peacemakertm oxidizing dry air scrubbers o & m...

PEACEMAKERTM OXIDIZING DRY AIR SCRUBBERS

Submittals 3000 Series O & M Manual 3000 Series

Syneco Systems, Inc.80 West 78th Street, Suite 133

Chanhassen, MN 55317Tele: 952-927-9215Fax: 952-927-9224

E-mail: mailto:[email protected]

Syneco Systems, Inc.80 West 78th Street, Suite 133Chanhassen, MN 55317

Tele: 952-927-9215Fax: 952-927-9224

E-mail: [email protected]

© 1994 - 2006 Syneco Systems, Inc. All Rights Reserved.FORM NO 550-IF (Page 1 of 1)

PEACEMAKERTM

OXIDIZING DRY AIR SCRUBBER

SUBMITTALS/O&M INFORMATION FORM

CUSTOMER:

PROJECT NAME:

PROJECT LOCATION

CONTRACTOR:

ENGINEER:

EQUIPMENT SUPPLIER: SYNECO SYSTEMS, INC.80 WEST 76TH STREET, SUITE 133

CHANHASSEN, MN 553171-952-927-9215

FORM NO 550 (Page 1 of 4) © 1994-2009 Syneco Systems, Inc. All Rights Reserved.

03/17/2009

Phone: (952) 927-9215Fax: (952) 927-9224

E-mail: [email protected]: www.synecosystems.com

AN ADVANCEMENT IN ODOR CONTROL TECHNOLOGY PEACEMAKERTM Scrubbers provide a two stage chemistry for the control of odors from hydrogen sulfide (H2S), mercaptans, ammonia, amines and other odors generated in wastewater collection and treatment systems. They are easy to use, effective and economic.

Lift Stations Headworks Grit Rooms Sludge Processing

In what follows, when we say “odor” we mostly mean H2S. We know there are other reduced-sulfur and nitrogen-based compounds involved and we have planned for them, but H2S is the main culprit and is most important in discussion and design.

OUR DESIGN PRINCIPLE… SIMPLICITY “The Best Solution Should be the Simplest, but Not Simpler.” – Albert Einstein Often it is the simplest solution that works the best. Complexity is the enemy of effective, long-term odor control. Too much fussing, too many bells and whistles spell trouble. PEACEMAKERTM scrubbers are fixed-bed systems, containing two layers of media. There is one moving part, a blower. There are no chemicals to add and there is no maintenance to do for the service life of the scrubber. When your PEACEMAKERTM does need attention, the entire scrubber is replaced or the media is replaced, depending upon the size of the scrubber and whether you choose to lease or buy (more on this later). But no matter how simple and easy, odor control solutions must be effective to be worthwhile.


03/17/2009

PEACEMAKERTM SCRUBBERS GET THE JOB DONE STAGE ONE - A Chlorine Dioxide Layer This layer releases chlorine dioxide (ClO2) when contacted by H2S molecules. Reactions are instantaneous, and produce inorganic sulfate. Simply stated, salt drops out. Chlorine dioxide is an extremely powerful oxidizing agent. Because it reacts selectively and primarily only with the most offensive odor- producing compounds, it will remain intact longer than chlorine, sodium hypochlorite, peroxide and potassium permanganate. Since unwanted reactions do not occur, power is not wasted and service life is extended. STAGE TWO - A Polishing Layer This layer uses Countervailant® technology. Malodorous molecules contain one or more chemically reactive groups called osmophores. Polishing reactions with these groups are varied, but are most commonly electrostatic and/or polymeric. The worst odors have the strongest negative charges, which are drawn to the positive charges of the Countervailant® chemistry. The union either facilitates a chemical reaction or creates a large molecule of low vapor pressure. A homo-polymer lattice forms around reacted or absorbed molecules and osmophoric activity ceases. CORROSION CONTROL

IT ISN’T ALWAYS JUST ABOUT ODOR. Corrosion control is a substantial secondary benefit, and in some cases it is primary. H2S accumulates in enclosed spaces. Turbulence releases it to atmosphere, but Henry’s Law is in play, too. It is not unusual to find several hundred ppm of H2S in enclosed spaces. It eventually forms sulfuric acid, a highly corrosive compound. In most cases, H2S cannot simply be exhausted into a neighborhood. But when it is continuously drawn off and scrubbed, corrosion commonly reduces by ninety percent or more, and complaints stay in check. This can save big money on repairs.


03/17/2009

SIZING PEACEMAKERTM SCRUBBERS THERE ARE TWO ESSENTIAL QUESTIONS TO BE ANSWERED. How much airflow is required? Benefits accrue from moving only enough air to maintain a slight negative pressure. This will prevent fugitive malodors and provide the best economics. Higher-than-necessary airflow increases static pressure through the media bed and reduces residence time. A larger scrubber may be needed and cost would increase. To calculate optimum airflow we must determine the potential for air displacement (e.g. gpm pumped into a wet well). Of course, if there is an air exchange requirement for confined space entry or a need for higher airflow for any other reasons, it can be accommodated. How much H2S is in that air? This can be a difficult question to answer. It can be influenced by time of day, time of year, residence time, measuring techniques and numerous additional factors. Truth is it is hard to escape applying some judgment in making this determination. Experience helps, of course, but PEACEMAKERTM systems have built-in flexibility and scalability, which helps, too. Ultimately, the formula is simple: cfm airflow x ppm H2S in the airflow = required oxidation capacity. This is an important process, and we need to work together. We start with a review of Form No. 550-A, “Information Required for Sizing PEACEMAKERTM Oxidizing Scrubbers”. AVAILABLE SIZES When we have determined needed oxidation capacity, we simply match need to the right vessel size and add the right blower to provide desired airflow at the existing static pressure. Small Scrubber Models range in diameter from 17 to 55 inches, in media capacity from 3 to 60 cubic feet and in airflow capacity from 40 to 900 cfm. They are generally leased and exchanged for “new” at the end of a planned service life. Large Scrubber Models are available in diameters of 5, 6, 8 and 10 feet, in media capacity from 70 to 385 cubic feet and in airflow capacity from 1,000 to 9,400 cfm. Large scrubbers are generally purchased and media is changed-out on a predetermined schedule, or when it is spent. Syneco Systems provides spent media disposal service at no charge when it is returned to us freight-paid. Custom Scrubbers are supplied when none of the above fits the need.


03/17/2009

LEASE OR BUY? YOUR CHOICE! Lease The length of “term” for most PEACEMAKERTM leases is one or two years. At the end of term, we provide a new scrubber, if you wish, and you return the old one to us, freight collect. If conditions change from one term to the next, we can change the new scrubber to match the new conditions. You’ll never get stuck with out-grown and useless equipment. And, our lease agreement is like our scrubbers – simple and straightforward.

Buy If your PEACEMAKERTM needs to come from a capital budget, this is obviously the way to go. It will still be a great value. Lease or buy, labor and maintenance costs will be minimal. There just isn’t much to do once the scrubber is up and running besides enjoying the nice clean air and the very quiet phone.

SUPPLEMENTARY INFORMATION FORM NO. 550A -- Information Required for Sizing PEACEMAKERTM Scrubbers 550C -- PEACEMAKERTM Standard Blower Specifications Summary 550E -- PEACEMAKERTM Small Scrubber Standard Models Specifications 550F -- PEACEMAKERTM Large Scrubber Standard Models Specifications 553A -- Installation and Operation Models 300 & 900 553B -- Installation and Operation Models 450 - 6000 553C -- Installation and Operation Large Scrubber Models The same media technology is used in other devices for odor control: FORM NO. 576 -- PEACEMAKERTM Vent Stack Filters Limited Warranty: Our only obligation shall be to replace or pay for any material proved defective. Beyond the purchase price of materials supplied by us, we assume no liability for damages of any kind and the user accepts the product "as is" and without warranties, expressed or implied. The suitability of the product for an intended use shall be solely up to the user.

Syneco Systems, Inc. 80 West 78th Street, Suite 133 Chanhassen, MN 55317

Tele: 952-927-9215Fax: 952-927-9224


FORM NO. 550C

PEACEMAKER™ STANDARD BLOWER SPECIFICATIONS SUMMARY

Blower Model RPM "WC" @ CFM HP CYCLES PHASE AMPS kW HEIGHT"

TOP MOUNTEDAO 70 3200 1.0" @ 60 0.033 60 1 1.3 0.12 8VBL5 2950 1.4" @ 60 0.75 60 1 7.4/3.7 0.72 14.5VBL6 3450 2.8" @ 150 0.33 60 1 7.4/3.7 0.72 15VBW6 2950 3.2" @ 450 0.75 60 1 2.4 0.55 15VBW6 2950 1.7" @ 750 0.75 60 1 2.4 0.55 15VBL9 3400 6.2" @ 900 3.35 60 3 7.4/4.3 1.76 21

FLOOR MOUNTEDGI 20-194 2060 8.2 @ 1500 5.00 60 3 13.4/6.7 3.73 NAGI 20-224 1880 9.0 @ 3000 7.50 60 3 20.4/10.2 5.60 NAGI 20-264 1700 9.0 @ 5000 15.0 60 3 38.4/19.2 11.20 NASWSI 18 3230 11.7 @ 7000 20.0 60 3 48.0/24.0 14.93 NA

Explosion-proof blowers are available in all models except for AO 70. Individual and more detailed information on each blower model listed above can be found in our manuals.

Limited Warranty: Our only obligation shall be to replace or pay for any material proved defective. Beyond the purchase price of materials supplied by us, we assume no liability for damages of any kind and the user accepts the product "as is" and without warranties, expressed or implied. The suitability of the product for an intended use shall be solely up to the user.

© 1994-2009 Syneco Systems, Inc. All Rights Reserved.


Tele: 952-927-9215Fax: 952-927-9224

E-mail: [email protected] FORM NO. 550-EPEACEMAKER® SMALL SCRUBBER MODELS PHYSICAL SPECIFICATIONS SUMMARY

MODELS 300 900 450V 1100V 2000V 3000V 6000VVessels (black HDPE, " thick )

3/16" 1/4" 3/16" 1/4" 1/4" 1/4" 5/16"

Cover (black ABS, " thick)

3/16" 3/16" 3/16" 3/16" 1/4" 1/4" 5/16"

Foul air intake size ( diameter , ")

2 2 4 6 8 12 12

Lower air diffuser (perforated HDPE, " )

NA NA 3/16" 3/16" 3/16" 3/16" 3/16"

Upper air diffuser (perforated HDPE, ")

NA NA NA NA 3/16" 3/16" 3/16"

Stage 1 oxidizing chamber (ft3)

1.5 4.5 2.5 5.5 9.0 15.0 30.0

Stage 2 oxidizing chamber (ft3)

1.0 3.0 1.25 3.5 7.5 10.0 20.0

Stage 3 polishing chamber (ft3)

0.5 1.5 0.75 2 3.5 5.0 10.0

Height (") 44" 58.5" 44" 58.5" 60" 58" 62"For total height, see Blower Specifications Form No. 550-C, for height of recommended blower and add to height of scrubberDiameter (") 17 26-1/4 17 26-1/4 32 44 55

Footprint (poly skid, ")26-1/4"x26-

1/4"37"x37"

26-1/4"x26-1/4"

37"x37" 37"x37" 42"x42" 60"x60"

Nominal Charged Weight (lbs.)

170 550 270 660 1150 1700 3400

Airflow (maximum cfm) 40 60 100 225 375 600 900

Scrubber Size is determined by PPM of H2S and CFM

Storage and Use: Store and use away from acids and reducing agents. Do not add any chemicals to the scrubber other than those recommended by the manufacturer. Individual Specification Sheets are available on each model. Drawings below are representative. See Specifications for actual dimensions. Passive (no fan) units are available, and are used mainly on air relief valves. Syneco Systems reserves the right to change specifications without prior notice. In no case shall such changes have an adverse effect on the performance of the product.

Limited Warranty: Our only obligation shall be to replace or pay for any material proved defective. Beyond the purchase price of materials supplied by us, we assume no liability for damages of any kind and the user accepts the product "as is" and without warranties, expressed or implied. The suitability of the product for an intended use shall be solely up to the user.



Tele: 952-927-9215Fax: 952-927-9224


©2005 Syneco Systems, Inc. All Rights Reserved. FORM NO 551-30 (Page 1 of 1)

FORM NO. 551-30 SPECIFICATIONS PEACEMAKER™ 3000 SERIES SCRUBBERS BLOWER See Form No. 550-C, “PEACEMAKER™ STANDARD BLOWER

SPECIFICATIONS,” for details. PHYSICAL Vessel 1/4" black HDPE Cover 1/4" black ABS Upper Air Diffuser 3/16" perforated HDPE Lower Air Diffuser 3/16" perforated HDPE Polishing Chamber 5 ft3 Oxidizing Chamber 25 ft3 total; Stage 1-15.0 ft3, Stage 2 - 10.0 ft3 Height 58" (without blower) Diameter 44" Nominal Charged Weight 1700 lbs Footprint Steel-reinforced black PE skid (42" x 42") Airflow 600 cfm max. Fittings Scrubber intake - 12" MISCELLANEOUS Storage/Use Remove shipping bag immediately upon receipt.

Store and use away from acids and reducing agents. Do not add any chemicals to the scrubber other than those recommended by the manufacturer.

Syneco Systems reserves the right to change specifications without prior notice. In no case will such changes have an adverse effect on the performance of the product. © 1994-2005 Syneco Systems, Inc. All Rights Reserved. Form No. 551-30


Tele: 952-927-9215Fax: 952-927-9224




Tele: 952-927-9215Fax: 952-927-9224


© 1994 - 2009 Syneco Systems, Inc. All Rights Reserved. FORM NO 554C

FORM NO. 554C

GATE VALVE SIZE 6” 8” 12”

A 3” 3” 3” B 6 5/8” I.D. 8 5/8” I.D. 12 3/4" I.D.


Tele: 952-927-9215Fax: 952-927-9224

E-mail: [email protected] FORM NO. 553B

INSTALLATION & OPERATION OF THE PEACEMAKER™ ODOR CONTROL DRY AIR SCRUBBER (Models 450 thru 6000 Series Scrubbers)

STEP 1. Remove from shipping bag and inspect for damage.

STEP 2. Do not remove the PEACEMAKER™ from the pallet. Place the entire assembly on a firm base.

STEP 3. Remove and save the cap from the foul-air intake. Install air damper if required, and connect into malodor source.

STEP 4. Connect exhaust stack. (If scrubber is in an enclosed building, continue stack through wall or roof.)

STEP 5. Install fan and connect it to the electrical power according to specifications and your local regulations. Switch on.

STEP 6. Remove/save the plug from the condensate line and install a drain line.

DISCONNECT & RETURNSTEP 1. Disconnect the power supply.STEP 2. Disconnect the PVC pipes leading to the scrubber and reinstall the intake cap and condensate

plug that were removed during installation.STEP 3. To arrange for pick-up, call Syneco Systems, Inc. at 1-800-442-7575. © 1994-2009 Syneco Systems, Inc. All Rights Reserved. 4/24/2009


Tele: 952-927-9215Fax: 952-927-9224

E-mail: [email protected] FORM NO. 502

PERSNICKETY® BRAND OX-PELLETSTM OXIDIZING/POLISHING MEDIA FOR MALODOR CONTROL

PATENTED, BREAKTHROUGH CHEMISTRY PERSNICKETY® OX PELLETS™ provide demand dependent oxidizing properties and sustained release polishing properties, simultaneously. The result is safe, extremely effective, broad-spectrum malodor control. Each technology has a critical role to play.

Oxidizing - Chlorine Dioxide Technology Chlorine dioxide (ClO2)is an extremely powerful oxidizing agent. For example, one pound of chlorine

dioxide is equivalent in oxidation power to 3.8 pounds of potassium permanganate. Because chlorine dioxide reacts selectively and primarily with only the most offensive odor producing compounds (hydrogen sulfide [H2S], organic sulfurs, organic amines, petroleum distilates), PERSNICKETY® OX PELLETS™ will

normally provide a much longer service life than competitive products such as activated carbon. Similarly, chlorine dioxide will remain intact longer than chlorine, hypochlorite, peroxide and permanganate. Unwanted reactions do not occur. Power is not needlessly spent. Chlorine dioxide remains available and ready on demand.

In contrast to chlorine and hypochlorite, chlorine dioxide does not react with ammonia and is not a chlorinating agent. It typically reacts with organics as an oxidant with no Trihalomethanes (THMs) or chlorinated by-products formed. Hydrogen sulfide is rapidly oxidized to inorganic sulfate; whereas organic sulfides react with chlorine dioxide to form sulfonyl compounds and oxygen containing by-products, thus effectively eliminating many odors. When sufficient chlorine dioxide is used to fully oxidize phenol, the primary products are converted to respective carboxylic acids. Primary and secondary amines react very slowly or not at all with chlorine dioxide, whereas chlorine dioxide will rapidly oxidize tertiary amines producing a secondary amine and an aldehyde. Chlorine dioxide has relatively low oxidizing activity toward olefins. Alcohols and carboxyl compounds react more slowly to produce carboxylic acids. The breaking of carbon - carbon bonds is generally not extensive in most reactions.

Polishing - Countervailant™ Technology This technology protects against the escape of malodors which can not be oxidized or readily oxidized. It functions synergistically with the technology to which it is wed. Countervailant™ technology is highly specialized, complex and broadly useful chemistry. It incorporates neutralization technology, but expands considerably beyond it. Polymeric adsorption is a facet. This involves the building up of malodor molecules via electrostatic attractions and Van der Waals forces so that they are not recognized as malodors. The process of esterification is also incorporated. Acids and alcohols react to form esters. These esters normally have a pleasant scent. Countervailant™ technology is effective in dealing with malodors in both liquid and gaseous phases.

NOTE: For more detailed information on the chemistry of PERSNICKETY® OX PELLETS™, see Form No. 151, Odor Perception • Qualities • Chemical Control Methods. PERSNICKETY® OX PELLETS™ are available as follows: 1) oxidizing only, 2) oxidizing and Countervailant™ combination, 3) Countervailant™ only. TYPICAL APPLICATIONS

PEACEMAKER™ scrubbers vented tanks (sludge, EQ) PEACEMAKER™ manhole inserts replacement for activated carbon roof vents

replacement for potassium permanganate landfill vents and any other compound in dry scrubbers

HEALTH, SAFETY AND DISPOSAL Care must be taken not to create even larger, more serious problems in the pursuit of malodor solutions. Many products in commercial use are toxic, create toxic by-products; are explosive, flammable, corrosive, damaging to the air, plants and animals and difficult to dispose of. Disposal is not a problem with PERSNICKETY® OX PELLETS™. We will do it for you. Simply retain the original shipping containers. When the product is spent, reload them and return them to us, freight pre-paid. We will recycle or dispose of, as necessary.

All chemical products should be handled with care (review PERSNICKETY® OX PELLETS™ MSDS).

Here are a few key points of interest concerning chlorine dioxide: Chlorine dioxide is approved by the EPA for use as a primary disinfectant in drinking water. It has shown no adverse effects to human health after several decades of use. The proprietary chlorine dioxide in PERSNICKETY® OX PELLETS™ and its precursors are EPA, FDA and USDA approved for sanitation uses in food and dairy plants. Does not react with water to form hypochlorus and hydrochloric acid, as does chlorine gas.

The Countervailant™ portion of PERSNICKETY® OX PELLETS™:Contains only those raw materials listed in the EPA TSCA Chemical Substances Inventory and in the European Economic Community Inventory of Chemical Substances. Is non-explosive and non-flammable. Contains only non-reactive, stable materials.

WARNING: DO NOT ADD ACIDS OR ANY CHEMICALS TO PERSNICKETY® OX PELLETS™ OTHER THAN THOSE RECOMMENDED BY THE MANUFACTURER. THERE IS POTENTIAL FOR DANGEROUS REACTIONS WITH ClO2.

PHYSICAL DATAAppearance Tan granulesMesh -3, +5 TaylorWeight 50 lbs. ft3, on averageOdor Slight chlorine dioxidePackaging 3-1/2 g. (approx. 25 lbs., 0.5 cu. ft.), 30 g. (approx. 200 lbs., 4.0 cu. ft.)Shelf Life One Year in unopened containerStorage Store in a cool dry, well ventilated place away from acids Limited Warranty: Our only obligation shall be to replace or pay for any material proved defective. Beyond the purchase price of materials supplied by us, we assume no liability for damages of any kind and the user accepts the product "as is" and without warranties, expressed or implied. The suitability of the product for an intended use shall be solely up to the user. © 1994-2009 Syneco Systems, Inc. All Rights Reserved.


Tele: 952-927-9215Fax: 952-927-9224

E-mail: [email protected] FORM NO. 502A-MSDS

MATERIAL SAFETY & DATA SHEET PERSNICKETY® BRAND OXIDIZING MEDIA FOR MALODOR CONTROL

HAZARDS IDENTIFICATION Hazard Summary: Sand-colored, granular solid with chlorine-like odor. This product contains corrosive material absorbed onto an absorbent material. If soaked in water, the resulting solution may be corrosive to the skin and eyes on contact. Do not mix with organic material or acids as an explosion could result. Potential Health Effects: Eyes: May be corrosive. Skin: May be corrosive to skin. Ingestion: Harmful if swallowed. Can irritate the nose and throat. Inhalation: May be irritating to eyes and respiratory tract.

FIRST AID MEASURES Eyes: Immediately wash eyes with water for at least 15 minutes. Lift upper and lower lids and rinse well under them. Get immediate medical attention. Skin: Wash off in flowing water or shower. If irritation persists, get medical attention. Ingestion: Do not induce vomiting. Do not give anything by mouth to an unconscious person. Immediately drink large quantities of water or milk. Get medical attention. Inhalation: Remove from exposure. If individual is not breathing, administer cardiopulmonary resuscitation (CPR) and get immediate medical attention. If individual is breathing, but with difficulty, get medical attention.

FIRE FIGHTING MEASURES Flammable Properties: This product is non-flammable. Flash Point: None. Method Used: Not applicable. Flammable Limits: Not applicable. Product is not flammable. Extinguishing Media: Water fog. No dry chemical, CO2 or halon. Fire & Explosion Hazards: Although this product is not combustible, soaking it in water and allowing it to evaporate can leave a residue that is an oxidizer. Solutions can react with acids and organic material to liberate chlorine dioxide, which is an explosion hazard. Fire Fighting Equipment: Wear full bunker gear including a positive pressure self-contained breathing apparatus.

ACCIDENTAL RELEASE MEASURES Scoop up spilled dry material and place in an appropriate container for disposal. If the material is wet, the spill area must be rinsed thoroughly, as a corrosive residue may remain. Do not allow spilled wet material to evaporate to dryness.

PRODUCT INFORMATIONTrade Name: Persnickety® Brand MediaName and/or Family Description: Oxidizing Media for Odor ControlEmergency Phone: (800) 424-9300 (CHEMTREC)The following information relates to safety conditions when media is in loose form and not enclosed within PEACEMAKER™ vessels. COMPOSITION (OSHA HAZARDOUS INGREDIENTS)

The specific identities of certain components of this formulation are withheld as trade secrets in accordance with 29 CFR 1910.1200.

COMPONENTS WT%Component A 54.2Component B 11.5

HANDLING AND STORAGE Store in a cool, dry place. Do not allow material to get wet, as a corrosive solution may result. Store separately from acids, reducing agents, organic material such as solvents, fuel, wood (i.e., pallets) and paper. Do not store in steel drums. After handling, wash hands with soap and water.

EXPOSURE CONTROL/PERSONAL PROTECTION Respiratory Protection: If dust appears in handling operations, wear a NIOSH approved respirator with replaceable dust filters. Skin Protection: Gloves are not normally necessary unless handling this material when wet. If wet, wear impervious gloves. Eye Protection: If dust appears in handling operations, wear goggles or safety glasses. Exposure Guidelines: PEL/TLV have not been established for the product as a whole.

Engineering Controls: Use with adequate ventilation. Local exhaust ventilation may be necessary for operations in which dust is generated.

PHYSICAL AND CHEMICAL PROPERTIES Appearance: Sand-colored granular solid Odor: Chlorine-like odor/minty Boiling Point: Not applicable Solubility in Water: Insoluble Specific Gravity: 6.55 lbs/gal (bulk density) Freezing Point: Not applicable pH: Not applicable % Volatile: 34.3%

STABILITY AND REACTIVITY Stability: (CONDITIONS TO AVOID) stable. Incompatibility: (SPECIFIC MATERIALS TO AVOID) organic combustible materials, decomposed acids, exposure to direct sunlight. Hazardous Decomposition Products: Chlorine dioxide and chlorine.

TOXICOLOGICAL INFORMATION Toxicological data is not available for the product as a whole. The following information is provided for Component B. LD50 (oral) Rats: 165 mg/kg

Toxic Effects: Liver - Jaundice, other or unclassified: Kidney, ureter, and bladder - interstitial nephritis; biochemical. LD50 (oral) Mouse: 350 mg/kg

LD50 (oral) Guinea Pig: 300 mg/kg

DISPOSAL CONSIDERATIONS Water Management Information (Disposal): Any disposal practice must be in compliance with local, state and federal laws and regulations (contact local or state environmental agency for specific rules).

TRANSPORT INFORMATION Transportation And Hazardous Materials Description: DOT SHIPPING NAME: Corrosive solid UN ID NO: 1759

COMPONENT OSHA PEL/TWA AGGIH TLV/TWACrystalline silica (Cristobalite) 0.05 mg/m 3 (as respirable dust) 0.05 mg/m 3

Crystalline silica (Quartz) 0.1 mg/m 3 (as respirable dust) 0.1 mg/m 3

Hazard Class: 8 (Corrosive); II REGULATORY INFORMATION OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200: According to the OSHA Hazard Communications standard, this product is considered hazardous because it contains Component B and trace amounts of crystalline silica. CERCLA/SUPERFUND, 40 CFR 117.302: This compound contains NO compounds subject to 40 CFR 117.302.

SARA 313 INFORMATION: This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning Community Right-To-Know Act of 1986 and of 40 CFR 372: None.

TOXIC SUBSTANCES CONTROL ACT (TSCA): The ingredients of this product are all on the TSCA Inventory list.

CALIFORNIA PROPOSITION 65: The following statement is made in order to comply with the California Safe Drinking Water and Toxic Enforcement Act of 1986: “Notice: This product contains a chemical known to the State of California to cause cancer, birth defects, or other reproductive harm.” [22 CCR 12705 (b)]. This product contains crystalline silica. OTHER INFORMATION

NFPA RATING HMIS RATINGFire 0 Health 2

Health 2 Flammability 0Reactivity 2 Reactivity 2

Hazard OX, Corrosive Protection A

Limited Warranty: Our only obligation shall be to replace or pay for any material proved defective. Beyond the purchase price of materials supplied by us, we assume no liability for damages of any kind and the user accepts the product "as is" and without warranties, expressed or implied. The suitability of the product for an intended use shall be solely up to the user. © 1994-2009 Syneco Systems, Inc. All Rights Reserved.


Tele: 952-927-9215Fax: 952-927-9224


FORM NO. 502B-MSDS

MATERIAL SAFETY & DATA SHEET PERSNICKETY® BRAND OX-PELLETSTM OXIDIZING/POLISHING MEDIA FOR MALODOR CONTROL

PRODUCT INFORMATION Trade Name: Persnickety® Brand Oxidizing Media Name and/or Family Description: Oxidizing media for malodor control Emergency Phone: (800) 424-9300 (CHEMTREC) The following information relates to safety conditions when media is in loose form and not enclosed within PeacemakerTM vessels.

COMPOSITION (OSHA Hazardous Ingredients) The specific identities of certain components of this formulation are withheld as trade secrets in accordance with 29 CFR 1910.1200.

COMPONENTS WT% Component A 54.2 Component B 11.5

HAZARDS IDENTIFICATION Hazard Summary:

Sand-colored, granular solid with chlorine-like odor. This product contains corrosive material absorbed onto an absorbent material. If soaked in water, the resulting solution may be corrosive to the skin and eyes on contact. Do not mix with organic material or acids as an explosion could result.

POTENTIAL HEALTH EFFECTS Eyes: May be corrosive. Skin: May be corrosive to skin. Ingestion: Harmful if swallowed. Can irritate the nose and throat. Inhalation: May be irritating to eyes and respiratory tract. FIRST AID MEASURES Eyes: Immediately wash eyes with water for at least 15 minutes. Lift upper and lower lids and

rinse well under them. Get immediate medical attention.Skin: Wash off in flowing water or shower. If irritation persists, get medical attention.Ingestion: Remove from exposure. If individual is not breathing, administer cardiopulmonary

resuscitation (CPR) and get immediate medical attention. If individual is breathing, but with difficulty, get medical attention.

Inhalation: Do not induce vomiting. Do not give anything by mouth to an unconscious person. Immediately drink large quantities of water or milk. Get medical attention.

FIRE FIGHTING MEASURES Flammable Properties: This product is non-flammable. Flash Point: None. Method Used: NA Flammable Limits: NA Extinguishing Media: Water fog. No dry chemical, CO2 or halon.

Fire & Explosion Hazards:

Although this product is not combustible, soaking it in water and allowing it to evaporate can leave a residue that is an oxidizer. Solutions can react with acids and organic material to liberate chlorine dioxide, which is an explosion hazard.

Fire Fighting Equipment:

Wear full bunker gear including a positive pressure self-contained breathing apparatus.

ACCIDENTAL RELEASE MEASURES Scoop up spilled dry material and place in an appropriate container for disposal. If the material is wet, the spill area must be rinsed thoroughly, as a corrosive residue may remain. Do not allow spilled wet material to evaporate to dryness. HANDLING AND STORAGE Store in a cool, dry place. Do not allow material to get wet, as a corrosive solution may result. Store separately from acids, reducing agents, organic material such as solvents, fuel, wood (i.e., pallets) and paper. Do not store in steel drums. After handling, wash hands with soap and water. EXPOSURE CONTROL/PERSONAL PROTECTION Respiratory Protection:

If dust appears in handling operations, wear a NIOSH approved respirator with replaceable dust filters.

Skin Protection: Gloves are not normally necessary unless handling this material when wet. If wet, wear impervious gloves.

Eye Protection: If dust appears in handling operations, wear goggles or safety glasses. Exposure Guidelines:

PEL/TLV have not been established for the product as a whole.

COMPONENT OSHA PEL/TWA ACGIH TLV/TWA

Crystalline silica (Cristobalite) 0.05 mg/m 3 (as respirable dust) 0.05 mg/m 3 Crystalline silica (Quartz) 0.1 mg/m 3 (as respirable dust) 0.1 mg/m 3 ENGINEERING CONTROLS Use with adequate ventilation. Local exhaust ventilation may be necessary for operations in which dust is generated. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Sand-colored granular solid. Odor: Chlorine-like odor/minty. Boiling Point: NA Solubility in Water:

Insoluble

Specific Gravity:

6.55 lbs/gal (bulk density)

Freezing Point:

NA

pH: NA % Volatile: 34.3%

STABILITY AND REACTIVITY Stability: (CONDITIONS TO AVOID) stable.Incompatibility: (SPECIFIC MATERIALS TO AVOID) organic combustible materials,

decomposed acids, exposure to direct sunlight.Hazardous Decomposition Products:

Chlorine dioxide and chlorine.

TOXICOLOGICAL INFORMATION Toxicological data is not available for the product as a whole. The following information is provided for Component B.LD 50 (oral) Rats: 165 mg/kgToxic Effects: Liver - Jaundice, other or unclassified: Kidney, ureter, and bladder - interstitial

nephritis; biochemical.

LD 50 (oral) Mouse:

350 mg/kg

LD 50 (oral) Guinea Pig:

300 mg/kg

DISPOSAL CONSIDERATIONS Waste Management Information (Disposal):

Any disposal practice must be in compliance with local, state and federal laws and regulations (contact local or state environmental agency for specific rules).

TRANSPORT INFORMATION Transportation & Hazardous Materials Description:

DOT Shipping Name: Corrosive solidUN ID NO: 1759Hazard Class: 8 (Corrosive); II REGULATORY INFORMATION OSHA Hazard Communication Rule, 29 CFR 1910.1200:

According to the OSHA Hazard Communications standard, this product is considered hazardous because it contains Component B and trace amounts of crystalline silica.

CERCLA/SUPERFUND, 40 CFR 117.302:

This compound contains NO compounds subject to 40 CFR 117.302.

SARA 313 Information: This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning Community Right-To-Know Act of 1986 and of 40 CFR 372: None.

Toxic Substances Control Act (TSCA):

The ingredients of this product are all on the TSCA Inventory list.

California Proposition 65:

The following statement is made in order to comply with the California Safe Drinking Water and Toxic Enforcement Act of 1986: “Notice: This product contains a chemical known to the State of California to cause cancer, birth defects, or other reproductive harm.” [22 CCR 12705 (b)]. This product contains crystalline silica.

OTHER INFORMATION

NFPA RATING HMIS RATING Fire 0 Health 2 Health 2 Flammability 0 Reactivity 2 Reactivity 2 Hazard OX, Corrosive Protection A Limited Warranty: Our only obligation shall be to replace or pay for any material proved defective. Beyond the purchase price of materials supplied by us, we assume no liability for damages of any kind and the user accepts the product "as is" and without warranties, expressed or implied. The suitability of the product for an intended use shall be solely up to the user. © 1994-2009 Syneco Systems, Inc. All Rights Reserved.

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