pops pesticides inventory reportinfofile.pcd.go.th/haz/pops_pesti_en.pdf · the project: enabling...

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POPs Ell i. Pesticides Inventory Report Enubling Activitie.~~fbr Development of'National Plan fir Implementation of'the Stockholm Cbnvention on POPs: Project no. GF/2732-03-4669 NIP/POPs Coordination Office I@$ pdd lZm7\( Y / POP0 Pollution Control Department, 92 Phahoo Yorhin 7. Phayalhai. Bangkok 10400 Thailand Tcl: (662) 298 24.27 nru~7uquuaftu 92 a.mraTu$u 7 n.nnnluiru wqiln nl~~nn-I i~oo in^. (MZ)BE 2457

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Page 1: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

POPs E l l i.

Pesticides Inventory Report

Enubling Activitie.~~fbr Development of'National Plan fir Implementation of'the Stockholm Cbnvention on POPs: Project no. GF/2732-03-4669

NIP/POPs Coordination Office I@$ p d d l Z m 7 \ ( Y / POP0 Pollution Control Department, 92 Phahoo Yorhin 7. Phayalhai. Bangkok 10400 Thailand Tcl: (662) 298 24.27

nru~7uquuaftu 92 a.mraTu$u 7 n.nnnluiru wqiln n l ~ ~ n n - I i ~ o o in^. (MZ)BE 2457

Page 2: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

Acknowledgements

The Pollut ion Control Department (PCD) acknowledges and expresses

their appreciation to all members of the National Coordination Committee (NCC) for

the Project: Enabling Activities for the Development of the National Implementation

Plan (NIP) of the Stockholm Convention on Persistent Organic Pollutants (POPS), for

their contributions over the POPS Pesticides Inventory Report.

A p p r e c i a t i o n i s a l so ex tended t o al l re levant s ta f fs o f PCD for the i r

performing and compi l ing of all available data during the preparat ion process.

Very s p e c i a l a p p r e c i a t i o n g o e s t o the NlP lPOPs Pro jec t Manager a n d a l l

Nationai Technical Experts for their times and efforts throughout the preparation of the

report

Mr. Apichai Chvajarernpun

Director-General of Pollution Control Deoartment

Page 3: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

POPS Pesticides Inventory Report

Page 4: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

Table of Contents

1. Overview of POPS pesticides production, import, export use and contamination

1 .I Introduction

1.2 Production

1.3 Import

1.4 Export

1.5 Use

1.6 Government programs on pesticide use management

1.6.1 Integrate Pest Management (IPM)

1.6.2 Special programs concerning the use of pestcides in Thailand

2. Status of POPS pesticides stockpiles, related wastes and environmental

contamination in Thailand

2.1 Preliminary inventory of obsolete (POPs) pesticides in Thailand

2.2 Results of the inventory of obsolete (POPs) pesticdes in Thailand

2.2.1 Background information

2.2.2 Prev~ously reported data concerning POPs Pest~cides Inventory

2.2.3 Inventory activtes

2.2.4 Overview of storage cond~tions of sites holding POPs pesticides

2.2.5 Previously reporled env~ronniental contam~nat~on by Obsolete

and POPs pes:cides

2.2.6 Prev~ously reported data about Obsolete and POPs pesticides

2.3 Waste management

3. National infrastructure for POPS pesticides management

3.1 institutional Structure and its mandates for POPs management

3.2 National policies for POPs pesticides management

3.3 Legal rnechan~srns for POPs pesticides management

3.3.1 National legal instrument for the management of POPs pesticides

3.3.2 Regionallinternational legal Instrument for the management

of POPs pesticides

4. Summary of the future production, use and disposal of POPS pesticides

requirement for exemptions

5. Existing programs for monitoring of environmentallhuman health impacts

6. Current level of information, awareness raising and education

Page 5: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

Annex : --

Annex 1. Detailed Overview sorted on Site

Annex 2. Detailed Overview sorted on active ingredienr

Annex 3. Detailed Overv~ew soried on manufacturer

Annex 4. Pictures of activities on POPS pesticides during the inventory

Page 6: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

1. Overview of POPS pesticides production, import, export use and contamination

1.1 Introduction

Pesticides use in Thailand. especially chemical and synthetic substances, began during the

second World War with the Import of DDT to launch an anti malaria campaign. The aim was to

target mosquitoes and the use as insecticide for health reason. Immediately after the War. DDT

was more widely used to kill mosquitoes and flies. Follow~ng this, more variety of chemicals and

syn!hetics were introduced, particularly those classified as organchlorines, followed by others such

as organophosphates and carbamates.

After 1957, the import of chemicals and synthetic substances increased remarkedly. According to

some reports, imported pesticides into Thailand rose from approximately 2,000 tons of active

ingredients in 1957 to approximately 4,000 tons in 1962 and then 37,039 tons in 2001. In the early

phases of import they were largely limited to types classified as organochlorine, organophosphates

and carbamates. Later on, there was further development in pesticides and other types of

synthetic substances were introduced in Thailand like the pyrethroids and extracts from plants and

microorganisms,

The development of pesticide use in Thailand has increased rapidly. However, the hazardous

effect to human health and env~ronment have been reported as ; direct impact to users or farmer,

toxic residues in agricultural products, impact on environment, impact on natural predator and

ecosystem, and etc. A special adverse effect on env~ronment had been pinpointed to the persistent

organic pollutants (POPS) which prevaile in environment for long time and causes damages to living

and nontarget organisms. Therefore, it is necessary to investigate more details to justify whether

the situation is really risk to human health and ecosystems.

1.2 Production (previous, current, future)

The majority of pesticides (active ingredients) used in Thailand are not produced in the country.

They are imported from foreign countries such as Germany, Switzerland, U.S.A, U.K.. China, India,

etc. The reasons for not being produced in the country might be related to the fact that many

difficulties are exuerienced in obta~ning the permit to produce pesticides irom government

authorities. The imported materials are both technical grades and finished products. The technical

Page 7: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

grade materials are forrnulated and packaged in Thailand. Formuialing plants count more than 70

spread all over the country and they belong both to local manufacturers and oversea companies

1.3 Import

Table 1 : Import of pesticides during 1977 - 2003 is shown below :

Source : Department of Agriculture Unit : Quantity = toniai Value=Million Baht

In Thaland, most of pesticides used in the country are Imported and the amount has increased

rap~dly n the past twenty years, Importation of pesticides in the early date was mostly in the form of

f~nshed products. Subsequently, sorne agrochen~ical companies started to formulate locally from

technical grade mported Only tne herblade Paraquat 1s locally manufactured from the

~ntermed~ate by two manufacturing plants whlch account for 6,000 metrlc tons a year Untl 1988,

there were 2 formulators registered in Thailand, the number of registered formulators increased to

77 I I . In 2001 (Agr~cultural Regulatory Division, 2001)

In 2003, Thailand imported pesticides 0.131 million tons, divided into 2 groups, chemical i bio-

pesticides and active ingredient. Che~nical and bio-pesticides imported counted for about 0.0806

rnilon tons while active Ingredient imported counted for about 0.0504 million tons. Imported

pesticides are divided into 11 categories, which are insecticide, fungicide, herbicide, acaricide,

rodent~cde, PGR, molluskicide, fumgants, nematczide, miscellaneous, and bio-pesticide

Page 8: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

1.4 Export

Information on export of pesticides to foreign markets is not available. Only reliable sources

report about export of pesticides formulated in Thailand to several neighboring countries such as

Laos, Cambodia Myanmar and Vietnam, but the volume are not recorded since the border trading

has occurred along long border lines without proper administration of quant~ties of material passing

the border.

POPs Pesticides Production, Import and Export

lnformatlon on the importation of the 19 specified POPs chemicals has not really been collected

from the very beginning. The term "toxlc chemicals" was not recognized at that time. The only term

that the people heard and understood in that period was "poison" from plants, snakes, mushrooms

and other living things. Thailand was very conservative in this field and never Introduced any toxlc

chemicals to the country in those days. The first report on the application of chemicals was issued

about after the Second World War. That was in 1949 when [ 1, l - (2,2,2,-trichloroethylidene) - bis

(4-chlorobenzenej] or DDT was first introduced for a malarla control trial in Chiangmai Province.

The Malaria epidemic in 1951 was very serious and killed over 40,000 Thai people at a mortality

rate of 2001100,000. DDT has been widely applied at rate of 2 gm-a.i. I m2 ever since. It proved

capable of decreasing the mortality rate each year until it reached 11100,000 in 1993. During those

days, this toxc angel has not only been used for malaria control but also in agricultural for pest

control. It was first applied to control the epidemic of corn grasshopper (Patanga) in 1953 and

became widely known after 1955 when it was applied to control the cotton ball worm and tobacco

insect pest.

Following DDT, the "drin family" was introduced in 1955. The Shell Company in Thailand imported

dieldrin aldrin and endrin, and also at this rime Yip In Soy, a local company Imported BHC and

Toxaphene. Since 1959 all of these organchlorine pesticides have been widely applied for the pest

control of almost all crops including casawa, fruit and vegetable corps. During 1960-1965, farmers

applied a mixture of DDT + Endrin, DDT + dieldrin and DDT + Toxaphene and even DDT +

Toxaphene + methyl parathion instead of DDT only for the control of cotton pests and other plant

pesrs

In 1971 when Toxaphene DDT and BHC formed the largest volume of 62, I. 968 and 17 metric tons

respectively, the volume of dieldrin, aidrln, endrin, chlorodane and heptachlor were less, as 8, 6, 0.6.

3 and 1 metric tons respectively, The mixtures of DDT + Toxaphene and DDT + Toxaphene + methyl

Page 9: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

parathion were also reported. The importation of such POPS increased for years and years. There

were increases and decreases in volumes yearly but in general they increased until they were

banned in specified years for the impact on human health and the env~ronment. Only chlordane

remained in use up until 2000.

Table 2 : Import of POPS Pesticides during 1971 - 1997 (tons)

Year Aldrin Chlordane DDT Dieldrin Endrin Heptachloi Taraphene

Source: Department of Agriculture

Page 10: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

1.5 Use

Thailand, a major food producing country, has ga~ned main income from exporting

agr~cultural commodities. In 1998 agr~cultural products were exported to foreign countries w~th

value of 14.642 millon US$, accounted tor 38.4% of the total export. When compared to the earlier

statistics of 1987, the value of exported agricultural products was 6.086 million US$, being 51% of

the total export (Agrcultural Statistics of Thaland Crop Year 1986187, 1997198). Thailand has been

a rnajor rice produc~ng country irom the history until now, but the country's agricultural sector has

becorne more diversified during the last decade,

As hoiticultural crops such as vegetables, fruits and flowers gain a growng importance due

to the demand from foreign countries, their physical appearances are significant for good market

prices. For thls purpose, t is revealed that vegetable and fruit farming are using highest amount of

pesticdes and fertilizers. Pesticides are needed in agricultural because roughly one-thrd of the

production of food and fiber was lost to weed, insect pests and diseased. The reasons for

extensive use of pesticides in Thailand is due to the wide variation in climate and crops and the

great multitude of pests and diseases, etc.

Use of POPs Pesticides (previous)

Aldrin was an insecticide applied to soil for termite control and other soil pests such as corn

rootworm. The chemical was also used to control insects in grain storage and ectoparasites on

cattle.

Chlordane was used extensively for termte and ant control in buildings, nurseres and forest

plantations. Chlordane was a broad-spectrum insecticide used to control pests on a wide range of

crops.

D~eldrin was a very effective pesticide applied against termite in buildings, crops, nurseries

and forest plantations. The main used in the past also focused on locust control as well as grain

storage and ectoparasites on cattle.

DDT the most important POPs chemical, was used widely on control of malaria, typhus and

other diseases spread by insects. It was also applied widely on crops and soil to protect insect pests.

e.g. Lepidoptera.

Endrin was used on several crops such as rice, maize, cotton, sugarcane to control on

Lepdoptera. It is also used to control rodents in house and store.

Heptachlor was used to kill soil insects and termites. The usage was also extended to crop

pests, grasshoppers and mosquitoes.

Page 11: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

Toxaphene was used mainly on cotton, and something was m~xed with DDT as Toxaphene -

DDT and then used on cereal grains and fruit trees. It was also used to control ticks and mites in

livestock.

1.6 Government programs on pesticide use management

1.6.1 Integrate Pest Management (IPM):

In the past there were several IPM programs on major crops in Thailand such as cotton, rice.

maize and other field crops. All these programs had incorporated many techniques and uses of bio

pesticides such as plant extracts, bacteria, virus and nematode as the tool to lower down the

problems from pesticides

1.6.2 Special programs concerning the use of pesticides in Thailand

There are recommendations in a Policy and Master Plan of Agricultural Pesticides in Thailand

(2002-2006) on the following policies:

- Policy on Promotion of Pesticide Free Pr~duction of Vegetables and Fruits.

- Policy on Promotion of Proper Use of Pesticides, Adopting Correct and Appropriate

Methods.

- Policy on Promotion of Public Awareness and Public against Pesticides.

- Policy on Extending and Accelerating a study on the Risks of Pesticide Use.

All of these programs are undergoing and has not yet evaluated.

2. Status of POPS pesticides stockpiles, related wastes and environmental contamination in Thailand

2.1 Preliminary inventory of obsolete (POPS) pesticides in Thailand

In Thailand, most of POPS Pest~cides that might be left over were under the ownership of

government offices such as :

Ministry of Agriculture (Department of Agriculture & Department of Agricultural

extens~on)

Forestry Department and 1 Department of Natural Resources

Ministry of Health (Vector Control Depanment)

These owners have obtained and kept pesticides for use against plant pests. for use on

individual farms and plantations; input supply programmes of government farm subsidy: farmers' co-

operatives, for use agairist household pests, etc. lt is also not unusual for private pesticide distributors

to accumulate obsolete slocks but to fail to declare them. Some POPS pesticide remained were

introduced to use in locust control 20 - 30 years ago.

Page 12: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

Obsolete stocks of pesticides also include small quantlties of organo-phosphates and

carbamates that have deteriorated as a result of prolonged, inappropriate and substandard storage

These Include pesticides such as malathion, fentrothlon, dimethoate, carbaryi and propoxur, along

with larger quantities of banned highly toxic products such as parathion, methyl-parathion,

monocrotophos and metharnidophos.

During the year 2000-2001, Thailand had started prel~~ninary work to carry out an Inventory

of obsolete and unwanted pesticide stocks in order to assess the magnitude of problems and to

plan appropriate management and arrangement for their disposal and destruction in the future with

the objectives to conduct nationwide surveys of obsolete and unwanted pesticide stocks existlng in

the country.

Data of obsolete pesticide stocks were collected by 2 methods, which were by

questionnaire and direct counting (vslt to the sites),

Questionnaire

Questionnaire was desgned and refined for the purpose of inventory taking. It was simple

and easy to answer. I t contained all parts of nformation needed for the inventory of obsolete

pesticide stocks. Questionnaires were distributed to both government agencies and agrochemical

busness.

For the government agencies, questionnaires were sent to the regonal agriculture offices,

which belong to the department of agriculture extension, in all of 76 provinces. Also, they were sent

to 120 research stationsicenters which belong to the department of agriculture.

For the private sectors, total of 397 questionnaires were sent to pesticide formulators,

distributors, and retailers.

Direct counting

Direct counting surveys were carried out in several pesticide formulation plants, distributor

and retailer stores. Farmlands where pesticides are used extensively such as orange grove and

vegetable plantation, were visited. The processes of data collecting include :

1. Interviewing the owners for background informat~on related to pesticides

2. Visual inspection of the storelsites and areas suspected of contamination

3. Completion of information on the Questionnaire

4. Direct counting on types and quantlties of obsolete pesticides stocks and empty

containers.

Page 13: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

Result :

The survey result is completed in the FA0 inventory format using computerized database

program. Total quantities and the number of items of obsolete pesticide stocks are shown in Table

3 It reflects the broaden situation of obsolete pest~c~de stocks in the country. Numbers of Items of

obsolete stocks when grouping by the~r type of actionluse are shown in Table 4, This total amount

of obsolete pesticide stocks when sorted into the sites where they are stored, accord~ng to the

agricultural region, is shown n Table 5.

Table 3 : Obsolete, unwanted andlor banned pesticide stocks in Thailand

1 1 Number of / Quantity 1 Quantity

1 ( Containers 1 (Kgs) (Lts) 1 Total Kgs, Lts and pieces of 24,557 1 12,8717 ' 22,993.6 i

1 P~eces of Containers 1 24,557 1 1 1

containers I

Combined total in Kgs 1 Lts k 1

n tons I I I

36 I

35,865.3

Source: Department of Agriculture

Table 4 : Numbers of obsolete pesticides when grouping by their type of actionsluses

ActionlUse ! Number of obsolete pesticides

Insecticide

Fungicide 7 47

Herbicide I 54

Miscellaneous I 49

Unknown 1 162

Source: Department of Agrculture

Page 14: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

Table 5 : Quantity of obsolete pesticide specified per Region where they are stored.

CONCLUSION 8 DISCUSSION

Information obtained from the prel~minary inventory taking during the short periou of 2

months in 2000-2001 revealed that there were about 36 tons of obsolete or abandoned pesticides

left over in several places all over Thailand. Among these obsolete pesticides, the only chemical

in POPS list that could be found was chlordane with total amount 905 kg. However, this data

concerns preliminary data and provdes only an indication. No extensive country wide survey has

been undertaken. This information has to be updated and confirmed to receive coirect data by

undertaking a new inventory of Obsolete & POPs pesticide in the country

Region Number of Quantity Quantity Total

Containers In Kgs + Lts

Central 8,831 4,378.5 17,850.6 22,229.1

The explanation for small figure of obsolete and POPs pesticide in Thailand lies in the narure

of pesticide business in the country that the sale and distribution of pesticides is mainly controlled

by the private sectors and using conservation sale projection. Therefore, the purchase of large,

unecono~nic quantities of pesticides is avoided. The same conservative approach is apparent at

the reformulation and repackaging levels of the pesticide industry by lim~ting the quantities of

pesticide processed in order to meet and not exceed the projected market demand. These

strategies also prevent the buildup of excessive pesticide stocks.

In some Afrlcan and other Asian countries where pesticide disposal problem have been

identified, the public sector was the major importer of pesticides. Pesticide purchases were

pr~marily made through government or donor acquisitions and market forecasts of pesticide

requ~rements were often inaccurate. As a result, excess stocks of pesticides accumulated and

North

North East

East

! ~ e s r

South

Source: Department of Agriculture

1.436

9.020

1 171

33

4,673

356.9

3,865.3

0

179

4,049.7

375.6

2,155.4

6

24

2,492.5

732.5

6,020.7

6 I

6,1422 1

Page 15: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

degraded under tropical weather conditions before the pesticides could be used up and often

created serious pesticide disposal problems. Such was not found to be the case in Thailand.

Although there are environmental regulations requiring that obsolete pesticide stocks ana

used pesticide containers be destroyed and disposed of by appropriate technology, these

regulations are rarely enforced. Drum refurbishing also appears to be a profitable business, and,

therefore, the disposal of used pestcide steel drums may not be a serious problem in Thailand.

The lack of a program for the disposal of used pastlc and glass pesticide containers. on the other

hand, does pose a potential environmentai and health problem.

The regonal pesticide warehouses owned and managed by the government agencies rnay

contain an excess of obsolete pesticides for the same reason that these excess stocks exist in

other countries where governments are the main purchasers and distributors of pesticides. An

inventory and inspection of government warehouses would assess if a pesticide disposal problem,

even on a minor scale, might ex~st in the country.

Pesticide waste sites may result from accidental fires or large scale spills involving

pesticides. Two such pesticide waste sltes have been identified. One was a retail pesticide store

where recently destroyed by fire, and another one was a Government warehouse of pestcide stock

where fire damaged all stock In 1982. Only limited details could be found from the second incident

at the government warehouse. where it was estimated that 1.8 million baht (about us 5 72,000 at

that time) worth of pesticides were damaged or destroyed. The resdue from the fire was buried one

meter deep in a 25 square meter plot near the site of the fire. There has been no monitoring of this

site unt~l recently, under NlPIPOPs project of Thaand, the site has been inspected and soil

samples was collected for analysis. The result has not yet been revealed.

Based on a systematic approach to many aspects of pesticides distribution and use in

Thailand, we can provis~onally conclude that it is unlikely that large quantities of abandoned or

obsolete which inciuded POPS pesticides exist in the country. However, since the study tinie was

of short duration, updat~ng the existing information should be undertaken to provlde more

information.

Page 16: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

2.2 Results of lhe inventory of obsolete (POPS) pesticides n Thailand

2.2.1 Background information

As had been mentioned many times in the National Implementation Plan Project Report the

Issue of obsolete pesticides stockpiles and storage is very important around the world due to the

concern over environmental and health effects from especially the POPS pesticides. Various factors

have contributed to the accurnuiatlon of obsolete pesticides in many countries. The nialn factors

include: ( 1 ) banning of pestcides w h e they are still kept in store; (2) sub-standard stores and poor

stock managemen:; (3) overstocking as a result of poor assessnient of requirements or difficulties

in forecast~ng outbreaks of mgratory pests; (4) inappropriate formulatons or poor quality containers

In some countrles, a significant part of the obsolete pesticide stocks are leftovers of pesticicles that

countries obtained under direct financ~al aid or through some kind of loan arrangements. Also

excessive donations and lnappropr~ate pestic~des contributed to the huge stockpiles of obsolete

pesticides in many countrles. The problem of obsolete stocks is not limited to few countries or

continents. In fact there are only a few countries that are not affected by deteriorating and leak~ng

obsolete pestic~des. But the problem and the negative effects are much more serious in developing

countries. The reason is lack of basic awareness of the inherent danger of pesticides, lack of

facities to handle or to get rid of the tox~c waste, and lack of resources.

However, there IS a strong need for inventory of obsolete stocks because lnventorles are the

gateway to f n d a solut~on to accumulated stocks and the frst step in mak~ng arrangement for the~r

destruct~on

Normally, a pesticide will be considered obsolete if its use is prohibited due to health

hazards and detrimental effects on environment, or it no longer meets minimum quality requrement.

Th~s definition is valid for banned chemicals under the current Thai regulation which established

guiclelines for banning pesticides in Thailand. As such, the guidelnes set priority on chemicals that

created adversed effects on human and environment as well as sub standard quality. Almost one

hundrecl chemicals had been put under the banned list so far, including all POPS pestcides

Page 17: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

The major objective of the POPS pesticides inventory in Thailand is to take inventory of

obsolete pesticides stocks inciuding POPS pest~c~des by physically visitlng stores. All places

reported to contaln obsolete pesticides from the work were visited. The other objective are to

estimate the quantities of POPS wlth pesticides left-over were recommend for further action to be

taken for the environmentaliy sound management of the observed stocks

2.2.2 Previously reported data concerning POPS Pesticides lnventory

Preliminary work for inventory of obsolete stocks had been carried out in 2000-2001 by staff

of Department of Agriculture and Agricultural Extension under the support from FA0 and the

government. The work was done mainly by questionnaires and visiting surveys on the areas

suspected of containing obsolete pesticides, especially organchlorines of the POPS lists. Only

Chlordane could be identified with quantity of 905 kg. A small amount of DDT and dieldrin was

reported as well amongst the total amount of 36 tons of obsolete pesticides.

2.2.3 lnventory activities

A Task team had been formed conlprising the national expert consuitant on POPS

pesticides and staff from the Pollution Control Department. The task team is responsible for field

surveys and slte visits. Based on the first survey report done in 2001, the government storage

houses were not inciuded in the inventory. The explanation could be clarified for the first inventory

about the small figure of obsolete and POPS pesticides in Thailand that the pesticide business in

Thailand is in private hands and avoids the purchase of large, uneconomic quantities of pesticides.

Therefore, this policy prevent the bulldup of excess pesticide stocks in distributors and retailers

warehouses. At the same titne, in the government storage houses, especially the storage under the

responsibility of Department of Agr~culture and Agriculture Extension who had engaged in the use

of pest~cide in research and control of sub-standard pesticides in the markets under the

government regulation might have the chance to contain the large quantities of banned and

unwanted pesticides in the research stations and field areas all over the country.

The Task team was trained during an extensive training session during the month of

December 2004. After that, the task team had drafted the plan and visited the major research

stations and government stores in 2 provinces in the Central Region (Supanburi. Nakorn Pathom), 1

provlnce in the Northern Region (Cniengmai), 2 provinces in the Northeastern Region

Page 18: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

(Mahasarakarm, Khon Kaen) and 1 province in the Southern Region (Krabij. All these visiting had

been done within 2 months of December 2004 and January 2005, subsequent the visiting of 2

stores in Bangkok and Prattiumthani with the lnternatlonal Consultant (Mr.Jan Betlem) durlng the

traning course for Task team members. Therefore, there are altogether 11 site visits under this

project. It is not excluded that there are more sites wth obsolete pesticides (and POPS pesticides)

in Tha~land

The details of all visiting had been compiled and computer~zed into the format

recommended by FA0 (as attached). For overall summary, there are 11 site visits, the toial

obsolete pesticides products recorded in these 11 sites are 165, having totai weight 71, 212 kg for

solid products and total volume 63, 414 liters for liquid formulation, including 20 m-or empty

packagings at site 2. Ail of the details are sorted into (1 ) Detailed overview sorted on Site (Annex

1 j , !2) Detailed Overview sorted on Manufacturer iAnnex Z ) , (3) Detailed O v e ~ ~ e w sorted on Active

Ingredient (Annex 3). When sorted from all data available from the countrywide survey, the POPS

pesticdes and other persistent. organochlorines can be arranged in the following manner:

Table 6 : Total amounts and formulations of POPS pesticides and other persistent organochlor~nes.

POPS pesticides' 8 other OC

Chlordane'

DDT'

tieptachlor*

Endosulfan

Endosulfan + BPMC

dicofol

Amounts remained

(kg or L)

30 kg

180 kg

10 kg

20 L

2865 kg

41 L

Formulation

40% WP

75% WG

2.96% dust

35% EC

2.5 + 2.0% G

18.5% EC

Source: Department of Agriculture

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Comments

When cornpared w~th the first inventory taken in 2001 the only rnajor POPS was found to be

chlordane at 905 kg. In trying to update thls information the Task team had visited this time rnost of

the places mentioned containing chlordane from the first report and could find only 30 kg left. This

rnight be due to the need to use this chen~lcal in the country to control termites. Therefore, the

figure obtained from other areas of the world that 15 - 20%, or even 30% of obsolete pesticides can

be considered as POPS pesticides is not related to the situaton in Thailand. However, it must be

recognized that the Task tearn did not extensively search for all obsolete pesticides and POPS

quantity of pestlcides could be rnuch higher although this inventory has been shown that only a

reiative sniall aniount of the obsolete pesticides can be considered as POPS pesticides.

The preliminary work on inventory of obsolete and POPS pesrcldes was carried out between 2000-

2001 and could identify 36 tons of such hazardous chemicals, Information from preliminary work

had been used as reference for the updated Inventory by the task team with elaboration for more

information to cover government storage house which did not appear in the first inventory. The

inventory this time contained about 132 tons of obsolete and POPS pesticides. For more accurate

information, POPS pesticides which were recorded (chlordane. DDT and heptachlor) only account

for 220 kg products. We could estimate from this figure that the total POPS in Thailand has a

tendency of going down and are not expected to create any problem in the future. As for other

organochlorines such as endosulfan, dicofol and organophosphates (such as monocrotophos and

methamdophos), the problem is still existing due to the stocks from banning or confiscating which

are kept in many places.

2.2.4 Overview of storage condit~ons of sites holding POPS pesticides

The storage conditions of sites holding POPS pesticides are generally acceptable in term

of facilities such as water and electricity availabity, beng put on shelves, separated from each

formulat~on except the sites such as the government storage house in Bangkok that stored lot of

banned and confiscated pestlcides without good separation and the storage is under poor

condition.

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2.2.5 Prevously reported environmental contamination by Obsolete and POPS pest~cides

During the slte visit to 2 storage houses of Department of Agrlculture in Bangkok and

Department of Agr~culture Extension in Patumthani whch IS the b~ggest storage house for obsolete

pesticides, the task team could identify approximately 76 tons of obsolete pesticides. The location

~ources of this storage house is behind the Rlce Research Statlon, without connection to water re-

and rice f~eld. The task team had collected 5 soil samples around the area of storage house by

using core sampler. The samples were sent to a laboratory for analysis of organochlorine and

organophosphate pesticides residues. Result of analysis revealed that there were no detectable

amounts of any resldues of pest~cides remainng in the soil in that area.

Another visit was to the waste site near the head quarter of Department of Agricuiture

Extension which used to be the pest~cides warehouse where fire broke out in 1982 and no report on

ttie amount of pesticides remained had been made since then. The task tear11 had Inspected the

area which has changed to be car park and soil samples were collected at 3 spots for analysis.

The analysis had been done to cover 15 important organophosphorous chemicals, POPS pesticide

which are organochlorine group and 8 carbamates. The result of ttie analysis shows that even after

23 years the chemicals which were buried underground (about 1 metre depth) could be detected:

Table 7 : Pesticide residues found in soil samples under inventory work

Sample no. Pestlcldes -

& so11 depth OC

# 1 150cm) BHC 0.06

Hept & H.E 0.21

aldrin & dieldrin 2 1 4

DDT 2.18

Chlordane 2.99

d 2 150 cm) BHC 0.02

aldrin & dieldr~n 0.10

D DT 0.07

Chlordane 0.15

Detected resdues In riigikg

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Sample no. & Pesticides

soil depth OC

# 2 (100 cm) BHC

aldrin & dieldrin

DDT

Chlordane

# 3 (50 cm) aldrin &dieldrin

DDT

Chlordane

8 3 (1 00 cm) BHC

aldrin &dieldrin

DDT

Chlordane

lsoprocarb 0.28

fenobucarb 1.0

ND

ND

ND

N D

N D

N D

N D

N D

N D

Detecied residues in rngikg

Based on the result of analysis, one can conclude that mainly organochlorine pesticides

(POPS) such as BHC, aldrin, dieldrin, DDT and chlordane were detected in each soil sample after

more than twenty years. Traces of carbamate were found in the soil at a depth of 1 metre from

surface in one sample.

Although the levels detecied appear relatively low (several ppni), based on industrial use of

the site aldrin and dieldrin levels are elevated on 3 out of 5 samples with a maximum of 15 times the

industrial PRG level. Based on residential use in 4 out of 5 samples pesticides were detected in

levels given !he fact that it is a car park residential use would not beconsidered, but it is not

industrial use either. If e.g. the car park has a concrete, asphalt or other type of cover there will be

little risk for direct contact.

0 P

The levels detected in soil may pose a risk for groundwater contamination, especially the dieldrin

and BHC levels. Depending on the geology, hydrogeology and the use of groundwater this is a

point of attention. We would need a conceptuai model of the site (description ot geology,

hydrogeology and conraminant situation and use of the site) to assess the groundwater exposure

risks. If the site is covered with an asphalt or concrete layer and groundwater is located at a large

depth current risks will be minimal. Of course we do not know what happened in the past, If the

C A

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roundwater 1s shallow, and there is no cover to prevent ~nf~itratlon of raln Into the so11 the

groundwater may be affected.

G~ven the above it was suggested by an env~ronmental expert of Tauw Env~ronmental Consultants

(the Netherlands) to execute a r~sk assessment based on the current use of the s~te before any

defnltve conclusions are drawn on the r~sks of the contamination

2.2.6 Previously revolted data about Obsolete and POPS pesticides residues in fish and other food

products, it- other agricultural products, etc, in Thailand

The suiveys and monitoring of organochlorine resldues in the environment was first initiated in

1976 and went on for ten years t i 1985 (Table 8). The work done was emphasized mainly on water,

sediment, soil, fish and shellfish collected from many sites in the central plain areas of the country.

The analyses showed that organochlor~ne persisted in majority of the samples, roughly 50% in water,

90% in sed~ments and aquatic animals and 90+ in soil samples. Since these surveys and

monitorings were taken during the time that organochlorine was widely used, the maximum

concentration of DDT could be detected as high as 4.0 ppb, whereas the levels in soil were found at

ppm levels. Besides DDT, the other persistent organochlorine insecticides that were frequently found

in environmental samples were KBHC, endrn, aldrin, dieldrin, heptachlor and its metabolites. After

the evidences that all these organochlorines had become widely distributed in food chain

envronment, endrin was banned in 1981 followed by DDT, banned from agriculture used in 1983 and

the rest were all banned in 1988.

During 1987-1989 there was another nationwide monitoring program for residue levels of

organochlorine insecticdes in soil, water, sediment, f~sh and shellfish to observe whether levels of

these chemicals after decreasing use will decline or not (Table 9). The results from extensive studies

revealed that the persistent organochlorine such as KBHC. aldrin, dieidrin, DDT and metabolites,

heptachlor and heptachlor epoxide were found to have been distributed in ail agr~cultural areas and

end up in living organisms such as fish and shelifish, same situation as ten years before, only the

amounts of accumulation were not alarming and had tendency to decline.

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Table 8 : Organochlorine residues detected in the analysis of environmental samples, 1976 - 1985

Type of samples Collection sites No. of analyzed Positive samples%

samples

Water 1 Rivers, canals and 1

1 Crop fields and orchards I

Sed~ment

Soil

Fish and shellf~sh

Markets, rivers and canals

Source: Department of Agriculture

reservoirs

Rivers. canals and

reservoirs

Agricultural areas

Table 9 : Organochlorine resldues detected in the analys~s of environmental samples, 1987 - 1989

Type of samples No. of samples Positive samples (%) Max.concentration of total

DDT

< 1 ppb

< 1 ppm

< 1 ppm

< I ppm

Water

Sediment

Soil

Fish and shellfish

Source: Department of Agriculture

220

256

253

402

ORGANOCHLORINE RESIDUES IN FOOD CROPS

The extensive studies on accumulation of organochlorine residues in food commodities were

carried out form 1982 to 1985 on several food conlmodities such as vegetables, fruits, grains, oil

coups, field crops, meat and eggs (Table 10). In these studies the results showed that a relatively

large number of samples were contaminated with residues of organochlorine which were mainly BHC,

heptachlor and its epox~de, adrin, dieldrin, endrin, DDT and metabolites. The levels of accumulation

were rangea from traces which were lower than determination limits to rather high levels such as

res~dues of adrin and dieldrln were found in Chinese kale at 2 ppm, and heptachlor and heptachlor

epoxide were also detected at 2 ppm in cassava.

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Table 10 : Organochlorine residues from anayss of food commodities during 1 9 8 2 1985.

Type of samples No. of samples Positive samples

Fruits 38.8

Vegetables 66

Grains

Oil crops

Component

66.7

Field crops

Meat

Egg

Cabbage, cauliflower, Chinese kale,

string

Bean, green mustard, sweet corn,

Grape, rose-apple, jejube, rambutan,

orange,

Water melon, strawberry,

606

225

Rice, mung bean, maize,

Soy bean, sesame.

Cassava, sorghum.

23.8

68.7

253

90

112

Source: Department of Agriculture

54.9

41 .O

72.5

However, when these were compared to the analyses of food commodities in 1988, three

years later, on the same commodities, the accumulation levels of organochlorine residues were

detected in lower concentration, less than 1 ppm in every positve sample.

ORGANOCHLORINE RESIDUES IN BIRDS

The information we have from all the preliminary studies has caused concern over

orgarlochlorine contamination not only in food and abiot~c environment but in living organisms, as well.

A case study that give some information on this was an investigation on pesticide residue levels in

birds from the central areas (Table 11). The birds collected were classified into 30 species and

divided into 5 groups according to their feeding habits. Result form analysis for organochlorine

insecticides in stomach content, livers and tissues showed residues of DDT and dieldrin in every

samples whereas traces of some other organochlorine were also present in some samples. Although

the average levels of the most commonly found DDT and dieldrin rarely exceeded 1 ppm which were

reported in several studies not hazardous to treated birds in laboratory experiments, However, the

combined effects of multiple organochlorine residues on birds and their long term consequences

should be carefully examined.

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Table 11 : Average values of DDT and dieldrin (mglkg) In stomach content, livers and tlssues of 5

arouDs of 90 birds. (1982)

Res~dues of DDT Residues of d~eldr~n

Group Number stornacn llver tlssue stomach he r tissue

Carnivorous 35 0.09 0.17 010 0.08 0.09 0.03

Herbivorous 17 0.09 0.16 0.05 0.07 0.12 0.03

Omnivorous 13 0.20 0.1 1 0.05 0.14 0.08 0.03

Insectivorous 16 0.19 0.31 0.13 0.09 0.12 0.06

Blrds of prey 8 0.26 0.30 0.13 1.1 0.03 0.1 6

Source: Department of Agriculture

IMPACT ON HUMAN HEALTH

In order to assess the risk from exposure of organochlorine pesticides or consumption of food

containing their residues, analysis of human blood and breast mlk had been initiated and carry on

during 1980- 1983 and 1980- 1986 (DOA 1980, 1983, 1986). The result of human blood analysis for

organochlorine residues on samples drawn from 127 farmers and 40 unidentified professions showed

that about 20% of the samples from both groups were found contained residues of organochlorine at

ppb levels whch were higher in farmers' group (Table 12). When this compared to 99 blood samples

taken from lactating mothers in 1994 it was revealed that trend of accumulation had decreased to

very low levels with fewer posltive samples. Investigation of organochlorine residues in breast milk

had been conducted during 1980, 1983 and 1986 (Table 13). The samples were collected from

lactating mothers in hospitals and analyzed for residues on a whole milk basis. The first batch of

samples were analyzed only for residues of DDT, whereas the second and third studies included

more organochlorine pesticides. The mean values of pesticide residues in breast milk from the three

surveys remain about the same which consistent with the levels reported on workdone by scientist

from different countres, eg USA, Australla, France. Germany, Japan, India and some Latin American

countries (Curie et al. 1979). Although all the studies worldwide have shown that almost 100% of milk

from lactating mothers contained residues of DDT however, it is contradictory regarding correlation of

age, frequency of pregnancies, de t and living place of the mother (Spicer et al. 1993). Therefore, it

would be appropriate to continue monitoring breast milk samples for residues ot all these

organochlorine Insecticides to see whether the level is still remain the same as before or it has a

downward trend, as well.

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Table 12 : Analyses of blood samples for organochlorine residue during 1 9 8 0 1983 and 1994

Number of Positive %

samples

Residues found

1980- 1983

Farmers 127 26 DDT, endrin, aldr~n, d~eldr~n,

Iindane, hept. epox

Unident~f~ed 40 19 DDT, hept epox

professions

1994 99 16 p,p' - DDE

Lactating mothers

Source: Department of Agriculture

Table 13 : Organochlorine residues in breast milk samples from 1980 - 1986 (whole milk basis).

Pesticide residue Mean, ppm Positive Samples, %

N=208 N=229 N=192 N=208 N=229 N=192 -

p,p' - DDE 0.125 0.127 0.198 100 94.7 100

p . p ' DDT 0.036 0.036 11.1 44.8

Dieldrin 0 0.0'14 0.011 18.3 7.3

Hept & H.E. 0.028 0.059 1.3 0.5

Source: Department of Agriculture

The result from all analysis had revealed that several organochlorine such as DDT, aldrin,

dieldrin, heptachlor, hept, epoxide could be detected. All these persistent insecticides have been

banned since many years. However, their persistent residues could be found only at very low levels,

showing that there is probably no alarming situatio~ any more.

2 3 Waste management

Presently the preferred disposal method of obsolete stocks is high temperature inclneratlon

in a dedicated hazardous waste incinerator With the exception of some newly lndustrlalized

countries, there are no safe and environmentally sound hazardous waste incineration fac~llties in

developing countries Small incinerators are generally not suitable for the destruction of bulk

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quantities of pesticides due to their low temperature destruction range, the possibility of forming

dioxins and the lack of proper flue gass cleaning. New technologies for destruction of obsolete

stocks might be forthcoming but currently are not wdely available or commercially feasible.

In the absence of local incneraton facilities, the alternative is to ship the waste to an

incinerator in industrialized countries overseas that are willing to accept for destruction. Generally,

the costs of such operations are beyond the f~nancial capacities of developing countries and needs

larger sums of money and technical expertise: All international transport has to be according to the

regulations of international Conventions and international regulations (Basel Convention,

International Maritime Dangerous Goods Code-IMDG). The answer to the problem of obsolete

pesticides therefore lies in awareness ratsing and prevention of accumulation of obsolete

pestic~des. In particular, there is a need for creating greater awareness at various concerned levels

of the country for the development of preventive measures for stock-piling of obsolete pesticides.

3. National infrastructure for POPs pesticides management

3.1 Institutional structure and its mandates for POPS management

Although there is presently no special legislation of POPs, Thailand has established a

number of legal instruments and non-regulatory mechanisms to control the use of chemicals and

reduce risk to human health and the environment originating from chemicals including POPs.

Among these are:

The Enhancement and Conservation of National Environment Quality Act B.E. 2535

(1992): This Act prov~des a legal bass for the management and control of environmental quality,

and emissionleffluent standards, montoring, policy development and requirements for EIA as well

as the pollution control.

With respect to the hazardous wastes and chemicals related to POPs and in case of no

specific law thereto, the Minister shall, with the advice of the Pollution Control Committee, have the

power to issue ministerial regulation spec~fying the types and categories of hazardous wastes

generated from the production and usage of chemicals or hazardous substances in the production

process of industry, agriculture, sanitation and other act~vates whch shall be brought under control

For this purpose, rules, regulations, measures and methods must also be prescribed for rhe control

of collection storage, safety measures, transportation, Import into the Kindom, export out of the

Kingdom, and for proper and techn~cally sound management, treatment and disposal of such

hazardous wastes.

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The Factory Act B E . 2535 (1992): Thls Act is to control factory operations regarding

Waste disposal, pollution ernlssion and contamination with the main objective of minimizing the

impact on the environment,

The Minister shall have the power to prescribe the ministerial rules fixing the factory of

any type, kind or size to be the group 1 factory, group 2 factory or group 3 factory as the case

many be by taklng into consideration the necessity for the contro, prevention of nuisance,

prevention of damage and prevention of nuisance, prevention of damage and prevention of danger

n accordance wlth the gravity of impact on the public or environment.

The Customs Act B.E. 2469 (1926) and amendments B.E. 2534 (1991): Is the prlmay

law governing the control of customs duties and the collection of taxes on imported and exported

goods on behalf of other government agencies, sbsh as value added tax, excise tax, and ~nunicipal

tax as well as the prevention and control smuggling of goods and other lieg gal products included

the imported and exported chemical products and hazardous wastes:

The Public Health Act B.E. 2535 (1992): This Act covers the prevention and

management of all aspects of danger and nuisance caused by pollutants. The Act is characterized

as most decentralization for the local administration. Minister of the Public Health Ministry IS

incharge and control of execution of the Act and have powers to appolnt public health offcials and

local governmental authorities all over the country . The Minister also have powers to issue the

Minsterla Regulation as;

(1) Prescribing rules, procedures and measures for controlling or overseeing actvites or

operations on ~natters under ths Act.

(2) Prescribing !iving standards suitable to the livelihood of the population and

procedures for controlling or overseeing or remedying things affecting the living

standard suitable to the livelihood of the population.

Hazardous Substance Act B.E. 2535 (1992) This Act has come into force in 1992 and

replace the other two of 1967 and 1973. The reason for the proclamation of this Act is that at

present a great nurnber of hazardous substance have been used in various business and some of

thern have caused serlous injury to the persons, animals, plants, property and environments.

Althouth at present there exisr some laws which are applicable to the hazardous substance, there

are so niany of thern wnich are under the powers of several ministries, bureaus, departments as a

result of different proclaniations made in different periods of time entailing discrepancies and

incomprehensive-ness of thelr provlsion. It is therefore expedient to revise the law on toxic

substance by expanding the scope of application to cover every kind of hazardous substance as

well as to adopt the criteria and procedures for an even more suitable control of the hazardous

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substance and to establish the administrative system to promote coordination among various a

agencies involved in the supervision of the said hazardous

3.2 Natlonal policies for POPS pesticides management

Exlsting pollcy and ~mplementation guidelines

To address the chemical (in general) management in the country, Thailand has set up 4

main policies as 1) Establish an effective system for rnanaging hazardous substances coverllig

import, export, production, transport, trade, use, storage and waste destruction. 2) Establish system

for prevention and mitigation of emergency and serious accident resulting from hazardous

substances 3) Promote reduced utilization of pesticides and 4) Encourage the private sector to

participate in investments for addressing problems related to chem~cal management.

Under these policies, guidelines on law enforcement and management have been

implemented.

Law Enforcement Guidelines

1) Strict and efficient control of hazardous substances according to the law by assigning

unlts other than government agencies and the private sector to monitor these

substances

2) Accelerate the ~mprovement and amend concerned laws and regulations for systematic

management of hazardous substances in all stages: import, export, production, trade,

transport, utllzation, storage and the &struction of wastes.

31 Formuiate standards for hazardous substances contaminating the environment,

agricultural products and consumable items, to cover a greater number of types of

substances.

4) Instruct all industries that use and p~~oduce large quantities of extremely dangerous

substances to prepare an environmental impact assessment report and risk

assessment.

5) Control the storage of hazardous substances by designat~ng areas for establishing

~NarehOUSeS f o ~ hazardous products. Stipulate srandards for warehousing ot

hazardous products, along with systems and insurance system to prevent and mitigate

emergencies 'Nhen an accldent occurs.

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6) Consider strictly prohibiting imports and production or restricted uses of hazardous

substances in agriculture, industry and public health that substantially affect heath and

the environment.

7) Control the transport of hazardous substances by stipulating standards for vehicles,

methods of transport, suitable routes for channeling transportation, diiving speed,

qualifications and duties of drivers of transport vehicles and labels giving details of the

hazardous substances.

3.3 Legal mechanisms for POPS pesticides nianagenient

3.3.1 National iegai instrument for the management of POPS pesticdes.

The hazardous substance is classified according to the needs for control as follows:

(1) Type 1 hazardous substance is that of which the production, import, export, or

having in possession must comply with the specified criteria and procedures.

(2) Type 2 hazardous substance is that of which the production, import, export, or

having possession must first be notified to the authority and must also comply with

the specified crteria and procedures.

(3) Type 3 hazardous substance is that of which the production, import, export, or

having possession must obtain a permit.

(4) Type 4 hazardous substance is that of which the production, import, export, or

having in possession is prohibited.

For the purpose of prevention and stop of danger that may be inflicted upon the

persons, animals, plants, property, or environments, the Minister of Industry with the opinions of the

committee, shall have the power to publish in the Government Gazette designating the names or

qualifications of hazardous substance, type of hazardous substance, period of application and

responsble agencies for the control of the said hazardous substance.

There are numerous chemicals considered as severely restricted or banned for

agriculturai and public health use, as well as in foods, cosmetics and household products. A

summary for the POPS gvlng the date of the ban and some of its reasons is shown as the following:

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Table 14 ' Banned POPS chemicals in Thailand

Chemicals

Aldrin

Chlordane

DDT

Date of Ban

1988

D~eldrin

Reasons

Persistent, accumulate in living organisms

2000 (AG) 1 environment. many alternatives

Source: Department of Agriculture, AG = agricultural use

1995 (PH) / Possible carcinogen, persistent, high impact. to I

1983 (AG)

1994 (PHI

1988

poisoning, high risk for users

Persistent in agricultural products and in food chain.

I

Heptachior

Hexachlorobenzene

Mirex

PCBs

Toxaphene

PH = public health use

Persistent and accumulation in food chains. possible

carcinogen in tested animais

Persistent, accumulate in living organisms, high acute

Endrin I

All POPs pesticides are classified and listed under the Type 4. It means that the whole

cycle of management from production, import, export and having in possession are prohibited or

banned. It is noted that banned or prohibited measure was applied only importation until the

amended Act after 1992. Therefore at present, all POPS pesticides are totally banned. It must be

noted that Mirex and Hexachlorobenzene (as Type 4 pesticide) have never been imported.

1981

I harm 10 non-target organisms

Responsible agencies and authorities under the Hazardous Substance Act 1992

This Act play an important role in management and control of POPs chemicals and

chemicals in general. All government agencies are able to implement this act in particular

purposes as referred in the Act. For instance, the government agencies have a direct power to

execure the Act as follows.

1) Department of Agriculture, Ministry of Agriculture and Cooperatives iMOAC)

empowered to regulate and control agricultural toxic substances i.e. pesticides, plant

1988

1995

1975

1983

growth regulator etc.

Persistent, accumulate in living organisms

Never imported I I

Never imported i Risk to human health and the environment

Possible carcinogen in tested animals, persistent

I

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2) Department of lndustrlal Works, Minstry of lndustry (MOI) empowered to control all

hazardous substances used in industries.

3) Food and Drug Administration Office, Ministry of Public Heath (MOPH) empowered to

control hazardous substances relating household products, daily or public health uses.

The Minister of Industry shall issue the prescription of the announcements the names or

identification of hazardous substances, types of hazardous substances, period of appllcatlon and

responsibiiity agencies for the control of said hazardous substances and also make a list of

hazardous substances of which production process and nature are likely to cause injury.

The hazardous substances are regulated by type as llsted under the Hazardous Substance

Act 1992 which is implemented jointly by main responsible agencies. The Ministry of lndustry has

the power to publish the list in the Government Gazette. Other notification on different matters. i.e.

registration, criteria and procedures of production, Import etc., shall be issued on its own ministeral

notifications.

3.3.2 Regionali~nternat~onal legal instrument for the management of POPS pest~cides.

Thailand has actlvely supported activities and international actions related to chemical's

management, includng the Stockholm Convention on Persistent Organic Pollutants (POPS). Having

recognized the impact of POPS chemicals to human health and the environment, Thailand by

several government agencies has carried out monitoring programs on chem~cal residues in soil,

water and agriculture products includ~ng POPS pest!cides and PCBs. Data and results have been

compiled and the environmental situation evaluated annually. Thailand is an active member of

international organizations and has partic~pated in various programs such as IFCS, IPCS. UNEP.

WHO, FAO, UNIDO, and ILO as well as nternatlonal agreements, such as Agenda 21, UNEP

London Guidelines, FA0 Code of Conduct, Montreal Protocol, Basel Convention, and WTO

agreements.

Thailand has recognized the problem of chemical hazards as a high pr~ority, particularly the

Importance of the chemical management under the chapter 19, Agenda 21. Since the 1960s it has

been tackling health and environmental problems systematically and enacted legislation at the

national ievel. At present, there are many government agencies responsible in the field of chemical

control and management as mentioned earlier.

Page 33: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

4. Summary of the future production, use and disposal of POPs pesticides requirement for

exemptions

Some of the POPs pesticdes were never produced nor imported into the country and a!l ot

the remainder pesticides have been banned for all uses since several years. Therefore, it is

antic~pated that the inventory for POPs pesticides will be very less for all chemicals and thls

conformed to lists of chemicals in Annexes A and B of the Convention. As none of the POPS

pesticdes are being used in Thailand as of requirement under the Stockholm Convention, there is

no need to ldenlify needs for country-specific exemptions to further usage of POPs. The Natlonal

Implementaton Plan required under Article 10 on public information , awareness and education has

already existed in Thailand, as well as research, development and monitoring under article 11

However, additional collection of information and cooperation among concerned agencies need to

be strengthened.

5. Existing programs for monitoring of environmental/human health impacts

The programs of monitoring of environmental /human health impacts had been done

intensively during 1970-1990 by many government research institutes. However, the results of

those investigations seemed to show no alarming situation. Therefore, the activities on monitoring of

health and environmental Impacts of POPs pestic~des are becoming on downtrend and finally, not

continue.

6. Current level of information, awareness raising and education

In general, the existing system in Thailand is in compliance with the legislative provisions

and control of hazardous substances including POPS pesticides. However, the knowledge on

disposal of wastes and impacts on health and environment 1s not enough disseminated to relevant

people at all levels.

Page 34: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

Annex

Page 35: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

Annex 1. Detailed Overview sorted on Site

Page 36: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm
Page 37: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm
Page 38: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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Page 39: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm
Page 40: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm
Page 41: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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Page 42: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm
Page 43: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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Page 44: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm
Page 45: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm
Page 46: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm
Page 47: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm
Page 48: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

Annex 2. Detailed Overview sorted

on active ingredient

Page 49: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm
Page 50: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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Page 51: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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Page 52: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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Page 53: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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Page 54: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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Page 55: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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Page 56: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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4

Page 57: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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5

Page 58: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

- ..

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6

Page 59: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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Page 60: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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Page 61: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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Page 62: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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Page 63: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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Page 64: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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Page 67: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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Page 68: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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Page 69: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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Page 70: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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Page 71: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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5

Page 72: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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aitn

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t. T

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nd

6

Page 73: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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7

Page 74: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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8

Page 75: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

--

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9

Page 76: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

--

~-

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IP:P

DP

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artm

ent,

Tha

iland

10

Page 77: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm
Page 78: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm
Page 79: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

Annex 3. Detailed Overview sorted on

manufacturer

Page 80: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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Page 81: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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Page 82: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

- 7

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Page 83: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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Page 84: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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Page 85: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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Page 86: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

- ~-

Manufacturer Active ingredient Concentration Site number ~ o r m . ~ ~ ~ e ' ~ o t a l quantity Trade name ~ ~ l l ~ a n u f a c t . Arrival

~ I I

I -

May 8 Baker. Dagenham Foselyl A1 8 0 % 1 I I A 6 ~ o r w p - 24 kg Aleate P I I

-~--~ ~ ~

Mitsomboon Ltd. Heptachlor

~ ~~~~~~ ~ ~ ~ ~ ~ - - ~ 1 ~~ ~ --

Milsomboon Ltd Chlordane 4 k g ~ e m o r y : P

~~- ~ ~~~ ~ ~~ ~ .. ~

. ~

-- -- --

Monsanlo Butachlor + Propanil 27.5+27. % wlv e - 264 lilre 'Challenge P

~ -~ ~~~p~ ~~ ~p

~ ~ ~

Monsanto Thailand Ltd. Unknown 1298 lire Lasso P 10-08-1998

~ ~~ ~ - ~ ~

~~-p~- . Parko Parathion methyi 3 grlkg 1 % k g ethyl parathion dust P

- ~ , - ~ ~- ~ ~-~ , ~~ ~. ~~-p~~ ~~ -~ ~~ p~

Pat0 Industrial Chem. Ltd Folpet 4 2 kg ~ o l ~ a n I P ~~ ~ A-

~ -- ~ ~ ~

Pato lnd&trial Chem. Ltd ~imethoate + 12+12 grllitre 5 A 36iEcor e - ! 366 litre Dimethoale + P 10-11-1994'

lsocarbophos ~ - - ~ ~ ~ ~~~ ~~ ~~ - ~ --L ~ 1 1 ;emulsifiable ~~ ~~ Isocarbophos ~~~~

./, ;-~- ~

~~~

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~ ~~p-~~

Pato Industrial hem. Ltd Folpet 501 5 A 5 G h o r w p - 234 kg Folpan P

1~J wettablei ~ ~ - - - - ~~~ ~ -- - ~ - ~- ~- ~ ~~ ~

~~ ~ -~ ~-~

Project Field Profenfos + 40+4 % wlv 5 1 A 6 7 ~ c or e - 115 lilre Proper 44 P 10-02-2001 / lemulsifiable I Cypermelhrin --

~-~ ~ ~ ~ ~ ~ - ~ ~ - ~ p ~ ~ ~ ~ ~ ~ ~ ~ - .... ~~

~~ ~- , A , r~ ~.~ ~ ~- - I L~-~~ , ~ ~

Ratchakitpauana LTD. Unknown 7 Liquid 12- Yeast Protein P Hydrolysate

-~ ~ ---- ~~~ - ~ ~ ~ ~

- ~ -- ~

-~ - ~

Rhone Poulenc Ethoprophos l o % [ 4 j ~ - 1201% kg ~lhoprophos I P 06-08-19971 ~ r i l n ~ l l a r , ~~ , ,

~~~ ~ - - ~ ~ . - - ~ ~- ~~

~~ ~p ~ -~ ~~

--

~ h o n e Pouienc Cvoermethrin + 22.50+2 arllitre ! 5 1 A 1 3 3 ~ c or e - 109 litre Panon P ' 11-07-1994 ~ h b s a ~ o n e -~ ~ 8.75: 1 1.- 1 emulsifiable ~~ - ~~

~~ ~~ -- ~

Rhone ~ou lknc lprodione 96' litre Rofral ~ 3 0 - 0 6 - 1 552

~~~ ~~~~ i

~ ~~~ ~ ~- -- ~- -- 7- ~

G o n e ~ou lenc Fipronil 5 % wlv 2 4 litre ~ i p r o n i l 50 SC P 10-03-19971

, ~ ~~~ ~ ~ ~~~~ ' -- ~2

Page 87: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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Page 88: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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Page 89: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

I 8

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Page 90: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm
Page 91: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

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Page 92: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

Annex 4. Pictures of activities on POPS

pesticides during the inventory

Page 93: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

Site visit at Chiengmai Province (23-24 December, 2004)

Page 94: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

Site visit at Supanburi Province (11 January, 2005)

Page 95: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

Site visit at Khonkaen and Mahasarakarm Province ( f c f s January, 2005)

Page 96: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

Site visit at Nakorn Pathom Province (17 Januaty, 2005)

Page 97: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

Site visit at Krabi Province (27-28 January, 2005)

Page 98: POPS Pesticides Inventory Reportinfofile.pcd.go.th/haz/POPs_Pesti_En.pdf · the Project: Enabling Activities for the Development of the National Implementation Plan (NIP) of the Stockholm

NIP/POPs Coordination Office p6drz1iwqn NIP I POPS Pollution Control Lkp.rtmeet, 92 P h a h ~otbio 7. mys~bsi BsagkaI~ IW n m i h m d T& (662) 298 2457

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