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· PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS H. N. SwanSC!1 D. E. Donnelly Colorado Division of Highways 4201 East Arkansas ~venue Denver, Colorado 80222 Fina1 Report September 1977 Please Return to the CDOT LIBRARY Prepared in Cooperation with the U. S. Department of Transportat;cn, Federal Highway Administration

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Page 1: · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS · · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS H. N. SwanSC!1 D. E. Donnelly Colorado

· PERFORMANCE OF CULVERT t1ATERIALS INVARIOUS COLORADO ENVIRONMENTS

H. N. SwanSC!1D. E. DonnellyColorado Division of Highways4201 East Arkansas ~venueDenver, Colorado 80222

Fina1 ReportSeptember 1977 Please Return to the

CDOT LIBRARY

Prepared in Cooperation with theU. S. Department of Transportat;cn,Federal Highway Administration

Page 2: · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS · · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS H. N. SwanSC!1 D. E. Donnelly Colorado

Technical Report Documentation Page

3. Recipient's COlolog -No.

PERFO~~CE OF CULVERT ~~TERIALS IN VARIOUSCOLORt~O ENVIROill4ENTS

September 1977~.

6. Perfo'ming Orgonizerion Code

7. Author'sl H. N. S"lanSOnn F.. Donnelly

9. Performing O,gonizotion Nome end Add,ess

Colorado Division of HighwaysPlanning and Research Branch4201 East Arkansas AvenueDenver. Colorado 80222

12. Sponsoring Ag••ncy Nome ond Addreu

11. Cont,'oct or Gron·' No.1475

State Department of High\olays4201 East Arkansas AvenueDenver, Colorado 80222

Prepared in cooperation with the U. S. Department ofTransportation, Federal High\olayAdministration

The history of culvert pipe in Colorado has gener~llr been a record of goodperformarice~ This report addresses extreme 'corrosive environments \~lich maybe found at various isolated sites, primarily alkali in nature, located inthe State. Various pipe materials have ,been observed, recorded and reportedbased on performance in these extreme soil and water environments.

Results of laboratory tests on culvert materials are also reported. Someconclusions and recommenaations are made for implementation and futureevaluations.

Culvert materials most susceptible to field corrosion in these isolated extremecon9itions are standard galvanized, stainless steel, concrete Type II, andasbestos bonded asphalt dipped. Those materials showing little or negligiblecorrosion are transite, plastic, aluminum, and concrete Type V. Consequentlythese stated materials should be considered in the extreme conditions foundapproximately 10% of the time in Colorado.

No restrictions. This document isavailable to the public through theNational Technical Information Service,Virginia 22161

~~U'iIY Clos.il. (of this rcporl)

~classified

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INTRODUCTION . . • . . . • . . .TEST SITES .PERFORMANCE OF CULVERT MATERIALS .

A 1urn; num . . . . . . . . . . . .Stainless Steel . . . . . .Standard Galvanized ...•Asbestos Bonded and Asphalt Dipped Metal Pipes •.Concrete . . . • . .Nexon Coated ~ . . . • . .Plasticote ..•••Transite Pipe.Plastic Drain PipeBLAC-KLAD . • . .

Metal Specimens TestedConcrete Specimens Tested .Environments and Salt ConcentrationsEvaluation •••.......Ratings of Individual Materials

ECONOMIC CONSIDERATIONSCONCLUSIONS . . .RECOMMENDATIONSIMPLEMENTATION . • .FUTURE NEEDS

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Page 4: · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS · · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS H. N. SwanSC!1 D. E. Donnelly Colorado

This report addresses extreme corrosive environments which may be foundat various isolated sites in Colorado, Corru9~ted metal and Type IIconcrete pipes are considered quite adequate for normal installationswhereas the special culvert materials discussed here should be consideredat isolated sites.

Colorado's culvert research program started in 1962 by comparingthe performance of different types of culverts in various environments.

A report entitled REPORT ON EXPERIMENTAL PROJECT ALUMINUM CULVERTSMarch 1965 was published and covers installation and experiences onaluminum culvert installations in three different Colorado environments,Another report published in August of 1968 CULVERT PERFORMANCE AT TESTSITES IN COLORADO describes five types of culverts in different Coloradoenvironments for a six year period.

In recent years interest in culvert materials and environments hasfluctuated considerably. Renewed interest was generated when in 1972,a eorrugated Metal ripe near Straight Creek failed after only a fewyears. Soil and water analysis at this 'site showed pH of 2.25 and 3.0respectively. This highway had not yet been paved or opened to trafficat the time of failure. The corroded and collapsing CMP was replacedby a Type II cement concrete culvert.

This acidic soj1 and water is very unusual in Colorado. Historicallythe major problem areas causing culvert corrosion in Colorado are soilsand water which are alkaline and/or carry high salt contents. Theseconditions are found quite extensively throughout Colorado and theWestern United States. In Colorado most soils below 7,000 feet (2,134 m)in elevation are alkaline to some extent.- This elevation generallydelineates climate and runoff characteristics. The lower elevations aregenerally semiarid to arid and low gradients are encountered, Anotherfactor which contributes to the formation of high alkaline soils andwater is the geology. Generally marine 'sediments containing high con-centrations of chlorides and sulfates (shales, silts, mudstones) are theorigin of alkaline soils and waters. Water from local precipitation orfrom springs dissolves the salts from the rock or soil and carries themto the surface where precipitation of the salts takes place due to rapidevaporation of water into the dry air. Field test sites were establishedunder these conditions.

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In the spring of 1976 some laboratory experiments were begun withsmall samples of various culvert materials placed in soils and watersof various chloride and sulfate concentrations. This series of testswas initiated to confirm the validity of criteria established in 1975currently being used in design specifications.

Figure 1 shows the location of culvert test sites in Colorado.Site 1 - Thirteen miles (21 km) south of Punkin Center

on State Highway 71. The environment at thislocation is in clay soil derived from PierreShale in a semiarid part of eastern Colorado.A typical analysis of the soil is:Loss on ignitionInsoluble residueIron and Aluminum OxidesCalcium Oxide~1agnesiurn Oxi deSulfates as S04Alkali as S04 (waterpHIntermittent flow in

4.76%87.22%

5.40%1.61 %0.79%3.5%0.8%8.1

Photograph No. 1This aluminum pipe atPunkin Center is asgood today as it waswhen it was installed

in 1962.

Page 6: · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS · · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS H. N. SwanSC!1 D. E. Donnelly Colorado

Site 2 - On State Highway 96, 6.85 ( 11 km) west of junctionof State Highway 165 west of Wetmore. In the springof 1962, an aluminum culvert was placed 6 feet f~ma standard corrugated galvanized steel culvert forcomparison of performance. The pH of the disintegratedPikes Peak granite type of backfill averages 6.4.Stream flow is intermittent.

Site 3 - On State Highway 56 east of Berthoud and approximately0.7 mile ( 1 km) west of I 25 is a 3611 aluminum culvert.Approximately 0.6 mile ( 1 km) west of this culvertis an aluminum culvert. Both culverts were placed in1962 with an A-6(7) type soil for backfill. The soilpH is 7.0 and the water pH is 7.4.

Site 4 - Between U. S. 50 and the east right-of-way fenceapproximately 1 mile(1.6 km) north of Whitewater.A single aluminum culvert was placed in a very dampalkaline soil in 1962 .. The_pH ranges between 7.4and 7.9.

Site 5 - At Fossil Creek between the roadway and the west right-of-way fence on Interstate 25 approximately 0.75 mile(1.2 km) north of the Windsor Interchange (SH 392).The running water has a pH of 7.4, a sulfate content of1160 ppm and a bicarbonate alkalinity of 533 ppm. Thesoil has a pH of 9.2 and has a high calcium carbonateand magnesium sulfate content.

Page 7: · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS · · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS H. N. SwanSC!1 D. E. Donnelly Colorado

Photograph No. 2General view of pipe samples at

Fossil Creek

Page 8: · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS · · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS H. N. SwanSC!1 D. E. Donnelly Colorado

Along U. S. Highway 6, at the east edge of Fruitanear Grand Junction. Culverts have been placedbetween the roadway and the north right-of-wayfence in a very alkaline area. Approximatelyone-third of the time, the culverts are under water.Some culverts were placed in 1964. The pH of thesoil ranges from 8.2 to 8.4 (see Photograph No. 3below).

Photograph No. 3General view of the Fruitasite with pipe samples.Note alkali o~ the surface.

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Site 7 - Along U. S. 50 between Delta and Montrose 2.8 miles(4.5 km) south of Olathe in the east borrow ditch.There is water in this ditch all the time and boththe water and soils are very alkaline.

Site 8 - Straight Creek - along the north borrow ditch ofInterstate 70 about 0.6 mile (2 km) east of theDillon Interchange. Slow percolating ground wateremerges from the adjacent coal and shale members ofthe Dakota formation rock cut. Precipitates ofsulfur on the exposed rock indicate abundance ofsulfates. The pH of water varies-from 1.0 off thewall to 3.0 and 6.0 in the ditch near the culvertinlet. (See Photograph No.4 below.)

General view of pipe samplesat Straight Creek.

The concrete end section tothe cross culvert under thehighway is at the lower center.

Page 10: · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS · · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS H. N. SwanSC!1 D. E. Donnelly Colorado

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Page 11: · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS · · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS H. N. SwanSC!1 D. E. Donnelly Colorado

PERFORMANCE OF CULVERT MATERIALSAluminumAluminum culverts have been installed at all sites exceptNumber 7 near Olathe. All of these have been reported on inprevious reports except the installation at Straight Creek.After five years in the acidic environment at Straight Creek,aluminum pipes show some corrosion of the cladding in the areassubmerged in the water or in contact with the soil. Eachattacked area is covered with a hard mud-like crust build-upwhich is very similar to corrosion of aluminum culverts inalkaline environments.Aluminum culvert materials have been installed in various testlocations for may years. Following is a summary:

Installation Date Test for Resistance to ••Westcliffe 1962 Scour and Abrasion No noticeable effectPunkin Center 1962 Slight Alkali Pierre Shale No visible corrosionFruita 1962 Heavy Alkali Mancos Shale Considerable attack on

cladding-no perforationsWhitewater 1962 Heavy Alkali Mancos Shale Considerable attack on

cladding-no perforationsBerthoud 1962 Mild Conditions No attackFossi1 Creek 1966 Alkaline Swamp Condition Considerable attack on

cladding-no performationsStraight Creek 1972 Acid Condition Slight attack on cladding-

no perforationsAs a .~esult of these long term installations, the following con-clusions are submitted:

1) Aluminum culvert has better corrosion resistance thangalvanized culvert material as long as their exposureis within the limits suggested by the manufacturers.

2) The cladding seems to prevent perforation type corrosionand limits the attack to the cladding, which is about10% of the cross sections area of 16 gage sheeting.(Photograph No.5, on the following page, is a goodexample of this.)

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This is an aluminumsample at Fruita.It has been in placesince 1962. There hasbeen attack and en-crustation of the claddingbut .the base aluminumis still sound

3) It requires more careful handling during transportftionand installation, since it is softer and not as stiffor "springy" as galvanized steel.

Colorado specifications allow the use of aluminum culvert andstructural plate pipe when some other specific culvert mate~ia1is not specified and therefore, no action is required. Fieldtesting of aluminum culvert is therefore concluded.Contractors have been hesitant to use aluminum for fear of damagein transit or installation. It is suggested that aluminum culvertscould be used where light equipment is required such as rest areasand bike paths.Stainless SteelSamples of stainless steel culverts have been placed at Sites 5,6, and 8. These samples in alkaline conditions of Fruita a~dFossil Creek have many holes corroded through, some as large as6 inch (15 cm) diameter. The sample at the Straight Creek site showsno sign of attack on the stainless steel but the steel rivetsare rusting.

Page 13: · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS · · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS H. N. SwanSC!1 D. E. Donnelly Colorado

Stainless steel should not be used in high salt or alkalineenvirOnments.Standard GalvanizedThe history of galvanized steel culverts in Colorado has generallybeen a record of good performance. Only in the areas where thereexists extremes of high concentrations of acids, alkali nd/orsalts, has this type of culvert shown a limited llfe.When the type of material for culvert pipe is not speci ied in aconstruction contract in Colorado, galvanized corrugated steelis selected by the low bidder in more than 90% of the contracts.

Photo raph No. 6This wak a galvanizedsteel pipe sample atFruita·1This sarPle has beenin this environment for14 years. A white clothinside ~he pipe showsthe hOlfs eroded away.The res of the pipeis very thin and fragile.

I

Samples of galvanized metal pipes have been placed at test Sites 5,6, and 8. The samples in the alkaline environment are badly corrodedwith many holes rusted clear through. (See Photograph No.6 aQove.)The galvanizing has been heavily attacked in large patch~s about2 inches (5 cm) in diameter on the Straight Creek sample] Wherethe galvanizing is gone, the base metal is heavily pitted. No.rustcolor is apparent, however, and attack areas seem to be limitedto a few local areas that were underwater.

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The original corrugated metal culvert installed under the roadwayat the Straight Creek site was replaced after only six yearsbecause of excessive corrosion.

Asbestos Bonded and Asphalt Dipped Metal PipesAsbestos bonded and/or asphalt dipped pipes seem to be slightlymore resistant to corrosion than the bare metal but the protectionis only good as long as the coating material is intact. Thecoating can be damaged during transportation and installation.Mechanical abrasion and thermal cracking as well as loss ofductility because of oxidation and age are responsible for theineffectiveness of the protective coating after a few years.A sample of asbestos bonded pipe at Straight Creek has spots wherethe asphalt has become brittle and broken off exposing the asbestosbonding. A sample of asphalt dipped pipe also at the StraightCreek site shows cracking and checking of the asphalt where it isexposed to the sun and water. (See Photographs No.7 and 8.)

This asbestos bondedasphalt dipped crossculvert at FossilCreek has peen in placesince 1963.The exterior is crackedand being eroded away.

Page 15: · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS · · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS H. N. SwanSC!1 D. E. Donnelly Colorado

PhotorraPh No.8This i~ the inside ofthe sa~e asbestos bondedasphalF dipped pipe asshown I'n Photograph No. 7Note: The asphalt andasbestos are gone belowthe high water line.The metal bottom iscorrod~d through inmany p1aces.

An asbestos bonded asphalt dipped metal pipe installed I'n 1963

during construction at Fossil Creek is corroded through andeaten away. All of the coating above the water line islcheckedand cracked exposing the metal which is rusting. The alPhaltcoating and asbestos has been removed near and below the waterline. During an inspection in the spring of 1976 one mAn triedto walk through the pipe and fell through twice.

This asphalt dipped sampleat Fossil reek was rolledup for the photograph toshow that t e asphalt belowthe water line is gone. Theasphalt above the water lin~is cracked and being erodedoff.'

Page 16: · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS · · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS H. N. SwanSC!1 D. E. Donnelly Colorado

Asphalt and asbestos coatings seem to provide only temporaryprotection in these harsh conditions.Concrete'Concrete sect ions made 0 f Type II cement, Type II low a1ka 1ii'Type II low C3A and Type V cements were placed at the Fruitaand the Olathe sites in 1974 and 1975. Samples made with Type IIand Type V cement were placed at Fossil Creek in 1966. All ofthe above concrete samples are sound and in good condition.Sections of concrete pipe, one made with regular aggregate andone with limestone aggregate have been exposed to the acidicconditions of the Straight Creek site for five years., The inletend of the reinforced concrete pipe-Class III made fr9m Type IIcement which replaced the corroded metal pipe under the hig~Wayin 1970 is included in the group of test specimens at StraightCreek.The areas exposed to the water show definite attackwater. Attack has only removed the cement surface,aggregate. (See Photograph No. 10.)

by the acideXPosini the

Photograph No. 10

This is the bottom of theinlet end section of theconcrete cross culvertat Straight Creek. Thispipe was Pla1ed in 1970.The top .2" ~5 mm) ofconcrete mortar has beenetched leaving silicateaggregate exposed.

Page 17: · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS · · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS H. N. SwanSC!1 D. E. Donnelly Colorado

The attack is not very serious and the pipe under the highwayis expected to remain in service for at least another twe~tyyears. The limestone aggregate in the sample listed abovehas also been attacked.

Samples of Nexon coated pipes were placed at the Fruita andIOlathe sites in 1974. At the lock seams, the Nexon coating had

been cut through by the seam forming rolls during fabrica~ion.These seams were not repaired. Those places in contact with thesoil show heavy attack. There is also a separation of the Nexoncoating from the galvanized steel sheet at the edges on the endof the pipe, with rust showing between the two layers. T~is does

Inot extend into the sheet very far, however. The coating is ingood condition wherever it is not damaged.Another sample at Fruita was Nexon coated inside, epoxy coatedoutside, then wrapped with po1yvi~y1 plastic sheet. WherJ moisturewas trapped under the sheet, the epoxy coating has rusted more thanwhere the pipe was not covered. The Nexon interior is in goodcondition except where small damage had occurred during fabricationand installation.Samples of Nexon coated interior and the exterior coated With yellowepoxy, one wrapped in clear plastic sheet and another without theplastic, were placed at Straight Creek in 1972. The plastic sheetingdid not help. The epoxy coating under the wrapping seemed to berrnre heavily attacked than the same coating not so wrapped. There

- Iwas no attack apparent on the interior Nexon coating although it""as stained in the submerged area. There was some separafion ofthe sheet from the pipe at the upstream edge.P1asticoteA piece of CSP made from Wheeling Stee1's PLASTICOTE was installedon September 22, 1976 at Straight Creek. This section of spiralpipe has a 10 mil coating of plastic on the outside and a greenepoxy paint coating 0,3 mi.1s.thick on the inside. Similar sampleswere installed at Fruita and Olathe in May of 1976.

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These pipes are all in good condition to date but moretime is needed to evaluate their performance.Transite PipeSamples of transite pipe were placed at Fruita and StraightCreek in 1972. They are both in very good condition and showno evidence of corrosion. (See Photograph No. 11.)

This -transite pipe atIFruita since 1972 is

unharmed by the harshenvironment

Plastic Drain PipePieces of plastic pipe were placed at Straight Creek in 1972 andat Olathe in 1975. The sample at Straight Creek was missingafter the second year but showed no corrosion until then. Theone at Olathe is in excellent condition. (See Photograph No. 12.)

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Plastic drain pipesIappeTr unaffected by

hars~ environments.The stains are onlyon the surface.

BLAC-KLADA piece of 16 gage helical steel pipe BLAC-KLAD polyethyleneprecoated was installed at Straight Creek November 16'J'973.There were a few ruptures of the cladding caused by haJdl ingprior to installation which were not repaired. There is nosign of attack on this pipe.

LABORATORY TESTINGOn March 4, 1976, a program designed to investigate various culvert

materials was started. Forty-nine sets of samples were preppred for theproject. Twenty-four were used for metal materials and the balance forconcretes. About one half of each type were exposed to eithfr soil orwater environments, with various concentrations of Chloride 0

1

r Sulfatesalts.

The investigation had several objectives, as follows:1. Development of a 'rapid' laboratory method for

evaluating relative effectiveness of culvertmaterials.

2. Evaluation of several culvert materials and specialprotective measures which are in use, or proposed,to extend the life of culverts.

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3. Verification of the limits established by theCulvert Committee which are used to determine thelevel of protection required for structures andculverts on Colorado projects.

Materials considered were divided into two types; 1) Metal and2) Concrete. Metals investigated include clad and unclad Aluminum,galvanized steel both plain and with various types of special coatings.Concrete samples included samples made using each of four types ofcement available in this area. Each of the samples used in the ~valuationmeasured about two by six inches.

Metal Specimens Tested1) Aluminum; Clad on both sides, clad one side only2) Galvanized steel, 2 oz. Zinc.3) Two oz. galvanized steel with one of the following

treatments:a) U. S. Steel NEXON coating one side, epoxy

paint one side.b) U. S. Steel NEXON coating both sidesc) Wheeling Corrugating PLASTICOTE one side,

epoxy one sided) Inland Steel BLAC-CLAD coating both sides

.e) Asphalt Dippedf) Asbestos Bonded Asphalt Dipped

4) Kenitex Corp. Kinkote plastic coating, one sample eachon steel and Aluminum. (Table I, W-10; Table II, S-ll)

Concrete Specimens Tested1) Type I cement2) Type II cement3) Type II, Low C3A cement4) Type V cement

Environments and Salt ConcentrationsDistilled water and soil free of Sulfate and Chloride,passing a no. 4 sieve were utilized for test environ~entsfor each type of specimens.

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Magneisum Sulfate and Sodium Chloride were the saltsused to prepare each of the test samples, as follows:

Metal/Water: None, 250 ppm C1; 500ppm C1; 1000PP~ C1;1000ppm S04; 2000ppm S04; 4000ppm S04; 250ppm, c1,1 150ppm S04;500ppm C1, 1000ppm S04; 1000ppm C1, 2000ppm S04; 2000ppm Cl,4000ppm S04' (Table I)Metal/Soil: None; 0.20% C1; 1.0% C1; 2.0% C1; 3.0% C1; 0.2% S04;0.5% S04; 1.0% S04; 2.0% S04; 0.1% C1iO.1% S04~ 1.0% Cl~0.5% S04; 2.05% Cl; 1.0% S04' (Table II)Concrete/Water: Same salt concentrations as Metal/Water.(Table III)Concrete/Soil: Same salt concentrations as Metal/Soil, withadditional sample of 3.0% C1, 2.0% S04' (Table IV)Soil samples were prepared at approximately 10% moisture.

Evaluation . tSelective evaluations were made on the samples at one nd three

months exposure. Detailed evaluations were made at six monl hs andeighteen months. To simplify the evaluation process, a numericalscale of 0 - 5, was selected to describe observed conditions.These scales, for metal and concrete types are:

5 - No visible corrosion I,4 - Light salt deposit or rusting at edges andror staining3 - Mild salt deposit or rusting, blistering njar edges2 - Extensive rusting and formation of blisters1 - Severe corrosion or rustingo - Very severe rusting or loss of adhesion of

protective coating.5 - No apparent change except slight staini[g4 - Light pitting and/or salt deposits3 - Moderate loss of surface mortar and sa lit

accumulation2 - Moderate loss of aggregate1 - Extensive aggregate loss, swelling and/or

warping of coupon° - Total failure of coupon

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Generally, except for the Aluminum coupons, Chlorides/have a more detrimental effect on metal coupons than SUlfa~es.The opposite effect seems to be true with concrete coupons.Numerical ratings for six month and eighteen month ratings maybe found in Table I - IV. Deviations in rating values may bein part equated to changes in salt deposits at different ratingperiods and experience developed in evaluation, which is Jitalin a test such as this.Ratings of Individual Materials

AluminumThese samples performed very well. Clad specimens generatedsomewhat low ratings because of the loss of cladding material.Base metal showed very little attack. The cladding is providedas a sacrificial protection similar to galvanizing on steel,therefore this rating is not considered to be serious.Galvanized SteelThis material exhibited poor resistance to Chloride Attack.Sulfates and combinations of Sulfate and Chloride, eiceptat quite high concentrations, seem to have only minimal effecton it.NexonCoupons prepared using this material performed quite wellexcept for those exposed to combinations of salts in water.Some loss of adhesion and blistering was evident how~ver.The epoxy coating did not fare well, especially in ehviron-ments where Chloride was present. The epoxy coatingl is notintended to provide protection. It is strictly decorative.P1asticoteSamples of this material used in this series of tes~s did notperform well. Information received from the manufa~turerindicated the material tested was not representativJ ofproduction.Asphalt Dipped Galvanized SteelThis.treatment seems to be very effective except at Ivery highsalt concentrations.

Page 23: · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS · · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS H. N. SwanSC!1 D. E. Donnelly Colorado

BLAC-KLADThis material did not perform well in any samples wherethe Chloride content was above 500 ppm. It does seem tobe quite satisfactory for resistance to attack from alkalialone.Asbestos Bonded Asphalt CoatedThis type of treatment also appears to be very effectiveexcept at high salt concentrations.KinkoteBoth the Aluminum and Iron specimens performed well.Type I CementThese samples are quite resistant to Chlorides, but breakdown rapidly at Sulfate concentrations over 0.2%.Type II CementThe same comment applies to these samples, except that theSulfate failure level seems to be above 1.0%.Type II, Low C3A CementThe performance of this material is only slightly betterthan Type II cement.Type V CementThough specimens made using this type of cement sufferedsomewhat from Sulfate attack, they were the most resistantto alkali conditions.

Page 24: · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS · · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS H. N. SwanSC!1 D. E. Donnelly Colorado

LABORA

TORY

TEST

RESULT

STAB

LEI

~Sa

mp1

,'Sp

tW

-lW

-2W

-)W

-4W

-5W

-6W

-7W

-8W

-9W

-I0

W-ll

W-1

2

250p

pmC

l50

0pp

mC

1zu

uupp

ml;

LLu

uupp

m"1

Salt

Con

e.N

onp

250p

pmC

L50

0ppm

CL

1000

ppm

Cl

150p

pmS0

410

00pp

mS0

420

00pp

mS0

440

00pp

mSO

l.15

0ppm

SO,.

1000

ppm

SOl.

4000

ppm

SOl.

2000

ppm

SO

Eval

uatio

nPp

riod

6m

o18

mo

6m

o18

mo

6m

o18

mo

6m

o18

mo

6m

o18

mo

6m

o18

mo

6m

o18

mo

6m

o18

mo

6m

o18

mo

6m

o18

mo

6m

o18

mo

6m

o18

mo

Gal

vani

znd

Stpe

l.1

4)

42

'4)

)1

))

44

44

44

4)

4)

4)

4)

24

)4

24

1)

2)

)4

44

44

44

)4

)4

)4

)

Cla

dA

lum

inum

14

34

44

34

44

44

44

44

44

44

44

)4

)

(bot

hS

id•.

a)2

43

44

4)

44

44

44

44

44

44

44

4)

4)

Alu

min

um1

54

44

44

44

44

44

44

44

44

44

44

44

25

44

44

44

44

44

44

)4

)4

44

44

44

4

..N

•.xon

!Epo

xy1

43

44

44

44

4)

)4

44

44

44

)4

24

32

4)

43

3)

32

)2

))

43

43

44

43

42

43

Npx

on-2

sid

•.a

14

34

34

33

34

44

44

44

44

44

14

13

22

43

42

43

3)

44

44

44

44

43

43

42

)2

Plaa

tieot

e!Ep

oxy

14

34

2)

2)

23

44

44

44

44

2)

23

0)

02

4)

42

32

)2

)4

44

44

44

42

)2

30

)1

Bla

ekel

ad1

43

43

44

)0

4)

44

44

44

41

41

30

42

24

)4

)3

32

04

34

44

44

44

04

03

24

1

Asp

halt

15

54

54

44

55

55

55

55

55

55

55

55

)

dipp

ed2

55

45

44

45

55

55

55

55

55

55

55

5)

Asb

esto

s1

55

55

55

55

55

55

55

,5

55

55

55

15

1B

ondp

d2

55

55

55

55

55

55

55

55

55

55

51

51

Kin

kote

Alu

m.

.5

Stee

l.

5

Meta

lSa

mple

sin

Wate

rEn

viro

nmen

tsNu

meri

cal

valu

esfr

om0

to5

indi

cate

seve

reco

rros

ion

tono

visi

ble

corr

osio

nre

spec

tive

ly

Page 25: · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS · · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS H. N. SwanSC!1 D. E. Donnelly Colorado

LABORA

TORY

TEST

RESULT

STAB

LEII

--_.

Sam

plE

'Se

t5-

1S-

25-

35-

4S-

5S-

65-

75-

8S-

9S-

10"_

11

"_1?

0.17

.C

l1.

07.

Cl

2.07

.C

lSa

ltC

one.

Non

~0.

27.

Cl

1.07

.C

l2.

07.

Cl

3.07

.C

l0.

27.

S04

0.57

.SO

l.1.

07.

504

2.07

.SO

"0.

17.

SO,.

0.57

.SO

,.1.

07.

S0"

Eva

luat

ion

Peri

od6

mo

18m

o6

mo

18m

o6

mo

18m

o6

mo

18m

o6

mo

18m

o6

mo

18m

o6

mo

18m

o6

mo

18m

o6

mo

18m

o6

mo

18m

o.

6m

o18

mo

6m

o18

mo

Gal

vani

zp.d

Stre

l1

44

31

21

21

10

44

44

43

43

43

31

13

24

44

23

12

12

04

54

44

34

34

33

11

3

Cla

dA

IU11

1inu

m1

42

33

33

33

33

44

43

44

43

43

33

22

(bot

hai

d••s

)2

42

43

43

43

43

44

43

44

43

43

33

33

Alu

min

um1

43

43

43

43

33

44

33

44

44

44

"3

33

42

44

33

33

3.3

33

33

34

44

33

33

33

4-

_....

.....

--N

~xon

/Epo

xy1

55

44

43

44

44

54

54

54

44

43

43

44

25

54

43

12

12

14

34

34

44

44

33

32

2-

N~x

on-2

sid

••s1

55

43

33

33

33

53

54

44

44

43

•3

33

32

55

43

33

33

33

53

54

54

44

33

33

·23

Plas

ticot

elE

poxy

14

43

~2

22

12

13

.3

44

44

44

22

24

43

32

22

22

23

34

44

44

42

22

12

12

12

2B

lack

clad

15

54

33

33

42

04

45

44

44

43

12

55

43

10

34-

20

44

54

44

44

32

30

22

31

31

Asp

halt

15

45

35

35

55

55

45

55

45

45

4-

Dip

ped

25

45

35

35

55

55

45

55

45

45

45

45

25

45

2A

sbrs

tos

15

45

35

35

55

55

55

55

45

45

1B

ond"

d2

54

53

53

54

55

53

55

54

54

51

54

54

54

54

Kin

kotr

Alu

m.

-5

5St

eel

-5

5-.

-..

Meta

lSa

mple

sin

Soil

Envi

ronm

ents

Nume

rica

lva

lues

from

0to

5in

dica

tese

vere

corr

osio

nto

novis

ible

corros

ionres

pectiv

ely

Page 26: · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS · · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS H. N. SwanSC!1 D. E. Donnelly Colorado

-_

._.

Sam

o1"

S••t

11-1

11-2

11-3

11-4

W-5

W-6

W-7

W-8

W-9

W-1

011

-11

11-1

225

0ppm

Cl

500p

pmC

l20

00pp

mC

l10

00pp

mCT

Salt

Con

e.N

on••

250p

pmC

l50

0ppm

Cl

1000

ppm

Cl

150p

pmSO

,.10

00pp

mSO

,.20

00pp

m50

440

00pp

m50

415

0ppm

504

1000

ppm

504

..~O

OO

ppm

504

2000

ppm

504

Eval

uatio

nPp

riod

6mo

18m

o6

mo

18m

o6

mo

18m

o6

mo

18m

o6

mo

18m

O6

mo

18m

o6

mo

18m

o6

mo

18m

o6

mo

18m

o6

mo

18m

o6

mo

18m

o6

mo

18m

o-

Typ~

I1

55

55

44

54

55

54

51

20

44

43

22

23

25

55

54

55

45

55

35

12

04

44

32

22

3

Typ

eII

15

55

54

44

45

54

44

44

44

44

32

33

32

55

55

45

44

55

44

44

44

44

43

23

33

Typ

••n.

15

55

54

54

45

54

44

44

44

44

43

33

4

Ie,A

25

55

54

54

45

54

44

44

44

44

41

33

4

~y1I5

55

55

54

55

55

54

44

44

44

44

44

4-.

25

55

55

54

55

55

5I

44

44

44

44

44

44

I...

\:.~.

~.

inWat

erEnv

ironme

ntsr'··

,Con

crete

Sample

s.

';")..If',~~ .

:~.

,,-,..

.l

'~;\

~;"

t:'

,"'...

.-{

...•.I.

i.~

"'.•.•...

...;..

~'.~

' ',,"t'.

.~

....

~'>

.,..w

;-TAB

LEIV

LABORA

TORY

TEST

RESULT

STAB

LEII

I

-_.--

_.

5•••

•1•

•Sl

Ot

5-1

5-2

5-3

5-4

5-5

5-6

'5-

75-

85-

95-

10S-

11S-

12s-

nO

.ltC

l1.

0tC

12.

0tC

13.

otC

1ISal

tC

one.

!Ion

••0.

2tC

1l.O

tC

12.

otC

13.

otC

10.

2t50

4._

0.5t

504

l.ot

504

2.0t

504

0.1'

.SO

"•O

.5t

504

l.ot

504

2.ot

504

.Ev

alua

tion

P••r

iod

6mo

18m

e6

mo

18m

o6

mo

18m

o6

mo

18m

o6

mo

18m

o6

mo

18m

o6

mo

18m

o6

mo

18m

e6

mo

18m

o6

mo

18m

o6

mo

18m

o6

mo

18m

o6

mo

18m

o

Typp

I1

55

54

44

34

34

32

22

24

11

44

44

22

10

25

55

44

43

43

43

22

22

41

14

44

44

42

2

Type

II1

55

54

44

34

34

34

34

33

11

44

43

22

10

25

55

44

43

43

43

43

43

31

1.4

44

32

21

0

Typ

••II

15

55

44

43

43

43

42

43

2'

-I1

43

33

12

21

CJA

25

55

44

43

43

43

42

43

21

14

33

31

22

1

'Typ

••.V

'1

55

54

44

34

44

44

44

42

21

54

44

23

11

--2-

e--5

--..

L-

L4

44

34

44

44

44

43

21

S4

44

23

11

Concre

teSam

ples

inSoi

lEnv

ironme

ntsNum

erical

values

from

0to

5ind

icate

severe

corros

ionto

novis

ible

corros

ionres

pectiv

ely

Page 27: · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS · · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS H. N. SwanSC!1 D. E. Donnelly Colorado

Photograph No. 13Original metal laboratory samples before placement

into corrosive environment

Photograph No. 14Metal samples after 18 months in

a harsh soil environment

Page 28: · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS · · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS H. N. SwanSC!1 D. E. Donnelly Colorado

Photograph No. 15Metal samples after 18 months in a

harsh water environment

Photograph No. 16Original concrete laboratory samples

No corrosion or decomposition

Page 29: · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS · · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS H. N. SwanSC!1 D. E. Donnelly Colorado

Photograph No. 17Concrete samples after 18 months in a

harsh water environment

Photograph No. 18Concrete samples after 18 months in a

harsh soil environment

Page 30: · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS · · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS H. N. SwanSC!1 D. E. Donnelly Colorado

ECONOMIC CONSIDERATIONSA 1977 cost estimate indicates that standard galvanized, all

types of concrete and aluminum are about equal in cost at $15 penlineal foot for 24 inch (61 em) diameter pipes. The same diamet rasbestos bonded asphalt dipped pipe would cost about $20 per lin alfoot, and a galvanized steel asphalt dipped also would be $20 pelineal foot. The same eost~stjmate showed that a steel pipe of

- ~.'.similar size with Nexon coating on one side would be an addition 120% and both sides would be an additional 30% or $18 and $19.50 ~respectively. Vitrified clay would cost slightly more than stan ardgalvanized pipe. No costs are available for the other types of oatingsbut it is assumed that they would be similar to that of Nexon.

These costs should be considered when a corrosion resistantculvert is to be specified for a harsh environment.

CONCLUSIONSStandard galvanized, stainless steel, concrete Type II and asbestos

dipped have corroded the most in harsh. field environments. Thesematerials should not be used where high alkali and salt contents arepresent or where high acid water and soi1s al~eencountered. I

A sample covered with Plasticote has only been in the test inviron-ment for on~ year and another with BLAC-KLAD for only three yea1s.There is insufficient observation time to dl'a\\'conclusions on t]osematerials.

Transite, plastic, aluminum and concrete Type V and Type II low..C3A seem to be the most resistant to high-Iy corrosive conditionr' Con-

crete made with Type V cement is the most resistant of concrete materialsto alkali conditions. It should be noted that all types of confretewill not be equally resistant and that the several types instal ed atFruita and Olathe have been under observation for three years. Moretime is required to determine the most corrosion resistant type.

Results from the laboratory and field tests are not compatitle inall cases bacause of fluctuating pH values and salt concentratipns.Field test sights fluctuate from season to season because of the amount

Of.wa ter present and; vadable flow rates. LaDora tory enVironmejlts:changedshghtly as some salts chemically combined \>lithculvert materiCl s •

.•' ...,." '. .

Page 31: · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS · · PERFORMANCE OF CULVERT t1ATERIALS IN VARIOUS COLORADO ENVIRONMENTS H. N. SwanSC!1 D. E. Donnelly Colorado

These salts were not replaced therefore concenteations declinedslightly as materials corroded. Some other inconsistencies can enoted but are considered to be insignificant.

RECOMMENDATIONSConcrete pipe made with Type II or Type V cement should be s b-

stituted in moderate to high alkaline or acidic environments.The drainage ditch, at the Straight Creek site, upstream frof the

inlet of the concrete cross culvert, could be lined with crushedl1ime-stone and powdered lime. 'The seepage water flowing through and !verthis lime would become more nearly neutral in pH value. The 1if: ofthe concrete culvert would then be substantially lengthened becatse ofa reduced etching action of acid.

When and if it becomes necessary to replace this concrete cu vertor any other culvert in an acidic environment, it is recommended thata small vitrified clay or plastic pipe be placed at a lower e1ev tionthan, or upstream of the inlet of the new culvert. The small pi ewould carry the corrosive seep water and the larger standard pip willcarry diluted storm runoff water.

IMPLEMENTATION jImplementation of the results of these experiments has beennd will

continue to. be a continuous and dynamic process. Specifications andspecial provisions have been implemented on the basis of field aidlaboratory experiences and the recommendations of the Culvert Co rosionCommi ttee. -_.

The recommendations in this report are for consideration by heCulvert Corrosion Committee and appropriate revisions could be mde inthe specifications, j

Future evaluations of new materials and the few materials st 11 intest environments will be handled in a similar manner.

FUTURE NEEDSP1asticote and BLAC-KLAD materials should be evaluated after a few

more years of exposure in their extreme test environments. someJofthe types of concrete pipe also require more time to determine tte mostcorrosion resistant. These and any other new materials should bevaluated and reported on by the Product Evaluation Procedure.