range of anionic and nonionic surfactants - clariant/media/files/corporate/events/2015/ecs/... ·...
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Trade name ProducT grouP
TyPe Pure acrylic
STyrene-acrylic
Vinyl aceTaTe
STyrene-buTadiene
e-PVc Hlb Value
aPPearance acTiVe conTenT
aPeo free
low Voc (<1%)
biodegradabiliTy uS fda1 regiSTraTion, cHaPTer 21 cfr
euroPean regiSTraTion direcTiVe 10/2011
german bfr2
aicS (auSTralia)
dSl (canada)
einecS (euroPe)
encS (JaPan)
iecSc (cHina)
Keci (Korea)
neci (Taiwan)
nZioc (new Zealand)
PiccS (PHiliPPi-neS)
TSca (uSa)
comPoSiTion5 label Signal word HaZard STaTemenT6
Dispersogen® LFA Phosphate Ester
Tristyrl phenol ether phosphate
● n.a. Brownish, viscous liquid
ca. 85% 3 3 - 3 3 3 3 3 3 3 3 Mixture - Warning H320
Emulsogen® APS 100 Sulfate ester Allyl polyalkylene glycol ether sulfate, ammonium salt
● ● n.a. Clear to cloudy yellowish liquid
ca. 100% 3 - 46% (28d)OECD301B
- - - 3 3 3 3 exempted 3 LVE7 Substance label free label free label free
Emulsogen® EPA 073 Sulfate ester Sodium alkyl ether sulfate ● ● ● n.a. Clear, colorless liquid ca. 30% 3 3 Readily biodegradable
>80% (28d)OECD 301A
§ 175.105, 176.170,176.180, 177.1210
3 BfR XIV,XXI, XXXIV
3 3 3 3 3 3 3 3 3 LVE7 3 Mixture ✖ Irritant (Xi) R36
Emulsogen® EPA 1954 Sulfate ester Sodium lauryl sulfate ● ● ● n.a. Clear, colorless to yellowish liquid
ca. 30% 3 3 Readily biodegradable
>60% OECD301B
3 BfR XXI,XXXVI
3 3 3 3 3 3 3 3 3 3 Mixture✖
Harmful (Xn),Irritant (Xi)
R22, R38, R41
Emulsogen® LA 083 Sulfate ester Ammonium alkyl ether sulfate
● ● n.a. Yellowish liquid ca. 30% 3 3 Readily biodegradable
>93% (28d)OECD 301B
3 BfR XIV, XXI XXXIV
3 3 3 3 3 3 3 3 3 Mixture ✖ Irritant (Xi) R36/38
Emulsogen® LCA 213 Sulfate ester Allyl polyalkylene glycol ether sulfate, ammonium salt
● ● ● n.a. Clear yellowish liquid ca. 30% 3 - 3 3 3 3 3 3 Mixture Warning R36/41
Emulsogen® PF 20 S Sulfate ester Polyalkylene glycol ether sulfate, ammonium salt
● ● n.a. Yellowish brown liquid ca. 50% 3 3 - <10% OECD302B
3 3 LVE7 3 exempted Mixture label free label free label free
Emulsogen® SF 8 Sulfosuccinate Dioctyl sulfosuccinate ● n.a. Colorless, clear tocloudy liquid
ca. 50% 3 3 Readily biodegradable
78% (28d)OECD 301B
§ 175.105, 175.300,175.320, 176.170,176.180, 176.210,177.1200, 177.2800,178.3400
3 BfR II, XIV,XXXIV,XXXVI
3 3 3 3 3 3 3 3 3 3 Mixture ✖ Irritant (Xi) R36/38
Genapol® LRO liquid Sulfonate Sodium lauryl ether sulfate ● ● ● ● n.a. Clear liquid ca. 27% 3 Readily biodegradable
95% (28d)OECD 301E
§ 176.210, 177.2800 3 BfR XIV, XXI,XXXIV
3 3 3 3 3 3 3 3 3 3 Mixture ✖ Irritant (Xi) R38, R41
Genapol® LRO paste Sulfonate Sodium lauryl ether sulfate ● ● ● ● n.a. Paste ca. 68-70% 3 Readily biodegradable
100% (28d)OECD 301B
§ 176.210, 177.2800 3 BfR XIV, XXI,XXXIV
3 3 3 3 3 3 3 3 3 3 Substance Danger H315, H318, H412
Hostapal® BV conc. Sulfate ester Sodium alkyl aryl ether sulfate
● ● ● n.a. Clear, colorless to yellowish liquid
ca. 50% 3 - <10% OECD302B
BfR XIV 3 3 3 3 3 3 3 3 3 3 Mixture ✖ Irritant (Xi),Dangerous for theenvironment (N)
R41, R52/53
Hostapal® BVQ 9 Sulfate ester Sodium nonyl phenol polyglycol ether sulphate
● ● ● n.a. Yellow liquid ca. 40% - 9% (28d)OECD301D
- - - 3 3 3 3 3 3 3 3 3 Mixture label free label free label free
Hostapal® BVQ 25 Sulfate ester Sodium nonyl phenol polyglycol ether sulphate
● ● ● n.a. Clear yellowish liquid ca. 30% - 23% (21d)OECD301D
3 3 3 3 3 3 3 3 3 Mixture Warning H315, H411
Hostaphat® 1306 Phosphate ester
Alkyl ether phosphate ● ● ● n.a. Clear, yellowih liquid ca. 100% 3 - 44% (28d)OECD 301B
§ 178.3400 3 3 3 3 3 3 3 3 3 Substance
Danger H315, H318, H411
Hostapur® OS liquid Sulfonate Sodium olefin sulfonate ● ● ● ● n.a. Yellowish clear liquid ca. 40% 3 3 Readily biodegradable
>80% (28d)OECD 301B
§ 175.105, 178.3400 3 3 3 3 3 3 3 3 3 3 Mixture ✖ Irritant (Xi) R38, R41
Hostapur® SAS 30 Sulfonate Sodium alkyl sulfonate ● ● ● ● ● n.a. Clear, slightly yellowish liquid
ca. 30% 3 3 Readily biodegradable
>89% (28d)OECD 301E
§ 176.170, 176.180,178.3400
3 BfR XIV,XXXVI
3 3 3 3 3 3 3 3 3 3 Mixture ✖ Irritant (Xi) R38, R41
Hostapur® SAS 60 Sulfonate Sodium alkyl sulfonate ● ● ● ● ● n.a. Yellowish soft paste ca. 60% 3 3 Readily biodegradable
>89% (28d)OECD 301E
§ 176.170, 176.180,178.3130, 178.3400
3 BfR II, V,VI, XIV, XV,XXI, XXXIV,XXXVI
3 3 3 3 3 3 3 3 3 3 Mixture ✖ Irritant (Xi) R38, R41
Hostapur® SAS 93 Sulfonate Sodium alkyl sulfonate ● ● ● ● ● n.a. Yellowish tablets ca. 93% 3 3 Readily biodegradable
>89% (28d)OECD 301E
§ 176.170, 176.180,178.3400
3 BfR XIV,XXXVI
3 3 3 3 3 3 3 3 3 3 Substance
Danger H302, H315, H318, H412
Range of anionic emulsifiers
1 Product listed in chapter 21 CFR of the US Food and Drug Administration 2 The product meets the requirements of the Bundesamt für Riskikobewertung (German authority of risk assessment) 3 Hazardous labeling according to the Globally Harmonized System 4 Hazardous labeling according to the European Dangerous Substance Directive (EU Annex I Directive 67/548/EEC) 5 (GHS) is an internationally agreed upon system set to use worldwide unified standards for classification of chemicals as well as safety data sheets under the roof of the United Nations. The European Commission approved GHS in the “Regulation on classification, labeling and packaging of substances and mixtures “ on 16.12.08 (EU regulation 1272/2008). According the EU regulation, the classification and labteling has to be done until: - 01.12.2010 for substances - 01.06.2015 for mixtures (i.e. chemical preparations)“
6 risk phrases: R22: Harmful if swallowed R36: Irritating to eyes R38: Irritating to skin: R36/38: Irritating to eyes and skin R41: Risk of serious damage to eyes R52: Harmful to aquatic organisms R53: May cause long-term adverse effects in the aquatic environment R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment n.a. Not applicable
aPPlicaTion ProPerTieS food conTacT regulaTion inVenTory regiSTraTion STaTuS HaZardouS labeling according To gHS3 or dangerouS SuSbSTance direcTiVe4
6 Hazard Statements: H302: Harmful if swallowed H315: Causes skin irritation H318: Causes serious eye damage H411: Toxic to aquatic life with long lasting effects H412: Harmful to aquatic life with long lasting effects
7 LVE = Low volume exempt
Range of anionic and nonionic suRfactants
Emulsion Polymerization
Range of nonionic emulsifiers
Trade name ProducT grouP
TyPe Pure acrylic
STyrene-acrylic
Vinyl aceTaTe
STyrene-buTadiene
e-PVc Hlb Value
aPPearance acTiVe conTenT
aPeo free
low Voc (<1%)
biodegradabiliTy uS fda1
regiSTraTion, cHaPTer 21 cfr
euroPean regiSTraTion direcTiVe 10/2011
german bfr2
aicS (auSTralia)
dSl (canada)
einecS (euroPe)
encS (JaPan)
iecSc (cHina)
Keci (Korea)
neci (Taiwan)
nZioc (new Zealand)
PiccS (PHiliPPi-neS)
TSca (uSa)
comPoSiTion5 label Signal word HaZard STaTemenT6
Emulsogen® 4084 EO/PO block copolymers
60% EO, 40% PO ● ● ● 18 Pale yellow wax ca. 100% 3 3 - <10% (28d)OECD302B
§ 175.105, 176.180,176.200, 176.210,177.1200, 177.1680
3 BfR XIV, XLVIII, LIII
3 3 3 3 3 3 3 3 3 3 Substance label free label free label free
Emulsogen® EPN 118 Fatty alcohol polyglycol ether
C11 oxo alcohol, ethoxylated with 11 moles EO
● ● ● ● 15 Clear colorless liquid ca. 80% 3 3 Inherentlybiodegradable
> 80 % OECD302 B
§ 175.105, 176.170,176.180, 181.30
3 BfR XIV, XXI,XXXIV,XXXVI
3 3 3 3 3 3 3 3 3 3 Mixture ✖ Harmful (Xn),Irritant (Xi)
R22, R41
Emulsogen® EPN 217 Fatty alcohol polyglycol ether
C11 oxo alcohol, ethoxylated with 21 moles EO
● ● ● ● 17 Clear colorless liquid ca. 70% 3 3 Inherentlybiodegradable
> 80 % OECD302 B
§ 176.170, 176.180,181.30
3 BfR XIV, XXI,XXXIV
3 3 3 3 3 3 3 3 3 3 Mixture label free label free label free
Emulsogen® EPN 287 Fatty alcohol polyglycol ether
C11 oxo alcohol, ethoxylated with 28 moles EO
● ● ● ● 17,5 Clear colorless liquid ca. 70% 3 3 Inherentlybiodegradable
> 80 % OECD302 B
§ 175.105, 176.170,176.180, 181.30
3 BfR XIV, XXI,XXXIV,XXXVI
3 3 3 3 3 3 3 3 3 3 Mixture label free label free label free
Emulsogen® EPN 407 Fatty alcohol polyglycol ether
C11 oxo alcohol, ethoxylated with 40 moles EO
● ● ● ● 18 Clear colorless liquid ca. 70% 3 3 Inherentlybiodegradable
> 80 % OECD302 B
§ 175.105, 176.170,176.180, 181.30
3 BfR XIV, XXI,XXXIV
3 3 3 3 3 3 3 3 3 3 Mixture label free label free label free
Emulsogen® LCN 070 Fatty alcohol ethoxylate
C11 oxo alcohol, ethoxylated with 7 moles EO
● ● ● 13 Clear to cloudy liquid ca. 100% 3 3 Readily biodegradable
>80% (28d)OECD301E
§ 175.105, 176.170,176.180, 181.30
3 BfR XIV, XXI,XXXIV,XXXVI
3 3 3 3 3 3 3 3 Substance
Danger H302, H318
Emulsogen® LCN 088 Fatty alcohol ethoxylate
C11 oxo alcohol, ethoxylated with 8 moles EO
● 13,5 Clear liquid ca. 80% 3 3 Readily biodegradable
>61% (28d)OECD301B
§ 175.105, 176.170,176.180, 181.30
3 BfR XIV, XXI,XXXIV,XXXVI
3 3 3 3 3 3 3 3 Mixture ✖ Harmful (Xn),Irritant (Xi)
R22, R41
Emulsogen® LCN 118 Fatty alcohol ethoxylate
C11 oxo alcohol, ethoxylated with 11 moles EO
● ● ● ● 14 Clear liquid ca. 80% 3 3 Readily biodegradable
>61% (28d)OECD301B
§ 175.105, 176.170,176.180, 181.30
3 BfR XIV, XXI,XXXIV,XXXVI
3 3 3 3 3 3 3 3 Mixture ✖ Harmful (Xn),Irritant (Xi)
R22, R41
Emulsogen® LCN 158 Fatty alcohol ethoxylate
C11 oxo alcohol, ethoxylated with 15 moles EO
● ● ● ● 16 Clear liquid ca. 80% 3 3 Readily biodegradable
>75% (28d) OECD301B
§ 175.105, 176.170,176.180, 181.30
3 BfR XIV, XXI,XXXIV
3 3 3 3 3 3 3 3 Mixture ✖ Harmful (Xn),Irritant (Xi)
R22, R41
Emulsogen® LCN 217 Fatty alcohol ethoxylate
C11 oxo alcohol, ethoxylated with 21 moles EO
● ● ● ● 17 Clear liquid ca. 70% 3 3 Readily biodegradable
>75% (28d)OECD301B
§ 175.105, 176.170,176.180, 181.30
3 BfR XIV, XXI,XXXIV,XXXVI
3 3 3 3 3 3 3 3 Mixture label free label free label free
Emulsogen® LCN 287 Fatty alcohol ethoxylate
C11 oxo alcohol, ethoxylated with 28 moles EO
● ● ● ● 17,5 Clear liquid ca. 70% 3 3 Readily biodegradable
>75% (28d)OECD301B
§ 175.105, 176.170,176.180, 181.30
3 BfR XIV, XXI,XXXIV
3 3 3 3 3 3 3 3 Mixture label free label free label free
Emulsogen® LCN 407 Fatty alcohol ethoxylate
C11 oxo alcohol, ethoxylated with 40 moles EO
● ● ● 18 Clear liquid ca. 70% 3 3 Inherently biodegradable
> 80 % OECD302B
§ 175.105, 176.170,176.180, 181.30
3 BfR XIV, XXI,XXXIV
3 3 3 3 3 3 3 3 Mixture label free label free label free
Emulsogen® TS 200 Tristyryl ethoxylate
Tristyryl ethoxylated with 20 moles EO
● ● ● 14 Yellowish brown liquid ca. 100% 3 3 - 10-35% OECD302B
BfR XIV, XXI,XXXIV
3 3 3 3 3 3 3 3 3 Substance label free label free label free
Genapol® PF 10 EO/PO block copolymers
10% EO, 90% PO ● ● ● 13 Clear colorless liquid ca. 100% 3 3 Readily biodegradable
100% (28d)OECD 301B
§ 175.105, 176.180,176.200, 176.210,
3 BfR V, VI,XIV, XXXVI
3 3 3 3 3 3 3 3 3 3 Substance label free label free label free
Genapol® PF 20 EO/PO block copolymers
20% EO, 80% PO ● ● ● 14 Slightly cloudy, colorless liquid
ca. 100% 3 3 Readily biodegradable
99% (28d)OECD 301F
§ 175.105, 176.180,176.200, 176.210,
3 BfR V, VI,XIV, XXXVI
3 3 3 3 3 3 3 3 3 3 Substance label free label free label free
Genapol® PF 40 EO/PO block copolymers
40% EO, 60% PO ● ● ● 16 Slightly cloudy, colorless liquid
ca. 100% 3 3 Readily biodegradable
61% (28d)OECD 301F
§ 175.105, 176.180,176.200, 176.210,
3 BfR V, VI,XIV, XXXVI
3 3 3 3 3 3 3 3 3 3 Substance label free label free label free
Genapol® PF 80 EO/PO blockcopolymers
80% EO, 20% PO ● ● ● ● 19 Wax ca. 100% 3 3 - <10% (28d)OECD302B
§ 175.105, 176.180,176.200, 176.210,
3 BfR XIV,XLVIII, LIII
3 3 3 3 3 3 3 3 3 3 Substance label free label free label free
Genapol® X 080 Fatty alcohol ethoxylate
C13 oxo alcohol, ethoxylated with 8 moles EO
● ● ● ● ● 12 Slightly cloudy, colorless liquid
ca. 100% 3 3 Readily biodegradable
60% (28d)OECD 301F
§ 175.105, 176.170,176.180, 176.200,176.210, 181.30
3 BfR V, VI,XIV, XV, XXI,XXXIV, XXXVI, LI, LII
3 3 3 3 3 3 3 3 3 3 Substance
Danger H302, H318
Genapol® X 307 Fatty alcohol ethoxylate
C13 oxo alcohol, ethoxylated with 30 moles EO
● ● ● ● 18 Clear colorless liquid ca. 70% 3 3 Readily biodegradable
100% (25d)OECD 301B
§ 176.170, 176.180,176.200, 181.30
3 BfR V, VI,XIV, XV, XXI,XXXIV
3 3 3 3 3 3 3 3 3 3 Mixture label free label free label free
Genapol® X 407 Fatty alcohol ethoxylate
C13 oxo alcohol, ethoxylated with 40 moles EO
● ● ● 18 Clear colorless liquid ca. 70% 3 3 Readily biodegradable
100% (25d)OECD 301B
§ 176.170, 176.180,176.200, 181.30
3 BfR V, VI,XIV, XV, XXI,XXXIV
3 3 3 3 3 3 3 3 3 3 Mixture label free label free label free
Genapol® X 1003 Fatty alcohol ethoxylate
C13 oxo alcohol, ethoxylated with 100 moles EO
● ● ● 19 Clear colorless liquid ca. 35% 3 3 - 50-60% OECD301B
§ 176.170, 176.180,176.200, 181.30
3 BfR V, VI,XIV, XV, XXI,XXXIV
3 3 3 3 3 3 3 3 3 3 Mixture label free label free label free
Genapol® X 1005 Fatty alcohol ethoxylate
C13 oxo alcohol, ethoxylated with 100 moles EO
● ● ● 19 Clear colorless liquid ca. 50% 3 3 Readily biodegradable
>95% (25d)OECD 301B
§ 176.170, 176.180,176.200, 181.30
3 BfR V, VI,XIV, XV, XXI,XXXIV
3 3 3 3 3 3 3 3 3 3 Mixture label free label free label free
aPPlicaTion ProPerTieS food conTacT regulaTion inVenTory regiSTraTion STaTuS HaZardouS labeling according To gHS3
or dangerouS SuSbSTance direcTiVe4
1 Product listed in chapter 21 CFR of the US Food and Drug Administration 2 The product meets the requirements of the Bundesamt für Riskikobewertung (German authority of risk assessment) 3 Hazardous labeling according to the Globally Harmonized System 4 Hazardous labeling according to the European Dangerous Substance Directive (EU Annex I Directive 67/548/EEC) 5 (GHS) is an internationally agreed upon system set to use worldwide unified standards for classification of chemicals as well as safety data sheets under the roof of the United Nations. The European Commission approved GHS in the “Regulation on classification, labeling and packaging of substances and mixtures “ on 16.12.08 (EU regulation 1272/2008). According the EU regulation, the classification and labteling has to be done until: - 01.12.2010 for substances - 01.06.2015 for mixtures (i.e. chemical preparations)“ 6 risk phrases: R22: Harmful if swallowed R36: Irritating to eyes R38: Irritating to skin: R36/38: Irritating to eyes and skin R41: Risk of serious damage to eyes R52: Harmful to aquatic organisms R53: May cause long-term adverse effects in the aquatic environment R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
6 Hazard Statements: H302: Harmful if swallowed H315: Causes skin irritation H318: Causes serious eye damage H411: Toxic to aquatic life with long lasting effects H412: Harmful to aquatic life with long lasting effects