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Reasonable Progress: Chiricahua NM & Wilderness Area Implementation Workgroup Meeting San Diego, California April 17 – 19, 2007

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Reasonable Progress: Chiricahua NM & Wilderness Area. Implementation Workgroup Meeting San Diego, California April 17 – 19, 2007. Chiricahua NM & Wilderness Area. Overview of Chiricahua NM & WA Monitoring/Baseline Conditions Annual Average 20% Worst Visibility Days - PowerPoint PPT Presentation

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Page 1: Reasonable Progress: Chiricahua NM & Wilderness Area

Reasonable Progress:Chiricahua NM & Wilderness Area

Implementation Workgroup Meeting

San Diego, California

April 17 – 19, 2007

Page 2: Reasonable Progress: Chiricahua NM & Wilderness Area

Chiricahua NM & Wilderness Area

Overview of Chiricahua NM & WA Monitoring/Baseline Conditions

Annual Average 20% Worst Visibility Days

Emissions & Source Apportionment Sources Species

Reasonable Progress/Modeling Model Performance Modeling Results Visibility Projections

Summary

Page 3: Reasonable Progress: Chiricahua NM & Wilderness Area

Source: http://www.epa.gov/region09/air/maps/az_clss1.html

Arizona Class One Areas

Page 4: Reasonable Progress: Chiricahua NM & Wilderness Area

Source: WRAP Causes of Haze Website (http://coha.dri.edu)

2km Terrain Map 20km Terrain Map

Chiricahua NM & Wilderness Area

The Chiricahua Wilderness is located south of the Chiricahua National Monument. The IMRPOVE monitor is located west of the National Monument.

Page 5: Reasonable Progress: Chiricahua NM & Wilderness Area

Glide Slope Annual Average (in dv)

Baseline Conditions: 8.75 dvNatural Conditions: 4.0 dv

Page 6: Reasonable Progress: Chiricahua NM & Wilderness Area

Annual Light Extinction

Results show particle extinction. The baseline extinction is 15.44 Mm -1.

Page 7: Reasonable Progress: Chiricahua NM & Wilderness Area

Glide Slope for 20% Worst Days (in dv)

Baseline = 13.43 dv; Natural Conditions = 7.2 dv

Page 8: Reasonable Progress: Chiricahua NM & Wilderness Area

Baseline Extinction Budget

Visibility impairment on worst days is mostly attributed to sulfates, coarse mass, fine soil, and organic carbon.

Page 9: Reasonable Progress: Chiricahua NM & Wilderness Area

Baseline Species – Time Series

This shows extinction for all species for each year of the baseline period.

Page 10: Reasonable Progress: Chiricahua NM & Wilderness Area

Baseline Worst 20% Light Extinction

Page 11: Reasonable Progress: Chiricahua NM & Wilderness Area

Average 20% Worst Day Composition(baseline ’00 – ‘04)

Source: Chart made from spreadsheet posted at:WRAP Technical Support System >> Resources >> Monitoring >> Composition

1.3

8.1 8.6

1.7

7.3

2.7

0

2

4

6

8

10

NO3 SO4 CM EC OC FineSoil

Aerosol Species

CHIR1

Lig

ht

Ext

inct

ion

(M

m -

1)

Page 12: Reasonable Progress: Chiricahua NM & Wilderness Area

Average 20% Best Day Composition (baseline ’00 – ’04)

Source: Chart made from spreadsheet posted at:WRAP Technical Support System >> Resources >> Monitoring >> Composition

0.5

2.3 1.20.7

1.40.3

0

2

4

6

8

10

12

14

NO3 SO4 CM EC OC FineSoil

Aerosol Species

CHIR1

Lig

ht

Ext

inct

ion

(M

m -

1)

Page 13: Reasonable Progress: Chiricahua NM & Wilderness Area

Species Glide Slope – Worst 20%

This shows the baseline and glide slope by species.

Page 14: Reasonable Progress: Chiricahua NM & Wilderness Area

Species Trends and URP Glide Slope (Worst Days)

Page 15: Reasonable Progress: Chiricahua NM & Wilderness Area

Emissions & Source Apportionment

Page 16: Reasonable Progress: Chiricahua NM & Wilderness Area

Upwind Residence Time on 20% Worst Visibility Days (2000-04)

Highest values are located in southern Arizona, west Sonora, Baja California Norte, and north Chihuahua.

Page 17: Reasonable Progress: Chiricahua NM & Wilderness Area

Sources Located Near Chiricahua

Point Sources Douglas Power Plant; Douglas, AZ Apache Station (AEPCO); Wilcox, AZ Apache Nitrogen; St. David, AZ Chemical Lime; Paul Spur, AZ

Area Sources Vehicle Emissions: highways, unpaved roads,

recreational areas Other Sources

Naco Dump: 40 miles south of wilderness area near Naco, Mexico

Page 18: Reasonable Progress: Chiricahua NM & Wilderness Area

Source Apportionment for Sulfate (SO4)

PSAT results indicate that sources in Arizona, Mexico, CENRAP, EUS, and pacific off-shore are the largest contributors.

The left column shows 2002 (plan02c) and the right column shows 2018 (base18b) for each state and region.

Page 19: Reasonable Progress: Chiricahua NM & Wilderness Area

Weighted Emissions Potential – SO4

Sources and Areas of Potential Sulfur Oxide Emissions Influence2000-2004 Baseline for Chiricahua National Monument,AZ

20% Worst Visibility Days

36.1

0.7 0.4 0.1 0.1 0.5 1.5 0.2 0.1 0.0 0.2 0.1 0.3

23.2

13.3

1.7

21.4

0.3

0

10

20

30

40

50

60

70

80

90

100

Pe

rcen

t o

f T

ota

l D

ista

nc

e W

eig

hte

d E

mis

x R

esT

ime

Biogenic Natural Fire Point Area WRAP Area O&G Off-Shore

On-Road Mobile Off-Road Mobile Road Dust Fugitive Dust WB Dust Anthro Fire

Page 20: Reasonable Progress: Chiricahua NM & Wilderness Area

Weighted Emissions Potential – SO4

Sources and Areas of Potential Sulfur Oxide Emissions Influence2018 Projections for Chiricahua National Monument,AZ

20% Worst Visibility Days

38.0

0.7 0.3 0.1 0.1 0.2 1.5 0.2 0.1 0.0 0.2 0.0 0.3

24.3

9.8

1.2

22.6

0.3

0

10

20

30

40

50

60

70

80

90

100

Arizon

a

Califo

rnia

Colora

doId

aho

Mon

tana

Nevad

a

New M

exico

North

Dak

ota

Orego

n

South

Dak

ota

Utah

Was

hingt

on

Wyo

ming

Pacific

Offs

hore

CENRAP

Easte

rn U

S

Mex

ico

Canad

a

Per

cen

t o

f T

ota

l D

ista

nce

Wei

gh

ted

Em

is x

Res

Tim

e

Biogenic Natural Fire Point Area WRAP Area O&G Off-Shore

On-Road Mobile Off-Road Mobile Road Dust Fugitive Dust WB Dust Anthro Fire

Page 21: Reasonable Progress: Chiricahua NM & Wilderness Area

Arizona SOx Emissions

AZ SO2 Emissions

0

20,000

40,000

60,000

80,000

100,000

120,000

Point

Area

WRAP A

rea

O&G

Off-Shore

On-Road

Mobile

Off-Road

Mobile

Road D

ust

Fugitive

Dust

WB D

ust

Anthro

Fire

Natura

l Fire

Biogen

ic

Total

Anthro

To

ns

Pe

r Y

ea

r

2002 (tpy) 2018 (tpy)

-3%

Source: Saguaro Reasonable Progress presentation on 1/22/07, L. Alter

Page 22: Reasonable Progress: Chiricahua NM & Wilderness Area

Source Apportionment for Nitrate (NO3)

The largest contributors of nitrate are Arizona and California. Sources from CENRAP, Mexico, New Mexico, and pacific off-shore are also likely to contribute to nitrate.

The left column shows 2002 (plan02c) and the right column shows 2018 (base 18b) for each state and region.

Page 23: Reasonable Progress: Chiricahua NM & Wilderness Area

Weighted Emissions Potential – NO3

Sources and Areas of Potential Nitrogen Oxide Emissions Influence2000-2004 Baseline for Chiricahua National Monument,AZ

20% Worst Visibility Days

63.5

3.90.5 0.1 0.1 0.2

4.60.1 0.1 0.1 0.2 0.1 0.2

3.2

11.4

1.0

10.6

0.2

0

10

20

30

40

50

60

70

80

90

100

Arizon

a

Califo

rnia

Colora

doId

aho

Mon

tana

Nevad

a

New M

exico

North

Dak

ota

Orego

n

South

Dak

ota

Utah

Was

hingt

on

Wyo

ming

Pacific

Offs

hore

CENRAP

Easte

rn U

S

Mex

ico

Canad

a

Per

cen

t o

f T

ota

l D

ista

nc

e W

eig

hte

d E

mis

x R

esT

ime

Biogenic Natural Fire Point Area WRAP Area O&G Off-Shore

On-Road Mobile Off-Road Mobile Road Dust Fugitive Dust WB Dust Anthro Fire

Page 24: Reasonable Progress: Chiricahua NM & Wilderness Area

Weighted Emissions Potential – NO3

Sources and Areas of Potential Nitrogen Oxide Emissions Influence2018 Projections for Chiricahua National Monument,AZ

20% Worst Visibility Days

63.0

2.90.5 0.1 0.1 0.2

4.90.1 0.1 0.1 0.2 0.1 0.3

3.8

9.6

0.8

13.0

0.3

0

10

20

30

40

50

60

70

80

90

100

Arizon

a

Califo

rnia

Colora

doId

aho

Mon

tana

Nevad

a

New M

exico

North

Dak

ota

Orego

n

South

Dak

ota

Utah

Was

hingt

on

Wyo

ming

Pacific

Offs

hore

CENRAP

Easte

rn U

S

Mex

ico

Canad

a

Per

cen

t o

f T

ota

l Dis

tan

ce W

eig

hte

d E

mis

x R

esT

ime

Biogenic Natural Fire Point Area WRAP Area O&G Off-Shore

On-Road Mobile Off-Road Mobile Road Dust Fugitive Dust WB Dust Anthro Fire

Page 25: Reasonable Progress: Chiricahua NM & Wilderness Area

Arizona NOx Emissions

AZ NOx Emissions

0

50,000

100,000

150,000

200,000

250,000

300,000

350,000

400,000

450,000

Point

Area

WRAP A

rea

O&G

Off-Shore

On-Road

Mobile

Off-Road

Mobile

Road D

ust

Fugitive

Dust

WB D

ust

Anthro

Fire

Natura

l Fire

Biogen

ic

Total

Anthro

To

ns

Pe

r Y

ea

r

2002 (tpy) 2018 (tpy)

-35%

Source: Saguaro Reasonable Progress presentation on 1/22/07, L. Alter

Page 26: Reasonable Progress: Chiricahua NM & Wilderness Area

Weighted Emissions Potential – Organic Carbon (OMC)

Sources and Areas of Potential Organic Carbon Emissions Influence2000-2004 Baseline for Chiricahua National Monument,AZ

20% Worst Visibility Days

63.6

4.10.4 0.2 0.1 0.1

3.10.0 0.6 0.1 0.1 0.3 0.1 0.9

16.6

1.0

8.8

0.2

0

10

20

30

40

50

60

70

80

90

100

Arizon

a

Califo

rnia

Colora

doId

aho

Mon

tana

Nevad

a

New M

exico

North

Dak

ota

Orego

n

South

Dak

ota

Utah

Was

hingt

on

Wyo

ming

Pacific

Offs

hore

CENRAP

Easte

rn U

S

Mex

ico

Canad

a

Per

cen

t o

f T

ota

l Dis

tan

ce

Wei

gh

ted

Em

is x

Re

sTim

e

Biogenic Natural Fire Point Area WRAP Area O&G Off-Shore

On-Road Mobile Off-Road Mobile Road Dust Fugitive Dust WB Dust Anthro Fire

Page 27: Reasonable Progress: Chiricahua NM & Wilderness Area

Weighted Emissions Potential – OMC

Sources and Areas of Potential Organic Carbon Emissions Influence2018 Projections for Chiricahua National Monument,AZ

20% Worst Visibility Days

64.5

3.40.4 0.1 0.1 0.1

2.80.0 0.5 0.1 0.1 0.3 0.1 0.7

16.9

1.1

8.7

0.2

0

10

20

30

40

50

60

70

80

90

100

Arizon

a

Califo

rnia

Colora

doId

aho

Mon

tana

Nevad

a

New M

exico

North

Dak

ota

Orego

n

South

Dak

ota

Utah

Was

hingt

on

Wyo

ming

Pacific

Offs

hore

CENRAP

Easte

rn U

S

Mex

ico

Canad

a

Per

cen

t o

f T

ota

l Dis

tan

ce W

eig

hte

d E

mis

x R

esT

ime

Biogenic Natural Fire Point Area WRAP Area O&G Off-Shore

On-Road Mobile Off-Road Mobile Road Dust Fugitive Dust WB Dust Anthro Fire

Page 28: Reasonable Progress: Chiricahua NM & Wilderness Area

Arizona OC Emissions

AZ OC Emissions

0

5,000

10,000

15,000

20,000

25,000

30,000

35,000

Point

Area

WRAP A

rea

O&G

Off-Shore

On-Road

Mobile

Off-Road

Mobile

Road D

ust

Fugitive

Dust

WB D

ust

Anthro

Fire

Natura

l Fire

Biogen

ic

Total

Anthro

To

ns

Pe

r Y

ea

r

2002 (tpy) 2018 (tpy)

+6%

Source: Saguaro Reasonable Progress presentation on 1/22/07, L. Alter

Page 29: Reasonable Progress: Chiricahua NM & Wilderness Area

Weighted Emissions Potential – Elemental Carbon (EC)

Sources and Areas of Potential Elemental Carbon Emissions Influence2000-2004 Baseline for Chiricahua National Monument,AZ

20% Worst Visibility Days

61.9

4.70.5 0.2 0.1 0.1

3.50.1 0.4 0.1 0.2 0.2 0.1 2.0

11.2

0.8

13.8

0.2

0

10

20

30

40

50

60

70

80

90

100

Pe

rce

nt

of

To

tal

Dis

tan

ce

We

igh

ted

Em

is x

Re

sT

ime

Biogenic Natural Fire Point Area WRAP Area O&G Off-Shore

On-Road Mobile Off-Road Mobile Road Dust Fugitive Dust WB Dust Anthro Fire

Page 30: Reasonable Progress: Chiricahua NM & Wilderness Area

Weighted Emissions Potential - EC

Sources and Areas of Potential Elemental Carbon Emissions Influence2018 Projections for Chiricahua National Monument,AZ

20% Worst Visibility Days

54.3

4.80.4 0.1 0.1 0.1

3.00.0 0.4 0.1 0.1 0.2 0.2

2.7

12.4

0.8

20.0

0.3

0

10

20

30

40

50

60

70

80

90

100

Arizon

a

Califo

rnia

Colora

doId

aho

Mon

tana

Nevad

a

New M

exico

North

Dak

ota

Orego

n

South

Dak

ota

Utah

Was

hingt

on

Wyo

ming

Pacific

Offs

hore

CENRAP

Easte

rn U

S

Mex

ico

Canad

a

Per

cen

t o

f T

ota

l Dis

tan

ce W

eig

hte

d E

mis

x R

esT

ime

Biogenic Natural Fire Point Area WRAP Area O&G Off-Shore

On-Road Mobile Off-Road Mobile Road Dust Fugitive Dust WB Dust Anthro Fire

Page 31: Reasonable Progress: Chiricahua NM & Wilderness Area

Weighted Emissions Potential – Fine Soil (Soil)

Sources and Areas of Potential Fine PM Emissions Influence2000-2004 Baseline for Chiricahua National Monument,AZ

20% Worst Visibility Days

30.2

2.6 0.5 0.2 0.2 0.1

9.0

0.1 0.2 0.3 0.1 0.1 0.14.4

16.3

0.6

34.6

0.3

0

10

20

30

40

50

60

70

80

90

100

Arizon

a

Califo

rnia

Colora

doId

aho

Mon

tana

Nevad

a

New M

exico

North

Dak

ota

Orego

n

South

Dak

ota

Utah

Was

hingt

on

Wyo

ming

Pacific

Offs

hore

CENRAP

Easte

rn U

S

Mex

ico

Canad

a

Per

cen

t o

f T

ota

l Dis

tan

ce

Wei

gh

ted

Em

is x

Re

sTim

e

Biogenic Natural Fire Point Area WRAP Area O&G Off-Shore

On-Road Mobile Off-Road Mobile Road Dust Fugitive Dust WB Dust Anthro Fire

Page 32: Reasonable Progress: Chiricahua NM & Wilderness Area

Weighted Emissions Potential - Soil

Sources and Areas of Potential Fine PM Emissions Influence2018 Projections for Chiricahua National Monument,AZ

20% Worst Visibility Days

33.9

2.5 0.5 0.2 0.2 0.2

8.7

0.1 0.2 0.3 0.1 0.2 0.14.1

15.2

0.6

32.5

0.3

0

10

20

30

40

50

60

70

80

90

100

Arizon

a

Califo

rnia

Colora

doId

aho

Mon

tana

Nevad

a

New M

exico

North

Dak

ota

Orego

n

South

Dak

ota

Utah

Was

hingt

on

Wyo

ming

Pacific

Offs

hore

CENRAP

Easte

rn U

S

Mex

ico

Canad

a

Per

cen

t o

f T

ota

l Dis

tan

ce W

eig

hte

d E

mis

x R

esT

ime

Biogenic Natural Fire Point Area WRAP Area O&G Off-Shore

On-Road Mobile Off-Road Mobile Road Dust Fugitive Dust WB Dust Anthro Fire

Page 33: Reasonable Progress: Chiricahua NM & Wilderness Area

Weighted Emissions Potential – Coarse Particulate Matter (CM)

Sources and Areas of Potential Coarse PM Emissions Influence2000-2004 Baseline for Chiricahua National Monument,AZ

20% Worst Visibility Days

29.3

1.8 0.6 0.1 0.3 0.2

11.5

0.1 0.1 0.4 0.1 0.1 0.1 1.0

15.7

0.3

37.9

0.3

0

10

20

30

40

50

60

70

80

90

100

Arizon

a

Califo

rnia

Colora

doId

aho

Mon

tana

Nevad

a

New M

exico

North

Dak

ota

Orego

n

South

Dak

ota

Utah

Was

hingt

on

Wyo

ming

Pacific

Offs

hore

CENRAP

Easte

rn U

S

Mex

ico

Canad

a

Per

cen

t o

f T

ota

l Dis

tan

ce

Wei

gh

ted

Em

is x

Re

sTim

e

Biogenic Natural Fire Point Area WRAP Area O&G Off-Shore

On-Road Mobile Off-Road Mobile Road Dust Fugitive Dust WB Dust Anthro Fire

Page 34: Reasonable Progress: Chiricahua NM & Wilderness Area

Weighted Emissions Potential – CM

Sources and Areas of Potential Coarse PM Emissions Influence2018 Projections for Chiricahua National Monument,AZ

20% Worst Visibility Days

39.2

1.8 0.5 0.1 0.3 0.2

10.4

0.1 0.1 0.4 0.1 0.1 0.1 0.9

12.8

0.3

32.4

0.2

0

10

20

30

40

50

60

70

80

90

100

Arizon

a

Califo

rnia

Colora

doId

aho

Mon

tana

Nevad

a

New M

exico

North

Dak

ota

Orego

n

South

Dak

ota

Utah

Was

hingt

on

Wyo

ming

Pacific

Offs

hore

CENRAP

Easte

rn U

S

Mex

ico

Canad

a

Per

cen

t o

f T

ota

l Dis

tan

ce W

eig

hte

d E

mis

x R

esT

ime

Biogenic Natural Fire Point Area WRAP Area O&G Off-Shore

On-Road Mobile Off-Road Mobile Road Dust Fugitive Dust WB Dust Anthro Fire

Page 35: Reasonable Progress: Chiricahua NM & Wilderness Area

Modeling

Page 36: Reasonable Progress: Chiricahua NM & Wilderness Area

Model Performance

The left points are modeled data and the right points are from IMPROVE.

Page 37: Reasonable Progress: Chiricahua NM & Wilderness Area

Visibility Modeling Results

Page 38: Reasonable Progress: Chiricahua NM & Wilderness Area

Visibility Projections – NO3

This shows baseline conditions, glide slope, and projected 2018 light extinction.

Page 39: Reasonable Progress: Chiricahua NM & Wilderness Area

Visibility Projections – SO4

This shows baseline conditions, glide slope, and projected 2018 light extinction.

Page 40: Reasonable Progress: Chiricahua NM & Wilderness Area

Visibility Projections - OMC

This shows baseline conditions, glide slope, and projected 2018 light extinction.

Page 41: Reasonable Progress: Chiricahua NM & Wilderness Area

Visibility Projections - EC

This shows baseline conditions, glide slope, and projected 2018 light extinction.

Page 42: Reasonable Progress: Chiricahua NM & Wilderness Area

Visibility Projections – CM

This shows baseline conditions, glide slope, and projected 2018 light extinction.

Page 43: Reasonable Progress: Chiricahua NM & Wilderness Area

Visibility Projections – Soil

This shows baseline conditions, glide slope, and projected 2018 light extinction.

Page 44: Reasonable Progress: Chiricahua NM & Wilderness Area

Summary

Largest Contributors to Visibility Impairment in ChiricahuaSulfatesCoarse Mass, Fine SoilOrganic Carbon

Page 45: Reasonable Progress: Chiricahua NM & Wilderness Area

Continuing Progress

Continuing Analysis of ChiricahuaAdditional WRAP Products (e.g. CoDust)Local Emission Inventories (e.g.

Douglas/Agua Prieta)Nonattainment/Maintenance Area PlansLocal analysis (FLM, Tribal) Impact from BART and other non-BARTMicroscale Modeling????