pro ii simulation output file for column

P:\2014-15\0603 - Rubamin Tail Scrubber System\Process\Working\Calculations\Flue Gas Composition.out 13 June 2014 15:36

$ Generated by PRO/II Keyword Generation System $ Generated on: Fri Jun 13 15:35:07 2014TITLE DIMENSION METRIC, STDTEMP=15.6 SEQUENCE SIMSCI CALCULATION TVPBASIS=37.7778, RVPBASIS=APINCOMPONENT DATA LIBID 1,CO2/2,NITROGEN/3,OXYGEN/4,H2O, BANK=PROCESS ASSAY FIT=ALTERNATE, CONVERSION=API94, CURVEFIT=CURRENT, & KVRECONCILE=TAILS, FORMATION=CURRENTTHERMODYNAMIC DATA METHOD SYSTEM=IDEAL, ENTROPY(L)=SRK, ENTROPY(V)=SRK, SET=IDEA01, & DEFAULTSTREAM DATA PROPERTY STREAM=S1, TEMPERATURE=2067, PRESSURE=1.028, PHASE=M, & COMPOSITION(M,KGM/H)=1,1.921/2,14.023/4,3.614, SET=IDEA01 PROPERTY STREAM=S2, TEMPERATURE=35, PRESSURE=1.033, PHASE=M, & RATE(M)=16.28, COMPOSITION(M)=2,0.79/ & 3,0.21, NORMALIZE, SET=IDEA01 PROPERTY STREAM=S5, TEMPERATURE=35, PRESSURE=2, PHASE=M, & RATE(LV)=0.6, COMPOSITION(M)=4,1, SET=IDEA01 PROPERTY STREAM=S9, TEMPERATURE=1200, PRESSURE=1.028, PHASE=M, & COMPOSITION(WT,KG/H)=4,200, SET=IDEA01 PROPERTY STREAM=S11, TEMPERATURE=35, PRESSURE=1.033, PHASE=M, & RATE(M)=87.96, COMPOSITION(M)=2,0.79/3,0.21, SET=IDEA01 PROPERTY STREAM=S13, TEMPERATURE=40, PRESSURE=4.5332, PHASE=M, & COMPOSITION(LV,M3/H)=4,30, SET=IDEA01 OUTPUT FORMAT=Flue Gas, STREAMS=S1,S2,S3,S9,S10,S11,S12,S4,S6,S16, & S14, SPTPRINT=ON FORMAT IDNO=Flue Gas,SID,NAME,DOUBLINE,PHASE,LINE,TEXT,LINE,RATE( & M),RATE(WT),TEMP,PRESSURE,MW,HTOTAL,LINE,TEXT,LINE,VAPOR, & RATE(M),RATE(WT),DENSITY(KG/M3),ARATE,SRATE(GV),MW,ZKVA, & ENTHALPY(KCAL/KG),TOTAL,CFRAC(M),CRATE(M),CFRAC(WT),CRATE(WT)UNIT OPERATIONS MIXER UID=M1 FEED S1,S2 PRODUCT M=S3 MIXER UID=M2 FEED S3,S9 PRODUCT M=S10 MIXER UID=M3 FEED S11,S10 PRODUCT M=S12 HX UID=E1 HOT FEED=S12, M=S4 OPER HTEMP=350 FLASH UID=F1 FEED S5,S4 PRODUCT V=S6, L=S7, W=S8 ISO TEMPERATURE=85, PRESSURE=1.0212 COMPRESSOR UID=C1 FEED S6 PRODUCT V=S16 OPERATION CALCULATION=ASME, COPT=SING, PRES=1.0502, & POLYTROPIC=70 METHOD SET=IDEA01 COLUMN UID=T1

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PARAMETER TRAY=10,IO FEED S16,10/S13,1 PRODUCT OVHD(M)=S14,168.158, BTMS(M)=S15 PSPEC PTOP=1.0402, DPTRAY=0.00049951 PRINT COMPOSITION=M,WT, PROPTABLE=PART, SUMMARY=WT, TLOADING PACK SECTION(COLSECT-1)=1,10, TYPE=5, SIZE=88.9, & HMETHOD=NORTON, DPPACK=0.0024975 METHOD SET=IDEA01ENDFF SIMULATION SCIENCES INC. R PAGE R-1 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM INPUT THERMODYNAMIC DATA ==============================================================================

THERMODYNAMIC SETS USED FOR EACH UNIT OPERATION

DEFAULT METHOD IS IDEA01

THERMODYNAMIC SET UNIT OPERATIONS ----------------- --------------- IDEA01 M1, E1, F1, M2, M3, T1, C1

UNIT IDENTIFIER UNIT OPERATION THERMODYNAMIC SET --------------- -------------- ----------------- M1 MIXER IDEA01 E1 HEAT EXCHANGER IDEA01, IDEA01 F1 FLASH DRUM IDEA01 M2 MIXER IDEA01 M3 MIXER IDEA01 T1 COLUMN IDEA01 C1 COMPRESSOR IDEA01FF SIMULATION SCIENCES INC. R PAGE R-2 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM INPUT THERMODYNAMIC DATA ==============================================================================

THERMODYNAMIC METHODS USED FOR EACH SET

THERMODYNAMIC SET IDEA01 (DEFAULT)

PROPERTY METHOD -------- ------ KVALUE(VLE) IDEAL KVALUE(LLE) UNSPECIFIED KVALUE(SLE) UNSPECIFIED LIQUID ENTHALPY IDEAL VAPOR ENTHALPY IDEAL LIQUID DENSITY IDEAL VAPOR DENSITY IDEAL LIQUID ENTROPY SOAVE-REDLICH-KWONG VAPOR ENTROPY SOAVE-REDLICH-KWONG LIQUID VISCOSITY IDEAL VAPOR VISCOSITY IDEAL

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LIQUID CONDUCTIVITY IDEAL VAPOR CONDUCTIVITY IDEAL SURFACE TENSION IDEAL FUGACITY IDEAL HENRY UNSPECIFIED LIQUID DIFFUSIVITY UNSPECIFIEDFF SIMULATION SCIENCES INC. R PAGE H-1 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM CALCULATION HISTORY 06/13/14 ==============================================================================

*** PROBLEM SOLUTION BEGINS ** WARNING ** The liquid enthalpy of CO2 at temperature 2340.1 K is outside the acceptable range of -50 K through 31.02 K. ** WARNING ** The liquid enthalpy of NITROGEN at temperature 2340.1 K is outside the acceptable range of -210 K through -146.92 K. ** WARNING ** The liquid enthalpy of H2O at temperature 2340.1 K is outside the acceptable range of -50 K through 374.18 K. ** WARNING ** The liquid enthalpy of OXYGEN at temperature 308.15 K is outside the acceptable range of -220 K through -118.42 K. FEED FLASH COMPLETE UNIT 1 SOLVED - 'M1 ' UNIT 4 SOLVED - 'M2 ' UNIT 5 SOLVED - 'M3 ' UNIT 2 SOLVED - 'E1 ' UNIT 3 SOLVED - 'F1 ' UNIT 7 SOLVED - 'C1 ' ** WARNING ** PRESSURE of feed STREAM 35, 'S16' = 1.0502 is LESS THAN the feed TRAY PRESSURE of 1.0533 on tray 10. INNER 0 : E(ENTH+SPEC) = 1.622E-02 CALCULATING NEW MATRIX INNER 1 : E(ENTH+SPEC) = 1.598E-02 ALPHA = 0.0226 INNER 2 : E(ENTH+SPEC) = 1.596E-02 ALPHA = 0.0050 INNER 3 : E(ENTH+SPEC) = 1.595E-02 ALPHA = 0.0041 INNER 4 : E(ENTH+SPEC) = 1.594E-02 ALPHA = 0.0043 INNER 5 : E(ENTH+SPEC) = 1.594E-02 ALPHA = 0.0044 ITER 1 E(K) = 1.634E-01 E(ENTH+SPEC) = 1.594E-02 E(SUM) = 1.691E+00 DAMP = 1.000E+00 INNER 0 : E(ENTH+SPEC) = 1.529E-02 INNER 1 : E(ENTH+SPEC) = 1.526E-02 ALPHA = 0.0044 INNER 2 : E(ENTH+SPEC) = 1.525E-02 ALPHA = 0.0012 INNER 3 : E(ENTH+SPEC) = 1.524E-02 ALPHA = 0.0053 INNER 4 : E(ENTH+SPEC) = 1.524E-02 ALPHA = 0.0055 CALCULATING NEW MATRIX INNER 1 : E(ENTH+SPEC) = 1.519E-02 ALPHA = 0.0061 INNER 2 : E(ENTH+SPEC) = 1.517E-02 ALPHA = 0.0064 INNER 3 : E(ENTH+SPEC) = 1.515E-02 ALPHA = 0.0071 INNER 4 : E(ENTH+SPEC) = 1.511E-02 ALPHA = 0.0081 CALCULATING NEW MATRIX INNER 1 : E(ENTH+SPEC) = 1.512E-02 ALPHA = 0.0373 INNER 2 : E(ENTH+SPEC) = 1.509E-02 ALPHA = 0.0117 INNER 3 : E(ENTH+SPEC) = 1.476E-02 ALPHA = 0.0604 INNER 4 : E(ENTH+SPEC) = 1.459E-02 ALPHA = 0.0625 INNER 5 : E(ENTH+SPEC) = 1.349E-02 ALPHA = 0.2500 INNER 6 : E(ENTH+SPEC) = 1.256E-02 ALPHA = 1.0000

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INNER 7 : E(ENTH+SPEC) = 6.102E-03 ALPHA = 1.0000 INNER 8 : E(ENTH+SPEC) = 3.054E-03 ALPHA = 1.0000 INNER 9 : E(ENTH+SPEC) = 1.420E-03 ALPHA = 1.0000 INNER 10 : E(ENTH+SPEC) = 2.760E-04 ALPHA = 1.0000 ITER 2 E(K) = 9.487E-01 E(ENTH+SPEC) = 2.760E-04 E(SUM) = 1.297E+01 TRAY PACKING PRESSURE DROP CORRELATION APPLIED ** WARNING ** PRESSURE of feed STREAM 35, 'S16' = 1.0502 is LESS THAN the feed TRAY PRESSURE of 1.0531 on tray 10. DAMP = 1.000E+00 INNER 0 : E(ENTH+SPEC) = 1.461E-03FF SIMULATION SCIENCES INC. R PAGE H-2 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM CALCULATION HISTORY 06/13/14 ==============================================================================

INNER 1 : E(ENTH+SPEC) = 1.003E-03 ALPHA = 0.2500 INNER 2 : E(ENTH+SPEC) = 5.943E-04 ALPHA = 0.2500 INNER 3 : E(ENTH+SPEC) = 3.329E-04 ALPHA = 0.2500 INNER 4 : E(ENTH+SPEC) = 1.785E-04 ALPHA = 0.2500 INNER 5 : E(ENTH+SPEC) = 1.367E-04 ALPHA = 0.2500 INNER 6 : E(ENTH+SPEC) = 1.100E-04 ALPHA = 0.2500 INNER 7 : E(ENTH+SPEC) = 8.020E-05 ALPHA = 0.2500 INNER 8 : E(ENTH+SPEC) = 5.626E-05 ALPHA = 0.2500 INNER 9 : E(ENTH+SPEC) = 5.012E-05 ALPHA = 1.0000 INNER 10 : E(ENTH+SPEC) = 5.082E-05 ALPHA = 1.0000 ITER 3 E(K) = 4.778E-03 E(ENTH+SPEC) = 5.082E-05 E(SUM) = 3.547E-02 TRAY PACKING PRESSURE DROP CORRELATION APPLIED ** WARNING ** PRESSURE of feed STREAM 35, 'S16' = 1.0502 is LESS THAN the feed TRAY PRESSURE of 1.0523 on tray 10. DAMP = 1.000E+00 INNER 0 : E(ENTH+SPEC) = 1.447E-04 INNER 1 : E(ENTH+SPEC) = 1.272E-04 ALPHA = 1.0000 INNER 2 : E(ENTH+SPEC) = 6.758E-05 ALPHA = 1.0000 INNER 3 : E(ENTH+SPEC) = 1.625E-05 ALPHA = 1.0000 ITER 4 E(K) = 1.588E-03 E(ENTH+SPEC) = 1.625E-05 E(SUM) = 5.777E-03 TRAY PACKING PRESSURE DROP CORRELATION APPLIED ** WARNING ** PRESSURE of feed STREAM 35, 'S16' = 1.0502 is LESS THAN the feed TRAY PRESSURE of 1.0524 on tray 10. DAMP = 1.000E+00 INNER 0 : E(ENTH+SPEC) = 5.641E-05 INNER 1 : E(ENTH+SPEC) = 1.703E-05 ALPHA = 1.0000 ITER 5 E(K) = 8.271E-04 E(ENTH+SPEC) = 1.703E-05 E(SUM) = 1.205E-03 TRAY PACKING PRESSURE DROP CORRELATION APPLIED ** WARNING ** PRESSURE of feed STREAM 35, 'S16' = 1.0502 is LESS THAN the feed TRAY PRESSURE of 1.0524 on tray 10. UNIT 6 SOLVED - 'T1 ' *** PROBLEM SOLUTION REACHED

*** THIS RUN USED 49.00 PRO/II SIMULATION UNITS

*** RUN STATISTICS STARTED 15:33:45 06/13/14 NO ERRORS FINISHED 15:33:46 06/13/14 9 WARNINGS RUN TIMES NO MESSAGES INTERACTIVE 0 MIN, 0.00 SEC

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CALCULATIONS 0 MIN, 0.45 SEC TOTAL 0 MIN, 0.45 SECFF SIMULATION SCIENCES INC. R PAGE I-1 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM OUTPUT INDEX 06/13/14 ==============================================================================

PAGE CONTENTS ------ ---------------------------------------------------------------- 1 COMPONENT DATA 2 CALCULATION SEQUENCE AND RECYCLES 2 SEQUENCE MAP 3 PLANT MATERIAL BALANCE 4 FLASH DRUM SUMMARY 5 MIXER SUMMARY COMPRESSOR SUMMARY 6 UNIT 7, 'C1' HEAT EXCHANGER SUMMARY 7 UNIT 2, 'E1' COLUMN SUMMARY 8 UNIT 6, 'T1' 10 TRAY LOADING 12 TRAY COMPOSITIONS 16 TRAY RATES AND DENSITIES 16 TRAY TRANSPORT PROPERTIES 17 TRAY PACKING 18 USER DEFINED PROPERTIES SET 21 STREAM MOLAR COMPONENT RATES 23 STREAM SUMMARYFF SIMULATION SCIENCES INC. R PAGE P-1 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM OUTPUT COMPONENT DATA 06/13/14 ==============================================================================

COMPONENT COMP. TYPE PHASE MOL. WEIGHT DENSITY KG/M3 --------------------- ----------- ----------- ----------- ----------- 1 CO2 LIBRARY VAP/LIQ 44.010 826.185 2 NITROGEN LIBRARY VAP/LIQ 28.013 807.313 3 OXYGEN LIBRARY VAP/LIQ 31.999 1126.378 4 H2O LIBRARY VAP/LIQ 18.015 998.566

COMPONENT NBP CRIT. TEMP. CRIT. PRES. CRIT. VOLM. C C KG/CM2 M3/KG-MOL --------------------- ----------- ----------- ----------- ----------- 1 CO2 -78.480 31.040 75.271 0.0940 2 NITROGEN -195.800 -146.900 34.613 0.0901 3 OXYGEN -182.980 -118.400 51.765 0.0764 4 H2O 100.000 374.200 225.553 0.0554

COMPONENT ACEN. FACT. HEAT FORM. G FORM. KCAL/KG-MOL KCAL/KG-MOL --------------------- ----------- ----------- -----------

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1 CO2 0.23100 -93984.43 -94203.21 2 NITROGEN 0.04500 0.00 0.00 3 OXYGEN 0.01900 0.00 0.00 4 H2O 0.34800 -57799.99 -54646.99

COMPONENT DATABANK(S) USED --------------------- --------------------- 1 CO2 PROCESS 2 NITROGEN PROCESS 3 OXYGEN PROCESS 4 H2O PROCESSFF SIMULATION SCIENCES INC. R PAGE P-2 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM OUTPUT CALCULATION SEQUENCE AND RECYCLES 06/13/14 ==============================================================================

CALCULATION SEQUENCE

SEQ UNIT ID UNIT TYPE SEQ UNIT ID UNIT TYPE --- ------------ ---------- --- ------------ ---------- 1 M1 MIXER 5 F1 FLASH 2 M2 MIXER 6 C1 COMPRESSOR 3 M3 MIXER 7 T1 COLUMN 4 E1 HX

SEQUENCE MAP

SEQ DESCRIPTION ---- ----------------------------------------- 1 MIXER 'M1' 2 MIXER 'M2' 3 MIXER 'M3' 4 HX 'E1' 5 FLASH 'F1' 6 COMPRESSOR 'C1' 7 COLUMN 'T1'FF SIMULATION SCIENCES INC. R PAGE P-3 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM OUTPUT PLANT MATERIAL BALANCE 06/13/14 ==============================================================================

FEED STREAMS: S1 S2 S5 S9 S11 S13

PRODUCT STREAMS: S7 S8 S14 S15

OVERALL PLANT MOLAR BALANCE

---------------- KG-MOL/HR ---------------- PERCENT COMPONENT FEED +REACTION -PRODUCT =DEVIATION DEV

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--------------------- ---------- ---------- ---------- ---------- ------- 1 CO2 1.921 0.000 1.921 0.000 0.00 2 NITROGEN 96.373 0.000 96.373 0.000 0.00 3 OXYGEN 21.890 0.000 21.890 0.000 0.00 4 H2O 1710.865 0.000 1710.865 0.000 0.00

TOTAL 1831.049 0.000 1831.049 0.000 0.00

OVERALL PLANT MASS BALANCE

------------------ KG/HR ------------------ PERCENT COMPONENT FEED +REACTION -PRODUCT =DEVIATION DEV --------------------- ---------- ---------- ---------- ---------- ------- 1 CO2 84.54 0.00 84.54 0.00 0.00 2 NITROGEN 2699.69 0.00 2699.69 0.00 0.00 3 OXYGEN 700.47 0.00 700.47 0.00 0.00 4 H2O 30821.24 0.00 30821.24 0.00 0.00

TOTAL 34305.94 0.00 34305.94 0.00 0.00FF SIMULATION SCIENCES INC. R PAGE P-4 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM OUTPUT FLASH DRUM SUMMARY 06/13/14 ==============================================================================

FLASH ID F1 NAME

FEEDS S5 S4

PRODUCTS VAPOR S6 LIQUID S7 WATER S8

TEMPERATURE, C 85.000 PRESSURE, KG/CM2 1.021 PRESSURE DROP, KG/CM2 6.770E-03 MOLE FRAC VAPOR 1.00000 MOLE FRAC LIQUID 0.00000 DUTY, M*KCAL/HR -0.05072 FLASH TYPE ISOTHERMALFF SIMULATION SCIENCES INC. R PAGE P-5 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM OUTPUT MIXER SUMMARY 06/13/14 ==============================================================================

MIXER ID M1 M2 M3 NAME

FEEDS S1 S3 S11 S2 S9 S10

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PRODUCTS VAPOR S3 S10 S12

TEMPERATURE, C 1201.340 1200.952 477.352 PRESSURE, KG/CM2 1.028 1.028 1.028 PRESSURE DROP, KG/CM2 0.000 0.000 0.000 MOLE FRAC VAPOR 1.00000 1.00000 1.00000 MOLE FRAC LIQUID 0.00000 0.00000 0.00000FF SIMULATION SCIENCES INC. R PAGE P-6 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM OUTPUT COMPRESSOR SUMMARY 06/13/14 ==============================================================================

UNIT 7, 'C1'

Feeds S6

Products Vapor S16

OPERATING CONDITIONS

INLET ISENTROPIC OUTLET ----------- ----------- ----------- TEMPERATURE, C 85.00 87.73 88.90 PRESSURE, KG/CM2 1.02 1.05 1.05 ENTHALPY, M*KCAL/HR 0.6837 0.6888 0.6911 ENTROPY, KCAL/KG-MOL-C 48.9302 48.9302 48.9541 CP, KCAL/KG-MOL-C 11.3067 11.2761 CV, KCAL/KG-MOL-C 9.3170 9.2862 CP/(CP-R) 1.2131 1.2138 CP/CV 1.2136 1.2143 MOLE PERCENT VAPOR 100.0000 100.0000 100.0000 MOLE PERCENT LIQUID 0.0000 0.0000 0.0000 ACT VAP RATE, M3/SEC 1.3889 ADIABATIC EFF, PERCENT 69.8866 POLYTROPIC EFF, PERCENT 70.0000 ISENTROPIC COEFFICIENT, K 1.3720 POLYTROPIC COEFFICIENT, N 1.6309 ASME "F" FACTOR 1.5422 HEAD, M ADIABATIC 508.31 POLYTROPIC 509.14 ACTUAL 727.34 WORK, KW THEORETICAL 6.02 POLYTROPIC 6.03 ACTUAL 8.62

NOTE: POLYTROPIC AND ISENTROPIC COEFFICIENTS CALCULATED FROM ASME EQUATIONSFF SIMULATION SCIENCES INC. R PAGE P-7 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM OUTPUT HEAT EXCHANGER SUMMARY 06/13/14

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==============================================================================

UNIT 2, 'E1'

OPERATING CONDITIONS

DUTY, M*KCAL/HR 0.189

HOT SIDE CONDITIONS INLET OUTLET ----------- ----------- FEED S12 VAPOR PRODUCT S4 VAPOR, KG-MOL/HR 134.900 134.900 K*KG/HR 3.750 3.750 CP, KCAL/KG-C 0.489 0.293 TOTAL, KG-MOL/HR 134.900 134.900 K*KG/HR 3.750 3.750 CONDENSATION, KG-MOL/HR 0.000 TEMPERATURE, C 477.352 350.000 PRESSURE, KG/CM2 1.028 1.028FF SIMULATION SCIENCES INC. R PAGE P-8 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM OUTPUT COLUMN SUMMARY 06/13/14 ==============================================================================

UNIT 6, 'T1'

TOTAL NUMBER OF ITERATIONS

IN/OUT METHOD 34

COLUMN SUMMARY

---------- NET FLOW RATES ----------- HEATER TRAY TEMP PRESSURE LIQUID VAPOR FEED PRODUCT DUTIES DEG C KG/CM2 KG-MOL/HR M*KCAL/HR ------ ------- -------- -------- -------- --------- --------- ------------ 1 40.0 1.04 1664.8 1662.9L 128.0V 2 40.0 1.04 1664.8 129.9 3 40.0 1.04 1664.8 129.9 4 40.0 1.04 1664.8 129.9 5 40.0 1.05 1664.8 129.9 6 40.1 1.05 1665.0 129.9 7 40.4 1.05 1665.6 130.1 8 41.6 1.05 1668.3 130.7 9 45.7 1.05 1678.5 133.4 10 56.2 1.05 143.6 168.2V 1703.1L

FEED AND PRODUCT STREAMS

TYPE STREAM PHASE FROM TO LIQUID FLOW RATES HEAT RATES TRAY TRAY FRAC KG-MOL/HR M*KCAL/HR

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----- ------------ ------ ---- ---- ------ ------------ ------------ FEED S13 LIQUID 1 1.0000 1662.89 1.1973 FEED S16 VAPOR 10 0.0000 168.16 0.6911 PROD S14 VAPOR 1 127.99 0.1671 PROD S15 LIQUID 10 1703.06 1.7211

OVERALL MOLE BALANCE, (FEEDS - PRODUCTS) 5.9952E-13 OVERALL HEAT BALANCE, (H(IN) - H(OUT) ) 2.4541E-04FF SIMULATION SCIENCES INC. R PAGE P-9 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM OUTPUT COLUMN SUMMARY 06/13/14 ==============================================================================

UNIT 6, 'T1' (Cont)

COLUMN SUMMARY

---------- NET FLOW RATES ----------- HEATER TRAY TEMP PRESSURE LIQUID VAPOR FEED PRODUCT DUTIES DEG C KG/CM2 KG/HR M*KCAL/HR ------ ------- -------- -------- -------- --------- --------- ------------ 1 40.0 1.04 30014.9 29957.0L 3606.2V 2 40.0 1.04 30016.2 3664.1 3 40.0 1.04 30016.2 3665.4 4 40.0 1.04 30016.2 3665.4 5 40.0 1.05 30016.7 3665.4 6 40.1 1.05 30019.2 3665.9 7 40.4 1.05 30030.3 3668.4 8 41.6 1.05 30078.2 3679.5 9 45.7 1.05 30260.6 3727.4 10 56.2 1.05 3909.8 4348.9V 30699.7L

FEED AND PRODUCT STREAM RATES

FROM TO WT RATE LV RATE GV RATE TYPE STREAM PHASE TRAY TRAY KG/HR M3/HR M3/HR ----- ------------ ------ ---- ---- ----------- ----------- ------------ FEED S13 LIQUID 1 29956.9936 30.0000 39400.7037 FEED S16 VAPOR 10 4348.9459 4.9337 3984.3433 PROD S14 VAPOR 1 3606.1934 4.1827 3032.5311 PROD S15 LIQUID 10 30699.7461 30.7510 40352.5158FF SIMULATION SCIENCES INC. R PAGE P-10 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM OUTPUT COLUMN SUMMARY 06/13/14 ==============================================================================

UNIT 6, 'T1' (Cont)

TRAY LOADING REPORT

** WARNING ** The liquid enthalpy of CO2 at temperature 362.05 K is outside the acceptable range of -50 K through 31.02 K.

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** WARNING ** The liquid enthalpy of NITROGEN at temperature 362.05 K is outside the acceptable range of -210 K through -146.92 K. ** WARNING ** The liquid enthalpy of OXYGEN at temperature 362.05 K is outside the acceptable range of -220 K through -118.42 K.

-------------------------- Vapor to Tray -------------------------- Density Viscosity Temp Pressure Rate at Cond at Cond Tray deg C KG/CM2 Molec Wt K*KG/HR KG/M3 CP ----- -------- ----------- ---------- ----------- ---------- ---------- 1 40.04 1.04145 28.2073 3.6640663 1.106316 0.0184124 2 40.03 1.04270 28.2122 3.6653879 1.107847 0.0184119 3 40.03 1.04394 28.2140 3.6654208 1.109255 0.0184123 4 40.05 1.04518 28.2146 3.6654134 1.110546 0.0184134 5 40.11 1.04643 28.2128 3.6659029 1.111563 0.0184153 6 40.39 1.04768 28.2020 3.6684104 1.111480 0.0184213 7 41.56 1.04896 28.1531 3.6795407 1.106769 0.0184444 8 45.70 1.05040 27.9465 3.7274040 1.085888 0.0185005 9 56.17 1.05236 27.2307 3.9098184 1.026345 0.0184908 10 88.90 1.05236 25.8623 4.3489459 0.886636 0.0189619

------------------------- Liquid from tray ------------------------ Density Viscosity Surface Temp Rate at Cond at Cond Tension Tray deg C Molec Wt K*KG/HR KG/M3 CP DYNE/CM ----- -------- ---------- ----------- ---------- ---------- ---------- 1 40.04 18.0291 30.0148665 987.59387 0.6493398 69.513755 2 40.04 18.0296 30.0161881 987.54077 0.6493021 69.512376 3 40.03 18.0297 30.0162211 987.53101 0.6493426 69.512654 4 40.03 18.0297 30.0162136 987.52784 0.6493995 69.513234 5 40.05 18.0298 30.0167031 987.51854 0.6492046 69.510846 6 40.11 18.0298 30.0192106 987.49183 0.6483923 69.501121 7 40.39 18.0297 30.0303409 987.39146 0.6449871 69.460346 8 41.56 18.0295 30.0782042 986.97600 0.6309275 69.287725 9 45.70 18.0285 30.2606186 985.46763 0.5851848 68.670409 10 56.17 18.0262 30.6997461 981.27808 0.4907724 67.039411

------------------------- Vapor from Tray -------------------------- Density Viscosity Temp Pressure Rate at Cond at Cond Tray deg C KG/CM2 Molec Wt K*KG/HR KG/M3 CP ----- -------- ----------- ---------- ----------- ---------- ---------- 1 40.04 1.04020 28.1763 3.6061934 1.103778 0.0184165 2 40.04 1.04145 28.2073 3.6640663 1.106316 0.0184124 3 40.03 1.04270 28.2122 3.6653879 1.107847 0.0184119 4 40.03 1.04394 28.2140 3.6654208 1.109255 0.0184123 5 40.05 1.04518 28.2146 3.6654134 1.110546 0.0184134FF SIMULATION SCIENCES INC. R PAGE P-11 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM OUTPUT COLUMN SUMMARY 06/13/14 ==============================================================================

UNIT 6, 'T1' (Cont)

-11-


------------------------- Vapor from Tray -------------------------- Density Viscosity Temp Pressure Rate at Cond at Cond Tray deg C KG/CM2 Molec Wt K*KG/HR KG/M3 CP ----- -------- ----------- ---------- ----------- ---------- ---------- 6 40.11 1.04643 28.2128 3.6659029 1.111563 0.0184153 7 40.39 1.04768 28.2020 3.6684104 1.111480 0.0184213 8 41.56 1.04896 28.1531 3.6795407 1.106769 0.0184444 9 45.70 1.05040 27.9465 3.7274040 1.085888 0.0185005 10 56.17 1.05236 27.2307 3.9098184 1.026345 0.0184908

------------------------- Liquid to Tray ------------------------ Density Viscosity Surface Temp Rate at Cond at Cond Tension Tray deg C Molec Wt K*KG/HR KG/M3 CP DYNE/CM ----- -------- ---------- ----------- ---------- ---------- ---------- 1 40.00 18.0150 29.9569936 990.45427 0.6513002 69.594232 2 40.04 18.0291 30.0148665 987.59387 0.6493398 69.513755 3 40.04 18.0296 30.0161881 987.54077 0.6493021 69.512376 4 40.03 18.0297 30.0162211 987.53101 0.6493426 69.512654 5 40.03 18.0297 30.0162136 987.52784 0.6493995 69.513234 6 40.05 18.0298 30.0167031 987.51854 0.6492046 69.510846 7 40.11 18.0298 30.0192106 987.49183 0.6483923 69.501121 8 40.39 18.0297 30.0303409 987.39146 0.6449871 69.460346 9 41.56 18.0295 30.0782042 986.97600 0.6309275 69.287725 10 45.70 18.0285 30.2606186 985.46763 0.5851848 68.670409FF SIMULATION SCIENCES INC. R PAGE P-12 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM OUTPUT COLUMN SUMMARY 06/13/14 ==============================================================================

UNIT 6, 'T1' (Cont)

TRAY MOLAR COMPOSITIONS

TRAY 1 TRAY 2 COMPONENT X Y X Y ---------- ---------- ---------- ---------- 1 CO2 1.5405E-04 0.01346 1.7459E-04 0.01523 2 NITROGEN 6.9984E-04 0.74541 6.9871E-04 0.74341 3 OXYGEN 2.2030E-04 0.16868 2.2098E-04 0.16902 4 H2O 0.99893 0.07245 0.99891 0.07233

RATE, KG-MOL/HR 1664.80 127.99 1664.83 129.90


RATE, KG-MOL/HR 1664.82 129.92 1664.82 129.92

-12-



RATE, KG-MOL/HR 1664.84 129.91 1664.98 129.94


RATE, KG-MOL/HR 1665.60 130.08 1668.28 130.70FF SIMULATION SCIENCES INC. R PAGE P-13 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM OUTPUT COLUMN SUMMARY 06/13/14 ==============================================================================

UNIT 6, 'T1' (Cont)


RATE, KG-MOL/HR 1678.49 133.38 1703.06 143.58FF SIMULATION SCIENCES INC. R PAGE P-14 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM OUTPUT COLUMN SUMMARY 06/13/14 ==============================================================================

UNIT 6, 'T1' (Cont)

TRAY WEIGHT COMPOSITIONS

TRAY 1 TRAY 2 COMPONENT X Y X Y ---------- ---------- ---------- ---------- 1 CO2 3.7604E-04 0.02102 4.2618E-04 0.02377 2 NITROGEN 0.00109 0.74109 0.00109 0.73829 3 OXYGEN 3.9100E-04 0.19156 3.9220E-04 0.19174

-13-


4 H2O 0.99815 0.04632 0.99810 0.04619

RATE, KG/HR 30014.866 3606.193 30016.188 3664.066

TRAY 3 TRAY 4 COMPONENT X Y X Y ---------- ---------- ---------- ---------- 1 CO2 4.3401E-04 0.02417 4.3575E-04 0.02424 2 NITROGEN 0.00109 0.73801 0.00109 0.73802 3 OXYGEN 3.9266E-04 0.19168 3.9317E-04 0.19168 4 H2O 0.99809 0.04613 0.99808 0.04606

RATE, KG/HR 30016.221 3665.388 30016.214 3665.421


RATE, KG/HR 30016.703 3665.413 30019.211 3665.903


RATE, KG/HR 30030.341 3668.410 30078.204 3679.541FF SIMULATION SCIENCES INC. R PAGE P-15 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM OUTPUT COLUMN SUMMARY 06/13/14 ==============================================================================

UNIT 6, 'T1' (Cont)

TRAY 9 TRAY 10 COMPONENT X Y X Y ---------- ---------- ---------- ---------- 1 CO2 3.7934E-04 0.02374 2.8463E-04 0.02232 2 NITROGEN 0.00102 0.72566 8.8477E-04 0.69146 3 OXYGEN 3.6745E-04 0.18846 3.1445E-04 0.17953 4 H2O 0.99823 0.06214 0.99852 0.10668

RATE, KG/HR 30260.619 3727.404 30699.746 3909.818FF SIMULATION SCIENCES INC. R PAGE P-16 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6

-14-


PROBLEM OUTPUT COLUMN SUMMARY 06/13/14 ==============================================================================

UNIT 6, 'T1' (Cont)

TRAY NET VAPOR RATES AND DENSITIES

--------------- RATES --------------- TRAY MW ACTUAL DENS Z FROM STANDARD ACTUAL KG/M3 DENSITY K*KG/HR K*M3/HR K*M3/HR ---- -------- ------------ -------- ----------- ----------- ----------- 1 28.176 1.10378 1.00000 3.606 3.033 3.267 2 28.207 1.10632 1.00000 3.664 3.078 3.312 3 28.212 1.10785 1.00000 3.665 3.078 3.309 4 28.214 1.10925 1.00000 3.665 3.078 3.304 5 28.215 1.11055 1.00000 3.665 3.078 3.301 6 28.213 1.11156 1.00000 3.666 3.079 3.298 7 28.202 1.11148 1.00000 3.668 3.082 3.300 8 28.153 1.10677 1.00000 3.680 3.097 3.325 9 27.947 1.08589 1.00000 3.727 3.160 3.433 10 27.231 1.02635 1.00000 3.910 3.402 3.809

TRAY NET LIQUID RATES AND DENSITIES

--------------- RATES --------------- TRAY MW ACTUAL DENS Z FROM STD LIQ ACTUAL KG/M3 DENSITY K*KG/HR M3/HR M3/HR ---- -------- ------------ -------- ----------- ----------- ----------- 1 18.029 987.594 7.15E-04 30.015 30.067 30.392 2 18.030 987.541 7.16E-04 30.016 30.068 30.395 3 18.030 987.531 7.17E-04 30.016 30.068 30.395 4 18.030 987.528 7.18E-04 30.016 30.068 30.395 5 18.030 987.519 7.19E-04 30.017 30.069 30.396 6 18.030 987.492 7.19E-04 30.019 30.071 30.399 7 18.030 987.391 7.20E-04 30.030 30.083 30.414 8 18.029 986.976 7.18E-04 30.078 30.130 30.475 9 18.029 985.468 7.11E-04 30.261 30.313 30.707 10 18.026 981.278 6.92E-04 30.700 30.751 31.285

TRAY TRANSPORT PROPERTIES

TRAY - THERMAL CONDUCTIVITY - ------ VISCOSITY ------- -- SURFACE -- KCAL/HR-M-C CP TENSION LIQUID VAPOR LIQUID VAPOR DYNE/CM ---- ----------- ----------- ----------- ----------- ------------- 1 5.0166E-01 2.2638E-02 6.4934E-01 1.8416E-02 6.9514E+01 2 5.0133E-01 2.2623E-02 6.4930E-01 1.8412E-02 6.9512E+01 3 5.0124E-01 2.2620E-02 6.4934E-01 1.8412E-02 6.9513E+01 4 5.0118E-01 2.2620E-02 6.4940E-01 1.8412E-02 6.9513E+01 5 5.0116E-01 2.2621E-02 6.4920E-01 1.8413E-02 6.9511E+01 6 5.0119E-01 2.2624E-02 6.4839E-01 1.8415E-02 6.9501E+01 7 5.0150E-01 2.2637E-02 6.4499E-01 1.8421E-02 6.9460E+01 8 5.0294E-01 2.2688E-02 6.3093E-01 1.8444E-02 6.9288E+01 9 5.0806E-01 2.2854E-02 5.8518E-01 1.8501E-02 6.8670E+01

-15-


10 5.2097E-01 2.3182E-02 4.9077E-01 1.8491E-02 6.7039E+01FF SIMULATION SCIENCES INC. R PAGE P-17 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM OUTPUT COLUMN SUMMARY 06/13/14 ==============================================================================

UNIT 6, 'T1' (Cont)

PACKED COLUMN DATA

SECTION ID = COLSECT-1 PACKED HEIGHT = 8.89 M COLUMN ID = 0.850 M PACKING TYPE (NORTON) = Pall rings, plastic PACKING FACTOR = 55.77 M2/M3 NOMINAL PACKING DIAMETER = 88.900 MM CAPACITY METHOD = fraction of flood HETP METHOD = Norton DP METHOD = Norton

TRAY ---PRESSURE DROP---- PRESSURE HETP MM H2O/M KG/CM2 KG/CM2 M ---- --------- -------- -------- -------- 1 14.0422 0.0012 1.040 0.889 2 14.0338 0.0012 1.041 0.889 3 14.0153 0.0012 1.043 0.889 4 13.9979 0.0012 1.044 0.889 5 13.9879 0.0012 1.045 0.889 6 14.0087 0.0012 1.046 0.889 7 14.1608 0.0013 1.048 0.889 8 14.8420 0.0013 1.049 0.889 9 17.3786 0.0015 1.050 0.889 10 26.8030 0.0024 1.052 0.889

TRAY X Y DESIGN FLOOD FLOOD M/SEC M/SEC APPROACH ---- ------- ------- -------- -------- -------- 1 0.2742 0.5173 0.054 0.115 0.473 2 0.2743 0.5169 0.054 0.115 0.473 3 0.2745 0.5163 0.054 0.115 0.473 4 0.2746 0.5157 0.054 0.115 0.472 5 0.2747 0.5154 0.054 0.115 0.472 6 0.2745 0.5161 0.054 0.115 0.472 7 0.2732 0.5212 0.055 0.115 0.474 8 0.2677 0.5442 0.056 0.116 0.480 9 0.2498 0.6297 0.060 0.120 0.501 10 0.2122 0.8902 0.072 0.130 0.557 ** WARNING ** The liquid enthalpy of H2O at temperature 2340.1 K is outside the acceptable range of -50 K through 374.18 K.FF SIMULATION SCIENCES INC. R PAGE P-18 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM OUTPUT USER DEFINED PROPERTIES SET 06/13/14 ==============================================================================

-16-


STREAM ID S1 S2 S3 S9 NAME PHASE VAPOR VAPOR VAPOR VAPOR THERMO ID IDEA01 IDEA01 IDEA01 IDEA01

STREAM ID S1 S2 S3 S9 NAME

PHASE VAPOR VAPOR VAPOR VAPOR

RATE, KG-MOL/HR 19.5580 16.2800 35.8380 11.1019 RATE, KG/HR 542.4757 469.6790 1012.1547 200.0000 TEMPERATURE, C 2067.00 35.00 1201.34 1200.00 PRESSURE, KG/CM2 1.028 1.033 1.028 1.028 MOLECULAR WEIGHT 27.7368 28.8501 28.2425 18.0150 ENTHALPY, M*KCAL/HR 0.5945 7.5333E-03 0.6020 0.2601

*** VAPOR PHASE *** RATE, KG-MOL/HR 19.5580 16.2800 35.8380 11.1019 RATE, KG/HR 542.4757 469.6790 1012.1547 200.0000 DENSITY, KG/K*IN3 2.3550E-03 0.0187 3.8058E-03 2.4298E-03 RATE, KG-MOL/HR 19.5580 16.2800 35.8380 11.1019 STD RATE, K*M3/HR 0.4634 0.3857 0.8491 0.2630 MOLECULAR WEIGHT 27.7368 28.8501 28.2425 18.0150 Z-FACTOR(from K-Value) 1.0000 1.0000 1.0000 1.0000 ENTHALPY, K*KCAL/KG-MOL 30.3973 0.4627 16.7990 23.4279 *** TOTAL STREAM *** COMP. MOLE FRACTIONS 1 CO2 0.0982 0.0000 0.0536 0.0000 2 NITROGEN 0.7170 0.7900 0.7502 0.0000 3 OXYGEN 0.0000 0.2100 0.0954 0.0000 4 H2O 0.1848 0.0000 0.1008 1.0000 COMP. MOLE RATES, KG-MOL/HR 1 CO2 1.9210 0.0000 1.9210 0.0000 2 NITROGEN 14.0230 12.8612 26.8842 0.0000 3 OXYGEN 0.0000 3.4188 3.4188 0.0000 4 H2O 3.6140 0.0000 3.6140 11.1019 COMP. WT. FRACTIONS 1 CO2 0.1558 0.0000 0.0835 0.0000 2 NITROGEN 0.7241 0.7671 0.7441 0.0000 3 OXYGEN 0.0000 0.2329 0.1081 0.0000 4 H2O 0.1200 0.0000 0.0643 1.0000 COMP. WT. RATES, KG/HR 1 CO2 84.5432 0.0000 84.5432 0.0000 2 NITROGEN 392.8263 360.2808 753.1071 0.0000 3 OXYGEN 0.0000 109.3982 109.3982 0.0000 4 H2O 65.1062 0.0000 65.1062 200.0000FF SIMULATION SCIENCES INC. R PAGE P-19 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM OUTPUT USER DEFINED PROPERTIES SET 06/13/14 ==============================================================================

-17-




PHASE VAPOR VAPOR VAPOR VAPOR

RATE, KG-MOL/HR 46.9399 87.9600 134.8999 134.8999 RATE, KG/HR 1212.1547 2537.6513 3749.8060 3749.8060 TEMPERATURE, C 1200.95 35.00 477.35 350.00 PRESSURE, KG/CM2 1.028 1.033 1.028 1.028 MOLECULAR WEIGHT 25.8236 28.8501 27.7970 27.7970 ENTHALPY, M*KCAL/HR 0.8621 0.0407 0.9028 0.7134

*** VAPOR PHASE *** RATE, KG-MOL/HR 46.9399 87.9600 134.8999 134.8999 RATE, KG/HR 1212.1547 2537.6513 3749.8060 3749.8060 DENSITY, KG/K*IN3 3.4807E-03 0.0187 7.3591E-03 8.8631E-03 RATE, KG-MOL/HR 46.9399 87.9600 134.8999 134.8999 STD RATE, K*M3/HR 1.1122 2.0841 3.1963 3.1963 MOLECULAR WEIGHT 25.8236 28.8501 27.7970 27.7970 Z-FACTOR(from K-Value) 1.0000 1.0000 1.0000 1.0000 ENTHALPY, K*KCAL/KG-MOL 18.3668 0.4627 6.6927 5.2886 *** TOTAL STREAM *** COMP. MOLE FRACTIONS 1 CO2 0.0409 0.0000 0.0142 0.0142 2 NITROGEN 0.5727 0.7900 0.7144 0.7144 3 OXYGEN 0.0728 0.2100 0.1623 0.1623 4 H2O 0.3135 0.0000 0.1091 0.1091 COMP. MOLE RATES, KG-MOL/HR 1 CO2 1.9210 0.0000 1.9210 1.9210 2 NITROGEN 26.8842 69.4884 96.3726 96.3726 3 OXYGEN 3.4188 18.4716 21.8904 21.8904 4 H2O 14.7159 0.0000 14.7159 14.7159 COMP. WT. FRACTIONS 1 CO2 0.0697 0.0000 0.0225 0.0225 2 NITROGEN 0.6213 0.7671 0.7200 0.7200 3 OXYGEN 0.0903 0.2329 0.1868 0.1868 4 H2O 0.2187 0.0000 0.0707 0.0707 COMP. WT. RATES, KG/HR 1 CO2 84.5432 0.0000 84.5432 84.5432 2 NITROGEN 753.1071 1946.5786 2699.6857 2699.6857 3 OXYGEN 109.3982 591.0727 700.4709 700.4709 4 H2O 265.1062 0.0000 265.1062 265.1062FF SIMULATION SCIENCES INC. R PAGE P-20 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM OUTPUT USER DEFINED PROPERTIES SET 06/13/14 ==============================================================================

STREAM ID S6 S16 S14

-18-


NAME PHASE VAPOR VAPOR VAPOR THERMO ID IDEA01 IDEA01 IDEA01

STREAM ID S6 S16 S14 NAME

PHASE VAPOR VAPOR VAPOR

RATE, KG-MOL/HR 168.1577 168.1577 127.9868 RATE, KG/HR 4348.9459 4348.9459 3606.1934 TEMPERATURE, C 85.00 88.90 40.04 PRESSURE, KG/CM2 1.021 1.050 1.040 MOLECULAR WEIGHT 25.8623 25.8623 28.1763 ENTHALPY, M*KCAL/HR 0.6837 0.6911 0.1671

*** VAPOR PHASE *** RATE, KG-MOL/HR 168.1577 168.1577 127.9868 RATE, KG/HR 4348.9459 4348.9459 3606.1934 DENSITY, KG/K*IN3 0.0143 0.0145 0.0181 RATE, KG-MOL/HR 168.1577 168.1577 127.9868 STD RATE, K*M3/HR 3.9843 3.9843 3.0325 MOLECULAR WEIGHT 25.8623 25.8623 28.1763 Z-FACTOR(from K-Value) 1.0000 1.0000 1.0000 ENTHALPY, K*KCAL/KG-MOL 4.0656 4.1097 1.3057 *** TOTAL STREAM *** COMP. MOLE FRACTIONS 1 CO2 0.0114 0.0114 0.0135 2 NITROGEN 0.5731 0.5731 0.7454 3 OXYGEN 0.1302 0.1302 0.1687 4 H2O 0.2853 0.2853 0.0725 COMP. MOLE RATES, KG-MOL/HR 1 CO2 1.9210 1.9210 1.7225 2 NITROGEN 96.3726 96.3726 95.4030 3 OXYGEN 21.8904 21.8904 21.5887 4 H2O 47.9737 47.9737 9.2727 COMP. WT. FRACTIONS 1 CO2 0.0194 0.0194 0.0210 2 NITROGEN 0.6208 0.6208 0.7411 3 OXYGEN 0.1611 0.1611 0.1916 4 H2O 0.1987 0.1987 0.0463 COMP. WT. RATES, KG/HR 1 CO2 84.5432 84.5432 75.8052 2 NITROGEN 2699.6857 2699.6857 2672.5233 3 OXYGEN 700.4709 700.4709 690.8175 4 H2O 864.2461 864.2461 167.0474FF SIMULATION SCIENCES INC. R PAGE P-21 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM OUTPUT STREAM MOLAR COMPONENT RATES 06/13/14 ==============================================================================


-19-


PHASE VAPOR VAPOR VAPOR VAPOR THERMO ID IDEA01 IDEA01 IDEA01 IDEA01

FLUID RATES, KG-MOL/HR 1 CO2 1.9210 0.0000 1.9210 1.9210 2 NITROGEN 14.0230 12.8612 26.8842 96.3726 3 OXYGEN 0.0000 3.4188 3.4188 21.8904 4 H2O 3.6140 0.0000 3.6140 14.7159

TOTAL RATE, KG-MOL/HR 19.5580 16.2800 35.8380 134.8999

TEMPERATURE, C 2067.0000 35.0000 1201.3400 350.0000 PRESSURE, KG/CM2 1.0280 1.0330 1.0280 1.0280 ENTHALPY, M*KCAL/HR 0.5945 7.5333E-03 0.6020 0.7134 MOLECULAR WEIGHT 27.7368 28.8501 28.2425 27.7970 MOLE FRAC VAPOR 1.0000 1.0000 1.0000 1.0000 MOLE FRAC LIQUID 0.0000 0.0000 0.0000 0.0000

STREAM ID S5 S6 S9 S10 NAME PHASE LIQUID VAPOR VAPOR VAPOR THERMO ID IDEA01 IDEA01 IDEA01 IDEA01



TEMPERATURE, C 35.0000 85.0000 1200.0000 1200.9523 PRESSURE, KG/CM2 2.0000 1.0212 1.0280 1.0280 ENTHALPY, M*KCAL/HR 0.0210 0.6837 0.2601 0.8621 MOLECULAR WEIGHT 18.0150 25.8623 18.0150 25.8236 MOLE FRAC VAPOR 0.0000 1.0000 1.0000 1.0000 MOLE FRAC LIQUID 1.0000 0.0000 0.0000 0.0000FF SIMULATION SCIENCES INC. R PAGE P-22 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM OUTPUT STREAM MOLAR COMPONENT RATES 06/13/14 ==============================================================================

STREAM ID S11 S12 S13 S14 NAME PHASE VAPOR VAPOR LIQUID VAPOR THERMO ID IDEA01 IDEA01 IDEA01 IDEA01



-20-


TEMPERATURE, C 35.0000 477.3524 40.0000 40.0389 PRESSURE, KG/CM2 1.0330 1.0280 4.5332 1.0402 ENTHALPY, M*KCAL/HR 0.0407 0.9028 1.1973 0.1671 MOLECULAR WEIGHT 28.8501 27.7970 18.0150 28.1763 MOLE FRAC VAPOR 1.0000 1.0000 0.0000 1.0000 MOLE FRAC LIQUID 0.0000 0.0000 1.0000 0.0000

STREAM ID S15 S16 NAME PHASE LIQUID VAPOR THERMO ID IDEA01 IDEA01

FLUID RATES, KG-MOL/HR 1 CO2 0.1985 1.9210 2 NITROGEN 0.9696 96.3726 3 OXYGEN 0.3017 21.8904 4 H2O 1701.5927 47.9737

TOTAL RATE, KG-MOL/HR 1703.0626 168.1577

TEMPERATURE, C 56.1670 88.9021 PRESSURE, KG/CM2 1.0524 1.0502 ENTHALPY, M*KCAL/HR 1.7211 0.6911 MOLECULAR WEIGHT 18.0262 25.8623 MOLE FRAC VAPOR 0.0000 1.0000 MOLE FRAC LIQUID 1.0000 0.0000

THE FOLLOWING STREAMS WERE NOT PRINTED BECAUSE THEY HAVE ZERO FLOW RATES OR THEIR TEMPERATURES OR PRESSURES ARE AT ABSOLUTE ZERO S7 S8FF SIMULATION SCIENCES INC. R PAGE P-23 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM OUTPUT STREAM SUMMARY 06/13/14 ==============================================================================


----- TOTAL STREAM ----- RATE, KG-MOL/HR 19.558 16.280 35.838 134.900 K*KG/HR 0.542 0.470 1.012 3.750 STD LIQ RATE, M3/HR 0.654 0.543 1.198 4.334 TEMPERATURE, C 2067.000 35.000 1201.340 350.000 PRESSURE, KG/CM2 1.028 1.033 1.028 1.028 MOLECULAR WEIGHT 27.737 28.850 28.242 27.797 ENTHALPY, M*KCAL/HR 0.595 7.533E-03 0.602 0.713 KCAL/KG 1095.920 16.039 594.813 190.259 MOLE FRACTION LIQUID 0.0000 0.0000 0.0000 0.0000 REDUCED TEMP (KAYS RULE) 9.7499 2.3303 7.7176 3.2754 PRES (KAYS RULE) 0.0139 0.0270 0.0178 0.0175

-21-


ACENTRIC FACTOR 0.1193 0.0395 0.0830 0.0765 WATSON K (UOPK) 7.024 6.047 6.571 6.333 STD LIQ DENSITY, KG/M3 829.329 864.341 845.217 865.260 SPECIFIC GRAVITY 0.8301 0.8652 0.8461 0.8661 API GRAVITY 38.952 32.047 35.748 31.873

-------- VAPOR --------- RATE, KG-MOL/HR 19.558 16.280 35.838 134.900 K*KG/HR 0.542 0.470 1.012 3.750 K*M3/HR 3.775 0.412 4.358 6.933 STD VAP RATE(1), K*M3/HR 0.463 0.386 0.849 3.196 SPECIFIC GRAVITY (AIR=1.0) 0.958 0.996 0.975 0.960 MOLECULAR WEIGHT 27.737 28.850 28.242 27.797 ENTHALPY, KCAL/KG 1095.920 16.039 594.813 190.259 CP, KCAL/KG-C 0.523 0.449 0.489 0.293 DENSITY, KG/K*M3 143.711 1140.699 232.242 540.859 Z (FROM DENSITY) 1.0000 1.0000 1.0000 1.0000 TH COND, KCAL/HR-M-C 0.13338 0.02281 0.08100 0.03994 VISCOSITY, CP 0.08146 0.01885 0.05608 0.03078 KVIS (VISC/DENS), CSTOKE 566.7993 16.5212 241.4616 56.9031

(1) STANDARD VAPOR VOLUME IS 23.694 M3/KG-MOLE (15.6 C AND 1 ATM)FF SIMULATION SCIENCES INC. R PAGE P-24 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM OUTPUT STREAM SUMMARY 06/13/14 ==============================================================================


-------- LIQUID -------- RATE, KG-MOL/HR N/A N/A N/A N/A K*KG/HR N/A N/A N/A N/A M3/HR N/A N/A N/A N/A GAL/MIN N/A N/A N/A N/A STD LIQ RATE, M3/HR N/A N/A N/A N/A SPECIFIC GRAVITY (H2O=1.0) N/A N/A N/A N/A MOLECULAR WEIGHT N/A N/A N/A N/A ENTHALPY, KCAL/KG N/A N/A N/A N/A CP, KCAL/KG-C N/A N/A N/A N/A DENSITY, KG/M3 N/A N/A N/A N/A Z (FROM DENSITY) N/A N/A N/A N/A SURFACE TENSION, DYNE/CM N/A N/A N/A N/A THERMAL COND, KCAL/HR-M-C N/A N/A N/A N/A VISCOSITY, CP N/A N/A N/A N/A KVIS (VISC/DENS), CSTOKE N/A N/A N/A N/AFF SIMULATION SCIENCES INC. R PAGE P-25 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM OUTPUT STREAM SUMMARY 06/13/14 ==============================================================================

-22-



----- TOTAL STREAM ----- RATE, KG-MOL/HR 33.258 168.158 11.102 46.940 K*KG/HR 0.599 4.349 0.200 1.212 STD LIQ RATE, M3/HR 0.600 4.934 0.200 1.398 TEMPERATURE, C 35.000 85.000 1200.000 1200.952 PRESSURE, KG/CM2 2.000 1.021 1.028 1.028 MOLECULAR WEIGHT 18.015 25.862 18.015 25.824 ENTHALPY, M*KCAL/HR 2.096E-02 0.684 0.260 0.862 KCAL/KG 34.979 157.204 1300.464 711.242 MOLE FRACTION LIQUID 1.0000 0.0000 0.0000 0.0000 REDUCED TEMP (KAYS RULE) 0.4760 1.2761 2.2757 4.9305 PRES (KAYS RULE) 8.8671E-03 0.0111 4.5577E-03 0.0106 ACENTRIC FACTOR 0.3480 0.1302 0.3480 0.1457 WATSON K (UOPK) 8.762 6.668 8.762 6.932 STD LIQ DENSITY, KG/M3 998.566 881.472 998.566 867.190 SPECIFIC GRAVITY 0.9996 0.8823 0.9996 0.8680 API GRAVITY 10.063 28.869 10.063 31.510

-------- VAPOR --------- RATE, KG-MOL/HR N/A 168.158 11.102 46.940 K*KG/HR N/A 4.349 0.200 1.212 K*M3/HR N/A 5.000 1.349 5.707 STD VAP RATE(1), K*M3/HR N/A 3.984 0.263 1.112 SPECIFIC GRAVITY (AIR=1.0) N/A 0.893 0.622 0.892 MOLECULAR WEIGHT N/A 25.862 18.015 25.824 ENTHALPY, KCAL/KG N/A 157.204 1300.464 711.242 CP, KCAL/KG-C N/A 0.437 1.007 0.574 DENSITY, KG/K*M3 N/A 869.785 148.274 212.406 Z (FROM DENSITY) N/A 1.0000 1.0000 1.0000 TH COND, KCAL/HR-M-C N/A 0.02431 0.13834 0.09311 VISCOSITY, CP N/A 0.01879 0.05387 0.05564 KVIS (VISC/DENS), CSTOKE N/A 21.6003 363.3425 261.9301



-------- LIQUID -------- RATE, KG-MOL/HR 33.258 N/A N/A N/A K*KG/HR 0.599 N/A N/A N/A M3/HR 0.604 N/A N/A N/A GAL/MIN 2.658 N/A N/A N/A STD LIQ RATE, M3/HR 0.600 N/A N/A N/A

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SPECIFIC GRAVITY (H2O=1.0) 0.9996 N/A N/A N/A MOLECULAR WEIGHT 18.015 N/A N/A N/A ENTHALPY, KCAL/KG 34.979 N/A N/A N/A CP, KCAL/KG-C 0.998 N/A N/A N/A DENSITY, KG/M3 992.343 N/A N/A N/A Z (FROM DENSITY) 1.3897E-03 N/A N/A N/A SURFACE TENSION, DYNE/CM 70.3191 N/A N/A N/A THERMAL COND, KCAL/HR-M-C 0.53611 N/A N/A N/A VISCOSITY, CP 0.71831 N/A N/A N/A KVIS (VISC/DENS), CSTOKE 0.7239 N/A N/A N/AFF SIMULATION SCIENCES INC. R PAGE P-27 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM OUTPUT STREAM SUMMARY 06/13/14 ==============================================================================


----- TOTAL STREAM ----- RATE, KG-MOL/HR 87.960 134.900 1662.892 127.987 K*KG/HR 2.538 3.750 29.957 3.606 STD LIQ RATE, M3/HR 2.936 4.334 30.000 4.183 TEMPERATURE, C 35.000 477.352 40.000 40.039 PRESSURE, KG/CM2 1.033 1.028 4.533 1.040 MOLECULAR WEIGHT 28.850 27.797 18.015 28.176 ENTHALPY, M*KCAL/HR 4.070E-02 0.903 1.197 0.167 KCAL/KG 16.039 240.769 39.969 46.340 MOLE FRACTION LIQUID 0.0000 0.0000 1.0000 0.0000 REDUCED TEMP (KAYS RULE) 2.3303 3.9447 0.4837 1.8293 PRES (KAYS RULE) 0.0270 0.0175 0.0201 0.0200 ACENTRIC FACTOR 0.0395 0.0765 0.3480 0.0651 WATSON K (UOPK) 6.047 6.333 8.762 6.265 STD LIQ DENSITY, KG/M3 864.341 865.260 998.566 862.160 SPECIFIC GRAVITY 0.8652 0.8661 0.9996 0.8630 API GRAVITY 32.047 31.873 10.063 32.461

-------- VAPOR --------- RATE, KG-MOL/HR 87.960 134.900 N/A 127.987 K*KG/HR 2.538 3.750 N/A 3.606 K*M3/HR 2.225 8.350 N/A 3.267 STD VAP RATE(1), K*M3/HR 2.084 3.196 N/A 3.033 SPECIFIC GRAVITY (AIR=1.0) 0.996 0.960 N/A 0.973 MOLECULAR WEIGHT 28.850 27.797 N/A 28.176 ENTHALPY, KCAL/KG 16.039 240.769 N/A 46.340 CP, KCAL/KG-C 0.449 0.489 N/A 0.450 DENSITY, KG/K*M3 1140.699 449.081 N/A 1103.778 Z (FROM DENSITY) 1.0000 1.0000 N/A 1.0000 TH COND, KCAL/HR-M-C 0.02281 0.04648 N/A 0.02264 VISCOSITY, CP 0.01885 0.03499 N/A 0.01842 KVIS (VISC/DENS), CSTOKE 16.5212 77.9201 N/A 16.6850

(1) STANDARD VAPOR VOLUME IS 23.694 M3/KG-MOLE (15.6 C AND 1 ATM)FF

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SIMULATION SCIENCES INC. R PAGE P-28 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM OUTPUT STREAM SUMMARY 06/13/14 ==============================================================================


-------- LIQUID -------- RATE, KG-MOL/HR N/A N/A 1662.892 N/A K*KG/HR N/A N/A 29.957 N/A M3/HR N/A N/A 30.246 N/A GAL/MIN N/A N/A 133.168 N/A STD LIQ RATE, M3/HR N/A N/A 30.000 N/A SPECIFIC GRAVITY (H2O=1.0) N/A N/A 0.9996 N/A MOLECULAR WEIGHT N/A N/A 18.015 N/A ENTHALPY, KCAL/KG N/A N/A 39.969 N/A CP, KCAL/KG-C N/A N/A 0.998 N/A DENSITY, KG/M3 N/A N/A 990.454 N/A Z (FROM DENSITY) N/A N/A 3.1056E-03 N/A SURFACE TENSION, DYNE/CM N/A N/A 69.5942 N/A THERMAL COND, KCAL/HR-M-C N/A N/A 0.54129 N/A VISCOSITY, CP N/A N/A 0.65130 N/A KVIS (VISC/DENS), CSTOKE N/A N/A 0.6576 N/AFF SIMULATION SCIENCES INC. R PAGE P-29 PROJECT PRO/II VERSION 9.2 ELEC V9.0.6 PROBLEM OUTPUT STREAM SUMMARY 06/13/14 ==============================================================================


----- TOTAL STREAM ----- RATE, KG-MOL/HR 1703.063 168.158 K*KG/HR 30.700 4.349 STD LIQ RATE, M3/HR 30.751 4.934 TEMPERATURE, C 56.167 88.902 PRESSURE, KG/CM2 1.052 1.050 MOLECULAR WEIGHT 18.026 25.862 ENTHALPY, M*KCAL/HR 1.721 0.691 KCAL/KG 56.061 158.907 MOLE FRACTION LIQUID 1.0000 0.0000 REDUCED TEMP (KAYS RULE) 0.5090 1.2900 PRES (KAYS RULE) 4.6689E-03 0.0114 ACENTRIC FACTOR 0.3478 0.1302 WATSON K (UOPK) 8.758 6.668 STD LIQ DENSITY, KG/M3 998.334 881.472 SPECIFIC GRAVITY 0.9993 0.8823 API GRAVITY 10.096 28.869

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-------- VAPOR --------- RATE, KG-MOL/HR N/A 168.158 K*KG/HR N/A 4.349 K*M3/HR N/A 4.915 STD VAP RATE(1), K*M3/HR N/A 3.984 SPECIFIC GRAVITY (AIR=1.0) N/A 0.893 MOLECULAR WEIGHT N/A 25.862 ENTHALPY, KCAL/KG N/A 158.907 CP, KCAL/KG-C N/A 0.436 DENSITY, KG/K*M3 N/A 884.813 Z (FROM DENSITY) N/A 1.0000 TH COND, KCAL/HR-M-C N/A 0.02454 VISCOSITY, CP N/A 0.01896 KVIS (VISC/DENS), CSTOKE N/A 21.4304



-------- LIQUID -------- RATE, KG-MOL/HR 1703.063 N/A K*KG/HR 30.700 N/A M3/HR 31.285 N/A GAL/MIN 137.746 N/A STD LIQ RATE, M3/HR 30.751 N/A SPECIFIC GRAVITY (H2O=1.0) 0.9993 N/A MOLECULAR WEIGHT 18.026 N/A ENTHALPY, KCAL/KG 56.061 N/A CP, KCAL/KG-C 0.998 N/A DENSITY, KG/M3 981.278 N/A Z (FROM DENSITY) 6.9238E-04 N/A SURFACE TENSION, DYNE/CM 67.0394 N/A THERMAL COND, KCAL/HR-M-C 0.52097 N/A VISCOSITY, CP 0.49077 N/A KVIS (VISC/DENS), CSTOKE 0.5001 N/A

THE FOLLOWING STREAMS WERE NOT PRINTED BECAUSE THEY HAVE ZERO FLOW RATES OR THEIR TEMPERATURES OR PRESSURES ARE AT ABSOLUTE ZERO S7 S8

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pro ii simulation output file for column

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