orgche1 syllabus

7/27/2019 ORGCHE1 Syllabus

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COLLEGE: Science DEPARTMENT: Chemistry

COURSE CODE:ORGCHE1/Organic Chemistry 1 for Chemistry Majors

Prerequisite: IOCHE!

Prerequisite to: ORCHEM!

o" of units # units

$erm

%ca&emic year

CLASS DAYS AND CLASS TIME:__________ ROOM:_____

INSTRUCTOR:

E'mai(:

Consu(tation Hours:

Office:

COURSE DESCRIPTION:

ORGCHE1 )Organic Chemistry for Chemistry majors* is a #'unit (ecture course that inc(u&es a re+ie, of -asic

.rinci.(es nomenc(ature as ,e(( as structure an& reacti+e sites of organic mo(ecu(es" It a(so &iscusses the

&ifferent forms of isomerism conformations an& configurations of organic com.oun&s" $he .hysica( an&

chemica( .ro.erties of a(0anes a(0y( ha(i&es a(0enes an& a(0ynes are &iscusse& in more &etai(s"

LEARNING OUTCOMES (LO):

On com.(etion of the course the stu&ent is e.ecte& to -e a-(e to &o the fo((o,ing:

ELGA LEARNING OUTCOME

Critica( an& Creati+e $hin0er 2se e(ectronic effects )hy.erconjugation in&ucti+e effect an& resonance*

an& structura( effects )steric effect* to .re&ict chemica( -eha+iors of

organic com.oun&s"

Recogni3e the functiona( grou.s .resent in an organic com.oun& Pre&ict the mo(ecu(ar geometry of com.oun&s using the 4a(ence She((

E(ectron Pair Re.u(sion )4SEPR* Mo&e(

Pre&ict the 0in&s an& re(ati+e strengths of e(ectrostatic forces -et,een

mo(ecu(es an& estimate .hysica( .ro.erties such as me(ting .oint -oi(ing

.oint an& so(u-i(ity -ase& on .o(arity an& sha.e of organic mo(ecu(es"

5etermine the re(ati+e aci&ity of organic com.oun&s -ase& on their

chemica( structures"

Recogni3e chira( mo(ecu(es an& rea(i3e that a sma(( &ifference in

orientation great(y affects their set of .ro.erties"

5ra, sim.(e three &imensiona( mo(ecu(ar formu(as of stereoisomers an&

&istinguish -et,een conformation configuration an& the &ifferent

isomeric forms"

I&entify the most (i0e(y mechanism of a reaction an& .re&ict the .ro&uct -y

consi&ering the factors affecting S! S1 E! an& E1 reactions"

I&entify the factors affecting the sta-i(ity of organic mo(ecu(es"

Out(ine a synthesis for sim.(e a(0enes an& a(0ynes"

Effecti+e Communicator 6rite/&ra, mo(ecu(ar structures using the -on&'(ine con&ense& an& &ash

structura( formu(as of organic com.oun&s"

Gi+e the systematic )I2P%C* an& common names of organic com.oun&s"

2se the )E*')7* system for &esignating a(0ene &iastereomers"

Pro.ose synthetic ste.s in the .re.aration of a(0anes an& a(0enes"

2se cur+e& arro,s to i((ustrate the mechanism of a reaction

8ife(ong 8earner Sho, .atience .erse+erance an& &i(igence in ans,ering .ro-(em sets an&

eercises"

Re(ate some of the organic reactions to in&ustria( an& (ife .rocesses"

Ser+ice 5ri+en Citi3en incor.orate 0no,(e&ge gaine& in .ursuits for the im.ro+ement of

hea(th an& ,e(('-eing of the community

1


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FINAL COURSE OUTPUT:

%s e+i&ence of attaining the a-o+e (earning outcomes the stu&ent is require& to gi+e a

LEARNING OUTCOME REQUIRED OUTPUT DUE DATE

8O 1: 2se e(ectronic effects )hy.erconjugation

in&ucti+e effect an& resonance* or structura(

effects )steric effect* to .re&ict chemica(

-eha+iors of organic com.oun&s an& recogni3e

ho, etensi+e(y organic su-stances affect

human (i+es an& the en+ironment"

$,o to three minute .resentation

in c(ass a-out a s.ecific organic

com.oun& of interest containing

an assigne& functiona( grou." $here.ort shou(& contain -oth.hysica( an& chemica( .ro.erties

of the com.oun&s"

6ee0 9 on,ar&s )one

or t,o stu&ents.resenting in ameeting*

RUBRIC FOR ASSESSMENT:

Criterion Ver S!ti"#!$tor%& Goo'% S!ti"#!$tor% Nee'" I*+ro,e*ent%-

Organi3ation Presentation is ,e((

organi3e& an&

com.(ete

Presentation is

organi3e& -ut not

com.(ete

Presentation is not

organi3e& -ut

com.(ete"

Presentation is not

organi3e& an&

incom.(ete"

Scientific

%ccuracy

Scientific

information or facts.resente&/cite& are

1; accurate"

Scientific information

or facts.resente&/cite& sho,

some inaccuracies"


or facts.resente&/cite& sho, a

significant num-er of

inaccuracies"


or facts .resente& orcite& are a(( inaccurate"

Presentation Presentation is +ery

(i+e(y an&

interesting" $he

stu&ent ,as a-(e to

ans,er a(( questions

from the c(ass"

Presentation is (i+e(y

an& generates the

interest of the +ie,er"

$he stu&ent ,as a-(e

to ans,er some

questions from the

c(ass"

Presentation is not that

(i+e(y -ut generates

the interest of the

+ie,er" $he stu&ent

,as a-(e to ans,er

some questions from

the c(ass

Presentation is -oring

&oes not generate the

interest of the +ie,er

an& the stu&ent ,as not

a-(e to ans,er

questions from the c(ass

OT.ER REQUIREMENTS AND ASSESSMENTS:%si&e from the fina( out.ut the stu&ent ,i(( -e assesse& at other times &uring the term -y the fo((o,ing:

6ritten Eams

Home,or0/Pro-(em Sets

GRADING SYSTEM:

$he stu&ent ,i(( -e gra&e& accor&ing to the fo((o,ing:

8ong Eams oar&,or0 19;

?ina( Eam !9 ;

Passing Gra&e


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LEARNING PLAN:

LEARNING

OUTCOME

TOPIC /EE0 NO1 LEARNING

ACTIVITIES

C2!+ter -:Intro'3$tion to Or4!ni$ C2e*i"tr

1"1 Organic Chemistry an& 8ife

1"1% $he 5e+e(o.ment of Organic Chemistry as a

Science1"! Structura( $heory of Organic Chemistry1"# $he Im.ortance of Structura( ?ormu(as:Isomers

6ee0 1 8ecture

Seat,or0

>oar& ,or0

2se the .erio&ic ta-(e

to com.are the

re(ati+e

e(ectronegati+ity of

one e(ement ,ith

another an&

&etermine the forma(charge of an atom or

ion"

Pre&ict the three

&imensiona( structure

of mo(ecu(es using

the 4a(ence She((

E(ectron Pair

Re.u(sion Mo&e(

C2!+ter -:B!"i$ Prin$i+5e"

1"B Chemica( >on&s: $he Octet ru(e

1"9 6riting 8e,is Structures

1"@ ?orma( Charge

1" Resonance $heory

1"1 %tomic Or-ita(s an& E(ectron Configuration

1"11 Mo(ecu(ar Or-ita(s

1"1! s.#Hy-ri&i3ation: Structure of Methane an&

Ethane

1"1# s.!Hy-ri&i3ation: Structure of Ethene1"1B s. Hy-ri&i3ation: Structure of Ethyne

1"1@ Mo(ecu(ar Geometry: $he 4SEPR $heory

1"1 Re.resentation of Structura( ?ormu(as

6ee0 1'! 8ecture

Po,er.oint

Presentation

Seat,or0

>oar& ,or0

Pro-(em Set

Recogni3e the

functiona( grou.s

.resent in a gi+enstructura( formu(a

Pre&ict the 0in& an&re(ati+e strength of

e(ectrostatic forces

-et,een mo(ecu(es

an& .re&ict the

.hysica( .ro.erties of

organic com.oun&s"

C2!+ter : F3n$tion!5 4ro3+" !n' Inter*o5e$35!r For$e"

!"1 Car-on'car-on co+a(ent -on&s

!"! Hy&rocar-ons: %(0anes %(0enes %(0ynes an&

%romatic

!"# Po(ar Co+a(ent >on&s!"B Po(ar an& on.o(ar Mo(ecu(es

!"9"!"1# ?unctiona( Grou.s

!"1B'!"19 Physica( Pro.erties an& Mo(ecu(ar Structure

6ee0 !'# 8ecturePo,er.oint

Presentation

Seat,or0

>oar& ,or0

" 5etermine the most

re(ati+e aci&ity of

organic com.oun&s

-ase& on chemica(

structures"

C2!+ter : A$i'" !n' B!"e": Intro'3$tion to Or4!ni$

Re!$tion" !n' Me$2!ni"*"

#"1 Reactions an& $heir Mechanisms

#"! %ci&'>ase Reactions

#"# Car-ocations an& Car-anions#"B $he 2se of Cur+e& arro,s in i((ustrating

Reactions

#"9 $he Strength of %ci&s an& >ases

#"< Pre&icting the Outcome of %ci&'>ase Reactions

#"@ Re(ationshi. -et,een structure an& an& %ci&ity

#"1"#"11 $he %ci&ity of Car-oy(ic %ci&s:

#"1# % Mechanism for an Organic Reaction

6ee0 B 8ecture

Po,er.oint

Presentation

Seat,or0

>oar& ,or0

E6!*- 6ee0 9 6ritten Eam

%..(y the

Internationa( 2nion of

Pure an& %..(ie&

Chemistry )I2P%C*ru(es in naming organic

com.oun&s

I&entify the

factors affecting the

sta-i(ity of a(0anes

C2!+ter &: No*en$5!t3re !n' Con#or*!tion" o# A57!ne"

B"1 Intro&uction to %(0anes an& Cyc(oa(0anes

B"! Sha.es of %(0anes

B"# I2P%C nomenc(ature of %(0anes %(0y( Ha(i&esan& %(coho(s

B"B omenc(ature of Cyc(oa(0anes

B"9 omenc(ature of %(0enes an& Cyc(oa(0enes

B"< omenc(ature of %(0ynes

B"@ Physica( Pro.erties of %(0anes an& Cyc(oa(0anes

B" Sigma >on&s an& >on& Rotation

B"D Conformationa( %na(ysis of >utane

B"1 Re(ati+e Sta-i(ities of Cyc(oa(0anes: Ring Strain

B"11 Conformations of Cyc(oheane

B"1! Su-stitute& Cyc(oheanes: %ia( an& Equatoria(

Hy&rogen %toms

6ee0 9 '@ 8ecture

Po,er.oint

Presentation

Seat,or0>oar& ,or0

#


4/6

B"1# Su-stitute& Cyc(oa(0anes:Cis an& $rans

Isomerism

Recogni3e chira(

mo(ecu(es an& rea(i3e

that a sma(( &ifference

in orientation great(y

affects its .otencyan&/or toicity"

5ra, sim.(e three

&imensiona(

mo(ecu(ar formu(as of

stereoisomers"&istinguish -et,een

conformation

configuration an& the

&ifferent isomericforms"

ame chira(

mo(ecu(es using theCahn'Ingo(&'Pre(og

system"

C2!+ter 8: Stereo$2e*i"tr: C2ir!5 Mo5e$35e"

9"1 Chira(ity an& stereochemistry

9"! Isomerism: Constitutiona( Isomers an&

Stereoisomers

9"# Enantiomers an& Chira( Mo(ecu(es9"< $ests for Chira(ity: P(ane of Symmetry

9"@ aming of Enantiomers: $he RS System

9" Pro.erties of Enantiomers: O.tica( %cti+ity

9"D $he Origin of O.tica( %cti+ity

9"1 $he Synthesis of Chira( Mo(ecu(es9"11 Chira( 5rugs

9"1! Mo(ecu(es ,ith More than One Chira(ity Center

9"1# ?ischer Projection ?ormu(as

9"1B Stereoisomerism of Cyc(ic Com.oun&s

9"19 Re(ating Configurations through Reactions in

,hich o >on&s to the Chira(ity Center

are >ro0en9"1< Se.aration of Enantiomers

9"1@ Com.oun&s ,ith Chira(ity Centers Other than

Car-on

9"1 Chira( Mo(ecu(es $hat 5o ot Possess a

Chira(ity Center

6ee0 D 8ecture

Po,er.oint

Presentation

Seat,or0

>oar& ,or0

E6!* 6ee0 D 6ritten Eam

I&entify the most

(i0e(y mechanism of a

reaction an& .re&ict

the .ro&uct -y

consi&ering the

factors affecting S!S1 E! an& E1

reactions"

6rite reaction

mechanisms using

cur+e& arro,s to

e.(ain the con+ersion

of one organic

com.oun& to another"

C2!+ter 9: Ioni$ Re!$tion"


5/6

Fin!5 E6!* 6ee0 1B

9


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REFERENCES:

Te6t;oo7:

So(omons G"$"6" ?ryh(e C" >" Organic Chemistry 1thE&" Fohn 6i(ey Sons )%sia* Pte 8t&: 2S%

orgche1 syllabus

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