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    Passive cooling of outdoor urban spaces. The role of materials

    L. Doulos, M. Santamouris   *, I. Livada

    Group Building Environmental Studies, Section Applied Physics, Physics Department, University of Athens, Panepistimioupolis,

    Athens 157 84, Greece

    Received 18 September 2003; received in revised form 22 January 2004; accepted 27 January 2004

    Available online 4 May 2004

    Communicated by: Associate Editor Volker Wittwer

    Abstract

    This paper presents the results of a comparative study aiming to investigate the suitability of materials used in

    outdoor urban spaces in order to contribute to lower ambient temperatures and fight heat island effect. The study

    involved in total 93 commonly used pavement materials outdoors and was performed during the whole summer period

    of 2001. The thermal performance of the materials was measured in detail using mainly infrared thermography pro-

    cedures.

    The collected data have been extensively analysed using statistical techniques. Comparative studies have been

    performed in order to identify the major advantages and disadvantages of the materials studied. Materials have been

    classified according to their thermal performance and physical properties into ‘cool’ and ‘warm’ materials. The impact

    of color, surface roughness and sizing has been analysed as well.

    The study can contribute to selection of more appropriate materials for outdoor urban applications, and thus assist

    to fight the heat island effect, decrease the electricity consumption of buildings and improve outdoor thermal comfortconditions.

     2004 Elsevier Ltd. All rights reserved.

    Keywords: Passive cooling; Pavement materials; Outdoor comfort

    1. Introduction

    The continuously growing size of the urban envi-

    ronment and the careless development of buildings and

    open spaces have a major impact on the urban micro-climate. The building’s energy behavior and perfor-

    mance are heavily influenced by the density of the

    building space. The observed ‘heat island’ effect is

    mainly influenced by urban design, namely the canyon

    radiative geometry, anthropogenic heat and the mate-

    rial’s street physical properties (Santamouris, 2001; Oke

    et al., 1991). The emitted infrared radiation from the

    various buildings and street surfaces impinges on the

    surroundings surfaces and is entrapped inside the can-

    yon. Besides, the total amount of the absorbed solar

    radiation is increased due to multiple reflections between

    the buildings (Santamouris and Assimakopoulos, 1997).Also the anthropogenic heat increases the intensity of 

    the ‘heat island’ effect through the use of fuels from ei-

    ther mobile or stationary sources. Finally the incident

    solar radiation and every available heat form can in-

    crease the storage of sensible heat in the city’s structure

    during the daytime. The stored heat is released into the

    urban atmosphere during the night period. Therefore

    the total amount of the energy balance is increased and

    air temperatures become greater (Santamouris et al.,

    1998).

    A more positive thermal balance can be achieved by

    reducing the thermal gains in the urban environment

    * Corresponding author. Tel.: +30-1-727-6934; fax: +30-1-

    729-5282/81.

    E-mail address:   [email protected] (M. Santamouris).

    0038-092X/$ - see front matter     2004 Elsevier Ltd. All rights reserved.

    doi:10.1016/j.solener.2004.04.005

    Solar Energy 77 (2004) 231–249

    www.elsevier.com/locate/solener

    http://mail%20to:%[email protected]/http://mail%20to:%[email protected]/

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    and in particular by reduction of the absorbed solar

    radiation. The role of building materials is decisive for

    the reduction of the thermal gains and overheating. The

    thermal performance of the building materials is mainly

    determined by their optical and thermal characteristics;

    the albedo to solar radiation and the emissivity to long

    wave radiation are the most significant factors. The useof appropriate materials, the so-called ‘‘cold’’ materials,

    can improve thermal comfort conditions during the

    summer period. They are characterized by a high

    reflectivity factor to the short wave radiation and high

    emissivity factor to the long wave radiation. They reduce

    the amount of solar radiation absorbed by the building

    envelopes and urban structures and keep their surfaces

    cooler. Respectively, they are good emitters of long wave

    radiation and release the energy that has been absorbed

    as short wave radiation. Using ‘‘cold’’ materials in urban

    environmental planning contributes to lower surface

    temperatures that affect the thermal exchanges with theair (Akbari et al., 1992, 1997; Bretz and Akbari, 1997).

    In this paper, the surface temperature distribution of 

    the total number of 93 selected materials is presented. A

    theoretical analysis is followed aiming at the investiga-

    tion of the thermal performance of the selected building

    materials. Also, a methodology for their classification in

    ‘cold’ materials is been developed. An experimental

    campaign was set up at an open space at the National

    and Kapodistrian University campus in Athens, during

    August 2001. For the theoretical analysis the selected

    materials were grouped according to their construction

    material, their surface texture and surface color (Table

    1). The measurements were obtained through infrared

    (IR) thermograph imaging.

    2. Materials for pavements and their role in the thermal

    balance of the urban environment

    The use of appropriate materials to reduce heat is-

    land and improve the thermal characteristics of the ur-

    ban environment has gained increasing interest during

    recent years. Many research works have been carried out

    to evaluate the possible energy and environmental ben-

    efits when light colored surfaces are used. Research triesto investigate the impact of the materials optical and

    thermal characteristics on the urban temperature as well

    as the possible energy conservation during the summer

    period. A detailed guide on light colored surfaces has

    been published by US EPA (Akbari et al., 1992). Re-

    search shows that important energy gains are possible

    when light color surfaces are used in combination with

    the plant of new trees.

    The use of materials define the global albedo of the

    cities. Typical albedo of European and American cities

    are close to 0.15–0.30. Much higher albedo have been

    measured in some North African cities (0.45–0.6). Taha

    (1997) has compiled data given by (Taha, 1994; Kung

    et al., 1964; Dabberdt and Davis, 1978; Vukovich, 1983;

    Brest, 1987; Coppin et al., 1978; Rouse and Bello, 1979;

    Mayer and Noack, 1980; Steyn and Oke, 1980; Aida,

    1982; Oguntoyinbo, 1970, 1986) for snow free urban

    albedos for several cities and has published the difference

    between the urban and rural albedo. Cantat (1989) hasestimated the albedo of various types of surfaces as well

    as their temperature in the major Paris area, It is found

    that urban areas have a much lower albedo while the

    albedo in Paris is to about 16% lower than in the sur-

    rounding rural areas.

    Various studies have been performed to understand

    better the thermal and optical performance of materials

    used for pavements and their impact to the city climate.

    Lower surface temperatures contribute to decrease the

    temperature of the ambient air as heat convection

    intensity from a cooler surface is lower. Such tempera-

    ture reductions can have significant impacts on coolingenergy consumption in urban areas, a fact of particular

    importance in hot climate cities.

    Yap (1975) has reported that systematic urban–rural

    differences of surface emissivity hold the potential to

    cause a portion of the heat island. Robinette (Santa-

    mouris, 2001) reports relative temperatures of 38   C

    over grass, 61  C, over asphalt, and 73  C over artificial

    turf. Santamouris (2001) reports asphalt temperatures

    close to 63   C and white pavements close to 45   C.

    Oke et al. (1991) have simulated the effect of the

    optical and thermal characteristics of ‘urban’ materials

    to the heat island intensity during the night period. They

    report that the role of emissivity is minor. As the emis-

    sivity increased from 0.85 to 1.0 there was a slight in-

    crease of 0.4   C of   DT   between the urban and rural

    environment for very tight canyons, where there was

    almost no change for higher view factors. On the con-

    trary, the effect of the thermal properties of the materials

    was found to be much more important. For a flat land, it

    is found that if the urban admittance was 2200 J/m 2/K,

    and the rural one was 800 units lower a heat island

    of about 2   C was developed during the night period,

    while when the urban admittance was decreased to 600

    J/m2/K, a cool island of over 4   C was formed during

    night.In an other study, Asaeda et al. (1996) have reported

    the experimental results of a study where the impact of 

    various pavement materials used commonly in urban

    environments were tested during the summer period.

    They found that the surface temperature, heat storage

    and its subsequent emission to the atmosphere were

    significantly higher for asphalt than for concrete and

    bare soil. At the maximum, asphalt pavement emitted an

    additional 150 W per square meter in infrared radiation

    and 200 W per square meter in sensible transport com-

    pared to a bare soil surface. They also found that the

    rate of infrared absorption by the lower atmosphere

    232   L. Doulos et al. / Solar Energy 77 (2004) 231–249

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    over asphalt pavement was greater by 60 W/m2 than that

    over the soil surface or concrete pavement. Gustavsson

    and Bogren (1991) measured the influence of road con-

    struction on road surface temperature. On a test road,

    they had found a nocturnal maximum difference of 1.5

    C between beds consisting of blast furnace slag and

    those consisting of gravel.

    Berg and Quinn (1978) reported that in mid-summer

    white painted roads with an albedo close to 0.55 have

    almost the same temperature with the ambient envi-

    Table 1

    Description of the studied materials (Bl stands for black, Bli for black inlays, Br for brown, Gn for green, Gr for gray, R for red, Wh

    for white, Whi for white inlays)

    Material

    number

    Construction

    material

    Surface color Surface

    texture

    Material

    number

    Construction

    material

    Surface color Surface

    texture

    1 Mosaic Green Smooth 48 Concrete Bl–Whi Smooth

    2 Mosaic Wh–Bl Smooth 49 Concrete Wh–Bli Smooth

    3 Mosaic Light–Br Smooth 50 Concrete Black Rough

    4 Mosaic Gray Smooth 51 Concrete Black Smooth

    5 Mosaic White Smooth 52 Concrete Red Rough

    6 Mosaic Brown Smooth 53 Concrete Red Smooth

    7 Mosaic Red Smooth 54 Concrete Red–Whi Smooth

    8 Mosaic Black Smooth 55 Concrete Red–Bli Smooth

    9 Concretea Red Smooth 56 Pebble Green Rough

    10 Concretea Black Smooth 57 Pebble Dark–Gr Rough

    11 Granite Red Smooth 58 Pebble Gray Rough

    12 Granite Black Smooth 59 Pebble Light–Gr Rough

    13 Concretea Orange Smooth 60 Asphalt Black Rough

    14 Concretea Brown Smooth 61 Concrete White Rough

    15 Concretea

    Gray Smooth 62 Concrete White Rough16 Concretea Gray Rough 63 Concrete White Smooth

    17 Concretea White Smooth 64 Concrete Wh–Whi Smooth

    18 Concretea White Rough 65 Concrete Or–Whi Smooth

    19 Granite White Smooth 66 Concrete Orange Rough

    20 Granite Wh–Bl Smooth 67 Concrete Orange Rough

    21 Granite Green Smooth 68 Concrete Or–Whi Smooth

    22 Granite Wh–Gn Smooth 69 Concrete Green Rough

    23 Marble White Smooth 70 Concrete Orange Rough

    24 Marble Wh–Bl–R Rough 71 Concrete Dark–Gn Rough

    25 Marble Wh–Bl Smooth 72 Concrete Green Smooth

    26 Marble Wh–Bl Rough 73 Pebble Gr–Wh Rough

    27 Marble White Smooth 74 Concrete Wh–Blue Smooth

    28 Marble White Rough 75 Pebble Wh–Gn–R Rough

    29 Marble Wh–Bl Smooth 76 Pebble White Rough30 Marble White Smooth 77 Pave stone Red Rough

    31 Marble White Smooth 78 Pave stone Gray Rough

    32 Marble Pink Smooth 79 Pave stone Brown Rough

    33 Marble Light–Br Smooth 80 Stone Black Rough

    34 Marble Red Smooth 81 Stone Brown Rough

    35 Marble Wh–Bl Smooth 82 Stone Gray Rough

    36 Marble Dark–Gr Smooth 83 Stone Green Rough

    37 Marble Gray Smooth 84 Stone Black Rough

    38 Pebble Brown Rough 85 Stone Brown Rough

    39 Pebble Light–Br Rough 86 Stone Brown Rough

    40 Pebble Bl–Br Rough 87 Stone Green Rough

    41 Pebble Light–Br Rough 88 Stone Brown Rough

    42 Pebble Red Rough 89 Stone Brown Rough

    43 Pebble Wh–Br Rough 90 Stone Brown Rough

    44 Concrete Gray Smooth 91 Stone Brown Rough

    45 Concrete Gray Rough 92 Stone Red Rough

    46 Concrete Gray Rough 93 Stone Red Rough

    47 Concrete Gray–Whi Smooth

    a The size of the material tile is 30 cm · 30 cm.

    L. Doulos et al. / Solar Energy 77 (2004) 231–249   233

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    ronment, while unpainted roads with albedo close to

    0.15 were approximately 11   C warmer than the air.

    Taha et al. (1992) have measured the albedo and

    surface temperatures of a variety of materials used in

    urban structures. They found that white elastomeric

    coatings having an albedo of 0.72 were 45  C, than black

    coatings with an albedo of 0.08. They also report that awhite surface with an albedo of 0.61 was only 5   C

    warmer than ambient air whereas conventional gravel

    with an albedo of 0.09 was 30   C warmer than the air.

    3. Implementation of the experimental measurements

    3.1. Instrumentation and description of the experimental 

    site

    The basic experimental equipment used for the

    implementation of the measurements consists of aninfrared camera to measure surface temperatures.

    Measurements were also performed by using a precise

    contact thermometer in order to take into account

    minor errors associated with reflected infrared radiation

    and the non-complete knowledge of the material’s

    emissivity.

    The surface temperature measurements were taken

    on an hourly basis from 9:00 to 18:00 (local time). The

    ambient meteorological conditions, recorded from ameteorological station at the university campus, were

    characterized by high air temperatures, low relative

    humidity (Figs. 1 and 2) and clear sky. Wind speed and

    direction were also measured. Wind speed was always

    low during the experimental period (

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    pebble and mosaic) of different surface color materials

    (white, gray, black, red, brown and green) and of dif-

    ferent surface texture materials (with smooth surfaces,

    rough surfaces and anaglyph surfaces with marks and

    designs). The tiles had a size of 40 cm · 40 cm. In order

    to compare the thermal performance of material tiles

    made of the same construction material, surface colorand texture but different size, a number of some extra

    concrete tiles sized 30 cm· 30 cm were studied. The

    sampling tiles were placed on an especially modulated

    platform covering a surface of 40 m2 (Fig. 3). The

    platform was horizontal and insulated from below. The

    heat transfer effects between the platform and the sam-

    ple materials were eliminated because of the platform’s

    insulation.

    3.2. Thermograph imaging method 

    The surface temperatures of the sample materialswere measured with an IR camera, that is an infrared

    condition monitoring system (AGEMA Thermovision

    570, 7.5–13   lm wavelength). The IR-camera measures

    and images the emitted infrared radiation from an object

    (Fig. 4). The fact that radiation is a function of the

    object’s corresponding surface temperature (Planck’s

    law equation (1)) makes it possible for the thermal

    camera to calculate and display this temperature(Gaussorgues, 1994; Thermovision, 1997). The mea-

    sured infrared radiation is also function of the object’s

    emissivity.

    Q ¼   erT 4 ð1Þ

    Q is the object’s long wave radiated energy (W/m2),   e  is

    the object’s emissivity that is a function of wavelength,

    the direction of observation relative to the surface

    and the surface temperature (Gaussorgues, 1994),   r   is

    the Stefan–Boltzmann’s constant (5.67 · 108 W/m2/K4)

    and T  is the object’s surface temperature (K) (Wolfe and

    Zissis, 1997).

    In the present study, the emissivity values given by

    Gaussorgues (1994) and Wolfe and Zissis (1997) have

    been used during the experimental procedure. The

    emissivity of most of the materials has been also mea-

    sured using hot plate techniques and no significant dif-

    ferences have been found. In practice, the emissivity

    values for the total number of the studied materials were

    close to 0.9. (Fig. 5).

    4. An analysis for the study of the thermal performance of 

    the tested materials

    Due to lack of uniformity in the surface temperature

    distribution at same studied materials, the measured

    surface temperatures correspond to the average tem-

    perature values of the total horizontal surface. The IR

    monitoring system estimated these values automatically.Fig. 3. The site of the experimental campaign with the modu-

    lated platform.

    Fig. 4. Visible and infrared image of selected building materials.

    L. Doulos et al. / Solar Energy 77 (2004) 231–249   235

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    The most important reasons for the existence of non-

    uniform surface temperature distribution are the color

    contrast, the surface roughness and the tile’s heat

    transfer effects (Fig. 6).

    The estimated mean hourly surface temperature val-

    ues for each material tile are given in Table 2 and in

    statistical box plots (Figs. 7–20). Table 2 gives the mean

    daily, the absolute maximum and the absolute minimum

    surface temperatures for every material tile within 9:00

    to 18:00. The box plots (Figs. 7–20) show the mean daily

    surface temperature and the mean daily temperature

    range of the material tiles. They are presented separately

    Fig. 5. Radiation contributions to the general measurement situation.

    Fig. 6. Same examples of material tiles characterized by non-uniform surface temperature distribution due to color contrast

    (a), roughness (b) and heat transfer phenomena (the arrows shows the direction of the incident solar radiation) (c).

    236   L. Doulos et al. / Solar Energy 77 (2004) 231–249

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    for the total number of the materials according to their

    construction material (Figs. 7–14) and their surface

    color (Figs. 15–20). The lower and upper lines of the box

    plots are the minimum and the maximum values of the

    corresponding mean hourly surface temperature values.

    The line inside the box is the average surface tempera-

    ture value. The materials with the smallest average sur-

    face temperature are presented at the left part of each

    graph, while the warmest materials are presented at the

    right part. Because of the large number of the studied

    Table 2

    Mean daily and absolute maximum surface temperatures during the experimental period of August 2001 within 9:00 to 18:00

    Material

    number

    Mean daily

    surface tem-

    perature (C)

    Absolute

    maximum

    surface

    temperature

    Absolute

    minimum

    surface

    temperature

    Material

    number

    Mean daily

    surface tem-

    perature (C)

    Absolute

    maximum

    surface

    temperature

    Absolute

    minimum

    surface

    temperature

    1 34.8 39.5 23.9 48 41.8 48.1 27.2

    2 35.5 40.6 23.7 49 35.2 40.3 23.1

    3 35.5 40.7 23.6 50 43.7 50.4 28.9

    4 37.5 43.3 24.7 51 44.4 52.0 27.6

    5 33.3 37.7 22.2 52 39.9 45.9 26.1

    6 36.9 42.5 23.7 53 39.1 45.5 24.8

    7 38.5 44.8 24.9 54 37.9 43.7 24.6

    8 42.1 49.6 26.1 55 41.1 48.2 25.5

    9 37.8 43.8 24.6 56 44.0 50.9 28.9

    10 44.0 51.6 27.5 57 45.2 52.7 28.5

    11 40.1 46.6 26.7 58 40.6 46.9 26.8

    12 43.9 51.7 27.9 59 40.1 46.3 26.0

    13 37.3 42.7 25.2 60 46.7 54.0 30.3

    14 39.5 45.8 25.5 61 33.9 38.1 23.715 37.6 43.0 25.6 62 33.2 37.5 23.1

    16 38.7 44.6 25.7 63 34.7 39.2 24.1

    17 33.2 37.7 23.1 64 32.6 37.2 21.9

    18 34.5 39.3 23.5 65 37.4 42.9 24.4

    19 32.5 36.8 22.8 66 38.9 44.9 25.2

    20 35.2 40.4 23.7 67 38.9 44.8 25.3

    21 36.2 41.4 24.6 68 37.6 43.2 24.7

    22 38.3 44.3 25.1 69 38.4 44.3 24.9

    23 33.4 38.0 23.4 70 37.3 42.9 24.3

    24 34.1 38.4 24.2 71 42.8 50.0 26.6

    25 31.6 36.1 22.5 72 37.7 43.7 23.9

    26 32.6 36.9 23.2 73 38.1 43.6 25.1

    27 29.7 33.4 21.0 74 37.7 43.3 24.5

    28 32.8 37.2 23.0 75 36.9 42.0 24.629 34.5 39.9 23.7 76 33.6 38.0 23.0

    30 30.1 34.2 21.1 77 43.2 49.6 28.8

    31 32.2 36.6 22.0 78 42.7 49.2 28.2

    32 38.3 44.5 26.1 79 40.6 46.3 27.1

    33 32.4 37.5 22.1 80 43.3 50.4 28.5

    34 41.4 48.3 28.2 81 40.3 46.9 26.3

    35 37.6 43.2 25.6 82 42.4 49.3 28.3

    36 43.1 50.7 29.0 83 40.3 47.2 26.0

    37 39.1 45.7 26.4 84 41.4 48.2 26.7

    38 40.8 46.7 27.4 85 37.8 43.8 24.4

    39 40.6 46.7 26.7 86 38.6 45.0 25.1

    40 39.9 45.8 26.7 87 38.1 44.3 25.2

    41 38.9 44.7 26.1 88 35.4 40.8 23.4

    42 39.5 45.1 26.6 89 33.9 38.6 22.5

    43 36.3 41.1 24.7 90 35.4 40.8 23.3

    44 38.0 43.1 26.0 91 40.5 46.7 27.3

    45 38.7 44.2 25.9 92 42.0 48.8 27.9

    46 38.6 43.8 26.8 93 42.5 49.2 27.7

    47 37.9 43.5 25.1

    L. Doulos et al. / Solar Energy 77 (2004) 231–249   237

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    materials a selection of the most commonly used ones

    was done.

    The minimum values of the mean daily and the

    absolute maximum surface temperatures were observed

    10

    15

    20

    25

    30

    35

    40

    45

    50

    55

    60

    No 5

    White

    No 1

    Green

    No 2

    White

    Black

    No 3 Light

    Brown

    No 6

    Brown

    No 4 Gray No 7 Red No 8 Black

    Surface color 

       T  e  m  p  e  r  a   t  u  r  e   (   °   C   )

      Mean surface temperature

    Temperature range

    Fig. 7. Mean daily surface temperature and temperature range, within 9:00 to 18:00 for the period of August 2001, for the material tiles

    made of mosaic.

    10

    15

    20

    25

    30

    35

    40

    45

    50

    55

    60

    No 19 Whi te No 20 Whi te-

    Black

    No 21 Green No 22 White-

    Green

    No 11 Red No 12 Black

    Surface color 

       T  e  m  p  e  r  a   t  u  r  e   (   °   C   )

      Mean surface temperature

    Temperature range

    Fig. 8. Mean daily surface temperature and temperature range, within 9:00 to 18:00 for the period of August 2001, for the material tiles

    made of granite.

    10

    15

    20

    25

    30

    35

    40

    45

    50

    55

    60

    No 17

    White

    No 18

    White

    No 13

    Orange

    No 15

    Gray

    No 9 Red No 16

    Gray

    No 14

    Brown

    No 10

    Black

    Surface color 

       T

      e  m  p  e  r  a   t  u  r  e   (   °   C   )

      Mean surface temperature

    Temperature range

    Fig. 9. Mean daily surface temperature and temperature range, within 9:00 to 18:00 for the period of August 2001, for the material tiles

    made of concrete (30 cm ·30 cm).

    238   L. Doulos et al. / Solar Energy 77 (2004) 231–249

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    for the white colored material tiles. On the contrary the

    maximum corresponding values were noticed in the dark

    colored material tiles. Namely, the mean daily surface

    temperatures ranged between 29.7   C (for the white

    marble tile no. 27) and 46.7   C (for the asphalt tile no.

    60). Furthermore the absolute maximum temperatures

    varied from 33.4 and 54   C for the same corresponding

    materials.

    From a first point of view it seems that from the

    white colored materials the ones made of marble pre-sented the lowest value of the mean daily surface tem-

    peratures. The observed differences in the measured

    surface temperatures for the white colored materials are

    due to the surface texture. In general the smooth sur-

    faced materials present lower surface temperatures than

    the ones with rough surface or anaglyph schematics

    (Fig. 15).

    Continuously, the black colored materials had the

    largest surface temperatures from the total number of 

    the material tiles. The material tile made of asphalt

    presented the greatest surface temperature because of its

    black and rough surface. Large surface temperatures

    10

    15

    20

    25

    30

    35

    40

    45

    50

    55

    60

    No 64

    White

    No 61

    White

    No 49

    White

    No 44

    Gray

    No 69

    Green

    No 66

    Orange

    No 52

    Red

    No 71

    Dark

    Green

    No 51

    Black

    Surface color 

       T  e  m

      p  e  r  a   t  u  r  e   (   °   C   )

      Mean surface temperature

    Temperature range

    Fig. 10. Mean daily surface temperature and temperature range, within 9:00 to 18:00 for the period of August 2001, for the material

    tiles made of concrete (40 cm ·40 cm).

    10

    15

    20

    25

    30

    35

    40

    45

    50

    55

    60

    No 27White

    No 30White

    No 25WhiteBlack

    No 31White

    No 33Light

    Brown

    No 26WhiteBlack

    No 28White

    No 23White

    No 24WhiteBlackRed

    No 29WhiteBlack

    No 35WhiteBlack

    No 32Pink

    No 37Gray

    No 34Red

    No 36DarkGray

    Surface color 

       T  e  m  p  e  r  a   t  u  r  e   (   °   C   )

      Mean surface temperature

    Temperature range

    Fig. 11. Mean daily surface temperature and temperature range, within 9:00 to 18:00 for the period of August 2001, for the materialtiles made of marble.

    10

    15

    20

    25

    30

    35

    40

    45

    50

    55

    60

    No 78

    Gray

    No 77

    Red

    No 79

    Brown

    No 60

    Black

    Surface color 

       T  e  m

      p  e  r  a   t  u  r  e   (   °   C   )

      Mean surface temperature

    Temperature range

    Fig. 12. Mean daily surface temperature and temperature

    range, within 9:00 to 18:00 for the period of August 2001, for

    the material tiles made of pave stone.

    L. Doulos et al. / Solar Energy 77 (2004) 231–249   239

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    were also observed in tiles made of pebble with dark

    gray and dark green surface color (no. 57, 44  C, no. 56,

    45.2   C). This was caused by the existing surface

    roughness at the pebble tiles (Fig. 17).

    10

    15

    20

    25

    30

    35

    40

    45

    50

    55

    60

    No 76

    White

    No 43

    White

    Brown

    No 75

    White

    Gn

    Red

    No 41

    Light

    Brown

    No 42

    Red

    No 40

    Black

    Brown

    No 59

    Light

    Gray

    No 58

    Gray

    No 39

    Light

    Brown

    No 38

    Brown

    No 56

    Green

    No 57

    Dark

    Gray

    Surface color 

       T  e  m

      p  e  r  a   t  u  r  e   (   °   C   )

      Mean surface temperature

    Temperature range

    Fig. 13. Mean daily surface temperature and temperature range, within 9:00 to 18:00 for the period of August 2001, for the material

    tiles made of pebble.

    10

    15

    20

    25

    30

    35

    40

    45

    50

    55

    60

    No 89

    Brown

    No 88

    Brown

    No 90

    Brown

    No 85

    Brown

    No 87

    Green

    No 86

    Brown

    No 81

    Brown

    No 83

    Green

    No 91

    Brown

    No 84

    Black

    No 92

    Red

    No 82

    Gray

    No 93

    Red

    No 80

    Black

    Surface color 

       T  e  m  p  e  r  a   t  u  r  e   (   °   C   )

      Mean surface temperature

    Temperature range

    Fig. 14. Mean daily surface temperature and temperature range, within 9:00 to 18:00 for the period of August 2001, for the materialtiles made of stone.

    10

    15

    20

    25

    30

    35

    40

    45

    50

    55

    60

    No 27 Marb le No 19 Grani te No 5 Mosaic No 76 Pebb le No 61 Concrete

    Construction material

       T  e  m  p  e  r  a   t  u  r  e   (   °   C   )

      Mean surface temperature

    Temperature range

    Fig. 15. Mean daily surface temperature and temperature

    range, within 9:00 to 18:00 for the period of August 2001, for

    the white colored material tiles.

    10

    15

    20

    25

    30

    35

    40

    45

    50

    55

    60

    No 4 Mosaic No 44

    Concrete

    No 37 Marble No 58 Pebble No 82 Stone No 78 Pave

    stone

    Construction material

       T  e  m  p  e  r  a   t  u  r  e   (   °   C   )

      Mean surface temperature

    Temperature range

    Fig. 16. Mean daily surface temperature and temperature

    range, within 9:00 to 18:00 for the period of August 2001, for

    the gray colored material tiles.

    240   L. Doulos et al. / Solar Energy 77 (2004) 231–249

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    10

    15

    20

    25

    30

    35

    40

    45

    50

    55

    60

    No 84

    Stone

    No 8

    Mosaic

    No 36

    Marble

    No 80

    Stone

    No 12

    Granite

    No 51

    Concrete

    No 57

    Pebble

    No 60

     Asphalt

    Construction material

       T  e  m  p  e  r  a   t  u  r  e   (   °   C   )

      Mean surface temperature

    Temperature range

    Fig. 17. Mean daily surface temperature and temperature range, within 9:00 to 18:00 for the period of August 2001, for the black

    colored material tiles.

    10

    15

    20

    25

    30

    35

    40

    45

    50

    55

    60

    No 9

    Concrete

    No 7 Mosaic No 42

    Pebble

    No 11

    Granite

    No 34

    Marble

    No 93 Stone No 77 Pave

    stone

    Construction material

       T  e  m  p  e  r  a   t  u  r  e   (   °   C   )

      Mean surface temperature

    Temperature range

    Fig. 18. Mean daily surface temperature and temperature range, within 9:00 to 18:00 for the period of August 2001, for the red colored

    material tiles.

    10

    15

    20

    25

    30

    35

    40

    45

    50

    55

    60

    No 1 Mosaic No 21 Granite No 87 Stone No 69

    Concrete

    No 83 Stone No 56 Pebble

    Construction material

       T  e  m  p  e  r  a   t  u  r  e   (   °   C

       )

      Mean surface temperature

    Temperature range

    Fig. 19. Mean daily surface temperature and temperature range, within 9:00 to 18:00 for the period of August 2001, for the green

    colored material tiles.

    L. Doulos et al. / Solar Energy 77 (2004) 231–249   241

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    In order to study the impact of the size of the

    building materials on their thermal performance during

    the daytime period a comparison analysis was per-

    formed for material tiles made of concrete. Two different

    groups of concrete tiles were measured and studied with

    respect to their size (30 cm · 30 cm, 40 cm · 40 cm). The

    two groups had the same surface color and texture. The

    t -test (Livada and Asimakopoulos, 2002) was applied on

    the mean daily surface temperatures and it was found

    that the surface temperatures were statistical equal

    (confidence level   a ¼  0:05). Table 3 gives the mean dailysurface temperatures of the two groups. From this

    comparison, can be assumed that the size of the tiles

    does not affect the thermal balance of the studied

    materials during the day.

    Fig. 21 shows the surface temperature distributionfor a number of representative building materials to-

    gether with the air temperature during the hot day

    period of the 7th August 2001. The selected material

    consist of white colored tiles made of marble (no. 27)

    and concrete (no. 49) and black colored tiles made of 

    concrete (no. 51) and asphalt (no. 60). The maximum

    difference (22.5   C) between surface temperatures was

    Table 3

    Comparison of the measured surface temperatures in the case of 

    concrete tiles with the two different sizes (30 cm ·30 cm, 40

    cm·40 cm)

    Surface color Surface

    texture

    Mean daily surface tem-

    perature (C)

    (30· 30) (40· 40)

    Black Smooth 44.0 44.4

    Gray Smooth 38.7 38.7

    Gray Rough 37.6 38.0

    Red Smooth 37.8 37.9

    Orange Smooth 37.3 37.4

    White Smooth 34.5 33.9White Rough 33.2 33.2

    10

    15

    20

    25

    30

    35

    40

    45

    50

    55

    60

    No 33 Marble No 3 Mosaic No 85 Stone No 66

    Concrete

    No 79 Pave

    stone

    No 38 Pebble

    Construction material

       T  e  m  p  e  r  a

       t  u  r  e   (   °   C   )

      Mean surface temperature

    Temperature range

    Fig. 20. Mean daily surface temperature and temperature range, within 9:00 to 18:00 for the period of August 2001, for the brown

    colored material tiles.

    20

    25

    30

    35

    40

    45

    50

    55

    60

    09:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00

    Time

       T  e  m  p  e  r  a   t  u  r  e   (   °   C   )

    No 60 Asphalt(Black)

    No 51Concrete(Black)

    No 49Concrete(White)

    No 27Marble(White)

     Air Temperature

    Fig. 21. Distribution of surface temperatures within 9:00 to 18:00 of 7th August 2001, between selected material tiles.

    242   L. Doulos et al. / Solar Energy 77 (2004) 231–249

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    observed for the tiles made of marble and the asphalt at

    14:00 LT.

    It is often that in the urban environment the building

    materials are not always chosen according to their sur-

    face color. The most commonly used construction

    materials are asphalt, concrete, pebble and pave stone.

    However, from the experimental procedures it wasfound that the thermal performance of these materials is

    not satisfactory. Figs. 15–17 and 20 show that tiles made

    of concrete, pebble and pavestone were warmer than the

    other materials. The marble tiles were the coldest from

    the total number of the studied materials. Therefore, the

    use of materials made of marble in the open urban areas

    is thermally more efficient than the use of concrete,

    pebble and pave stone materials.

    5. A comparative analysis between the surface material

    temperatures and the ambient air temperature

    The concluding remarks, comparing the material

    mean surface temperatures with the mean ambient air

    temperature (31.2   C, Fig. 1) during the experimental

    time period, are the following:

    (A) The majority of the materials studied were

    characterized by greater average surface temperatures

    than the average air temperature. Only the white colored

    tiles made of marble (no. 27 and no. 30) were cooler than

    the ambient air. The surface temperatures varied from

    29.7 to 30.1   C correspondingly for the two material

    tiles.(B) The warmest (38.1   C) light-colored material tile

    was the one made of pebble with white and green surface

    color (no. 73). The maximum temperature difference

    between the light colored materials and the ambient air

    was estimated equal to 6.9   C.

    (C) In the case of the dark colored materials the

    maximum temperature difference was observed for the

    one made of asphalt (no. 60) equal to 15.5   C. Besides,

    the coldest dark colored material was that made of stone

    (no. 84) with average surface temperature of 41.4  C and

    a temperature difference with the ambient air of 10.2  C.

    6. Statistical analysis of the material surface temperatures

    on a 24-h basis

    A further investigation of the thermal performance of 

    the studied materials is attempted through a statistical

    analysis. The analysis was based on a number of mea-

    surements performed on a 24-h basis during the period

    from 9:00 of 14th August 2001 to 9:00 of 15th August

    2001. The 24-h period has been divided in three different

    subperiods, namely 9:00 to 3:00, 11:00 to 15:00 and

    22:00 to 3:00.

    6.1. Analysis of the mean surface temperature of building 

    materials within 9:00 to 3:00 (LT)

    The total number of the studied building materials

    was separated into nine different groups with respect to

    their construction material. Namely each group was

    consisted from material tiles made of the same con-struction material but different surface color.   F -ANO-

    VA test (Livada and Asimakopoulos, 2002) of the means

    was applied on the mean surface temperatures within

    9:00 to 3:00 LT, in order to study the statistical signifi-

    cant differences that caused by the differences in the

    surface color.

    Table 4 shows that the   F -values for each of the

    studied group are smaller than the critical values  F 0:05  at

    a confidence level of 0.05 (a ¼  0:05). It was found thatthe color of the building materials in each group does

    not affect the estimated mean surface temperatures.

    A similar methodology was applied on the meansurface temperatures of building materials categorized

    into six different groups according to their surface color

    (Table 5). Namely, in this case the   F -values of mean

    surface temperatures were estimated for same colored

    materials but of different construction material.

    Similar results were obtained in this case. The mean

    surface temperatures of the studied building materials

    with the same color but of different construction

    Table 4

     F -ANOVA test of mean surface temperatures for nine groupsof materials, with respect to their construction material and of 

    different color

    Building materials   F F 0:05

    Mosaic 0.405

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    material were found statistically significant at the con-

    fidence level of 0.05 (a ¼  0:05).As a result it could be mentioned that the balance

    between the absorbed and the emitted heat during a 24-h

    day period appears to be the same for the total number

    of the studied materials. However, examining the daily

    temperature profile (Figs. 22 and 23) of the materialswith black surface color and with white surface color,

    high temperature differences are observed especially

    during midday hours.

    6.2. Analysis of the mean surface building material 

    temperatures during the midday hours

    In order to investigate the thermal behavior of the

    building materials during the day the surface tempera-

    tures were studied within the period of 11:00 to 15:00 of 

    14th August in the daytime. Namely, the mean surface

    temperatures and their standard deviation were calcu-

    lated and the F -ANOVA test was applied on the surface

    temperature values considering the two different cate-

    gories according to their construction material (Table 6)

    and surface color (Table 7) (Livada and Asimakopoulos,

    2002).

    As far as the mean surface temperatures of same

    construction materials are concerned, these were found

    statistically significant different except for those materi-

    10

    15

    20

    25

    30

    35

    40

    45

    50

    55

    60

    9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 0 1 2 3 4 5 6 7 8 9

    Time

       T  e  m  p  e  r  a   t  u  r  e   (   °   C   )

    No 12Black

    No 11 Red

    No 22WhiteGreen

    No 21Green

    No 19White

    Fig. 22. Distribution of hourly surface temperatures, within 9:00 of 14th August 2001 to 9:00 of 15th August 2001, for material tiles

    made of granite.

    10

    15

    20

    25

    30

    35

    40

    45

    50

    55

    60

    9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 0 1 2 3 5 7 8 9

    Time

       T  e  m  p  e  r  a   t  u  r  e   (   °   C   )

    No 51Black

    No 71DarkGreen

    No 52Red

    No 44Gray

    No 61White

    Fig. 23. Distribution of hourly surface temperatures, within 9:00 of 14th August 2001 to 9:00 of 15th August 2001, for material tiles

    made of concrete.

    Table 6

     F -ANOVA test of mean surface temperatures, within 11:00 to

    15:00 of 14th August, for nine groups with respect to their

    construction material and of different color

    Building materials   F F 0:05

    Mosaic 6.91 >2.32

    Granite 10.55 >2.62

    Concrete (30· 30) 8.61 >2.32

    Concrete (40· 40) 5.70 >1.63

    Marble 15.81 >1.86

    Pave stone 1.013 1.94

    Stone 5.69 >1.94

    244   L. Doulos et al. / Solar Energy 77 (2004) 231–249

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    als made of pave stone (Table 6). From the pave stone

    material group, only three different colors were studied

    (red no. 77, gray no. 78 and brown no. 79) where simi-

    lar mean surface temperatures were measured during

    the day (varying from 40.7 to 43.8  C). Furthermore, the

    differences of the mean surface temperatures for thesame colored materials are statistically significant for

    each group (Table 7). As a result both the construction

    material and color should be taken into account for the

    lowest surface temperatures.

    In an attempt to define ‘‘cold’’ and ‘‘warm’’ materials

    the multiple statistical test of Tukey and Kramer were

    applied on the mean surface temperature values (Livada

    and Asimakopoulos, 2002). This was to examine the

    significance of the mean surface temperatures differ-

    ences, within the daytime hours, for each pair of the

    studied materials.

    The Tukey and Kramer test became more reliable

    with the performance of the   t -test of the mean surface

    temperature differences for all the possible pairs of the

    studied building materials as both of these statistical

    tests are applied at the same confidence level (Livada

    and Asimakopoulos, 2002).

    The concluding remarks are as follows:

    1. For building materials made of mosaic as ‘‘cold’’ can

    be considered the white, the white–black, the green

    and the brown surface colored materials (no. 5, no.

    2, no. 1 and no. 6).

    2. For those made of the granite as ‘‘cold’’ can be con-

    sidered the white and the white–black surface coloredmaterials (no. 19 and no. 20).

    3. For those made of the concrete as ‘‘cold’’ can be con-

    sidered all the white colored materials (no. 17, no. 18,

    no. 49, no. 61, no. 62, no. 63 and no. 64).

    4. For those made of the pebble as ‘‘cold’’ can be con-

    sidered the white, the white–brown and the white– 

    green–red surface colored materials (no. 76, no. 43

    and no. 75).

    5. For those made of the marble as ‘‘cold’’ can be con-

    sidered the white, the brown (beige) and the white

    with black shades surface colored materials (no. 27,

    no. 33 and no. 29).

    6. For those made of the stone as ‘‘cold’’ can be consid-

    ered the brown surface colored materials (no. 88, no.

    89 and no. 90).

    The same statistical test was performed between the

    different colored construction tiles. The corresponding

    results are the following:

    (A) For black surface colored materials the lowest tem-

    peratures were observed at those made of mosaic,

    concrete and marble (no. 8, no. 48 and no. 37).

    (B) For white surface colored materials the lowest tem-

    peratures were observed at those made of mosaic,

    concrete, granite, pebble and marble (no. 5, no.

    64, no. 19, no. 76 and no. 27).

    (C) For gray surface colored materials all of them ex-

    cept for those made of pebble (no. 58) and pave

    stone (no. 78) presented low temperatures.

    (D) For green surface colored materials the lowest tem-peratures were observed at those made of mosaic

    and granite (no. 1 and no. 21).

    (E) For brown surface colored materials the lowest tem-

    peratures were observed at those made of mosaic

    and stone (no. 6 and no. 89).

    From the combination of the above comparisons

    turned up seven tiles (Table 8), which can be considered

    the tiles with the lowest temperatures.

    The same multiply comparison by Tukey and Kra-

    mer statistical test was applied for the 21 sampling pairs

    of materials that turned up from the above table (Livada

    and Asimakopoulos, 2002). The corresponding results

    show that the mean surface temperatures for the green

    colored mosaic tile, the brown colored mosaic tile and

    the brown colored stone tile (marked with * in Table 8)

    are statistically significant higher than the others at a

    confidence level of 0.05 (a ¼  0:05).Finally as ‘‘cold’’ materials can be considered, from

    the colder to warmer, the white marble, the white

    Table 7

     F -ANOVA test of mean surface temperatures, within 11:00 to

    15:00 of 14th August, for the six groups of building materials,

    according to their color and of different construction material

    Surface material color   F F 0:05

    White 2.16 >1.90

    Gray 4.02 >1.94

    Black 2.90 >2.12

    Red 2.50 >2.05

    Green 7.18 >2.44

    Brown 4.00 >2.12

    Table 8

    Mean surface temperatures and deviation for ‘‘cold’’ materials

    as they assumed by statistical tests with respect to their con-struction material and surface color within 11:00 to 15:00 of 

    14th August

    Material–surface color Surface tem-

    perature (C)

    Deviation

    Mosaic–white (no. 5) 32.32 5.162

    Mosaic–green (no. 1) 33.92 5.812

    Mosaic–brown (no. 6) 34.98 6.932

    Granite–white (no. 19) 31.46 5.353

    Concrete (40·40) and White

    with marble inlay (no. 64)

    32.36 6.523

    Marble–white (no. 27) 29.1 4.625

    Stone–brown (no. 89) 33.6 7.655

    L. Doulos et al. / Solar Energy 77 (2004) 231–249   245

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    granite, the white mosaic and finally the white concrete

    with marble inlay. In this comparison the surface texture

    was not taken into account.

    6.3. The impact of the surface texture on the thermal 

     performance of the materials

    In order to investigate the impact of the surface

    texture on the mean surface temperatures, 24 different

    pairs of same colored and construction building mate-

    rials but of different texture were studied for the period

    of 11:00 to 15:00 within the 14th August.

    The F -test of the variance differences was applied for

    each of the studied pairs in order to define a proper

    equation of   t -test of the differences of the mean values

    (Table 9) (Livada and Asimakopoulos, 2002).

    The standard deviations for each of the studied pair

    of building material were considered statistically signif-

    icant equal at a confidence level of 0.05 (a ¼  0:

    05).

    Afterwards the statistical test of the means (t -test)

    was applied for all the samples with the same size and

    with statistical equal standard. For all the cases the   jt jvalues were smaller from the critical value   t 0:05   at the

    0.05 confidence level in the two tailed test.

    Therefore the material’s surface texture does not af-

    fect statistically the measured surface temperature during

    the daytime (9:00 to 15:00). ‘‘Cold’’ building materials

    can be considered independently of the surface texture.

    6.4. Analysis of the mean surface building material temperatures during the night period 

    In order to investigate the thermal behavior of the

    building materials during the night the surface temper-

    atures were studied within the period of 22:00 of 14th

    August to 3:00 of 15th August in the nighttime. Simi-

    larly as above, the mean surface temperatures and their

    standard deviation were calculated and the   F -ANOVA

    test was applied, considering the two different categories

    according to the construction material (Table 10) and

    the color (Table 11) (Livada and Asimakopoulos, 2002).

    According to the construction material the mean

    nocturnal surface temperatures were found statistically

    significant different only for marble and stone (confi-

    dence level   a ¼  0:05) (Table 10). According to the samecolored materials, the differences of the mean surface

    temperatures are statistically significant for every group

    (confidence level   a ¼  0:05) (Table 11).

    Table 9

    Various material pairs comparison to examine the surface texture impact in the measured surface temperatures

    Construction material Surface color–texture Surface mean

    temperatures (C)

    Deviation   jt -testj

    Concrete (30 cm·30 cm) Gray, smooth without schematic (no. 15) 36.74 6.97 0.98

    Gray, rough without schematic (no. 16) 38.44 8.39

    White, smooth without schematic (no. 17) 32.06 5.93 1.05

    White, rough without schematic (no. 18) 33.76 7.25

    Concrete (40 cm·40 cm) Gray, smooth without schematic (no. 44) 38.14 6.70 1.86

    Gray, rough without schematic (no. 45) 39.2 8.72

    Red, smooth without schematic (no. 53) 39.86 11.85 0.144

    Red, rough without schematic (no. 52) 40.16 9.99

    White, smooth without schematic (no. 62) 32.88 5.93 0.406

    White, rough without schematic (no. 61) 33.52 6.48

    White, smooth with inlay (no. 64) 32.36 6.52 1.246

    White, rough with schematic (no. 63) 34.36 6.37

    Orange, smooth with schematic and inlay (no. 65) 37.7 9.37 0.943Orange, rough without schematic (no. 66) 39.6 10.94

    Green, smooth with inlay (no. 72) 38.66 13.93 2.23

    Green, rough with schematic (no. 71) 44.28 17.69

    Orange, rough with schematic (no. 70) 37.88 11.56 0.811

    Orange, rough without schematic (no. 66) 39.6 10.94

    Black, smooth with schematic (no. 50) 44.26 12.05 0.855

    Black, smooth without schematic (no. 51) 46.28 15.86

    Marble White, smooth with black shades (no. 25) 31.38 5.78 1.667

    White, rough with black shades (no. 24) 33.76 4.41

    White, smooth (no. 27) 29.1 4.63 1.363

    White, anaglyph (no. 28) 32.0 6.31

    246   L. Doulos et al. / Solar Energy 77 (2004) 231–249

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    The Tukey–Kramer test was applied again on the

    mean nocturnal surface temperature values for those

    materials made of marble and stone. The concluding

    remarks are the following:

    1. For building materials made of marble, the white

    with black and red shades (no. 24) and the white

    (no. 28) surface colored materials could be character-

    ized as ‘‘warm’’ materials, while the light brown (no.

    33) surface colored material could be characterized as

    ‘‘cold’’ material.

    2. For building materials made of stone, the brown (no.89, no. 91) and the red (no. 93) surface colored mate-

    rials could be characterized as ‘‘warm’’ materials,

    while the brown (no. 88) and the red (no. 92) surface

    colored materials could be characterized as ‘‘cold’’

    materials.

    As a result it could be mentioned that the construc-

    tion material determines the thermal balance during the

    night (by affecting the emissivity), while the surface color

    determines significant the thermal balance only during

    the day (by affecting the albedo).

    The same statistical test was performed between the

    different colored construction tiles. The corresponding

    results are the following:

    (A) For black surface colored materials low tempera-

    tures were observed for all the construction materi-

    als, except for those made of asphalt (no. 60). Theconstruction material made of asphalt defined as

    the ‘‘warmest’’ of all.

    (B) For white surface colored materials, the rough with

    schematics concrete (no. 63) could be characterized

    as ‘‘warm’’ material, and the light brown marble

    (no. 33) as ‘‘cold’’. The light brown marble was con-

    sidered in the group with the white surface colored

    materials.

    (C) For gray surface colored materials, the cement

    with the smooth surface (no. 46) and the pave

    stone (no. 78) could be characterized as ‘‘warm’’

    materials. For the rest gray surface colored materi-als, the mean surface nocturnal temperatures were

    similar, so no material could be characterized as

    ‘‘cold’’.

    (D) For green surface colored materials, the pebble (no.

    56) could be characterized as ‘‘warm’’ material.

    (E) For brown surface colored materials, the pebble

    (no. 38) could be characterized as ‘‘warm’’ material.

    6.5. The impact of the surface texture on the thermal 

     performance during the night period 

    In order to investigate the impact of the surfacetexture on the mean surface temperatures during the

    night, the same pairs (as given in Table 9) of same col-

    ored and construction building materials, but of differ-

    ent texture, were studied for the period within the 22:00

    of 14th August to 3:00 of 15th August.

    The F -test of the variance differences was applied for

    each of the studied pairs in order to define a proper

    equation for the   t -test of the differences of the mean

    values (Table 12) (Livada and Asimakopoulos, 2002).

    The mean nocturnal surface temperature comparison

    according to the texture of the materials indicates,

    showed in some cases statistically significant differences(confidence level   a ¼  0:05) (Table 12). In particular, forboth concrete and marble, the differences were caused

    due to the low surface temperatures measured in the

    smooth surface materials during the night, while the

    corresponding tiles with rough surface had warmer

    surface.

    Generally the smooth surface materials appear to be

    colder than the rough materials during the night. For 24-

    h time period the light brown marble (no. 33) and the

    brown stone (no. 90) could be characterized as ‘‘cold’’

    materials.

    Table 10

     F -ANOVA test of mean surface temperatures, within 22:00 of 

    14th August to 3:00 of 15th August, for nine groups with re-

    spect to their construction material and of different color

    Building materials   F F 0:05

    Mosaic 2.03 2.22

    Green 10.97 >2.49

    Brown 11.72 >2.30

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    7. Conclusions

    The materials’ thermal balance is determined mainly

    by their reflectivity to solar radiation and their emis-

    sivity to the long wave radiation during the daytime. As

    the emissivity values for the total number of the studied

    materials were close to 0.9, the observed differences in

    the mean daily surface temperatures are mainly caused

    by the different albedo factors of the total number of the

    studied materials. The physical characteristics of the

    material tiles that affect their albedo are the color,

    the surface texture and the construction material. The

    rough and dark colored surfaces tend to absorb more

    solar radiation than the smooth, light colored and flat

    surfaces. Therefore the dark colored surfaces are warmer

    than the light colored.

    From the study of the total number of the pavement

    materials according to their surface color material it was

    found that the light colored tiles were cooler than the

    others. As expected the white colored tiles were the

    coldest, while the black colored were the warmest.

    Afterwards from the analysis of the building materials

    according to their construction material it was found

    that tiles made of marble, mosaic and stone were cooler

    than the other ones. Besides, from the analysis based on

    the material textures, the tiles with smooth and flat

    surface were cooler than the tiles with rough and ana-

    glyph surface. Finally studying the impact of sizing it

    Table 12

    Various material pairs comparison to examine the surface texture impact in the measured nocturnal surface temperatures

    Construction material Surface color–texture Surface mean

    temperatures  C

    Deviation   jt -testj

    Concrete (30 cm· 30 cm) Gray, smooth without schematic (no. 15) 17.87 0.539 0.211

    Gray, rough without schematic (no. 16) 17.95 0.319

    White, smooth without schematic (no. 17) 17.33 0.578 1.531

    White, rough without schematic (no. 18) 17.93 0.343

    Concrete (40 cm· 40 cm) Gray, smooth without schematic (no. 44) 18.22 1.001 0.321

    Gray, rough without schematic (no. 45) 18.4 0.884

    Red, smooth without schematic (no. 53) 17.42 0.57 2.51

    Red, rough without schematic (no. 52) 18.51 0.562

    White, smooth without schematic (no. 62) 17.78 0.622 1.27

    White, rough without schematic (no. 61) 18.33 0.503

    White, smooth with inlay (no. 64) 17.08 0.662 3.82

    White, rough with schematic (no. 63) 18.73 0.455

    Orange, smooth with schematic and inlay (no. 65) 17.83 0.707 0.76

    Orange, rough without schematic (no. 66) 18.2 0.724

    Green, smooth with inlay (no. 72) 17.13 0.679 1.43

    Green, rough with schematic (no. 71) 17.82 0.718

    Orange, rough with schematic (no. 70) 18.02 0.722 0.37

    Orange, rough without schematic (no. 66) 18.2 0.724

    Black, smooth with schematic (no. 50) 18.62 0.822 3.38

    Black, smooth without schematic (no. 51) 16.85 0.827

    Marble White, smooth with black shades (no. 25) 15.6 1.452 2.19

    White, rough with black shades (no. 24) 16.93 0.759

    White, smooth (no. 27) 16.18 0.722 3.72

    White, anaglyph (no. 28) 18 0.711

    Fig. 24. Definitions of ‘cold’ and ‘warm’ materials.

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    was concluded that for the material tiles with the same

    construction material, surface color and texture but

    different geometry characteristics (surface size and

    thickness) the differences in the surface temperatures are

    not statistical significant during the daytime period. The

    observed non-uniform temperature distribution on some

    materials’ surfaces was caused by their surface colorcontrast; the surface roughness and the heat transfer

    phenomena. Therefore as ‘‘cold’’ materials can be

    characterized those having a smooth and light colored

    surface and construction materials made of marble,

    mosaic and stone. Similarly as ‘‘warm’’ materials could

    be defined those having a rough and dark colored sur-

    face and construction materials made of pebble, pave

    stone and asphalt (Fig. 24).

    The use of ‘‘cold’’ materials is important in the urban

    environment and especially in cities with hot climate.

    The use of ‘‘cold’’ materials contributes to the reduction

    of the air temperature due to heat transfer phenomena.However ‘‘warm’’ materials instead of ‘‘cold’’ are used

    to the urban environments structure. This use is caused

    either due to economic and esthetic reasons, or by bad

    environmental planning. As a result, the temperature in

    the urban environment is raised and the demand for

    cooling load in the buildings is getting greater.

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