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Radford University Environmental Health and Safety
Hazardous Waste Management Program Guidebook
Revised 12/5/14
Table of Contents1.0 Introduction pg.1 2.0 Responsibilities pg.2 3.0 Procedures pg.3
3.1 Hazardous Waste Determination pg.3 3.1.1 Characteristic Hazardous Waste pg.4 3.1.2 Listed Hazardous Wastes pg.5 3.1.3 Restrictions pg.6
3.2 Satellite Accumulation of Hazardous Waste pg.7 3.2.1 Accumulation Areas pg.7 3.2.2 Requirements for Waste Containers pg.8 3.2.3 Segregation of Hazardous Wastes pg.8 3.2.4 Special Handling pg.10 3.2.5 Pickup for Full Waste Containers pg.10 3.2.6 Weekly Inspection of Accumulation Areas pg.11
3.3 Other Waste Requirements pg.11 3.3.1 Biohazardous Wastes pg.11 3.3.2 Radioactive Wastes pg.11 3.3.3 Mixed Wastes pg.11 3.3.4 Ethidium Bromide pg.12 3.3.5 Photograhpic and X-ray Fixer Waste pg.12 3.3.6 Spray Cans pg.12 3.3.7 Reagents Used in Biological Procedures pg.12 3.3.8 Broken Glass pg.12
3.4 Empty Containers pg.13 3.5 Waste Minimization pg.13
3.5.1 Source Reduction pg.13 3.5.2 Recycling pg.15 3.5.3 Process Modification pg.16
3.6 Emergency and Spill Response pg.16
3.6.1 Chemical Spill Emergency Procedures pg.17 3.6.2 General Emergency Procedures pg.20
3.7 Training pg.20 4.0 Document Management pg.21 5.0 Associated Documents pg.21 Appendix A pg.22 Appendix B pg.24
Appendix C pg.26
Appendix D pg.86
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1.0 Introduction
Hazardous waste is strictly regulated by the Environmental Protection Agency under the 1976
Resource Conservation and Recovery Act (RCRA). This Act mandates a "cradle-to-grave"
system (i.e. from the laboratory to complete destruction) for managing hazardous waste and
applies to those who generate, store, transport, treat, recycle, or dispose of hazardous waste. The
purpose of the Act is to protect human health and the environment from improper waste
management practices. RCRA regulations are found in the 40 Code of Federal Regulations
(CFR) Parts 260-279 and can be accessed at the United States Environmental Protection Agency
(USEPA) website (www.epa.gov).
At first environmental laws were mainly focused on industry, which generates the largest portion
of hazardous waste. In 1986, however, amendments to RCRA extended the law to cover most
colleges and universities. This was done in response to public concerns about pollution from the
mismanagement of even small quantities of hazardous waste. Although not comparable in
volume to industry, academic institution produce a large variety of hazardous waste, creating
numerous waste management problems. In addition to chemistry laboratories, hazardous waste is
routinely produced in areas such as biology, geology, art, printing, drama, and the physical plant.
There are specific regulatory requirements for individuals who generate and accumulate
chemical waste requiring disposal. Generators are legally and morally obligated to dispose of
hazardous waste in a manner that will minimize damage to health and the environment. This
effort requires the cooperation and commitment of workers, departments, and top management.
It is the practice of Radford University to provide generators with a safe and appropriate means
of managing hazardous waste. This will normally be done at no cost to generators.
An overview of the RU hazardous waste management procedures is presented in this document.
The procedures outlined in this document are designed to promote:
Safe handling of wastes to prevent spills and other accidents
An efficient disposal process for all employees at RU
Compliance with all applicable regulations governing hazardous wastes
Implementation of these procedures requires the cooperation of faculty, staff, and students.
The purpose of this manual is to provide the following concise and direct information:
Hazardous waste requirements by regulatory agencies
Hazardous waste determination
Hazardous waste accumulation, storage, and pickup procedures
Procedures for empty hazardous material and waste containers
Waste minimization procedures
Emergency and spill response procedures
Training requirements
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Every lab at RU is subject to unannounced inspections by the USEPA and the Virginia
Department of Environmental Quality (DEQ). A single violation can result in costly fines.
Any questions should be directed to Environmental Health and Safety (EHS) at 540-831-7790.
2.0 Responsibilities
Individuals who generate hazardous waste are responsible for ensuring that their waste is
managed properly. Chemicals must be disposed of in compliance with EPA, RCRA, and DOT
regulations. Non-compliance with these regulations could result in fines and legal action. Fines
of $37,500 per incident per day are possible for the institution, and individuals may be held
criminally and civilly liable for violating waste management regulations, up to 5 years in prison
and/or $50,000 fine per incident per day. (See http://www2.epa.gov/enforcement/rcra-corrective-
action-enforcement-authorities and http://www2.epa.gov/enforcement/criminal-provisions-
resource-conservation-and-recovery-act-rcra for more details). Even after legal disposal,
generators retain responsibility for the waste as long as it can harm human health or the
environment.
EHS functions both in an advisory and consultative capability, and as a service organization for
the hazardous waste management program at Radford University. EHS shall:
Coordinate the comprehensive hazardous waste management program
Ensure all hazardous waste permits are obtained and maintained current
Operate a campus-wide hazardous waste collection service which provides for the safe
and timely collection/removal of hazardous materials
Manage applicable disposal service contracts
Prepare and submit regulatory reports and fees as applicable
Provide training to individuals who handle hazardous waste or inspect accumulation
areas
Coordinate the waste minimization program
Assist academic personnel (customers) with compliance questions and problems to
continuously improve campus compliance
Faculty, staff, and students are responsible for complying with the regulations and practices
promulgated as a result of federal and state legislation, university policies, and established
guidelines. In addition, faculty and staff are responsible for ensuring employees and students are
aware of and properly implementing safe handling and storage procedures for hazardous
materials and wastes. Generators (e.g. faculty, staff, or students who produce hazardous waste)
can dispose of hazardous waste in a responsible manner by ensuring that:
Hazardous waste is disposed of by legal and safe means.
Absolute minimum quantities are produced.
Non-hazardous or the least hazardous chemicals are used.
Hazardous waste is collected in proper containers.
Hazardous waste is correctly identified and labels are properly completed.
Only compatible chemicals are mixed in a common container.
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Waste is temporarily stored in an acceptable manner in a satellite accumulation area.
EHS is notified for a pick-up in a timely manner.
3.0 Procedures
Disposal of hazardous waste using sinks, intentional evaporation, and general trash cans is
prohibited by law. Dilution of a waste is not a legitimate form of disposal. RU laboratory
personnel must abide by strict state and federal waste disposal requirements Use the following
information to make sure you have identified all hazardous waste you generate and dispose of it
properly.
3.1 Hazardous Waste Determination
USEPA explicitly describes the requirements:
1. You must determine if you are a generator of hazardous waste. USEPA defines a
generator in 40 CFR 260.10 as, βAny person, by site, whose act or process produces
hazardous waste identified or listed in Part 261 or whose act first causes a hazardous
waste to become subject to regulation.β
The first things you need to know is βWho is a Generator?β Within the definition
presented here, there are several βkey wordsβ that need some explanation:
Person β (40 CFR 260.10) RCRA defines a βpersonβ very broadly to mean an
individual, trust, firm, joint stock company, federal agency, corporation,
partnership, association, state, municipality, commission, political subdivision of
a state, or any interstate body. For Radford University, a βpersonβ would be a
Principal Investigator (PI) or Supervisor, lab worker, or lab student.
Site β while βsiteβ is not specifically defined, the definition of the term βon-siteβ
(40 CFR 260.10) talks about the same or geographically contiguous property. For
the University, the campus (as is shown on a campus map) is considered a site.
Produces a Waste β as it implies, those whose act or process produce a waste are
generators of the waste. At the University, the βpersonβ that would produce the
waste would be respective PI or Supervisor, lab worker, or lab student that
generates the waste.
Note that the EPA definition of generator provides no exclusion for infrequent or
accidental waste generation. If you are not a generator, you can become a generator if you
spill a product which is a hazardous waste when discarded. Understanding the definition of
generator will help you to better understand when and how your activities are regulated by
law.
2. A generator must determine if the waste is a solid waste. According to the USEPA, a
solid waste does not have to be a waste in a solid state of matter. A βsolidβ waste can be
either solid, liquid, or a compressed gas and is specifically defined as:
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βAny discarded material that is:
Abandoned through (1) disposal, (2) burning or incineration, or (3)
accumulation, storage, or treatment; or
Recycled; or
Inherently waste-like (dioxins and furans)
And is not excludedβ
Abandoned Chemicals
Many laboratory waste generators accumulate or store chemicals which have value, but over
time become βforgotten.β When the PI or Supervisor fails to manage and maintain their
chemicals (containers corrode, labels fall off, labels yellow with age, etc.) the chemicals, by
USEPA definitions, become βabandoned.β An abandoned material is considered discarded,
and is therefore a solid waste. MANAGE OR DISPOSE OF ABANDONED CHEMICALS
IMMEDIATELY
3. If it is a solid waste, a generator must determine if the waste is a hazardous waste.
All wastes generated at the University must be characterized to determine whether they
are a hazardous waste. Once you have a waste, it can be defined as a Hazardous Waste by
two different means:
A. Characteristic
B. Listed
3.1.1 Characteristic Hazardous Waste
Most wastes generated in laboratories will be hazardous due to one of the four characteristics
discussed below. If there is doubt as to whether your waste meets one of the four characteristics,
EHS requires it to be handled as hazardous waste.
A waste is hazardous if it exhibits any one of the four characteristics of a hazardous waste:
Ignitability, Corrosivity, Reactivity, or Toxicity.
CONTACT EHS to make a definitive hazardous waste determination. Assume that all chemical
wastes are hazardous until a definitive determination can be made. This includes low
concentration wastes or chemicals where you are unsure of the properties. If you have any
questions, contact EHS at 540-831-7790 for assistance.
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The following are the four characteristics and a few examples of common wastes at the
University:
Ignitable
Flammable liquids β flashpoint <140Β°F β Alcohols, Benzene, Toluene, Xylene
Flammable solids β solids that ignite easily and burn vigorously
Oxidizers β Nitrates, Perchlorates, Bromates, Permanganates, Peroxides, Iodates
Organic Peroxides β Benzoyl Peroxide, Methyl Ethyl Keytone Peroxide
Ignitable compressed gases β Butane, Acetylene, Ammonia
Corrosive
Aqueous liquids with pH < 2 or pH > 12.5 or other liquids capable of corroding steel at a
rate of > 6.35 mm (0.250 inches) per year at a test temperature of 55Β°C (using an ASTM
test procedure)
o Inorganic acids β Hydrochloric Acid, Sulfuric Acid, Nitric Acid, Perchloric Acid,
Phosphoric Acid
o Organic acids β Formic Acid, Lactic Acid
o Bases β Hydroxide Solutions, Amines
Reactive
Materials which are normally unstable and readily undergo violent change, react violently
with water, form potentially explosive mixtures with water, form toxic gases, vapors, or
fumes when mixed with water, capable of detonation or explosive decomposition if
subjected to a strong initiating source or heated under confinement, or capable of
detonation or reaction at standard temperature and pressure
o Sulfides and cyanides
o Peroxide formers β Ethers, Potassium Amide, Sodium Amide, Vinyl Acetate,
Tetrahydrofuran
o Alkali metals β Sodium, Potassium, Lithium
o Dinitro β and trinitro β compounds β Picric Acid
o Carbonyl compounds
o Isocyanates
o Perchlorate crystal formers β Perchloric Acid
Toxic
The USEPA specified a selected group of eight (8) heavy metals, ten (10) pesticides, and twenty-
two (22) organic chemicals as classified as hazardous due to their toxicity characteristic
(Appendix A). Any detectable amount of these chemicals must be identified on the Hazardours
Waste label.
In addition, wastes that exhibit the following toxicity are considered hazardous wastes:
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An acute oral LD50 less than 5,000 mg/kg
An acute dermal LD50 less than 4,300 mg/kg
An acute inhalation LC50 less than 10,000 ppm as a gas or vapor
An acute aquatic 96-hour LC50 less than 500 mg/L
Waste that pose a hazard to human health or environment because of its carcinogenicity
(carcinogen, mutagen, teratogen), acute toxicity, chronic toxicity, bioaccumulative
properties, or persistence in the environment
3.1.2 Listed Hazardous Wastes
The USEPA has promulgated a list of chemicals found in 40 CFR 260-279 that are automatically
determined to be a hazardous waste. If your waste is a chemical on the list, it is a hazardous
waste. There are a substantial number of chemicals found on these lists. If you do not have a
copy of these lists, one can be obtained by calling EHS at 540-831-7790. Also, you can refer to Appendix C. CHECK THIS LIST FOR YOUR WASTE MATERIAL. If it is on the list, treat
it as a hazardous chemical waste. If you donβt see your material on this list, determine if it meets
any of the characteristics listed in the previous section, above. If your waste meets any of those
characteristics, it is a hazardous chemical waste and must be handled according to the
instructions given in this guidebook.
CONTACT EHS to make a definitive hazardous waste determination. Assume that all chemical
wastes are hazardous until a definitive determination can be made. This includes low
concentration wastes or chemicals where you are unsure of the properties. If you have any
questions, contact EHS for assistance at 540-831-7790.
3.1.2.1 Acute Hazardous Waste
Some wastes are on a sub-list of what the USEPA calls βacutely hazardous wastesβ (also called
βP-listedβ wastes because their USEPA waste numbers all start with a βPβ for βpoisonβ). The
acutely hazardous wastes are specifically identified in Appendix C by name. Wastes containing
these chemicals are limited to one total quart per accumulation area [your laboratory].
3.1.3 Restrictions
Virginia Hazardous Waste Management Regulations apply to the generation, storage, treatment,
transportation, and disposal of hazardous waste. Radford University is classified as a "generator
only." Under these regulations individuals who generate hazardous waste are prohibited from:
Treatment of a hazardous waste except as part of an on-going process at the point of
generation (e.g., neutralization as the last step in a laboratory experiment). Acids and
bases cannot be collected in a common container and neutralized.
Transportation of any hazardous waste from the generating facility (Radford University)
except through a licensed disposal firm. Transportation to waste storage facilities on
campus is restricted to properly trained individuals.
Discarding of hazardous waste in the general refuse, storm drains, or by burning, burial,
sale, giveaway, or any route other than that provided by the waste disposal service.
Chemical exchange between university departments is encouraged.
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Biological, radioactive, and asbestos waste must be handled separately. Please call EHS
at 540-831-7790 for proper procedures. Radioactive waste shall not be mixed with
general chemical waste.
Chemical mixtures from laboratories are acceptable as waste, however, ensure that only
compatible chemicals are poured into common containers.
Disposal of hazardous waste in the sanitary sewer is prohibited unless steps are taken to
render the material non-hazardous. Toxic, flammable, organic solvents, noxious, or
lachrymatory chemicals cannot be disposed of in the sink. Strong acids and bases must be
neutralized to pH 5.0-10.5 to be in compliance with local wastewater regulations
however, acids and bases can only be neutralized as part of an ongoing process (such as
the last step in a procedure).
Generally, limited quantities of some wastes can be disposed of in the sanitary sewer. In
general, only water soluble, non-toxic substances may be poured down the sink. The
university must comply with local regulations regarding what can be poured into the
sewer system. Permission must first be obtained from the local sewer authority. Contact
EHS before disposing of any chemicals into the laboratory sink. At the time of this
documents publication, there has been no approval for drain disposal for any chemical
wastes.
3.2 Satellite Accumulation of Hazardous Waste
Ten Golden Rules of Hazardous Waste Accumulation:
1. Use only collection containers that are capable of safely storing the waste and that are in
good condition.
2. Place supplied βHazardous Wasteβ labels on all containers, indicate the contents and the
nature of the hazard, as soon as hazardous waste is first added. Position the containers so
that the waste labels are visible (face forward).
3. Keep the waste container closed, except when adding waste.
4. Store all liquid containers in secondary containment.
5. Segregate containers, keeping incompatible wastes, radioactive wastes, and regulated
medical wastes separate.
6. Maintain ten percent free space in waste containers to allow for expansion.
7. Conduct weekly inspections of hazardous waste accumulation area and maintain an
inspection log.
8. Submit the completed Request For Hazardous Waste Disposal form to EHS when the
containers are 90% full. Forms are available at: www.radford.edu/ehs
9. Attend and document all annual training for all persons generating hazardous waste.
10. Post the name and phone numbers for responsible person to contact 24 hours a day in
case of an emergency.
Regulated medical waste can be picked up by either contacting your latest approved contractor
for disposal services or by contacting EHS at 540-831-7790.
3.2.1 Accumulation Areas
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Generators may accumulate up to a total of 55 gallons of hazardous waste, or a total of one (1)
quart of acutely hazardous waste, at or near the point of generation [your laboratory],
provided that the waste:
Remains under the control of the PI or Supervisor and their assistants
Containers are closed and in good condition
Contents are marked on the outside of the container
Hazardous wastes must not be transported outside your laboratory by anyone other than EHS
personnel. Hazardous waste must be transported directly from you laboratory accumulation area
to the RU Hazardous Materials Storage Building. EHS is responsible for and maintains the
storage building in accordance with applicable regulations.
3.2.2 Requirements for Hazardous Waste Containers
Chemicals for disposal must be placed in a sealed container, preferably with a screw type
cap. Containers with cracked or corroded caps, paraffin, rubber, cork, or glass stoppers
are not acceptable.
Hazardous waste containers must be labeled with a hazardous waste label as soon as
waste is first added
o Follow instructions on the back of the label to guide you in filling out the label.
Labels must be completely filled out, except for the βDATE WHEN FULLβ
o BY LAW, chemical symbols, abbreviations, and/or formulas are not permitted as
means of identification
o Do not omit the cation, or anion name for aqueous solutions of salts
o Do not use βExp. #...β or βLab #...β as a means of identification
o For any questions, call EHS at 540-831-7790
Hazardous waste containers must be compatible with their contents
o Do not store corrosive or halogenated solvent wastes in metal containers
o Do not store waste hydrofluoric acid in glass containers
o Do not store waste organic solvents in plastic containers
Hazardous waste containers must be kept closed, except when waste is added. Use a
container with a flat bottom. Most common problems found with containers:
o The funnel is left in open container
o An open container is left in a fume hood
o DO NOT USE stoppers or corks! Use a screw top lid
Hazardous waste containers must be leak-proof and free of exterior contamination
An inventory log must be maintained for each hazardous waste container (see Appendix
D).
Wipe down containers prior to requesting pickup by EHS
Hazardous waste containers should be in secondary containment
o Secondary containment can be any container or tray that will hold 110% of the
volume of the largest waste container stored within the secondary containment,
and should be compatible with the hazardous waste
o Secondary containment will hold any waste chemical spills or leaks from the
waste containers within it
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o Secondary containment also is used to segregate hazardous wastes that are
incompatible, such as waste acids and bases
o Lab trays and dishpans are frequently used for secondary containment in
laboratories
3.2.3 Segregation of Hazardous Wastes
Chemical Hazardous wastes must be segregated (stored separately) from incompatible
chemical wastes, radioactive wastes, and regulated medical wastes
Chemical wastes should be accumulated and segregated by the following general
groupings:
o Mineral (Inorganic) Acids β Examples: hydrochloric acid, sulfuric acid,
phosphoric acid, boric acid, and hydrobromic acid
o Oxidizers β Examples: bromic acid, perchloric acid, chromic acid, nitric acid,
many perchlorates, permanganates, bromine, chlorine, fluorine, silver nitrate
Oxidizers should not be stored directly on wooden shelves or on paper
shelf liners, spills may react and ignite spontaneously
Perchloric acid presents special hazards; it must be isolated from
oxidizable materials and dehydrating agents
Hypochlorite solutions (e.g. bleach) are oxidizers; however, they will
release chlorine gas on contact with acids, so store them separately
o Bases/Caustics β Examples: aqueous ammonia, ammonium hydroxide, potassium
hydroxide, and sodium hydroxide
o Flammable Non-Halogenated Organic Solvents β Examples: acetone,
methanol, isopropyl ether, benzene, and tetrahydrofuran. If space is limited,
laboratories may wish to store these flammable organic wastes solvents in
flammable storage cabinets
o Halogenated Organic Solvents β Examples: methylene chloride, carbon
tetrachloride, tribromoethane
o Organic Acids β Examples: acetic acid, butyric acid
o Highly Toxic/Carcinogenic β Examples: formalin/formaldehyde, ethidium
bromide, sodium azide, acrolein, arsenic pentoxide, pentachlorophenol,
hydrazine, botulinum toxin, acrylamide, methyl isocyanate, phorbol esters
o Mercury/Mercury Compounds o General βDryβ Lab Chemicals β Examples: This would include many of the
relatively innocuous or unreactive solid materials commonly found in laboratories
o Gases β Segregate waste compressed gases according to hazard class.
Acutely toxic and toxic gases should be stored in gas cabinets or fume
hoods
Cylinders should be chained or strapped to a substantial, fixed surface
Cylinders should be turned off at the cylinder valve when not in use and
should be capped when stored
Compressed gas cylinders can corrode or degrade over time and should be
returned to the manufacturer if they are no longer being used. This will
remove any potential hazard and save the demurrage charge, which can
exceed the cost of the gas over time
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Do not use lecture bottles if other cylinders are available! Waste
lecture bottles are very difficult and costly to dispose of and they use
universal threads and valves (some of which are interchangeable). Attempt
to return waste lecture bottle cylinders directly to the manufacturer
o Water/Air Reactives β Examples: sodium, potassium, calcium, aluminum
tribromide, calcium oxide, acid anhydrides, metal hydrides, alkyl phosphines
o Pyrophoric Materails β Examples: diethyl aluminum chloride, lithium, white or
yellow phosphorous, trimethylaluminum
o Oils β Used pump oil with organic or inorganic components
o Photographic Waste
o Spray Cans
3.2.4 Special Handling
Gas Cycinders
Gas cylinders can be very expensive and/or impossible to dispose of through a hazardous
waste company. The cylinders should be returned to the supplier, if possible. Generally a
rental charge or cash deposit on the empty cylinder is included in the purchase price.
Lecture bottles should be returned to the supplier.
Reactives and Explosives
1. Reactives and potential explosives require special handling for disposal. The procedure is
very time consuming and expensive. To reduce disposal costs personnel should take
necessary precautions to prevent the production and storage of waste explosives in
laboratories. Many laboratories produce potential explosives by not following safety
guidelines. Two of the most common items produced in this manner are peroxidized
ethers and dry picric acid. Do not disturb potential explosives.
2. Peroxide forming compounds (e.g. ethyl ether, 1,4 dioxane, THF, etc.) should have a date
of receipt and a date of opening on the container. Discard within six months if opened or
one year if unopened.
3. Ensure that picric acid always contains at least 10% water.
Unknowns
1. Unknown wastes are handled on a case by case basis and can be very expensive to
dispose of. Please ensure that all chemicals are identified, properly labeled, and
expiration dates are observed.
2. Unknown materials cannot be disposed of until a sample has been analyzed. Every
possible effort should be made to identify each waste. Unknowns can be accepted
conditionally, but may be returned to the department for chemical analysis (expenses to
be paid by the department) if the hazardous waste contractor cannot categorize the waste.
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3. Do not guess at the identity or create a name for an unknown. A wrongly identified waste
could harm life and property. It could also subject the individual generator and the
University to USEPA regulatory fines and potential lawsuits.
3.2.5 Pickup for Full Waste Containers
When hazardous waste containers in laboratory satellite accumulation areas are no more than
90% full:
Complete DATE WHEN FULL on the hazardous waste label
Complete the βRequest For Hazardous Waste Disposalβ form from the EHS website,
wwwβ¦memoryβ¦edu, and send to EHS
o The first page of the form is for listing generator information, hazardous wastes,
etc.
o The second page has the instructions for completing the form
Full Container Must Be Removed From Accumulation Areas Within 3 Days
3.2.6 Weekly Inspection of Accumulation Areas
All satellite accumulation areas should be inspected weekly. An inspection form is given in
Appendix B. Weekly inspections should be documented on a form like the one found in
Appendix B and records of these inspections must be kept in each lab that accumulates waste for
a duration of three (3) years.
3.3 Other Waste Requirements
3.3.1 Biohazardous Wastes
Red Regulated Medical Waste (RMW) bags NEVER go in the general trash, whether
autoclaved in-house or not
Non-RMW-contaminated syringes/sharps must be treated as if they are RMW
Proper disposal is the Department or PI responsibility.
Retain copies of manifests, shipping documents provided by the vendor for 3 years
Contact EHS at 540-831-7790 for assistance
3.3.2 Radioactive Wastes
For disposal of radioactive wastes please contact EHS at 540-831-7790. At the time of this
publication, there are no PIs authorized to possess radioactive material.
3.3.3 Mixed Wastes: Chemical/Biohazardous/Radioactive
Mixed Infections/Chemical Waste
Whenever possible, disinfect infectious waste at the source of generation. Contact EHS at 540-
831-7790 for approved methods of disinfection.
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Containers and Storage: Collect non-sharps infectious waste which is also contaminated with
chemicals (mixed waste) in a red biohazard bag. After the infectious agent has been disinfected,
place the red biohazard bag in a second, clear plastic bag. Add absorbent material (such as
diatomaceous earth) to the second bag, sufficient to absorb fluids which may leach from the
waste.
Seal and attach a completed hazardous waste label to the clear bag. On the βcontentsβ section of
the tag it is important to note both the chemical waste and the infectious waste and the
disinfection method that was used.
Sharps and piercing objects contaminated with both chemicals and infectious agents are
handled separately from those contaminated with chemicals only. Since they will create both
a physical hazard and contamination problems if placed in regular waste bags, dispose of mixed
waste sharps and piercing objects in a specially designed rigid, polyethylene sharps container.
Sharps containers must not contain free liquids (such as fully syringes). When the sharps
container is full, seal and remove it from the collection area. Place the container in a clear plastic
bag and seal it. Attach a hazardous waste label and list all chemical and infectious agents and the
method of deactivation/disinfection used. For pickup, please follow the instructions laid out
earlier in this document.
3.3.4 Ethidium Bromide
Concentrated stock solutions and gels that have not been destained must be handled as hazardous
waste. (Do not put gels down the sink drain.) If a lab chooses to decontaminate their ethidium
bromide, the filter and/or resin beads must be handled as hazardous waste.
3.3.5 Photographic and X-ray Fixer Waste
Fixers contain some silver which must be treated before it can be disposed of. Hazardous waste
labels must be placed on the containers and the Request for Disposal form completed and sent to
EHS for pickup. At this time, EHS is providing waste containers for bulking of Photographic
Fixer waste.
3.3.6 Spray Cans
Waste spray cans still containing product are considered hazardous waste and must be disposed
of through EHS. Place a completed hazardous waste label on the spray can and send in the
completed Request for Disposal form to EHS.
3.3.7 Reagents Used in Biological Procedures
The following are reagents that contain mercury and should be managed as hazardous wastes:
Dobbinβs Reagent, Hayemβs Solution, Hopkins-Cole Reagent, Hubbβs Reagent,
Jacquemartβs Reagent, Knappβs Solution, Mercresin, Meyerβs Solution, Millonβs
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Reagent, Morellβs Solution, Nesslerβs Reagent, Rohrbachβs Solution, Sachsseβs Solution,
Spieglerβs Reagent, Tanretβs Reagent, and Tyrosine Reagents
Other hazardous reagents include:
Erlickiβs Solution (chromium)
Fisherβs Reagent (phenyl hydrazine)
Flemmingβs Solution (osmium, chromic acid)
Folin-Dennis Solutions (mercuric cyanide)
3.3.8 Broken Glass
Broken glassware should be placed into an appropriate broken glassware container. Since they
will be picked up by the custodial staff these containers should be labeled with the words
βBroken Glass.β Do not place broken glassware, pipettes, or other sharp-edged materials of
any type into the regular trash.
3.4 Empty Containers
A container that held any hazardous waste is empty if:
All wastes have been removed that can be removed using the practices commonly
employed to remove materials from the type of container (e.g., pouring, pumping, and
aspirating) AND it does not contain acutely hazardous waste
If the waste container held acutely hazardous waste, the container MUST be triple rinsed
using a solvent capable of removing the residual chemical product before disposing of the
container:
o The solvent can be water or any liquid that will remove the hazardous residue in
the container
o Make sure you collect wash solvent and add to a compatible hazardous waste
accumulation container in the lab
Under no circumstances may a container labeled with the International Radioactive
Symbol or with the words βHazardous Wasteβ be disposed of in the general trash.
When empty, so it is clear that the container no longer contains hazardous materials, do one of
the following:
Remove the label
Completely deface the label with a marker
Tape over the label
If the container that held acutely hazardous waste is not triple rinsed, then it is not empty
and the CONTAINER MUST have a hazardous waste label attached and be
properly disposed of as hazardous waste.
3.5 Waste Minimization
14
Effective hazardous waste management requires not only safe, sound practices, but also requires
good efforts to reduce the volume and toxicity of hazardous wastes. RUβs waste minimization
efforts reduce disposal, hazards, and environmental impact associated with chemical wastes. The
success in minimizing hazardous wastes depends on a conscientious effort by each individual at
the University. The following are some common waste minimization strategies.
3.5.1 Source Reduction
The most desirable method of waste minimization is source reduction. This is any activity that
reduces or eliminates the generation of chemical hazardous waste at the source. This can be
accomplished by good material management, substitution of less hazardous materials, and good
laboratory procedures. Examples include:
Reducing Chemical Purchases: A substantial portion of hazardous waste produced at the
University consists of unused, outdated chemicals. Careful planning of quantities of chemicals
required can reduce costs to the laboratory and reduce waste volumes. Many chemicals may also
degrade over time, so careful consideration of quantities purchased is important to reducing
potential waste. Also, risk of accident and exposure to these chemicals and space allocations are
less when handling smaller volumes of materials.
Although it may seem less expensive to buy chemicals in larger quantities, it is in fact more
expensive, if the cost for disposal is taken into consideration. Some chemical manufacturers sell
chemicals in smaller containers to help laboratories reduce the excess purchase of chemicals.
When disposal costs are considered, it is more economical to purchase only the quantities
of chemicals that will be used.
Teaching labs should consider the use of microscale experiments
Teaching labs should use demonstrations or video presentations as a substitute for some
student experiments that generate chemical wastes
Teaching labs should use pre-weighed or pre-measured reagent packets where waste
generation is high
Substitution: A non-hazardous chemical can often be used in place of a hazardous chemical. For
example, some academic laboratory procedures still specify benzene or carbon tetrachloride as
reagents or solvents. These compounds often can be replaced by less hazardous materials. This
results not only in safer procedures, but also in wastes that may be less hazardous in some
respects. Additionally, many commercial, non-hazardous glass cleaners are available in lieu of
toxic and corrosive chromic acid. Similarly, different procedures may be available which do not
require the use of hazardous chemicals.
Evaluate procedures to see if a less hazardous or non-hazardous reagent could be used
Avoid the use of reagents containing: arsenic, barium, cadmium, chromium, lead,
mercury, selenium, and silver
SEARCH FOR A SAFER SUBSTITUTE. Let us know if you find any not mentioned
here! Call us at 540-831-7790.
15
For many laboratory methods, environmentally sound alternatives exist:
If You Use: Substitute:
Xylene-,benzene-, and toluene-containing
reagents in histology laboratories
Citric acid-based reagents (e.g. AmeriClear or
Limonene-based extract)
Solvent based inks in printing operations Soy based inks
Formaldehyde Peracetic acid or ethanol
Mercury thermometers Non-mercury thermometers
Solvent extraction Solid phase or supercritical fluid extraction
Carbon tetrachloride Cyclohexane
If You Use: Substitute:
Sulfuric acid/potassium dichromate
(chromerge) cleaning solutions Detergents and enzymatic cleaners
Ultrasonic baths (these work well for
many labs)
Alconox or similar detergents
Pierce RBS-35 or similar detergents
Biodegradable surfactants
Potassium persulfate/sulfuric acid (sold
commercially as No-Chromix)
Aqua regia (mixture of hydrochloric and
nitric acids)
Potassium hydroxide/ethanol solutions
(also flammable)
Dilute hydrochloric acid
Ethidium bromide New filtration product to concentrate solvent
waste 10 times
Phosphate chloride detergents for lab glass
washing
Non-phosphate, non-chloride detergents
Chemical Exchange/Redistribution: Chemical purchases can often be reduced by borrowing
and sharing chemicals between laboratories. Departments are encouraged to exchange chemicals
whenever possible, rather than dispose of virgin chemicals as wastes. Many of these chemicals
are only partially used, have not exceeded their shelf life, and have not been altered in anyway.
Others are unused and still in the original sealed container. In some cases, these chemicals can be
used by someone else at the University.
Centralize purchasing of chemicals through one person in the department or laboratory
Date chemical containers when received so that older ones will be used first
Keep SDSs for chemicals on file
Inventory chemicals and identify their location at least once per year
Update inventory when chemicals are purchased or used up
16
Purchase chemicals in the smallest quantities needed
Label all chemical containers to prevent the generation of unknowns
βLess Is Betterβ Publication: The American Chemical Society has a laboratory waste
minimization publication entitled, βLess is Better.β This web document (available on our web
page and at http://www.acs.org/content/dam/acsorg/about/governance/committees/chemicalsafety/publications/less-is-
better.pdf ) presents more details on laboratory chemical waste minimization strategies outlined in
this section.
3.5.2 Recycling
The second most desirable approach is recycling. When a waste material is used for another
purpose, treated and reused in the same process, or reclaimed for another process, this is called
recycling. The following are examples:
When solvent is used for cleaning purposes, use contaminated solvent for initial cleaning
and fresh solvent for final cleaning.
Recover, redistill, and reuse your organic solvents whenever possible
Purchase compressed gas cylinders (including lecture bottles) only from manufacturers
who will accept the return of partially full or empty cylinders
Do not contaminate used oil with solvents because this prevents the oil from being
recycled
3.5.3 Process Modification
The third basic way to minimize waste is to modify processes, where practical. To the extent that
it DOES not affect vital research or teaching, modify experiments to decrease the quantity of
hazardous chemicals used and generated. Micro analysis techniques can greatly reduce the
amount of waste generated. An example of this is the use of microscale chemistry in entry level
teaching laboratories. Also, new equipment can reduce the amount of waste generated. For
example, new high performance liquid chromatography (HPLC) machines use microprocessors
to reduce the amount of waste generated. Contact peers or professional organizations for the
latest pollution prevention techniques.
3.6 Emergency and Spill Response
Quick Reference for Chemical Spill Emergency Procedures
Evacuate
o Leave the spill area; alert others in the area and direct/assist them in leaving
o Without endangering yourself: remove victims to fresh air, remove contaminated
clothing and flush contaminated skin and eyes with water for 15 minutes. If
anyone has been injured or exposed to toxic chemicals or chemical vapors, call
the Radford University Police Department (RUPD) at 540-831-5500 and request
medical attention immediately
Confine
17
o Close doors and isolate the area. Prevent people from entering the spill area
Report
o From a safe place, call RUPD at 540-831-5500
o Report the emergency and give your name, phone and location, locations of the
spill, the name and amount of material spilled, extent of injuries, and the safest
route to the spill
o The Fire Department Hazardous Materials (HazMat) team will clean up or
stabilize spills which are considered high hazard (fire, health, or reactivity
hazard). In the case of a small spill and low hazard situation, EHS will advise you
on what precautions and protective equipment to use
o If you have any doubt about whether a spill can be safely and effectively
cleaned up by staff in the lab, call RUPD at 540-831-5500 immediately
Secure
o Until emergency response personnel arrive: block off areas leading to the spill,
lock doors, post signs and warning tape, and alert others of the spill
o Post staff by commonly used entrances to the area to direct people to use other
routes
3.6.1 Chemical Spill Emergency Procedures
Evacuate
1. Remove People From The Area: As you leave an area involved in a chemical spill,
assist people exiting the area. Never enter a chemical spill area where you may place your
health in jeopardy β Call the RUPD at 540-831-5500 for assistance.
a. Evacuate personnel from the spill area and close doors
b. If safe to do so, shut off electrical equipment as you leave the area
c. Direct personnel to nearest fire exit. Do not use elevators
d. Attend to victims
e. Alert neighbors
Caution: Just as you are not to re-enter a burning building, DO NOT go back in to an area
where a chemical spill has occurred! In many documented cases, rescuers not wearing proper
protective equipment have been overcome by toxic or asphyxiating fumes trying to rescue other
victims and died as a result. Do not make this mistake!
2. First aid: Remove victims from spill area to fresh air, but do not endanger your own life
by entering areas with toxic gases a. Immediately remove contaminated clothing
b. Flush skin or eyes with running water for 15 minutes
c. Get medical attention for victims
Caution: Flush skin and/or eyes with running water for at least 15 minutes. (You may not feel
any immediate effects from chemical spills, but it is very important to wash quickly and
thoroughly because contact with many chemicals can cause severe tissue damage that is not
apparent until hours later.)
18
d. Chemical spills over large body areas:
i. Remove contaminated clothing while under shower
ii. Flush affected body area with water for at least 15 minutes
iii. Resume water wash if pain returns
iv. Wash off chemicals with mild detergent and water; do not use neutralizing
chemicals, unguents, creams, lotions or salves
v. Get immediate medical help
vi. Make sure medical personnel understand exactly what chemicals are
involved
e. Victims of Bromine spills
i. Flush with cold water; apply compress saturated with a dilute sodium
thiosulfate solution
ii. Get immediate medical help
f. Victims of Hydrogen Fluoride (HF) spills
i. Flush with cool water until any whitening of tissue disappears
ii. Swath injured area with soaking wet, iced cloths
iii. If calcium gluconate cream or salve is available, wash skin with running
water for five minutes, then cover area with cream
iv. Get immediate medical help
Confine
1. Close fire doors
2. Isolate the area
3. Establish exhaust ventilation
4. Vent fumes only to outside of the building
5. Open windows, if possible, without exposing yourself to more fumes
6. If vapor or gases are in a room which is not vented to the outside of the building, close
off the room
Report
1. Call RUPD at 540-831-5500 for all chemical spills that:
a. Involve injury requiring medical treatment
b. Involve fire or explosion hazards
c. Are potentially life threatening
d. Are larger than one liter or cover a large area
2. The type of information you will need to provide when you call RUPD consist of the
following:
a. State that this is an emergency
b. Give your name, telephone number, and location
c. Tell the location of the incident
d. Tell the time and type of incident
e. Give the name and quantity of material involved
f. Provide the extent of injuries, if any
g. Explain the possible hazards to human health or the environment
19
h. Warn emergency responders of any other hazards they may encounter, such as
large quantities of stored chemicals (particularly flammables, oxidizers, and air-
born toxic or irritant materials), radioactive materials, biohazards, mechanical
hazards, etc. Outline the safest route to approach the spill
Secure
Until emergency responders arrive on the scene, you and your staff will need to block off
entrances to the spill location and prevent people from entering the contaminated area.
1. Lock doors leading to the chemical spill (while keeping keys handy for emergency
personnel) and post signs on doors warning of the spill
2. Tape or rope off stairwells, corridors, and elevators leading to the spill and hang signs on
the tape
3. Post staff by commonly used entrances to the spill location, so they can warn people to
use other routes
Clean Up
Every laboratory or suite of laboratories (interconnected labs that do not require walking in a
hallway to get to) should have access to a fully-stocked spill kit to aid in the containment and
cleanup of chemical spills. Spill kits at the minimum should contain the following:
(1) 5-gallon plastic pail
(1) pair of neoprene gloves
(2) disposable plastic trash bags
(2) cable ties (for sealing trash bags)
(1) pair of latex booties
(1) Tyvek coverall, size XXXL
(10) universal absorbent pads
(1) pair of chemical splash goggles
Contact EHS at 540-831-7790 for assistance with spill kits.
The following are general guidelines for spill cleanup:
1. EHS and/or the Fire Department HazMat Team will clean up or stabilize spills which are
considered a high hazard (fire, health, or reactivity hazard).
2. You should clean up a low hazard spill for which you have proper training and proper
protective equipment. In general, small spills should be absorbed, neutralized, and
collected immediately. Consult the SDS for specific instructions on spill response. The
instructions below are general guidelines only and may need to be modified to safely
handle the spill.
a. Liquids should be covered with spill universal absorbent pads, vermiculite, or
equivalent absorbent to contain and absorb the material. DO NOT use a
combustible absorbent for cleaning up oxidizer spills! Absorb all liquid in the
20
pads or absorbent and put the absorbent into a heavy-walled plastic trash bag or
other suitable container and seal. Put the plastic bag or container in a second
plastic bag or the 5-gallon pail that is part of the spill kit and seal. Treat the
contents as a hazardous waste and follow the procedures outlined earlier in this
document.
b. Solids should be carefully pushed with absorbent pads or swept into a pile and
transferred to a plastic trash bag or other suitable container and sealed. Put the
plastic bag or container in a second plastic bag or the 5-gallon pail that is part of
the spill kit and seal. Treat the contents as a hazardous waste and follow the
procedures outlined earlier in this document.
c. Decontamination of the spill area with a mild soap solution or sodium bicarbonate
(for acid neutralization) may also be necessary. Questions, regarding procedures
can be directed to EHS at 540-831-7790.
If you have any doubt about whether a spill can be safely and effective cleaned up by staff in
the lab, call RUPD at 540-831-5500 immediately.
Management of Materials from Spill Cleanup: Materials that are generated as a result of spill
cleanup are considered to be hazardous waste if the original material when disposed of would be
hazardous waste. These materials must be pleace into appropriate sealed containers and must be
managed as any other hazardous waste.
3.6.2 General Emergency Procedures
An emergency condition is any SPILL, LEAK, FIRE, or other uncontrolled release that presents
a hazard to human health or the environment. Any person discovering an imminent or actual
emergency, which is not readily controllable with the training and equipment on hand MUST
CONTACT RUPD at 540-831-5500.
Emergency Procedures for a chemical spill are given in the previous section.
The following are general fire safety procedures:
Know where the βPull Boxesβ are
Know at least two (2) ways to get out of the building
DO NOT use the elevator
Close all doors behind you
ALWAYS exit the building when the alarm is ringing
Have a rally point or assembly area where all personnel in your lab will meet if you have
to leave the building for an emergency
Follow the R.A.C.E. procedure:
Remove anyone from danger
Alarm: Pull Fire Alarm Box or call RUPD at 540-831-5500
Confine: Close all doors
21
Extinguish or Evacuate
3.7 Training
Hazardous Waste Training (also known as RCRA Training) is required if you:
Decide what is a hazardous waste
Add hazardous waste into accumulation containers
Transport waste from accumulation points
Inspect hazardous waste storage areas
Respond to spill involving hazardous wastes
Training should be for new employees and refreshed annually thereafter.
EHS will provide RCRA Training upon request by a Department or School. The training meets
all USEPA and Virginia DEQ hazardous waste requirement and takes about 1.5 hours to
complete. Participants are required to provide their RU ID number at course registration.
4.0 Document Management
This guidebook shall be reviewed every two years, or as changes require.
5.0 Associated Documents
The following are a listing of associated documents relevant to this guidebook:
βSafety Policy,β Environmental Health and Safety, Radford University
40 Code of Federal Regulations Part 260 et seq.
9VAC20-60
22
APPENDIX A
TOXIC HAZARDOUS WASTES
23
TOXIC HAZARDOUS WASTES
8 HEAVY METALS 22 ORGANIC CHEMICALS
ARSENIC BENZENE
CADMIUM CARBON TETRACHLORIDE
LEAD CHLORDANE
SELENIUM CHLOROBENZENE
BARIUM CHLOROFORM
CHROMIUM O-CRESOL
MERCURY M-CRESOL
SILVER P-CRESOL
CRESOL
10 PESTICIDES 1,4-DICHLOROBENZENE
2,4-D 1,2-DICHLOROETHANE
ENDRIN 1,1-DICHLOROETHYLENE
HEPTACHLOR (& ITS EPOXIDE) 2,4-DINITROTOLUENE
HEXACHLOROBENZENE METHYL ETHYL KETONE
HEXACHLOROBUTADIENE NITROBENZENE
HEXACHLOROETHANE PENTACHLOROPHENOL
LINDANE PYRIDINE
METHOXYCHLOR TETRACHLOROETHYLENE
TOXAPHENE TRICHLOROETHYLENE
2,4,5-TP (SILVEX) 2,4,5-TRICHLOROPHENOL
2,4,6-TRICHLOROPHENOL
VINYL CHLORIDE
24
APPENDIX B
HAZARDOUS WASTE WEEKLY
INSPECTION SHEET
25 KEEP ON FILE IN THE INSPECTED LAB FOR 3 YEARS
If you have any questions, Contact EHS at 540-831-7790
Satellite Accumulation Area/Hazardous Waste Weekly Inspection Sheet D
ate
Con
tain
ers
Lab
eled
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Con
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ers
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ped
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ly s
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mp
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epa
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ary
con
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26
APPENDIX C
U & P LISTED HAZARDOUS WASTE
27
These wastes and their corresponding EPA Hazardous Waste Numbers are:
Hazardous waste No.
Chemical abstracts
No. Substance
P023 107β20β0 Acetaldehyde, chloro-
P002 591β08β2 Acetamide, N-(aminothioxomethyl)-
P057 640β19β7 Acetamide, 2-fluoro-
P058 62β74β8 Acetic acid, fluoro-, sodium salt
P002 591β08β2 1-Acetyl-2-thiourea
P003 107β02β8 Acrolein
P070 116β06β3 Aldicarb
P203 1646β88β4 Aldicarb sulfone.
P004 309β00β2 Aldrin
P005 107β18β6 Allyl alcohol
P006 20859β73β8 Aluminum phosphide (R,T)
P007 2763β96β4 5-(Aminomethyl)-3-isoxazolol
P008 504β24β5 4-Aminopyridine
P009 131β74β8 Ammonium picrate (R)
P119 7803β55β6 Ammonium vanadate
P099 506β61β6 Argentate(1-), bis(cyano-C)-, potassium
P010 7778β39β4 Arsenic acid H3AsO4
P012 1327β53β3 Arsenic oxide As2O3
P011 1303β28β2 Arsenic oxide As2O5
P011 1303β28β2 Arsenic pentoxide
P012 1327β53β3 Arsenic trioxide
P038 692β42β2 Arsine, diethyl-
P036 696β28β6 Arsonous dichloride, phenyl-
P054 151β56β4 Aziridine
28
P067 75β55β8 Aziridine, 2-methyl-
P013 542β62β1 Barium cyanide
P024 106β47β8 Benzenamine, 4-chloro-
P077 100β01β6 Benzenamine, 4-nitro-
P028 100β44β7 Benzene, (chloromethyl)-
P042 51β43β4 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]-, (R)-
P046 122β09β8 Benzeneethanamine, alpha,alpha-dimethyl-
P014 108β98β5 Benzenethiol
P127 1563β66β2 7-Benzofuranol, 2,3-dihydro-2,2-dimethyl-, methylcarbamate.
P188 57β64β7 Benzoic acid, 2-hydroxy-, compd. with (3aS-cis)-1,2,3,3a,8,8a-hexahydro-1,3a,8-trimethylpyrrolo[2,3-b]indol-5-yl methylcarbamate ester (1:1).
P001 181β81β2 2H-1-Benzopyran-2-one, 4-hydroxy-3-(3-oxo-1-phenylbutyl)-, & salts, when present at concentrations greater than 0.3%
P028 100β44β7 Benzyl chloride
P015 7440β41β7 Beryllium powder
P017 598β31β2 Bromoacetone
P018 357β57β3 Brucine
P045 39196β18β4 2-Butanone, 3,3-dimethyl-1-(methylthio)-, O-[(methylamino)carbonyl] oxime
P021 592β01β8 Calcium cyanide
P021 592β01β8 Calcium cyanide Ca(CN)2
P189 55285β14β8 Carbamic acid, [(dibutylamino)- thio]methyl-, 2,3-dihydro-2,2-dimethyl- 7-benzofuranyl ester.
P191 644β64β4 Carbamic acid, dimethyl-, 1-[(dimethyl-amino)carbonyl]- 5-methyl-1H- pyrazol-3-yl ester.
P192 119β38β0 Carbamic acid, dimethyl-, 3-methyl-1- (1-methylethyl)-1H- pyrazol-5-yl ester.
P190 1129β41β5 Carbamic acid, methyl-, 3-methylphenyl ester.
P127 1563β66β2 Carbofuran.
P022 75β15β0 Carbon disulfide
P095 75β44β5 Carbonic dichloride
29
P189 55285β14β8 Carbosulfan.
P023 107β20β0 Chloroacetaldehyde
P024 106β47β8 p-Chloroaniline
P026 5344β82β1 1-(o-Chlorophenyl)thiourea
P027 542β76β7 3-Chloropropionitrile
P029 544β92β3 Copper cyanide
P029 544β92β3 Copper cyanide Cu(CN)
P202 64β00β6 m-Cumenyl methylcarbamate.
P030 Cyanides (soluble cyanide salts), not otherwise specified
P031 460β19β5 Cyanogen
P033 506β77β4 Cyanogen chloride
P033 506β77β4 Cyanogen chloride (CN)Cl
P034 131β89β5 2-Cyclohexyl-4,6-dinitrophenol
P016 542β88β1 Dichloromethyl ether
P036 696β28β6 Dichlorophenylarsine
P037 60β57β1 Dieldrin
P038 692β42β2 Diethylarsine
P041 311β45β5 Diethyl-p-nitrophenyl phosphate
P040 297β97β2 O,O-Diethyl O-pyrazinyl phosphorothioate
P043 55β91β4 Diisopropylfluorophosphate (DFP)
P004 309β00β2 1,4,5,8-Dimethanonaphthalene, 1,2,3,4,10,10-hexa- chloro-1,4,4a,5,8,8a,-hexahydro-, (1alpha,4alpha,4abeta,5alpha,8alpha,8abeta)-
P060 465β73β6 1,4,5,8-Dimethanonaphthalene, 1,2,3,4,10,10-hexa- chloro-1,4,4a,5,8,8a-hexahydro-, (1alpha,4alpha,4abeta,5beta,8beta,8abeta)-
P037 60β57β1 2,7:3,6-Dimethanonaphth[2,3-b]oxirene, 3,4,5,6,9,9-hexachloro-1a,2,2a,3,6,6a,7,7a-octahydro-, (1aalpha,2beta,2aalpha,3beta,6beta,6aalpha,7beta, 7aalpha)-
P051 172β20β8 2,7:3,6-Dimethanonaphth [2,3-b]oxirene, 3,4,5,6,9,9-hexachloro-1a,2,2a,3,6,6a,7,7a-octahydro-, (1aalpha,2beta,2abeta,3alpha,6alpha,6abeta,7beta, 7aalpha)-, & metabolites
P044 60β51β5 Dimethoate
30
P046 122β09β8 alpha,alpha-Dimethylphenethylamine
P191 644β64β4 Dimetilan.
P047 1534β52β1 4,6-Dinitro-o-cresol, & salts
P048 51β28β5 2,4-Dinitrophenol
P020 88β85β7 Dinoseb
P085 152β16β9 Diphosphoramide, octamethyl-
P111 107β49β3 Diphosphoric acid, tetraethyl ester
P039 298β04β4 Disulfoton
P049 541β53β7 Dithiobiuret
P185 26419β73β8 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)- carbonyl]oxime.
P050 115β29β7 Endosulfan
P088 145β73β3 Endothall
P051 72β20β8 Endrin
P051 72β20β8 Endrin, & metabolites
P042 51β43β4 Epinephrine
P031 460β19β5 Ethanedinitrile
P194 23135β22β0 Ethanimidothioic acid, 2-(dimethylamino)-N-[[(methylamino) carbonyl]oxy]-2-oxo-, methyl ester.
P066 16752β77β5 Ethanimidothioic acid, N-[[(methylamino)carbonyl]oxy]-, methyl ester
P101 107β12β0 Ethyl cyanide
P054 151β56β4 Ethyleneimine
P097 52β85β7 Famphur
P056 7782β41β4 Fluorine
P057 640β19β7 Fluoroacetamide
P058 62β74β8 Fluoroacetic acid, sodium salt
P198 23422β53β9 Formetanate hydrochloride.
P197 17702β57β7 Formparanate.
P065 628β86β4 Fulminic acid, mercury(2+) salt (R,T)
P059 76β44β8 Heptachlor
31
P062 757β58β4 Hexaethyl tetraphosphate
P116 79β19β6 Hydrazinecarbothioamide
P068 60β34β4 Hydrazine, methyl-
P063 74β90β8 Hydrocyanic acid
P063 74β90β8 Hydrogen cyanide
P096 7803β51β2 Hydrogen phosphide
P060 465β73β6 Isodrin
P192 119β38β0 Isolan.
P202 64β00β6 3-Isopropylphenyl N-methylcarbamate.
P007 2763β96β4 3(2H)-Isoxazolone, 5-(aminomethyl)-
P196 15339β36β3 Manganese, bis(dimethylcarbamodithioato-S,Sβ²)-,
P196 15339β36β3 Manganese dimethyldithiocarbamate.
P092 62β38β4 Mercury, (acetato-O)phenyl-
P065 628β86β4 Mercury fulminate (R,T)
P082 62β75β9 Methanamine, N-methyl-N-nitroso-
P064 624β83β9 Methane, isocyanato-
P016 542β88β1 Methane, oxybis[chloro-
P112 509β14β8 Methane, tetranitro- (R)
P118 75β70β7 Methanethiol, trichloro-
P198 23422β53β9 Methanimidamide, N,N-dimethyl-Nβ²-[3-[[(methylamino)-carbonyl]oxy]phenyl]-, monohydrochloride.
P197 17702β57β7 Methanimidamide, N,N-dimethyl-Nβ²-[2-methyl-4-[[(methylamino)carbonyl]oxy]phenyl]-
P050 115β29β7 6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10- hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide
P059 76β44β8 4,7-Methano-1H-indene, 1,4,5,6,7,8,8-heptachloro- 3a,4,7,7a-tetrahydro-
P199 2032β65β7 Methiocarb.
P066 16752β77β5 Methomyl
P068 60β34β4 Methyl hydrazine
P064 624β83β9 Methyl isocyanate
32
P069 75β86β5 2-Methyllactonitrile
P071 298β00β0 Methyl parathion
P190 1129β41β5 Metolcarb.
P128 315β8β4 Mexacarbate.
P072 86β88β4 alpha-Naphthylthiourea
P073 13463β39β3 Nickel carbonyl
P073 13463β39β3 Nickel carbonyl Ni(CO)4, (T-4)-
P074 557β19β7 Nickel cyanide
P074 557β19β7 Nickel cyanide Ni(CN)2
P075 154β11β5 Nicotine, & salts
P076 10102β43β9 Nitric oxide
P077 100β01β6 p-Nitroaniline
P078 10102β44β0 Nitrogen dioxide
P076 10102β43β9 Nitrogen oxide NO
P078 10102β44β0 Nitrogen oxide NO2
P081 55β63β0 Nitroglycerine (R)
P082 62β75β9 N-Nitrosodimethylamine
P084 4549β40β0 N-Nitrosomethylvinylamine
P085 152β16β9 Octamethylpyrophosphoramide
P087 20816β12β0 Osmium oxide OsO4, (T-4)-
P087 20816β12β0 Osmium tetroxide
P088 145β73β3 7-Oxabicyclo[2.2.1]heptane-2,3-dicarboxylic acid
P194 23135β22β0 Oxamyl.
P089 56β38β2 Parathion
P034 131β89β5 Phenol, 2-cyclohexyl-4,6-dinitro-
P048 51β28β5 Phenol, 2,4-dinitro-
P047 1534β52β1 Phenol, 2-methyl-4,6-dinitro-, & salts
P020 88β85β7 Phenol, 2-(1-methylpropyl)-4,6-dinitro-
P009 131β74β8 Phenol, 2,4,6-trinitro-, ammonium salt (R)
P128 315β18β4 Phenol, 4-(dimethylamino)-3,5-dimethyl-, methylcarbamate (ester).
33
P199 2032β65β7 Phenol, (3,5-dimethyl-4-(methylthio)-, methylcarbamate
P202 64β00β6 Phenol, 3-(1-methylethyl)-, methyl carbamate.
P201 2631β37β0 Phenol, 3-methyl-5-(1-methylethyl)-, methyl carbamate.
P092 62β38β4 Phenylmercury acetate
P093 103β85β5 Phenylthiourea
P094 298β02β2 Phorate
P095 75β44β5 Phosgene
P096 7803β51β2 Phosphine
P041 311β45β5 Phosphoric acid, diethyl 4-nitrophenyl ester
P039 298β04β4 Phosphorodithioic acid, O,O-diethyl S-[2-(ethylthio)ethyl] ester
P094 298β02β2 Phosphorodithioic acid, O,O-diethyl S-[(ethylthio)methyl] ester
P044 60β51β5 Phosphorodithioic acid, O,O-dimethyl S-[2-(methylamino)-2-oxoethyl] ester
P043 55β91β4 Phosphorofluoridic acid, bis(1-methylethyl) ester
P089 56β38β2 Phosphorothioic acid, O,O-diethyl O-(4-nitrophenyl) ester
P040 297β97β2 Phosphorothioic acid, O,O-diethyl O-pyrazinyl ester
P097 52β85β7 Phosphorothioic acid, O-[4-[(dimethylamino)sulfonyl]phenyl] O,O-dimethyl ester
P071 298β00β0 Phosphorothioic acid, O,O,-dimethyl O-(4-nitrophenyl) ester
P204 57β47β6 Physostigmine.
P188 57β64β7 Physostigmine salicylate.
P110 78β00β2 Plumbane, tetraethyl-
P098 151β50β8 Potassium cyanide
P098 151β50β8 Potassium cyanide K(CN)
P099 506β61β6 Potassium silver cyanide
P201 2631β37β0 Promecarb
P070 116β06β3 Propanal, 2-methyl-2-(methylthio)-, O-[(methylamino)carbonyl]oxime
P203 1646β88β4 Propanal, 2-methyl-2-(methyl-sulfonyl)-, O-[(methylamino)carbonyl] oxime.
34
P101 107β12β0 Propanenitrile
P027 542β76β7 Propanenitrile, 3-chloro-
P069 75β86β5 Propanenitrile, 2-hydroxy-2-methyl-
P081 55β63β0 1,2,3-Propanetriol, trinitrate (R)
P017 598β31β2 2-Propanone, 1-bromo-
P102 107β19β7 Propargyl alcohol
P003 107β02β8 2-Propenal
P005 107β18β6 2-Propen-1-ol
P067 75β55β8 1,2-Propylenimine
P102 107β19β7 2-Propyn-1-ol
P008 504β24β5 4-Pyridinamine
P075 154β11β5 Pyridine, 3-(1-methyl-2-pyrrolidinyl)-, (S)-, & salts
P204 57β47β6 Pyrrolo[2,3-b]indol-5-ol, 1,2,3,3a,8,8a-hexahydro-1,3a,8-trimethyl-, methylcarbamate (ester), (3aS-cis)-.
P114 12039β52β0 Selenious acid, dithallium(1+) salt
P103 630β10β4 Selenourea
P104 506β64β9 Silver cyanide
P104 506β64β9 Silver cyanide Ag(CN)
P105 26628β22β8 Sodium azide
P106 143β33β9 Sodium cyanide
P106 143β33β9 Sodium cyanide Na(CN)
P108 157β24β9 Strychnidin-10-one, & salts
P018 357β57β3 Strychnidin-10-one, 2,3-dimethoxy-
P108 157β24β9 Strychnine, & salts
P115 7446β18β6 Sulfuric acid, dithallium(1+) salt
P109 3689β24β5 Tetraethyldithiopyrophosphate
P110 78β00β2 Tetraethyl lead
P111 107β49β3 Tetraethyl pyrophosphate
P112 509β14β8 Tetranitromethane (R)
P062 757β58β4 Tetraphosphoric acid, hexaethyl ester
35
P113 1314β32β5 Thallic oxide
P113 1314β32β5 Thallium oxide Tl2O3
P114 12039β52β0 Thallium(I) selenite
P115 7446β18β6 Thallium(I) sulfate
P109 3689β24β5 Thiodiphosphoric acid, tetraethyl ester
P045 39196β18β4 Thiofanox
P049 541β53β7 Thioimidodicarbonic diamide [(H2N)C(S)]2NH
P014 108β98β5 Thiophenol
P116 79β19β6 Thiosemicarbazide
P026 5344β82β1 Thiourea, (2-chlorophenyl)-
P072 86β88β4 Thiourea, 1-naphthalenyl-
P093 103β85β5 Thiourea, phenyl-
P185 26419β73β8 Tirpate.
P123 8001β35β2 Toxaphene
P118 75β70β7 Trichloromethanethiol
P119 7803β55β6 Vanadic acid, ammonium salt
P120 1314β62β1 Vanadium oxide V2O5
P120 1314β62β1 Vanadium pentoxide
P084 4549β40β0 Vinylamine, N-methyl-N-nitroso-
P001 181β81β2 Warfarin, & salts, when present at concentrations greater than 0.3%
P205 137β30β4 Zinc, bis(dimethylcarbamodithioato-S,Sβ²)-,
P121 557β21β1 Zinc cyanide
P121 557β21β1 Zinc cyanide Zn(CN)2
P122 1314β84β7 Zinc phosphide Zn3P2, when present at concentrations greater than 10% (R,T)
P205 137β30β4 Ziram.
P001 181β81β2 2H-1-Benzopyran-2-one, 4-hydroxy-3-(3-oxo-1-phenylbutyl)-, & salts, when present at concentrations greater than 0.3%
P001 181β81β2 Warfarin, & salts, when present at concentrations greater than 0.3%
P002 591β08β2 Acetamide, -(aminothioxomethyl)-
P002 591β08β2 1-Acetyl-2-thiourea
36
P003 107β02β8 Acrolein
P003 107β02β8 2-Propenal
P004 309β00β2 Aldrin
P004 309β00β2 1,4,5,8-Dimethanonaphthalene, 1,2,3,4,10,10-hexa-chloro-1,4,4a,5,8,8a,-hexahydro-, (1alpha,4alpha,4abeta,5alpha,8alpha,8abeta)-
P005 107β18β6 Allyl alcohol
P005 107β18β6 2-Propen-1-ol
P006 20859β73β8 Aluminum phosphide (R,T)
P007 2763β96β4 5-(Aminomethyl)-3-isoxazolol
P007 2763β96β4 3(2H)-Isoxazolone, 5-(aminomethyl)-
P008 504β24β5 4-Aminopyridine
P008 504β24β5 4-Pyridinamine
P009 131β74β8 Ammonium picrate (R)
P009 131β74β8 Phenol, 2,4,6-trinitro-, ammonium salt (R)
P010 7778β39β4 Arsenic acid H3AsO4
P011 1303β28β2 Arsenic oxide As2O5
P011 1303β28β2 Arsenic pentoxide
P012 1327β53β3 Arsenic oxide As2O3
P012 1327β53β3 Arsenic trioxide
P013 542β62β1 Barium cyanide
P014 108β98β5 Benzenethiol
P014 108β98β5 Thiophenol
P015 7440β41β7 Beryllium powder
P016 542β88β1 Dichloromethyl ether
P016 542β88β1 Methane, oxybis[chloro-
P017 598β31β2 Bromoacetone
P017 598β31β2 2-Propanone, 1-bromo-
P018 357β57β3 Brucine
P018 357β57β3 Strychnidin-10-one, 2,3-dimethoxy-
P020 88β85β7 Dinoseb
37
P020 88β85β7 Phenol, 2-(1-methylpropyl)-4,6-dinitro-
P021 592β01β8 Calcium cyanide
P021 592β01β8 Calcium cyanide Ca(CN)2
P022 75β15β0 Carbon disulfide
P023 107β20β0 Acetaldehyde, chloro-
P023 107β20β0 Chloroacetaldehyde
P024 106β47β8 Benzenamine, 4-chloro-
P024 106β47β8 p-Chloroaniline
P026 5344β82β1 1-(o-Chlorophenyl)thiourea
P026 5344β82β1 Thiourea, (2-chlorophenyl)-
P027 542β76β7 3-Chloropropionitrile
P027 542β76β7 Propanenitrile, 3-chloro-
P028 100β44β7 Benzene, (chloromethyl)-
P028 100β44β7 Benzyl chloride
P029 544β92β3 Copper cyanide
P029 544β92β3 Copper cyanide Cu(CN)
P030 Cyanides (soluble cyanide salts), not otherwise specified
P031 460β19β5 Cyanogen
P031 460β19β5 Ethanedinitrile
P033 506β77β4 Cyanogen chloride
P033 506β77β4 Cyanogen chloride (CN)Cl
P034 131β89β5 2-Cyclohexyl-4,6-dinitrophenol
P034 131β89β5 Phenol, 2-cyclohexyl-4,6-dinitro-
P036 696β28β6 Arsonous dichloride, phenyl-
P036 696β28β6 Dichlorophenylarsine
P037 60β57β1 Dieldrin
P037 60β57β1 2,7:3,6-Dimethanonaphth[2,3-b]oxirene, 3,4,5,6,9,9-hexachloro-1a,2,2a,3,6,6a,7,7a-octahydro-, (1aalpha,2beta,2aalpha,3beta,6beta,6aalpha,7beta, 7aalpha)-
P038 692β42β2 Arsine, diethyl-
P038 692β42β2 Diethylarsine
38
P039 298β04β4 Disulfoton
P039 298β04β4 Phosphorodithioic acid, O,O-diethyl S-[2-(ethylthio)ethyl] ester
P040 297β97β2 O,O-Diethyl O-pyrazinyl phosphorothioate
P040 297β97β2 Phosphorothioic acid, O,O-diethyl O-pyrazinyl ester
P041 311β45β5 Diethyl-p-nitrophenyl phosphate
P041 311β45β5 Phosphoric acid, diethyl 4-nitrophenyl ester
P042 51β43β4 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]-, (R)-
P042 51β43β4 Epinephrine
P043 55β91β4 Diisopropylfluorophosphate (DFP)
P043 55β91β4 Phosphorofluoridic acid, bis(1-methylethyl) ester
P044 60β51β5 Dimethoate
P044 60β51β5 Phosphorodithioic acid, O,O-dimethyl S-[2-(methyl amino)-2-oxoethyl] ester
P045 39196β18β4 2-Butanone, 3,3-dimethyl-1-(methylthio)-, O-[(methylamino)carbonyl] oxime
P045 39196β18β4 Thiofanox
P046 122β09β8 Benzeneethanamine, alpha,alpha-dimethyl-
P046 122β09β8 alpha,alpha-Dimethylphenethylamine
P047 1534β52β1 4,6-Dinitro-o-cresol, & salts
P047 1534β52β1 Phenol, 2-methyl-4,6-dinitro-, & salts
P048 51β28β5 2,4-Dinitrophenol
P048 51β28β5 Phenol, 2,4-dinitro-
P049 541β53β7 Dithiobiuret
P049 541β53β7 Thioimidodicarbonic diamide [(H2N)C(S)]2NH
P050 115β29β7 Endosulfan
P050 115β29β7 6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10-hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide
P051 172β20β8 2,7:3,6-Dimethanonaphth [2,3-b]oxirene, 3,4,5,6,9,9-hexachloro-1a,2,2a,3,6,6a,7,7a-octahydro-, (1aalpha,2beta,2abeta,3alpha,6alpha,6abeta,7beta, 7aalpha)-, & metabolites
P051 72β20β8 Endrin
39
P051 72β20β8 Endrin, & metabolites
P054 151β56β4 Aziridine
P054 151β56β4 Ethyleneimine
P056 7782β41β4 Fluorine
P057 640β19β7 Acetamide, 2-fluoro-
P057 640β19β7 Fluoroacetamide
P058 62β74β8 Acetic acid, fluoro-, sodium salt
P058 62β74β8 Fluoroacetic acid, sodium salt
P059 76β44β8 Heptachlor
P059 76β44β8 4,7-Methano-1H-indene, 1,4,5,6,7,8,8-heptachloro-3a,4,7,7a-tetrahydro-
P060 465β73β6 1,4,5,8-Dimethanonaphthalene, 1,2,3,4,10,10-hexa-chloro-1,4,4a,5,8,8a-hexahydro-, (1alpha,4alpha,4abeta,5beta,8beta,8abeta)-
P060 465β73β6 Isodrin
P062 757β58β4 Hexaethyl tetraphosphate
P062 757β58β4 Tetraphosphoric acid, hexaethyl ester
P063 74β90β8 Hydrocyanic acid
P063 74β90β8 Hydrogen cyanide
P064 624β83β9 Methane, isocyanato-
P064 624β83β9 Methyl isocyanate
P065 628β86β4 Fulminic acid, mercury(2+) salt (R,T)
P065 628β86β4 Mercury fulminate (R,T)
P066 16752β77β5 Ethanimidothioic acid, N-[[(methylamino)carbonyl]oxy]-, methyl ester
P066 16752β77β5 Methomyl
P067 75β55β8 Aziridine, 2-methyl-
P067 75β55β8 1,2-Propylenimine
P068 60β34β4 Hydrazine, methyl-
P068 60β34β4 Methyl hydrazine
P069 75β86β5 2-Methyllactonitrile
P069 75β86β5 Propanenitrile, 2-hydroxy-2-methyl-
40
P070 116β06β3 Aldicarb
P070 116β06β3 Propanal, 2-methyl-2-(methylthio)-, O-[(methylamino)carbonyl]oxime
P071 298β00β0 Methyl parathion
P071 298β00β0 Phosphorothioic acid, O,O,-dimethyl O-(4-nitrophenyl) ester
P072 86β88β4 alpha-Naphthylthiourea
P072 86β88β4 Thiourea, 1-naphthalenyl-
P073 13463β39β3 Nickel carbonyl
P073 13463β39β3 Nickel carbonyl Ni(CO)4, (T-4)-
P074 557β19β7 Nickel cyanide
P074 557β19β7 Nickel cyanide Ni(CN)2
P075 154β11β5 Nicotine, & salts
P075 154β11β5 Pyridine, 3-(1-methyl-2-pyrrolidinyl)-, (S)-, & salts
P076 10102β43β9 Nitric oxide
P076 10102β43β9 Nitrogen oxide NO
P077 100β01β6 Benzenamine, 4-nitro-
P077 100β01β6 p-Nitroaniline
P078 10102β44β0 Nitrogen dioxide
P078 10102β44β0 Nitrogen oxide NO2
P081 55β63β0 Nitroglycerine (R)
P081 55β63β0 1,2,3-Propanetriol, trinitrate (R)
P082 62β75β9 Methanamine, -methyl-N-nitroso-
P082 62β75β9 N-Nitrosodimethylamine
P084 4549β40β0 N-Nitrosomethylvinylamine
P084 4549β40β0 Vinylamine, -methyl-N-nitroso-
P085 152β16β9 Diphosphoramide, octamethyl-
P085 152β16β9 Octamethylpyrophosphoramide
P087 20816β12β0 Osmium oxide OsO4, (T-4)-
P087 20816β12β0 Osmium tetroxide
P088 145β73β3 Endothall
41
P088 145β73β3 7-Oxabicyclo[2.2.1]heptane-2,3-dicarboxylic acid
P089 56β38β2 Parathion
P089 56β38β2 Phosphorothioic acid, O,O-diethyl O-(4-nitrophenyl) ester
P092 62β38β4 Mercury, (acetato-O)phenyl-
P092 62β38β4 Phenylmercury acetate
P093 103β85β5 Phenylthiourea
P093 103β85β5 Thiourea, phenyl-
P094 298β02β2 Phorate
P094 298β02β2 Phosphorodithioic acid, O,O-diethyl S-[(ethylthio)methyl] ester
P095 75β44β5 Carbonic dichloride
P095 75β44β5 Phosgene
P096 7803β51β2 Hydrogen phosphide
P096 7803β51β2 Phosphine
P097 52β85β7 Famphur
P097 52β85β7 Phosphorothioic acid, O-[4-[(dimethylamino)sulfonyl]phenyl] O,O-dimethyl ester
P098 151β50β8 Potassium cyanide
P098 151β50β8 Potassium cyanide K(CN)
P099 506β61β6 Argentate(1-), bis(cyano-C)-, potassium
P099 506β61β6 Potassium silver cyanide
P101 107β12β0 Ethyl cyanide
P101 107β12β0 Propanenitrile
P102 107β19β7 Propargyl alcohol
P102 107β19β7 2-Propyn-1-ol
P103 630β10β4 Selenourea
P104 506β64β9 Silver cyanide
P104 506β64β9 Silver cyanide Ag(CN)
P105 26628β22β8 Sodium azide
P106 143β33β9 Sodium cyanide
P106 143β33β9 Sodium cyanide Na(CN)
42
P108 1157β24β9 Strychnidin-10-one, & salts
P108 1157β24β9 Strychnine, & salts
P109 3689β24β5 Tetraethyldithiopyrophosphate
P109 3689β24β5 Thiodiphosphoric acid, tetraethyl ester
P110 78β00β2 Plumbane, tetraethyl-
P110 78β00β2 Tetraethyl lead
P111 107β49β3 Diphosphoric acid, tetraethyl ester
P111 107β49β3 Tetraethyl pyrophosphate
P112 509β14β8 Methane, tetranitro-(R)
P112 509β14β8 Tetranitromethane (R)
P113 1314β32β5 Thallic oxide
P113 1314β32β5 Thallium oxide Tl2O3
P114 12039β52β0 Selenious acid, dithallium(1+) salt
P114 12039β52β0 Tetraethyldithiopyrophosphate
P115 7446β18β6 Thiodiphosphoric acid, tetraethyl ester
P115 7446β18β6 Plumbane, tetraethyl-
P116 79β19β6 Tetraethyl lead
P116 79β19β6 Thiosemicarbazide
P118 75β70β7 Methanethiol, trichloro-
P118 75β70β7 Trichloromethanethiol
P119 7803β55β6 Ammonium vanadate
P119 7803β55β6 Vanadic acid, ammonium salt
P120 1314β62β1 Vanadium oxide V2O5
P120 1314β62β1 Vanadium pentoxide
P121 557β21β1 Zinc cyanide
P121 557β21β1 Zinc cyanide Zn(CN)2
P122 1314β84β7 Zinc phosphide Zn3P2, when present at concentrations greater than 10% (R,T)
P123 8001β35β2 Toxaphene
P127 1563β66β2 7-Benzofuranol, 2,3-dihydro-2,2-dimethyl-, methylcarbamate.
43
P127 1563β66β2 Carbofuran
P128 315β8β4 Mexacarbate
P128 315β18β4 Phenol, 4-(dimethylamino)-3,5-dimethyl-, methylcarbamate (ester)
P185 26419β73β8 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O-[(methylamino)-carbonyl]oxime.
P185 26419β73β8 Tirpate
P188 57β64β7 Benzoic acid, 2-hydroxy-, compd. with (3aS-cis)-1,2,3,3a,8,8a-hexahydro-1,3a,8-trimethylpyrrolo[2,3-b]indol-5-yl methylcarbamate ester (1:1)
P188 57β64β7 Physostigmine salicylate
P189 55285β14β8 Carbamic acid, [(dibutylamino)-thio]methyl-, 2,3-dihydro-2,2-dimethyl-7-benzofuranyl ester
P189 55285β14β8 Carbosulfan
P190 1129β41β5 Carbamic acid, methyl-, 3-methylphenyl ester
P190 1129β41β5 Metolcarb
P191 644β64β4 Carbamic acid, dimethyl-, 1-[(dimethyl-amino)carbonyl]-5-methyl-1H-pyrazol-3-yl ester
P191 644β64β4 Dimetilan
P192 119β38β0 Carbamic acid, dimethyl-, 3-methyl-1-(1-methylethyl)-1H-pyrazol-5-yl ester
P192 119β38β0 Isolan
P194 23135β22β0 Ethanimidthioic acid, 2-(dimethylamino)-N-[[(methylamino) carbonyl]oxy]-2-oxo-, methyl ester
P194 23135β22β0 Oxamyl
P196 15339β36β3 Manganese, bis(dimethylcarbamodithioato-S,S')-,
P196 15339β36β3 Manganese dimethyldithiocarbamate
P197 17702β57β7 Formparanate
P197 17702β57β7 Methanimidamide, N,N-dimethyl-N'-[2-methyl-4-[[(methylamino)carbonyl]oxy]phenyl]-
P198 23422β53β9 Formetanate hydrochloride
P198 23422β53β9 Methanimidamide, N,N-dimethyl-N'-[3-[[(methylamino)-carbonyl]oxy]phenyl]-monohydrochloride
P199 2032β65β7 Methiocarb
44
P199 2032β65β7 Phenol, (3,5-dimethyl-4-(methylthio)-, methylcarbamate
P201 2631β37β0 Phenol, 3-methyl-5-(1-methylethyl)-, methyl carbamate
P201 2631β37β0 Promecarb
P202 64β00β6 m-Cumenyl methylcarbamate
P202 64β00β6 3-Isopropylphenyl N-methylcarbamate
P202 64β00β6 Phenol, 3-(1-methylethyl)-, methyl carbamate
P203 1646β88β4 Aldicarb sulfone
P203 1646β88β4 Propanal, 2-methyl-2-(methyl-sulfonyl)-, O-[(methylamino)carbonyl] oxime
P204 57β47β6 Physostigmine
P204 57β47β6 Pyrrolo[2,3-b]indol-5-ol, 1,2,3,3a,8,8a-hexahydro-1,3a,8-trimethyl-, methylcarbamate (ester), (3aS-cis)-
P205 137β30β4 Zinc, bis(dimethylcarbamodithioato-S,S')-,
P205 137β30β4 Ziram
1CAS Number given for parent compound only.
(f) The commercial chemical products, manufacturing chemical intermediates, or off-specification commercial chemical products referred to in paragraphs (a) through (d) of this section, are identified as toxic wastes (T), unless otherwise designated and are subject to the small quantity generator exclusion defined in Β§ 261.5 (a) and (g).
[ Comment: For the convenience of the regulated community, the primary hazardous properties of these materials have been indicated by the letters T (Toxicity), R (Reactivity), I (Ignitability) and C (Corrosivity). Absence of a letter indicates that the compound is only listed for toxicity. Wastes are first listed in alphabetical order by substance and then listed again in numerical order by Hazardous Waste Number.]
These wastes and their corresponding EPA Hazardous Waste Numbers are:
Hazardous waste No.
Chemical abstracts
No. Substance
U394 30558β43β1
A2213.
U001 75β07β0 Acetaldehyde (I)
U034 75β87β6 Acetaldehyde, trichloro-
45
U187 62β44β2 Acetamide, N-(4-ethoxyphenyl)-
U005 53β96β3 Acetamide, N-9H-fluoren-2-yl-
U240 194β75β7 Acetic acid, (2,4-dichlorophenoxy)-, salts & esters
U112 141β78β6 Acetic acid ethyl ester (I)
U144 301β04β2 Acetic acid, lead(2+) salt
U214 563β68β8 Acetic acid, thallium(1+) salt
see F027 93β76β5 Acetic acid, (2,4,5-trichlorophenoxy)-
U002 67β64β1 Acetone (I)
U003 75β05β8 Acetonitrile (I,T)
U004 98β86β2 Acetophenone
U005 53β96β3 2-Acetylaminofluorene
U006 75β36β5 Acetyl chloride (C,R,T)
U007 79β06β1 Acrylamide
U008 79β10β7 Acrylic acid (I)
U009 107β13β1 Acrylonitrile
U011 61β82β5 Amitrole
U012 62β53β3 Aniline (I,T)
U136 75β60β5 Arsinic acid, dimethyl-
U014 492β80β8 Auramine
U015 115β02β6 Azaserine
U010 50β07β7 Azirino[2β²,3β²:3,4]pyrrolo[1,2-a]indole-4,7-dione, 6-amino-8-[[(aminocarbonyl)oxy]methyl]-1,1a,2,8,8a,8b-hexahydro-8a-methoxy-5-methyl-, [1aS-(1aalpha, 8beta,8aalpha,8balpha)]-
U280 101β27β9 Barban.
U278 22781β23β3
Bendiocarb.
U364 22961β Bendiocarb phenol.
46
82β6
U271 17804β35β2
Benomyl.
U157 56β49β5 Benz[j]aceanthrylene, 1,2-dihydro-3-methyl-
U016 225β51β4 Benz[c]acridine
U017 98β87β3 Benzal chloride
U192 23950β58β5
Benzamide, 3,5-dichloro-N-(1,1-dimethyl-2-propynyl)-
U018 56β55β3 Benz[a]anthracene
U094 57β97β6 Benz[a]anthracene, 7,12-dimethyl-
U012 62β53β3 Benzenamine (I,T)
U014 492β80β8 Benzenamine, 4,4β²-carbonimidoylbis[N,N-dimethyl-
U049 3165β93β3
Benzenamine, 4-chloro-2-methyl-, hydrochloride
U093 60β11β7 Benzenamine, N,N-dimethyl-4-(phenylazo)-
U328 95β53β4 Benzenamine, 2-methyl-
U353 106β49β0 Benzenamine, 4-methyl-
U158 101β14β4 Benzenamine, 4,4β²-methylenebis[2-chloro-
U222 636β21β5 Benzenamine, 2-methyl-, hydrochloride
U181 99β55β8 Benzenamine, 2-methyl-5-nitro-
U019 71β43β2 Benzene (I,T)
U038 510β15β6 Benzeneacetic acid, 4-chloro-alpha-(4-chlorophenyl)-alpha-hydroxy-, ethyl ester
U030 101β55β3 Benzene, 1-bromo-4-phenoxy-
U035 305β03β3 Benzenebutanoic acid, 4-[bis(2-chloroethyl)amino]-
U037 108β90β7 Benzene, chloro-
U221 25376β45β8
Benzenediamine, ar-methyl-
U028 117β81β7 1,2-Benzenedicarboxylic acid, bis(2-
47
ethylhexyl) ester
U069 84β74β2 1,2-Benzenedicarboxylic acid, dibutyl ester
U088 84β66β2 1,2-Benzenedicarboxylic acid, diethyl ester
U102 131β11β3 1,2-Benzenedicarboxylic acid, dimethyl ester
U107 117β84β0 1,2-Benzenedicarboxylic acid, dioctyl ester
U070 95β50β1 Benzene, 1,2-dichloro-
U071 541β73β1 Benzene, 1,3-dichloro-
U072 106β46β7 Benzene, 1,4-dichloro-
U060 72β54β8 Benzene, 1,1β²-(2,2-dichloroethylidene)bis[4-chloro-
U017 98β87β3 Benzene, (dichloromethyl)-
U223 26471β62β5
Benzene, 1,3-diisocyanatomethyl- (R,T)
U239 1330β20β7
Benzene, dimethyl- (I,T)
U201 108β46β3 1,3-Benzenediol
U127 118β74β1 Benzene, hexachloro-
U056 110β82β7 Benzene, hexahydro- (I)
U220 108β88β3 Benzene, methyl-
U105 121β14β2 Benzene, 1-methyl-2,4-dinitro-
U106 606β20β2 Benzene, 2-methyl-1,3-dinitro-
U055 98β82β8 Benzene, (1-methylethyl)- (I)
U169 98β95β3 Benzene, nitro-
U183 608β93β5 Benzene, pentachloro-
U185 82β68β8 Benzene, pentachloronitro-
U020 98β09β9 Benzenesulfonic acid chloride (C,R)
U020 98β09β9 Benzenesulfonyl chloride (C,R)
U207 95β94β3 Benzene, 1,2,4,5-tetrachloro-
U061 50β29β3 Benzene, 1,1β²-(2,2,2-
48
trichloroethylidene)bis[4-chloro-
U247 72β43β5 Benzene, 1,1β²-(2,2,2-trichloroethylidene)bis[4- methoxy-
U023 98β07β7 Benzene, (trichloromethyl)-
U234 99β35β4 Benzene, 1,3,5-trinitro-
U021 92β87β5 Benzidine
U202 181β07β2 1,2-Benzisothiazol-3(2H)-one, 1,1-dioxide, & salts
U278 22781β23β3
1,3-Benzodioxol-4-ol, 2,2-dimethyl-, methyl carbamate.
U364 22961β82β6
1,3-Benzodioxol-4-ol, 2,2-dimethyl-,
U203 94β59β7 1,3-Benzodioxole, 5-(2-propenyl)-
U141 120β58β1 1,3-Benzodioxole, 5-(1-propenyl)-
U367 1563β38β8
7-Benzofuranol, 2,3-dihydro-2,2-dimethyl-
U090 94β58β6 1,3-Benzodioxole, 5-propyl-
U064 189β55β9 Benzo[rst]pentaphene
U248 181β81β2 2H-1-Benzopyran-2-one, 4-hydroxy-3-(3-oxo-1-phenyl-butyl)-, & salts, when present at concentrations of 0.3% or less
U022 50β32β8 Benzo[a]pyrene
U197 106β51β4 p-Benzoquinone
U023 98β07β7 Benzotrichloride (C,R,T)
U085 1464β53β5
2,2β²-Bioxirane
U021 92β87β5 [1,1β²-Biphenyl]-4,4β²-diamine
U073 91β94β1 [1,1β²-Biphenyl]-4,4β²-diamine, 3,3β²-dichloro-
U091 119β90β4 [1,1β²-Biphenyl]-4,4β²-diamine, 3,3β²-dimethoxy-
U095 119β93β7 [1,1β²-Biphenyl]-4,4β²-diamine, 3,3β²-dimethyl-
49
U225 75β25β2 Bromoform
U030 101β55β3 4-Bromophenyl phenyl ether
U128 87β68β3 1,3-Butadiene, 1,1,2,3,4,4-hexachloro-
U172 924β16β3 1-Butanamine, N-butyl-N-nitroso-
U031 71β36β3 1-Butanol (I)
U159 78β93β3 2-Butanone (I,T)
U160 1338β23β4
2-Butanone, peroxide (R,T)
U053 4170β30β3
2-Butenal
U074 764β41β0 2-Butene, 1,4-dichloro- (I,T)
U143 303β34β4 2-Butenoic acid, 2-methyl-, 7-[[2,3-dihydroxy- 2-(1-methoxyethyl)-3-methyl-1-oxobutoxy]methyl]- 2,3,5,7a-tetrahydro-1H-pyrrolizin-1-yl ester, [1S-[1alpha(Z),7(2S*,3R*),7aalpha]]-
U031 71β36β3 n-Butyl alcohol (I)
U136 75β60β5 Cacodylic acid
U032 13765β19β0
Calcium chromate
U372 10605β21β7
Carbamic acid, 1H-benzimidazol-2-yl, methyl ester.
U271 17804β35β2
Carbamic acid, [1-[(butylamino)carbonyl]-1H-benzimidazol-2-yl]-, methyl ester.
U280 101β27β9 Carbamic acid, (3-chlorophenyl)-, 4-chloro-2-butynyl ester.
U238 51β79β6 Carbamic acid, ethyl ester
U178 615β53β2 Carbamic acid, methylnitroso-, ethyl ester
U373 122β42β9 Carbamic acid, phenyl-, 1-methylethyl ester.
U409 23564β05β8
Carbamic acid, [1,2-phenylenebis (iminocarbonothioyl)]bis-, dimethyl ester.
50
U097 79β44β7 Carbamic chloride, dimethyl-
U389 2303β17β5
Carbamothioic acid, bis(1-methylethyl)-, S-(2,3,3-trichloro-2-propenyl) ester.
U387 52888β80β9
Carbamothioic acid, dipropyl-, S-(phenylmethyl) ester.
U114 1111β54β6
Carbamodithioic acid, 1,2-ethanediylbis-, salts & esters
U062 2303β16β4
Carbamothioic acid, bis(1-methylethyl)-, S-(2,3-dichloro-2-propenyl) ester
U279 63β25β2 Carbaryl.
U372 10605β21β7
Carbendazim.
U367 1563β38β8
Carbofuran phenol.
U215 6533β73β9
Carbonic acid, dithallium(1+) salt
U033 353β50β4 Carbonic difluoride
U156 79β22β1 Carbonochloridic acid, methyl ester (I,T)
U033 353β50β4 Carbon oxyfluoride (R,T)
U211 56β23β5 Carbon tetrachloride
U034 75β87β6 Chloral
U035 305β03β3 Chlorambucil
U036 57β74β9 Chlordane, alpha & gamma isomers
U026 494β03β1 Chlornaphazin
U037 108β90β7 Chlorobenzene
U038 510β15β6 Chlorobenzilate
U039 59β50β7 p-Chloro-m-cresol
U042 110β75β8 2-Chloroethyl vinyl ether
U044 67β66β3 Chloroform
U046 107β30β2 Chloromethyl methyl ether
U047 91β58β7 beta-Chloronaphthalene
51
U048 95β57β8 o-Chlorophenol
U049 3165β93β3
4-Chloro-o-toluidine, hydrochloride
U032 13765β19β0
Chromic acid H2CrO4, calcium salt
U050 218β01β9 Chrysene
U051 Creosote
U052 1319β77β3
Cresol (Cresylic acid)
U053 4170β30β3
Crotonaldehyde
U055 98β82β8 Cumene (I)
U246 506β68β3 Cyanogen bromide (CN)Br
U197 106β51β4 2,5-Cyclohexadiene-1,4-dione
U056 110β82β7 Cyclohexane (I)
U129 58β89β9 Cyclohexane, 1,2,3,4,5,6-hexachloro-, (1alpha,2alpha,3beta,4alpha,5alpha,6beta)-
U057 108β94β1 Cyclohexanone (I)
U130 77β47β4 1,3-Cyclopentadiene, 1,2,3,4,5,5-hexachloro-
U058 50β18β0 Cyclophosphamide
U240 194β75β7 2,4-D, salts & esters
U059 20830β81β3
Daunomycin
U060 72β54β8 DDD
U061 50β29β3 DDT
U062 2303β16β4
Diallate
U063 53β70β3 Dibenz[a,h]anthracene
U064 189β55β9 Dibenzo[a,i]pyrene
U066 96β12β8 1,2-Dibromo-3-chloropropane
52
U069 84β74β2 Dibutyl phthalate
U070 95β50β1 o-Dichlorobenzene
U071 541β73β1 m-Dichlorobenzene
U072 106β46β7 p-Dichlorobenzene
U073 91β94β1 3,3β²-Dichlorobenzidine
U074 764β41β0 1,4-Dichloro-2-butene (I,T)
U075 75β71β8 Dichlorodifluoromethane
U078 75β35β4 1,1-Dichloroethylene
U079 156β60β5 1,2-Dichloroethylene
U025 111β44β4 Dichloroethyl ether
U027 108β60β1 Dichloroisopropyl ether
U024 111β91β1 Dichloromethoxy ethane
U081 120β83β2 2,4-Dichlorophenol
U082 87β65β0 2,6-Dichlorophenol
U084 542β75β6 1,3-Dichloropropene
U085 1464β53β5
1,2:3,4-Diepoxybutane (I,T)
U108 123β91β1 1,4-Diethyleneoxide
U028 117β81β7 Diethylhexyl phthalate
U395 5952β26β1
Diethylene glycol, dicarbamate.
U086 1615β80β1
N,Nβ²-Diethylhydrazine
U087 3288β58β2
O,O-Diethyl S-methyl dithiophosphate
U088 84β66β2 Diethyl phthalate
U089 56β53β1 Diethylstilbesterol
U090 94β58β6 Dihydrosafrole
U091 119β90β4 3,3β²-Dimethoxybenzidine
53
U092 124β40β3 Dimethylamine (I)
U093 60β11β7 p-Dimethylaminoazobenzene
U094 57β97β6 7,12-Dimethylbenz[a]anthracene
U095 119β93β7 3,3β²-Dimethylbenzidine
U096 80β15β9 alpha,alpha-Dimethylbenzylhydroperoxide (R)
U097 79β44β7 Dimethylcarbamoyl chloride
U098 57β14β7 1,1-Dimethylhydrazine
U099 540β73β8 1,2-Dimethylhydrazine
U101 105β67β9 2,4-Dimethylphenol
U102 131β11β3 Dimethyl phthalate
U103 77β78β1 Dimethyl sulfate
U105 121β14β2 2,4-Dinitrotoluene
U106 606β20β2 2,6-Dinitrotoluene
U107 117β84β0 Di-n-octyl phthalate
U108 123β91β1 1,4-Dioxane
U109 122β66β7 1,2-Diphenylhydrazine
U110 142β84β7 Dipropylamine (I)
U111 621β64β7 Di-n-propylnitrosamine
U041 106β89β8 Epichlorohydrin
U001 75β07β0 Ethanal (I)
U404 121β44β8 Ethanamine, N,N-diethyl-
U174 55β18β5 Ethanamine, N-ethyl-N-nitroso-
U155 91β80β5 1,2-Ethanediamine, N,N-dimethyl-Nβ²-2-pyridinyl-Nβ²-(2-thienylmethyl)-
U067 106β93β4 Ethane, 1,2-dibromo-
U076 75β34β3 Ethane, 1,1-dichloro-
U077 107β06β2 Ethane, 1,2-dichloro-
U131 67β72β1 Ethane, hexachloro-
54
U024 111β91β1 Ethane, 1,1β²-[methylenebis(oxy)]bis[2-chloro-
U117 60β29β7 Ethane, 1,1β²-oxybis-(I)
U025 111β44β4 Ethane, 1,1β²-oxybis[2-chloro-
U184 76β01β7 Ethane, pentachloro-
U208 630β20β6 Ethane, 1,1,1,2-tetrachloro-
U209 79β34β5 Ethane, 1,1,2,2-tetrachloro-
U218 62β55β5 Ethanethioamide
U226 71β55β6 Ethane, 1,1,1-trichloro-
U227 79β00β5 Ethane, 1,1,2-trichloro-
U410 59669β26β0
Ethanimidothioic acid, N,Nβ²- [thiobis[(methylimino)carbonyloxy]]bis-, dimethyl ester
U394 30558β43β1
Ethanimidothioic acid, 2-(dimethylamino)-N-hydroxy-2-oxo-, methyl ester.
U359 110β80β5 Ethanol, 2-ethoxy-
U173 1116β54β7
Ethanol, 2,2β²-(nitrosoimino)bis-
U395 5952β26β1
Ethanol, 2,2β²-oxybis-, dicarbamate.
U004 98β86β2 Ethanone, 1-phenyl-
U043 75β01β4 Ethene, chloro-
U042 110β75β8 Ethene, (2-chloroethoxy)-
U078 75β35β4 Ethene, 1,1-dichloro-
U079 156β60β5 Ethene, 1,2-dichloro-, (E)-
U210 127β18β4 Ethene, tetrachloro-
U228 79β01β6 Ethene, trichloro-
U112 141β78β6 Ethyl acetate (I)
U113 140β88β5 Ethyl acrylate (I)
U238 51β79β6 Ethyl carbamate (urethane)
55
U117 60β29β7 Ethyl ether (I)
U114 1111β54β6
Ethylenebisdithiocarbamic acid, salts & esters
U067 106β93β4 Ethylene dibromide
U077 107β06β2 Ethylene dichloride
U359 110β80β5 Ethylene glycol monoethyl ether
U115 75β21β8 Ethylene oxide (I,T)
U116 96β45β7 Ethylenethiourea
U076 75β34β3 Ethylidene dichloride
U118 97β63β2 Ethyl methacrylate
U119 62β50β0 Ethyl methanesulfonate
U120 206β44β0 Fluoranthene
U122 50β00β0 Formaldehyde
U123 64β18β6 Formic acid (C,T)
U124 110β00β9 Furan (I)
U125 98β01β1 2-Furancarboxaldehyde (I)
U147 108β31β6 2,5-Furandione
U213 109β99β9 Furan, tetrahydro-(I)
U125 98β01β1 Furfural (I)
U124 110β00β9 Furfuran (I)
U206 18883β66β4
Glucopyranose, 2-deoxy-2-(3-methyl-3-nitrosoureido)-, D-
U206 18883β66β4
D-Glucose, 2-deoxy-2-[[(methylnitrosoamino)- carbonyl]amino]-
U126 765β34β4 Glycidylaldehyde
U163 70β25β7 Guanidine, N-methyl-Nβ²-nitro-N-nitroso-
U127 118β74β1 Hexachlorobenzene
U128 87β68β3 Hexachlorobutadiene
56
U130 77β47β4 Hexachlorocyclopentadiene
U131 67β72β1 Hexachloroethane
U132 70β30β4 Hexachlorophene
U243 1888β71β7
Hexachloropropene
U133 302β01β2 Hydrazine (R,T)
U086 1615β80β1
Hydrazine, 1,2-diethyl-
U098 57β14β7 Hydrazine, 1,1-dimethyl-
U099 540β73β8 Hydrazine, 1,2-dimethyl-
U109 122β66β7 Hydrazine, 1,2-diphenyl-
U134 7664β39β3
Hydrofluoric acid (C,T)
U134 7664β39β3
Hydrogen fluoride (C,T)
U135 7783β06β4
Hydrogen sulfide
U135 7783β06β4
Hydrogen sulfide H2S
U096 80β15β9 Hydroperoxide, 1-methyl-1-phenylethyl- (R)
U116 96β45β7 2-Imidazolidinethione
U137 193β39β5 Indeno[1,2,3-cd]pyrene
U190 85β44β9 1,3-Isobenzofurandione
U140 78β83β1 Isobutyl alcohol (I,T)
U141 120β58β1 Isosafrole
U142 143β50β0 Kepone
U143 303β34β4 Lasiocarpine
U144 301β04β2 Lead acetate
U146 1335β32β6
Lead, bis(acetato-O)tetrahydroxytri-
U145 7446β27β Lead phosphate
57
7
U146 1335β32β6
Lead subacetate
U129 58β89β9 Lindane
U163 70β25β7 MNNG
U147 108β31β6 Maleic anhydride
U148 123β33β1 Maleic hydrazide
U149 109β77β3 Malononitrile
U150 148β82β3 Melphalan
U151 7439β97β6
Mercury
U152 126β98β7 Methacrylonitrile (I, T)
U092 124β40β3 Methanamine, N-methyl- (I)
U029 74β83β9 Methane, bromo-
U045 74β87β3 Methane, chloro- (I, T)
U046 107β30β2 Methane, chloromethoxy-
U068 74β95β3 Methane, dibromo-
U080 75β09β2 Methane, dichloro-
U075 75β71β8 Methane, dichlorodifluoro-
U138 74β88β4 Methane, iodo-
U119 62β50β0 Methanesulfonic acid, ethyl ester
U211 56β23β5 Methane, tetrachloro-
U153 74β93β1 Methanethiol (I, T)
U225 75β25β2 Methane, tribromo-
U044 67β66β3 Methane, trichloro-
U121 75β69β4 Methane, trichlorofluoro-
U036 57β74β9 4,7-Methano-1H-indene, 1,2,4,5,6,7,8,8-octachloro-2,3,3a,4,7,7a-hexahydro-
U154 67β56β1 Methanol (I)
58
U155 91β80β5 Methapyrilene
U142 143β50β0 1,3,4-Metheno-2H-cyclobuta[cd]pentalen-2-one, 1,1a,3,3a,4,5,5,5a,5b,6-decachlorooctahydro-
U247 72β43β5 Methoxychlor
U154 67β56β1 Methyl alcohol (I)
U029 74β83β9 Methyl bromide
U186 504β60β9 1-Methylbutadiene (I)
U045 74β87β3 Methyl chloride (I,T)
U156 79β22β1 Methyl chlorocarbonate (I,T)
U226 71β55β6 Methyl chloroform
U157 56β49β5 3-Methylcholanthrene
U158 101β14β4 4,4β²-Methylenebis(2-chloroaniline)
U068 74β95β3 Methylene bromide
U080 75β09β2 Methylene chloride
U159 78β93β3 Methyl ethyl ketone (MEK) (I,T)
U160 1338β23β4
Methyl ethyl ketone peroxide (R,T)
U138 74β88β4 Methyl iodide
U161 108β10β1 Methyl isobutyl ketone (I)
U162 80β62β6 Methyl methacrylate (I,T)
U161 108β10β1 4-Methyl-2-pentanone (I)
U164 56β04β2 Methylthiouracil
U010 50β07β7 Mitomycin C
U059 20830β81β3
5,12-Naphthacenedione, 8-acetyl-10-[(3-amino-2,3,6-trideoxy)-alpha-L-lyxo-hexopyranosyl)oxy]-7,8,9,10-tetrahydro-6,8,11-trihydroxy-1-methoxy-, (8S-cis)-
U167 134β32β7 1-Naphthalenamine
U168 91β59β8 2-Naphthalenamine
59
U026 494β03β1 Naphthalenamine, N,Nβ²-bis(2-chloroethyl)-
U165 91β20β3 Naphthalene
U047 91β58β7 Naphthalene, 2-chloro-
U166 130β15β4 1,4-Naphthalenedione
U236 72β57β1 2,7-Naphthalenedisulfonic acid, 3,3β²-[(3,3β²- dimethyl[1,1β²-biphenyl]-4,4β²-diyl)bis(azo)bis[5-amino-4-hydroxy]-, tetrasodium salt
U279 63β25β2 1-Naphthalenol, methylcarbamate.
U166 130β15β4 1,4-Naphthoquinone
U167 134β32β7 alpha-Naphthylamine
U168 91β59β8 beta-Naphthylamine
U217 10102β45β1
Nitric acid, thallium(1+) salt
U169 98β95β3 Nitrobenzene (I,T)
U170 100β02β7 p-Nitrophenol
U171 79β46β9 2-Nitropropane (I,T)
U172 924β16β3 N-Nitrosodi-n-butylamine
U173 1116β54β7
N-Nitrosodiethanolamine
U174 55β18β5 N-Nitrosodiethylamine
U176 759β73β9 N-Nitroso-N-ethylurea
U177 684β93β5 N-Nitroso-N-methylurea
U178 615β53β2 N-Nitroso-N-methylurethane
U179 100β75β4 N-Nitrosopiperidine
U180 930β55β2 N-Nitrosopyrrolidine
U181 99β55β8 5-Nitro-o-toluidine
U193 1120β71β4
1,2-Oxathiolane, 2,2-dioxide
U058 50β18β0 2H-1,3,2-Oxazaphosphorin-2-amine, N,N-bis(2-chloroethyl)tetrahydro-, 2-oxide
60
U115 75β21β8 Oxirane (I,T)
U126 765β34β4 Oxiranecarboxyaldehyde
U041 106β89β8 Oxirane, (chloromethyl)-
U182 123β63β7 Paraldehyde
U183 608β93β5 Pentachlorobenzene
U184 76β01β7 Pentachloroethane
U185 82β68β8 Pentachloronitrobenzene (PCNB)
See F027 87β86β5 Pentachlorophenol
U161 108β10β1 Pentanol, 4-methyl-
U186 504β60β9 1,3-Pentadiene (I)
U187 62β44β2 Phenacetin
U188 108β95β2 Phenol
U048 95β57β8 Phenol, 2-chloro-
U039 59β50β7 Phenol, 4-chloro-3-methyl-
U081 120β83β2 Phenol, 2,4-dichloro-
U082 87β65β0 Phenol, 2,6-dichloro-
U089 56β53β1 Phenol, 4,4β²-(1,2-diethyl-1,2-ethenediyl)bis-, (E)-
U101 105β67β9 Phenol, 2,4-dimethyl-
U052 1319β77β3
Phenol, methyl-
U132 70β30β4 Phenol, 2,2β²-methylenebis[3,4,6-trichloro-
U411 114β26β1 Phenol, 2-(1-methylethoxy)-,methylcarbamate.
U170 100β02β7 Phenol, 4-nitro-
See F027 87β86β5 Phenol, pentachloro-
See F027 58β90β2 Phenol, 2,3,4,6-tetrachloro-
See F027 95β95β4 Phenol, 2,4,5-trichloro-
See F027 88β06β2 Phenol, 2,4,6-trichloro-
61
U150 148β82β3 L-Phenylalanine, 4-[bis(2-chloroethyl)amino]-
U145 7446β27β7
Phosphoric acid, lead(2+) salt (2:3)
U087 3288β58β2
Phosphorodithioic acid, O,O-diethyl S-methyl ester
U189 1314β80β3
Phosphorus sulfide (R)
U190 85β44β9 Phthalic anhydride
U191 109β06β8 2-Picoline
U179 100β75β4 Piperidine, 1-nitroso-
U192 23950β58β5
Pronamide
U194 107β10β8 1-Propanamine (I,T)
U111 621β64β7 1-Propanamine, N-nitroso-N-propyl-
U110 142β84β7 1-Propanamine, N-propyl- (I)
U066 96β12β8 Propane, 1,2-dibromo-3-chloro-
U083 78β87β5 Propane, 1,2-dichloro-
U149 109β77β3 Propanedinitrile
U171 79β46β9 Propane, 2-nitro- (I,T)
U027 108β60β1 Propane, 2,2β²-oxybis[2-chloro-
U193 1120β71β4
1,3-Propane sultone
See F027 93β72β1 Propanoic acid, 2-(2,4,5-trichlorophenoxy)-
U235 126β72β7 1-Propanol, 2,3-dibromo-, phosphate (3:1)
U140 78β83β1 1-Propanol, 2-methyl- (I,T)
U002 67β64β1 2-Propanone (I)
U007 79β06β1 2-Propenamide
U084 542β75β6 1-Propene, 1,3-dichloro-
U243 1888β71β7
1-Propene, 1,1,2,3,3,3-hexachloro-
62
U009 107β13β1 2-Propenenitrile
U152 126β98β7 2-Propenenitrile, 2-methyl- (I,T)
U008 79β10β7 2-Propenoic acid (I)
U113 140β88β5 2-Propenoic acid, ethyl ester (I)
U118 97β63β2 2-Propenoic acid, 2-methyl-, ethyl ester
U162 80β62β6 2-Propenoic acid, 2-methyl-, methyl ester (I,T)
U373 122β42β9 Propham.
U411 114β26β1 Propoxur.
U387 52888β80β9
Prosulfocarb.
U194 107β10β8 n-Propylamine (I,T)
U083 78β87β5 Propylene dichloride
U148 123β33β1 3,6-Pyridazinedione, 1,2-dihydro-
U196 110β86β1 Pyridine
U191 109β06β8 Pyridine, 2-methyl-
U237 66β75β1 2,4-(1H,3H)-Pyrimidinedione, 5-[bis(2- chloroethyl)amino]-
U164 56β04β2 4(1H)-Pyrimidinone, 2,3-dihydro-6-methyl-2-thioxo-
U180 930β55β2 Pyrrolidine, 1-nitroso-
U200 50β55β5 Reserpine
U201 108β46β3 Resorcinol
U202 181β07β2 Saccharin, & salts
U203 94β59β7 Safrole
U204 7783β00β8
Selenious acid
U204 7783β00β8
Selenium dioxide
U205 7488β56β4
Selenium sulfide
63
U205 7488β56β4
Selenium sulfide SeS2(R,T)
U015 115β02β6 L-Serine, diazoacetate (ester)
See F027 93β72β1 Silvex (2,4,5-TP)
U206 18883β66β4
Streptozotocin
U103 77β78β1 Sulfuric acid, dimethyl ester
U189 1314β80β3
Sulfur phosphide (R)
See F027 93β76β5 2,4,5-T
U207 95β94β3 1,2,4,5-Tetrachlorobenzene
U208 630β20β6 1,1,1,2-Tetrachloroethane
U209 79β34β5 1,1,2,2-Tetrachloroethane
U210 127β18β4 Tetrachloroethylene
See F027 58β90β2 2,3,4,6-Tetrachlorophenol
U213 109β99β9 Tetrahydrofuran (I)
U214 563β68β8 Thallium(I) acetate
U215 6533β73β9
Thallium(I) carbonate
U216 7791β12β0
Thallium(I) chloride
U216 7791β12β0
thallium chloride TlCl
U217 10102β45β1
Thallium(I) nitrate
U218 62β55β5 Thioacetamide
U410 59669β26β0
Thiodicarb.
U153 74β93β1 Thiomethanol (I,T)
U244 137β26β8 Thioperoxydicarbonic diamide[(H2N)C(S)]2S2, tetramethyl-
64
U409 23564β05β8
Thiophanate-methyl.
U219 62β56β6 Thiourea
U244 137β26β8 Thiram
U220 108β88β3 Toluene
U221 25376β45β8
Toluenediamine
U223 26471β62β5
Toluene diisocyanate (R,T)
U328 95β53β4 o-Toluidine
U353 106β49β0 p-Toluidine
U222 636β21β5 o-Toluidine hydrochloride
U389 2303β17β5
Triallate.
U011 61β82β5 1H-1,2,4-Triazol-3-amine
U226 71β55β6 1,1,1-Trichloroethane
U227 79β00β5 1,1,2-Trichloroethane
U228 79β01β6 Trichloroethylene
U121 75β69β4 Trichloromonofluoromethane
See F027 95β95β4 2,4,5-Trichlorophenol
See F027 88β06β2 2,4,6-Trichlorophenol
U404 121β44β8 Triethylamine.
U234 99β35β4 1,3,5-Trinitrobenzene (R,T)
U182 123β63β7 1,3,5-Trioxane, 2,4,6-trimethyl-
U235 126β72β7 Tris(2,3-dibromopropyl) phosphate
U236 72β57β1 Trypan blue
U237 66β75β1 Uracil mustard
U176 759β73β9 Urea, N-ethyl-N-nitroso-
U177 684β93β5 Urea, N-methyl-N-nitroso-
65
U043 75β01β4 Vinyl chloride
U248 181β81β2 Warfarin, & salts, when present at concentrations of 0.3% or less
U239 1330β20β7
Xylene (I)
U200 50β55β5 Yohimban-16-carboxylic acid, 11,17-dimethoxy-18-[(3,4,5-trimethoxybenzoyl)oxy]-, methyl ester, (3beta,16beta,17alpha,18beta,20alpha)-
U249 1314β84β7
Zinc phosphide Zn3P2, when present at concentrations of 10% or less
U001 75β07β0 Acetaldehyde (I)
U001 75β07β0 Ethanal (I)
U002 67β64β1 Acetone (I)
U002 67β64β1 2-Propanone (I)
U003 75β05β8 Acetonitrile (I,T)
U004 98β86β2 Acetophenone
U004 98β86β2 Ethanone, 1-phenyl-
U005 53β96β3 Acetamide, -9H-fluoren-2-yl-
U005 53β96β3 2-Acetylaminofluorene
U006 75β36β5 Acetyl chloride (C,R,T)
U007 79β06β1 Acrylamide
U007 79β06β1 2-Propenamide
U008 79β10β7 Acrylic acid (I)
U008 79β10β7 2-Propenoic acid (I)
U009 107β13β1 Acrylonitrile
U009 107β13β1 2-Propenenitrile
U010 50β07β7 Azirino[2',3':3,4]pyrrolo[1,2-a]indole-4,7-dione, 6-amino-8-[[(aminocarbonyl)oxy]methyl]-1,1a,2,8,8a,8b-hexahydro-8a-methoxy-5-methyl-, [1aS-(1aalpha,
66
8beta,8aalpha,8balpha)]-
U010 50β07β7 Mitomycin C
U011 61β82β5 Amitrole
U011 61β82β5 1H-1,2,4-Triazol-3-amine
U012 62β53β3 Aniline (I,T)
U012 62β53β3 Benzenamine (I,T)
U014 492β80β8 Auramine
U014 492β80β8 Benzenamine, 4,4'-carbonimidoylbis[N,N-dimethyl-
U015 115β02β6 Azaserine
U015 115β02β6 L-Serine, diazoacetate (ester)
U016 225β51β4 Benz[c]acridine
U017 98β87β3 Benzal chloride
U017 98β87β3 Benzene, (dichloromethyl)-
U018 56β55β3 Benz[a]anthracene
U019 71β43β2 Benzene (I,T)
U020 98β09β9 Benzenesulfonic acid chloride (C,R)
U020 98β09β9 Benzenesulfonyl chloride (C,R)
U021 92β87β5 Benzidine
U021 92β87β5 [1,1'-Biphenyl]-4,4'-diamine
U022 50β32β8 Benzo[a]pyrene
U023 98β07β7 Benzene, (trichloromethyl)-
U023 98β07β7 Benzotrichloride (C,R,T)
U024 111β91β1 Dichloromethoxy ethane
U024 111β91β1 Ethane, 1,1'-[methylenebis(oxy)]bis[2-chloro-
U025 111β44β4 Dichloroethyl ether
U025 111β44β4 Ethane, 1,1'-oxybis[2-chloro-
U026 494β03β1 Chlornaphazin
67
U026 494β03β1 Naphthalenamine, N,N'-bis(2-chloroethyl)-
U027 108β60β1 Dichloroisopropyl ether
U027 108β60β1 Propane, 2,2'-oxybis[2-chloro-
U028 117β81β7 1,2-Benzenedicarboxylic acid, bis(2-ethylhexyl) ester
U028 117β81β7 Diethylhexyl phthalate
U029 74β83β9 Methane, bromo-
U029 74β83β9 Methyl bromide
U030 101β55β3 Benzene, 1-bromo-4-phenoxy-
U030 101β55β3 4-Bromophenyl phenyl ether
U031 71β36β3 1-Butanol (I)
U031 71β36β3 n-Butyl alcohol (I)
U032 13765β19β0
Calcium chromate
U032 13765β19β0
Chromic acid H2CrO4, calcium salt
U033 353β50β4 Carbonic difluoride
U033 353β50β4 Carbon oxyfluoride (R,T)
U034 75β87β6 Acetaldehyde, trichloro-
U034 75β87β6 Chloral
U035 305β03β3 Benzenebutanoic acid, 4-[bis(2-chloroethyl)amino]-
U035 305β03β3 Chlorambucil
U036 57β74β9 Chlordane, alpha & gamma isomers
U036 57β74β9 4,7-Methano-1H-indene, 1,2,4,5,6,7,8,8-octachloro-2,3,3a,4,7,7a-hexahydro-
U037 108β90β7 Benzene, chloro-
U037 108β90β7 Chlorobenzene
U038 510β15β6 Benzeneacetic acid, 4-chloro-alpha-(4-chlorophenyl)-alpha-hydroxy-, ethyl ester
68
U038 510β15β6 Chlorobenzilate
U039 59β50β7 p-Chloro-m-cresol
U039 59β50β7 Phenol, 4-chloro-3-methyl-
U041 106β89β8 Epichlorohydrin
U041 106β89β8 Oxirane, (chloromethyl)-
U042 110β75β8 2-Chloroethyl vinyl ether
U042 110β75β8 Ethene, (2-chloroethoxy)-
U043 75β01β4 Ethene, chloro-
U043 75β01β4 Vinyl chloride
U044 67β66β3 Chloroform
U044 67β66β3 Methane, trichloro-
U045 74β87β3 Methane, chloro- (I,T)
U045 74β87β3 Methyl chloride (I,T)
U046 107β30β2 Chloromethyl methyl ether
U046 107β30β2 Methane, chloromethoxy-
U047 91β58β7 beta-Chloronaphthalene
U047 91β58β7 Naphthalene, 2-chloro-
U048 95β57β8 o-Chlorophenol
U048 95β57β8 Phenol, 2-chloro-
U049 3165β93β3
Benzenamine, 4-chloro-2-methyl-, hydrochloride
U049 3165β93β3
4-Chloro-o-toluidine, hydrochloride
U050 218β01β9 Chrysene
U051 Creosote
U052 1319β77β3
Cresol (Cresylic acid)
U052 1319β77β3
Phenol, methyl-
69
U053 4170β30β3
2-Butenal
U053 4170β30β3
Crotonaldehyde
U055 98β82β8 Benzene, (1-methylethyl)-(I)
U055 98β82β8 Cumene (I)
U056 110β82β7 Benzene, hexahydro-(I)
U056 110β82β7 Cyclohexane (I)
U057 108β94β1 Cyclohexanone (I)
U058 50β18β0 Cyclophosphamide
U058 50β18β0 2H-1,3,2-Oxazaphosphorin-2-amine, N,N-bis(2-chloroethyl)tetrahydro-, 2-oxide
U059 20830β81β3
Daunomycin
U059 20830β81β3
5,12-Naphthacenedione, 8-acetyl-10-[(3-amino-2,3,6-trideoxy)-alpha-L-lyxo-hexopyranosyl)oxy]-7,8,9,10-tetrahydro-6,8,11-trihydroxy-1-methoxy-, (8S-cis)-
U060 72β54β8 Benzene, 1,1'-(2,2-dichloroethylidene)bis[4-chloro-
U060 72β54β8 DDD
U061 50β29β3 Benzene, 1,1'-(2,2,2-trichloroethylidene)bis[4-chloro-
U061 50β29β3 DDT
U062 2303β16β4
Carbamothioic acid, bis(1-methylethyl)-, S-(2,3-di chloro-2-propenyl) ester
U062 2303β16β4
Diallate
U063 53β70β3 Dibenz[a,h]anthracene
U064 189β55β9 Benzo[rst]pentaphene
U064 189β55β9 Dibenzo[a,i]pyrene
U066 96β12β8 1,2-Dibromo-3-chloropropane
70
U066 96β12β8 Propane, 1,2-dibromo-3-chloro-
U067 106β93β4 Ethane, 1,2-dibromo-
U067 106β93β4 Ethylene dibromide
U068 74β95β3 Methane, dibromo-
U068 74β95β3 Methylene bromide
U069 84β74β2 1,2-Benzenedicarboxylic acid, dibutyl ester
U069 84β74β2 Dibutyl phthalate
U070 95β50β1 Benzene, 1,2-dichloro-
U070 95β50β1 o-Dichlorobenzene
U071 541β73β1 Benzene, 1,3-dichloro-
U071 541β73β1 m-Dichlorobenzene
U072 106β46β7 Benzene, 1,4-dichloro-
U072 106β46β7 p-Dichlorobenzene
U073 91β94β1 [1,1'-Biphenyl]-4,4'-diamine, 3,3'-dichloro-
U073 91β94β1 3,3'-Dichlorobenzidine
U074 764β41β0 2-Butene, 1,4-dichloro-(I,T)
U074 764β41β0 1,4-Dichloro-2-butene (I,T)
U075 75β71β8 Dichlorodifluoromethane
U075 75β71β8 Methane, dichlorodifluoro-
U076 75β34β3 Ethane, 1,1-dichloro-
U076 75β34β3 Ethylidene dichloride
U077 107β06β2 Ethane, 1,2-dichloro-
U077 107β06β2 Ethylene dichloride
U078 75β35β4 1,1-Dichloroethylene
U078 75β35β4 Ethene, 1,1-dichloro-
U079 156β60β5 1,2-Dichloroethylene
U079 156β60β5 Ethene, 1,2-dichloro-, (E)-
U080 75β09β2 Methane, dichloro-
71
U080 75β09β2 Methylene chloride
U081 120β83β2 2,4-Dichlorophenol
U081 120β83β2 Phenol, 2,4-dichloro-
U082 87β65β0 2,6-Dichlorophenol
U082 87β65β0 Phenol, 2,6-dichloro-
U083 78β87β5 Propane, 1,2-dichloro-
U083 78β87β5 Propylene dichloride
U084 542β75β6 1,3-Dichloropropene
U084 542β75β6 1-Propene, 1,3-dichloro-
U085 1464β53β5
2,2'-Bioxirane
U085 1464β53β5
1,2:3,4-Diepoxybutane (I,T)
U086 1615β80β1
N,N'-Diethylhydrazine
U086 1615β80β1
Hydrazine, 1,2-diethyl-
U087 3288β58β2
O,O-Diethyl S-methyl dithiophosphate
U087 3288β58β2
Phosphorodithioic acid, O,O-diethyl S-methyl ester
U088 84β66β2 1,2-Benzenedicarboxylic acid, diethyl ester
U088 84β66β2 Diethyl phthalate
U089 56β53β1 Diethylstilbesterol
U089 56β53β1 Phenol, 4,4'-(1,2-diethyl-1,2-ethenediyl)bis-,(E)-
U090 94β58β6 1,3-Benzodioxole, 5-propyl-
U090 94β58β6 Dihydrosafrole
U091 119β90β4 [1,1'-Biphenyl]-4,4'-diamine, 3,3'-dimethoxy-
U091 119β90β4 3,3'-Dimethoxybenzidine
72
U092 124β40β3 Dimethylamine (I)
U092 124β40β3 Methanamine, -methyl-(I)
U093 60β11β7 Benzenamine, N,N-dimethyl-4-(phenylazo)-
U093 60β11β7 p-Dimethylaminoazobenzene
U094 57β97β6 Benz[a]anthracene, 7,12-dimethyl-
U094 57β97β6 7,12-Dimethylbenz[a]anthracene
U095 119β93β7 [1,1'-Biphenyl]-4,4'-diamine, 3,3'-dimethyl-
U095 119β93β7 3,3'-Dimethylbenzidine
U096 80β15β9 alpha,alpha-Dimethylbenzylhydroperoxide (R)
U096 80β15β9 Hydroperoxide, 1-methyl-1-phenylethyl-(R)
U097 79β44β7 Carbamic chloride, dimethyl-
U097 79β44β7 Dimethylcarbamoyl chloride
U098 57β14β7 1,1-Dimethylhydrazine
U098 57β14β7 Hydrazine, 1,1-dimethyl-
U099 540β73β8 1,2-Dimethylhydrazine
U099 540β73β8 Hydrazine, 1,2-dimethyl-
U101 105β67β9 2,4-Dimethylphenol
U101 105β67β9 Phenol, 2,4-dimethyl-
U102 131β11β3 1,2-Benzenedicarboxylic acid, dimethyl ester
U102 131β11β3 Dimethyl phthalate
U103 77β78β1 Dimethyl sulfate
U103 77β78β1 Sulfuric acid, dimethyl ester
U105 121β14β2 Benzene, 1-methyl-2,4-dinitro-
U105 121β14β2 2,4-Dinitrotoluene
U106 606β20β2 Benzene, 2-methyl-1,3-dinitro-
U106 606β20β2 2,6-Dinitrotoluene
U107 117β84β0 1,2-Benzenedicarboxylic acid, dioctyl ester
73
U107 117β84β0 Di-n-octyl phthalate
U108 123β91β1 1,4-Diethyleneoxide
U108 123β91β1 1,4-Dioxane
U109 122β66β7 1,2-Diphenylhydrazine
U109 122β66β7 Hydrazine, 1,2-diphenyl-
U110 142β84β7 Dipropylamine (I)
U110 142β84β7 1-Propanamine, N-propyl-(I)
U111 621β64β7 Di-n-propylnitrosamine
U111 621β64β7 1-Propanamine, N-nitroso-N-propyl-
U112 141β78β6 Acetic acid ethyl ester (I)
U112 141β78β6 Ethyl acetate (I)
U113 140β88β5 Ethyl acrylate (I)
U113 140β88β5 2-Propenoic acid, ethyl ester (I)
U114 1111β54β6
Carbamodithioic acid, 1,2-ethanediylbis-, salts & esters
U114 1111β54β6
Ethylenebisdithiocarbamic acid, salts & esters
U115 75β21β8 Ethylene oxide (I,T)
U115 75β21β8 Oxirane (I,T)
U116 96β45β7 Ethylenethiourea
U116 96β45β7 2-Imidazolidinethione
U117 60β29β7 Ethane, 1,1'-oxybis-(I)
U117 60β29β7 Ethyl ether (I)
U118 97β63β2 Ethyl methacrylate
U118 97β63β2 2-Propenoic acid, 2-methyl-, ethyl ester
U119 62β50β0 Ethyl methanesulfonate
U119 62β50β0 Methanesulfonic acid, ethyl ester
U120 206β44β0 Fluoranthene
U121 75β69β4 Methane, trichlorofluoro-
74
U121 75β69β4 Trichloromonofluoromethane
U122 50β00β0 Formaldehyde
U123 64β18β6 Formic acid (C,T)
U124 110β00β9 Furan (I)
U124 110β00β9 Furfuran (I)
U125 98β01β1 2-Furancarboxaldehyde (I)
U125 98β01β1 Furfural (I)
U126 765β34β4 Glycidylaldehyde
U126 765β34β4 Oxiranecarboxyaldehyde
U127 118β74β1 Benzene, hexachloro-
U127 118β74β1 Hexachlorobenzene
U128 87β68β3 1,3-Butadiene, 1,1,2,3,4,4-hexachloro-
U128 87β68β3 Hexachlorobutadiene
U129 58β89β9 Cyclohexane, 1,2,3,4,5,6-hexachloro-,(1alpha,2alpha,3beta,4alpha,5alpha,6beta)-
U129 58β89β9 Lindane
U130 77β47β4 1,3-Cyclopentadiene, 1,2,3,4,5,5-hexachloro-
U130 77β47β4 Hexachlorocyclopentadiene
U131 67β72β1 Ethane, hexachloro-
U131 67β72β1 Hexachloroethane
U132 70β30β4 Hexachlorophene
U132 70β30β4 Phenol, 2,2'-methylenebis[3,4,6-trichloro-
U133 302β01β2 Hydrazine (R,T)
U134 7664β39β3
Hydrofluoric acid (C,T)
U134 7664β39β3
Hydrogen fluoride (C,T)
U135 7783β06β4
Hydrogen sulfide
75
U135 7783β06β4
Hydrogen sulfide H2S
U136 75β60β5 Arsinic acid, dimethyl-
U136 75β60β5 Cacodylic acid
U137 193β39β5 Indeno[1,2,3-cd]pyrene
U138 74β88β4 Methane, iodo-
U138 74β88β4 Methyl iodide
U140 78β83β1 Isobutyl alcohol (I,T)
U140 78β83β1 1-Propanol, 2-methyl- (I,T)
U141 120β58β1 1,3-Benzodioxole, 5-(1-propenyl)-
U141 120β58β1 Isosafrole
U142 143β50β0 Kepone
U142 143β50β0 1,3,4-Metheno-2H-cyclobuta[cd]pentalen-2-one, 1,1a,3,3a,4,5,5,5a,5b,6-decachlorooctahydro-
U143 303β34β4 2-Butenoic acid, 2-methyl-, 7-[[2,3-dihydroxy-2-(1-methoxyethyl)-3-methyl-1-oxobutoxy]methyl]-2,3,5,7a-tetrahydro-1H-pyrrolizin-1-yl ester, [1S-[1alpha(Z),7(2S*,3R*),7aalpha]]-
U143 303β34β4 Lasiocarpine
U144 301β04β2 Acetic acid, lead(2+) salt
U144 301β04β2 Lead acetate
U145 7446β27β7
Lead phosphate
U145 7446β27β7
Phosphoric acid, lead(2+) salt (2:3)
U146 1335β32β6
Lead, bis(acetato-O)tetrahydroxytri-
U146 1335β32β6
Lead subacetate
U147 108β31β6 2,5-Furandione
76
U147 108β31β6 Maleic anhydride
U148 123β33β1 Maleic hydrazide
U148 123β33β1 3,6-Pyridazinedione, 1,2-dihydro-
U149 109β77β3 Malononitrile
U149 109β77β3 Propanedinitrile
U150 148β82β3 Melphalan
U150 148β82β3 L-Phenylalanine, 4-[bis(2-chloroethyl)amino]-
U151 7439β97β6
Mercury
U152 126β98β7 Methacrylonitrile (I,T)
U152 126β98β7 2-Propenenitrile, 2-methyl- (I,T)
U153 74β93β1 Methanethiol (I,T)
U153 74β93β1 Thiomethanol (I,T)
U154 67β56β1 Methanol (I)
U154 67β56β1 Methyl alcohol (I)
U155 91β80β5 1,2-Ethanediamine, N,N-dimethyl-N'-2-pyridinyl-N'-(2-thienylmethyl)-
U155 91β80β5 Methapyrilene
U156 79β22β1 Carbonochloridic acid, methyl ester (I,T)
U156 79β22β1 Methyl chlorocarbonate (I,T)
U157 56β49β5 Benz[j]aceanthrylene, 1,2-dihydro-3-methyl-
U157 56β49β5 3-Methylcholanthrene
U158 101β14β4 Benzenamine, 4,4'-methylenebis[2-chloro-
U158 101β14β4 4,4'-Methylenebis(2-chloroaniline)
U159 78β93β3 2-Butanone (I,T)
U159 78β93β3 Methyl ethyl ketone (MEK) (I,T)
U160 1338β23β4
2-Butanone, peroxide (R,T)
77
U160 1338β23β4
Methyl ethyl ketone peroxide (R,T)
U161 108β10β1 Methyl isobutyl ketone (I)
U161 108β10β1 4-Methyl-2-pentanone (I)
U161 108β10β1 Pentanol, 4-methyl-
U162 80β62β6 Methyl methacrylate (I,T)
U162 80β62β6 2-Propenoic acid, 2-methyl-, methyl ester (I,T)
U163 70β25β7 Guanidine, -methyl-N'-nitro-N-nitroso-
U163 70β25β7 MNNG
U164 56β04β2 Methylthiouracil
U164 56β04β2 4(1H)-Pyrimidinone, 2,3-dihydro-6-methyl-2-thioxo-
U165 91β20β3 Naphthalene
U166 130β15β4 1,4-Naphthalenedione
U166 130β15β4 1,4-Naphthoquinone
U167 134β32β7 1-Naphthalenamine
U167 134β32β7 alpha-Naphthylamine
U168 91β59β8 2-Naphthalenamine
U168 91β59β8 beta-Naphthylamine
U169 98β95β3 Benzene, nitro-
U169 98β95β3 Nitrobenzene (I,T)
U170 100β02β7 p-Nitrophenol
U170 100β02β7 Phenol, 4-nitro-
U171 79β46β9 2-Nitropropane (I,T)
U171 79β46β9 Propane, 2-nitro- (I,T)
U172 924β16β3 1-Butanamine, N-butyl-N-nitroso-
U172 924β16β3 N-Nitrosodi-n-butylamine
U173 1116β54β Ethanol, 2,2'-(nitrosoimino)bis-
78
7
U173 1116β54β7
N-Nitrosodiethanolamine
U174 55β18β5 Ethanamine, -ethyl-N-nitroso-
U174 55β18β5 N-Nitrosodiethylamine
U176 759β73β9 N-Nitroso-N-ethylurea
U176 759β73β9 Urea, N-ethyl-N-nitroso-
U177 684β93β5 N-Nitroso-N-methylurea
U177 684β93β5 Urea, N-methyl-N-nitroso-
U178 615β53β2 Carbamic acid, methylnitroso-, ethyl ester
U178 615β53β2 N-Nitroso-N-methylurethane
U179 100β75β4 N-Nitrosopiperidine
U179 100β75β4 Piperidine, 1-nitroso-
U180 930β55β2 N-Nitrosopyrrolidine
U180 930β55β2 Pyrrolidine, 1-nitroso-
U181 99β55β8 Benzenamine, 2-methyl-5-nitro-
U181 99β55β8 5-Nitro-o-toluidine
U182 123β63β7 1,3,5-Trioxane, 2,4,6-trimethyl-
U182 123β63β7 Paraldehyde
U183 608β93β5 Benzene, pentachloro-
U183 608β93β5 Pentachlorobenzene
U184 76β01β7 Ethane, pentachloro-
U184 76β01β7 Pentachloroethane
U185 82β68β8 Benzene, pentachloronitro-
U185 82β68β8 Pentachloronitrobenzene (PCNB)
U186 504β60β9 1-Methylbutadiene (I)
U186 504β60β9 1,3-Pentadiene (I)
U187 62β44β2 Acetamide, -(4-ethoxyphenyl)-
79
U187 62β44β2 Phenacetin
U188 108β95β2 Phenol
U189 1314β80β3
Phosphorus sulfide (R)
U189 1314β80β3
Sulfur phosphide (R)
U190 85β44β9 1,3-Isobenzofurandione
U190 85β44β9 Phthalic anhydride
U191 109β06β8 2-Picoline
U191 109β06β8 Pyridine, 2-methyl-
U192 23950β58β5
Benzamide, 3,5-dichloro-N-(1,1-dimethyl-2-propynyl)-
U192 23950β58β5
Pronamide
U193 1120β71β4
1,2-Oxathiolane, 2,2-dioxide
U193 1120β71β4
1,3-Propane sultone
U194 107β10β8 1-Propanamine (I,T)
U194 107β10β8 n-Propylamine (I,T)
U196 110β86β1 Pyridine
U197 106β51β4 p-Benzoquinone
U197 106β51β4 2,5-Cyclohexadiene-1,4-dione
U200 50β55β5 Reserpine
U200 50β55β5 Yohimban-16-carboxylic acid, 11,17-dimethoxy-18-[(3,4,5-trimethoxybenzoyl)oxy]-, methyl ester,(3beta,16beta,17alpha,18beta,20alpha)-
U201 108β46β3 1,3-Benzenediol
U201 108β46β3 Resorcinol
U202 181β07β2 1,2-Benzisothiazol-3(2H)-one, 1,1-dioxide,& salts
80
U202 181β07β2 Saccharin, & salts
U203 94β59β7 1,3-Benzodioxole, 5-(2-propenyl)-
U203 94β59β7 Safrole
U204 7783β00β8
Selenious acid
U204 7783β00β8
Selenium dioxide
U205 7488β56β4
Selenium sulfide
U205 7488β56β4
Selenium sulfide SeS2(R,T)
U206 18883β66β4
Glucopyranose, 2-deoxy-2-(3-methyl-3-nitrosoureido)-, D-
U206 18883β66β4
D-Glucose, 2-deoxy-2-[[(methylnitrosoamino)-carbonyl]amino]-
U206 18883β66β4
Streptozotocin
U207 95β94β3 Benzene, 1,2,4,5-tetrachloro-
U207 95β94β3 1,2,4,5-Tetrachlorobenzene
U208 630β20β6 Ethane, 1,1,1,2-tetrachloro-
U208 630β20β6 1,1,1,2-Tetrachloroethane
U209 79β34β5 Ethane, 1,1,2,2-tetrachloro-
U209 79β34β5 1,1,2,2-Tetrachloroethane
U210 127β18β4 Ethene, tetrachloro-
U210 127β18β4 Tetrachloroethylene
U211 56β23β5 Carbon tetrachloride
U211 56β23β5 Methane, tetrachloro-
U213 109β99β9 Furan, tetrahydro-(I)
U213 109β99β9 Tetrahydrofuran (I)
U214 563β68β8 Acetic acid, thallium(1+) salt
U214 563β68β8 Thallium(I) acetate
81
U215 6533β73β9
Carbonic acid, dithallium(1+) salt
U215 6533β73β9
Thallium(I) carbonate
U216 7791β12β0
Thallium(I) chloride
U216 7791β12β0
Thallium chloride TlCl
U217 10102β45β1
Nitric acid, thallium(1+) salt
U217 10102β45β1
Thallium(I) nitrate
U218 62β55β5 Ethanethioamide
U218 62β55β5 Thioacetamide
U219 62β56β6 Thiourea
U220 108β88β3 Benzene, methyl-
U220 108β88β3 Toluene
U221 25376β45β8
Benzenediamine, ar-methyl-
U221 25376β45β8
Toluenediamine
U222 636β21β5 Benzenamine, 2-methyl-, hydrochloride
U222 636β21β5 o-Toluidine hydrochloride
U223 26471β62β5
Benzene, 1,3-diisocyanatomethyl- (R,T)
U223 26471β62β5
Toluene diisocyanate (R,T)
U225 75β25β2 Bromoform
U225 75β25β2 Methane, tribromo-
U226 71β55β6 Ethane, 1,1,1-trichloro-
U226 71β55β6 Methyl chloroform
U226 71β55β6 1,1,1-Trichloroethane
82
U227 79β00β5 Ethane, 1,1,2-trichloro-
U227 79β00β5 1,1,2-Trichloroethane
U228 79β01β6 Ethene, trichloro-
U228 79β01β6 Trichloroethylene
U234 99β35β4 Benzene, 1,3,5-trinitro-
U234 99β35β4 1,3,5-Trinitrobenzene (R,T)
U235 126β72β7 1-Propanol, 2,3-dibromo-, phosphate (3:1)
U235 126β72β7 Tris(2,3-dibromopropyl) phosphate
U236 72β57β1 2,7-Naphthalenedisulfonic acid, 3,3'-[(3,3'-dimethyl[1,1'-biphenyl]-4,4'-diyl)bis(azo)bis[5-amino-4-hydroxy]-, tetrasodium salt
U236 72β57β1 Trypan blue
U237 66β75β1 2,4-(1H,3H)-Pyrimidinedione, 5-[bis(2-chloroethyl)amino]-
U237 66β75β1 Uracil mustard
U238 51β79β6 Carbamic acid, ethyl ester
U238 51β79β6 Ethyl carbamate (urethane)
U239 1330β20β7
Benzene, dimethyl- (I,T)
U239 1330β20β7
Xylene (I)
U240 194β75β7 Acetic acid, (2,4-dichlorophenoxy)-, salts & esters
U240 194β75β7 2,4-D, salts & esters
U243 1888β71β7
Hexachloropropene
U243 1888β71β7
1-Propene, 1,1,2,3,3,3-hexachloro-
U244 137β26β8 Thioperoxydicarbonic diamide[(H2N)C(S)]2S2, tetramethyl-
U244 137β26β8 Thiram
83
U246 506β68β3 Cyanogen bromide (CN)Br
U247 72β43β5 Benzene, 1,1'-(2,2,2-trichloroethylidene)bis[4- methoxy-
U247 72β43β5 Methoxychlor
U248 181β81β2 2H-1-Benzopyran-2-one, 4-hydroxy-3-(3-oxo-1-phenyl-butyl)-, & salts, when present at concentrations of 0.3% or less
U248 181β81β2 Warfarin, & salts, when present at concentrations of 0.3% or less
U249 1314β84β7
Zinc phosphide Zn3P2, when present at concentrations of 10% or less
U271 17804β35β2
Benomyl
U271 17804β35β2
Carbamic acid, [1-[(butylamino)carbonyl]-1H-benzimidazol-2-yl]-, methyl ester
U278 22781β23β3
Bendiocarb
U278 22781β23β3
1,3-Benzodioxol-4-ol, 2,2-dimethyl-, methyl carbamate
U279 63β25β2 Carbaryl
U279 63β25β2 1-Naphthalenol, methylcarbamate
U280 101β27β9 Barban
U280 101β27β9 Carbamic acid, (3-chlorophenyl)-, 4-chloro-2-butynyl ester
U328 95β53β4 Benzenamine, 2-methyl-
U328 95β53β4 o-Toluidine
U353 106β49β0 Benzenamine, 4-methyl-
U353 106β49β0 p-Toluidine
U359 110β80β5 Ethanol, 2-ethoxy-
U359 110β80β5 Ethylene glycol monoethyl ether
U364 22961β82β6
Bendiocarb phenol
84
U364 22961β82β6
1,3-Benzodioxol-4-ol, 2,2-dimethyl-,
U367 1563β38β8
7-Benzofuranol, 2,3-dihydro-2,2-dimethyl-
U367 1563β38β8
Carbofuran phenol
U372 10605β21β7
Carbamic acid, 1H-benzimidazol-2-yl, methyl ester
U372 10605β21β7
Carbendazim
U373 122β42β9 Carbamic acid, phenyl-, 1-methylethyl ester
U373 122β42β9 Propham
U387 52888β80β9
Carbamothioic acid, dipropyl-, S-(phenylmethyl) ester
U387 52888β80β9
Prosulfocarb
U389 2303β17β5
Carbamothioic acid, bis(1-methylethyl)-, S-(2,3,3-trichloro-2-propenyl) ester
U389 2303β17β5
Triallate
U394 30558β43β1
A2213
U394 30558β43β1
Ethanimidothioic acid, 2-(dimethylamino)-N-hydroxy-2-oxo-, methyl ester
U395 5952β26β1
Diethylene glycol, dicarbamate
U395 5952β26β1
Ethanol, 2,2'-oxybis-, dicarbamate
U404 121β44β8 Ethanamine, N,N-diethyl-
U404 121β44β8 Triethylamine
U409 23564β05β8
Carbamic acid, [1,2-phenylenebis (iminocarbonothioyl)]bis-, dimethyl ester
U409 23564β05β8
Thiophanate-methyl
85
U410 59669β26β0
Ethanimidothioic acid, N,N'-[thiobis[(methylimino)carbonyloxy]]bis-, dimethyl ester
U410 59669β26β0
Thiodicarb
U411 114β26β1 Phenol, 2-(1-methylethoxy)-,methylcarbamate
U411 114β26β1 Propoxur
See F027 93β76β5 Acetic acid, (2,4,5-trichlorophenoxy)-
See F027 87β86β5 Pentachlorophenol
See F027 87β86β5 Phenol, pentachloro-
See F027 58β90β2 Phenol, 2,3,4,6-tetrachloro-
See F027 95β95β4 Phenol, 2,4,5-trichloro-
See F027 88β06β2 Phenol, 2,4,6-trichloro-
See F027 93β72β1 Propanoic acid, 2-(2,4,5-trichlorophenoxy)-
See F027 93β72β1 Silvex (2,4,5-TP)
See F027 93β76β5 2,4,5-T
See F027 58β90β2 2,3,4,6-Tetrachlorophenol
See F027 95β95β4 2,4,5-Trichlorophenol
See F027 88β06β2 2,4,6-Trichlorophenol 1CAS Number given for parent compound only.
86
APPENDIX D
RECORD OF HAZARDOUS WASTE ACCUMULATION
HW-03 (8/5/14)
Container Description:
DESCRIPTION OF WASTE ADDED AMOUNT INITIALS DATE ADDED
Special Notes or Handling Instructions:
RECORD OF HAZARDOUS WASTE ACCUMULATION
Instructions on reverse side.
HW-03 (8/5/14)
Guidelines for Chemical Waste Disposal
Preparing the Waste
1) Separate solids from liquids. All liquids must be free of solid material. If solids cannot be separated fromliquids the identification and quality of the solid must be listed on the βRequest for Disposalβ form. Everyeffort should be made to separate solids from liquids.
2) Waste Consolidation. Every effort must be made by the waste generator to consolidate same-type
waste into as few containers as possible.
3) Packaging the Waste. Make sure containers are compatible with the waste inside. If not, transfer to anew container. The container must be leak-free, have a tight screw cap, and be clean on the outside.
4) Label the Container. Make sure the containers are labeled with: (1) the words βHazardous Wasteβ; (2) acomplete list of contents; (3) the date that the container was filled or date of the βRequest for Disposalβ; (4)the volume or weight; (5) the department. The information on the label must agree with the information onthe βRequest for Disposalβ form.
5) Prepare Waste for Transport. The waste shall be transported in an EHS vehicle only.
Do not mix incompatible waste.
6) Fill Out the Request Form as Outlined on the Request for HazardousWaste Disposal Form.
Chemical Waste Disposal Golden Rules1) Provide a secondary container for waste collection containers.
2) Keep waste containers closed at all times except when adding or removing waste.
3) Position containers so that waste labels are visible (face forward).
4) Place supplied "Hazardous Waste"labels on all waste containers and indicate the contents andthe nature of the hazard.
5) Maintain ten percent free space in waste containers to allow for expansion.
Submit the completed Request for Hazardous Waste Dipsoal Form to EHS when the containers arefull (90%).
6)
7)
8)
9)
10) Use only collection containers that are capable of safely storing the waste and that are in good condition.
Conduct weekly inspections of hazardous waste collection area and maintain an inspection log.
Post the name and phone numbers for responsible person to contact 24 hours a day in case of an emergency.
Attend and document all annual training for all persons generating hazardous wastes.