overhead projectors

6
n W. Tho Columbus, Ohio ROBERT State Ohio university BARNARD O n e of the most versatile and valuable devices available for the chemistry classroom is the overhead projector. It can be used in a variety of classroom conditions and is available with a wide number of characteristics. The newest models of overhead projectors give clear images in well-lighted classrooms, are potentially superior substitutes for the chalkboard, and are light enough to be truly called portable. In addition to handwriting they can project transparencies prepared in advance; motion and color can easily be added; and many demonstrations can be performed on the pro- jector stage such that the true color of solutions or the formation of the uroducts in a reaction is visible to any student in a class~oom without straining. The contribution of the overhead ~roiector is almost A . exclusively an expression of the teacher. It enables him to do something better than he could without it, yet he completely controls the con- text, sequence, and equipment (Fig. 1). Types of Overhead Projectors Overhead projectors consist basically of a light source, a light condensing system, a writing stage, and a lens sys- tem; there are many combina- tions available as is indicated in Table 1. Since this projector is an optical instrument, most at- tention should be given to this area. The following informa- tion should be made available to the person selecting a pro- jector for a specific application. Lamp Type and Wattage. Gen- erdly the lamp wattage should not be less than 600 w for a 5-ft square soreen or 1000 w for an aft square screen. The tungsten-halogen lamps used in many models of over- bead projectors maintain excellent light output and give longer life than conventional incandescent lamps. Focal Length of the Prqiedion Las. A 14in. focal length lens is commonly supplied with the over- head projector. Other lenses teaching aids Overheard Projectors are available (see Table 2), hut it should he noted that the shorter focal length lenses tend to introduce distortion at the edge of the picture. Condensing System. There are two principal designs of over- head projectors: Those in which light is reflected out of the light box and into the focusing head by a large parabolic mirror, and those which use a plastic Fresnel lens just beneath the writing stage. Cooling System. If the projector is to be used as a. substi- tute for the blackboard and will he on for hour-long periods, the tremendous amount of heat generated by the projector's bulb should be taken into consideration. Overhead projectors con- vert from one half to s, whole kilowatt of power into heat. Thus, the effectiveness of the cooling system is of considerable importance. Some cooling systems have excessive noise and can make it difficult for the instructor to hear questions. Projec- Figure 1. A demonstrotion performed on the rtoge of the overhead with accompanying equations. The color differences in the two tuber is readily opporenttoitudentr. Volume 45, Number 5, May 1968 / 341

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Page 1: Overhead projectors

n W. Tho Columbus, Ohio ROBERT State Ohio university BARNARD

O n e of the most versatile and valuable devices available for the chemistry classroom is the overhead projector. It can be used in a variety of classroom conditions and is available with a wide number of characteristics.

The newest models of overhead projectors give clear images in well-lighted classrooms, are potentially superior substitutes for the chalkboard, and are light enough to be truly called portable. I n addition to handwriting they can project transparencies prepared in advance; motion and color can easily be added; and many demonstrations can be performed on the pro- jector stage such that the true color of solutions or the formation of the uroducts in a reaction is visible to any student in a class~oom without straining.

The contribution of the overhead ~roiector is almost

A .

exclusively an expression of the teacher. It enables him to do something better than he could without it, yet he completely controls the con- text, sequence, and equipment (Fig. 1).

Types of Overhead Projectors

Overhead projectors consist basically of a light source, a light condensing system, a writing stage, and a lens sys- tem; there are many combina- tions available as is indicated in Table 1.

Since this projector is an optical instrument, most at- tention should be given to this area. The following informa- tion should be made available to the person selecting a pro- jector for a specific application.

Lamp Type and Wattage. Gen- erdly the lamp wattage should not be less than 600 w for a 5-ft square soreen or 1000 w for an aft square screen. The tungsten-halogen lamps used in many models of over- bead projectors maintain excellent light output and give longer life than conventional incandescent lamps.

Focal Length of the Prqiedion L a s . A 14in. focal length lens is commonly supplied with the over- head projector . O the r lenses

teaching aids

Overheard Projectors

are available (see Table 2), hut i t should he noted that the shorter focal length lenses tend to introduce distortion at the edge of the picture.

Condensing System. There are two principal designs of over- head projectors: Those in which light is reflected out of the light box and into the focusing head by a large parabolic mirror, and those which use a plastic Fresnel lens just beneath the writing stage.

Cooling System. If the projector is to be used as a. substi- tute for the blackboard and will he on for hour-long periods, the tremendous amount of heat generated by the projector's bulb should be taken into consideration. Overhead projectors con- vert from one half to s, whole kilowatt of power into heat. Thus, the effectiveness of the cooling system is of considerable importance. Some cooling systems have excessive noise and can make i t difficult for the instructor to hear questions. Projec-

Figure 1. A demonstrotion performed on the rtoge of the overhead with accompanying equations. The color differences in the two tuber is readily opporenttoitudentr.

Volume 45, Number 5, May 1968 / 341

Page 2: Overhead projectors

Table 1. Directory of Manufacturers of Overhead Proiactors

Address

AcM)-Matic Stephen A. Lwick Co. 2100 Dremo Road Richmond, Va. 23230

American Optical Co. Buffalo, N. Y. 14215

Charles Beseler Co. 219 South 18th St. East Orange, N. J. 07050

Bell B Howell Co. 7100 McCormick Road Chicago, Ill. 60645

Buhl Projector Co., Inc. 1770 New Highwa Farmingdale, N. l? 11735

Graflex, Inc. Rochester, N. Y. 14603

Fbytheon Education Co. 285 Columbus Ave. Waltham, Mass. 03154

Projection Optics Co., Inc. 271 11th Ave. East Orange, N. J.

Technifax COT. Holyoke, Mass. 01040

H. Wilson Cow. 546 W. 119th St. Chicaeo. Ill. 60628

Writing Weight Model area. Lamp (w) Lens focal length (in.) (lb) Remarks

5 X 5 500 5 X 5 f t image from 7 Easily wnverts from ver- 7-ft projector dis- tical to horisontd stage tance for use of TOPS cells.

Apallo 6 10 X 10 600 14 16 Built& roll writing halogen attachment.

56027 10 X 10 650 14 17 halogen

56013 5 X 5 TOPS Overhead Proieo- tor.

=Master Vu-Graph 10 X 10 1000 14 34

Ewn-O-Graph 10 X 10 1000 14 35 Ewnomy version Vu- Graph.

LumsrScrihe 10 X 10 1000 14 23 Has o~tional 12'lrin. , - lens:

Porta-Scribe 600 10 X 10 600 14 17 halogen

Porta-Scribe 1000 10 X 10 1000 14 23 Has ir filter, lamp chang- halogen ing device. 12'/rin.

lens available. Porta-Scribe Standard 10 X 10 420 14 17 Portable version avail.

halogen PorteScribe Acces- sories, Science table, 2 X 2, 3l/rin. slide projection attachment.

301 10 X 10 600 14 17 Has, lamp changing de- vme.

lOOCF 10 X 10 1000 14 24 Available with lZ'/riu. or 10L/rin. lens

*Koolite 6000 10 X 10 1000 14 40 Model 7000 has identical optics hut "low sil- houette." All models have removable Fres- nel lens for cleanine.

OH-2000 10 X 10 650 14 22 halogen

OH3000 10 X 10 650 14 24 halogen

5 x 5 ... . . . . . . TOPS vertical overhead projector.

"Transpaque Auto 10 X 10 1000 Level

14 . . . Available with 10 X 10- in. or 7'/n X 10%. stage. Uses parabolic mirror.

Travel-Graph 2000 10 X 10 420 14 17 halogen

Travel-Graph 1000 10 X 10 1000 14 22 halogen

Travel-Graph Resolute 10 X 10 1000 14 22 Projection bulb can he halogen repositioned far fine

focusing. Has ir filter. Travel-Grauh RXB 10 X 10 600 14 17

halogen ~Vizucam 7l/* X 10 750 14 34 Uses parabolic mirror. Portable Desk-Top 10 X 10 500 10'1s 10

Model 88

Overhead Model 66 10 X 10 600 14 15 Science table sttschment. halogen 1000 w projectar a v d -

able. 'Auditorium Overhead 10 X 10 Two-1000 14 38

Model 42 Wilson Overhead 10 X 10 650 14 161/. Has high impact plastic

halogen case. - .

' Auditorium models suitable for heavy use.

342 / Journal of Chemicol Edumfion

Page 3: Overhead projectors

Table 2. Screen Size Chart for 10 in.2 Copy Proieotion Distance (ft)

Lens focal, Minimum squsra sive screen (in.) leneth (in.) 40 50 60 70 84 86

tors using 1000 w bulbs usually offer ir filters as accessories to further aid cooling.

Additional characteristics of overhead projectors which should he considered before purchasing are: the working height from stage to bottom of lens-so that sufficient room is available for demonstrations; availability of transparent rolls for writing; the light beam adjustment; the projector support; and ease of replacing lamps.

Location of the Projector. On a vertical screen, the tilted beam of light from the overhead projector pro- duces an image wide a t the top and narrow at the bottom: very often this "keystone" distortion is no great disadvantage. If the effect is too pronounced, drawings become distorted, and there is excessive reduc- tion of screen illumination across the upper portion of the image. To maintain a suitable angle from the screen to the projection axis, a tilted screen is suggested (Fig. 2).

Figure 2. A number of different screen designs are ovalable for use with overheod projecton lo) A keystone odiurter can be purchased as an accessory for many tripod mounted screens. lb) Pull downscreens can be mounted fmm 18 to 24 in. from the wall using simple metal brackets The screen con be pviled bock at the bottom, e.g. to a chalkrail for min- imizing keystaning. k) A sheet of celotex motes an inexpensive pro- jection xreen. Sash cord supports the meon a t the top to adiurt tilt. A 1 X 2 wooden frome cemented to an un-primed celotex foce adds rigidityto thescreen. Mount screens m high or possible.

Making Transparencies

There are several simple methods for making quality transparencies for the overhead projector. The sim- plest techniques produce black on white transparencies, colored areas, or combinations of the two. The basic transparency is prepared by drawing on 8 X 10-in. sheets of clear plastic available from the suppliers of the projectors (Fig. 3). Additional resources for writing plastic are listed in Table 3; reclaimed X-ray film is the least expensive material; DuPont's Mylar film is a good choice if the intent is to clean and reuse the plastic a number of times. Pencils such as used on the bowling score machines or pencils and pens especially prepared for overhead projection are required. Color can he added manually by means of transparent colored tapes, pencils with a special transparent colored wax, felt tip markers or sheets of colored acetate; the sheets are

Figure 3. The prerr-on type letters and toper provide o convenient way lo add flgvrer or captions to transparency ma3ter3. Specify heat resistant materials for maximum Rexibility in copying from a master.

useful if several large areas are to he emphasized as in a phase diagram.

Color Methods. In a second technique, s. separate drawing is prepared on a translucent material such as tracing paper for each color desired on the final transparency. Each piece of art work is plrtced in contact with an appropriate diazo material which is then exposed to ultraviolet light passing through the drawing. Diazo+ensitiaed films produce brilliant colored positive dye images on a transparent film hase when exposed to an ammonia atmosphere. (When the sensitized material is exposed to ultrsr violet light, the diazo molecule is decomposed to a colorless com- pound which is cleared from the film by ammonia vapor.) The 6lms me members of the ammonia. developing diazotype repro- duotion (white print papers) in which a positive original gives a positive print. A group of cola= transparencies can be mounted an a common mount to produce a multicolor effect s t a cost of shout 256 per color.

A tri-color foil which combines the colors of red and blue on a single sheet with the option to combine the red and blue to form black bas been developed by the General Aniline and Film Corp. (GAF), Johnson City, N. Y. Instead of using two or three pieces to form an overlay, y, single sheet is exposed twice in a copy machine, once on each side to a different master.

A modification of the Diazo process has been produced in the Multicolor Kit No. 6300 by the VwiTyper Corp., 720 Freling- huysen Ave., Newark, N. J. 07114. The dye colors desired at development are supplied in aerosol cans. After the basic foil has been exposed to ultraviolet light, cotton swabs &re moistened with the appropriate spray and rubbed onto the plastic in the area where the lines or letters are to appear. A number of color combinations in a single sheet are possible; this process has been highly suitable for colored line transparencies of structures, graphs, etc., but lacks even color development for lsrge areas. A single composite master is used with this system.

Table 3. Suppliers of Overhead Projection Materials Panspencils

proieet as: Color Mars Lumacolor J. S. Stsedtler Ino.

MO~~V~II. . N. j. Color Pmiwto-Color Koh-I-Noor Inc.

~ l o o m s b u r i N. J. 08804 Color Sanfords Sanfords

Beiiwaod Ill. Bhok Beseler Vu-Graph marking Charles deseler Co,

pencil /7281 219 S. 18th St. Esst Omnge, N. J. 07018

Pressure sensitive films, odored or patterned Artype, Ino. transparent tapes, and presetype transfer 345 E. Terra Cotts Ave. lettering Crystal Lake 111. 60014

Chart-Pak lhc. 1 Ri"er &d Leeds. Mass. 01053 Crafting Mfg. Co. 18501 Euehd Ave. Cleveland 12. Ohio

Rwlaimed X-ray film 8% X 11-in.; 0.010 SPC Corp. BsWe BOX 407

Chatham, N. J. Johnson Prooeas Co. 80-88 Front St. Elirabeth. N. J.

D u Pont polished Mylar. 0.003 Mil thickness. Plsatio Pmduots of Utah sheets or mils P.O. Box 1415

Salt Lake City. U b h

Volume 45, Number 5, May 1968 / 343

Page 4: Overhead projectors

Figure 4. A simple copy mochine con be conrtrvcted "ring '%in. or the boric material. Material specifications ore not critical; however, only one timer ho. been found to be suitable: a Mark-Time model 74701 available from Allied Radio, No. 58E 8259.

The terms Diazochrome (a trademark of the Technifax Corp), diaso, foil, or transparency are generdly used to identify any of these base materials avaihble in 8l/% X ll-in. sheets. Diazo materials are sensitive only to ultraviolet light and make excellent msterials for students or office personnel to handle since no special facilities or handling is required.

Mechanical Deuices. A simple copy machine which can be constructed and operated in a department office consists of a. platen to hold the copy material and diaso, an ultraviolet source and timer to control exposure (Fig. 4). Concentrated ammonia. in a polyethylene cake container or in a wide month l-gal. reagent jar is all that is necessary for the developing stage. Detailed instructions for the construction of this copy machine are avail- able from the author.

Timing is critical only in the stage where the diazo is exposed to the ultraviolet light. averaaine about 2 min. Develovment in the ammonia can run to several minutes with satisfactory results.

There are a number of excellent manuals on how to prepare transparencies.' Potentially an office secretary is the resource to develop for preparing these materials within the department as there is much to he said for having this type of skilled help immediately accessible to the instructor.

There are several other simple methods for making quality transparencies for the overhead projector using office copy machines. Perhaps the most popular, because of its speed, is a thermographic process developed by the Thermofax division of the 3M Company. Thermofax transparencies cast from 25$ to 456 per sheet depending on the type and will make an instant transparency in any Thermofax office copier. The major limita- tion in preparing transparencies using the thermographic process is that theoriginal has to he composedof lines containing carbon, and the detail must be large enough to be easily resolved as the fine detail in lines tends to bleed together in this process. A first carbon copy from the typewriter or India Ink drawings are excellent for the thermographic process. (Later, in the dis- cussion of legibility standards, the cautions concerning the use of typewritten materid for projection is disoussed.) Thermofax makes several transparency films which reproduce the original copy as colored lines on s. clear background, black lines against a solid color background, white lines an 8. colored background, or color negative films which show on the screen as colored letters against a. dark background. The instructor will have to decide which of these materials is the most suitable for his aoolication. Our experience has been that the Type 127 which &es a black

MORLAN, JOAN E., ''Prepamtion of Inexpen~ive Teaohimg Materials," Chandler Publishing Co., San Francisco, 1963. POWELL, L. S., "A Guide to the Overhead Projector" (Snd ed.), British Association for Commercial and Industrial Education. London, England, 1966. Technifax Corporation, "~iasoehrome Projectuals for Visual Communication," Technifax, Holyoke, Mass., 1962.

344 / Journal of Chemical Education

line against a clear background is the mast suitable from the standpoint of resolution and ease of the instructor reading the material from the projector stage.

Transparency films are now available for the electrostatic wpy process from ArkwrightJnterlaken Corp., Main St., Fiskeville, R. I., and Direct Reproduction Corp., 835 Union Street, Brook- lyn, N. Y. 1121.5. This material replaces the paper in the storage drawer of a Xerox machine and transparencies can be made di- rectly from any material which can be copied on the Xerox machine. It is best to have a qualified Xerox serviceman handy the first time the transparency materials are tried; the plastic has been known to jam the feed mechanism in incorrectly ad- justed machines.

The spirit duplicating process is potentially a useful device in preparing lecture materials if the instructor wishes to give a wpy of a handout to each student and have an identical trans- parency far project,ian. I t is possible to buy special masters (Transofax type 1250T available from Columbia Ribbon, Glen Cove, N. Y.) so that the master is a projection transparency after the copies have been run.

Full color transparencies can he made from clay-based printed matter using the lxminatawatet lift method. Self-adhesive (T. J. Donahue, Corp., Kimhertan, Pa. 19442) or heat sensitive film (Seal, Inc., Derby, Conn. 06418) is applied to the image sur- face. The bonded material is placed in water and the paper and excess olay iis separated from the plastio. After washing is com- plete the dried plastic is sprayed with a, transparent plastic spray to increase transparency. This process tends to be somewhat of an art, and since i t destroys the original copy, testing of the process on other than the particular picture to be reproduced is suggested.

Legibilitg Standards. One of the reasons that the overhead ~roiector is such a useful device in the classroom is that it maeni-

seeing all of the material presented on the screen. A rule of thumb is that the students in a back row should be no further than six times the image width from the screen. Establishing a lettering size and line weight standard based on this 6W rule iF suggested. Unfortunately this precludes one of the easiest and most accessible forms of neat letter formins-the tvnewrit,er. - ~~ . , ~~~ ~

Pic* type. i<.r cxnmrh i- nheut ime-hlli the u ~ ~ u i ~ u u u t Iwg111 and l i e i I . I : I i t m i I l-in.) lens. The typing from primary typewriters can be used with marginal success; the 24 point adhesive transfer letters, the f240 Leroy lettering, and the Rapidogreph template, number 2 (Fig. 5) provide a reliable standard type size and when used in a 36 point or larger type add variety and legibility to headings.

I t is probably best to make transparencies in a horizontal for- met (7l/1 X 10 in.) whenever possible so that the projector need

Figure 5. The Rapidogroph pens and templates supplied by the Koh- I-Nom Corp. provide an inexpensive woy to produce neat letterng wing drawing ink. Templates ore marked or to sire of pen required.

Page 5: Overhead projectors

not be pulled unnecessarily close to the screen, violating the 6W rule, in order to get all the material an a t once.

Writing out notes for the lecture in advance has obvi- ous advantages. However instructors must be certain that the notes remain on the screen long enough far stu- dents to take notes.

Figure 6 illustrates the ad- dition of s. simple ratsting polrtroid disc in front of the projector lens. This can give the effect of motionsuch as vibrating, radiating, travel- ling, or rotatory-to the ma- terial on the slide. The "breathing" motions of wrt- ter molecules can be illus- trated in this way.

Technamation, Inc., 16 Sintsink Dr., E., Port Wash- ington, N. Y., produces in- expensive motorized polar- izing spinners and the motion materids.

Commercial Transparencies. There me many sources of prepared transparencies, and bulletins detailing the con- tents are available from the manufacturers (Table 4). Keuffel andEsser supplies the masters for 80 transparen- cies in book form (set no. 30-6020) which can be pro- duced usina diaeo materials.

Figure 6. Motion attachments for the overhead projector ore ovoil- able in two model* one with flxed speed, the other with a vari- able speed motor drive for the polomid analyzer. The mimotsd effects possible in o transparency are more effective generally if the animdion speed is adjusted by the instructor for on optimum effect.

Mounting brackets ore ovoilrrble to odopt this unit to m y modal overheod projector.

In addition to basic transparencies the 3M Science Series has developed several combination units of text and transparency origin& for CHEM study and the following Reinhold publica- tions: "Principles of Chemical Equilibrium," Morris; "Cbemi- cal Energy," Strong and Stratton; "Acids, Bases, and Chem- istry of the Covalent Bond," VmderWerf; "Chemical Bonding

Table 4. Sources of Prepared Tronsporencies for the Overheod Projector

W. A. Benjamin, Inc. 3M Company 1 Park Avenue Visual Pmdwta New York. N. Y. 10010 2501 Hudaon Road

St. Paul, Mim. 55119 John Colburn Associates, Inc. Mettler Instrument Cow. 1122 Central Avenue 20 Nasasu Street Wilmette, IN. 00091 Prinoeton. N. J. 08540 Keuffei & Esser Co. Technifsx Cow. 300 ~ d ; m s Street Halyoke. Maw. 01040 Hoboken, N. J. 07030

snd the Geometry of Molecules," Ryschke&sch; and "Elec- tronic Structure Properties and the Periodic Law," Sisler.

Periodic reviews of prepared overhead projection transparencies and expanded references of sources are planned as a. feature in the Teaching Aids column. Dr. S. Schrage, University of Illinois, has consented to handle this feature as well as the periodic f h reviews.

Demonstrations

Demonstrations can be effectively presented on the overhead projector, both on the horizontal stage of the 10 X 10-in. projectors or by using the projector with the stage in the vertical position. Dr. Hubert Alyea's TOPS projectors and Plexiglas cells utilize a vertical, 5 X 5-in. format, and as his unique concept is described monthly in THIS JOURNAL, no other reference should be necessary. Several manufacturers offer science table

accessories which convert the conventional overhead to a vertical configured projector (Table 1) which will accommodate the TOPS cells as well as larger mate- rials. Previous publicationsZ give ideas of how solu- tions can be handled on the horizontal projector stage.

Other demonstrations which can be projected as they are performed include meters, models, ripple tanks. The clear styrene boxes used to package tools, jewelry etc., make excellent containers for water in the ripple tank. Figure 7 suggests a design for a projection Geiger counter meter; the device serves as a holder for

m- a."

Figure 7. Exploded penpostive of radiotion counter. The type meter will vary according to the design of the Geiger counter. The meters have a Plexiglws body and face and in thb unit the back of the meter body is sawed away to the back of the dial; the metal d i d i s removed, and the back of the meter replaced with 0 sheet of gloss. A 4-in. meter face war used in the abovedevice.

the GM tube, sample absorbers, and the meter. A lime of meters with Plexiglas bodies which can be con- verted to projection devices is available from the Ideal Precision Meter Co., 214 Franklin St., Brooklyn 22, N. Y.

Dr. Rod O'Connor, staff associate, Advisory Council on College Chemistry, has devised a number of mechan- ical analogs and devices using magnet models for the overhead projector and the following are Dr. O'Conuor's descriptions of several of these demonstrations.

Magnetic Simulation of Electrostatic Phenomena

Strips of magnetic material (available from Leyman Corp., 5178 Crookshauk Road, Cincinnati, Ohio, or Edmund Scientific Co., 101 E. Gloucester Pike, Barrington, N. J.) c m be obtained with one maior face of the striu uolarized N and the other S. Bv attach& such strius in suiL61e fashion to stvrofoam models anb

simulate the behavior of vasiaus types of eleotroststic system. Several examples are given below.

Neutrmz-Prota Interactions. Cut ten 1-in. diameter cylinders from '/&I. thick sheets of foam polystyrene. Cut + signs in the centers of five of the cylinders and secure '/s in. wide mag- netic strips to the outsides of these cylinders using thin waterproof plastic tape. Be sure that d l these cylinders have the same external polarization. Wrap the remaining cylinders with iron wire. The + cylinders simulate protons and the others simulate neutrons.

KEENAN, C. W., J. CHEM. EDUC., 35,36 (1958). SLABAUQH, W. H., J. CHEM. EDUC., 28, 579 (1951). SLABAUQH, W. H., J. CHEM. EDUC., 30, 68 (1953).

Volume 45, Number 5, May 1968 / 345

Page 6: Overhead projectors

Place a large rectangular hakimg dish containing about an inch of water on the stage of a horizontal overhead projector. Float two of the + cvlinders so that their shadows are projected onto a screen. Bym&ing one near the other, show that they simulate like charges by repelling each other.

Remove the + cylinders and replace by two of the other type. By moving one near the other, show that they neither attract nor repel each other and thus simulate uncharged bodies, in this case neitrons.

Remove the "neutral" cylinders and replace by the five + cylinders. Show that these resist clustering. Point out that no stable nuclei exist consisting only of collections of protons. Now add the "neutral" cvlinders. Note that clusterine ocours.

protons (Fig. 8).

Figure 8. (ol "Protons" alone. Ib) "Protons" plus "neutrons;

Simulatia of Hydroge+Bonding. Cut four models of water molecules from '/An. thick sheets of foam polystyrene. Cut - signs in oxygen part of each model and + signs in hydrogen part of each model. Tape small pieces of magnetic strips along the most remote edges of each model, using one polarized face out for hydrogen and the other face out for oxygen (Fig. 9).

Place a large rectangular baking dish containing an inch of water an the stage of a horizontal overhead projector. Float one model in the dish and then add a second. Note orientation effects as models attract the fourth model. Observe orientation effects. Point out that + and - signs do not represent "full" charges, hut only relative polarities. Cut to slide or trans- parency of 3-D structure in ice.

Far a modification of this compare scale models of H B and HIO; compare models of ethanol and dimethyl ether.

Simulaiion of Electrophoresis. Cut 10 l-in. diameter cylinders from in. sheets of foam polystyrene. Prepare five as per directions for protons in the first example. Use opposite polarize tion of magnetic strips for the other five and cut - signs in centers of these. Select two powerful bar magnets and deter- mine in advance which end attracts + cylinders. Mark that end ' < - > I and the other pole of the second magnet "+". Also pre- pare lsrge cardboard + and - signs.

Place a large rectangular baking dish containing about an inch of water on the stage of a horizontal overhead projector and float the cylinders in the dish. On a second projeotor, start a gel electrophoresis separation on a Cu-CnO7 system.

Slip the cardboard + sign under one end of the baking dish and the cardboard - sign under the other end. Clamp the "+"

1

Figure 9. lo) Projection xene of model "water molecules." A glass cake plate with bowom just covered with water ollow~ the models to move freely without turning over. Ib) Model of woter moleculecut from 'I+,. sheets of foam polystyrene. Strip magnets are glued to the edge using 3 M Spro-ment adhesive or equivalent.

pole of one bsr magnet in the baking dish near the + sign and the "-" pole of the other magnet in the other end of the dish. Agitate the cylinders gently to break up clusters. Compare this analogy with the projected electrophoretic separation.

Solubility and Liquid-Liquid Extraction

Apparatus and Supplies Standard horizontal overhead projector Vertical overhead projector 12 transparent marbles 12 smdl iron nails 12 smdl magnets 3 ml distilled water 3 ml diethyl ether (CAUTION) 20 mg methyl purple &in. Petri dish 10 ml flattened test tube (TOPS) Procedure. Arrange the overhead projectors for simultaneous

projection onto two screens or mssk portions of each projector for use on a single screen.

Place marbles in Petri dish on horizontal projector. Shake to show that marbles do not attract each other. Place ether in test tube on vertical projector.

Slowly add nails to marbles and mix. Show that intimate mixing is easy, even though marbles and nails do not appear to attraot each other. Add methyl purple to ether.

Slowly add magnets to marhle-nail mixture. Show that tvo distinct regions form (marbles versus msgnet-nail clusters). Add water to ether-dye mixture, shake thoroughly and replace on projector.

Dismsion. Note that one aspect of considering solubility is concerned with interparticle forces. Note that failure of ether to dissolve is not because of strong interparticle forces in ether.

Ask for suggestions on how some substances mey be readily extracted from their aqueous solutions by ether.

346 / Journal of Chemical Education