petnology 2010 holland colours final
DESCRIPTION
TRANSCRIPT
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
Functional colourants; adding value to the PET supply chain
Hans Werink Project Manager Packaging
Holland Colours
PETnology 2010 - Nuremberg - 9 November 2010
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
Outline
� Holland Colours Company Profile & Markets Served
� Functional additives� UV-barrier
� Visible light barrier
� Combinations with oxygen barrier resins & additives
� Lightweighting & Opacity
� Recycling
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
Holland Colours Profile
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
Holland Colours Profile
� Founded in 1979� Around 450 employees� Listed at Euronext, 48% employee
owned� 6 Plants, 6 Sales Offices� 2000 Customers in 70 Countries
Focus markets:� Building and Construction� Silicones/Elastomers� PET Packaging
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
Holland Colours Product Formats for PET
� Non-polymeric solids – Holcobatch & Holcoprill
� Liquids - HolcoPET� High opacity masterbatch - Holcomer
to benefit from
� Optimized processability� Economy of colouring� Optimal productivity
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
� Unique product technology, based on non-polymer carrier systems
� Each product is custom formulated
� Small to large batch capability, multiple formats available
� Uniform global production� Extensive knowledge from raw material to end product
Holland Colours Product Formats for PET
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
Our Strategic Partners
� PET converters
� Key influencers
� Producers of preforms,
bottles, sheet, rod & film
� PET resin producers
� Recycling industry
� Brand owners
� Machine manufacturers
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
Protection of PET-packed products against UV radiation,
visible light & oxygen
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
UV-protection specification forliquid detergents
�<1% @ 370 nm�50% @ 400 nm�>85% @ 420 nm
Light Sensitivity of Liquid Detergents
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
Protective UV-absorbers
0
10
20
30
40
50
60
70
80
90
100
320 370 420 470 520 570 620 670
Wavelength (nm)
Tran
smission
(%)
PET natural
0,3% standard Benzotriazole UV Absorber @ 0,3 mm
0,3% Holland Colours Broad Spectrum UV-absorber @ 0.3 mm
370 nm: <1% transmission
420 nm: >85% transmission
400 nm: 50% transmission
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
Light sensitivity of NutrientsRiboflavin and Beta-carotene absorption spectra
0
0,05
0,1
0,15
0,2
0,25
0,3
0,35
0,4
0,45
0,5
300 350 400 450 500 550 600 650 700
Wavelength (nm)
Molar ex
tinction coefficient
Riboflavin
Beta-carotene
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
Protective Colourants – Transparent
0
10
20
30
40
50
60
70
80
90
100
320 370 420 470 520 570 620 670
Wavelength (nm)
Transm
ission (%T)
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
Protective Colourants – Opaque
0
10
20
30
40
50
60
70
80
90
100
300 350 400 450 500 550 600 650 700
Wavelength (nm)
Transm
ission (%)
Vanilla Yellow
Pistachio Green
Cappucino Light Brown
Strawberry Red
Chocolate Brown
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
Light protection of milkMilk typ e Heat t reatment Shelf life
Pas teurised
C old c ha in
d i s t r ibut i on
72 -75°C, 15-4 0 sec
b efo re filling
4 -7 d ays at <8 °C
No light prot e c t ion
re quire d
ESL
C old c ha in
d i s t r ibut i on
Pas teurised b efo re
filling , filled under lo g
4 - 5 asep t ic co nd it io ns
Up to 12 0 d ays at
<8 °C Me dium light
prot e c t ion re quire d
UHT
Ambi e nt t e mpe r a t ur e
d i s t r ibut i on
13 5-150 °C, 4 -2 0 sec
b efo re filling , filled
und er lo g 6 asep tic
co nd it io ns
Up to 12 0 d ays at
amb ient temp erature
High light prot e c t ion
re quire d
Sterilised
Ambi e nt t e mpe r a t ur e
d i s t r ibut i on
110 -12 0 °C, 10 -4 0 min. in
the b o tt le after filling
Up to 9 mo nths at
amb ient temp eratures
No light prot e c t ion
re quire d
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
Extended exposure to visible light will initiate photo-oxidation of vitamins B6/B12 and riboflavin (vitamin B2). Very high light protection is required up to 550 nm.
1
2
In the case of milk, secondary degradation due to auto-oxidation of lipids (milk fats) results in off-flavours and nutrient losses, especially of vitamins. All this results in a specific “light taste”.
Effects of UV radiation & Visible Light on Food & Dairy- the Chemistry
3
Taste & nutrition protection can not be captured by mathematical formulas or generic data: taste & odor and analytical tests must be performed in the chosen package option.
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
�High-concentrated solid format� Recommended dosing level 5 -14%, depending on application, required opacity and wall thickness
�Generates a white monolayer bottle that blocks 100% UV radiation and up to 99% of visible light
� EU & FDA food contact compliant
�High-concentrated solid format� Recommended dosing level 5 -14%, depending on application, required opacity and wall thickness
�Generates a white monolayer bottle that blocks 100% UV radiation and up to 99% of visible light
� EU & FDA food contact compliant
Key product featuresKey product features
Holland Colours Holcomer UHT White
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
Holland Colours Holcomer UHT WhiteLight transmission at 550 nm
Wall thickness 0.20 mm
0
10
20
30
40
50
60
70
80
90
100
0 2 4 6 8 10 12 14 16
Holcomer ldr (%)
Lig
ht
tra
nsm
issio
n (
%).
ESL Milk
UHT Milk
Opaque white
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
Marketplace
�Product Quality
�Premium appearance
�Established technology
Flexibility
�Bottle Design
�Sourcing of base resin
�Molded & blown on standard monolayer equipment
Process Performance
� Injection Moulding & Blowing performance
�Bottle integrity� Taste preservation equal to multilayer and carton packaging
Cost Effectiveness
�Higher opacity than resin based concepts
�Adjustable dosing levelsoffers further light-weighting
Holland Colours Holcomer UHT White
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
� Range of commercial applications in Europe and the USA with leading dairy companies
� Variety of UHT and ESL milktypes and flavored milk drinks in a range of different bottle designs
� Several new market introductions globally in 2011
� Range of commercial applications in Europe and the USA with leading dairy companies
� Variety of UHT and ESL milktypes and flavored milk drinks in a range of different bottle designs
� Several new market introductions globally in 2011
Holland Colours Holcomer UHT White
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
Previous preform & bottle design generation:
New generation:
Previous preform & bottle design generation:
New generation:
Taking the Next Step in Lightweighting
� 0.24 mm wall thickness
� 1.8% light transmission @ 550 nm
� 60 days shelf life
� 0.2 mm wall thickness
� 1.5% light transmission @ 550 nm
� Up to 120 days shelf life
� Meets all requirements on mechanical properties
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
Light Protection & Oxygen Barrier
O2 O2
O2O2O2
O2
O2O2
Some products need LightAND Oxygen protectionSome products need LightAND Oxygen protection
� Soy milk� Milk-juice blends� Baby formula� Fortified & Functional drinks
� Soy milk� Milk-juice blends� Baby formula� Fortified & Functional drinks
� Omega-3
� Enzymes
� Vitamins
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
Light Protection & Oxygen Barrier
O2 O2
O2O2O2
O2
O2O2
Combined functionalityCombined functionality
� It is possible to combine Holcomer UHT White and oxygen barrier resins
� Holcomer has additional passive barrier properties
� Needs to be validated case by case
� It is possible to combine Holcomer UHT White and oxygen barrier resins
� Holcomer has additional passive barrier properties
� Needs to be validated case by case
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
Light Protection & Oxygen BarrierM&G Poliprotect & Holcomer White
0
0,1
0,2
0,3
0,4
0,5
0,6
0,7
0,8
0,9
1
0 50 100 150 200 250 300
Time (days)
Oxygen
concentratio
n (PPM)
M&G Poliprotect + 14% Holcomer White
M&G Poliprotect + 10% Holcomer White
M&G Poliprotect Natural
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
Sustainability
The challenge
� In today’s PET packaging market there is a trend toward increasing the use of post-consumer recycled PET for theproduction of bottles, sheets and fibers
� This material often exhibits a slight tint or contains colored particles that affect the clarity of the material compared to 100% natural PET resin
� This lowers the value and limits thepossible application areas of the PCR resin
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
TintMask - Extending the Value of Recycled PETThe concept
� Holland Colours’ TintMask concept is based on the principle of complementary colours. The system is designed to effectively neutralize the discolorationthat is commonly present in recycled PET.
� TintMask product range is fully compliant with EU, FDA and Coca Cola Company directives.
� The concept is designed for the PET recycling environment, the components will not migrate or sublimate in a high vacuum process.
� TintMask products are available in liquid and solid formats.
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
TintMask - Extending the Value of Recycled PET
Benefits that make the difference
TintMask delivers significant advantages toprocessors and users of recycled PET:
� Increased sourcing flexibility
� Greater batch-to-batch colour consistency
� Added value to end users of recycled material
� No migration or sublimation in high vacuum processing
� On-site color adjustment at customer’s facility
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
Bottle Recycling Options: End Applications
Source: PCI for Petcore
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
Sustainability & Holcomer
Fact is that opaque white PET dairy bottles can significantly disturb clear PET bottle-to-bottle recycling1
All stakeholders are concerned by the potentially negative image of opaque PET2
A working group on opaque PET recycling has recently been created around COTREP (Comité Technique du Recyclage des Emballages Plastiques) in France
3
This group has taken the initiative to propose a Bottle to Bottle and Bottle to Fibre recyclability assessment protocol for each individual white opacifying solution
4
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
Bottle-to-bottle recycling currently is only valid for the light coloured/non coloured stream. Sorting of colouredfractions is key and can be achieved
1
Current main end applications for heavy coloured PET-recyclate: Strapping, Fibers, Sheet 2
Trials for recycling of 50% white Holcomer-based bottles into new white bottles have been successfully executed with PTI by means of a standardized protocol
3
Tests are under way with COTREP in France to assess the influence of the introduction of 50% white bottle chips coloured with Holcomer in the fiber process
4
Sustainability & Holcomer
Offer Our Customers COLOURS of VALUE and VALUE of COLOURS
Con
nec
tin
g co
mP
ET
ence®
………………………..……………………………………………………………………………….
Cost-Effective and Sustainable Solutions
� Protection against UV-radiation, visible light and oxygen ingress can be combined and customized
� End-of-life options have been secured
� The concepts are flexible and competitive against all alternatives
� BtoB and BtoF recycling is feasible
� Protection against UV-radiation, visible light and oxygen ingress can be combined and customized
� End-of-life options have been secured
� The concepts are flexible and competitive against all alternatives
� BtoB and BtoF recycling is feasible
Consistent resultsConsistent results