

Chloroform U 0.324 5.00 1 11/16/2018 16:59 WG1197903

Chloromethane U 0.276 2.50 1 11/16/2018 16:59 WG1197903

Dibromomethane U 0.346 1.00 1 11/16/2018 16:59 WG1197903

1,2-Dibromoethane U 0.381 1.00 1 11/16/2018 16:59 WG1197903

1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 11/16/2018 16:59 WG1197903

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 12 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 12 of 40

Page 126: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 04L 1 0 4 4 7 5 3

EB-1C o l l e c t e d d a t e / t i m e : 1 1 / 1 3 / 1 8 1 5 : 0 0

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

1,2-Dichlorobenzene U 0.349 1.00 1 11/16/2018 16:59 WG1197903

1,4-Dichlorobenzene U 0.274 1.00 1 11/16/2018 16:59 WG1197903

trans-1,4-Dichloro-2-butene U J4 0.866 2.50 1 11/16/2018 16:59 WG1197903

1,1-Dichloroethane U 0.259 1.00 1 11/16/2018 16:59 WG1197903

1,2-Dichloroethane U 0.361 1.00 1 11/16/2018 16:59 WG1197903

1,1-Dichloroethene U 0.398 1.00 1 11/16/2018 16:59 WG1197903

cis-1,2-Dichloroethene U 0.260 1.00 1 11/16/2018 16:59 WG1197903

trans-1,2-Dichloroethene U 0.396 1.00 1 11/16/2018 16:59 WG1197903

1,2-Dichloropropane U 0.306 1.00 1 11/16/2018 16:59 WG1197903

cis-1,3-Dichloropropene U 0.418 1.00 1 11/16/2018 16:59 WG1197903

trans-1,3-Dichloropropene U 0.419 1.00 1 11/16/2018 16:59 WG1197903

Ethylbenzene U 0.384 1.00 1 11/16/2018 16:59 WG1197903

2-Hexanone U 3.82 10.0 1 11/16/2018 16:59 WG1197903

Iodomethane U 1.71 10.0 1 11/16/2018 16:59 WG1197903

2-Butanone (MEK) U 3.93 15.0 1 11/16/2018 16:59 WG1197903

Methylene Chloride U 1.00 5.00 1 11/16/2018 16:59 WG1197903

4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 11/16/2018 16:59 WG1197903

Styrene U 0.307 1.00 1 11/16/2018 16:59 WG1197903

1,1,1,2-Tetrachloroethane U 0.385 1.00 1 11/16/2018 16:59 WG1197903

1,1,2,2-Tetrachloroethane U 0.130 1.00 1 11/16/2018 16:59 WG1197903

Tetrachloroethene U 0.372 1.00 1 11/16/2018 16:59 WG1197903

Toluene U 0.412 1.00 1 11/16/2018 16:59 WG1197903

1,1,1-Trichloroethane U 0.319 1.00 1 11/16/2018 16:59 WG1197903

1,1,2-Trichloroethane U 0.383 1.00 1 11/16/2018 16:59 WG1197903

Trichloroethene U 0.398 1.00 1 11/16/2018 16:59 WG1197903

Trichlorofluoromethane U 1.20 5.00 1 11/16/2018 16:59 WG1197903

1,2,3-Trichloropropane U 0.807 2.50 1 11/16/2018 16:59 WG1197903

Vinyl acetate U 1.63 10.0 1 11/16/2018 16:59 WG1197903

Vinyl chloride U 0.259 1.00 1 11/16/2018 16:59 WG1197903

Xylenes, Total U 1.06 3.00 1 11/16/2018 16:59 WG1197903

(S) Toluene-d8 92.9 80.0-120 11/16/2018 16:59 WG1197903

(S) Dibromofluoromethane 114 75.0-120 11/16/2018 16:59 WG1197903

(S) 4-Bromofluorobenzene 112 77.0-126 11/16/2018 16:59 WG1197903

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 13 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 13 of 40

Page 127: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 05L 1 0 4 4 7 5 3

LEACHATE BLDG AC o l l e c t e d d a t e / t i m e : 1 1 / 1 4 / 1 8 1 0 : 3 0

Gravimetric Analysis by Method 2540 C-2011

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Dissolved Solids 5220000 56400 200000 1 11/18/2018 15:12 WG1198284

Wet Chemistry by Method 9056A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Chloride 2380000 2600 50000 50 11/17/2018 18:16 WG1198004

Sulfate U 77.4 5000 1 11/20/2018 17:49 WG1199280

Wet Chemistry by Method 9060A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

TOC (Total Organic Carbon) 781000 2040 20000 20 11/21/2018 00:40 WG1199249

Metals (ICPMS) by Method 6020

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Antimony 19.1 0.754 2.00 1 11/19/2018 23:13 WG1197586

Arsenic 79.3 0.250 2.00 1 11/19/2018 20:51 WG1197586

Barium 2460 0.360 5.00 1 11/19/2018 20:51 WG1197586

Beryllium U 0.120 2.00 1 11/19/2018 20:51 WG1197586

Cadmium U 0.160 1.00 1 11/19/2018 20:51 WG1197586

Chromium 58.3 0.540 2.00 1 11/19/2018 20:51 WG1197586

Copper 13.4 0.520 5.00 1 11/19/2018 20:51 WG1197586

Cobalt 58.6 0.260 2.00 1 11/19/2018 20:51 WG1197586

Iron 5340 15.0 100 1 11/19/2018 20:51 WG1197586

Lead 0.444 J 0.240 2.00 1 11/19/2018 20:51 WG1197586

Manganese 515 0.250 5.00 1 11/19/2018 20:51 WG1197586

Nickel 159 0.350 2.00 1 11/19/2018 20:51 WG1197586

Selenium 3.11 0.380 2.00 1 11/19/2018 20:51 WG1197586

Silver U 0.310 2.00 1 11/19/2018 20:51 WG1197586

Thallium U 0.190 2.00 1 11/19/2018 20:51 WG1197586

Vanadium 25.5 0.180 5.00 1 11/19/2018 20:51 WG1197586

Zinc 16.8 J 2.56 25.0 1 11/19/2018 20:51 WG1197586

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Acetone 286 10.0 50.0 1 11/16/2018 17:21 WG1197903

Acrylonitrile U 1.87 10.0 1 11/16/2018 17:21 WG1197903

Benzene 1.95 0.331 1.00 1 11/16/2018 17:21 WG1197903

Bromochloromethane U 0.520 1.00 1 11/16/2018 17:21 WG1197903

Bromodichloromethane U 0.380 1.00 1 11/16/2018 17:21 WG1197903

Bromoform U 0.469 1.00 1 11/16/2018 17:21 WG1197903

Bromomethane U 0.866 5.00 1 11/16/2018 17:21 WG1197903

Carbon disulfide U 0.275 1.00 1 11/16/2018 17:21 WG1197903

Carbon tetrachloride U 0.379 1.00 1 11/16/2018 17:21 WG1197903

Chlorobenzene 0.378 J 0.348 1.00 1 11/16/2018 17:21 WG1197903

Chlorodibromomethane U 0.327 1.00 1 11/16/2018 17:21 WG1197903

Chloroethane U 0.453 5.00 1 11/16/2018 17:21 WG1197903

Chloroform U 0.324 5.00 1 11/16/2018 17:21 WG1197903

Chloromethane U 0.276 2.50 1 11/16/2018 17:21 WG1197903

Dibromomethane U 0.346 1.00 1 11/16/2018 17:21 WG1197903

1,2-Dibromoethane U 0.381 1.00 1 11/16/2018 17:21 WG1197903

1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 11/16/2018 17:21 WG1197903

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 14 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 14 of 40

Page 128: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 05L 1 0 4 4 7 5 3

LEACHATE BLDG AC o l l e c t e d d a t e / t i m e : 1 1 / 1 4 / 1 8 1 0 : 3 0

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

1,2-Dichlorobenzene U 0.349 1.00 1 11/16/2018 17:21 WG1197903

1,4-Dichlorobenzene 3.98 0.274 1.00 1 11/16/2018 17:21 WG1197903

trans-1,4-Dichloro-2-butene U J4 0.866 2.50 1 11/16/2018 17:21 WG1197903

1,1-Dichloroethane U 0.259 1.00 1 11/16/2018 17:21 WG1197903

1,2-Dichloroethane 0.434 J 0.361 1.00 1 11/16/2018 17:21 WG1197903

1,1-Dichloroethene U 0.398 1.00 1 11/16/2018 17:21 WG1197903

cis-1,2-Dichloroethene 0.467 J 0.260 1.00 1 11/16/2018 17:21 WG1197903

trans-1,2-Dichloroethene U 0.396 1.00 1 11/16/2018 17:21 WG1197903

1,2-Dichloropropane U 0.306 1.00 1 11/16/2018 17:21 WG1197903

cis-1,3-Dichloropropene U 0.418 1.00 1 11/16/2018 17:21 WG1197903

trans-1,3-Dichloropropene U 0.419 1.00 1 11/16/2018 17:21 WG1197903

Ethylbenzene 7.20 0.384 1.00 1 11/16/2018 17:21 WG1197903

2-Hexanone U 3.82 10.0 1 11/16/2018 17:21 WG1197903

Iodomethane U 1.71 10.0 1 11/16/2018 17:21 WG1197903

2-Butanone (MEK) 777 3.93 15.0 1 11/16/2018 17:21 WG1197903

Methylene Chloride U 1.00 5.00 1 11/16/2018 17:21 WG1197903

4-Methyl-2-pentanone (MIBK) 28.8 2.14 10.0 1 11/16/2018 17:21 WG1197903

Styrene 0.698 J 0.307 1.00 1 11/16/2018 17:21 WG1197903

1,1,1,2-Tetrachloroethane U 0.385 1.00 1 11/16/2018 17:21 WG1197903

1,1,2,2-Tetrachloroethane U 0.130 1.00 1 11/16/2018 17:21 WG1197903

Tetrachloroethene U 0.372 1.00 1 11/16/2018 17:21 WG1197903

Toluene 5.57 0.412 1.00 1 11/16/2018 17:21 WG1197903

1,1,1-Trichloroethane U 0.319 1.00 1 11/16/2018 17:21 WG1197903

1,1,2-Trichloroethane U 0.383 1.00 1 11/16/2018 17:21 WG1197903

Trichloroethene U 0.398 1.00 1 11/16/2018 17:21 WG1197903

Trichlorofluoromethane U 1.20 5.00 1 11/16/2018 17:21 WG1197903

1,2,3-Trichloropropane U 0.807 2.50 1 11/16/2018 17:21 WG1197903

Vinyl acetate U 1.63 10.0 1 11/16/2018 17:21 WG1197903

Vinyl chloride 0.399 J 0.259 1.00 1 11/16/2018 17:21 WG1197903

Xylenes, Total 10.4 1.06 3.00 1 11/16/2018 17:21 WG1197903

(S) Toluene-d8 86.1 80.0-120 11/16/2018 17:21 WG1197903

(S) Dibromofluoromethane 81.9 75.0-120 11/16/2018 17:21 WG1197903

(S) 4-Bromofluorobenzene 116 77.0-126 11/16/2018 17:21 WG1197903

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 15 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 15 of 40

Page 129: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 06L 1 0 4 4 7 5 3

LEACHATE BLDG BC o l l e c t e d d a t e / t i m e : 1 1 / 1 4 / 1 8 1 1 : 0 0

Gravimetric Analysis by Method 2540 C-2011

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Dissolved Solids 1750000 28200 100000 1 11/18/2018 15:12 WG1198284

Wet Chemistry by Method 9056A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Chloride 571000 1040 20000 20 11/17/2018 18:49 WG1198004

Sulfate 2360 J 77.4 5000 1 11/17/2018 18:32 WG1198004

Wet Chemistry by Method 9060A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

TOC (Total Organic Carbon) 101000 204 2000 2 11/21/2018 01:10 WG1199249

Metals (ICPMS) by Method 6020

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Antimony 0.909 J 0.754 2.00 1 11/19/2018 19:48 WG1197586

Arsenic 13.9 0.250 2.00 1 11/19/2018 19:48 WG1197586

Barium 578 0.360 5.00 1 11/19/2018 19:48 WG1197586

Beryllium U 0.120 2.00 1 11/19/2018 19:48 WG1197586

Cadmium U 0.160 1.00 1 11/19/2018 19:48 WG1197586

Chromium 9.73 0.540 2.00 1 11/19/2018 19:48 WG1197586

Copper 66.0 0.520 5.00 1 11/19/2018 19:48 WG1197586

Cobalt 15.6 0.260 2.00 1 11/19/2018 19:48 WG1197586

Iron 18400 15.0 100 1 11/19/2018 19:48 WG1197586

Lead 8.13 0.240 2.00 1 11/19/2018 19:48 WG1197586

Manganese 1030 0.250 5.00 1 11/19/2018 19:48 WG1197586

Nickel 51.6 0.350 2.00 1 11/19/2018 19:48 WG1197586

Selenium 0.437 J 0.380 2.00 1 11/19/2018 19:48 WG1197586

Silver U 0.310 2.00 1 11/19/2018 19:48 WG1197586

Thallium U 0.190 2.00 1 11/19/2018 19:48 WG1197586

Vanadium 4.05 J 0.180 5.00 1 11/19/2018 19:48 WG1197586

Zinc 58.3 2.56 25.0 1 11/19/2018 19:48 WG1197586

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Acetone 49.6 J 10.0 50.0 1 11/16/2018 17:43 WG1197903

Acrylonitrile U 1.87 10.0 1 11/16/2018 17:43 WG1197903

Benzene U 0.331 1.00 1 11/16/2018 17:43 WG1197903

Bromochloromethane U 0.520 1.00 1 11/16/2018 17:43 WG1197903

Bromodichloromethane U 0.380 1.00 1 11/16/2018 17:43 WG1197903

Bromoform U 0.469 1.00 1 11/16/2018 17:43 WG1197903

Bromomethane U 0.866 5.00 1 11/16/2018 17:43 WG1197903

Carbon disulfide U 0.275 1.00 1 11/16/2018 17:43 WG1197903

Carbon tetrachloride U 0.379 1.00 1 11/16/2018 17:43 WG1197903

Chlorobenzene U 0.348 1.00 1 11/16/2018 17:43 WG1197903

Chlorodibromomethane U 0.327 1.00 1 11/16/2018 17:43 WG1197903

Chloroethane U 0.453 5.00 1 11/16/2018 17:43 WG1197903

Chloroform U 0.324 5.00 1 11/16/2018 17:43 WG1197903

Chloromethane U 0.276 2.50 1 11/16/2018 17:43 WG1197903

Dibromomethane U 0.346 1.00 1 11/16/2018 17:43 WG1197903

1,2-Dibromoethane U 0.381 1.00 1 11/16/2018 17:43 WG1197903

1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 11/16/2018 17:43 WG1197903

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 16 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 16 of 40

Page 130: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 06L 1 0 4 4 7 5 3

LEACHATE BLDG BC o l l e c t e d d a t e / t i m e : 1 1 / 1 4 / 1 8 1 1 : 0 0

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

1,2-Dichlorobenzene U 0.349 1.00 1 11/16/2018 17:43 WG1197903

1,4-Dichlorobenzene 6.03 0.274 1.00 1 11/16/2018 17:43 WG1197903

trans-1,4-Dichloro-2-butene U J4 0.866 2.50 1 11/16/2018 17:43 WG1197903

1,1-Dichloroethane 1.86 0.259 1.00 1 11/16/2018 17:43 WG1197903

1,2-Dichloroethane U 0.361 1.00 1 11/16/2018 17:43 WG1197903

1,1-Dichloroethene U 0.398 1.00 1 11/16/2018 17:43 WG1197903

cis-1,2-Dichloroethene U 0.260 1.00 1 11/16/2018 17:43 WG1197903

trans-1,2-Dichloroethene U 0.396 1.00 1 11/16/2018 17:43 WG1197903

1,2-Dichloropropane U 0.306 1.00 1 11/16/2018 17:43 WG1197903

cis-1,3-Dichloropropene U 0.418 1.00 1 11/16/2018 17:43 WG1197903

trans-1,3-Dichloropropene U 0.419 1.00 1 11/16/2018 17:43 WG1197903

Ethylbenzene U 0.384 1.00 1 11/16/2018 17:43 WG1197903

2-Hexanone U 3.82 10.0 1 11/16/2018 17:43 WG1197903

Iodomethane U 1.71 10.0 1 11/16/2018 17:43 WG1197903

2-Butanone (MEK) 47.5 3.93 15.0 1 11/16/2018 17:43 WG1197903

Methylene Chloride U 1.00 5.00 1 11/16/2018 17:43 WG1197903

4-Methyl-2-pentanone (MIBK) 3.00 J 2.14 10.0 1 11/16/2018 17:43 WG1197903

Styrene U 0.307 1.00 1 11/16/2018 17:43 WG1197903

1,1,1,2-Tetrachloroethane U 0.385 1.00 1 11/16/2018 17:43 WG1197903

1,1,2,2-Tetrachloroethane U 0.130 1.00 1 11/16/2018 17:43 WG1197903

Tetrachloroethene U 0.372 1.00 1 11/16/2018 17:43 WG1197903

Toluene U 0.412 1.00 1 11/16/2018 17:43 WG1197903

1,1,1-Trichloroethane U 0.319 1.00 1 11/16/2018 17:43 WG1197903

1,1,2-Trichloroethane U 0.383 1.00 1 11/16/2018 17:43 WG1197903

Trichloroethene U 0.398 1.00 1 11/16/2018 17:43 WG1197903

Trichlorofluoromethane U 1.20 5.00 1 11/16/2018 17:43 WG1197903

1,2,3-Trichloropropane U 0.807 2.50 1 11/16/2018 17:43 WG1197903

Vinyl acetate U 1.63 10.0 1 11/16/2018 17:43 WG1197903

Vinyl chloride 0.701 J 0.259 1.00 1 11/16/2018 17:43 WG1197903

Xylenes, Total U 1.06 3.00 1 11/16/2018 17:43 WG1197903

(S) Toluene-d8 93.1 80.0-120 11/16/2018 17:43 WG1197903

(S) Dibromofluoromethane 95.3 75.0-120 11/16/2018 17:43 WG1197903

(S) 4-Bromofluorobenzene 109 77.0-126 11/16/2018 17:43 WG1197903

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 17 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 17 of 40

Page 131: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 07L 1 0 4 4 7 5 3

LEACHATE BLDG CC o l l e c t e d d a t e / t i m e : 1 1 / 1 4 / 1 8 1 1 : 3 0

Gravimetric Analysis by Method 2540 C-2011

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Dissolved Solids 2180000 28200 100000 1 11/18/2018 15:12 WG1198284

Wet Chemistry by Method 9056A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Chloride 932000 1040 20000 20 11/17/2018 19:54 WG1198004

Sulfate 1770 J 77.4 5000 1 11/17/2018 19:05 WG1198004

Wet Chemistry by Method 9060A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

TOC (Total Organic Carbon) 93000 204 2000 2 11/21/2018 16:39 WG1199834

Metals (ICPMS) by Method 6020

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Antimony U 0.754 2.00 1 11/19/2018 19:53 WG1197586

Arsenic 4.25 0.250 2.00 1 11/19/2018 19:53 WG1197586

Barium 654 0.360 5.00 1 11/19/2018 19:53 WG1197586

Beryllium U 0.120 2.00 1 11/19/2018 19:53 WG1197586

Cadmium U 0.160 1.00 1 11/19/2018 19:53 WG1197586

Chromium 3.27 0.540 2.00 1 11/19/2018 19:53 WG1197586

Copper U 0.520 5.00 1 11/19/2018 19:53 WG1197586

Cobalt 3.76 0.260 2.00 1 11/19/2018 19:53 WG1197586

Iron 13900 15.0 100 1 11/19/2018 19:53 WG1197586

Lead 0.330 J 0.240 2.00 1 11/19/2018 19:53 WG1197586

Manganese 2500 0.250 5.00 1 11/19/2018 19:53 WG1197586

Nickel 78.6 0.350 2.00 1 11/19/2018 19:53 WG1197586

Selenium 0.904 J 0.380 2.00 1 11/19/2018 19:53 WG1197586

Silver U 0.310 2.00 1 11/19/2018 19:53 WG1197586

Thallium U 0.190 2.00 1 11/19/2018 19:53 WG1197586

Vanadium 2.94 J 0.180 5.00 1 11/19/2018 19:53 WG1197586

Zinc 4.91 J 2.56 25.0 1 11/19/2018 19:53 WG1197586

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Acetone U 10.0 50.0 1 11/16/2018 18:04 WG1197903

Acrylonitrile U 1.87 10.0 1 11/16/2018 18:04 WG1197903

Benzene 1.23 0.331 1.00 1 11/16/2018 18:04 WG1197903

Bromochloromethane U 0.520 1.00 1 11/16/2018 18:04 WG1197903

Bromodichloromethane U 0.380 1.00 1 11/16/2018 18:04 WG1197903

Bromoform U 0.469 1.00 1 11/16/2018 18:04 WG1197903

Bromomethane U 0.866 5.00 1 11/16/2018 18:04 WG1197903

Carbon disulfide U 0.275 1.00 1 11/16/2018 18:04 WG1197903

Carbon tetrachloride U 0.379 1.00 1 11/16/2018 18:04 WG1197903

Chlorobenzene U 0.348 1.00 1 11/16/2018 18:04 WG1197903

Chlorodibromomethane U 0.327 1.00 1 11/16/2018 18:04 WG1197903

Chloroethane U 0.453 5.00 1 11/16/2018 18:04 WG1197903

Chloroform U 0.324 5.00 1 11/16/2018 18:04 WG1197903

Chloromethane U 0.276 2.50 1 11/16/2018 18:04 WG1197903

Dibromomethane U 0.346 1.00 1 11/16/2018 18:04 WG1197903

1,2-Dibromoethane U 0.381 1.00 1 11/16/2018 18:04 WG1197903

1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 11/16/2018 18:04 WG1197903

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 18 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 18 of 40

Page 132: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 07L 1 0 4 4 7 5 3

LEACHATE BLDG CC o l l e c t e d d a t e / t i m e : 1 1 / 1 4 / 1 8 1 1 : 3 0

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

1,2-Dichlorobenzene U 0.349 1.00 1 11/16/2018 18:04 WG1197903

1,4-Dichlorobenzene 0.413 J 0.274 1.00 1 11/16/2018 18:04 WG1197903

trans-1,4-Dichloro-2-butene U J4 0.866 2.50 1 11/16/2018 18:04 WG1197903

1,1-Dichloroethane U 0.259 1.00 1 11/16/2018 18:04 WG1197903

1,2-Dichloroethane 0.362 J 0.361 1.00 1 11/16/2018 18:04 WG1197903

1,1-Dichloroethene U 0.398 1.00 1 11/16/2018 18:04 WG1197903

cis-1,2-Dichloroethene U 0.260 1.00 1 11/16/2018 18:04 WG1197903

trans-1,2-Dichloroethene U 0.396 1.00 1 11/16/2018 18:04 WG1197903

1,2-Dichloropropane U 0.306 1.00 1 11/16/2018 18:04 WG1197903

cis-1,3-Dichloropropene U 0.418 1.00 1 11/16/2018 18:04 WG1197903

trans-1,3-Dichloropropene U 0.419 1.00 1 11/16/2018 18:04 WG1197903

Ethylbenzene U 0.384 1.00 1 11/16/2018 18:04 WG1197903

2-Hexanone U 3.82 10.0 1 11/16/2018 18:04 WG1197903

Iodomethane U 1.71 10.0 1 11/16/2018 18:04 WG1197903

2-Butanone (MEK) U 3.93 15.0 1 11/16/2018 18:04 WG1197903

Methylene Chloride U 1.00 5.00 1 11/16/2018 18:04 WG1197903

4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 11/16/2018 18:04 WG1197903

Styrene U 0.307 1.00 1 11/16/2018 18:04 WG1197903

1,1,1,2-Tetrachloroethane U 0.385 1.00 1 11/16/2018 18:04 WG1197903

1,1,2,2-Tetrachloroethane U 0.130 1.00 1 11/16/2018 18:04 WG1197903

Tetrachloroethene U 0.372 1.00 1 11/16/2018 18:04 WG1197903

Toluene U 0.412 1.00 1 11/16/2018 18:04 WG1197903

1,1,1-Trichloroethane U 0.319 1.00 1 11/16/2018 18:04 WG1197903

1,1,2-Trichloroethane U 0.383 1.00 1 11/16/2018 18:04 WG1197903

Trichloroethene U 0.398 1.00 1 11/16/2018 18:04 WG1197903

Trichlorofluoromethane U 1.20 5.00 1 11/16/2018 18:04 WG1197903

1,2,3-Trichloropropane U 0.807 2.50 1 11/16/2018 18:04 WG1197903

Vinyl acetate U 1.63 10.0 1 11/16/2018 18:04 WG1197903

Vinyl chloride U 0.259 1.00 1 11/16/2018 18:04 WG1197903

Xylenes, Total 4.28 1.06 3.00 1 11/16/2018 18:04 WG1197903

(S) Toluene-d8 92.7 80.0-120 11/16/2018 18:04 WG1197903

(S) Dibromofluoromethane 107 75.0-120 11/16/2018 18:04 WG1197903

(S) 4-Bromofluorobenzene 106 77.0-126 11/16/2018 18:04 WG1197903

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 19 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 19 of 40

Page 133: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 08L 1 0 4 4 7 5 3

TRIP BLANKC o l l e c t e d d a t e / t i m e : 1 1 / 1 3 / 1 8 0 0 : 0 0

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Acetone U 10.0 50.0 1 11/16/2018 15:09 WG1197903

Acrylonitrile U 1.87 10.0 1 11/16/2018 15:09 WG1197903

Benzene U 0.331 1.00 1 11/16/2018 15:09 WG1197903

Bromochloromethane U 0.520 1.00 1 11/16/2018 15:09 WG1197903

Bromodichloromethane U 0.380 1.00 1 11/16/2018 15:09 WG1197903

Bromoform U 0.469 1.00 1 11/16/2018 15:09 WG1197903

Bromomethane U 0.866 5.00 1 11/16/2018 15:09 WG1197903

Carbon disulfide U 0.275 1.00 1 11/16/2018 15:09 WG1197903

Carbon tetrachloride U 0.379 1.00 1 11/16/2018 15:09 WG1197903

Chlorobenzene U 0.348 1.00 1 11/16/2018 15:09 WG1197903

Chlorodibromomethane U 0.327 1.00 1 11/16/2018 15:09 WG1197903

Chloroethane U 0.453 5.00 1 11/16/2018 15:09 WG1197903

Chloroform U 0.324 5.00 1 11/16/2018 15:09 WG1197903

Chloromethane U 0.276 2.50 1 11/16/2018 15:09 WG1197903

Dibromomethane U 0.346 1.00 1 11/16/2018 15:09 WG1197903

1,2-Dibromoethane U 0.381 1.00 1 11/16/2018 15:09 WG1197903

1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 11/16/2018 15:09 WG1197903

1,2-Dichlorobenzene U 0.349 1.00 1 11/16/2018 15:09 WG1197903

1,4-Dichlorobenzene U 0.274 1.00 1 11/16/2018 15:09 WG1197903

trans-1,4-Dichloro-2-butene U J4 0.866 2.50 1 11/16/2018 15:09 WG1197903

1,1-Dichloroethane U 0.259 1.00 1 11/16/2018 15:09 WG1197903

1,2-Dichloroethane U 0.361 1.00 1 11/16/2018 15:09 WG1197903

1,1-Dichloroethene U 0.398 1.00 1 11/16/2018 15:09 WG1197903

cis-1,2-Dichloroethene U 0.260 1.00 1 11/16/2018 15:09 WG1197903

trans-1,2-Dichloroethene U 0.396 1.00 1 11/16/2018 15:09 WG1197903

1,2-Dichloropropane U 0.306 1.00 1 11/16/2018 15:09 WG1197903

cis-1,3-Dichloropropene U 0.418 1.00 1 11/16/2018 15:09 WG1197903

trans-1,3-Dichloropropene U 0.419 1.00 1 11/16/2018 15:09 WG1197903

Ethylbenzene U 0.384 1.00 1 11/16/2018 15:09 WG1197903

2-Hexanone U 3.82 10.0 1 11/16/2018 15:09 WG1197903

Iodomethane U 1.71 10.0 1 11/16/2018 15:09 WG1197903

2-Butanone (MEK) U 3.93 15.0 1 11/16/2018 15:09 WG1197903

Methylene Chloride U 1.00 5.00 1 11/16/2018 15:09 WG1197903

4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 11/16/2018 15:09 WG1197903

Styrene U 0.307 1.00 1 11/16/2018 15:09 WG1197903

1,1,1,2-Tetrachloroethane U 0.385 1.00 1 11/16/2018 15:09 WG1197903

1,1,2,2-Tetrachloroethane U 0.130 1.00 1 11/16/2018 15:09 WG1197903

Tetrachloroethene U 0.372 1.00 1 11/16/2018 15:09 WG1197903

Toluene U 0.412 1.00 1 11/16/2018 15:09 WG1197903

1,1,1-Trichloroethane U 0.319 1.00 1 11/16/2018 15:09 WG1197903

1,1,2-Trichloroethane U 0.383 1.00 1 11/16/2018 15:09 WG1197903

Trichloroethene U 0.398 1.00 1 11/16/2018 15:09 WG1197903

Trichlorofluoromethane U 1.20 5.00 1 11/16/2018 15:09 WG1197903

1,2,3-Trichloropropane U 0.807 2.50 1 11/16/2018 15:09 WG1197903

Vinyl acetate U 1.63 10.0 1 11/16/2018 15:09 WG1197903

Vinyl chloride U 0.259 1.00 1 11/16/2018 15:09 WG1197903

Xylenes, Total U 1.06 3.00 1 11/16/2018 15:09 WG1197903

(S) Toluene-d8 92.7 80.0-120 11/16/2018 15:09 WG1197903

(S) Dibromofluoromethane 115 75.0-120 11/16/2018 15:09 WG1197903

(S) 4-Bromofluorobenzene 107 77.0-126 11/16/2018 15:09 WG1197903

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 20 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 20 of 40

Page 134: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1198057G r a v i m e t r i c A n a l y s i s b y M e t h o d 2 5 4 0 C - 2 0 1 1 L 1 0 4 4 7 5 3 - 0 1 , 0 2 , 0 3 , 0 4

Method Blank (MB)

(MB) R3362464-1 11/18/18 11:45

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

Dissolved Solids U 2820 10000

L1044662-03 Original Sample (OS) • Duplicate (DUP)

(OS) L1044662-03 11/18/18 11:45 • (DUP) R3362464-3 11/18/18 11:45

Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits

Analyte ug/l ug/l % %

Dissolved Solids 131000 144000 1 9.45 J3 5

Laboratory Control Sample (LCS)

(LCS) R3362464-2 11/18/18 11:45

Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier

Analyte ug/l ug/l % %

Dissolved Solids 8800000 8620000 98.0 85.0-115

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 21 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 21 of 40

Page 135: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1198284G r a v i m e t r i c A n a l y s i s b y M e t h o d 2 5 4 0 C - 2 0 1 1 L 1 0 4 4 7 5 3 - 0 5 , 0 6 , 0 7

Method Blank (MB)

(MB) R3362492-1 11/18/18 15:12

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

Dissolved Solids U 2820 10000

L1044761-01 Original Sample (OS) • Duplicate (DUP)

(OS) L1044761-01 11/18/18 15:12 • (DUP) R3362492-3 11/18/18 15:12

Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits

Analyte ug/l ug/l % %

Dissolved Solids 93000 98000 1 5.24 J3 5

Laboratory Control Sample (LCS)

(LCS) R3362492-2 11/18/18 15:12

Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier

Analyte ug/l ug/l % %

Dissolved Solids 8800000 8450000 96.0 85.0-115

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 22 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 22 of 40

Page 136: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1197480W e t C h e m i s t r y b y M e t h o d 9 0 5 6 A L 1 0 4 4 7 5 3 - 0 1 , 0 2

Method Blank (MB)

(MB) R3360837-1 11/16/18 23:24

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

Chloride U 51.9 1000

Sulfate U 77.4 5000

L1044612-03 Original Sample (OS) • Duplicate (DUP)

(OS) L1044612-03 11/17/18 03:14 • (DUP) R3360837-3 11/17/18 03:30

Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits

Analyte ug/l ug/l % %

Chloride 8460 8440 1 0.314 15

Sulfate 11400 11300 1 0.611 15

L1044612-07 Original Sample (OS) • Duplicate (DUP)

(OS) L1044612-07 11/17/18 05:42 • (DUP) R3360837-6 11/17/18 05:58

Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits

Analyte ug/l ug/l % %

Chloride 13000 13000 1 0.0660 15

Sulfate 52800 53000 1 0.275 15

Laboratory Control Sample (LCS)

(LCS) R3360837-2 11/16/18 23:41

Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier

Analyte ug/l ug/l % %

Chloride 40000 40200 100 80.0-120

Sulfate 40000 40500 101 80.0-120

L1044612-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)

(OS) L1044612-03 11/17/18 03:14 • (MS) R3360837-4 11/17/18 03:47 • (MSD) R3360837-5 11/17/18 04:03

Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l ug/l % % % % %

Chloride 50000 8460 60600 60600 104 104 1 80.0-120 0.119 15

Sulfate 50000 11400 62100 62500 101 102 1 80.0-120 0.687 15

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 23 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 23 of 40

Page 137: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1197480W e t C h e m i s t r y b y M e t h o d 9 0 5 6 A L 1 0 4 4 7 5 3 - 0 1 , 0 2

L1044612-07 Original Sample (OS) • Matrix Spike (MS)

(OS) L1044612-07 11/17/18 05:42 • (MS) R3360837-7 11/17/18 06:14

Spike Amount Original Result MS Result MS Rec. Dilution Rec. Limits MS Qualifier

Analyte ug/l ug/l ug/l % %

Chloride 50000 13000 65100 104 1 80.0-120

Sulfate 50000 52800 103000 101 1 80.0-120 E

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 24 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 24 of 40

Page 138: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1198004W e t C h e m i s t r y b y M e t h o d 9 0 5 6 A L 1 0 4 4 7 5 3 - 0 3 , 0 4 , 0 5 , 0 6 , 0 7

Method Blank (MB)

(MB) R3361346-1 11/17/18 09:42

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

Chloride U 51.9 1000

Sulfate U 77.4 5000

L1044753-03 Original Sample (OS) • Duplicate (DUP)

(OS) L1044753-03 11/17/18 16:54 • (DUP) R3361346-3 11/17/18 17:10

Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits

Analyte ug/l ug/l % %

Chloride 6930 6940 1 0.176 15

Sulfate 10100 10100 1 0.0572 15

L1044950-35 Original Sample (OS) • Duplicate (DUP)

(OS) L1044950-35 11/17/18 23:28 • (DUP) R3361346-6 11/17/18 23:44

Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits

Analyte ug/l ug/l % %

Chloride 1080 1070 1 0.960 15

Sulfate 5080 4960 1 2.47 15

Laboratory Control Sample (LCS)

(LCS) R3361346-2 11/17/18 09:59

Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier

Analyte ug/l ug/l % %

Chloride 40000 38800 97.1 80.0-120

Sulfate 40000 39300 98.1 80.0-120

L1044753-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)

(OS) L1044753-03 11/17/18 16:54 • (MS) R3361346-4 11/17/18 17:26 • (MSD) R3361346-5 11/17/18 17:43

Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l ug/l % % % % %

Chloride 50000 6930 56300 56800 98.8 99.8 1 80.0-120 0.916 15

Sulfate 50000 10100 59900 60500 99.5 101 1 80.0-120 0.981 15

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 25 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 25 of 40

Page 139: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1198004W e t C h e m i s t r y b y M e t h o d 9 0 5 6 A L 1 0 4 4 7 5 3 - 0 3 , 0 4 , 0 5 , 0 6 , 0 7

L1044950-35 Original Sample (OS) • Matrix Spike (MS)

(OS) L1044950-35 11/17/18 23:28 • (MS) R3361346-7 11/18/18 00:00

Spike Amount Original Result MS Result MS Rec. Dilution Rec. Limits MS Qualifier

Analyte ug/l ug/l ug/l % %

Chloride 50000 1080 51900 102 1 80.0-120

Sulfate 50000 5080 56200 102 1 80.0-120

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 26 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 26 of 40

Page 140: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1199280W e t C h e m i s t r y b y M e t h o d 9 0 5 6 A L 1 0 4 4 7 5 3 - 0 5

Method Blank (MB)

(MB) R3361873-1 11/20/18 16:26

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

Sulfate U 77.4 5000

L1045280-02 Original Sample (OS) • Duplicate (DUP)

(OS) L1045280-02 11/20/18 18:38 • (DUP) R3361873-3 11/20/18 18:54

Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits

Analyte ug/l ug/l % %

Sulfate 69500 69800 1 0.433 15

L1045353-01 Original Sample (OS) • Duplicate (DUP)

(OS) L1045353-01 11/20/18 22:27 • (DUP) R3361873-6 11/20/18 22:44

Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits

Analyte ug/l ug/l % %

Sulfate 19100 19400 1 1.41 15

Laboratory Control Sample (LCS)

(LCS) R3361873-2 11/20/18 16:42

Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier

Analyte ug/l ug/l % %

Sulfate 40000 39900 99.8 80.0-120

L1045280-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)

(OS) L1045280-02 11/20/18 18:38 • (MS) R3361873-4 11/20/18 19:10 • (MSD) R3361873-5 11/20/18 19:27

Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l ug/l % % % % %

Sulfate 50000 69500 117000 117000 94.1 94.2 1 80.0-120 E E 0.0444 15

L1045353-01 Original Sample (OS) • Matrix Spike (MS)

(OS) L1045353-01 11/20/18 22:27 • (MS) R3361873-7 11/20/18 23:33

Spike Amount Original Result MS Result MS Rec. Dilution Rec. Limits MS Qualifier

Analyte ug/l ug/l ug/l % %

Sulfate 50000 19100 70300 102 1 80.0-120

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 27 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 27 of 40

Page 141: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1199249W e t C h e m i s t r y b y M e t h o d 9 0 6 0 A L 1 0 4 4 7 5 3 - 0 1 , 0 2 , 0 3 , 0 4 , 0 5 , 0 6

Method Blank (MB)

(MB) R3361665-1 11/20/18 10:10

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

TOC (Total Organic Carbon) U 102 1000

L1043880-01 Original Sample (OS) • Duplicate (DUP)

(OS) L1043880-01 11/20/18 12:30 • (DUP) R3361665-3 11/20/18 12:55

Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits

Analyte ug/l ug/l % %

TOC 3960 3880 1 2.17 20

L1044364-01 Original Sample (OS) • Duplicate (DUP)

(OS) L1044364-01 11/20/18 21:15 • (DUP) R3361665-8 11/20/18 21:36

Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits

Analyte ug/l ug/l % %

TOC ND 186 1 0.000 20

Laboratory Control Sample (LCS)

(LCS) R3361665-2 11/20/18 11:01

Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier

Analyte ug/l ug/l % %

TOC 75000 82100 109 85.0-115

L1044066-06 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)

(OS) L1044066-06 11/20/18 17:09 • (MS) R3361665-4 11/20/18 17:29 • (MSD) R3361665-5 11/20/18 17:50

Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l ug/l % % % % %

TOC 50000 ND 53300 53400 106 106 1 80.0-120 0.150 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 28 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 28 of 40

Page 142: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1199834W e t C h e m i s t r y b y M e t h o d 9 0 6 0 A L 1 0 4 4 7 5 3 - 0 7

Method Blank (MB)

(MB) R3362293-1 11/21/18 14:44

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

TOC (Total Organic Carbon) U 102 1000

L1044909-02 Original Sample (OS) • Duplicate (DUP)

(OS) L1044909-02 11/21/18 17:47 • (DUP) R3362293-3 11/21/18 18:08

Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits

Analyte ug/l ug/l % %

TOC 393 568 1 36.5 J P1 20

L1044957-04 Original Sample (OS) • Duplicate (DUP)

(OS) L1044957-04 11/22/18 00:38 • (DUP) R3362293-6 11/22/18 00:59

Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits

Analyte ug/l ug/l % %

TOC ND 598 1 0.000 20

Laboratory Control Sample (LCS)

(LCS) R3362293-2 11/21/18 15:23

Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier

Analyte ug/l ug/l % %

TOC 75000 77700 104 85.0-115

L1044944-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)

(OS) L1044944-02 11/21/18 21:00 • (MS) R3362293-4 11/21/18 21:23 • (MSD) R3362293-5 11/21/18 21:43

Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l ug/l % % % % %

TOC 50000 1020 51900 51800 102 102 1 80.0-120 0.0771 20

L1044958-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)

(OS) L1044958-01 11/22/18 01:17 • (MS) R3362293-7 11/22/18 01:39 • (MSD) R3362293-8 11/22/18 01:59

Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l ug/l % % % % %

TOC 50000 ND 51800 51300 102 101 1 80.0-120 0.970 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 29 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 29 of 40

Page 143: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1197586M e t a l s ( I C P M S ) b y M e t h o d 6 0 2 0 L 1 0 4 4 7 5 3 - 0 1 , 0 2 , 0 3 , 0 4 , 0 5 , 0 6 , 0 7

Method Blank (MB)

(MB) R3361401-1 11/19/18 18:44

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

Antimony U 0.754 2.00

Arsenic U 0.250 2.00

Barium U 0.360 5.00

Beryllium U 0.120 2.00

Cadmium U 0.160 1.00

Chromium U 0.540 2.00

Copper U 0.520 5.00

Cobalt U 0.260 2.00

Iron 15.3 J 15.0 100

Lead U 0.240 2.00

Manganese U 0.250 5.00

Nickel U 0.350 2.00

Selenium U 0.380 2.00

Silver U 0.310 2.00

Thallium U 0.190 2.00

Vanadium U 0.180 5.00

Zinc U 2.56 25.0

Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)

(LCS) R3361401-2 11/19/18 18:48 • (LCSD) R3361401-3 11/19/18 18:53

Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l % % % % %

Antimony 50.0 58.1 57.5 116 115 80.0-120 1.00 20

Arsenic 50.0 48.5 49.5 97.1 99.1 80.0-120 2.04 20

Barium 50.0 48.0 47.0 96.0 94.1 80.0-120 2.06 20

Beryllium 50.0 46.7 47.3 93.3 94.7 80.0-120 1.41 20

Cadmium 50.0 48.1 48.1 96.2 96.2 80.0-120 0.0439 20

Chromium 50.0 51.8 51.7 104 103 80.0-120 0.178 20

Copper 50.0 51.3 50.6 103 101 80.0-120 1.22 20

Cobalt 50.0 51.7 52.4 103 105 80.0-120 1.45 20

Iron 5000 5030 5080 101 102 80.0-120 0.967 20

Lead 50.0 50.9 49.7 102 99.4 80.0-120 2.52 20

Manganese 50.0 48.7 50.1 97.3 100 80.0-120 2.94 20

Nickel 50.0 51.8 52.6 104 105 80.0-120 1.42 20

Selenium 50.0 53.9 53.6 108 107 80.0-120 0.570 20

Silver 50.0 52.4 52.9 105 106 80.0-120 1.01 20

Thallium 50.0 48.7 48.8 97.5 97.6 80.0-120 0.199 20

Vanadium 50.0 49.1 50.4 98.1 101 80.0-120 2.62 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 30 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 30 of 40

Page 144: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1197586M e t a l s ( I C P M S ) b y M e t h o d 6 0 2 0 L 1 0 4 4 7 5 3 - 0 1 , 0 2 , 0 3 , 0 4 , 0 5 , 0 6 , 0 7

Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)

(LCS) R3361401-2 11/19/18 18:48 • (LCSD) R3361401-3 11/19/18 18:53

Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l % % % % %

Zinc 50.0 53.1 53.8 106 108 80.0-120 1.26 20

L1044753-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)

(OS) L1044753-01 11/19/18 18:58 • (MS) R3361401-5 11/19/18 19:07 • (MSD) R3361401-6 11/19/18 19:11

Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l ug/l % % % % %

Antimony 50.0 U 57.0 56.9 114 114 1 75.0-125 0.266 20

Arsenic 50.0 1.14 49.7 50.0 97.1 97.7 1 75.0-125 0.612 20

Barium 50.0 140 186 190 91.3 101 1 75.0-125 2.58 20

Beryllium 50.0 U 46.4 45.3 92.9 90.7 1 75.0-125 2.38 20

Cadmium 50.0 U 49.2 48.8 98.4 97.6 1 75.0-125 0.775 20

Chromium 50.0 U 49.9 49.8 99.7 99.6 1 75.0-125 0.129 20

Copper 50.0 U 48.4 48.2 96.8 96.3 1 75.0-125 0.504 20

Cobalt 50.0 U 50.0 50.0 100 99.9 1 75.0-125 0.0616 20

Iron 5000 1710 6770 6750 101 101 1 75.0-125 0.276 20

Lead 50.0 0.643 49.2 49.4 97.2 97.5 1 75.0-125 0.285 20

Manganese 50.0 396 435 444 77.4 94.8 1 75.0-125 1.98 20

Nickel 50.0 U 50.9 50.2 102 100 1 75.0-125 1.40 20

Selenium 50.0 U 52.5 54.2 105 108 1 75.0-125 3.19 20

Silver 50.0 U 53.0 52.7 106 105 1 75.0-125 0.714 20

Thallium 50.0 U 48.7 48.2 97.3 96.4 1 75.0-125 0.956 20

Vanadium 50.0 U 48.9 48.4 97.7 96.8 1 75.0-125 0.896 20

Zinc 50.0 U 51.6 49.4 103 98.9 1 75.0-125 4.36 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 31 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 31 of 40

Page 145: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1197903V o l a t i l e O r g a n i c C o m p o u n d s ( G C / M S ) b y M e t h o d 8 2 6 0 B L 1 0 4 4 7 5 3 - 0 1 , 0 2 , 0 3 , 0 4 , 0 5 , 0 6 , 0 7 , 0 8

Method Blank (MB)

(MB) R3360974-3 11/16/18 13:17

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

Acetone U 10.0 50.0

Acrylonitrile U 1.87 10.0

Benzene U 0.331 1.00

Bromodichloromethane U 0.380 1.00

Bromochloromethane U 0.520 1.00

Bromoform U 0.469 1.00

Bromomethane U 0.866 5.00

Carbon disulfide U 0.275 1.00

Carbon tetrachloride U 0.379 1.00

Chlorobenzene U 0.348 1.00

Chlorodibromomethane U 0.327 1.00

Chloroethane U 0.453 5.00

Chloroform U 0.324 5.00

Chloromethane U 0.276 2.50

1,2-Dibromo-3-Chloropropane U 1.33 5.00

1,2-Dibromoethane U 0.381 1.00

1,2-Dichlorobenzene U 0.349 1.00

Dibromomethane U 0.346 1.00

1,4-Dichlorobenzene U 0.274 1.00

trans-1,4-Dichloro-2-butene U 0.866 2.50

1,1-Dichloroethane U 0.259 1.00

1,2-Dichloroethane U 0.361 1.00

1,1-Dichloroethene U 0.398 1.00

cis-1,2-Dichloroethene U 0.260 1.00

trans-1,2-Dichloroethene U 0.396 1.00

1,2-Dichloropropane U 0.306 1.00

cis-1,3-Dichloropropene U 0.418 1.00

trans-1,3-Dichloropropene U 0.419 1.00

Ethylbenzene U 0.384 1.00

2-Hexanone U 3.82 10.0

2-Butanone (MEK) U 3.93 15.0

Iodomethane U 1.71 10.0

Methylene Chloride U 1.00 5.00

4-Methyl-2-pentanone (MIBK) U 2.14 10.0

Styrene U 0.307 1.00

1,1,2,2-Tetrachloroethane U 0.130 1.00

Tetrachloroethene U 0.372 1.00

Toluene U 0.412 1.00

1,1,1,2-Tetrachloroethane U 0.385 1.00

1,1,1-Trichloroethane U 0.319 1.00

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 32 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 32 of 40

Page 146: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1197903V o l a t i l e O r g a n i c C o m p o u n d s ( G C / M S ) b y M e t h o d 8 2 6 0 B L 1 0 4 4 7 5 3 - 0 1 , 0 2 , 0 3 , 0 4 , 0 5 , 0 6 , 0 7 , 0 8

Method Blank (MB)

(MB) R3360974-3 11/16/18 13:17

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

1,1,2-Trichloroethane U 0.383 1.00

Trichloroethene U 0.398 1.00

Trichlorofluoromethane U 1.20 5.00

1,2,3-Trichloropropane U 0.807 2.50

Vinyl chloride U 0.259 1.00

Xylenes, Total U 1.06 3.00

Vinyl acetate U 1.63 10.0

(S) Toluene-d8 93.2 80.0-120

(S) Dibromofluoromethane 115 75.0-120

(S) 4-Bromofluorobenzene 113 77.0-126

Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)

(LCS) R3360974-1 11/16/18 12:13 • (LCSD) R3360974-2 11/16/18 12:34

Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l % % % % %

Acetone 125 154 163 123 130 19.0-160 5.88 27

Benzene 25.0 23.5 23.1 94.1 92.3 70.0-123 1.93 20

Bromodichloromethane 25.0 26.1 25.5 104 102 75.0-120 2.53 20

Bromochloromethane 25.0 22.2 22.0 89.0 87.8 76.0-122 1.29 20

Bromoform 25.0 25.2 25.4 101 102 68.0-132 0.697 20

Bromomethane 25.0 23.8 22.5 95.4 90.2 10.0-160 5.61 25

Carbon disulfide 25.0 21.4 20.0 85.7 80.2 61.0-128 6.65 20

Carbon tetrachloride 25.0 26.5 25.6 106 103 68.0-126 3.40 20

Chlorobenzene 25.0 20.9 20.6 83.7 82.6 80.0-121 1.34 20

Chlorodibromomethane 25.0 22.9 23.3 91.5 93.1 77.0-125 1.77 20

Chloroethane 25.0 25.9 24.4 104 97.4 47.0-150 6.28 20

Chloroform 25.0 24.9 24.7 99.5 98.9 73.0-120 0.620 20

Chloromethane 25.0 30.4 30.4 121 122 41.0-142 0.223 20

Acrylonitrile 125 134 137 107 109 55.0-149 2.03 20

1,2-Dibromo-3-Chloropropane 25.0 20.8 21.6 83.3 86.3 58.0-134 3.57 20

1,2-Dibromoethane 25.0 21.6 21.3 86.5 85.3 80.0-122 1.38 20

1,2-Dichlorobenzene 25.0 22.0 21.0 87.9 84.0 79.0-121 4.58 20

1,4-Dichlorobenzene 25.0 21.7 20.7 86.8 82.9 79.0-120 4.63 20

1,1-Dichloroethane 25.0 25.9 25.6 103 102 70.0-126 1.17 20

1,2-Dichloroethane 25.0 28.8 29.2 115 117 70.0-128 1.63 20

1,1-Dichloroethene 25.0 23.1 22.4 92.3 89.6 71.0-124 2.94 20

cis-1,2-Dichloroethene 25.0 22.2 22.2 88.8 89.0 73.0-120 0.205 20

trans-1,2-Dichloroethene 25.0 23.6 23.0 94.3 91.9 73.0-120 2.50 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 33 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 33 of 40

Page 147: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1197903V o l a t i l e O r g a n i c C o m p o u n d s ( G C / M S ) b y M e t h o d 8 2 6 0 B L 1 0 4 4 7 5 3 - 0 1 , 0 2 , 0 3 , 0 4 , 0 5 , 0 6 , 0 7 , 0 8

Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)

(LCS) R3360974-1 11/16/18 12:13 • (LCSD) R3360974-2 11/16/18 12:34

Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l % % % % %

1,2-Dichloropropane 25.0 24.5 23.5 98.1 94.0 77.0-125 4.24 20

cis-1,3-Dichloropropene 25.0 23.5 22.9 93.9 91.5 80.0-123 2.61 20

trans-1,3-Dichloropropene 25.0 24.1 23.7 96.5 94.8 78.0-124 1.84 20

Dibromomethane 25.0 24.9 24.6 99.6 98.5 80.0-120 1.14 20

Ethylbenzene 25.0 21.1 20.5 84.5 82.0 79.0-123 2.92 20

trans-1,4-Dichloro-2-butene 25.0 37.0 35.9 148 144 33.0-144 J4 2.92 20

2-Hexanone 125 122 123 97.6 98.2 67.0-149 0.615 20

2-Butanone (MEK) 125 152 155 122 124 44.0-160 1.50 20

Methylene Chloride 25.0 21.9 21.8 87.6 87.4 67.0-120 0.240 20

4-Methyl-2-pentanone (MIBK) 125 146 144 117 115 68.0-142 1.42 20

Styrene 25.0 24.8 24.0 99.1 96.1 73.0-130 3.05 20

1,1,2,2-Tetrachloroethane 25.0 25.0 24.5 99.9 98.1 65.0-130 1.74 20

Tetrachloroethene 25.0 19.4 18.6 77.6 74.5 72.0-132 4.04 20

Iodomethane 125 115 113 91.6 90.4 33.0-147 1.37 26

Toluene 25.0 21.4 20.9 85.5 83.6 79.0-120 2.17 20

1,1,1-Trichloroethane 25.0 27.7 27.0 111 108 73.0-124 2.42 20

1,1,2-Trichloroethane 25.0 21.2 21.2 84.7 84.9 80.0-120 0.288 20

Trichloroethene 25.0 22.5 21.5 90.0 86.1 78.0-124 4.48 20

Trichlorofluoromethane 25.0 31.2 31.3 125 125 59.0-147 0.334 20

Vinyl chloride 25.0 28.2 26.6 113 106 67.0-131 5.98 20

1,1,1,2-Tetrachloroethane 25.0 22.3 22.3 89.4 89.3 75.0-125 0.0440 20

Xylenes, Total 75.0 62.9 61.1 83.9 81.5 79.0-123 2.90 20

1,2,3-Trichloropropane 25.0 26.4 26.2 106 105 73.0-130 0.732 20

Vinyl acetate 125 162 160 130 128 11.0-160 1.51 20

(S) Toluene-d8 94.6 95.6 80.0-120

(S) Dibromofluoromethane 103 108 75.0-120

(S) 4-Bromofluorobenzene 106 108 77.0-126

L1044762-19 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)

(OS) L1044762-19 11/16/18 22:05 • (MS) R3360974-4 11/16/18 22:27 • (MSD) R3360974-5 11/16/18 22:49

Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l ug/l % % % % %

Acetone 125 ND 165 151 132 120 1 10.0-160 9.06 35

Benzene 25.0 ND 25.9 24.3 103 97.0 1 17.0-158 6.42 27

Bromodichloromethane 25.0 ND 27.5 26.7 110 107 1 31.0-150 3.12 27

Bromochloromethane 25.0 25.5 23.0 102 92.2 1 38.0-142 10.3 26

Bromoform 25.0 ND 25.9 25.2 103 101 1 29.0-150 2.71 29

Bromomethane 25.0 ND 24.7 22.4 98.7 89.5 1 10.0-160 9.83 38

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 34 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 34 of 40

Page 148: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1197903V o l a t i l e O r g a n i c C o m p o u n d s ( G C / M S ) b y M e t h o d 8 2 6 0 B L 1 0 4 4 7 5 3 - 0 1 , 0 2 , 0 3 , 0 4 , 0 5 , 0 6 , 0 7 , 0 8

L1044762-19 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)

(OS) L1044762-19 11/16/18 22:05 • (MS) R3360974-4 11/16/18 22:27 • (MSD) R3360974-5 11/16/18 22:49

Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l ug/l % % % % %

Carbon disulfide 25.0 22.6 20.4 90.2 81.4 1 10.0-156 10.2 28

Carbon tetrachloride 25.0 ND 28.6 26.0 114 104 1 23.0-159 9.63 28

Chlorobenzene 25.0 ND 22.0 21.2 87.9 84.7 1 33.0-152 3.66 27

Chlorodibromomethane 25.0 ND 24.3 23.4 97.1 93.5 1 37.0-149 3.85 27

Chloroethane 25.0 ND 27.7 25.0 111 100 1 10.0-160 10.2 30

Chloroform 25.0 ND 28.1 25.9 112 104 1 29.0-154 8.06 28

Chloromethane 25.0 ND 31.7 28.6 127 114 1 10.0-160 10.3 29

Acrylonitrile 125 ND 150 148 120 118 1 21.0-160 1.65 32

1,2-Dibromo-3-Chloropropane 25.0 ND 22.3 22.8 89.3 91.4 1 22.0-151 2.27 34

1,2-Dibromoethane 25.0 ND 22.5 21.9 89.9 87.5 1 34.0-147 2.75 27

1,2-Dichlorobenzene 25.0 ND 22.0 22.0 87.9 88.2 1 34.0-149 0.333 28

1,4-Dichlorobenzene 25.0 ND 22.0 22.1 87.9 88.2 1 35.0-142 0.309 27

1,1-Dichloroethane 25.0 ND 28.8 26.6 115 106 1 25.0-158 7.91 27

1,2-Dichloroethane 25.0 ND 32.4 30.1 129 120 1 29.0-151 7.21 27

1,1-Dichloroethene 25.0 ND 25.2 22.9 101 91.8 1 11.0-160 9.33 29

cis-1,2-Dichloroethene 25.0 ND 24.8 23.2 99.1 92.7 1 10.0-160 6.69 27

trans-1,2-Dichloroethene 25.0 ND 26.1 24.1 104 96.5 1 17.0-153 7.88 27

1,2-Dichloropropane 25.0 ND 25.4 24.2 101 97.0 1 30.0-156 4.55 27

cis-1,3-Dichloropropene 25.0 ND 22.1 21.8 88.5 87.1 1 34.0-149 1.59 28

trans-1,3-Dichloropropene 25.0 ND 24.7 23.7 98.7 94.6 1 32.0-149 4.19 28

Ethylbenzene 25.0 ND 21.2 20.5 84.9 82.1 1 30.0-155 3.35 27

Dibromomethane 25.0 ND 27.0 25.7 108 103 1 30.0-151 5.24 27

2-Hexanone 125 127 123 102 98.7 1 21.0-160 3.09 29

trans-1,4-Dichloro-2-butene 25.0 37.3 37.4 149 150 1 10.0-157 0.134 37

2-Butanone (MEK) 125 ND 167 159 134 127 1 10.0-160 5.41 32

Methylene Chloride 25.0 ND 24.8 22.7 99.2 90.7 1 23.0-144 8.99 28

4-Methyl-2-pentanone (MIBK) 125 ND 153 148 123 118 1 29.0-160 3.73 29

Styrene 25.0 ND 24.7 24.4 98.8 97.6 1 33.0-155 1.16 28

1,1,2,2-Tetrachloroethane 25.0 ND 26.1 25.9 104 104 1 33.0-150 0.570 28

Tetrachloroethene 25.0 ND 19.3 18.1 77.1 72.4 1 10.0-160 6.22 27

Toluene 25.0 ND 21.7 21.0 86.7 84.0 1 26.0-154 3.16 28

Iodomethane 125 125 115 100 92.4 1 10.0-160 7.96 40

1,1,1-Trichloroethane 25.0 ND 30.1 27.7 120 111 1 23.0-160 8.09 28

1,1,2-Trichloroethane 25.0 ND 22.2 21.7 88.9 86.6 1 35.0-147 2.58 27

Trichloroethene 25.0 ND 23.3 22.3 93.3 89.3 1 10.0-160 4.40 25

Trichlorofluoromethane 25.0 ND 34.5 31.4 138 125 1 17.0-160 9.58 31

Vinyl chloride 25.0 ND 28.5 25.8 114 103 1 10.0-160 9.93 27

Xylenes, Total 75.0 ND 65.1 62.5 86.8 83.3 1 29.0-154 4.08 28

1,1,1,2-Tetrachloroethane 25.0 ND 23.7 22.8 94.8 91.1 1 36.0-151 4.01 29

1,2,3-Trichloropropane 25.0 ND 27.5 27.0 110 108 1 34.0-151 1.78 29

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 35 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 35 of 40

Page 149: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1197903V o l a t i l e O r g a n i c C o m p o u n d s ( G C / M S ) b y M e t h o d 8 2 6 0 B L 1 0 4 4 7 5 3 - 0 1 , 0 2 , 0 3 , 0 4 , 0 5 , 0 6 , 0 7 , 0 8

L1044762-19 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)

(OS) L1044762-19 11/16/18 22:05 • (MS) R3360974-4 11/16/18 22:27 • (MSD) R3360974-5 11/16/18 22:49

Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l ug/l % % % % %

Vinyl acetate 125 170 161 136 129 1 12.0-160 5.81 31

(S) Toluene-d8 91.8 91.6 80.0-120

(S) Dibromofluoromethane 114 107 75.0-120

(S) 4-Bromofluorobenzene 106 106 77.0-126

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 36 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 36 of 40

Page 150: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.GLOSSARY OF TERMS

Guide to Reading and Understanding Your Laboratory Report

The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative.

Abbreviations and Definitions

MDL Method Detection Limit.

ND Not detected at the Reporting Limit (or MDL where applicable).

RDL Reported Detection Limit.

Rec. Recovery.

RPD Relative Percent Difference.

SDG Sample Delivery Group.

(S)Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be detected in all environmental media.

U Not detected at the Reporting Limit (or MDL where applicable).

Analyte The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported.

Dilution

If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor.

LimitsThese are the target % recovery ranges or % difference value that the laboratory has historically determined as normal for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or duplicated within these ranges.

Original Sample The non-spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control sample. The Original Sample may not be included within the reported SDG.

QualifierThis column provides a letter and/or number designation that corresponds to additional information concerning the resultreported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable.

Result

The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state “ND” (Not Detected) or “BDL” (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte.

Case Narrative (Cn)A brief discussion about the included sample results, including a discussion of any non-conformances to protocol observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.

Quality Control Summary (Qc)

This section of the report includes the results of the laboratory quality control analyses required by procedure or analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material.

Sample Chain of Custody (Sc)

This is the document created in the field when your samples were initially collected. This is used to verify the time and date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis.

Sample Results (Sr)This section of your report will provide the results of all testing performed on your samples. These results are provided by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section foreach sample will provide the name and method number for the analysis reported.

Sample Summary (Ss) This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates andtimes of preparation and/or analysis.

Qualifier Description

E The analyte concentration exceeds the upper limit of the calibration range of the instrument established by the initial calibration (ICAL).

J The identification of the analyte is acceptable; the reported value is an estimate.

J3 The associated batch QC was outside the established quality control range for precision.

J4 The associated batch QC was outside the established quality control range for accuracy.

P1 RPD value not applicable for sample concentrations less than 5 times the reporting limit.

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 37 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 37 of 40

Page 151: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.

Pace National is the only environmental laboratory accredited/certified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as accessible or prepared to handle your needs throughout the country. Our capacity and capability from our single location laboratory is comparable to the collective totals of the network laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing turn-around time, and preventing cross contamination, thus protecting sample integrity. Our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE. * Not all certifications held by the laboratory are applicable to the results reported in the attached report. * Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace National.

State AccreditationsAlabama 40660 Nebraska NE-OS-15-05

Alaska 17-026 Nevada TN-03-2002-34

Arizona AZ0612 New Hampshire 2975

Arkansas 88-0469 New Jersey–NELAP TN002

California 2932 New Mexico ¹ n/a

Colorado TN00003 New York 11742

Connecticut PH-0197 North Carolina Env375

Florida E87487 North Carolina ¹ DW21704

Georgia NELAP North Carolina ³ 41

Georgia ¹ 923 North Dakota R-140

Idaho TN00003 Ohio–VAP CL0069

Illinois 200008 Oklahoma 9915

Indiana C-TN-01 Oregon TN200002

Iowa 364 Pennsylvania 68-02979

Kansas E-10277 Rhode Island LAO00356

Kentucky ¹ ⁶ 90010 South Carolina 84004

Kentucky ² 16 South Dakota n/a

Louisiana AI30792 Tennessee ¹ ⁴ 2006

Louisiana ¹ LA180010 Texas T 104704245-17-14

Maine TN0002 Texas ⁵ LAB0152

Maryland 324 Utah TN00003

Massachusetts M-TN003 Vermont VT2006

Michigan 9958 Virginia 460132

Minnesota 047-999-395 Washington C847

Mississippi TN00003 West Virginia 233

Missouri 340 Wisconsin 9980939910

Montana CERT0086 Wyoming A2LA

Third Party Federal AccreditationsA2LA – ISO 17025 1461.01 AIHA-LAP,LLC EMLAP 100789

A2LA – ISO 17025 ⁵ 1461.02 DOD 1461.01

Canada 1461.01 USDA P330-15-00234

EPA–Crypto TN00003

ACCREDITATIONS & LOCATIONS

¹ Drinking Water ² Underground Storage Tanks ³ Aquatic Toxicity ⁴ Chemical/Microbiological ⁵ Mold ⁶ Wastewater n/a Accreditation not applicable

Our LocationsPace National has sixty-four client support centers that provide sample pickup and/or the delivery of sampling supplies. If you would like assistance from one of our support offices, please contactour main office. Pace National performs all testing at our central laboratory.

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/23/18 15:48 38 of 40

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1044753 11/26/18 10:40 38 of 40

Page 152: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 153: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 154: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ANALYTICAL REPORTDecember 03, 2018

Legacy Landfill

Sample Delivery Group: L1047705

Samples Received: 11/13/2018

Project Number: 04469-1767-001

Description: Craighead County - Legacy Landfill

Report To: Angela Sparks

P.O. Box 16777

Jonesboro, AR 72403

Entire Report Reviewed By:

December 03, 2018

[Preliminary Report]

Mark W. BeasleyPro ject Manager

Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace Nationalis performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304.

12065 Lebanon Rd Mount Jul iet , TN 37122 615-758-5858 800-767-5859 www.pacenational .com

December 03, 2018

Mark W. BeasleyPro ject Manager

Page 155: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.TABLE OF CONTENTS

Cp: Cover Page 1

Tc: Table of Contents 2

Ss: Sample Summary 3

Cn: Case Narrative 4

Sr: Sample Results 5

MW-14R L1047705-01 5

MW-20 L1047705-02 6

Qc: Quality Control Summary 7

Metals (ICPMS) by Method 6020 7

Gl: Glossary of Terms 8

Al: Accreditations & Locations 9

Sc: Sample Chain of Custody 10

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1047705 12/03/18 13:05 2 of 13

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1047705 12/03/18 18:34 2 of 13

Page 156: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE SUMMARY

Collected by Collected date/time Received date/time

MW-14R L1047705-01 GW Michael Clayton 11/12/18 11:50 11/13/18 08:45

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Metals (ICPMS) by Method 6020 WG1204258 1 12/02/18 17:14 12/03/18 11:14 LAT

Collected by Collected date/time Received date/time

MW-20 L1047705-02 GW Michael Clayton 11/13/18 10:15 11/15/18 13:15

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Metals (ICPMS) by Method 6020 WG1204258 1 12/02/18 17:14 12/03/18 11:18 LAT

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1047705 12/03/18 13:05 3 of 13

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1047705 12/03/18 18:34 3 of 13

Page 157: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.CASE NARRATIVE

All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated withinthe report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental sampleshave been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data.

[Preliminary Report]

Mark W. BeasleyPro jec t Manager

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1047705 12/03/18 13:05 4 of 13

Mark W. BeasleyPro jec t Manager

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1047705 12/03/18 18:34 4 of 13

Page 158: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 01L 1 0 4 7 7 0 5

MW-14RC o l l e c t e d d a t e / t i m e : 1 1 / 1 2 / 1 8 1 1 : 5 0

Metals (ICPMS) by Method 6020

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Copper 1.83 J 0.520 5.00 1 12/03/2018 11:14 WG1204258

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1047705 12/03/18 13:05 5 of 13

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1047705 12/03/18 18:34 5 of 13

Page 159: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 02L 1 0 4 7 7 0 5

MW-20C o l l e c t e d d a t e / t i m e : 1 1 / 1 3 / 1 8 1 0 : 1 5

Metals (ICPMS) by Method 6020

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Barium 230 0.360 5.00 1 12/03/2018 11:18 WG1204258

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1047705 12/03/18 13:05 6 of 13

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1047705 12/03/18 18:34 6 of 13

Page 160: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1204258M e t a l s ( I C P M S ) b y M e t h o d 6 0 2 0 L 1 0 4 7 7 0 5 - 0 1 , 0 2

Method Blank (MB)

(MB) R3364683-1 12/03/18 09:55

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

Barium U 0.360 5.00

Copper U 0.520 5.00

Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)

(LCS) R3364683-2 12/03/18 10:00 • (LCSD) R3364683-3 12/03/18 10:04

Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l % % % % %

Barium 50.0 47.5 46.2 95.0 92.3 80.0-120 2.81 20

Copper 50.0 51.2 50.4 102 101 80.0-120 1.72 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1047705 12/03/18 13:05 7 of 13

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1047705 12/03/18 18:34 7 of 13

Page 161: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.GLOSSARY OF TERMS

Guide to Reading and Understanding Your Laboratory Report

The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative.

Abbreviations and Definitions

MDL Method Detection Limit.

RDL Reported Detection Limit.

Rec. Recovery.

RPD Relative Percent Difference.

SDG Sample Delivery Group.

U Not detected at the Reporting Limit (or MDL where applicable).

Analyte The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported.

Dilution

If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor.

LimitsThese are the target % recovery ranges or % difference value that the laboratory has historically determined as normal for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or duplicated within these ranges.

QualifierThis column provides a letter and/or number designation that corresponds to additional information concerning the resultreported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable.

Result

The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state “ND” (Not Detected) or “BDL” (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte.

Case Narrative (Cn)A brief discussion about the included sample results, including a discussion of any non-conformances to protocol observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.

Quality Control Summary (Qc)

This section of the report includes the results of the laboratory quality control analyses required by procedure or analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material.

Sample Chain of Custody (Sc)

This is the document created in the field when your samples were initially collected. This is used to verify the time and date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis.

Sample Results (Sr)This section of your report will provide the results of all testing performed on your samples. These results are provided by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section foreach sample will provide the name and method number for the analysis reported.

Sample Summary (Ss) This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates andtimes of preparation and/or analysis.

Qualifier Description

J The identification of the analyte is acceptable; the reported value is an estimate.

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1047705 12/03/18 13:05 8 of 13

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1047705 12/03/18 18:34 8 of 13

Page 162: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.

Pace National is the only environmental laboratory accredited/certified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as accessible or prepared to handle your needs throughout the country. Our capacity and capability from our single location laboratory is comparable to the collective totals of the network laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing turn-around time, and preventing cross contamination, thus protecting sample integrity. Our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE. * Not all certifications held by the laboratory are applicable to the results reported in the attached report. * Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace National.

State AccreditationsAlabama 40660 Nebraska NE-OS-15-05

Alaska 17-026 Nevada TN-03-2002-34

Arizona AZ0612 New Hampshire 2975

Arkansas 88-0469 New Jersey–NELAP TN002

California 2932 New Mexico ¹ n/a

Colorado TN00003 New York 11742

Connecticut PH-0197 North Carolina Env375

Florida E87487 North Carolina ¹ DW21704

Georgia NELAP North Carolina ³ 41

Georgia ¹ 923 North Dakota R-140

Idaho TN00003 Ohio–VAP CL0069

Illinois 200008 Oklahoma 9915

Indiana C-TN-01 Oregon TN200002

Iowa 364 Pennsylvania 68-02979

Kansas E-10277 Rhode Island LAO00356

Kentucky ¹ ⁶ 90010 South Carolina 84004

Kentucky ² 16 South Dakota n/a

Louisiana AI30792 Tennessee ¹ ⁴ 2006

Louisiana ¹ LA180010 Texas T 104704245-17-14

Maine TN0002 Texas ⁵ LAB0152

Maryland 324 Utah TN00003

Massachusetts M-TN003 Vermont VT2006

Michigan 9958 Virginia 460132

Minnesota 047-999-395 Washington C847

Mississippi TN00003 West Virginia 233

Missouri 340 Wisconsin 9980939910

Montana CERT0086 Wyoming A2LA

Third Party Federal AccreditationsA2LA – ISO 17025 1461.01 AIHA-LAP,LLC EMLAP 100789

A2LA – ISO 17025 ⁵ 1461.02 DOD 1461.01

Canada 1461.01 USDA P330-15-00234

EPA–Crypto TN00003

ACCREDITATIONS & LOCATIONS

¹ Drinking Water ² Underground Storage Tanks ³ Aquatic Toxicity ⁴ Chemical/Microbiological ⁵ Mold ⁶ Wastewater n/a Accreditation not applicable

Our LocationsPace National has sixty-four client support centers that provide sample pickup and/or the delivery of sampling supplies. If you would like assistance from one of our support offices, please contactour main office. Pace National performs all testing at our central laboratory.

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1047705 12/03/18 13:05 9 of 13

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1047705 12/03/18 18:34 9 of 13

Page 163: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 164: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 165: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 166: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 167: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

January 2019 Sampling Event

Page 168: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ANALYTICAL REPORTFebruary 04, 2019

Legacy Landfill

Sample Delivery Group: L1065266

Samples Received: 01/30/2019

Project Number: 04469-1767-001

Description: Craighead County - Legacy Landfill

Report To: Angela Sparks

P.O. Box 16777

Jonesboro, AR 72403

Entire Report Reviewed By:

February 04, 2019

[Preliminary Report]

Mark W. BeasleyPro ject Manager

Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace Nationalis performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304.

12065 Lebanon Rd Mount Jul iet , TN 37122 615-758-5858 800-767-5859 www.pacenational .com

February 04, 2019

Mark W. BeasleyPro ject Manager

Page 169: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.TABLE OF CONTENTS

Cp: Cover Page 1

Tc: Table of Contents 2

Ss: Sample Summary 3

Cn: Case Narrative 4

Sr: Sample Results 5

MW-22 L1065266-01 5

MW-22 DUP L1065266-02 7

EB-1 L1065266-03 9

MW-20 L1065266-04 11

TRIP BLANK L1065266-05 12

Qc: Quality Control Summary 13

Gravimetric Analysis by Method 2540 C-2011 13

Wet Chemistry by Method 9056A 14

Wet Chemistry by Method 9060A 16

Metals (ICPMS) by Method 6020 17

Volatile Organic Compounds (GC/MS) by Method 8260B 19

Gl: Glossary of Terms 22

Al: Accreditations & Locations 23

Sc: Sample Chain of Custody 24

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 14:14 2 of 24

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 15:54 2 of 24

Page 170: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE SUMMARY

Collected by Collected date/time Received date/time

MW-22 L1065266-01 GW Michael Clayton 01/29/19 12:10 01/30/19 08:45

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Gravimetric Analysis by Method 2540 C-2011 WG1230826 1 02/02/19 15:49 02/02/19 16:21 AJS

Wet Chemistry by Method 9056A WG1230678 1 01/31/19 22:54 01/31/19 22:54 ST

Wet Chemistry by Method 9060A WG1230357 1 01/31/19 18:47 01/31/19 18:47 EEM

Metals (ICPMS) by Method 6020 WG1230569 1 01/30/19 17:35 01/30/19 22:26 LD

Volatile Organic Compounds (GC/MS) by Method 8260B WG1230798 1 01/31/19 15:06 01/31/19 15:06 DWR

Collected by Collected date/time Received date/time

MW-22 DUP L1065266-02 GW Michael Clayton 01/29/19 12:15 01/30/19 08:45

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Gravimetric Analysis by Method 2540 C-2011 WG1230826 1 02/02/19 15:49 02/02/19 16:21 AJS

Wet Chemistry by Method 9056A WG1230678 1 01/31/19 23:10 01/31/19 23:10 ST

Wet Chemistry by Method 9060A WG1230357 1 01/31/19 19:33 01/31/19 19:33 EEM

Metals (ICPMS) by Method 6020 WG1230569 1 01/30/19 17:35 01/30/19 22:31 LD

Volatile Organic Compounds (GC/MS) by Method 8260B WG1230798 1 01/31/19 15:25 01/31/19 15:25 DWR

Collected by Collected date/time Received date/time

EB-1 L1065266-03 GW Michael Clayton 01/29/19 14:20 01/30/19 08:45

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Gravimetric Analysis by Method 2540 C-2011 WG1230826 1 02/02/19 15:49 02/02/19 16:21 AJS

Wet Chemistry by Method 9056A WG1230678 1 01/31/19 23:56 01/31/19 23:56 ST

Wet Chemistry by Method 9060A WG1230357 1 01/31/19 19:54 01/31/19 19:54 EEM

Metals (ICPMS) by Method 6020 WG1230569 1 01/30/19 17:35 01/30/19 22:36 LD

Volatile Organic Compounds (GC/MS) by Method 8260B WG1230798 1 01/31/19 14:46 01/31/19 14:46 DWR

Collected by Collected date/time Received date/time

MW-20 L1065266-04 GW Michael Clayton 01/29/19 14:00 01/30/19 08:45

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Gravimetric Analysis by Method 2540 C-2011 WG1230826 1 02/02/19 15:49 02/02/19 16:21 AJS

Metals (ICPMS) by Method 6020 WG1230569 1 01/30/19 17:35 01/30/19 21:15 LD

Collected by Collected date/time Received date/time

TRIP BLANK L1065266-05 GW Michael Clayton 01/29/19 00:00 01/30/19 08:45

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Volatile Organic Compounds (GC/MS) by Method 8260B WG1230798 1 01/31/19 14:07 01/31/19 14:07 DWR

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 14:14 3 of 24

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 15:54 3 of 24

Page 171: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.CASE NARRATIVE

All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated withinthe report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental sampleshave been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data.

[Preliminary Report]

Mark W. BeasleyPro jec t Manager

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 14:14 4 of 24

Mark W. BeasleyPro jec t Manager

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 15:54 4 of 24

Page 172: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 01L 1 0 6 5 2 6 6

MW-22C o l l e c t e d d a t e / t i m e : 0 1 / 2 9 / 1 9 1 2 : 1 0

Gravimetric Analysis by Method 2540 C-2011

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Dissolved Solids 231000 2820 10000 1 02/02/2019 16:21 WG1230826

Wet Chemistry by Method 9056A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Chloride 4300 51.9 1000 1 01/31/2019 22:54 WG1230678

Sulfate 7720 77.4 5000 1 01/31/2019 22:54 WG1230678

Wet Chemistry by Method 9060A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

TOC (Total Organic Carbon) 1010 B 102 1000 1 01/31/2019 18:47 WG1230357

Metals (ICPMS) by Method 6020

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Antimony U J4 0.754 2.00 1 01/30/2019 22:26 WG1230569

Arsenic 2.14 0.250 2.00 1 01/30/2019 22:26 WG1230569

Barium 57.1 0.360 5.00 1 01/30/2019 22:26 WG1230569

Beryllium U 0.120 2.00 1 01/30/2019 22:26 WG1230569

Cadmium U 0.160 1.00 1 01/30/2019 22:26 WG1230569

Chromium U 0.540 2.00 1 01/30/2019 22:26 WG1230569

Copper 0.580 B J 0.520 5.00 1 01/30/2019 22:26 WG1230569

Cobalt U 0.260 2.00 1 01/30/2019 22:26 WG1230569

Iron 453 15.0 100 1 01/30/2019 22:26 WG1230569

Lead U 0.240 2.00 1 01/30/2019 22:26 WG1230569

Manganese 217 0.250 5.00 1 01/30/2019 22:26 WG1230569

Nickel U 0.350 2.00 1 01/30/2019 22:26 WG1230569

Selenium U 0.380 2.00 1 01/30/2019 22:26 WG1230569

Silver U 0.310 2.00 1 01/30/2019 22:26 WG1230569

Thallium U 0.190 2.00 1 01/30/2019 22:26 WG1230569

Vanadium U 0.180 5.00 1 01/30/2019 22:26 WG1230569

Zinc U 2.56 25.0 1 01/30/2019 22:26 WG1230569

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Acetone U 10.0 50.0 1 01/31/2019 15:06 WG1230798

Acrylonitrile U 1.87 10.0 1 01/31/2019 15:06 WG1230798

Benzene U 0.331 1.00 1 01/31/2019 15:06 WG1230798

Bromochloromethane U 0.520 1.00 1 01/31/2019 15:06 WG1230798

Bromodichloromethane U 0.380 1.00 1 01/31/2019 15:06 WG1230798

Bromoform U 0.469 1.00 1 01/31/2019 15:06 WG1230798

Bromomethane U 0.866 5.00 1 01/31/2019 15:06 WG1230798

Carbon disulfide U 0.275 1.00 1 01/31/2019 15:06 WG1230798

Carbon tetrachloride U 0.379 1.00 1 01/31/2019 15:06 WG1230798

Chlorobenzene U 0.348 1.00 1 01/31/2019 15:06 WG1230798

Chlorodibromomethane U 0.327 1.00 1 01/31/2019 15:06 WG1230798

Chloroethane U 0.453 5.00 1 01/31/2019 15:06 WG1230798

Chloroform U 0.324 5.00 1 01/31/2019 15:06 WG1230798

Chloromethane U 0.276 2.50 1 01/31/2019 15:06 WG1230798

Dibromomethane U 0.346 1.00 1 01/31/2019 15:06 WG1230798

1,2-Dibromoethane U 0.381 1.00 1 01/31/2019 15:06 WG1230798

1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 01/31/2019 15:06 WG1230798

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 14:14 5 of 24

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 15:54 5 of 24

Page 173: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 01L 1 0 6 5 2 6 6

MW-22C o l l e c t e d d a t e / t i m e : 0 1 / 2 9 / 1 9 1 2 : 1 0

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

1,2-Dichlorobenzene U 0.349 1.00 1 01/31/2019 15:06 WG1230798

1,4-Dichlorobenzene U 0.274 1.00 1 01/31/2019 15:06 WG1230798

trans-1,4-Dichloro-2-butene U 0.866 2.50 1 01/31/2019 15:06 WG1230798

1,1-Dichloroethane U 0.259 1.00 1 01/31/2019 15:06 WG1230798

1,2-Dichloroethane U 0.361 1.00 1 01/31/2019 15:06 WG1230798

1,1-Dichloroethene U 0.398 1.00 1 01/31/2019 15:06 WG1230798

cis-1,2-Dichloroethene U 0.260 1.00 1 01/31/2019 15:06 WG1230798

trans-1,2-Dichloroethene U 0.396 1.00 1 01/31/2019 15:06 WG1230798

1,2-Dichloropropane U 0.306 1.00 1 01/31/2019 15:06 WG1230798

cis-1,3-Dichloropropene U 0.418 1.00 1 01/31/2019 15:06 WG1230798

trans-1,3-Dichloropropene U 0.419 1.00 1 01/31/2019 15:06 WG1230798

Ethylbenzene U 0.384 1.00 1 01/31/2019 15:06 WG1230798

2-Hexanone U 3.82 10.0 1 01/31/2019 15:06 WG1230798

Iodomethane U 1.71 10.0 1 01/31/2019 15:06 WG1230798

2-Butanone (MEK) U 3.93 15.0 1 01/31/2019 15:06 WG1230798

Methylene Chloride U 1.00 5.00 1 01/31/2019 15:06 WG1230798

4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 01/31/2019 15:06 WG1230798

Styrene U 0.307 1.00 1 01/31/2019 15:06 WG1230798

1,1,1,2-Tetrachloroethane U 0.385 1.00 1 01/31/2019 15:06 WG1230798

1,1,2,2-Tetrachloroethane U 0.130 1.00 1 01/31/2019 15:06 WG1230798

Tetrachloroethene U 0.372 1.00 1 01/31/2019 15:06 WG1230798

Toluene U 0.412 1.00 1 01/31/2019 15:06 WG1230798

1,1,1-Trichloroethane U 0.319 1.00 1 01/31/2019 15:06 WG1230798

1,1,2-Trichloroethane U 0.383 1.00 1 01/31/2019 15:06 WG1230798

Trichloroethene U 0.398 1.00 1 01/31/2019 15:06 WG1230798

Trichlorofluoromethane U 1.20 5.00 1 01/31/2019 15:06 WG1230798

1,2,3-Trichloropropane U 0.807 2.50 1 01/31/2019 15:06 WG1230798

Vinyl acetate U 1.63 10.0 1 01/31/2019 15:06 WG1230798

Vinyl chloride U 0.259 1.00 1 01/31/2019 15:06 WG1230798

Xylenes, Total U 1.06 3.00 1 01/31/2019 15:06 WG1230798

(S) Toluene-d8 99.3 80.0-120 01/31/2019 15:06 WG1230798

(S) 4-Bromofluorobenzene 119 77.0-126 01/31/2019 15:06 WG1230798

(S) 1,2-Dichloroethane-d4 94.8 70.0-130 01/31/2019 15:06 WG1230798

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 14:14 6 of 24

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 15:54 6 of 24

Page 174: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 02L 1 0 6 5 2 6 6

MW-22 DUPC o l l e c t e d d a t e / t i m e : 0 1 / 2 9 / 1 9 1 2 : 1 5

Gravimetric Analysis by Method 2540 C-2011

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Dissolved Solids 228000 2820 10000 1 02/02/2019 16:21 WG1230826

Wet Chemistry by Method 9056A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Chloride 4260 51.9 1000 1 01/31/2019 23:10 WG1230678

Sulfate 7650 77.4 5000 1 01/31/2019 23:10 WG1230678

Wet Chemistry by Method 9060A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

TOC (Total Organic Carbon) 747 B J 102 1000 1 01/31/2019 19:33 WG1230357

Metals (ICPMS) by Method 6020

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Antimony U J4 0.754 2.00 1 01/30/2019 22:31 WG1230569

Arsenic 1.96 J 0.250 2.00 1 01/30/2019 22:31 WG1230569

Barium 55.9 0.360 5.00 1 01/30/2019 22:31 WG1230569

Beryllium U 0.120 2.00 1 01/30/2019 22:31 WG1230569

Cadmium U 0.160 1.00 1 01/30/2019 22:31 WG1230569

Chromium U 0.540 2.00 1 01/30/2019 22:31 WG1230569

Copper U 0.520 5.00 1 01/30/2019 22:31 WG1230569

Cobalt U 0.260 2.00 1 01/30/2019 22:31 WG1230569

Iron 434 15.0 100 1 01/30/2019 22:31 WG1230569

Lead U 0.240 2.00 1 01/30/2019 22:31 WG1230569

Manganese 211 0.250 5.00 1 01/30/2019 22:31 WG1230569

Nickel U 0.350 2.00 1 01/30/2019 22:31 WG1230569

Selenium U 0.380 2.00 1 01/30/2019 22:31 WG1230569

Silver U 0.310 2.00 1 01/30/2019 22:31 WG1230569

Thallium U 0.190 2.00 1 01/30/2019 22:31 WG1230569

Vanadium U 0.180 5.00 1 01/30/2019 22:31 WG1230569

Zinc U 2.56 25.0 1 01/30/2019 22:31 WG1230569

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Acetone U 10.0 50.0 1 01/31/2019 15:25 WG1230798

Acrylonitrile U 1.87 10.0 1 01/31/2019 15:25 WG1230798

Benzene U 0.331 1.00 1 01/31/2019 15:25 WG1230798

Bromochloromethane U 0.520 1.00 1 01/31/2019 15:25 WG1230798

Bromodichloromethane U 0.380 1.00 1 01/31/2019 15:25 WG1230798

Bromoform U 0.469 1.00 1 01/31/2019 15:25 WG1230798

Bromomethane U 0.866 5.00 1 01/31/2019 15:25 WG1230798

Carbon disulfide U 0.275 1.00 1 01/31/2019 15:25 WG1230798

Carbon tetrachloride U 0.379 1.00 1 01/31/2019 15:25 WG1230798

Chlorobenzene U 0.348 1.00 1 01/31/2019 15:25 WG1230798

Chlorodibromomethane U 0.327 1.00 1 01/31/2019 15:25 WG1230798

Chloroethane U 0.453 5.00 1 01/31/2019 15:25 WG1230798

Chloroform U 0.324 5.00 1 01/31/2019 15:25 WG1230798

Chloromethane U 0.276 2.50 1 01/31/2019 15:25 WG1230798

Dibromomethane U 0.346 1.00 1 01/31/2019 15:25 WG1230798

1,2-Dibromoethane U 0.381 1.00 1 01/31/2019 15:25 WG1230798

1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 01/31/2019 15:25 WG1230798

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 14:14 7 of 24

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 15:54 7 of 24

Page 175: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 02L 1 0 6 5 2 6 6

MW-22 DUPC o l l e c t e d d a t e / t i m e : 0 1 / 2 9 / 1 9 1 2 : 1 5

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

1,2-Dichlorobenzene U 0.349 1.00 1 01/31/2019 15:25 WG1230798

1,4-Dichlorobenzene U 0.274 1.00 1 01/31/2019 15:25 WG1230798

trans-1,4-Dichloro-2-butene U 0.866 2.50 1 01/31/2019 15:25 WG1230798

1,1-Dichloroethane U 0.259 1.00 1 01/31/2019 15:25 WG1230798

1,2-Dichloroethane U 0.361 1.00 1 01/31/2019 15:25 WG1230798

1,1-Dichloroethene U 0.398 1.00 1 01/31/2019 15:25 WG1230798

cis-1,2-Dichloroethene U 0.260 1.00 1 01/31/2019 15:25 WG1230798

trans-1,2-Dichloroethene U 0.396 1.00 1 01/31/2019 15:25 WG1230798

1,2-Dichloropropane U 0.306 1.00 1 01/31/2019 15:25 WG1230798

cis-1,3-Dichloropropene U 0.418 1.00 1 01/31/2019 15:25 WG1230798

trans-1,3-Dichloropropene U 0.419 1.00 1 01/31/2019 15:25 WG1230798

Ethylbenzene U 0.384 1.00 1 01/31/2019 15:25 WG1230798

2-Hexanone U 3.82 10.0 1 01/31/2019 15:25 WG1230798

Iodomethane U 1.71 10.0 1 01/31/2019 15:25 WG1230798

2-Butanone (MEK) U 3.93 15.0 1 01/31/2019 15:25 WG1230798

Methylene Chloride U 1.00 5.00 1 01/31/2019 15:25 WG1230798

4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 01/31/2019 15:25 WG1230798

Styrene U 0.307 1.00 1 01/31/2019 15:25 WG1230798

1,1,1,2-Tetrachloroethane U 0.385 1.00 1 01/31/2019 15:25 WG1230798

1,1,2,2-Tetrachloroethane U 0.130 1.00 1 01/31/2019 15:25 WG1230798

Tetrachloroethene U 0.372 1.00 1 01/31/2019 15:25 WG1230798

Toluene U 0.412 1.00 1 01/31/2019 15:25 WG1230798

1,1,1-Trichloroethane U 0.319 1.00 1 01/31/2019 15:25 WG1230798

1,1,2-Trichloroethane U 0.383 1.00 1 01/31/2019 15:25 WG1230798

Trichloroethene U 0.398 1.00 1 01/31/2019 15:25 WG1230798

Trichlorofluoromethane U 1.20 5.00 1 01/31/2019 15:25 WG1230798

1,2,3-Trichloropropane U 0.807 2.50 1 01/31/2019 15:25 WG1230798

Vinyl acetate U 1.63 10.0 1 01/31/2019 15:25 WG1230798

Vinyl chloride U 0.259 1.00 1 01/31/2019 15:25 WG1230798

Xylenes, Total U 1.06 3.00 1 01/31/2019 15:25 WG1230798

(S) Toluene-d8 98.4 80.0-120 01/31/2019 15:25 WG1230798

(S) 4-Bromofluorobenzene 117 77.0-126 01/31/2019 15:25 WG1230798

(S) 1,2-Dichloroethane-d4 97.8 70.0-130 01/31/2019 15:25 WG1230798

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 14:14 8 of 24

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 15:54 8 of 24

Page 176: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 03L 1 0 6 5 2 6 6

EB-1C o l l e c t e d d a t e / t i m e : 0 1 / 2 9 / 1 9 1 4 : 2 0

Gravimetric Analysis by Method 2540 C-2011

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Dissolved Solids 3000 J 2820 10000 1 02/02/2019 16:21 WG1230826

Wet Chemistry by Method 9056A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Chloride U 51.9 1000 1 01/31/2019 23:56 WG1230678

Sulfate U 77.4 5000 1 01/31/2019 23:56 WG1230678

Wet Chemistry by Method 9060A

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

TOC (Total Organic Carbon) 362 B J 102 1000 1 01/31/2019 19:54 WG1230357

Metals (ICPMS) by Method 6020

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Antimony U J4 0.754 2.00 1 01/30/2019 22:36 WG1230569

Arsenic U 0.250 2.00 1 01/30/2019 22:36 WG1230569

Barium U 0.360 5.00 1 01/30/2019 22:36 WG1230569

Beryllium U 0.120 2.00 1 01/30/2019 22:36 WG1230569

Cadmium U 0.160 1.00 1 01/30/2019 22:36 WG1230569

Chromium U 0.540 2.00 1 01/30/2019 22:36 WG1230569

Copper U 0.520 5.00 1 01/30/2019 22:36 WG1230569

Cobalt U 0.260 2.00 1 01/30/2019 22:36 WG1230569

Iron U 15.0 100 1 01/30/2019 22:36 WG1230569

Lead U 0.240 2.00 1 01/30/2019 22:36 WG1230569

Manganese 0.570 J 0.250 5.00 1 01/30/2019 22:36 WG1230569

Nickel U 0.350 2.00 1 01/30/2019 22:36 WG1230569

Selenium U 0.380 2.00 1 01/30/2019 22:36 WG1230569

Silver U 0.310 2.00 1 01/30/2019 22:36 WG1230569

Thallium U 0.190 2.00 1 01/30/2019 22:36 WG1230569

Vanadium U 0.180 5.00 1 01/30/2019 22:36 WG1230569

Zinc U 2.56 25.0 1 01/30/2019 22:36 WG1230569

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Acetone U 10.0 50.0 1 01/31/2019 14:46 WG1230798

Acrylonitrile U 1.87 10.0 1 01/31/2019 14:46 WG1230798

Benzene U 0.331 1.00 1 01/31/2019 14:46 WG1230798

Bromochloromethane U 0.520 1.00 1 01/31/2019 14:46 WG1230798

Bromodichloromethane U 0.380 1.00 1 01/31/2019 14:46 WG1230798

Bromoform U 0.469 1.00 1 01/31/2019 14:46 WG1230798

Bromomethane U 0.866 5.00 1 01/31/2019 14:46 WG1230798

Carbon disulfide U 0.275 1.00 1 01/31/2019 14:46 WG1230798

Carbon tetrachloride U 0.379 1.00 1 01/31/2019 14:46 WG1230798

Chlorobenzene U 0.348 1.00 1 01/31/2019 14:46 WG1230798

Chlorodibromomethane U 0.327 1.00 1 01/31/2019 14:46 WG1230798

Chloroethane U 0.453 5.00 1 01/31/2019 14:46 WG1230798

Chloroform U 0.324 5.00 1 01/31/2019 14:46 WG1230798

Chloromethane U 0.276 2.50 1 01/31/2019 14:46 WG1230798

Dibromomethane U 0.346 1.00 1 01/31/2019 14:46 WG1230798

1,2-Dibromoethane U 0.381 1.00 1 01/31/2019 14:46 WG1230798

1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 01/31/2019 14:46 WG1230798

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 14:14 9 of 24

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 15:54 9 of 24

Page 177: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 03L 1 0 6 5 2 6 6

EB-1C o l l e c t e d d a t e / t i m e : 0 1 / 2 9 / 1 9 1 4 : 2 0

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

1,2-Dichlorobenzene U 0.349 1.00 1 01/31/2019 14:46 WG1230798

1,4-Dichlorobenzene U 0.274 1.00 1 01/31/2019 14:46 WG1230798

trans-1,4-Dichloro-2-butene U 0.866 2.50 1 01/31/2019 14:46 WG1230798

1,1-Dichloroethane U 0.259 1.00 1 01/31/2019 14:46 WG1230798

1,2-Dichloroethane U 0.361 1.00 1 01/31/2019 14:46 WG1230798

1,1-Dichloroethene U 0.398 1.00 1 01/31/2019 14:46 WG1230798

cis-1,2-Dichloroethene U 0.260 1.00 1 01/31/2019 14:46 WG1230798

trans-1,2-Dichloroethene U 0.396 1.00 1 01/31/2019 14:46 WG1230798

1,2-Dichloropropane U 0.306 1.00 1 01/31/2019 14:46 WG1230798

cis-1,3-Dichloropropene U 0.418 1.00 1 01/31/2019 14:46 WG1230798

trans-1,3-Dichloropropene U 0.419 1.00 1 01/31/2019 14:46 WG1230798

Ethylbenzene U 0.384 1.00 1 01/31/2019 14:46 WG1230798

2-Hexanone U 3.82 10.0 1 01/31/2019 14:46 WG1230798

Iodomethane U 1.71 10.0 1 01/31/2019 14:46 WG1230798

2-Butanone (MEK) U 3.93 15.0 1 01/31/2019 14:46 WG1230798

Methylene Chloride U 1.00 5.00 1 01/31/2019 14:46 WG1230798

4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 01/31/2019 14:46 WG1230798

Styrene U 0.307 1.00 1 01/31/2019 14:46 WG1230798

1,1,1,2-Tetrachloroethane U 0.385 1.00 1 01/31/2019 14:46 WG1230798

1,1,2,2-Tetrachloroethane U 0.130 1.00 1 01/31/2019 14:46 WG1230798

Tetrachloroethene U 0.372 1.00 1 01/31/2019 14:46 WG1230798

Toluene U 0.412 1.00 1 01/31/2019 14:46 WG1230798

1,1,1-Trichloroethane U 0.319 1.00 1 01/31/2019 14:46 WG1230798

1,1,2-Trichloroethane U 0.383 1.00 1 01/31/2019 14:46 WG1230798

Trichloroethene U 0.398 1.00 1 01/31/2019 14:46 WG1230798

Trichlorofluoromethane U 1.20 5.00 1 01/31/2019 14:46 WG1230798

1,2,3-Trichloropropane U 0.807 2.50 1 01/31/2019 14:46 WG1230798

Vinyl acetate U 1.63 10.0 1 01/31/2019 14:46 WG1230798

Vinyl chloride U 0.259 1.00 1 01/31/2019 14:46 WG1230798

Xylenes, Total U 1.06 3.00 1 01/31/2019 14:46 WG1230798

(S) Toluene-d8 95.7 80.0-120 01/31/2019 14:46 WG1230798

(S) 4-Bromofluorobenzene 114 77.0-126 01/31/2019 14:46 WG1230798

(S) 1,2-Dichloroethane-d4 94.0 70.0-130 01/31/2019 14:46 WG1230798

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 14:14 10 of 24

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 15:54 10 of 24

Page 178: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 04L 1 0 6 5 2 6 6

MW-20C o l l e c t e d d a t e / t i m e : 0 1 / 2 9 / 1 9 1 4 : 0 0

Gravimetric Analysis by Method 2540 C-2011

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Dissolved Solids 373000 2820 10000 1 02/02/2019 16:21 WG1230826

Metals (ICPMS) by Method 6020

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Barium 185 0.360 5.00 1 01/30/2019 21:15 WG1230569

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 14:14 11 of 24

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 15:54 11 of 24

Page 179: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.SAMPLE RESULTS - 05L 1 0 6 5 2 6 6

TRIP BLANKC o l l e c t e d d a t e / t i m e : 0 1 / 2 9 / 1 9 0 0 : 0 0

Volatile Organic Compounds (GC/MS) by Method 8260B

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Acetone U 10.0 50.0 1 01/31/2019 14:07 WG1230798

Acrylonitrile U 1.87 10.0 1 01/31/2019 14:07 WG1230798

Benzene U 0.331 1.00 1 01/31/2019 14:07 WG1230798

Bromochloromethane U 0.520 1.00 1 01/31/2019 14:07 WG1230798

Bromodichloromethane U 0.380 1.00 1 01/31/2019 14:07 WG1230798

Bromoform U 0.469 1.00 1 01/31/2019 14:07 WG1230798

Bromomethane U 0.866 5.00 1 01/31/2019 14:07 WG1230798

Carbon disulfide U 0.275 1.00 1 01/31/2019 14:07 WG1230798

Carbon tetrachloride U 0.379 1.00 1 01/31/2019 14:07 WG1230798

Chlorobenzene U 0.348 1.00 1 01/31/2019 14:07 WG1230798

Chlorodibromomethane U 0.327 1.00 1 01/31/2019 14:07 WG1230798

Chloroethane U 0.453 5.00 1 01/31/2019 14:07 WG1230798

Chloroform U 0.324 5.00 1 01/31/2019 14:07 WG1230798

Chloromethane U 0.276 2.50 1 01/31/2019 14:07 WG1230798

Dibromomethane U 0.346 1.00 1 01/31/2019 14:07 WG1230798

1,2-Dibromoethane U 0.381 1.00 1 01/31/2019 14:07 WG1230798

1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 01/31/2019 14:07 WG1230798

1,2-Dichlorobenzene U 0.349 1.00 1 01/31/2019 14:07 WG1230798

1,4-Dichlorobenzene U 0.274 1.00 1 01/31/2019 14:07 WG1230798

trans-1,4-Dichloro-2-butene U 0.866 2.50 1 01/31/2019 14:07 WG1230798

1,1-Dichloroethane U 0.259 1.00 1 01/31/2019 14:07 WG1230798

1,2-Dichloroethane U 0.361 1.00 1 01/31/2019 14:07 WG1230798

1,1-Dichloroethene U 0.398 1.00 1 01/31/2019 14:07 WG1230798

cis-1,2-Dichloroethene U 0.260 1.00 1 01/31/2019 14:07 WG1230798

trans-1,2-Dichloroethene U 0.396 1.00 1 01/31/2019 14:07 WG1230798

1,2-Dichloropropane U 0.306 1.00 1 01/31/2019 14:07 WG1230798

cis-1,3-Dichloropropene U 0.418 1.00 1 01/31/2019 14:07 WG1230798

trans-1,3-Dichloropropene U 0.419 1.00 1 01/31/2019 14:07 WG1230798

Ethylbenzene U 0.384 1.00 1 01/31/2019 14:07 WG1230798

2-Hexanone U 3.82 10.0 1 01/31/2019 14:07 WG1230798

Iodomethane U 1.71 10.0 1 01/31/2019 14:07 WG1230798

2-Butanone (MEK) U 3.93 15.0 1 01/31/2019 14:07 WG1230798

Methylene Chloride U 1.00 5.00 1 01/31/2019 14:07 WG1230798

4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 01/31/2019 14:07 WG1230798

Styrene U 0.307 1.00 1 01/31/2019 14:07 WG1230798

1,1,1,2-Tetrachloroethane U 0.385 1.00 1 01/31/2019 14:07 WG1230798

1,1,2,2-Tetrachloroethane U 0.130 1.00 1 01/31/2019 14:07 WG1230798

Tetrachloroethene U 0.372 1.00 1 01/31/2019 14:07 WG1230798

Toluene U 0.412 1.00 1 01/31/2019 14:07 WG1230798

1,1,1-Trichloroethane U 0.319 1.00 1 01/31/2019 14:07 WG1230798

1,1,2-Trichloroethane U 0.383 1.00 1 01/31/2019 14:07 WG1230798

Trichloroethene U 0.398 1.00 1 01/31/2019 14:07 WG1230798

Trichlorofluoromethane U 1.20 5.00 1 01/31/2019 14:07 WG1230798

1,2,3-Trichloropropane U 0.807 2.50 1 01/31/2019 14:07 WG1230798

Vinyl acetate U 1.63 10.0 1 01/31/2019 14:07 WG1230798

Vinyl chloride U 0.259 1.00 1 01/31/2019 14:07 WG1230798

Xylenes, Total U 1.06 3.00 1 01/31/2019 14:07 WG1230798

(S) Toluene-d8 96.5 80.0-120 01/31/2019 14:07 WG1230798

(S) 4-Bromofluorobenzene 121 77.0-126 01/31/2019 14:07 WG1230798

(S) 1,2-Dichloroethane-d4 96.8 70.0-130 01/31/2019 14:07 WG1230798

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 14:14 12 of 24

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 15:54 12 of 24

Page 180: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1230826G r a v i m e t r i c A n a l y s i s b y M e t h o d 2 5 4 0 C - 2 0 1 1 L 1 0 6 5 2 6 6 - 0 1 , 0 2 , 0 3 , 0 4

Method Blank (MB)

(MB) R3380991-1 02/02/19 16:21

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

Dissolved Solids U 2820 10000

L1065444-01 Original Sample (OS) • Duplicate (DUP)

(OS) L1065444-01 02/02/19 16:21 • (DUP) R3380991-3 02/02/19 16:21

Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits

Analyte ug/l ug/l % %

Dissolved Solids 1020000 1020000 1 0.196 5

Laboratory Control Sample (LCS)

(LCS) R3380991-2 02/02/19 16:21

Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier

Analyte ug/l ug/l % %

Dissolved Solids 8800000 8620000 98.0 85.0-115

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 14:14 13 of 24

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 15:54 13 of 24

Page 181: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1230678W e t C h e m i s t r y b y M e t h o d 9 0 5 6 A L 1 0 6 5 2 6 6 - 0 1 , 0 2 , 0 3

Method Blank (MB)

(MB) R3380469-1 01/31/19 17:46

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

Chloride U 51.9 1000

Sulfate U 77.4 5000

L1064615-04 Original Sample (OS) • Duplicate (DUP)

(OS) L1064615-04 01/31/19 18:48 • (DUP) R3380469-3 01/31/19 19:03

Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits

Analyte ug/l ug/l % %

Chloride 25700 25700 1 0.0989 15

Sulfate 29300 29300 1 0.137 15

L1065266-03 Original Sample (OS) • Duplicate (DUP)

(OS) L1065266-03 01/31/19 23:56 • (DUP) R3380469-6 02/01/19 00:11

Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits

Analyte ug/l ug/l % %

Chloride U 0.000 1 0.000 15

Sulfate U 0.000 1 0.000 15

Laboratory Control Sample (LCS)

(LCS) R3380469-2 01/31/19 18:01

Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier

Analyte ug/l ug/l % %

Chloride 40000 40300 101 80.0-120

Sulfate 40000 41000 102 80.0-120

L1064615-04 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)

(OS) L1064615-04 01/31/19 18:48 • (MS) R3380469-4 01/31/19 19:18 • (MSD) R3380469-5 01/31/19 19:34

Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l ug/l % % % % %

Chloride 50000 25700 74500 74500 97.7 97.7 1 80.0-120 0.000671 15

Sulfate 50000 29300 78100 78200 97.5 97.7 1 80.0-120 0.127 15

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 14:14 14 of 24

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 15:54 14 of 24

Page 182: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1230678W e t C h e m i s t r y b y M e t h o d 9 0 5 6 A L 1 0 6 5 2 6 6 - 0 1 , 0 2 , 0 3

L1065266-03 Original Sample (OS) • Matrix Spike (MS)

(OS) L1065266-03 01/31/19 23:56 • (MS) R3380469-7 02/01/19 00:27

Spike Amount Original Result MS Result MS Rec. Dilution Rec. Limits MS Qualifier

Analyte ug/l ug/l ug/l % %

Chloride 50000 U 51400 103 1 80.0-120

Sulfate 50000 U 51700 103 1 80.0-120

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 14:14 15 of 24

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 15:54 15 of 24

Page 183: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1230357W e t C h e m i s t r y b y M e t h o d 9 0 6 0 A L 1 0 6 5 2 6 6 - 0 1 , 0 2 , 0 3

Method Blank (MB)

(MB) R3380513-1 01/31/19 10:37

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

TOC (Total Organic Carbon) 232 J 102 1000

L1065152-02 Original Sample (OS) • Duplicate (DUP)

(OS) L1065152-02 01/31/19 13:19 • (DUP) R3380513-3 01/31/19 13:39

Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits

Analyte ug/l ug/l % %

TOC 4800 4900 1 2.08 20

Laboratory Control Sample (LCS)

(LCS) R3380513-2 01/31/19 11:59

Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier

Analyte ug/l ug/l % %

TOC 75000 77100 103 85.0-115

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 14:14 16 of 24

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 15:54 16 of 24

Page 184: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1230569M e t a l s ( I C P M S ) b y M e t h o d 6 0 2 0 L 1 0 6 5 2 6 6 - 0 1 , 0 2 , 0 3 , 0 4

Method Blank (MB)

(MB) R3380058-1 01/30/19 21:01

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

Antimony U 0.754 2.00

Arsenic U 0.250 2.00

Barium U 0.360 5.00

Beryllium U 0.120 2.00

Cadmium U 0.160 1.00

Chromium 0.744 J 0.540 2.00

Copper 1.74 J 0.520 5.00

Cobalt U 0.260 2.00

Iron U 15.0 100

Lead U 0.240 2.00

Manganese U 0.250 5.00

Nickel U 0.350 2.00

Selenium U 0.380 2.00

Silver U 0.310 2.00

Thallium U 0.190 2.00

Vanadium U 0.180 5.00

Zinc U 2.56 25.0

Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)

(LCS) R3380058-2 01/30/19 21:06 • (LCSD) R3380058-3 01/30/19 21:10

Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l % % % % %

Antimony 50.0 63.1 65.4 126 131 80.0-120 J4 J4 3.63 20

Arsenic 50.0 48.2 48.3 96.5 96.6 80.0-120 0.107 20

Barium 50.0 47.9 46.8 95.9 93.7 80.0-120 2.37 20

Beryllium 50.0 41.3 42.0 82.6 83.9 80.0-120 1.57 20

Cadmium 50.0 47.8 49.0 95.5 98.1 80.0-120 2.61 20

Chromium 50.0 50.0 49.1 99.9 98.3 80.0-120 1.69 20

Copper 50.0 48.7 50.8 97.3 102 80.0-120 4.23 20

Cobalt 50.0 49.2 49.6 98.4 99.2 80.0-120 0.734 20

Iron 5000 4780 4740 95.6 94.9 80.0-120 0.783 20

Lead 50.0 46.1 46.2 92.2 92.5 80.0-120 0.366 20

Manganese 50.0 47.6 47.7 95.3 95.4 80.0-120 0.102 20

Nickel 50.0 49.7 48.6 99.5 97.3 80.0-120 2.21 20

Selenium 50.0 52.1 54.9 104 110 80.0-120 5.19 20

Silver 50.0 47.7 48.9 95.3 97.9 80.0-120 2.64 20

Thallium 50.0 48.3 46.3 96.7 92.6 80.0-120 4.32 20

Vanadium 50.0 48.1 47.3 96.2 94.5 80.0-120 1.78 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 14:14 17 of 24

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 15:54 17 of 24

Page 185: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1230569M e t a l s ( I C P M S ) b y M e t h o d 6 0 2 0 L 1 0 6 5 2 6 6 - 0 1 , 0 2 , 0 3 , 0 4

Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)

(LCS) R3380058-2 01/30/19 21:06 • (LCSD) R3380058-3 01/30/19 21:10

Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l % % % % %

Zinc 50.0 48.8 48.1 97.5 96.2 80.0-120 1.40 20

L1065266-04 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)

(OS) L1065266-04 01/30/19 21:15 • (MS) R3380058-5 01/30/19 21:24 • (MSD) R3380058-6 01/30/19 21:29

Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l ug/l % % % % %

Antimony 50.0 U 64.4 63.5 129 127 1 75.0-125 J5 J5 1.30 20

Arsenic 50.0 0.532 46.9 46.1 92.7 91.1 1 75.0-125 1.77 20

Barium 50.0 185 224 226 78.2 80.9 1 75.0-125 0.594 20

Beryllium 50.0 U 42.0 41.7 84.0 83.3 1 75.0-125 0.770 20

Cadmium 50.0 U 47.0 46.3 94.1 92.7 1 75.0-125 1.50 20

Chromium 50.0 U 47.6 46.4 95.2 92.9 1 75.0-125 2.43 20

Copper 50.0 U 47.7 46.0 95.4 91.9 1 75.0-125 3.72 20

Cobalt 50.0 U 47.1 46.2 94.1 92.4 1 75.0-125 1.81 20

Iron 5000 2590 7170 7160 91.7 91.5 1 75.0-125 0.106 20

Lead 50.0 U 46.1 44.2 92.2 88.3 1 75.0-125 4.29 20

Manganese 50.0 571 611 620 79.7 97.5 1 75.0-125 1.45 20

Nickel 50.0 U 47.7 46.6 95.5 93.2 1 75.0-125 2.36 20

Selenium 50.0 U 54.3 57.3 109 115 1 75.0-125 5.41 20

Silver 50.0 U 48.6 47.7 97.1 95.5 1 75.0-125 1.67 20

Thallium 50.0 U 45.6 45.6 91.3 91.3 1 75.0-125 0.0503 20

Vanadium 50.0 U 47.0 46.0 93.9 92.0 1 75.0-125 2.09 20

Zinc 50.0 U 45.5 47.1 91.1 94.3 1 75.0-125 3.44 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 14:14 18 of 24

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 15:54 18 of 24

Page 186: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1230798V o l a t i l e O r g a n i c C o m p o u n d s ( G C / M S ) b y M e t h o d 8 2 6 0 B L 1 0 6 5 2 6 6 - 0 1 , 0 2 , 0 3 , 0 5

Method Blank (MB)

(MB) R3380863-3 01/31/19 10:28

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

Acetone U 10.0 50.0

Acrylonitrile U 1.87 10.0

Benzene U 0.331 1.00

Bromodichloromethane U 0.380 1.00

Bromochloromethane U 0.520 1.00

Bromoform U 0.469 1.00

Bromomethane U 0.866 5.00

Carbon disulfide U 0.275 1.00

Carbon tetrachloride U 0.379 1.00

Chlorobenzene U 0.348 1.00

Chlorodibromomethane U 0.327 1.00

Chloroethane U 0.453 5.00

Chloroform U 0.324 5.00

Chloromethane U 0.276 2.50

1,2-Dibromo-3-Chloropropane U 1.33 5.00

1,2-Dibromoethane U 0.381 1.00

Dibromomethane U 0.346 1.00

1,2-Dichlorobenzene U 0.349 1.00

1,4-Dichlorobenzene U 0.274 1.00

trans-1,4-Dichloro-2-butene U 0.866 2.50

1,2-Dichloroethane U 0.361 1.00

1,1-Dichloroethane U 0.259 1.00

1,1-Dichloroethene U 0.398 1.00

cis-1,2-Dichloroethene U 0.260 1.00

trans-1,2-Dichloroethene U 0.396 1.00

1,2-Dichloropropane U 0.306 1.00

cis-1,3-Dichloropropene U 0.418 1.00

trans-1,3-Dichloropropene U 0.419 1.00

Ethylbenzene U 0.384 1.00

2-Hexanone U 3.82 10.0

Iodomethane U 1.71 10.0

2-Butanone (MEK) U 3.93 15.0

Methylene Chloride U 1.00 5.00

4-Methyl-2-pentanone (MIBK) U 2.14 10.0

Styrene U 0.307 1.00

1,1,1,2-Tetrachloroethane U 0.385 1.00

1,1,2,2-Tetrachloroethane U 0.130 1.00

Tetrachloroethene U 0.372 1.00

Toluene U 0.412 1.00

1,1,1-Trichloroethane U 0.319 1.00

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 14:14 19 of 24

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 15:54 19 of 24

Page 187: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1230798V o l a t i l e O r g a n i c C o m p o u n d s ( G C / M S ) b y M e t h o d 8 2 6 0 B L 1 0 6 5 2 6 6 - 0 1 , 0 2 , 0 3 , 0 5

Method Blank (MB)

(MB) R3380863-3 01/31/19 10:28

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

1,1,2-Trichloroethane U 0.383 1.00

Trichloroethene U 0.398 1.00

Trichlorofluoromethane U 1.20 5.00

1,2,3-Trichloropropane U 0.807 2.50

Vinyl acetate U 1.63 10.0

Xylenes, Total U 1.06 3.00

Vinyl chloride U 0.259 1.00

(S) Toluene-d8 100 80.0-120

(S) 4-Bromofluorobenzene 115 77.0-126

(S) 1,2-Dichloroethane-d4 94.6 70.0-130

Laboratory Control Sample (LCS)

(LCS) R3380863-1 01/31/19 09:28

Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier

Analyte ug/l ug/l % %

Benzene 25.0 25.0 100 70.0-123

Acetone 125 117 93.8 19.0-160

Acrylonitrile 125 128 103 55.0-149

Bromodichloromethane 25.0 21.7 86.9 75.0-120

Bromochloromethane 25.0 22.5 89.9 76.0-122

Bromoform 25.0 24.2 96.7 68.0-132

Bromomethane 25.0 22.6 90.2 10.0-160

Carbon disulfide 25.0 20.6 82.4 61.0-128

Carbon tetrachloride 25.0 22.2 89.0 68.0-126

Chlorobenzene 25.0 22.9 91.4 80.0-121

Chlorodibromomethane 25.0 23.6 94.5 77.0-125

Chloroethane 25.0 22.6 90.2 47.0-150

Chloroform 25.0 24.9 99.7 73.0-120

Chloromethane 25.0 22.4 89.6 41.0-142

1,2-Dichloroethane 25.0 22.9 91.5 70.0-128

1,2-Dibromo-3-Chloropropane 25.0 24.6 98.4 58.0-134

1,2-Dibromoethane 25.0 25.0 99.9 80.0-122

Dibromomethane 25.0 22.4 89.7 80.0-120

1,2-Dichlorobenzene 25.0 23.0 91.9 79.0-121

1,4-Dichlorobenzene 25.0 22.2 88.6 79.0-120

trans-1,4-Dichloro-2-butene 25.0 25.4 102 33.0-144

1,1-Dichloroethane 25.0 25.0 100 70.0-126

Ethylbenzene 25.0 24.0 95.9 79.0-123

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 14:14 20 of 24

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 15:54 20 of 24

Page 188: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1230798V o l a t i l e O r g a n i c C o m p o u n d s ( G C / M S ) b y M e t h o d 8 2 6 0 B L 1 0 6 5 2 6 6 - 0 1 , 0 2 , 0 3 , 0 5

Laboratory Control Sample (LCS)

(LCS) R3380863-1 01/31/19 09:28

Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier

Analyte ug/l ug/l % %

1,1-Dichloroethene 25.0 21.2 84.6 71.0-124

cis-1,2-Dichloroethene 25.0 23.1 92.2 73.0-120

trans-1,2-Dichloroethene 25.0 20.9 83.7 73.0-120

1,2-Dichloropropane 25.0 23.6 94.3 77.0-125

cis-1,3-Dichloropropene 25.0 23.8 95.3 80.0-123

trans-1,3-Dichloropropene 25.0 24.7 98.7 78.0-124

2-Hexanone 125 127 102 67.0-149

Iodomethane 125 105 84.1 33.0-147

2-Butanone (MEK) 125 134 107 44.0-160

Toluene 25.0 23.2 93.0 79.0-120

Methylene Chloride 25.0 21.2 84.7 67.0-120

4-Methyl-2-pentanone (MIBK) 125 125 100 68.0-142

Styrene 25.0 25.5 102 73.0-130

1,1,1,2-Tetrachloroethane 25.0 22.8 91.3 75.0-125

1,1,2,2-Tetrachloroethane 25.0 26.2 105 65.0-130

Tetrachloroethene 25.0 24.4 97.7 72.0-132

Xylenes, Total 75.0 71.4 95.2 79.0-123

1,1,1-Trichloroethane 25.0 23.6 94.3 73.0-124

1,1,2-Trichloroethane 25.0 24.4 97.5 80.0-120

Trichloroethene 25.0 23.8 95.2 78.0-124

Trichlorofluoromethane 25.0 24.2 96.9 59.0-147

1,2,3-Trichloropropane 25.0 23.1 92.5 73.0-130

Vinyl acetate 125 160 128 11.0-160

Vinyl chloride 25.0 25.1 100 67.0-131

(S) Toluene-d8 96.1 80.0-120

(S) 4-Bromofluorobenzene 110 77.0-126

(S) 1,2-Dichloroethane-d4 105 70.0-130

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 14:14 21 of 24

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 15:54 21 of 24

Page 189: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.GLOSSARY OF TERMS

Guide to Reading and Understanding Your Laboratory Report

The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative.

Abbreviations and Definitions

MDL Method Detection Limit.

RDL Reported Detection Limit.

Rec. Recovery.

RPD Relative Percent Difference.

SDG Sample Delivery Group.

(S)Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be detected in all environmental media.

U Not detected at the Reporting Limit (or MDL where applicable).

Analyte The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported.

Dilution

If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor.

LimitsThese are the target % recovery ranges or % difference value that the laboratory has historically determined as normal for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or duplicated within these ranges.

Original Sample The non-spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control sample. The Original Sample may not be included within the reported SDG.

QualifierThis column provides a letter and/or number designation that corresponds to additional information concerning the resultreported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable.

Result

The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state “ND” (Not Detected) or “BDL” (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte.

Uncertainty (Radiochemistry) Confidence level of 2 sigma.

Case Narrative (Cn)A brief discussion about the included sample results, including a discussion of any non-conformances to protocol observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.

Quality Control Summary (Qc)

This section of the report includes the results of the laboratory quality control analyses required by procedure or analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material.

Sample Chain of Custody (Sc)

This is the document created in the field when your samples were initially collected. This is used to verify the time and date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis.

Sample Results (Sr)This section of your report will provide the results of all testing performed on your samples. These results are provided by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section foreach sample will provide the name and method number for the analysis reported.

Sample Summary (Ss) This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates andtimes of preparation and/or analysis.

Qualifier Description

B The same analyte is found in the associated blank.

J The identification of the analyte is acceptable; the reported value is an estimate.

J4 The associated batch QC was outside the established quality control range for accuracy.

J5 The sample matrix interfered with the ability to make any accurate determination; spike value is high.

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 14:14 22 of 24

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 15:54 22 of 24

Page 190: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

ONE LAB. NATIONWIDE.

Pace National is the only environmental laboratory accredited/certified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as accessible or prepared to handle your needs throughout the country. Our capacity and capability from our single location laboratory is comparable to the collective totals of the network laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing turn-around time, and preventing cross contamination, thus protecting sample integrity. Our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE. * Not all certifications held by the laboratory are applicable to the results reported in the attached report. * Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace National.

State AccreditationsAlabama 40660 Nebraska NE-OS-15-05

Alaska 17-026 Nevada TN-03-2002-34

Arizona AZ0612 New Hampshire 2975

Arkansas 88-0469 New Jersey–NELAP TN002

California 2932 New Mexico ¹ n/a

Colorado TN00003 New York 11742

Connecticut PH-0197 North Carolina Env375

Florida E87487 North Carolina ¹ DW21704

Georgia NELAP North Carolina ³ 41

Georgia ¹ 923 North Dakota R-140

Idaho TN00003 Ohio–VAP CL0069

Illinois 200008 Oklahoma 9915

Indiana C-TN-01 Oregon TN200002

Iowa 364 Pennsylvania 68-02979

Kansas E-10277 Rhode Island LAO00356

Kentucky ¹ ⁶ 90010 South Carolina 84004

Kentucky ² 16 South Dakota n/a

Louisiana AI30792 Tennessee ¹ ⁴ 2006

Louisiana ¹ LA180010 Texas T 104704245-17-14

Maine TN0002 Texas ⁵ LAB0152

Maryland 324 Utah TN00003

Massachusetts M-TN003 Vermont VT2006

Michigan 9958 Virginia 460132

Minnesota 047-999-395 Washington C847

Mississippi TN00003 West Virginia 233

Missouri 340 Wisconsin 9980939910

Montana CERT0086 Wyoming A2LA

Third Party Federal AccreditationsA2LA – ISO 17025 1461.01 AIHA-LAP,LLC EMLAP 100789

A2LA – ISO 17025 ⁵ 1461.02 DOD 1461.01

Canada 1461.01 USDA P330-15-00234

EPA–Crypto TN00003

ACCREDITATIONS & LOCATIONS

¹ Drinking Water ² Underground Storage Tanks ³ Aquatic Toxicity ⁴ Chemical/Microbiological ⁵ Mold ⁶ Wastewater n/a Accreditation not applicable

Our LocationsPace National has sixty-four client support centers that provide sample pickup and/or the delivery of sampling supplies. If you would like assistance from one of our support offices, please contactour main office. Pace National performs all testing at our central laboratory.

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 14:14 23 of 24

ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

Legacy Landfill 04469-1767-001 L1065266 02/04/19 15:54 23 of 24

Page 191: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,
Page 192: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

APPENDIX C Historical Database

Page 193: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

Am

mo

nia

as

N

(mg/

L)

An

tim

on

y (m

g/L)

Ars

enic

(m

g/L)

Bar

ium

(m

g/L)

Ber

ylliu

m (

mg/

L)

Cad

miu

m (

mg/

L)

Cal

ciu

m (

mg/

L)

Ch

lori

de

(mg/

L)

Ch

rom

ium

(m

g/L)

Co

bal

t (m

g/L)

CO

D (

mg/

L)

MW-8 downgradient

3/16/1995 0.06 <0.006 <0.005 <1 <0.004 <0.005 25.9 17 <0.005 <0.1 <3.7

5/23/1995 0.16 <0.006 <0.005 <1 <0.004 <0.005 100 18.5 <0.05 <0.03 8

6/29/1995 0.2 <0.006 <0.005 <1 <0.004 <0.005 110 18 <0.05 <0.03 31

7/25/1995 0.23 <0.006 <0.005 <1 <0.004 <0.005 95 13 <0.05 <0.03 <3.7

2/8/1996 <0.05 <0.014 <0.008 <1 <0.004 <0.005 94 19 <0.05 <0.03 <3.7

8/6/1996 0.091 <0.006 <0.01 <1 <0.004 <0.005 89.8 14 <0.05 <0.02 <3.7

2/26/1997 <0.07 <0.006 <0.01 <1 <0.004 <0.005 103 15 <0.05 <0.02 <3.7

9/10/1997 0.18 <0.006 <0.01 <1 <0.004 <0.005 93 34 <0.05 <0.02 7

4/9/1998 0.08 <0.006 <0.01 0.2 <0.002 <0.003 94.6 12.7 <0.01 <0.02 <3.7

9/23/1998 <0.06 <0.006 <0.005 <0.1 <0.002 <0.003 98 13.5 <0.01 <0.02 11

3/16/1999 <0.06 <0.006 <0.005 <0.1 <0.002 <0.003 96.2 16 <0.01 <0.02 <3.7

9/29/1999 0.12 <0.006 <0.005 0.18 <0.002 <0.003 86.2 7.5 <0.01 <0.02 <3.7

3/14/2000 <0.06 <0.006 <0.005 0.122 <0.002 <0.003 94.1 14 <0.01 <0.01 <3.7

9/20/2000 <0.06 <0.006 <0.005 0.162 <0.002 <0.003 96.2 11.5 <0.01 <0.02 <3.7

3/21/2001 <0.06 <0.006 <0.005 0.166 <0.002 <0.003 80.2 17 <0.01 <0.02 <3.7

9/26/2001 <0.05 <0.006 <0.005 0.094 <0.002 <0.003 78.1 12 <0.01 <0.02 <3.7

3/27/2002 0.06 <0.006 <0.005 0.201 <0.002 <0.003 78.2 11.5 <0.01 <0.02 <3.7

9/25/2002 0.06 <0.006 <0.005 0.214 <0.002 <0.003 72.1 9.5 <0.01 <0.02 <3.7

4/1/2003 <0.05 <0.006 <0.005 0.16 <0.002 <0.003 80 11.5 <0.01 <0.02 <3.7

9/17/2003 <0.06 <0.006 <0.005 0.08 <0.002 <0.003 88 13 <0.01 <0.02 <3.7

3/24/2004 0.05 <0.006 <0.005 0.123 <0.002 <0.003 57.2 12.7 <0.01 <0.02 <3.7

9/14/2004 n/a <0.006 <0.005 0.139 <0.004 <0.003 n/a 13.5 <0.01 <0.02 n/a

3/9/2005 n/a <0.006 <0.005 0.02 <0.002 <0.003 n/a 13.2 <0.005 <0.02 n/a

9/28/2005 n/a 0.0973(R) <0.00018 <0.0003 0.00134 <0.02 14.5 0.348 <0.002 <0.001 0.643

3/15/2006 n/a <0.002 0.00215 0.0356 <0.00018 <0.0003 n/a 27 0.00115 <0.02 n/a

9/20/2006 n/a <0.002 <0.005 0.0381 <5E-05 <0.0003 n/a 14 <0.0015 <0.1 n/a

3/6/2007 n/a <0.002 <0.0015 0.0335 <5E-05 <0.0003 n/a 12.5 0.000899 <0.02 n/a

9/19/2007 n/a <0.00092 <0.00074 0.138 <0.00032 <0.000595 n/a 26 0.00175 <0.0005 n/a

4/1/2008 n/a <0.0025 <0.0037 0.146 <0.0016 <0.003 n/a 24.9 0.0008 <0.0025 n/a

9/18/2008 n/a <0.0004 0.00212 0.158 <0.0002 <0.0002 n/a <15 0.00104 <0.001 n/a

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 1 of 105

Page 194: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

Am

mo

nia

as

N

(mg/

L)

An

tim

on

y (m

g/L)

Ars

enic

(m

g/L)

Bar

ium

(m

g/L)

Ber

ylliu

m (

mg/

L)

Cad

miu

m (

mg/

L)

Cal

ciu

m (

mg/

L)

Ch

lori

de

(mg/

L)

Ch

rom

ium

(m

g/L)

Co

bal

t (m

g/L)

CO

D (

mg/

L)

MW-8 3/17/2009 n/a <0.0004 0.0012 0.141 <0.0002 <0.0002 n/a 10.3 0.00036 <0.001 n/a

(cont.) 10/7/2009 n/a <0.0004 0.00214 0.146 <0.0002 6.00E-05 n/a 10.5 0.00204 0.00044 n/a

3/16/2010 n/a <0.0003 0.0021 0.149 <0.0003 <0.0002 n/a 8.18 0.003 <0.001 n/a

9/28/2010 n/a <0.0003 0.004 0.164 <0.0003 <0.0002 n/a 9.13 0.009 <0.001 n/a

9/26/2012 n/a <0.001 0.0018 0.16 <0.001 <0.0005 n/a 11 0.0043 <0.01 n/a

3/5/2014 n/a <0.001 0.0021 0.14 <0.001 0.00041(J) n/a 9.5 0.0054 0.00075(J) n/a

10/16/2015 n/a <0.002 0.00247 0.129 <0.002 <0.001 n/a 8.1 0.0065 0.00039(J) n/a

6/15/2017 n/a <0.002 0.00183(J) 0.13 <0.002 <0.001 n/a 7.94 0.00182(J) 0.000327(J) n/a

MW-9R downgradient

9/28/2010 n/a <0.0003 0.0012 0.189 <0.0003 <0.0002 n/a 6.65 0.0011 <0.001 n/a

12/30/2010 n/a <0.001 0.00115 0.143 <0.0005 <0.0005 n/a 7 0.0016 <0.0025 n/a

3/9/2011 n/a <0.001 <0.001 0.18 <0.001 <0.0005 n/a 7.3 <0.01 <0.01 n/a

6/3/2011 n/a <0.001 <0.001 0.2 <0.001 <0.0005 n/a 7.3 <0.01 <0.01 n/a

9/13/2011 n/a <0.001 0.002 0.14 <0.001 <0.0005 n/a 12 <0.01 <0.01 n/a

3/13/2012 n/a <0.001 0.0007 0.19 <0.001 <0.0005 n/a 7.2 0.026 <0.01 n/a

9/26/2012 n/a <0.001 0.0017 0.16 <0.001 <0.0005 n/a 7.6 0.0071 <0.01 n/a

3/6/2013 n/a 0.00073(J) 0.0031 0.2 0.00036(J) <0.0005 n/a 0.24(BJO) 0.092(R) 0.0031(J) n/a

9/12/2013 n/a 0.00031(J) 0.0036 0.19 0.0005(J) 0.00018(J) n/a 8 0.013 0.0025 n/a

3/5/2014 n/a <0.001 0.0013 0.11 0.00019(J) 0.00033(J) n/a 7.4 0.0057 0.0014 n/a

10/9/2014 n/a <0.001 0.00056(J) 0.17 <0.001 <0.0005 n/a 7.4 0.0029 0.00042(J) n/a

4/22/2015 n/a <0.002 <0.002(J) 0.17 <0.002 <0.001 n/a 7.2 0.014 <0.002(J) n/a

11/12/2015 n/a 0.000285(J) 0.00148(J) 0.132 <0.002 <0.001 n/a 7.3 0.0228 0.000486(J) n/a

11/29/2017 n/a <0.002 0.00215 0.115 <0.002 <0.001 n/a 5.92 <0.002 0.00098(J) n/a

MW-9R2 downgradient

5/25/2018 n/a <0.002 0.00242 0.124 <0.002 <0.001 n/a 6.14 0.000594(J) <0.002 n/a

11/13/2018 n/a <0.002 0.00114(J) 0.14 <0.002 <0.001 n/a 7.02 <0.002 <0.002 n/a

MW-14R upgradient

9/14/2004 n/a <0.006 <0.005 0.225 <0.004 <0.003 n/a 24.2 <0.01 <0.02 n/a

3/9/2005 n/a <0.006 <0.005 0.021 <0.002 <0.003 n/a 29.2 <0.005 <0.02 n/a

9/28/2005 n/a <0.002 0.0018 0.134 <0.00018 <0.0003 n/a 33.2 0.000801 <0.02 n/a

3/15/2006 n/a <0.002 0.00189 0.0501 <0.00018 <0.0003 n/a 33 0.000824 0.0618 n/a

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 2 of 105

Page 195: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

Am

mo

nia

as

N

(mg/

L)

An

tim

on

y (m

g/L)

Ars

enic

(m

g/L)

Bar

ium

(m

g/L)

Ber

ylliu

m (

mg/

L)

Cad

miu

m (

mg/

L)

Cal

ciu

m (

mg/

L)

Ch

lori

de

(mg/

L)

Ch

rom

ium

(m

g/L)

Co

bal

t (m

g/L)

CO

D (

mg/

L)

MW-14R 9/20/2006 n/a <0.002 <0.005 0.0493 <5E-05 <0.0003 n/a 25.5 <0.0015 <0.1 n/a

(cont.) 3/6/2007 n/a <0.002 <0.0015 0.0506 <5E-05 <0.0003 n/a 20 0.00087 <0.02 n/a

9/19/2007 n/a <0.00092 <0.00074 0.22 <0.00032 <0.000595 n/a 18.5 0.0017 <0.0005 n/a

4/1/2008 n/a <0.0025 <0.0037 0.238 <0.0016 <0.003 n/a 26.9 0.0132 <0.0025 n/a

9/18/2008 n/a <0.0004 0.00194 0.246 <0.0002 <0.0002 n/a 21.1 0.00106 0.00136 n/a

3/17/2009 n/a <0.0004 0.00216 0.247 <0.0002 <0.0002 n/a 26.2 0.013 0.0027 n/a

10/7/2009 n/a <0.0004 0.00194 0.24 <0.0002 <0.0002 n/a 27.8 0.00054 0.00106 n/a

3/16/2010 n/a <0.0003 0.0022 0.28 <0.0003 <0.0002 n/a 33.3 <0.0005 <0.001 n/a

9/28/2010 n/a <0.0003 0.0018 0.285 <0.0003 <0.0002 n/a 41.1 <0.0005 <0.001 n/a

3/9/2011 n/a <0.001 0.0011 0.28 <0.001 <0.0005 n/a 47 <0.01 <0.01 n/a

9/13/2011 n/a <0.001 0.0023 0.28 <0.001 <0.0005 n/a 56 <0.01 <0.01 n/a

3/13/2012 n/a <0.001 0.0016 0.3 <0.001 <0.0005 n/a 52 <0.01 <0.01 n/a

9/26/2012 n/a <0.001 0.0015 0.29 <0.001 <0.0005 n/a 56 <0.01 <0.01 n/a

3/5/2013 n/a <0.001 0.0027 0.29 0.00023(J) <0.0005 n/a 47(B) 0.018 <0.01 n/a

9/10/2013 n/a 0.00032(J) 0.0028 0.27 <0.001 0.00017(J) n/a 37 0.0013(J) 0.0015 n/a

3/4/2014 n/a <0.001 0.0027 0.29 <0.001 0.00037(J) n/a 52 0.0014(J) 0.0013 n/a

10/6/2014 n/a <0.001 0.0029 0.32 <0.001 <0.0005 n/a 55 0.029 0.0018 n/a

4/14/2015 n/a <0.002(JB) <0.002(J) 0.31 <0.002 <0.001 n/a 50(B) <0.002(J) <0.002(J) n/a

10/14/2015 n/a 0.000262(J) 0.00299 0.322 <0.002 <0.001 n/a 45.3 0.0016(J) 0.00134(J) n/a

4/12/2016 n/a 0.000347(J) 0.00259 0.289 <0.002 <0.001 n/a 51.8 0.00477 0.00124(J) n/a

8/2/2016 n/a n/a n/a 0.304 n/a n/a n/a 52.5 n/a n/a n/a

12/20/2016 n/a 0.000921(J) 0.00161(J) 0.282 <0.002 <0.001 n/a 54.5 0.00142(J) 0.00114(J) n/a

6/13/2017 n/a <0.002 0.00175(J) 0.294 <0.002 <0.001 n/a 56.1 <0.002 0.00101(J) n/a

11/29/2017 n/a <0.002 0.00178(J) 0.275 <0.002 <0.001 n/a 61.2 <0.002 0.000852(J) n/a

5/23/2018 n/a <0.002 0.00215 0.275 <0.002 <0.001 n/a 49.9 <0.002 0.001(J) n/a

11/12/2018 n/a <0.002 0.00117(J) 0.254 <0.002 <0.001 n/a 44.7 <0.002 0.000644(J) n/a

MW-16R downgradient

9/28/2010 n/a <0.0003 0.0015 0.2 <0.0003 <0.0002 n/a 12.9 <0.0005 <0.001 n/a

12/30/2010 n/a <0.001 0.0009 0.19 <0.0005 <0.0005 n/a 8.18 0.0006 <0.0025 n/a

3/9/2011 n/a <0.001 <0.001 0.14 <0.0005 <0.0005 n/a 8.6 <0.01 <0.01 n/a

6/3/2011 n/a <0.001 <0.001 0.14 <0.0005 <0.0005 n/a 8.9 <0.01 <0.01 n/a

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 3 of 105

Page 196: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

Am

mo

nia

as

N

(mg/

L)

An

tim

on

y (m

g/L)

Ars

enic

(m

g/L)

Bar

ium

(m

g/L)

Ber

ylliu

m (

mg/

L)

Cad

miu

m (

mg/

L)

Cal

ciu

m (

mg/

L)

Ch

lori

de

(mg/

L)

Ch

rom

ium

(m

g/L)

Co

bal

t (m

g/L)

CO

D (

mg/

L)

MW-16R 9/13/2011 n/a <0.001 0.0018 0.12 <0.0005 <0.0005 n/a 8.4 <0.01 <0.01 n/a

(cont.) 3/13/2012 n/a <0.001 0.00067 0.16 <0.0005 <0.0005 n/a 9.6 0.0098 <0.01 n/a

9/26/2012 n/a <0.001 0.0018 0.12 <0.001 <0.0005 n/a 7.9 0.0049 <0.01 n/a

3/5/2013 n/a 0.00026(J) 0.0047 0.24 0.0012(R) <0.0005 n/a 8(B) 0.16(R) 0.0086(JR) n/a

9/11/2013 n/a 0.00036(J) 0.0059 0.19 0.00022(J) <0.0005 n/a 9.9 0.052 0.0032 n/a

3/4/2014 n/a <0.001 0.0017 0.11 <0.001 0.00037(J) n/a 7.4 0.0031 0.00091(J) n/a

10/23/2014 n/a 0.00059(J) 0.00064(J) 0.11 <0.002 <0.001 n/a 7.8 0.0037 <0.002 n/a

4/21/2015 n/a <0.002 <0.002(J) 0.12 <0.002 <0.001 n/a 8.21 <0.002(J) <0.002 n/a

10/16/2015 n/a 0.00029(J) 0.00159(J) 0.12 <0.002 <0.001 n/a 8.17 0.0133 <0.002 n/a

4/14/2016 n/a 0.000336(J) 0.00163(J) 0.109 <0.002 <0.001 n/a 7.53 0.00322 <0.002 n/a

12/20/2016 n/a <0.002 0.001(J) 0.102 <0.002 <0.001 n/a 8.07 0.00155(J) <0.002 n/a

6/15/2017 n/a <0.002 0.00101(J) 0.121 <0.002 <0.001 n/a 7.77 0.00638 <0.002 n/a

12/1/2017 n/a <0.002 0.00207 0.119 <0.002 <0.001 n/a 8.4 0.000575(BJ) <0.002 n/a

3/8/2018 n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

5/24/2018 n/a <0.002 0.00197(J) 0.113 <0.002 <0.001 n/a 8.78 <0.002 <0.002 n/a

11/12/2018 n/a <0.002 0.00094(J) 0.0908 <0.002 <0.001 n/a 6.88 <0.002 <0.002 n/a

MW-17R upgradient

9/14/2004 n/a <0.006 <0.005 0.113 <0.004 <0.003 n/a 15.7 <0.01 <0.02 n/a

3/9/2005 n/a <0.006 <0.005 <0.01 <0.002 <0.003 n/a 15.5 <0.005 <0.02 n/a

9/28/2005 n/a <0.002 <0.0015 0.0724 <0.00018 <0.0003 n/a 26 0.00179 <0.02 n/a

3/15/2006 n/a <0.002 <0.0015 0.0266 <0.00018 <0.0003 n/a 32 0.000743 <0.02 n/a

9/20/2006 n/a <0.002 <0.005 0.0274 <5E-05 <0.0003 n/a 12.5 <0.0015 <0.1 n/a

3/6/2007 n/a <0.002 <0.0015 0.036 <5E-05 <0.0003 n/a 12 0.000914 <0.02 n/a

9/19/2007 n/a <0.00092 <0.00074 0.0852 <0.00032 <0.000595 n/a 14 0.00085 <0.0005 n/a

4/1/2008 n/a <0.0025 <0.0037 0.0968 <0.0016 <0.003 n/a 12.9 0.0152(R) <0.0025 n/a

9/18/2008 n/a <0.0004 0.00086 0.0959 <0.0002 <0.0002 n/a <15 0.00132 <0.001 n/a

3/17/2009 n/a <0.0004 0.00192 0.0854 <0.0002 <0.0002 n/a 6.3 0.0114(R) <0.001 n/a

10/7/2009 n/a 0.00014 0.0008 0.0855 <0.0002 <0.0002 n/a 8.74 0.00076 <0.001 n/a

3/16/2010 n/a <0.0003 0.0009 0.0945 <0.0003 <0.0002 n/a 6.58 0.0013 <0.001 n/a

9/28/2010 n/a <0.0003 <0.0002 0.0965 <0.0003 <0.0002 n/a 7.2 0.0012 <0.001 n/a

3/9/2011 n/a <0.001 <0.001 0.088 <0.001 <0.0005 n/a 8.5 <0.01 <0.01 n/a

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 4 of 105

Page 197: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

Am

mo

nia

as

N

(mg/

L)

An

tim

on

y (m

g/L)

Ars

enic

(m

g/L)

Bar

ium

(m

g/L)

Ber

ylliu

m (

mg/

L)

Cad

miu

m (

mg/

L)

Cal

ciu

m (

mg/

L)

Ch

lori

de

(mg/

L)

Ch

rom

ium

(m

g/L)

Co

bal

t (m

g/L)

CO

D (

mg/

L)

MW-17R 9/13/2011 n/a <0.001 <0.001 0.09 <0.001 <0.0005 n/a 14 <0.01 <0.01 n/a

(cont.) 3/13/2012 n/a <0.001 0.00038 0.11 <0.001 <0.0005 n/a 10 0.021(R) <0.01 n/a

9/26/2012 n/a <0.001 <0.001 0.11 0.00013 <0.0005 n/a 11 <0.01 <0.01 n/a

3/5/2013 n/a <0.001 0.00073(J) 0.1 0.0002(J) <0.0005 n/a 8.1(B) 0.012 <0.01 n/a

9/11/2013 n/a 0.00043(J) 0.0016 0.1 <0.001 0.00016(J) n/a 8.2 0.44(R) 0.0041 n/a

3/5/2014 n/a <0.001 0.0011 0.1 <0.001 0.00032(J) n/a 8.2 0.0014(J) 0.00034(J) n/a

10/9/2014 n/a 0.00027(J) 0.00046(J) 0.11 <0.001 <0.0005 n/a 8.2 0.0091 0.00028(J) n/a

4/21/2015 n/a <0.002(J) <0.002(J) 0.1 <0.002 <0.001 n/a 8.44 0.0035 <0.002 n/a

10/14/2015 n/a <0.002 0.00165(J) 0.109 <0.002 <0.001 n/a 8.31 0.0197 0.000306(J) n/a

4/12/2016 n/a 0.000478(J) 0.0014(J) 0.104 <0.002 <0.001 n/a 8.61 0.0238 0.000378(J) n/a

8/2/2016 n/a n/a n/a n/a n/a n/a n/a n/a 0.00228(J) n/a n/a

12/20/2016 n/a <0.002 0.000667(J) 0.0961 <0.002 <0.001 n/a 8.56 0.0181 0.000328(J) n/a

4/12/2017 n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

6/14/2017 n/a <0.002 0.000678(J) 0.097 <0.002 <0.001 n/a 10.3 0.00322 <0.002 n/a

11/29/2017 n/a <0.002 0.00153(J) 0.106 <0.002 <0.001 n/a 8.32 <0.002 <0.002 n/a

5/23/2018 n/a <0.002 0.00323 0.122 <0.002 <0.001 n/a 7.5 <0.002 <0.002 n/a

8/20/2018 n/a n/a 0.000788(J) n/a n/a n/a n/a n/a n/a n/a n/a

11/9/2018 n/a <0.002 0.00111(J) 0.105 <0.002 <0.001 n/a 7.32 <0.002 <0.002 n/a

MW-18 downgradient

3/16/1995 0.42 <0.006 <0.005 <1 <0.004 <0.005 41.2 15 <0.005 <0.1 33

5/23/1995 0.29 <0.006 <0.005 <1 <0.004 <0.005 75 19 <0.05 <0.03 12

6/29/1995 0.26 0.012 <0.005 <1 <0.004 <0.005 140 15.2 <0.05 <0.03 21

7/25/1995 0.29 <0.006 <0.005 <1 <0.004 <0.005 147 12 <0.05 <0.03 <3.7

2/8/1996 0.16 <0.014 <0.008 <1 <0.004 <0.005 133 17 <0.05 <0.03 <3.7

8/6/1996 <0.1 <0.006 <0.01 <1 <0.004 <0.005 131 14 <0.05 <0.02 <3.7

2/26/1997 <0.07 <0.006 <0.01 <1 <0.004 <0.005 120 15 <0.05 0.02 <3.7

9/10/1997 0.12 <0.006 <0.01 <1 <0.004 <0.005 145 32 <0.05 <0.02 <3.7

4/9/1998 0.23 <0.006 <0.01 0.307 <0.002 <0.003 135 17 <0.01 <0.02 <3.7

9/23/1998 0.12 <0.006 <0.005 <0.1 <0.002 <0.003 146 18 <0.01 <0.02 14

3/16/1999 <0.06 <0.006 <0.005 <0.1 <0.002 <0.003 140 20 <0.01 <0.02 <3.7

9/29/1999 0.06 <0.006 <0.005 0.35 <0.002 <0.003 140 11.8 <0.01 <0.02 <3.7

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 5 of 105

Page 198: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

Am

mo

nia

as

N

(mg/

L)

An

tim

on

y (m

g/L)

Ars

enic

(m

g/L)

Bar

ium

(m

g/L)

Ber

ylliu

m (

mg/

L)

Cad

miu

m (

mg/

L)

Cal

ciu

m (

mg/

L)

Ch

lori

de

(mg/

L)

Ch

rom

ium

(m

g/L)

Co

bal

t (m

g/L)

CO

D (

mg/

L)

MW-18 3/14/2000 <0.06 <0.006 <0.005 0.255 <0.002 <0.003 136 22 <0.01 <0.01 <3.7

(cont.) 9/20/2000 <0.06 <0.006 <0.005 0.342 <0.002 <0.003 132.2 26.2 <0.01 <0.02 <3.7

3/21/2001 <0.06 0.016 <0.005 0.294 <0.002 <0.003 122.2 33 <0.01 <0.02 <3.7

9/26/2001 <0.05 <0.006 <0.005 0.236 <0.002 <0.003 140 20.8 <0.01 <0.02 <3.7

3/27/2002 <0.06 <0.006 <0.005 0.372 <0.002 <0.003 118 34 <0.01 <0.02 <3.7

9/25/2002 0.06 <0.006 <0.005 0.399 <0.002 <0.003 128 39.5 <0.01 <0.02 <3.7

4/1/2003 <0.05 <0.006 <0.005 0.287 <0.002 <0.003 128 39.5 <0.01 <0.02 <3.7

9/17/2003 0.23 <0.006 0.00798 0.274 0.00222 <0.003 112 39.8 0.0177 <0.02 55

MW-19 downgradient

9/28/2010 n/a <0.0003 0.0022 0.189 <0.0003 <0.0002 n/a 12.7 <0.0005 <0.001 n/a

12/30/2010 n/a <0.001 0.0013 0.145 <0.0005 <0.0005 n/a 11.3 0.00085 <0.0025 n/a

3/9/2011 n/a <0.001 <0.001 0.16 <0.001 <0.0005 n/a 15 <0.01 <0.01 n/a

6/3/2011 n/a <0.001 <0.001 0.2 <0.001 <0.0005 n/a 15 <0.01 <0.01 n/a

9/13/2011 n/a <0.001 0.0019 0.19 <0.001 <0.0005 n/a 19 <0.01 <0.01 n/a

3/13/2012 n/a 0.00022 0.00078 0.27 <0.001 <0.0005 n/a 16 0.0084 <0.01 n/a

9/26/2012 n/a <0.001 0.0019 0.3 <0.001 <0.0005 n/a 16 <0.01 <0.01 n/a

3/5/2013 n/a <0.001 0.001(J) 0.3 <0.001 <0.0005 n/a 16(B) 0.47(R) 0.0038(J) n/a

9/11/2013 n/a 0.00068(J) 0.015 0.27 <0.001 <0.0005 n/a 15 0.025 0.0016 n/a

11/20/2013 n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

3/4/2014 n/a <0.001 0.002 0.24 <0.001 0.00029(J) n/a 17 0.007 0.00058(J) n/a

6/9/2014 n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

10/9/2014 n/a <0.001 0.00061(J) 0.25 <0.001 <0.0005 n/a 14 0.021 0.00035(J) n/a

4/21/2015 n/a <0.002 <0.002(J) 0.22 <0.002 <0.001 n/a 13 0.022 <0.002(J) n/a

10/16/2015 n/a <0.002 0.00148(J) 0.23 <0.002 <0.001 n/a 13.6 0.321 0.00354 n/a

2/3/2016 n/a n/a n/a n/a n/a n/a n/a n/a 0.175 n/a n/a

4/14/2016 n/a 0.000289(J) 0.00104(J) 0.226 <0.002 <0.001 n/a 15.4 0.0206 0.000341(J) n/a

8/3/2016 n/a n/a n/a n/a n/a n/a n/a n/a 0.0149 n/a n/a

12/22/2016 n/a <0.002 0.000711(J) 0.2 <0.002 <0.001 n/a 13.4 0.0186 0.000345(J) n/a

4/12/2017 n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

6/15/2017 n/a <0.002 0.000726(J) 0.216 <0.002 <0.001 n/a 13.6 0.00566 <0.002 n/a

12/1/2017 n/a <0.002 0.00168(J) 0.203 <0.002 <0.001 n/a 14 0.000638(BJ) <0.002 n/a

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 6 of 105

Page 199: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

Am

mo

nia

as

N

(mg/

L)

An

tim

on

y (m

g/L)

Ars

enic

(m

g/L)

Bar

ium

(m

g/L)

Ber

ylliu

m (

mg/

L)

Cad

miu

m (

mg/

L)

Cal

ciu

m (

mg/

L)

Ch

lori

de

(mg/

L)

Ch

rom

ium

(m

g/L)

Co

bal

t (m

g/L)

CO

D (

mg/

L)

MW-19 3/8/2018 n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

(cont.) 5/24/2018 n/a <0.002 0.00198(J) 0.211 <0.002 <0.001 n/a 14.1 <0.002 <0.002 n/a

11/12/2018 n/a <0.002 0.000815(J) 0.188 <0.002 <0.001 n/a 12.2 <0.002 <0.002 n/a

MW-20 downgradient

9/28/2010 n/a <0.0003 <0.0002 0.193 <0.0003 <0.0002 n/a 8.02 0.0021 <0.001 n/a

12/30/2010 n/a <0.001 0.0006 0.145 <0.0005 <0.0005 n/a 7.87 0.0007 <0.0025 n/a

3/9/2011 n/a <0.001 <0.001 0.15 <0.001 <0.0005 n/a 8.3 <0.01 <0.01 n/a

6/3/2011 n/a <0.001 <0.001 0.16 <0.001 <0.0005 n/a 8.2 <0.01 <0.01 n/a

9/13/2011 n/a <0.001 0.0015 0.16 <0.001 <0.0005 n/a 13 <0.01 <0.01 n/a

3/13/2012 n/a 0.0003 0.00033 0.17 <0.001 <0.0005 n/a 7.4 0.0086 <0.01 n/a

9/26/2012 n/a <0.001 0.0014 0.18 <0.001 <0.0005 n/a 8.3 <0.01 <0.01 n/a

3/6/2013 n/a <0.001 0.0013 0.21 <0.005 <0.0005 n/a 7.6(B) 0.031(R) <0.01 n/a

9/12/2013 n/a 0.00035(J) 0.011 0.2 <0.001 0.00018(J) n/a 10 0.018 0.0028 n/a

11/20/2013 n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

3/5/2014 n/a <0.001 0.0012 0.17 <0.001 0.00033(J) n/a 8.4 0.0015(J) 0.00049(J) n/a

6/9/2014 n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

10/23/2014 n/a 0.00028(J) <0.002 0.18 <0.002 <0.001 n/a 8.8 0.008 <0.002 n/a

4/21/2015 n/a <0.002 <0.002(J) 0.18 <0.002 <0.001 n/a 15 0.006 <0.002 n/a

10/15/2015 n/a <0.002 0.00125(J) 0.16 <0.002 <0.001 n/a 8.43 0.00618 <0.002 n/a

4/13/2016 n/a 0.000326(J) 0.00107(J) 0.209 <0.002 <0.001 n/a 8.39 0.0179 0.000478(J) n/a

8/3/2016 n/a n/a n/a n/a n/a n/a n/a n/a 0.0212 n/a n/a

12/20/2016 n/a <0.002 0.000423(J) 0.213 <0.002 <0.001 n/a 8.43 0.00923 0.000358(J) n/a

4/12/2017 n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

6/14/2017 n/a <0.002 0.000433(J) 0.23 <0.002 <0.001 n/a 8.41 0.00278 <0.002 n/a

10/5/2017 n/a n/a n/a 0.174 n/a n/a n/a n/a n/a n/a n/a

12/1/2017 n/a <0.002 0.00109(J) 0.2 <0.002 <0.001 n/a 8.16 <0.002 <0.002 n/a

5/24/2018 n/a <0.002 0.00134(J) 0.182 <0.002 <0.001 n/a 8.75 <0.002 <0.002 n/a

11/13/2018 n/a <0.002 0.000335(J) 0.23 <0.002 <0.001 n/a 9.43 <0.002 <0.002 n/a

1/29/2019 n/a n/a n/a 0.185 n/a n/a n/a n/a n/a n/a n/a

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 7 of 105

Page 200: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

Am

mo

nia

as

N

(mg/

L)

An

tim

on

y (m

g/L)

Ars

enic

(m

g/L)

Bar

ium

(m

g/L)

Ber

ylliu

m (

mg/

L)

Cad

miu

m (

mg/

L)

Cal

ciu

m (

mg/

L)

Ch

lori

de

(mg/

L)

Ch

rom

ium

(m

g/L)

Co

bal

t (m

g/L)

CO

D (

mg/

L)

MW-21 downgradient

9/28/2010 n/a <0.00015 0.0009 0.0918 <0.00015 <0.0001 n/a 5.83 <0.00025 <0.0005 n/a

12/30/2010 n/a <0.001 0.00175 0.16 <0.0005 <0.0005 n/a 6.79 0.0009 <0.0025 n/a

3/9/2011 n/a <0.001 <0.001 0.18 <0.001 <0.0005 n/a 7.2 <0.01 <0.01 n/a

6/3/2011 n/a <0.001 <0.001 0.19 <0.001 <0.0005 n/a 7.1 <0.01 <0.01 n/a

9/13/2011 n/a <0.001 0.003 0.18 <0.001 <0.0005 n/a 12 <0.01 <0.01 n/a

3/13/2012 n/a <0.001 0.0016 0.22 <0.001 <0.0005 n/a 7 0.014 <0.01 n/a

9/26/2012 n/a <0.001 0.00063 0.17 0.00017 <0.0005 n/a 7.1 0.0047 <0.01 n/a

3/6/2013 n/a <0.001 0.0016 0.18 <0.001 <0.0005 n/a 6.8(B) 0.0076(J) <0.01 n/a

9/12/2013 n/a 0.00032(J) 0.0081 0.27 0.00012(J) 0.00018(J) n/a 9.3 0.012 0.0061 n/a

3/6/2014 n/a <0.001 0.017 0.19 <0.001 0.00031(J) n/a 7 0.0029 0.00049(J) n/a

10/8/2014 n/a <0.001 0.0038 0.17 <0.001 <0.0005 n/a 6.8 0.0026 <0.001 n/a

4/22/2015 n/a <0.002 0.0047 0.18 <0.002 <0.001 n/a 7 <0.002(J) <0.002 n/a

10/14/2015 n/a <0.002 0.00883 0.216 <0.002 <0.001 n/a 7.21 0.0374 0.00127(J) n/a

4/13/2016 n/a 0.000244(J) 0.00387 0.154 <0.002 <0.001 n/a 6.9 0.00718 <0.002 n/a

12/20/2016 n/a <0.002 0.00198(J) 0.144 <0.002 <0.001 n/a 7.09 0.00315 0.000264(J) n/a

6/14/2017 n/a <0.002 0.0155 0.196 <0.002 <0.001 n/a 7.3 0.00208 <0.002 n/a

11/29/2017 n/a <0.002 0.0024 0.148 <0.002 <0.001 n/a 7.17 <0.002 <0.002 n/a

5/24/2018 n/a <0.002 0.00445 0.171 <0.002 <0.001 n/a 7.14 <0.002 <0.002 n/a

11/13/2018 n/a <0.002 0.00128(J) 0.127 <0.002 <0.001 n/a 6.93 <0.002 <0.002 n/a

MW-22 downgradient

11/29/2017 n/a <0.002 0.00268 0.0638 <0.002 <0.001 n/a 3.73 0.000705(BJ) <0.002 n/a

3/8/2018 n/a <0.002 0.00261 0.0516 <0.002 <0.001 n/a 3.47 0.000633(J) <0.002 n/a

5/23/2018 n/a <0.002 0.00296 0.0638 <0.002 <0.001 n/a 4.32 <0.002 <0.002 n/a

8/20/2018 n/a <0.002 0.00217 0.0606 <0.002 <0.001 n/a 4.78 <0.002 <0.002 n/a

11/9/2018 n/a <0.002 0.00199(J) 0.0533 <0.002 <0.001 n/a 4.11 <0.002 <0.002 n/a

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 8 of 105

Page 201: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

Am

mo

nia

as

N

(mg/

L)

An

tim

on

y (m

g/L)

Ars

enic

(m

g/L)

Bar

ium

(m

g/L)

Ber

ylliu

m (

mg/

L)

Cad

miu

m (

mg/

L)

Cal

ciu

m (

mg/

L)

Ch

lori

de

(mg/

L)

Ch

rom

ium

(m

g/L)

Co

bal

t (m

g/L)

CO

D (

mg/

L)

LEACHATEBLDGA downgradient

3/6/2013 n/a 0.0011 0.17 10 0.00022 <0.0005 n/a 1800 0.016 0.088 n/a

9/11/2013 n/a 0.0034 0.069 2.4 <0.005 <0.0025 n/a 1900 0.049 0.047 n/a

3/5/2014 n/a 0.0013(J) 0.083 3.1 <0.005 <0.0025 n/a 2000 0.043 0.052 n/a

10/9/2014 n/a 0.0018 0.069 2.9 <0.001 <0.0005 n/a 2200 0.041 0.056 n/a

4/14/2015 n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

4/16/2015 n/a <0.018(J) 0.067 2.1 <0.018 <0.009 n/a 1500 0.036 0.098 n/a

10/16/2015 n/a 0.00278(J) 0.0775 2.58 <0.018 <0.009 n/a 2160 0.0462 0.0641 n/a

4/13/2016 n/a 0.00276(J) 0.0653 2.59 <0.018 <0.009 n/a 1990 0.0372 0.0565 n/a

12/22/2016 n/a <0.018 0.064 3.26 0.00163(J) <0.009 n/a 2640 0.0877 0.0762 n/a

6/15/2017 n/a 0.0252 0.0464 1.82 <0.002 <0.001 n/a 1490 0.036 0.0567 n/a

12/1/2017 n/a 0.0068 0.0702 2.67 <0.002 <0.001 n/a 2280 0.0569 0.0673 n/a

5/25/2018 n/a 0.0327 0.094 3.1 0.000779(J) <0.001 n/a 2470 0.067 0.0711 n/a

11/14/2018 n/a 0.0191 0.0793 2.46 <0.002 <0.001 n/a 2380 0.0583 0.0586 n/a

LEACHATEBLDGB downgradient

3/6/2013 n/a 0.00023 0.025 0.86 0.00065 <0.0005 n/a 410 0.002 0.018 n/a

3/5/2014 n/a 0.00047(J) 0.0084 0.48 <0.001 <0.0005 n/a 440 0.0027 0.0059 n/a

10/9/2014 n/a 0.0004(J) 0.011 0.57 <0.001 <0.0005 n/a 510 0.0036 0.0096 n/a

4/14/2015 n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

4/16/2015 n/a <0.002(J) 0.0056 0.81 <0.002 <0.001 n/a 510 0.0034 0.01 n/a

10/16/2015 n/a 0.000498(J) 0.00789 0.599 <0.002 <0.001 n/a 523 0.0035 0.00987 n/a

4/13/2016 n/a 0.000694(J) 0.00943 0.568 <0.002 <0.001 n/a 467 0.00392 0.00789 n/a

12/22/2016 n/a 0.00107(J) 0.0296 0.611 <0.002 0.000163(J) n/a 511 0.00512 0.00862 n/a

6/15/2017 n/a 0.000892(J) 0.00622 0.536 <0.002 <0.001 n/a 424 0.00347 0.00721 n/a

12/1/2017 n/a <0.002 0.0284 1.7 0.000123(J) <0.001 n/a 510 0.00711 0.00857 n/a

5/25/2018 n/a n/a 0.00993 1.06 <0.002 <0.001 n/a 367 0.00289 0.00703 n/a

11/14/2018 n/a 0.000909(J) 0.0139 0.578 <0.002 <0.001 n/a 571 0.00973 0.0156 n/a

LEACHATEBLDGC downgradient

9/11/2013 n/a 0.00051 0.0067 0.33 <0.001 <0.0005 n/a 470 0.0046 0.0014 n/a

3/5/2014 n/a 0.00054(J) 0.016 0.39 <0.001 <0.0005 n/a 520 0.004 0.0034 n/a

10/9/2014 n/a 0.0022 0.0044 0.59 <0.001 <0.0005 n/a 670 0.0024 0.0038 n/a

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 9 of 105

Page 202: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

Am

mo

nia

as

N

(mg/

L)

An

tim

on

y (m

g/L)

Ars

enic

(m

g/L)

Bar

ium

(m

g/L)

Ber

ylliu

m (

mg/

L)

Cad

miu

m (

mg/

L)

Cal

ciu

m (

mg/

L)

Ch

lori

de

(mg/

L)

Ch

rom

ium

(m

g/L)

Co

bal

t (m

g/L)

CO

D (

mg/

L)

LEACHATEBLDGC 4/14/2015 n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

(cont.) 4/16/2015 n/a <0.002(J) 0.005 0.49 <0.002 <0.001 n/a 620 <0.002(J) 0.0029 n/a

10/16/2015 n/a 0.000744(J) 0.00503 0.481 <0.002 <0.001 n/a 691 0.00184(J) 0.00226 n/a

4/13/2016 n/a 0.000588(J) 0.00348 0.445 <0.002 <0.001 n/a 682 0.00183(J) 0.00241 n/a

12/22/2016 n/a 0.001(J) 0.0142 1.66 <0.002 <0.001 n/a 788 0.00415 0.00407 n/a

6/15/2017 n/a <0.002 0.00346 0.555 <0.002 <0.001 n/a 538 0.00147(J) 0.00276 n/a

12/1/2017 n/a <0.002 0.00673 3.72 <0.002 <0.001 n/a 864 0.00198(BJ) 0.00328 n/a

5/25/2018 n/a <0.002 0.00462 0.572 <0.002 <0.001 n/a 743 0.00174(J) 0.00335 n/a

11/14/2018 n/a <0.002 0.00425 0.654 <0.002 <0.001 n/a 932 0.00327 0.00376 n/a

MW-6 downgradient

3/16/1995 0.29 <0.006 <0.005 <1 <0.004 <0.005 28.4 12 <0.005 <1 <3.7

5/23/1995 0.25 <0.006 <0.005 <1 <0.004 <0.005 101 22.5 <0.05 <0.03 21

6/29/1995 0.12 <0.006 <0.005 <1 <0.004 <0.005 114 13.8 <0.05 <0.03 24

7/25/1995 0.3 <0.006 <0.005 <1 <0.004 <0.005 106 12 <0.05 <0.03 <3.7

2/8/1996 0.09 <0.014 <0.008 <1 <0.004 <0.005 103 12 <0.05 <0.03 <3.7

8/6/1996 <0.1 <0.006 <0.01 <1 <0.004 <0.005 91.3 10 <0.05 <0.02 <3.7

2/26/1997 <0.07 <0.006 <0.01 <1 <0.004 <0.005 109 10.5 <0.05 <0.02 7

9/10/1997 0.37 <0.006 <0.01 <1 <0.004 <0.005 109 22 <0.05 <0.02 11

MW-6R downgradient

9/23/1998 <0.06 <0.006 <0.005 <0.1 <0.002 <0.003 87 20.5 <0.01 <0.02 7

3/16/1999 <0.06 <0.006 <0.005 <0.1 <0.002 <0.003 88.2 21 <0.01 <0.02 <3.7

9/29/1999 0.36 <0.006 <0.005 0.19 <0.002 <0.003 88.2 11.3 <0.01 <0.02 4

3/14/2000 <0.06 <0.006 <0.005 0.144 <0.002 <0.003 94.1 21 <0.01 <0.01 <3.7

9/20/2000 <0.06 <0.006 <0.005 0.191 <0.002 <0.003 94.2 21 <0.01 <0.02 <3.7

3/21/2001 <0.06 <0.006 <0.005 0.179 <0.002 <0.003 92.2 10.8 <0.01 <0.02 <3.7

9/26/2001 0.11 <0.006 <0.005 0.079 <0.002 <0.003 178 13.2 <0.01 <0.02 <3.7

3/27/2002 <0.06 <0.006 <0.005 0.232 <0.002 <0.003 94.1 18.2 <0.01 <0.02 <3.7

9/25/2002 <0.06 <0.006 <0.005 0.258 <0.002 <0.003 114 17 <0.01 <0.02 <3.7

4/1/2003 0.12 <0.006 <0.005 0.187 <0.002 <0.003 102 19.8 <0.01 <0.02 <3.7

9/17/2003 0.07 <0.006 <0.005 0.087 <0.002 <0.003 108 17 <0.01 <0.02 <3.7

3/24/2004 0.1 <0.006 <0.005 0.158 <0.002 <0.003 62.3 20.5 <0.01 <0.02 <3.7

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 10 of 105

Page 203: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

Am

mo

nia

as

N

(mg/

L)

An

tim

on

y (m

g/L)

Ars

enic

(m

g/L)

Bar

ium

(m

g/L)

Ber

ylliu

m (

mg/

L)

Cad

miu

m (

mg/

L)

Cal

ciu

m (

mg/

L)

Ch

lori

de

(mg/

L)

Ch

rom

ium

(m

g/L)

Co

bal

t (m

g/L)

CO

D (

mg/

L)

MW-6R 9/14/2004 n/a <0.006 <0.005 0.172 <0.004 <0.003 n/a 21.7 <0.01 <0.02 n/a

(cont.) 3/9/2005 n/a <0.006 <0.005 <0.01 <0.002 <0.003 n/a 23.5 <0.005 <0.02 n/a

9/28/2005 n/a <0.002 <0.0015 0.131 0.00241 <0.0003 n/a 20.5 0.000593 <0.02 n/a

3/15/2006 n/a <0.002 0.00191 0.0544 <0.00018 <0.0003 n/a 32 0.000893 <0.02 n/a

9/20/2006 n/a <0.002 <0.005 0.0629 <5E-05 <0.0003 n/a 19.5 <0.0015 <0.1 n/a

3/6/2007 n/a <0.002 <0.0015 0.0605 <5E-05 <0.0003 n/a 19 <0.0005 <0.02 n/a

9/19/2007 n/a <0.00092 <0.00074 0.199 <0.00032 <0.000595 n/a 22 0.00065 <0.0005 n/a

4/1/2008 n/a <0.0025 <0.0037 0.194 <0.0016 <0.003 n/a 24.9 0.002 <0.0025 n/a

9/18/2008 n/a <0.0004 0.00184 0.232 <0.0002 <0.0002 n/a <15 0.00038 <0.001 n/a

3/17/2009 n/a <0.0004 0.00318 0.198 <0.0002 <0.0002 n/a 17 0.00136 <0.001 n/a

10/7/2009 n/a <0.0004 0.00216 0.215 <0.0002 <0.0002 n/a 18.4 0.00046 <0.001 n/a

3/16/2010 n/a <0.0003 0.0021 0.213 <0.0003 <0.0002 n/a 17.8 <0.0005 <0.001 n/a

9/28/2010 n/a <0.0003 0.0017 0.243 <0.0003 <0.0002 n/a 17.3 <0.0005 <0.001 n/a

3/13/2012 n/a <0.001 0.0013 0.26 <0.001 <0.0005 n/a 21 <0.01 <0.01 n/a

9/26/2012 n/a <0.001 0.001 0.26 <0.001 <0.0005 n/a 21 <0.01 <0.01 n/a

3/5/2014 n/a <0.001 0.0024 0.21 <0.001 0.00038 n/a 18 0.0031 0.00054 n/a

6/9/2014 n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

MW-9 downgradient

3/16/1995 0.13 <0.006 <0.005 <1 <0.004 <0.005 31.8 12 <0.005 <0.1 <3.7

5/23/1995 0.27 <0.006 <0.005 <1 <0.004 <0.005 87 21 <0.05 <0.03 13

6/29/1995 0.18 <0.006 <0.005 <1 <0.004 <0.005 70.5 14.5 <0.05 <0.03 7

7/25/1995 0.49 <0.006 <0.005 <1 <0.004 <0.005 75 14.2 <0.05 <0.03 <3.7

2/8/1996 0.13 <0.014 <0.008 <1 <0.004 <0.005 75 13 <0.05 <0.03 10

8/6/1996 0.27 <0.006 <0.01 <1 <0.004 <0.005 76.1 13 <0.05 <0.02 <3.7

2/26/1997 <0.07 <0.006 <0.01 <1 <0.004 <0.005 77 14 <0.05 <0.02 <3.7

9/10/1997 0.55 <0.006 <0.01 <1 <0.004 <0.005 75 45 <0.05 <0.02 <3.7

4/9/1998 0.15 <0.006 <0.01 0.129 <0.002 <0.003 81.4 12.2 <0.01 <0.02 <3.7

9/23/1998 <0.06 <0.006 <0.005 <0.1 <0.002 <0.003 74 11.5 <0.01 <0.02 12

3/16/1999 <0.06 <0.006 <0.005 <0.1 <0.002 <0.003 60.1 15 <0.01 <0.02 <3.7

9/29/1999 0.24 <0.006 <0.005 0.13 <0.002 <0.003 68.1 4.8 <0.01 <0.02 <3.7

3/14/2000 <0.06 <0.006 <0.005 <0.1 <0.002 <0.003 84.2 10 <0.01 <0.01 <3.7

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 11 of 105

Page 204: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

Am

mo

nia

as

N

(mg/

L)

An

tim

on

y (m

g/L)

Ars

enic

(m

g/L)

Bar

ium

(m

g/L)

Ber

ylliu

m (

mg/

L)

Cad

miu

m (

mg/

L)

Cal

ciu

m (

mg/

L)

Ch

lori

de

(mg/

L)

Ch

rom

ium

(m

g/L)

Co

bal

t (m

g/L)

CO

D (

mg/

L)

MW-9 9/20/2000 <0.06 <0.006 <0.005 0.134 <0.002 <0.003 78.2 8.5 <0.01 <0.02 <3.7

(cont.) 3/21/2001 <0.06 0.007 <0.005 0.142 <0.002 <0.003 84.2 10.5 <0.01 <0.02 <3.7

9/26/2001 0.11 <0.006 <0.005 0.085 <0.002 <0.003 76.1 10 <0.01 <0.02 <3.7

3/27/2002 <0.06 <0.006 <0.005 0.213 <0.002 <0.003 92.2 11 <0.01 <0.02 <3.7

9/25/2002 <0.06 <0.006 <0.005 0.228 <0.002 <0.003 74.1 12 <0.01 <0.02 <3.7

4/1/2003 0.06 <0.006 <0.005 0.169 <0.002 <0.003 88 11.5 <0.01 <0.02 <3.7

9/17/2003 0.2 <0.006 <0.005 0.075 <0.002 <0.003 78 10.5 0.0865 <0.02 <3.7

3/24/2004 <0.05 <0.006 <0.005 0.108 <0.002 <0.003 60.4 10.3 <0.01 <0.02 <3.7

9/14/2004 n/a <0.006 <0.005 0.126 <0.004 <0.003 n/a 10 <0.01 <0.02 n/a

3/9/2005 n/a <0.006 <0.005 0.03 <0.002 <0.003 n/a 13.2 <0.005 <0.02 n/a

9/28/2005 n/a <0.002 <0.0015 0.0997 0.00117 <0.0003 n/a 15.5 0.000819 <0.02 n/a

3/15/2006 n/a <0.002 0.00153 0.0457 <0.00018 <0.0003 n/a 21 0.000744 <0.02 n/a

9/20/2006 n/a <0.002 <0.005 0.039 <5E-05 <0.0003 n/a 11 <0.0015 <0.1 n/a

3/6/2007 n/a <0.002 <0.0015 0.0336 <5E-05 <0.0003 n/a 8 <0.0015 <0.02 n/a

9/19/2007 n/a <0.00092 <0.00074 0.145 <0.00032 <0.000595 n/a 11 <0.00025 <0.0005 n/a

4/1/2008 n/a <0.0025 <0.0037 0.0978 <0.0016 <0.003 n/a 10.9 0.00965 <0.0025 n/a

9/18/2008 n/a <0.0004 0.00062 0.127 <0.0002 <0.0002 n/a <15 0.00048 <0.001 n/a

3/17/2009 n/a <0.0004 0.00144 0.119 <0.0002 <0.0002 n/a 5.57 0.0463 0.00232 n/a

10/7/2009 n/a <0.0004 0.00086 0.108 <0.0002 <0.0002 n/a 7.32 0.00156 <0.001 n/a

3/16/2010 n/a <0.0003 <0.0002 0.124 <0.0003 <0.0002 n/a 5.74 0.0011 <0.001 n/a

MW-14 downgradient

3/16/1995 0.06 <0.006 <0.005 <1 <0.004 <0.005 68.9 19 <0.005 <0.1 <3.7

5/23/1995 0.34 <0.006 <0.005 <1 <0.004 <0.005 170 26 <0.05 <0.03 4

6/29/1995 0.15 <0.006 <0.005 <1 <0.004 <0.005 120 20.5 <0.05 <0.03 18

7/25/1995 0.19 <0.006 <0.005 <1 <0.004 <0.005 132 17 0.19 <0.03 <3.7

2/8/1996 0.1 <0.014 <0.008 <1 <0.004 <0.005 137 28 <0.05 <0.03 5

8/6/1996 0.1 <0.006 <0.01 <1 <0.004 <0.005 128.3 30 <0.05 <0.02 <3.7

2/26/1997 <0.07 <0.006 <0.01 <1 <0.004 <0.005 139 31 <0.05 <0.02 4

9/10/1997 0.12 <0.006 <0.01 <1 <0.004 <0.005 147 68 <0.05 <0.02 <3.7

4/9/1998 0.23 <0.006 <0.01 0.21 <0.002 <0.003 136 12.2 <0.01 <0.02 <3.7

9/23/1998 0.06 <0.006 <0.005 <0.1 <0.002 <0.003 130 27 <0.01 <0.02 10

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 12 of 105

Page 205: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

Am

mo

nia

as

N

(mg/

L)

An

tim

on

y (m

g/L)

Ars

enic

(m

g/L)

Bar

ium

(m

g/L)

Ber

ylliu

m (

mg/

L)

Cad

miu

m (

mg/

L)

Cal

ciu

m (

mg/

L)

Ch

lori

de

(mg/

L)

Ch

rom

ium

(m

g/L)

Co

bal

t (m

g/L)

CO

D (

mg/

L)

MW-14 3/16/1999 <0.06 <0.006 <0.005 <0.1 <0.002 <0.003 140 18 <0.01 <0.02 <3.7

(cont.) 9/29/1999 <0.06 <0.006 <0.005 0.22 <0.002 <0.003 126 11 <0.01 <0.02 <3.7

3/14/2000 <0.06 <0.006 <0.005 0.145 0.023 <0.003 126 18 <0.01 <0.01 <3.7

9/20/2000 <0.06 <0.006 <0.005 0.213 <0.002 <0.003 128.2 18.8 <0.01 <0.02 <3.7

3/21/2001 <0.06 <0.006 <0.005 0.209 <0.002 <0.003 122.2 15.3 <0.01 <0.02 <3.7

9/26/2001 <0.05 <0.006 <0.005 0.138 <0.002 <0.003 136 22.7 <0.01 <0.02 <3.7

3/27/2002 <0.06 <0.006 <0.005 0.265 <0.002 <0.003 130 18 <0.01 <0.02 <3.7

9/25/2002 <0.06 <0.006 <0.005 0.281 <0.002 <0.003 137 20 <0.01 <0.02 <3.7

4/1/2003 <0.05 <0.006 <0.005 0.23 <0.002 <0.003 122 15.5 <0.01 <0.02 <3.7

9/17/2003 <0.06 <0.006 <0.005 0.146 <0.002 <0.003 132 17 <0.01 <0.02 <3.7

3/24/2004 <0.05 <0.006 <0.005 0.143 <0.002 <0.003 101 16.5 <0.01 <0.02 <3.7

MW-16 downgradient

3/16/1995 0.13 <0.006 <0.005 <1 <0.004 <0.005 34.4 11 <0.005 <0.1 250

5/23/1995 0.05 0.006 0.005 1 0.004 0.005 1 1 0.05 0.03 3.7

6/29/1995 0.37 <0.006 <0.005 <1 <0.004 <0.005 148 19.5 <0.05 <0.03 28

7/25/1995 0.27 <0.006 <0.005 <1 <0.004 <0.005 156 18.7 <0.05 <0.03 <3.7

2/8/1996 0.09 <0.014 <0.008 <1 <0.004 <0.005 72 15 <0.05 <0.03 <3.7

8/6/1996 0.14 <0.006 <0.01 <1 <0.004 <0.005 73.7 10 <0.05 <0.02 <3.7

2/26/1997 <0.07 <0.006 <0.01 <1 <0.004 <0.005 76 12 <0.05 <0.02 <3.7

9/10/1997 0.43 <0.006 <0.01 <1 <0.004 <0.005 91 23 <0.05 <0.02 <3.7

4/9/1998 0.38 <0.006 <0.01 0.193 <0.002 <0.003 91.4 12.2 <0.01 <0.02 <3.7

9/23/1998 0.12 <0.006 <0.005 <0.1 <0.002 <0.003 107 13 <0.01 <0.02 10

3/16/1999 <0.06 <0.006 <0.005 <0.1 <0.002 <0.003 84.2 13 <0.01 <0.02 <3.7

9/29/1999 0.3 <0.006 <0.005 0.26 <0.002 <0.003 116 7.5 <0.01 <0.02 <3.7

3/14/2000 <0.06 <0.006 <0.005 0.123 <0.002 <0.003 86.2 14 <0.01 <0.01 <3.7

9/20/2000 <0.06 <0.006 <0.005 0.194 <0.002 <0.003 84.2 12 <0.01 <0.02 <3.7

3/21/2001 <0.06 <0.006 <0.005 0.166 <0.002 <0.003 76.1 11 <0.01 <0.02 <3.7

9/26/2001 0.11 <0.006 <0.005 0.103 <0.002 <0.003 82.2 10.8 <0.01 <0.02 <3.7

3/27/2002 <0.06 <0.006 <0.005 0.208 <0.002 <0.003 68.1 11 <0.01 <0.02 <3.7

9/25/2002 <0.06 <0.006 <0.005 0.222 <0.002 <0.003 90.2 12.5 <0.01 <0.02 <3.7

4/1/2003 <0.05 <0.006 <0.005 0.214 <0.002 <0.003 86 13.5 <0.01 <0.02 <3.7

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 13 of 105

Page 206: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

Am

mo

nia

as

N

(mg/

L)

An

tim

on

y (m

g/L)

Ars

enic

(m

g/L)

Bar

ium

(m

g/L)

Ber

ylliu

m (

mg/

L)

Cad

miu

m (

mg/

L)

Cal

ciu

m (

mg/

L)

Ch

lori

de

(mg/

L)

Ch

rom

ium

(m

g/L)

Co

bal

t (m

g/L)

CO

D (

mg/

L)

MW-16 9/17/2003 <0.06 <0.006 <0.005 0.096 <0.002 <0.003 88 12.8 <0.01 <0.02 <3.7

(cont.) 3/24/2004 <0.05 <0.006 <0.005 0.163 <0.002 <0.003 63.1 13.3 <0.01 <0.02 <3.7

9/14/2004 n/a <0.006 <0.005 0.184 <0.004 <0.003 n/a 14.3 <0.01 <0.02 n/a

3/9/2005 n/a <0.006 <0.005 0.024 <0.004 <0.003 n/a 15.2 <0.005 <0.02 n/a

9/28/2005 n/a <0.002 <0.0015 0.126 <0.00018 <0.0003 n/a 15 0.000768 <0.02 n/a

3/15/2006 n/a <0.002 <0.0015 0.0562 <0.00018 <0.0003 n/a 14 0.00431 <0.02 n/a

9/20/2006 n/a <0.002 <0.005 0.0703 <5E-05 <0.0003 n/a 12 <0.0015 <0.1 n/a

3/6/2007 n/a <0.002 <0.0015 0.0444 <5E-05 <0.0003 n/a 9.5 <0.0015 <0.02 n/a

9/19/2007 n/a <0.00092 <0.00074 <0.00154 <0.00032 <0.000595 n/a 15 0.0008 <0.0005 n/a

4/1/2008 n/a <0.0025 <0.0037 0.187 <0.0016 <0.003 n/a 12.9 0.00435 <0.0025 n/a

9/18/2008 n/a <0.0004 0.00076 0.221 <0.0002 <0.0002 n/a <15 0.00044 <0.001 n/a

3/17/2009 n/a <0.0004 0.00162 0.15 <0.0002 <0.0002 n/a 7.37 0.0122 0.00192 n/a

10/7/2009 n/a <0.0004 0.0011 0.157 <0.0002 <0.0002 n/a 11.4 0.00058 <0.001 n/a

3/16/2010 n/a <0.0003 <0.0002 0.185 <0.0003 <0.0002 n/a 11 0.0014 <0.001 n/a

MW-17 downgradient

3/16/1995 <0.05 <0.006 <0.005 <1 <0.004 <0.005 87.3 41 <0.005 <0.1 364

5/23/1995 0.19 <0.006 <0.005 <1 <0.004 <0.005 185 55 <0.05 <0.03 124

6/29/1995 0.34 <0.006 <0.005 <1 <0.004 <0.005 145 47.5 <0.05 <0.03 58

7/25/1995 0.26 <0.006 <0.005 <1 <0.004 <0.005 128 38.7 <0.05 <0.03 9

2/8/1996 0.33 <0.014 <0.008 <1 <0.004 <0.005 108 41 <0.05 <0.03 <3.7

8/6/1996 0.35 <0.006 <0.01 <1 <0.004 <0.005 108.2 27 <0.05 <0.02 <3.7

2/26/1997 <0.07 <0.006 <0.01 <1 <0.004 <0.005 100 35 <0.05 <0.02 5

9/10/1997 0.68 <0.006 <0.01 <1 <0.004 <0.005 95 53 <0.05 <0.02 <3.7

4/9/1998 0.08 <0.006 <0.01 0.128 <0.002 <0.003 97 34 <0.01 <0.02 <3.7

9/23/1998 0.06 <0.006 <0.005 <0.1 <0.002 <0.003 95 30.5 <0.01 <0.02 9

3/16/1999 <0.06 <0.006 <0.005 <0.1 <0.002 <0.003 100 38 <0.01 <0.02 <3.7

9/29/1999 0.12 <0.006 <0.005 0.14 <0.002 <0.003 96.2 15.7 <0.01 <0.02 <3.7

3/14/2000 <0.06 <0.006 <0.005 <0.1 <0.002 <0.003 92.1 23 <0.01 <0.01 <3.7

9/20/2000 <0.06 <0.006 <0.005 0.139 <0.002 <0.003 100.2 30.5 <0.01 <0.02 <3.7

3/21/2001 <0.06 <0.006 <0.005 0.143 <0.002 <0.003 100.2 35 <0.01 <0.02 <3.7

9/26/2001 <0.05 <0.006 <0.005 0.1 <0.002 <0.003 98.2 35 <0.01 <0.02 16

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 14 of 105

Page 207: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

Am

mo

nia

as

N

(mg/

L)

An

tim

on

y (m

g/L)

Ars

enic

(m

g/L)

Bar

ium

(m

g/L)

Ber

ylliu

m (

mg/

L)

Cad

miu

m (

mg/

L)

Cal

ciu

m (

mg/

L)

Ch

lori

de

(mg/

L)

Ch

rom

ium

(m

g/L)

Co

bal

t (m

g/L)

CO

D (

mg/

L)

MW-17 3/27/2002 0.06 <0.006 <0.005 0.18 <0.002 <0.003 104 34.5 0.01 <0.02 <3.7

(cont.) 9/25/2002 <0.06 <0.006 <0.005 0.201 <0.002 <0.003 96.2 36 <0.01 <0.02 <3.7

4/1/2003 <0.05 <0.006 <0.005 0.157 <0.002 <0.003 106 32.5 <0.01 <0.02 <3.7

9/17/2003 <0.06 <0.006 <0.005 0.079 <0.002 <0.003 102 32.2 <0.01 <0.02 34

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 15 of 105

Page 208: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-8 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

3/24/2004

9/14/2004

3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

Co

pp

er (

mg/

L)

Dis

solv

ed s

olid

s

(mg/

L)

Iro

n (

mg/

L)

Lead

(m

g/L)

Man

gan

ese

(mg/

L)

Mer

cury

(m

g/l)

Nic

kel (

mg/

L)

pH

(su

)

Sele

niu

m (

mg/

L)

Silv

er (

mg/

L)

Sod

ium

(m

g/L)

<0.03 429 0.72 <0.015 <0.05 n/a <1 7.11 <0.005 <0.05 40.9

<0.03 425 2.56 <0.015 0.795 n/a <0.05 6.88 <0.005 <0.05 23.1

<0.03 399 1.39 <0.015 0.69 n/a <0.1 7.22 <0.005 <0.05 21.3

<0.03 405 1.74 <0.015 0.7 n/a <0.1 6.81 <0.005 <0.05 50.4

<0.03 404 1.78 0.036 0.68 n/a <0.1 6.88 <0.008 <0.05 52.2

<0.03 395 1.68 <0.015 0.66 n/a <0.05 7 <0.01 <0.05 14.9

<0.03 398 1.49 0.02 0.53 n/a <0.05 6.64 <0.01 <0.05 16.7

<0.03 422 2.4 <0.015 0.685 n/a <0.05 6.79 <0.02 <0.05 15.4

<0.005 395 1.85 <0.005 0.65 n/a <0.01 6.42 <0.01 <0.01 13.5

<0.005 420 1.68 <0.005 0.622 n/a <0.01 6.86 <0.01 <0.01 11.7

<0.005 410 1.85 <0.005 0.62 n/a <0.01 6.63 <0.01 <0.01 13.9

<0.005 387 1.56 <0.005 0.644 n/a <0.01 7.16 <0.01 <0.01 14

<0.005 382 1.35 <0.005 0.56 n/a <0.01 7.07 <0.01 <0.01 13.4

<0.005 386 <0.03 <0.005 0.44 n/a <0.01 6.89 <0.01 <0.01 17

<0.005 369 1.11 <0.005 0.49 n/a <0.01 7.06 <0.01 <0.01 13.3

<0.005 333 0.831 <0.005 0.477 n/a <0.01 7.02 <0.005 <0.01 13.1

<0.005 360 0.803 <0.005 0.471 n/a <0.01 7.05 <0.01 <0.01 13.4

<0.005 336 0.768 <0.005 0.425 n/a <0.01 6.92 <0.01 <0.01 14.3

<0.005 353 0.854 <0.005 0.44 n/a <0.01 7.1 <0.01 <0.01 14.2

<0.005 373 1.41 <0.005 0.402 n/a <0.01 7.21 <0.01 <0.01 13.5

<0.005 377 0.846 <0.005 0.499 n/a <0.01 6.92 <0.01 <0.01 14.4

<0.005 362 1.167 <0.005 0.528 n/a <0.01 6.95 <0.01 <0.01 n/a

<0.005 366 0.728 <0.005 0.438 n/a <0.01 7.02 <0.01 <0.01 n/a

<0.01 <0.0015(O) n/a <0.003 45.2(O) n/a <0.00057 22.2(R) <0.001 <0.002 355

<0.002 347 0.566 <0.001 0.348 n/a 0.0334 7.08 <0.003 <0.00057 n/a

<0.002 364 0.376 <0.001 0.369 n/a <0.005 6.82 <0.005 <0.00057 n/a

<0.002 355 0.355 <0.001 0.328 n/a 0.00238 7.15 <0.003 <0.00057 n/a

<0.0005 384 <0.05 <0.000424 0.366 n/a 0.00145 7.13 <0.00356 <0.000434 n/a

<0.001 388 <10 <0.0005 0.383 n/a 0.0012 7.16 <0.0178 <0.00125 n/a

0.0002 405 0.763 <0.0002 0.461 n/a 0.00166 7.31 <0.001 <0.0002 n/a

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 16 of 105

Page 209: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-8 3/17/2009

(cont.) 10/7/2009

3/16/2010

9/28/2010

9/26/2012

3/5/2014

10/16/2015

6/15/2017

MW-9R downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

9/13/2011

3/13/2012

9/26/2012

3/6/2013

9/12/2013

3/5/2014

10/9/2014

4/22/2015

11/12/2015

11/29/2017

MW-9R2 downgradient

5/25/2018

11/13/2018

MW-14R upgradient

9/14/2004

3/9/2005

9/28/2005

3/15/2006

Co

pp

er (

mg/

L)

Dis

solv

ed s

olid

s

(mg/

L)

Iro

n (

mg/

L)

Lead

(m

g/L)

Man

gan

ese

(mg/

L)

Mer

cury

(m

g/l)

Nic

kel (

mg/

L)

pH

(su

)

Sele

niu

m (

mg/

L)

Silv

er (

mg/

L)

Sod

ium

(m

g/L)

0.00598 456 0.104 <0.0002 0.0206 n/a 0.00094 7.41 <0.001 <0.0002 n/a

0.00222 379 0.725 6.00E-05 0.384 n/a 0.00238 6.84 <0.001 <0.0002 n/a

<0.0003 340 0.679 0.0002 0.401 n/a 0.0043 7.13 <0.002 <0.0008 n/a

0.0022 353 2.04 0.0012 0.349 n/a 0.0064 7.3 <0.002 <0.0008 n/a

0.00053 360 1.1 <0.001 0.27 n/a <0.02 7.21 <0.001 <0.01 n/a

0.0029 330 0.56 0.0025 0.24 n/a 0.0053 7 0.0014 <0.001 n/a

<0.005 307 0.374 <0.002 0.261 n/a 0.00512 7 <0.002 <0.002 n/a

<0.005 325 0.424 <0.002 0.292 n/a 0.000979(J) 6.96 <0.002 <0.002 n/a

<0.0003 384 3.42 <0.0001 0.478 n/a 0.0029 6.88 <0.002 <0.0008 n/a

0.00165 303 2.24 0.00155 0.303 n/a 0.0026 7 <0.0025 <0.0005 n/a

<0.002 360 3 <0.001 0.57 n/a <0.02 7.51 <0.001 <0.01 n/a

0.0076 420 3.7 <0.001 0.71 n/a <0.02 6.65 <0.001 <0.01 n/a

<0.002 310 2.2 <0.001 0.29 n/a <0.02 6.96 <0.001 <0.01 n/a

0.0032 330 3.5 0.0019 0.36 n/a 0.019 6.58 <0.001 <0.01 n/a

0.0024 340 2.9 0.0015 0.34 n/a <0.02 6.7 <0.001 <0.01 n/a

0.017 330 8.1(BR) 0.01(R) 0.65(B) <0.0002 0.052(R) 6.3 0.00053(J) <0.01 n/a

0.25(BRO) 430 5.7 0.0085(R) 0.69 <0.0002 0.014 6.6 0.00049(J) <0.001 n/a

0.0049 300 2.8 0.0017 0.85 n/a 0.0072 6.8 0.001 <0.001 n/a

0.0011(J) 400(B) 3.1 0.00035(J) 0.65 n/a 0.0034 6.9 <0.001 <0.001 n/a

0.0095 353 2.7 <0.002(J) 0.67 n/a 0.02 6.9 <0.002 <0.002 n/a

0.00263(J) 286 1.8 0.000478(J) 0.522 n/a 0.0159 6.8 <0.002 <0.002 n/a

0.000777(BJ) 251 2.43 <0.002 0.33 n/a <0.002 7.7 <0.002 <0.002 n/a

0.000759(BJ) 257 1.4 0.000346(BJ) 0.299 n/a <0.002 7.2 <0.002 <0.002 n/a

<0.005 277 1.71 0.000643(J) 0.396 n/a <0.002 6.9 <0.002 <0.002 n/a

<0.005 602 2.565 <0.005 0.637 n/a <0.01 6.75 <0.01 <0.01 n/a

<0.005 617 2.71 <0.005 0.455 n/a <0.01 6.9 <0.01 <0.01 n/a

<0.002 645 3.69 <0.001 0.37 n/a <0.01 6.6 <0.003 <0.00057 n/a

<0.002 598 3.88 <0.001 0.375 n/a 0.0277 6.75 <0.003 <0.00057 n/a

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 17 of 105

Page 210: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-14R 9/20/2006

(cont.) 3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

9/28/2010

3/9/2011

9/13/2011

3/13/2012

9/26/2012

3/5/2013

9/10/2013

3/4/2014

10/6/2014

4/14/2015

10/14/2015

4/12/2016

8/2/2016

12/20/2016

6/13/2017

11/29/2017

5/23/2018

11/12/2018

MW-16R downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

Co

pp

er (

mg/

L)

Dis

solv

ed s

olid

s

(mg/

L)

Iro

n (

mg/

L)

Lead

(m

g/L)

Man

gan

ese

(mg/

L)

Mer

cury

(m

g/l)

Nic

kel (

mg/

L)

pH

(su

)

Sele

niu

m (

mg/

L)

Silv

er (

mg/

L)

Sod

ium

(m

g/L)

<0.002 615 4.01 <0.001 0.413 n/a <0.005 6.72 <0.005 <0.00057 n/a

<0.002 585 3.02 <0.001 0.348 n/a 0.00248 6.94 <0.003 <0.00057 n/a

<0.0005 677 4.25 <0.000424 0.377 n/a 0.0022 6.78 <0.00356 <0.000434 n/a

0.00165 597 <10 <0.0005 0.389 n/a 0.01 6.95 <0.0178 <0.00125 n/a

0.00178 645 4.37 <0.0002 0.407 n/a 0.00166 6.91 <0.001 <0.0002 n/a

0.0004 632 4.22 <0.0002 0.413 n/a 0.0189 7.33 <0.001 0.0003 n/a

0.00176 616 3.89 4.00E-05 0.398 n/a 0.00128 6.47 <0.001 <0.0002 n/a

0.001 603 3.95 <0.0001 0.506 n/a 0.0026 6.47 <0.002 <0.0008 n/a

<0.0003 596 4.43 <0.0001 0.527 n/a 0.0019 7.08 <0.002 <0.0008 n/a

<0.002 660 5 <0.001 0.56 n/a <0.02 7.59 <0.001 <0.01 n/a

<0.002 660 5.2 <0.001 0.57 n/a <0.02 6.85 <0.001 <0.01 n/a

0.0014 660 5.7 0.00044 0.6 n/a <0.02 6.51 0.0012 <0.01 n/a

<0.002 640 5.2 <0.001 0.58 n/a <0.02 6.7 <0.001 <0.01 n/a

0.0016(J) 610 5.3(B) 0.00027(J) 0.56(B) <0.0002 0.012(J) 6.6 0.00086(J) <0.01 n/a

0.00077(JB) 600 4.6 0.00029(J) 0.54 <0.0002 0.0039 6.8 0.0008(J) <0.001 n/a

0.00084(J) 600 5.7 0.00086(J) 0.54 n/a 0.0074 6.8 0.0039 <0.001 n/a

0.003 720(B) 8.1 0.0014 0.58 n/a 0.018 7 0.0023 <0.001 n/a

<0.005(B) 600 5.9 <0.002 0.54 n/a <0.002(J) 6.6 <0.002 <0.002 n/a

0.00091(J) 608 5.84 0.000284(J) 0.535 n/a 0.00184(J) 6.9 <0.002 <0.002 n/a

0.00122(J) 635 5.89 0.000588(J) 0.507 n/a 0.00369 6.7 <0.002 <0.002 n/a

n/a n/a 5.55 n/a n/a n/a n/a n/a n/a n/a n/a

0.00152(BJ) 621 4.94 <0.002 0.437 n/a 0.0015(J) 6.9 <0.002 <0.002 n/a

<0.005 655 5.72 <0.002 0.475 n/a 0.000786(J) 6.43 <0.002 <0.002 n/a

0.00115(BJ) 631 4.8 <0.002 0.429 n/a 0.000444(BJ) 7.1 <0.002 <0.002 n/a

0.000722(BJ) 652 6.54 0.000315(BJ) 0.44 n/a <0.002 6.8 <0.002 <0.002 n/a

0.00183(BJ) 533 5.54 0.000288(J) 0.355 n/a 0.000463(J) 6.9 <0.002 <0.002 n/a

<0.0003 346 2.2 <0.0001 0.592 n/a 0.0017 6.99 <0.002 <0.0008 n/a

<0.001 368 1.61 <0.0005 0.542 n/a <0.001 6.97 <0.0025 <0.0005 n/a

<0.002 310 1.9 <0.001 0.55 n/a <0.02 7.62 <0.001 <0.01 n/a

<0.002 340 1.4 <0.001 0.54 n/a <0.02 7.12 <0.001 <0.01 n/a

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 18 of 105

Page 211: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-16R 9/13/2011

(cont.) 3/13/2012

9/26/2012

3/5/2013

9/11/2013

3/4/2014

10/23/2014

4/21/2015

10/16/2015

4/14/2016

12/20/2016

6/15/2017

12/1/2017

3/8/2018

5/24/2018

11/12/2018

MW-17R upgradient

9/14/2004

3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

9/28/2010

3/9/2011

Co

pp

er (

mg/

L)

Dis

solv

ed s

olid

s

(mg/

L)

Iro

n (

mg/

L)

Lead

(m

g/L)

Man

gan

ese

(mg/

L)

Mer

cury

(m

g/l)

Nic

kel (

mg/

L)

pH

(su

)

Sele

niu

m (

mg/

L)

Silv

er (

mg/

L)

Sod

ium

(m

g/L)

<0.002 320 1.3 <0.001 0.52 n/a <0.02 7.1 <0.001 <0.01 n/a

0.002 360 2.1 0.00051 0.65 n/a 0.0063 6.8 <0.001 <0.01 n/a

0.0012 320 1.6 0.00094 0.52 n/a <0.02 7.06 0.00054 <0.01 n/a

0.039(R) 410 11(BR) 0.024(R) 0.83(B) <0.0002 0.14(R) 6.8 0.00075(J) 0.0036(J) n/a

0.24(BO) 330 5.5 0.013 0.61 <0.0002 0.037 6.8 0.00063(J) <0.001 n/a

0.0056 280 1.4 0.0026 0.52 n/a 0.0049 7.1 0.0012 <0.001 n/a

0.00063(J) 300 1.3 0.00037(J) 0.48 n/a 0.0034 n/a <0.002 0.0027 n/a

<0.005 310 1.2 <0.002 0.54 n/a <0.002(J) 6.5 <0.002 <0.002 n/a

0.00101(J) 319 1.16 0.000439(J) 0.511 n/a 0.00736 6.9 <0.002 <0.002 n/a

0.000761(J) 287 0.918 <0.002 0.481 n/a 0.00219 7 <0.002 <0.002 n/a

0.00089(BJ) 313 0.996 0.00131(J) 0.471 n/a 0.00109(J) 7.3 <0.002 <0.002 n/a

0.00106(J) 300 1.15 0.000318(J) 0.507 n/a 0.00376 6.92 <0.002 <0.002 n/a

0.00149(BJ) 348 1.02 <0.002 0.625 n/a 0.000371(BJ) 7.9 <0.002 <0.002 n/a

n/a n/a n/a n/a n/a n/a n/a 6.8 n/a n/a n/a

0.000703(BJ) 308 0.805 0.000312(BJ) 0.618 n/a <0.002 7 <0.002 <0.002 n/a

0.000948(BJ) 276 0.519 0.000344(J) 0.567 n/a <0.002 7.1 <0.002 0.00047(J) n/a

<0.005 335 0.874 <0.005 0.09 n/a <0.01 6.82 <0.01 <0.01 n/a

<0.005 332 0.932 <0.005 <0.05 n/a <0.01 6.84 <0.01 <0.01 n/a

<0.001 324 1.22 <0.001 <0.03 n/a <0.01 6.59 <0.003 <0.00057 n/a

<0.001 312 1.11 <0.001 <0.03 n/a 0.0233 6.75 <0.003 <0.00057 n/a

<0.002 309 0.755 <0.001 <0.03 n/a <0.005 6.82 <0.005 <0.00057 n/a

<0.002 313 0.649 <0.001 <0.03 n/a <0.002 6.9 <0.003 <0.00057 n/a

<0.0005 357 <0.25 <0.000424 <0.015 n/a 0.00075 6.76 <0.00356 <0.000434 n/a

0.00165 318 <10 <0.0005 <0.015 n/a 0.0125 6.91 <0.0178 <0.00125 n/a

0.00044 321 1.27 0.00042 0.0414 n/a 0.00142 6.98 <0.001 <0.0002 n/a

0.00088 287 1.81 0.0006 0.0431 n/a 0.0224 7.56 <0.001 <0.0002 n/a

0.00122 303 0.862 4.00E-05 0.0359 n/a 0.00068 6.33 <0.001 <0.0002 n/a

<0.0003 294 0.998 <0.0001 0.0455 n/a 0.0029 6.84 <0.002 <0.0008 n/a

<0.0003 223 1.19 <0.0001 0.0426 n/a 0.0019 7.13 <0.002 <0.0008 n/a

<0.002 290 1.1 <0.001 0.42 n/a <0.02 7.6 <0.001 <0.01 n/a

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 19 of 105

Page 212: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-17R 9/13/2011

(cont.) 3/13/2012

9/26/2012

3/5/2013

9/11/2013

3/5/2014

10/9/2014

4/21/2015

10/14/2015

4/12/2016

8/2/2016

12/20/2016

4/12/2017

6/14/2017

11/29/2017

5/23/2018

8/20/2018

11/9/2018

MW-18 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

Co

pp

er (

mg/

L)

Dis

solv

ed s

olid

s

(mg/

L)

Iro

n (

mg/

L)

Lead

(m

g/L)

Man

gan

ese

(mg/

L)

Mer

cury

(m

g/l)

Nic

kel (

mg/

L)

pH

(su

)

Sele

niu

m (

mg/

L)

Silv

er (

mg/

L)

Sod

ium

(m

g/L)

<0.002 300 1.1 <0.001 0.039 n/a <0.02 6.93 <0.001 <0.01 n/a

0.0018 280 1.9 0.00094 0.052 n/a 0.02 6.41 <0.001 <0.01 n/a

<0.002 340 1.4 0.00085 0.06 n/a <0.02 6.82 <0.001 <0.01 n/a

<0.002 310 1.3(B) <0.001 0.055(B) <0.0002 0.01(J) 6.7 <0.001 0.0031(J) n/a

0.016(BR) 310 5.8(R) 0.00078(J) 0.15(R) <0.0002 0.38(R) 6.6 <0.001 <0.001 n/a

<0.002 300 1.5 0.00093(J) 0.058 n/a 0.0045 6.8 0.00081(J) <0.001 n/a

<0.002 310(B) 1 <0.001 0.053 n/a 0.0065 6.9 <0.001 <0.001 n/a

<0.005 310 1.6 <0.002 0.049 n/a 0.0033 6.4 <0.002 <0.002 n/a

0.000979(J) 325 2.08 <0.002 0.0476 n/a 0.0114 6.9 <0.002 <0.002 n/a

0.00126(J) 320 1.89 <0.002 0.0513 n/a 0.016 6.7 <0.002 0.000378(J) n/a

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

0.0017(BJ) 323 1.3 <0.002 0.0464 n/a 0.0121 7 <0.002 <0.002 n/a

n/a n/a n/a n/a n/a n/a n/a 6.84 n/a n/a n/a

<0.005 335 1.34 <0.002 0.0491 n/a 0.00329 6.61 <0.002 <0.002 n/a

0.0018(BJ) 330 1.67 <0.002 0.047 n/a <0.002 7.4 <0.002 <0.002 n/a

0.000846(BJ) 353 4.84 0.00049(BJ) 0.0527 n/a <0.002 6.8 <0.002 <0.002 n/a

n/a n/a n/a n/a n/a n/a n/a 6.5 n/a n/a n/a

0.00139(BJ) 349 2.24 0.000401(J) 0.051 n/a <0.002 6.8 <0.002 <0.002 n/a

<0.03 608 0.81 <0.015 <0.05 n/a <0.1 6.73 <0.005 <0.05 74.2

<0.03 344 6.86 <0.015 1.61 n/a <0.05 6.5 <0.005 <0.05 33.9

<0.03 497 4.17 <0.015 1.34 n/a <0.1 6.86 <0.005 <0.05 38.6

<0.03 554 5.31 <0.015 1.29 n/a <0.1 6.81 <0.005 <0.05 48.8

<0.03 546 7.08 0.048 1.43 n/a <0.1 6.89 <0.008 <0.05 51.3

<0.03 575 3.15 0.033 0.97 n/a <0.05 6.86 <0.01 <0.05 39

<0.03 528 3.17 0.041 0.84 n/a <0.05 6.44 <0.01 <0.05 23.6

<0.03 620 3.15 <0.015 1.13 n/a <0.05 6.81 <0.02 <0.05 40

<0.005 595 2.36 <0.005 1.11 n/a <0.01 6.82 <0.01 <0.01 40.3

<0.005 650 1.66 <0.005 0.938 n/a <0.01 6.84 <0.01 <0.01 26.2

<0.005 619 1.97 <0.005 0.95 n/a <0.01 6.51 <0.01 <0.01 37.8

<0.005 656 1.69 <0.005 1.12 n/a <0.01 7.04 0.01 <0.01 35.5

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 20 of 105

Page 213: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-18 3/14/2000

(cont.) 9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

MW-19 downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

9/13/2011

3/13/2012

9/26/2012

3/5/2013

9/11/2013

11/20/2013

3/4/2014

6/9/2014

10/9/2014

4/21/2015

10/16/2015

2/3/2016

4/14/2016

8/3/2016

12/22/2016

4/12/2017

6/15/2017

12/1/2017

Co

pp

er (

mg/

L)

Dis

solv

ed s

olid

s

(mg/

L)

Iro

n (

mg/

L)

Lead

(m

g/L)

Man

gan

ese

(mg/

L)

Mer

cury

(m

g/l)

Nic

kel (

mg/

L)

pH

(su

)

Sele

niu

m (

mg/

L)

Silv

er (

mg/

L)

Sod

ium

(m

g/L)

<0.005 606 1.57 <0.005 0.93 n/a <0.01 7 0.096 <0.01 37.5

<0.005 618 0.46 <0.005 0.8 n/a <0.01 6.81 <0.01 <0.01 41.2

<0.005 585 1.5 <0.005 0.88 n/a 0.014 7.03 <0.01 <0.01 33.13

<0.005 634 1.62 <0.005 0.827 n/a <0.01 6.78 <0.005 <0.01 29.3

<0.005 599 0.954 <0.005 0.642 n/a <0.01 6.86 0.232 <0.01 33.5

<0.005 645 2.2 <0.005 0.583 n/a <0.01 6.74 <0.01 <0.01 36.9

<0.005 585 1.561 <0.005 0.503 n/a <0.01 7 <0.01 <0.01 37.9

0.0311 555 30.8(R) <0.005 0.864 n/a <0.01 7.08 <0.01 <0.01 66.2

0.004 371 1.86 <0.0001 0.698 n/a 0.0016 7.3 <0.002 <0.0008 n/a

<0.001 372 1.01 <0.0005 0.448 n/a 0.0014 7.16 <0.0025 <0.0005 n/a

<0.002 400 1.2 <0.001 0.48 n/a <0.02 7.66 <0.001 <0.01 n/a

<0.002 430 1.4 <0.001 0.5 n/a <0.02 7.09 <0.001 <0.01 n/a

<0.002 400 1.2 <0.001 0.45 n/a <0.02 7.08 <0.001 <0.01 n/a

0.0016 440 2.1 0.00066 0.57 n/a <0.02 6.71 <0.001 <0.01 n/a

0.00071 510 2.2 0.00052 0.51 n/a <0.02 6.87 0.0007 <0.01 n/a

0.014 460 5.1(B) 0.00091(J) 0.6(B) <0.0002 0.29(R) 6.6 <0.001 <0.01 n/a

0.33(BO) 370 3.8 0.0018 0.75 <0.0002 0.022 6.6 0.00075(J) <0.001 n/a

n/a n/a n/a n/a n/a n/a n/a 6.8 n/a n/a n/a

0.0017(J) 400 2.5 0.00079(J) 0.63 n/a 0.011 7 0.0013 <0.001 n/a

n/a n/a n/a n/a n/a n/a n/a 6.9 n/a n/a n/a

0.0013(J) 420(B) 2.4 0.00028(J) 0.65 n/a 0.01 7 <0.001 <0.001 n/a

<0.005(J) 400 1.7 <0.002(J) 0.6 n/a 0.016 6.3 <0.002 <0.002 n/a

0.0105 420 3.42 0.00059(J) 0.658 n/a 0.163 6.8 <0.002 <0.002 n/a

n/a n/a n/a n/a n/a n/a 0.0804 7 n/a n/a n/a

0.00236(J) 407 1.72 <0.002 0.568 n/a 0.0109 6.8 <0.002 <0.002 n/a

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

0.00087(BJ) 428 1.37 <0.002 0.518 n/a 0.0135 7.7 <0.002 <0.002 n/a

n/a n/a n/a n/a n/a n/a n/a 6.93 n/a n/a n/a

0.000588(J) 381 1.64 <0.002 0.588 n/a 0.00354 6.9 <0.002 <0.002 n/a

0.00099(BJ) 401 1.51 <0.002 0.577 n/a <0.002 7.9 <0.002 <0.002 n/a

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 21 of 105

Page 214: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-19 3/8/2018

(cont.) 5/24/2018

11/12/2018

MW-20 downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

9/13/2011

3/13/2012

9/26/2012

3/6/2013

9/12/2013

11/20/2013

3/5/2014

6/9/2014

10/23/2014

4/21/2015

10/15/2015

4/13/2016

8/3/2016

12/20/2016

4/12/2017

6/14/2017

10/5/2017

12/1/2017

5/24/2018

11/13/2018

1/29/2019

Co

pp

er (

mg/

L)

Dis

solv

ed s

olid

s

(mg/

L)

Iro

n (

mg/

L)

Lead

(m

g/L)

Man

gan

ese

(mg/

L)

Mer

cury

(m

g/l)

Nic

kel (

mg/

L)

pH

(su

)

Sele

niu

m (

mg/

L)

Silv

er (

mg/

L)

Sod

ium

(m

g/L)

n/a n/a n/a n/a n/a n/a n/a 6.9 n/a n/a n/a

0.00118(BJ) 404 1.43 <0.002 0.666 n/a <0.002 6.8 <0.002 <0.002 n/a

0.000618(BJ) 387 1.42 0.000254(J) 0.619 n/a <0.002 7 <0.002 <0.002 n/a

<0.001 270 3.57 <0.0001 0.498 n/a 0.0042 6.77 <0.002 <0.0008 n/a

0.0013 318 2.99 <0.0005 0.391 n/a 0.00185 6.68 <0.0025 <0.0005 n/a

<0.002 300 3.1 <0.001 0.42 n/a <0.02 7.5 <0.001 <0.01 n/a

<0.002 310 3.5 <0.001 0.45 n/a <0.02 6.75 <0.001 <0.01 n/a

<0.002 320 3.1 <0.001 0.41 n/a <0.02 6.78 <0.001 <0.01 n/a

0.002 310 3.1 0.0008 0.4 n/a <0.02 6.18 <0.001 <0.01 n/a

0.0018 350 4.1 0.001 0.47 n/a <0.02 6.62 0.00047 <0.01 n/a

0.0068 300 5.4(B) 0.0054(R) 0.49(B) <0.0002 0.028(R) 6.3 <0.001 <0.01 n/a

0.0062(B) 330 6.3 0.00071(J) 0.77 <0.0002 0.015 6.4 0.0004(J) <0.001 n/a

n/a n/a n/a n/a n/a n/a n/a 6.6 n/a n/a n/a

0.0018(J) 280 2.6 0.001 0.47 n/a 0.005 6.8 0.0011 <0.001 n/a

n/a n/a n/a n/a n/a n/a n/a 6.7 n/a n/a n/a

<0.005 360 2.8 <0.002 0.53 n/a 0.006 n/a <0.002 <0.002 n/a

<0.005(J) 360 3.2 <0.002(J) 0.56 n/a 0.0044 6.2 <0.002 <0.002 n/a

0.00312(J) 310 2.36 0.000348(J) 0.443 n/a 0.00413 6.8 <0.002 <0.002 n/a

0.00304(J) 383 3.83 0.000483(J) 0.557 n/a 0.0109 6.5 <0.002 <0.002 n/a

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

0.00278(BJ) 382 4.48 0.000398(J) 0.579 n/a 0.00489 6 <0.002 <0.002 n/a

n/a n/a n/a n/a n/a n/a n/a 6.48 n/a n/a n/a

0.00157(J) 407 5.28 0.000367(J) 0.679 n/a 0.00198(J) 6.35 <0.002 <0.002 n/a

n/a 341 n/a n/a n/a n/a n/a n/a n/a n/a n/a

0.00101(BJ) 356 2.8 <0.002 0.626 n/a <0.002 7.2 <0.002 <0.002 n/a

0.000683(BJ) 339 2.45 <0.002 0.522 n/a <0.002 6.7 <0.002 <0.002 n/a

0.000554(BJ) 392 3.72 <0.002 0.732 n/a <0.002 6.4 <0.002 <0.002 n/a

n/a 373 n/a n/a n/a n/a n/a 6.5 n/a n/a n/a

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 22 of 105

Page 215: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-21 downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

9/13/2011

3/13/2012

9/26/2012

3/6/2013

9/12/2013

3/6/2014

10/8/2014

4/22/2015

10/14/2015

4/13/2016

12/20/2016

6/14/2017

11/29/2017

5/24/2018

11/13/2018

MW-22 downgradient

11/29/2017

3/8/2018

5/23/2018

8/20/2018

11/9/2018

Co

pp

er (

mg/

L)

Dis

solv

ed s

olid

s

(mg/

L)

Iro

n (

mg/

L)

Lead

(m

g/L)

Man

gan

ese

(mg/

L)

Mer

cury

(m

g/l)

Nic

kel (

mg/

L)

pH

(su

)

Sele

niu

m (

mg/

L)

Silv

er (

mg/

L)

Sod

ium

(m

g/L)

0.0006 377 0.748 <5E-05 0.257 n/a 0.0009 7.15 <0.001 <0.0004 n/a

<0.001 393 1.23 0.0005 0.435 n/a 0.00125 7.09 <0.0025 <0.0005 n/a

<0.002 400 1.4 <0.001 0.52 n/a <0.02 7.69 <0.001 <0.01 n/a

<0.002 440 1.5 <0.001 0.53 n/a <0.02 7.05 <0.001 <0.01 n/a

<0.002 400 1.4 <0.001 0.48 n/a <0.02 7.02 <0.001 <0.01 n/a

0.0017 420 1.9 0.0011 0.53 n/a 0.0069 6.76 <0.001 <0.01 n/a

0.0013 370 1.9 0.00062 0.49 n/a <0.02 6.88 <0.001 <0.01 n/a

0.0025 320 3.1(B) 0.0057(R) 0.45(B) <0.0002 0.019(J) 6.5 <0.001 <0.01 n/a

0.059(BO) 630 4.8 0.0023 1.5 <0.0002 0.024 6.4 0.00043(J) <0.001 n/a

0.0016(J) 510 2.7 0.00057(J) 1.1 n/a 0.0058 6.6 0.00097(J) <0.001 n/a

<0.002 380(B) 1.4 <0.001 0.57 n/a 0.0025 6.9 <0.001 <0.001 n/a

<0.005(J) 370 1.5 <0.002(J) 0.56 n/a <0.002(J) 7.2 <0.002 <0.002 n/a

0.00176(J) 468 2.48 0.000281(J) 0.916 n/a 0.028 6.7 <0.002 <0.002 n/a

0.00117(J) 330 1.48 0.000414(J) 0.472 n/a 0.00474 6.8 <0.002 <0.002 n/a

<0.005 349 1.34 0.000252(J) 0.482 n/a 0.00276 6.5 <0.002 <0.002 n/a

<0.005 454 2.8 <0.002 0.962 n/a 0.00176(J) 6.56 <0.002 <0.002 n/a

0.00113(BJ) 332 1.38 <0.002 0.503 n/a <0.002 7.3 <0.002 <0.002 n/a

0.000749(BJ) 372 1.78 0.00033(BJ) 0.6 n/a <0.002 6.7 <0.002 <0.002 n/a

<0.005 290 0.964 <0.002 0.491 n/a <0.002 6.7 <0.002 <0.002 n/a

0.00093(BJ) 207 0.78 <0.002 0.193 n/a <0.002 7.2 <0.002 <0.002 n/a

0.00109(J) 180 0.477 <0.002 0.207 n/a 0.000505(J) 6.9 <0.002 <0.002 n/a

0.000579(BJ) 226 0.553 <0.002 0.234 n/a <0.002 7.4 <0.002 <0.002 n/a

<0.005 236 0.499 <0.002 0.222 n/a <0.002 7.3 <0.002 <0.002 n/a

<0.005 212 0.392 0.000535(J) 0.234 n/a <0.002 7.5 <0.002 <0.002 n/a

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 23 of 105

Page 216: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

LEACHATEBLDGA downgradient

3/6/2013

9/11/2013

3/5/2014

10/9/2014

4/14/2015

4/16/2015

10/16/2015

4/13/2016

12/22/2016

6/15/2017

12/1/2017

5/25/2018

11/14/2018

LEACHATEBLDGB downgradient

3/6/2013

3/5/2014

10/9/2014

4/14/2015

4/16/2015

10/16/2015

4/13/2016

12/22/2016

6/15/2017

12/1/2017

5/25/2018

11/14/2018

LEACHATEBLDGC downgradient

9/11/2013

3/5/2014

10/9/2014

Co

pp

er (

mg/

L)

Dis

solv

ed s

olid

s

(mg/

L)

Iro

n (

mg/

L)

Lead

(m

g/L)

Man

gan

ese

(mg/

L)

Mer

cury

(m

g/l)

Nic

kel (

mg/

L)

pH

(su

)

Sele

niu

m (

mg/

L)

Silv

er (

mg/

L)

Sod

ium

(m

g/L)

0.014 4600 180 0.013 4.2 0.00065 0.11 7.5 0.018 <0.01 n/a

0.079 5200 7.2 0.0069 0.74 5.50E-05 0.14 7.4 0.032 <0.005 n/a

0.0043(J) 82 14 0.0038(J) 0.92 n/a 0.15 7.6 0.022 <0.005 n/a

0.0013(J) 5900(B) 7.3 <0.001 0.78 n/a 0.15 7.9 0.0028 <0.001 n/a

n/a n/a n/a n/a n/a n/a n/a 6.8 n/a n/a n/a

<0.045(J) 4500 43 <0.018(J) 5.7 n/a 0.18 n/a <0.018 <0.018 n/a

0.00596(J) 5500 12.3 <0.018 0.701 n/a 0.167 7.7 <0.018 <0.018 n/a

<0.045 5060 5.72 <0.018 0.758 n/a 0.14 n/a <0.018 <0.018 n/a

0.0331(BJ) 5500 30.5 0.0227 0.865 n/a 0.196 8.4 0.00449(J) <0.018 n/a

0.00167(J) 5240 5.81 0.0003(J) 0.614 n/a 0.144 7.2 0.00201 <0.002 n/a

0.0436 5620 5.62 0.000391(J) 0.679 n/a 0.166 8.1 0.00302 <0.002 n/a

0.0295 5960 22.9 0.0114 0.779 0.000492(J) 0.187 7.5 0.00289 <0.002 n/a

0.0134(B) 5220 5.34 0.000444(J) 0.515 n/a 0.159 n/a 0.00311 <0.002 n/a

0.14 1100 58 0.011 2.9 <0.0002 0.038 7 0.0045 <0.01 n/a

0.0018(J) 12000 4.3 0.00071(J) 2.3 n/a 0.036 7.5 0.0047 0.0027 n/a

0.034 1500(B) 8.8 0.00043(J) 1.7 n/a 0.044 7.5 0.00087(J) <0.001 n/a

n/a n/a n/a n/a n/a n/a n/a 6.9 n/a n/a n/a

0.037 1400 25 0.024 2 n/a 0.047 n/a <0.002 <0.002 n/a

0.018 1440 10.2 0.00914 1.28 n/a 0.045 n/a 0.000444(J) <0.002 n/a

0.0475 1460 10.4 0.00262 1.72 n/a 0.044 n/a 0.000388(J) <0.002 n/a

0.472 1620 18.6 0.0125 1.35 n/a 0.0483 8.3 0.000666(J)0.000348(J) n/a

0.00268(J) 1380 5.12 0.000914(J) 1.59 n/a 0.0457 6.61 0.000438(J) <0.002 n/a

1.74 1400 127 0.0168 1.95 n/a 0.0502 n/a 0.000449(J) <0.002 n/a

n/a 1320 50.1 n/a 1.73 n/a 0.0447 6.7 n/a <0.002 n/a

0.066(B) 1750 18.4 0.00813 1.03 n/a 0.0516 n/a 0.000437(J) <0.002 n/a

0.0023 1300 3.7 0.00038 1.3 <0.0002 0.014 7.4 0.0073 <0.001 n/a

0.00053(J) 1600 26 0.001 2.2 n/a 0.02 7 0.0072 <0.001 n/a

<0.002 2300(B) 2.1 <0.001 2 n/a 0.047 7.4 0.0012 <0.001 n/a

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 24 of 105

Page 217: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

LEACHATEBLDGC 4/14/2015

(cont.) 4/16/2015

10/16/2015

4/13/2016

12/22/2016

6/15/2017

12/1/2017

5/25/2018

11/14/2018

MW-6 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

MW-6R downgradient

9/23/1998

3/16/1999

9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

3/24/2004

Co

pp

er (

mg/

L)

Dis

solv

ed s

olid

s

(mg/

L)

Iro

n (

mg/

L)

Lead

(m

g/L)

Man

gan

ese

(mg/

L)

Mer

cury

(m

g/l)

Nic

kel (

mg/

L)

pH

(su

)

Sele

niu

m (

mg/

L)

Silv

er (

mg/

L)

Sod

ium

(m

g/L)

n/a n/a n/a n/a n/a n/a n/a 6.9 n/a n/a n/a

<0.005(J) 2000 25 <0.002 3 n/a 0.04 n/a <0.002(J) <0.002 n/a

0.00166(J) 2060 14.2 <0.002 2.21 n/a 0.0479 7.7 0.000643(J) <0.002 n/a

0.000731(J) 2240 8.4 <0.002 2.55 n/a 0.0434 n/a 0.000603(J) <0.002 n/a

0.00922 2390 116 0.000386(J) 3.01 n/a 0.0563 8 0.000959(J) <0.002 n/a

0.00054(J) 2830 10.4 <0.002 2.7 n/a 0.0576 6.72 0.000727(J) <0.002 n/a

0.0239 2370 20.1 0.000562(J) 2.48 n/a 0.0627 n/a 0.00082(J) <0.002 n/a

0.00384(BJ) 1990 11.7 0.000271(BJ) 2.6 n/a 0.0716 7 0.00102(J) <0.002 n/a

<0.005 2180 13.9 0.00033(J) 2.5 n/a 0.0786 n/a 0.000904(J) <0.002 n/a

<0.03 389 0.94 <0.015 <0.05 n/a <1 6.79 <0.005 <0.05 142

<0.03 377 17.4 0.0217 0.86 n/a <0.05 6.73 <0.005 <0.05 17.9

<0.03 366 2.51 <0.015 0.56 n/a <0.1 7.02 <0.005 <0.05 19.7

<0.03 368 0.98 <0.015 0.58 n/a <0.1 6.55 <0.005 <0.05 18.8

<0.03 362 1.37 <0.015 0.95 n/a <0.1 6.51 <0.008 <0.05 21.2

<0.03 382 2.33 0.033 0.79 n/a <0.05 6.85 <0.01 <0.05 13.8

<0.03 473 3.22 0.036 0.59 n/a <0.05 6.39 <0.01 <0.05 16.1

<0.03 467 2.95 <0.015 0.149 n/a <0.05 6.5 <0.02 <0.05 14.2

<0.005 395 1.26 <0.005 0.455 n/a <0.01 7.05 <0.01 <0.01 13.5

<0.005 403 2.66 <0.005 0.31 n/a <0.01 6.86 <0.01 <0.01 15.2

<0.005 404 3.19 <0.005 0.327 n/a <0.01 7.1 0.007 <0.01 14.2

<0.005 401 2.71 <0.005 0.24 n/a <0.01 7.05 <0.01 <0.01 14.1

<0.005 416 1.51 <0.005 0.26 n/a <0.01 6.84 <0.01 <0.01 17.2

<0.005 412 3.31 <0.005 0.24 n/a <0.01 6.95 <0.01 <0.01 14.07

<0.005 824 3.4 <0.005 2.77(O) n/a <0.01 6.65 <0.005 <0.01 13.9

<0.005 424 2.65 <0.005 0.421 n/a <0.01 6.86 <0.01 <0.01 14.4

<0.005 561 2.56 <0.005 1.38(O) n/a <0.01 6.68 <0.01 <0.01 16.8

0.0062 435 2.91 <0.005 0.346 n/a <0.01 6.9 <0.01 <0.01 16.9

<0.005 480 4.06 <0.005 0.281 n/a <0.01 6.95 <0.01 <0.01 16.2

<0.005 432 2.95 <0.005 0.351 n/a <0.01 6.73 <0.01 <0.01 18.1

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 25 of 105

Page 218: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-6R 9/14/2004

(cont.) 3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

9/28/2010

3/13/2012

9/26/2012

3/5/2014

6/9/2014

MW-9 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

3/14/2000

Co

pp

er (

mg/

L)

Dis

solv

ed s

olid

s

(mg/

L)

Iro

n (

mg/

L)

Lead

(m

g/L)

Man

gan

ese

(mg/

L)

Mer

cury

(m

g/l)

Nic

kel (

mg/

L)

pH

(su

)

Sele

niu

m (

mg/

L)

Silv

er (

mg/

L)

Sod

ium

(m

g/L)

<0.005 511 2.93 <0.005 0.407 n/a <0.01 6.81 <0.01 <0.01 n/a

<0.005 442 2.87 <0.005 0.355 n/a <0.01 6.9 <0.01 <0.01 n/a

<0.002 434 3.81 0.00233 0.243 n/a <0.01 6.67 <0.003 <0.00057 n/a

<0.002 428 3.22 <0.001 0.37 n/a 0.0414(O) 6.79 <0.003 <0.00057 n/a

<0.002 488 2.99 <0.001 0.346 n/a <0.005 6.69 <0.005 <0.00057 n/a

<0.002 417 2.05 <0.001 0.303 n/a <0.002 7 <0.003 <0.00057 n/a

<0.005 623 <0.05 <0.000424 0.319 n/a 0.00065 6.8 <0.00356 <0.000434 n/a

0.0022 495 <10 <0.0005 0.349 n/a 0.0033 6.91 <0.0178 <0.00125 n/a

0.00188 545 3.86 <0.0002 0.372 n/a 0.00066 7 <0.001 <0.0002 n/a

0.00046 502 5.26 0.00074 0.33 n/a 0.000178 7.33 <0.001 <0.0002 n/a

0.00186 535 10.1 2.00E-05 0.346 n/a 0.00048 6.5 <0.001 <0.0002 n/a

<0.0003 459 3.01 <0.0001 0.654 n/a 0.0068 6.73 <0.002 <0.0008 n/a

<0.0003 484 3.9 <0.0001 0.37 n/a 0.0012 7.21 <0.002 <0.0008 n/a

0.0012 510 4.6 0.00024 0.44 n/a <0.02 6.72 0.00057 <0.01 n/a

<0.002 580 4.8 <0.001 0.45 n/a <0.02 6.76 <0.001 <0.01 n/a

0.00089 420 3.6 0.0022 0.44 n/a 0.0091 6.8 0.0017 <0.001 n/a

n/a n/a n/a n/a n/a n/a n/a 6.8 n/a n/a n/a

<0.03 345 1.08 <0.015 0.31 n/a <0.1 7.2 <0.005 <0.05 217

<0.03 332 1.06 <0.015 0.29 n/a <0.05 7.05 <0.005 <0.05 19.4

<0.03 318 0.77 <0.015 0.23 n/a <0.1 7.45 <0.005 <0.05 20.7

<0.03 309 0.91 <0.015 0.22 n/a <0.1 6.87 <0.005 <0.05 20.9

<0.03 315 1.11 <0.015 0.19 n/a <0.1 6.87 <0.008 <0.05 17.1

<0.03 350 1.03 0.029 0.23 n/a <0.05 7.17 <0.01 <0.05 17.5

<0.03 335 0.78 0.031 0.25 n/a <0.05 6.75 <0.01 <0.05 17.9

<0.03 333 1.42 <0.015 0.247 n/a <0.05 7.04 <0.02 <0.05 16.3

<0.005 310 1.56 <0.005 0.25 n/a <0.01 7.01 <0.01 <0.01 15.1

<0.005 332 1.12 <0.005 0.188 n/a <0.01 7.03 <0.01 <0.01 13.2

<0.005 385 1.55 <0.005 0.18 n/a <0.01 6.64 <0.01 <0.01 14.9

<0.005 317 1.65 <0.005 0.176 n/a <0.01 7.27 <0.01 <0.01 13.8

<0.005 336 1.45 <0.005 0.092 n/a <0.01 7.25 <0.01 <0.01 13.1

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 26 of 105

Page 219: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-9 9/20/2000

(cont.) 3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

3/24/2004

9/14/2004

3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

MW-14 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

Co

pp

er (

mg/

L)

Dis

solv

ed s

olid

s

(mg/

L)

Iro

n (

mg/

L)

Lead

(m

g/L)

Man

gan

ese

(mg/

L)

Mer

cury

(m

g/l)

Nic

kel (

mg/

L)

pH

(su

)

Sele

niu

m (

mg/

L)

Silv

er (

mg/

L)

Sod

ium

(m

g/L)

<0.005 392 0.58 <0.005 0.15 n/a <0.01 6.99 <0.01 <0.01 19.4

<0.005 365 1.91 <0.005 0.16 n/a <0.01 7.12 <0.01 <0.01 16.77

<0.005 325 1.33 <0.005 0.187 n/a <0.01 7.02 <0.005 <0.01 14.8

<0.005 403 1.5 <0.005 0.224 n/a <0.01 6.98 <0.01 <0.01 16.6

<0.005 362 1.56 <0.005 0.197 n/a <0.01 6.9 <0.01 <0.01 18.3

<0.005 376 1.682 <0.005 0.181 n/a <0.01 7.01 <0.01 <0.01 16

0.0404 351 2.35 <0.005 0.098 n/a <0.01 7.16 <0.01 <0.01 15.3

<0.005 381 1.5 <0.005 0.235 n/a <0.01 6.92 <0.01 <0.01 15.5

<0.005 326 1.62 <0.005 0.224 n/a <0.01 6.9 <0.01 <0.01 n/a

<0.005 343 1.22 <0.005 0.164 n/a <0.01 7.02 <0.01 <0.01 n/a

<0.002 357 1.45 <0.001 0.146 n/a <0.01 6.95 <0.003 <0.00057 n/a

<0.002 386 1.69 0.00214 0.208 n/a 0.0234 6.98 <0.003 <0.00057 n/a

0.00685 373 1.01 <0.001 0.225 n/a <0.005 6.9 <0.005 <0.00057 n/a

<0.002 285 0.601 <0.001 0.126 n/a <0.002 7.15 <0.003 <0.00057 n/a

<0.0005 389 <0.25 <0.000424 0.244 n/a <0.000128 7.02 <0.00356 <0.000434 n/a

0.00115 285 <10 <0.0005 0.16 n/a 0.0005 7.26 <0.0178 <0.00125 n/a

0.00024 314 1.27 <0.0002 0.199 n/a 0.00056 7.19 <0.001 <0.0002 n/a

0.00396 314 1.43 0.00032 0.181 n/a 0.0583 7.24 <0.001 0.00592 n/a

0.00244 293 1.07 0.00012 0.185 n/a 0.0016 6.79 <0.001 <0.0002 n/a

<0.0003 280 0.975 <0.0001 0.216 n/a 0.0024 7.13 <0.002 <0.0008 n/a

<0.03 601 1.32 <0.015 0.27 n/a <0.1 6.98 <0.005 <0.05 104

<0.03 580 2.45 0.025 0.33 n/a <0.05 6.75 <0.005 <0.05 26

<0.03 543 1.54 <0.015 0.26 n/a <0.1 7.03 <0.005 <0.05 23.3

<0.03 546 8.35 <0.015 0.44 n/a 0.52 6.81 <0.005 <0.05 29.2

<0.03 583 0.92 0.03 0.29 n/a <0.1 6.79 <0.008 <0.05 27.4

<0.03 548 0.61 0.022 0.74 n/a <0.05 6.85 <0.01 <0.05 17.1

<0.03 570 2.02 0.041 0.25 n/a <0.05 6.35 <0.01 <0.05 17.9

<0.03 636 1.84 <0.015 0.305 n/a <0.05 6.85 <0.02 <0.05 17.2

<0.005 597 0.16 <0.005 0.22 n/a <0.01 6.77 <0.01 <0.01 15.4

<0.005 578 0.106 <0.005 0.218 n/a <0.01 6.84 <0.01 <0.01 13.2

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 27 of 105

Page 220: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-14 3/16/1999

(cont.) 9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

3/24/2004

MW-16 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

Co

pp

er (

mg/

L)

Dis

solv

ed s

olid

s

(mg/

L)

Iro

n (

mg/

L)

Lead

(m

g/L)

Man

gan

ese

(mg/

L)

Mer

cury

(m

g/l)

Nic

kel (

mg/

L)

pH

(su

)

Sele

niu

m (

mg/

L)

Silv

er (

mg/

L)

Sod

ium

(m

g/L)

<0.005 534 0.05 <0.005 0.18 n/a <0.01 6.65 <0.01 <0.01 14.2

<0.005 534 0.24 <0.005 0.194 n/a <0.01 6.91 0.01 <0.01 14.6

<0.005 499 0.19 <0.005 0.099 n/a <0.01 6.95 <0.01 <0.01 12.7

<0.005 540 <0.03 <0.005 0.15 n/a <0.01 6.76 <0.01 <0.01 17.9

<0.005 527 0.1 <0.005 0.13 n/a <0.01 6.93 <0.01 <0.01 14.84

<0.005 555 0.248 <0.005 0.224 n/a <0.01 6.8 <0.005 <0.01 13.9

<0.005 550 0.146 <0.005 0.226 n/a <0.01 6.79 <0.01 <0.01 14.5

<0.005 545 0.317 <0.005 0.272 n/a <0.01 6.67 <0.01 <0.01 15.2

<0.005 554 0.272 <0.005 0.219 n/a <0.01 6.91 <0.01 <0.01 39.1

<0.005 556 0.364 <0.005 0.153 n/a <0.01 6.78 <0.01 <0.01 14.18

<0.005 556 0.307 <0.005 0.251 n/a <0.01 6.65 <0.01 <0.01 15.8

<0.03 390 1.94 <0.015 0.72 n/a <0.1 7.23 <0.005 <0.05 233

0.03 1 0.05 0.015 0.05 n/a 0.05 n/a 0.005 0.05 1

<0.03 616 5.93(R) <0.015 1.17(R) n/a <0.1 6.92 <0.005 <0.05 19.4

<0.03 615 6.55(R) <0.015 1.18(R) n/a <0.1 6.49 <0.005 <0.05 23.3

<0.03 320 2.87 <0.015 0.39 n/a <0.1 7.09 <0.008 <0.05 24.8

<0.03 331 1.16 0.018 0.38 n/a <0.05 6.94 <0.01 <0.05 11.3

<0.03 345 2.31 0.026 0.38 n/a <0.05 6.95 <0.01 <0.05 13.2

<0.03 379 1.72 <0.015 0.443 n/a <0.05 7.07 <0.02 <0.05 25.1

<0.005 370 1.37 <0.005 0.46 n/a <0.01 6.89 <0.01 <0.01 12

<0.005 517 2.17 <0.005 0.524 n/a <0.01 7.05 <0.01 <0.01 10.6

<0.005 416 1.62 <0.005 0.45 n/a <0.01 6.68 <0.01 <0.01 11.6

<0.005 540 2.3 <0.005 0.609 n/a <0.01 7.04 <0.01 <0.01 12.5

<0.005 365 1.49 <0.005 0.35 n/a <0.01 7.14 <0.01 <0.01 9.71

<0.005 384 0.42 <0.005 0.34 n/a <0.01 6.95 <0.01 <0.01 15

<0.005 327 1.5 <0.005 0.31 n/a <0.01 7.07 <0.01 <0.01 10.99

<0.005 341 1.49 <0.005 0.441 n/a <0.01 6.95 <0.005 <0.01 11

<0.005 336 1.11 <0.005 0.345 n/a <0.01 6.97 <0.01 <0.01 10.5

<0.005 393 1.45 <0.005 0.423 n/a <0.01 6.88 <0.01 <0.01 13.5

<0.005 400 1.569 <0.005 0.448 n/a <0.01 7.01 <0.01 <0.01 14.1

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 28 of 105

Page 221: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-16 9/17/2003

(cont.) 3/24/2004

9/14/2004

3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

MW-17 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

Co

pp

er (

mg/

L)

Dis

solv

ed s

olid

s

(mg/

L)

Iro

n (

mg/

L)

Lead

(m

g/L)

Man

gan

ese

(mg/

L)

Mer

cury

(m

g/l)

Nic

kel (

mg/

L)

pH

(su

)

Sele

niu

m (

mg/

L)

Silv

er (

mg/

L)

Sod

ium

(m

g/L)

<0.005 380 2.28 <0.005 0.362 n/a <0.01 6.91 <0.01 <0.01 12.9

<0.005 419 1.67 <0.005 0.542 n/a <0.01 6.7 <0.01 <0.01 15.3

<0.005 429 1.61 <0.005 0.589 n/a <0.01 6.77 <0.01 <0.01 n/a

<0.005 440 1.78 <0.005 0.563 n/a <0.01 6.85 <0.01 <0.01 n/a

<0.002 325 1.74 <0.001 0.348 n/a <0.01 6.72 <0.003 <0.00057 n/a

<0.002 372 1.84 <0.001 0.454 n/a 0.0463 6.76 <0.003 <0.00057 n/a

<0.002 380 1.51 <0.001 0.496 n/a <0.005 6.7 <0.005 <0.00057 n/a

<0.002 317 0.996 <0.001 0.384 n/a <0.002 7.01 <0.003 <0.00057 n/a

<0.0005 382 <0.25 <0.000424 0.405 n/a 0.00075 7.01 <0.00356 <0.000434 n/a

0.001 399 <10 <0.0005 0.475 n/a 0.0027 6.97 <0.0178 <0.00125 n/a

0.00134 457 2.06 <0.0002 0.587 n/a 0.00062 6.91 <0.001 <0.0002 n/a

0.00626 363 5.17(R) 0.00284 0.506 n/a 0.0282 7.04 <0.001 0.00044 n/a

0.00274 364 1.48 6.00E-05 0.427 n/a 0.00106 6.44 <0.001 <0.0002 n/a

0.0022 368 2.14 <0.0001 0.546 n/a 0.0021 6.86 <0.002 <0.0008 n/a

<0.03 839 1.47 <0.015 0.51 n/a <0.1 6.92 <0.005 <0.05 86.2

<0.03 641 11.4 0.017 0.12 n/a <0.05 6.38 <0.005 <0.05 30

<0.03 552 7.24 <0.015 0.93 n/a <0.1 6.63 <0.005 <0.05 29.3

<0.03 469 5.93 <0.015 0.78 n/a <0.1 6.49 <0.005 <0.05 30.2

<0.03 502 6.93 0.024 0.6 n/a <0.1 6.9 <0.008 <0.05 31.1

<0.03 460 0.93 0.025 0.29 n/a <0.05 6.53 <0.01 <0.05 23.3

<0.03 481 4.18 0.036 0.23 n/a <0.05 6.42 <0.01 <0.05 22.6

<0.03 467 2.89 <0.015 0.196 n/a <0.05 6.84 <0.02 <0.05 21.6

<0.005 450 2.56 <0.005 0.15 n/a <0.01 6.75 <0.01 <0.01 19

<0.005 497 1.89 <0.005 0.129 n/a <0.01 6.76 <0.01 <0.01 16.2

<0.005 526 2.64 <0.005 0.13 n/a <0.01 6.73 <0.01 <0.01 18.8

<0.005 487 3.52 <0.005 0.114 n/a <0.01 7.01 <0.01 <0.01 17.9

<0.005 422 7.01 <0.005 <0.05 n/a <0.01 6.92 <0.01 <0.01 18.3

<0.005 491 1.59 <0.005 0.09 n/a <0.01 6.81 <0.01 <0.01 22.1

<0.005 532 1.28 <0.005 0.08 n/a <0.01 6.87 <0.01 <0.01 18.89

<0.005 492 3.19 <0.005 0.122 n/a <0.01 6.8 <0.005 <0.01 16.6

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 29 of 105

Page 222: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-17 3/27/2002

(cont.) 9/25/2002

4/1/2003

9/17/2003

Co

pp

er (

mg/

L)

Dis

solv

ed s

olid

s

(mg/

L)

Iro

n (

mg/

L)

Lead

(m

g/L)

Man

gan

ese

(mg/

L)

Mer

cury

(m

g/l)

Nic

kel (

mg/

L)

pH

(su

)

Sele

niu

m (

mg/

L)

Silv

er (

mg/

L)

Sod

ium

(m

g/L)

<0.005 519 1.87 <0.005 0.164 n/a <0.01 6.8 <0.01 <0.01 18.1

<0.005 524 2.22 <0.005 0.122 n/a <0.01 6.69 <0.01 <0.01 17.7

0.0056 535 3.863 <0.005 0.083 n/a <0.01 6.81 <0.01 <0.01 19.3

<0.005 551 4.5 <0.005 <0.05 n/a <0.01 6.82 0.00848 <0.01 17.8

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 30 of 105

Page 223: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-8 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

3/24/2004

9/14/2004

3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

Spec

ific

con

du

ctan

ce

(um

ho

s/cm

)

Sulf

ate

(mg/

L)

Tem

per

atu

re (

C)

Tetr

ach

loro

eth

ene

(mg/

l)

Thal

lium

(m

g/L)

TOC

[to

tal o

rgan

ic

carb

on

] (m

g/L)

Tric

hlo

roet

hen

e

(mg/

l)

Turb

idit

y (N

TU)

Van

adiu

m (

mg/

L)

Zin

c (m

g/L)

Ace

ton

e (u

g/L)

590 66.1 18.2 <0.001 <0.002 n/a <0.0005 2.32 <0.4 <0.05 <5

580 114 20.3 <0.001 <0.002 n/a <0.0005 2.4 <0.4 <0.05 <5

570 65.6 21.6 <0.001 <0.002 n/a <0.0005 4.37 <0.4 <0.01 <5

620 69.9 21.3 <0.001 <0.002 n/a <0.0005 2.77 <0.4 <0.01 <5

550 61.6 15.7 <0.001 <0.002 n/a <0.0005 1.17 <0.4 <0.01 <5

575 50.7 20.5 <0.001 0.004 n/a <0.0005 6.38 <0.4 <0.01 <5

580 68 15.1 <0.001 <0.002 n/a <0.0005 23.1 <0.1 0.06 <5

650 54 16.4 <0.001 <0.002 n/a <0.0005 3.62 <0.1 0.013 <5

510 43.8 12.7 <0.0005 <0.001 n/a <0.0005 1.58 <0.4 <0.03 <5

690 46 16.7 <0.0005 <0.001 n/a <0.0005 2.27 <0.4 <0.03 <5

580 41.4 18.8 <0.0005 <0.001 n/a <0.0005 2.32 <0.4 <0.03 <5

593 43.9 19.3 <0.0005 <0.001 n/a <0.0005 0.34 <0.4 <0.03 <5

646 41 17.3 <0.0005 <0.001 n/a <0.0005 0.1 <0.4 <0.03 <5

614 40.3 18.5 <0.0005 <0.001 n/a <0.0005 <1 <0.4 <0.03 <5

577 48.3 18.6 <0.0005 <0.001 n/a <0.0005 0.21 <0.4 <0.03 <5

557 39.9 19.2 <0.0005 <0.001 n/a <0.0005 0.2 <0.4 <0.03 <5

564 43.4 16.1 <0.0005 <0.001 n/a <0.0005 0.6 <0.4 <0.03 <5

555 42.1 18.1 <0.0005 <0.001 n/a <0.0005 0.2 <0.4 <0.03 <5

572 45.2 18.3 <0.0005 <0.001 n/a <0.0005 0.29 <0.4 <0.03 <5

617 47.2 21.5 <0.0005 <0.001 n/a <0.0005 1.68 <0.4 <0.03 <5

598 38.4 18.6 <0.0005 <0.001 n/a <0.0005 0.3 <0.4 <0.03 <5

577 36.7 22.4 <0.0005 <0.001 <1 <0.0005 0.86 <0.4 <0.03 <5

604 42.5 12 <0.0005 <0.001 2.1 <0.0005 0.34 <0.4 <0.03 <5

0.25 <0.002(R) n/a <7E-05 <0.01 n/a <0.00011 n/a <5 <5 <0.5

567 49.7 16.5 <0.00025 <0.001 <1 <0.00025 0.21 <0.002 <0.01 <10

567 65.5 18.1 <0.00025 <0.01 <0.5 <0.00025 0.3 <0.002 <0.01 <10

556 46.3 15.8 <0.00025 <0.001 1.64 <0.00025 0.25 <0.002 <0.01 <10

585 60.9 23 <0.00025 <0.00174 <1 <0.00025 0.82 <0.01 <0.0025 <10

580 44.8 18.3 <0.00025 <0.00075 <1 <0.00025 0.47 <0.05 <0.025 <10

435 34.8 24.8 <0.00025 <0.0002 1.39 <0.00025 0.91 <0.02 <0.01 <10

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 31 of 105

Page 224: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-8 3/17/2009

(cont.) 10/7/2009

3/16/2010

9/28/2010

9/26/2012

3/5/2014

10/16/2015

6/15/2017

MW-9R downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

9/13/2011

3/13/2012

9/26/2012

3/6/2013

9/12/2013

3/5/2014

10/9/2014

4/22/2015

11/12/2015

11/29/2017

MW-9R2 downgradient

5/25/2018

11/13/2018

MW-14R upgradient

9/14/2004

3/9/2005

9/28/2005

3/15/2006

Spec

ific

con

du

ctan

ce

(um

ho

s/cm

)

Sulf

ate

(mg/

L)

Tem

per

atu

re (

C)

Tetr

ach

loro

eth

ene

(mg/

l)

Thal

lium

(m

g/L)

TOC

[to

tal o

rgan

ic

carb

on

] (m

g/L)

Tric

hlo

roet

hen

e

(mg/

l)

Turb

idit

y (N

TU)

Van

adiu

m (

mg/

L)

Zin

c (m

g/L)

Ace

ton

e (u

g/L)

696 80.6 19.6 <0.00025 <0.0002 <1 <0.00025 63.1 <0.02 <0.01 <10

625 48 21.3 <0.00025 <0.0002 1.01 <0.00025 3.35 <0.02 0.0145 <10

591 37.5 19.6 <0.00025 <0.0005 <1 <0.00025 5.95 <0.0005 <0.005 <10

128.5 39.8 22.6 <0.00025 <0.0005 <1 <0.00025 7.54 <0.001 <0.005 <10

584 34 22 <0.001 <0.001 2.6 <0.001 27.3 <0.01 0.0033 <50

525 41 6.8 <0.001 <0.001 0.47(J) <0.001 9 0.00034(J) 0.0082(J) <50

540 25.2 22.8 <0.001 <0.002 1.07 <0.001 4.5 0.000469(J) 0.0215(J) <50

521 24.1 27.93 <0.001 <0.002 0.64(J) <0.001 3.22 0.000204(J) 0.0157(J) <50

129.5 36.7 21.4 <0.00025 <0.0005 <1 <0.00025 1.97 <0.001 <0.005 <10

525 13 18.3 <0.001 <0.0005 <1 <0.001 4.98 <0.05 <0.025 <10

599 45 16.4 <0.001 <0.001 <1 <0.001 5.02 <0.01 <0.01 <50

664 74 23.2 <0.001 <0.001 64(O) <0.001 6.18 <0.01 <0.01 <50

495 28 23.1 <0.001 <0.001 <1 <0.001 5.01 <0.01 <0.01 <50

543 14 20.14 <0.001 <0.001 0.84 <0.001 9.89 0.0025 0.0092 <50

522 16 23.4 <0.001 <0.001 0.55 <0.001 16.4 0.0024 0.0086 <50

500 0.65(BJ) 10.1 <0.001 0.00019(J) 3.9 <0.001 307 0.016(J) 0.027 <50

663 46 32.9 <0.001 <0.001 2 <0.001 59 0.0041 0.066(BR) <50

471 20 1.6 0.00044(J) <0.001 0.71(J) <0.001 10 0.00056(J) 0.0056(J) <50

529 52 23.1 <0.001 <0.001 0.53(J) <0.001 9.7 0.00032(J) 0.014 <50

600.5 13 21.7 <0.001 <0.002 <1(J) <0.001 9.6 <0.005(J) <0.025(J) <50

496 15.1 20.1 <0.001 <0.002 0.63(J) <0.001 9.26 0.000696(J) 0.0938 <50

394 14.7 19.1 <0.001 <0.002 1.28 <0.001 2.2 0.000264(J) <0.025 <50

370 21.6 22.9 <0.001 <0.002 0.861(BJ) <0.001 1 0.000208(J) <0.025 <50

n/a 17.2 n/a <0.001 <0.002 0.649(J) <0.001 0.6 <0.005 <0.025 <50

892 136 19.9 <0.0005 <0.001 <1 <0.0005 0.56 <0.4 <0.03 <5

927 162 12.7 <0.0005 <0.001 2.46 <0.0005 0.69 <0.4 <0.03 <5

904 154 18.5 <5E-05 <0.001 1.07 <5E-05 0.87 <0.002 <0.01 <5

899 167 17.7 <0.00025 <0.001 19(O) <0.00025 0.95 <0.002 <0.01 <10

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 32 of 105

Page 225: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-14R 9/20/2006

(cont.) 3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

9/28/2010

3/9/2011

9/13/2011

3/13/2012

9/26/2012

3/5/2013

9/10/2013

3/4/2014

10/6/2014

4/14/2015

10/14/2015

4/12/2016

8/2/2016

12/20/2016

6/13/2017

11/29/2017

5/23/2018

11/12/2018

MW-16R downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

Spec

ific

con

du

ctan

ce

(um

ho

s/cm

)

Sulf

ate

(mg/

L)

Tem

per

atu

re (

C)

Tetr

ach

loro

eth

ene

(mg/

l)

Thal

lium

(m

g/L)

TOC

[to

tal o

rgan

ic

carb

on

] (m

g/L)

Tric

hlo

roet

hen

e

(mg/

l)

Turb

idit

y (N

TU)

Van

adiu

m (

mg/

L)

Zin

c (m

g/L)

Ace

ton

e (u

g/L)

848 121 17.2 <0.00025 <0.01 <0.5 <0.00025 1.19 <0.002 <0.01 <10

850 94.7 13.4 <0.00025 <0.001 1.14 <0.00025 1.24 <0.002 <0.01 <10

862 104 20.1 <0.00025 <0.00174 1.04 <0.00025 2.22 <0.01 <0.0025 <10

872 105 19.7 <0.00025 <0.00075 <1 <0.00025 3.11 <0.05 <0.025 <10

581 86 18.5 <0.00025 <0.0002 2.48 <0.00025 4.65 <0.02 0.0106 <10

745 91.8 18 <0.00025 <0.0002 <1 <0.00025 38.5 <0.02 <0.01 <10

919 106 18.7 <0.00025 <0.0002 <1 <0.00025 4.44 <0.02 0.0167 <10

973 84.4 18.4 <0.00025 <0.0005 <1 <0.00025 1.88 <0.0005 <0.005 <10

131.2 85.4 20.1 <0.00025 <0.0005 <1 <0.00025 1.28 <0.001 <0.005 <10

972 94 18 <0.001 <0.001 <1 <0.001 3.53 <0.01 <0.01 <50

935 85 22.4 <0.001 <0.001 <1 <0.001 3.66 <0.01 <0.01 <50

1001 84 22.5 <0.001 <0.001 0.92 <0.001 4.55 <0.01 0.0039 <50

978 74 22.6 <0.001 <0.001 <1 <0.001 5.42 <0.01 <0.01 <50

896 72(B) 16.4 <0.001 <0.001 2.7 <0.001 8 <0.01 0.0037(J) <50

935 69 23.8 <0.001 <0.001 0.58(J) <0.001 5 0.00051(J) 0.0034(JB) <50

916 77 14.5 0.00063(J) <0.001 0.47(J) <0.001 10 0.00049(J) 0.0054(J) <50

1059 81 20.3 <0.001 <0.001 0.68(J) <0.001 29.5 0.002(J) 0.094 <50

725 76 n/a <0.001 <0.002 4.5 <0.001 5 0.00099(B) <0.025(J) <50

993 74.1 22.2 <0.001 <0.002 1.6 <0.001 9.2 0.000677(J) 0.00291(J) <50

1053 77.8 18.8 <0.001 <0.002 0.595(J) <0.001 8.3 0.000991(J) 0.0307 <50

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

914 73.7 13.8 <0.001 <0.002 1.37 <0.001 8.6 0.000317(J) 0.00632(J) <50

987 73.4 25.43 <0.001 <0.002 0.552(J) <0.001 9.5 0.00026(J) 0.0549 <50

970 75.4 19 <0.001 <0.002 0.882(J) <0.001 9.9 <0.005 <0.025 <50

971 69.1 21.6 <0.001 <0.002 0.562(BJ) <0.001 15 <0.005 <0.025 <50

n/a 64.1 n/a <0.001 <0.002 0.937(J) <0.001 20.1 <0.005 <0.025 <50

94.1 32.1 18.5 <0.00025 <0.0005 <1 <0.00025 1.88 <0.001 <0.005 <10

629 22.4 18.2 <0.001 <0.0005 <1 <0.001 3.5 <0.05 <0.025 <10

503 24 15.8 <0.001 <0.001 <1 <0.001 3.54 <0.01 <0.01 <50

537 25 21.8 <0.001 <0.001 46(O) <0.001 4.34 <0.01 <0.01 <50

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 33 of 105

Page 226: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-16R 9/13/2011

(cont.) 3/13/2012

9/26/2012

3/5/2013

9/11/2013

3/4/2014

10/23/2014

4/21/2015

10/16/2015

4/14/2016

12/20/2016

6/15/2017

12/1/2017

3/8/2018

5/24/2018

11/12/2018

MW-17R upgradient

9/14/2004

3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

9/28/2010

3/9/2011

Spec

ific

con

du

ctan

ce

(um

ho

s/cm

)

Sulf

ate

(mg/

L)

Tem

per

atu

re (

C)

Tetr

ach

loro

eth

ene

(mg/

l)

Thal

lium

(m

g/L)

TOC

[to

tal o

rgan

ic

carb

on

] (m

g/L)

Tric

hlo

roet

hen

e

(mg/

l)

Turb

idit

y (N

TU)

Van

adiu

m (

mg/

L)

Zin

c (m

g/L)

Ace

ton

e (u

g/L)

505 25 22 <0.001 <0.001 1 <0.001 4.26 <0.01 <0.01 <50

581 26 22.3 <0.001 <0.001 0.99 <0.001 9.7 <0.01 0.0045 <50

471 20 21.7 <0.001 <0.001 0.44 <0.001 23.9 0.0024 0.0035 <50

475 22(B) 18.1 <0.001 <0.001 3.1 <0.001 846 0.023(R) 0.061 <50

532 28 26.9 <0.001 <0.001 0.83(J) <0.001 9 0.0066 0.11(B) <50

434 20 12.9 <0.001 <0.001 0.51(J) <0.001 9 0.0022 0.0079(J) <50

n/a 22 n/a <0.001 <0.002 52(O) <0.001 n/a <0.005 0.015(J) <50

224.3 21.3 23.9 <0.001 <0.002 <1(J) <0.001 9.4 <0.005(J) <0.025 <50

532 21.5 20.9 <0.001 <0.002 1.08 <0.001 9.3 0.000994(J) 0.0682 <50

471 20.3 22.8 <0.001 <0.002 0.571(J) <0.001 5.7 0.000773(J) 0.0082(J) <50

494 20.8 21.5 <0.001 <0.002 0.967(J) <0.001 8.5 0.000687(J) <0.025 <50

512 19.5 26.23 <0.001 <0.002 0.58(J) <0.001 9.68 0.000596(J) 0.0111(J) <50

541 21.4 22.2 <0.001 <0.002 0.753(J) <0.001 2.6 0.000377(J) <0.025 <50

522 n/a 21.8 n/a n/a n/a n/a 0.9 n/a n/a n/a

531 22.6 26.4 <0.001 <0.002 0.654(BJ) <0.001 1.4 0.000286(J) <0.025 <50

n/a 17.3 n/a <0.001 <0.002 0.702(J) <0.001 1.9 0.000214(J) <0.025 <50

575 58.5 19.9 <0.0005 <0.001 <1 <0.0005 0.73 <0.4 <0.03 <5

557 58.4 14.4 <0.0005 <0.001 1.36 <0.0005 0.57 <0.4 <0.03 <5

545 61.6 18.7 <5E-05 <0.001 3.59 <5E-05 0.5 <0.002 <0.01 <5

530 57.8 18.9 <0.00025 <0.001 <1 <0.00025 1.07 <0.002 <0.01 <10

514 58.1 17.2 <0.00025 <0.01 <0.5 <0.00025 1.29 <0.002 <0.01 <10

513 47.7 14.1 <0.00025 <0.001 1.13 <0.00025 2.56 <0.002 <0.01 <10

521 47.4 19.4 <0.00025 <0.00174 <1 <0.00025 1.83 <0.01 <0.0025 <10

494 45.2 18.1 <0.00025 <0.00075 <1 <0.00025 30.6 <0.05 <0.025 <10

381 38.3 22.2 <0.00025 <0.0002 1.02 <0.00025 16.9 <0.02 <0.01 <10

485 36.9 19.6 <0.00025 <0.0002 <1 <0.00025 52 <0.02 <0.01 <10

512 43.5 18.9 <0.00025 <0.0002 <1 <0.00025 4.98 <0.02 0.0127 <10

525 33.7 19.6 <0.00025 <0.0005 <1 <0.00025 4.09 <0.0005 <0.005 <10

117.7 31.9 19.7 <0.00025 <0.0005 <1 <0.00025 2.59 <0.001 <0.005 <10

491 34 16.2 <0.001 <0.001 <1 <0.001 4.4 <0.01 <0.01 <50

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 34 of 105

Page 227: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-17R 9/13/2011

(cont.) 3/13/2012

9/26/2012

3/5/2013

9/11/2013

3/5/2014

10/9/2014

4/21/2015

10/14/2015

4/12/2016

8/2/2016

12/20/2016

4/12/2017

6/14/2017

11/29/2017

5/23/2018

8/20/2018

11/9/2018

MW-18 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

Spec

ific

con

du

ctan

ce

(um

ho

s/cm

)

Sulf

ate

(mg/

L)

Tem

per

atu

re (

C)

Tetr

ach

loro

eth

ene

(mg/

l)

Thal

lium

(m

g/L)

TOC

[to

tal o

rgan

ic

carb

on

] (m

g/L)

Tric

hlo

roet

hen

e

(mg/

l)

Turb

idit

y (N

TU)

Van

adiu

m (

mg/

L)

Zin

c (m

g/L)

Ace

ton

e (u

g/L)

491 36 22.1 <0.001 <0.001 <1 <0.001 4.51 <0.01 <0.01 <50

525 36 21.74 <0.001 <0.001 0.61 <0.001 23.2 <0.01 0.0049 <50

513 37 20.6 <0.001 <0.001 0.34 <0.001 99.1 <0.01 0.0038 <50

477 30(B) 14.02 <0.001 <0.001 0.48(J) <0.001 8 <0.01 <0.01 <50

524 33 23.4 <0.001 <0.001 0.85(J) <0.001 86 0.0044 0.0048(JB) <50

503 33 14.8 0.00046(J) <0.001 0.23(J) <0.001 9 <0.002 <0.01 <50

557 34 22 <0.001 <0.001 0.76(J) <0.001 9.7 <0.002 0.015 <50

235.8 33.8 19.5 <0.001 <0.002 <1(J) <0.001 9 <0.005(J) <0.025 <50

584 34.8 n/a <0.001 <0.002 0.94(J) <0.001 6.9 0.000551(J) <0.025 <50

587 35.8 20.4 <0.001 <0.002 0.33(J) <0.001 9.5 0.000619(J) 0.0141(J) <50

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

506 33.1 18.1 <0.001 <0.002 0.647(J) <0.001 8.7 0.000292(J) 0.0288 <50

543 n/a 23.74 n/a n/a n/a n/a 7.15 n/a 0.0395 n/a

537 32.9 22.58 <0.001 <0.002 0.343(J) <0.001 9.33 <0.005 0.0115(J) <50

540 31.9 18.7 <0.001 <0.002 0.53(J) <0.001 8.2 <0.005 <0.025 <50

591 30.1 22.5 <0.001 <0.002 0.598(BJ) <0.001 5.2 0.000279(J) <0.025 <50

n/a n/a n/a n/a n/a n/a n/a 3.8 n/a n/a n/a

n/a 30.1 n/a <0.001 <0.002 0.713(J) <0.001 5.1 <0.005 <0.025 <50

800 79.6 17.4 <0.001 <0.002 n/a <0.0005 7.97 <0.4 <0.05 <5

480 36 19.2 <0.001 <0.002 n/a <0.0005 6.72 <0.4 <0.05 <5

700 53.1 21.6 <0.001 <0.002 n/a <0.0005 40.8 <0.4 <0.01 <5

850 57.3 22.1 <0.001 <0.002 n/a <0.0005 30.2 <0.4 <0.01 <5

800 53.9 16.5 <0.001 <0.002 n/a <0.0005 48 <0.4 <0.01 <5

900 52.7 20.8 <0.001 0.014 n/a <0.0005 25.8 <0.4 <0.01 <5

780 56 16.2 <0.001 <0.002 n/a <0.0005 27.4 <0.1 0.06 <5

950 56 14.8 <0.001 <0.002 n/a <0.0005 16.9 <0.1 <0.01 <5

910 64.3 14.4 <0.0005 <0.001 n/a <0.0005 2.31 <0.4 <0.03 <5

1000 63 17 <0.0005 <0.001 n/a <0.0005 2.4 <0.4 <0.03 <5

900 68.4 19.5 <0.0005 <0.001 n/a <0.0005 1.71 <0.4 <0.03 <5

975 79.3 19.2 <0.0005 <0.001 n/a <0.0005 0.48 <0.4 <0.03 <5

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 35 of 105

Page 228: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-18 3/14/2000

(cont.) 9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

MW-19 downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

9/13/2011

3/13/2012

9/26/2012

3/5/2013

9/11/2013

11/20/2013

3/4/2014

6/9/2014

10/9/2014

4/21/2015

10/16/2015

2/3/2016

4/14/2016

8/3/2016

12/22/2016

4/12/2017

6/15/2017

12/1/2017

Spec

ific

con

du

ctan

ce

(um

ho

s/cm

)

Sulf

ate

(mg/

L)

Tem

per

atu

re (

C)

Tetr

ach

loro

eth

ene

(mg/

l)

Thal

lium

(m

g/L)

TOC

[to

tal o

rgan

ic

carb

on

] (m

g/L)

Tric

hlo

roet

hen

e

(mg/

l)

Turb

idit

y (N

TU)

Van

adiu

m (

mg/

L)

Zin

c (m

g/L)

Ace

ton

e (u

g/L)

1015 79 19.8 <0.0005 <0.001 n/a <0.0005 0.59 <0.4 <0.03 <5

1072 98.9 19.2 <0.0005 <0.001 n/a <0.0005 <1 <0.4 <0.03 <5

881 100 20.4 <0.0005 <0.001 n/a <0.0005 0.72 <0.4 <0.03 <5

1053 129 18.3 <0.0005 <0.001 n/a <0.0005 0.41 <0.4 <0.03 <5

953 118.5 14.2 <0.0005 <0.001 n/a <0.0005 0.75 <0.4 <0.03 <5

1016 144 20.5 <0.0005 <0.001 n/a <0.0005 1.74 <0.4 <0.03 <5

923 119 17.2 <0.0005 <0.001 n/a <0.0005 0.69 <0.4 <0.03 <5

840 114 20.1 <0.0005 <0.001 n/a <0.0005 305 <0.4 0.051 <5

125.6 27.4 19.2 <0.00025 <0.0005 <1 <0.00025 1.69 <0.001 <0.005 <10

651 29.4 17.8 <0.001 <0.0005 <1 <0.001 4 <0.05 <0.025 <10

631 37 17.2 <0.001 <0.001 <1 <0.001 3.68 <0.01 <0.01 <50

682 38 21.7 <0.001 <0.001 9.1 <0.001 2.64 <0.01 <0.01 <50

611 38 22.1 <0.001 <0.001 1.1 <0.001 4.67 <0.01 <0.01 <50

694 45 21.2 <0.001 <0.001 1 <0.001 7.64 <0.01 0.0035 <50

788 42 22.6 <0.001 <0.001 2.3 <0.001 22.6 <0.01 0.0033 <50

691 43(B) 18.4 <0.001 <0.001 1.2 <0.001 141 0.0034(J) 0.007(J) <50

594 55 23.9 <0.001 <0.001 1.9 <0.001 10 0.0019(J) 0.028(B) <50

749 n/a 17.9 n/a n/a n/a n/a 9.9 n/a n/a n/a

600 45 13.8 0.00061(J) <0.001 0.47(J) <0.001 10 0.0012(J) 0.0028(J) <50

n/a n/a n/a <0.001 n/a n/a <0.001 15 n/a n/a <50

594 38 26.9 <0.001 <0.001 0.5(J) <0.001 8.7 0.0006(J) 0.071 <50

287.4 37 20.4 <0.001 <0.002 <1(J) <0.001 9.7 <0.005(J) <0.025(J) <50

720 37.5 23.8 <0.001 <0.002 1.34 <0.001 27.4 0.00237(J) 0.0119(J) <50

n/a n/a n/a n/a n/a n/a n/a 12.4 n/a n/a n/a

642 41.7 21.5 <0.001 <0.002 0.493(J) <0.001 7.3 0.000858(J) 0.0183(J) <50

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

612 36.7 20.4 <0.001 <0.002 0.971(J) <0.001 6.2 0.000409(J) 0.0636 <50

672 n/a 26.24 n/a n/a n/a n/a 10.7 n/a n/a n/a

670 36.9 23.34 <0.001 <0.002 0.55(J) <0.001 4.76 0.000407(J) 0.0421 <50

587 36.9 20 <0.001 <0.002 0.646(J) <0.001 2.8 0.000272(J) <0.025 <50

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 36 of 105

Page 229: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-19 3/8/2018

(cont.) 5/24/2018

11/12/2018

MW-20 downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

9/13/2011

3/13/2012

9/26/2012

3/6/2013

9/12/2013

11/20/2013

3/5/2014

6/9/2014

10/23/2014

4/21/2015

10/15/2015

4/13/2016

8/3/2016

12/20/2016

4/12/2017

6/14/2017

10/5/2017

12/1/2017

5/24/2018

11/13/2018

1/29/2019

Spec

ific

con

du

ctan

ce

(um

ho

s/cm

)

Sulf

ate

(mg/

L)

Tem

per

atu

re (

C)

Tetr

ach

loro

eth

ene

(mg/

l)

Thal

lium

(m

g/L)

TOC

[to

tal o

rgan

ic

carb

on

] (m

g/L)

Tric

hlo

roet

hen

e

(mg/

l)

Turb

idit

y (N

TU)

Van

adiu

m (

mg/

L)

Zin

c (m

g/L)

Ace

ton

e (u

g/L)

658 n/a 18.1 n/a n/a n/a n/a 2.6 n/a n/a n/a

652 37.6 23.3 <0.001 <0.002 0.7(BJ) <0.001 0.6 0.000218(J) <0.025 <50

n/a 34.1 n/a <0.001 <0.002 0.975(J) <0.001 0.9 <0.005 <0.025 <50

124.9 32.4 20.3 <0.00025 <0.0005 <1 <0.00025 6.82 0.034 <0.005 <10

533 25 18.2 <0.001 <0.0005 <1 <0.001 2.15 <0.05 <0.025 <10

493 29 16.4 <0.001 <0.001 1 <0.001 4.98 <0.01 <0.01 <50

523 30 23.1 <0.001 <0.001 51(O) <0.001 4.91 <0.01 <0.01 <50

608 29 19.2 <0.001 <0.001 <1 <0.001 5.01 <0.01 <0.01 <50

488 25 20.51 <0.001 <0.001 1.1 <0.001 8.88 0.0027 0.0037 <50

530 27 21 <0.001 <0.001 0.54 <0.001 17.3 0.044(R) 0.0041 <50

475 30(B) 16.7 <0.001 <0.001 0.84(J) <0.001 461 0.0083(J) 0.026(R) <50

498 41 21.9 <0.001 <0.001 4.2 <0.001 8 0.0015(J) 0.0037(JB) <50

561 n/a 20.2 n/a n/a n/a n/a 9.9 n/a n/a n/a

457 24 7.8 0.00057(J) <0.001 0.67(J) <0.001 9 0.00079(J) 0.003(J) <50

n/a n/a n/a <0.001 n/a n/a <0.001 7.5 n/a n/a <50

n/a 30 n/a <0.001 <0.002 0.8(J) <0.001 n/a <0.005 0.075 <50

253.2 38 22.9 <0.001 <0.002 <1(J) <0.001 9.7 <0.005(J) <0.025 <50

519 27.7 24.9 <0.001 <0.002 1.1 <0.001 7.4 0.000973(J) 0.0159(J) <50

440 34.7 22 <0.001 <0.002 0.646(J) <0.001 8.7 0.00112(J) 0.0436 <50

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

573 30 13.6 <0.001 <0.002 1.2 <0.001 9.6 0.000952(J) 0.0793 <50

564 n/a 23.39 n/a n/a n/a n/a 9.83 n/a 0.00854(J) n/a

658 41.2 26.9 <0.001 <0.002 0.843(J) <0.001 8.86 0.000691(J) 0.0615 <50

n/a n/a n/a n/a n/a n/a n/a n/a n/a 0.00597(J) n/a

576 25 19.9 <0.001 <0.002 0.877(J) <0.001 1.5 0.000297(J) <0.025 <50

550 25.1 23.7 <0.001 <0.002 0.648(BJ) <0.001 0.8 <0.005 <0.025 <50

n/a 26 n/a <0.001 <0.002 0.863(J) <0.001 0.6 <0.005 <0.025 <50

n/a n/a n/a n/a n/a n/a n/a 0.8 n/a n/a n/a

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 37 of 105

Page 230: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-21 downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

9/13/2011

3/13/2012

9/26/2012

3/6/2013

9/12/2013

3/6/2014

10/8/2014

4/22/2015

10/14/2015

4/13/2016

12/20/2016

6/14/2017

11/29/2017

5/24/2018

11/13/2018

MW-22 downgradient

11/29/2017

3/8/2018

5/23/2018

8/20/2018

11/9/2018

Spec

ific

con

du

ctan

ce

(um

ho

s/cm

)

Sulf

ate

(mg/

L)

Tem

per

atu

re (

C)

Tetr

ach

loro

eth

ene

(mg/

l)

Thal

lium

(m

g/L)

TOC

[to

tal o

rgan

ic

carb

on

] (m

g/L)

Tric

hlo

roet

hen

e

(mg/

l)

Turb

idit

y (N

TU)

Van

adiu

m (

mg/

L)

Zin

c (m

g/L)

Ace

ton

e (u

g/L)

109.8 19.9 20.6 <0.00025 <0.00025 <1 <0.00025 6.6 <0.0005 <0.0025 <10

664 16.9 18.9 <0.001 <0.0005 <1 <0.001 2.88 <0.05 <0.025 <10

652 22 16.6 <0.001 <0.001 <1 <0.001 3.12 <0.01 <0.01 <50

702 23 21.5 <0.001 <0.001 73(O) <0.001 2.13 <0.01 <0.01 <50

639 20 23.6 <0.001 <0.001 4 <0.001 2.81 <0.01 <0.01 <50

682 19 20.83 <0.001 <0.001 0.66 <0.001 6.4 0.0036 0.0039 <50

579 11 22.2 <0.001 <0.001 0.24 <0.001 23.2 <0.01 <0.01 <50

497 11(B) 17.3 <0.001 <0.001 0.41(J) <0.001 126 0.0041(J) 0.02 <50

798 200 24.8 <0.001 <0.001 1.7 <0.001 11 0.0017(J) 0.027(B) <50

756 72 0.8 <0.001 <0.001 0.54(J) <0.001 9 0.00019(J) 0.0048(J) <50

654 18 24.6 <0.001 <0.001 0.51(J) <0.001 9.7 <0.002 0.019 <50

664 17 22.8 <0.001 <0.002 <1(J) <0.001 9 <0.005(J) <0.025(J) <50

711 88.6 24.6 <0.001 <0.002 1.2 <0.001 6.9 0.000712(J) <0.025 <50

383 18.7 20.7 <0.001 <0.002 0.381(J) <0.001 4.4 0.000839(J) 0.00977(J) <50

509 19.9 17.2 <0.001 <0.002 1.23 <0.001 7.4 0.000347(J) 0.00344(J) <50

722 85.1 25.95 <0.001 <0.002 0.751(J) <0.001 8.33 0.000291(J) 0.00882(J) <50

527 11.6 19.7 <0.001 <0.002 0.585(J) <0.001 2.1 0.000192(J) <0.025 <50

618 26.3 32.8 <0.001 <0.002 0.508(BJ) <0.001 2.9 0.000265(J) <0.025 <50

n/a 10.1 n/a <0.001 <0.002 0.562(J) <0.001 0.6 <0.005 <0.025 <50

308 5.56 19.1 <0.001 <0.002 0.725(J) <0.001 0.6 0.000293(J) <0.025 <50

296 3.48(J) 14.3 <0.001 <0.002 1.46 <0.001 2.1 0.00021(J) <0.025 <50

368 9.61 20.7 <0.001 <0.002 0.658(BJ) <0.001 0.8 0.000237(J) <0.025 <50

n/a 11.7 n/a <0.001 <0.002 0.631(BJ) <0.001 1.9 <0.005 <0.025 <50

n/a 7.22 n/a <0.001 <0.002 0.726(J) <0.001 0.5 <0.005 <0.025 <50

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 38 of 105

Page 231: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

LEACHATEBLDGA downgradient

3/6/2013

9/11/2013

3/5/2014

10/9/2014

4/14/2015

4/16/2015

10/16/2015

4/13/2016

12/22/2016

6/15/2017

12/1/2017

5/25/2018

11/14/2018

LEACHATEBLDGB downgradient

3/6/2013

3/5/2014

10/9/2014

4/14/2015

4/16/2015

10/16/2015

4/13/2016

12/22/2016

6/15/2017

12/1/2017

5/25/2018

11/14/2018

LEACHATEBLDGC downgradient

9/11/2013

3/5/2014

10/9/2014

Spec

ific

con

du

ctan

ce

(um

ho

s/cm

)

Sulf

ate

(mg/

L)

Tem

per

atu

re (

C)

Tetr

ach

loro

eth

ene

(mg/

l)

Thal

lium

(m

g/L)

TOC

[to

tal o

rgan

ic

carb

on

] (m

g/L)

Tric

hlo

roet

hen

e

(mg/

l)

Turb

idit

y (N

TU)

Van

adiu

m (

mg/

L)

Zin

c (m

g/L)

Ace

ton

e (u

g/L)

8380 11 13.1 <0.001 <0.001 260 <0.001 1100 0.041 11 45

11292 0.99 25.9 <0.001 <0.005 480 <0.001 49.6 0.033 0.21 <50

11550 0.47(J) 9.3 <0.001 <0.005 620 <0.001 306 0.038 0.023(J) 15(J)

10480 <5 26.9 <0.001 <0.001 450 <0.001 62.6 0.022 0.0062(J) <50

5623 n/a 20.7 n/a n/a n/a n/a 404 n/a n/a n/a

n/a 91 n/a <0.001 <0.018 1300 <0.001 n/a <0.045(J) 1 1600

1278 7.42 25.5 <0.001 <0.018 557 <0.001 252 0.0273(J) 0.138(J) 20.1(J)

n/a 4.48(J) n/a <0.001 <0.018 429 <0.001 n/a 0.0217(J) <0.225 10.3(J)

1272 6.53 13.3 <0.001 <0.018 1710 <0.001 n/a 0.0681 0.213(J) 24.2(J)

110.2 <5 7.28 <0.001 <0.002 434 <0.001 27.9 0.0176 0.031 2340(J)

1156 <5 14.3 <0.005 <0.002 533 <0.005 28.3 0.0276 0.0593(B) 550

1205 <5 30.7 <0.001 <0.002 555 <0.001 864 0.0414 0.267 1300

n/a <5 n/a <0.001 <0.002 781 <0.001 n/a 0.0255 0.0168(J) 286

2435 3.8 11.3 <0.001 <0.001 40 0.0007 622 0.022 0.55 12

2750 4.6(J) 5.8 <0.001 <0.001 43 0.00081(J) 77 0.0039 0.023 <50

2768 1.2(J) 28.4 <0.001 <0.001 54 <0.001 99.1 0.0011(J) 0.31 <50

1887 n/a 16.7 n/a n/a n/a n/a 885 n/a n/a n/a

n/a <5(J) n/a <0.001 <0.002 95 <0.001(J) n/a <0.005(J) 0.43 5800

3603 1.67(J) 23.7 <0.001 <0.002 56.8 <0.001 117 0.00162(J) 0.0132(J) <50

n/a 1.6(J) n/a <0.001 <0.002 46.1 <0.001 n/a 0.00195(J) 0.06 <50

3052 4.6(J) 8.4 <0.001 <0.002 52.7 <0.001 637 0.00467(J) 0.422 <50

2798 1.93(J) 33.94 <0.001 <0.002 44.9 <0.001 95.8 0.00128(J) 0.03 <50

n/a 2.33(J) n/a <0.001 <0.002 45.7 <0.001 n/a 0.0125 0.371 <50

2589 3.81(BJ) 29.4 <0.001 n/a 40.4 <0.001 254 0.00116(J) n/a <50

n/a 2.36(J) n/a <0.001 <0.002 101 <0.001 n/a 0.00405(J) 0.0583 49.6(J)

2429 55 25.9 <0.001 <0.001 34 <0.001 31.4 0.005 0.008 77

2479 1.6(J) 7.4 <0.001 <0.001 54 <0.001 70 0.01 0.051 170

2929 4.9(J) 28 <0.001 <0.001 69 <0.001 22.4 0.0023 0.012 <50

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 39 of 105

Page 232: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

LEACHATEBLDGC 4/14/2015

(cont.) 4/16/2015

10/16/2015

4/13/2016

12/22/2016

6/15/2017

12/1/2017

5/25/2018

11/14/2018

MW-6 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

MW-6R downgradient

9/23/1998

3/16/1999

9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

3/24/2004

Spec

ific

con

du

ctan

ce

(um

ho

s/cm

)

Sulf

ate

(mg/

L)

Tem

per

atu

re (

C)

Tetr

ach

loro

eth

ene

(mg/

l)

Thal

lium

(m

g/L)

TOC

[to

tal o

rgan

ic

carb

on

] (m

g/L)

Tric

hlo

roet

hen

e

(mg/

l)

Turb

idit

y (N

TU)

Van

adiu

m (

mg/

L)

Zin

c (m

g/L)

Ace

ton

e (u

g/L)

2235 n/a 18.6 n/a n/a n/a n/a 198 n/a n/a n/a

n/a 8.6 n/a <0.001 <0.002 81 <0.001 n/a <0.005(J) <0.025(J) <50

3384 4.02(J) 23.5 <0.001 <0.002 63.6 <0.001 110 0.00246(J) 0.00376(J) <50

n/a 4.66(J) n/a <0.001 <0.002 50.2 <0.001 n/a 0.002(J) 0.00413(J) <50

3861 1.92(J) 9.35 <0.001 <0.002 70.3 <0.001 n/a 0.0116 0.0366 <50

3882 4.63(J) 31.31 <0.001 <0.002 61.5 <0.001 87.1 0.0017(J) 0.0149(J) <50

n/a 2.01(J) n/a <0.001 <0.002 76.4 <0.001 n/a 0.00279(J) 0.0114(BJ) <50

3995 1.4(BJ) 28.2 <0.001 <0.002 73.6 <0.001 110 0.00175(J) 0.00283(BJ) 18.3(J)

n/a 1.77(J) n/a <0.001 <0.002 93 <0.001 n/a 0.00294(J) 0.00491(J) <50

550 53 20.2 <0.001 <0.002 n/a <0.0005 115 <0.4 <0.05 <5

550 48.4 24.7 <0.001 <0.002 n/a <0.0005 212 <0.4 0.061 <5

550 45.3 20.2 <0.001 <0.002 n/a <0.0005 42.3 <0.4 0.015 <5

590 44.8 24.5 <0.001 <0.002 n/a <0.0005 82.9 <0.4 <0.01 <5

550 43 17 <0.001 <0.002 n/a <0.0005 157 <0.4 <0.01 <5

610 56.2 23.7 <0.001 0.014 n/a <0.0005 52.9 <0.4 0.041 <5

620 61 14.7 <0.001 <0.002 n/a <0.0005 22 <0.1 0.07 <5

700 86.1 16.7 <0.001 <0.002 n/a <0.0005 844 <0.1 0.098 <5

600 36 18.2 <0.0005 <0.001 n/a <0.0005 1.91 <0.4 <0.03 <5

580 41.8 19 <0.0005 <0.001 n/a <0.0005 1.4 <0.4 <0.03 <5

608 43.4 19.2 <0.0005 <0.001 n/a <0.0005 0.54 <0.4 <0.03 <5

676 39.1 17.3 <0.0005 <0.001 n/a <0.0005 1.16 <0.4 <0.03 <5

709 40.9 18.4 <0.0005 <0.001 n/a <0.0005 <1 <0.4 <0.03 <5

655 47.1 19 <0.0005 <0.001 n/a <0.0005 0.5 <0.4 <0.03 <5

1147 333(O) 19.9 <0.0005 <0.001 n/a <0.0005 0.79 <0.4 <0.03 <5

678 59 16.2 <0.0005 <0.001 n/a <0.0005 1.13 <0.4 <0.03 <5

850 151 19.3 <0.0005 <0.001 n/a <0.0005 0.59 <0.4 <0.03 <5

687 69.5 17.8 <0.0005 <0.001 n/a <0.0005 0.39 <0.4 <0.03 <5

697 114 25.2 <0.0005 <0.001 n/a <0.0005 1.07 <0.4 <0.03 <5

663 51.2 18.1 <0.0005 <0.001 n/a <0.0005 0.53 <0.4 <0.03 <5

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 40 of 105

Page 233: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-6R 9/14/2004

(cont.) 3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

9/28/2010

3/13/2012

9/26/2012

3/5/2014

6/9/2014

MW-9 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

3/14/2000

Spec

ific

con

du

ctan

ce

(um

ho

s/cm

)

Sulf

ate

(mg/

L)

Tem

per

atu

re (

C)

Tetr

ach

loro

eth

ene

(mg/

l)

Thal

lium

(m

g/L)

TOC

[to

tal o

rgan

ic

carb

on

] (m

g/L)

Tric

hlo

roet

hen

e

(mg/

l)

Turb

idit

y (N

TU)

Van

adiu

m (

mg/

L)

Zin

c (m

g/L)

Ace

ton

e (u

g/L)

794 104 20.7 <0.0005 <0.001 <1 <0.0005 0.38 <0.4 <0.03 <5

730 62.6 12.7 <0.0005 <0.001 1.31 <0.0005 0.56 <0.4 <0.03 <5

708 81.2 19.7 <5E-05 <0.001 <1 <5E-05 0.21 <0.002 <0.01 <5

690 81.2 16.4 <0.00025 <0.001 <1 <0.00025 0.35 <0.002 <0.01 <10

742 87.9 18.1 <0.00025 <0.01 <0.5 <0.00025 0.32 <0.002 <0.01 <10

655 73.6 15 <0.00025 <0.001 1.45 <0.00025 0.57 <0.002 <0.01 <10

794 130 20.5 <0.00025 <0.00174 <1 <0.00025 0.85 <0.01 <0.0025 <10

702 82.4 17.8 <0.00025 <0.00075 <1 <0.00025 1.25 <0.05 <0.025 <10

543 92.4 23.9 <0.00025 <0.0002 1.68 <0.00025 2.41 <0.02 <0.01 <10

745 72.1 18.4 <0.00025 <0.0002 <1 <0.00025 38.5 <0.02 <0.01 <10

808 132 19.6 <0.00025 <0.0002 1 <0.00025 3.55 <0.02 0.0145 <10

764 73.1 18.2 <0.00025 <0.0005 <1 <0.00025 2.08 <0.005 <0.005 <10

138.3 96.8 21.4 <0.00025 <0.0005 <1 <0.00025 1.75 <0.001 <0.005 <10

814 88 20.1 <0.001 <0.001 <1 <0.001 1.56 <0.01 0.0044 <50

818 87 19.2 <0.001 <0.001 0.4 <0.001 1.71 <0.01 <0.01 <50

648 74 3.6 0.001(R) <0.001 0.57 <0.001 9 <0.002 0.0054 <50

n/a n/a n/a <0.001 n/a n/a <0.001 3.5 n/a n/a <50

490 18.7 19.4 <0.001 <0.002 n/a <0.0005 1.84 <0.4 <0.05 <5

470 20.6 20.5 <0.001 <0.002 n/a <0.0005 1.64 <0.4 <0.05 <5

485 22.5 23.7 <0.001 0.008 n/a <0.0005 2.2 <0.4 <0.01 <5

485 21.2 23 <0.001 <0.002 n/a <0.0005 2.12 <0.4 <0.01 <5

450 22.6 16.1 <0.001 <0.002 n/a <0.0005 2.02 <0.4 <0.01 <5

500 25.4 22.3 <0.001 0.005 n/a <0.0005 9.47 <0.4 <0.01 <5

485 31 16.5 <0.001 <0.002 n/a <0.0005 3.56 <0.1 0.03 <5

550 17.3 15 <0.001 <0.002 n/a <0.0005 2.18 <0.1 <0.01 <5

510 27.1 12.9 <0.0005 <0.001 n/a <0.0005 1.88 <0.4 <0.03 <5

495 16 17.2 <0.0005 <0.001 n/a <0.0005 1.7 <0.4 <0.03 <5

495 23.4 20 <0.0005 <0.001 n/a <0.0005 <1 <0.4 <0.03 <5

472 17.2 19.3 <0.0005 <0.001 n/a <0.0005 0.32 <0.4 <0.03 <5

579 18.8 19.6 <0.0005 <0.001 n/a <0.0005 0.22 <0.4 <0.03 <5

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 41 of 105

Page 234: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-9 9/20/2000

(cont.) 3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

3/24/2004

9/14/2004

3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

MW-14 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

Spec

ific

con

du

ctan

ce

(um

ho

s/cm

)

Sulf

ate

(mg/

L)

Tem

per

atu

re (

C)

Tetr

ach

loro

eth

ene

(mg/

l)

Thal

lium

(m

g/L)

TOC

[to

tal o

rgan

ic

carb

on

] (m

g/L)

Tric

hlo

roet

hen

e

(mg/

l)

Turb

idit

y (N

TU)

Van

adiu

m (

mg/

L)

Zin

c (m

g/L)

Ace

ton

e (u

g/L)

593 23.6 18.5 <0.0005 <0.001 n/a <0.0005 <1 <0.4 <0.03 <5

590 21 17.9 <0.0005 <0.001 n/a <0.0005 0.38 <0.4 <0.03 <5

555 21.5 19.8 <0.0005 <0.001 n/a <0.0005 0.49 <0.4 <0.03 <5

661 22.4 17.3 <0.0005 <0.001 n/a <0.0005 0.32 <0.4 <0.03 <5

610 23.6 19.3 <0.0005 <0.001 n/a <0.0005 0.39 <0.4 <0.03 <5

628 26.2 20.3 <0.0005 <0.001 n/a <0.0005 0.34 <0.4 <0.03 <5

597 26.2 21.7 <0.0005 <0.001 n/a <0.0005 0.89 <0.4 <0.03 <5

628 34.1 20.1 <0.0005 <0.001 n/a <0.0005 0.25 <0.4 <0.03 <5

558 22.4 23.4 <0.0005 <0.001 <1 <0.0005 0.32 <0.4 <0.03 <5

575 22 12.5 <0.0005 <0.001 1.58 <0.0005 0.16 <0.4 <0.03 <5

600 22.3 23.7 <5E-05 <0.001 1.25 <5E-05 0.28 <0.002 <0.01 <5

662 24.1 18.3 <0.00025 <0.001 <1 <0.00025 0.16 <0.002 <0.01 <10

595 32.9 22.7 <0.00025 <0.01 <0.5 <0.00025 0.29 <0.002 <0.01 <10

468 14.2 18.6 <0.00025 <0.001 <1 <0.00025 0.24 <0.002 <0.01 <10

632 21.8 23.8 <0.00025 <0.00174 <1 <0.00025 0.59 <0.01 <0.0025 <10

425 10.9 22 <0.00025 <0.00075 <1 <0.00025 1.48 <0.05 <0.025 <10

383 12.2 25.2 <0.00025 <0.0002 1.53 <0.00025 0.74 <0.02 <0.01 <10

521 20.6 18.4 <0.00025 <0.0002 <1 <0.00025 31 <0.02 <0.01 <10

493 18.3 21.5 <0.00025 <0.0002 <1 <0.00025 2.31 <0.02 0.013 <10

495 15.1 20.2 <0.00025 <0.0005 <1 <0.00025 0.63 <0.0005 <0.005 <10

780 69.7 17.1 <0.001 <0.002 n/a <0.0005 31 <0.4 <0.05 <5

710 79.1 18.6 <0.001 <0.002 n/a <0.0005 14.2 <0.4 <0.05 <5

720 83.1 18.8 <0.001 <0.002 n/a <0.0005 17 <0.4 <0.01 <5

750 78.3 20.7 <0.001 <0.002 n/a <0.0005 13.4 <0.4 <0.01 <5

750 94.6 16.5 <0.001 <0.002 n/a <0.0005 20.4 <0.4 <0.01 <5

775 90.3 22 <0.001 0.009 n/a <0.0005 25.8 <0.4 <0.01 <5

780 109 15.2 <0.001 <0.002 n/a <0.0005 18.1 <0.1 0.04 <5

890 93.3 14.7 <0.001 <0.002 n/a <0.0005 14 <0.1 0.014 <5

780 78.4 12.8 <0.0005 <0.001 n/a <0.0005 0.53 <0.4 <0.03 <5

820 88 16.5 <0.0005 <0.001 n/a <0.0005 1.36 <0.4 <0.03 <5

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 42 of 105

Page 235: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-14 3/16/1999

(cont.) 9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

3/24/2004

MW-16 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

Spec

ific

con

du

ctan

ce

(um

ho

s/cm

)

Sulf

ate

(mg/

L)

Tem

per

atu

re (

C)

Tetr

ach

loro

eth

ene

(mg/

l)

Thal

lium

(m

g/L)

TOC

[to

tal o

rgan

ic

carb

on

] (m

g/L)

Tric

hlo

roet

hen

e

(mg/

l)

Turb

idit

y (N

TU)

Van

adiu

m (

mg/

L)

Zin

c (m

g/L)

Ace

ton

e (u

g/L)

710 86.2 17.1 <0.0005 <0.001 n/a <0.0005 1.37 <0.4 <0.03 <5

702 81.9 17.7 <0.0005 <0.001 n/a <0.0005 0.2 <0.4 <0.03 <5

816 75.2 18.6 <0.0005 0.0057 n/a <0.0005 0.17 <0.4 <0.03 <5

859 78.4 19.3 <0.0005 <0.001 n/a <0.0005 <1 <0.4 <0.03 <5

801 86.2 16.4 <0.0005 <0.001 n/a <0.0005 0.16 <0.4 <0.03 <5

897 84.7 17.9 <0.0005 <0.001 n/a <0.0005 0.16 <0.4 <0.03 <5

862 89.3 17.2 <0.0005 <0.001 n/a <0.0005 0.48 <0.4 <0.03 <5

860 83.5 17.8 <0.0005 <0.001 n/a <0.0005 0.68 <0.4 <0.03 <5

831 90.8 15.3 <0.0005 <0.001 n/a <0.0005 0.27 <0.4 <0.03 <5

832 86.2 17.2 <0.0005 <0.001 n/a <0.0005 0.56 <0.4 <0.03 <5

836 61.2 16.6 <0.0005 <0.001 <1 <0.0005 0.25 <0.4 <0.03 <5

510 42.4 18.5 <0.001 <0.002 n/a <0.0005 24.3 <0.4 <0.05 <5

10 5 n/a 0.001 0.002 n/a 0.0005 1 0.4 0.05 5

800 182 20.8 <0.001 <0.002 n/a <0.0005 41.6 <0.4 <0.01 <5

805 168 20.7 <0.001 <0.002 n/a <0.0005 110 <0.4 <0.01 <5

450 33.9 16.4 <0.001 <0.002 n/a <0.0005 17.4 <0.4 <0.01 <5

475 34 22.2 <0.001 0.014 n/a <0.0005 4.84 <0.4 <0.01 <5

495 44 17.3 <0.001 <0.002 n/a <0.0005 130 <0.1 0.03 <5

590 40.9 16 <0.001 <0.002 n/a <0.0005 6.41 <0.1 <0.005 <5

510 55.8 12.9 <0.0005 <0.001 n/a <0.0005 1.47 <0.4 <0.03 <5

750 121 17.4 <0.0005 <0.001 n/a <0.0005 3.17 <0.4 <0.03 <5

570 69.5 18.5 <0.0005 <0.001 n/a <0.0005 2.57 <0.4 <0.03 <5

721 126 20.3 <0.0005 <0.001 n/a <0.0005 0.84 <0.4 <0.03 <5

619 40.2 17.3 <0.0005 <0.001 n/a <0.0005 1.52 <0.4 <0.03 <5

637 47.2 21.1 <0.0005 <0.001 n/a <0.0005 1.26 <0.4 <0.03 <5

508 33.2 18.3 <0.0005 <0.001 n/a <0.0005 1.6 <0.4 <0.03 <5

570 43.7 19.9 <0.0005 <0.001 n/a <0.0005 1.04 <0.4 <0.03 <5

544 34.8 20.8 <0.0005 <0.001 n/a <0.0005 1.46 <0.4 <0.03 <5

661 44.3 20.4 <0.0005 <0.001 n/a <0.0005 1.5 <0.4 <0.03 <5

675 49.6 20.4 <0.0005 <0.001 n/a <0.0005 0.51 <0.4 <0.03 <5

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 43 of 105

Page 236: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-16 9/17/2003

(cont.) 3/24/2004

9/14/2004

3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

MW-17 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

Spec

ific

con

du

ctan

ce

(um

ho

s/cm

)

Sulf

ate

(mg/

L)

Tem

per

atu

re (

C)

Tetr

ach

loro

eth

ene

(mg/

l)

Thal

lium

(m

g/L)

TOC

[to

tal o

rgan

ic

carb

on

] (m

g/L)

Tric

hlo

roet

hen

e

(mg/

l)

Turb

idit

y (N

TU)

Van

adiu

m (

mg/

L)

Zin

c (m

g/L)

Ace

ton

e (u

g/L)

634 45.8 22.9 <0.0005 <0.001 n/a <0.0005 1.21 <0.4 <0.03 <5

673 37.4 20.1 <0.0005 <0.001 n/a <0.0005 0.51 <0.4 <0.03 <5

704 42.3 23.8 <0.0005 <0.001 <1 <0.0005 0.92 <0.4 <0.03 <5

762 44.4 16.4 <0.0005 <0.001 1.37 <0.0005 0.43 <0.4 <0.03 <5

537 31.8 24.6 <5E-05 <0.001 1.53 <5E-05 0.54 <0.002 <0.01 <5

624 36.8 21.5 <0.00025 <0.001 <1 <0.00025 0.33 <0.002 <0.01 <10

651 40.6 22.7 <0.00025 <0.01 <0.5 <0.00025 0.73 <0.002 <0.01 <10

531 26.1 20.9 <0.00025 <0.001 1.32 <0.00025 1.47 <0.002 <0.01 <10

589 32.6 23.8 <0.00025 <0.00174 <1 <0.00025 1.44 <0.01 <0.0025 <10

612 35.2 23.1 <0.00025 <0.00075 <1 <0.00025 2.24 <0.05 <0.025 <10

489 34.2 25.8 <0.00025 <0.0002 1.79 <0.00025 4.14 <0.02 <0.01 <10

579 28.1 21 <0.00025 <0.0002 <1 <0.00025 65.7 <0.02 <0.01 <10

616 47.6 22.9 <0.00025 <0.0002 1.06 <0.00025 4.98 <0.02 0.0172 <10

652 38.8 22.4 <0.00025 <0.0005 <1 <0.00025 1.95 <0.0005 <0.005 <10

1100 41.9 18.4 <0.001 <0.002 n/a <0.0005 83.4 <0.4 <0.05 <5

880 53.2 20.3 <0.001 <0.002 n/a <0.0005 33.1 <0.4 <0.05 <5

780 74.3 21.5 <0.001 <0.002 n/a <0.0005 49.7 <0.4 <0.01 <5

790 56.4 23.4 <0.001 <0.002 n/a <0.0005 70.9 <0.4 <0.01 <5

700 86 16 <0.001 <0.002 n/a <0.0005 12.9 <0.4 <0.01 <5

610 87.8 20.8 <0.001 0.007 n/a <0.0005 25.1 <0.4 <0.01 <5

690 104 16 <0.001 <0.002 n/a <0.0005 46.5 <0.1 0.06 <5

685 94.9 18.4 <0.001 <0.002 n/a <0.0005 8.69 <0.1 <0.01 <5

740 109.5 12.9 <0.0005 <0.001 n/a <0.0005 1.87 <0.4 <0.03 <5

800 89 17.2 <0.0005 <0.001 n/a <0.0005 2.03 <0.4 <0.03 <5

710 107 17.4 <0.0005 <0.001 n/a <0.0005 2.81 <0.4 <0.03 <5

696 110 19.3 <0.0005 <0.001 n/a <0.0005 23.8 <0.4 <0.03 <5

751 73.4 17.7 <0.0005 <0.001 n/a <0.0005 44.6 <0.4 <0.03 <5

808 107.8 24.5 <0.0005 <0.001 n/a <0.0005 111 <0.4 <0.03 <5

753 129 22.6 <0.0005 <0.001 n/a <0.0005 3.47 <0.4 <0.03 <5

795 117 18.6 <0.0005 <0.001 n/a <0.0005 3.71 <0.4 <0.03 <5

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 44 of 105

Page 237: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-17 3/27/2002

(cont.) 9/25/2002

4/1/2003

9/17/2003

Spec

ific

con

du

ctan

ce

(um

ho

s/cm

)

Sulf

ate

(mg/

L)

Tem

per

atu

re (

C)

Tetr

ach

loro

eth

ene

(mg/

l)

Thal

lium

(m

g/L)

TOC

[to

tal o

rgan

ic

carb

on

] (m

g/L)

Tric

hlo

roet

hen

e

(mg/

l)

Turb

idit

y (N

TU)

Van

adiu

m (

mg/

L)

Zin

c (m

g/L)

Ace

ton

e (u

g/L)

834 122.8 14 <0.0005 <0.001 n/a <0.0005 12.5 <0.4 <0.03 <5

840 129 18.6 <0.0005 <0.001 n/a <0.0005 6.21 <0.4 <0.03 <5

815 124 18.1 <0.0005 <0.001 n/a <0.0005 8.03 <0.4 <0.03 <5

816 135 20.8 <0.0005 <0.001 n/a <0.0005 11.7 <0.4 <0.03 <5

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 45 of 105

Page 238: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-8 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

3/24/2004

9/14/2004

3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

Acr

ylo

nit

rile

(u

g/L)

Ben

zen

e (u

g/L)

Bro

mo

chlo

rom

eth

an

e (u

g/L)

Bro

mo

dic

hlo

rom

eth

ane

(ug/

L)

Bro

mo

form

(u

g/L)

Car

bo

n d

isu

lfid

e

(ug/

L)

Car

bo

n t

etra

chlo

rid

e

(ug/

L)

Ch

loro

ben

zen

e

(ug/

L)

Ch

loro

eth

ane

(ug/

L)

Ch

loro

form

(u

g/L)

Ch

loro

dib

rom

om

eth

ane

(ug/

L)

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 2.2 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.5 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.5 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5 <0.2 <0.05

<10 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 46 of 105

Page 239: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-8 3/17/2009

(cont.) 10/7/2009

3/16/2010

9/28/2010

9/26/2012

3/5/2014

10/16/2015

6/15/2017

MW-9R downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

9/13/2011

3/13/2012

9/26/2012

3/6/2013

9/12/2013

3/5/2014

10/9/2014

4/22/2015

11/12/2015

11/29/2017

MW-9R2 downgradient

5/25/2018

11/13/2018

MW-14R upgradient

9/14/2004

3/9/2005

9/28/2005

3/15/2006

Acr

ylo

nit

rile

(u

g/L)

Ben

zen

e (u

g/L)

Bro

mo

chlo

rom

eth

an

e (u

g/L)

Bro

mo

dic

hlo

rom

eth

ane

(ug/

L)

Bro

mo

form

(u

g/L)

Car

bo

n d

isu

lfid

e

(ug/

L)

Car

bo

n t

etra

chlo

rid

e

(ug/

L)

Ch

loro

ben

zen

e

(ug/

L)

Ch

loro

eth

ane

(ug/

L)

Ch

loro

form

(u

g/L)

Ch

loro

dib

rom

om

eth

ane

(ug/

L)

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 0.278(J) <1 <1 <5 <5 <1

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<2 <1 <1 <1 <1 <1 <1 <1 <2 <1 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 0.428(J) <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<5 <0.5 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.5 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 47 of 105

Page 240: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-14R 9/20/2006

(cont.) 3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

9/28/2010

3/9/2011

9/13/2011

3/13/2012

9/26/2012

3/5/2013

9/10/2013

3/4/2014

10/6/2014

4/14/2015

10/14/2015

4/12/2016

8/2/2016

12/20/2016

6/13/2017

11/29/2017

5/23/2018

11/12/2018

MW-16R downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

Acr

ylo

nit

rile

(u

g/L)

Ben

zen

e (u

g/L)

Bro

mo

chlo

rom

eth

an

e (u

g/L)

Bro

mo

dic

hlo

rom

eth

ane

(ug/

L)

Bro

mo

form

(u

g/L)

Car

bo

n d

isu

lfid

e

(ug/

L)

Car

bo

n t

etra

chlo

rid

e

(ug/

L)

Ch

loro

ben

zen

e

(ug/

L)

Ch

loro

eth

ane

(ug/

L)

Ch

loro

form

(u

g/L)

Ch

loro

dib

rom

om

eth

ane

(ug/

L)

<10 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 1.08 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <5

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <5

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <5

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <5

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 0.59(J) <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5(B) <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<10 <1 <1 <1 <1 0.642(BJ) <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<2 <1 <1 <1 <1 <1 <1 <1 <2 <1 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 48 of 105

Page 241: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-16R 9/13/2011

(cont.) 3/13/2012

9/26/2012

3/5/2013

9/11/2013

3/4/2014

10/23/2014

4/21/2015

10/16/2015

4/14/2016

12/20/2016

6/15/2017

12/1/2017

3/8/2018

5/24/2018

11/12/2018

MW-17R upgradient

9/14/2004

3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

9/28/2010

3/9/2011

Acr

ylo

nit

rile

(u

g/L)

Ben

zen

e (u

g/L)

Bro

mo

chlo

rom

eth

an

e (u

g/L)

Bro

mo

dic

hlo

rom

eth

ane

(ug/

L)

Bro

mo

form

(u

g/L)

Car

bo

n d

isu

lfid

e

(ug/

L)

Car

bo

n t

etra

chlo

rid

e

(ug/

L)

Ch

loro

ben

zen

e

(ug/

L)

Ch

loro

eth

ane

(ug/

L)

Ch

loro

form

(u

g/L)

Ch

loro

dib

rom

om

eth

ane

(ug/

L)

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 0.3(J) <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 0.661(BJ) <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<5 <0.5 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.5 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 2.16 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <5

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 49 of 105

Page 242: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-17R 9/13/2011

(cont.) 3/13/2012

9/26/2012

3/5/2013

9/11/2013

3/5/2014

10/9/2014

4/21/2015

10/14/2015

4/12/2016

8/2/2016

12/20/2016

4/12/2017

6/14/2017

11/29/2017

5/23/2018

8/20/2018

11/9/2018

MW-18 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

Acr

ylo

nit

rile

(u

g/L)

Ben

zen

e (u

g/L)

Bro

mo

chlo

rom

eth

an

e (u

g/L)

Bro

mo

dic

hlo

rom

eth

ane

(ug/

L)

Bro

mo

form

(u

g/L)

Car

bo

n d

isu

lfid

e

(ug/

L)

Car

bo

n t

etra

chlo

rid

e

(ug/

L)

Ch

loro

ben

zen

e

(ug/

L)

Ch

loro

eth

ane

(ug/

L)

Ch

loro

form

(u

g/L)

Ch

loro

dib

rom

om

eth

ane

(ug/

L)

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <5

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <5

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <5

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<10 <1 <1 <1 <1 0.558(BJ) <1 <1 <5 <5 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 50 of 105

Page 243: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-18 3/14/2000

(cont.) 9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

MW-19 downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

9/13/2011

3/13/2012

9/26/2012

3/5/2013

9/11/2013

11/20/2013

3/4/2014

6/9/2014

10/9/2014

4/21/2015

10/16/2015

2/3/2016

4/14/2016

8/3/2016

12/22/2016

4/12/2017

6/15/2017

12/1/2017

Acr

ylo

nit

rile

(u

g/L)

Ben

zen

e (u

g/L)

Bro

mo

chlo

rom

eth

an

e (u

g/L)

Bro

mo

dic

hlo

rom

eth

ane

(ug/

L)

Bro

mo

form

(u

g/L)

Car

bo

n d

isu

lfid

e

(ug/

L)

Car

bo

n t

etra

chlo

rid

e

(ug/

L)

Ch

loro

ben

zen

e

(ug/

L)

Ch

loro

eth

ane

(ug/

L)

Ch

loro

form

(u

g/L)

Ch

loro

dib

rom

om

eth

ane

(ug/

L)

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<2 <1 <1 <1 <1 <1 <1 <1 <2 <1 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 0.7(J) <1 <1 <5 <5 <1

<10 <1 1.8(R) <1 <1 0.73(J) <1 <1 <5 0.76(J) <1

n/a n/a <1 n/a n/a n/a n/a n/a n/a n/a n/a

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 0.314(J) <1 <1 <5 <5 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<10 <1 <1 <1 <1 0.518(BJ) <1 <1 <5 <5 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 51 of 105

Page 244: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-19 3/8/2018

(cont.) 5/24/2018

11/12/2018

MW-20 downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

9/13/2011

3/13/2012

9/26/2012

3/6/2013

9/12/2013

11/20/2013

3/5/2014

6/9/2014

10/23/2014

4/21/2015

10/15/2015

4/13/2016

8/3/2016

12/20/2016

4/12/2017

6/14/2017

10/5/2017

12/1/2017

5/24/2018

11/13/2018

1/29/2019

Acr

ylo

nit

rile

(u

g/L)

Ben

zen

e (u

g/L)

Bro

mo

chlo

rom

eth

an

e (u

g/L)

Bro

mo

dic

hlo

rom

eth

ane

(ug/

L)

Bro

mo

form

(u

g/L)

Car

bo

n d

isu

lfid

e

(ug/

L)

Car

bo

n t

etra

chlo

rid

e

(ug/

L)

Ch

loro

ben

zen

e

(ug/

L)

Ch

loro

eth

ane

(ug/

L)

Ch

loro

form

(u

g/L)

Ch

loro

dib

rom

om

eth

ane

(ug/

L)

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<2 <1 <1 <1 <1 <1 <1 <1 <2 <1 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 0.38(J) <1 <1 <1 0.37(J) <1 <1 <5 <5 <1

<10 <1 0.55(JR) <1 <1 0.55(J) <1 <1 <5 0.75(J) <1

n/a n/a <1 n/a n/a n/a n/a n/a n/a n/a n/a

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<10 <1 <1 <1 <1 0.549(BJ) <1 <1 <5 <5 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 52 of 105

Page 245: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-21 downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

9/13/2011

3/13/2012

9/26/2012

3/6/2013

9/12/2013

3/6/2014

10/8/2014

4/22/2015

10/14/2015

4/13/2016

12/20/2016

6/14/2017

11/29/2017

5/24/2018

11/13/2018

MW-22 downgradient

11/29/2017

3/8/2018

5/23/2018

8/20/2018

11/9/2018

Acr

ylo

nit

rile

(u

g/L)

Ben

zen

e (u

g/L)

Bro

mo

chlo

rom

eth

an

e (u

g/L)

Bro

mo

dic

hlo

rom

eth

ane

(ug/

L)

Bro

mo

form

(u

g/L)

Car

bo

n d

isu

lfid

e

(ug/

L)

Car

bo

n t

etra

chlo

rid

e

(ug/

L)

Ch

loro

ben

zen

e

(ug/

L)

Ch

loro

eth

ane

(ug/

L)

Ch

loro

form

(u

g/L)

Ch

loro

dib

rom

om

eth

ane

(ug/

L)

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<2 <1 <1 <1 <1 <1 <1 <1 <2 <1 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 0.438(BJ) <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 0.315(J) <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 0.415(J) <1 <1 <5 <5 <1

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 53 of 105

Page 246: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

LEACHATEBLDGA downgradient

3/6/2013

9/11/2013

3/5/2014

10/9/2014

4/14/2015

4/16/2015

10/16/2015

4/13/2016

12/22/2016

6/15/2017

12/1/2017

5/25/2018

11/14/2018

LEACHATEBLDGB downgradient

3/6/2013

3/5/2014

10/9/2014

4/14/2015

4/16/2015

10/16/2015

4/13/2016

12/22/2016

6/15/2017

12/1/2017

5/25/2018

11/14/2018

LEACHATEBLDGC downgradient

9/11/2013

3/5/2014

10/9/2014

Acr

ylo

nit

rile

(u

g/L)

Ben

zen

e (u

g/L)

Bro

mo

chlo

rom

eth

an

e (u

g/L)

Bro

mo

dic

hlo

rom

eth

ane

(ug/

L)

Bro

mo

form

(u

g/L)

Car

bo

n d

isu

lfid

e

(ug/

L)

Car

bo

n t

etra

chlo

rid

e

(ug/

L)

Ch

loro

ben

zen

e

(ug/

L)

Ch

loro

eth

ane

(ug/

L)

Ch

loro

form

(u

g/L)

Ch

loro

dib

rom

om

eth

ane

(ug/

L)

<10 2.6 <1 <1 <1 0.96 <1 <1 <5 <5 <1

<10 1.4 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 4 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 3.4 <1 <1 <1 <1 <1 <1 <5 <5 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<10 1.9 <1 <1 <1 3.5 <1 <1 <5 <5 <1

<10 1.95 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 2.33 <1 <1 <1 <1 <1 0.367(J) <5 <5 <1

<10 2.42 <1 <1 <1 0.421(BJ) <1 <1 <5 <5 <1

<10 2.21 <1 <1 <1 <1 <1 <1 <5 <5 <1

<50 <5 <5 <5 <5 <5 <5 <5 <25 <25 <5

<10 2.08 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 1.95 <1 <1 <1 <1 <1 0.378(J) <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 0.49 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 0.33(J) <1 <1 <1 <1 <1 <1 <5 <5 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 0.765(BJ) <1 <1 <5 <5 <1

<10 0.758(J) <1 <1 <1 <1 <1 0.357(J) <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 0.55 <1 <1 <5 <5 <1

<10 0.75(J) <1 <1 <1 0.31(J) <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 54 of 105

Page 247: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

LEACHATEBLDGC 4/14/2015

(cont.) 4/16/2015

10/16/2015

4/13/2016

12/22/2016

6/15/2017

12/1/2017

5/25/2018

11/14/2018

MW-6 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

MW-6R downgradient

9/23/1998

3/16/1999

9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

3/24/2004

Acr

ylo

nit

rile

(u

g/L)

Ben

zen

e (u

g/L)

Bro

mo

chlo

rom

eth

an

e (u

g/L)

Bro

mo

dic

hlo

rom

eth

ane

(ug/

L)

Bro

mo

form

(u

g/L)

Car

bo

n d

isu

lfid

e

(ug/

L)

Car

bo

n t

etra

chlo

rid

e

(ug/

L)

Ch

loro

ben

zen

e

(ug/

L)

Ch

loro

eth

ane

(ug/

L)

Ch

loro

form

(u

g/L)

Ch

loro

dib

rom

om

eth

ane

(ug/

L)

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 1.11 <1 <1 <1 0.6(BJ) <1 <1 <5 <5 <1

<10 0.356(J) <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 0.543(J) <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 1.23 <1 <1 <1 <1 <1 <1 <5 <5 <1

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 55 of 105

Page 248: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-6R 9/14/2004

(cont.) 3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

9/28/2010

3/13/2012

9/26/2012

3/5/2014

6/9/2014

MW-9 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

3/14/2000

Acr

ylo

nit

rile

(u

g/L)

Ben

zen

e (u

g/L)

Bro

mo

chlo

rom

eth

an

e (u

g/L)

Bro

mo

dic

hlo

rom

eth

ane

(ug/

L)

Bro

mo

form

(u

g/L)

Car

bo

n d

isu

lfid

e

(ug/

L)

Car

bo

n t

etra

chlo

rid

e

(ug/

L)

Ch

loro

ben

zen

e

(ug/

L)

Ch

loro

eth

ane

(ug/

L)

Ch

loro

form

(u

g/L)

Ch

loro

dib

rom

om

eth

ane

(ug/

L)

<5 <0.5 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.5 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<10 <1 <1 <1 <1 <1 <1 <1 <5 <5 <1

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 56 of 105

Page 249: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-9 9/20/2000

(cont.) 3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

3/24/2004

9/14/2004

3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

MW-14 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

Acr

ylo

nit

rile

(u

g/L)

Ben

zen

e (u

g/L)

Bro

mo

chlo

rom

eth

an

e (u

g/L)

Bro

mo

dic

hlo

rom

eth

ane

(ug/

L)

Bro

mo

form

(u

g/L)

Car

bo

n d

isu

lfid

e

(ug/

L)

Car

bo

n t

etra

chlo

rid

e

(ug/

L)

Ch

loro

ben

zen

e

(ug/

L)

Ch

loro

eth

ane

(ug/

L)

Ch

loro

form

(u

g/L)

Ch

loro

dib

rom

om

eth

ane

(ug/

L)

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.5 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.5 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 57 of 105

Page 250: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-14 3/16/1999

(cont.) 9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

3/24/2004

MW-16 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

Acr

ylo

nit

rile

(u

g/L)

Ben

zen

e (u

g/L)

Bro

mo

chlo

rom

eth

an

e (u

g/L)

Bro

mo

dic

hlo

rom

eth

ane

(ug/

L)

Bro

mo

form

(u

g/L)

Car

bo

n d

isu

lfid

e

(ug/

L)

Car

bo

n t

etra

chlo

rid

e

(ug/

L)

Ch

loro

ben

zen

e

(ug/

L)

Ch

loro

eth

ane

(ug/

L)

Ch

loro

form

(u

g/L)

Ch

loro

dib

rom

om

eth

ane

(ug/

L)

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

5 0.1 1 0.5 1 0.1 0.5 0.25 1 0.5 0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 58 of 105

Page 251: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-16 9/17/2003

(cont.) 3/24/2004

9/14/2004

3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

MW-17 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

Acr

ylo

nit

rile

(u

g/L)

Ben

zen

e (u

g/L)

Bro

mo

chlo

rom

eth

an

e (u

g/L)

Bro

mo

dic

hlo

rom

eth

ane

(ug/

L)

Bro

mo

form

(u

g/L)

Car

bo

n d

isu

lfid

e

(ug/

L)

Car

bo

n t

etra

chlo

rid

e

(ug/

L)

Ch

loro

ben

zen

e

(ug/

L)

Ch

loro

eth

ane

(ug/

L)

Ch

loro

form

(u

g/L)

Ch

loro

dib

rom

om

eth

ane

(ug/

L)

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.5 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.5 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<10 <0.5 <0.5 <0.5 <0.2 <0.5 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.1 <1 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 4 <0.5 <0.25 <1 <0.5 <0.5

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 59 of 105

Page 252: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-17 3/27/2002

(cont.) 9/25/2002

4/1/2003

9/17/2003

Acr

ylo

nit

rile

(u

g/L)

Ben

zen

e (u

g/L)

Bro

mo

chlo

rom

eth

an

e (u

g/L)

Bro

mo

dic

hlo

rom

eth

ane

(ug/

L)

Bro

mo

form

(u

g/L)

Car

bo

n d

isu

lfid

e

(ug/

L)

Car

bo

n t

etra

chlo

rid

e

(ug/

L)

Ch

loro

ben

zen

e

(ug/

L)

Ch

loro

eth

ane

(ug/

L)

Ch

loro

form

(u

g/L)

Ch

loro

dib

rom

om

eth

ane

(ug/

L)

<5 <0.05 <0.5 <0.5 <1 13.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 <0.1 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 1.6 <0.5 <0.25 <1 <0.5 <0.5

<5 <0.05 <0.5 <0.5 <1 2.3 <0.5 <0.25 <1 <0.5 <0.5

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 60 of 105

Page 253: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-8 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

3/24/2004

9/14/2004

3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

1,2

-Dib

rom

o-3

-

chlo

rop

rop

ane

(ug/

L)

1,2

-Dib

rom

oet

han

e

(ug/

L)

1,2

-Dic

hlo

rob

enze

ne

(ug/

L)

1,4

-Dic

hlo

rob

enze

ne

(ug/

L)

tran

s-1

,4-D

ich

loro

-2-

bu

ten

e (u

g/L)

1,1

-Dic

hlo

roet

han

e

(ug/

L)

1,2

-Dic

hlo

roet

han

e

(ug/

L)

1,1

-Dic

hlo

roet

hen

e

(ug/

L)

cis-

1,2

-

Dic

hlo

roet

hen

e

(ug/

L)

tran

s-1

,2-

Dic

hlo

roet

hen

e

(ug/

L)

1,2

-Dic

hlo

rop

rop

ane

(ug/

L)

cis-

1,3

-

Dic

hlo

rop

rop

ene

(ug/

L)

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 1.5 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.07 <0.06 <1 <0.2 <0.2 <0.5 <0.5 <0.5 <0.08 <0.05 <0.05 <0.06

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 61 of 105

Page 254: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-8 3/17/2009

(cont.) 10/7/2009

3/16/2010

9/28/2010

9/26/2012

3/5/2014

10/16/2015

6/15/2017

MW-9R downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

9/13/2011

3/13/2012

9/26/2012

3/6/2013

9/12/2013

3/5/2014

10/9/2014

4/22/2015

11/12/2015

11/29/2017

MW-9R2 downgradient

5/25/2018

11/13/2018

MW-14R upgradient

9/14/2004

3/9/2005

9/28/2005

3/15/2006

1,2

-Dib

rom

o-3

-

chlo

rop

rop

ane

(ug/

L)

1,2

-Dib

rom

oet

han

e

(ug/

L)

1,2

-Dic

hlo

rob

enze

ne

(ug/

L)

1,4

-Dic

hlo

rob

enze

ne

(ug/

L)

tran

s-1

,4-D

ich

loro

-2-

bu

ten

e (u

g/L)

1,1

-Dic

hlo

roet

han

e

(ug/

L)

1,2

-Dic

hlo

roet

han

e

(ug/

L)

1,1

-Dic

hlo

roet

hen

e

(ug/

L)

cis-

1,2

-

Dic

hlo

roet

hen

e

(ug/

L)

tran

s-1

,2-

Dic

hlo

roet

hen

e

(ug/

L)

1,2

-Dic

hlo

rop

rop

ane

(ug/

L)

cis-

1,3

-

Dic

hlo

rop

rop

ene

(ug/

L)

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 0.16 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<1 <2 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.07 <0.06 <1 <0.2 <0.2 <0.5 <0.5 <0.5 <0.08 <0.05

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 62 of 105

Page 255: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-14R 9/20/2006

(cont.) 3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

9/28/2010

3/9/2011

9/13/2011

3/13/2012

9/26/2012

3/5/2013

9/10/2013

3/4/2014

10/6/2014

4/14/2015

10/14/2015

4/12/2016

8/2/2016

12/20/2016

6/13/2017

11/29/2017

5/23/2018

11/12/2018

MW-16R downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

1,2

-Dib

rom

o-3

-

chlo

rop

rop

ane

(ug/

L)

1,2

-Dib

rom

oet

han

e

(ug/

L)

1,2

-Dic

hlo

rob

enze

ne

(ug/

L)

1,4

-Dic

hlo

rob

enze

ne

(ug/

L)

tran

s-1

,4-D

ich

loro

-2-

bu

ten

e (u

g/L)

1,1

-Dic

hlo

roet

han

e

(ug/

L)

1,2

-Dic

hlo

roet

han

e

(ug/

L)

1,1

-Dic

hlo

roet

hen

e

(ug/

L)

cis-

1,2

-

Dic

hlo

roet

hen

e

(ug/

L)

tran

s-1

,2-

Dic

hlo

roet

hen

e

(ug/

L)

1,2

-Dic

hlo

rop

rop

ane

(ug/

L)

cis-

1,3

-

Dic

hlo

rop

rop

ene

(ug/

L)

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 63 of 105

Page 256: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-16R 9/13/2011

(cont.) 3/13/2012

9/26/2012

3/5/2013

9/11/2013

3/4/2014

10/23/2014

4/21/2015

10/16/2015

4/14/2016

12/20/2016

6/15/2017

12/1/2017

3/8/2018

5/24/2018

11/12/2018

MW-17R upgradient

9/14/2004

3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

9/28/2010

3/9/2011

1,2

-Dib

rom

o-3

-

chlo

rop

rop

ane

(ug/

L)

1,2

-Dib

rom

oet

han

e

(ug/

L)

1,2

-Dic

hlo

rob

enze

ne

(ug/

L)

1,4

-Dic

hlo

rob

enze

ne

(ug/

L)

tran

s-1

,4-D

ich

loro

-2-

bu

ten

e (u

g/L)

1,1

-Dic

hlo

roet

han

e

(ug/

L)

1,2

-Dic

hlo

roet

han

e

(ug/

L)

1,1

-Dic

hlo

roet

hen

e

(ug/

L)

cis-

1,2

-

Dic

hlo

roet

hen

e

(ug/

L)

tran

s-1

,2-

Dic

hlo

roet

hen

e

(ug/

L)

1,2

-Dic

hlo

rop

rop

ane

(ug/

L)

cis-

1,3

-

Dic

hlo

rop

rop

ene

(ug/

L)

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.07 <0.06 <1 <0.2 <0.2 <0.5 <0.5 <0.5 <0.08 <0.05

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 64 of 105

Page 257: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-17R 9/13/2011

(cont.) 3/13/2012

9/26/2012

3/5/2013

9/11/2013

3/5/2014

10/9/2014

4/21/2015

10/14/2015

4/12/2016

8/2/2016

12/20/2016

4/12/2017

6/14/2017

11/29/2017

5/23/2018

8/20/2018

11/9/2018

MW-18 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

1,2

-Dib

rom

o-3

-

chlo

rop

rop

ane

(ug/

L)

1,2

-Dib

rom

oet

han

e

(ug/

L)

1,2

-Dic

hlo

rob

enze

ne

(ug/

L)

1,4

-Dic

hlo

rob

enze

ne

(ug/

L)

tran

s-1

,4-D

ich

loro

-2-

bu

ten

e (u

g/L)

1,1

-Dic

hlo

roet

han

e

(ug/

L)

1,2

-Dic

hlo

roet

han

e

(ug/

L)

1,1

-Dic

hlo

roet

hen

e

(ug/

L)

cis-

1,2

-

Dic

hlo

roet

hen

e

(ug/

L)

tran

s-1

,2-

Dic

hlo

roet

hen

e

(ug/

L)

1,2

-Dic

hlo

rop

rop

ane

(ug/

L)

cis-

1,3

-

Dic

hlo

rop

rop

ene

(ug/

L)

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 65 of 105

Page 258: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-18 3/14/2000

(cont.) 9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

MW-19 downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

9/13/2011

3/13/2012

9/26/2012

3/5/2013

9/11/2013

11/20/2013

3/4/2014

6/9/2014

10/9/2014

4/21/2015

10/16/2015

2/3/2016

4/14/2016

8/3/2016

12/22/2016

4/12/2017

6/15/2017

12/1/2017

1,2

-Dib

rom

o-3

-

chlo

rop

rop

ane

(ug/

L)

1,2

-Dib

rom

oet

han

e

(ug/

L)

1,2

-Dic

hlo

rob

enze

ne

(ug/

L)

1,4

-Dic

hlo

rob

enze

ne

(ug/

L)

tran

s-1

,4-D

ich

loro

-2-

bu

ten

e (u

g/L)

1,1

-Dic

hlo

roet

han

e

(ug/

L)

1,2

-Dic

hlo

roet

han

e

(ug/

L)

1,1

-Dic

hlo

roet

hen

e

(ug/

L)

cis-

1,2

-

Dic

hlo

roet

hen

e

(ug/

L)

tran

s-1

,2-

Dic

hlo

roet

hen

e

(ug/

L)

1,2

-Dic

hlo

rop

rop

ane

(ug/

L)

cis-

1,3

-

Dic

hlo

rop

rop

ene

(ug/

L)

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 66 of 105

Page 259: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-19 3/8/2018

(cont.) 5/24/2018

11/12/2018

MW-20 downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

9/13/2011

3/13/2012

9/26/2012

3/6/2013

9/12/2013

11/20/2013

3/5/2014

6/9/2014

10/23/2014

4/21/2015

10/15/2015

4/13/2016

8/3/2016

12/20/2016

4/12/2017

6/14/2017

10/5/2017

12/1/2017

5/24/2018

11/13/2018

1/29/2019

1,2

-Dib

rom

o-3

-

chlo

rop

rop

ane

(ug/

L)

1,2

-Dib

rom

oet

han

e

(ug/

L)

1,2

-Dic

hlo

rob

enze

ne

(ug/

L)

1,4

-Dic

hlo

rob

enze

ne

(ug/

L)

tran

s-1

,4-D

ich

loro

-2-

bu

ten

e (u

g/L)

1,1

-Dic

hlo

roet

han

e

(ug/

L)

1,2

-Dic

hlo

roet

han

e

(ug/

L)

1,1

-Dic

hlo

roet

hen

e

(ug/

L)

cis-

1,2

-

Dic

hlo

roet

hen

e

(ug/

L)

tran

s-1

,2-

Dic

hlo

roet

hen

e

(ug/

L)

1,2

-Dic

hlo

rop

rop

ane

(ug/

L)

cis-

1,3

-

Dic

hlo

rop

rop

ene

(ug/

L)

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<1 <1 <1 <1 <1 0.256 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<5 <1 <1 <1 <2.5 0.39(J) <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 0.54(J) <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 0.46(J) <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1(J) <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 0.651(J) <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 0.431(J) <1 <1 <1 <1 <1 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<5 <1 <1 <1 <2.5 0.366(J) <1 <1 <1 <1 <1 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<5 <1 <1 <1 <2.5 0.263(J) <1 <1 <1 <1 <1 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<5 <1 <1 <1 <2.5 0.639(J) <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 0.475(J) <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 0.964(J) <1 <1 <1 <1 <1 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 67 of 105

Page 260: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-21 downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

9/13/2011

3/13/2012

9/26/2012

3/6/2013

9/12/2013

3/6/2014

10/8/2014

4/22/2015

10/14/2015

4/13/2016

12/20/2016

6/14/2017

11/29/2017

5/24/2018

11/13/2018

MW-22 downgradient

11/29/2017

3/8/2018

5/23/2018

8/20/2018

11/9/2018

1,2

-Dib

rom

o-3

-

chlo

rop

rop

ane

(ug/

L)

1,2

-Dib

rom

oet

han

e

(ug/

L)

1,2

-Dic

hlo

rob

enze

ne

(ug/

L)

1,4

-Dic

hlo

rob

enze

ne

(ug/

L)

tran

s-1

,4-D

ich

loro

-2-

bu

ten

e (u

g/L)

1,1

-Dic

hlo

roet

han

e

(ug/

L)

1,2

-Dic

hlo

roet

han

e

(ug/

L)

1,1

-Dic

hlo

roet

hen

e

(ug/

L)

cis-

1,2

-

Dic

hlo

roet

hen

e

(ug/

L)

tran

s-1

,2-

Dic

hlo

roet

hen

e

(ug/

L)

1,2

-Dic

hlo

rop

rop

ane

(ug/

L)

cis-

1,3

-

Dic

hlo

rop

rop

ene

(ug/

L)

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 0.283(J) <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 0.299(J) <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 68 of 105

Page 261: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

LEACHATEBLDGA downgradient

3/6/2013

9/11/2013

3/5/2014

10/9/2014

4/14/2015

4/16/2015

10/16/2015

4/13/2016

12/22/2016

6/15/2017

12/1/2017

5/25/2018

11/14/2018

LEACHATEBLDGB downgradient

3/6/2013

3/5/2014

10/9/2014

4/14/2015

4/16/2015

10/16/2015

4/13/2016

12/22/2016

6/15/2017

12/1/2017

5/25/2018

11/14/2018

LEACHATEBLDGC downgradient

9/11/2013

3/5/2014

10/9/2014

1,2

-Dib

rom

o-3

-

chlo

rop

rop

ane

(ug/

L)

1,2

-Dib

rom

oet

han

e

(ug/

L)

1,2

-Dic

hlo

rob

enze

ne

(ug/

L)

1,4

-Dic

hlo

rob

enze

ne

(ug/

L)

tran

s-1

,4-D

ich

loro

-2-

bu

ten

e (u

g/L)

1,1

-Dic

hlo

roet

han

e

(ug/

L)

1,2

-Dic

hlo

roet

han

e

(ug/

L)

1,1

-Dic

hlo

roet

hen

e

(ug/

L)

cis-

1,2

-

Dic

hlo

roet

hen

e

(ug/

L)

tran

s-1

,2-

Dic

hlo

roet

hen

e

(ug/

L)

1,2

-Dic

hlo

rop

rop

ane

(ug/

L)

cis-

1,3

-

Dic

hlo

rop

rop

ene

(ug/

L)

<5 <1 <1 4.1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 2.4 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 6.2 <2.5 0.32(J) 0.4(J) <1 <1 <1 <1 <1

<5 <1 <1 4.2 <2.5 0.32(J) <1 <1 <1 <1 <1 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<5 <1 <1 3.8 <2.5 <1 <1 <1 <1(J) <1 <1 <1

<5 <1 <1 3.47 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 4.78 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 5.42 <2.5 0.265(J) <1 <1 <1 <1 <1 <1

<5 <1 <1 3.95 <2.5 <1 <1 <1 <1 <1 <1 <1

<25 <5 <5 4.73(J) <12.5 <5 <5 <5 <5 <5 <5 <5

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 3.98 <2.5 <1 0.434(J) <1 0.467(J) <1 <1 <1

<5 <1 <1 1.9 <2.5 2.2 <1 <1 1.3 <1 <1 <1

<5 <1 <1 2.6 <2.5 2.3 <1 <1 1.4 <1 <1 <1

<5 <1 <1 2 <2.5 1.7 <1 <1 0.59(J) <1 <1 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<5 <1 <1 2 <2.5 1.8 <1 <1 1.3 <1 <1 <1

<5 <1 <1 2.3 <2.5 1.1 <1 <1 <1 <1 <1 <1

<5 <1 <1 4.2 <2.5 1.46 <1 <1 0.708(J) <1 <1 <1

<5 <1 <1 3.62 <2.5 0.863(J) <1 <1 <1 <1 <1 <1

<5 <1 <1 4.91 <2.5 1.38 <1 <1 0.934(J) <1 <1 <1

<5 <1 <1 4.06 <2.5 0.758(J) <1 <1 0.371(J) <1 <1 <1

<5 <1 <1 <1 <2.5 1.29 <1 <1 <1 <1 <1 <1

<5 <1 <1 6.03 <2.5 1.86 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 0.47(J) <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 69 of 105

Page 262: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

LEACHATEBLDGC 4/14/2015

(cont.) 4/16/2015

10/16/2015

4/13/2016

12/22/2016

6/15/2017

12/1/2017

5/25/2018

11/14/2018

MW-6 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

MW-6R downgradient

9/23/1998

3/16/1999

9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

3/24/2004

1,2

-Dib

rom

o-3

-

chlo

rop

rop

ane

(ug/

L)

1,2

-Dib

rom

oet

han

e

(ug/

L)

1,2

-Dic

hlo

rob

enze

ne

(ug/

L)

1,4

-Dic

hlo

rob

enze

ne

(ug/

L)

tran

s-1

,4-D

ich

loro

-2-

bu

ten

e (u

g/L)

1,1

-Dic

hlo

roet

han

e

(ug/

L)

1,2

-Dic

hlo

roet

han

e

(ug/

L)

1,1

-Dic

hlo

roet

hen

e

(ug/

L)

cis-

1,2

-

Dic

hlo

roet

hen

e

(ug/

L)

tran

s-1

,2-

Dic

hlo

roet

hen

e

(ug/

L)

1,2

-Dic

hlo

rop

rop

ane

(ug/

L)

cis-

1,3

-

Dic

hlo

rop

rop

ene

(ug/

L)

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 0.413(J) <2.5 <1 0.362(J) <1 <1 <1 <1 <1

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 1.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 70 of 105

Page 263: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-6R 9/14/2004

(cont.) 3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

9/28/2010

3/13/2012

9/26/2012

3/5/2014

6/9/2014

MW-9 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

3/14/2000

1,2

-Dib

rom

o-3

-

chlo

rop

rop

ane

(ug/

L)

1,2

-Dib

rom

oet

han

e

(ug/

L)

1,2

-Dic

hlo

rob

enze

ne

(ug/

L)

1,4

-Dic

hlo

rob

enze

ne

(ug/

L)

tran

s-1

,4-D

ich

loro

-2-

bu

ten

e (u

g/L)

1,1

-Dic

hlo

roet

han

e

(ug/

L)

1,2

-Dic

hlo

roet

han

e

(ug/

L)

1,1

-Dic

hlo

roet

hen

e

(ug/

L)

cis-

1,2

-

Dic

hlo

roet

hen

e

(ug/

L)

tran

s-1

,2-

Dic

hlo

roet

hen

e

(ug/

L)

1,2

-Dic

hlo

rop

rop

ane

(ug/

L)

cis-

1,3

-

Dic

hlo

rop

rop

ene

(ug/

L)

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.07 <0.06 <1 <0.2 <0.2 <0.5 <0.5 <0.5 <0.08 <0.05

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 0.26 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<5 <1 <1 <1 <2.5 <1 <1 <1 <1 <1 <1 <1

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 71 of 105

Page 264: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-9 9/20/2000

(cont.) 3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

3/24/2004

9/14/2004

3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

MW-14 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

1,2

-Dib

rom

o-3

-

chlo

rop

rop

ane

(ug/

L)

1,2

-Dib

rom

oet

han

e

(ug/

L)

1,2

-Dic

hlo

rob

enze

ne

(ug/

L)

1,4

-Dic

hlo

rob

enze

ne

(ug/

L)

tran

s-1

,4-D

ich

loro

-2-

bu

ten

e (u

g/L)

1,1

-Dic

hlo

roet

han

e

(ug/

L)

1,2

-Dic

hlo

roet

han

e

(ug/

L)

1,1

-Dic

hlo

roet

hen

e

(ug/

L)

cis-

1,2

-

Dic

hlo

roet

hen

e

(ug/

L)

tran

s-1

,2-

Dic

hlo

roet

hen

e

(ug/

L)

1,2

-Dic

hlo

rop

rop

ane

(ug/

L)

cis-

1,3

-

Dic

hlo

rop

rop

ene

(ug/

L)

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 1.4 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.07 <0.06 <1 <0.2 <0.2 <0.5 <0.5 <0.5 <0.08 <0.05

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 72 of 105

Page 265: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-14 3/16/1999

(cont.) 9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

3/24/2004

MW-16 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

1,2

-Dib

rom

o-3

-

chlo

rop

rop

ane

(ug/

L)

1,2

-Dib

rom

oet

han

e

(ug/

L)

1,2

-Dic

hlo

rob

enze

ne

(ug/

L)

1,4

-Dic

hlo

rob

enze

ne

(ug/

L)

tran

s-1

,4-D

ich

loro

-2-

bu

ten

e (u

g/L)

1,1

-Dic

hlo

roet

han

e

(ug/

L)

1,2

-Dic

hlo

roet

han

e

(ug/

L)

1,1

-Dic

hlo

roet

hen

e

(ug/

L)

cis-

1,2

-

Dic

hlo

roet

hen

e

(ug/

L)

tran

s-1

,2-

Dic

hlo

roet

hen

e

(ug/

L)

1,2

-Dic

hlo

rop

rop

ane

(ug/

L)

cis-

1,3

-

Dic

hlo

rop

rop

ene

(ug/

L)

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 1.4 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

1 0.5 0.2 0.2 1 0.5 0.5 1 1 1 0.5 0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 73 of 105

Page 266: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-16 9/17/2003

(cont.) 3/24/2004

9/14/2004

3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

MW-17 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

1,2

-Dib

rom

o-3

-

chlo

rop

rop

ane

(ug/

L)

1,2

-Dib

rom

oet

han

e

(ug/

L)

1,2

-Dic

hlo

rob

enze

ne

(ug/

L)

1,4

-Dic

hlo

rob

enze

ne

(ug/

L)

tran

s-1

,4-D

ich

loro

-2-

bu

ten

e (u

g/L)

1,1

-Dic

hlo

roet

han

e

(ug/

L)

1,2

-Dic

hlo

roet

han

e

(ug/

L)

1,1

-Dic

hlo

roet

hen

e

(ug/

L)

cis-

1,2

-

Dic

hlo

roet

hen

e

(ug/

L)

tran

s-1

,2-

Dic

hlo

roet

hen

e

(ug/

L)

1,2

-Dic

hlo

rop

rop

ane

(ug/

L)

cis-

1,3

-

Dic

hlo

rop

rop

ene

(ug/

L)

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 1.4 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.07 <0.06 <1 <0.2 <0.2 <0.5 <0.5 <0.5 <0.08 <0.05

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<0.2 <0.05 <0.1 <0.1 <2 <0.2 <0.2 <0.5 <0.5 <0.5 <0.18 <0.25

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<1 <0.5 <0.2 <0.2 <1 <0.5 <0.5 <1 <1 <1 <0.5 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 74 of 105

Page 267: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-17 3/27/2002

(cont.) 9/25/2002

4/1/2003

9/17/2003

1,2

-Dib

rom

o-3

-

chlo

rop

rop

ane

(ug/

L)

1,2

-Dib

rom

oet

han

e

(ug/

L)

1,2

-Dic

hlo

rob

enze

ne

(ug/

L)

1,4

-Dic

hlo

rob

enze

ne

(ug/

L)

tran

s-1

,4-D

ich

loro

-2-

bu

ten

e (u

g/L)

1,1

-Dic

hlo

roet

han

e

(ug/

L)

1,2

-Dic

hlo

roet

han

e

(ug/

L)

1,1

-Dic

hlo

roet

hen

e

(ug/

L)

cis-

1,2

-

Dic

hlo

roet

hen

e

(ug/

L)

tran

s-1

,2-

Dic

hlo

roet

hen

e

(ug/

L)

1,2

-Dic

hlo

rop

rop

ane

(ug/

L)

cis-

1,3

-

Dic

hlo

rop

rop

ene

(ug/

L)

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

<0.2 <0.05 <0.2 <0.2 <1 <0.5 <0.2 <1 <1 <1 <0.2 <0.5

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 75 of 105

Page 268: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-8 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

3/24/2004

9/14/2004

3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

tran

s-1

,3-

Dic

hlo

rop

rop

ene

(ug/

L)

Eth

ylb

enze

ne

(ug/

L)

2-H

exan

on

e (u

g/L)

Bro

mo

met

han

e

(ug/

L)

Ch

loro

met

han

e

(ug/

L)

Dib

rom

om

eth

ane

(ug/

L)

Met

hyl

ene

chlo

rid

e

(ug/

L)

2-B

uta

no

ne

[MEK

]

(ug/

L)

Iod

om

eth

ane

(ug/

L)

4-M

eth

yl-2

-

pen

tan

on

e [M

IBK

]

(ug/

L)

Styr

ene

(ug/

L)

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.3 <5 <1 <0.5 <1 <4 <5 <0.5 <5 <0.2

<0.5 <0.3 <5 <1 <0.5 <1 <4 <5 <0.5 <5 <0.2

<0.6 <0.2 <0.05 <1 <0.35 <5 <0.5 <0.26 <0.03 <0.08 <0.1

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 76 of 105

Page 269: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-8 3/17/2009

(cont.) 10/7/2009

3/16/2010

9/28/2010

9/26/2012

3/5/2014

10/16/2015

6/15/2017

MW-9R downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

9/13/2011

3/13/2012

9/26/2012

3/6/2013

9/12/2013

3/5/2014

10/9/2014

4/22/2015

11/12/2015

11/29/2017

MW-9R2 downgradient

5/25/2018

11/13/2018

MW-14R upgradient

9/14/2004

3/9/2005

9/28/2005

3/15/2006

tran

s-1

,3-

Dic

hlo

rop

rop

ene

(ug/

L)

Eth

ylb

enze

ne

(ug/

L)

2-H

exan

on

e (u

g/L)

Bro

mo

met

han

e

(ug/

L)

Ch

loro

met

han

e

(ug/

L)

Dib

rom

om

eth

ane

(ug/

L)

Met

hyl

ene

chlo

rid

e

(ug/

L)

2-B

uta

no

ne

[MEK

]

(ug/

L)

Iod

om

eth

ane

(ug/

L)

4-M

eth

yl-2

-

pen

tan

on

e [M

IBK

]

(ug/

L)

Styr

ene

(ug/

L)

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<1 <1 <1 <1 <1 <1 <1 <1 <10 <1 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 0.39(J) <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5(J) <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<0.5 <0.3 <5 <1 <0.5 <1 <4 <5 <0.5 <5 <0.2

<0.5 <0.3 <5 <1 <0.5 <1 <4 <5 <0.5 <5 <0.2

<0.05 <0.06 <0.6 <0.2 <0.05 <1 <0.35 <5 <0.5 <0.26 <0.03

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 77 of 105

Page 270: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-14R 9/20/2006

(cont.) 3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

9/28/2010

3/9/2011

9/13/2011

3/13/2012

9/26/2012

3/5/2013

9/10/2013

3/4/2014

10/6/2014

4/14/2015

10/14/2015

4/12/2016

8/2/2016

12/20/2016

6/13/2017

11/29/2017

5/23/2018

11/12/2018

MW-16R downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

tran

s-1

,3-

Dic

hlo

rop

rop

ene

(ug/

L)

Eth

ylb

enze

ne

(ug/

L)

2-H

exan

on

e (u

g/L)

Bro

mo

met

han

e

(ug/

L)

Ch

loro

met

han

e

(ug/

L)

Dib

rom

om

eth

ane

(ug/

L)

Met

hyl

ene

chlo

rid

e

(ug/

L)

2-B

uta

no

ne

[MEK

]

(ug/

L)

Iod

om

eth

ane

(ug/

L)

4-M

eth

yl-2

-

pen

tan

on

e [M

IBK

]

(ug/

L)

Styr

ene

(ug/

L)

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<1 <1 <1 <1 <1 <1 <5 <1 <10 <1 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 78 of 105

Page 271: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-16R 9/13/2011

(cont.) 3/13/2012

9/26/2012

3/5/2013

9/11/2013

3/4/2014

10/23/2014

4/21/2015

10/16/2015

4/14/2016

12/20/2016

6/15/2017

12/1/2017

3/8/2018

5/24/2018

11/12/2018

MW-17R upgradient

9/14/2004

3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

9/28/2010

3/9/2011

tran

s-1

,3-

Dic

hlo

rop

rop

ene

(ug/

L)

Eth

ylb

enze

ne

(ug/

L)

2-H

exan

on

e (u

g/L)

Bro

mo

met

han

e

(ug/

L)

Ch

loro

met

han

e

(ug/

L)

Dib

rom

om

eth

ane

(ug/

L)

Met

hyl

ene

chlo

rid

e

(ug/

L)

2-B

uta

no

ne

[MEK

]

(ug/

L)

Iod

om

eth

ane

(ug/

L)

4-M

eth

yl-2

-

pen

tan

on

e [M

IBK

]

(ug/

L)

Styr

ene

(ug/

L)

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5(J) <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<0.5 <0.3 <5 <1 <0.5 <1 <4 <5 <0.5 <5 <0.2

<0.5 <0.3 <5 <1 <0.5 <1 <4 <5 <0.5 <5 <0.2

<0.05 <0.06 <0.6 <0.2 <0.05 <1 <0.35 <5 <0.5 <0.26 <0.03

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 79 of 105

Page 272: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-17R 9/13/2011

(cont.) 3/13/2012

9/26/2012

3/5/2013

9/11/2013

3/5/2014

10/9/2014

4/21/2015

10/14/2015

4/12/2016

8/2/2016

12/20/2016

4/12/2017

6/14/2017

11/29/2017

5/23/2018

8/20/2018

11/9/2018

MW-18 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

tran

s-1

,3-

Dic

hlo

rop

rop

ene

(ug/

L)

Eth

ylb

enze

ne

(ug/

L)

2-H

exan

on

e (u

g/L)

Bro

mo

met

han

e

(ug/

L)

Ch

loro

met

han

e

(ug/

L)

Dib

rom

om

eth

ane

(ug/

L)

Met

hyl

ene

chlo

rid

e

(ug/

L)

2-B

uta

no

ne

[MEK

]

(ug/

L)

Iod

om

eth

ane

(ug/

L)

4-M

eth

yl-2

-

pen

tan

on

e [M

IBK

]

(ug/

L)

Styr

ene

(ug/

L)

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5(J) <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 80 of 105

Page 273: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-18 3/14/2000

(cont.) 9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

MW-19 downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

9/13/2011

3/13/2012

9/26/2012

3/5/2013

9/11/2013

11/20/2013

3/4/2014

6/9/2014

10/9/2014

4/21/2015

10/16/2015

2/3/2016

4/14/2016

8/3/2016

12/22/2016

4/12/2017

6/15/2017

12/1/2017

tran

s-1

,3-

Dic

hlo

rop

rop

ene

(ug/

L)

Eth

ylb

enze

ne

(ug/

L)

2-H

exan

on

e (u

g/L)

Bro

mo

met

han

e

(ug/

L)

Ch

loro

met

han

e

(ug/

L)

Dib

rom

om

eth

ane

(ug/

L)

Met

hyl

ene

chlo

rid

e

(ug/

L)

2-B

uta

no

ne

[MEK

]

(ug/

L)

Iod

om

eth

ane

(ug/

L)

4-M

eth

yl-2

-

pen

tan

on

e [M

IBK

]

(ug/

L)

Styr

ene

(ug/

L)

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<1 <1 <1 <1 <1 <1 <5 <1 <10 <1 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 1.8(R) 1.1(J) <15 <10 <10 <1

n/a n/a n/a n/a n/a <1 n/a n/a n/a n/a n/a

<1 0.4(J) <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 0.45(J) <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 0.45(J)

<1 <1 <10 <5 <2.5 <1 <5(J) <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 81 of 105

Page 274: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-19 3/8/2018

(cont.) 5/24/2018

11/12/2018

MW-20 downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

9/13/2011

3/13/2012

9/26/2012

3/6/2013

9/12/2013

11/20/2013

3/5/2014

6/9/2014

10/23/2014

4/21/2015

10/15/2015

4/13/2016

8/3/2016

12/20/2016

4/12/2017

6/14/2017

10/5/2017

12/1/2017

5/24/2018

11/13/2018

1/29/2019

tran

s-1

,3-

Dic

hlo

rop

rop

ene

(ug/

L)

Eth

ylb

enze

ne

(ug/

L)

2-H

exan

on

e (u

g/L)

Bro

mo

met

han

e

(ug/

L)

Ch

loro

met

han

e

(ug/

L)

Dib

rom

om

eth

ane

(ug/

L)

Met

hyl

ene

chlo

rid

e

(ug/

L)

2-B

uta

no

ne

[MEK

]

(ug/

L)

Iod

om

eth

ane

(ug/

L)

4-M

eth

yl-2

-

pen

tan

on

e [M

IBK

]

(ug/

L)

Styr

ene

(ug/

L)

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<1 <1 <1 <1 <1 <1 <5 <1 <10 <1 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 0.5(JR) <5 <15 <10 <10 <1

n/a n/a n/a n/a n/a <1 n/a n/a n/a n/a n/a

<1 0.5(J) <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 82 of 105

Page 275: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-21 downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

9/13/2011

3/13/2012

9/26/2012

3/6/2013

9/12/2013

3/6/2014

10/8/2014

4/22/2015

10/14/2015

4/13/2016

12/20/2016

6/14/2017

11/29/2017

5/24/2018

11/13/2018

MW-22 downgradient

11/29/2017

3/8/2018

5/23/2018

8/20/2018

11/9/2018

tran

s-1

,3-

Dic

hlo

rop

rop

ene

(ug/

L)

Eth

ylb

enze

ne

(ug/

L)

2-H

exan

on

e (u

g/L)

Bro

mo

met

han

e

(ug/

L)

Ch

loro

met

han

e

(ug/

L)

Dib

rom

om

eth

ane

(ug/

L)

Met

hyl

ene

chlo

rid

e

(ug/

L)

2-B

uta

no

ne

[MEK

]

(ug/

L)

Iod

om

eth

ane

(ug/

L)

4-M

eth

yl-2

-

pen

tan

on

e [M

IBK

]

(ug/

L)

Styr

ene

(ug/

L)

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<1 <1 <1 <1 <1 <1 <5 <1 <10 <1 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5(J) <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 83 of 105

Page 276: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

LEACHATEBLDGA downgradient

3/6/2013

9/11/2013

3/5/2014

10/9/2014

4/14/2015

4/16/2015

10/16/2015

4/13/2016

12/22/2016

6/15/2017

12/1/2017

5/25/2018

11/14/2018

LEACHATEBLDGB downgradient

3/6/2013

3/5/2014

10/9/2014

4/14/2015

4/16/2015

10/16/2015

4/13/2016

12/22/2016

6/15/2017

12/1/2017

5/25/2018

11/14/2018

LEACHATEBLDGC downgradient

9/11/2013

3/5/2014

10/9/2014

tran

s-1

,3-

Dic

hlo

rop

rop

ene

(ug/

L)

Eth

ylb

enze

ne

(ug/

L)

2-H

exan

on

e (u

g/L)

Bro

mo

met

han

e

(ug/

L)

Ch

loro

met

han

e

(ug/

L)

Dib

rom

om

eth

ane

(ug/

L)

Met

hyl

ene

chlo

rid

e

(ug/

L)

2-B

uta

no

ne

[MEK

]

(ug/

L)

Iod

om

eth

ane

(ug/

L)

4-M

eth

yl-2

-

pen

tan

on

e [M

IBK

]

(ug/

L)

Styr

ene

(ug/

L)

<1 2.5 <10 <5 <2.5 <1 <5 18 <10 2.4 0.93

<1 2.1 <10 <5 <2.5 <1 <5 <15 <10 2.8 <1

<1 13 <10 <5 <2.5 <1 <5 <15 <10 <10 0.51(J)

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 9.1 43 <5 <2.5 <1 <5 2800 <10 23 <1(J)

<1 1.49 <10 <5 <2.5 <1 <5 6.38(J) <10 <10 <1

<1 1.02 <10 <5 <2.5 <1 <5 <15 <10 3.91(J) <1

<1 3.14 <10 <5 <2.5 <1 <5 <15 <10 3.68(J) 0.64(J)

<1 8.99 <10 <5 <2.5 <1 <5 3380 <10 74.1 1.04

<5 9.05 <50 <25 <12.5 <5 <25 869 <50 27.7(J) <5

<1 9.89 6.31(J) <5 <2.5 <1 <5 1530 <10 46.5 1.04

<1 7.2 <10 <5 <2.5 <1 <5 777 <10 28.8 0.698(J)

<1 <1 <10 <5 <2.5 <1 1.4 6.6 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <10 <5 <2.5 <1 <5 9200 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 0.53(J) <10 <5 <2.5 <1 <5 6.33(J) <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 47.5 <10 3(J) <1

<1 0.55 <10 <5 <2.5 <1 <5 180 <10 36 <1

<1 3.2 <10 <5 <2.5 <1 <5 250 <10 17 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 2.4(J) <1

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 84 of 105

Page 277: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

LEACHATEBLDGC 4/14/2015

(cont.) 4/16/2015

10/16/2015

4/13/2016

12/22/2016

6/15/2017

12/1/2017

5/25/2018

11/14/2018

MW-6 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

MW-6R downgradient

9/23/1998

3/16/1999

9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

3/24/2004

tran

s-1

,3-

Dic

hlo

rop

rop

ene

(ug/

L)

Eth

ylb

enze

ne

(ug/

L)

2-H

exan

on

e (u

g/L)

Bro

mo

met

han

e

(ug/

L)

Ch

loro

met

han

e

(ug/

L)

Dib

rom

om

eth

ane

(ug/

L)

Met

hyl

ene

chlo

rid

e

(ug/

L)

2-B

uta

no

ne

[MEK

]

(ug/

L)

Iod

om

eth

ane

(ug/

L)

4-M

eth

yl-2

-

pen

tan

on

e [M

IBK

]

(ug/

L)

Styr

ene

(ug/

L)

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10(J) <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 3.04(J) <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 7.57(J) <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 85 of 105

Page 278: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-6R 9/14/2004

(cont.) 3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

9/28/2010

3/13/2012

9/26/2012

3/5/2014

6/9/2014

MW-9 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

3/14/2000

tran

s-1

,3-

Dic

hlo

rop

rop

ene

(ug/

L)

Eth

ylb

enze

ne

(ug/

L)

2-H

exan

on

e (u

g/L)

Bro

mo

met

han

e

(ug/

L)

Ch

loro

met

han

e

(ug/

L)

Dib

rom

om

eth

ane

(ug/

L)

Met

hyl

ene

chlo

rid

e

(ug/

L)

2-B

uta

no

ne

[MEK

]

(ug/

L)

Iod

om

eth

ane

(ug/

L)

4-M

eth

yl-2

-

pen

tan

on

e [M

IBK

]

(ug/

L)

Styr

ene

(ug/

L)

<0.5 <0.3 <5 <1 <0.5 <1 <4 <5 <0.5 <5 <0.2

<0.5 <0.3 <5 <1 <0.5 <1 <4 <5 <0.5 <5 <0.2

<0.05 <0.06 <0.6 <0.2 <0.05 <1 <0.35 <5 <0.5 <0.26 <0.03

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 1.43 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 <1 <5 <5 <2.5 <1 <5 <15 <5 <5 <1

<1 0.73 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<1 <1 <10 <5 <2.5 <1 <5 <15 <10 <10 <1

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 86 of 105

Page 279: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-9 9/20/2000

(cont.) 3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

3/24/2004

9/14/2004

3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

MW-14 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

tran

s-1

,3-

Dic

hlo

rop

rop

ene

(ug/

L)

Eth

ylb

enze

ne

(ug/

L)

2-H

exan

on

e (u

g/L)

Bro

mo

met

han

e

(ug/

L)

Ch

loro

met

han

e

(ug/

L)

Dib

rom

om

eth

ane

(ug/

L)

Met

hyl

ene

chlo

rid

e

(ug/

L)

2-B

uta

no

ne

[MEK

]

(ug/

L)

Iod

om

eth

ane

(ug/

L)

4-M

eth

yl-2

-

pen

tan

on

e [M

IBK

]

(ug/

L)

Styr

ene

(ug/

L)

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.3 <5 <1 <0.5 <1 <4 <5 <0.5 <5 <0.2

<0.5 <0.3 <5 <1 <0.5 <1 <4 <5 <0.5 <5 <0.2

<0.05 <0.06 <0.6 <0.2 <0.05 <1 <0.35 <5 <0.5 <0.26 <0.03

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 87 of 105

Page 280: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-14 3/16/1999

(cont.) 9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

3/24/2004

MW-16 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

tran

s-1

,3-

Dic

hlo

rop

rop

ene

(ug/

L)

Eth

ylb

enze

ne

(ug/

L)

2-H

exan

on

e (u

g/L)

Bro

mo

met

han

e

(ug/

L)

Ch

loro

met

han

e

(ug/

L)

Dib

rom

om

eth

ane

(ug/

L)

Met

hyl

ene

chlo

rid

e

(ug/

L)

2-B

uta

no

ne

[MEK

]

(ug/

L)

Iod

om

eth

ane

(ug/

L)

4-M

eth

yl-2

-

pen

tan

on

e [M

IBK

]

(ug/

L)

Styr

ene

(ug/

L)

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

0.5 0.2 1 1 1 1 0.1 5 0.5 5 0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 88 of 105

Page 281: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-16 9/17/2003

(cont.) 3/24/2004

9/14/2004

3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

MW-17 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

tran

s-1

,3-

Dic

hlo

rop

rop

ene

(ug/

L)

Eth

ylb

enze

ne

(ug/

L)

2-H

exan

on

e (u

g/L)

Bro

mo

met

han

e

(ug/

L)

Ch

loro

met

han

e

(ug/

L)

Dib

rom

om

eth

ane

(ug/

L)

Met

hyl

ene

chlo

rid

e

(ug/

L)

2-B

uta

no

ne

[MEK

]

(ug/

L)

Iod

om

eth

ane

(ug/

L)

4-M

eth

yl-2

-

pen

tan

on

e [M

IBK

]

(ug/

L)

Styr

ene

(ug/

L)

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.3 <5 <1 <0.5 <1 <4 <5 <0.5 <5 <0.2

<0.5 <0.3 <5 <1 <0.5 <1 <4 <5 <0.5 <5 <0.2

<0.05 <0.06 <0.6 <0.2 <0.05 <1 <0.35 <5 <0.5 <0.26 <0.03

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.25 <0.1 <0.6 <0.2 <0.2 <1 <0.35 <5 <0.5 <1.8 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <1 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 89 of 105

Page 282: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-17 3/27/2002

(cont.) 9/25/2002

4/1/2003

9/17/2003

tran

s-1

,3-

Dic

hlo

rop

rop

ene

(ug/

L)

Eth

ylb

enze

ne

(ug/

L)

2-H

exan

on

e (u

g/L)

Bro

mo

met

han

e

(ug/

L)

Ch

loro

met

han

e

(ug/

L)

Dib

rom

om

eth

ane

(ug/

L)

Met

hyl

ene

chlo

rid

e

(ug/

L)

2-B

uta

no

ne

[MEK

]

(ug/

L)

Iod

om

eth

ane

(ug/

L)

4-M

eth

yl-2

-

pen

tan

on

e [M

IBK

]

(ug/

L)

Styr

ene

(ug/

L)

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

<0.5 <0.2 <1 <1 <0.5 <1 <0.1 <5 <0.5 <5 <0.2

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 90 of 105

Page 283: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-8 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

3/24/2004

9/14/2004

3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

1,1

,1,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

1,1

,2,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

Tolu

ene

(ug/

L)

1,1

,1-

Tric

hlo

roet

han

e

(ug/

L)

1,1

,2-

Tric

hlo

roet

han

e

(ug/

L)

Tric

hlo

rofl

uo

rom

eth

ane

(ug/

L)

1,2

,3-

Tric

hlo

rop

rop

ane

(ug/

L)

Vin

yl a

ceta

te (

ug/

L)

Vin

yl c

hlo

rid

e (u

g/L)

Xyl

enes

, to

tal (

ug/

L)

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <1 <1 <0.5 <0.5 <0.2 <5 <0.6 <1

<1 <0.2 <1 <1 <0.5 <0.5 <0.2 <5 <0.6 <1

<0.05 <0.05 <0.03 <0.05 <0.05 <0.16 <0.04 <0.2 <1 n/a

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 91 of 105

Page 284: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-8 3/17/2009

(cont.) 10/7/2009

3/16/2010

9/28/2010

9/26/2012

3/5/2014

10/16/2015

6/15/2017

MW-9R downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

9/13/2011

3/13/2012

9/26/2012

3/6/2013

9/12/2013

3/5/2014

10/9/2014

4/22/2015

11/12/2015

11/29/2017

MW-9R2 downgradient

5/25/2018

11/13/2018

MW-14R upgradient

9/14/2004

3/9/2005

9/28/2005

3/15/2006

1,1

,1,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

1,1

,2,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

Tolu

ene

(ug/

L)

1,1

,1-

Tric

hlo

roet

han

e

(ug/

L)

1,1

,2-

Tric

hlo

roet

han

e

(ug/

L)

Tric

hlo

rofl

uo

rom

eth

ane

(ug/

L)

1,2

,3-

Tric

hlo

rop

rop

ane

(ug/

L)

Vin

yl a

ceta

te (

ug/

L)

Vin

yl c

hlo

rid

e (u

g/L)

Xyl

enes

, to

tal (

ug/

L)

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<1 <1 0.214 <1 <1 <1 <1 <10 <1 <1

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 0.32 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 3(J)

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<1 <0.2 <1 <1 <0.5 <0.5 <0.2 <5 <0.6 <1

<1 <0.2 <1 <1 <0.5 <0.5 <0.2 <5 <0.6 <1

<0.08 <0.1 <0.05 <0.07 <0.03 <0.05 <0.11 <0.16 <0.04 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 92 of 105

Page 285: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-14R 9/20/2006

(cont.) 3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

9/28/2010

3/9/2011

9/13/2011

3/13/2012

9/26/2012

3/5/2013

9/10/2013

3/4/2014

10/6/2014

4/14/2015

10/14/2015

4/12/2016

8/2/2016

12/20/2016

6/13/2017

11/29/2017

5/23/2018

11/12/2018

MW-16R downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

1,1

,1,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

1,1

,2,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

Tolu

ene

(ug/

L)

1,1

,1-

Tric

hlo

roet

han

e

(ug/

L)

1,1

,2-

Tric

hlo

roet

han

e

(ug/

L)

Tric

hlo

rofl

uo

rom

eth

ane

(ug/

L)

1,2

,3-

Tric

hlo

rop

rop

ane

(ug/

L)

Vin

yl a

ceta

te (

ug/

L)

Vin

yl c

hlo

rid

e (u

g/L)

Xyl

enes

, to

tal (

ug/

L)

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 3(J)

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<1 <1 <1 <1 <1 <1 <1 <10 <1 <1

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 93 of 105

Page 286: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-16R 9/13/2011

(cont.) 3/13/2012

9/26/2012

3/5/2013

9/11/2013

3/4/2014

10/23/2014

4/21/2015

10/16/2015

4/14/2016

12/20/2016

6/15/2017

12/1/2017

3/8/2018

5/24/2018

11/12/2018

MW-17R upgradient

9/14/2004

3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

9/28/2010

3/9/2011

1,1

,1,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

1,1

,2,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

Tolu

ene

(ug/

L)

1,1

,1-

Tric

hlo

roet

han

e

(ug/

L)

1,1

,2-

Tric

hlo

roet

han

e

(ug/

L)

Tric

hlo

rofl

uo

rom

eth

ane

(ug/

L)

1,2

,3-

Tric

hlo

rop

rop

ane

(ug/

L)

Vin

yl a

ceta

te (

ug/

L)

Vin

yl c

hlo

rid

e (u

g/L)

Xyl

enes

, to

tal (

ug/

L)

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 1.3(J)

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<1 <0.2 <1 <1 <0.5 <0.5 <0.2 <5 <0.6 <1

<1 <0.2 <1 <1 <0.5 <0.5 <0.2 <5 <0.6 <1

<0.08 <0.1 <0.05 <0.07 <0.03 <0.05 <0.11 <0.16 <0.04 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 94 of 105

Page 287: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-17R 9/13/2011

(cont.) 3/13/2012

9/26/2012

3/5/2013

9/11/2013

3/5/2014

10/9/2014

4/21/2015

10/14/2015

4/12/2016

8/2/2016

12/20/2016

4/12/2017

6/14/2017

11/29/2017

5/23/2018

8/20/2018

11/9/2018

MW-18 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

1,1

,1,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

1,1

,2,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

Tolu

ene

(ug/

L)

1,1

,1-

Tric

hlo

roet

han

e

(ug/

L)

1,1

,2-

Tric

hlo

roet

han

e

(ug/

L)

Tric

hlo

rofl

uo

rom

eth

ane

(ug/

L)

1,2

,3-

Tric

hlo

rop

rop

ane

(ug/

L)

Vin

yl a

ceta

te (

ug/

L)

Vin

yl c

hlo

rid

e (u

g/L)

Xyl

enes

, to

tal (

ug/

L)

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 2.3(J)

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 95 of 105

Page 288: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-18 3/14/2000

(cont.) 9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

MW-19 downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

9/13/2011

3/13/2012

9/26/2012

3/5/2013

9/11/2013

11/20/2013

3/4/2014

6/9/2014

10/9/2014

4/21/2015

10/16/2015

2/3/2016

4/14/2016

8/3/2016

12/22/2016

4/12/2017

6/15/2017

12/1/2017

1,1

,1,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

1,1

,2,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

Tolu

ene

(ug/

L)

1,1

,1-

Tric

hlo

roet

han

e

(ug/

L)

1,1

,2-

Tric

hlo

roet

han

e

(ug/

L)

Tric

hlo

rofl

uo

rom

eth

ane

(ug/

L)

1,2

,3-

Tric

hlo

rop

rop

ane

(ug/

L)

Vin

yl a

ceta

te (

ug/

L)

Vin

yl c

hlo

rid

e (u

g/L)

Xyl

enes

, to

tal (

ug/

L)

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<1 <1 <1 <1 <1 <1 <1 <10 <1 <1

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 3.4

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 2.1(J)

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 96 of 105

Page 289: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-19 3/8/2018

(cont.) 5/24/2018

11/12/2018

MW-20 downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

9/13/2011

3/13/2012

9/26/2012

3/6/2013

9/12/2013

11/20/2013

3/5/2014

6/9/2014

10/23/2014

4/21/2015

10/15/2015

4/13/2016

8/3/2016

12/20/2016

4/12/2017

6/14/2017

10/5/2017

12/1/2017

5/24/2018

11/13/2018

1/29/2019

1,1

,1,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

1,1

,2,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

Tolu

ene

(ug/

L)

1,1

,1-

Tric

hlo

roet

han

e

(ug/

L)

1,1

,2-

Tric

hlo

roet

han

e

(ug/

L)

Tric

hlo

rofl

uo

rom

eth

ane

(ug/

L)

1,2

,3-

Tric

hlo

rop

rop

ane

(ug/

L)

Vin

yl a

ceta

te (

ug/

L)

Vin

yl c

hlo

rid

e (u

g/L)

Xyl

enes

, to

tal (

ug/

L)

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<1 <1 <1 <1 <1 <1 <1 <10 <1 <1

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 4.2(R)

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <1 <1 <1 <5 <2.5 <10 0.29(J) <3

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <1 <1 <1 <5 <2.5 <10 0.35(J) <3

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 97 of 105

Page 290: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-21 downgradient

9/28/2010

12/30/2010

3/9/2011

6/3/2011

9/13/2011

3/13/2012

9/26/2012

3/6/2013

9/12/2013

3/6/2014

10/8/2014

4/22/2015

10/14/2015

4/13/2016

12/20/2016

6/14/2017

11/29/2017

5/24/2018

11/13/2018

MW-22 downgradient

11/29/2017

3/8/2018

5/23/2018

8/20/2018

11/9/2018

1,1

,1,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

1,1

,2,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

Tolu

ene

(ug/

L)

1,1

,1-

Tric

hlo

roet

han

e

(ug/

L)

1,1

,2-

Tric

hlo

roet

han

e

(ug/

L)

Tric

hlo

rofl

uo

rom

eth

ane

(ug/

L)

1,2

,3-

Tric

hlo

rop

rop

ane

(ug/

L)

Vin

yl a

ceta

te (

ug/

L)

Vin

yl c

hlo

rid

e (u

g/L)

Xyl

enes

, to

tal (

ug/

L)

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<1 <1 <1 <1 <1 <1 <1 <10 <1 <1

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 0.45(J) 2(J)

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <1 <1 <1 <5 <2.5 <10 0.324(J) <3

<1 <1 <1 <1 <1 <5 <2.5 <10 0.398(J) <3

<1 <1 <1 <1 <1 <5 <2.5 <10 0.412(J) <3

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 98 of 105

Page 291: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

LEACHATEBLDGA downgradient

3/6/2013

9/11/2013

3/5/2014

10/9/2014

4/14/2015

4/16/2015

10/16/2015

4/13/2016

12/22/2016

6/15/2017

12/1/2017

5/25/2018

11/14/2018

LEACHATEBLDGB downgradient

3/6/2013

3/5/2014

10/9/2014

4/14/2015

4/16/2015

10/16/2015

4/13/2016

12/22/2016

6/15/2017

12/1/2017

5/25/2018

11/14/2018

LEACHATEBLDGC downgradient

9/11/2013

3/5/2014

10/9/2014

1,1

,1,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

1,1

,2,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

Tolu

ene

(ug/

L)

1,1

,1-

Tric

hlo

roet

han

e

(ug/

L)

1,1

,2-

Tric

hlo

roet

han

e

(ug/

L)

Tric

hlo

rofl

uo

rom

eth

ane

(ug/

L)

1,2

,3-

Tric

hlo

rop

rop

ane

(ug/

L)

Vin

yl a

ceta

te (

ug/

L)

Vin

yl c

hlo

rid

e (u

g/L)

Xyl

enes

, to

tal (

ug/

L)

<1 <1 11 <1 <1 <5 <2.5 <10 0.64 27

<1 <1 1.6 <1 <1 <5 <2.5 <10 <1 12

<1 <1 4.8(J) <1 <1 <5 <2.5 <10 0.98(J) 29

<1 <1 3.3(J) <1 <1 <5 <2.5 <10 0.76(J) 24

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 25 <1 <1 <5 <2.5 <10 <1(J) 19

<1 <1 4.61(J) <1 <1 <5 <2.5 <10 0.532(J) 17.6

<1 <1 10.2 <1 <1 <5 <2.5 <10 0.566(J) 23.2

<1 <1 6.46 <1 <1 <5 <2.5 <10 0.571(J) 20.7

<1 <1 9.21 <1 <1 <5 <2.5 <10 0.529(J) 16.6

<5 <5 8.78 <5 <5 <25 <12.5 <50 <5 15.6

<1 <1 8.01 <1 <1 <5 <2.5 <10 <1 15.2

<1 <1 5.57 <1 <1 <5 <2.5 <10 0.399(J) 10.4

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 2.3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 1.4(J)

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 1.2(J)

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 1.23(J)

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 0.414(J) <1 <1 <5 <2.5 <10 0.374(J) 2.14(J)

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <1 <1 <1 <5 <2.5 <10 0.475(J) <3

<1 <1 <1 <1 <1 <5 <2.5 <10 0.701(J) <3

<1 <1 58 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 320 <1 <1 <5 <2.5 <10 3.6 2.7(J)

<1 <1 <5 <1 <1 <5 <2.5 <10 1.9 <3

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 99 of 105

Page 292: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

LEACHATEBLDGC 4/14/2015

(cont.) 4/16/2015

10/16/2015

4/13/2016

12/22/2016

6/15/2017

12/1/2017

5/25/2018

11/14/2018

MW-6 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

MW-6R downgradient

9/23/1998

3/16/1999

9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

3/24/2004

1,1

,1,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

1,1

,2,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

Tolu

ene

(ug/

L)

1,1

,1-

Tric

hlo

roet

han

e

(ug/

L)

1,1

,2-

Tric

hlo

roet

han

e

(ug/

L)

Tric

hlo

rofl

uo

rom

eth

ane

(ug/

L)

1,2

,3-

Tric

hlo

rop

rop

ane

(ug/

L)

Vin

yl a

ceta

te (

ug/

L)

Vin

yl c

hlo

rid

e (u

g/L)

Xyl

enes

, to

tal (

ug/

L)

n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

<1 <1 <5 <1 <1 <5 <2.5 <10 1.7 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 2.8 1.14(J)

<1 <1 <1 <1 <1 <5 <2.5 <10 1.66 5.23

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 1.38(J)

<1 <1 <1 <1 <1 <5 <2.5 <10 0.48(J) <3

<1 <1 0.975(J) <1 <1 <5 <2.5 <10 <1 2.2(J)

<1 <1 <1 <1 <1 <5 <2.5 <10 <1 4.28

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 100 of 105

Page 293: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-6R 9/14/2004

(cont.) 3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

9/28/2010

3/13/2012

9/26/2012

3/5/2014

6/9/2014

MW-9 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

3/14/2000

1,1

,1,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

1,1

,2,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

Tolu

ene

(ug/

L)

1,1

,1-

Tric

hlo

roet

han

e

(ug/

L)

1,1

,2-

Tric

hlo

roet

han

e

(ug/

L)

Tric

hlo

rofl

uo

rom

eth

ane

(ug/

L)

1,2

,3-

Tric

hlo

rop

rop

ane

(ug/

L)

Vin

yl a

ceta

te (

ug/

L)

Vin

yl c

hlo

rid

e (u

g/L)

Xyl

enes

, to

tal (

ug/

L)

<1 <0.2 <1 <1 <0.5 <0.5 <0.2 <5 <0.6 <1

<1 <0.2 <1 <1 <0.5 <0.5 <0.2 <5 <0.6 <1

<0.08 <0.1 <0.05 <0.07 <0.03 <0.05 <0.11 <0.16 <0.04 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 0.12 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <5 <1 <3

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 5.8(R)

<1 <1 <5 <1 <1 <5 <2.5 <10 <1 <3

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 101 of 105

Page 294: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-9 9/20/2000

(cont.) 3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

3/24/2004

9/14/2004

3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

MW-14 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

1,1

,1,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

1,1

,2,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

Tolu

ene

(ug/

L)

1,1

,1-

Tric

hlo

roet

han

e

(ug/

L)

1,1

,2-

Tric

hlo

roet

han

e

(ug/

L)

Tric

hlo

rofl

uo

rom

eth

ane

(ug/

L)

1,2

,3-

Tric

hlo

rop

rop

ane

(ug/

L)

Vin

yl a

ceta

te (

ug/

L)

Vin

yl c

hlo

rid

e (u

g/L)

Xyl

enes

, to

tal (

ug/

L)

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <1 <1 <0.5 <0.5 <0.2 <5 <0.6 <1

<1 <0.2 <1 <1 <0.5 <0.5 <0.2 <5 <0.6 <1

<0.08 <0.1 <0.05 <0.07 <0.03 <0.05 <0.11 <0.16 <0.04 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 102 of 105

Page 295: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-14 3/16/1999

(cont.) 9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

9/17/2003

3/24/2004

MW-16 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

3/27/2002

9/25/2002

4/1/2003

1,1

,1,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

1,1

,2,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

Tolu

ene

(ug/

L)

1,1

,1-

Tric

hlo

roet

han

e

(ug/

L)

1,1

,2-

Tric

hlo

roet

han

e

(ug/

L)

Tric

hlo

rofl

uo

rom

eth

ane

(ug/

L)

1,2

,3-

Tric

hlo

rop

rop

ane

(ug/

L)

Vin

yl a

ceta

te (

ug/

L)

Vin

yl c

hlo

rid

e (u

g/L)

Xyl

enes

, to

tal (

ug/

L)

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

1 0.2 0.1 0.1 0.5 1 0.2 5 1 0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 103 of 105

Page 296: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-16 9/17/2003

(cont.) 3/24/2004

9/14/2004

3/9/2005

9/28/2005

3/15/2006

9/20/2006

3/6/2007

9/19/2007

4/1/2008

9/18/2008

3/17/2009

10/7/2009

3/16/2010

MW-17 downgradient

3/16/1995

5/23/1995

6/29/1995

7/25/1995

2/8/1996

8/6/1996

2/26/1997

9/10/1997

4/9/1998

9/23/1998

3/16/1999

9/29/1999

3/14/2000

9/20/2000

3/21/2001

9/26/2001

1,1

,1,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

1,1

,2,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

Tolu

ene

(ug/

L)

1,1

,1-

Tric

hlo

roet

han

e

(ug/

L)

1,1

,2-

Tric

hlo

roet

han

e

(ug/

L)

Tric

hlo

rofl

uo

rom

eth

ane

(ug/

L)

1,2

,3-

Tric

hlo

rop

rop

ane

(ug/

L)

Vin

yl a

ceta

te (

ug/

L)

Vin

yl c

hlo

rid

e (u

g/L)

Xyl

enes

, to

tal (

ug/

L)

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <1 <1 <0.5 <0.5 <0.2 <5 <0.6 <1

<1 <0.2 <1 <1 <0.5 <0.5 <0.2 <5 <0.6 <1

<0.08 <0.1 <0.05 <0.07 <0.03 <0.05 <0.11 <0.16 <0.04 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<0.25 <0.1 <0.25 <0.5 <0.5 <0.4 <0.42 <2.4 <0.5 <0.2

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 104 of 105

Page 297: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Legacy Landfill

Permit No. 0254-S1-R4

Groundwater Database

MW-17 3/27/2002

(cont.) 9/25/2002

4/1/2003

9/17/2003

1,1

,1,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

1,1

,2,2

-

Tetr

ach

loro

eth

ane

(ug/

L)

Tolu

ene

(ug/

L)

1,1

,1-

Tric

hlo

roet

han

e

(ug/

L)

1,1

,2-

Tric

hlo

roet

han

e

(ug/

L)

Tric

hlo

rofl

uo

rom

eth

ane

(ug/

L)

1,2

,3-

Tric

hlo

rop

rop

ane

(ug/

L)

Vin

yl a

ceta

te (

ug/

L)

Vin

yl c

hlo

rid

e (u

g/L)

Xyl

enes

, to

tal (

ug/

L)

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

<1 <0.2 <0.1 <0.1 <0.5 <1 <0.2 <5 <1 <0.6

B: analyte was detected in associated blank sample.

J: analyte was detected below the PQL; value is an estimate.

O: value is a statistical outlier.

R: value was rejected due to suspected error; not used in statistics. Page 105 of 105

Page 298: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

APPENDIX D Background Data Used for Statistics

Page 299: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Appendix D: Background Used for Statistics February 8, 2019

D-1

BACKGROUND DATA

Background Data Sets for Prediction Limit Evaluations In accordance with the groundwater sampling and analysis plan (Terracon 2012)

background data sets are comprised of data collected from existing wells. Background is

evaluated and updated every 2 to 3 years, as recommended in EPA's Statistical Analysis of

Groundwater Monitoring Data at RCRA Facilities: Unified Guidance (Unified Guidance).

Background data were last evaluated and updated, where applicable, prior to the first half

of 2016 monitoring period.

Data Evaluated using the Mann-Kendall/Sen’s Slope test for trends Well-parameter pairs evaluated using the Mann-Kendall/Sen’s Slope test for trends are

identified in Table D.1. These well-parameter pairs were found to have non-stationary

background data sets during the last background data evaluation. As such, they are tested for

compliance using the Mann-Kendall/Sen’s Slope test for trends as opposed to a prediction limit

test, which requires background data to have a stationary statistical distribution.

Data Not Statistically Evaluated At this time, monitoring wells MW-9R2 and MW-22 do not have sufficient data for

statistical analysis. Monitoring well MW-22 is currently being sampled quarterly to collect a

minimum of 8 to 10 data for background. A total of four rounds of semiannual data will be

collected from MW-9R2 for statistical comparison to data from former well MW-9R. Data from

former well MW-9R will be used as background for MW-9R2 as long as the evaluation shows

that the two wells produce geochemically similar groundwater.

Outliers and Rejected Data in Background EPA Unified Guidance recommends that background data be screened for potential

outliers. However, it also advises that outliers not be removed unless a source of error or reason

for the discrepancy can be identified. As advised in the Unified Guidance, select removal of

Page 300: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Appendix D: Background Used for Statistics February 8, 2019

D-2

extreme outliers without knowledge of error may be warranted to improve environmental

protection, but removal of all outliers can mask real and legitimate changes in background data.

Outliers excluded from background data are flagged with an “O” in the historical database and

are excluded from statistical analyses. Data that are excluded from the historical database based

on independent evidence of error or that are suspected of being unrepresentative of groundwater

quality due to excessively high sample turbidity are flagged with an “R” (for rejected) and are

also excluded from statistical analyses. These data are summarized in Table D.2.

Table D.1. Well-parameter pairs under formal trend testing.

Parameter Well

Chloride MW-8, MW-17R Chromium MW-19

Copper MW-8 Iron MW-8, MW-14R

Manganese MW-8 pH MW-8

Sulfate MW-8, MW-14R, MW-17R TDS MW-8

Page 301: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Appendix D: Background Used for Statistics February 8, 2019

D-3

Table D.2. Data excluded from statistical analysis.

Well Date Analyte

Value

(mg/L) Flag Reason

MW-8 9/28/2005 Antimony 0.0973 R Value is suspect and appears to be an error. MW-8 9/28/2005 Dissolved Solids <0.0015 O Statistically low compared to background dataset. MW-8 9/28/2005 Manganese 45.2 O Statistically high compared to background dataset. MW-8 9/28/2005 pH 22.2 (su) R pH value outside of possible range. MW-8 9/28/2005 Sulfate <0.002 R Value is suspect and appears to be an error. MW-14R 3/15/2006 TOC 19 O Value is suspect and appears to be an error. MW-16R 6/3/2011 TOC 46 O Statistically high compared to background dataset. MW-16R 3/5/2013 Beryllium 0.0012 R Turbidity of 846 NTUs during sampling. MW-16R 3/5/2013 Chromium 0.16 R Turbidity of 846 NTUs during sampling. MW-16R 3/5/2013 Cobalt 0.0086 R Turbidity of 846 NTUs during sampling. MW-16R 3/5/2013 Copper 0.039 R Turbidity of 846 NTUs during sampling. MW-16R 3/5/2013 Iron 11 R Turbidity of 846 NTUs during sampling. MW-16R 3/5/2013 Lead 0.024 R Turbidity of 846 NTUs during sampling. MW-16R 3/5/2013 Nickel 0.14 R Turbidity of 846 NTUs during sampling. MW-16R 3/5/2013 Vanadium 0.023 R Turbidity of 846 NTUs during sampling. MW-16R 9/11/2013 Copper 0.24 O Statistically high compared to background dataset. MW-16R 10/23/2014 TOC 52 O Statistically high compared to background dataset. MW-17R 4/1/2008 Chromium 0.0152 R Turbidity of 30.6 NTUs during sampling. MW-17R 3/17/2009 Chromium 0.0114 R Turbidity of 52 NTUs during sampling. MW-17R 3/13/2012 Chromium 0.021 R Turbidity of 23.2 NTUs during sampling. MW-17R 9/11/2013 Chromium 0.44 R Turbidity of 86 NTUs during sampling. MW-17R 9/11/2013 Copper 0.016 R Turbidity of 86 NTUs during sampling. MW-17R 9/11/2013 Iron 5.8 R Turbidity of 86 NTUs during sampling. MW-17R 9/11/2013 Manganese 0.15 R Turbidity of 86 NTUs during sampling. MW-17R 9/11/2013 Nickel 0.38 R Turbidity of 86 NTUs during sampling. MW-19 3/5/2013 Chromium 0.47 R Turbidity of 141 NTUs during sampling. MW-19 3/5/2013 Nickel 0.29 R Turbidity of 141 NTUs during sampling. MW-19 9/11/2013 Bromochloromethane 0.0018 R Resample on 11/20/2013 disconfirmed detection. MW-19 9/11/2013 Copper 0.33 O Statistically high compared to background dataset. MW-19 9/11/2013 Dibromomethane 0.0018 R Resample on 11/20/2013 disconfirmed detection. MW-20 6/3/2011 TOC 51 O Statistically high compared to background dataset. MW-20 9/26/2012 Vanadium 0.044 R Turbidity of 17.3 NTUs during sampling. MW-20 3/6/2013 Chromium 0.031 R Turbidity of 461 NTUs during sampling. MW-20 3/6/2013 Lead 0.0054 R Turbidity of 461 NTUs during sampling. MW-20 3/6/2013 Nickel 0.028 R Turbidity of 461 NTUs during sampling. MW-20 3/6/2013 Zinc 0.026 R Turbidity of 461 NTUs during sampling. MW-20 9/12/2013 Bromochloromethane 0.00055 R Resample on 11/20/2013 disconfirmed detection. MW-20 9/12/2013 Dibromomethane 0.0005 R Resample on 11/20/2013 disconfirmed detection. MW-20 3/5/2014 Xylenes, Total 0.0042 R Resample on 6/09/2014 disconfirmed detection MW-21 6/3/2011 TOC 73 O Statistically high compared to background dataset. MW-21 3/6/2013 Lead 0.0057 R Statistically high compared to background dataset. MW-21 9/12/2013 Copper 0.059 O Statistically high compared to background dataset.

Page 302: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Sanitas™ v.9.6.12 For the statistical analyses of ground water by FTN Associates only. UG

Date RangesDate: 2/8/2019 10:17 AM

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Page 1

Antimony (mg/L)MW-8 background:3/16/1995-9/26/2012MW-14R background:3/16/1995-10/16/2015MW-16R background:3/16/1995-10/16/2015MW-17R background:3/16/1995-10/16/2015MW-19 background:3/16/1995-10/16/2015MW-20 background:3/16/1995-10/16/2015MW-21 background:3/16/1995-10/16/2015

Arsenic (mg/L)MW-8 background:9/23/1998-9/26/2012MW-14R background:3/16/1995-9/26/2012MW-16R background:3/16/1995-10/16/2015MW-17R background:3/16/1995-10/16/2015MW-19 background:3/16/1995-10/16/2015MW-20 background:3/16/1995-10/16/2015MW-21 background:3/16/1995-4/22/2015

Barium (mg/L)MW-8 background:4/9/1998-9/26/2012MW-14R background:3/16/1995-10/7/2009MW-16R background:3/16/1995-10/16/2015MW-17R background:3/16/1995-9/13/2011MW-19 background:3/16/1995-10/16/2015MW-20 background:3/16/1995-10/16/2015MW-21 background:3/16/1995-10/16/2015

Beryllium (mg/L)MW-8 background:3/16/1995-9/26/2012MW-14R background:3/16/1995-10/16/2015MW-16R background:3/16/1995-10/16/2015MW-17R background:3/16/1995-10/16/2015MW-19 background:3/16/1995-10/16/2015MW-20 background:3/16/1995-10/16/2015MW-21 background:3/16/1995-10/16/2015

Cadmium (mg/L)MW-8 background:3/16/1995-9/26/2012MW-14R background:3/16/1995-10/16/2015MW-16R background:3/16/1995-10/16/2015MW-17R background:3/16/1995-10/16/2015MW-19 background:3/16/1995-10/16/2015MW-20 background:3/16/1995-3/6/2014MW-21 background:3/16/1995-10/16/2015

Chloride (mg/L)MW-14R background:3/16/1995-10/7/2009MW-16R background:3/16/1995-10/16/2015MW-19 background:3/16/1995-10/16/2015MW-20 background:3/16/1995-10/16/2015MW-21 background:3/16/1995-10/16/2015

Chromium (mg/L)MW-8 background:3/9/2005-9/26/2012MW-14R background:3/16/1995-10/16/2015MW-16R background:3/16/1995-10/16/2015MW-17R background:3/16/1995-9/26/2012MW-20 background:3/16/1995-10/16/2015MW-21 background:3/16/1995-3/6/2014

Cobalt (mg/L)MW-8 background:3/16/1995-9/26/2012MW-14R background:9/19/2007-10/16/2015MW-16R background:3/16/1995-10/16/2015MW-17R background:9/19/2007-10/16/2015MW-19 background:3/16/1995-10/16/2015MW-20 background:3/16/1995-10/16/2015MW-21 background:3/16/1995-10/16/2015

Copper (mg/L)MW-14R background:3/16/1995-10/16/2015MW-16R background:3/16/1995-10/16/2015MW-17R background:3/16/1995-10/16/2015MW-19 background:3/16/1995-10/16/2015MW-20 background:3/16/1995-4/22/2015MW-21 background:3/16/1995-10/16/2015

Dissolved solids (mg/L)MW-14R background:3/16/1995-10/16/2015

Page 303: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Sanitas™ v.9.6.12 For the statistical analyses of ground water by FTN Associates only. UG

Date RangesDate: 2/8/2019 10:17 AM

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Page 2

MW-16R background:3/16/1995-10/16/2015MW-17R background:3/16/1995-10/16/2015MW-19 background:3/16/1995-10/16/2015MW-20 background:3/16/1995-4/22/2015MW-21 background:3/16/1995-10/16/2015

Iron (mg/L)MW-16R background:3/16/1995-10/16/2015MW-17R background:3/16/1995-10/16/2015MW-19 background:3/16/1995-10/16/2015MW-20 background:3/16/1995-4/22/2015MW-21 background:3/16/1995-10/16/2015

Lead (mg/L)MW-8 background:3/15/2006-9/26/2012MW-14R background:3/15/2006-10/16/2015MW-16R background:3/16/1995-10/16/2015MW-17R background:3/15/2006-9/26/2012MW-19 background:3/16/1995-10/16/2015MW-20 background:3/16/1995-10/16/2015MW-21 background:3/16/1995-10/16/2015

Manganese (mg/L)MW-14R background:3/16/1995-10/7/2009MW-16R background:3/16/1995-10/16/2015MW-17R background:3/16/1995-10/7/2009MW-19 background:3/16/1995-10/16/2015MW-20 background:3/16/1995-10/16/2015MW-21 background:3/16/1995-4/22/2015

Nickel (mg/L)MW-8 background:4/9/1998-9/26/2012MW-14R background:3/16/1995-10/16/2015MW-16R background:3/16/1995-10/16/2015MW-17R background:3/16/1995-10/16/2015MW-19 background:3/16/1995-3/6/2014MW-20 background:3/16/1995-10/16/2015MW-21 background:3/16/1995-10/16/2015

pH (su)MW-14R background:3/16/1995-10/16/2015MW-16R background:3/16/1995-10/16/2015MW-17R background:3/16/1995-10/16/2015MW-19 background:3/16/1995-2/3/2016MW-20 background:3/16/1995-10/16/2015MW-21 background:3/16/1995-10/16/2015

Selenium (mg/L)MW-8 background:3/16/1995-9/26/2012MW-14R background:9/18/2008-10/16/2015MW-16R background:3/16/1995-10/16/2015MW-17R background:9/18/2008-10/16/2015MW-19 background:3/16/1995-10/16/2015MW-20 background:3/16/1995-10/16/2015MW-21 background:3/16/1995-10/16/2015

Silver (mg/L)MW-8 background:3/16/1995-9/26/2012MW-14R background:3/16/1995-10/16/2015MW-16R background:3/16/1995-10/16/2015MW-17R background:3/16/1995-10/16/2015MW-19 background:3/16/1995-10/16/2015MW-20 background:3/16/1995-10/16/2015MW-21 background:3/16/1995-10/16/2015

Sulfate (mg/L)MW-16R background:3/16/1995-10/16/2015MW-19 background:3/16/1995-10/16/2015MW-20 background:3/16/1995-10/16/2015MW-21 background:3/16/1995-10/16/2015

Thallium (mg/L)MW-8 background:3/16/1995-9/26/2012MW-14R background:3/16/1995-10/16/2015MW-16R background:3/16/1995-10/16/2015MW-17R background:3/16/1995-10/16/2015MW-19 background:3/16/1995-10/16/2015MW-20 background:3/16/1995-10/16/2015MW-21 background:3/16/1995-10/16/2015

Page 304: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Sanitas™ v.9.6.12 For the statistical analyses of ground water by FTN Associates only. UG

Date RangesDate: 2/8/2019 10:17 AM

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Page 3

Vanadium (mg/L)MW-8 background:3/16/1995-9/26/2012MW-14R background:3/16/1995-10/16/2015MW-16R background:3/16/1995-10/16/2015MW-17R background:3/16/1995-10/16/2015MW-19 background:3/16/1995-10/16/2015MW-20 background:3/9/2011-10/16/2015MW-21 background:3/16/1995-10/16/2015

Zinc (mg/L)MW-8 background:3/16/1995-9/26/2012MW-14R background:3/16/1995-10/16/2015MW-16R background:3/16/1995-10/16/2015MW-17R background:3/16/1995-10/16/2015MW-19 background:3/16/1995-10/16/2015MW-20 background:3/16/1995-10/16/2015MW-21 background:3/16/1995-10/16/2015

Page 305: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

APPENDIX E Distributional Plots

Page 306: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Time-Series Plots

Page 307: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

0.1

0.2

0.3

0.4

0.5

3/16/95 12/8/99 9/1/04 5/26/09 2/18/14 11/13/18

MW-8

MW-9R2

MW-14R (bg)

MW-16R

MW-17R (bg)

MW-19

MW-20

MW-21

MW-22

Time Series

Constituent: Barium Analysis Run 11/21/2018 10:11 AM View: 1H2018 Distributional

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Hollow symbols indicate censored values.

0

14

28

42

56

70

3/16/95 12/8/99 9/1/04 5/26/09 2/18/14 11/13/18

MW-8

MW-9R2

MW-14R (bg)

MW-16R

MW-17R (bg)

MW-19

MW-20

MW-21

MW-22

Time Series

Constituent: Chloride Analysis Run 11/21/2018 10:11 AM View: 1H2018 Distributional

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Hollow symbols indicate censored values.

Page 308: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

160

320

480

640

800

3/16/95 12/8/99 8/31/04 5/26/09 2/17/14 11/12/18

MW-8

MW-9R2

MW-14R (bg)

MW-16R

MW-17R (bg)

MW-19

MW-20

MW-21

MW-22

Time Series

Constituent: Dissolved solids Analysis Run 11/21/2018 10:11 AM View: 1H2018 Distributional

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

0

1.8

3.6

5.4

7.2

9

3/16/95 12/8/99 9/1/04 5/26/09 2/18/14 11/13/18

MW-8

MW-9R2

MW-14R (bg)

MW-16R

MW-17R (bg)

MW-19

MW-20

MW-21

MW-22

Time Series

Constituent: Iron Analysis Run 11/21/2018 10:11 AM View: 1H2018 Distributional

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Hollow symbols indicate censored values.

Page 309: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

0.4

0.8

1.2

1.6

2

3/16/95 12/8/99 9/1/04 5/26/09 2/18/14 11/13/18

MW-8

MW-9R2

MW-14R (bg)

MW-16R

MW-17R (bg)

MW-19

MW-20

MW-21

MW-22

Time Series

Constituent: Manganese Analysis Run 11/21/2018 10:11 AM View: 1H2018 Distributional

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Hollow symbols indicate censored values.

0

1.6

3.2

4.8

6.4

8

3/16/95 12/8/99 9/1/04 5/26/09 2/18/14 11/13/18

MW-8

MW-9R2

MW-14R (bg)

MW-16R

MW-17R (bg)

MW-19

MW-20

MW-21

MW-22

Time Series

Constituent: pH Analysis Run 11/21/2018 10:11 AM View: 1H2018 Distributional

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

su

Page 310: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

40

80

120

160

200

3/16/95 12/8/99 9/1/04 5/26/09 2/18/14 11/13/18

MW-8

MW-9R2

MW-14R (bg)

MW-16R

MW-17R (bg)

MW-19

MW-20

MW-21

MW-22

Time Series

Constituent: Sulfate Analysis Run 11/21/2018 10:11 AM View: 1H2018 Distributional

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Page 311: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Box-and-Whisker Plots

Page 312: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

0.1

0.2

0.3

0.4

0.5

Box & Whiskers Plot

Constituent: Barium Analysis Run 11/21/2018 10:13 AM View: 1H2018 Distributional

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

MW

-8n=38 28%

nds

______

+

MW

-9R2

n=2

______+

MW-14R (bg)

n=30

______

+

MW

-16R

n=19

______+

MW-17R (bg)

n=29 3%nds

______+

MW

-19

n=19

______+

MW

-20

n=20

______+

MW

-21

n=19

______+

MW

-22

n=5

______+

0

14

28

42

56

70

Box & Whiskers Plot

Constituent: Chloride Analysis Run 11/21/2018 10:13 AM View: 1H2018 Distributional

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

MW

-8n=38 2%

nds

______+

MW

-9R2

n=2

______+

MW-14R (bg)

n=30

______

+

MW

-16R

n=19

______+

MW-17R (bg)

n=29 3%nds

______+

MW

-19

n=19

______+

MW

-20

n=19

______+

MW

-21

n=19

______+

MW

-22

n=5

______+

Page 313: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

160

320

480

640

800

Box & Whiskers Plot

Constituent: Dissolved solids Analysis Run 11/21/2018 10:13 AM View: 1H2018 Distributional

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

MW

-8n=37

______+

MW

-9R2

n=1

______+

MW-14R (bg)

n=29

______+

MW

-16R

n=19

______+

MW-17R (bg)

n=29

______+

MW

-19

n=19

______+

MW

-20

n=19

______+

MW

-21

n=18

______+

MW

-22

n=5

______+

0

1.8

3.6

5.4

7.2

9

Box & Whiskers Plot

Constituent: Iron Analysis Run 11/21/2018 10:13 AM View: 1H2018 Distributional

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

MW

-8n=37 8%

nds

______+

MW

-9R2

n=2

______+

MW-14R (bg)

n=30 3%nds

______+

MW

-16R

n=18

______+

MW-17R (bg)

n=28 7%nds

______+

MW

-19

n=19

______+

MW

-20

n=19

______+

MW

-21

n=19

______+

MW

-22

n=5

______+

Page 314: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

0.4

0.8

1.2

1.6

2

Box & Whiskers Plot

Constituent: Manganese Analysis Run 11/21/2018 10:13 AM View: 1H2018 Distributional

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

MW

-8n=37 2%

nds

______+

MW

-9R2

n=2

______+

MW-14R (bg)

n=29

______+

MW

-16R

n=19

______+

MW-17R (bg)

n=28 25%nds

______+

MW

-19

n=19

______+

MW

-20

n=19

______+

MW

-21

n=19

______+

MW

-22

n=5

______+

0

1.6

3.2

4.8

6.4

8

Box & Whiskers Plot

Constituent: pH Analysis Run 11/21/2018 10:13 AM View: 1H2018 Distributional

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

su

MW

-8n=37

______+

MW

-9R2

n=2

______+

MW-14R (bg)

n=29

______+

MW

-16R

n=19

______+

MW-17R (bg)

n=31

______+

MW

-19

n=24

______+

MW

-20

n=21

______+

MW

-21

n=19

______+

MW

-22

n=5

______+

Page 315: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

40

80

120

160

200

Box & Whiskers Plot

Constituent: Sulfate Analysis Run 11/21/2018 10:13 AM View: 1H2018 Distributional

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

MW

-8n=37

______+

MW

-9R2

n=2

______+

MW-14R (bg)

n=29

______+

MW

-16R

n=19

______+

MW-17R (bg)

n=29

______+

MW

-19

n=19

______+

MW

-20

n=19

______+

MW

-21

n=19

______

+

MW

-22

n=5

______+

Page 316: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

APPENDIX F Statistical Results

Page 317: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Prediction Limit Results

Page 318: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

0.08

0.16

0.24

0.32

0.4

9/14/04 7/15/07 5/14/10 3/14/13 1/12/16 11/12/18

MW-14R background

MW-14R compliance

Limit = 0.2796

Prediction Limit

Intrawell Parametric

Constituent: Barium Analysis Run 11/21/2018 10:52 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Background Data Summary (based on x^4 transformation): Mean=0.001742, Std. Dev.=0.001654, n=11. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.793, critical = 0.792. Kappa = 2.642 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Within Limit

0

0.06

0.12

0.18

0.24

0.3

9/28/10 5/13/12 12/27/13 8/13/15 3/28/17 11/12/18

MW-16R background

MW-16R compliance

Limit = 0.255

Prediction Limit

Intrawell Parametric

Constituent: Barium Analysis Run 11/21/2018 10:52 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Background Data Summary: Mean=0.1508, Std. Dev.=0.04173, n=13. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.8582, critical = 0.814. Kappa = 2.498 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Within Limit

Page 319: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

0.04

0.08

0.12

0.16

0.2

9/14/04 7/14/07 5/13/10 3/12/13 1/10/16 11/9/18

MW-17R background

MW-17R compliance

Limit = 0.1252

Prediction Limit

Intrawell Parametric

Constituent: Barium Analysis Run 11/21/2018 10:52 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Hollow symbols indicate censored values.

Background Data Summary (based on square transformation): Mean=0.006354, Std. Dev.=0.003887, n=15, 6.667% NDs. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.8797, critical = 0.835. Kappa = 2.398 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Within Limit

0

0.08

0.16

0.24

0.32

0.4

9/28/10 5/13/12 12/27/13 8/13/15 3/28/17 11/12/18

MW-19 background

MW-19 compliance

Limit = 0.3526

Prediction Limit

Intrawell Parametric

Constituent: Barium Analysis Run 11/21/2018 10:52 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Background Data Summary: Mean=0.228, Std. Dev.=0.04988, n=13. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.961, critical = 0.814. Kappa = 2.498 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Within Limit

Page 320: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

0.06

0.12

0.18

0.24

0.3

9/28/10 5/13/12 12/28/13 8/13/15 3/29/17 11/13/18

MW-20 background

MW-20 compliance

Limit = 0.2219

Prediction Limit

Intrawell Parametric

Constituent: Barium Analysis Run 11/21/2018 10:52 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Background Data Summary: Mean=0.1737, Std. Dev.=0.01931, n=13. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.9604, critical = 0.814. Kappa = 2.498 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Exceeds Limit

0

0.06

0.12

0.18

0.24

0.3

9/28/10 5/13/12 12/28/13 8/13/15 3/29/17 11/13/18

MW-21 background

MW-21 compliance

Limit = 0.2847

Prediction Limit

Intrawell Parametric

Constituent: Barium Analysis Run 11/21/2018 10:52 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Background Data Summary: Mean=0.1844, Std. Dev.=0.04012, n=13. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.8891, critical = 0.814. Kappa = 2.498 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Within Limit

Page 321: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

14

28

42

56

70

9/14/04 7/15/07 5/14/10 3/14/13 1/12/16 11/12/18

MW-14R background

MW-14R compliance

Limit = 38.77

Prediction Limit

Intrawell Parametric

Constituent: Chloride Analysis Run 11/21/2018 10:52 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Background Data Summary: Mean=25.96, Std. Dev.=4.847, n=11. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.956, critical = 0.792. Kappa = 2.642 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Exceeds Limit

0

4

8

12

16

20

9/28/10 5/13/12 12/27/13 8/13/15 3/28/17 11/12/18

MW-16R background

MW-16R compliance

Limit = 12.9

Prediction Limit

Intrawell Non-parametric

Constituent: Chloride Analysis Run 11/21/2018 10:52 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Non-parametric test used in lieu of parametric prediction limit because the Shapiro Wilk normality test showed the data to be non-normal at the 0.01 alpha level. Limit is highest of 13 background values. Well-constituent pair annual alpha = 0.01929. Individual comparison alpha = 0.009692 (1 of 2).

Within Limit

Page 322: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

4

8

12

16

20

9/28/10 5/13/12 12/27/13 8/13/15 3/28/17 11/12/18

MW-19 background

MW-19 compliance

Limit = 19.93

Prediction Limit

Intrawell Parametric

Constituent: Chloride Analysis Run 11/21/2018 10:52 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Background Data Summary: Mean=14.89, Std. Dev.=2.016, n=13. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.9785, critical = 0.814. Kappa = 2.498 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Within Limit

0

4

8

12

16

20

9/28/10 5/13/12 12/28/13 8/13/15 3/29/17 11/13/18

MW-20 background

MW-20 compliance

Limit = 15

Prediction Limit

Intrawell Non-parametric

Constituent: Chloride Analysis Run 11/21/2018 10:52 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Non-parametric test used in lieu of parametric prediction limit because the Shapiro Wilk normality test showed the data to be non-normal at the 0.01 alpha level. Limit is highest of 13 background values. Well-constituent pair annual alpha = 0.01929. Individual comparison alpha = 0.009692 (1 of 2).

Within Limit

Page 323: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

4

8

12

16

20

9/28/10 5/13/12 12/28/13 8/13/15 3/29/17 11/13/18

MW-21 background

MW-21 compliance

Limit = 12

Prediction Limit

Intrawell Non-parametric

Constituent: Chloride Analysis Run 11/21/2018 10:52 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Non-parametric test used in lieu of parametric prediction limit because the Shapiro Wilk normality test showed the data to be non-normal at the 0.01 alpha level. Limit is highest of 13 background values. Well-constituent pair annual alpha = 0.01929. Individual comparison alpha = 0.009692 (1 of 2).

Within Limit

0

160

320

480

640

800

9/14/04 7/15/07 5/14/10 3/14/13 1/12/16 11/12/18

MW-14R background

MW-14R compliance

Limit = 698.6

Prediction Limit

Intrawell Parametric

Constituent: Dissolved solids Analysis Run 11/21/2018 10:52 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Background Data Summary (based on cube root transformation): Mean=8.55, Std. Dev.=0.1481, n=23. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.8816, critical = 0.881. Kappa = 2.185 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Within Limit

Page 324: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

100

200

300

400

500

9/28/10 5/13/12 12/27/13 8/13/15 3/28/17 11/12/18

MW-16R background

MW-16R compliance

Limit = 415.8

Prediction Limit

Intrawell Parametric

Constituent: Dissolved solids Analysis Run 11/21/2018 10:53 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Background Data Summary: Mean=331.8, Std. Dev.=33.64, n=13. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.9457, critical = 0.814. Kappa = 2.498 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Within Limit

0

80

160

240

320

400

9/14/04 7/14/07 5/13/10 3/12/13 1/10/16 11/9/18

MW-17R background

MW-17R compliance

Limit = 365.3

Prediction Limit

Intrawell Parametric

Constituent: Dissolved solids Analysis Run 11/21/2018 10:53 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Background Data Summary: Mean=308.8, Std. Dev.=25.86, n=23. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.8882, critical = 0.881. Kappa = 2.185 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Within Limit

Page 325: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

120

240

360

480

600

9/28/10 5/13/12 12/27/13 8/13/15 3/28/17 11/12/18

MW-19 background

MW-19 compliance

Limit = 513.4

Prediction Limit

Intrawell Parametric

Constituent: Dissolved solids Analysis Run 11/21/2018 10:53 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Background Data Summary: Mean=414.8, Std. Dev.=39.43, n=13. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.8976, critical = 0.814. Kappa = 2.498 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Within Limit

0

100

200

300

400

500

9/28/10 5/13/12 12/28/13 8/13/15 3/29/17 11/13/18

MW-20 background

MW-20 compliance

Limit = 391.1

Prediction Limit

Intrawell Parametric

Constituent: Dissolved solids Analysis Run 11/26/2018 1:57 PM View: 2018-1H Trend

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.11 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Background Data Summary: Mean=317.3, Std. Dev.=28.95, n=12. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.949, critical = 0.805. Kappa = 2.548 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Exceeds Limit

Page 326: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

140

280

420

560

700

9/28/10 5/13/12 12/28/13 8/13/15 3/29/17 11/13/18

MW-21 background

MW-21 compliance

Limit = 618.7

Prediction Limit

Intrawell Parametric

Constituent: Dissolved solids Analysis Run 11/26/2018 1:57 PM View: 2018-1H Trend

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.11 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Background Data Summary: Mean=421.4, Std. Dev.=78.98, n=13. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.8473, critical = 0.814. Kappa = 2.498 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Within Limit

0

1.2

2.4

3.6

4.8

6

9/28/10 5/13/12 12/27/13 8/13/15 3/28/17 11/12/18

MW-16R background

MW-16R compliance

Limit = 5.5

Prediction Limit

Intrawell Non-parametric

Constituent: Iron Analysis Run 11/21/2018 10:53 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Non-parametric test used in lieu of parametric prediction limit because the Shapiro Wilk normality test showed the data to be non-normal at the 0.01 alpha level. Limit is highest of 12 background values. Well-constituent pair annual alpha = 0.02143. Individual comparison alpha = 0.01077 (1 of 2).

Within Limit

Page 327: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

1

2

3

4

5

9/14/04 7/14/07 5/13/10 3/12/13 1/10/16 11/9/18

MW-17R background

MW-17R compliance

Limit = 5

Prediction Limit

Intrawell Non-parametric

Constituent: Iron Analysis Run 11/21/2018 10:53 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Hollow symbols indicate censored values.

Non-parametric test used in lieu of parametric prediction limit because the Shapiro Wilk normality test showed the data to be non-normal at the 0.01 alpha level. Limit is highest of 22 background values. 9.091% NDs. Well-constituent pair annual alpha = 0.007401. Individual comparison alpha = 0.003707 (1 of 2).

Within Limit

0

1.2

2.4

3.6

4.8

6

9/28/10 5/13/12 12/27/13 8/13/15 3/28/17 11/12/18

MW-19 background

MW-19 compliance

Limit = 5.263

Prediction Limit

Intrawell Parametric

Constituent: Iron Analysis Run 11/21/2018 10:53 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Background Data Summary: Mean=2.299, Std. Dev.=1.186, n=13. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.8888, critical = 0.814. Kappa = 2.498 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Within Limit

Page 328: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

1.4

2.8

4.2

5.6

7

9/28/10 5/13/12 12/28/13 8/13/15 3/29/17 11/13/18

MW-20 background

MW-20 compliance

Limit = 6.655

Prediction Limit

Intrawell Parametric

Constituent: Iron Analysis Run 11/21/2018 10:53 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Background Data Summary (based on square root transformation): Mean=1.892, Std. Dev.=0.2699, n=12. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.8158, critical = 0.805. Kappa = 2.548 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Within Limit

0

1

2

3

4

5

9/28/10 5/13/12 12/28/13 8/13/15 3/29/17 11/13/18

MW-21 background

MW-21 compliance

Limit = 4.657

Prediction Limit

Intrawell Parametric

Constituent: Iron Analysis Run 11/21/2018 10:53 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Background Data Summary: Mean=2.004, Std. Dev.=1.062, n=13. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.8382, critical = 0.814. Kappa = 2.498 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Within Limit

Page 329: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

0.14

0.28

0.42

0.56

0.7

9/14/04 7/15/07 5/14/10 3/14/13 1/12/16 11/12/18

MW-14R background

MW-14R compliance

Limit = 0.637

Prediction Limit

Intrawell Non-parametric

Constituent: Manganese Analysis Run 11/21/2018 10:53 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Non-parametric test used in lieu of parametric prediction limit because the Shapiro Wilk normality test showed the data to be non-normal at the 0.01 alpha level. Limit is highest of 11 background values. Well-constituent pair annual alpha = 0.02537. Individual comparison alpha = 0.01276 (1 of 2).

Within Limit

0

0.18

0.36

0.54

0.72

0.9

9/28/10 5/13/12 12/27/13 8/13/15 3/28/17 11/12/18

MW-16R background

MW-16R compliance

Limit = 0.83

Prediction Limit

Intrawell Non-parametric

Constituent: Manganese Analysis Run 11/21/2018 10:53 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Non-parametric test used in lieu of parametric prediction limit because the Shapiro Wilk normality test showed the data to be non-normal at the 0.01 alpha level. Limit is highest of 13 background values. Well-constituent pair annual alpha = 0.01929. Individual comparison alpha = 0.009692 (1 of 2).

Within Limit

Page 330: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

0.1

0.2

0.3

0.4

0.5

9/14/04 7/14/07 5/13/10 3/12/13 1/10/16 11/9/18

MW-17R background

MW-17R compliance

Limit = 0.09

Prediction Limit

Intrawell Non-parametric

Constituent: Manganese Analysis Run 11/21/2018 10:53 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Hollow symbols indicate censored values.

Non-parametric test used in lieu of parametric prediction limit because censored data exceeded 50%. Limit is highest of 11 background values. 63.64% NDs. Well-constituent pair annual alpha = 0.02537. Individual comparison alpha = 0.01276 (1 of 2).

Within Limit

0

0.18

0.36

0.54

0.72

0.9

9/28/10 5/13/12 12/27/13 8/13/15 3/28/17 11/12/18

MW-19 background

MW-19 compliance

Limit = 0.8225

Prediction Limit

Intrawell Parametric

Constituent: Manganese Analysis Run 11/21/2018 10:53 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Background Data Summary: Mean=0.5803, Std. Dev.=0.09697, n=13. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.9514, critical = 0.814. Kappa = 2.498 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Within Limit

Page 331: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

0.16

0.32

0.48

0.64

0.8

9/28/10 5/13/12 12/28/13 8/13/15 3/29/17 11/13/18

MW-20 background

MW-20 compliance

Limit = 0.7383

Prediction Limit

Intrawell Parametric

Constituent: Manganese Analysis Run 11/21/2018 10:53 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Background Data Summary (based on square root transformation): Mean=0.6933, Std. Dev.=0.06642, n=13. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.8272, critical = 0.814. Kappa = 2.498 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Within Limit

0

0.4

0.8

1.2

1.6

2

9/28/10 5/13/12 12/28/13 8/13/15 3/29/17 11/13/18

MW-21 background

MW-21 compliance

Limit = 1.743

Prediction Limit

Intrawell Parametric

Constituent: Manganese Analysis Run 11/21/2018 10:53 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Background Data Summary (based on natural log transformation): Mean=-0.5835, Std. Dev.=0.447, n=12. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.844, critical = 0.805. Kappa = 2.548 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Within Limit

Page 332: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

1.6

3.2

4.8

6.4

8

9/14/04 7/15/07 5/14/10 3/14/13 1/12/16 11/12/18

MW-14R background

MW-14R compliance

Limit = 7.402

Limit = 6.25

Prediction Limit

Intrawell Parametric

Constituent: pH Analysis Run 11/21/2018 10:53 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

su

Background Data Summary: Mean=6.826, Std. Dev.=0.2636, n=23. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.9107, critical = 0.881. Kappa = 2.185 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Within Limits

0

1.6

3.2

4.8

6.4

8

9/28/10 5/13/12 12/27/13 8/13/15 3/28/17 11/12/18

MW-16R background

MW-16R compliance

Limit = 7.667

Limit = 6.293

Prediction Limit

Intrawell Parametric

Constituent: pH Analysis Run 11/21/2018 10:53 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

su

Background Data Summary: Mean=6.98, Std. Dev.=0.2694, n=12. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.911, critical = 0.805. Kappa = 2.548 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Within Limits

Page 333: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

1.6

3.2

4.8

6.4

8

9/14/04 7/14/07 5/13/10 3/12/13 1/10/16 11/9/18

MW-17R background

MW-17R compliance

Limit = 7.501

Limit = 6.177

Prediction Limit

Intrawell Parametric

Constituent: pH Analysis Run 11/21/2018 10:53 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

su

Background Data Summary: Mean=6.839, Std. Dev.=0.3029, n=23. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.8853, critical = 0.881. Kappa = 2.185 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Within Limits

0

1.6

3.2

4.8

6.4

8

9/28/10 5/13/12 12/27/13 8/13/15 3/28/17 11/12/18

MW-19 background

MW-19 compliance

Limit = 7.669

Limit = 6.19

Prediction Limit

Intrawell Parametric

Constituent: pH Analysis Run 11/21/2018 10:53 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

su

Background Data Summary: Mean=6.929, Std. Dev.=0.3148, n=16. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.9734, critical = 0.844. Kappa = 2.348 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Within Limits

Page 334: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

1.6

3.2

4.8

6.4

8

9/28/10 5/13/12 12/28/13 8/13/15 3/29/17 11/13/18

MW-20 background

MW-20 compliance

Limit = 7.459

Limit = 5.838

Prediction Limit

Intrawell Parametric

Constituent: pH Analysis Run 11/21/2018 10:53 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

su

Background Data Summary: Mean=6.649, Std. Dev.=0.331, n=14. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.8726, critical = 0.825. Kappa = 2.448 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Within Limits

0

1.6

3.2

4.8

6.4

8

9/28/10 5/13/12 12/28/13 8/13/15 3/29/17 11/13/18

MW-21 background

MW-21 compliance

Limit = 7.773

Limit = 6.064

Prediction Limit

Intrawell Parametric

Constituent: pH Analysis Run 11/21/2018 10:53 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

su

Background Data Summary: Mean=6.918, Std. Dev.=0.3422, n=13. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.9621, critical = 0.814. Kappa = 2.498 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Within Limits

Page 335: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

8

16

24

32

40

9/28/10 5/13/12 12/27/13 8/13/15 3/28/17 11/12/18

MW-16R background

MW-16R compliance

Limit = 32.42

Prediction Limit

Intrawell Parametric

Constituent: Sulfate Analysis Run 11/21/2018 10:53 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Background Data Summary: Mean=23.79, Std. Dev.=3.454, n=13. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.8941, critical = 0.814. Kappa = 2.498 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Within Limit

0

12

24

36

48

60

9/28/10 5/13/12 12/27/13 8/13/15 3/28/17 11/12/18

MW-19 background

MW-19 compliance

Limit = 56.94

Prediction Limit

Intrawell Parametric

Constituent: Sulfate Analysis Run 11/21/2018 10:53 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Background Data Summary: Mean=39.41, Std. Dev.=7.017, n=13. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.9289, critical = 0.814. Kappa = 2.498 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Within Limit

Page 336: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

10

20

30

40

50

9/28/10 5/13/12 12/28/13 8/13/15 3/29/17 11/13/18

MW-20 background

MW-20 compliance

Limit = 42.19

Prediction Limit

Intrawell Parametric

Constituent: Sulfate Analysis Run 11/21/2018 10:53 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Background Data Summary: Mean=29.85, Std. Dev.=4.939, n=13. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.8784, critical = 0.814. Kappa = 2.498 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Within Limit

0

40

80

120

160

200

9/28/10 5/13/12 12/28/13 8/13/15 3/29/17 11/13/18

MW-21 background

MW-21 compliance

Limit = 200

Prediction Limit

Intrawell Non-parametric

Constituent: Sulfate Analysis Run 11/21/2018 10:53 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Non-parametric test used in lieu of parametric prediction limit because the Shapiro Wilk normality test showed the data to be non-normal at the 0.01 alpha level. Limit is highest of 13 background values. Well-constituent pair annual alpha = 0.01929. Individual comparison alpha = 0.009692 (1 of 2).

Within Limit

Page 337: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Trend Testing Results

Page 338: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

8

16

24

32

40

9/14/04 7/14/07 5/13/10 3/12/13 1/10/16 11/9/18

Sen's Slope Estimator

MW-17R (bg)

Constituent: Chloride Analysis Run 11/21/2018 11:03 AM View: 2018-1H Trend

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/Ln = 29

Slope = -0.4331units per year.

Mann-Kendallstatistic = -147critical = -125

Decreasing trendsignificant at 98%confidence level(α = 0.01 pertail).

Hollow symbols indicate censored values.

0

1.8

3.6

5.4

7.2

9

9/14/04 7/15/07 5/14/10 3/14/13 1/12/16 11/12/18

Sen's Slope Estimator

MW-14R (bg)

Constituent: Iron Analysis Run 11/21/2018 11:03 AM View: 2018-1H Trend

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

n = 30

Slope = 0.2035units per year.

Mann-Kendallstatistic = 278critical = 132

Increasing trendsignificant at 98%confidence level(α = 0.01 pertail).

Hollow symbols indicate censored values.

Page 339: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

40

80

120

160

200

9/14/04 7/15/07 5/14/10 3/14/13 1/12/16 11/12/18

Sen's Slope Estimator

MW-14R (bg)

Constituent: Sulfate Analysis Run 11/21/2018 11:03 AM View: 2018-1H Trend

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/Ln = 29

Slope = -4.101units per year.

Mann-Kendallstatistic = -306critical = -125

Decreasing trendsignificant at 98%confidence level(α = 0.01 pertail).

0

14

28

42

56

70

9/14/04 7/14/07 5/13/10 3/12/13 1/10/16 11/9/18

Sen's Slope Estimator

MW-17R (bg)

Constituent: Sulfate Analysis Run 11/21/2018 11:03 AM View: 2018-1H Trend

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.10 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

n = 29

Slope = -1.62units per year.

Mann-Kendallstatistic = -283critical = -125

Decreasing trendsignificant at 98%confidence level(α = 0.01 pertail).

Page 340: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

Prediction Limit Results from Verification Sampling

Page 341: Rec’d Digitally By Caroline Rieger at 10:51 am, Feb 13, 2019 · FTN No. R04469-1767-001 Dear Ms. Kilburn: On behalf of the Craighead County Solid Waste Disposal Authority, FTN Associates,

0

0.06

0.12

0.18

0.24

0.3

9/28/10 5/29/12 1/28/14 9/29/15 5/30/17 1/29/19

MW-20 background

MW-20 compliance

Limit = 0.2219

Prediction Limit

Intrawell Parametric

Constituent: Barium Analysis Run 2/5/2019 8:39 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.12 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Background Data Summary: Mean=0.1737, Std. Dev.=0.01931, n=13. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.9604, critical = 0.814. Kappa = 2.498 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Within Limit

0

100

200

300

400

500

9/28/10 5/29/12 1/28/14 9/29/15 5/30/17 1/29/19

MW-20 background

MW-20 compliance

Limit = 391.1

Prediction Limit

Intrawell Parametric

Constituent: Dissolved solids Analysis Run 2/5/2019 8:39 AM View: 2018-2H PL

Legacy Landfill Client: CCSWDA Data: Craighead County LF

Sanitas™ v.9.6.12 For the statistical analyses of ground water by FTN Associates only. UG

mg

/L

Background Data Summary: Mean=317.3, Std. Dev.=28.95, n=12. Normality test: Shapiro Wilk @alpha = 0.01, calculated = 0.949, critical = 0.805. Kappa = 2.548 (c=12, w=5, 1 of 2, event alpha = 0.05132). Report alpha = 0.0008776.

Within Limit