polyurethane foam in automotive seats-bachelor year project
DESCRIPTION
This project was to reduce the production cost of PU foam without disturbing its quality, by altering formulation of Polyurethane foam which OEMs are using. Successfully completed the task by increasing production rate to 25% and moreover decreasing amount of raw materials required per unit production.TRANSCRIPT
AUTOMOTIVE APPLICATION OF POLYURETHANE FOAM
BY
M. Osama Adil PP-30
Rabia Raza Khan PP-19
Noureen Naz PP-37
Group-8 Department of Polymer & Petrochemical Engineering
In Collaboration With:
BASF-The Chemical Company
Internal Advisor: M. Raza Khan External Advisor: M. Abbas Ameer Meerani
• Overview
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Introduction
Polyurethane Foam and their Chemistry
Application’s Selection
Aims and Objectives
Mold and Tools Designing
Experiments
Testing Results and Comparison
Profit Estimation
Conclusion and Future Work
• Introduction
Foam
Classification of f oam
o Open cell foam
o Closed cell foam
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• PU Foam and their Chemistry
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Polyurethane Foam
o versatile comparing with all polymer foams
o can be manufactured between two extremes of softness and
hardness
o resist bacterial growth
o availability of raw materials at cheap rate
o can be classified as
a) rigid polyurethane foam
b) flexible polyurethane foam
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Applications of Flexible Polyurethane Foams
• PU Foam and their Chemistry
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Polyurethane Chemistry
o Reactants are:
1) Polyol
1) Isocyanates
• PU Foam and their Chemistry
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Reactions
o Blow reaction
• PU Foam and their Chemistry
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Reactions
o Gel reaction
• PU Foam and their Chemistry
• Application’s Selection
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Major automotive applications of PU Foam we discussed
1. Tyres 2. Headliners 3. Seats
SEATS Final Selection
Car Seats Bike Seats
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• Application’s Selection
Motorbike Seat Car Seat
1. Product divisions 1 Part: Seat 4 Parts: Seat base,
Backrest, Headrest
and Armrest
1. Additional Parts Nothing Supports
1. Cost 800-2000 PKR More than 3000 PKR
Comparison between bike seat and car seat
So after doing general feasibility analysis, bike seat was
selected to proceed our project
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• Aims & Objectives
Depending on selection of automotive application of PU foam,
aims of this proposal are:
o To significantly reduce the density of PU foam without
disturbing its mechanical properties
o To reduce the production cost of PU foam for bike seats
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• Tools & Stirrer Designing
Mold Designing
o Sample seat of OEM’s product – Master Foam CD-100 Seat
o Reverse engineering
o CAD Models
o Fabrication
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CAD Model
o Front View
• Tools & Stirrer Designing
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CAD Model
o Top view
• Tools & Stirrer Designing
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Fabrication of study mold
• Tools & Stirrer Designing
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• Tools & Stirrer Designing
Stirrer Designing
o CAD Model
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• Tools & Stirrer Designing
Stirrer Designing
o CAD Model
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Stirrer
o Before fabrication, workshop concluded that discussed model of stirrer would
be failure due to wings instability during mixing which can break it.
o Workshop proposed another 3D stirrer(beater) having following properties
Speed Switch 3-Speed
Revolution: 700-1050 rpm
Switches: 700rpm, 875rpm and
1050rpm
Weight: 0.45 Kg
Dimensions (H×W×D): 12.2×8.0×18.4 cm
• Tools & Stirrer Designing
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• Experiments
Composition of reactants
Composition of Polyol Composition of Isocyanate
Components Parts by weight
Polyol 70.000
Co-polymer polyol 30.000
Silicon Surfactant 1.000
Water, Blowing agent 4.2000
Dimethanol Amine,
Pure, Chain Extender 1.700
Amine Catalyst 0.1
Tin Catalyst 0.5
Component Parts by weight
ELASTOFLEX
Diphenylmethane-
4,4'-diisocyanate
(MDI)
90
Polymeric MDI (P-
MDI)
10
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Formulations
• Experiments
Sample No Polyol
(A) (gm)
Isocyanate (B)
(gm)
Mixing
time (sec)
Curing time
(min)
Mixing
Speed (rpm)
Foam
Weight
(gm)
Density
(lb/ft3)
A/B Ratio Remarks
A1 30 15 5 4 700 27.00 3.8095 2 Polyol remains in
bottom
A2 30 16 5 4 700 26.21 3.7813 1.87 Still Polyol remains
in bottom
A3 30 17 5 4 700 25.73 3.6319 1.76 Polyol odor in foam
A4 30 18 5 4 700 25.10 3.5471 1.66
A5 30 19 5 4 700 24.81 3.4988 1.57
A6 30 20 5 4 700 24.55 3.4539 1.5
A7 30 21 5 4 700 24.06 3.3947 1.42
A8 30 22 5 4 700 23.56 3.3242 1.36
A9 30 23 5 4 700 23.71 3.3453
1.30
A10 30 24 5 4 700 24.7 3.4850
1.25
A11 30 25 5 4 700 26.13 3.6868
1.20
A12 30 26 5 5 700 27.45 3.8730
1.15
A13 30 27 5 5 700 27.82 3.9252
1.11 Unstable
A14 30 28 5 7.8 700 28.1 3.9647 1.07 Unstable, yellowish,
isocyanate is visible
A15 30 29 5 9 700 28.26 3.9873 1.03 Fail, Settling time is
very high, unstable
A16 30 30 5 Infinity 700 28.49 4.0198 1 Fail, Iso everywhere
un-reacted
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Formulations
• Experiments
Sample No Polyol (A)
(gm)
Isocyanate (B)
(gm)
Mixing time
(sec)
Curing time
(min)
Mixing Speed
(rpm)
Foam Weight
(gm)
Density
(lb/ft3)
A/B Ratio Remarks
B1 30 15 3 4 875 25.97 3.6642 2 Polyol remains in
bottom,
B2 30 16 3 4 875 25.49 3.5965 1.87 Still Polyol
remains in bottom
B3 30 17 3 4 875 24.85 3.5062 1.76 Polyol odor in
foam
B4 30 18 3 4 875 24.67 3.4808 1.66
B5 30 19 3 4 875 24.41 3.4441 1.57
B6 30 20 3 4 875 24.25 3.4215 1.5
B7 30 21 3 4 875 24.02 3.3891 1.42
B8 30 22 3 4 875 23.91 3.3736 1.36
B9 30 23 3 4 875 24.55 3.4639 1.30
B10 30 24 3 4 875 25.46 3.5922 1.25
B11 30 25 3 4 875 26.93 3.7997 1.2
B12 30 26 3 4 875 27.38 3.8632 1.15
B13 30 27 3 6 875 28.08 3.9619 1.11 Unstable
B14 30 28 3 8.5 875 28.23 3.9831 1.07 Unstable,
yellowish,
isocyanate is
visible
B15 30 29 3 Infinity 875 28.57 4.0311 1.03 Fail, Settling time
is very high,
unstable
B16 30 30 3 Infinity 875 28.74 4.0550 1 Fail, Iso-
unreacted
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Formulations
• Experiments
Sample No Polyol (A)
(gm)
Isocyanate (B)
(gm) Mixing time
(sec)
Curing time
(min)
Mixing
Speed (rpm)
Foam
Weight (gm)
Density
(lb/ft3)
A/B Ratio Remarks
C1 30 15 3 4 1050 26.47 3.7348 2 Polyol remains
in bottom,
C2 30 16 3 4 1050 25.81 3.6416 1.87 Still Polyol
remains in
bottom
C3 30 17 3 4 1050 25.36 3.5781 1.76 Polyol odor in
foam
C4 30 18 3 4 1050 24.72 3.4878 1.66
C5 30 19 3 4 1050 24.51 3.4582 1.57
C6 30 20 3 4 1050 24.27 3.4243 1.5
C7 30 21 3 4 1050 24.02 3.3891 1.42
C8 30 22 3 4 1050 23.87 3.3679 1.36
C9 30 23 3 4 1050 23.92 3.3750 1.30
C10 30 24 3 4 1050 24.01 3.3877 1.25
C11 30 25 3 4 1050 25.67 3.6219 1.2
C12 30 26 3 4 1050 26.74 3.7729 1.15
C13 30 27 3 6 1050 27.32 3.8547 1.11 Unstable
C14 30 28 3 8.5 1050 27.65 3.9012 1.07 Unstable,
yellowish
isocyanate is
visible
C15 30 29 3 Infinity 1050 27.92 3.9393 1.03 Fail, Settling
time is very
high, unstable
C16 30 30 3 Infinity 1050 28.13 3.9690 1 Fail, Iso- un-
reacted
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Observations
• Experiments
3
3.5
4
4.5
15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
De
nsi
ty (l
b/f
t3 )
Isocyanate (gm)
Graph of A Series Samples -Iso (gm) vs. Density (lb/ft3)
at 700 rpm
3
3.2
3.4
3.6
3.8
4
4.2
15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
De
nsi
ty (l
b/f
t3 )
Isocyanate (gm)
Graph of B Series Samples -Iso (gm) vs. Density (lb/ft3)
at 875 rpm
3
3.2
3.4
3.6
3.8
4
4.2
15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Den
sity
(lb
/ft3 )
Isocyanate (gm)
Graph of C Series Samples -Iso (gm) vs. Density (lb/ft3) at 1050 rpm
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• Testing Results & Comparison
Foam testing is quite different than plastic testing
There were 4 tests conducted to analyze mechanical properties
o Density
o Indentation force deflection
o Compression force deflection
o Tear resistance
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Density
• Testing Results & Comparison
3 3.1 3.2 3.3 3.4 3.5 3.6 3.7 3.8 3.9
4
Sample 1
Sample 2
Sample 3
Average
OEM foam
Altered foam
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Indentation force deflection (IFD) test
IFD Comfort Factor
• Testing Results & Comparison
0 100 200 300 400 500 600 700 800 900
1000
IFD@25% IFD@65%
lbf/
50
in2
OEM's Foam
ALTERED FOAM
0
0.1
0.2
0.3
0.4
0.5
Comfort Factor
OEM's Foam
Altered Foam
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Compression force deflection (CFD) test
• Testing Results & Comparison
0
20
40
60
80
100
120
140
160
180
200
CFD
(K
g f)
OEM's Foam
Altered Foam
Comparison of CFD Values
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Compression force deflection (CFD) test
• Testing Results & Comparison
0
1
2
3
4
5
6
Rec
ove
ry t
hic
knes
s d
iffe
ren
ce
(mm
)
OEM's Foam
Altered Foam
Comparison of recovery thickness after CFD test
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Tear resistance
• Testing Results & Comparison
0.25
0.26
0.27
0.28
0.29
0.3
0.31
Tear
Str
engt
h (
N/m
m)
OEM's Foam
Altered Foam
Comparison of tear resistance
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• Profit Estimation
Comparison of OEM FOAM vs. ALTERED FOAM on basis of
density
OEM’s FOAM ALTERED FOAM
1. Density 3.85 lb/ft3 3.34 lb/ft3
1. Seat Weight 1.76 lbs 1.53 lbs
1. Seat Volume 0.458 ft3 0.458 ft3
1. Polyol/Iso Ratio 1/0.85 1/0.73
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• Profit Estimation
Profit estimated with respect to material’s cost price
Weight difference 0.23 lbs
Weight difference (%) 13.07 %
Material Saved 13.07%
Cost Price of material for OEM/Product X
Price of Material Saved 0.13X
Material’s Cost Price per seat reduced X-0.13X
Profit in producing higher density PU foam Y
Production Profit using Altered Foam Y+0.13X
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• Conclusion
Successfully reduced foam density
Better mechanical properties of reduced density foam are
achieved
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• Future Work
Our Limitations and recommendations for future work
o RIM
o Molecular level research
o Blended reactants
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