place your title here - electrochem

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ADVANCED MULTILEVEL INTERCONNECTS TECHNOLOGIES FOR 40- nm Lg DEVICES Takayuki Ohba Process Development Department Advanced LSI Manufacturing Group FUJITSU LIMITED [email protected] Abstract 10 level Cu interconnects have been developed for 90 nm high speed processing logic devices operating in the above 3 GHz band. The fully integrated Cu Damascene process provides a high enough capability for production and it is shown that the use of Cu/SiLK TM (k = 2.65) and Cu/SiOC (k = 3.1, CORAL TM ) in Cu/VLK satisfies the requirements of RC design and reliability. Wiring capacity is below 190 fF/mm at the minimum feature size of 280 nm line and space in Cu/SiLK TM interconnects which yields the lowest effective k-value (k eff ) of 3.0. An adequate reliability in terms of Electro-Migration (EM), Stress Migration (SM), and packaging resistance has been demonstrated. This paper described production-worthy Cu/VLK multi-level interconnects for 90 nm interconnect technology. A roadmap towards 65 nm and beyond will be presented. 90 nm Cu Damascene Process and Features Cu Damascene interconnect is formed on ultra-high-density 6T SRAM with a minimum cell size below 1 μm 2 and 40 nm gate length, with 960 μA/μm and 300 μA/μm of an NMOS on-current and off-current at 1V, respectively [1]. In this transistor, a 320 psec access time (1.7 times faster than 130 nm technology) at above 3GHz has been achieved for a 144-kb SRAM macro [2]. The 10 interconnect levels are integrated using a Dual-damascene (DD) process as shown in Figure 1. A lot of expertise has been accumulated for Cu Damascene technology since the 180 nm process at Fujitsu [3]-[8]. Different dielectric materials are used at different levels in the structure, i.e. levels M1-M4 (280 nm pitch) use SiLK TM , M5-M8 (560 nm pitch) use Silicon-Oxy-Carbide (SiOC, CORAL TM ), and M9-M10 (840 nm pitch) use SiO 2 . ArF lithography with an Optical Proximity Correction (OPC) technique is used for patterning of minimum features. Electrochemical Cu Deposition (ECD) is performed on a sputtered Cu/Ta bilayer, with the Cu and Ta being used as a seed layer and Cu diffusion barrier, respectively. A continuous Ta layer of the order of 8 nm in thickness is used at the sidewall of via-holes to prevent agglomeration of seed Cu and void-formation in the ECD-Cu. Since the presence of micro-voids with typical sizes below 5 nm due to plating chemistry, and random grains degrade the reliability of the Cu interconnect, an optimized ECD-Cu process involving control of the additive concentration and plating rate, and annealing (<200°C) to recrystallize the metallurgically meta-stable film is used Electrical Characteristics and Reliability Wiring capacitance below 190 fF/mm is low enough for the requirements of RC delay design and lower than that of 130 nm technology using SiLK TM /SiO 2 hybrid structure. This is because SiC (k = 4.5) is used instead of SiN (k = 7) as a cap layer of hybrid structure, and SiLK TM is used between the vias without SiO 2 . As a result, the lowest k eff of 3.0 at a narrow line and space has been achieved. Figure 2 shows life time due to Electro-Migration (EM) failure compared to 130 nm technology for a stress condition of 250°C and 2.5 MA/cm 2 . Similar reliabilities are seen even for different dielectric structures (SiLK TM /SiO 2 hybrid vs. SiLK TM ) and smaller feature size. Figures 3 shows the resistance change of via-chains for Cu/SiLK TM . Samples are thermally stressed at 200°C for 504 hours and Stress Migration (SM) failure is evaluated. No significant resistance changes are observed for Cu lines ranging in width from 0.14 μm to 3 μm. For packaging reliability, even in case of the smallest feature size in the Cu/SiLK TM multi-level interconnects, a 100% yield is obtained after 1000 thermal stress cycles from –65°C to 150°C. Accordingly, these Cu technologies promise production-worthy reliability from wafer process to packaging and can be used for the highest performance microprocessors in 90 nm node. Acknowledgements The author would like to thank all the staff members of the 90 nm development program in Fujitsu and Fujitsu Laboratories who participated in BEOL and packaging (JISSO) technologies. References [1] S. Nakai, et al., Symp. VLSI Technol., 66 (2002); IEICE Tech. Rep., 102 (272), 83(2002) in Japanese. [2] H. Akiyoshi, et al., ISSCC Dig. Tech. Papers 2003, to be presented. [3] S. Sugatani, et al, Proc. Dry Process Intl. Symp., 255 (2002). [4] M. Ikeda, et al., Proc. IEEE Intl. Interconnect Technol. Conf. (IITC), 131 (1998); Materials Transactions, The Japan Inst. of Metals, 43 (7), 1577 (2002). [5] H. Kudo, et al., Proc. IEEE Intl. Interconnect Technol. Conf. (IITC), 270 (2000). [6] T. Ohba, J. Electronic Materials, 29 (10), 314 (2000); Proc. of IEEE 6 th Intl. Conf. on Solid-State Integrated Circuit Technol. (ICSICT), ed. Bing-Zong Li et al., 46 (2001). [7] Y. Takao, et al., in Ref. 1, 122 (2002); Microelectronics Reliability, 42, 15 (2002). [8] T. Ohba, Fujitsu Sci. Tech. J., 38, 13 (2002). M10 SiO 2 M9 M8 SiOC (CORAL TM ) M7 M6 M5 M4 90nm Node Cu Damascene Interconnetcs M3 SiLK TM M2 M1 Fig. 1. 3D view of the 10 level Cu Damascene interconnects. 1 .01 .1 1 7080 9095 99 99.999.99 Cumulative Failure (%) 1000 10 4 10 5 10 6 10 7 .01 .1 1 5 10 20 30 50 70 80 90 95 99 99.9 99.99 10 100 Cu 130 nm Via = 0.22µm SiLK TM /SiO 2 Cu 90nm Via = 0.14µm SiLK TM Fig. 2. A comparison of life time due to EM failure. Blue: as-prepared Red: after stressed at 200C for 504hrs Cu/SiLK TM 0.14µm Via Hole 4M Vias Line/Space =0.14µm/0.7µm (%) 1 3µm/0.8µm µm/0.28µm Fig. 3. The resistance change due to stress migration (SM). Chain Resistance (ohm)

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Page 1: Place your title here - Electrochem

ADVANCED MULTILEVEL INTERCONNECTS TECHNOLOGIES FOR 40- nm Lg DEVICES

Takayuki Ohba

Process Development Department Advanced LSI Manufacturing Group

FUJITSU LIMITED [email protected]

Abstract

10 level Cu interconnects have been developed for 90 nm high speed processing logic devices operating in the above 3 GHz band. The fully integrated Cu Damascene process provides a high enough capability for production and it is shown that the use of Cu/SiLKTM (k = 2.65) and Cu/SiOC (k = 3.1, CORALTM) in Cu/VLK satisfies the requirements of RC design and reliability. Wiring capacity is below 190 fF/mm at the minimum feature size of 280 nm line and space in Cu/SiLKTM interconnects which yields the lowest effective k-value (keff) of 3.0. An adequate reliability in terms of Electro-Migration (EM), Stress Migration (SM), and packaging resistance has been demonstrated.

This paper described production-worthy Cu/VLK multi-level interconnects for 90 nm interconnect technology. A roadmap towards 65 nm and beyond will be presented.

90 nm Cu Damascene Process and Features Cu Damascene interconnect is formed on

ultra-high-density 6T SRAM with a minimum cell size below 1 µm2 and 40 nm gate length, with 960 µA/µm and 300 µA/µm of an NMOS on-current and off-current at 1V, respectively [1]. In this transistor, a 320 psec access time (1.7 times faster than 130 nm technology) at above 3GHz has been achieved for a 144-kb SRAM macro [2].

The 10 interconnect levels are integrated using a Dual-damascene (DD) process as shown in Figure 1. A lot of expertise has been accumulated for Cu Damascene technology since the 180 nm process at Fujitsu [3]-[8]. Different dielectric materials are used at different levels in the structure, i.e. levels M1-M4 (280 nm pitch) use SiLKTM, M5-M8 (560 nm pitch) use Silicon-Oxy-Carbide (SiOC, CORALTM), and M9-M10 (840 nm pitch) use SiO2. ArF lithography with an Optical Proximity Correction (OPC) technique is used for patterning of minimum features.

Electrochemical Cu Deposition (ECD) is performed on a sputtered Cu/Ta bilayer, with the Cu and Ta being used as a seed layer and Cu diffusion barrier, respectively. A continuous Ta layer of the order of 8 nm in thickness is used at the sidewall of via-holes to prevent agglomeration of seed Cu and void-formation in the ECD-Cu. Since the presence of micro-voids with typical sizes below 5 nm due to plating chemistry, and random grains degrade the reliability of the Cu interconnect, an optimized ECD-Cu process involving control of the additive concentration and plating rate, and annealing (<200°C) to recrystallize the metallurgically meta-stable film is used

Electrical Characteristics and Reliability Wiring capacitance below 190 fF/mm is low enough

for the requirements of RC delay design and lower than that of 130 nm technology using SiLKTM/SiO2 hybrid structure. This is because SiC (k = 4.5) is used instead of SiN (k = 7) as a cap layer of hybrid structure, and SiLKTM is used between the vias without SiO2. As a result, the lowest keff of 3.0 at a narrow line and space has been achieved.

Figure 2 shows life time due to Electro-Migration (EM) failure compared to 130 nm technology for a stress condition of 250°C and 2.5 MA/cm2. Similar reliabilities are seen even for different dielectric structures (SiLKTM/SiO2 hybrid vs. SiLKTM) and smaller feature size. Figures 3 shows the resistance change of via-chains for Cu/SiLKTM. Samples are thermally stressed at 200°C for 504 hours and Stress Migration (SM) failure is evaluated. No significant resistance changes are observed for Cu lines ranging in width from 0.14 µm to 3 µm.

For packaging reliability, even in case of the smallest feature size in the Cu/SiLKTM multi-level interconnects, a 100% yield is obtained after 1000 thermal stress cycles from –65°C to 150°C. Accordingly, these Cu technologies promise production-worthy reliability from wafer process to packaging and can be used for the highest performance microprocessors in 90 nm node.

Acknowledgements The author would like to thank all the staff members

of the 90 nm development program in Fujitsu and Fujitsu Laboratories who participated in BEOL and packaging (JISSO) technologies.

References [1] S. Nakai, et al., Symp. VLSI Technol., 66 (2002); IEICE Tech. Rep.,

102 (272), 83(2002) in Japanese. [2] H. Akiyoshi, et al., ISSCC Dig. Tech. Papers 2003, to be presented. [3] S. Sugatani, et al, Proc. Dry Process Intl. Symp., 255 (2002). [4] M. Ikeda, et al., Proc. IEEE Intl. Interconnect Technol. Conf. (IITC),

131 (1998); Materials Transactions, The Japan Inst. of Metals, 43 (7), 1577 (2002).

[5] H. Kudo, et al., Proc. IEEE Intl. Interconnect Technol. Conf. (IITC), 270 (2000).

[6] T. Ohba, J. Electronic Materials, 29 (10), 314 (2000); Proc. of IEEE 6th Intl. Conf. on Solid-State Integrated Circuit Technol. (ICSICT), ed. Bing-Zong Li et al., 46 (2001).

[7] Y. Takao, et al., in Ref. 1, 122 (2002); Microelectronics Reliability, 42, 15 (2002).

[8] T. Ohba, Fujitsu Sci. Tech. J., 38, 13 (2002).

M10SiO2

M9M8

SiOC (CORALTM)

M7M6M5

M490nm Node Cu DamasceneInterconnetcs

M3SiLKTM M2M1

Fig. 1. 3D view of the 10 level Cu Damascene interconnects.

1.01 .1 1 5 10 2030 50 70 80 90 9 5 99 99 .99 9.99

Cu m u la tiv e Fa ilu re (% )

1000 104 105 106 107.01.1

15

102030507080909599

99.999.99

10

100

Cu130 nm

Via = 0.22µmSiLKTM/SiO2

Cu90nm

Via = 0.14µmSiLKTM

Fig. 2. A comparison of life time due to EM failure.

Blue: as-prepared Red: after stressed at 200C for 504hrs

Cu/SiLKTM 0.14µm Via Hole4M Vias

Line/Space =0.14µm/0.7µm

((%%))

13µm/0.8µm µm/0.28µm

Fig. 3. The resistance change due to stress migration (SM). Chain Resistance (ohm)