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Pharmaceuticals and Personal Care Products in the Environment Rebecca Harvey Squam Lakes Association

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Page 1: Pharmaceuticals and Personal Care Products in the Environment€¦ · Personal Care Products in the Environment Rebecca Harvey Squam Lakes Association. Outline • Intro to PPCPs

Pharmaceuticals andPersonal Care Products in the 

Environment

Rebecca HarveySquam Lakes Association

Page 2: Pharmaceuticals and Personal Care Products in the Environment€¦ · Personal Care Products in the Environment Rebecca Harvey Squam Lakes Association. Outline • Intro to PPCPs

Outline• Intro to PPCPs

– Definitions

– Occurrence and Fate

– Effects

– Regulations

• PPCPs in NH– Adapting a Method

– Pilot Study

– Limiting the Impact

Page 3: Pharmaceuticals and Personal Care Products in the Environment€¦ · Personal Care Products in the Environment Rebecca Harvey Squam Lakes Association. Outline • Intro to PPCPs

What Are They?

• Pharmaceuticals and Personal Care Products (PPCPs)

Perfumes

Page 4: Pharmaceuticals and Personal Care Products in the Environment€¦ · Personal Care Products in the Environment Rebecca Harvey Squam Lakes Association. Outline • Intro to PPCPs

Occurrence and Fate

Page 5: Pharmaceuticals and Personal Care Products in the Environment€¦ · Personal Care Products in the Environment Rebecca Harvey Squam Lakes Association. Outline • Intro to PPCPs

Wastewater Treatment Facilities

Environment Drinking Water

pg/L 

ng/L (ppt) 

μg/L (ppb) 

mg/L

PPCP

 Con

centratio

n

g/L

Occurrence and Fate

Acute toxicity range

Chronic  toxicity range

Page 6: Pharmaceuticals and Personal Care Products in the Environment€¦ · Personal Care Products in the Environment Rebecca Harvey Squam Lakes Association. Outline • Intro to PPCPs

Environmental Effects

• Antibiotic resistance in bacteria and viruses

Page 7: Pharmaceuticals and Personal Care Products in the Environment€¦ · Personal Care Products in the Environment Rebecca Harvey Squam Lakes Association. Outline • Intro to PPCPs

Environmental Effects

• Feminization/abnormalities of frogs and fish 

• Bird and fish population decline/collapse

Page 8: Pharmaceuticals and Personal Care Products in the Environment€¦ · Personal Care Products in the Environment Rebecca Harvey Squam Lakes Association. Outline • Intro to PPCPs

PPCPs in New Hampshire

• Establishing an analytical method in‐state

• Determining preliminary occurrence data

Page 9: Pharmaceuticals and Personal Care Products in the Environment€¦ · Personal Care Products in the Environment Rebecca Harvey Squam Lakes Association. Outline • Intro to PPCPs

PPCPs in New Hampshire

• Establishing an analytical method in‐state– Partnership with NH DES

– Adapted USGS Method using • Solid Phase Extraction • High Performance Liquid Chromatography • Mass Spectrometry 

– Target Compounds  • Acetaminophen • Caffeine  • Carbamazepine• Trimethoprim

Page 10: Pharmaceuticals and Personal Care Products in the Environment€¦ · Personal Care Products in the Environment Rebecca Harvey Squam Lakes Association. Outline • Intro to PPCPs

PPCPs in New Hampshire

• Determining preliminary occurrence data

Page 11: Pharmaceuticals and Personal Care Products in the Environment€¦ · Personal Care Products in the Environment Rebecca Harvey Squam Lakes Association. Outline • Intro to PPCPs

PPCPs in New Hampshire

• Squam Lake NH– 6 samples collected 

– October 2009

Page 12: Pharmaceuticals and Personal Care Products in the Environment€¦ · Personal Care Products in the Environment Rebecca Harvey Squam Lakes Association. Outline • Intro to PPCPs

PPCPs in New Hampshire

• Distribution Box

c

From Holding Tank

To Leach Field 

Page 13: Pharmaceuticals and Personal Care Products in the Environment€¦ · Personal Care Products in the Environment Rebecca Harvey Squam Lakes Association. Outline • Intro to PPCPs

PPCPs in New Hampshire

• Pemigewasset

• Winnipesaukee

• Merrimack

• Wastewater Treatment Plants

• 9 samples collected

• October, 2009

Page 14: Pharmaceuticals and Personal Care Products in the Environment€¦ · Personal Care Products in the Environment Rebecca Harvey Squam Lakes Association. Outline • Intro to PPCPs

PPCPs in New Hampshire

• None of the targetPPCPs found

Page 15: Pharmaceuticals and Personal Care Products in the Environment€¦ · Personal Care Products in the Environment Rebecca Harvey Squam Lakes Association. Outline • Intro to PPCPs

PPCPs in New Hampshire

Acetaminophen(ng/L)

Caffeine(ng/L)

Carbamazepine(ng/L)

Trimethoprim(ng/L)

Distribution Box >2,000 >2,000

c

From Holding Tank

To Leach Field 

Page 16: Pharmaceuticals and Personal Care Products in the Environment€¦ · Personal Care Products in the Environment Rebecca Harvey Squam Lakes Association. Outline • Intro to PPCPs

PPCPs in New Hampshire

Acetaminophen(ng/L)

Caffeine(ng/L)

Carbamazepine(ng/L)

Trimethoprim(ng/L)

Pemi WTP Effluent

720 1200 280

Pemi River 79

Merrimack WTP 

Effluent330

Page 17: Pharmaceuticals and Personal Care Products in the Environment€¦ · Personal Care Products in the Environment Rebecca Harvey Squam Lakes Association. Outline • Intro to PPCPs

WTP Effluent

Aquatic Environment

Drinking Water

pg/L

ng/L (ppt) 

μg/L (ppm) 

mg/L

PPCP

 Con

centratio

n

g/L

PPCPs in New Hampshire

Acute toxicity range

Chronic  toxicity range

Page 18: Pharmaceuticals and Personal Care Products in the Environment€¦ · Personal Care Products in the Environment Rebecca Harvey Squam Lakes Association. Outline • Intro to PPCPs

Conclusions

• Appears to be no risk of acute toxicity to target PPCPs in sampled lakes and rivers

• Chronic toxicity cannot be ruled out

• Other PPCPs or their metabolites may be present

Page 19: Pharmaceuticals and Personal Care Products in the Environment€¦ · Personal Care Products in the Environment Rebecca Harvey Squam Lakes Association. Outline • Intro to PPCPs

Limiting The Impact

Things You Can Do

• Don’t Rush to Flush!

• Fill prescriptions as needed

• Drug Take‐Back Programs

• Educate

Things We Can Do

• Optimize the effectiveness of prescriptions

• Sustainable farming/cattle practices

• Improve WTP technology

Page 20: Pharmaceuticals and Personal Care Products in the Environment€¦ · Personal Care Products in the Environment Rebecca Harvey Squam Lakes Association. Outline • Intro to PPCPs

Thank You!

• NH Water Resources Research Center, UNH

• Squam Lakes Conservation Society

• Squam Lakes Association

• Plymouth State University

• NH Department of Environmental Services

• Field Volunteers 

• Committee and Advisor 

Page 21: Pharmaceuticals and Personal Care Products in the Environment€¦ · Personal Care Products in the Environment Rebecca Harvey Squam Lakes Association. Outline • Intro to PPCPs

Questions ?