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    Palm oil and fractioPalm oil and fractio

    WAI-LIN, SIEW

    and JOHARI MINAL

    MPOB

    WAI-LIN, SIEW

    and JOHARI MINALMPOB

    OFI Middle OFI Middle

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    PALM OIL INDUSTRYPALM OIL INDUSTRY--RM31RM31

    PLANTED AREA 0F 4.17m hecPLANTED AREA 0F 4.17m hec

    production of 15.9 mproduction of 15.9 m

    tonnestonnes

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    Oil Palm BunchFru

    KernelsBunch weight 20-30 kg

    Oil per bunch20-30%

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    The PALM OIL optioThe PALM OIL optio

    !

    "

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    PALM OILPALM OIL-- A BALANA BALAN

    OILOIL

    •• 50% SATURATED50% SATURATED

    •• 50% UNSA50% UNSA

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    Fractionation of palmFractionation of palm

    PO

    Ol 56St 33

    Sp ol

    64-65

    Soft pmf

    45

    HardPmf 36

    Mid ol54

    PO

    St 40

    st25 pmf48

    POSt 30-45 Ol 56-64

    Hard st15-25

    Soft pmf42-50

    Hard pmf34-42

    Mid ol54-56

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    FameFame Palm Palm SupePalm Palm Super

    OilOil OleinOlein OleinOlein

    C12:0 0.2C12:0 0.2 0.20.2 0.3 0.3

    C14:0 1.1C14:0 1.1 1.11.1 1.01.0

    C16:0 44.0 40.9 35.4 C16:0 44.0 40.9 35.4

    C18:0C18:0 4.5 4.2 3.8 4.5 4.2 3.8

    C18:1 39.2 41.5 45.1 C18:1 39.2 41.5 45.1

    C18:2C18:2 10.1 11.6 13.4 10.1 11.6 13.4

    C18:3 0.4 0.3 0.3C18:3 0.4 0.3 0.3

    C20:0 0.4 0.2 0.3C20:0 0.4 0.2 0.3

    FATTY ACID COMPOSITION OF PFATTY ACID COMPOSITION OF P

    OIL PRODUCTSOIL PRODUCTS

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    Positional distribution of fatty Positional distribution of fatty

    palm oil and palm oleinpalm oil and palm olein

    19

    3.

    66.3

    23.8

    13.7

    72.9

    Palm oleinsn-2

    Position1,3

    174.

    61.925.2

    20.670.5

    Palm oil

    sn -2Position 1,3

    linoleicSat FA

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    Total and positional distributionTotal and positional distribution

    fatty acids in PMFfatty acids in PMF

    ##

    $

    %##

    #

    %

    #

    &

    '$'

    (!

    )%

    ( *+*

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    0

    10

    20

    30

    40

    50

    60

    70

    80

    90

    sat FA monounsaturated polyunsatur

    type of fatty acids in sn2 postion

       c   o   n   t   e   n   t   o   f   F   A

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    Triacylglycerol composition of Triacylglycerol composition of

    TAG wt% TAG wt% TAG wt% TAG wt%

    All 0 db 7.4 All 1 db 36.8 All 2 db 34 All 3 db 1

    PPP 5.1 MOP 0.9 POO 20.3 OOO

    PPSt 1.2 POP 23.7 StOO 2.4 POL

    PStP 0.3 POSt 5.7 OPO 1 PLO

    PPO 4.4 PLP 6.5

    PStO 0.2 StLP 1.6

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    TRIGLYCERIDES OF PALMTRIGLYCERIDES OF PALM

    PRODUCTS(C No.)PRODUCTS(C No.)C. No Palm Palm Super C. No Palm Palm Super

    OilOil OleinOlein OleinOlein

    C46C46 0.80.8 0.80.8 0.20.2

    C48C48 7.47.4 3.33.3 1.9 1.9

    C50C50 42.642.6 39.539.5 30.8 30.8

    C52C52 40.540.5 42.742.7 53.4 53.4 C54C54 8.88.8 12.8 13.6 12.8 13.6

    C56C56 -- 0.70.7 0.2 0.2

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    Two important physTwo important physproperties of palm properties of palm

    (./0 *+1 "12"1(

    .3456/(4

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    5 15 25 5 15 25

    Palm oilPalm oil

    oleinolein

    stearinstearin

    Hpo(43)Hpo(43)

    Hard steaHard stea

    shortenishorteni

    1010

    3030

    5050

    7070

    9090

    Solid fat contents of palm oiSolid fat contents of palm oi

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    Morphology of CrMorphology of Cry

    αααααααα SmallSmall

    ββββββββ’’ Small,Small, ≈≈≈≈≈≈≈≈55 µµµµµµµµm, needlem, needle--likelike

    ββββββββ large, course, as large as 5large, course, as large as 5

    more, dense, flatmore, dense, flat

    ββββββββ’’ TENDINGTENDING

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    TWO

    • IV 5

    • IV >

    TWO

    • IV 5

    • IV >

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    Fatty acid composition(wt

    palm olein

    Fatty acid composition(wt

    palm oleinIV C14 C16 C18 C18-1

    65 1.0 30.8 3.6 47.9

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    58 60 62 64 6658 60 62 64 66 22

    44

    66

    IODINE VALUESIODINE VALUES

    CLOUD PT (C)CLOUD PT (C)

    Super oSuper ol

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    58 60 62 6458 60 62 64 6666

    IODINE VALUEIODINE VALUE

    00

    2020

    4040

    6060

    SFC AT 2.5 AND 5CSFC AT 2.5 AND 5C

    Super oleiSuper olei

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    SFC of palm oil and olSFC of palm oil and ol

    SFC of palm oil and ole in

    0

    10

    20

    30

    40

    50

    60

    10 15 20 25 30 35 40 45 50 55

    temperature C

       S   F   C

       %

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    Typical specifications of Typical specifications of

    olein for snack food fryolein for snack food fry FFA

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    15 - 3718:1

    3 - 1018:2

    4 - 618:0

    47 - 7416:0

    Range(wt%Fatty acids

    Fatty Acid Composition oPalm Stearins

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    ! $/

    $$ ! #( 4 °

    5

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    SFC of palm stearinsSFC of palm stearins

    SFC of palm stearins

    0

    20

    40

    60

    80

    100

    120

    10 15 20 25 30 35 40 45 50 55

    temperature C

       S   F   C

       %

    Palm ste

    PMF har

    PMF sofHard Ste

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    PROPERTIES OF PALM MID FPROPERTIES OF PALM MID F

    Fatty Acid Composition (%)Fatty Acid Composition (%)

    C12C12 00

    C14C14 00C16C16 5656

    C18C18 44

    C18:1C18:1 3434

    C18:2C18:2 33

    C20C20 00

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    C NOC NO %%

    C46C46 1.11.1C48C48 5.55.5

    C50C50 76.176.1

    C52C52 16.416.4

    C54C54 1.01.0

    TRIGLYCERIDETRIGLYCERIDE COMPOSITIOCOMPOSITIO

    PMFPMF

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    PROPERTIES OF PALM MID FRPROPERTIES OF PALM MID FR

    Iodine valueIodine valueSlip melting pointSlip melting point

    Solid fat contentSolid fat content °°CC

    1010 9090

    1515 8585

    2020 8080

    2525 6363

    3030 4242

    3535 334040 00

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    TOCOPHEROLS/ TOCOTRIETOCOPHEROLS/ TOCOTRIE

    IN OILSIN OILS

    TOCOPHEROLTOCOPHEROL

    -- RICHEDRICHED

    SOY, CORNSOY, CORN

    COTTONSEED,COTTONSEED,

    SUNFLOWER,SUNFLOWER,RAPESEEDRAPESEED

    TOCOTRIETOCOTRIE

    RICHEDRICHED

    PALM,PALM,

    WHEATGWHEATGE

    RICEBRANRICEBRAN

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    1625.(7115/2".(1625.(7115/2".(/" +.4 /. 5081(/" +.4 /. 5081(

    11   7979

      ## !! 

    & & !! 

    5 %5 % !! #%#%

    5 $#&5 $#& !! #'%#'%

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    αααααααα--tocopheroltocopherol

    ββββββββ--tocopheroltocopherol

    γ γγ γ γ γγ γ  --tocopheroltocopherolδδδδδδδδ--tocopherol tocopherol

    αααααααα --tocotrienoltocotrienol

    ββββββββ--tocotrienoltocotrienolγ γγ γ γ γγ γ  --tocotrienoltocotrienol

    δδδδδδδδ--tocotrienoltocotrienol

    - - : ;: ;

    Scavengers of free radicals

    5 ) -

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    CAROTENOID COMPOSITIOCAROTENOID COMPOSITIO

    CRUDE PALM OILCRUDE PALM OIL

    TYPETYPE

    PHYTOENEPHYTOENEββββββββ CAROTENECAROTENE

    αααααααα CAROTENECAROTENE

    LYCOPENELYCOPENE

    OTHERSOTHERS +

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    Novel palm productsNovel palm products--nunu

     + 9 )

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    400   525

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    Why choose palm oWhy choose palm o

    Price consideration

    Functionality

    Trans-free formulations

    Stability Consistent supply

    Healthy, natural oil

    Contains vitamin E, sterols,

    Unique in composition Variety of products

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