proper testing of odorant levels 7-12 (2)2).pdfproper testing of odorant levels in natural gaslevels...
TRANSCRIPT
![Page 1: Proper Testing of Odorant Levels 7-12 (2)2).pdfProper Testing of Odorant Levels in Natural GasLevels in Natural Gas ... Natural Gas Odor Intensity ... MERCAPTAN / MERCAPTAN / SULFIDE](https://reader031.vdocuments.site/reader031/viewer/2022020120/5ae3a0817f8b9a0d7d8ddfd6/html5/thumbnails/1.jpg)
Proper Testing of Odorant Levels in Natural GasLevels in Natural Gas
IURC PIPELINE SAFETY SEMINARIURC PIPELINE SAFETY SEMINARJuly 14 2010
Drew YandoHeath Consultants
![Page 2: Proper Testing of Odorant Levels 7-12 (2)2).pdfProper Testing of Odorant Levels in Natural GasLevels in Natural Gas ... Natural Gas Odor Intensity ... MERCAPTAN / MERCAPTAN / SULFIDE](https://reader031.vdocuments.site/reader031/viewer/2022020120/5ae3a0817f8b9a0d7d8ddfd6/html5/thumbnails/2.jpg)
GPTC / DOT 192.625 (a)A combustible gas in a distributionline must contain a natural odorant orbe odorized so that at concentration inair of one-fifth of the lower explosiveplimit, the gas is readily detectable by aperson with a normal sense of smell.
![Page 3: Proper Testing of Odorant Levels 7-12 (2)2).pdfProper Testing of Odorant Levels in Natural GasLevels in Natural Gas ... Natural Gas Odor Intensity ... MERCAPTAN / MERCAPTAN / SULFIDE](https://reader031.vdocuments.site/reader031/viewer/2022020120/5ae3a0817f8b9a0d7d8ddfd6/html5/thumbnails/3.jpg)
FLAMMABLE FLAMMABLE RANGE –– NATURAL GASNATURAL GAS
![Page 4: Proper Testing of Odorant Levels 7-12 (2)2).pdfProper Testing of Odorant Levels in Natural GasLevels in Natural Gas ... Natural Gas Odor Intensity ... MERCAPTAN / MERCAPTAN / SULFIDE](https://reader031.vdocuments.site/reader031/viewer/2022020120/5ae3a0817f8b9a0d7d8ddfd6/html5/thumbnails/4.jpg)
DEFINITIONS
Readil ad erb in a read manner as A Readily – adverb, in a ready manner as A: willingly, B: speedily, C: easily.*
Detect or (adj ) Detectable 1 To Detect or (adj.) Detectable – 1. Todiscover the true, hidden, or disguisedcharacter of. 2. To discover or determinecharacter of. 2. To discover or determinethe existence, presence or fact of.*
* Webster 7th Collegiate Dictionary
![Page 5: Proper Testing of Odorant Levels 7-12 (2)2).pdfProper Testing of Odorant Levels in Natural GasLevels in Natural Gas ... Natural Gas Odor Intensity ... MERCAPTAN / MERCAPTAN / SULFIDE](https://reader031.vdocuments.site/reader031/viewer/2022020120/5ae3a0817f8b9a0d7d8ddfd6/html5/thumbnails/5.jpg)
GPTC / DOT 192.625 (f) (revised 10/15/03)
To assure the proper concentration ofodorant in accordance with this sectionodorant in accordance with this section,each operator must conduct periodicsampling of combustible gases using ansampling of combustible gases using aninstrument capable of determining thepercentage of gas in air at which the odorp g gbecomes readily detectable.
![Page 6: Proper Testing of Odorant Levels 7-12 (2)2).pdfProper Testing of Odorant Levels in Natural GasLevels in Natural Gas ... Natural Gas Odor Intensity ... MERCAPTAN / MERCAPTAN / SULFIDE](https://reader031.vdocuments.site/reader031/viewer/2022020120/5ae3a0817f8b9a0d7d8ddfd6/html5/thumbnails/6.jpg)
DEFINITIONS
Periodic – (adj) Occurring at regular intervals.*
Sufficient – Enough to meet the needs of a situation or a proposed end.*
Frequent – Common, usual, happening at short intervals, habitual, persistent.*
![Page 7: Proper Testing of Odorant Levels 7-12 (2)2).pdfProper Testing of Odorant Levels in Natural GasLevels in Natural Gas ... Natural Gas Odor Intensity ... MERCAPTAN / MERCAPTAN / SULFIDE](https://reader031.vdocuments.site/reader031/viewer/2022020120/5ae3a0817f8b9a0d7d8ddfd6/html5/thumbnails/7.jpg)
GPTC / DOT 192.625 (f) – Periodic Sampling ASTM D 6273.98 Standard Test Method for
Natural Gas Odor IntensityThese test methods co er the proced res for- These test methods cover the procedures for determining the ODOR intensity of natural gas through the use of instruments that dilute and mix sampled natural gas with air. The mixed gas stream is sniffed by the operator for the purpose of determining the threshold detection level or theof determining the threshold detection level or the readily detection level, or both, for Odorant in the natural gas stream.
![Page 8: Proper Testing of Odorant Levels 7-12 (2)2).pdfProper Testing of Odorant Levels in Natural GasLevels in Natural Gas ... Natural Gas Odor Intensity ... MERCAPTAN / MERCAPTAN / SULFIDE](https://reader031.vdocuments.site/reader031/viewer/2022020120/5ae3a0817f8b9a0d7d8ddfd6/html5/thumbnails/8.jpg)
DEFINITIONS
Readily Detectable Level:Readily Detectable Level:The concentration of natural gas and odorant mixture in air which the operator is pable to detect and identify natural gas odor.
Threshold Detection Level:Threshold Detection Level:The concentration of natural gas and odorant mixture in air which the operator is barely able to detect an odor.
* Webster 7th Collegiate Dictionary
![Page 9: Proper Testing of Odorant Levels 7-12 (2)2).pdfProper Testing of Odorant Levels in Natural GasLevels in Natural Gas ... Natural Gas Odor Intensity ... MERCAPTAN / MERCAPTAN / SULFIDE](https://reader031.vdocuments.site/reader031/viewer/2022020120/5ae3a0817f8b9a0d7d8ddfd6/html5/thumbnails/9.jpg)
REMEMBER! Odor is for the Customer’s Use Only. Odorization is the Customer’s Leak Odorization is the Customer s Leak
Detector. It is their Lifeline to Safety!y
![Page 10: Proper Testing of Odorant Levels 7-12 (2)2).pdfProper Testing of Odorant Levels in Natural GasLevels in Natural Gas ... Natural Gas Odor Intensity ... MERCAPTAN / MERCAPTAN / SULFIDE](https://reader031.vdocuments.site/reader031/viewer/2022020120/5ae3a0817f8b9a0d7d8ddfd6/html5/thumbnails/10.jpg)
HEATH ODORATORHEATH ODORATOR
![Page 11: Proper Testing of Odorant Levels 7-12 (2)2).pdfProper Testing of Odorant Levels in Natural GasLevels in Natural Gas ... Natural Gas Odor Intensity ... MERCAPTAN / MERCAPTAN / SULFIDE](https://reader031.vdocuments.site/reader031/viewer/2022020120/5ae3a0817f8b9a0d7d8ddfd6/html5/thumbnails/11.jpg)
HEATH ODORATORHEATH ODORATOR
![Page 12: Proper Testing of Odorant Levels 7-12 (2)2).pdfProper Testing of Odorant Levels in Natural GasLevels in Natural Gas ... Natural Gas Odor Intensity ... MERCAPTAN / MERCAPTAN / SULFIDE](https://reader031.vdocuments.site/reader031/viewer/2022020120/5ae3a0817f8b9a0d7d8ddfd6/html5/thumbnails/12.jpg)
BACHARACH ODOROMETERBACHARACH ODOROMETER
![Page 13: Proper Testing of Odorant Levels 7-12 (2)2).pdfProper Testing of Odorant Levels in Natural GasLevels in Natural Gas ... Natural Gas Odor Intensity ... MERCAPTAN / MERCAPTAN / SULFIDE](https://reader031.vdocuments.site/reader031/viewer/2022020120/5ae3a0817f8b9a0d7d8ddfd6/html5/thumbnails/13.jpg)
YZ SYSTEMS-DTEX
![Page 14: Proper Testing of Odorant Levels 7-12 (2)2).pdfProper Testing of Odorant Levels in Natural GasLevels in Natural Gas ... Natural Gas Odor Intensity ... MERCAPTAN / MERCAPTAN / SULFIDE](https://reader031.vdocuments.site/reader031/viewer/2022020120/5ae3a0817f8b9a0d7d8ddfd6/html5/thumbnails/14.jpg)
FACTORS WHICH AFFECT ODOR QUANTITY
Odorizer Shut-down Contaminants in Odorizer Natural Occurring Sulfurs Distillates in Pipelinep Pipe wall Adsorption Oxidation in Pipeline Oxidation in Pipeline
![Page 15: Proper Testing of Odorant Levels 7-12 (2)2).pdfProper Testing of Odorant Levels in Natural GasLevels in Natural Gas ... Natural Gas Odor Intensity ... MERCAPTAN / MERCAPTAN / SULFIDE](https://reader031.vdocuments.site/reader031/viewer/2022020120/5ae3a0817f8b9a0d7d8ddfd6/html5/thumbnails/15.jpg)
FACTORS WHICH AFFECTODOR QUALITY
Physical Ailments Soil Adsorption Masking Masking Distraction
![Page 16: Proper Testing of Odorant Levels 7-12 (2)2).pdfProper Testing of Odorant Levels in Natural GasLevels in Natural Gas ... Natural Gas Odor Intensity ... MERCAPTAN / MERCAPTAN / SULFIDE](https://reader031.vdocuments.site/reader031/viewer/2022020120/5ae3a0817f8b9a0d7d8ddfd6/html5/thumbnails/16.jpg)
METHODS TO VERIFY ODOR QUALITY DOCUMENTATION OF ODORIZATION
Injection Rates Odorizer Inspections Customer Complaints Callsp Serviceman Tests Odor Concentration Meter Tests Odor Concentration Meter Tests Chromatographic Analysis
![Page 17: Proper Testing of Odorant Levels 7-12 (2)2).pdfProper Testing of Odorant Levels in Natural GasLevels in Natural Gas ... Natural Gas Odor Intensity ... MERCAPTAN / MERCAPTAN / SULFIDE](https://reader031.vdocuments.site/reader031/viewer/2022020120/5ae3a0817f8b9a0d7d8ddfd6/html5/thumbnails/17.jpg)
CHROMATOGRAPH TECHNOLOGIES
Lead Acetate Chemiluminescence's Flame Photometric Infrared Electrochemical
![Page 18: Proper Testing of Odorant Levels 7-12 (2)2).pdfProper Testing of Odorant Levels in Natural GasLevels in Natural Gas ... Natural Gas Odor Intensity ... MERCAPTAN / MERCAPTAN / SULFIDE](https://reader031.vdocuments.site/reader031/viewer/2022020120/5ae3a0817f8b9a0d7d8ddfd6/html5/thumbnails/18.jpg)
CHROMATOGRAPH
![Page 19: Proper Testing of Odorant Levels 7-12 (2)2).pdfProper Testing of Odorant Levels in Natural GasLevels in Natural Gas ... Natural Gas Odor Intensity ... MERCAPTAN / MERCAPTAN / SULFIDE](https://reader031.vdocuments.site/reader031/viewer/2022020120/5ae3a0817f8b9a0d7d8ddfd6/html5/thumbnails/19.jpg)
MERCAPTAN / MERCAPTAN / SULFIDE COMPONENTSCOMPONENTS
EM Eth l M t 1 08
ABBR NAME W
EM Ethyl Mercaptan 1.08DMS Dimethyl Sulfide 1.00IPM ISO Propyl Mercaptan 0.88MES Methyl Ethyl Sulfide 0.66NPM Normal Propyl Mercaptan 0.85TBM Tertiary Butyl Mercaptan 1.00 (REF)TBM Tertiary Butyl Mercaptan 1.00 (REF)SBM Secondary Butyl Mercaptan 1.99DES Diethyl Sulfide 0.22
THT Thiophane 1 63THT Thiophane 1.63EIS Ethyl Isoprpoyl Sulfide 0.07
Compare with H2S at W = 0.08
![Page 20: Proper Testing of Odorant Levels 7-12 (2)2).pdfProper Testing of Odorant Levels in Natural GasLevels in Natural Gas ... Natural Gas Odor Intensity ... MERCAPTAN / MERCAPTAN / SULFIDE](https://reader031.vdocuments.site/reader031/viewer/2022020120/5ae3a0817f8b9a0d7d8ddfd6/html5/thumbnails/20.jpg)
CHROMATOGRAPHS
![Page 21: Proper Testing of Odorant Levels 7-12 (2)2).pdfProper Testing of Odorant Levels in Natural GasLevels in Natural Gas ... Natural Gas Odor Intensity ... MERCAPTAN / MERCAPTAN / SULFIDE](https://reader031.vdocuments.site/reader031/viewer/2022020120/5ae3a0817f8b9a0d7d8ddfd6/html5/thumbnails/21.jpg)
CHROMATOGRAPHSCHROMATOGRAPHS
![Page 22: Proper Testing of Odorant Levels 7-12 (2)2).pdfProper Testing of Odorant Levels in Natural GasLevels in Natural Gas ... Natural Gas Odor Intensity ... MERCAPTAN / MERCAPTAN / SULFIDE](https://reader031.vdocuments.site/reader031/viewer/2022020120/5ae3a0817f8b9a0d7d8ddfd6/html5/thumbnails/22.jpg)
CONCLUSIONCONCLUSION Overall:
– Make sure you understand your instrument Read the manual Read the manual Get training – manufacturers rep, gas
company, personnel Keep all records – calibration test etc Keep all records – calibration, test, etc.
The PUC will check.– Understand rules and regulations– Be aware of your surroundings