prof. rafael luque - uestuest.ntua.gr/iwwatv/proceedings/presentations/21... · mechanochemistry...
TRANSCRIPT
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Possibilities for Waste valorisation: the
concept of modular biorefineries
Prof. Rafael Luque
DEPARTAMENTO DE QUÍMICA ORGÁNICA,
UNIVERSIDAD DE CÓRDOBA
http://www.uco.es/~q62alsor/
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Produce Use Dispose
ITS ALWAYS THE SAME THING………
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Produce Use Dispose
Reduce
Re-use
Recycle
Something wrong with this?
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What do we do?
Heterogeneous catalysis
(acid-base, redox, C-C y
C-heteroatom couplings)
Microwave assisted
catalysis
Flow Chemistry
Supramolecular gels
Nanomaterials
Supported nanoparticles
Microwave nanocatalysis
Mechanochemistry (milling)
Transformations of
platform molecules
Biomass valorisation
Biofuels production
Waste valorisation
(biorefineries)
Group leader: Alina M. Balu
Group Leader:
Weiyi Ouyang
Group Leader:
Sudipta De
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Feedstock(s)
biological raw materials
Environmentally benign
Processing Technologies
Food, chemical products and
energy
• Food and feed grain
• Ligno-cellulosic biomass
• Waste
• Green Chemical Processes
• Bio-processes
• Thermal processes
• Physical processes
Integrated facilities that can convert a variety of bio-feedstocks into energy,
chemicals and other valuable materials cleanly and efficiently maximising
the value of the biomass and minimizing waste
BIOREFINERIES
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WASTE TO WEALTH: FROM RESIDUES TO MARKETABLE PRODUCTS
Paint additives Biodegradable plastics
Personal care products
Coatings and unguents Other derivatives (chemicals, fuels, etc.)
Green technologies (e.g. microwaves, extraction, fractionation)
http://www.cbme.ust.hk/rafaluque.html
http://images.google.co.uk/imgres?imgurl=www.ethnicbeauty.co.uk/living_nature/images/wavelips.jpg&imgrefurl=http://www.ethnicbeauty.co.uk/living_nature/ls9.htm&h=375&w=375&sz=11&tbnid=f-yhb_OVHUwJ:&tbnh=118&tbnw=118&prev=/images?q=carnauba&start=40&hl=en&lr=&ie=UTF-8&oe=UTF-8&sa=N
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Biorefinery: The big picture
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HEMICELLULOSE
LIGNIN CELLULOSE
MINOR CONSTITUENTS
Knowing chemical composition is the
key to success!!!
Lignocellulosics
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ChemSocRev 2011
Green Chem 2014
ChemSocRev 2014
FUELS
CHEMICALS
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Wheat
BioreactionDownstream processing Succinic
acid
Derivatives
Upstream processing
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Succinic acid as a C4 building block
HO
OH
H2N
NH2
O
O
H2N
NH2
NC
CN
O
O
O
O
H3C
CH3
O
OO
NO
H
NO
CH3
HO
OH
O
O Succinic acid
Tetrahydrofuran (THF)
2-Pyrrolidone
N-Methyl-2-Pyrrolidone
(NMP)
Succinonitrile
1,4-Diaminobutane
Succindiamide
1,4-Butanediol
(BDO)γ-Butyrolactone
(GBL)
Dimethyl succinate
(DBE)
4,4-Bionolle
(polyester)
Applications: solvents, adhesives, printing inks, magnetic tapes, coating resins, plasticizer/emulsifier,
de-icing compounds, herbicide ingredient, chemical and pharmaceutical intermediates
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properties
applications
Ability to functionalise
i.e. acid, basic, metallic
Different forms including
particles & monoliths
Range of composites
High to low conductivity
Fuel cells
adsorbency
catalysis
Water purification
chromatography
Higher temperature materials stable
to hot water & organic solvents
High mesoporosity, surface areas
and surface energies
From Starch to Starbon®
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With the mighty team
at York (UK)
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Extraction of Phytosterols
(cholesterol-reducing agents)
Biores. Technol. 2012, Carb. Polym. 2013; Green Chem 2013; JMaterChem B 2014; Nature Commun. 20155
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BIOMASS VALORISATION (II)… with
INCAR (Oviedo) MIP concept
RSC Adv. 2014
Gracillaria gracilis
Table 1. Biochemical composition (% d.w.) of Gracilaria
gracilis sampled in the Lesina lagoon (Italy).
Total Lipids 1.98
Fatty Acids Methyl Esters 0.47
Proteins 30.93
Carbohydrates 27.54
Ashes 27.89
(EES 2012)
http://www.cbme.ust.hk/rafaluque.html
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http://www.uco.es/~q62alsor/
Green Chem. 2011, 13, 3162
FOOD WASTE VALORISATION (I)… with Rick
Arancon (Ateneo Uni)
2 FOOD WASTE RESIDUES:
CORNCOBS, WASTE BREAD, OTHERS
+
WASTE COOKING OILS
2 VALUABLE PRODUCTS:
CARBONACEOUS MATERIAL (CATALYST)
+
BIODIESEL
Gasification
residue
J. Natural Gas Chem.
2012, 21, 246
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http://www.uco.es/~q62alsor/
Materials 2013, 6, 1599
Materials 2013, 6, 4641
FOOD WASTE VALORISATION (II)… with
Jaume Cot (IQAC)
FROM SLAUGHTER WASTE TO BIO-HEALING NATURAL POLYMERS (BIO-COLLAGEN)
TREATMENT OF WOUND HEALING IN RATS
Green Chem. 2012, 14, 308
PCT Patent 2013
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http://www.uco.es/~q62alsor/
Porous materials
FOOD WASTE VALORISATION (III):
Microwave-assisted
extraction:
-simple
-rapid (5-10 min)
-efficient
Unique form of
mesoporous
cellulose
ChemSusChem, 2012; Energy Env. Sci. 2013
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ChemSusChem 2013
Green Chem. 2013
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Conclusions
Biomaterials Speciality chemicals
CHEMICAL INDUSTRIAL
PRODUCTS
MATERIALS, CHEMICALS &
FUELS
Biopolymers
Platform molecules
BIOMASS &
WASTE
Commodity chemicals
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T. U. Gerngross, Nature Biotechnology, 17, (1999), 541 - 544
Some food for thought….
• The synthesis of 1 kg of
polystyrene requires a total of 2.26
kg of fossil oil (1 kg to generate
electricity and 1.26 kg to serve as
feedstocks for polymer production).
• The production of 1 kg of PHAs
requires 2.39 kg of fossil resources.
Simply deriving chemical
products from renewable
resources is NOT ENOUGH!
Real environmental benefit?
Biodegradability?
Toxicity?
SAFETY!!!
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Many thanks for your attention!!