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Aftertreatment system selection
The problematic emissions from combustion
in Diesel engines are nitrogen oxides [NOX]
and particulate or soot [PM].To reduce these
emissions two types of emission
aftertreatment devices are used:
• Diesel Particulate Filter to trap the PM,
DPF
• Selective Catalytic Reduction to reduce
the NOX, SCR.
The scoped legislations are MARPOL VI
[TIER III] for coasters and sea going vessels,
and Stage 4 for inland shipping in Europe and
EPA TIER 4 for the inland vessels in U.S.A..
To fulfill MARPOL [TIER III], NOX must be
reduced between 60 and 90%.
This can be achieved by the Multronic SCR
and SCR+’ systems.
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0,050
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0,500
0,0
1,0
2,0
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5,0
6,0
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8,0
9,0
PM
g/k
Wh
NOX g/kWh
Mechanical injection Electronic injection
Ultra modern common rail
D
P
F
SCR
Aftertreatment system selection
To fulfill Stage IV/V and EPA TIER 4 both NOX and
PM must be reduced between 60 and 90%.
This can be achieved by the Multronic EEV and
SCRonDPF systems.
For the marine market, Multronic has developed
dedicated emission systems:
• specific catalytic coatings to be durable with
the different fuels present
• specific heat management and regeneration
technologies for applications like propulsion,
diesel electric and power generation
• designs with low pressure drop, short mixing
distances and airless urea dosing.
• protection methods to allow the usage of
automotive sensors and components in harsh
environments with low fuel qualities.
0
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4
6
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16
0 250 500 750 1000 1250 1500 1750 2000
NO
X g
/kW
h
RPM
IMO Tier I IMO Tier II IMO (MARPOL 6) Tier III
Marine Diesel engines
Name Low speed Medium Speed High Speed
Displacement (l/cyl) 200 - 2000 16-120 5 - 16 0,8 - 3 < 0,8
Power range (kW) 4000 – 100000 800 - 40000 kW Up to 10000 kW Up to 800 kW Up to 300 kW
Combustion type 2-stroke & 4 stroke 2-stroke & 4 stroke 2-stroke & 4 stroke 4 stroke 4 stroke
Rotation speed (rpm) 70-300 350 - 850 600 - 2200 600 - 3000 >3000
The marine market is characterized by an enormous variety of engines and power ranges. Each type, application
must fulfill different emission requirements.
Multronic scope
Large cargo vessels, use low speed diesel engines, 2 and 4
stroke, and are powered by heavy fuel oil due to its low cost. This
fuel contains high sulphur levels, phosphor and ash. All the
components of the emission system, catalysts, sensors and
actuator package must be selected specifically for this fuel.
Inland vessels, coasters and luxury yachts have access to good
quality fuels, use mainly medium and high speed diesel engines
and have a load profile allowing the use of high efficient
aftertreatment technology similar to onroad heavy duty emission
systems..
Emission systems for ships
DOC and Open DPF systems for
propulsion engines For some applicationans a DOC or open DPF systems can be sufficient to reduce PM. The cost is low, the
installation is easy and there is no maintenance. Lowest cost of operation.
0
20
40
60
80
100
CO HC PM NOX
OE DOC Open DPF2
Engin
e
DO
C/D
EC
T
U
R
B
O
Engin
e
Open,DPF
T
U
R
B
O
DPF systems for propulsion engines
Nevertheless Multronic equips all the DPF systems with
a back-up active regeneration system, Diesel Hydro
Carbon Post Injection (DHCPI). In case of long periods
of low engine load, the temperature of the exhaust gas
is raised by the injection of fuel over the catalyst.
The main advantages of the DHCPI system compared
to a burner are:
• very large operational window
• Independent from the engine load
• fuel efficient temperature raise
• stepless temperature regulation
• no air injection needed
Engin
e
DPF
Temp 1 Temp 3
DO
C/D
EC
Diesel
injecton
T
U
R
B
O
Temp 2 Press 1
Driven by local rules, environmental
conscience, ship-owners or transport
companies equip the propulsion engines of
their vessels with DPF systems.
The soot is trapped in the filter and is
oxidised by means of a catalytic reaction
that takes place between 280 and 420°C.
Under normal operation this is the
temperature present after the turbocharger
in the exhaust stack.
0
20
40
60
80
100
CO HC PM NOX NO NO2
OE DPF
DPF systems for generators
The main driver to install DPF’s on ships is to
avoid deposits of soot on the water around the
ship, the hull and on the deck.
The engines responsible for these practical
problems are mainly the auxiliary engines used
for the generators.
Multronic has developed the E-DPF for a
durable solution on generators. The DPF
regenerates passively when the engine is
loaded above 50%.
Engin
e
DPF
Temp 3 Press 1 Temp 2
Heate
r
T
U
R
B
O
Generator
Temp 1
Engin
e
DPF
DO
C/D
EC
T
U
R
B
O
Generator
Temp 1 Temp 4
Hea
ter
Diesel
injecton
Temp 3 Temp 2 Press 1
Under low load conditions the exhaust gas
temperature is artificially raised to oxidise the
trapped soot.
The electrical heater can be combined with a
diesel oxidation catalyst and diesel post injection
(DHCPI) to speed up the regeneration and
enlarge the operational window of the system.
The coating on both the DPF and DOC can be
chosen in function of the fuel quality.
Multronic recommend the use of fuel with a
maximum of 1000PPM sulphur.
SCR systems for propulsion engines
Engin
e
SCR
Temp 2
Urea
dosing
T
U
R
B
O
Temp 1 Press 1
Emission legislation for marine
engines focuses mainly on Nitrogen
oxide reduction.
One of the most effective methods to
reduce NOX is SCR, Selective
Catalytic Reduction.
Adblue / DEF, an aqueous urea
solution is injected in the exhaust gas
upstream of the SCR catalyst.
The urea is transformed into ammonia
and In the catalyst the ammonia reacts
with the NOX and is reduced to
nitrogen and water.
Standard SCR system
0
20
40
60
80
100
CO HC PM NOX NO NO2
OE SCR
SCR+ systems for propulsion engines
Optional
Optional
Engin
e
AdBlue
injection
SCR
Hydro
Cat.
Temp
1
Temp
3
Temp
4
Press
1
NOX
DO
C/D
EC
Diesel
injecton
Temp
2
Mixer Mixer
AS
C
To increase the efficiency of the SCR (SCR+ system) additional catalysts
can be added to the system. A hydrolysing catalyst can help to form the
ammonia at lower temperature, an ammonia slip catalyst can remove
excessive ammonia that can slip through the system when high
efficiencies are needed and an upstream diesel oxidation catalyst
balances the relation between NO and NO2 to improve the system
efficiency and urea consumption. A DOC can also be used, when
needed, for crystal removal within the SCR system.
SCR + system
0 20 40 60 80 100
CO
HC
PM
NOX
NO
NO2
SCR+ OE
Option 1 : Multronic EEV :DPF + SCR E
ng
ine
C/DPF D
OC
/ D
EC
SCR
AS
C
AdBlue
injecton
Hyd
ro C
at.
Temp 1 Temp 3 Temp 4 Temp 2 Temp 5 Press 1 Press /
Ref 2
NOX
Diesel
injecton
Mixer Mixer
To achieve Stage IV/V and EPA TIER 4 both NOX and PM
must be reduced between 60 and 90%. This can be
achieved with the Multronic EEV and SCRonDPF
solutions.
The Multronic EEV is a combination of 2 Multronic
systems, the DHCPI particle filter and the Multronic SCR+.
The efficiency of the system exceeds 90 % for the full
range of emissions.
0
20
40
60
80
100
CO HC PM NOX NO NO2
OE SCR
Option 2 : SCRonDPF
En
gin
e
AdBlue
injecton
SCRonDPF
Temp 1 Temp 3 Temp 4 Press 1 NOX
DO
C/D
EC
Diesel
injecton
Temp 2
Mixer Mixer
AS
C
En
gin
e
C/DPF D
OC
/ D
EC
SCR
AS
C
AdBlue
injecton
Temp 1 Temp 3 Temp 4 Temp 2 Temp 5 Press 1 Press /
Ref 2
NOX
Diesel
injecton
Mixer Mixer
System layout : combined DPF & SCR
Option 1
DPF => SCR
Option 2
SCR => DPF
Option 3
SCRonDPF
DPF regeneration via NO2 / fuel penalty for
regeneration ++ - +
N° of substrates* *(without hydrolysing catalyst and with end-zone coating for
ASC when applicable)
3 4 2
Total substrate volume / compactness of the
system
Medium
volume
Highest
volume
Lowest
volume
Passive & active heat management / fuel penalty High thermal
inertia
High thermal
inertia
Low thermal
inertia
Complexity of the temperature management High High Medium
N° of cans
N° of temperature sensors
3 cans
minimum
4 (optional 5)
4 cans
minimum
4 (optional 5)
2 cans
minimum
3 (optional 4)
Integration / geometrical freedom
Installation - + ++
Marine specific Low SV – Low Pressure drop
requirement - - +
To reduce the size of the
system Multronic has
developed solutions to
integrate the DPF and
the SCR into the same
substrate.
The results is the SCR
on DPF.
The product was
selected by the Dutch
government in 2011 as
the best potential solution
to reduce emissions from
inland vessels.
This resulted in 2
validation programs, one
on a barge and one on a
patrol vessel.
Validation of SCRonDPF on two ships
Barge
This is considered as a normal
application
Engine: Scania V8 16 liter 450 kW
Police Patrol ship
Considered as a worst case
scenario
Engine : 2 x MTU V2000-01 600 kW
SCR
T1
NOX2
(Post)
NOX1
(Pre) RPM MAP
Urea
Press
1
Urea
Level
Urea
quality
(option
)
SCR
T2
Urea
Temp
1
Urea
Pump
(1)
cont.
CAN
OBD
Line
Heat
Cool.
valve
Inj 1
Master Slave
Inj 2
Inj 3
Inj 4
Inj 5
Inj 6
Urea
Pump
(2)
Cont.
Urea
Press
2
Urea
Temp
2
NOX2
Protect
Air
NOX1
Protect
Air
NOX2
Calib
Gas
NOX1
Calib.
Gas
Urea dosing multi nozzle