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Page 1: Polymer Matrix Composites

Classification based on Matrices

Page 2: Polymer Matrix Composites

Polymer Matrix Composite (PMC) is the material consisting of a polymer (resin) matrix combined with a fibrous reinforcing dispersed phase.

Polymer Matrix Composites are very popular due to their low cost and simple fabrication methods.

Page 3: Polymer Matrix Composites

Discontinuous phase - ReinforcementContinuous phase - Matrix

Polymer(Matrix) Composite (Matrix + Reinforcement)

• Reinforcements– Principal load bearing member.

• Matrix– provides a medium for binding and holding the reinforcements

together into a solid.– protects the reinforcement from environmental degradation.– serves to transfer load from one insert (fibre, flake or particles) to

the other.– Provides finish, colour, texture, durability and other functional

properties.

Page 4: Polymer Matrix Composites

What is a polymer?

Poly mer

many repeat unit

C C C C C C

HHHHHH

HHHHHH

Polyethylene (PE)

ClCl Cl

C C C C C C

HHH

HHHHHH

Polyvinyl chloride (PVC)

HH

HHH H

Polypropylene (PP)

C C C C C C

CH3

HH

CH3CH3H

repeatunit

repeatunit

repeatunit

Examples of polymers:

A polymer is a large molecule (macromolecule) composed of repeating structural units typically connected by covalent chemical bonds

Page 5: Polymer Matrix Composites

Classification of Polymers Thermoplastic polymers - Linear or branched polymers in

which chains of molecules are not interconnected to one another.

Thermosetting polymers - Polymers that are heavily cross-linked to produce a strong three dimensional network structure.

Elastomers - These are polymers (thermoplastics or lightly cross-linked thermosets) that have an elastic deformation > 200%.

Page 6: Polymer Matrix Composites

Polymerisation:This is the process of joining monomers into gaint chain like molecules.

Methods of Polymerisation:• Condensation polymerisation• Addition polymerisation

Degree of polymerization = No of monomer units in a chain 103 to 105

Page 7: Polymer Matrix Composites

Thermosets

Thermoset materials are usually liquid or malleable prior to curing, and designed to be molded into their final form.

Has the property of undergoing a chemical reaction by the action of heat, catalyst, ultraviolet light, etc., to become a relatively insoluble and infusible substance.

They develop a well-bonded three-dimensional structure upon curing. Once hardened or cross-linked, they will decompose rather than melt.

Thermoset materials are generally stronger than thermoplastic materials due to this 3-D network of bonds, and are also better suited to high-temperature applications up to the decomposition temperature of the material.

Page 8: Polymer Matrix Composites

• Thermosets are made by mixing two components (a resin and a

hardener) which react and harden, either at room temperature or on

heating.

• The resulting polymer is usually heavily cross-linked, so thermosets

are also called as network polymers.

• The cross-links form during the polymerisation of the liquid resin and

hardener, so the structure is almost always amorphous.

• On reheating the crosslinks prevent true melting or viscous flow so

the polymer cannot be hot-worked. Further heating just causes it to

decompose.

Page 9: Polymer Matrix Composites

Types of Thermosetting plastics

Page 10: Polymer Matrix Composites

Thermoplastics In thermoplastic polymer, individual molecules are linear in structure with

no chemical linking between them.

They are held in place by weak secondary bond (intermolecular force), such as van der Walls bonds and hydrogen.

Page 11: Polymer Matrix Composites

Some thermoplastics normally do not crystallize, they are termed

as"amorphous" plastics and are useful at temperatures below the Tg.

Generally, amorphous thermoplastics are less chemically resistant.

Page 12: Polymer Matrix Composites

Types of Thermoplastics

Page 13: Polymer Matrix Composites

Effect of Temperature on Thermoplastics

Degradation temperature - The temperature above which a polymer burns, chars, or decomposes.

Glass temperature - The temperature range below which the amorphous polymer assumes a rigid glassy structure.

The effect of temperature on the modulus of elasticity for an amorphous thermoplastic.

Page 14: Polymer Matrix Composites

Thermoplastics Vs Thermosets

Page 15: Polymer Matrix Composites

Stress-strain behavior of different polymer matrices

0

10

20

30

40

50

60

70

80

90

0 1 2 3 4 5Strian(%)

Str

ess

(Mp

a) Phenolic

Polyester Epoxy

0

10

20

30

40

50

60

70

80

0 100 200 300 400 500Strian(%)

Str

ess

(Mp

a)

Polysulfon

PolyamidPolyethylene

Thermoplastic polymers Thermosetting polymers

Notice to the range of ultimate strains of different polymers

Page 16: Polymer Matrix Composites

Functions of MatrixHolds the fibres together.

Protects the fibres from environment.

Distributes the loads evenly between fibres so that all fibres are subjected to the same amount of strain.

Enhances transverse properties of a laminate. Improves impact and fracture resistance of a component.

Helps to avoid propagation of crack growth through the fibres by providing alternate failure path along the interface between the fibres and the matrix.

Carry inter-laminar shear.

Page 17: Polymer Matrix Composites

Desired Properties of a MatrixReduced moisture absorption.

Low shrinkage.

Low coefficient of thermal expansion.

Good flow characteristics so that it penetrates the fibre bundles completely and eliminates voids during the compacting/curing process.

Must be elastic to transfer load to fibres.

Page 18: Polymer Matrix Composites

Reasonable strength, modulus and elongation (elongationshould be greater than fibre).

Strength at elevated temperature (depending on application).

Low temperature capability (depending on application).

Excellent chemical resistance (depending on application).

Should be easily processable into the final composite shape.

Dimensional stability (maintains its shape).

Page 19: Polymer Matrix Composites

Polymer Processing

Forming Processes for Thermosetting matrix composites:

Hand layup and sprayup techniques. Filament winding. Pultrusion. Resin transfer moulding. Autoclave moulding.

Forming Processes for Thermoplastic matrix composites:

Injection moulding. Film stacking. Diaphragm forming. Thermoplastic tape laying.

Page 20: Polymer Matrix Composites

Hand Layup• Hand layup process:

Gel coat is applied to open mold.

Fiberglass reinforcement is placed in the mold.

Base resin mixed with catalysts is applied by pouring and brushing.

Layup is made by building layer upon layer to obtain the desired thickness.

Page 21: Polymer Matrix Composites

Hand Layup

The most popular type of Open Molding is Hand Layup process. The Hand Layup is a manual, slow, labor consuming method, which involves the following operations:

The mold is coated by a release anti-adhesive agent, preventing sticking the molded part to the mold surface.

The prime surface layer of the part is formed by applying gel coating.

A layer of fine fiber reinforcing tissue is applied. Layers of the liquid matrix resin and reinforcing fibers

in form of woven fabric, rovings or chopped strands are applied. The resin mixture may be applied by either brush or roll.

The part is cured (usually at room temperature). The part is removed from the mold surface. The disadvantages of the Hand Layup method are: low

concentration of reinforcing phase (up to 30%) and low densification of the composites (entrapped air bubbles).

Page 22: Polymer Matrix Composites

Hand layup products:

Page 23: Polymer Matrix Composites

Hand layup products:

Page 24: Polymer Matrix Composites

In Sprayup process liquid resin matrix and chopped reinforcing fibers are sprayed by two separate sprays onto the mold surface. The fibers are chopped into fibers of 1-2” (25-50 mm) length and then sprayed by an air jet simultaneously with a resin spray at a predetermined ratio between the reinforcing and matrix phase. The Sprayup method permits rapid formation of uniform composite coating, however the mechanical properties of the material are moderate since the method is unable to use continuous reinforcing fibers.

Page 25: Polymer Matrix Composites

A spray gun supplying resin in two converging streams into which roving is chopped.

Automation with robots results in high rate of production.

Labor costs are lower.

Page 26: Polymer Matrix Composites

Sprayup process:

In Sprayup process, chopped fibers and resins are sprayed simultaneously into or onto the mold.

Applications are lightly loaded structural panels, e.g. caravan bodies, truck fairings, bathtubs, small boats, etc

Page 27: Polymer Matrix Composites

Hand and Spray Layup

In both the cases the deposited layers are densified with rollers.

Catalysts and Accelerators are used.

* Catalyst - substance added to the gel coat or resin to initiate the

curing process.

* Accelerator - A compound added to speed up the action of a

catalyst in a resin mix.

Curing at room temperature or at a moderately high temperature in an oven.

Page 28: Polymer Matrix Composites

Advantages of Hand Layup and Sprayup

Tooling cost is low.

Semiskilled workers are easily trained.

Design Flexibility.

Molded-in inserts and structural changes are possible.

Sandwich constructions are possible.

Large and Complex items can be produced.

Minimum equipment investment is necessary.

The startup lead time and the cost are minimal.

Page 29: Polymer Matrix Composites

Disadvantages of Hand Layup and Sprayup

Labor Intensive.

Low volume process.

Longer curing times.

Production uniformity is difficult.

Waste factor is high.

Page 30: Polymer Matrix Composites

Filament WindingFilament Winding method involves a continuous filament of reinforcing material wound onto a rotating mandrel in layers at different layers. If a liquid thermosetting resin is applied on the filament prior to winding the, process is called Wet Filament Winding. If the resin is sprayed onto the mandrel with wound filament, the process is called Dry Filament Winding. Besides conventional curing of molded parts at room temperature, Autoclave curing may be used.

30

Page 31: Polymer Matrix Composites

Filament Winding Filament Winding Process

For Round or Cylindrical parts A tape of resin impregnated fibers is

wrapped over a rotating mandrel to form a part.

These windings can be helical or hooped.

There are also processes that use dry fibres with resin application later, or prepregs are used.

Parts vary in size from 1" to 20’ Winding direction

Hoop/helical layers Layers of different material

High strengths are possible due to winding designs in various direction

Winding speeds are typically 100 m/min and typical winding tensions are 0.1 to 0.5 kg.

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Page 32: Polymer Matrix Composites

Filament Winding

Advantages Good for wide variety of part sizes Parts can be made with strength in several different directions Very low scrap rate Non-cyclindrical parts can be formed after winding Flexible mandrels can be left in as tank liners Reinforcement panels, and fittings can be inserted during winding Due to high hoop stress, parts with high pressure ratings can be made

Disadvantages Viscosity and pot life of resin must be carefully chosen NC programming can be difficult Some shapes can't be made with filament winding Factors such as filament tension must be controlled

 

Copyright Joseph Greene 2001 32

Page 33: Polymer Matrix Composites

Filament winding - applications

pressure vessels, storage tanks and pipes

rocket motors, launch tubes

Light Anti-armour Weapon (LAW)

Hunting Engineering made a nesting pair in 4 minutes

with ~20 mandrels circulated through the machine

and a continuous curing oven.

drive shafts

Entec “the world’s largest five-axis filament winding machine” for wind

turbine blades

length 45.7 m, diameter 8.2 m, weight > 36 tonnes.

Page 34: Polymer Matrix Composites

FILAMENT WINDING CHARACTERISTICS

۰The cost is about half that of tape laying

۰Productivity is high (50 kg/h).

۰Applications include: fabrication of composite pipes, tanks, and pressure vessels. Carbon fiber reinforced rocket motor cases used for

Space Shuttle and other rockets are made this way.

Page 35: Polymer Matrix Composites

Filament winding

Page 36: Polymer Matrix Composites

Filament winding - winding patterns hoop (90º) - girth or circumferential

winding angle is normally just below 90°

degrees each complete rotation of the

mandrel shifts the fibre band to lie alongside the previous band.

helical complete fibre coverage without

the band having to lie adjacent to that previously laid.

polar domed ends or spherical

components fibres constrained by bosses on

each pole of the component. axial (0º)

beware: difficult to maintain fibre tension

Page 37: Polymer Matrix Composites

Filament wound pressurebottles for gas storage

Page 38: Polymer Matrix Composites

PultrusionPultrusion is an automated, highly productive process of

fabrication of Polymer Matrix Composites in form of continuous long products of constant cross-section.

A scheme of the process is presented on the picture:

Page 39: Polymer Matrix Composites

PultrusionPultrusion process involves the following operations: Reinforcing fibers are pulled from the creels. Fiber (roving) creels

may be followed by rolled mat or fabric creels. Pulling action is controlled by the pulling system.

Guide plates collect the fibers into a bundle and direct it to the resin bath.

Fibers enter the resin bath where they are wetted and impregnated with liquid resin. Liquid resin contains thermosetting polymer, pigment, fillers, catalyst and other additives.

The wet fibers exit the bath and enter preformer where the excessive resin is squeezed out from fibers and the material is shaped.

The preformed fibers pass through the heated die where the final cross-section dimensions are determined and the resin curing occurs.

The cured product is cut on the desired length by the cut-off saw.

Page 40: Polymer Matrix Composites

Pultrusion Pultrusion process is characterized by the following features:

High productivity.

The process parameters are easily controllable.

Low manual labor component.

Precise cross-section dimensions of the products.

Good surface quality of the products.

Homogeneous distribution and high concentration of the reinforcing

fibers in the material is achieved (up to 80% of roving reinforcement, up

to 50% of mixed mat + roving reinforcement).

Pultrusion is used for fabrication of Fiber glass and Carbon fiber

reinforced polymer composites and Kevlar (aramid) fiber reinforced

polymers.

Page 41: Polymer Matrix Composites

PultrusionManufacturing

Fibers are brought together over rollers, dipped in resin and drawn through a heated die. A continuous cross section composite part emerges on the other side.

Page 42: Polymer Matrix Composites

production of constant cross-section profiles

Page 43: Polymer Matrix Composites
Page 44: Polymer Matrix Composites

Pultrusion

44

• Design· Hollow parts can be made using a mandrel that extends out the exit

side of the die.

· Variable cross section parts are possible using dies with sliding parts.

· Two main types of dies are used, fixed and floating. Fixed dies can generate large forces to wet fiber. Floating dies require an external power source to create the hydraulic forces in the resin. Multiple dies are used when curing is to be done by the heated dies.

 

Page 45: Polymer Matrix Composites

· Very low scrap. Up to 95% utilization of materials (75% for layup).

· Rollers are used to ensure proper resin impregnation of the fiber.

· Material forms can also be used at the inlet to the die when materials such

as mats, weaves, or stitched material is used.

· For curing, tunnel ovens can be used. After the part is formed and gelled

in the die, it emerges, enters a tunnel oven where curing is completed.

· Another method is, the process runs intermittently with sections emerging

from the die, and the pull is stopped, split dies are brought up to the

sections to cure it, they then retract, and the pull continues. (Typical

lengths for curing are 6" to 24")

Page 46: Polymer Matrix Composites

Materials Most fibers are used (carbon, glass, aramids) and Resins must be fast curing

because of process speeds. (polyester and epoxy) Processing

speeds are 0.6 to 1 m/min; thickness are 1 to 76 mm; diameters are 3 mm to 150mm

double clamps, or belts/chains can be used to pull the part through. The best designs allow for continuous operation for production.

diamond or carbide saws are used to cut sections of the final part. The saw is designed to track the part as it moves.

these parts have good axial properties. Advantages

good material usage compared to layup high throughput and higher resin contents are possible

Disadvantages part cross section should be uniform. Fiber and resin might accumulate at the die opening, leading to increased friction

causing jamming, and breakage. when excess resin is used, part strength will decrease void can result if the die does not conform well to the fibers being pulled quick curing systems decrease strength

 

Copyright Joseph Greene 2001 46

Page 47: Polymer Matrix Composites

Pultrusion

Advantages:

Minimal kinking of

fibres/fabrics

Rapid processing

Low material scrap rate

Good quality control

Potential Problems:

Improper fibre wet-out

Fibre breakage

Inadequate cure

Die jamming

Complex die design

Page 48: Polymer Matrix Composites

Pultrusion -characteristics

seek uniform thickness in order to achieve uniform cooling and hence minimise residual stress.

hollow profiles require a cantilevered mandrel to enter the die from the fibre-feed end.

continuous constant cross-section profile normally thermoset (thermoplastic possible)

impregnate with resin pull through a heated die

resin shrinkage reduces friction in the die polyester easier to process than epoxy

tension control as in filament winding post-die, profile air-cooled before gripped

hand-over-hand hydraulic clamps conveyor belt/caterpillar track systems.

moving cut-off machine ("flying cutter"). The solid laminate will be cut to the desired length

Inside the metal die, precise temperature control activates the curing of the thermoset resin.

Page 49: Polymer Matrix Composites

Shapes such as rods, channels, angle and flat stocks can be easily

produced.

Production rate is 10 to 200 cm/min.

Profiles as wide as 1.25 m with more than 60% fiber volume fraction

can be made routinely.

No bends or tapers allowed (continuous molding cycle)

Page 50: Polymer Matrix Composites

Pultrusion -applications

panels – beams – gratings – ladders tool handles - ski poles – kiteselectrical insulators and enclosures light poles - hand rails – roll-up doors450 km of cable trays in the Channel Tunnel

Page 51: Polymer Matrix Composites

Pultrusion Applications

Advanced Composite Construction Systemcomponents: plank ............... and connectors

used in Aberfeldy and Bonds Mill Lock bridges

http://

Page 52: Polymer Matrix Composites

Resin Transfer Molding

In the RTM process, dry (i.e. non-impregnated ) reinforcement is pre-shaped and oriented into skeleton of the actual part known as the preform which is inserted into a matched die mold.

The heated mold is closed and the liquid resin is injectedThe part is cured in mold.The mold is opened and part is removed from mold.

Page 53: Polymer Matrix Composites

Resin Transfer Moulding

Close mold low pressure process.

A dry preform is placed in a matched metal die.

A vaccum pulls the Low – viscosity resin through a flow medium that helps impregnate the preform.

Resin may also be forced by means of a pump.

Page 54: Polymer Matrix Composites

Resin Transfer Moulding

Page 55: Polymer Matrix Composites

RTMTransfer Molding (Resin Transfer Molding) is a Closed Mold

process in which a pre-weighed amount of a polymer is preheated in a separate chamber (transfer pot) and then forced into a preheated mold filled with a reinforcing fibers, taking a shape of the mold cavity, impregnating the fibers and performing curing due to heat and pressure applied to the material.

The picture below illustrates the Transfer Molding Process. The method uses a split mold and a third plate equipped with a plunger

mounted in a hydraulic press. The method combines features of both Compression Molding -

hydraulic pressing, the same molding materials (thermosets) and Injection Molding – ram (plunger), filling the mold through a sprue.

Transfer Molding cycle time is shorter than Compression Molding cycle but longer than Injection Molding cycle.

The method is capable to produce very large parts (car body shell), more complicated than Compression Molding, but not as complicated as Injection Molding.

Page 56: Polymer Matrix Composites

RTMTransfer Molding process involves the following steps:

The mold cavity is filled with preformed reinforcing fibers.

A pre-weighed amount of a polymer mixed with additives and fillers (charge) is placed into the transfer pot.

The charge may be in form of powders, pellets, putty-like masses or pre-formed blanks.

The charge is heated in the pot where the polymer softens.

The plunger, mounted on the top plate, moves downwards, pressing on the polymer charge and forcing it to fill the mold cavity through the sprue and impregnate the fibers.

The mold, equipped with a heating system, provides curing (cross-linking) of the polymer (if thermoset is processed).

The mold is opened and the part is removed from it by means of the ejector pin.

If thermosetting resin is molded, the mold may be open in hot state – cured thermosets maintain their shape and dimensions even in hot state.

If thermoplastic is molded, the mold and the molded part are cooled down before opening.

The scrap left on the pot bottom (cull), in the sprue and in the channels is removed. Scrap of thermosetting polymers is not recyclable.

Page 57: Polymer Matrix Composites

Resin Transfer Moulding

Advantages:

Low skill labour required

Low tooling cost

Low volatile emission

Required design tailorability

Potential Problems:

Control of resin flow

Kinking of fibres

Criticality in mould design

Page 58: Polymer Matrix Composites

RTM Products:

Page 59: Polymer Matrix Composites

Autoclave moulding Autoclave Curing is a method in which a part, molded by one of the

open molding methods, is cured by a subsequent application of

vacuum, heat and inert gas pressure.

The molded part is first placed into a plastic bag, from which air is

exhausted by a vacuum pump. This operation removes air inclusions

and volatile products from the molded part.

Then heat and inert gas pressure are applied in the autoclave

causing curing and densification of the material.

Autoclave Curing enables fabrication of consistent homogeneous

materials. The method is relatively expensive and is used for

manufacturing high quality aerospace products.

Page 60: Polymer Matrix Composites

Autoclave mouldingAn autoclave is a closed vessel (round or cylindrical) in which

processes occur under simultaneous application of high temperature and pressure.

Page 61: Polymer Matrix Composites

AutoclaveAn oven that allows for high pressures to be used.Composites cure under heat and pressure provides a superior part because

the voids are reduced due to the pressure.Process

The part is placed in the pressure vessel, and heated, pressure is applied simultaneously.

Vacuum bagging can be used in an autoclave.Thermoset composites are crosslinked.Thermoplastics are melted.

AdvantagesThe pressure helps bond composite layers, and remove more voids in the

matrix.Very large parts can be made with high fiber loadings.Properties are improved.Many different parts can be cured at the same time.

DisadvantagesAutoclaves are expensive

Copyright Joseph Greene 2001 61

Page 62: Polymer Matrix Composites

a) Autoclave process to make a laminated compositeb) Prepregs of different orientations stacked to form a laminated composite

a)

b)

Higher fiber volume fractions (60 – 65%) can be obtained

Page 63: Polymer Matrix Composites

Autoclave process- Charcteristics

Very high quality product

Generally prepregs are used

Chopped fibres with resin can also be used

Hybrid composites can be produced

High fibre volume fractions can be obtained

simultaneous application of high temperature and pressure helps in,

* Consolidating the laminate.

* Removing the entrapped air.

* Curing the polymeric matrix.

Page 64: Polymer Matrix Composites

Autoclave Moluding

Page 65: Polymer Matrix Composites

Injection moulding Injection Molding is a Closed Mold process in which molten

polymer (commonly thermoplastic) mixed with very short reinforcing fibers (10-40%) is forced under high pressure into a mold cavity through an opening (sprue).

Polymer-fiber mixture in form of pellets is fed into an Injection Molding machine through a hopper. The material is then conveyed forward by a feeding screw and forced into a split mold, filling its cavity through a feeding system with sprue gate and runners.

Screw of injection molding machine is called reciprocating screw since it not only rotates but also moves forward and backward according to the steps of the molding cycle.

It acts as a ram in the filling step when the molten polymer-fibers mixture is injected into the mold and then it retracts backward in the molding step.

Heating elements, placed over the barrel, soften and melt the polymer.

The mold is equipped with a cooling system providing controlled cooling and solidification of the material.

Page 66: Polymer Matrix Composites

Injection moulding

The polymer is held in the mold until solidification and then the mold opens and the part is removed from the mold by ejector pins.

Injection Molding is used mainly for thermoplastic matrices, but thermosetting matrices are also may be extruded. In this case curing (cross-linking) occurs during heating and melting of the material in the heated barrel.

A principal scheme of an Injection Molding Machine is shown in the picture below.

Injection Molding is highly productive method providing high accuracy and control of shape of the manufactured parts. The method is profitable in mass production of large number of identical parts.

One of the disadvantages of the method is limited length of fibers decreasing their reinforcing effect.

Page 67: Polymer Matrix Composites

Injection moulding

Page 68: Polymer Matrix Composites

Injection moulding machine

The injection molding machine comprises of:

The plasticating and injection unit: The major tasks of the

plasticating unit are to melt the polymer, to accumulate the melt in

the screw chamber, to inject the melt into the cavity and to maintain

the holding pressure during cooling.

The clamping unit: It’s role is to open and close the mold, and hold

the mold tightly to avoid flash during the filling and holding.

Clamping can be mechanical or hydraulic.

The mold cavity: The mold is the central point in an injection

molding machine. Each mold can contain multiple cavities. It

distributes polymer melt into and throughout the cavities, shapes the

part, cools the melt and ejects the finished product.

Page 69: Polymer Matrix Composites

The Injection MoldThe mold consists Sprue and runner

systemGateMold cavityCooling system

(for thermoplastics)Ejector system

Features of injection molding

Direct path from molding compound to finished productProcess can be fully automatedHigh productivity & quality

Page 70: Polymer Matrix Composites

Injection molding machine

Page 71: Polymer Matrix Composites

Injection Molding Machine

Page 72: Polymer Matrix Composites

INJECTION MOLDING

Thermoplastics : Polystyrene,PE, PP, ABC, PC,PMMA etc

Page 73: Polymer Matrix Composites

Injection Molding CycleInjection molding involves two basic steps:

Melt generation by a rotating screwForward movement of the screw to fill the mold with melt and to

maintain the injected melt under high pressure

Injection molding is a “cyclic” process:

Injection: The polymer is injected into the mold cavity.

Hold on time: Once the cavity is filled, a holding pressure is maintained to compensate for material shrinkage.

Cooling: The molding cools and solidifies.

Screw-back: At the same time, the screw retracts and turns, feeding the next shot in towards the front

Injection molding is the most important process used to manufacture plastic products. It is ideally suited to manufacture mass produced parts of complex shapes requiring precise dimensions.

It is used for numerous products, ranging from boat hulls and lawn chairs, to bottle cups. Car parts, TV and computer housings are injection molded.

Page 74: Polymer Matrix Composites

Thermosets : Unsaturated polyester resin, Phenol formaldehyde etc

Page 75: Polymer Matrix Composites

Reaction injection moulding

Reaction injection

moulding (RIM) - Two

reactive ingredients are

pumped at high speeds and

pressures into a mixing

head and injected into a

mold cavity where curing

and solidification occur due

to chemical reaction.

Page 76: Polymer Matrix Composites

Reinforced reaction injection molding

Reinforced reaction injection moulding (RRIM) - similar to RIM but

includes reinforcing fibers, typically glass fibers, in the mixture .

Advantages: similar to RIM (e.g., no heat energy required, lower cost

mold), with the added benefit of fiber reinforcement.

Products: auto body, truck cab applications for bumpers, fenders,

and other body parts

Page 77: Polymer Matrix Composites

Film stacking

Stack of laminate consists of fibers, impregnated with insufficient

thermoplastic matrix, and polymer films of complementary weight to

give the desired fiber volume fraction in the end product. These are

then consolidated by simultaneous application of heat and pressure.

Generally, a pressure of 6-12 MPa, a temperature between 275 and

350º C, and dwell times of up to 30 mins are appropriate for

thermoplastics such as polysulfones and polyetheretherketone

(PEEK).

Page 78: Polymer Matrix Composites

DIAPHRAGM FORMING This process involves the sandwiching of freely floating thermoplastic

prepreg layers between two diaphragms .

The air between the diaphragms is evacuated and thermoplastic laminate is

heated above the melting point of the matrix.

Page 79: Polymer Matrix Composites

DIAPHRAGM FORMING

Pressure is applied to one side, which deforms the diaphragm and makes

them take the shape of the mold.

The laminate layers are freely floating and very flexible above the melting

point of the matrix, thus they readily conform to the mold shape.

Page 80: Polymer Matrix Composites

DIAPHRAGM FORMINGAfter the completion of the forming process, the mold is cooled, the

diaphragms are stripped off, and the composite is obtained.

The diaphragms are the key to the forming process, and their

stiffness is a very critical parameter.

For very complex shapes requiring high molding pressures, stiff

diaphragm are needed. At high pressures, a significant transverse

squeezing flow can result, and this can produce undesirable

thickness variations in the final composite.

Page 81: Polymer Matrix Composites

DIAPHRAGM FORMING

ADVANTAGES:

Components with double curvatures can be formed.

Compliant diaphragm do the job for simple components.

Page 82: Polymer Matrix Composites

Thermoplastic tape laying (Automated Layup)

In this method layers of prepreg (reinforcing phase impregnated by

liquid resin) tape are applied on the mold surface by a tape

application robot.

Cost is about half of hand lay-up.

used for thermoset or thermoplastic matrix.

limited to flat or low curvature surfaces.

Extensively used for products such as airframe components, bodies

of boats, truck ,tanks, swimming pools and ducts.

Page 83: Polymer Matrix Composites

Automated tape‑laying machine (photo courtesy of Cincinnati Milacron).

Automated tape‑laying machines operate by dispensing a prepreg tape onto an

open mold following a programmed path .

Typical machine consists of overhead gantry to which the dispensing head is

attached

The gantry permits x‑y‑z travel of the head, for positioning and following a defined

continuous path.

Page 84: Polymer Matrix Composites

APPLICATIONS OF PMCs

Polymer composites are used to make very light bicycles that are faster and easier to handle than standard ones, fishing boats that are resistant to corrosive seawater and lightweight turbine blades that generate wind power efficiently. New commercial aircraft also contain more composites than their predecessors. A 555-passenger plane recently built by Airbus, for example, consists of 25 percent composite material, while Boeing is designing a new jumbo aircraft that is planned to be more than half polymer composites.

Polymer Matrix Composites (PMCs) are used for manufacturing: secondary load-bearing aerospace structures, boat bodies, canoes, kayaks, automotive parts, radio controlled vehicles, sport goods (golf clubs, skis, tennis racquets), fishing rods, bullet-proof vests and other armor parts, brake and clutch linings.