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    Petroleum (from Latin petrarock and oleumoil), crude oil,

    sometimes colloquially called black gold, is a thick, dark brown or

    greenish flammable liquid, which exists in the upper strata of some

    areas of the Earth's crust. It consists of a complex mixture of various

    hydrocarbons, largely of the alkane series, but may vary much in

    appearance, composition, and purity. Petroleum is also the raw

    material for many chemical products, including solvents, fertilizers,

    pesticides, and plastics.

    PETROLEUUM

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    HISTORYThe first oil wells were drilled in China in the 4th century or

    earlier. The oil was burned to evaporate brine and produce

    salt. By the 10th century, extensive bamboo pipelines

    connected oil wells with salt springs.The modern history of oil began in 1853, with the discovery

    of the process of oil distillation. Crude oil was distilled into

    kerosene by Ignacy Lukasiewicz, a Polish Scientist. The first

    "rock oil" mine was created inRobrka, near Krosno in

    southern Poland in the following year and the first refinery(actually a distillery) was built in Ulaszowice, also by

    Lukasiewicz.

    PETROLEUUM

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    4TH CENTURY --OIL DRILLED IN CHINA AND BURNED TO EVAPORATE

    BRINE TO PRODUCE SALT

    10TH

    CENTURY--TRANSPORTATION OF OIL THROUGH BAMBOOPIELINES

    1853----------OIL DISTILLED BY POLISH SCIENTISTIGNANCYLUKASIEWICZ AND IN 1854 FIRST REFINERY WAS SET UP

    BY MR LUKASIEWICZ

    1859--- ------------OIL DISCOVERED BY COL DRAKE IN PENSYLVANIA, USA

    1866-----------------OIL FOUND BY MR GOODENOUGH IN UPPER ASSAM

    1889-----------------OIL PRODUCTION STARTED UNDER ASSAM RAILWAY &

    TRADINGCORPORATION

    1901-----------------500 BARRELS PER DAY REFINERY SET UP IN DIGBOI,

    ASSAM

    2005------- ABOUT 2135 BILLION BBLS/DAY REFINING CAPACITY

    (17 REFINERIES) IN INDIA

    ABOUT 81995 BILLION BBLS/DAY REFINING CAPACITY(739 REFINERIES) IN WORLD

    A FEW HISTORICAL MILESTONES IN PETROLEUM

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    What Is Crude Oil?

    Crude Oil is a liquid mixture ofthousandsof organic chemicals found underground. Itis the result of organic matter decaying overthousands of years; hence the namefossilfuel

    Crude oil is found all over the world and variestremendously in its density, aromatics, sulfur, andmetals content Crude oil is found all over theworld and varies tremendously in its density,aromatics, sulfur, and metals content

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    So, HowDo You Make Good Stuff Out

    Of Crude? Separate crude into fractions

    Convert low octane components to higher

    octane components Convert the very heavy stuff to heavy oils

    Convert heavy oils togasoline,diesel,jet fuel

    Remove sulfur/nitrogen through reaction Blend intermediate streams together to meet

    product specifications

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    Crude oil is a finite resource. It is estimated that there is a total of

    2,390 billion barrels (380 km) of crude oil on Earth. Estimates ofundiscovered reserves range widely from 275 to 1,469 billion

    barrels (44 to 234 km).

    Between 1859 and 1968, 200 billion barrels (31 km) of oil were

    used, and since then oil production has stabilized at 22 billion

    barrels (3.5 km) per year. In 2004, as prices reach record highs,

    world consumption is on track to 30 billion barrels per year.

    It is believed that about 77% of crude oil has already been

    discovered, and 30% of it has been used so far. Current estimates

    are that oil reserves will become scarce by the 2050s, although thisdate has been pushed forward many times as new oil wells are

    discovered.

    Some observations w.r.t. Crude Reserve and consumption

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    Refineries

    Refineries are very complicatedchemical

    processing plants that use reactions and

    separations to convert crude oil into gasoline andother valuable products

    The purpose of an oil refinery is to transform

    relatively low value crude oil into high value

    products as efficiently, profitably and

    environmentally sound a way as possible

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    Distillation The initial separation takes place

    in the distillation Column

    The Crude is first heated in a furnaceto a temperature of 360 oC

    It enters the column and vapours and

    liquids separate

    The light vapours rise to the top whilst

    the heavier liquids fall to the bottom

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    Distillation (Atmospheric and Vacuum)

    This is the first stage in the refining for separating crude oil

    components at atmospheric pressure by heating, and subsequent

    condensing, of the fractions (unfinished petroleum products) by

    cooling.

    Distillation under reduced pressure (less than atmospheric) i.e.

    Vacuum Distillation lowers the boiling temperature of the liquid

    being distilled permitting the production of distillates at lowertemperature than would be necessary in atmospheric distillation,

    thus avoiding coke formation.

    The Jamnagar Refinery has a combined Crude Distillation Unit /

    Vacuum Distillation Unit (CDU / VDU) to separate the crude oil into

    primarily fractions of LPG, Naphtha, Kerosene, Gasoil, Vacuum Gas

    Oil and Vacuum Residue. The combined CDU/VDU maximizes

    energy integration to minimize the energy required for primary

    separation.

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    http://en.wikipedia.org/wiki/Image:ShellMartinez.jpghttp://en.wikipedia.org/wiki/Image:ShellMartinez.jpg
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    Furnace

    Distillation Column

    Crude

    Kerosene

    Gases +Tops + Naphtha

    Light Gasoil

    Heavy Gasoil

    Long Residue

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    Diesel

    Gas Oil

    CrudeOil

    Bitumen

    Roads

    Long Chain Molecules

    Gas treatmentSulphur

    RecoverySulphur

    H2S H2S

    Waxy Distillate

    Butane

    De-asphalting

    AsphaltFuel oil

    De-asphalted oil DAO

    Desulphurisation

    Kerosine

    Shorter Chain Molecules

    Hydrogen

    ManufacturingUnit

    Hyrdr

    ocracker

    Hydrogen

    High Vacuum

    Separation

    Vacuum Gas Oil

    Long Residue

    Distillation

    Diagram of Refinery Units

    Platformer Petrol

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    GASOILS32%

    JET/ KERO14%

    MOGAS30%

    FUEL AND LOSS7%

    FUEL OILS17%

    Approx 7 Barrels to the Tonne

    A Typical Crude Barrel

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    NATURAL

    GAS

    C3/C4 (LPG)

    NAPHTHA

    ETHANE

    KEROSENE

    CATALYTIC

    REFORMING

    GAS CRACKER

    GAS OIL

    FCC

    PROPYLENE

    BUTANE

    METHANESTEAM

    REFORMING

    HYDROGEN

    ETHYLENE GLYCOL

    ETHYLENE DICHLORIDE

    POLY PROPYLENE

    ACRYLONITRILE

    TOLUENE

    O-XYLENE

    P-XYLENE

    BUTADIENE

    MALEIC ANHYDRIDE

    POLYISOBUTYLENE

    POLYBUTADIENE

    ETHYL BENZENE STYRENE

    CUMENE PHENOL

    POLY ETHYLENE TEREPHTHALATE

    ETHYLENE OXIDE

    POLY VINYL CHLORIDEPOLYETHYLENE

    METHYLMETHACRYLATE

    METHANOLFORMALDEHYDE ACETIC ACID

    LINEAR ALPHA OLEFIN

    POLYACRYLONITRILE

    CARBON FIBRE

    RESIDUE

    CRU

    DE

    OIL

    NAPHTHA

    CRACKER

    BENZOIC ACID

    PHTHALIC ANHYDRIDE

    DETERGENT

    CYCLO HEXANE CAPROLACTUM

    POLYCARBONATE

    SYNTHESIS GAS

    BUTYLENE BIS-PHENOL A

    BENZENE

    OVERVIEW OF REFINERY & PETROCHEMICAL PRODUCTS

    ABS

    RUBBER

    STYRENE

    BUTADIE

    NE

    RUBBER

    ACRYLO

    NITRILE

    BUTADIE

    NE

    RUBBER

    POLY

    STYRENE

    ETHYLENE

    NYLON 6

    GASOLINE

    HYDROCRACKING

    DIESEL

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    Major Refinery Products

    LPG (Propane/Butane)

    GASOLINE (hundreds of blends)

    JET FUELS

    DIESEL FUELS

    HEATING OILS

    GREASES

    ASPHALTS

    COKE (not the kind you drink )

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    Top petroleum-producing countriesSource: Energy Statistics from the U.S. Government

    (Ordered by amount (barrels per dayproduced in 2004):

    Saudi Arabia (OPEC)

    RussiaUnited States

    Iran (OPEC)

    Mexico

    China

    Norway

    Canada

    Venezuela (OPEC)

    United Arab Emirates (OPEC)

    Kuwait (OPEC)

    Nigeria (OPEC)

    United Kingdom

    Iraq

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    Ordered by amount exportedin 2003:

    Saudi Arabia (OPEC)

    Russia

    Norway

    Iran (OPEC)

    United Arab Emirates (OPEC)

    Venezuela (OPEC)

    Kuwait (OPEC)

    Nigeria (OPEC)

    Mexico

    Algeria (OPEC)

    Libya (OPEC)

    Note that the USA consumes almost all of its own production.Total world production/consumption (as of 2005) is approximately 84 million

    barrels per day.

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    Crude processed in India are:

    1. Indigenous crude oil sources

    a. Bombay high and satellite fields

    b. North Gujarat and Ankaleshwar crude

    c. Assam crudes

    d. KG Basin-Rava crude

    e. Cauvery Basin crude

    All the above crudes are low sulphur =

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    2. Imported crudes are sourced mostly from:

    a. Gulf Region

    b. Nigeria

    c. Malaysia

    d. Australia

    The above crudes are specially selected for production of Bitumen/LOBS/ATF, beside fuel

    products.

    These crudes are having varying range of sulphur from low of high.

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    OIL PRICE DURING 1860 TO 2000

    http://en.wikipedia.org/wiki/Image:Oil_Prices_Short_Term.pnghttp://en.wikipedia.org/wiki/Image:Oil_Prices_Medium_Term.png
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    Country/Region OIL Natural Gas

    As on Jan.1 2005 As on Jan.1 2005

    Billion barrels % Trillion Cuft. %Middle east 729.341 57.08 2522.125 41.76

    East Europe & 88.3 6.91 1964.16 32.52

    USSR

    Western Europe 16.255 1.27 182.487 3.02

    Central & 100.595 7.87 250.52 4.15South America

    North America 215.291 16.85 260.494 4.31

    (USA) 21.891 1.71 189.046 3.13

    (Canada) 178.8 13.99 56.6 0.94

    Asea & 36.246 2.84 383.913 6.36Oceania

    (India) 5.371 0.42 30.14 0.50

    Africa 100.784 7.89 476.509 7.89

    WORLD 1277.702 100.00 6040.208 100.00

    OIL & NATURAL GAS RESERVE

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    Country/Region Number of Crude Catalytic Thermal Reforming

    (All capacity Refineries Capacity Cracking Cracking

    Billion bbls/day)Middle east 46 6319 372 483 599

    East Europe & 88 10128 824 516 1396

    USSR

    Western Europe 112 15072 2236 1597 2220

    Central & 70 6634 1321 452 407

    South America

    North America 176 20425 6683 2392 4215

    (USA) 149 16757 5813 2254 3581

    Asea & 202 20205 2720 432 2019Oceania

    (India) 17 2135 167 93 42

    Africa 45 3213 195 78 387

    WORLD 739 81995 14352 5949 11243

    REFINING CAPACITY

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    REFINING CAPACITY IN INDIA (MMTPA) : AS ON 1.04.2000

    FIGS IN MT

    1 INSTALLED CAPICITY AS OF DATE PUBLIC JOINT PRIVATE TOTAL

    SECTOR SECTOR SECTOR

    1. IOC-DIGBOI 0.65 0.65

    2. BPCL-BOMBAY 6.90 6.90

    3. HPCL-BOMBAY 5.50 5.50

    4. HPCL-VIZAG 7.50 7.505. IOC-GAUHATI 1.00 1.00

    6. IOC-BARAUNI 4.20 4.20

    7. IOC-KOYALI 12.50 12.50

    8. IOC-HALDIA 3.75 3.75

    9. IOC-MATHURA 7.50 7.50

    11 IOC-PANIPAT 6.00 6.00

    12 CRL-COCHIN 7.50 7.50

    13 CPCL-CHENNAI 6.50 6.50

    14 BRPL-ASSAM 2.35 2.3515 MRL-NARIMANAM 0.50 0.50

    16 NRL - NUMALIGARH 2.35 2.35

    17 RPL - JAMNAGAR 27.00 27.00

    18 MRPL-MANGALORE 9.69 9.69

    SUB TOTAL 72.35 12.04 27.00 111.39

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    2. ADDITIONS IN REFINING CAPACITY

    A) PROJECTS APPROVED BY THE GOVT:

    Expected

    REFINERY EXPANSIONS Commissioning

    IOC-MATHURA 0.50 0.50 2000-01

    MRPL-MANGALORE 6.90 6.00 12.90 2000-01

    IOC-KOYALI 3.00 3.00 2000-01

    SUB TOTAL 10.40 6.00 16.40

    NEW REFINERIES

    CENTRAL INDIA (JVC-BPC) 6.00 6.00 2001-02

    SUB TOTAL 0.00 6.00 6.00

    B) PROJECTS UNDER CONSIDERATION (EXPANSION)IOC-PANIPAT (PSU) 3.00 3.00 2002-03

    IOC-BARAUNI 2.70 2.70 1999-02

    CRL-COCHIN 3.00 3.00 2002-03

    MRL-MADRAS 3.00 3.00 2002-03

    SUB TOTAL 11.70 11.70

    C) NET CAPACITY ADDITION (A+B) 22.10 12.00 34.10

    3. PROPOSED REFINERIES

    EAST COAST (JVC-IOC/PVT.PARTY) 12.00 12.00 X PLAN

    WEST COAST (JVC-HPC) 6.00 6.00 2002-03UP REFINERY (JVC-BPC/SHELL) 7.00 7.00 X PLAN

    PUNJAB REFINERY 6.00 6.00 X PLAN

    SUB TOTAL 31.00 31.00

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    4. PROPOSED PRIVATE SECTOR REFINERIES:

    ESSAR ( UNDER CONSTRUCTION ) 9.00 9.00 X PLAN

    ASHOK LEYLAND (GOTCO) 2.00 2.00 X PLAN

    SOROS 6.00 6.00 X PLAN

    NIPPON DENRO 9.00 9.00 X PLAN

    SUB TOTAL 26.00 26.00

    5. PROPOSED PRIVATE SECTOR REFINERIES (EOUs) LOI issued onINTERNATIONAL PETROLEUM 5.00 5.00 14.6.92

    BLACK GOLD 2.50 2.50 10.6.93

    PETRO ENERGY PRODUCTS 4.80 4.80 22.6.94 (FIPB)

    JINDAL FERRO 6.00 6.00 22.9.94 (CCFI)

    TIDCO 2.00 2.00 17.9.94 (CCFI)

    ABAN LLOYD 3.00 3.00 12.1.95 (FFCI)

    MOPLACE UDYOG 3.00 3.00 14.3.96

    SUB TOTAL 26.30 26.30

    6. TOTAL (1+2+3+4+5) 94.45 55.04 79.30 228.79

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    Oil Refining Companies in India (As on 31stMarch 2001)

    Name of the Oil

    company

    Principal Shareholders Location of refineries Capacity

    (million

    tons/year)

    Age of refineries

    (years)

    Indian Oil Government of India (82%) Gujarat 12.5 36

    Mathura 7.5 19

    Panipat 6.0 3

    Barauni 4.2 37

    Haldia 3.8 27

    Guwahati 1.0 39

    Digboi 0.7 100

    Reliance Petroleum Reliance Industries, its subsidiaries

    and associates (65.8%)

    Jamnagar 27.0 2

    Hindustan Petroleum Government of India (51%) Vizag 7.5 44

    Mahul 5.5 47

    Mangalore Refineriesand Petrochemicals

    Limited

    Hindustan Petroleum (37%)/AdityaBirla Group (37%)

    Mangalore 9.6 5

    Kochi Refineries Bharat Petroleum (55%) Kochi 7.5 35

    Chennai Petroleum Indian Oil Corporation (52%) Chennai 6.5 32

    Narimanam 0.5 7

    Bharat Petroleum Government of India (66%) Mahul 6.9 46

    Bongaigaon Refineries Indian Oil Corporation (75%) Bongaigaon 2.4 22

    Numaligarh Refineries Bharat Petroleum (51%) Numaligarh 3.0 2

    Total 112.1

    Source: Annual Reports &Industry Data

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    Oil production & consumption in India (Million tons)

    1997 1998 1999 2000 2001

    Crude oil production 32.9 33.9 32.7 32 32.5

    Crude oil consumption 62.9 65.2 68.5 86 103.5

    Deficit (Met by Imports) (33.9) (34.5) (39.8) (54.0) (71.0)

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    Growth & Development of Refinerieries in

    India

    1866 Oil discovery at Nahorpung, Assam.

    1889 Oil Production started at Digboi, Assam.

    1893 First Refinery started at Margharita, Assam.

    1899 Assam Oil Company was formed.

    1901

    Digboi Refinery was commissioned

    supplanting the earlier refinery at Margarita.

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    Year Incident

    1947-1957

    Setting up of three coastal refineries by

    Multi National Oil Companies (MNCs)

    2 at Mumbai (Esso & Burmah Shell)

    1 at Vizag (Caltex)

    The MNCs were already marketing

    petroleum products in India by then.

    1954

    Indian Oil exploration with the help of

    Russian Geologists.

    1956

    Formation of Oil and Natural GasCommission for exploration and

    production of crude oil and gas.

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    Year Incident

    1958

    Indian Refineries Ltd (IRL) was formed in

    the public sector to install refineries and

    pipelines in India.Oil India Ltd (OIL) was formed as a joint

    venture company between Government

    of India and Burmah Oil Co.

    1959

    Indian Oil Company formed for

    marketing petroleum products.

    1962

    The first refinery in the public sector

    commissioned at Guwahati (0.75

    MMTPA) under IRL.

    1963

    Indian Oil Blending Ltd. -A JV between

    Indian Oil Co. and Mobil Petroleum Co.

    Inc. was formed for manufacture of lube

    oils and greases.

    1964

    IRL was dissolved and merged withIndian Oil Co. Ltd, to form Indian Oil

    Corporation Ltd. (IOCL)

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    Year Incident

    1974 IOBL became part of IOCL.

    1981

    Assets of erstwhile Assam Oil Co. were

    taken over and vested in IOC as Assam

    Oil Division (AOD).

    1998 Panipat Refinery of IOC commissioned.

    1999

    Reliance Petroleum Refinery at

    Jamnagar, commissioned.

    2000 Numaligarh refinery commisssioned.

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    Year Incident Total Refining Capacity

    MMTPA

    2002-03 135

    Barauni Expansion

    Haldia Expansion

    HPCL, Mumbai ExpansionCPCL, Nagapatinam

    RPL Expansion

    Future Outlook (as per 2025 vision document)

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    Year Incident Total Refining Capacity

    MMTPA

    2003-04 170

    Koyali Expansion

    Panipat Expansion

    BPCL Expansion

    CPCL ExpansionBRPL Expansion

    Paradip

    Essar Oil Expansion

    Nagarjuna Oil

    Future Outlook (as per 2025 vision document)

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    Year Incident Total Refining Capacity

    MMTPA

    2004-05 176

    Kochi Refinery Expansion

    2005-06 214

    Essar Oil Expansion

    RPL Expansion

    Bhatinda

    2006-07 BRPL Expansion 221

    Bina

    Future Outlook (as per 2025 vision document)

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    Strategies for Indian Refineries

    Residue upgradation technologies for heavy crudes

    Technologies for producing lighter fuels.

    Process technologies to improve quality with

    respect to :

    - performance parameters- eco-friendly products

    Value addition to refinery streams

    Increased emphasis on Process Control/

    Automation

    Evolutionary/innovative technological changes

    expected rather than evolutionary ones.

    Refineries to be integrated, compact and flexible

    with respect to crude/ product mix.

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    Future Technological Challenges

    Meeting higher demand of petroleum

    products (viz. distillates)

    Meeting higher standards of product

    qualities.

    More emphasis on environment

    Value addition to refineries

    Technologies to improve margins

    Zero emission refinery

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    DISTILLATION RANGE IMPROVEMENT

    New residue conversion technologies like FCC,

    Hydrocracker, RDS-RFCC

    Advanced controls and optimisation

    Advanced catalysts

    Continuous simulation of plants/product mix through

    computer models

    Prudent selection of technologies and proper

    integration of secondary units/ plants.

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    REFINING CAPACITY IN INDIA AS IN THE YEAR 2002

    No Refineries MMTPA

    Year of

    Commissioning

    1 Indian Oil Corporation Limited, Digboi 0.65 1901

    2 Indian Oil Corporation Limited, Guwahati 1.00 1962

    3 Indian Oil Corporation Limited, Barauni 3.30 (6.0) 1964

    4 Indian Oil Corporation Limited, Koyali 13.5 (18) 1965

    5 Indian Oil Corporation Limited, Haldia 3.75 (7.5) 1974

    6 Indian Oil Corporation Limited, Mathura 7.50 1982

    7 Hindustan Petroleum Corporation Limited, Vizag 7.50 1975

    8 Hindustan Petroleum Corporation Limited, Mumbai 5.50 1954

    9 Bharat Petroleum Corporation Limited, Mumbai 8.90 1955

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    No Refineries MMTPA

    Year of

    Commissioning

    10

    Cochin Refineries Limited, Cochin

    7.50 (10.5)

    1966

    11Chennai Petroleum Corporation Limited, Chennia

    6.50 (9.5)1969

    12 Bongaigaon Refineries Limited, Bongaigaon 2.35 1972

    13

    Madras Refineries Limited (CBR), Nagapatinam

    0.50

    1994

    14 Mangalore Refineries & Petrochemicals Ltd.,

    Mangalore6.00 (9.0)

    1995

    15 Indian Oil Corporation Limited, Panipat 6.00 1998

    16 Reliance Petroleum Limited, Jamnagar 27.00 1999

    17 Numaligarh Refineries Ltd., Numaligarh 3.00 2000

    Total Capacity

    112.45

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    ADVANCES IN PETROLEUM REFINING

    Various issues faced by the refining industry have

    led to many major developments in this area. The

    challenges are:

    1. Crude oil is becoming heavier and higher in

    sulphur and metal content.

    2. Reduced growth in fuel oil demand.

    3. Rapid growth in light/middle distillates.

    4. Stringent environmental regulation for cleaner

    products/processes and demand for quality

    products.

    5. Declining refining margins

    6. Improved engine design/automobiles need better

    quality fuel and lubricating oils.

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    Advances in refining technology can bebroadly divided into the following

    categories.

    Improved and integrated refining

    Production of better quality products

    Processing of residues/heavier ends

    Management of power and utilitues.

    Value addition through optimisation of refineryconfiguration

    Petrochemicals production

    Better quality and increased lube oil production

    Power generation from heavier petroleumproducts.

    Specialty chemicals production.

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    Improvements are taking place in many

    areas. Some of them are listed below

    Distillation

    Fluid Catalytic Cracking (FCC), Resid Fluid

    Catalytic cracking (RFCC).

    Delayed coking Needle coke manufacturing,

    Visbreaker-Soaker Technology.

    Hydro processing

    Hydro treatment of various streams including

    residues.

    Hydro cracking

    Super Oil Cracking (SOC) of heavy distillates

    to get 90% conversion to distillates.

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    Improvements are taking place in many areas. Some of

    them are listed below

    Mobile Distillate De-Waxing (MDDW) to upgrade heavy

    fuel oil to high quality distillate and gas yield of 93-95%.

    Isomerisation

    Catalytic Reforming

    Alkylation

    Etherification

    Power generation by petroleum residue and coke by using

    Gasification Combined Cycle (GCC) technology.

    In this process along with power, steam and H2 can be

    produced which are required in the refinery.

    More and more use of information technology.

    Modeling simulation

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    Refinery integration and value addition strategies

    Small an Medium Refineries Integration with Specialty Chemical

    Production Units for Value addition

    Anode Grade Coke Needle Coke

    Production Microcrystalline Wax Production

    Alpha-Olefins Production

    Larger Refineries

    Petrochemicals and Specialty Products

    Integration of Refining and Power Generation Integration of Fuels and Lube Production

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    Thank you

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