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Diamond Field Emitter Arrays Diamond Field Emitter Arrays on Micromachined Silicon on Micromachined Silicon Nano Science & Engineering Lab Nano Science & Engineering Lab ECE ECE Old Dominion University Old Dominion University Norfolk, Virginia 23529 Norfolk, Virginia 23529 Dr. Wehai Fu Dr. Wehai Fu Dr. Sacharia Dr. Sacharia Albin Albin

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  • Diamond Field Emitter Arrayson Micromachined Silicon

    Nano Science & Engineering Lab

    ECE

    Old Dominion University

    Norfolk, Virginia 23529

    Dr. Wehai Fu

    Dr. Sacharia Albin

  • Outline

    Summary

    Introduction

    Field emission

    Experiments

    I

    II

    III

    IV

    Field emission and applications

    Advantages of diamond field emitters

    Project goal

    Fowler-Nordheim field emission

    Field emission enhancement

    Silicon tip array fabrication

    Diamond emitter fabrication

    Results and discussion

    V

    Silicon tip array wet etching

    Diamond film characterization

    Diamond emitter I-V characteristics

  • I. Introduction

    Thermal excitation

    Photo excitation

    Tunneling

    Electron emission mechanisms

    Surface barrier

    Surface barrier bending

    due to applied field

    Advantages of field emission

    Low energy consumption

    High current density

    Small device size (sharp tips)

  • Cold cathode

    Flat panel display

    Vacuum microelectronic device

    Microsensor

    Scanning probe microscope

    for surface imaging

    Anode

    Gate

    Emitter

    Probe

    Gate

    Emitter array

    Phosphor

    Conductive

    coating

    5 mm

    d

    E-beam

    Emitter array

    Extracting

    gate

    Focusing

    electrode

    Field Emission Applications

    Pressure

    I. Introduction

  • Requirements for applications:

    Drawbacks of metal and silicon emitters:

    Low turn-on voltage

    Large emission current

    Uniform over the array

    Stable emission

    High extracting field

    Sputtering damage

    Surface adsorption

    Emitter overheating

    Anode

    Emitter

    I. Introduction

  • Diamond Field Emitter

    Hardest known material

    10,400 kg/cm2

    Highest thermal conductivity

    20 W/cm-oC

    5 times larger than copper

    Chemically inert

    Small effective work function

    Properties of diamond

    Advantages for field emission

    Low threshold voltage for electron emission

    Resistance to sputtering damage by residual gas

    Efficient and fast thermal dissipation

    Robust performance in harsh environment

    I. Introduction

  • Research Developments

    1928 Field emission theory proposed (Fowler and Nordheim)

    1968 First metal field emitter with self-aligned gate demonstrated (Spindt)

    1990 Silicon field emitter array with self-aligned gate developed (Betsui)

    1979 Negative electron affinity (NEA) of diamond discovered (Himpsel)

    1976 Enhanced chemical vapor deposition (CVD) diamond developed (Deryagin)

    1994 Mold-filled CVD diamond tip array fabricated (Okano)

    1997 Diamond film coated silicon sharp tips demonstrated (Zhirnov)

    1997 Diamond tips for tunneling microscopy developed (Albin)

    Year

    Highlights

    I. Introduction

    1999 Diamond field emitter arrays with self-aligned gate succeeded (Albin)

  • Project Goal

    Scanning electron microscopy

    Optical emission spectroscopy

    Raman spectroscopy

    I-V measurement

    Design, fabricate, and characterize diamond

    field emitter arrays using:

    Silicon surface micro-machining

    Plasma enhanced CVD diamond

    I. Introduction

  • Surface Energy Barrier#

    Image Charge

    Applied Field

    Combined effect

    # S. O. Kasap, Principles of Electrical Engineering Materials and Devices (McGraw-Hill, 1997).

    II. Field Emission

    f

    Ef

    Ef

    Ef

    x

    x

    x

    f

    Feff

    f

    - exF

    Pe(x)

    Pext(x)

    P(x)

    Schottky barrier

    reduction

    d

    Surface barrier

    thinning

    Vacuum

    Level

    Vacuum

    Level

    Vacuum

    Level

  • Fowler-Nordheim Equation#

    m mass of electron work function of the cathode y function of F and t(y), v(y) approximated as constants

    # R. H. Fowler and L. W. Nordheim, Proc. R. Soc. London A119, 173 (1928).

    J emission current density e electron charge h Plancks constant F electric field at cathode

    II. Field Emission

    Field Emission Current Density

    N(T,S): electron density

    D(F,s,): tunneling probability

    s: kinetic energy

    T: temperature

    F: applied field

    : work function

  • F-N Plot

    Where:

    Simplified F-N Equation#

    a emitting area

    f emitter work function

    field enhancement factor

    # C. A. Spindt, I. Brodie, L. Humphrey, and E. R.Westerberg, J. Appl. Phys. 47, 5248 (1976).

    5.5 eV

    3 eV

    2 eV

    5 eV

    4 eV

    I-V Plot

    F-N Plot

    II. Field Emission

    or

    (400 tip array with a tip radius of 20 nm and a field enhancement factor of 105 cm-1)

    Chart2

    8.65800487535904E-818.98218814371246E-1481.1467959517898E-22600

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    179.22319291246.74555650220.37197868690.02216635310.0053667978

    Voltage (v)

    Emission current (A)

    Sheet1

    23455.523455.5

    00000012345108.65800487535904E-818.98218814371246E-1481.1467959517898E-22600

    0.19.15750515662924E-719.50039130584971E-1381.21295725670061E-2166.29470527876383E-306021439.194519435552.43E+091.97E+107.67E+10201.23880013403641E-401.65922232206053E-743.43403471217E-1145.31747475183195E-1593.63974245165202E-183

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    0.10416666679.6-8.6466853023-11.9899671892-14.9630064776-17.8686066436-19.3330585488

    Sheet1

    9.15750515662924E-719.50039130584971E-1381.21295725670061E-2166.29470527876383E-3060

    1.31026937253847E-301.75494668679479E-643.63215209941037E-1045.6242521413604E-1493.84972759309348E-173

    4.5086956111284E-176.57557789277513E-401.59869662286773E-661.65420919464718E-961.15798386450892E-112

    0.00000000031.50853412998997E-271.25705212673937E-473.36232328845558E-702.38026316618985E-82

    0.00000441934.35332820547517E-203.02412102075181E-362.26653501996054E-544.05762585410012E-64

    0.002758155301.25096615976991E-288.64955076180169E-446.19230713763773E-52

    0.287086923503.61813515274466E-233.28154985559194E-363.27482046374012E-43

    9.69668174660.00000000884.67711354235979E-191.64420819128751E-301.18372946988884E-36

    154.04129850360.00000116817.58405110216937E-164.5844838435867E-261.53484669690174E-31

    1439.19399831660.000059398301.68743985762204E-221.93190596913337E-27

    9121.36176950530.001505675201.42142286948747E-194.45016653167975E-24

    43145.21249029350.02260919660.00000000223.95571603786175E-172.86389753360995E-21

    162762.0978763110.22667572610.000000070606.90277330114284E-19

    513542.9236669911.65304607460.000001388607.68372420688193E-17

    1403470.92216159.33800075770.000018534300

    3410935.9277909242.83990894290.00018043480.00000000020

    7522568.82874859165.50226222830.00135388860.00000000370

    15294423.0390804553.83733520140.00817399590.00000004320.0000000001

    29027019.5021241641.65841642650.04108015130.00000039510.0000000009

    51943555.47072774388.13647582880.17660244470.0000029120.0000000084

    88360951.309050110731.98294948520.66391101440.00001782740.0000000672

    143844920.06427124302.53172101962.22239266710.00009296760.0000004451

    225342379.99083751460.39827211696.72390936960.00042162090.0000025121

    341286850.625046102734.66102054618.61787794610.00169188520.000012318

    501674663.178503194710.51300523447.67623018350.00609525450.0000533652

    718111687.988366352402.548905532113.91923878310.01995870970.0002071739

    1003831752.05693612126.433216778255.92221623550.06002775830.0007294813

    1373688978.83721024858.00074753544.07675208910.16732561510.0023539319

    1844126966.374231660046.057028451100.7595533520.43565077880.0070235275

    2433128087.782152609825.032139152129.71348366341.06661592710.0195283023

    3160146316.377313993557.40691263957.23518664532.47015049970.0509396112

    4046026910.878565962624.126828667087.96185437985.4390092920.1254001517

    5112916100.666848705374.2031820412278.133754520911.43834811780.2928542265

    6384163634.1637312452142.140503820629.165979977823.06695594960.6517954787

    7884220731.9231117480243.218121933704.189561014444.76514739941.3881818263

    9638535647.7929424118861.324390453669.925161680583.86524000982.8394222522

    11673448706.356932753751.258031783465.8467256035152.10333736115.5958578193

    14016088366.220543831686.4389761127002.098326891267.734964213910.6564859144

    16694269564.939557864593.1312177189387.069577122458.420944883119.6608143172

    19736395337.070775433322.9771657277184.939268992765.072680262335.2246318251

    23171362463.768397191026.3811598398702.8891721311246.866546580161.4140436346

    27028471710.4347123866099.66712564307.0938008561987.6544533895104.3991906832

    31337343036.7788156264688.678579786766.0282872883104.0107277826173.3364565186

    36127836019.0463195272740.3848391081619.122237634755.1636819824281.5354321007

    41429975604.5806241857601.978041467568.335610987155.0629312886447.9742047763

    47273883221.4556297069173.8296521966889.8521847510586.8304502793699.233399727

    53689713187.9414362040628.5092142605862.78219715419.83441393441071.9255720002

    60707594305.3542437988712.8796383415211.5400113922129.61021772881615.7017832736

    68357576470.9524526213654.126724430558.4139516331320.83305905412396.9212862746

    76669582112.7276628098693.5294755692882.7702428943753.52161465483503.0730046641

    85673362223.203745109273.9178427248983.3259016660372.62332332655048.0388037732

    95398456752.9435878791908.1862789151939.9797460182341.09933543067178.2883113392

    105874159114.8631030772757.0281811461571.7989324111076.59213611510080.0932288826

    117129484546.2841202755944.3168914244887.9126073148291.72202741313987.8456821199

    129193142075.9151396521638.3700817576528.2563438196038.0208986219193.5602452887

    142093509846.5711613923926.774321539191.3331512256753.4738236826057.6329312662

    155858613550.6851856888511.5891126224046.4015163333313.60174241735020.9227924066

    170516107743.9112127410250.6581931731127.7612392429085.98248065946618.2129789122

    186093259811.7092427550569.4875938169709.0774629547988.07323022261493.0983257575

    202616936374.4372759434766.756845658655.956687694548.16584011780414.3359731711

    220113591927.6513125249235.0499454326755.2608556873969.277268244104293.684364508

    238609259525.8743527238616.8689464313019.91266971092195.75161796134205.244405877

    258129543329.6723967702914.4465475766968.20368641355982.32755639171406.30480745

    278699612847.4414448994570.3409888848876.86375091672965.40571645217359.681842448

    300344198714.5814973515534.28518103730007.3837042051736.23498124273757.532130035

    323087589863.7085543714330.29697120592805.3015212501915.7243267342546.605732129

    346953631950.1046162083136.64649139631072.3639313034230.57808599425954.895993819

    371965726906.736831154889.92986161050111.6605093660590.44697536526519.632277266

    398146833512.6857553500423.22289185066845.9948044394165.78482224647116.552145137

    425519468868.118331725647.08711211909909.9074375249466.10146549790990.380728326

    454105710677.0949168468781.07667241819715.8993376242418.30553174961786.437031692

    483927200248.15210066397642.3489275048495.5200437390444.836491551163583.27984044

    515005146129.40511028206997.0126311860316.0867878712541.293311631400926.29972118

    547360328302.56712056615978.9555352531073.88574110229353.2768891678862.15838227

    581013102866.41913154365580.0753397348464.77820511963252.1750222002973.97237048

    615983407146.48614324216215.0889446611933.19254613938409.63168822379417.13472404

    652290765173.27215568945363.4182500632600.5283816180870.45661822814955.66575502

    689954293476.61416891345290.0334559733174.03376718718623.7463353316998.98256416

    728992707148.51418294220846.583624247837.24008621581672.00376143893638.97615995

    769424326131.23419780387353.6413694522123.05371224802098.05996394553687.28511411

    811267081691.55321352668564.4621770912770.60963328414129.61841245306712.65548666

    854538523045.78123013894710.2332853787566.9905632454201.25912576163078.27823965

    899255824103.6524766900626.4776943525174.90683336961013.75706357133978.99747236

    945435790302.27726614523959.94381040514947.418341975590.58600098231478.28549111

    993094865504.38328559603455.05921145156730.7600947541331.49572969468544.88391539

    1042249138937.5330604977318.79121257860656.3107353704063.066684210859089.0136581

    1092914352153.6532753481662.56181379046922.7134660512086.161883112417998.0606413

    1145105905990.2135007949019.69331509145569.1316168016220.211325714161171.6484649

    1198838867516.6237371206936.72081648596240.5856376269844.278639616105556.0138769

    1254127976951.139846076636.7911797847946.2844885328934.87376218269177.6057474

    1310987654535.0342435371753.26951957358811.8277695252100.488734220671175.8332769

    1369432007353.3445141897131.6062127595826.11709106100612.84624423331834.8943227

    1429474836090.8647968447697.44592309034583.77687117938434.86236526272614.6199623

    1491129641715.7650917807388.93732502159023.84586130832245.33598329516180.276692

    1554409632082.653992748151.15242707461165.4617144851460.3876633086431.2729435

    1619327728448.0957196028990.52762925440841.22192160068251.68020937008528.7218529

    1685896571894.2560530395087.22143156605428.86626176557561.4619741308921.8174181

    1754128529653.7863998576963.29423401469581.88698194397114.48177746015372.9862884

    Electric Field (107 V/cm)

    Current Density (A/cm2)

    Sheet2

    1/F (10-7 cm/V)

    ln (J/F2) (ln(A/V2)

    10

    10

    10

    10

    10

    5

    5

    5

    5

    5

    3.3333333333

    3.3333333333

    3.3333333333

    3.3333333333

    3.3333333333

    2.5

    2.5

    2.5

    2.5

    2.5

    2

    2

    2

    2

    2

    1.6666666667

    1.6666666667

    1.6666666667

    1.6666666667

    1.6666666667

    1.4285714286

    1.4285714286

    1.4285714286

    1.4285714286

    1.4285714286

    1.25

    1.25

    1.25

    1.25

    1.25

    1.1111111111

    1.1111111111

    1.1111111111

    1.1111111111

    1.1111111111

    1

    1

    1

    1

    1

    0.9090909091

    0.9090909091

    0.9090909091

    0.9090909091

    0.9090909091

    0.8333333333

    0.8333333333

    0.8333333333

    0.8333333333

    0.8333333333

    0.7692307692

    0.7692307692

    0.7692307692

    0.7692307692

    0.7692307692

    0.7142857143

    0.7142857143

    0.7142857143

    0.7142857143

    0.7142857143

    0.6666666667

    0.6666666667

    0.6666666667

    0.6666666667

    0.6666666667

    0.625

    0.625

    0.625

    0.625

    0.625

    0.5882352941

    0.5882352941

    0.5882352941

    0.5882352941

    0.5882352941

    0.5555555556

    0.5555555556

    0.5555555556

    0.5555555556

    0.5555555556

    0.5263157895

    0.5263157895

    0.5263157895

    0.5263157895

    0.5263157895

    0.5

    0.5

    0.5

    0.5

    0.5

    0.4761904762

    0.4761904762

    0.4761904762

    0.4761904762

    0.4761904762

    0.4545454545

    0.4545454545

    0.4545454545

    0.4545454545

    0.4545454545

    0.4347826087

    0.4347826087

    0.4347826087

    0.4347826087

    0.4347826087

    0.4166666667

    0.4166666667

    0.4166666667

    0.4166666667

    0.4166666667

    0.4

    0.4

    0.4

    0.4

    0.4

    0.3846153846

    0.3846153846

    0.3846153846

    0.3846153846

    0.3846153846

    0.3703703704

    0.3703703704

    0.3703703704

    0.3703703704

    0.3703703704

    0.3571428571

    0.3571428571

    0.3571428571

    0.3571428571

    0.3571428571

    0.3448275862

    0.3448275862

    0.3448275862

    0.3448275862

    0.3448275862

    0.3333333333

    0.3333333333

    0.3333333333

    0.3333333333

    0.3333333333

    0.3225806452

    0.3225806452

    0.3225806452

    0.3225806452

    0.3225806452

    0.3125

    0.3125

    0.3125

    0.3125

    0.3125

    0.303030303

    0.303030303

    0.303030303

    0.303030303

    0.303030303

    0.2941176471

    0.2941176471

    0.2941176471

    0.2941176471

    0.2941176471

    0.2857142857

    0.2857142857

    0.2857142857

    0.2857142857

    0.2857142857

    0.2777777778

    0.2777777778

    0.2777777778

    0.2777777778

    0.2777777778

    0.2702702703

    0.2702702703

    0.2702702703

    0.2702702703

    0.2702702703

    0.2631578947

    0.2631578947

    0.2631578947

    0.2631578947

    0.2631578947

    0.2564102564

    0.2564102564

    0.2564102564

    0.2564102564

    0.2564102564

    0.25

    0.25

    0.25

    0.25

    0.25

    0.243902439

    0.243902439

    0.243902439

    0.243902439

    0.243902439

    0.2380952381

    0.2380952381

    0.2380952381

    0.2380952381

    0.2380952381

    0.2325581395

    0.2325581395

    0.2325581395

    0.2325581395

    0.2325581395

    0.2272727273

    0.2272727273

    0.2272727273

    0.2272727273

    0.2272727273

    0.2222222222

    0.2222222222

    0.2222222222

    0.2222222222

    0.2222222222

    0.2173913043

    0.2173913043

    0.2173913043

    0.2173913043

    0.2173913043

    0.2127659574

    0.2127659574

    0.2127659574

    0.2127659574

    0.2127659574

    0.2083333333

    0.2083333333

    0.2083333333

    0.2083333333

    0.2083333333

    0.2040816327

    0.2040816327

    0.2040816327

    0.2040816327

    0.2040816327

    0.2

    0.2

    0.2

    0.2

    0.2

    0.1960784314

    0.1960784314

    0.1960784314

    0.1960784314

    0.1960784314

    0.1923076923

    0.1923076923

    0.1923076923

    0.1923076923

    0.1923076923

    0.1886792453

    0.1886792453

    0.1886792453

    0.1886792453

    0.1886792453

    0.1851851852

    0.1851851852

    0.1851851852

    0.1851851852

    0.1851851852

    0.1818181818

    0.1818181818

    0.1818181818

    0.1818181818

    0.1818181818

    0.1785714286

    0.1785714286

    0.1785714286

    0.1785714286

    0.1785714286

    0.1754385965

    0.1754385965

    0.1754385965

    0.1754385965

    0.1754385965

    0.1724137931

    0.1724137931

    0.1724137931

    0.1724137931

    0.1724137931

    0.1694915254

    0.1694915254

    0.1694915254

    0.1694915254

    0.1694915254

    0.1666666667

    0.1666666667

    0.1666666667

    0.1666666667

    0.1666666667

    0.1639344262

    0.1639344262

    0.1639344262

    0.1639344262

    0.1639344262

    0.1612903226

    0.1612903226

    0.1612903226

    0.1612903226

    0.1612903226

    0.1587301587

    0.1587301587

    0.1587301587

    0.1587301587

    0.1587301587

    0.15625

    0.15625

    0.15625

    0.15625

    0.15625

    0.1538461538

    0.1538461538

    0.1538461538

    0.1538461538

    0.1538461538

    0.1515151515

    0.1515151515

    0.1515151515

    0.1515151515

    0.1515151515

    0.1492537313

    0.1492537313

    0.1492537313

    0.1492537313

    0.1492537313

    0.1470588235

    0.1470588235

    0.1470588235

    0.1470588235

    0.1470588235

    0.1449275362

    0.1449275362

    0.1449275362

    0.1449275362

    0.1449275362

    0.1428571429

    0.1428571429

    0.1428571429

    0.1428571429

    0.1428571429

    0.1408450704

    0.1408450704

    0.1408450704

    0.1408450704

    0.1408450704

    0.1388888889

    0.1388888889

    0.1388888889

    0.1388888889

    0.1388888889

    0.1369863014

    0.1369863014

    0.1369863014

    0.1369863014

    0.1369863014

    0.1351351351

    0.1351351351

    0.1351351351

    0.1351351351

    0.1351351351

    0.1333333333

    0.1333333333

    0.1333333333

    0.1333333333

    0.1333333333

    0.1315789474

    0.1315789474

    0.1315789474

    0.1315789474

    0.1315789474

    0.1298701299

    0.1298701299

    0.1298701299

    0.1298701299

    0.1298701299

    0.1282051282

    0.1282051282

    0.1282051282

    0.1282051282

    0.1282051282

    0.1265822785

    0.1265822785

    0.1265822785

    0.1265822785

    0.1265822785

    0.125

    0.125

    0.125

    0.125

    0.125

    0.1234567901

    0.1234567901

    0.1234567901

    0.1234567901

    0.1234567901

    0.1219512195

    0.1219512195

    0.1219512195

    0.1219512195

    0.1219512195

    0.1204819277

    0.1204819277

    0.1204819277

    0.1204819277

    0.1204819277

    0.119047619

    0.119047619

    0.119047619

    0.119047619

    0.119047619

    0.1176470588

    0.1176470588

    0.1176470588

    0.1176470588

    0.1176470588

    0.1162790698

    0.1162790698

    0.1162790698

    0.1162790698

    0.1162790698

    0.1149425287

    0.1149425287

    0.1149425287

    0.1149425287

    0.1149425287

    0.1136363636

    0.1136363636

    0.1136363636

    0.1136363636

    0.1136363636

    0.1123595506

    0.1123595506

    0.1123595506

    0.1123595506

    0.1123595506

    0.1111111111

    0.1111111111

    0.1111111111

    0.1111111111

    0.1111111111

    0.1098901099

    0.1098901099

    0.1098901099

    0.1098901099

    0.1098901099

    0.1086956522

    0.1086956522

    0.1086956522

    0.1086956522

    0.1086956522

    0.1075268817

    0.1075268817

    0.1075268817

    0.1075268817

    0.1075268817

    0.1063829787

    0.1063829787

    0.1063829787

    0.1063829787

    0.1063829787

    0.1052631579

    0.1052631579

    0.1052631579

    0.1052631579

    0.1052631579

    0.1041666667

    0.1041666667

    0.1041666667

    0.1041666667

    0.1041666667

    -188.8999889397

    -343.1364309613

    -524.796339811

    0

    0

    -97.8246355229

    -175.8203229501

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    -19.3330585488

    Work Function (eV)

    Current Density (A/cm2)

    2

    2

    2

    2

    2

    3

    3

    3

    3

    3

    4

    4

    4

    4

    4

    5

    5

    5

    5

    5

    5.5

    5.5

    5.5

    5.5

    5.5

    1439.194

    51943555

    2430000000

    19700000000

    76700000000

    0.0000594

    4388.136

    2609825

    75433323

    628000000

    0

    0.176602

    2129.713

    277184.9

    5692883

    1.69E-22

    0.00000291

    1.066616

    765.0727

    43753.52

    1.93E-27

    0.0000000084

    0.019528

    35.22463

    3503.073

    Voltage (v)

    Emission current (A)

    Sheet3

    Chart1

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    -30.5713360823-43.2176953656-57.2077254364-72.6083641159-80.8251175589

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    -18.7749551299-21.5464191751-23.842392103-25.9797926873-27.0293461303

    -18.7589770597-21.5170656663-23.7971991206-25.9166347926-26.9564803408

    -18.7434140043-21.4884745864-23.7531799818-25.8551173626-26.8855071693

    -18.7282500017-21.460616611-23.7102895389-25.7951773027-26.8163538226

    -18.7134698978-21.4334639009-23.66848493-25.7367547126-26.7489511936

    -18.6990592965-21.4069900085-23.6277254364-25.6797926873-26.6832336303

    -18.6850045126-21.3811697924-23.5879723499-25.6242371317-26.6191387229

    -18.6712925283-21.3559793377-23.549188851-25.5700365897-26.5566071059

    -18.6579109532-21.3313958819-23.5113398942-25.5171420849-26.4955822749

    -18.644847987-21.3073977465-23.474392103-25.465506973-26.436010416

    -18.6320923848-21.2839642732-23.4383136717-25.415086805-26.377840248

    -18.6196334245-21.2610757643-23.4030742736-25.3658391989-26.3210228745

    -18.607460877-21.238713428-23.3686449766-25.3177237218-26.2655116476

    -18.5955649784-21.2168593266-23.3349981636-25.2707017782-26.2112620394

    -18.5839364033-21.1954963287-23.3021074588-25.2247365075-26.1582315236

    -18.572566241-21.174608064-23.2699476586-25.1797926873-26.1063794637

    -18.5614459724-21.1541788821-23.2384946671-25.1358366433-26.0556670094

    -18.5505674487-21.1341938128-23.2077254364-25.0928361656-26.0060569999

    -18.5399228718-21.11463853-23.1776179095-25.0507604292-25.9575138723

    -18.5295047753-21.095499317-23.1481509683-25.0095799213-25.9100035771

    -18.5193060071-21.0767630348-23.1193043837-24.9692663715-25.8634934987

    -18.5093197132-21.0584170918-23.0910587697-24.9297926873-25.8179523803

    -18.4995393223-21.0404494157-23.0633955395-24.8911328935-25.773350254

    -18.4899585312-21.0228484268-23.0362968649-24.8532620751-25.7296583752

    -18.4805712915-21.0056030135-23.0097456384-24.8161563237-25.6868491606

    -18.4713717965-20.9887025085-22.9837254364-24.7797926873-25.6448961303

    1/V (1/V)

    ln(I/V2) (A/V2)

    Sheet1

    202.64368013052173E-453.54356890727403E-797.325527581101E-1191.14229799420822E-1637.77501898347378E-188400 tips with radius of 20 nm

    406.32344678286746E-253.04432836036757E-422.53529306407785E-626.80528234063405E-854.80408596407681E-97b= 10e5 cm-1

    605.56371287381822E-188.83766533281595E-302.52301854537045E-431.74862861262691E-581.24951956786857E-66

    8001.78462426942883E-239.43306428716453E-343.32207559490913E-452.38833598225963E-51

    10001.19830089237853E-195.78343351147276E-283.40824032865019E-373.89762793930845E-42

    1200.00000000014.56101061321648E-174.46365058355251E-247.98778719065231E-325.77767124683741E-36

    1400.00000000102.80063551684011E-215.73910533485507E-281.55007787118086E-31

    1600.000000006903.63910932578391E-194.64217157224046E-253.3679663457615E-28

    1800.000000030801.64857721847342E-178.71964174980045E-231.36432740413664E-25

    2000.000000104803.5618169170757E-165.87748529001078E-211.70070988215188E-23

    2200.0000002901001.87630880456338E-198.97868769772678E-22

    2400.00000068840.000000000203.4144513910213E-182.48477863784563E-20

    2600.00000144840.000000000704.02775626689451E-174.1790658669254E-19

    2800.00000277070.000000002103.37657638613955E-164.7482638008729E-18

    3000.00000490760.0000000053003.93915171705394E-17

    3200.00000816080.000000012002.5294954327909E-16

    3400.00001287680.0000000251000

    3600.00001944080.00000004860.000000000100

    3800.00002827030.00000008840.000000000300

    4000.0000398080.00000015220.000000000600

    4200.0000545160.00000024980.000000001100

    4400.00007286920.00000039390.000000002200

    4600.00009535050.00000059920.00000000400

    4800.00012244590.00000088340.000000006900

    5000.00015464080.00000126690.00000001150.00000000010

    5200.00019241640.00000177260.00000001850.00000000020

    5400.00023624720.0000024260.00000002870.00000000030

    5600.00028659890.00000325530.00000004340.00000000050.0000000001

    5800.00034392640.00000429110.0000000640.00000000090.0000000001

    6000.00040867280.00000556590.00000009210.00000000140.0000000002

    6200.00048126810.00000711450.00000012970.00000000220.0000000003

    6400.0005621290.00000897370.00000017920.00000000340.0000000004

    6600.0006516580.00001118180.00000024320.0000000050.0000000007

    6800.00075024360.00001377860.00000032480.00000000740.0000000011

    7000.00085825960.00001680520.00000042740.00000001060.0000000016

    7200.00097606590.00002030410.00000055470.00000001490.0000000023

    7400.00110400820.00002431840.0000007110.00000002060.0000000034

    7600.00124241840.00002889210.00000090080.00000002810.0000000048

    7800.0013916150.000034070.00000112890.00000003780.0000000067

    8000.0015519030.00003989720.00000140080.000000050.0000000092

    8200.00172357510.00004641920.0000017220.00000006550.0000000124

    8400.00190691140.00005368170.00000209860.00000008470.0000000166

    8600.00210218020.00006173040.00000253690.00000010830.0000000219

    8800.00230963830.00007061120.00000304370.00000013720.0000000286

    9000.00252953150.00008036960.0000036260.00000017210.0000000368

    9200.00276209520.00009105130.00000429110.0000002140.0000000471

    9400.00300755450.00010270120.00000504650.00000026390.0000000595

    9600.00326612480.00011536440.00000590020.00000032290.0000000746

    9800.00353801260.0001290850.00000686030.00000039210.0000000928

    10000.00382341510.00014390720.00000793510.00000047290.0000001145

    10200.00412252150.00015987430.00000913320.00000056670.0000001402

    10400.00443551250.00017702910.00001046350.00000067480.0000001705

    10600.00476256140.00019541390.00001193480.00000079880.0000002059

    10800.00510383410.00021507030.00001355620.00000094030.0000002471

    11000.00545948960.00023603920.00001533720.00000110120.0000002948

    11200.00582968010.00025836110.0000172870.00000128310.0000003497

    11400.00621455140.00028207540.00001941520.00000148810.0000004127

    11600.00661424350.0003072210.00002173140.0000017180.0000004845

    11800.00702889040.00033383610.00002424530.0000019750.0000005661

    12000.00745862060.00036195810.00002696680.00000226110.0000006583

    12200.00790355750.00039162370.00002990560.00000257870.0000007622

    12400.00836381940.0004228690.00003307180.000002930.0000008788

    12600.00883951990.0004557290.00003647510.00000331730.0000010091

    12800.0093307680.00049023840.00004012570.00000374320.0000011544

    13000.00983766830.0005264310.00004403330.00000421010.0000013158

    13200.01036032150.00056433970.00004820820.00000472060.0000014945

    13400.01089882420.00060399690.00005266010.00000527740.0000016918

    13600.01145326920.00064543420.00005739920.00000588310.000001909

    13800.01202374570.00068868260.00006243520.00000654040.0000021475

    14000.01261033970.00073377230.00006777820.00000725230.0000024086

    14200.01321313360.00078073290.00007343790.00000802150.0000026939

    14400.0138322070.00082959310.00007942430.00000885090.0000030048

    14600.01446763630.00088038140.0000857470.00000974340.0000033429

    14800.0151194950.00093312510.00009241590.00001070220.0000037096

    15000.01578785420.00098785130.00009944050.00001173010.0000041066

    15200.01647278210.00104458620.00010683040.00001283030.0000045356

    15400.01717434440.00110335560.00011459520.00001400580.0000049982

    15600.01789260460.00116418450.00012274430.00001525970.0000054961

    15800.01862762390.00122709750.0001312870.00001659520.000006031

    16000.01937946110.00129211850.00014023270.00001801560.0000066048

    16200.02014817320.00135927080.00014959040.00001952380.0000072191

    16400.0209338150.00142857720.00015936940.00002112330.0000078759

    16600.02173643940.00150006010.00016957860.00002281720.0000085769

    16800.02255609770.00157374110.00018022690.00002460870.0000093241

    17000.02339283910.00164964160.00019132320.00002650120.0000101192

    17200.02424671140.00172778230.00020287610.00002849790.0000109643

    17400.02511776050.00180818330.00021489430.00003060210.0000118613

    17600.02600603110.00189086450.00022738640.0000328170.0000128121

    17800.02691156610.00197584520.00024036060.0000351460.0000138186

    18000.02783440720.00206314410.00025382540.00003759240.0000148829

    18200.02877459460.00215277980.0002677890.00004015940.000016007

    18400.02973216720.00224477020.00028225950.00004285040.0000171929

    18600.03070716270.00233913280.00029724480.00004566870.0000184425

    18800.03169961750.00243588480.0003127530.00004861760.0000197581

    19000.03270956690.00253504290.00032879170.00005170020.0000211414

    19200.03373704510.00263662350.00034536880.00005492010.0000225948

    19400.03478208520.00274064250.00036249170.00005828030.0000241201

    19600.03584471920.00284711540.0003801680.00006178420.0000257196

    19800.03692497810.00295605770.0003984050.00006543510.0000273951

    20000.03802289210.0030674840.00041721010.00006923610.000029149

    0.05-108.6356217965-186.6305525085-278.0077254364-381.1797926873-436.8265461303

    0.025-63.0981217965-102.9730525085-149.2077254364-201.1797926873-229.1590461303

    0.0166666667-47.9189551299-75.0872191751-106.274392103-141.1797926873-159.9365461303

    0.0125-40.3293717965-61.1443025085-84.8077254364-111.1797926873-125.3252961303

    0.01-35.7756217965-52.7785525085-71.9277254364-93.1797926873-104.5585461303

    0.0083333333-32.7397884632-47.2013858418-63.3410587697-81.1797926873-90.7140461303

    0.0071428571-30.5713360823-43.2176953656-57.2077254364-72.6083641159-80.8251175589

    0.00625-28.9449967965-40.2299275085-52.6077254364-66.1797926873-73.4084211303

    0.0055555556-27.680066241-37.906108064-49.0299476586-61.1797926873-67.6398794637

    0.005-26.6681217965-36.0470525085-46.1677254364-57.1797926873-63.0250461303

    0.0045454545-25.8401672511-34.5260070539-43.8259072545-53.9070654146-59.249273403

    0.0041666667-25.1502051299-33.2584691751-41.874392103-51.1797926873-56.1027961303

    0.0038461538-24.5663910273-32.1859371238-40.2231100518-48.8721003796-53.4403922842

    0.0035714286-24.0659789394-31.266623937-38.8077254364-46.8940784016-51.1583318446

    0.0033333333-23.6322884632-30.4698858418-37.5810587697-45.1797926873-49.1805461303

    0.003125-23.2528092965-29.7727400085-36.5077254364-43.6797926873-47.4499836303

    0.0029411765-22.9179747377-29.157611332-35.5606666128-42.3562632755-45.9230167186

    0.0027777778-22.6203440188-28.6108302862-34.7188365475-41.1797926873-44.565712797

    0.0026315789-22.3540428492-28.12160514-33.9656201732-40.1271611084-43.3512829724

    0.0025-22.1143717965-27.6813025085-33.2877254364-39.1797926873-42.2582961303

    0.0023809524-21.8975265585-27.2829334608-32.674392103-38.3226498302-41.2694032732

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    0.002173913-21.5204044052-26.5901177258-31.6077254364-36.8319666003-39.5495896086

    0.0020833333-21.3554134632-26.2870108418-31.1410587697-36.1797926873-38.7971711303

    0.002-21.2036217965-26.0081525085-30.7117254364-35.5797926873-38.1049461303

    0.0019230769-21.0635064119-25.7507448161-30.3154177441-35.0259465335-37.4659692072

    0.0018518519-20.9337699447-25.5124043603-29.9484661771-34.5131260206-36.8743239081

    0.0017857143-20.813300368-25.2910882227-29.6077254364-34.0369355444-36.3249389875

    0.0017241379-20.7011390379-25.0850352671-29.2904840571-33.5935857908-35.813442682

    0.0016666667-20.5964551299-24.8927191751-28.994392103-33.1797926873-35.3360461303

    0.0016129032-20.4985250224-24.712810573-28.7174028557-32.7926959131-34.8894493561

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    0.0015151515-20.3204702814-24.3857040236-28.2137860424-32.0888835964-34.0774552212

    0.0014705882-20.2392982671-24.2365819202-27.9841960246-31.7680279814-33.7072814244

    0.0014285714-20.1627646537-24.0959810799-27.7677254364-31.465506973-33.358260416

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    0.0013157895-19.9573323229-23.7185788242-27.1866728048-30.6534768978-32.4214145514

    0.0012820513-19.8958782068-23.6056807136-27.0128536415-30.4105619181-32.1411615149

    0.00125-19.8374967965-23.4984275085-26.8477254364-30.1797926873-31.8749211303

    0.0012195122-19.78196326-23.396406167-26.6906522656-29.9602804922-31.6216680815

    0.0011904762-19.7290741775-23.2992429846-26.5410587697-29.7512212587-31.3804747018

    0.0011627907-19.6786450524-23.2065990201-26.3984231108-29.5518857106-31.1504996187

    0.0011363636-19.6305081602-23.1181661448-26.2622708909-29.3616108691-30.9309779485

    0.0011111111-19.5845106854-23.0336636196-26.1321698808-29.1797926873-30.721212797

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    0.0010204082-19.4192952659-22.7301443452-25.6648682935-28.5267314628-29.9677706201

    0.001-19.3821217965-22.6618525085-25.5597254364-28.3797926873-29.7982461303

    0.0009803922-19.3464061103-22.596238783-25.4587058285-28.2386162167-29.6353696597

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    0.0009259259-19.2471958706-22.4139784344-25.1780958067-27.846459354-29.1829350192

    0.0009090909-19.2165308875-22.3576434175-25.0913618-27.7252472328-29.0430915849

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    0.0005434783-18.5505674487-21.1341938128-23.2077254364-25.0928361656-26.0060569999

    0.0005376344-18.5399228718-21.11463853-23.1776179095-25.0507604292-25.9575138723

    0.0005319149-18.5295047753-21.095499317-23.1481509683-25.0095799213-25.9100035771

    0.0005263158-18.5193060071-21.0767630348-23.1193043837-24.9692663715-25.8634934987

    0.0005208333-18.5093197132-21.0584170918-23.0910587697-24.9297926873-25.8179523803

    0.0005154639-18.4995393223-21.0404494157-23.0633955395-24.8911328935-25.773350254

    0.0005102041-18.4899585312-21.0228484268-23.0362968649-24.8532620751-25.7296583752

    0.0005050505-18.4805712915-21.0056030135-23.0097456384-24.8161563237-25.6868491606

    0.0005-18.4713717965-20.9887025085-22.9837254364-24.7797926873-25.6448961303

    Sheet1

    1/V (1/V)

    ln(I/V2) (A/V2)

    Sheet2

    Sheet3

  • Field Enhancement Factor

    Anode

    Cathode

    = F / V

    Field enhancement factor for typical emitters#

    # H. G. Kosmahl, IEEE Trans. Electron Devices 38 (6), 1534 (1991)

    h

    d

    r

    F: electric field at emitter tip

    V: voltage between anode and cathode

    II. Field Emission

    r

    Spacer

  • Emitter Structure Effect Simulation

    Tip height (top to bottom)

    4 mm

    3 mm

    2 mm

    1 mm

    0.5 mm

    Tip radius (top to bottom)

    10 nm

    20 nm

    40 nm

    60 nm

    80 nm

    100 nm

    Effect of tip radius

    Effect of emitter height

    II. Field Emission

    Chart1

    30.31848936550.106921316685.3859451441117.8764131384148.7608525507

    19.192604102830.31848936550.106921316668.229429061785.3859451441

    15.153546567923.045306400337.181638090450.106921316662.3177213531

    13.075156485619.192604102830.31848936540.49913865850.1069213166

    11.84217141816.792423484226.014789669334.476428794542.4592279104

    11.062745544915.153546567923.045306400330.31848936537.1816380904

    10.563175130213.967572115720.864944756727.261368195433.3015008252

    10.255351484513.075156485619.192604102824.911685632330.318489365

    10.090985264812.385312219417.867923953323.045306400327.947784756

    10.0428601811.84217141816.792423484221.524727438326.0147896693

    10.096275018111.409493440215.90211864120.260689433324.406241904

    10.244926900611.062745544915.153546567919.192604102823.0453064003

    10.489014515210.784753990914.516099923118.277828169221.8779339404

    10.834658166310.563175130213.967572115717.485435244220.8649447567

    11.294320702410.388954568613.491442744516.792423484219.9772106938

    0.5mm

    1mm

    2mm

    3mm

    4mm

    Emitter radius (nm)

    Field enhancement factor

    Sheet1

    tip radius

    1030.31848936550.106921316685.3859451441117.8764131384148.7608525507

    2019.192604102830.31848936550.106921316668.229429061785.3859451441

    3015.153546567923.045306400337.181638090450.106921316662.3177213531

    4013.075156485619.192604102830.31848936540.49913865850.1069213166

    5011.84217141816.792423484226.014789669334.476428794542.4592279104

    6011.062745544915.153546567923.045306400330.31848936537.1816380904

    7010.563175130213.967572115720.864944756727.261368195433.3015008252

    8010.255351484513.075156485619.192604102824.911685632330.318489365

    9010.090985264812.385312219417.867923953323.045306400327.947784756

    10010.0428601811.84217141816.792423484221.524727438326.0147896693

    11010.096275018111.409493440215.90211864120.260689433324.406241904

    12010.244926900611.062745544915.153546567919.192604102823.0453064003