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Luminescence Technology Corp.

Organic Light Emitting Diode (OLED)

Thermally Activated Delayed Fluorescence (TADF) OLED

Solution-Processed OLED

Organic Photovoltaic (OPV)

Dye-Sensitized Solar Cell (DSSC)

Perovskite Solar Cells

Organic Thin-Film Transistor (OTFT)

Flexible Printed Electronics

Photonic and Optical Device

Fluorescent Probes

Synthetic Intermediates and Reagents

Electrode / Substrate and Sealing

Custom Synthesis Services

www.lumtec.com.tw

2016 Product Catalog

Our products are used for testing and research purpose; they are not guaranteed in patent contention by customer use.

Head office: 2F, No. 17, R&D Road II, Science-Based Industrial Park, Hsin-Chu 30076, Taiwan, R.O.C., Tel: +886-3-666-3188, Fax: +886-3-666-9288 Email: [email protected], Web: http://www.lumtec.com.tw

7

Ab

ou

t us

About us

Our Brand

Our Strength

Our Commitment

Our Equipment

Luminescence Technology Corp. (Lumtec) is a professional manufacturer of organic

chemicals since 2001. With many years experience in the market, Lumtec obtained

reputation of high quality products and excellent performance. Lumtec has presence

in Japan, Korea, North America, Europe, Middle East, Asian-Pacific, China and other

countries. We are grateful being supported by customers all over the world.

With the emphasis on innovation and IP, Lumtec has a group of experts to support

various needs of clients as well as our internal technology objectives. We offer

customized synthesis for designed structure and publication compounds. In particular

Lumtec wholly designed and invested Vacuum Deposition Equipment to pioneer OLED

technology. This enables Lumtec to offer technical consultancy for companies who

intends to optimize materials, device performance and process parameters. Moreover

Lumtec made significant efforts in developing materials with better performance,

and applied considerable patents. In order to meet the future potential demand

of materials for commercial production, we have installed adequate synthesis and

sublimation equipment to enhance our supply ability ranging from grams to tons.

Certified by ISO 9001 and ISO 14001, Lumtec strives for excellence in quality,

management and service, as well as to fulfill our responsibility in environment

protection and contribute to the world sustainability.

•2 Manufacturing facilities located in Science-Based Industrial Park, Hsin-Chu, Taiwan.

•1ton/month production capacity (500Lx2, 150Lx2, 100Lx4, 50Lx4, 30Lx4 etc. reactors).

•200kg/month sublimation capacity (6~8inch×10 sets).

•NMR, LC-MS, HPLC, GPC, TGA, UV, PL etc. analysis equipment.

•Lithographically patterned ITO production and vacuum deposition equipment in

clean room.



8

Ab

ou

t us

About us

US9,190,619

US9,166,177

US9,048,437

US9,040,174

US8,993,130

US8,962,160

US7,754,348

US7,282,586

US20140175383

US20140131664

US20130180589

US20110163300

TWI402243

TW201329083

TWI482757

CN101372455

CN103508835

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Compound for organic electroluminescence device

Ditriphenylene Derivative And Organic Electroluminescent Device

Using The Same

Organic Compound For Organic Electroluminescent Device

Fluorene compound and organic electroluminescent device using

the same

Organic compound and organic electroluminescent device using

the same

Material for organic electroluminescent device

Phenanthroline compound and organic light emitting device using

the same

Dipyridine-based compound and the use thereof

Indenotriphenylene derivatives and organic light emitting device

using the same

Indenotriphenylene derivatives and organic light emitting device

using the same

Organic photovoltaic cell materials and components

Organic Light-emitting material, Organic Light-emitting element

using the same and method of forming the same

有機發光材料

有機太陽電池材料及有機太陽電池元件

VEGF-2/3受體及蛋白質酪胺酸激酶抑制劑及其醫藥用途

芳基胺化合物及應用該化合物之有机發光組件

茚并苯并菲衍生物及使用其的有机电致发光器件

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Following Patents and Publications for Reference:

•Patents



9

Ab

ou

t us

About us

•Publications

•

•

•

•

•

•

•

•

The improvement of efficiency and lifetime for organic light-emitting devices by using

a high Tg and heat-resistant hole injection material.

Asia Display 2007 ConferenceStable White OLED device using mixed dopant and simple process.

The 1st International Conference on Display LEDsEfficient Deep Blue, Blue, Green, Yellow, Reddish- Orange and Red Organic Light-

Emitting Device using 2,7-Dipyrenespirofluorene(DPSF) as a Fluorescent Emitting Host.

SID Symposium Digest of Technical Papers, 2007, V38, p883-887All-solution-processed blue small molecular organic light-emitting diodes with

multilayer device structure.

1. SID Symposium Digest of Technical Papers, 2009, V40, p1737-1739.

2. Organic Electronics, 2009, V10, p1610-1614

Highly efficient solution-processed red organic light-emitting diodes with longside-

chained triplet emitter. Synthetic Metals 161 (2011) 148–152Nanoscale Correlation between Exciton Dissociation and Carrier Transport in Silole-

Containing Cyclopentadithiophene-Based Bulk Heterojunction Films.

J. Phys. Chem. C 2011, 115, 2398–2405Molecular-weight-dependent nanoscale morphology in si lole-containing

cyclopentadithiophene polymer and fullerene derivative blends.

Organic Electronics, 2011, V12, p1755-1762Continuous blade coating for multi-layer large-area organic light-emitting diode and

solar cell. Journal of Applied Physics, 110, 094501 (2011)



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Organic Light Emitting Diode (OLED)Contents

• Introduction -------------------------------------------------------------------------11

• Hole Transport Layer / Electron Blocking Layer (HTL/EBL) Materials (47) ---------13

• Hole Injection Layer(HIL) Materials (28) --------------------------------------------22

• Phosphorescent Host Materials (79) ------------------------------------------------28

• Fluorescent Host Materials (31) -----------------------------------------------------42

• Green Dopant Materials (16) --------------------------------------------------------48

• Blue Dopant Materials (31) ----------------------------------------------------------51

• Red Dopant Materials (39) ----------------------------------------------------------57

• Electron Transport Layer / Hole Blocking Layer(ETL/HBL) Materials (37) ----------64

• Electron Injection Layer(EIL) Materials / Metal (5) ----------------------------------72



11

Organ

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)Organic Light Emitting Diode (OLED)

Introduction

　Organic light emitting diode (OLED) is a light-emitting diode (LED) whose emissive

electroluminescent layer is composed of a film of organic compounds.

　The first diode device was reported at Eastman Kodak by Dr. Ching W Tang and

Steven Van Slyke in 19871. This device used a novel two-layer structure with separate

hole transporting and electron transporting layers such that recombination and light

emission occurred in the middle of the organic layer. This resulted in a reduction in

operating voltage and improvements in

efficiency and led to the current area of OLED research and device production.

　There are two main families of OLED: those based on small molecules and those

employing polymers. Research into polymer electroluminescence culminated in 1990

with J. H. Burroughes et al. at the Cavendish Laboratory in Cambridge reporting a

high efficiency green light-emitting polymer based device using 100 nm thick films of

poly(p-phenylene vinylene). However multilayer OLEDs can be fabricated with two or

more layers in order to improve device efficiency.

　Another highly efficient white OLED device is to produce laminated structure. Kido

believes that contains a structural unit N brightness white OLED can achieve a single

OLED, N times, thus substantially increase the efficiency of the device.



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Organic Light Emitting Diode (OLED)Introduction

　OLED systems can be used in television screens, computer monitors, small portable

system screens such as cell phones and PDAs, advertising, information and indication.

OLEDs can also be used in light sources for general space illumination, and large area

light-emitting elements.

　Recently, researchers from Kyushu University that led by Chihaya Adachi

developed one kind of new OLED light-emitting fluorescent materials with 100%

internal quantum efficiency. They have established light emission principle called

thermally activated delayed fluorescence (TDAF) and worked on designing a material

to increase its luminous efficiency. TADF OLEDs are free from the heavy metals

used in phosphorescent emitters and so they could be cheaper and better for the

environment. It can expect that will be great development in the future.

1. C. W. Tang, S. A. VanSlyke, Appl. Phys. Lett. 1987, 51, 913.

　Advantages of OLED: 1. Much faster response time.

2. Consume significantly less energy.

3. Able to display "True Black" picture.

4. Wider viewing angles.

5. Thinner display.

6. Better contrast ratio.

7. Safer for the environment.

8. Has potential to be mass produced inexpensively.



13

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Hole Transport Layer / Electron Blocking Layer (HTL/EBL) Materials

NNNN

NN

CAS No.GradeFormulaM.W.UVPLTGA



: : : :: ::

: : : :: ::

: : : :: ::

123847-85-8Sublimed, > 99.5% (HPLC)C44H32N2

588.74 g/mole339 nm (in THF)450 nm (in THF)> 350 °C (0.5% weight loss)

139255-17-7Sublimed, > 99% (HPLC)C44H32N2




N,N' -Bis(naphthalen-1-yl)-N,N' -bis(phenyl)-benzidine

N,N' -Bis(naphthalen-2-yl)-N,N' -bis(phenyl)-benzidine

N,N' -Bis(3-methylphenyl)-N,N' -bis(phenyl)-benzidine




: : : :: ::

: : : :: ::

: : : :: ::







N,N' -Bis(3-methylphenyl)-N,N' -bis(phenyl)-2,7-diamino-9,9-spirobifluorene

N,N' -Bis(naphthalen-1-yl)-N,N' -bis(phenyl)-2,7-diamino-9,9-spirobifluorene

N,N' -Bis(3-methylphenyl)-N,N' -bis(phenyl)-2,7-diamino-9,9-dimethyl-fluorene

NN

N N

NN

LT-E102

LT-E105

LT-E106

LT-E109

LT-E103

LT-E101

β-NPB

Spiro-TPD

Spiro-NPB

DMFL-TPD

TPD

NPB



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Organ

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Organic Light Emitting Diode (OLED)Hole Transport Layer / Electron Blocking Layer (HTL/EBL) Materials

LT-E110 LT-E115

LT-E116

LT-N121

LT-E111

LT-E112

DMFL-NPB α-NPD

Spiro-TAD

NPAPF

DPFL-TPD

DPFL-NPB

NN

NN

NN

N N

N

NN

N

N N







: : : :: ::

: : : :: ::

: : : :: ::

: : : :: ::

: : : :: ::

: : : :: ::













N,N' -Bis(naphthalen-1-yl)-N,N' -bis(phenyl)-2,7-diamino-9,9-dimethyl-fluorene

N,N' -Bis(3-methylphenyl)-N,N' -bis(phenyl)-2,7-diamino-9,9-diphenyl-fluorene

N,N' -Bis(naphthalen-1-yl)-N,N' -bis(phenyl)-2,7-diamino-9,9-diphenyl-fluorene

N,N' -Bis(naphthalen-1-yl)-N,N' -bis(phenyl)-2,2'-dimethylbenzidine

2,2',7,7'-Tetrakis(N,N -diphenylamino)-2,7-diamino-9,9-spirobifluorene

9,9-Bis[4-(N,N -bis-naphthalen-2-yl-amino)phenyl]-9H-fluorene



15

Organ

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N N

N N

NN

NN

N

N

N

N


: : : :: ::



9,9-Bis[4-(N -naphthalen-1-yl-N -phenylamino)-phenyl]-9H-fluorene


: : : :: ::



2,2',7,7'-Tetrakis[N-naphthalenyl(phenyl)-amino]-9,9-spirobifluorene



: : : :: ::

: : : :: ::





N,N' -Bis(phenanthren-9-yl)-N,N' -bis(phenyl)-benzidine

2,2'-Bis[N,N-bis(biphenyl-4-yl)amino]-9,9-spirobifluorene


: : : :: ::



2,2'-Bis(N,N-di-phenyl-amino)-9,9-spirobifluorene

Reference : Adv. Mater. 2006, 18, 1216-1220.

N N

Reference : Journal of Applied Physics, Vol. 95, No.12, 7798


: : : :: ::



Di-[4-(N,N-di-p-tolyl-amino)-phenyl]cyclohexane

LT-N124 LT-N135

LT-N136

LT-N137

LT-N125

LT-N131

NPBAPF 2,2'-Spiro-DBP

Spiro-BPA

TAPC

Spiro-2NPB

PAPB



16

Organ

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)


N

NN

N

NN

NN

NN

NN



: : : :: ::

: : : :: ::





2,2',7,7'-Tetra(N,N-di-p-tolyl)amino-9,9-spirobifluorene

N,N,N',N' -Tetra-(3-methylphenyl)-3,3'-dimethylbenzidine

Reference : Adv. Funct. Mater. 2006, 16, 966-974.




: : : :: ::

: : : :: ::

: : : :: ::




688.86 g/mole345 nm (in CH2Cl2)462 nm (in CH2Cl2)> 370 °C (0.5% weight loss)


688.86 g/mole297,362 nm (in CH2Cl2)462 nm (in CH2Cl2)> 360 °C (0.5% weight loss)

N,N,N',N' -Tetra-naphthalen-2-yl-benzidine

N,N' -Di(naphthalenyl)-N,N' -di(naphthalen-2-yl)-benzidine

N,N,N',N' -Tetra-naphthalenyl-benzidine

LT-N138 LT-N141

LT-N142

LT-N143

LT-N139

LT-N140

Spiro-TTB α,β-TNB

α-TNB

β-NPP

β-TNB

HMTPD

NN


: : : :: ::



N,N' -Di(naphthalen-2-yl)-N,N' -diphenylbenzene-1,4-diamine



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Organ

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N

n

CAS No.GradeFormulaUVPLSolubility

: : : :: :

472960-35-3MW > 10,000 (GPC)(C22H21N)n

371,388 nm (in CH2Cl2)424 nm (in CH2Cl2)Soluble in CHCl3, Chlorobenzene

Poly[N,N' -bis(4-butylphenyl)-N,N' -bis(phenyl)-benzidine]

Reference : J. Mater. Chem., 2012, 22, 22769-22773

N N

NN

N

N

N

N

C8H17 C8H17

N

n


: : : :: :

220797-16-0MW > 30,000 (GPC)(C51H61N)n

389 nm (in CH2Cl2) 443 nm (in CH2Cl2)Soluble in CH2Cl2,Toluene, CHCl3

Poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(4,4'-(N-(4-sec-butylphenyl) diphenylamine)]

Reference : Synthetic Metals 160 (2010) 2393-2396


: : : :: ::


626.75 g/mole287, 368 nm (in CH2Cl2)431 nm (in CH2Cl2)> 390 °C (0.5% weight loss)

Tris(4-(quinolin-8-yl)phenyl)amine

Reference : Chem. Mater. 2009, 21, 1284-1287



: : : :: ::

: : : :: ::





N1,N4-Diphenyl-N1,N4-di-m-tolylbenzene-1,4-diamine

N2,N2,N6,N6-Tetraphenylnaphthalene-2,6-diamine

LT-N144 LT-N148

LT-N149LT-N145

LT-N146

TTP TFB

Poly-TPDNDDP

TQTPA

NN

C8H17 C8H17


: : : :: ::

870197-09-4> 99% (HPLC)C61H64N2


N2,N7-Di(naphthalen-1-yl)-9,9-dioctyl-N2,N7-diphenyl-9H-fluorene-2,7-diamine

LT-N154 DOFL-NPB



18

Organ

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)


NN

C8H17 C8H17


: : : :: ::

439942-97-9> 99% (HPLC)C55H64N2


N,N' -Bis(3-methylphenyl)-N,N' -bis(phenyl)-9,9-dioctyl-fluorene

N N

CAS No.GradeFormulaM.W.UVPL

: : : :: :

1010396-31-2> 95% (HPLC)C48H36N2

640.81 g/mole339 nm (in THF)450 nm (in THF)

N4,N4'-Di(naphthalen-1-yl)-N4,N4'-bis(4-vinylphenyl)biphenyl-4,4'-diamine

LT-N155

LT-N157

LT-N158

DOFL-TPD

VNPB

ONPB

N N

C8H17

Reference : Journal of Photopolymer Science andTechnology, Vol, 25, 3(2012) 335-339


: : : :: ::

1431521-16-2> 99% (HPLC)C52H48N2

700.95 g/mole347 nm (film)439 nm (film)> 300 °C (0.5% weight loss)

N4,N4'-Di(naphthalen-1-yl)-N4-(4-octylphenyl)-N4'-phenylbiphenyl-4,4'-diamine

NN

O

O

O

O

Reference : 1. Adv. Mater. 2006, 18, 948-9542. Appl. Phys. Lett. 91, 103507(2007)


: : : :: :

746634-00-4> 99% (HPLC)C60H72N2O4

885.22 g/mole308, 353 nm (in CH2Cl2)410 nm (in CH2Cl2)

N4,N4'-Bis(4-(6-((3-ethyloxetan-3-yl)methoxy)hexyl) phenyl)-N4,N4'-diphenylbiphenyl-4,4'-diamine

LT-N159 OTPD

N4,N4'-Bis(4-(6-((3-ethyloxetan-3-yl)methoxy)hexyloxy)phenyl)-N4,N4'-bis(4-methoxyphenyl)biphenyl-4,4'-diamine



: : : :: :

864130-79-0> 99% (HPLC)C62H76N2O8

945.28 g/mole353 nm (in CH2Cl2)439 nm (in CH2Cl2)

N N

O O

O O

OO

O O

LT-N160 QUPD



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Organ

ic Light Em

itting D

iod

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: : : :: :

1173170-48-3> 95% (HPLC)C75H56N2O2


9,9-Bis[4-[(4-ethenylphenyl)methoxy]phenyl]-N2,N7-di-1-naphthalenyl-N2,N7-diphenyl-9H-fluorene-2,7-diamine


GradeFormulaM.W.UV

: : ::

> 99% (HPLC)C64H72F6N2O4

1047.26 g/mole300 nm (in CH2Cl2)

N,N' -(4,4'-(Cyclohexane-1,1-diyl)bis(4,1-phenylene))bis(N-(4-(6-(2-ethyloxetan-2-yloxy)hexyl)phenyl)-3,4,5-trifluoroaniline)

Reference : Adv. Funct. Mater. 2013, 23, 359–365

N N

F

F

FF

F

F

OO

O O

NN


: : : :: ::



4,4'-(Diphenylmethylene)bis(N,N-diphenylaniline)

LT-N162

LT-N164

LT-N165

TCBPA

VB-FNPD

X-F6-TAPC

NN

O O


: : : :: ::



N4,N4'-Bis(9,9-dimethyl-9H-fluoren-2-yl)-N4,N4'-diphenylbiphenyl-4,4'-diamine

N N

LT-N002

LT-N1002

Ir(ppz)3

BF-DPB

NN

Ir

NN

NN

Reference : 1. Applied Physics Letters, 86, 263502 (2005)2. Advanced Materials, Volume 16, (2004)


: : : :: ::

562824-31-1Sublimed, > 99% (HPLC)C27H21N6Ir621.71 g/mole242, 320 nm (in THF)423 nm (in THF)> 270 °C (0.5% weight loss)

Tris(phenylpyrazole)iridium



20

Organ

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)


Reference : J. Mater. Chem. C, 2014,2, 3270-3277

CAS No.GradeFormula

: ::

1345045-27-3MW > 20,000 (GPC)(C70H102N2O4)nC12H10

6,6'-(9',9'-Bis(6-((3-ethyloxetan-3-yl)methoxy)hexyl)-7,7'-diphenyl-9H ,9'H-2,2'-bifluorene-9,9-diyl)bis(N,N-diethylhexan-1-amine)

LT-N177 PFN-OX

O O

O O

N N

n

CAS No.GradeFormulaM.W.TGA

: :: ::

1303951-71-4> 99% (HPLC)C45H39N593.8 g/mole> 150 °C (0.5% weight loss)

Tris(9,9-dimethylfluoren- 2-yl)amine

LT-N179 TFlA

N


: :: ::

6543-20-0> 99% (HPLC)C36H27N473.61 g/mole> 150 °C (0.5% weight loss)

Tri(biphenyl-4-yl)amine

LT-N178 TBA

Reference : Australian Journal of Chemistry (2009), 62(5), 483-492

N

N

N

N

N

Reference : 1. J.Appl.Phys.100,064507(2006)2. Synthetic Metals,148(2005)205-211

Reference : Synthetic Metals (2013), 167, 1-4

GradeFormulaM.W.Solubility



: :::

: :: ::::

: :: ::::

MW > 20,000 (GPC)(C37H50I2N4S)n

670.91 g/moleSoluble in CHCl3, Chlorobenzene, Dichlorobenzene

205327-13-5> 99% (HPLC)C48H38N2Si670.91 g/mole309 nm (in CH2Cl2)376 nm (in CH2Cl2)> 180 °C (0.5% weight loss)

302344-41-8> 99% (HPLC)C81H68N4


Poly(9,9-bis(6-trimethyl ammoniumiodide)-hexyl-fluorene-2,7-diyl-alt(benzo[2,1,3]thiadiazol-4,7-diyl))

4,4'-(Diphenylsilanediyl)bis(N,N-diphenylaniline)

2,2',7,7'-Octa(m-tolylamine)-9,9-spirobifluorene

Si NN

LT-N181

LT-N182

LT-N180

PFNIBT

TSBPA

Spiro-mTTB

NN

NSN

n

II



21

Organ

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Reference : Dalton Transactions (2015), 44(33), 14613-14624


: :: ::::



4,4'-(9H-fluoren-9-ylidene)bis[N,N-bis(4-methylphenyl)- benzenamine

LT-N183 DTAF

N N



22

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)

Organic Light Emitting Diode (OLED)Hole Injection Layer(HIL) Materials

Reference :

Reference :

Reference :

1. Journal of Nanoscience and Nanotechnology (2014), 14(8), 6404-64082.Applied Mechanics and Materials (2014), 536-537

1. Journal of Nanoscience and Nanotechnology (2014), 14(8), 6404-64082.Synthetic Metals (2015), 203, 174-179

1. Advanced Materials (Weinheim, Germany) (2014), 26(6), 878-8852.Organic Electronics (2010), 11(4), 564-572

N

N

N

N

N

N

N

N Cu





: : : :: ::

: : : :: ::

: : : :: ::

: : : :: ::

147-14-8Sublimed, > 99%C32H16N8Cu576.07 g/mole345, 631 nm (in CH2Cl2)404 nm (film)> 430 °C (0.5% weight loss)


789.02 g/mole312, 342 nm (in THF)425 nm (in THF)> 350 °C (0.5% weight loss)





Copper(II) phthalocyanine

4,4',4" -Tris(N-3-methylphenyl-N-phenyl-amino)triphenylamine

4,4',4" -Tris(N-(naphthalen-2-yl)-N-phenyl-amino)triphenylamine

4,4',4" -Tris(N-(naphthalen-1-yl)-N-phenyl-amino)triphenylamine

LT-E201

LT-E202

LT-E203

LT-E204

CuPC

m-MTDATA

2T-NATA

1T-NATA

N

N

N

N

N

N

N

N

N

N

N

N



23

Organ

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Hole Injection Layer(HIL) Materials

N

N N

N

NC

NC

N N

O

OO

O

N N

O

O O

O


: : : :: ::



Pyrazino[2,3-f ][1,10]phenanthroline-2,3-dicarbonitrile

Reference : 1. J.Appl.Phys.100,064507(2006)2. Synthetic Metals,148(2005)205-211


: : : :: ::

244260-36-4Sublimed, > 99% (HPLC)C40H36N2O4


N,N,N',N' -Tetrakis(4-methoxyphenyl)benzidine


: : : :: ::



2,7-Bis[N,N-bis(4-methoxy-phenyl)amino]-9,9-spirobifluorene

LT-N211

LT-N212

LT-N213

PPDN

MeO-TPD

MeO-Spiro-TPDN

N

N

N

N

N

N

N TiO

CN

CN

NC

NC

FF

FF


: : : :: ::

26201-32-1Sublimed, > 99%C32H16N8OTi576.39 g/mole349, 689 nm (in CH2Cl2)392 nm (in film)> 440 °C (0.5% weight loss)

Titanium(IV) oxide phthalocyanine


: : : :: ::

29261-33-4Sublimed, > 99%C12F4N4


2,3,5,6-Tetrafluoro-7,7,8,8-tetracyano-quinodimethane

Reference : J. Appl. Phys. 103, 043105(2008)

LT-E206

LT-E208

TiOPC

F4-TCNQ

Reference : 1. Applied Physics Letters (2004), 85(21), 4848-48502. Advanced Functional Materials (2001), 11(4), 310-314


: : : :: ::



4,4',4" -Tris(N,N-diphenyl-amino)triphenylamine

LT-E205 NATA

N

N

N

N



24

Organ

ic Light Em

itting D

iod

e (OLED

)


N

N

O

O

O

O

NN

N

N

NN

N

N


: : : :: ::



2,2'-Bis[N,N-bis(4-methoxy-phenyl)amino]-9,9-spirobifluorene



: : : :: ::

: : : :: ::





N,N' -Diphenyl-N,N' -di-[4-(N,N-di-p-tolyl-amino)phenyl]benzidine

N,N' -Diphenyl-N,N' -di-[4-(N,N-diphenyl-amino)phenyl]benzidine

LT-N214

LT-N215

LT-N2162,2'-MeO-Spiro-TPD

NTNPB

NPNPB

N

NN

N

N

N

N

NPt


: : : :: ::

14075-08-2Sublimed, > 99%C32H16N8Pt707.60 g/mole228, 270 nm (in CH2Cl2)372.5 nm (in CH2Cl2)> 460 °C (0.5% weight loss)

Platium(II) phthalocyanine

N N

N N


: : : :: ::



N4,N4'-(Biphenyl-4,4'-diyl)bis(N4,N4',N4'-triphenylbiphenyl-4,4'-diamine)

LT-N218

LT-N219

TPT1

PtPC



25

Organ

ic Light Em

itting D

iod

e (OLED



NN

N

N N

N

NC CN

NC

NC CN

CN

NNH

N

NN

HNN

N

NN

N

N N

N

NN

N

N N

N

Cl Cl

Cl

ClCl

Cl



: : : :: ::

: : : :: ::

105598-27-4Sublimed, > 99% (HPLC)C18N12


389121-44-2Sublimed, > 99% (HPLC)C24H6N6Cl6591.06 g/mole305 nm (in CH2Cl2)425 nm (in CH2Cl2)> 350 °C (0.5% weight loss)

Reference : J. Mater. Chem. C, 2013, 1, 3967–3975 Reference : Chem. Eur. J. 2007, 13, 3537 – 3547

Dipyrazino[2,3-f :2',3'-h]quinoxaline-2,3,6,7,10,11-hexacarbonitrile

2,3,8,9,14,15-Hexachlorodiquinoxalino[2,3-a :2',3'-c ]phenazine


: : : :: ::

574-93-6Sublimed productC32H18N8


Phthalocyanine


: : : :: ::



Diquinoxalino[2,3-a :2',3'-c ]phenazine

Reference : Chem. Eur. J. 2007, 13, 3537 – 3547

LT-N224

LT-N225

LT-N226

LT-N221

LT-N222

HATNA

HATNA-Cl6

HATNA-F6

HAT-CN

H2PC

NN

N

N N

N

F F

F

FF

F


: : : :: :

872140-95-9Sublimed, > 99% (HPLC)C24H6N6F6


2,3,8,9,14,15-Hexafluorodiquinoxalino[2,3-a :2',3'-c ]phenazine

Reference : Chem. Eur. J. 2007, 13, 3537 – 3547

NN

C8H17 C8H17

NN

N2,N2'-(9,9-Dioctyl-9H-fluorene-2,7-diyl)bis(9,9- dimethyl-N2,N7,N7-triphenyl-9H-fluorene-2,7-diamine

GradeFormulaM.W.UVPL

: : : ::

> 97% (HPLC)C95H94N4


LT-N260 3FTPD-C8



26

Organ

ic Light Em

itting D

iod

e (OLED

)


GradeFormulaM.W.

: ::

> 99%C16H17IN2O380.22 g/mole

2-(2-Methoxyphenyl)-1,3-dimethyl-1H-benzoimidazol-3-ium iodide

N

NO

I

NC

NC CN

CN


: : : ::

6251-01-0> 99%C16H6N4

254.25 g/mole> 150 °C (0.5% weight loss)

2,2'-(Naphthalene-2,6-diylidene)dimalononitrile

LT-N261

LT-N262

MeOPBI

TNAP

Reference : Journal of Physical Chemistry C (2014), 118(10), 5284-5293


: : : ::



Reference : Adv. Funct. Mater.2012, 22,(2),405–414

N4,N4'-(Biphenyl-4,4'-diyl)bis(N4'-(naphthalen-1-yl)-N4,N4'-diphenylbiphenyl-4,4'-diamine)

NN

N N


: : : :: ::



N2,N2'-(9,9-Dimethyl-9H-fluorene-2,7-diyl)bis(9,9-dimethyl-N2,N7,N7-triphenyl-9H-fluorene-2,7-diamine)

NN

N N

LT-N2001

LT-N2002

Di-NPB

3DMFL-BPA


: : : :: ::



N1,N1'-(Biphenyl-4,4'-diyl)bis(N1-(naphthalen-1-yl)-N4,N4-diphenylbenzene-1,4-diamine)

NN

N N

LT-N2003 NPB-DPA



27

Organ

ic Light Em

itting D

iod

e (OLED




: : : :: ::



N1,N1'-(Biphenyl-4,4'-diyl)bis(N1-(naphthalen-2-yl)-N4,N4-diphenylbenzene-1,4-diamine)

NN

N N

CAS No.GradeFormulaM.W.UVTGA

: : : :::

1518-16-7Sublimed, > 99%C12H4N4

204.19 g/mole259, 404 nm (in CH2Cl2)> 210 °C (0.5% weight loss)

7,7,8,8-Tetracyanoquinodimethane

NC CN

CNNC

LT-N2004

LT-S973

β- NPB-DPA

TCNQ



28

Organ

ic Light Em

itting D

iod

e (OLED

)

Organic Light Emitting Diode (OLED)Phosphorescent Host Materials

NN

N

N

N

N

N

N

N

NN

N N

NN






: : : :: ::

: : : :: ::

: : : :: ::

: : : :: ::

: : : :: ::






512.64 g/mole292, 340 nm (in THF)349, 364 nm (in THF)> 280 °C (0.5% weight loss)





1,3-Bis(carbazol-9-yl)benzene 4,4'-Bis(carbazol-9-yl)biphenyl

4,4'-Bis(carbazol-9-yl)-2,2'-dimethylbiphenyl

2,7-Bis(carbazol-9-yl)-9,9-dimethylfluorene

1,3,5-Tris(carbazol-9-yl)benzene

Reference : Physical Chemistry Chemical Physics (2013), 15(38), 15850-15855.


: : : :: ::



4,4',4"-Tris(carbazol-9-yl)triphenylamine

LT-E107 LT-E409

LT-E414

LT-N415

LT-E108

LT-E207

MCP CBP

CDBP

DMFL-CBP

TCP

TcTa



29

Organ

ic Light Em

itting D

iod

e (OLED


Phosphorescent Host Materials

NN

N N

NN

N N

N N

Si Si

SiSi




: : : :: ::

: : : :: ::

: : : :: ::




646.78 g/mole293,343 nm (in THF)367 nm (in THF)> 360 °C (0.5% weight loss)



2,2',7,7'-Tetrakis(carbazol-9-yl)-9,9-spirobifluorene 2,7-Bis(carbazol-9-yl)-9,9-spirobifluorene

2,7-Bis(carbazol-9-yl)-9,9-ditolylfluorene


: : : :: ::



9,9-Bis[4-(carbazol-9-yl)-phenyl]fluorene

Reference : 1. Applied Physics Letters, 86, 263502 (2005)2. Chem. Mater. 2004, 16, 4743-4747


: : : :: ::

40491-34-7Sublimed, > 99% (HPLC)C42H34Si2594.89 g/mole265 nm (in CH2Cl2)296 nm (in CH2Cl2)> 270 °C (0.5% weight loss)

1,4-Bis(triphenylsilyl)benzene


: : : :: ::

18920-16-6Sublimed, > 99% (HPLC)C42H34Si2594.89 g/mole265 nm (in THF)301, 418 nm (in THF)> 270 °C (0.5% weight loss)

1,3-Bis(triphenylsilyl)benzene


LT-N416 LT-N420

LT-N448

LT-N449

LT-N418

LT-N419

Spiro-CBP Spiro-2CBP

UGH-2

UGH-3

DPFL-CBP

FL-2CBP



30

Organ

ic Light Em

itting D

iod

e (OLED

)


NN

Si Si

Si Si

N

Si

Si




: : : :: ::

: : : :: ::

: : : :: ::

848900-30-1> 99% (HPLC)C53H56N2


1046146-39-7Sublimed, > 99% (HPLC)C54H42Si2747.08 g/mole296 nm (in CH2Cl2)358 nm (in CH2Cl2)> 360 °C (0.5% weight loss)

18826-13-6Sublimed, > 99%C48H38Si2670.99 g/mole271 nm (in CH2Cl2)432 nm (in CH2Cl2)> 320 °C (0.5% weight loss)

2,7-Bis(carbazol-9-yl)-9,9-dioctylfluorene

4,4''-Di(triphenylsilyl)-p-terphenyl

4,4'-Di(triphenylsilyl)-biphenyl


Reference : Adv. Funct. Mater. 2008, 18, 485

Reference : Adv. Funct. Mater. 2008, 18, 485Reference : 1. Appl. Phys. Lett. Vol. 85, No. 21, 22

November 20042. Appl. Phys. Lett. 87, 193501 (2005)


: : : :: ::

70895-80-6> 99% (HPLC)C30H40N2


Bis(4-N,N-diethylamino-2-methylphenyl)-4-methylphenylmethane


: : : :: ::

898546-82-2Sublimed, > 99%C58H49NSi2816.19 g/mole275,301 nm (in CH2Cl2)354 nm (in CH2Cl2)> 320 °C (0.5% weight loss)

Reference : Adv. Mater. 2006, 18, 1216

9-(4-tert -Butylphenyl)-3,6-bis(triphenylsilyl)-9H-carbazole

N N

C8H17 C8H17

LT-N450 LT-N483

LT-N484

LT-N451

LT-N482

MPMP BSB

CzSi

DOFL-CBP

BST

N


: : : :: ::

956373-04-9Sublimed, > 99%C60H49N784.04 g/mole277,305 nm (in CH2Cl2)369 nm (in CH2Cl2)> 330 °C (0.5% weight loss)

9-(4-tert-Butylphenyl)-3,6-ditrityl-9H-carbazole

Reference : Appl. Mater. Interfaces, 2009, 1(3), 567–574

LT-N485 CzC



31

Organ

ic Light Em

itting D

iod

e (OLED



LT-N497 SimCP

Si

N N


: : : :: ::

850221-63-5Sublimed, > 99% (HPLC)C48H34N2Si666.88 g/mole293, 312, 345 nm (in THF)446 nm (in THF)> 300 °C (0.5% weight loss)

9,9'-(5-(Triphenylsilyl)-1,3-phenylene)bis(9H-carbazole)

Reference : Adv. Mater., 17, 285, 2005

NN

N

N OO


: : : :: ::

871018-07-4Sublimed, > 99%C62H49NO2


Reference : Org. Lett., Vol. 7, No. 24, 2005

9-(4-tert -Butylphenyl)-3,6-bis(9-(4-methoxyphenyl)-9H-fluoren-9-yl)-9H-carbazole

NNN


: : : :: ::



2,6-Bis(3-(9H-carbazol-9-yl)phenyl)pyridine

Reference : Chem. Mater. 2008, 20, 1691–1693

Reference : Advanced Functional Materials (2009), 19, (16), 2661-2670


: : :: :::



9,9-Dimethyl-N,N-diphenyl-7-(4-(1-phenyl-1H-benzo[d ]imidazol-2-yl)phenyl)-9H-fluoren-2-amine

N

NN

P O



: : : :: ::

: : : :: ::



1125547-88-7Sublimed, > 99% (HPLC)C37H25OP516.57 g/mole307, 317 nm (in CH2Cl2)346 nm (in CH2Cl2)> 290 °C (0.5% weight loss)


9,9-Spirobifluoren-2-yl-diphenyl-phosphine oxide


Reference : Appl. Phys. Lett. 94, 013301 2009

LT-N486 LT-N494

LT-N496

LT-N491

LT-N493

DFC 35DCzPPy

SPPO1

26DCzPPy

EFIN



32

Organ

ic Light Em

itting D

iod

e (OLED

)


S

P POO


: : : :: ::

1019842-99-9Sublimed, > 99% (HPLC)C36H26O2P2S584.60 g/mole315, 328 nm (in CH2Cl2)351 nm (in CH2Cl2)> 320 °C (0.5% weight loss)

2,8-Bis(diphenylphosphoryl)dibenzo[b,d]thiophene

Reference : J. Mater. Chem., 2011, 21, 14604–14609

Si


: : : :: :

18849-24-6Sublimed, > 99% (HPLC)C26H24Si364.55 g/mole265 nm (in CH2Cl2)298 nm (in CH2Cl2)

Bis(2-methylphenyl)diphenylsilane

Reference : Chem. Mater., 2004, 16, 4743-4747

N

N N

N N


: : : :: ::


510.59 g/mole280, 335, 364 nm (in THF)425 nm (in THF)> 340 °C (0.5% weight loss)

4,7-Di(9H-carbazol-9-yl)-1,10-phenanthroline

Reference : Appl. Mater. 2009, 21, 688-692


: : : :: ::

1131007-94-7Sublimed, > 99% (HPLC)C63H51N822.09 g/mole311 nm (in Toluene)375 nm (in Toluene)> 320 °C (0.5% weight loss)

Reference : Org. Lett., Vol. 11, No. 7, 2009, 1503-1506

4,4,8,8,-12,12-Hexa-p-tolyl-4H-8H-12H-12C-aza-dibenzo[cd,mn]pyrene

LT-N499

LT-N4006

LT-N4008

LT-N4001

FATPA

PPT

UGH-1

BUPH1


: : : :: ::

944465-42-3Sublimed, > 99% (HPLC)C72H48N4Si977.26 g/mole324, 338 nm (in CH2Cl2)362 nm (in CH2Cl2)> 380 °C (0.5% weight loss)

Bis[3,5-di(9H-carbazol-9-yl)phenyl]diphenylsilane

Reference : J. Mater. Chem. 2010, 20, 8411-8416

Si

N

N N

N

LT-N4009 SimCP2


: : : :: ::



3,6-Bis(carbazol-9-yl)-9-(2-ethyl-hexyl)-9H-carbazole

Reference : Applide physics letters, 96, 093304, 2010

N

NN

LT-N4010 TCz1



33

Organ

ic Light Em

itting D

iod

e (OLED



LT-N4015 SPPO13

PO

PO


: : : :: ::

1234510-13-4> 99% (HPLC)C49H34O2P2


2,7-Bis(diphenylphosphoryl)-9,9'-spirobifluorene

Reference : Thin Solid Films 519 (2010) 906-910


: : : :: ::

1233407-28-7Sublimed, > 99% (HPLC)C42H29N2OP608.67 g/mole292 nm (in CH2Cl2)391 nm (in CH2Cl2)> 360 °C (0.5% weight loss)

Bis-4-(N-carbazolyl)phenyl)phenylphosphine oxide

Reference : Adv. Mater. 2010, 22, 2468–2471

N N

P

N N

O


: : : :: ::

166256-60-6> 99% (HPLC)C32H24N2

436.55 g/mole293 nm (in CH2Cl2)351, 366 nm (in CH2Cl2)> 230 °C (0.5% weight loss)

1,4-Bis((9H-carbazol-9-yl)methyl)benzene

Reference : Appl. Phys. 41 (2008) 105114-105117

LT-N4016

LT-N4017

DCB

BCPO

N P

PO

O


: : : :: ::

1226860-68-9Sublimed, > 99% (HPLC)C42H31NO2P2

643.65 g/mole294, 338 nm (in CH2Cl2)361 nm (in THF)> 300 °C (0.5% weight loss)

Reference : Adv. Mater. 2010, 22, 1-5

3-(Diphenylphosphoryl)-9-(4-(diphenylphosphoryl)phenyl)-9H-carbazole


: : : :: ::

1201649-79-7Sublimed, > 99% (HPLC)C54H37N699.88 g/mole260 nm (in CH2Cl2)390 nm (in CH2Cl2)> 360 °C (0.5% weight loss)

3,6-Bis[(3,5-diphenyl)phenyl]-9-phenyl-carbazole

Reference : Chem. Commun, 2009, 6655-6657

N

LT-N4014

LT-N4011

LT-N4012

ADBP

PPO21

CzTP


: : : :: ::

1188546-10-2Sublimed, > 99% (HPLC)C37H26N2O514.62 g/mole375, 394 nm (in CH2Cl2)408 nm (in CH2Cl2)> 310 °C (0.5% weight loss)

10-(4'-(Diphenylamino)biphenyl-4-yl)acridin-9(10H)-one

Reference : Org. Lett. , Vol. 11, No. 19, 2009

N ON



34

Organ

ic Light Em

itting D

iod

e (OLED

)


C8H17 C8H17 n

NN


: : : :: :

673474-74-3MW > 10,000 (GPC)(C52H70N2)n

378 nm (in CH2Cl2) 414 nm (in CH2Cl2)Soluble in CH2Cl2, CHCl3, Toluene

Poly[(9,9-bis(3'-(N,N-dimethylamino)propyl)-2,7-fluorene)-alt-2,7-(9,9-dioctylfluorene)]

Reference : Chem. Mater. , Vol. 16, No. 4, 2004

PO

PO

N

Reference : Advanced Functional Materials (2009), 19, (17), 2834-2843


: : : :: ::



2,7-Bis(diphenylphosphoryl)-9-(4-diphenylamino)phenyl-9'-phenyl-fluorene

NPO

PO


: : : :: ::



2,7-Bis(diphenylphosphoryl)-9-phenyl-9H-carbazole

Reference : J. Mater. Chem. , 2011, 21, 5638-5644

LT-N4025

LT-N4027

LT-N4018

PPO27

PFN-DOF

POAPF



: : : :: ::

: : : :: ::

1415633-86-1> 98% (HPLC)C74H53N2OP1017.20 g/mole349 nm (in CH2Cl2)466 nm (in CH2Cl2)> 320 °C (0.5% weight loss)

824426-27-9Sublimed, > 99% (HPLC)C56H35OP754.85 g/mole275 nm (film)365 nm (film)> 350 °C (0.5% weight loss)

Reference : Chem. Eur. J. 2012, 18, 13828-13835

Reference : Appl. Phys. Lett. 91, 103507(2007)

4'' ,4'''-(Phenylphosphoryl)bis(N-1-naphthyl-N-phenyl-1,1':4',1''-terphenyl-4-amine)

Di(9,9-spirobifluoren-2-yl)-phenyl-phosphine oxide

PO

PN NO3 3

LT-N4035

LT-N4034

NP3PPO

Dspiro-PO

PO

PO


: : : :: ::

1270960-64-9Sublimed, > 99% (HPLC)C53H36O2P2


Reference : Thin Solid Films 519 (2011) 4342–4346

2,7-Bis(diphenylphosphoryl)spiro[fluorene-7,11'-benzofluorene]

LT-N4029 SPPO21



35

Organ

ic Light Em

itting D

iod

e (OLED




: : : :: ::



Reference : Org. Lett. , 2011, 13, 3146-3149

9-(3,5-Bis(diphenylphosphoryl)phenyl)-9H-carbazole

LT-N4039 CzPO2

N

P PO O

Reference : Adv. Mater., 2012, 24, 1873-1877

6-(3',6'-Di-tert-butyl-6-(3,6-di-tert-butyl-9H -carbazol-9-yl)-9H-3,9'-bicarbazol-9-yl)-9-(4-(3',6'-di-tert-butyl-6-(3,6-di-tert-butyl-9H -carbazol-9-yl)-9H -3,9'-bicarbazol-9-yl)phenyl)-3',6'-bis(3,6-di-tert-butyl-9H -carbazol-9-yl)-9H -3,9'-bicarbazole


: : : :::

1025079-68-8> 98% (HPLC)C174H172N10


N

N

NN

N N

N

N N

N

LT-N4041 G3-tCbz


: : : :: ::

1415633-87-2> 98% (HPLC)C86H61N2OP1169.39 g/mole347 nm (in CH2Cl2)471 nm (in CH2Cl2)> 450 °C (0.5% weight loss)


4''' ,4''''-(Phenylphosphoryl)bis(N-1-naphthyl-N-phenyl-1,1':4',1'':4'',1'''-quaterphenyl-4-amine)

HO

N

H

n

GradeFormulaUVSolubility

: : ::

MW > 10000 (GPC)(C17H17NO)n

237, 263 nm (in CH2Cl2)Soluble in CHCl3, Chlorobenzene, Dichlorobenzene

Poly[3-(carbazol-9-ylmethyl)-3-methyloxetane]


LT-N4036

LT-N4037

LT-N4038

NP4PPO

PCMO

PCOC

HO

N

N

H

n


GradeFormulaUVPLSolubility

: : : ::

MW > 10000 (GPC)(C29H24N2O)n

238, 265 nm (in CH2Cl2)382 nm (in CH2Cl2)Soluble in CHCl3, Chlorobenzene, Dichlorobenzene

Poly[3-(carbazol-9-yl)-9-(3-methyloxetan-3-ylmethyl)carbazole]

PN NO4 4



36

Organ

ic Light Em

itting D

iod

e (OLED

)


N

N N

NN

N

N


: : : :: ::


484.59 g/mole241, 292 nm (in CH2Cl2) 363 nm (in CH2Cl2)> 270 °C (0.5% weight loss)

3,5-Di(9H-carbazol-9-yl)biphenyl

LT-N4042 Ph-MCP


: : : :: ::


779.93 g/mole299 nm (in CH2Cl2) 392 nm (in CH2Cl2)> 350 °C (0.5% weight loss)


9-Phenyl-3,6-bis(4-(1-phenyl-1H-benzo[d]imidazol-2-yl)phenyl)-9H-carbazole

LT-N4046 CNBzIm

N NP O

Reference : 1. Organic Electronics 12 (2011) 1711-17152. Adv. Mater. 2011, 23, 1436-1441


: : : :: ::

1296229-26-9Sublimed, > 99% (HPLC)C42H29N2OP608.67 g/mole324, 338 nm (in CH2Cl2)361 nm (in CH2Cl2)> 270 °C (0.5% weight loss)

9-(3-(9H-Carbazol-9-yl)phenyl)-3-(diphenylphosphoryl)-9H-carbazole

LT-N4047 mCPPO1

PO


: : : :: ::

1349901-36-5Sublimed, > 99% (HPLC)C36H24NO2P533.56 g/mole291, 338 nm (in CH2Cl2)392 nm (in CH2Cl2)> 300 °C (0.5% weight loss)

Reference : Chem. Asian J. 2011, 6, 2895-2898

9-(8-(Diphenylphosphoryl)dibenzo[b,d]furan-2-yl)-9H-carbazole

LT-N4050 DFCzPO


: : : :: ::

1314243-72-5Sublimed, > 99% (HPLC)C37H25OP516.57 g/mole273, 309, 323 nm (in CH2Cl2)346 nm (in CH2Cl2)> 250 °C (0.5% weight loss)

Reference : Organic Electronics 11 (2010) 1059–1065

9,9-Spirobifluoren-4-yl-diphenyl-phosphineoxide

LT-N4049 SPPO11

O

N PO

Si P O


: : : :: ::

1286708-86-8Sublimed, > 99% (HPLC)C36H29OPSi536.67 g/mole266 nm (in CH2Cl2)298 nm (in CH2Cl2)> 300 °C (0.5% weight loss)


Diphenyl-4-triphenylsilylphenyl-phosphine oxide

LT-N4048 TSPO1



37

Organ

ic Light Em

itting D

iod

e (OLED



S N

N


: : : :: ::

1421599-23-6Sublimed, > 99% (HPLC)C29H18N2S426.53 g/mole291, 339 nm (in CH2Cl2)365 nm (in CH2Cl2)> 270 °C (0.5% weight loss)

Reference : Chem. Commun., 2013, 49, 1446-1448

3-(3-(9H-Carbazol-9-yl)phenyl)benzo[4,5]thieno[2,3-b ]pyridine

LT-N4058 BTP1

Nn

F F

OP PO O



:: : : ::

: : : :: ::

1227083-33-1MW > 30,000 (GPC)(C14H9F2N)n




Reference : J Phys. Chem. C 2012, 116, 20681-20687


Poly[9-sec-butyl-2,7-difluoro-9H-carbazole]

Bis[2-(diphenylphosphino)phenyl]ether oxide

LT-N4062

LT-N4060

2,7-F-PVF

DPEPO



: : : :: ::

: : : :: ::

1268162-33-9Sublimed, > 99% (HPLC)C24H17O2P368.36 g/mole288 nm (in CH2Cl2)328 nm (in CH2Cl2)> 320 °C (0.5% weight loss)





Dibenzofuran-4-yl-diphenyl-phosphine-oxide

9,9-Di(9-methyl-carbazol-3-yl)-4,5-diazafluoren

LT-N4051

LT-N4052

DBFPPO

MCAF

N N

N N

OPO

NO

N


: : : :: ::

1424369-36-7Sublimed, > 99% (HPLC)C29H18N2O410.47 g/mole241, 293 nm (in CH2Cl2)364 nm (in CH2Cl2)> 270 °C (0.5% weight loss)


3-(3-(9H-Carbazol-9-yl)phenyl)benzofuro[2,3-b]pyridine

LT-N4057 PCz-BFP



38

Organ

ic Light Em

itting D

iod

e (OLED

)



: : : :: :

1428901-78-3> 99% (HPLC)C54H40N2O2


Reference : Organic Electronics, 14, 2013, 1614–1620

4,4'-Bis(3-((4-vinylphenoxy)methyl)-9H-carbazol-9-yl)biphenyl

N N

O

O

LT-N4063 DV-CBP


: : : :: ::



3,3'-Di(9H-carbazol-9-yl)biphenyl

LT-N4069 m-CBP


N

N

Nn


: : : :: :

25067-59-8MW > 20,000 (GPC)(C14H11N)n

261, 294 nm (in CH2Cl2)380 nm (in THF)Soluble in CHCl3, Chlorobenzene, Dichlorobenzene

Poly(9-vinylcarbazole)

LT-N4077 PVK

NN N



: : : :: ::

: : : :: ::




409.48 g/mole241,290 nm (in CH2Cl2)373 nm (in THF)> 250 °C (0.5% weight loss)

9-(4-(9H-Pyrido[2,3-b]indol-9-yl)phenyl)-9H-3,9'-bicarbazole

2,6-Di(9H-carbazol-9-yl)pyridine

LT-N4070

LT-N4072

pBCb2Cz

PYD-2Cz

N

N

N

N




39

Organ

ic Light Em

itting D

iod

e (OLED



N



: ::::::

: ::::::

1498411-20-3Sublimed, > 99% (HPLC) C54H33N695.85 g/mole273 nm (in CHCl3)377 nm (in CHCl3)> 280 °C (0.5% weight loss)

1467099-24-6Sublimed, > 99% (HPLC) C43H27NS589.75 g/mole316 nm (in Toluene)376 nm (in Toluene)> 270 °C (0.5% weight loss)

9-(3,5-Di(triphenylen-2-yl)phenyl)-9H-carbazole

3'-(Dibenzo[b,d]thiophen-4-yl)-10-phenyl-10H-spiro[acridine-9,9'-fluorene]

LT-N4082

LT-N4081

DTP-mCP

STDBT-4

N

S

Reference : Journal of Materials Chemistry C: Materials for Optical and Electronic Devices (2013), 1(40), 6575-6584


: :::::


484.59 g/mole303 nm (in CH2Cl2)> 250 °C (0.5% weight loss)

9,9'-Diphenyl-9H,9'H-3,3'-bicarbazole

LT-N4085 BCzPh

N N

Nn



: : : :: ::

: : : :: :



25067-59-8MW > 100,000 (GPC)(C14H11N)n

261, 294 nm (in CH2Cl2)380 nm (in THF)Soluble in CHCl3, Chlorobenzene, Dichlorobenzene

Reference : Organic Electronics (2011), 12(5), 843-850

4,6-Bis(3-(9H-carbazol-9-yl)phenyl)pyrimidine


LT-N4080

LT-N4079

LT-N4078

46DCzPPM

CPCBPTz

PVK


: : : :::



3-(4-(9H-Carbazol-9-yl)phenyl)-9-(4,6-diphenyl-1,3,5-triazin-2-yl)-9H-carbazole

N

NN

N

N

N NNN



40

Organ

ic Light Em

itting D

iod

e (OLED

)


FormulaM.W.



: :

: : : :: ::

: : : :: ::

C34H22N4

486.57 g/mole

1361953-33-4 Sublimed, > 99% (HPLC)C30H20N6




3,3'-Di(9H-pyrido[2,3-b]-indol-9-yl)biphenyl

9-(3-(3,5-Di(pyridin-2-yl)-1H-1,2,4-triazol-1-yl)phenyl)-9H-carbazole

9,9'-Diphenyl-9H,9'H-3,3'-bicarbazole-6-carbonitrile

LT-N4092

LT-N4099

LT-N4088

CbBPCb

m- cbtz

BCzSCN

Reference :

Reference :

Journal of Materials Chemistry C: Materials for Optical and Electronic Devices (2013), 1(48), 8177-8185

Journal of Materials Chemistry (2012), 22(12), 5410-5418

N

N

CN

NN

N

N

N

N


: : : :: ::

1470161-29-5Sublimed, > 99% (HPLC)C48H32N2O652.78 g/mole240 nm (in CH2Cl2)350 nm (in CH2Cl2)> 270 °C (0.5% weight loss)

Reference : Dyes and Pigments (2013), 98(3), 372-376

9,9'-(Oxybis([1,1'-biphenyl]-4',3-diyl))bis(9H-carbazole)

LT-N4086 CBBPE

O

N N


: : : :: ::



4- (4, 6-Bis[12-phenylindolo[2, 3- a] carbazol- 11(12H) - yl] - 1, 3, 5- triazin- 2- yl) -benzonitrile

LT-N4100 BBICT

Reference : Advanced Functional Materials (2014), 24(23), 3551-3561

N N

NN N

CN

NN


: : : :: ::

1579983-04-2Sublimed, > 99% (HPLC)C38H32NOP549.64 g/mole444 nm (in Toluene)458 nm (in 2-MeTHF)> 250 °C (0.5% weight loss)

Reference : Angew. Chem. Int. Ed. 2014, 53, 2147–2151

2'-(Diphenylphosphinyl)-N,N-bis(4-methylphenyl)-1,1'-biphenyl]-2-amine

LT-N4101 POBPmDPA

NP O

*New

N

N

N

N



41

Organ

ic Light Em

itting D

iod

e (OLED




: : : :: :


819.00 g/mole310, 341 nm (film)397 nm (film)

4,4'-(9H,9'H-3,3'-Bicarbazole- 9,9'-diyl)bis(N,N-diphenylaniline)

LT-N4102 BCzTPA

Reference : 1. Adv. Funct. Mater. 2013, 23, 5550–5555 ;2. Adv. Mater. 2012, 24, 3212–32173. J. Mater. Chem. C, 2015, 3, 1700

N

NN

N



GradeFormulaM.W.UVPLTGA

: : : :: ::

: : : :: ::

: : : :::



446.54 g/mole247, 292, 342 nm (in CH2Cl2)442 nm (in CH2Cl2)> 270 °C (0.5% weight loss)

Sublimed, > 99% (HPLC)C42H32O2P2630.65 g/mole251, 290 nm (in CH2Cl2)340 nm (in CH2Cl2)> 270 °C (0.5% weight loss)

3,3',3''-Phosphinylidynetris[9-phenyl-9H-carbazole

1,3-Bis(3-(diphenylphosphoryl)phenyl)benzene

9-(4-(4-Phenylquinolin-2-yl)phenyl)-9H-carbazole

LT-N4107

LT-N4115

LT-N4116

POCz3

BPOPB

CzPPQ

Reference :

Reference :

1. Dalton Transactions (2015), 44(33), 14613-146242. Organic Electronics (2011), 12(12), 2025-2032

1.Journal of Materials Chemistry C: Materials for Optical and Electronic Devices, 2(30), 6183-6191; 2014 2.ACS Applied Materials & Interfaces (2015), 7(19), 10466-10474

PO

N N

N

N

N

P POO



42

Organ

ic Light Em

itting D

iod

e (OLED

)

Organic Light Emitting Diode (OLED)Fluorescent Host Materials

NO

NO

N

OAl






: : : :: ::

: : : :: ::

: : : :: ::

: : : :: ::

: : : :: ::

2085-33-8Sublimed, > 99.5% (HPLC)C27H18AlN3O3


122648-99-1Sublimed, > 99.5% (HPLC)C34H22


804560-00-7Sublimed, > 99.5% (HPLC)C35H24


274905-73-6Sublimed, > 99% (HPLC)C38H30


142289-08-5Sublimed, > 99% (HPLC)C40H30

510.23 g/mole353 nm (in CHCl3)442 nm (in CHCl3)> 300 °C (0.5% weight loss)

Tris(8-hydroxy-quinolinato)aluminium

9,10-Di(naphth-2-yl)anthracene

2-Methyl-9,10-bis(naphthalen-2-yl)anthracene

2-tert-Butyl-9,10-di(naphth-2-yl)anthracene

4,4'-Bis(2,2-diphenylethenyl)-1,1'-biphenyl

LT-E401

LT-E403

LT-E410LT-E404

LT-E405Alq3

ADN

MADNTBADN

DPVBi


: : : :: ::

474918-42-8Sublimed, > 98% (HPLC)C81H62


Reference : J. Phys. Chem. C 2007, 111, 108-115

2,7-Bis[9,9-di(4-methylphenyl)-fluoren-2-yl]-9,9-di(4-methylphenyl)fluorene

LT-E408 TDAF



43

Organ

ic Light Em

itting D

iod

e (OLED


Fluorescent Host Materials



: : : :: ::

664345-18-0Sublimed, > 99% (HPLC)C50H30


2-(9,9-Spirobifluoren-2-yl)-9,9-spirobifluorene

LT-E411 BSBF


Reference : J. Phys. Chem. C 2007, 111, 108-115Reference : Synthetic Metals 143 (2004) 89–96





: : : :: ::

: : : :: ::

: : : :: ::

: : : :: ::

518997-91-6Sublimed, > 99% (HPLC)C75H44


349666-25-7Sublimed, > 95% (HPLC)C54H30


1174006-47-3Sublimed, > 99% (HPLC)C57H34


831222-16-3Sublimed, > 98% (HPLC)C57H32


2,7-Bis(9,9-spirobifluoren-2-yl)-9,9-spirobifluorene1,3,5-Tri(pyren-1-yl)benzene

9,9-Bis[4-(pyrenyl)phenyl]-9H-fluorene

2,2'-Dipyrenyl-9,9-spirobifluorene

LT-E412LT-N429

LT-N447

LT-N428

TSBFTSB3

BPPF

2,2'-Spiro-Pye


: : : :: ::

854046-47-2Sublimed, > 97% (HPLC)C54H42


2-[9,9-Di(4-methylphenyl)-fluoren-2-yl]-9,9-di(4-methylphenyl)fluorene

LT-E413 BDAF



44

Organ

ic Light Em

itting D

iod

e (OLED

)


Reference : Advanced Functional Materials (2008), 18, (1), 67-75.


: : : :: ::

1616657-81-8Sublimed, > 99% (HPLC)C38H22


1,3-Di(pyren-1-yl)benzene


: : : :: ::

959611-30-4 and 919089-75-1Sublimed, > 99%C40H24


Reference : Journal of Applied Physics, 102,104908(2007)

3,9-Di(naphthalen-2-yl)perylene and 3,10-di(naphthalen-2-yl) perylene mixture

Reference : J. Phys. Chem. Lett. 2012, 3, 1079-1083

CAS No.GradeFormulaM.W.UVPLTGACAS No.



: : : :: :::

: : :: ::

: : : :: ::

1254039-84-3Sublimed, > 99%C46H30

582.73 g/mole305 nm (in THF)620 nm (in THF)> 360 °C (0.5% weight loss)886456-80-0

Sublimed, > 99% (HPLC)C57H32


475460-77-6Sublimed, > 99% (HPLC)C38H22


6,13-Di-biphenyl-4-yl-pentacene

2,7-Dipyrenyl-9,9-spirobifluorene

1,4-Di(pyren-1-yl)benzene

LT-N478

LT-N479

LT-N473

LT-N458

LT-N472

DBPenta

DNP

m-Bpye

Spiro-Pye

p-Bpye

Reference : Appl. Phys. Lett., 89, 063504(2006).


: : : :: ::

172285-72-2Sublimed, > 99%C52H34


2,2'-Bi(9,10-diphenyl-anthracene)

LT-N452 TPBA



45

Organ

ic Light Em

itting D

iod

e (OLED



CAS No.GradeFormulaM.W.PLTGA

: : :: ::

1036404-84-8Sublimed, > 99% (HPLC)C40H26


1,1'-(2,5-Dimethyl-1,4-phenylene)dipyrene


LT-N481 DMPPP

N

NN



: : : :: ::

: : : :: ::



1705571-70-5Sublimed, > 99% (HPLC)C59H38



Reference : TW. I402243

N,N' -Di-(1-naphthalenyl)-N,N' -diphenyl-[1,1':4',1'':4'',1'''-quaterphenyl]-4,4'''-diamine

1-(7-(9,9'-Bianthracen-10-yl)-9,9-dimethyl-9H-fluoren-2-yl)pyrene

LT-N489

LT-N4004

4P-NPB

BAnFPye

Reference : Appl. Phys. Lett., 91, 023503 (2007).

Reference : Organic Electronics 8 (2007), 735~742.

Reference : Appl. Phys. Lett. 91, 183504 (2007)




: : : :: ::

: : : :: ::

: : : :: ::

349669-77-8Sublimed, > 99% (HPLC)C66H39N846.02 g/mole271 nm (in CH2Cl2)479 nm (in CH2Cl2)> 470 °C (0.5% weight loss)

172285-79-9Sublimed, > 99% (HPLC)C52H34


1002328-32-6Sublimed, > 99% (HPLC)C60H38


Tris[4-(pyrenyl)-phenyl]amine

10,10'-Di(biphenyl-4-yl)-9,9'-bianthracene

4,4'-Di[10-(naphthalen-1-yl)anthracen-9-yl]biphenyl

LT-N487

LT-N488

LT-N490TPyPA

BANE

BUBH-3



46

Organ

ic Light Em

itting D

iod

e (OLED

)


C8H17C8H17



CAS No.GradeFormulaM.W.


: : : :: ::

: : : ::

: : : :

: : : :: :

1258522-34-7> 99% (HPLC)C73H66


1499-10-1Sublimed, > 99%C26H18


1499-10-1Sublimed, > 99%C26H18

330.42 g/mole

1529774-51-3> 98% (HPLC)C118H120N6



1-(7-(9,9'-Bianthracen-10-yl)-9,9-dioctyl-9H-fluoren-2-yl)pyrene

9,10-Diphenylanthracene

1,4-Di(spiro[benzo[c]fluorine-7,9'-fluorene]-5-yl)benzene

9,9'-(2,2'-Dimethylbiphenyl-4,4'-diyl)bis(3',6'-di-tert -butyl-6-(3,6-di-tert -butyl-9H-carbazol-9-yl)-9H-3,9'-bicarbazole)

Reference :

Reference :

Journal of Chemical Education (2013), 90(6), 786-789

Advanced Functional Materials (2014), 24(22), 3413-3421

LT-N4040

LT-N4084

LT-N4087

LT-N4090

BAnF8Pye

ADP

SBFF2B

CMP

N N

N

NN

N


: : : :::

1705571-71-6> 99% (HPLC)C69H58


1-(7-(9,9'-Bianthracen-10-yl)-9,9-dihexyl-9H-fluoren-2-yl)pyrene


C6H13 C6H13

LT-N4005 DAnF6Pye*New



47

Organ

ic Light Em

itting D

iod

e (OLED




: : : :: ::

1257308-66-9> 99% (NMR)C27H15AlF3N3O3


Tris(6-fluoro-8-hydroxy-quinolinato)aluminium

NO

F

N

O F

NO

F

Al

Reference : Chemistry - A European Journal (2011), 17(33), 9076-9082

LT-N4091 6FAlq3

NO

NO Zn

CAS No.FormulaM.W.PLTGA



: : : ::

: : :::

: : :: :::

13978-85-3C18H12N2O2Zn353.71 g/mole465 nm (film)> 220 °C (0.5% weight loss)

1583238-16-7> 99% (HPLC)C35H23N3


1454615-69-0> 99% (HPLC)C37H25OP516.57 g/mole308, 314 nm (in CH2Cl2)322 nm (in CH2Cl2)> 200 °C (0.5% weight loss)


Reference : Chemistry of Materials (2014), 26(7), 2368-2373


Bis(8-hydroxyquinoline) zinc

9-(5-(3-(9H-Carbazol-9-yl)phenyl)pyridin-3-yl)-9H-carbazole

Bis(9,9-spirobifluorene-3-yl)-phenylphosphane oxide

LT-N4093

LT-N4094

LT-N4096

Znq2

CPPyC

SF3PO

N

N

N

PO



48

Organ

ic Light Em

itting D

iod

e (OLED

)

Organic Light Emitting Diode (OLED)Green Dopant Materials

O ON

N

S

O ON

N

S

N

NO

O

N

N NIr

NIr

O

O

2

Reference : Appl. Phys. Lett., Vol. 84, No. 14, 5 April 2004, 2476~2478.


: : : :: ::

149005-33-4Sublimed, > 99% (HPLC)C36H30IrN3


Tris[2-(p-tolyl)pyridine]iridium(III)

Ir

N

N N





: : : :: ::

: : : :: ::

: : : :: ::

: : : :: ::

38215-36-0Sublimed, > 99% (HPLC)C20H18N2O2S350.43 g/mole443 nm (in THF)493 nm (in THF)> 260 °C (0.5% weight loss)



337526-85-9Sublimed, > 99% (HPLC)C27H23IrN2O2




3-(2-Benzothiazolyl)-7-(diethylamino)coumarin fac-Tris(2-phenylpyridine)iridium(III)

Bis(2-phenylpyridine)(acetylacetonate)iridium(III)

N,N' -Dimethyl-quinacridone

LT-E501 LT-E504

LT-E505

LT-N506LT-E503

Coumarin 6 fac-Ir(ppy)3

Ir(ppy)2(acac)

Ir(mppy)3DMQA


: : : :: ::

155306-71-1Sublimed, > 99% (HPLC)C26H26N2O2S430.56 g/mole473 nm (in THF)506 nm (in THF)> 240 °C (0.5% weight loss)

2,3,6,7-Tetrahydro-1,1,7,7,-tetramethyl-1H,5H,11H-10-(2-benzothiazolyl)quinolizino[9,9a,1gh]coumarin

LT-E502 C545T



49

Organ

ic Light Em

itting D

iod

e (OLED


Green Dopant Materials

N N

N N

ZnN

N

S

S

OO

N N

N N

N N




: : : :: ::

: : : :: ::

: : : :: ::







N10,N10,N10',N10'-Tetra-tolyl-9,9'-bianthracene-10,10'-diamine

N10,N10,N10',N10'-Tetraphenyl-9,9'-bianthracene-10,10'-diamine

N10,N10'-Diphenyl-N10,N10'-dinaphthalenyl-9,9'-bianthracene-10,10'-diamine




: : : :: ::

: : : :: ::

: : : :: ::





58280-31-2Sublimed, > 99%C26H16N2O2S2Zn517.96 g/mole287, 334 nm (in CH2Cl2)458 nm (in CH2Cl2)> 300 °C (0.5% weight loss)

9,10-Bis[N,N-di-(p-tolyl)-amino]anthracene

9,10-Bis[phenyl(m-tolyl)-amino]anthracene

Bis[2-(2-hydroxyphenyl)benzothiazolato]zinc(II)

Reference : Chem. Mater., 2002, 14, 3958~3963.


Reference : Current Applied Physics. 2 (2002), 295~298.

LT-N507 LT-N510

LT-N511

LT-N512

LT-N508

LT-N509

TTPA BA-TTB

BA-TAD

BA-NPB

TPA

Zn(BTZ)2



50

Organ

ic Light Em

itting D

iod

e (OLED

)

Organic Light Emitting Diode (OLED)Green Dopant Materials

NIr

3


: : : :: ::

1338784-40-9> 99% (HPLC)C57H48IrN3

967.3 g/mole400 nm (in film)539 nm (in film)> 250 °C (0.5% weight loss)

fac-Tris(2-(3-p-xylyl)phenyl)pyridine iridium(III)





: :: ::::

: :: ::

1447998-13-1 Sublimed, > 99% (HPLC)C38H24N4O3

584.62 g/mole291 nm (in Toluene)501.5 nm (in Toluene)> 270 °C (0.5% weight loss)



2,5-Bis(4-(10H-phenoxazin-10-yl)phenyl)-1,3,4-oxadiazole

Bis(2-(naphthalen-2-yl)pyridine)(acetylacetonate) iridium(III)

LT-N528

LT-N529

LT-N522

2PXZ-OXD

Ir(npy)2acac

TEG

NIr

3


: : : :: ::



Tris(2-phenyl-3-methyl-pyridine)iridium

LT-N5002 Ir(3mppy)3


N N

ON N

OO

NIr

O

O

2



51

Organ

ic Light Em

itting D

iod

e (OLED


Blue Dopant Materials

N

N

N

N

N

N

N

N







: : : :: ::

: : : :: ::

: : : :: ::

: : : :: ::

: : : :: ::

: : : :: ::



62608-15-5> 99% (HPLC)C38H32N2


119586-44-6> 99% (HPLC)C56H48N2


596103-58-1> 99% (HPLC)C50H44N2


198-55-0Sublimed, > 99.5% (HPLC)C20H12


80663-92-9Sublimed, > 99% (HPLC)C36H44


4,4'-Bis(9-ethyl-3-carbazovinylene)-1,1'-biphenyl 1,4-Bis[2-(3-N-ethylcarbazoryl)vinyl]benzene

4,4'-Bis[4-(di-p-tolylamino)styryl]biphenyl

4-(Di-p-tolylamino)-4'-[(di-p-tolylamino)styryl]stilbene

Perylene

2,5,8,11-Tetra-tert-butylperylene

LT-E601 LT-E604

LT-E605

LT-E606

LT-E602

LT-E603

BCzVBi BCzVB

DPAVBi

DPAVB

Perylene

TBPe



52

Organ

ic Light Em

itting D

iod

e (OLED

)

Organic Light Emitting Diode (OLED)Blue Dopant Materials

N

N

NN

N N

N N



: : : :: ::

: : : :: ::

669016-17-5> 99% (HPLC)C77H60N2


239476-24-5> 99% (HPLC)C71H60N2


N,N'-Bis(naphthalen-2-yl)-N,N'-bis(phenyl)-tris-(9,9-dimethylfluorenylene)

2,7-Bis{2-[phenyl(m-tolyl)amino]-9,9-dimethyl-fluorene-7-yl}-9,9-dimethyl-fluorene

LT-N623

LT-N624

BNP3FL

MDP3FL



: : : :: ::

: : : :: ::

523977-57-3> 99% (HPLC)C52H40N2


436798-89-9> 99% (HPLC)C65H46N2


4,4'-Bis[4-(diphenylamino)styryl]biphenyl

2,7-Bis[4-(diphenylamino)styryl]-9,9-spirobifluorene

LT-E608

LT-N446

BDAVBi

Spiro-BDAVBi

N

N

N

N Ir

3

Reference : Applied Physics Letters. 87, 243507, 2005.



: : : :: ::

: : : :: ::

1542678-40-9> 99% (HPLC)C42H33IrN6


1032556-63-0> 99% (HPLC)C50H38N2


fac-Iridium(III) tris(1-phenyl-3-methylbenzimidazolin-2-ylidene-C,C2')

N-(4-((E)-2-(6-((E )-4-(Diphenylamino)styryl)naphthalen-2-yl)vinyl)phenyl)-N-phenylbenzenamine

LT-N629

LT-N627

fac-Ir(Pmb)3

N-BDAVBi



53

Organ

ic Light Em

itting D

iod

e (OLED



N

N Ir

3

N

N

N

N

Reference : Applied Physics Letters. 87, 243507, 2005.


: : : :: ::

926292-95-7> 99% (HPLC)C42H33IrN6


mer-Iridium(III) tris(1-phenyl-3-methylbenzimidazolin-2-ylidene-C,C2')

LT-N630 mer-Ir(Pmb)3



: : : :: ::

: : : :: ::

358374-59-1> 99% (HPLC)C46H36N2


320575-30-2> 99% (HPLC)C46H32N2


1-4-Di-[4-(N,N-diphenyl)amino]styryl-benzene

1,4-Bis(4-(9H-carbazol-9-yl)styryl)benzene

LT-N631

LT-N632

DSA-Ph

BCzSB


: : : : ::

220694-90-6Sublimed, > 99%C22H16BeN2O2

349.39 g/mole445 nm (in CHCl3)> 250 °C (0.5% weight loss)

Bis(2-(2-hydroxyphenyl)-pyridine)beryllium

Reference : 1. Chem. Mater., 2000, 12 (9), pp 2672–2675 2. J. Mater. Chem., 2011, 21, 3551

NO

NO Be

LT-N634 Bepp2

NIr

F

F 2

NNN

N

N

NB

N

N

F F



: : : :: ::

: : : :: ::

1219078-44-0> 99% (HPLC)C28H16F4IrN7


1338788-44-5> 99% (HPLC)C36H32BF2N3



Reference : Organic Electronics 12(2011) 666-676

Bis(2,4-difluorophenylpyridinato)(5-(pyridin-2-yl)-1H-tetrazolate) iridium(III)

(Z)-6-Mesityl-N-(6-mesitylquinolin-2(1H)-ylidene)quinolin-2-amine-BF2 complex

LT-N635

LT-N642

FIrN4

MQAB



54

Organ

ic Light Em

itting D

iod

e (OLED

)



: : : :: ::

1239588-65-8> 99% (HPLC)C56H45N731.96 g/mole386 nm (in CH2Cl2)465 nm (in CH2Cl2)> 260 °C (0.5% weight loss)


9-[4-(2-(7-(N,N-Diphenylamino)-9,9-diethylflouren-2-yl)vinyl)phenyl]-9-phenyl-fluorene

N

LT-N645 DPAFVF


: : : :: ::

870009-65-7> 99% (HPLC)C30H27IrN6


mer-Tris(1-phenyl-3-methylimidazolin-2-ylidene-C,C(2)'iridium(III)

N

N

Ir

3

LT-N646 mer-Ir(pmi)3

N

N

Ir

3


: : : :: ::

888725-36-8> 99% (HPLC)C57H42IrN6


fac-Tris(1,3-diphenyl-benzimidazolin-2-ylidene-C,C2')iridium(III)

LT-N658 fac-Ir(dpbic)3



: : : ::::

: : : :::

1261580-75-9Sublimed, > 99% (HPLC)C42H27N545.67 g/mole244, 397 nm (in CH2Cl2)441 nm (in CH2Cl2)> 330 °C (0.5% weight loss)

1258522-36-9> 99% (HPLC)C74H86N2

1003.49 g/mole407 nm (in THF)469 nm (in THF)

9-(9-Phenylcarbazole-3-yl)-10-(naphthalene-1-yl)anthracene

4,4'-(1E,1'E)-2,2'-(Naphthalene-2,6-diyl)bis(ethene-2,1-diyl)bis(N,N-bis(4-hexylphenyl)aniline)


Reference : Organic Electronics (2009), 10, (8), 1610-1614

N

LT-N662

LT-N663

PCAN

N-BDAVBi-C6

NN

C6H13

C6H13

C6H13

C6H13


: : : ::::

1421058-47-0> 99% (HPLC)C33H33F4IrN2O2


Bis[4-tert-butyl-2',6'-difluoro-2,3'-bipyridine](acetylacetonate)iridium(III)

Reference : J. Mater. Chem. C, 2013, 1, 1070-1075

N

N

F

F IrO

O

2

LT-N669 FK306



55

Organ

ic Light Em

itting D

iod

e (OLED



Reference : J. Mater. Chem. C, 2013, 1,4599

N N

NN N

OO


: : : :: ::

850594-34-2Sublimed, > 99%C52H36N2


4,4'-Bis(4-(9H-carbazol-9-yl)styryl)biphenyl

N

N

LT-S9058 BSB4

CAS No.GradeFormulaM.W.UVPL⊿ESTTGA

: :::::::


659.73 g/mole473 nm (in Toluene)462 nm0.86 eV> 300 °C (0.5% weight loss)

10,10'-(4,4'-(4-Phenyl-4H-1,2,4-triazole-3,5-diyl)bis(4,1-phenylene))bis(10H-phenoxazine)

LT-N675 2PXZ-TAZ



: :::

: ::::::


700.87 g/mole

1505456-00-7> 99% (HPLC)C44H22F12


N5,N5,N9,N9-tetraphenylspiro[benzo[c]fluorene-7,9'-fluorene]-5,9-diamine

10,10'-Bis(3,5-bis(trifluoromethyl)phenyl)-9,9'-bianthracene

LT-N677

LT-N678

TPA-SBFF

Ban-(3,5)-CF3

F3C

F3C CF3

CF3



: ::::::

1417790-60-3 > 99% (HPLC)C28H14F6IrN3O2


Bis(3,4,5-trifluoro-2-(2-pyridyl)phenyl-(2-carboxypyridyl) iridium(III)

LT-N679 Ir(tfpd)2pic

Reference : Dyes and Pigments (2013), 96(1), 237-241

NN


: ::::::

1262281-91-3> 99% (HPLC)C55H40N2


N5,N9-Diphenyl-N5,N9-di-m-tolylspiro[benzo[c]fluorene-7,9'-fluorene]-5,9-diamine

LT-N680 BD-6MDPA

NIr

N

O

FF

2

F

O

N N

*New



56

Organ

ic Light Em

itting D

iod

e (OLED

)



: : : :: ::

387859-70-3 > 99% (HPLC)C33H18F6IrN3


Tris(2-(4,6-difuorophenyl)pyridine)iridium(III)

LT-N697 Ir(Fppy)3

N

F

F Ir

3


: : : :: ::

850018-19-8Sublimed, > 99%C42H28N2S2

624.82 g/mole311, 376, 396 nm (in THF)448 nm (in THF)> 400 °C (0.5% weight loss)

6-Methyl-2-(4-(9-(4-(6-methylbenzo[d]thiazol-2-yl)phenyl)anthracen-10-yl)phenyl)benzo[d]thiazole

LT-N832 DBzA

S

NN

S



57

Organ

ic Light Em

itting D

iod

e (OLED


Red Dopant Materials

O

NC CN

N

N

O

CNNC

O

CNNC

N

Reference : Proc. 2nd Internat. Sym. Chem. Functional Dyes, 1992, 536.

N

NEu

O

O

3







: : : :: ::

: : : :: ::

: : : :: ::

: : : :: ::

: : : :: ::

: : : :: ::

51325-91-8Sublimed, > 99% (HPLC)C19H17N3O303.36 g/mole462 nm (in THF)577 nm (in THF)> 250 °C (0.5% weight loss)


17904-83-5Sublimed, > 99%C57H41N2O6Eu1001.93 g/mole257, 355 nm (in THF)615 nm (in THF)> 180 °C (0.5% weight loss)

517-51-1Sublimed, > 99%C42H28


51325-95-2> 99% (HPLC)C23H21N3O355.43 g/mole497 nm (in THF)605 nm (in THF)> 230 °C (0.5% weight loss)


(E)-2-(2-(4-(Dimethylamino)styryl)-6-methyl-4H-pyran-4-ylidene)malononitrile

4-(Dicyanomethylene)-2-tert -butyl-6-(1,1,7,7-tetramethyljulolidin-4-yl-vinyl)-4H-pyran

Tris(dibenzoylmethane)phenanthroline europium(III)

5,6,11,12-Tetraphenylnaphthacene

4-(Dicyanomethylene)-2-methyl-6-julolidyl-9-enyl-4H-pyran

4-(Dicyanomethylene)-2-methyl-6-(1,1,7,7-tetramethyljulolidyl-9-enyl)-4H-pyran

Reference : Appl. Phys. Lett. 79, 7, P1045-1047, 2001.

Reference : Chem. Phys. Lett. 287, 3~4, 455-460, 1998.

LT-E701 LT-E704

LT-E706

LT-E707

LT-E702

LT-E703

DCM DCJTB

Eu(dbm)3(Phen)

Rubrene

DCM2

DCJT

O

NC CN

N



58

Organ

ic Light Em

itting D

iod

e (OLED

)

Organic Light Emitting Diode (OLED)Red Dopant Materials

N

SIr

O

O

2

Bis[1-(9,9-dimethyl-9H-fluoren-2-yl)-isoquinoline](acetylacetonate)iridium(III)


: : : ::::

1617506-77-0Sublimed, > 98.5% (HPLC)C53H43IrN2O2


NIr

O

O

2

NIr

O

O

2



: : : :: ::

: : : :: ::

343978-79-0Sublimed, > 99% (HPLC)C31H23IrN2O2S2




Bis(2-benzo[b]thiophen-2-yl-pyridine)(acetylacetonate)iridium(III)

Bis[2-(9,9-dimethyl-9H-fluoren-2-yl)quinoline](acetylacetonate)iridium(III)

LT-E709

LT-N724

LT-N721

Ir(btp)2(acac)

Ir(flq)2(acac)

Ir(fliq)2(acac)

NN

N

N

NN

Ru . (PF6-)2

2+


: : : :::

Sublimed, > 99%C54H72F12N6P2Ru1196.19 g/mole289, 462 nm (in THF)614 nm (in THF)> 350 °C (0.5% weight loss)

Tris[4,4'-di-tert-butyl-(2,2')-bipyridine]ruthenium(III) complex

Reference : Appl. Phys. Lett. 79, 7, P1045-1047, 2001.

LT-N727 Ru(dtb-bpy)3 2(PF6)‧

CAS No.GradeFormulaUVPLTGA

: : : :: :

682806-51-5Sublimed, > 99%C58H60

306 nm (in CH2Cl2)571 nm (in CH2Cl2)> 310 °C (0.5% weight loss)

2,8-Di-tert-butyl-5,11-bis(4-tert-butylphenyl)-6,12-diphenyltetracene

Reference : Thin Solid Films 496 (2006) 626~630

LT-N732 TBRb

S NIrO

O

2


: : : :: ::

337526-88-2Sublimed, > 98.5% (HPLC)C31H23IrN2O2S2


Bis(2-phenylbenzothiazolato)(acetylacetonate)iridium(III)

Reference : Journal of Organometallic Chemistry,Vol 689, Issue 26, P4882-4888, 2004.

LT-N733 Ir(BT)2(acac)



59

Organ

ic Light Em

itting D

iod

e (OLED



NIr

C6H13 3


: : : :: ::

1404197-18-799% (HPLC)C47H51IrN2O2


Bis[2-(4-n-hexylphenyl)quinoline](acetylacetonate)iridium(III)

NIr

C6H13 2

O

O


: : : :: ::

1268460-37-2> 99% (HPLC)C63H66IrN3


Tris[2-(4-n-hexylphenyl)quinoline)]iridium(III)

Reference : Synthetic Metals 161 (2011) 148–152

NIr

3

NIr

N

2


: : : :::

Sublimed, > 99% (HPLC)C42H30IrN3


Bis(2-phenylquinoline)(2-(3-methylphenyl)pyridinate)iridium(III)

Reference : 1. Angew . Chem . Int . Ed .2008 ,47 ,5812. Chem. Mater. 2004 , 16 ,2480


: : : :: ::

725251-24-1> 99% (HPLC)C65H57IrN4O2


Bis(2-(9,9-diethyl-fluoren-2-yl)-1-phenyl-1H-benzo[d]imidazolato)(actylacetonate)iridium(III)

NNIr

O

O

2


: : : :: ::



Tris[2-phenyl-4-methylquinoline)]iridium(III)

Reference : Journal of Information Display Vol. 12, No. 1, March 2011, 51–55

LT-N742

LT-N743

LT-N744

LT-N740

LT-N741

Ir(Mphq)3

Ir(phq)2tpy

Ir(fbi)2(acac)

Hex-Ir(phq)2(acac)

Hex-Ir(phq)3

NIr

2

N

O

O

Reference : Thin Solid Films 496 (2006) 626~630


: : : :: ::



Bis(2-phenylpyridine)(3-(pyridin-2-yl)-2H-chromen-2-onate)iridium(III)

LT-N745 fac-Ir(ppy)2Pc



60

Organ

ic Light Em

itting D

iod

e (OLED

)


NIr

2

O

O

Reference : J. Photopolym. Sci. Technol., Vol.21. No.2. 2008

NIr

2

O

O

O

CNNC

N

N

N N

NPt


: : : :: ::

953079-91-9> 98% (HPLC)C28H31N3O425.57 g/mole485 nm (in THF)629 nm (in THF)> 340 °C (0.5% weight loss)

(E)-2-(2-tert-Butyl-6-(2-(2,6,6-trimethyl-2,4,5,6-tetrahydro-1H-pyrrolo[3,2,1-ij ]quinolin-8-yl)vinyl)-4H-pyran-4-ylidene)malononitrile


N

C6H13

Ir

2

O

O


: : : :: ::

31248-39-2> 95% (HPLC)C36H44N4Pt727.84 g/mole389, 534 nm (in CH2Cl2)649 nm (in CH2Cl2)> 290 °C (0.5% weight loss)

Platium(II) octaethylporphine





: : : :: ::

: : : :: ::

: : :: ::

: : : :: ::





Sublimed, > 99% (HPLC)C41H39IrN2O2


435294-13-6> 99% (HPLC)C47H51IrN2O2


Bis(2-phenylquinoline)(2,2,6,6-tetramethylheptane-3,5-dionate)iridium(III)

Bis(phenylisoquinoline)(2,2,6,6-tetramethylheptane-3,5-dionate) iridium(III)

Bis(phenylisoquinoline)(2,2,6,6-tetramethylheptane-3,5-dionate) iridium(III)

Bis[(4-n-hexylphenyl)isoquinoline](acetylacetonate)iridium (III)

LT-N749LT-N746

LT-N747

LT-N748

LT-N751

LT-N752

DCQTBIr(dpm)PQ2

Ir(dpm)(piq)2

Ir(dpm)(piq)2

Hex-Ir(piq)2(acac)

PtOEP

N

S

IrO

O

2



61

Organ

ic Light Em

itting D

iod

e (OLED



Reference : Adv. Mater. 2003, 15, 3, p224-228

NN

Ir

2

O

O


: : : :: ::



Bis(2-methyldibenzo[f,h]quinoxaline)(acetylacetonate)iridium(III)

LT-N753 Ir(MDQ)2(acac)

N

C6H13

Ir

3


GradeFormulaM.W.TGA

: : : :: ::

: : ::

1240249-29-9> 99% (HPLC)C63H66IrN3


Sublimed, > 99% (HPLC)C51H42IrN3



Tris(2-(3-methylphenyl)-7-methyl-quinolato)iridium




: : : :: ::

: : : :: ::





Iridium(III) bis(4-(4-tert-butylphenyl) thieno[3,2-c]pyridinato-N,C2') acetylacetonate

Bis[2-(2-methylphenyl)-7-methyl-quinoline](acetylacetonate)iridium(III)

Reference : Thin Solid Films 496 (2006)626~630

N OIr

O

2

NIr

3

LT-N754

LT-N758

LT-N762

LT-N757

Hex-Ir(piq)3

PO-01-TB

Ir(dmpq)2acac

Ir(dmpq)3

Reference : 1. TW I395804 , US 8,722,207 ; 2. Organic Electronics, 2012, 13, 2149-2155 ; 3. Mater. Chem. C, 2013, 1, 5008–5014

N

S

IrO

O

2



: : : :: ::

1621179-34-7 > 99% (HPLC)C36H1F4IrN3O2


Iridium(III) bis(2-(2,4-difluorophenyl)quinoline) picolinate

LT-N765 FPQIrpic

N

F

F

Ir

2

N

OO



62

Organ

ic Light Em

itting D

iod

e (OLED

)


Reference : ACS Appl. Mater. Interfaces 2013, 5, 192

Reference : RSC Advances (2013), 3(1), 215-220


GradeUVPLTGA

GradeUVPLTGA

GradeUVPLTGA



: : : :: ::

: : : :

: : : :

: : : :

: : : :: ::

: : : :: :



> 99% (HPLC)254, 301, 523 nm (in CH2Cl2)593 nm (in CH2Cl2)> 230 °C (0.5% weight loss)

> 99% (HPLC)460 nm (in CH2Cl2)582 nm (in CH2Cl2)> °C (0.5% weight loss)

> 99% (HPLC)258, 292, 413 nm (in CH2Cl2)558 nm (in CH2Cl2)> 260 °C (0.5% weight loss)

1415845-07-6> 99% (HPLC)C24H22N4




Tris[3-(2,6-dimethylphenoxy)-6-phenylpyridazine] iridium(III)

LT-N767 Ir(DMP)3

NIr

2

O

O

Bis[2-(3,5-dimethylphenyl)-4-methyl-quinoline](acetylacetonate)iridium(III)

(E)-2-(2-(4-(Dimethylamino)styryl)-1-ethylquinolin-4(1H)-ylidene)malononitrileLT-N768

LT-N771

LT-N772

LT-N777

LT-N778

Ir(mphmq)2acac

PR-08

PO-10

PO-10

ED

Reference :

Reference :

Reference :

Reference :

Organic Electronics Volume 13, Issue 10, October 2012, Pages 1956–1961

Applied Mechanics and Materials, 2015, 748 57-61



NN

O

Ir

3

N

NC CN

N


: : : :: ::



Bis[2-(9-phenylcarbazol-2-yl)-benzothiazole] iridium(III) picolinate

LT-N766 Ir(2-BtcPh)2(pic)

S N

N

Ir

2

N

O O



63

Organ

ic Light Em

itting D

iod

e (OLED




: : : ::

1651166-05-0> 99% (HPLC)C42H34N4O4S690.8180 g/mole> 250 °C (0.5% weight loss)

(E)-2-(2-(2-(7-(4-(Bis(4-methoxyphenyl)amino)phenyl)-2,3-dihydrothieno[3,4-b ][1,4]dioxin-5-yl)vinyl)-1-ethylquinolin-4(1H)-ylidene)malononitrile

LT-N779 QM-5

Reference : Angew. Chem. Int. Ed. 2015, DOI:10.1002/anie.201501478

N

NC CN

SN

O OO

O


: : : :: ::

1404192-47-7> 99% (HPLC)C69H48IrN3


Tris[1,1':4',1''-terphenyl-2-(2-pyridinyl-κN )phenyl-κC ] iridium

LT-N780 Ir(ppy)3-Bp

Reference : Advanced Functional Materials (2012), 22(16), 3406-3413

IrN

3



64

Organ

ic Light Em

itting D

iod

e (OLED

)

Organic Light Emitting Diode (OLED)Electron Transport Layer / Hole Blocking Layer(ETL/HBL) Materials

N

OLi

N

NN

N

N N

NN

O

NN

NN

NO

N OOAl







: : : :: ::

: : : :: ::

: : : :: ::

: : : :: ::

: : : :: ::

: : : :: ::

850918-68-2Sublimed, > 99.5% (HPLC)C9H6NOLi151.09 g/mole261 nm (in THF)331 nm (in THF)> 310 °C (0.5% weight loss)








146162-54-1Sublimed, > 99%C32H25N2O3Al512.53 g/mole259 nm (in THF)477 nm (in THF)> 230 °C (0.5% weight loss)

8-Hydroxyquinolinolato-lithium 2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline

4,7-Diphenyl-1,10-phenanthroline

2-(4-Biphenyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole

2,2',2"-(1,3,5-Benzinetriyl)-tris(1-phenyl-1-H-benzimidazole)

Bis(2-methyl-8-quinolinolate)-4-(phenylphenolato)aluminium

LT-E301 LT-E304

LT-E305

LT-E303

LT-E302

LT-E407

Liq BCP

Bphen

PBD

TPBi

BAlq



65

Organ

ic Light Em

itting D

iod

e (OLED


Electron Transport Layer / Hole Blocking Layer(ETL/HBL) Materials

NN

O O

NN

N N

N N

N NO

NN N

N

O

NN

N

N

NN

NN

NN

O O

NN

N NN N





: : : :: ::

: : : :: ::

: : : :: ::

: : : :: ::









1,3-Bis[2-(2,2'-bipyridine-6-yl)-1,3,4-oxadiazo-5-yl]benzene

6,6'-Bis[5-(biphenyl-4-yl)-1,3,4-oxadiazo-2-yl]-2,2'-bipyridyl

2,9-Bis(naphthalen-2-yl)-4,7-diphenyl-1,10-phenanthroline

2,7-Bis[2-(2,2'-bipyridine-6-yl)-1,3,4-oxadiazo-5-yl]-9,9-dimethylfluorene



: : : :: ::



3-(4-Biphenyl)-4-phenyl-5-tert-butylphenyl-1,2,4-triazole

Reference : 1. Appl. Phys. Lett. Vol. 85, No. 21, 22 November 22. Appl. Phys. Lett. 87, 193501 (2005)

LT-N821

LT-N828

LT-N843

LT-N851

LT-N836

Bpy-OXD

BP-OXD-Bpy

NBphen

Bpy-FOXD

TAZ


: : : :: ::



4-(Naphthalen-1-yl)-3,5-diphenyl-4H-1,2,4-triazole

LT-N837 NTAZ



66

Organ

ic Light Em

itting D

iod

e (OLED

)


NN

O O

NN

B N

N

N

N

N N

N

NN

PO

Reference : 1. JP Journal of Appl. Phys. Vol.44, No.6A, 2005, 2. Organic Electronics, Vol. 4, Issues 2-3, Sep. 2


: : : :: ::



1,3-Bis[2-(4-tert-butylphenyl)-1,3,4-oxadiazo-5-yl]benzene



: : : :: ::

: : : :: ::

929203-02-1Sublimed, > 99% (HPLC)C42H42BN3


721969-93-3Sublimed, > 99% (HPLC)C38H23OP526.56 g/mole281, 360 nm (in CH2Cl2)382 nm (in CH2Cl2)> 370 °C (0.5% weight loss)

Tris(2,4,6-trimethyl-3-(pyridin-3-yl)phenyl)boranePhenyl-dipyrenylphosphine oxide

Reference : Chemistry Letters. Vol. 36, No. 2, P262, 2007. Reference : Appl. Phys. Lett. 92, 063306 2008


: : : :: ::

1234997-42-2Sublimed, > 99%C30H20N4


1-Methyl-2-(4-(naphthalen-2-yl)phenyl)-1H-imidazo[4,5f] [1,10]phenanthroline


: : : :: ::


458.55 g/mole281,327 nm (in CH2Cl2)398 nm (in CH2Cl2)> 320 °C (0.5% weight loss)

2-(Naphthalen-2-yl)-4,7-diphenyl-1,10-phenanthroline

LT-N855 LT-N860

LT-N861LT-N856

LT-N857

OXD-7 HNBphen

POPy2

3TPYMB

2-NPIP



67

Organ

ic Light Em

itting D

iod

e (OLED



N

N

N

N


: : : :: ::



3,3',5,5'-Tetra[(m-pyridyl)-phen-3-yl]biphenyl

Reference : Org. Lett., 2008, 10(5), p941-944.

LT-N862 BP4mPy

N

N

N

NN

N NN

N

N

NN

N



: : : ::

: : : :: ::





4,4'-Bis(4,6-diphenyl-1,3,5-triazin-2-yl)biphenyl

1,3-Bis[3,5-di(pyridin-3-yl)phenyl]benzene

Reference : Organic Electronics, 2008, 9(3), p285



: : : :: ::



1,3,5-Tri[(3-pyridyl)-phen-3-yl]benzene

Reference : Adv.Mater., 2008, 20, p2125-2130.

LT-N863

LT-N864

LT-N865

TmPyPB

BTB

BmPyPhB


: : : ::::

148896-39-3Sublimed productC26H16BeN2O2


2-(4-(9,10-Di(naphthalen-2-yl)anthracen-2-yl)phenyl)-1-phenyl-1H-phenanthro[9,10-d ]imidazole

NO Be O

N

LT-N868 Bepq2



68

Organ

ic Light Em

itting D

iod

e (OLED

)


N

N

N

N

N

N


: : : :::



1,3,5-Tris(4-(pyridin-4-yl)quinolin-2-yl)benzene

Reference : Advanced Functional Materials (2011), 21(20), 3889-3899.

C8H17 C8H17 n

NNBr Br


: : : ::

MW > 10,000 (GPC)(C56H80N2Br2)n

375 nm (in MeOH) 440 nm (in MeOH)Soluble in MeOH

Poly[(9,9-bis(3'-((N,N-dimethyl)-N-ethylammonium)-propyl)-2,7-fluorene)-alt-2,7-(9,9-dioctylfluorene)]

Reference : Chem. Mater. , 2004, 16, 708

LT-N879

LT-N878

TPyQB

PFNBr


: : : ::::


2,2'-(4,4'-(Phenylphosphoryl)bis(4,1-phenylene))bis(1-phenyl-1H-benzo[d ]imidazole)

N

NP

N

N

O

LT-N885 BIPO

N


: : : :: ::

1246467-58-2Sublimed, > 99% (HPLC)C37H21N479.57 g/mole246, 282, 351 nm (in CH2Cl2)389 nm (in CH2Cl2)> 390 °C (0.5% weight loss)

3,5-Di(pyren-1-yl)pyridine

Reference : Organic electronics.10,(2009),877-882

LT-N870 PY1

SiN

N


: : : :: ::

1152162-74-7Sublimed, > 99% (HPLC)C34H26N2Si490.67 g/mole251 nm (in CH2Cl2)366 nm (in CH2Cl2)> 230 °C (0.5% weight loss)

Diphenylbis(4-(pyridin-3-yl)phenyl)silane


LT-N869 DPPS



69

Organ

ic Light Em

itting D

iod

e (OLED



Lithium 2-(2', 2''-bipyridine-6'-yl)phenolate

LT-N887 Libpp


: : : ::::

1049805-81-3Sublimed, > 99% (NMR)C16H11LiN2O254.21 g/mole235, 265 nm (in CH2Cl2)345 nm (in CH2Cl2)> 220 °C (0.5% weight loss)

NN

OLi




: : : ::::

: : : :::

1492917-78-8Sublimed, > 99% (NMR)C54H36N6

768.9 g/mole255 nm (in CH2Cl2)357 nm (film)> 280 °C (0.5% weight loss)

1382639-67-9Sublimed, > 99% (NMR)C41H27N7


1,3,5-Tris(6-(3-(pyridin-3-yl)phenyl)pyridin-2-yl)benzene

4,6-Bis(3,5-di(pyridin-3-yl)phenyl)-2-(pyridin-3-yl)pyrimidine

LT-N889

LT-N890

Tm3PyP26PyB

B3PYPPM

Reference :

Reference :

Advanced Functional Materials (2014), 24(21), 3268-3275

Chemistry of Materials (2012), 24(20), 3817-3827

NN

N

N

N

N

N N

N

N

N N

N


: : : :::

1382639-70-4Sublimed, > 99% (NMR)C47H31N7


4,6-Bis(3,5-di(pyridin-4-yl)phenyl)-2-(3-(pyridin-3-yl)phenyl)pyrimidine

LT-N891 B4PYPPyPM


N NN

N N

N

N



70

Organ

ic Light Em

itting D

iod

e (OLED

)


1,3,5-Tri(diphenylphosphoryl-phen-3-yl) benzene

LT-N892 TP3PO



: : :::::

: : :::::



2872-54-0Sublimed, > 99% (HPLC)C9H6NONa167.14 g/mole261 nm (in THF)331 nm (in THF)> 310 °C (0.5% weight loss)


PO

PO

PO

Poly[9,9-bis[6'-(N,N,N-trimethylammonium)hexyl]fluorene-alt-co-1,4-phenylene]bromide

8-Hydroxyquinoline sodium salt

LT-N894

LT-N895

FPQ-Br

NaQ*New

GradeFormula

: :

Mw > 20,000 (GPC)(C37H52Br2N2)n

Reference : Adv Mate., 2011, V23, 2759–2763

N

n

Br

N

Br

N N

NN N

N


: : : :: :



4,7-Diphenyl-2,9-bis(4-(1-phenyl-1H-benzo[d]imidazol-2-yl)phenyl)-1,10-phenanthroline

LT-N8001 DBimiBphen

N

ONa



71

Organ

ic Light Em

itting D

iod

e (OLED



GradeFormulaM.W.TGA


: : : :

: : : ::

Sublimed, > 99% (HPLC)C43H28N4




4,7-Diphenyl-2-(4-(1-phenyl-1H-benzo[d]imidazol-2-yl)phenyl)-1,10-phenanthroline

2-(4-(9,10-Di(naphthalen-2-yl)anthracen-2-yl)phenyl)-1-phenyl-1H-phenanthro[9,10-d]imidazole

N N

NN

N

N

LT-N8002

LT-N8003

BimiBphen

ADN-PAimi



72

Organ

ic Light Em

itting D

iod

e (OLED

)

Organic Light Emitting Diode (OLED)Electron Injection Layer(EIL) Materials / Metal

CAS No.GradeFormulaM.W.Melting PointBoiling Point

CAS No.GradeFormulaM.W.Melting Point






: : : :::

: : : ::

: : : ::

: : : ::

: : :::

: : ::

: : ::

7789-24-4 > 99.99%LiF25.94 g/mole848 °C1681 °C

534-17-8> 99.994%Cs2CO3

325.82 g/mole610 °C

1313-27-5> 99.998%MoO3

143.94 g/mole795 °C

13400-13-0> 99%CsF151.90 g/mole682 °C

7429-90-5> 99.999%Al26.98 g/mole660 °C

584-09-8>99.9%Rb2CO3

588.74 g/mole

1314-28-9> 99.9%ReO3

234.21 g/mole

Lithium fluoride

Cesium carbonate

Molybdenum(VI) Oxide

Cesium fluoride

Aluminium

Rubidium carbonate

Rhenium(VI) oxide

LT-E001

LT-E002

LT-E003

LT-E004

LT-E005

LT-E007

LT-E008LiF

Cs2CO3

MoO3

CsF

Al

Rb2CO3

ReO3

O

OORb Rb

Re

O

O O

*New

*New



73

Organ

ic Light Em

itting D

iod

e (OLED

)Thermally Activated Delayed Fluorescence (TADF) OLED

Contents

• Introduction ----------------------------------------------------------------- 74

• TADF Host Materials (13) ---------------------------------------------------- 77

• TADF Blue Dopant Materials (14) ------------------------------------------- 80

• TADF Green Dopant Materials (9) ------------------------------------------- 84

• TADF Red Dopant Materials (3) --------------------------------------------- 86



74

Therm

ally Activated

Delayed

Fluo

rescence (TA

DF) O

LED

Thermally Activated Delayed Fluorescence (TADF) OLEDIntroduction

　TADF techno log ies have been

developed that change the performance

of future OLEDs to enable their practical

appl icat ion greatly . Furthermore,

in the view of photochemistry and

material chemistry, TADF technologies

have given rise to a new category of

luminescent materials, contributing to

the academic progress in this field. [1]

　Since the pioneering work of Tang and Vanslyke in 1980s[2], using organic materials

for OLEDs has thrived for decades because of the enormous potential of OLEDs for

smart phones, flatpanel displays, and solid-light emitting applications. The extensive

research in this field to gain insight into the fundamental processes that determine the

operation of the devices provides numerous interesting challenges to material design

and fundamental questions to generate and transport charges and excitons.

　The exciton formation under electrical excitation typically results in 25% singlet

excitons and 75% triplet excitons is well known, in spite of that, 75% of the electrically

generated energy is dissipated as heat by triplet excitons in the fluorescence materials,

leading to the theoretically highest external quantum efficiency (EQE) of 5% after

considering a light outcoupling efficiency of ~20% in device.

　Many efforts to utilize the non-emissive triplet excitons have been devoted to

breaking through the 5% limitation of the OLED device in order to increase the

efficiency of the OLEDs. The most successful one is by incorporating heavy metals

into the organic aromatic frameworks to increase spin–orbit interactions, which

facilitate the lowest triplet excited state (T1) to the ground state (S0) transition (T1→S0)

for phosphorescence luminescence. This approach harvests light from both triplet

and singlet excitons, allowing the internal quantum efficiency of the device to reach

nearly 100%. After delicately dispersed in carefully selected host materials, the

phosphorescent metal complex exhibits very high external quantum efficiency (EQE),

which has been over 30% in doped phosphorescent OLEDs(PhOLEDs) recently.

Fluorescence

Phosphorescence

Electrical excitation

75%

T1 -0.5-1.0 eV

S1

S0

TADF

25%



75

Therm

ally Activated

Delayed

Fluo

rescence (TA

DF) O

LEDThermally Activated Delayed Fluorescence (TADF) OLED

Introduction

　According to a professor Chihaya Adachi at Kyushu University with“Hyper-

Fluorescence" idea , the new 3.5 -generation TADF element is the common use of a

TADF and fluorescence characteristics of co-dopant material , more to further improve

efficiency.[6]

　The success in theoretical and technical challenges of TADF may prepare for the

future of organoelectronics.

Nevertheless, the heavy metals Iridium (Ir) and Platinum (Pt) are confined for

phosphorescence generally, which are rather expensive and relying on limited global

resources. So that, several other strategies to avoid the use of those expensive metals

in practical applications, such as triplet–triplet annihilation (TTA), tuning spin–orbit

coupling by side-stepping Kasha’s rule, hybridized local and charge transfer (HLCT)

and thermally activated delayed fluorescence (TADF)[3][4][5] have also been proposed

to harvest the 75% triplet excitons for luminescence. In those researches, TADF was

found to have the most rapid progress in recent investigations. The TADF strongly

depends on HOMO–LUMO separation in a single molecule. TADF materials have a

sufficiently small energy gap between (S1) and (T1) (⊿EST) to enable up-conversion of the triplet exciton from (T1) to (S1). This small ⊿EST enables TADF materials to realize 100% of the exciton formation generated by electrical excitation at (S1).

N

O

N N

O

O

N

TADF Assistant dopant

Fluorescent Dopant

O NN

NN

O NN

NN

N

N

O

O

LT-E603 LT-N507 LT-N732 LT-N4003



76

Therm

ally Activated

Delayed

Fluo

rescence (TA

DF) O

LED

Thermally Activated Delayed Fluorescence (TADF) OLEDIntroduction

[1] Japanese Journal of Applied Physics 53, 060101 (2014)

[2] C. W. Tang , S. A. Vanslyke , Appl. Phys. Lett. 1987 , 51 , 913 .

[3] Q. Zhang , Q. Zhou , Y. Cheng , L. Wang , D. Ma , X. Jing , F. Wang ,Adv. Mater. 2004 , 16 , 432 .

[4] H. Uoyama , K. Goushi , K. Shizu , H. Nomura , C. Adachi , Nature 2012 , 492 , 234 .

[5] A. Chihaya , Jpn. J. Appl. Phys. 2014 , 53 , 60101 .



77

Therm

ally Activated

Delayed

Fluo

rescence (TA

DF) O


TADF Host Materials

NN


: : : :: ::



1,3-Bis(carbazol-9-yl)benzene

LT-E107 MCP

Reference : Reference :

Reference :

1. J. Mater. Chem. C, 2014, 2, 81912. Chem. Commun., 2015, 51, 3181 1. Adv. Mater. (2014), 26(38), 6642-6646

2. J. Am. Chem. Soc. 2012, 134, 14706−14709

1. Nature Materials 14, 330–336 (2015)2. J. Am. Chem. Soc. 2012, 134, 14706−14709

N

N

N

N


: : : :: ::



4,4',4"-Tris(carbazol-9-yl)triphenylamine

LT-E207 TcTa

Reference : Nature Photonics 8, 326–332 (2014)

Reference : Nature Photonics 8, 326–332 (2014)

NN


: : : :: ::



4,4'-Bis(carbazol-9-yl)biphenyl

LT-E409 CBP

N

Si

Si


: : : :: ::

898546-82-2Sublimed, > 99%C58H49NSi2816.19 g/mole275,301 nm (in CH2Cl2)354 nm (in CH2Cl2)> 320 °C (0.5% weight loss)

9-(4-tert -butylphenyl)-3,6-bis(triphenylsilyl)-9H-carbazole

LT-N484 CzSi

S

P POO


: : : :: ::

1019842-99-9Sublimed, > 99% (HPLC)C36H26O2P2S584.60 g/mole315, 328 nm (in CH2Cl2)351 nm (in CH2Cl2)> 320 °C (0.5% weight loss)



LT-N4006 PPT

OP PO O


: : : :: ::



Bis[2-(diphenylphosphino)phenyl]ether oxide

LT-N4060 DPEPO



78

Therm

ally Activated

Delayed

Fluo

rescence (TA

DF) O

LED

Thermally Activated Delayed Fluorescence (TADF) OLEDTADF Host Materials

Reference : 1. Adv. Funct. Mater. 2013, 23, 5550–55552. Adv. Mater. 2012, 24, 3212–32173. J. Mater. Chem. C, 2015, 3, 1700

NN N



: : : :: ::

: : : :: ::


409.48 g/mole241,290 nm (in CH2Cl2)373 nm (in THF)> 250 °C (0.5% weight loss)



2,6-Di(9H-carbazol-9-yl)pyridine

3',5'-Di(carbazol-9-yl)-[1,1'-biphenyl]-3,5-dicarbonitrile

LT-N4072

LT-N4098

PYD-2Cz

DCzDCN

Reference : Chem. Mater. 2013, 25, 3910−3920

NC

CN

N

N

N

N

N





: : : :: ::

: : : :: ::

: : : :: ::

: : : :: ::






819.00 g/mole310, 341 nm (film)397 nm (film)> 300 °C (0.5% weight loss)




4'-(9H-carbazol-9-yl)biphenyl-3,5-dicarbonitrile



Reference : Adv. Mater. (2014), 26(30), 5198-5204



LT-N863

LT-N4104

LT-N4102

LT-N4105

TmPyPB

pCzB-2CN

BCzTPA

mCzB-2CN

N

NC CN

N

CN

CN

N

NN

N



79

Therm

ally Activated

Delayed

Fluo

rescence (TA

DF) O


TADF Host Materials


: : : :: ::

911397-27-8 Sublimed, > 99% (HPLC)C36H26O3P2


2,8-Bis(diphenylphosphoryl)dibenzo[b,d]furan


LT-N4106 PPF

O

PO

PO



80

Therm

ally Activated

Delayed

Fluo

rescence (TA

DF) O

LED

Thermally Activated Delayed Fluorescence (TADF) OLEDTADF Blue Dopant Materials






: : : :: :::

: : : :: :::

: : : :: :::

: : : :: :::

: : : :: :::

1396165-20-0 Sublimed, > 99% (HPLC)C52H56N2O2S773.08 g/mole346 nm (in Toluene)404 nm (in Toluene)0.32 eV> 250 °C (0.5% weight loss)


659.73 g/mole473 nm (in Toluene)462 nm0.86 eV> 300 °C (0.5% weight loss)

1233215-35-4 Sublimed, > 99% (HPLC)C61H38N4O842.98 g/mole345 nm (in Toluene)475 nm0.14 eV> 250 °C (0.5% weight loss)


1206626-95-0 Sublimed, > 99% (HPLC)C32H21NO435.52 g/mole430 nm (in Toluene)490 nm0.04 eV> 250 °C (0.5% weight loss)

9,9'-(4,4'-sulfonylbis(4,1-phenylene))bis(3,6-di-tert-butyl-9H-carbazole)

10,10'-(4,4'-(4-phenyl-4H-1,2,4-triazole-3,5-diyl)bis(4,1-phenylene))bis(10H-phenoxazine)

Bis(4-(9H-3,9'-bicarbazol-9-yl)phenyl)methanone

10,10'-(4,4'-sulfonylbis(4,1-phenylene))bis(9,9-dimethyl-9,10-dihydroacridine)

10-Phenyl-10H,10'H-spiro[acridine-9,9'-anthracen]-10'-one

Reference : J. Am. Chem. Soc. 2012, 134, 14706-14709


Reference : Angew. Chem. 2014, 126, 6520-6524

Reference : Nature Photonics 8, 326-332 (2014)

LT-N672

LT-N675

LT-N684

LT-N685

LT-N681

CZ-PS

2PXZ-TAZ

CC2BP

DMAC-DPS

ACRSA

N N

NN N

O O

SO O

N N

Reference : 1. Chem. Commun., 2013, 49, 103852. Nature Communications (2014), 5, 4016

N

O

O

NNNN

S

N N

O O



81

Therm

ally Activated

Delayed

Fluo

rescence (TA

DF) O


TADF Blue Dopant Materials



: : : :: :::

: : : :: :::


804.94 g/mole283 nm (in Toluene)462 nm (in Toluene)0.28 eV> 300 °C (0.5% weight loss)



9'- [4- (4, 6- diphenyl- 1, 3, 5- triazin- 2- yl) phenyl] -9, 3':6', 9''- ter- 9H- carbazole

9,9'-(5-(4,6-diphenyl-1,3,5-triazin-2-yl)-1,3-phenylene)bis(9H-carbazole)

Reference : Nature Materials 14, 330-336 (2015)


LT-N687

LT-N689

BCC-TPTA

DCzTrz

N

N N

N

N

N


: : : :: :::



9'- [4- (4, 6- diphenyl- 1, 3, 5- triazin- 2- yl) phenyl] - 3, 3'', 6, 6''- tetraphenyl-9, 3':6', 9''- ter- 9H- carbazole


LT-N686 BDPCC-TPTA

N

N N

N

N

N

N

NNN

N


: : : :: :::



9,9',9'',9'''-((6-phenyl-1,3,5-triazine-2,4-diyl)bis(benzene-5,3,1-triyl))tetrakis(9H-carbazole)


LT-N690 DDCzTrz

N

N

NN

N N

N



82

Therm

ally Activated

Delayed

Fluo

rescence (TA

DF) O

LED

Thermally Activated Delayed Fluorescence (TADF) OLEDTADF Blue Dopant Materials




: : : :: :::

: : : :: ::

: : : :: :





516.63 g/mole390 nm (in Toluene)425 nm (in Toluene)

9,9'-(4,4'-sulfonylbis(4,1-phenylene))bis(3,6-dimethoxy-9H-carbazole)

9-(4-(4,6-Diphenyl-1,3,5-triazin-2-yl)phenyl)-3',6'-diphenyl-9H-3,9'-bicarbazole

10-(4-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl)-9,9-dimethyl-9,10-dihydroacridine

Reference : J. Mater. Chem. C, 2014, 2, 421

LT-N691

LT-N698

LT-N699DMOC-DPS

DPCC-TPTA

DMAC-TRZ


: : : :: ::

1357066-21-7 Sublimed, > 99% (HPLC)C27H18N4O414.46 g/mole231, 267, 306 nm (in CH2Cl2)497 nm (in CH2Cl2)> 300 °C (0.5% weight loss)

10-(4,6-Diphenyl-1,3,5-triazin-2-yl)-10H-phenoxazine

LT-N4117 Phen-TRZ

SO O

N NO

O O

O

N

NN

NN

N N

N

N

O

NN

NN

*New



83

Therm

ally Activated

Delayed

Fluo

rescence (TA

DF) O


TADF Blue Dopant Materials

Reference : Nature Communications (2014), 5, 4016


: : : :: ::

80663-92-9Sublimed, > 99% (HPLC)C36H44


2,5,8,11-Tetra-tert-butylperylene

LT-E603 TBPe



84

Therm

ally Activated

Delayed

Fluo

rescence (TA

DF) O

LED

Thermally Activated Delayed Fluorescence (TADF) OLEDTADF Green Dopant Materials

CAS No.GradeFormulaM.W.PL⊿ESTTGA



: : : : :::

: : : : ::::

: : : : :::


743.89 g/mole499 nm (film)0.021 eV> 250 °C (0.5% weight loss)



1643983-89-4 Sublimed, > 99% (HPLC)C28H21NO2

403.47 g/mole530 nm (in CH2Cl2)0.06 eV> 200 °C (0.5% weight loss)

2,7-Bis(diphenylamino)-10-phenyl-10H-spiro(acridine-9,9'(4,5-diazafluorene)

2,5-Bis(4-(10H-phenoxazin-10-yl)phenyl)-1,3,4-oxadiazole

3-(9,9-dimethylacridin-10(9H)-yl)-9H-xanthen-9-one

Reference : Chem. Lett. 2014, 43, 1017-1019



LT-N536

LT-N528

LT-N532

DPAA-AF

2PXZ-OXD

ACRXTN

N

N N

N N

N N


: : : :: ::





LT-N507 TTPA

N N

ON N

O O

O

O

N


: : : : :::



1,4-Bis(9,9-dimethylacridan-10-yl-pphenyl)-2,5-bis(p-tolyl-methanoyl)benzene

Reference : Dalton Transactions (2015), 44(18), 8356-8359

LT-N538 AcPmBPX

N

N

OO



85

Therm

ally Activated

Delayed

Fluo

rescence (TA

DF) O


TADF Green Dopant Materials



: : : : :::

: : : : ::::




718.85 g/mole428 nm (in CH2Cl2)550 nm (in CH2Cl2)0.83 eV> 250 °C (0.5% weight loss)

1,4-Bis(9,9-phenoxazin-10-yl-p-phenyl)-2,5-bis(p-tolyl-methanoyl)-benzene

5,10-Bis(4-(1-phenyl-1H-benzo[d]imidazol-2-yl)phenyl)-5,10-dihydrophenazine

Reference : Dalton Transactions (2015), 44(18), 8356-8359.

Reference : J. Mater. Chem. C, 2015, 3, 2175

LT-N540

LT-N541

PxPmBPX

DHPZ-2BI

N

NO

O

OO

N NN

N N

N


: : : : :::

1477511-57-1 Sublimed, > 99%C36H24N2O4S580.65 g/mole507 nm (in Toluene)0.08 eV> 220 °C (0.5% weight loss)

10,10'-(4,4'-sulfonylbis(4,1-phenylene))bis(10H-phenoxazine)


LT-N545 PXZ-DPS

S

N NO O

O O


: : : : ::::



1,3,5-Tris(4-(diphenylamino)phenyl)-2,4,6-tricyanobenzene

Reference : Chem. Commun., 2015, 51, 5028

LT-N547 3DPA3CN

CN

NC CN

N N

N



86

Therm

ally Activated

Delayed

Fluo

rescence (TA

DF) O

LED

Thermally Activated Delayed Fluorescence (TADF) OLEDTADF Red Dopant Materials



: : : : ::::

: : : : ::::

1623010-63-8Sublimed, > 99% (HPLC)C31H21NO3S487.57 g/mole396 nm (in Toluene)625 nm (film)0.052 eV> 250 °C (0.5% weight loss)

1623010-64-9Sublimed, > 99% (HPLC)C31H19NO3S487.55 g/mole415 nm (in Toluene)570 nm (film)0.073 eV> 250 °C (0.5% weight loss)

2- [4- (diphenylamino) phenyl] - 10, 10- dioxide-9H- thioxanthen- 9- one

2- (9- phenyl- 9H- carbazol- 3- yl) - 10, 10- dioxide-9H- thioxanthen- 9- one



LT-N775

LT-N776

TXO-TPA

TXO-PhCz


: : : :: :

682806-51-5Sublimed, > 99%C58H60

306 nm (in CH2Cl2)571 nm (in CH2Cl2)> 310 °C (0.5% weight loss)

2,8-Di-tert-butyl-5,11-bis(4-tert-butylphenyl)-6,12-diphenyltetracene


LT-N732 TBRb

SO O

ON

SO O

O N



Solu

tion

-Pro

cessed O

LEDSolution-Processed OLED

Contents

87PB

• Introduction --------------------------------------------------------------------88

•

• Hole Transport Layer/Hole Injection Layer (HTL/HIL) Materials (14) ----------90

• Phosphorescent Host Materials (17) -------------------------------------------93

• Phosphorescent Dopant Materials (9)------------------------------------------96

• Fluorescent Host Materials (4) --------------------------------------------------98

• Fluorescent Dopant Materials (4) ----------------------------------------------99

• Electron Transport Layer / Hole Blocking Layer (ETL/HBL) Materials (11) ----100

•

• Hole Transport Layer (9) -------------------------------------------------------102

• Emitting layer (46) -------------------------------------------------------------104

• Electron Transport Layer (2) ---------------------------------------------------112

Small molecules for solution-processed OLEDs

Polymers for solution-processed OLEDs



Solu

tion

-Pro

cessed O

LED

Solution-Processed OLEDIntroduction

8988

　 The earliest multilayered organic light-emitting diodes (OLEDs) were reported by Tang and Van Slyke in 1987 and were based on a bilayer architecture1. Since then, OLEDs have drawn tremendous attention during the past decades because of their po-tential applications in solid-state lightings and flat-panel displays.

　 OLEDs are characterized by low driving voltage, high brightness, full-color emis-sion, rapid response, and easy fabrication of potentially large-area, flexible thin-film devices. Recently, organic light-emitting diodes (OLEDs) have been successfully devel-oped and have now entered the commercial marketplace; however the general meth-od for fabricating organic light-emitting diodes (OLEDs) is vapor deposition under vacuum, which has critical drawbacks most notably the pixilation using evaporation masks limit its scalability and resolution. Other limitations include low use of the ex-pensive OLED materials (~20%), and high manufacturing costs. Despite these limita-tions OLEDs do have some advantages over thermal evaporation processing because of its low-cost and large area manufacturability2,3 and have attractive use in solution processing, such as spin-coating, inkjet-printing, blade coating and screen printing.

ITO Substrate

Source

Heater

Vapor Deposition Process

to vacuum pump

Hot Plate

ITO Substrate

Polymer Film (dry)

Small Molecular Film (wet)

Doctor Blade Solvent Evaporation

moving

Small molecular Solution

Blade Coating Process

ITO Substrate

Spin

Spin-Coating Process

Nozzle

Small Molecular Solution

ITO Substrate

Ink-Jet Printing Process

Small Molecular Solution

Nozzle

v



Solu

tion

-Pro

cessed O

LEDSolution-Processed OLED

Introduction

8988

　 In the past decades, numerous efforts have been focused on the synthesis of new materials which have been developed for solution-processed OLEDs. Among them are light-emitting polymer and dendrimers. Light-emitting polymers are considered to be suitable for solution-processed, although their performances are lower than vacuum deposited small molecules, and there are some intrinsic difficulties such as the control of batch-to-batch variations and the purification of the polymeric materials. Further-more, dendrimers are another important class of macromolecule since they were also successfully developed and used in solution-processed OLEDs5,6.

　 One of the most challenging tasks in fabricating multilayer solution-processed OLEDs is to avoid the interfacial mixing between different layers because most of the emissive and charge-transporting materials are soluble in common organic solvents. Extensive efforts have been invested in developing novel crosslinkable materials, after thermo- or photo-crosslinking, all these crosslinked layers possess very good solvent resistance which greatly facilitates the subsequent processing of the emitting layer. By taking advantage of these materials, high efficiency OLEDs have been realized7.

　 Recently, by adopting novel molecule structure design or processing strategies, solution-processed small molecule OLEDs are also successfully demonstrated and showed comparable performance to those vacuum evaporated processed counterparts8,9.

1.

2.

3.

4.

5.

6.

7.

8.

9.

Tang, C. W.; Van Slyke, S. A. Appl. Phys. Lett. 1987, 51, 913.

M. C. Gather, A. Köhnen , K. Meerholz , Adv. Mater. 2011, 23, 2.

J. Huang , G. Li , E. Wu , Q. Xu , Y. Yang , Adv. Mater. 2006, 18,114.

Grimsdale, A. C.; Chan, K. L.; Martin, R. E.; Jokisz, P. G.; Holmes, A. B. Chem. Rev. 2009, 109, 897–1091

and the references therein.

Li, J.; Liu, D. J. Mater. Chem. 2009, 19, 7584–7591 and the references therein.

Lo, S.; Burn, P. L. Chem. Rev. 2007, 107, 1097–1116 and the references therein.

Carlos A. Zuniga, Stephen Barlow, and Seth R. Marder, Chem. Mater. 2011, 23, 658–681.

Rehmann, N.; Hertel, D.; Meerholz, K.; Becker, H.; Heun, S. Appl. Phys. Lett. 2007, 91, 103507.

Hou, L. D.; Duan, L.; Qiao, J.; Li, W.; Zhang, D. Q.; Qiu, Y. Appl.Phys. Lett. 2008, 92, 263301.



Solu

tion

-Pro

cessed O

LED

Solution-Processed OLED : Small moleculesHole Transport Layer / Hole Injection Layer(HTL/HIL) Materials

9190

LT-E105 LT-N154

LT-N155LT-N137

LT-N140

Spiro-TPD DOFL-NPB

DOFL-TPDTAPC

HMTPD

NN

CAS No.GradeFormulaM.W.UVPLTGASolvent



: : : :: :::

: : : :: :::

: : : :: :::


678.86 g/mole379 nm (in THF)416 nm (in THF)> 280 °C (0.5% weight loss)Toluene, Chloroform

870197-09-4> 99% (HPLC)C61H64N2


439942-97-9> 99% (HPLC)C55H64N2


N,N'-Bis(3-methylphenyl)-N,N'-bis(phenyl)-2,7-diamino-9,9-spirobifluorene

N2,N7-Di(naphthalen-1-yl)-9,9-dioctyl-N2,N7-diphenyl-9H-fluorene-2,7-diamine

N,N'-Bis(3-methylphenyl)-N,N'-bis(phenyl)-9,9-dioctyl-fluorene

N N


: : : :: :::



Di-[4-(N,N-di-p-tolyl-amino)-phenyl]cyclohexane

NN


: : : :: :::



N,N,N',N'-Tetra-(3-methylphenyl)-3,3'-dimethylbenzidine

Reference : Organic Electronics 13 (2012) 914-918

NN

C8H17 C8H17

NN

C8H17 C8H17

LT-N157 VNPB

CAS No.GradeFormulaM.W.UVPLSolvent

: : : :: ::

1010396-31-2> 95% (HPLC)C48H36N2

640.81 g/mole339 nm (in THF)450 nm (in THF)Toluene, Chloroform

N4,N4'-Di(naphthalen-1-yl)-N4,N4'-bis(4-vinylphenyl)biphenyl-4,4'-diamine

N N



Solu

tion

-Pro

cessed O

LEDSolution-Processed OLED : Small molecules

Hole Transport Layer / Hole Injection Layer(HTL/HIL) Materials

9190

LT-N160

LT-N164

LT-N158

LT-N159

QUPD

VB-FNPD

ONPB

OTPD


: : : :: :::

1431521-16-2> 99% (HPLC)C52H48N2

700.95 g/mole347 nm (film)439 nm (film)> 300 °C (0.5% weight loss)Toluene, Chloroform

N4,N4'-Di(naphthalen-1-yl)-N4-(4-octylphenyl)-N4'-henylbiphenyl-4,4'-diamine

N N

C8H17

Reference : Journal of Photopolymer Science andTechnology, Vol, 25, 3(2012) 335-339

NN

O

O

O

O



: : : :: ::

746634-00-4> 99% (HPLC)C60H72N2O4

885.22 g/mole308,353 nm (in CH2Cl2)410 nm (in CH2Cl2)Toluene, Chloroform

N4,N4'-Bis(4-(6-((3-ethyloxetan-3-yl)methoxy)hexyl) phenyl)-N4,N4'-diphenylbiphenyl-4,4'-diamine

N4,N4'-Bis(4-(6-((3-ethyloxetan-3-yl)methoxy)hexyloxy)phenyl)-N4,N4'-bis(4-methoxyphenyl)biphenyl-4,4'-diamine



: : : :: ::

864130-79-0> 99% (HPLC)C62H76N2O8

945.28 g/mole353 nm (in CH2Cl2)439 nm (in CH2Cl2)Toluene, Chloroform

N N

O O

O O

OO

O O


: : : :: ::

1173170-48-3> 95% (HPLC)C75H56N2O2


9,9-Bis[4-[(4-ethenylphenyl)methoxy]phenyl]-N2,N7-di-1-naphthalenyl-N2,N7-diphenyl-9H -fluorene-2,7-diamine

Reference : 1. Organic Electronics 14 (2013) 1204–12102. J. Mater. Chem., 2009, 19, 3618-3623

NN

O O

9392



Solu

tion

-Pro

cessed O

LED

Solution-Processed OLED : Small moleculesHole Transport Layer / Hole Injection Layer(HTL/HIL) Materials

9392

GradeFormulaM.W.UVSolvent

: : :: :

> 99% (HPLC)C64H72F6N2O4

1047.26 g/mole300 nm (in CH2Cl2)Toluene, Chloroform

N,N'-(4,4'-(Cyclohexane-1,1-diyl)bis(4,1-phenylene))bis(N-(4-(6-(2-ethyloxetan-2-yloxy)hexyl)phenyl)-3,4,5-trifluoroaniline)


N N

F

F

FF

F

F

OO

O O

NN

C8H17 C8H17

NN

N2,N2'-(9,9-Dioctyl-9H-fluorene-2,7-diyl)bis(9,9- dimethyl-N2,N7,N7-triphenyl-9H-fluorene-2,7-diamine

GradeFormulaM.W.UVPLSolvent

: : : :::

> 97% (HPLC)C95H94N4


NN

N

N N

N

NC CN

NC

NC CN

CN


: : : :: :::

105598-27-4Sublimed, > 99% (HPLC)C18N12

384.27 g/mole282, 321 nm (in CH2Cl2)422 nm (in CH2Cl2)> 400 °C (0.5% weight loss)2-Propanone


Dipyrazino[2,3-f :2',3'-h ]quinoxaline-2,3,6,7,10,11-hexacarbonitrile

LT-N165

LT-N260

LT-N221X-F6-TAPC

3FTPD-C8

HAT-CN

CAS No.Grade

: :

MW > 20,000 (GPC)(C37H50N4S)n


LT-N181 PFNIBT

NN

NSN

n

II



Solu

tion

-Pro

cessed O



9392 9392

NNN


: : : :: :::


561.67 g/mole239, 292 nm (in CH2Cl2)410 nm (in CH2Cl2)> 370 °C (0.5% weight loss)Toluene, Chloroform


P O


: : : :: :::

1125547-88-7Sublimed, > 99% (HPLC)C37H25OP516.57 g/mole307, 317 nm (in CH2Cl2)346 nm (in CH2Cl2)> 290 °C (0.5% weight loss)Toluene, Chloroform


Reference : Appl. Phys. Lett. 94, 013301 2009


: : : :: :::

944465-42-3Sublimed, > 99% (HPLC)C72H48N4Si977.26 g/mole324, 338 nm (in CH2Cl2)362 nm (in CH2Cl2)> 380 °C (0.5% weight loss)Toluene, Chloroform

Bis[3,5-di(9H-carbazol-9-yl)phenyl]diphenylsilane


Si

N

N N

N

N P

PO

O


: : : :: :::


643.65 g/mole294, 338 nm (in CH2Cl2)361 nm (in THF)> 300 °C (0.5% weight loss)Toluene, Chloroform


3-(Diphenylphosphoryl)-9-(4-(diphenylphosphoryl)phenyl)-9H-carbazole

N

NN


: : : :: :::





S

P POO


: : : :: :::

1019842-99-9Sublimed, > 99% (HPLC)C36H26O2P2S584.60 g/mole315, 328 nm (in CH2Cl2)351 nm (in CH2Cl2)> 320 °C (0.5% weight loss)Toluene, Chloroform


Reference : J. Mater. Chem., 2011, 21, 14604–14609Reference : 1. Organic Electronics 13 (2012) 586-5922. Organic Electronics 13 (2012) 914-918

LT-N491

LT-N4011

LT-N494

LT-N4006

LT-N496

LT-N4009

26DCzPPy

PPO21

35DCzPPy

PPT

SPPO1

SiMCP2



Solu

tion

-Pro

cessed O

LED

Solution-Processed OLED : Small moleculesPhosphorescent Host Materials

9594

PO

PO


: : : :: :::


766.8 g/mole287 nm (in CH2Cl2)419 nm (in CH2Cl2)> 350 °C (0.5% weight loss)Toluene, Chloroform

Reference : Thin Solid Films 519 (2011) 4342–4346

2,7-Bis(diphenylphosphoryl)spiro[fluorene-7,11'-benzofluorene]


: : : :: :::

824426-27-9Sublimed, > 99% (HPLC)C56H35OP754.85 g/mole275 nm (film)365 nm (film)> 350 °C (0.5% weight loss)Toluene, Chloroform

Di(9,9-spirobifluoren-2-yl)-phenyl-phosphine oxide



: : : :: :::

1415633-86-1> 98% (HPLC)C74H53N2OP1017.20 g/mole349 nm (in CH2Cl2)466 nm (in CH2Cl2)> 320 °C (0.5% weight loss)Toluene, Chloroform


4'' ,4'''-(Phenylphosphoryl)bis(N-1-naphthyl-N-phenyl-1,1':4',1''-terphenyl-4-amine)

PO

PN NO3 3

PN NO4 4


: : : :: :::

1415633-87-2> 98% (HPLC)C86H61N2OP1169.39 g/mole347 nm (in CH2Cl2)471 nm (in CH2Cl2)> 450 °C (0.5% weight loss)Toluene, Chloroform


4''' ,4''''-(Phenylphosphoryl)bis(N-1-naphthyl-N-phenyl-1,1':4',1'':4'',1'''-quaterphenyl-4-amine)


: : : :: :::



9-(3,5-Bis(diphenylphosphoryl)phenyl)-9H-carbazole

Reference : Org. Lett. , 2011, 13, 3146-3149

N

P PO O

N

N


: : : :: :::


484.59 g/mole241, 292 nm (in CH2Cl2) 363 nm (in CH2Cl2)> 270 °C (0.5% weight loss)Chloroform

3,5-Di(9H-carbazol-9-yl)biphenyl

LT-N4029 LT-N4036

LT-N4039

LT-N4042

LT-N4034

LT-N4035

SPPO21 NP4PPO

CzPO2

Ph-MCP

Dspiro-PO

NP3PPO



Solu

tion

-Pro

cessed O



9594


6-(3',6'-Di-tert-butyl-6-(3,6-di-tert-butyl-9H-carbazol-9-yl)-9H-3,9'-bicarbazol-9-yl)-9-(4-(3',6'-di-tert-butyl-6-(3,6-di-tert-butyl-9H-carbazol-9-yl)-9H-3,9'-bicarbazol-9-yl)phenyl)-3',6'-bis(3,6-di-tert-butyl-9H-carbazol-9-yl)-9H-3,9'-bicarbazole


: : : ::::

1025079-68-8> 98% (NMR)C174H172N10

2403.29 g/mole244, 349 nm (in CH2Cl2)402 nm (in CH2Cl2)Toluene, Chloroform

N

N

NN

N N

N

N N

N

N NP O


: : : :: :::

1296229-26-9Sublimed, > 99% (HPLC)C42H29N2OP608.67 g/mole324, 338 nm (in CH2Cl2)361 nm (in CH2Cl2)> 270 °C (0.5% weight loss)Toluene, Chloroform

9-(3-(9H-Carbazol-9-yl)phenyl)-3-(diphenylphosphoryl)-9H-carbazole

NO

N


: : : :: :::

1424369-36-7Sublimed, > 99% (HPLC)C29H18N2O410.47 g/mole241, 293 nm (in CH2Cl2)364 nm (in CH2Cl2)> 270 °C (0.5% weight loss)Toluene, Chloroform

3-(3-(9H-Carbazol-9-yl)phenyl)benzofuro[2,3-b]pyridine




: : : :: :::

1338446-77-7Sublimed, > 99% (HPLC)C30H19NO409.48 g/mole242, 291 nm (in CH2Cl2)350 nm (in CH2Cl2)> 270 °C (0.5% weight loss)Toluene, Chloroform

9-(3-(Dibenzo[b,d]furan-2-yl)phenyl)-9H-carbazole


N

O


: : : :: ::

1428901-78-3> 99% (HPLC)C54H40N2O2

748.91 g/mole246, 295 nm (in CH2Cl2)381 nm (in CH2Cl2)1,2-dichloroethane, CHCl3

Reference : Organic Electronics, 14, 2013, 1614–1620

4,4'-Bis(3-((4-vinylphenoxy)methyl)-9H-carbazol-9-yl)biphenyl

N N

O

O

LT-N4041 LT-N4057

LT-N4061

LT-N4063

LT-N4047

G3-tCbz PCz-BFP

CzDBF

DV-CBP

mCPPO1



Solu

tion

-Pro

cessed O

LED

Solution-Processed OLED : Small moleculesPhosphorescent Dopant Materials

9796

N

N NIr



: : : :: :::

: : : :: :::


654.78 g/mole282, 377 nm (in THF)513 nm (in THF)> 300 °C (0.5% weight loss)Toluene, Chloroform



fac-Tris(2-phenylpyridine)iridium(III)

Bis(2-phenylpyridine)(acetylacetonate)iridium(III)

NIr

O

O

2


: : : :: :::



Tris[2-(p-tolyl)pyridine]iridium(III)

Ir

N

N N

NIr

3


: : : :: :::

1338784-40-9> 99% (HPLC)C57H48IrN3

967.3 g/mole400 nm (in film)539 nm (in film)> 250 °C (0.5% weight loss)Chloroform

fac-Tris(2-(3-p-xylyl)phenyl)pyridine iridium(III)

Reference : Appl. Phys. Lett. 91, 103507(2007)Reference : Appl. Phys. Lett. 91, 103507(2007)


LT-E504 LT-N522

LT-E505

LT-N506

fac-Ir(ppy)3 TEG

Ir(ppy)2(acac)

Ir(mppy)3

Reference : J. Mater. Chem., 2011,21, 4918-4926


: : : :: :::



Bis(2-benzo[b]thiophen-2-yl-pyridine)(acetylacetonate)iridium(III)

N

SIr

O

O

2

NIr

C6H13 3


: : : :: :::

1268460-37-2> 99% (HPLC)C63H66IrN3



Reference : Synthetic Metals 161 (2011) 148–152

LT-N741

LT-E709

Hex-Ir(phq)3

Ir(btp)2(acac)



Solu

tion

-Pro

cessed O


Phosphorescent Dopant Materials

9796



: : : :: :::

725251-24-1> 99% (HPLC)C65H57IrN4O2


Bis(2-(9,9-diethyl-fluoren-2-yl)-1-phenyl-1H-benzo[d ]imidazolato)(actylacetonate)iridium(III)

NNIr

O

O

2

N

C6H13

Ir

3


: : : :: :::

1240249-29-9> 99% (HPLC)C63H66IrN3




LT-N744

LT-N754

Ir(fbi)2(acac)

Hex-Ir(piq)3

Iridium(III) bis(4-(4-tert -butylphenyl) thieno[3,2-c ]pyridinato-N,C2') acetylacetonate

LT-N758 PO-01-TB

N

S

IrO

O

2


: : : :: ::



Reference : 1. TW I395804 , US 8,722,207 ; 2. Organic Electronics, 2012, 13, 2149-2155 ; 3. Mater. Chem. C, 2013, 1, 5008–5014

9998



Solu

tion

-Pro

cessed O

LED

Solution-Processed OLED : Small moleculesFluorescent Host Materials

9998


: : : ::::

1705571-71-6> 99% (HPLC)C69H58


1-(7-(9,9'-Bianthracen-10-yl)-9,9-dihexyl-9H-fluoren-2-yl)pyrene


C6H13 C6H13


: : : :: :::

474918-42-8Sublimed, > 98% (HPLC)C81H62

1035.36 g/mole353 nm (in THF)397, 419 nm (in THF)> 370 °C (0.5% weight loss)Toluene, Chloroform


2,7-Bis[9,9-di(4-methylphenyl)-fluoren-2-yl]-9,9-di(4-methylphenyl)fluorene


: : : :: :::

854046-47-2Sublimed, > 97% (HPLC)C54H42



2-[9,9-Di(4-methylphenyl)-fluoren-2-yl]-9,9-di(4-methylphenyl)fluorene

C8H17C8H17


: : : :: :::

1258522-34-7> 99% (HPLC)C73H66



1-(7-(9,9'-bianthracen-10-yl)-9,9-dioctyl-9H-fluoren-2-yl)pyrene

LT-N4005 LT-N4040

LT-E408

LT-E413

DAnF6Pye BAnF8Pye

TDAF

BDAF



Solu

tion

-Pro

cessed O


Fluorescent Dopant Materials

9998 9998

N N


: : : :: :::





N N


: : : :: :::



9,10-Bis[phenyl(m-tolyl)-amino]anthracene



: : : :: :::

517-51-1Sublimed, > 99%C42H28


5,6,11,12-Tetraphenylnaphthacene

NN

C6H13

C6H13

C6H13

C6H13


: : : :: ::

1258522-36-9> 99% (HPLC)C74H86N2

1003.49 g/mole303, 418 nm (in CH2Cl2)502 nm (in CH2Cl2)Toluene, Chloroform

4,4'-(1E ,1'E )-2,2'-(Naphthalene-2,6-diyl)bis(ethene-2,1-diyl)bis(N,N-bis(4-hexylphenyl)aniline)


Reference : 1. Organic Electronics 11 (2010) 641-648; 2. Appl. Mater. Interfaces, 2011, 3(7), 2496–2503

LT-N507 LT-N663

LT-N508

LT-E707

TTPA N-BDAVBi-C6

TPA

Rubrene



Solu

tion

-Pro

cessed O

LED

Solution-Processed OLED : Small moleculesElectron Transport Layer / Hole Blocking Layer (ETL/HBL) Materials

101100

NN

O


: : : ::: ::

15082-28-7Sublimed, > 99% (HPLC)C24H22N2O354.44 g/mole305 nm (in THF)380 nm (in THF)> 210 °C (0.5% weight loss)Toluene, Chloroform

2-(4-Biphenyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole

NN


: : : :: :::



2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline

NN


: : : :: :::



4,7-Diphenyl-1,10-phenanthroline

NN

N


: : : :: :::



3-(4-Biphenyl)-4-phenyl-5-tert-butylphenyl-1,2,4-triazole

NN

O O

NN

Reference :

Reference :

Journal of the Society for Information Display, Volume 19, Issue 4, pages 346–352, April 2011

Australian Journal of Chemistry 2012, 65(9), 1244-1251


: : : :: :::



1,3-Bis[2-(4-tert-butylphenyl)-1,3,4-oxadiazo-5-yl]benzene

B N

N

N


: : : :: :::

929203-02-1Sublimed, > 99% (HPLC)C42H42BN3


Tris(2,4,6-trimethyl-3-(pyridin-3-yl)phenyl)borane

Reference : Chemistry Letters. Vol. 36, No. 2, P262, 2007.

Reference : Chemistry Letters. Vol. 36, No. 2, P262, 2007.



LT-E303 LT-N836

LT-N855

LT-N856

LT-E304

LT-E305

PBD TAZ

OXD-7

3TPYMB

BCP

Bphen



Solu

tion

-Pro

cessed O


Electron Transport Layer / Hole Blocking Layer (ETL/HBL) Materials

101100



CAS No.GradeFormulaM.W.PLTGASolvent

: : : :: :::

: : : :: :::

: : : :: ::



1286708-86-8Sublimed, > 99% (HPLC)C36H29OPSi536.67 g/mole266 nm (in CH2Cl2)298 nm (in CH2Cl2)> 420 °C (0.5% weight loss)Toluene, Chloroform


690.79 g/mole381 nm (in CH2Cl2)> 400 °C (0.5% weight loss)Toluene, Chloroform

3,3',5,5'-Tetra[(m-pyridyl)-phen-3-yl]biphenyl

Diphenyl-4-triphenylsilylphenyl-phosphine oxide

1,3,5-Tris(4-(pyridin-4-yl)quinolin-2-yl)benzene

Reference : Org. Lett., 2008, 10(5), p941-944.


Reference : Adv. Funct. Mater. 2011, 21, 3889-3899

N

N

N


: : : :: :::





P O


: : : :: :::

1125547-88-7Sublimed, > 99% (HPLC)C37H25OP516.57 g/mole307, 317 nm (in CH2Cl2)346 nm (in CH2Cl2)> 290 °C (0.5% weight loss)Toluene, Chloroform


N

N

N

N

N

N

Reference : Electrochem. Solid-State Lett. 2011, Volume 14, Issue 1, Pages H33-H35.

LT-N862

LT-N4048

LT-N879

LT-N496

LT-N863

BP4mPy

TSPO1

TPyQB

SPPO1

TmPyPB

N

N

N

N

Si P O



Solu

tion

-Pro

cessed O

LED

Solution-Processed OLED : PolymersHole Transport Layer

103102

C8H17 C8H17

N

n


: : : :: :

220797-16-0MW > 30,000 (GPC)(C51H61N)n


Poly[(9,9-dioctylfluorenyl-2,7-diyl)-co -(4,4'-(N-(4-sec-butylphenyl) diphenylamine)]


N

n


: : : :: :

472960-35-3MW > 10000 (GPC)(C22H21N)n

371,388 nm (in CH2Cl2)424 nm (in CH2Cl2)Soluble in CHCl3, Chlorobenzene



n

N


: : : :: :

1333317-99-9MW > 10,000 (GPC)(C21H19N)n

371,388 nm (in CH2Cl2)424 nm (in CH2Cl2)Soluble in CHCl3, Chlorobenzene, Dichlorobenzene


: : :: :

MW > 10,000 (GPC)C73H82N2

380 nm (in THF)435 nm (in THF)Soluble in CHCl3, Chlorobenzene, Dichlorobenzene

Poly[(9,9-dioctylfluorenyl-2,7-diyl)-alt -co -(N,N' -bis{4-butylphenyl}-benzidine-N,N' -{1,4-diphenylene})]


: : :: :

MW > 10,000 (GPC)C16H18(C67H78N2)380 nm (in THF)494 nm (in THF)Soluble in CHCl3, Chlorobenzene, Dichlorobenzene

Poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(N,N' -diphenyl)-N,N' -di(p-butylphenyl)-1,4-diamino-benzene)] end capped with dimethylphenyl

Poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine]

LT-N168

LT-N169

LT-N170

LT-N148

LT-N149

PTAA

TFB

Poly-TPD

N N n


: : : :: :

870517-32-1MW > 10,000 (GPC)(C51H62N2)n

398 nm (in THF)425 nm (in THF)Soluble in CHCl3,Chlorobenzene, Dichlorobenzene

Poly[(9,9-dihexylfluorenyl-2,7-diyl)-alt-(N,N'bis{p-butylphenyl}-1,4-diaminophenylene)]

LT-N171

N Nn

HN N nH



Solu

tion

-Pro

cessed O

LEDSolution-Processed OLED : Polymers

Hole Transport Layer

103102

DescriptionSodium SulfateSolid contentPSD d50

PSD d90

ResistivityViscosity

Storage

FormOdourColourPEDOT:PSS ratioPEDOT work functionpHBoiling Point

: : : :: :::

:

: : : :: ::

Aqueous dispersion, blue liquid.Max. 400 ppmMax. 40 ppm1.3 - 1.7 wt%80 nm100 nm500-5000 Ωcm5-12 mPas

The product is sensitive to frost and should therefore not be stored at temperatures below 5°C.Avoid freezing!

liquidodourlessdark blue1:6 (by weight)approx 5.2 eV1.2 - 2.2 at 20°Capprox 100°C

Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate)

Technical Data (guide values, not a specification)

Specification

SO3HSO3- SO3H SO3HSO3

-

n

S

OOS

O OS

OOS

O OS

OOS

O O

2+

m

LT-PS001 PEDOT:PSS

N N n


: : : :: :

1115424-53-7MW > 10,000 (GPC)(C61H74N2)n


Poly[(9,9-dioctylfluorenyl-2,7-diyl)-alt-(N,N' -bis{p-butylphenyl}-1,1' -biphenylene-4,4' -diamine)]

Nn


: : : :: :

223569-31-1MW > 30,000 (GPC)(C51H61N)n


Poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(4,4'-(N-(p-butyl-phenyl))diphenylamine)]

LT-N174

LT-N172



Solu

tion

-Pro

cessed O

LED

Solution-Processed OLED : PolymersEmitting layer

105104

HO

N

H

n

HO

N

N

H

n


: : ::

MW > 10,000 (GPC)(C17H17NO)n

237, 263 nm (in CH2Cl2)Soluble in CHCl3,Chlorobenzene, Dichlorobenzene

Poly[3-(carbazol-9-ylmethyl)-3-methyloxetane] Poly(N-ethyl-2-vinylcarbazole)









: : : ::

: : : ::

MW > 10,000 (GPC)(C29H24N2O)n

238, 265 nm (in CH2Cl2)382 nm (in CH2Cl2)Soluble in CHCl3,Chlorobenzene, Dichlorobenzene

MW > 30,000 (GPC)(C14H9F2N)n



Poly[9-sec-butyl-2,7-difluoro-9H-carbazole]

CAS No.GradeFormulaSolubility


: : : :

: : : :

41008-78-0MW > 20,000 (GPC)(C16H15N)n

Soluble in CHCl3,Chlorobenzene, Dichlorobenzene

55447-28-4MW > 10,000 (GPC)(C14H11N)n

Soluble in CHCl3,Chlorobenzene, Dichlorobenzene


N

n

NH

n


: : : :: :

25067-59-8MW > 100,000 (GPC)(C14H11N)n

261, 294 nm (in CH2Cl2)380 nm (in THF)Soluble in CHCl3,Chlorobenzene, Dichlorobenzene

Nn


: : : :: :

25067-59-8MW > 20,000 (GPC)(C14H11N)n

261, 294 nm (in CH2Cl2)380 nm (in THF)Soluble in CHCl3,Chlorobenzene, Dichlorobenzene

Nn

LT-N4037 LT-N4075

LT-N4076

LT-N4077

LT-N4078

LT-N4038

LT-N4062

PCMO

PVK

PVK

PCOC

2,7-F-PVF

Nn

F F



Solu

tion

-Pro

cessed O


Emitting layer

105104


:: : : ::

874816-14-5MW = 50,000 ~ 150,000 (GPC)C16H18(C29H40)n


Poly(9,9-dioctylfluorenyl-2,7-diyl) end capped with dimethylphenyl

Reference : Appl. Phys. Lett., 2004, 85, 4576-4578


: : : :: :

123864-00-6MW = 50,000 ~ 150,000 (GPC)(C29H40)n




: : : :: :

210347-52-7MW > 20,000(C35H42N2S)n


Poly[(9,9-dioctylfluorenyl-2,7-diyl)-alt-(benzo[2,1,3]thiadiazol-4,7-diyl)]

Reference : Synthetic Metals, 152, 105, 2005


: : : :: :

201807-75-2MW = 50,000 ~ 150,000 (GPC)(C25H32)n


n

n

CH3

CH3CH3

CH3

NS

N

n

n


: : : :: :

210347-56-1MW > 20,000 (GPC)(C37H44S2)n


Poly[(9,9-di-n-octylfluorenyl-2,7-diyl)-alt-2,2'-bithiophene-5,5'-diyl)]

Poly[9,9-bis(2-ehtylhexyl)fluorenyl-2,7-diyl]


SS n


: : : :: :

188201-16-3MW > 20,000 (GPC)(C29H40)n


n

Poly(9,9-dioctylfluorenyl-2,7-diyl) Poly(9,9-dihexylfluorenyl-2,7-diyl)

LT-S933 LT-S958

LT-S979

LT-S9004

LT-S934

LT-S957

PFO PHF

P8T2PFO-DMP

F8BT



Solu

tion

-Pro

cessed O

LED


107106

Poly(9,9-di-(2-ethylhexyl)-9H-fluorene-2,7-vinylene) Poly(9,9-di-n-hexylfluorenyl-2,7-vinylene)



: : : :: :

: : : :: :

1019638-19-7MW > 20,000 (GPC)(C31H42)n

280 nm (in CH2Cl2)454 nm (in CH2Cl2)Soluble in CHCl3, Chlorobenzene, Dichlorobenzene

203927-82-6MW > 20,000 (GPC)(C27H34)n


n



: : :: :

: : :: :

MW > 20,000 (GPC)(C29H38)m(C17H24O2)n


MW > 20,000 (GPC)(C27H34)m(C17H24O2)n


Poly[(9,9-di-(2-ethylhexyl)-9H-fluorene-2,7-vinylene)-co-(2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene)](m:n=95:5 mole ratio)

Poly((9,9-dihexyl-9H-fluorene-2,7-vinylene)-co-(1-methoxy-4-(2-ethylhexyloxy)-2,5-phenylenevinylene)), (m:n=95:5 mole ratio)

Reference : Macromolecules, 2003, 36 (11), pp 3841-3847

O

O

nm

n



: : :: ::

: : : :: :

474975-19-4MW > 20,000 (GPC)(C47H52)n


474975-20-7MW > 20,000 (GPC)(C45H52)n


Poly[(9,9-dioctyl-2,7-divinylenefluorenylene)-alt -(9,10-anthracene)]

Poly[(9,9-dioctyl-2,7-divinylenefluorenylene)-alt -(4,4'-biphenylene)]

n

n

LT-A1007 LT-A1010

LT-A1011

LT-A1012

LT-A1008

LT-A1009 Poly(FV-CO-MEHPV)

O

Om

n



Solu

tion

-Pro

cessed O


Emitting layer

107106


: : : :: :

475101-36-1MW > 30,000 (GPC)(C48H66O2)n


Poly[(9,9-dioctyl-2,7-divinylenefluorenylene)-alt-{2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylene}]

Poly(9,9-di-n-dodecylfluorenyl-2,7-diyl)

O

O n

Reference : J. Am. Chem. Soc., 2007, 129 (43), pp 12904-12905


: : : :: :

248256-53-3MW > 40,000 (GPC)(C37H56)n


Reference : Sensors, 2010 IEEE, 2603-2606

n



: : : :: :

: : : :: :

577705-37-4MW > 30,000 (GPC)(C60H74O2)n


579505-60-5MW > 30,000 (GPC)(C39H48)n


Poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(1,4-diphenylene-vinylene-2-methoxy-5-{2-ethylhexyloxy}-benzene)]

Poly[(9,9-dioctyl-2,7-divinylenefluorenylene)-alt- (1,4-phenylene)]

nO

O

n



: : : ::

: : : :: :

MW > 10,000 (GPC)C16H18(C39H40)n


579505-48-9MW > 20,000 (GPC)C16H18(C33H48)n


Poly[(9,9-dihexylfluoren-2,7-diyl)-co -(anthracen-9,10-diyl)] end capped with dimethylphenyl

Poly[(9,9-dihexylfluoren-2,7-diyl)-alt -(2,5-dimethyl-1,4-phenylene)] end capped with dimethylphenyl

Reference : Nano Lett., 2007, 7 (10), pp 3013-3017

Reference : Nanotechnology. 2012, 23(7), 075701

n

n

LT-A1013 LT-A1016

LT-A1017

LT-A1018

LT-A1014

LT-A1015

PEPV PFD

PFH-A-DMP

PF-DMB



Solu

tion

-Pro

cessed O

LED


109108


: : : ::

MW > 20,000 (GPC)C16H18(C39H43N)n


Poly[(9,9-dihexylfluoren-2,7-diyl)-co -(9-ethylcarbazol-2,7-diyl)]end capped with dimethylphenyl

Reference : Journal of Power Sources 246, 2014, 184-191

N

n



: : : ::

: : : :: :

MW > 20,000 (GPC)C16H18(C37H48O2)n


856893-75-9MW > 30,000 (GPC)(C42H43N)n


Poly[{9,9-dioctylfluorenyl-2,7-diyl}-co-{1,4-(2,5-dimethoxy)benzene}] end capped with dimethylphenyl

Poly(9,9-n-dihexyl-2,7-fluorene-alt-9-phenyl-3,6-carbazole)

Nn

n

O

O


: : : :: :

1423043-97-3MW > 20,000 (GPC)(C39H46N2)n


Poly[(9,9-dioctylfluorenyl-2,7-diyl)-alt-(6,6'-{2,2'-bipyridine})]

Poly[(9,9-dioctylfluorenyl-2,7-diyl)-alt-(6,6'-{2,2':6',2''-terpyridine})]

Reference : ACS Nano, 2013, 7(3), pp 2231-2239

nN N



: : : ::

: : : :: :

MW > 30,000 (GPC)C16H18(C41H46N2)n


934690-41-2MW > 20,000 (GPC)(C44H49N3)n


Poly[(9,9-dioctyl-2,7-fluorenylene)-co-(3,8-phenanthroline)] end capped with dimethylphenyl

nNN

N

nN N

LT-A1019 LT-A1023

LT-A1024

LT-A1025

LT-A1020

LT-A1021

PFH-EC PFO-BPy



Solu

tion

-Pro

cessed O


Emitting layer

109108


: : : ::

MW > 20,000 (GPC)C40H36N2(C30H42)n


Poly[9,9-dioctylfluorenyl-2,7-diyl] end capped with N,N-Bis(4-methylphenyl)-aniline

Reference : New J. Phys. 2004, 6, 185

nN N



: : :: ::

: : :: :

1010129-39-1MW = 50,000 ~ 150,000 (GPC)C16H18(C25H32)n


MW > 20,000 (GPC)C28H18N4O2(C30H42)n


Poly[9,9-dihexylfluorenyl-2,7-diyl] end capped with dimethylphenyl

Poly[9,9-di-(2-ethylhexyl)-fluorenyl-2,7-diyl] end capped with dimethylphenyl

Poly[9,9-di-(2-ethylhexyl)-fluorenyl-2,7-diyl] end capped with 2,5-diphenyl-1,2,4-oxadiazole

nN

NO O

NN

n


: : : ::

MW > 20,000 (GPC)C28H18N4O2(C30H42)n


Poly[9,9-dioctylfluorenyl-2,7-diyl] end capped with 2,5-diphenyl-1,2,4-oxadiazole

NN

O ON

Nn



: : :: :

: : :: :

MW > 20,000 (GPC)C16H18(C29H40)n


MW > 20,000 (GPC)C40H36N2(C30H42)n


Poly[9,9-di-(2-ethylhexyl)-fluorenyl-2,7-diyl] end capped with N,N-Bis(4-methylphenyl)-aniline

Reference : Chin. J. Chem. 2010, 28, 1482-1486


n

N Nn

LT-A1026 LT-A1029

LT-A1030

LT-A1031

LT-A1027

LT-A1028



Solu

tion

-Pro

cessed O

LED


111110

Poly[(9,9-dihexylfluorenyl-2,7-diyl)-co-(9,10-anthracene)]


: : : :: :

474975-22-9MW > 10,000 (GPC)(C39H40)n



n



: : : ::

: : : :: :

MW > 20,000 (GPC)(C29H40)m(C6H4N2S)n


475102-99-9MW > 30,000 (GPC)(C40H54O2)n


Poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(1,4-benzo-{2,1',3}-thiadiazole)] (m:n=95:5 mole ratio)

Poly[(9,9-dihexylfluorenyl-2,7-diyl)-alt-(2-methoxy-5-{2-ethylhexyloxy}-1,4-phenylene)]


O

O n

nN

S N

m

Reference : Journal of Nanoscience and Nanotechnology, 2012, Vol.12, pp 5407-5411


: : : ::

MW > 10,000 (GPC)(C47H60N)n


Poly[(9,9-dioctylfluorenyl-2,7-diyl)-alt-(9-hexyl-3,6-carbazole)]

N

n


: : : ::

MW > 10,000 (GPC)C16H18(C47H60N)n


Poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(9-hexyl-3,6-carbazole)] end capped with dimethylphenyl

N

n


: : : :: :

474975-24-1MW > 20,000 (GPC)(C50H46)n


Poly[(9,9-dihexylfluorenyl-2,7-diyl)-alt-(9,9'-spiro-bifluorene-2,7-diyl)]

n

LT-A1032 LT-A1035

LT-A1036

LT-A1037

LT-A1033

LT-A1034

PFH-A



Solu

tion

-Pro

cessed O


Emitting layer

111110

n


: : : :::

1025775-95-4MW > 30,000 (GPC)C16H18(C35H44)n


Poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(1,4-phenylene)] end capped with dimethylphenyl

n


: : : :: :

773895-96-8MW > 20,000 (GPC)(C34H43N)n


nN


: : :: ::

1687752-52-8MW > 20,000 (GPC)(C37H48)n


Poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(2,5-p-xylene)]

Poly[(9,9-dioctylfluorenyl-2,7-diyl)-alt-(2,6-pyridine)]

LT-A1038

LT-A1039

LT-A1040



Solu

tion

-Pro

cessed O

LED

Solution-Processed OLED : PolymersElectron Transport Layer

PB112

C8H17 C8H17 n

NN


: : : :: :

673474-74-3MW > 10,000 (GPC)(C52H70N2)n




C8H17 C8H17 n

NNBr Br


: : : ::

MW > 10,000 (GPC)(C56H80N2Br2)n




LT-N4027

LT-N878

PFN-DOF

PFNBr



Organ

ic Ph

oto

voltaic (O

PV)

Organic Photovoltaic (OPV)Contents

113PB

• Introduction --------------------------------------------------------------------114

• Small Molecular / Oligomer Materials (65) -----------------------------------116

• Polymer Materials (36) ---------------------------------------------------------128

• Metallic Oxide Compact Layer Materials (5) ----------------------------------134



Organ

ic Ph

oto

voltaic (O

PV)

Organic Photovoltaic (OPV)Introduction

115114

Although organic photovoltaics have a relatively low efficiency compared to inorganic technologies, it is evaluated as one of the future key technologies, which could bring new applications and markets for the photovoltaics.

In the last decades, studies in the organic photovoltaics(OPVs) cells have achieved excellent results and high efficiencies. Heterojunction polymer solar cells with solution process, small molecule with vacuumed process and dye-sensitized solar cell with dyes has risen power conversion efficiency(PCE) above 10%.

Several improvements in research and studies have helped the development of organic photovoltaics :

( i ) (ii) (iii) (iv)

a better understanding of the mechanism of photon-to-electron conversion; new materials with tailored energy levels and solubility; new processing approaches to induce optimal microstructures in the active layer new device architectures with novel interfacial layers.



Organ

ic Ph

oto

voltaic (O

PV)

Organic Photovoltaic (OPV)Introduction

115114

Organic photovoltaics(OPV) have a lot of potentials and it is considered very promising in the field of solar energy. Lumtec is aimed to make efforts on the current challenges and hopefully we could make contributions in the recent progress as a manufacturer.

1. the potential to be flexible and semitransparent.2. potential to be manufactured in a continuous printing process.3. large area coating.4. easy integration in different devices.5. significant cost reduction compared to traditional solutions.6. substantial ecological and economic advantages.

Many advantages have been found in organic photovoltaics(OPV):



Organ

ic Ph

oto

voltaic (O

PV)

Organic Photovoltaic (OPV)Small Molecular / Oligomer Materials

117116

LT-S901 LT-S905

LT-S906

LT-E201

LT-S902

LT-S903

LT-S904

Pentacene PCBM

ZnPC

CuPC

PDCDT

C60

PenPTCN

N

N

N

N

N

N

N Cu


: : : :: ::

147-14-8Sublimed, > 99%C32H16CuN8

576.07 g/mole681 nm (in CH2Cl2)404 nm (film)> 430 °C (0.5% weight loss)


N

O

O

N

O

O

NN

O

O

O

O

C5H11C5H11

N

N

N

N

N

N

N

N Zn



: : : :: ::

: : : :: ::

135-48-8Sublimed, > 99%C22H14


76372-75-3Sublimed, > 99%C34H30N2O4


Pentacene

N,N'-Dipentyl-3,4,9,10-perylene dicarboximide


: : : :: ::

83054-80-2Sublimed, > 99%C52H50N2O4


N,N' -Bis(2,5-di-tert -butylphenyl)-3,4,9,10-perylene dicarboximide




: : : :::

: : : :::

: : : :::

99685-96-8> 99.5% (HPLC)C60


160848-22-6> 99.5% (HPLC)C72H14O2

910.88 g/mole258, 328 nm (in THF)> 350 °C (0.5% weight loss)

14320-04-8Sublimed, > 99%C32H16N8Zn577.91 g/mole534 nm (in CH2Cl2)> 410 °C (0.5% weight loss)

Fullerene-C60

(6,6)-Phenyl C61 butyric acid methyl ester

Zinc(II) phthalocyanine

OCH3

O



Organ

ic Ph

oto

voltaic (O

PV)


117116

LT-E206

LT-S918

LT-S919

LT-S920

LT-S921

LT-S923

TiOPC

PTCBI

ADIDI

PTCDA

PTCDI

PC71BM

N

N

N

N

N

N

N

N TiO

O

O

N

N

N

N

O

O

NN

N

N

O O

O

OO

O

N N

O

OO

O

HH



: : : :: ::

: : : : ::

26201-32-1Sublimed, > 99%C32H16N8OTi576.39 g/mole349, 689 nm (in CH2Cl2)392 nm (film)> 440 °C (0.5% weight loss)

81-33-4Sublimed, > 99%C24H10N2O4


Titanium(IV) oxide phthalocyanine

3,4,9,10-Perylenetetracarboxylic acid diimide



: : : :::

: : : : ::

55034-79-2Sublimed, > 99%C36H16N4O2


6859-32-1Sublimed, > 99%C44H20N4O4


Bisbenzimidazo[2,1-a :1',2-b']anthra[2,1,9-def:6,5,10-d'e'f' ] diisoguinoline-10,21-dione, with cis isomer

Anthra[2",1",9":4,5,6:6",5",10":4',5',6']diisoquino[2,1-a: 2',1'-a' ]diperimidine-12,25-dione, with cis isomer


: : : : ::

128-69-8Sublimed, > 99%C24H8O6


3,4,9,10-Perylenetetracarboxylic dianhydride

Reference : Organic Electronics 8 (2007), 735~742


: : : :: :

609771-63-3> 99% (HPLC)C82H14O2

1030.93 g/mole372 nm (in Toluene)> 360 °C (0.5% weight loss)

(6,6)-Phenyl C71 butyric acid methyl ester, mixture of isomers

Reference : Nature Photonic 6, 591-595 (2012)

OCH3

O



Organ

ic Ph

oto

voltaic (O

PV)


119118


: : : :::

1242279-48-6> 99% (HPLC)C74H18O2


(6,6)-Phenyl-C61 methyl-hexanoate

OCH3

O

N N

O

OO

O

NN

O

OO

O

C7H15 C7H15

N

NN

N

N

N

N

NCu

FF

F

F

FF

F

F

F

F

FFF

F

F

F

NN

NB N

N

N

Cl

CAS No.GradeFormulaM.W.UVPLTGA CAS No.



: : : :: :: :

: : :: ::

: : : :: ::

5521-31-3Sublimed, > 99%C26H14N2O4

419.40 g/mole522 nm (in CH2Cl2)532, 571 nm (in CH2Cl2)> 440 °C (0.5% weight loss) 36530-06-0

Sublimed, > 99%C24H12BN6Cl430.66 g/mole565 nm (in DMF)577 nm (in DMF)> 330 °C (0.5% weight loss)

95689-91-1Sublimed, > 99%C38H38N2O4


N,N'-Dimethyl-3,4,9,10-perylene dicarboximide

Boron subphthalocyanine chloride

N,N'-Diheptyl-3,4,9,10-perylene dicarboximide



Reference : Orange Electronics, vol.11 (No.8), pp1399-1402


: : : :: :

14916-87-1Sublimed, > 99%C32F16CuN8


Copper(II) 1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-hexadecafluoro-29H ,31H-phthalocyanine

OO

O

O

O

O


: : : :: ::

81-30-1Sublimed, > 99%C14H4O6

268.18 g/mole347, 366 nm (in CH2Cl2)394 nm (in CH2Cl2)>270 °C (0.5% weight loss)

1,4,5,8-Naphthalenetetracarboxylic dianhydride

LT-S924

LT-S925

LT-S926

LT-S928

LT-S943

LT-S946

NTDA

MePTC

HepPTC

F16CuPC

SubPC

PC61HM



Organ

ic Ph

oto

voltaic (O

PV)


119118

NN

NB N

N

N

Cl

N

N

SS

O

O

SSC6H13 S

S C6H13

N

NN

N

N

N

N

NCu


: : : :::

33273-09-5Sublimed, > 99%C48H24CuN8


Copper(II) 2,3-naphthalocyanine



: : : :::

: : : :::

142710-56-3Sublimed, > 99%C36H18BClN6


115383-22-7> 99% (HPLC)C70


Boron sub-2,3-naphthalocyanine chloride

(5,6)-Fullerene-C70


Reference : J. Am. Chem. Soc., 2011, 133(40) 15822-15825



: : : :::

: : : :::

1093468-95-1> 98% (NMR)C58H72N2O2S6


153151-22-5> 98%C80H112CuN8


2,5-Di-(2-ethylhexyl)-3,6-bis-(5''-n-hexyl-[2,2',5',2''] terthiophen-5-yl)-pyrrolo[3,4-c ]pyrrole-1,4-dione

Copper(II)-2,3,9,10,16,17,23,24-octa-n-hexyl-29H ,31H-phthalocyanine


N

NN

N

N

N

N

NCu

C6H13

C6H13

C6H13

C6H13

C6H13

C6H13 C6H13

C6H13

LT-S947 LT-S963

LT-S967

LT-S983

LT-S952

LT-S962

SubNC CuPC-8H

C70

TTPA

SMDPPEH

CuNC


: : : :::

142807-63-4Sublimed, > 99% (HPLC)C30H21NS3


Tris(4-(thiophen-2-yl)phenyl)amine

Reference : Appl. Phys. Lett., 94, 063304(2009)

N

S

S

S



Organ

ic Ph

oto

voltaic (O

PV)


121120

N

NN

N

N

N

N

NAl Cl


: : : :::

14154-42-8Sublimed, > 99%C32H16AlClN8

574.96 g/mole675 nm (in DMF)> 470 °C (0.5% weight loss)

Aluminum phthalocyanine chloride


N

S

S

S

N

NS S

O

O

C6H13

C6H13

SSC6H13

S SC6H13

N

NS S

O

O

C8H17

C8H17

SSC6H13

S SC6H13


: : : :::

1092356-36-9Sublimed, > 99% (HPLC)C48H33NS3


Reference : Appl. Phys. Lett., 94, 063304(2009)



: : : :::

: : ::::

1077629-69-6> 98% (NMR)C54H64N2O2S6


1435933-95-1> 98% (NMR)C58H72N2O2S6


2,5-Dihexyl-3,6-bis-(5''-n-hexyl-[2,2',5',2'']terthiophen-5-yl)-pyrrolo[3,4-c ]pyrrole-1,4-dione

2,5-Dioctyl-3,6-bis-(5''-n-hexyl-[2,2',5',2'']terthiophen-5-yl)-pyrrolo[3,4-c ]pyrrole-1,4-dione



N

NN

N

N

N

N

NPt


: : : :: ::

14075-08-2Sublimed, > 99%C32H16N8Pt707.60 g/mole228, 270 nm (in CH2Cl2)372.5 nm (in CH2Cl2)> 460 °C (0.5% weight loss)

Platium(II) phthalocyanineTris(4-(5-phenylthiophen-2-yl)phenyl)amine

LT-S984 LT-N219

LT-S9025

LT-S985

LT-S986

TPTPA PtPC

AlPCCl

SMDPPH

SMDPPO



Organ

ic Ph

oto

voltaic (O

PV)


121120



: : : :::

: : : :::

172885-96-0> 99% (HPLC)C69H8


1207461-57-1> 99% (HPLC)C78H16


C60 derivative,indene-C60 monoadduct

C60 derivative, indene-C60 bisadduct, mixture of isomers

Reference : J. Am. Chem. Soc.,2010, 132(4), pp1377-1382

Reference : J. Am. Chem. Soc.,2010, 132(4), pp1377-1382


: : : :::

1241836-03-2> 99% (NMR)C46H48N2O4S2


3,6-Bis(5-(benzofuran-2-yl)thiophen-2-yl)-2,5-bis(2-ethylhexyl)pyrrolo[3,4-c ]pyrrole-1,4(2H ,5H )-dione



: : : :::

188-94-3Sublimed, > 99%C32H16


Diindeno[1,2,3-cd :1',2',3'-lm ]perylene


N

N

O

O

S OSO

LT-S9029

LT-S9036

LT-S9040

LT-S9044

LT-S9030

ICMA

DIP

DPP(TBFu)2

BP

ICBA

N

NH N

HN

CAS No.FormulaM.W.UV

: : ::

52952-31-5C36H22N4

510.59 g/mole418, 432, 609, 665 nm (in CH2Cl2)

Tetrabenzoporphine

SN

NS

N

NCCN


: : : :::

1335150-09-8> 99% (HPLC)C28H19N5S2


2-((7-(5-(di-p-tolylamino)thiophen-2-yl)benzo[c ][1,2,5] thiadiazol-4-yl)methylene)malononitrile

Reference : J. Am. Chem. Soc., 2011, 133(40) 15822-15825

LT-S9046 DTDCTB



Organ

ic Ph

oto

voltaic (O

PV)


123122

S

S

S

SCN

CNNC

NC


: : : :::

1432613-96-1Sublimed, > 99%C22H8N4S4


2,2'-(5,5'-(thieno[3,2-b]thiophene-2,5-diyl)bis(thiophene-5,2-diyl))bis(methan-1-yl-1-ylidene)dimalononitrile

Si

SS

C8H17 C8H17

NC CN

NS

N NS

N

CAS No.GradeFormulaM.W.UV

: : : ::

1331742-87-0> 99% (HPLC)C38H40N6S4Si737.11 g/mole553 nm (in CH2Cl2)

7,7'-(4,4-bis-(n-octyl)dithieno[3,2-b:2',3'-d ]silole-2,6-diyl)dibenzo[c ][1,2,5]thiadiazole-4-carbonitrile

Reference : Org. lett., Vol. 13(18), 2011, p4962



: : : :::

1251742-94-5> 99% (NMR)C48H46N4S6


2,2'-(5',5''-(2,2'-bithiophene-5,5'-diyl)bis(3,4'-dibutyl-2,2'-bithiophene-5',5-diyl))bis(methan-1-yl-1-ylidene)dimalononitrile

S SSS S

NC

CN

CN

NC2

N

NN

N

N

N

N

NVO

Si

SS

NC CN

N


: : : :::

13930-88-6Sublimed, > 99%C32H16N8OV579.46 g/mole338, 684 nm (in CH2Cl2)> 400 °C (0.5% weight loss)

Vanadyl(IV) phthalocyanine



: : :::

1321562-79-1> 99% (HPLC)C42H27N3S2Si665.90 g/mole> 250 °C (0.5% weight loss)

2-(6-(4-(diphenylamino)phenyl)-4,4'-diphenyl-dithieno[3,2-b:2',3'-d ]silol-2-yl)-methylene-malononitrile


LT-S9053

LT-S9056

LT-S9061

LT-S9063

LT-S9048

VOPc

TPDCDTS

FT2TDMN

BCNDTS

DCV6T-Bu(1,2,5,6)



Organ

ic Ph

oto

voltaic (O

PV)


123122


: : : ::

1373957-22-2> 99% (HPLC)C84H41NO9


C60,N,N,N -trimethyl-1-(2,3,4-tris(2-(2-methoxyethoxy)ethoxy)phenyl)methanaminium monoadduct

Reference : J. Mater. Chem., 2012, 22, 8574–8578

NO

O O

O

O

O

O

O

O

Reference :

Reference :

1. Advanced Materials (Weinheim, Germany) (2014), 26(34), 5957-59612. Journal of the American Chemical Society (2012), 134(39), 16345-16351

Phys. Chem. Chem. Phys., 2012, 14, 14661–14666



: : : :::

: : : ::

1397242-70-4> 99% (NMR)C94H124N2O4S12


432493-75-9> 99% (HPLC)C32H48N2O6


2,6-Bis[2,5-bis(3-ethylrhodanine)-(3,3-dioctyl-2,2':5,2''-terthiophene)]-4,8-bis(2-ethylhexoy)benzo[1,2-b:4,5-b']dithiophene

2,4-Bis(4-(diisobutylamino)-2,6-dihydroxyphenyl)cyclobutane-1,3-bis(olate)

O

O

N N

OH

OH

HO

HO

LT-S9078

LT-S9079

LT-S9071

LT-S9073

LT-S9074

IC70BA

PrC60MA Iodide salt

PrC60MA

DR3TBDT

DIBSQ

Indene-C70 bisadduct, mixture of isomers


: : : :::

1563175-93-8> 99% (HPLC)C88H16



C60,N,N,N-trimethyl-1-(2,3,4-tris(2-(2-methoxyethoxy)ethoxy)phenyl)dimethanaminium monoadduct iodide salt


: : : :

1373957-23-3> 99% (HPLC)C85H44INO9

1386.23 g/moleReference : J. Mater. Chem., 2012, 22, 8574–8578

N

O

O

O

O O

O

O

O

O

I

S

S S

S

S

S

S

S

O

OC8H17

C8H17

S

NS

N

C8H17

C8H17S

O

S

O


: : : ::



Reference : J. Mater. Chem. A, 2013, 1, 4077–4082

N4,N4'-Bis(dibenzo[b,d ]thiophen-4-yl)-N4,N4'-diphenylbiphenyl-4,4'-diamine

N

N

N

LT-S9084 TBDI



Organ

ic Ph

oto

voltaic (O

PV)


125124

2,6-Bis{5-fluoro-7-(5'-hexyl-2,2'-bithiophen-5-yl)benzo[c ][1,2,5]thiadiazol-4-yl}-(4,4'-bis(2-ethylhexyl)dithieno[3,2-b :2',3'-d ]silole


: : :::

1402460-84-7> 99% (NMR)C64H72F2N4S8Si1219.89 g/mole690 nm (film)

Reference : 1. ACS Nano (2014), 8(8), 8141-81512.Chemistry of Materials (2014), 26(14), 4109-4118

LT-S9138 p-DTS(PTT2)2

Si

SS

NS N N S

N

SS

SSF F

3',4'-Dibutyl-5,5''-bis(dicyanovinyl)-2,2':5',2''-terthiophene

2,6-Bis[2,5-bis(3-octylrhodanine)-(3,3-dioctyl-2,2':5,2''-terthiophene)]-4,8-bis((5-ethylhexyl)thiophen-2-yl)benzo[1,2-b:4,5-b']dithiophene

5,5'-Bis((4-(7-hexylthiophen-2-yl)thiophen-2-yl)-[1,2,5]thiadiazolo[3,4-c]pyridine)-3,3'-di-2-ethylhexylsilylene-2,2'-bithiophene

Tin(II) phthalocyanine


: : : :::

15304-57-1Sublimed, > 99%C32H16N8Sn631.23 g/mole693 nm (in CHCl3)> 440 °C (0.5% weight loss)

Reference : Appl. Phys. Lett. 87, 153511(2005)Reference : ACS Nano (2015), 9(1), 371-377





: : ::::

: : ::::

: : :::

: : :::



908588-68-1Sublimed, > 99% (NMR)C28H24N4S3

512.71 g/mole578 nm(in CH2Cl2)> 200 °C (0.5% weight loss)

1651168-29-4> 99% (NMR)C114H152N2O2S14

2031.35 g/mole360, 504 nm (in CH2Cl2)

1351374-94-1> 99% (NMR)C62H72N6S8Si1185.88 g/mole366, 645 nm(in CH2Cl2)

2-(3,6-Bis(di-p-tolylamino)-9H-fluoren-9-ylidene)malononitrile

N

N

N

N

N

N

N

N Sn


Reference :

Solar Energy Materials & Solar Cells, 109, (2013), 33–39 Solar Energy Materials & Solar Cells, 109,

(2013), 33–39

ACS Applied Materials & Interfaces (2015), 7(6), 3691-3698

LT-S9125

LT-S9123

LT-S9124LT-S9086

LT-S9089 DCV3T

SMPV1

DTS(PTTh2)2SnPC

3,6-DTNFMN

NC CN

N N

SS S

CN

NC

NC

CN

S

S

S S

S S

S S

SN

NS

S

O

S

O

C8H17

C8H17

C8H17 C8H17 C8H17 C8H17

S

S

Si

SS

NN

N SN N

S N

SSSS C6H13C6H13



Organ

ic Ph

oto

voltaic (O

PV)


125124

3'H-Cyclopropa[8,25][5,6]fullerene-C70-3'-carboxylic acid


: : :::

180777-24-6> 99%C72H3O2

899.79 g/mole353, 370, 406 nm (in CH2Cl2)

Reference : Journal of Organic Chemistry (1996), 61(16), 5198-5199

LT-S9157

OH

H O

C70-COOH

2,3,9,10,16,17-Hexachlorinated boron subphthalocyanine chloride

5,10,15-Triphenyl-10,15-dihydro-5H-diindolo[3,2-a:3',2'-c]carbazole

Zinc(II)-1,8,15,22-tetrafluoro-29H ,31H -phthalocyanin,mixture of isomers




: : ::::

: : :::::

: : ::::

309963-65-3Sublimed, > 99%C24H6BCl7N6




1120355-28-3 Sublimed, > 99%C32H12F4N8Zn649.89 g/mole681, 725 nm (in CHCl3)> 250 °C (0.5% weight loss)

Reference :


Journal of Physical Chemistry C (2014), 118(27), 14813-14823

Journal of Materials Chemistry A: Materials for Energy and Sustainability (2013), 1(12), 4077-4082

Solar Energy Materials & Solar Cells (2013), 118, 165-170

LT-S9149

LT-S9156 LT-S9171

Cl6SubPc

TPDI F4ZnPc

N

N

NB

NNN

ClCl

Cl

Cl Cl

Cl

Cl

N

NN

N

NN

N

N

N

N

NZn

F

F

F

F

4-(1',5'-dihydro-1'-methyl-2'H -[5,6]fullereno-C60-Ih-[1,9-c ]pyrrol-2'-yl) benzoic acid


: : :::

631918-72-4> 99% (HPLC)C70H11NO2


Reference : 1. Journal of Physical Chemistry Letters (2015), 6(12), 2399-24052. ACS Nano (2014), 8(12), 12701-12709

LT-S9161 C60-COOH-SAM

NCH3

O

OH



Organ

ic Ph

oto

voltaic (O

PV)


127126

Zinc(II)-2,3,9,10,16,17,23,24-octafluoro-29H ,31H -phthalocyanin

Indium(III) phthalocyanine chloride

Tin(IV) 2,3-naphthalocyanine dichloride

[2,3,9,10,16,17-Hexachloro-7,12:14,19-diimino-21,5-nitrilo-5H -tribenzo[c,h,m][1,6,11]triazacyclopentadecinato(2)-N22,N23,N24]phenoxy-Boron

Iron(II) 1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-hexadecafluoro-29H ,31H -phthalocyanine







GradeFormulaM.W.UV

: : ::::

: : ::::

: : :::

: : :::

: : ::::

: : ::

676519-80-5Sublimed, > 99%C32H8F8N8Zn721.86 g/mole269, 633 nm (in CHCl3)> 300 °C (0.5% weight loss)

19631-19-7Sublimed, > 99%C32H16ClInN8

662.79 g/mole358, 683 nm (in CHCl3)> 300 °C (0.5% weight loss)

26857-61-4Sublimed, > 99%C48H24Cl2N8Sn902.37 g/mole> 300 °C (0.5% weight loss)

1309390-01-9> 99% (HPLC)C30H11BCl6N6O694.98 g/mole267, 318, 569 nm (in CHCl3)

23844-93-1Sublimed, > 99%C32F16FeN8

856.22 g/mole333, 627 nm (in Acetone)> 300 °C (0.5% weight loss)

> 99% (NMR)C66H82S8

1131.88 g/mole249, 359, 442 nm (in CH2Cl2)

Reference :

Reference :

Reference :

Reference :

Reference :

ChemPhysChem (2014), 15(12), 2462-2472

Organic Electronics (2015), 17, 229-239

Organic Electronics (2013), 14(3), 804-808


Nano Letters (2014), 14(10), 5547-5554

LT-S9172

LT-S9176

LT-S9180

LT-S9181

LT-S9177

LT-S9179F8ZnPc

InClPC

SnNCCl2

PhO-BsubPc

F16FePC

BDT2TH

N

NN

N

N

N

N

N

F

F

F

F F

F

F

F

Zn

N

NN

N

N

N

N

NInCl

N

NN

N

N

N

N

N

F

F

F

F F

F

F

F

Fe

F

F

F

F F

F

F

F

S

S

S

S

C8H17

C8H17

S

S

S

S

C8H17

C8H17

N

NN

N

N

N

N

NSnCl

Cl

N

Cl Cl

BN

N

N

N

N Cl

Cl

Cl

Cl

O



Organ

ic Ph

oto

voltaic (O

PV)


127126

Tin(II) 2,3-naphthalocyanine


: : :::

110479-58-8Sublimed, > 99%C48H24N8Sn831.47 g/mole> 300 °C (0.5% weight loss)

Reference : Journal of Physical Chemistry A (2011), 115(33), 9265-9272

LT-S9182 SnNC

N

NN

N

N

N

N

NSn



Organ

ic Ph

oto

voltaic (O

PV)

Organic Photovoltaic (OPV)Polymer Materials

129128

LT-S932

LT-S933

LT-S934

PFO

PFO-DMP


: : : :: :

177716-59-5MW > 100,000 (GPC)(C19H28O2)n


Poly[2-methoxy-5-(3,7-dimethyoctyoxyl)-1,4-phenylenevinylene]

Reference : Thin Solid Films 511-512 (2006) 587-592


: : : :: :

123864-00-6MW = 50,000 ~ 150,000 (GPC)(C29H40)n

376 nm (in THF)426, 440 nm (in THF)Soluble in CHCl3, Chlorobenzene, Dichlorobenzene

Poly(9,9-dioctylfluorenyl-2,7-diyl)


n

O

H3CO

n


: : : :::

874816-14-5MW = 50,000 ~ 150,000 (GPC)C16H18(C29H40)n




n

CH3

CH3CH3

CH3

MDMO-PPVLT-S909

LT-S911

LT-S931

P3HT

PT

MEH-PPV

CAS No.Grade

FormulaUVPLSolubility

: :

: :: :

104934-50-1MW > 45,000 (GPC)Regioregular Electronic Grade > 93%(C10H14S)n

445 nm (in THF) 564 nm (in THF)Soluble in CHCl3, Chlorobenzene, Dichlorobenzene

Poly(3-hexylthiophene-2,5-diyl)


CAS No.FormulaUVPL

: : ::

25233-34-5(C4H2S)n

427 nm (in CH2Cl2)510 nm (in CH2Cl2)

Poly(thiophene-2,5-diyl)


: : : :: :

138184-36-8MW > 100,000 (GPC)(C17H24O2)n


Poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene]


S n

S n

n

O

H3CO



Organ

ic Ph

oto

voltaic (O

PV)


129128


: : : :: :

888491-18-7MW = 40,000 ~ 80,000 (GPC)(C38H54S4)n

460 nm (in THF)557 nm (in THF)> 5 mg/mL in CHCl3

Poly[2,5-bis(3-dodecylthiophen-2-yl)thieno[3,2-b ]thiophene]



: : : :: :

: : : :: :

210347-52-7MW > 20,000(C35H42N2S)n


888491-19-8MW = 40,000 ~ 80,000 (GPC)(C42H62S4)n


Poly[(9,9-dioctylfluorenyl-2,7-diyl)-alt -(benzo[2,1,3]thiadiazol-4,7-diyl)]

Poly[2,5-bis(3-tetradecylthiophen-2-yl)thieno[3,2-b ]thiophene]

Reference : Synthetic Metals, 152, 105, 2005Reference : Appl. Phys. Lett., 92, 113309, 2008


: : : :: :

201807-75-2MW = 50,000 ~ 150,000 (GPC)(C25H32)n


Poly(9,9-dihexylfluorenyl-2,7-diyl)



: : : :: :

: : : :::

579505-53-6MW = 20,000 ~ 50,000 (GPC)(C31H34N2S)n


1379051-13-4MW = 20,000 ~ 50,000 (GPC)(C35H42N2S)n


Poly[(9,9-dihexylfluorenyl-2,7-diyl)-alt -(benzo[2,1,3]thiadiazol-4,7-diyl)]

Poly[(9,9-bis(2-ethylhexyl)fluorenyl-2,7-diyl)-alt -(benzo[2,1,3]thiadiazol-4,7-diyl)]

NS

N

n

n

S

SSS

C12H25

C12H25n

S

SSS

C14H29

C14H29n

NS

Nn

NS

Nn

LT-S957 LT-S982

LT-S9002

LT-S9003

LT-S958

LT-S981

F8BT PBTTT-C14

F6BT

F2EHBT

PHF

PBTTT-C12



Organ

ic Ph

oto

voltaic (O

PV)


131130


: : : :: :

188201-16-3MW > 20,000 (GPC)(C29H40)n

389 nm (in THF)418 nm (in THF)Soluble in THF, CHCl3, Chlorobenzene, Dichlorobenzene





: : : :: :

: : : :: :

: : : :: :

958261-50-2MW = 20,000 ~ 100,000 (GPC)(C43H47N3S3)n

390, 554 nm (in THF)639 nm (in THF)> 5 mg/mL in CHCl3

920515-34-0MW = 7,000 ~ 20,000 (GPC)(C31H38N2S3)n


782469-77-6MW = 10,000 ~ 50,000 (GPC)(C43H46N2S3)n


Poly[N-9'-heptadecanyl-2,7-carbazole-alt -5,5-(4',7'-di-2-thienyl-2',1',3'-benzothiadiazole)]

Poly[2,6-(4,4-bis-(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b']dithiophene)-alt -4,7(2,1,3-benzothiadiazole)]

Poly[2,7-(9,9-di-octyl-fluorene)-alt -4,7-bis(thiophen-2-yl)benzo-2,1,3-thiadiazole]

Reference : Orange Electronics, v12, 2011, P1788-1793


Reference : Adv. Funct. Mater., 2006, 16, 667-674

n

SS

NS

Nn

C8H17 C8H17

S S

NS

Nn


: : : :: :

1089687-02-4MW = 10,000 ~ 30,000 (GPC)(C30H38N2S3Si)n


Poly[2,6-(4,4'-bis(2-ethylhexyl)dithieno[3,2-b:2',3'-d]silole)-alt -4,7(2,1,3-benzothiadiazole)]

Reference : J.Am. Chem. Soc., 2008, 130, 16144-16145


: : : :: :

1035681-83-4MW = 8,000 ~ 20,000 (GPC)(C39H42N2S5)n


Poly[2,6-(4,4-bis(2-ethylhexyl)-4H-cyclopenta-[2,1-b:3,4-b']dithiophene-alt -4,7-bis(thiophen-2-yl)benzo-2,1,3-thiadiazole]


Si

SS

NS

Nn

SSS S

NS

N n

LT-S9004 LT-S950

LT-S951

LT-S953

LT-S948

LT-S949

PF2EH PFOBT

PSBTBT

PCPDTTBTT

PCDTBT

PCPDTBT

NS S

NS

Nn

C8H17 C8H17



Organ

ic Ph

oto

voltaic (O

PV)


131130

CAS No.GradeFormulaUVSolubility

: : : ::

1004272-92-7MW = 10,000 ~ 80,000 (GPC)(C42H46N2S3Si)n

530 nm (in CH2Cl2)Soluble in CHCl3, Chlorobenzene, Dichlorobenzene

Poly[2,7-(9,9-dioctyl-dibenzosilole)-alt -4,7-bis(thiophen-2-yl)benzo-2,1,3-thiadiazole]

Reference : Appl. Phys. Lett. 92, 033307, 2008



: : : ::

: : : ::

1098102-96-5MW > 50,000 (GPC)(C45H62O4S4)n


1147374-60-4MW > 10,000 (GPC)(C59H81N3O2S2)n


Poly[4,6-(dodecyl-thieno[3,4-b]thiophene-2-carboxylate)-alt -2,6-(4,8-dioctoxylbenzo[1,2-b:4,5-b ]dithiophene)]

Poly[N-9'-heptadecanyl-2,7carbazole-alt -3,6-bis(thiophen-5-yl)-2,5-dioctyl-2,5-dihydropyrrolo[3,4]pyrrole-1,4-dione]




: : : ::

1266549-31-8MW > 50,000 (GPC)(C41H53FO4S4)n


Poly{4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b' ]dithiophene-2,6-diyl-alt -3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophene-4,6-diyl}


CAS No.GradeFormulaUV

: : : ::

:: : :

1334549-75-5MW = 20,000 ~ 50,000 (GPC)(C56H70N2O2S3)n

522 nm (in CHCl3)Soluble in CHCl3, Chlorobenzene, Dichlorobenzene

360068-36-6Mw > 20,000 (GPC)(C31H42)n

455 nm (in CH2Cl2) Poly[2,7-(9-(tridecan-7-ylidene)-9H-fluorene)-alt -4,7-bis(thiophen-2-yl)-5,6-bis(octyloxy)benzo[c ][1,2,5]thiadiazole]

Poly[2,7-(9-(tridecan-7-ylidene)-9H-fluorene)-alt -4,7-bis(thiophen-2-yl)-5,6-bis(octyloxy)benzo[c ][1,2,5]thiadiazole]

Reference : Macromolecules, 2011, 4409, pp7617-7624

Reference : 1. Nature Photonics 6, 591-595 (2012)2. Adv. Mater., 2010, 22, 135-1383. Adv. Mater., 2014, 26, 6653-6657

SiC8H17 C8H17

S S

NS

Nn

S

SOC8H17

S

S

O OC12H25 n

OC8H17

N

NS

S

N

C8H17

C8H17 C8H17 C8H17

O

On

S

SF

S

SO

O

OO

n

S S

NS

N

C8H17O OC8H17

C6H13 C6H13

n

LT-S954

LT-S9050

LT-S9065

LT-S9006

LT-S955

LT-S9032PSiF-DTB

PTB7

PAFDTBT

PTB1

PCBTDPP

C8H17 C8H17 n



Organ

ic Ph

oto

voltaic (O

PV)


133132


: : : ::

1223479-75-1MW > 30,000 (GPC)(C40H53NO4S3)n


Poly{4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b' ]dithiophene-2,6-diyl-alt -(1,3-(5-octyl-4H -thieno[3,4-c]pyrrole-4,6(5H )-dione))}

Reference : 1. Chem. Mater. 2010, 22, 2696-26982. J. Am. Joc. Soc. 2010, 132, 5330-5331

S

N

S

SO

O

n

OO

C8H17


: : : :

MW > 30,000 (GPC)(C78H124N2O2S4)n


Poly[3,6-bis(4'-dodecyl[2,2'-bithiophen]-5-yl)-2,5-bis(2-ethylhexyl)-2,5-dihydropyrrolo[3,4-c ]-pyrrole-1,4-dione]

Reference : J. Phys. Chem. C, 2011,115(30), pp15075-15080

nSS

N

NS

O

O

C8H17

C8H17

C6H13

C6H13

S

C12H25

C12H25

LT-S9111

LT-S9112

PBDTTPD

pBBTDPP2

LT-S9109 PDPP3T


: : : ::

1198291-01-8MW > 30,000 (GPC)(C50H72N2O2S3)n


Poly{2,2'-[(2,5-bis(2-hexyldecyl)-3,6-dioxo-2,3,5,6-tetrahydropyrrolo[3,4-c ]pyrrole-1,4-diyl)dithiophene]-5,5'-diyl-alt -thiophen-2,5-diyl}


nS

S

N

NS

O

O

C8H17

C8H17

C6H13

C6H13


: : : ::

1279109-93-1MW = 7,000 ~ 30,000 (GPC)(C38H53NO2S3Si)n

614, 670 nm (film)Soluble in CHCl3, Chlorobenzene, Dichlorobenzene

Poly[2,6-(4,4'-bis(ethylhexyl)dithieno[3,2-b:2',3'-d ]silole)-alt -(1,3-(5-octyl-4H-thieno[3,4-c]pyrrole-4,6(5H)-dione))]


Si

SSS

NO O

C8H17

n

LT-S9066 PDTSTPD


: : : ::

1204005-82-2MW > 10,000 (GPC)(C47H54N2S3)n


poly{[2,7-(9,9-bis-(3,7-dimethyl-octyl)-fluorene)]-alt -[5,5-(4,7-di-2'-thienyl-2,1,3-benzothiadiazole)]}


nS

N SN

S


: : : ::

1255939-39-9MW > 30,000 (GPC)(C52H74N2O2S2)n


Poly{2,2'-[(2,5-bis(2-hexyldecyl)-3,6-dioxo-2,3,5,6-tetrahydropyrrolo[3,4-c ]pyrrole-1,4-diyl)]dithiophene-5,5'-diyl-alt -benzen-1,4-diyl}

Reference : 1. Chem. Mater. 2012, 24, 1316-13232. Adv. Mater. 2010, E242-E246

SN

NS

O

O

C8H17

C8H17

C6H13

C6H13

n

LT-S9113

LT-S9114

BisDMO-PFDTBT

PDPPTPT



Organ

ic Ph

oto

voltaic (O

PV)


133132


: : : :

MW > 7,000 (GPC)(C50H66N2S6Si)n


Poly{5,5'-bis(2-thienyl)-4,4,-dihexyl-2,2'-bithiazole-5',5''-diyl-alt -4,4'-bis(2-ethylhexyl)-dithieno[3,2-b:2',3'-d ]-silole-5,5'-diyl}

Reference : Macromolecules 2010, 43, 5706-5712

SS

N

N

SS

C6H13

C6H13

Si

SSn


: : : ::

1267540-03-3MW > 30,000 (GPC)(C62H90N2O2S4)n


Poly{2,2'-[(2,5-bis(2-octyldodecyl)-3,6-dioxo-2,3,5,6-tetrahydropyrrolo[3,4-c ]pyrrole-1,4-diyl)]dithiophene-5,5'-diyl-alt -2,2'-bithiophene-5,5'-diyl}


SS

N

NS

O

O

C8H17

C8H17

C10H21

C10H21

S n

LT-S9116

LT-S9117

LT-S9118

PBTzSBT

PDQT

PDBT-co-TT


: : : :

1260685-65-1MW > 30,000 (GPC)(C60H88N2O2S4)n


Poly{2,2'-[(2,5-bis(2-octyldodecyl)-3,6-dioxo-2,3,5,6-tetrahydropyrrolo[3,4-c ]pyrrole-1,4-diyl)]dithiophene-5,5'-diyl-alt -thieno[3,2-b]thiophen-2,5-diyl}

Reference : 1. Adv. Mater. 2010, 22, 4862-48662. Chem. Mater. 2012, 24, 1316-1323

nS

S

N

NS

O

O

C8H17

C8H17

C10H21

C10H21

S

LT-S9119

LT-S9139

PDPPBTT

PTB7-Th



: : : ::

: : ::

1270977-98-4MW > 30,000 (GPC)(C62H88N2O2S5)n


MW > 50,000 (GPC)(C8H6S2)(C49H57FO2S6)n

812 nm (in CHCl3)> 5 mg/mL in CHCl3

Poly{2,2'-(2,5-bis(2-octyldodecyl)-3,6-dioxo-2,3,5,6-tetrahydropyrrolo[3,4-c ]pyrrole-1,4-diyl)dithieno[3,2-b ]thiophene-5,5'-diyl-alt -thiophen-2,5-diyl}

Poly{4,8-bis[5-(2-ethylhexyl)thiophen-2-yl]benzo[1,2-b :4,5-b']dithiophene-2,6-diyl-alt-3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophene-4,6-diyl}



SN

NS

O

O

C8H17

C8H17

C10H21

C10H21

nS

S

S

S

SS

S

O O

F S

S

n

S

S

LT-S9178 PMDPP3T

GradeFormulaUV

: : :

MW > 30,000 (GPC)(C52H76N2O2S3)n

830 nm (in CHCl3)

Poly[[2,5-bis(2-hexyldecyl)-2,3,5,6-tetrahydro-3,6-dioxopyrrolo[3,4-c]pyrrole-1,4-diyl]-alt -[3',3''-dimethyl-2,2':5',2''-terthiophene]-5,5''-diyl]

N

NO

O

SS

C8H17

C8H17

C6H13

C6H13

Sn



Organ

ic Ph

oto

voltaic (O

PV)

Organic Photovoltaic (OPV)Metallic Oxide Compact Layer Materials

PB134


CAS No.GradeFormula

: ::

1345045-27-3MW > 20,000 (GPC)(C70H102N2O4)nC12H10

6,6'-(9',9'-Bis(6-((3-ethyloxetan-3-yl)methoxy)hexyl)-7,7'-diphenyl-9H ,9'H -2,2'-bifluorene-9,9-diyl)bis(N,N-diethylhexan-1-amine)

LT-N177 PFN-OX

O O

O O

N N

n


: :::

MW > 20,000 (GPC)(C37H50I2N4S)n


Poly(9,9-bis(6-trimethyl ammoniumiodide)-hexyl-fluorene-2,7-diyl-alt-(benzo[2,1,3]thiadiazol-4,7-diyl))

LT-N181 PFNIBT

NN

NSN

n

II

C8H17 C8H17 n

NNBr Br


: : : ::

MW > 10,000 (GPC)(C56H80N2Br2)n


Poly[(9,9-bis(3'-((N,N -dimethyl)-N -ethylammonium)-propyl)-2,7-fluorene)-alt-2,7-(9,9-dioctylfluorene)]


LT-N878 PFNBr

C8H17 C8H17 n

NN


: : : :: :

673474-74-3MW > 10,000 (GPC)(C52H70N2)n




LT-N4027 PFN-DOF



: : :::

631918-72-4> 99%C70H11NO2




NCH3

O

OH



135

Dye-Sen

sitized So

lar Cell(D

SSC)

Dye-Sensitized Solar Cell (DSSC)Contents

• Introduction --------------------------------------------------------------------136

• Hole Transport Materials (8) ---------------------------------------------------138

• Redox Couple Electrolytes Materials (14) --------------------------------------140

• Dye-sensitized Materials (13) --------------------------------------------------142



136

Dye-Sen

sitized So

lar Cell (D

SSC)

Dye-Sensitized Solar Cell (DSSC)Introduction

　Dye –sensitized solar cell (DSSC) is one of the alternatives for global energy in

recent years. It has attracted much attention for the next-generation photovoltaic

(PV) devices over conventional silicon based solar cells. Basically the components of

DSSC device consist of a porous layer of titanium dioxide nano-particles covered by

a molecular dye, a redox couple, and a metal-based (Pt) counter electrode. Among all

these components, the redox couple is the critical factor to achieve high efficiency and

durability.

　Recently, the power conversion efficiency (PCE) has risen up to 13% by using cobalt

redox couple1. In DSSC, the redox electrolyte is not only produced by the oxidized

sensitizer but also acts as an electrically conducting medium. Electrolytes have three

groups: liquid electrolyte, quasi-solid electrolyte and solid electrolyte. Liquid electrolyte

is commonly used in the most of DSSCs. The redox couple is the key component in a

liquid electrolyte and it has some vital requirements[2]:

Device structure of Dye –Sensitized Solar Cells

FTO FTOTiO2 Dye Electrolyte P1

1.

2.

3.

4.

5.

The redox potential should be less negative than the oxidized level of a dye molecule.

Slow electron recombination kinetics as the interface.

Slight visible-light absorption.

Fast electron-transfer (ET) kinetics at counter electrode.

Good photochemical stability.



137

Dye-Sen

sitized So

lar Cell (D

SSC)

Dye-Sensitized Solar Cell (DSSC)Introduction

　The I-/I3- is a typically redox couple in DSSCs device for many years. But it has certain constraints. Comparing to the sensitizer oxidation potential (E0= ~1.0V vs NHE), The I

-/

I3- oxidation potential (E0= 0.35V vs NHE) has large difference. Additional drawbacks

of the I-/I3- redox couple are the absorption of tri-iodide up to 430 nm and the volatile of iodine, so the alternative redox couples also have been studied for DSSCs. The

transition-metal-based redox is also investigated, including ferrocene/ferrocenium,

copper(I/II), cobalt(I/II), nickel(III/IV) complexes..

1.

2.

S. Mathew, A. Yella, P. Gao, R. Humphry-Baker, B. F. E. Curchod, N. Ashari-Astani, I. Tavernelli, U.

Rothlisberger, M. K. Nazeeruddin, M. Grätzel, Nat. Chem. 2014, 6, 242-247.

Lingamallu Giribabu, Ramababu Bolligarla, Mallika Panigrahi, Chem. Rec. 2015, 15, 4, 760-788.



138

Dye-Sen

sitized So

lar Cell (D

SSC)

Dye-Sensitized Solar Cell (DSSC)Hole Transport Materials

C8H17 C8H17

N

n


: : : :: :

220797-16-0MW > 30,000 (GPC)(C51H61N)n


Poly[(9,9-dioctylfluorenyl-2,7-diyl)-co -(4,4'-(N-(4-sec-butylphenyl)diphenylamine)]

LT-N148 TFB

N

n


: : : :: :

472960-35-3MW > 10,000 (GPC)(C22H21N)n

371, 388 nm (in CH2Cl2)424 nm (in CH2Cl2)Soluble in CHCl3, Chlorobenzene



LT-N149 Poly-TPD

N

N

OCH3

N

N

OCH3

H3CO

H3CO

OCH3

OCH3

OCH3

OCH3

Reference :


Reference : J. Am. Chem. Soc. 2014, 136, 7837-7840 1.MRS. BULLETIN, 30, 2005, p232.Appl. Phys. Lett. 100, 173512 (2012)




: : : :: ::

: : :: :::

: : :::::

207739-72-8> 99.5% (HPLC)C81H68N4O8


1573202-44-4> 99% (HPLC)C81H68N4O8


1628961-22-7> 98.5% (HPLC)C81H68N4O8


2,2',7,7'-Tetrakis(N,N-di-p-methoxyphenylamino)-9,9'-spirobifluorene

N2,N2',N7,N7'-Tetrakis(3-methoxyphenyl)-N2,N2',N7,N7'-tetrakis(4-methoxyphenyl)-9,9'-spirobi[fluorene]-2,2',7,7'-tetraamine


LT-S922

LT-S9145

LT-S9146Spiro-MeOTAD

p,m-Spiro-MeOTAD

p,o-Spiro-MeOTAD

N

N

N

N

H3CO

H3CO OCH3

OCH3

OCH3

OCH3 H3CO

H3CO

N

N

OCH3

N

N

OCH3

OCH3

OCH3

OCH3

OCH3

H3CO

H3CO



139

Dye-Sen

sitized So

lar Cell (D

SSC)

Dye-Sensitized Solar Cell (DSSC)Hole Transport Materials


n

N


: : : :: :

1333317-99-9MW > 10,000 (GPC)(C21H19N)n



LT-N168 PTAA

LT-S909 P3HT


: : : :: :

156074-98-5MW > 45,000 (GPC)(C10H14S)n



Reference : Journal of Power Sources, 251, (2014), 152-156

S n


PSD d90


Storage


: : : :: :::

:

: : : :: ::






Specification


-

n

S

OOS

O OS

OOS

O OS

OOS

O O

2+

m

LT-PS001 PEDOT:PSS



140

Dye-Sen

sitized So

lar Cell (D

SSC)

Dye-Sensitized Solar Cell (DSSC)Redox Couple Electrolytes Materials

CAS No.GradeFormulaM.W.E0

2+/3+


2+/3+


2+/3+


2+/3+


2+/3+


2+/3+

: : : ::

: : : ::

: : : ::

: : : ::

: : : ::

: : : ::

1346416-70-3> 99% (NMR)C24H21CoF18N9P3

1169.43 g/mol0.96 V vs NHE

1353745-90-0 > 99% (NMR)C34H24CoF12N8O8S4

1087.78 g/mol0.57 V vs NHE

79151-78-3> 99% (HPLC)C30H24CoF12N6P2

817.41 g/mol0.56 V vs NHE

1353745-91-1 > 99% (NMR)C36H24CoF18N9O12S6

1367.92 g/mol0.57 V vs NHE

28277-53-4 > 99% (NMR)C30H24CoF18N6P3


312322-08-0 > 99% (NMR)C26H20CoF12N8P2


Tris(1-(pyridin-2-yl)-1H-pyrazol)cobalt(III) tris(hexafluorophosphate)

Tris-(2,2'-bipyridine)cobalt(II) bis(trifluoromethanesulfonimide)

Tris-(2,2'-bipyridine)cobalt(II) bis(hexafluorophosphate) Tris-(2,2'-bipyridine)cobalt(III) tris(trifluoromethanesulfonimide)

Tris-(2,2'-bipyridine)cobalt(III) tris(hexafluorophosphate)

Bis(6-(1H -pyrazol-1-yl)-2,2'-bipyridine)cobalt(II) bis(hexafluorophosphate), mixture of stereoisomers

LT-S9135 LT-S9185

LT-S9183 LT-S9186

LT-S9184LT-S9187

FK102 Co(III) PF6_Salt Co(II)(bpy)3(TFSI)2

Co(II)(bpy)3(PF6)2 Co(III)(bpy)3(TFSI)3

Co(III) (bpy)3(PF6)3

Co(II)(bpy-pz)2(PF6)2


Reference :

Reference :

Reference :

Reference :

J. Am. Chem. Soc., 2011, 133, 18042-18045 Chem. Mater., 2013, 25 (13), pp 2733-2739

J. Am. Chem. Soc., 2010, 132, 16714

Chem. Mater., 2013, 25 (13), pp 2733-2739

Chem. Mater., 2013, 25 (13), pp 2733-2739

1. Phys. Chem. Chem. Phys., 2013, 15, 7087-70972. Nat. Commun. 3:631

Co

3+

(PF6)3

NNN

N

N NN

NN

NN

NN

N

NCo

2+

(PF6)2

NN

NN

N

NCo

3+

(PF6)3

NN

NN

N

NCo

2+

(TFSI)2

NN

NN

N

NCo

3+

(TFSI)3

Co

2+

NN

NN

NN

NN

(PF6)2



141

Dye-Sen

sitized So

lar Cell (D

SSC)

Dye-Sensitized Solar Cell (DSSC)Redox Couple Electrolytes Materials


2+/3+

GradeFormulaM.W.E0

2+/3+


2+/3+


2+/3+

: : : ::

: : ::

: : : ::

: : : ::

1346417-60-4> 99% (NMR)C26H20CoF18N8P3


> 99% (NMR)C36H21CoF12N9O6P2

1024.47 g/mol0.85 V vs NHE

31876-74-1> 99% (NMR)C36H24CoF12N6P2


28277-59-0> 99% (NMR)C36H24CoF18N6P3

1034.44 g/mol0.61 V vs NHE

Bis(6-(1H -pyrazol-1-yl)-2,2'-bipyridine)cobalt(III) tris(hexafluorophosphate) , mixture of stereoisomers

Tris(5-nitro-1,10-phenanthroline)cobalt(II) bis(hexafluorophosphate)

Tris(1,10-phenanthroline)cobalt(II) bis(hexafluorophosphate)

Tris(1,10-phenanthroline)cobalt(III) tris(hexafluorophosphate)

LT-S9188 LT-S9193

LT-S9191

LT-S9192

Co(III)(bpy-pz)2(PF6)3 Co(II)(NO2-phen)3(PF6)2

Co(II)(phen)3(PF6)2

Co(III)(phen)3(PF6)3

Reference :

Reference :

Reference :

1. Phys. Chem. Chem. Phys., 2013, 15, 7087-70972. Nat. Commun. 3:631

Phys. Chem. Chem. Phys., 2013, 15, 7087-7097

Phys. Chem. Chem. Phys., 2013, 15, 7087-7097

Co

3+

NN

NN

NN

NN

(PF6)3

NN

NN

N

NCo

2+

(PF6)2

NN

NN

N

NCo

3+

(PF6)3

NN

NN

N

NCo

2+

(PF6)2

NO2

O2N

NO2

GradeFormulaM.W.E0

2+/3+


2+/3+

: : ::

: : : ::

> 99% (NMR)C36H21CoF18N9O6P3

1169.43 g/mol0.85 V vs NHE

1392221-69-0> 99% (NMR)C24H21CoF12N9P2


Tris(1-(pyridin-2-yl)-1H-pyrazol)cobalt(II) bis(hexafluorophosphate)

Tris(5-nitro-1,10-phenanthroline)cobalt(III) tris(hexafluorophosphate)

LT-S9195

LT-S9194

FK102 Co(II) PF6Salt

Co(III)(NO2-phen)3(PF6)3

Reference : J.Mater. Chem. A, 2015,3, 12159-12162

NN

NN

N

NCo

3+

(PF6)3

NO2

O2N

NO2

Co

2+

(PF6)2

NNN

N

N NN

NN



142

Dye-Sen

sitized So

lar Cell (D

SSC)

Dye-Sensitized Solar Cell (DSSC)Dye-sensitized Materials

N

N

OCH3

N

N

OCH3

H3CO

H3CO

OCH3

OCH3

OCH3

OCH3

NN

RuNCS

NCSN

N

OO

O O

HO

O

OH

O

NBu4

NBu4

NN

C9H19

RuNCS

NCSN

N

HOOC

C9H19

COOH

NS COOH

NC

N O COOH

CN

Reference : 1.MRS. BULLETIN, 30, 2005, p232.Appl. Phys. Lett. 100, 173512 (2012)


: : : :: ::

207739-72-8> 99.5% (HPLC)C81H68N4O8





: : : ::

: : : ::

207347-46-4 > 98% (HPLC)C58H86N8O8RuS2 1188.55 g/mole313, 534 nm (in EtOH)

502693-09-6 > 98% (HPLC)C42H52N6O4RuS2 870.10 g/mole 295, 531 nm (in EtOH)

Di-tetrabutylammonium cis-bis(isothiocyanato)bis(2,2'-bipyridyl-4,4'-dicarboxylato)ruthenium(II)

cis-Bis(isothiocyanato)(2,2'-bipyridyl-4,4'-dicarboxylato)(4,4'-di-nonyl-2'-bipyridyl)ruthenium(II)



: : : :: ::

1234799-59-7> 99% (NMR)C41H32N2O2S616.10 g/mole421 nm (in THF)538 nm (in THF)> 250 °C (0.5% weight loss)

(E)-3-(5-(2-(N-(naphthalen-5-yl)-N-phenylamino)-9,9-diethyl-9H-fluoren-7-yl)thiophen-2-yl)-2-cyanoacrylic acid

Reference : Chem. Commun.,2005, 4098-4010Reference : Inorg. Chem. 1999, 38, 6298-6305


: : : :: ::

1096712-02-5> 99% (NMR)C28H20N2O3


(E)-2-cyano-3-(5-(4-(diphenylamino)styryl)furan-2-yl)acrylic acid

Reference : Org. Lett. 2009, 11, 97

LT-S922 LT-S964

LT-S9023

LT-S9024

LT-S945

Spiro-MeOTAD Z-907

DEFL-NPB-TCA

DPAS-FCA

N719



143

Dye-Sen

sitized So

lar Cell (D

SSC)


O-

ON

N+C8H17

OHO

O-

ON

N+C8H17

OHO



: : : :::

: : : :::

951248-19-4> 99% (HPLC)C37H44N2O4


1240041-84-2> 99% (HPLC)C41H46N2O4


(E)-4-((5-carboxy-3,3-dimethyl-1-octyl-3H-indolium-2-yl)methylene)-2-((E)-(1-ethyl-3,3-dimethylindolin-2-ylidene)methyl)-3-oxocyclobut-1-enolate

(E)-4-((5-carboxy-3,3-dimethyl-1-octyl-3H -indolium-2-yl)methylene)-2-((E)-(3-ethyl-1,1-dimethyl-1H-benzo[e ]indol-2(3H )-ylidene)methyl)-3-oxocyclobut-1-enolate



COOH

SN N

N

NC

CAS No.GradeFormulaUVTGA

: : : ::

1415134-59-6> 99% (NMR)C28H18N4O2S324, 486 nm (in THF)> 240 °C (0.5% weight loss)

2-Cyano-3-(7-(4-(diphenylamino)phenyl)-benzo[c ][1,2,5] thiadiazol-4-yl)acrylic acid

Reference : Chem. Commun. 2012, 48, 12071-12073

LT-S9037

LT-S9038

LT-S9068

SQ01

SQ02

RL-1

Reference : ACS Nano, 2014, 8 (2), pp 1674-1680


GradeFormulaM.W.

GradeFormulaM.W.

: : : ::

: : :

: : :

1393343-58-2> 99% (NMR)C30H21N5S483.59 g/mole306, 568 nm (in CH2Cl2)

> 99% (NMR)C18H14N4O2S350.39 g/mole

> 99% (NMR)C40H43N3O2S629.85 g/mole

2-((7-(4-(dip-tolylamino)phenyl)benzo[c ] [1,2,5]thiadiazol-4-yl)methylene)malononitrile

2-Cyano-3-(7-(4-(dimethylamino)phenyl)-benzo[c ][1,2,5]-thiadiazol-4-yl)acrylic acid

(E)-2-cyano-3-(10-hexyl-7-(9-hexyl-9H-carbazol-3-yl)-10,10a-dihydro-4aH-phenothiazin-3-yl)acrylic acid

LT-S9122

LT-S9121

LT-S9120

DTDCPB

CDMA-PBTCA

PTCbCA

CO2H

SN N

N

NC

N

NS

N

CNNC


: : :::

1263863-11-1> 99% (HPLC)C32H24N4O2S2

560.6900 g/mole546 nm (in CH2Cl2)

(E)-2-cyano-3-(5-(7-(4-(p-tolyl)-1,2,3,3a,4,8b-hexahydrocyclopenta[b]indol-7-yl)benzo[c][1,2,5]thiadiazol-4-yl)thiophen-2-yl)acrylic acid

LT-S9166 WS-2

Reference : 1.MRS. BULLETIN, 30, 2005, p232.Appl. Phys. Lett. 100, 173512 (2012)

N

NS

NS COOH

CN

N

S

N

COOH

CN

C6H13

C6H13

*New



144

Dye-Sen

sitized So

lar Cell (D

SSC)





: : :::

: : :::

: : ::::

1334739-85-3> 99% (HPLC)C40H41N5O2S655.8610 g/mole496 nm (in CH2Cl2)

1440205-23-1> 99% (HPLC)C46H34N4O2S706.8640 g/mole529 nm (in CH2Cl2)

1573202-31-9> 99% (HPLC)C85H76N4O8


(E)-2-cyano-3-(5-(2-octyl-7-(4-(p-tolyl)-1,2,3,3a,4,8b-hexahydrocyclopenta[b]indol-7-yl)-2H-benzo[d ][1,2,3]triazol-4-yl)thiophen-2-yl)acrylic acid

(E)-2-cyano-3-(5-(2,3-diphenyl-8-(4-(p-tolyl)-1,2,3,3a,4,8b-hexahydrocyclopenta[b]indol-7-yl)quinoxalin-5-yl)thiophen-2-yl)acrylic acid

2,2',7,7'-Tetrakis(4,4'-dimethoxy-3-methyldiphenylamino)-9,9'-spirobifluorene

LT-S9167

LT-S9168

LT-S9170WS-5

IQ-4

Spiro-MeOTAD-HTM1

Reference :

Reference :

Reference : Chem. Mater. 2011, 23, 4394; ACS Appl. Mater. Interfaces 2014, 6, 14621

ACS Appl. Mater. Interfaces 2013, 5, 4986; J. Am. Chem. Soc. 2014, 136, 5722.

ACS Appl. Mater. Interfaces 2015, 7, 11107−11116

N

NN

NS COOH

CN

NS COOH

CN

NN

N

N

OCH3

N

N

OCH3

H3CO

H3CO

OCH3

OCH3

OCH3

OCH3Me Me

Me Me

*New



Pero

vskite Solar C

ellsPerovskite Solar Cells

Contents

145PB

• Introduction --------------------------------------------------------------------146

• Perovskite Precursors (7) ------------------------------------------------------148

• Hole Transport Materials (8) ---------------------------------------------------149

• Hole Transport Dopant Materials (2) ------------------------------------------151

• Metallic Oxide Compact Layer Materials (5) ----------------------------------152



Pero

vskite Solar C

ells

Perovskite Solar CellsIntroduction

147146

　 The photovoltaics researchers have increase the interest to perovskite solar cells thanks to its improvement. The academic research is trying to reach and brighten the futures opportunity into physics and chemistry field.

　 The excellent properties and the innovative device possibilities in perovskite-struc-tured organometal halides have resulted in excited increase of publications reporting high efficiencies. [1] [2]

　 Furthermore, 15% efficient solar cells were reported with CH3NH3PbI3 recently, the target efficiency of 20% is considered as a feasible goal. Therefore, evaluating the potential and analyzing the prospects of this exciting technology have simulated the pho-tovoltaic research community.

　 In spite of perovskite solar cells use a hole-transportation layer to promote the efficient movement of electrical current after exposure to sunlight. Manufacturing the hole-transportation organic materials is costly and it lacks long term stability. So the development of highly efficient organic/inorganic halide perovskite solar cells demands attention to be paid while the researcher pursing new materials and device improvement for the widespread deployment of solution processed photovoltaic tech-nology.

Figure 1: Crystal structure. [3]



Pero

vskite Solar C


Introduction

147146

　 The rapid improvement of perovskite solar cells has made them the rising star of the photovoltaics world and of huge interest to the academic community. Since their operational methods are still relatively new, there is great opportunity for further re-search into the basic physics and chemistry around perovskites.

　 Since late 2012, organic/inorganic halides with the perovskite structure have strongly attracted the attention of the photovoltaic community when efficiencies close to 10% were first achieved in solid state cells[1]. The excellent properties and the inno-vative device possibilities in perovskite-structured organometal halides has resulted in a frenzied increase of publications reporting high efficiencies[2].

　 Recently 15% efficient solar cells were reported with CH3NH3PbI3 target efficiencies of 20% identified as a feasible goal. It is therefore pertinent to evaluate the potential and analyze the prospects of this exciting technology that have galvanized the photo-voltaic research community.

　 The rapid strides in the development of highly efficient organic/inorganic halide perovskite solar cells now demands attention to be paid to fundamental studies while simultaneously pursuing new materials and device development for the widespread deployment of this solution processed photovoltaic technology.

Reference:

[1] Nature Photonics, 7 (2013), p. 486, J.H. Heo, et al.

[2] Energy & Environmental Science, 6 (2013), p. 1739, J.M. Ball, et al.

[3] Nature Materials, 12, 1087–1089 (2013), figure 1

149148



Pero

vskite Solar C

ells

Perovskite Solar CellsPerovskite Precursors

149148

Reference : ACS Nano, 2014, 8 (2), pp 1674-1680 Reference : Chem. Mater., 2013, 25 (22), pp 4613-4618

Reference : Energy Environ. Sci., 2014, 7, 982–988

Reference : Energy Environ. Sci., 2014, 7, 982–988








: : : :

: : : :

: : : :

: : : :

: : : :

: : : :

:: : :

14965-49-2> 99.5% , recrystallized 4 timesCH6IN158.97 g/mole

6876-37-5> 99.5% , recrystallized 4 timesCH6BrN111.97 g/mole

10101-63-099.999% (trace metals basis)PbI2461.01 g/mole

7758-95-499.999% (trace metals basis)PbCl2278.11 g/mole

593-51-1> 99.5% , recrystallized 4 timesCH6ClN67.52 g/mole

10031-22-899.999% (trace metals basis)PbBr2

367.01 g/mole

879643-71-7> 99.5% , recrystallized 4 timesCH5IN2

171.97 g/mole

Methylammonium iodide

Methylammonium bromide

Lead(II) iodide

Lead(II) chloride

Methylammonium chloride

Lead(II) bromideFormamidinium iodide

LT-S9126

LT-S9137

LT-S9147

LT-S9148

LT-S9151

LT-S9152LT-S9136

PbI2

PbCI2

Methylammonium chloride

PbBr2

NH3 I

H2N NH2 I

NH3 Br

Reference :

Reference :

1. Science, 345, 542(2014)2. ACS Nano, 2014, 8 (2), pp 1674-1680

1. Science, 345, 542(2014)2. ACS Nano, 2014, 8 (2), pp 1674-1680

NH3 Cl



Pero

vskite Solar C


Hole Transport Materials

149148 149148

C8H17 C8H17

N

n


: : : :: :

220797-16-0MW > 30,000 (GPC)(C51H61N)n


Poly[(9,9-dioctylfluorenyl-2,7-diyl)-co -(4,4'-(N-(4-sec -butylphenyl)diphenylamine)]

LT-N148 TFB

N

n


: : : :: :

472960-35-3MW > 10,000 (GPC)(C22H21N)n




LT-N149 Poly-TPD

N

N

OCH3

N

N

OCH3

H3CO

H3CO

OCH3

OCH3

OCH3

OCH3

Reference :


Reference : J. Am. Chem. Soc. 2014, 136, 7837-7840 1. MRS. BULLETIN, 30, 2005, p232. Appl. Phys. Lett. 100, 173512 (2012)




: : : :: ::

: : :: :::

: : :::::

207739-72-8> 99.5% (HPLC)C81H68N4O8


1573202-44-4> 99% (HPLC)C81H68N4O8


1628961-22-7> 98.5% (HPLC)C81H68N4O8





LT-S922

LT-S9145

LT-S9146Spiro-MeOTAD

p,m-Spiro-MeOTAD

p,o-Spiro-MeOTAD

N

N

N

N

H3CO

H3CO OCH3

OCH3

OCH3

OCH3 H3CO

H3CO

N

N

OCH3

N

N

OCH3

OCH3

OCH3

OCH3

OCH3

H3CO

H3CO

151150



Pero

vskite Solar C

ells

Perovskite Solar CellsHole Transport Materials

151150


n

N


: : : :: :

1333317-99-9MW > 10,000 (GPC)(C21H19N)n



LT-N168 PTAA

LT-S909 P3HT


: : : :: :

156074-98-5MW > 45,000 (GPC)(C10H14S)n



Reference : Journal of Power Sources, 251, (2014), 152-156

S n


PSD d90


Storage


: : : :: :::

:

: : : :: ::






Specification


-

n

S

OOS

O OS

OOS

O OS

OOS

O O

2+

m

LT-PS001 PEDOT:PSS



Pero

vskite Solar C


Hole Transport Dopant Materials

151150 151150

Reference :

Reference : J. Am. Chem. Soc. 2011, 133, 18042–18045

1. J. Mater. Chem. A, 2013,1, 11842-118472. J. Am. Chem. Soc., 2013, 135 (51), pp 19087-19090



: : : ::

: : :: :

1447938-61-5>99% (NMR)C42H45CoF18N12O12S6

1503.18 g/mole227, 287 nm (in Acetonitrile)

1346416-70-3> 99% (NMR)C24H21CoF18N9P3

929.31 g/mole215, 292 nm (in Acetonitrile)

Tris(2-(1H-pyrazol-1-yl)-4-tert-butylpyridine)-cobalt(III) tris(bis(trifluoromethylsulfonyl)imide))

Tris(1-(pyridin-2-yl)-1H-pyrazol)cobalt(III) tris(hexafluorophosphate)

LT-S9127

LT-S9135

FK209 Co(III) TFSI Salt

FK102 Co(III) PF6 Salt

N

N

N

N

N

NCo

N

N N

(PF6)3

3+

N

N

N

N

N

NCo

N

N N

(TFSI)3

3+



Pero

vskite Solar C

ells

Perovskite Solar CellsMetallic Oxide Compact Layer Materials

PB152


CAS No.GradeFormula

: ::

1345045-27-3MW > 20,000 (GPC)(C70H102N2O4)nC12H10

6,6'-(9',9'-Bis(6-((3-ethyloxetan-3-yl)methoxy)hexyl)-7,7'-diphenyl-9H ,9'H -2,2'-bifluorene-9,9-diyl)bis(N,N-diethylhexan-1-amine)

LT-N177 PFN-OX

O O

O O

N N

n


: :::

MW > 20,000 (GPC)(C37H50I2N4S)n



LT-N181 PFNIBT

NN

NSN

n

II

C8H17 C8H17 n

NNBr Br


: : : ::

MW > 10,000 (GPC)(C56H80N2Br2)n




LT-N878 PFNBr

C8H17 C8H17 n

NN


: : : :: :

673474-74-3MW > 10,000 (GPC)(C52H70N2)n




LT-N4027 PFN-DOF



: : :::

631918-72-4> 99%C70H11NO2




NCH3

O

OH



Organ

ic Thin

-Film Tran

sistor (O

TFT)Organic Thin-Film Transistor (OTFT)

Contents

153PB

• Introduction --------------------------------------------------------------------154

• Small Molecular / Oligomer Materials (71) -----------------------------------156

• Polymer Materials (12) ---------------------------------------------------------167



Organ

ic Thin

-Film Tran

sistor (O

TFT)

Organic Thin-Film Transistor (OTFT)Introduction

155154

　Transistors are the fundamental building block in modern circuitry and are used either as switches or signal amplifiers. The field effect is a phenomenon in which the conductivity of a semiconductor changes due to the application of an electric field normal to its surface.

　Several factors have motivated engineers to conduct and continue research in or-ganic semiconductor technology. One of these factors is cost. Organic displays are rel-atively cheap, but until recently, they have proven slow in terms of carrier mobility (the ease with which an atom shares electron s and hole s with other atoms). Slow carrier mobility translates into sluggish response time, which limits the ability of a display to render motion

　Recently developed a process for growing organic crystals with carrier mobility rival-ing that of traditional TFT materials. Further improvements are expected. A mid 2011 review concluded that there were ca. 40 organic semiconductor (OSC) materials with charge mobilities exceeding 1 cm2/VS-1 the majority of these being small molecule sys-tems. The formulation of small molecule organic semiconductor with binders improves solution processing, reducing OTFT variation to a level acceptable for applications.1



Organ

ic Thin

-Film Tran

sistor (O


Introduction

155154

　There is a need to develop technologies for relatively fast circuits (~100 kHz clock rate) for use in RFID tags and display drivers. Calculations indicate that,with such materials, ring oscillators with frequencies greater than or equal to 1 MHz and sequential circuits with clock rates of 100 kHz are possible. OTFTs have several developments in organic complementary circuits, RFID tags, chemical and biological sensors, and electronic paper.2

1.　C. Wang, H. Dong, W. Hu, Y. Liu and D. Zhu, Chem. Rev., 112, 2208-67 (2012)

2.　Materialstoday, April 2006, Volume 9, Number 4, P24-30

　In recent years, the complexity of circuits made with organic transistors has increased, and the first large-scale complementary circuits have been fabricated. Researchers have reported active-matrix displays and electronic paper with hundreds or thousands of transistors. The speed of ring oscillators is now in excess of 100 kHz and the clock speed of clocked sequential circuits such as registers is in the kilohertz range.

N N

O

O

O

O

R R

SH H

S

S

R R

6



Organ

ic Thin

-Film Tran

sistor (O

TFT)

Organic Thin-Film Transistor (OTFT)Small Molecular / Oligomer Materials

157156

LT-S901 LT-S916

LT-S918

LT-S919

LT-S920

LT-S902

LT-S904

LT-S915

Pentacene Pentacene precursor

PTCBI

ADIDI

PTCDA

PDCDT

PenPTC

Pentacene precursor

NN

OO

OO

N

O

O

N

O

O


: : : :: ::

135-48-8Sublimed productC22H14


Pentacene


: : : :: ::

83054-80-2Sublimed productC52H50N2O4


N,N'-Bis(2,5-di-tert-butylphenyl)-3,4,9,10-perylene dicarboximide

NN

O

O

O

O

C5H11C5H11


: : : :: ::



N,N'-Dipentyl-3,4,9,10-perylene dicarboximide

O

O

N

N

N

N


: : : : ::



Bisbenzimidazo[2,1-a :1',2-b']anthra[2,1,9-def:6,5,10-d'e'f' ] diisoguinoline-10,21-dione, with cis isomer



: : : :: :

: : : :: ::

> 99% (HPLC)C26H20N2O4


732308-35-9> 99% (HPLC)C28H24N2O4


Pentacene precursor

Pentacene precursor

Reference :

Reference :

Bull. Koren Chem. Soc. 2003, Vol. 24, No.12, 1862

Bull. Koren Chem. Soc. 2003, Vol. 24, No.12, 1862

NN

OO

OO

O

O

NN

N

N


: : : : ::



Anthra[2",1",9":4,5,6;6",5",10":4',5',6']diisoquino[2,1-a : 2',1'-a ']diperimidine-12,25-dione, with cis isomer

O O

O

OO

O


: : : :: :

128-69-8Sublimed productC24H8O6


3,4,9,10-Perylenetetracarboxylic dianhydride

Reference : Organic Electronics 8 (2007), 735~742



Organ

ic Thin

-Film Tran

sistor (O


Small Molecular / Oligomer Materials

157156

LT-S921 LT-S928

LT-S935

LT-S936

LT-S924

LT-S925

LT-S926

PTCDI F16CuPC

4ClPEPTC

4FPEPTC

NTDA

MePTC

HepPTC

N N

O

OO

O

HH


: : : : ::



3,4,9,10-Perylenetetracarboxylic acid diimide

OO

O

O

O

O

N N

O

OO

O

NN

O

OO

O

C7H15 C7H15


: : : :: ::

81-30-1Sublimed, > 99%C14H4O6


1,4,5,8-Naphthalenetetracarboxylic dianhydride



: : : :: ::

: : : :: ::





N,N'-Dimethyl-3,4,9,10-perylene dicarboximide

N,N'-Diheptyl-3,4,9,10-perylene dicarboximide


N

NN

N

N

N

N

NCu

FF

F

F

FF

F

F

F

F

FFF

F

F

F

NN

O

O

O

OCl

Cl

NN

O

O

O

OF

F



: : : :: ::

: : : :: ::

215726-51-5Sublimed, > 99%C40H24Cl2N2O4


215726-57-1Sublimed, > 99%C40H24F2N2O4


N,N'-Bis[2-(4-chlorophenyl)-ethyl]-3,4,9,10-perylene dicarboximide

N,N'-Bis[2-(4-fluorophenyl)-ethyl]-3,4,9,10-perylene dicarboximide

Reference : Orange Electronics, vol.11 (No.8), pp1399-1402


: : : :: :

14916-87-1Sublimed productC32F16CuN8


Copper(II) 1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-hexadecafluoro-29H,31H-phthalocyanine



Organ

ic Thin

-Film Tran

sistor (O

TFT)


159158

NN

O

O

O

OCl

Cl

Cl

Cl

NN

O

O

O

O

Cl

Cl

Cl

Cl

NN

O

O

O

O



: : : :: :

: : : :: :

Sublimed, > 99%C40H22Cl4N2O4


Sublimed, > 99%C40H22Cl4N2O4


N,N'-Bis[2-(2,4-dichlorophenyl)-ethyl]-3,4,9,10-perylene dicarboximide

N,N'-Bis[2-(2,6-dichlorophenyl)-ethyl]-3,4,9,10-perylene dicarboximide


: : : :: ::

67075-37-0Sublimed, > 99%C40H26N2O4


N,N'-Bis(2-phenyl-ethyl)-3,4,9,10-perylene dicarboximide

Reference : J. Phys. Chem. B 2005, 109 (50) pp23918-23924

N N

O

O

O

O

NN

O

OO

O

OC12H25

OC12H25

OC12H25

C12H25O

C12H25O

C12H25O

N N

O

O

O

OMeO

OMe


: : : :: ::

119215-14-4Sublimed, > 99%C42H30N2O6


N,N'-Bis[2-(4-methoxylphenyl)-ethyl]-3,4,9,10-perylene dicarboximide



: : : :: ::

: : : :: ::

92-24-0Sublimed, > 99% (HPLC)C18H12


128-65-4Sublimed, > 99%C36H18N2O4


2,3-Benzanthracene

N,N'-Diphenyl-3,4,9,10-perylene dicarboximide


: : : :: :

351377-40-7> 99% (NMR)C108H162N2O10


N,N' -Bis(3,4,5-tridodecyloxyphenyl)-3,4,9,10-perylene dicarboximide


LT-S937 LT-S941

LT-S956

LT-S960

LT-S938

LT-S939

LT-S940

2,4ClPEPTC DP-PTCDI

PDI1

4MeOPEPTC

2,6ClPEPTC

PEPTC

Tetracene



Organ

ic Thin

-Film Tran

sistor (O



159158

Reference : J. Inorg. Organomet. Polym. (2010) 20: 161-167



: : : :: ::

: : : :: ::

76727-11-2Sublimed, > 99%C34H22


88493-55-4Sublimed, > 99%C24H14S6


6,13-Diphenylpentacene

α-Sexithiophene

Reference : Solid State Commun. 72, 381 (1989)

SH H6

LT-S968 LT-S972

LT-S973

LT-S975

LT-S969

LT-S970

6,13-DP-Penta α,ω-DH6T

TCNQ

FTTF

α-6T

PTCDI-C8

N N

O

O

O

O

C8H17C8H17


: : : :: ::

78151-58-3Sublimed, > 99%C40H42N2O4


N,N'-Dioctyl-3,4,9,10-perylene dicarboximide


: : : :::



7,7,8,8-Tetracyanoquinodimethane

SS S

S SS

C6H13C6H13

NC

NC CN

CN


: : : :::

151271-43-1Sublimed, > 99%C36H38S6


5,5'' ' ' '-Dihexyl-2,2' :5' ,2' ' :5' ' ,2' ' ' :5' ' ' ,2' ' ' ' :5' ' ' ' ,2' ' ' ' '-sexithiophene

Reference : AIP Conf. Proc. 1399, 859 (2011)


: : : :::

369599-41-7Sublimed, > 99%C34H22S2


5,5'-Di(9H-fluoren-2-yl)-2,2'-bithiophene

Reference : J. Am. Chem. Soc., 2001, 123, 9214

SS

SSC6H13

C6H13


: : : :: :

369599-42-8Sublimed, > 99%C46H46S2


5,5'-Bis(7-hexyl-9H-fluoren-2-yl)-2,2'-bithiophene

Reference : J. Am. Chem. Soc., 2001, 123, 9214

LT-S976 DH-FTTF



Organ

ic Thin

-Film Tran

sistor (O

TFT)


161160

Si

Si


: : : :: :

373596-08-8> 99% (HPLC)C44H54Si2639.07 g/mole307 nm (in CH2Cl2)> 230 °C (0.5% weight loss)

6,13-Bis(triisopropylsilylethynyl)pentacene

Reference : J. Am. Chem. Soc., 2001,123, 9482

S

S

S

S

Si

Si



: : : :: :

: : : :: :

27130-32-1Sublimed, > 99% (HPLC)C30H20


144413-58-1Sublimed, > 99%C18H10S2


5,12-Diphenyltetracene

Anthra[2,3-b:6,7-b']dithiophene

Reference : Nature Commun. 3, 1259 (2012)


: : : :: :

851817-11-3> 99% (NMR)C34H38S2Si2566.97 g/mole306 nm (in CH2Cl2)> 230 °C (0.5% weight loss)

5,11-Bis(triethylsilylethynyl)anthradithiophene

LT-S9034

LT-S9035LT-S977

LT-S9026

TES-ADT

DPTTIPS

ADT


: : : :: :

188-94-3Sublimed productC32H16


Diindeno[1,2,3-cd :1',2',3'-lm ]perylene


LT-S9036 DIP

LT-S9041 PTCDI-C18H37


: : : :: :

25834-02-0Sublimed, > 99%C60H82N2O4

895.30 g/mole485, 520 nm (in Toluene)> 340 °C (0.5% weight loss)

N,N'-Dioctadecyl-3,4,9,10-perylene dicarboximide

Reference : J. Appl. Phys. Lett. 93, 033305 (2008)

N N

O

O

O

O

C18H37C18H37



Organ

ic Thin

-Film Tran

sistor (O



161160

LT-S9043

LT-S9049

LT-S9057

LT-S9059

LT-S9042

Ddodec-FTTF

2,4-FPEPTC

DFH-4T

TEPTC

PTCDI-C13H27


: : : :: :

95689-92-2Sublimed, > 99%C50H62N2O4

755.04 g/mole484, 520 nm (in Toluene)> 390 °C (0.5% weight loss)

N,N'-Ditridecyl-3,4,9,10-perylene dicarboximide


N N

O

O

O

O

C13H27C13H27


: : : :: :

846542-27-6Sublimed, > 99%C58H70S2


5,5'-Bis(7-dodecyl-9H-fluoren-2-yl)-2,2'-bithiophene

SSC12H25

C12H25

NN

O

O

O

O

F

F

F

F


: : : :::

1644439-37-1Sublimed, > 99%C40H22F4N2O4


N,N'-Bis[2-(2,4-difluorophenyl)-ethyl]-3,4,9,10-perylene dicarboximide

NN

O

O

O

OS

S


: : : :::

1559069-50-9Sublimed, > 99%C36H22N2O4S2


N,N'-Di(thiophen-2-yl)ethyl-3,4,9,10-perylene dicarboximide


: : : :::

446043-85-2Sublimed, > 99%C28H8F26S4


5,5'-Bis((5-perfluorohexyl)thiophen-2-yl)-2,2'-bithiophene

SC6F13 C6F134


: : : : :

1430207-54-7Sublimed, > 99% (NMR)C48H50S4

755.17 g/mole322, 410 nm(in CHCl3)

Reference : ACS Applied Materials & Interfaces (2013), 5(9), 3855-3860

1,6-Bis(5'-octyl-2,2'- bithiophen-5-yl)pyrene

LT-S9077 BOBTP

S

S

S

S

C8H17

C8H17



Organ

ic Thin

-Film Tran

sistor (O

TFT)


163162


: : : : :

59156-92-2Sublimed, > 99%C22H12Cl2347.24 g/mole> 350 °C (0.5% weight loss)

Reference : 1. J. Mater. Chem., 2012, 22, 104962. Adv. Mater. 2013, 25, 2229-2233

Cl

Cl





: : : ::

: : : ::

: : : ::

: : : ::

41572-86-5Sublimed, > 99%C36H30N2O4


23536-15-4Sublimed, > 99%C26H30N2O4


34155-21-0Sublimed, > 99%C30H38N2O4


173409-43-3Sublimed, > 99%C26H26N2O4


N,N'-Dicyclohexylperylene-3,4:9,10-tetracarboxylic acid bisimide

2,7-Dihexylbenzo[lmn ][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone

2,7-Dioctylbenzo[lmn ][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone

2,7-Dicyclohexylbenzo[lmn ][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone


: : : : :

1225220-87-0Sublimed, > 99% (HPLC)C34H20S2


S

S

CAS No.GradeFormulaM.W.PL

: : : ::

110590-81-3Sublimed, > 99%C34H30N2O4


NN

O

O

O

O

NN

O

O

O

O

N N

O

O

O

O

C6H13 C6H13

N N

O

O

O

O

C8H17 C8H17

N N

O

O

O

O

6,13-Dichloropentacene

5,12-Di(benzo[b]thiophen-2-yl)tetracene

N,N'-Bis(ethylpropyl)perylene-3,4,9,10-tetracarboxylic acid

LT-S9080

LT-S9094

LT-S9095

LT-S9096

LT-S9088

LT-S9092

LT-S9093DCP

NTDA-C6H13

NTDA-C8H17

DCyNTDA

5,12-DBTT

3PenPTC

DCyPTC



Organ

ic Thin

-Film Tran

sistor (O



163162


: : : ::

173409-41-1Sublimed, > 99%C24H26N2O4


2,7-Dipentylbenzo[lmn ][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone

N N

O

O

O

O

C5H11 C5H11

LT-S9098 LT-S9102

LT-S9103

LT-S9128

LT-S9099

LT-S9100

LT-S9101

NTDA-C5H11 DTT-12

DTT-8

Dp-triene-2,5-CN

NTDA-C7H15

NTDA-C13H27

NTDA-C18H37




: : : ::

: : : ::

: : : ::

698370-78-4Sublimed, > 99%C28H34N2O4


1373274-00-0Sublimed, > 99%C40H58N2O4


144742-50-7Sublimed, > 99%C50H78N2O4


2,7-Diheptylbenzo[lmn ][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone

2,7-Ditridecylbenzo[lmn ][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone

2,7-Dioctadecylbenzo[lmn ][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone

N N

O

O

O

O

C7H15 C7H15

N N

O

O

O

O

C13H27 C13H27

N N

O

O

O

O

C18H37 C18H37


: : : ::

1446140-70-0Sublimed, > 99% (NMR)C44H60S3


2,6-Bis(4-dodecylphenyl)-dithieno[3,2-b:2',3'-d]thiophene

2,6-Bis(4-octylphenyl)-dithieno[3,2-b:2',3'-d ]thiophene

(2Z,3E ,5Z)-2,5-Dibenzylidenehex-3-enedinitrile


S

SSC12H25C12H25



: : : ::

: : : :

1429377-95-6Sublimed, > 99% (NMR)C36H44S3


1376166-32-3> 99%C20H14N2

282.34 g/mole


Reference : Chemical Science (2012), 3(4), 1007-1014

S

SSC8H17C8H17

CN

CN


: : : ::

24259-89-0Sublimed, > 99%C26H14N2O4


2,7-Diphenylbenzo[lmn ][3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone

N N

O

O

O

O

LT-S9097 DPNTDA



Organ

ic Thin

-Film Tran

sistor (O

TFT)


165164

LT-S9158

LT-S9129

BTCB

Dp-tetraene


: : : :::

958891-96-8Sublimed, > 99% (HPLC)C42H26


1,4-Bis(5-tetracenyl)benzene

(1E ,3E ,5E ,7E )-1,8-Diphenylocta-1,3,5,7-tetraene



: : : :

3029-40-1> 99%C20H18

258.36 g/mole

N

N

O

OO

O

FF

F FF

FF

F F

FFF

FF

N

NN

N

N

N

N

N

F

F

F

F

Cu

LT-S9132 PTCPI-CH2C3F7N,N'-Bis(2,2,3,3,4,4,4-heptafluorobutyl)-3,4,9,10-perylene dicarboximide

LT-S9130

LT-S9131

LT-S9134

LT-S9154

Dp-pentaene

Dp-triene

F4-CuPC

di-PBI

(1E ,3E ,5E ,7E ,9E )-1,10-Diphenyldeca-1,3,5,7,9-pentaene

(1E ,3E ,5E )-1,6-Diphenylhexa-1,3,5-triene

Copper(II)-2,9,16,23-tetrafluoro-29H,31H-phthalocyanine

Bis[N,N-1-pentylhextyl)-perylene-3,4:9,10-tetracarboxylic diimide]






: : : :

: : : :

: : : ::

: : ::

: : : ::

3029-41-2> 99%C22H20

284.39 g/mole

1720-32-7> 99%C18H16

232.32 g/mole

65602-84-8Sublimed, > 99%C32H12CuF4N8


1609131-78-3 > 99% (NMR)C92H106N4O8

1395.85 g/mole

1150578-28-1Sublimed, > 99%C32H14F14N2O4


Reference :

Reference :

1. J. Mater. Chem., 2012, 22, 104962. Adv. Mater. 2013, 25, 2229-2233

Journal of the American Chemical Society (2009), 131(17), 6215-6228

N N

O

O

O

O

N N

O

O

O

O



Organ

ic Thin

-Film Tran

sistor (O



165164

LT-S9159 p-Septiphenyl


: : : ::

70352-20-4> 99%C42H30


p-Septiphenyl

LT-S9171

LT-S9173

LT-S9174

LT-S9172

F4ZnPc

An-PDN

BD-PDN

F8ZnPc

Zinc(II)-1,8,15,22-tetrafluoro-29H ,31H-hthalocyanin,mixture of isomers

2,2'-(9,10-anthracenediylidene)-bis-propanedinitrile

2,2'-Benzo[1,2-b :4,5-b ']dithiophene-4,8-diylidenebis-propanedinitrile

Zinc(II)-2,3,9,10,16,17,23,24-octafluoro-29H ,31H-phthalocyanin





: : : :::

: : : :::

: : : :::

: : : :::




109573-90-2Sublimed, > 99% (HPLC)C16H4N4S2



Reference : ChemPhysChem (2014), 15(12), 2462-2472

N

NN

N

N

N

N

NZn

F

F

F

F

Reference :

Reference :

Reference :


Chemical Communications (Cambridge, United Kingdom) (2014), 50(7), 833-835

Advanced Materials (Weinheim, Germany) (2014), 26(24), 4093-4099

N

NN

N

N

N

N

N

F

F

F

F F

F

F

F

Zn

N N

N N

S

S

NN

NN

LT-S9175 5,12-TIPS-Tetracene5,12-Bis((triisopropylsilyl)ethynyl)tetracene


: : : :::

628316-50-7 > 99% (NMR)C40H52Si2589.01 g/mole389 nm (in CH2Cl2)> 250 °C (0.5% weight loss)

Reference : Chemical Communications, (2014), 50(85), 12828-12831

SiSi

167166



Organ

ic Thin

-Film Tran

sistor (O

TFT)


167166

LT-S9177

LT-S9179

F16FePC

BDT2TH


2,6-Bis[(5'-octyl[2,2'-bithiophene)]{4,8-bis(5-octyl-2-thienyl)benzo[1,2-b:4,5-b']dithiophene]


GradeFormulaM.W.UV

: : : :::

: : : :

23844-93-1Sublimed, > 99%C32F16FeN8


> 99% (NMR)C66H82S8

1131.88 g/mole249, 359, 442 nm (in CHCl3)

Reference : Nano Letters (2014), 14(10), 5547-5554

N

NN

N

N

N

N

N

F

F

F

F F

F

F

F

Fe

F

F

F

F F

F

F

F

S

S

S

S

C8H17

C8H17

S

S

S

S

C8H17

C8H17



Organ

ic Thin

-Film Tran

sistor (O


Polymer Materials

167166 167166

LT-S979 LT-S982

LT-S9060

LT-S9117

LT-S980

LT-S981

F8T2 PBTTT-C14

PBTTT-C16

PDQT

PQT-12

PBTTT-C12

SS S

S

C12H25

C12H25n

S

SSS

C12H25

C12H25n

S

SSS

C14H29

C14H29n

S

SSS

C16H33

C16H33n





: : : :: :

: : : :: :

: : : :: :

: : : ::

210347-56-1MW > 20,000 (GPC)(C37H44S2)n


888491-18-7MW = 40,000 ~ 80,000 (GPC)(C38H54S4)n


888491-19-8MW = 40,000 ~ 80,000 (GPC)(C38H54S4)n


MW = 40,000 ~ 80,000 (GPC)(C46H70S4)n





Poly[2,5-bis(3-hexadecylthiophen-2-yl)thieno[3,2-b ]thiophene]




Reference : Nano Lett., 2009, 9 (12), pp4153-4157


: : : : :

827343-06-6MW = 10,000 ~ 40,000 (GPC)(C40H56S4)n

473 nm (in Toluene)> 5 mg/mL in CHCl3

Poly[bis(3-dodecyl-2-thienyl)-2,2'-dithiophene -5,5'-diyl]



: : : ::

1267540-03-3MW > 30,000 (GPC)(C62H90N2O2S4)n


Poly{2,2'-[(2,5-bis(2-octyldodecyl)-3,6-dioxo-2,3,5,6-tetrahydropyrrolo[3,4-c ]pyrrole-1,4-diyl)]dithiophene-5,5'-diyl-alt-2,2'-bithiophene-5,5'-diyl}


SS n

SS

N

NS

O

O

C8H17

C8H17

C10H21

C10H21

S n



Organ

ic Thin

-Film Tran

sistor (O

TFT)

Organic Thin-Film Transistor (OTFT)Polymer Materials

PB168

LT-S9178 PMDPP3T

GradeFormulaUV

: : :

MW > 30,000 (GPC)(C52H76N2O2S3)n

830 nm (in CHCl3)

Poly[[2,5-bis(2-hexyldecyl)-2,3,5,6-tetrahydro-3,6-dioxopyrrolo[3,4-c]pyrrole-1,4-diyl]-alt-[3',3''-dimethyl-2,2':5',2''-terthiophene]-5,5''-diyl]

Poly{3,6-dithiophen-2-yl-2,5-di(2-decyltetradecyl)-pyrrolo[3,4-c ]pyrrole-1,4-dione-alt-thienylenevinylene -2,5-yl}

Poly[2,3-bis-(3-octyloxyphenyl)quinoxaline-5,8-diyl-alt-thiophene-2,5-diyl]

Poly{3,6-dithiophen-2-yl-2,5-di(2-octyldodecyl)pyrrolo[3,4-c]pyrrole-1,4-dione-alt-thienylenevinylene-2,5-yl}

N

NO

O

S

S

C12H25

C12H25

C10H21

C10H21

SS

n

N N

OC8H17C8H17O

Sn



: : ::

: : : ::

1260685-65-1MW > 30,000 (GPC)(C60H88N2O2S4)n


1270977-98-4MW > 30,000 (GPC)(C62H88N2O2S5)n


Poly{2,2'-[(2,5-bis(2-octyldodecyl)-3,6-dioxo-2,3,5,6-tetrahydropyrrolo[3,4-c ]pyrrole-1,4-diyl)]dithiophene-5,5'-diyl-alt-thieno[3,2-b]thiophen-2,5-diyl}

Poly{2,2'-(2,5-bis(2-octyldodecyl)-3,6-dioxo-2,3,5,6-tetrahydropyrrolo[3,4-c ]pyrrole-1,4-diyl)dithieno[3,2-b ]thiophene-5,5'-diyl-alt-thiophen-2,5-diyl}



Reference :

Reference :

1. Adv. Mater. 2010, 22, 4862-48662. Chem. Mater. 2012, 24, 1316-1323



Nature Communications 5, Article number: 4183

nS

S

N

NS

O

O

C8H17

C8H17

C10H21

C10H21

S

SN

NS

O

O

C8H17

C8H17

C10H21

C10H21

nS

S

S

LT-S9118

LT-S9119

LT-S9133

LT-S9091

LT-S9155

PDBT-co-TT

PDPPBTT

PDVT-10

TQ1

PDVT-8

CAS No.FormulaGradeSolubility

CAS No.GradeFormulaM.W.Solubility


::::

:::::

::::

1442682-99-6(C72H108N2O2S4)n

MW > 30,000 (GPC)Soluble in CHCl3, Chlorobenzene, Dichlorobenzene

565228-37-7MW > 20,000 (GPC)(C40H46N2O2S)n


1403959-01-2MW > 20,000 (GPC)(C64H92N2O2S4)n

Soluble in CHCl3, Chlorobenzene, Dichlorobenzene

N

NO

O

SS

C8H17

C8H17

C10H21

C10H21

SS

n

N

NO

O

SS

C8H17

C8H17

C6H13

C6H13

Sn



Flexible P

rinted

Electron

icsFlexible Printed Electronics

Contents

• Introduction -----------------------------------------------------------------------170

• Organic Photovoltaic (OPV) Polymers (36) ---------------------------------------173

• Organic Thin-Film Transistor (OTFT) Polymers (12) ------------------------------179

• Hole Transport Layer / Hole Injection Layer (HTL/HIL) Polymers (15) -----------181

• Host Layer Polymers (6) ----------------------------------------------------------184

• Light-Emitting Layer Polymers (68) ----------------------------------------------185

• Electron Transport Layer / Hole Blocking Layer (ETL/HBL) Polymers (2) --------197



Flexible P

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Electron

ics

Flexible Printed ElectronicsIntroduction

　Flexible Printed Electronics(FPE) is a new exiting technology with large potential market expectations.

　FPE describes a broad set of technologies applicable across a multitude of products. FPE may be very small, such has cell phone components, or very large (literally thousands of square meters), enabling applications that can only be dreamed of today.

　The common theme of FPE is that it enables the production of electronic devices that can be readily integrated into all aspects of life in a seamless manner, at low cost, on large scales, using inherently green processes and materials.

　The elements of FPE— flexible and printed— each describe a different aspect of improvement over traditional silicon electronics.

• Flexible: Unlike silicon microelectronics, FPE can be bent or shaped without damage. This allows integration into everyday items and places, such as paper or textiles, which are not generally flat and shock protected.

• Printed: Printing innovations make high volume production of FPE at low cost, using green materials and on flexible substrates possible. Most of the printing methods used today, including offset, gravure, flexo and ink jet can be adapted to FPE.

• FPE are inherently green: In many cases, FPE replaces the materials in traditional electronics, including toxic metals such as germanium, with plastics and inks. These new materials have the advantages of low energy consumption, high fault-tolerance, transparency, light weight and shock resistance.[1]



Flexible P

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Introduction

171

　The benefits of these new electronics are numerous - ranging from lower cost, improved performance, flexibility, transparency, reliability, better environmental credentials and much more. Many of the applications will be newly created, and where existing electronic and electrical products are impacted, the extent will be varied.

• In LCD fabrication, glass is used as a substrate. If thin flexible plastic or metal foil is used as the substrate instead, the entire system can be flexible, as the film deposited on top of the substrate is usually very thin.

• Organic light-emitting diodes(OLEDs) are normally used instead of a back-light for flexible displays, making a flexible organic light-emitting diode display.

• Most flexible circuits are passive wiring structures that are used to interconnect electronic components such as integrated circuits, resistor, capacitors and the like, however some are used only for making interconnections between other electronic assemblies either directly or by means of connectors.

• In the automotive field, flexible circuits are used in instrument panels, under-hood controls, circuits to be concealed within the headliner of the cabin, and in ABS systems.

• In computer peripherals f lexible circuits are used on the moving print head of printers, and to connect signals to the moving arm carrying the read/write heads of disk drives.

• Consumer electronics devices make use of flexible circuits in cameras, personal entertainment devices, calculators, or exercise monitors.

• Flexible circuits are found in industrial and medical devices where many interconnections are required in a compact package.

• Cellular telephones are another widespread example of flexible circuits.

• Flexible solar cells have been developed for powering satellites. These cells are lightweight, can be rolled up for launch, and are easily deployable, making them a good match for the application. They can also be sewn into backpacks or outerwear.

Application field:

173172



Flexible P

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Electron

ics

Flexible Printed ElectronicsIntroduction

　Total market for printed, flexible organic electronics will grow from $16.04 Billion in 2013 to $76.79 Billion in 2023. The majority of that is OLEDs (organic but not printed) and conductive ink used for a wide range of applications. On the other hand, stretchable electronics, logic and memory, thin film sensors are much smaller segments but with huge growth potential as they emerge from R&D.[2]

[1] SEMI Press, By Kevin Cammack, FlexTech Alliance

[2] Printed, Organic & Flexible Electronics Forecasts, Players & Opportunities

2013-2023, PR Newswire, June 28, 2013



Flexible P

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Electron


Organic Photovoltaic(OPV) Polymers

173172

LT-S909 LT-S932

LT-S933

LT-S934

LT-S911

LT-S931

P3HT MDMO-PPV

PFO

PFO-DMP

PT

MEH-PPV

CAS No.Grade

FormulaUVPLSolubility

: :

: :: :

156074-98-5MW > 45,000 (GPC)Regioregular Electronic Grade > 93%(C10H14S)n




CAS No.FormulaUVPL

: : ::

25233-34-5(C4H2S)n

427 nm (in CH2Cl2)510 nm (in CH2Cl2)

Poly(thiophene-2,5-diyl)


: : : :: :

138184-36-8MW > 100,000 (GPC)(C17H24O2)n


Poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene]



: : : :: :

177716-59-5MW > 100,000 (GPC)(C19H28O2)n





: : : :: :

123864-00-6MW = 50,000 ~ 150,000 (GPC)(C29H40)n

376 nm (in THF)426, 440 nm (in THF)Soluble in CHCl3, Chlorobenzene, Dichlorobenzene



S n

S n

n

O

H3CO

n


: : : :::

874816-14-5MW = 50,000 ~ 150,000 (GPC)C16H18(C29H40)n




n

CH3

CH3CH3

CH3

n

O

H3CO



Flexible P

rinted

Electron

ics

Flexible Printed ElectronicsOrganic Photovoltaic(OPV) Polymers

175174


: : : :: :

888491-18-7MW = 40,000 ~ 80,000 (GPC)(C38H54S4)n





: : : :: :

: : : :: :

210347-52-7MW > 20,000(C35H42N2S)n


888491-19-8MW = 40,000 ~ 80,000 (GPC)(C42H62S4)n




Reference : Synthetic Metals, 152, 105, 2005Reference : Appl. Phys. Lett., 92, 113309, 2008


: : : :: :

201807-75-2MW = 50,000 ~ 150,000 (GPC)(C25H32)n





: : : :: :

: : : :::

579505-53-6MW = 20,000 ~ 50,000 (GPC)(C31H34N2S)n


1379051-13-4MW = 20,000 ~ 50,000 (GPC)(C35H42N2S)n


Poly[(9,9-dihexylfluorenyl-2,7-diyl)-alt-(benzo[2,1,3]thiadiazol-4,7-diyl)]

Poly[(9,9-bis(2-ethylhexyl)fluorenyl-2,7-diyl)-alt-(benzo[2,1,3]thiadiazol-4,7-diyl)]

NS

N

n

n

S

SSS

C12H25

C12H25n

S

SSS

C14H29

C14H29n

NS

Nn

NS

Nn

LT-S957 LT-S982

LT-S9002

LT-S9003

LT-S958

LT-S981

F8BT PBTTT-C14

F6BT

F2EHBT

PHF

PBTTT-C12



Flexible P

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Electron



175174


: : : :: :

188201-16-3MW > 20,000 (GPC)(C29H40)n






: : : :: :

: : : :: :

: : : :: :

958261-50-2MW = 20,000 ~ 100,000 (GPC)(C43H47N3S3)n

390, 554 nm (in THF)639 nm (in THF)> 5 mg/mL in CHCl3

920515-34-0MW = 7,000 ~ 20,000 (GPC)(C31H38N2S3)n


782469-77-6MW = 10,000 ~ 50,000 (GPC)(C43H46N2S3)n


Poly[N-9'-heptadecanyl-2,7-carbazole-alt-5,5-(4',7'-di-2-thienyl-2',1',3'-benzothiadiazole)]

Poly[2,6-(4,4-bis-(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b']dithiophene)-alt-4,7(2,1,3-benzothiadiazole)]

Poly[2,7-(9,9-di-octyl-fluorene)-alt-4,7-bis(thiophen-2-yl)benzo-2,1,3-thiadiazole]

Reference : Orange Electronics, v12, 2011, P1788-1793


Reference : Adv. Funct. Mater., 2006, 16, 667-674

n

SS

NS

Nn

C8H17 C8H17

S S

NS

Nn


: : : :: :

1089687-02-4MW = 10,000 ~ 30,000 (GPC)(C30H38N2S3Si)n


Poly[2,6-(4,4'-bis(2-ethylhexyl)dithieno[3,2-b:2',3'-d]silole)-alt-4,7(2,1,3-benzothiadiazole)]

Reference : J.Am. Chem. Soc., 2008, 130, 16144-16145


: : : :: :

1035681-83-4MW = 8,000 ~ 20,000 (GPC)(C39H42N2S5)n


Poly[2,6-(4,4-bis(2-ethylhexyl)-4H-cyclopenta-[2,1-b:3,4-b']dithiophene-alt-4,7-bis(thiophen-2-yl)benzo-2,1,3-thiadiazole]


Si

SS

NS

Nn

SSS S

NS

N n

LT-S9004 LT-S950

LT-S951

LT-S953

LT-S948

LT-S949

PF2EH PFOBT

PSBTBT

PCPDTTBTT

PCDTBT

PCPDTBT

NS S

NS

Nn

C8H17 C8H17



Flexible P

rinted

Electron

ics


177176


: : : ::

1004272-92-7MW = 10,000 ~ 80,000 (GPC)(C42H46N2S3Si)n


Poly[2,7-(9,9-dioctyl-dibenzosilole)-alt-4,7-bis(thiophen-2-yl)benzo-2,1,3-thiadiazole]

Reference : Appl. Phys. Lett. 92, 033307, 2008



: : : ::

: : : ::

1098102-96-5MW > 50,000 (GPC)(C45H62O4S4)n


1147374-60-4MW = 10,000 ~ 50,000 (GPC)(C59H81N3O2S2)n


Poly[4,6-(dodecyl-thieno[3,4-b]thiophene-2-carboxylate)-alt-2,6-(4,8-dioctoxylbenzo[1,2-b:4,5-b ]dithiophene)]

Poly[N-9'-heptadecanyl-2,7carbazole-alt-3,6-bis(thiophen-5-yl)-2,5-dioctyl-2,5-dihydropyrrolo[3,4]pyrrole-1,4-dione]




: : : ::

1266549-31-8MW > 50,000 (GPC)(C41H53FO4S4)n


Poly{4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b' ]dithiophene-2,6-diyl-alt-3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophene-4,6-diyl}



: : : ::

: : ::

1334549-75-5MW = 20,000 ~ 50,000 (GPC)(C56H70N2O2S3)n


360068-36-6Mw > 20,000 (GPC)(C31H42)n

455 nm (in CH2Cl2)Poly[2,7-(9-(tridecan-7-ylidene)-9H-fluorene)-alt-4,7-bis(thiophen-2-yl)-5,6-bis(octyloxy)benzo[c ][1,2,5]thiadiazole]

Poly[2,7-(9-(tridecan-7-ylidene)-9H-fluorene)-alt-4,7-bis(thiophen-2-yl)-5,6-bis(octyloxy)benzo[c ][1,2,5]thiadiazole]

Reference : Macromolecules, 2011, 4409, pp7617-7624

Reference : 1. Nature Photonics 6, 591-595 (2012)2. Adv. Mater., 2010, 22, 135-1383. Adv. Mater., 2014, 26, 6653-6657

SiC8H17 C8H17

S S

NS

Nn

S

SOC8H17

S

S

O OC12H25 n

OC8H17

N

NS

S

N

C8H17

C8H17 C8H17 C8H17

O

On

S

SF

S

SO

O

OO

n

S S

NS

N

C8H17O OC8H17

C6H13 C6H13

n

LT-S954

LT-S9050

LT-S9065

LT-S9006

LT-S955

LT-S9032PSiF-DTB

PTB7

PAFDTBT

PTB1

PCBTDPP

C8H17 C8H17 n



Flexible P

rinted

Electron



177176

LT-S9109 PDPP3T


: : : ::

1198291-01-8MW > 30,000 (GPC)(C50H72N2O2S3)n


Poly{2,2'-[(2,5-bis(2-hexyldecyl)-3,6-dioxo-2,3,5,6-tetrahydropyrrolo[3,4-c ]pyrrole-1,4-diyl)dithiophene]-5,5'-diyl-alt-thiophen-2,5-diyl}


nS

S

N

NS

O

O

C8H17

C8H17

C6H13

C6H13


: : : ::

1279109-93-1MW = 7,000 ~ 30,000 (GPC)(C38H53NO2S3Si)n

614, 670 nm (film)Soluble in CHCl3, Chlorobenzene, Dichlorobenzene

Poly[2,6-(4,4'-bis(ethylhexyl)dithieno[3,2-b:2',3'-d ]silole)-alt-(1,3-(5-octyl-4H-thieno[3,4-c]pyrrole-4,6(5H)-dione))]


Si

SSS

NO O

C8H17

n

LT-S9066 PDTSTPD


: : : ::

1223479-75-1MW > 30,000 (GPC)(C40H53NO4S3)n


Poly{4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b' ]dithiophene-2,6-diyl-alt-(1,3-(5-octyl-4H-thieno[3,4-c]pyrrole-4,6(5H )-dione))}

Reference : 1. Chem. Mater. 2010, 22, 2696-26982. J. Am. Joc. Soc. 2010, 132, 5330-5331

S

N

S

SO

O

n

OO

C8H17


: : : :

MW > 30,000 (GPC)(C78H124N2O2S4)n


Poly[3,6-bis(4'-dodecyl[2,2'-bithiophen]-5-yl)-2,5-bis(2-ethylhexyl)-2,5-dihydropyrrolo[3,4-c ]-pyrrole-1,4-dione]

Reference : J. Phys. Chem. C, 2011,115(30), pp15075-15080

nSS

N

NS

O

O

C8H17

C8H17

C6H13

C6H13

S

C12H25

C12H25

LT-S9111

LT-S9112

PBDTTPD

pBBTDPP2


: : : ::

1204005-82-2MW > 10,000 (GPC)(C47H54N2S3)n


poly{[2,7-(9,9-bis-(3,7-dimethyl-octyl)-fluorene)]-alt-[5,5-(4,7-di-2'-thienyl-2,1,3-benzothiadiazole)]}


nS

N SN

S


: : : ::

1255939-39-9MW > 30,000 (GPC)(C52H74N2O2S2)n


Poly{2,2'-[(2,5-bis(2-hexyldecyl)-3,6-dioxo-2,3,5,6-tetrahydropyrrolo[3,4-c ]pyrrole-1,4-diyl)]dithiophene-5,5'-diyl-alt-benzen-1,4-diyl}

Reference : 1. Chem. Mater. 2012, 24, 1316-13232. Adv. Mater. 2010, E242-E246

SN

NS

O

O

C8H17

C8H17

C6H13

C6H13

n

LT-S9113

LT-S9114

BisDMO-PFDTBT

PDPPTPT

179178



Flexible P

rinted

Electron

ics


179178


: : : :

MW > 7,000 (GPC)(C50H66N2S6Si)n


Poly{5,5'-bis(2-thienyl)-4,4,-dihexyl-2,2'-bithiazole-5',5''-diyl-alt-4,4'-bis(2-ethylhexyl)-dithieno[3,2-b:2',3'-d ]-silole-5,5'-diyl}

Reference : Macromolecules 2010, 43, 5706-5712

SS

N

N

SS

C6H13

C6H13

Si

SSn


: : : ::

1267540-03-3MW > 30,000 (GPC)(C62H90N2O2S4)n




SS

N

NS

O

O

C8H17

C8H17

C10H21

C10H21

S n

LT-S9116

LT-S9117

LT-S9118

PBTzSBT

PDQT

PDBT-co-TT


: : : ::

1260685-65-1MW > 30,000 (GPC)(C60H88N2O2S4)n



Reference : 1. Adv. Mater. 2010, 22, 4862-48662. Chem. Mater. 2012, 24, 1316-1323

nS

S

N

NS

O

O

C8H17

C8H17

C10H21

C10H21

S

LT-S9119

LT-S9139

PDPPBTT

PTB7-Th



: : : ::

: : ::

1270977-98-4MW > 30,000 (GPC)(C62H88N2O2S5)n


MW > 50,000 (GPC)(C8H6S2)(C49H57FO2S6)n

812 nm (in CHCl3)> 5 mg/mL in CHCl3


Poly{4,8-bis[5-(2-ethylhexyl)thiophen-2-yl]benzo[1,2-b :4,5-b']dithiophene-2,6-diyl-alt-3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophene-4,6-diyl}



SN

NS

O

O

C8H17

C8H17

C10H21

C10H21

nS

S

S

S

SS

S

O O

F S

S

n

S

S

LT-S9178 PMDPP3T

GradeFormulaUV

: : :

MW > 30,000 (GPC)(C52H76N2O2S3)n

830 nm (in CHCl3)


N

NO

O

SS

C8H17

C8H17

C6H13

C6H13

Sn



Flexible P

rinted

Electron


Organic Thin-Film Transistor(OTFT) Polymers

179178 179178

LT-S979 LT-S982

LT-S9060

LT-S980

LT-S981

F8T2 PBTTT-C14

PBTTT-C16

PQT-12

PBTTT-C12

SS S

S

C12H25

C12H25n

S

SSS

C12H25

C12H25n

S

SSS

C14H29

C14H29n

S

SSS

C16H33

C16H33n





: : : :: :

: : : :: :

: : : :: :

: : : ::

210347-56-1MW > 20,000 (GPC)(C37H44S2)n


888491-18-7MW = 40,000 ~ 80,000 (GPC)(C38H54S4)n


888491-19-8MW = 40,000 ~ 80,000 (GPC)(C38H54S4)n


MW = 40,000 ~ 80,000 (GPC)(C46H70S4)n





Poly[2,5-bis(3-hexadecylthiophen-2-yl)thieno[3,2-b ]thiophene]




Reference : Nano Lett., 2009, 9 (12), pp4153-4157


: : : : :

827343-06-6MW = 10,000 ~ 40,000 (GPC)(C40H56S4)n

473 nm (in Toluene)> 5 mg/mL in CHCl3

Poly[bis(3-dodecyl-2-thienyl)-2,2'-dithiophene -5,5'-diyl]


SS n

Poly[2,3-bis-(3-octyloxyphenyl)quinoxaline-5,8-diyl-alt -thiophene-2,5-diyl]

N N

OC8H17C8H17O

Sn

Reference : Journal of Materials Chemistry A: Materials for Energy and Sustainability (2014), 2(41), 17676-17682

LT-S9091 TQ1

CAS No.GradeFormulaM.W.Solubility

:::::

565228-37-7MW > 20,000 (GPC)(C40H46N2O2S)n

618.89 g/mole> 5 mg/mL in CHCl3

181180



Flexible P

rinted

Electron

ics

Flexible Printed ElectronicsOrganic Thin-Film Transistor(OTFT) Polymers

181180

Poly{3,6-dithiophen-2-yl-2,5-di(2-decyltetradecyl)-pyrrolo[3,4-c ]pyrrole-1,4-dione-alt-thienylenevinylene -2,5-yl}


N

NO

O

S

S

C12H25

C12H25

C10H21

C10H21

SS

n



: : :: :

: : : ::

1260685-65-1MW > 30,000 (GPC)(C60H88N2O2S4)n


1270977-98-4MW > 30,000 (GPC)(C62H88N2O2S5)n





Reference :

Reference :

Reference :

1. Adv. Mater. 2010, 22, 4862-48662. Chem. Mater. 2012, 24, 1316-1323


Nature Communications 5, Article number: 4183

nS

S

N

NS

O

O

C8H17

C8H17

C10H21

C10H21

S

SN

NS

O

O

C8H17

C8H17

C10H21

C10H21

nS

S

S

LT-S9118

LT-S9119

LT-S9133

LT-S9155PDBT-co-TT

PDPPBTT

PDVT-10

PDVT-8

CAS No.FormulaGradeSolubility


::::

::::

1442682-99-6(C72H108N2O2S4)n

MW > 30,000 (GPC)Soluble in CHCl3, Chlorobenzene, Dichlorobenzene

1403959-01-2MW > 20,000 (GPC)(C64H92N2O2S4)n


N

NO

O

SS

C8H17

C8H17

C10H21

C10H21

SS

n

LT-S9117 PDQT


: : : ::

1267540-03-3MW > 30,000 (GPC)(C62H90N2O2S4)n




SS

N

NS

O

O

C8H17

C8H17

C10H21

C10H21

S n

LT-S9178 PMDPP3T

GradeFormulaUV

: : :

MW > 30,000 (GPC)(C52H76N2O2S3)n

830 nm (in CHCl3)


N

NO

O

SS

C8H17

C8H17

C6H13

C6H13

Sn



Flexible P

rinted

Electron


Hole Transport Layer / Hole Injection Layer(HTL/HIL) Polymers

181180 181180

N

n

n

N

C8H17 C8H17

N

n


: : : :: :

220797-16-0MW > 10,000 (GPC)(C51H61N)n


Poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(4,4'-(N-(4-sec-butylphenyl)diphenylamine)]

Poly[N,N'-bis(4-butylphenyl)-N,N'-bis(phenyl)-benzidine]




: : : :: :

472960-35-3MW > 10,000 (GPC)(C22H21N)n




: : : :: :

1333317-99-9MW > 10,000 (GPC)(C21H19N)n

371, 388 nm (in CH2Cl2)424 nm (in CH2Cl2)Soluble in THF, CHCl3, Chlorobenzene, Dichlorobenzene


: : :: :

MW > 10,000 (GPC)C73H82N2

380 nm (in THF)435 nm (in THF)Soluble in THF, CHCl3,Chlorobenzene, Dichlorobenzene

Poly[(9,9-dioctylfluorenyl-2,7-diyl)-alt-(N,N'-bis{4-butylphenyl}-benzi(dine-N,N')-{1,4-diphenylene})]


: : :: :

MW > 10,000 (GPC)C16H18(C67H78N2)380 nm (in THF)494 nm (in THF)Soluble in THF, CHCl3, Chlorobenzene, Dichlorobenzene


LT-N148 LT-N169

LT-N170

LT-N171

LT-N149

LT-N168

TFB

Poly-TPD

PTAA

N N n


: : : :: :

870517-32-1MW > 10,000 (GPC)(C51H62N2)n


Poly[(9,9-dihexylfluorenyl-2,7-diyl)-alt -(N,N'- bis{p -butylphenyl}-1,4-diaminophenylene)]

N Nn

HN N nH



Flexible P

rinted

Electron

ics

Flexible Printed ElectronicsHole Transport Layer / Hole Injection Layer(HTL/HIL) Polymers

183182

N N n

Nn

n



: : : :: :

: : : :: :

1115424-53-7MW > 10,000 (GPC)(C61H74N2)n


223569-31-1MW > 30,000 (GPC)(C51H61N)n



Poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(4,4'-(N-(p-butyl-phenyl))diphenylamine)]

Poly(1-vinylnaphthalene)

Poly(2-vinylnaphthalene)

Poly(N-ethyl-2-vinylcarbazole)



: : : :

: : : :

29793-40-6MW > 20,000 (GPC)(C12H10)n

Soluble in THF, CHCl3, Chlorobenzene, Dichlorobenzene

28406-56-6MW > 100,000 (GPC)(C12H10)n


n


: : : :

41008-78-0MW > 20,000 (GPC)(C16H15N)n



N

n

LT-N172 LT-N176

LT-N4075

LT-N174

LT-N175



: : : :

55447-28-4MW > 10,000 (GPC)(C14H11N)n


NH

n

LT-N4076



Flexible P

rinted

Electron


Hole Transport Layer / Hole Injection Layer(HTL/HIL) Polymers

183182





: : : :: :

: : : :: :

25067-59-8MW > 20,000 (GPC)(C14H11N)n

261, 294 nm (in CH2Cl2)380 nm (in THF)Soluble in THF, CHCl3, Chlorobenzene, Dichlorobenzene

25067-59-8MW > 100,000 (GPC)(C14H11N)n


N

n

N

n

Reference :

Reference :

1. J. Chem. Phys. 62, 4697 (1975)2. Appl. Phys. Lett. 88, 251110 (2006)


LT-N4077

LT-N4078

PVK

PVK


Reference : Journal of Materials Chemistry A: Materials for Energy and Sustainability (2014), 2(41), 17676-17682

LT-S9155 PDVT-8


::::

1403959-01-2MW > 20,000 (GPC)(C64H92N2O2S4)n


N

NO

O

SS

C8H17

C8H17

C10H21

C10H21

SS

n



Flexible P

rinted

Electron

ics

Flexible Printed ElectronicsHost Layer Polymers

184


: : : : :

69678-71-3MW > 30,000 (GPC)(C17H17NO)n

237, 263 nm (in CH2Cl2)Soluble in THF, CHCl3, Chlorobenzene, Dichlorobenzene



: : : ::

1318091-74-5MW > 30,000 (GPC)(C29H24N2O)n

238, 263 nm (in CH2Cl2)Soluble in THF, CHCl3, Chlorobenzene, Dichlorobenzene



HO

N

H

n

HO

N

N

H

n

Poly[3-(carbazol-9-ylmethyl)-3-methyloxetane]

LT-N4037

LT-N4038

PCMO

PCOC

Poly(N-ethyl-2-vinylcarbazole)








: : : :

: : : :: :

: : : :: :

: : : :

55447-28-4MW > 10,000 (GPC)(C14H11N)n


25067-59-8MW > 20,000 (GPC)(C14H11N)n


25067-59-8MW > 100,000 (GPC)(C14H11N)n


41008-78-0MW > 20,000 (GPC)(C16H15N)n



N

n

NH

n

N

n

N

n

Reference :

Reference :



LT-N4075

LT-N4076

LT-N4077

LT-N4078

PVK

PVK



Flexible P

rinted

Electron


Light-Emitting Layer Polymers

185



: : : :: :

: : : :::

138184-36-8MW > 100,000 (GPC)(C17H24O2)n

501 nm (in CH2Cl2)502 nm (in CH2Cl2)Soluble in THF, CHCl3, Chlorobenzene, Dichlorobenzene

874816-14-5MW = 50,000 ~ 150,000 (GPC)C16H18(C29H40)n


Poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] Poly(9,9-dioctylfluorenyl-2,7-diyl) end capped with dimethylphenyl

Reference : Appl. Phys. Lett. 78, 841 (2001)Reference : Appl. Phys. Lett., 2004, 85, 4576-4578


: : : :: :

123864-00-6MW = 50,000 ~ 150,000 (GPC)(C29H40)n




: : : :: :

177716-59-5MW > 100,000 (GPC)(C19H28O2)n

485 nm (in CH2Cl2)555 nm (in CH2Cl2)Soluble in THF, CHCl3, Chlorobenzene, Dichlorobenzene





n

O

H3CO

n

O

H3CO

n

n

CH3

CH3CH3

CH3


: : : :: :

210347-52-7MW = 20,00 ~ 100,000 (GPC)(C35H42N2S)n



Reference : Synthetic Metals, 152, 105, 2005


: : : :: :

201807-75-2MW = 50,000 ~ 150,000 (GPC)(C25H32)n


NS

N

n

n

LT-S931 LT-S934

LT-S957

LT-S958

LT-S932

LT-S933

MEH-PPV PFO-DMP

F8BT

PHF

MDMO-PPV

PFO



Flexible P

rinted

Electron

ics

Flexible Printed ElectronicsLight-Emitting Layer Polymers

186


: : : :: :

210347-56-1MW = 20,000 ~ 60,000 (GPC)(C37H44S2)n




Poly[2,5-bis(3',7'-dimethyloctyloxy)-1,4-phenylenevinylene]

Poly[2,5-bisoctyloxy)-1,4-phenylenevinylene]



: : : :: :

189012-99-5MW > 100,000 (GPC)(C28H46O2)n

480 nm (in Toluene)548 nm (in Toluene)Soluble in CHCl3, Chlorobenzene, Dichlorobenzene

n

O

O

SS n


: : : :: :

188201-16-3MW > 20,000 (GPC)(C29H40)n



: : : :: :

133069-19-9MW > 3,000 (GPC)(C24H38O2)n


n

O

O


: : : ::

MW > 100,000 (GPC)(C17H26O2)n(C28H38O2)m


Poly{[2-[2',5'-bis(2'-ethylhexyloxy)phenyl]-1,4-phenylenevinylene]-co-[2-methoxy-5-(2'-ethylhexyloxy)-1,4-phenylenevinylene]}, (m:n=60:40 mole ratio)

OO

mO

O

n

Reference : Physica E: Low-dimensional Systems and Nanostructures 53, 2013, 66-71

n

LT-S979 LT-A1003

LT-A1004LT-S9004

LT-A1001

F8T2 BEHP-CO-MEH-PPV



Flexible P

rinted

Electron



187

Poly(2,5-dioctyl-1,4-phenylenevinylene)

Poly(9,9-di-(2-ethylhexyl)-9H-fluorene-2,7-vinylene)

Poly(9,9-di-n-hexylfluorenyl-2,7-vinylene)


: : : :: :

221244-49-1MW > 10,000 (GPC)(C21H32O8)n


Poly(2,5-bis(1,4,7,10-tetraoxaundecyl)-1,4-phenylenevinylene)




: : : :: :

: : : :: :

808735-22-0MW > 3,000 (GPC)(C24H38)n


1019638-19-7MW > 20,000 (GPC)(C31H42)n



n

C8H17

C8H17

n

n

O

O

O3

O 3



: : :: :

: : :: :

MW > 20,000 (GPC)(C29H38)m(C17H24O2)n


MW > 20,000 (GPC)(C27H34)m(C17H24O2)n


Poly[(9,9-di-(2-ethylhexyl)-9H -fluorene-2,7-vinylene)-co-(2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene)](m:n=95:5 mole ratio)

Poly((9,9-dihexyl-9H-fluorene-2,7-vinylene)-co-(1-methoxy-4-(2-ethylhexyloxy)-2,5-phenylenevinylene)), (m:n=95:5 mole ratio)


O

O

nm

n


: : : :: :

203927-82-6MW > 20,000 (GPC)(C27H34)n


LT-A1005 LT-A1008

LT-A1009

LT-A1010

LT-A1006

LT-A1007

BTEM-PPV

Poly(FV-CO-MEHPV)

POPPV

O

Om

n



Flexible P

rinted

Electron

ics


188



: : :: ::

: : : :: :

474975-19-4MW > 20,000 (GPC)(C47H52)n


474975-20-7MW > 20,000 (GPC)(C45H52)n


Poly[(9,9-dioctyl-2,7-divinylenefluorenylene)-alt -(9,10-anthracene)]

Poly[(9,9-dioctyl-2,7-divinylenefluorenylene)-alt -(4,4'-biphenylene)]

n


: : : :: :

475101-36-1MW > 30,000 (GPC)(C48H66O2)n


Poly[(9,9-dioctyl-2,7-divinylenefluorenylene)-alt-{2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylene}]

O

O n

Reference : J. Am. Chem. Soc., 2007, 129 (43), pp 12904-12905


: : : :: :

248256-53-3MW > 40,000 (GPC)(C37H56)n


Reference : Sensors, 2010 IEEE, 2603-2606

n



: : : :: :

: : : :: :

577705-37-4MW > 30,000 (GPC)(C60H74O2)n


579505-60-5MW > 30,000 (GPC)(C39H48)n


Poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(1,4-diphenylene-vinylene-2-methoxy-5-{2-ethylhexyloxy}-benzene)]

Poly[(9,9-dioctyl-2,7-divinylenefluorenylene)-alt- (1,4-phenylene)]

Poly(9,9-di-n-dodecylfluorenyl-2,7-diyl)

nO

O

n

n

LT-A1011 LT-A1014

LT-A1015

LT-A1016

LT-A1012

LT-A1013

PFD

PEPV



Flexible P

rinted

Electron



189



: : :: :

: : : :: :

MW > 10,000 (GPC)C16H18(C39H40)n


579505-48-9MW > 20,000 (GPC)C16H18(C33H40)n


Poly[(9,9-dihexylfluoren-2,7-diyl)-co -(anthracen-9,10-diyl)] end capped with dimethylphenyl

Poly[(9,9-dihexylfluoren-2,7-diyl)-alt -(2,5-dimethyl-1,4-phenylene)] end capped with dimethylphenyl


Reference : Nanotechnology. 2012, 23(7), 075701

n

n


: : : ::

MW > 20,000 (GPC)C16H18(C39H43N)n


Poly[(9,9-dihexylfluoren-2,7-diyl)-co -(9-ethylcarbazol-2,7-diyl)]end capped with dimethylphenyl

Reference : Journal of Power Sources 246, 2014, 184-191

N

n



: : : ::

: : : :: :

MW > 20,000 (GPC)C16H18(C37H48O2)n


856893-75-9MW > 30,000 (GPC)(C43H43N)n


Poly[{9,9-dioctylfluorenyl-2,7-diyl}-co-{1,4-(2,5-dimethoxy)benzene}] end capped with dimethylphenyl

Poly(9,9-n-dihexyl-2,7-fluorene-alt-9-phenyl-3,6-carbazole)

Nn

n

O

O


: : : :: :

1423043-97-3MW > 20,000 (GPC)(C39H46N2)n


Poly[(9,9-dioctylfluorenyl-2,7-diyl)-alt-(6,6'-{2,2'-bipyridine})]


nN N

LT-A1017 LT-A1020

LT-A1021

LT-A1023

LT-A1018

LT-A1019

PFH-A-DMP

PFO-BPy

PF-DMB

PFH-EC



Flexible P

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Electron

ics


190



: : : ::

: : : :: :

MW > 30,000 (GPC)C16H18(C41H46N2)n


934690-41-2MW > 20,000 (GPC)(C44H49N3)n


Poly[(9,9-dioctyl-2,7-fluorenylene)-co-(3,8-phenanthroline)] end capped with dimethylphenyl

Poly[(9,9-dioctylfluorenyl-2,7-diyl)-alt-(6,6'-{2,2':6',2''-terpyridine})]

nNN

N

nN N


: : : ::

MW > 20,000 (GPC)C40H36N2(C29H40)n


Poly[9,9-dioctylfluorenyl-2,7-diyl] end capped with N,N-Bis(4-methylphenyl)-aniline

Reference : New J. Phys. 2004, 6, 185

nN N



: : :: ::

: : :: :

1010129-39-1MW = 50,000 ~ 150,000 (GPC)C16H18(C25H32)n


MW > 20,000 (GPC)C28H18N4O2(C29H42)n


Poly[9,9-dihexylfluorenyl-2,7-diyl] end capped with dimethylphenyl

Poly[9,9-di-(2-ethylhexyl)-fluorenyl-2,7-diyl] end capped with 2,5-diphenyl-1,2,4-oxadiazole

nN

NO O

NN

n


: : : ::

MW > 20,000 (GPC)C28H18N4O2(C29H42)n


Poly[9,9-dioctylfluorenyl-2,7-diyl] end capped with 2,5-diphenyl-1,2,4-oxadiazole

NN

O ON

Nn

LT-A1024 LT-A1027

LT-A1028

LT-A1029

LT-A1025

LT-A1026



Flexible P

rinted

Electron



191



: : :: :

: : :: :

MW > 20,000 (GPC)C16H18(C29H40)n


MW > 20,000 (GPC)C40H36N2(C29H40)n


Poly[9,9-di-(2-ethylhexyl)-fluorenyl-2,7-diyl] end capped with dimethylphenyl

Poly[9,9-di-(2-ethylhexyl)-fluorenyl-2,7-diyl] end capped with N,N-Bis(4-methylphenyl)-aniline

Poly[(9,9-dihexylfluorenyl-2,7-diyl)-co-(9,10-anthracene)]



n

N Nn


: : :: ::

474975-22-9MW > 10,000 (GPC)(C39H40)n



n



: : : ::

: : : :: :

MW > 20,000 (GPC)(C29H40)m(C6H2N2S)n


475102-99-9MW > 30,000 (GPC)(C40H54O2)n


Poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(1,4-benzo-{2,1,3}-thiadiazole)] (m:n=95:5 mole ratio)

Poly[(9,9-dihexylfluorenyl-2,7-diyl)-alt-(2-methoxy-5-{2-ethylhexyloxy}-1,4-phenylene)]


O

O n

nN

S N

m

Reference : Journal of Nanoscience and Nanotechnology, 2012, Vol.12, pp 5407-5411


: : : ::

MW > 10,000 (GPC)(C47H59N)n


Poly[(9,9-dioctylfluorenyl-2,7-diyl)-alt-(9-hexyl-3,6-carbazole)]

N

n

LT-A1030 LT-A1033

LT-A1034

LT-A1035

LT-A1031

LT-A1032 PFH-A



Flexible P

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Electron

ics


192


: : : ::

MW > 10,000 (GPC)C16H18(C47H59N)n


Poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(9-hexyl-3,6-carbazole)] end capped with dimethylphenyl

Poly[(9,9-dioctylfluorenyl-2,7-diyl)-alt-(2,6-pyridine)]

N

n


: : : :: :

474975-24-1MW > 20,000 (GPC)(C50H46)n


Poly[(9,9-dihexylfluorenyl-2,7-diyl)-alt-(9,9'-spiro-bifluorene-2,7-diyl)]

Poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(2,5-p-xylene)]

n


: : : :::

1687752-52-8MW > 20,000 (GPC)(C37H48)n


n


: : : :::

1025775-95-4MW > 30,000 (GPC)C16H18(C35H44)n


Poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(1,4-phenylene)] end capped with dimethylphenyl

Poly(2,5-di(3,7-dimethyloctyloxy)cyanoterephthalylidene)


: : : :

1047680-39-6MW > 30,000 (GPC)(C58H90N2O4)n


n

O

O

NC

O

O

CN

n


: : : :: :

773895-96-8MW > 20,000 (GPC)(C34H43N)n


nN

LT-A1036 LT-A1039

LT-A1040

LT-A1041

LT-A1037

LT-A1038



Flexible P

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Electron



193

Poly(2,5-di(hexyloxy)cyanoterephthalylidene)


: : : :

151897-69-7MW > 30,000 (GPC)(C42H58N2O4)n


Reference : J. Phys. Chem. B, 2010, 114(47), 15451-8

O

O

NC

O

O

CN

n



: : : :

: : : :

320725-67-5MW > 30,000 (GPC)(C40H54N2O4)n


194292-84-7MW > 30,000 (GPC)(C36H46N2O4)n


Poly(5-(3,7-dimethyloctyloxy)-2-methoxy-cyanoterephthalylidene)

Poly(5-(2-ethylhexyloxy)-2-methoxy-cyanoterephthalylidene)

nO

O

NCO

OCN

nO

O

NCO

OCN



: : :: :

: : : :: :

MW > 20,000 (GPC)(C50H64N2O2)n


369370-71-8MW > 20,000 (GPC)(C61H56N4)n


Poly[(9,9-dioctyl-2,7-bis{2-cyanovinylenefluorenylene})-alt-(2-methoxy-5-{2-ethylhexyloxy}-1,4-phenylene)]

Poly[{9,9-dihexyl-2,7-bis(1-cyanovinylene)fluorenylene}-alt-{2,5-bis(N,N'-diphenylamino)-1,4-phenylene}]

n

CN

NC

N

N


: : : ::

MW > 20,000 (GPC)(C51H46N4O2)n


Poly[{2-methoxy-5-(2-ethylhexyloxy)-1,4-(1-cyanovinylenephenylene)}-co-{2,5-bis(N,N'-diphenylamino)-1,4-phenylene}]

CN

NC

N

N

O

On

O

OnNC

CN

LT-A1042 LT-A1045

LT-A1046

LT-A1047

LT-A1043

LT-A1044



Flexible P

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Electron

ics


194




: : : :: :

: : : ::

: : :: :

608512-95-4MW > 20,000 (GPC)(C56H66N2)n


MW > 30,000 (GPC)(C24H34N2O2)n


MW > 20,000 (GPC)C16H18(C14H17NO)n


Poly[(9,9-dihexyl-2,7-(2-cyanodivinylene)-fluorenylenyl-2,7-diyl)]

Poly{[2,5-bis(2-(N,N-diethylamino)ethoxy)-1,4-phenylene]-alt-1,4-phenylene}

Poly[2-(5-cyano-5-methylhexyloxy)-1,4-phenylene] end capped with dimethylphenyl


n

O

CN

nCN

NC


: : : ::

MW > 30,000 (GPC)(C18H18Na2O8S2)n

341 nm (in H2O)420 nm (in H2O)Soluble in H2O

Poly(2,5-bis(3-sulfonatopropoxy)-1,4-phenylene, disodium salt-alt-1,4-phenylene)

Poly[2,5-dioctyl-1,4-phenylene] end capped withdimethylphenyl


: : : ::

MW > 30,000 (GPC)(C24H36Br2N2O2)n

340 nm (in DMSO)421 nm (in DMSO)Soluble in MeOH

Poly[(2,5-bis(2-(N,N-diethylammonium bromide)ethoxy)-1,4-phenylene)-alt-1,4-phenylene]

Reference : 1. Macromolecules, 1998, 31 (4), pp 964-9742. Phys. Rev. B 86, 235420 (2012)

nO

O


: : : ::

MW > 20,000 (GPC)C16H18(C22H36O2)n


LT-A1048 LT-A1051

LT-A1052

LT-A1054

LT-A1049

LT-A1050

PPP-OPSO3

O S

O

O

O

ONa

SO

O

NaO n

O

O

H H

N

N

n

O

O

H

N

N

n

HBr



Flexible P

rinted

Electron



195



: : :: :

: : :: :

MW > 20,000 (GPC)C16H18(C15H22O2)n


MW > 20,000 (GPC)(C44H58O2)n


Poly[2-methoxy-5-(2-ethylhexyloxy)-1,4phenylene] end capped with dimethylphenyl

Poly((9,9-dihexyl-9H -fluorene-2,7-vinylene)-co-(1- methoxy-4-(2-ethylhexyloxy)-2,5-phenylenevinylene))

O

O

n


: : :: :

MW > 10,000 (GPC)C73H82N2


Poly[(9,9-dioctylfluorenyl-2,7-diyl)-alt-(N,N' -bis{4-butylphenyl}-benzidine-N,N'-{1,4-diphenylene})]


: : :: :

MW > 10,000 (GPC)C16H18(C67H78N2)380 nm (in THF)494 nm (in THF)Soluble in CHCl3, Chlorobenzene, Dichlorobenzene




: : : :: :

: : : :: :

1115424-53-7MW > 10,000 (GPC)(C61H74N2)n


870517-32-1MW > 10,000 (GPC)(C51H62N2)n



Poly[(9,9-dihexylfluorenyl-2,7-diyl)-alt-(N,N'bis-{p-butylphenyl}-1,4-diaminophenylene)]

N N n

N N n

LT-A1055

LT-A1056

LT-N171

LT-N172

LT-N169

LT-N170

C6H13

C6H13

MeO

O

n

N Nn

HN N nH



Flexible P

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Electron

ics


196

LT-N174

Nn


: : : :: :

223569-31-1MW > 30,000 (GPC)(C51H61N)n


Poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(4,4' -(N-(p-butyl-phenyl))diphenylamine)]


: : :::

360068-36-6Mw > 20,000 (GPC)(C31H42)n

455 nm (in CH2Cl2)Soluble in CHCl3,Chlorobenzene, Dichlorobenzene

Poly[2,7-(9-(tridecan-7-ylidene)-9H-fluorene)-alt-4,7-bis(thiophen-2-yl)-5,6-bis(octyloxy)benzo[c ][1,2,5]thiadiazole]

LT-S9006

C8H17 C8H17 n



Flexible P

rinted

Electron


Electron Transport Layer / Hole Blocking Layer (ETL/HBL) Polymers

197

C8H17 C8H17 n

NNBr Br


: : : ::

MW > 10,000 (GPC)(C56H80N2Br2)n




C8H17 C8H17 n

NN


: : : :: :

673474-74-3MW > 10,000 (GPC)(C52H70N2)n

378 nm (in CH2Cl2) 414 nm (in CH2Cl2)Soluble in CH2Cl2,CHCl3,Toluene



LT-N878

LT-N4027

PFNBr

PFN-DOF

199198



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Photonic and Optical DeviceContents

199198

• Introduction ------------------------------------------------------------199

• Porphyrins (70) ----------------------------------------------------------202

• Phthalocyanines (32) ----------------------------------------------------214

• Near-Infrared(NIR) Dyes (17) -------------------------------------------219



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Introduction

199198 199198

　Porphyrins, Phthalocyanines and Near-Infrared(NIR) Dyes of the Future.

　Porphyrins are a group of organic compounds, many naturally occurring. One of the best-known porphyrins is heme. Porphyrins are heterocyclic macrocycles composed of four modified pyrrole subunits interconnected at their α carbon atoms via methine bridges (=CH-). Porphyrins are aromatic. That is, they obey Hückel's rule for aromaticity, possessing 4n+2 π electrons (n=4 for the shortest cyclic path) delocalized over the macrocycle. Thus porphyrin macrocycles are highly conjugated systems. As a consequence, they typically have very intense absorption bands in the visible region and may be deeply colored.

　Medicine Porphyrins have been evaluated in the context of photodynamic therapy since they strongly absorb light, which is then converted to energy and heat in the illuminated areas.

Porphyrins applications:

Molecular electronics

　Porphyrin-based compounds are of interest in molecular electronics and super molecular building blocks. Phthalocyanines, which are structurally related to porphyrins, are used in commerce as dyes and catalysts. Synthetic porphyrin dyes that are incorporated in the design of solar cells are the subject of ongoing research. Recent applications of porphyrin dyes for dye-sensitized solar cells have shown solar conversion efficiencies approaching silicon based photovoltaic devices.

Photonic and Optical Device



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Photonic and Optical DeviceIntroduction

201200

　Phthalocyanines are an intensely blue-green-coloured aromatic macrocyclic compound that is widely used in dyeing. Phthalocyanines form coordination complexes with most elements of the periodic table. These complexes are also intensely colored and also are used as dyes or pigments.

　Metal phthalocyanines have long been examined as catalysts for redox reactions. Areas of interest are the oxygen reduction reaction and the sweetening of gas streams by removal of hydrogen sulfide.

　Phthalocyanine compounds have been investigated as donor materials in molecular electronics, e.g. organic field-effect transistors.

　Copper Phthalocyanine (CuPC) may possibly be used as storage in quantum computing, due to the length of time its electrons can remain in superposition.

Phthalocyanines applications:

Optical, Electronic and Photo-electronic Devices



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Introduction

201200

Near-Infrared(NIR) Dyes applications

　Near-infrared (near-IR, NIR) dyes offer important advantages over traditional visible light dyes. Because cellular or tissue components produce minimal autofluorescence in the near-IR region, near-IR dyes have the potential to offer highly specific and sensitive detection in complex biological systems.



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Photonic and Optical DevicePorphyrins

202

LT-D0001 LT-D0004

LT-D0005

LT-D0006

LT-D0002

LT-D0003




: : : ::

: : : ::

: : : ::

917-23-7> 95% (HPLC)C44H30N4


14172-92-0 > 95% (HPLC)C44H28N4Ni 671.41 g/mole525 nm (in THF)

14705-63-6 > 95% (HPLC)C44H28N4OV679.66 g/mole423 nm (in THF)

meso-Tetraphenylporphine

Nickel(II) meso-tetraphenylporphine

Vanadyl meso-tetraphenylporphine

HN

NNH

N

N

NN

N

Ni

N

NN

NVO

N

NN

NFeCl

N

NN

NZn

N

NN

NMg

H2O

CAS No.FormulaM.W.

CAS No.FormulaM.W.

: : :

: : :

14074-80-7C44H28N4Zn678.11 g/mole

14640-21-2C44H30MgN4O 655.04 g/mole

Zinc(II) meso-tetraphenylporphine

Magnesium(II) meso-tetraphenylporphine hydrate


: :: :

16456-81-8> 97% (HPLC)C44H28ClFeN4

704.02 g/mole

Iron(III) meso-tetraphenylporphine Chloride



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Porphyrins

203

LT-D0007 LT-D0010

LT-D0011

LT-D0012

LT-D0008

LT-D0009



: : : ::

: : : ::

32195-55-4> 95% (HPLC)C44H28ClMnN4

703.11 g/mole583 nm (in THF)

14609-54-2 > 97% (HPLC)C48H30N4O8


Manganese(III) meso-tetraphenylporphine chloride meso-Tetra(4-carboxyphenyl)porphine

N

NN

NMnCl

N

NN

NPt

N

NN

NCo

HN

NNH

N

COOH

HOOC

COOH

COOH

N

NN

N

Pd

COOH

HOOC

COOH

COOH

N

NN

NFeCl

COOH

COOH

COOH

HOOC




CAS No.FormulaM.W.

: : : :

: : : :

: :: :

: : :

14187-14-5 > 95% (HPLC)C44H28N4Pt 807.8 g/mole

94288-44-5> 95% (HPLC)C48H28N4O8Pd 895.18 g/mole

14172-90-8> 97% (HPLC)C44H28CoN4

671.65 g/mole55266-17-6C48H28ClFeN4O8 880.06 g/mole

Platinum(II) meso-tetraphenylporphine

Palladium(II) meso-tetra(4-carboxyphenyl)porphine

Cobalt(II) meso-tetraphenylporphine

Iron(III) meso-tetra(4-carboxyphenyl)porphine chloride



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204


: : : ::

51094-17-8> 95% (HPLC)C44H30N4O4


meso-Tetra(p-hydroxyphenyl)porphine

N

NN

NCu

COOH

COOH

COOH

HOOC

N

NN

NMn COOHHOOCCl

COOH

COOH

N

NN

NPtHOOC COOH

COOH

COOH

CAS No.FormulaM.W.

CAS No.FormulaM.W.

FormulaM.W.

FormulaM.W.

: : :

: : :

: :

: :

22112-83-0C52H38N4O8

846.88 g/mole

22112-79-4C44H30N4O4

678.73 g/mole

C48H28CuN4O8 852.3 g/mole

C48H28N4O8Pt 983.84 g/mole

meso-Tetra(4-carboxyphenyl)porphine tetramethyl ester

meso-Tetra(3-hydroxyphenyl)porphine

Copper(II) meso-tetra(4-carboxyphenyl)porphine

Platinum(II) meso-tetra(4-carboxyphenyl)porphine

CAS No.FormulaM.W.

: : :

55266-18-7C48H28ClMnN4O8 879.15 g/mole

Manganese(III) meso-tetra(4-carboxyphenyl)porphine chloride

HN

NNH

N

COOCH3

H3COOC

COOCH3

COOCH3

HN

NNH

N

OH

HO

OH

OH

HN

NNH

N

HO

HO

OH

OH

LT-D0013 LT-D0016

LT-D0017

LT-D0018

LT-D0014

LT-D0015



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Porphyrins

205

HN

NNH

N

OCH3

OCH3

OCH3H3CO

N

NN

NCo

OCH3

H3CO

OCH3

OCH3

HN

NNH

N

FF

F

F

F F

F

F

FF

F

F

F

F

FF

F

F

F

F

N

NN

N

FF

F

F

F F

F

F

FF

F

F

F

F

FF

F

F

F

F Pt

N

NN

N

FF

F

F

F F

F

F

FF

F

F

F

F

FF

F

F

F

F Pd



: : : ::

: : : ::

22112-78-3> 95% (HPLC)C48H38N4O4


25440-14-6> 90% (HPLC)C44H10F20N4


meso-Tetra (4-methoxyphenyl) porphine

meso-Tetra(pentafluorophenyl)porphine

CAS No.FormulaM.W.

CAS No.FormulaM.W.

CAS No.FormulaM.W.

: : :

: : :

: : :

28903-71-1C48H36CoN4O4

791.77 g/mole

37083-37-7C44H22Cl8N4

890.29 g/mole

109781-47-7C44H8F20N4Pt 1167.61 g/mole

Cobalt(II) meso-Tetra (4-methoxyphenyl) porphine

meso-Tetra(o-dichlorophenyl)porphine

Platinum(II) meso-tetra(pentafluorophenyl)porphine


: : : :

72076-09-6C44H8F20N4Pd1078.95 g/mole400 nm (in Acetone)

Palladium(II) meso-tetra(pentafluorophenyl)porphine

HN

NNH

N

ClCl

Cl

Cl

Cl Cl

Cl

Cl

LT-D0019 LT-D0022

LT-D0023

LT-D0024

LT-D0020

LT-D0021



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206

CAS No.FormulaM.W.

CAS No.FormulaM.W.

CAS No.FormulaM.W.

CAS No.FormulaM.W.

CAS No.FormulaM.W.

: : :

: : :

: : :

: : :

: : :

91042-27-2C45H23Cl9FeN4

979.58 g/mole

37083-40-2C48H38N4

670.84 g/mole

50849-45-1C48H38N4 670.84 g/mole

14527-51-6C48H38N4 670.84 g/mole

56396-12-4C56H54N4

783.08 g/mole

Iron(III) meso-tetra(o-dichlorophenyl)porphine chloride meso-Tetra(2-methylphenyl)porphine

meso-Tetra(3-methylphenyl) porphine

meso-Tetra(4-methylphenyl) porphine

meso-Tetra(2,4,6-trimethylphenyl)porphine

N

NN

NFeCl

ClCl

Cl

Cl

Cl Cl

Cl

Cl

HN

NNH

N

N

NN

NMnCl

HN

NNH

N


: : : :

85939-49-7> 95% (HPLC)C56H52ClMnN4

871.43 g/mole

Manganese(III) meso-tetra(2,4,6-trimethylphenyl)porphine chloride

HN

NNH

N

HN

NNH

N

LT-D0025 LT-D0028

LT-D0029

LT-D0030

LT-D0026

LT-D0027



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Porphyrins

207

HN

NNH

N

HN

NNH

N

CAS No.FormulaM.W.

CAS No.FormulaM.W.

CAS No.FormulaM.W.

CAS No.FormulaM.W.

: : :

: : :

: : :

: : :

89372-90-7C76H94N4

1063.59 g/mole

31183-11-6C40H24N8Zn 682.06 g/mole

40904-90-3C40H26N8

618.69 g/mole

22112-84-1C44H34N8

674.81 g/mole

meso-Tetra(3,5-di-t-butylphenyl)porphine Zinc(II) meso-tetra(4-pyridyl)porphine

meso-Tetra(2-pyridyl)porphine

meso-Tetra(4-aminophenyl)porphine


: : : :

110452-48-7> 95% (HPLC)C60H62N4

839.16 g/mole

meso-Tetra(4-tert-butylphenyl)porphine

HN

NNH

N

N

N

N N

N

NN

N

N

NZn

N

N

HN

NNH

N

N

N

N

N

HN

NNH

N

NH2

H2N

NH2

NH2


: : : ::

16834-13-2> 97% (HPLC)C40H26N8 618.69 g/mole412 nm (in CH2Cl2)

meso-Tetra(4-pyridyl)porphine

LT-D0031 LT-D0034

LT-D0035

LT-D0036

LT-D0032

LT-D0033



Ph

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208

CAS No.FormulaM.W.

CAS No.FormulaM.W.

CAS No.FormulaM.W.

: : :

: : :

: : :

22112-77-2C44H26Cl4N4 752.52 g/mole

29162-73-0C44H26Br4N4

930.32 g/mole

92739-63-4C44H38Cl4N8 820.64 g/mole

meso-Tetra (4-chlorophenyl) porphine

meso-Tetra (4-bromophenyl) porphine

meso-Tetra (N-methyl-4-pyridyl) porphine tetrachloride

HN

NNH

N

Cl

Cl

Cl

Cl

HN

NNH

N

Br

Br

Br

Br

HN

NNH

N

N+

N+

N+ N+

4Cl-

N

NN

N

N+

N+

N+ N+

4Cl-

Zn

N

NN

N

N+

N+

N+ N+

4Cl-

FeCl

CAS No.FormulaM.W.

CAS No.FormulaM.W.

CAS No.FormulaM.W.

: : :

: : :

: : :

28850-44-4C44H36Cl4N8Zn 884.03 g/mole

133314-07-5C44H36Cl5FeN8 909.92 g/mole

110314-07-3 C44H36Cl4N8Pd 925.04 g/mole

Zinc(II) meso-tetra(N-methyl-4-pyridyl)porphine tetrachloride

Iron(III) meso-tetra(N-methyl-4-pyridyl)porphine pentachloride

Palladium(II) meso-tetra(N -methyl-4-pyridyl)porphine tetrachloride

N

NN

N

N+

N+

N+ N+

4Cl-

Pd

LT-D0037 LT-D0040

LT-D0041

LT-D0042

LT-D0038

LT-D0039



Ph

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Porphyrins

209

CAS No.FormulaM.W.

: : :

94343-62-1C44H38Cl4N8 820.64 g/mole


CAS No.FormulaM.W.

: : :

79407-86-6C44H36Cl4N8Ni 877.32 g/mole

Nickel(II) meso-tetra(N-methyl-4-pyridyl)porphine tetrachloride

N

NN

N

N+

N+ N+Mn

N+

Cl

4Cl-

N

NN

NNi

N+

N+

N+ N+

4Cl-

HN

NNH

N

N+

N+

N+

N+

4Cl-

HN

NNH

N

N+

N+

4Cl-

N+

N+

HN

NNH

N

HN

NNH

NBr Br


: : : ::

125565-45-9> 85% (HPLC)C44H36Cl5MnN8


Manganese(III) meso-tetra(N-methyl-4-pyridyl)porphine pentachloride CAS No.

FormulaM.W.

CAS No.FormulaM.W.

: : :

: : :

129051-18-9C44H38Cl4N8

820.64 g/mole

151256-86-9C32H20Br2N4 620.34 g/mole


5,15-Dibromo-10,20-diphenylporphine


: : : :

22112-89-6> 97% (HPLC)C32H22N4

462.56 g/mole

5,15-Diphenylporphine

LT-D0043 LT-D0046

LT-D0047

LT-D0048

LT-D0044

LT-D0045



Ph

oto

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210

HN

NNH

NBr

HN

NNH

N

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

N

NN

NNi

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

CAS No.FormulaM.W.

: : :

14409-63-3C36H44CuN4

596.31 g/mole

Copper(II) octaethylporphine



: : : :

: : : :

67066-09-5> 95% (HPLC)C38H25BrN4

617.54 g/mole

2683-82-1> 97% (HPLC)C36H46N4

534.78 g/mole

5-Bromo-10,15,20-triphenylporphine

Octaethylporphine

N

NN

NPt

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

N

NN

NV

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

O


: : : :: :

31248-39-2> 95% (HPLC)C36H44N4Pt 727.84 g/mole389, 534 nm (in CH2Cl2)649 nm (in CH2Cl2)

Platinum(II) octaethylporphine


: : : ::

27860-55-5 > 95% (HPLC)C36H44N4OV599.7 g/mole407 nm (in THF)

Vanadyl octaethylporphine

N

NN

N

Cu

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

N

NN

N

Sn

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

Cl

Cl


: : : :

25777-43-9> 95% (HPLC)C36H44Cl2N4Sn 722.38 g/mole

Tin(IV) octaethylporphine dichloride

LT-D0049 LT-N752

LT-D0052

LT-D0053

LT-D0054

LT-D0050

CAS No.FormulaM.W.

: : :

24803-99-4C36H44N4Ni 591.45 g/mole

Nickel(II) octaethylporphine

LT-D0051



Ph

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Porphyrins

211

CAS No.FormulaM.W.

CAS No.FormulaM.W.

: : :

: : :

28755-93-3C36H44ClFeN4

624.06 g/mole

28265-17-0C36H44ClMnN4

623.15 g/mole

Iron(III) octaethylporphine chloride

Manganese(III) octaethylporphine chloride


: : : ::

24804-00-0> 99% (HPLC)C36H44N4Pd 639.18 g/mole393 nm (in THF)

Palladium(II) octaethylporphine

N

NN

N

Mn

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

Cl

N

NN

N

Pd

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

N

NN

N

Fe

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

Cl

N

NN

N

Zn

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5

C2H5


: : : ::

17632-18-7> 98% (HPLC)C36H44N4Zn 598.17 g/mole400 nm (in THF)

Zinc(II) octaethylporphine

LT-D0056

LT-D0057

LT-D0058

LT-D0055 LT-D0062

HN

NNH

N

SO3H

HO3S

SO3H

SO3H

2HCl

FormulaM.W.

: :

C44H32Cl2N4O12S4

1007.99 g/mole

meso-Tetra(4-sulfonatophenyl)porphine dihydrochloride

N

NN

N

SO3H

HO3S

SO3H

SO3HFeCl

N

NN

N

SO3H

HO3S

SO3H

SO3HMnCl

CAS No.FormulaM.W.

CAS No.FormulaM.W.

: : :

: : :

90384-82-0C44H28ClFeN4O12S4

1024.27 g/mole

221176-50-7 C44H28ClMnN4O12S4

1023.36 g/mole

Iron(III) meso-tetra(4-sulfonatophenyl)porphine chloride (acid form)

Manganese(III) meso-tetra(4-sulfonatophenyl)porphine chloride (acid form)

LT-D0063

LT-D0064



Ph

oto

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evice


212

CAS No.FormulaM.W.

CAS No.FormulaM.W.

CAS No.FormulaM.W.

: : :

: : :

: : :

22112-80-7C48H38N4O8

798.84 g/mole

71410-72-5C42H28N6

616.71 g/mole

116206-75-8C44H32N6

644.77 g/mole

meso-Tetra(3-methoxy-4-hydroxyphenyl) porphine

5,15-Diphenyl-10,20-di(4-pyridyl)-21H,23H-porphine

5,15-Di(4-aminophenyl)-10,20-diphenyl porphine


: : : ::

36951-72-1> 97% (HPLC)C72H66N8O12S4

1363.6 g/mole421 nm

meso-Tetra (N-methyl-4-pyridyl) porphine tetratosylate

HN

NNH

N

OHH3CO

OHOCH3

OH

OCH3

HO

H3CO

HN

NNH

N

N+

N+

N+N+

CH3

SO3-

4

HN

NNH

N

N

N

HN

NNH

NNH2H2N

LT-D0065

LT-D0068

LT-D0069

LT-D0066

HN

NNH

N

H3CO OCH3

OCH3

OCH3

OCH3H3CO

H3CO

H3CO


: : : :

74684-34-7 > 95% (HPLC)C52H46N4O8

854.96 g/mole

5,10,15,20-Tetrakis(3,5-dimethoxyphenyl)porphyrin

LT-D0074


: : : :

166174-13-6> 96% (HPLC)C76H44N4Pt1208.27 g/mole

N

NN

NPt

Platium(II) tetraphenyl naphtholporphyrin

LT-N760 PtTPNP



Ph

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Porphyrins

213


: : : :

173613-63-3> 97% (HPLC)C48H54N4

686.97 g/mole

N

NH

HN

N

N

NH N

HN

CAS No.FormulaM.W.

: : :

52952-31-5C36H22N4

510.59 g/mole

Tetrabenzoporphine

5,15-Bis[3,5-di(tert-butyl)phenyl]porphyrin

LT-S9044

K0485



Ph

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Photonic and Optical DevicePhthalocyanines

214





CAS No.GradeFormulaM.W.PL

: : : ::

: : : :::

: : : :::

: : : :::

: : : ::

14075-08-2Sublimed productC32H16N8Pt707.6 g/mole314, 684 nm (in CH2Cl2)

574-93-6Sublimed productC32H18N8 514.54 g/mole268 nm (in CH2Cl2) 415 nm (in CH2Cl2)

147-14-8Sublimed productC32H16CuN8

576.08 g/mole345, 631 nm (in CH2Cl2) 404 nm (in film)

26201-32-1Sublimed productC32H16N8OTi576.39 g/mole692 nm392 (in film)

14320-04-8Sublimed productC32H16N8Zn577.92 g/mole534 nm (in CH2Cl2)

Phthalocyanine, platium complex

Phthalocyanine


Titanium oxide phthalocyanine

Zinc phthalocyanine

HN

N

NN

N

NHN

N

N

N

NN

N

NN

NCu

N

N

N

N

N

N

N

N TiO

N

N

NN

N

NN

NZn


: : : ::

14916-87-1Sublimed productC32CuF16N8

863.93 g/mole690 nm (in THF)

Copper(II) 1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25- hexadecafluoro- 29H,31H-phthalocyanine

N

N

NN

N

NN

N

Cu

F

F

F

F

F

F

F

F

F

F

F

FF

F

F

F

N

NN

N

N

N

N

NPt

LT-N219 LT-E206

LT-S906

LT-S928

LT-N222

LT-E201

PtPC TiOPC

ZnPC

F16CuPC

H2PC

CuPC



Ph

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Phthalocyanines

215







: : : ::

: : : :::

: : : ::

: : : ::

: : : ::

: : : ::

14154-42-8Sublimed productC32H16AlClN8

574.97 g/mole675 nm (in DMF)

36530-06-0Sublimed productC24H12BN6Cl430.66 g/mole565 nm (in DMF)577 nm (in DMF)

153151-22-5> 98% (NMR)C80H112CuN8


142710-56-3Sublimed productC36H18BClN6


13930-88-6Sublimed productC32H16N8OV579.47 g/mole338, 684 nm (in CH2Cl2)

33273-09-5Sublimed productC48H24CuN8


Phthalocyanine chloroaluminum

Boron subphthalocyanine chloride

Boron sub-2,3-naphthalocyanine chloride

Oxyvanadium phthalocyanineCopper(II) 2,3-naphthalocyanine

Copper(II)-2,3,9,10,16,17,23,24-octa-n-hexyl-29H,31H-phthalocyanine

NN

NB N

N

N

Cl

NN

NB N

N

N

Cl

N

NN

N

N

N

N

NCu

N

NN

N

N

N

N

NCu

C6H13

C6H13

C6H13

C6H13

C6H13

C6H13 C6H13

C6H13

N

N

NN

N

NN

NAlCl

N

NN

N

N

N

N

NVO

LT-S943 LT-S963

LT-S9025

LT-S9053

LT-S947

LT-S962

SubPC CuPC-8H

AlPCCI

VOPc

SubNC

CuNC



Ph

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216



: : : :

: : : :

3317-67-7Sublimed productC32H16CoN8

571.47 g/mole

15304-57-1 Sublimed productC32H16N8Sn631.25 g/mole

Cobalt(II) phthalocyanine

Tin(II) phthalocyanine

N

N

NN

N

NN

NCo





: : : ::

: : : ::

: : : ::

: : : ::

25510-41-2Sublimed productC32H16Li2N8


25476-27-1Sublimed productC32H16Na2N8

558.52 g/mole656, 692 nm (in CHCl3)

15187-16-3> 99%C32H16N8Pb719.74 g/mole698 nm (in DMF)

1661-03-6Sublimed productC32H16N8Mg536.84 g/mole668 nm (in DMF)

Dilithium phthalocyanine

Disodium phthalocyanine

Lead(II) phthalocyanine

Magnesium(II) phthalocyanine

N

N

NN

N

NN

NLi2

N

N

NN

N

NN

N

Na2

N

N

NN

N

NN

N

Pb

N

N

NN

N

NN

NMg

N

N

NN

N

NN

NSn

LT-D2001 LT-D2006

LT-S9086

LT-D2008

LT-D2009

LT-D2002

LT-D2003

LT-D2004

CoPC MgPC

SnPC

SnCl2PC

FePC

Li2PC

Na2PC

PbPC


: : : :

18253-54-8Sublimed productC32H16Cl2N8Sn702.15 g/mole

Tin(IV) phthalocyanine dichloride


: : : ::

132-16-1Sublimed productC32H16FeN8


Iron(II) phthalocyanine

N

N

NN

N

NN

N

Fe

N

N

NN

N

NN

N

SnCl

Cl



Ph

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Phthalocyanines

217



: : : :

: : : :

148651-60-9Sublimed productC32H8CuF8N8

720.01 g/mole

33308-41-7> 96% (with isomers)C32H18N8O12S4

834.79 g/mole

Copper(II) 2,3,9,10,16,17,23,24-octafluorophthalocyanine

Phthalocyanine tetrasulfonic acid


: : : ::

39001-64-4 Sublimed productC48H48CuN8


Copper(II) 2,9,16,23-tetra-tert-butylphthalocyanine

N

N

NN

N

NN

N

Cu

F

F

F

F

F

F

F

F

N

N

NN

N

NN

NCu

C(CH3)3

C(CH3)3

(H3C)3C

(H3C)3C

HN

N

NN

N

NHN

N

SO3H

SO3H

HO3S

HO3S

N

N

NN

N

NN

N

Zn

SO3H

HO3S

HO3S

SO3H



: : : :

: : : :

61586-86-5> 96% (with isomers)C32H16N8O12S4Zn 898.19 g/mole

82800-48-4> 99%C64H32N16Sm 1175.41 g/mole

Zinc(II) phthalocyanine tetrasulfonic acid

N

N

NN

N

NN

NAlCl

SO3H

HO3S

HO3S

SO3H

GradeFormulaM.W.

: ::

> 96% (with isomers)C32H16AlClN8O12S4

895.21 g/mole

Aluminum(III) phthalocyanine chloride tetrasulfonic acid

Bis{2(3),9(10),16(17),23(24)-tetrakis-(3,4-phenyl)phthalocyaninato}Samarium(III)

LT-D2010 LT-D2013

LT-D2014

LT-D2015

LT-D2011

LT-D2012

2,3-F8CuPC

SmPC2

Reference : Inorganica Chimica Acta (2007), 360(1), 122-130

NN

N

N

N

NN

N

NN

N

N

N

NN

N

Sm



Ph

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218





: : : :::

: : : :::

: : : :::

: : : :::

1120355-28-3 Sublimed, > 99%C32H12F4N8Zn834.79 g/mole681, 725 nm (in CHCl3)> 300 °C (0.5% weight loss)


19631-19-7Sublimed, > 99%C32H16ClInN8


23844-93-1Sublimed, > 99%C32F16FeN8


Zinc(II)-1,8,15,22-tetrafluoro-29H ,31H-phthalocyanin,mixture of isomers

Zinc(II)-2,3,9,10,16,17,23,24-octafluoro-29H ,31H-phthalocyanin



LT-S9171

LT-S9172

LT-S9176

LT-S9177F4ZnPc

F8ZnPc

InClPC

F16FePC

Reference :

Reference :

Reference :

Reference : Solar Energy Materials & Solar Cells (2013), 118, 165-170


Organic Electronics (2015), 17, 229-239

Nano Letters (2014), 14(10), 5547-5554

N

NN

N

N

N

N

NZn

F

F

F

F

N

NN

N

N

N

N

N

F

F

F

F F

F

F

F

Zn

N

NN

N

N

N

N

NInCl

N

NN

N

N

N

N

NInCl


: : : ::

26857-61-4Sublimed, > 99%C48H24Cl2N8Sn902.37 g/mole> 300 °C (0.5% weight loss)

Tin(IV) 2,3-naphthalocyanine dichloride

LT-S9180 SnNCCl2


N

NN

N

N

N

N

NSnCl

Cl


: : : ::

110479-58-8 Sublimed, > 99%C48H24N8Sn831.47 g/mole> 300 °C (0.5% weight loss)

Tin(II) 2,3-naphthalocyanine

LT-S9182 SnNC

Reference : Journal of Physical Chemistry A (2011), 115(33), 9265-9272

N

NN

N

N

N

N

NSn



Ph

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Near-Infrared (NIR) Dyes

219

LT-D1233 LT-D1237

LT-D1238

LT-D1240

LT-D1241

LT-D1234

LT-D1235

LT-D1236

LDS 730 HIDC iodide

HITC iodide

HITC perchlorate

LDS 798

LDS 798



: : : :::

: : : :::

76433-27-7> 97% (HPLC)C23H27N2.ClO4

430.93 g/mole603 nm (in MeOH)668 nm (in MeOH)

89872-07-1> 97% (HPLC)C25H25N2S.ClO4

484 g/mole572 nm (in MeOH)704 nm (in MeOH)

2-[4-[4-(Dimethylamino)phenyl]-1,3-butadienyl]-1,3,3- trimethyl-3H-indolium perchlorate

2-[4-[4-(Dimethylamino)phenyl]-1,3-butadienyl]-3-ethyl-naphtho[2,1-d ]thiazolium perchlorate

ClO4-N+

N

NS

N+

ClO4-


: : : ::

385437-35-4> 95% (HPLC)C31H35N2S.ClO4

567.15 g/mole651 nm (in EtOH)

2-(6-(9-(2,3,6,7-Tetrahydro-1H,5H-benzo(i,j )quinolizinium)))-2,4-neopentylene-1,3,5-hexatrienyl)-3-methylbenzothiazoliumperchlorate

ClO4-

S

N+

N


: : : :: :

15185-43-0> 97% (HPLC)C25H25N2O2.I512.38 g/mole686 nm (in EtOH)726 nm (in EtOH)

3,3'-Diethyl-2,2'-oxathiacarbocyanine iodide

N+

I-N

O

N+ N

O

I-


: : : :::

36536-22-8> 98% (HPLC)C27H31IN2

510.45 g/mole643 nm (in EtOH)670 nm (in EtOH)

1,1',3,3,3',3'-Hexamethylindodicarbocyanine iodide


: : : :: :

19764-96-6 > 97% (HPLC) C29H33IN2 536.49 g/mole751 nm (in DMSO)792 nm (in DMSO)

1,1',3,3,3',3'-Hexamethylindotricarbocyanine iodide

N+ NH3C

H3C CH3H3C CH3

CH3 I-


: : : :: :

92479-59-9> 97% (HPLC)C23H25N2.ClO4


4-(4-(4-(Dimethylamino)phenyl)-1,3-butadienyl)-1-ethylquinolinium perchlorate

ClO4-

N

N+Et


: : : :: :

16595-48-5> 97% (HPLC)C29H33N2.ClO4

509.04 g/mole750 nm (in DMSO)790 nm (in DMSO)

1,1',3,3,3',3'-Hexamethylindotricarbocyanine perchlorate

N+ NH3C

H3C CH3H3C CH3

CH3

ClO4-



Ph

oto

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evice

Photonic and Optical DeviceNear-Infrared (NIR) Dyes

220


: : : :: :

3071-70-3> 98% (HPLC)C25H25IN2S2 544.51 g/mole761 nm (in EtOH)813 nm (in EtOH)

3,3'-Diethylthiatricarbocyanine iodide


: : : :: :

3599-32-4> 90% (NMR)C43H47N2NaO6S2 774.96 g/mole795 nm (in DMSO)832 nm (in DMSO)

Sodium 2-(7-(3,3-dimethyl-1-(4-sulfonatobutyl)benz(e )indolin-2-ylidene)hepta-1,3,5-trien-1-yl)-3,3-dimethyl-1-(4-sulfonatobutyl)benz[e]indolinium

S

N+ N

S

I-

N+ N

S SO

OO-

O

ONaO



: : : :: :

: : : :: :

56289-67-9> 98% (HPLC)C32H36ClIN2


102185-03-5 > 98% (HPLC)C32H36Cl2N2O4 583.55 g/mole775 nm (in MeOH)817 nm (in MeOH)

2-[2-[2-Chloro-3-[(1,3-dihydro-1,3,3-trimethyl-2H-indol-2-ylidene) ethylidene]-1-cyclohexen-1-yl]ethenyl]-1,3,3-trimethylindolium iodide

2- (2- [2- Chloro- 3- ([1,3- dihydro- 1,3,3- trimethyl- 2H- indol- 2- ylidene] ethylidene) - 1- cyclohexen- 1- yl] ethenyl) - 1,3,3- trimethylindolium perchlorate

N+ N

Cl

I-

N+ N

Cl

ClO4-


: : : :: :

207399-07-3> 98% (HPLC)C36H44ClIN2


2-[2-[2-Chloro-3-[(1,3-dihydro-3,3-dimethyl-1-propyl-2H-indol-2-ylidene)ethylidene]-1-cyclohexen-1-yl]ethenyl]-3,3-dimethyl-1-propylindolium iodide

N+ N

Cl

I-

LT-D1242

LT-D1248

LT-D1249

LT-D1250

LT-D1243

DTTC iodide

IR-786

IR-786 perchlorate

IR-780 iodide

Indocyanine green



Ph

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Near-Infrared (NIR) Dyes

221

N+ NH3C

H3C CH3H3C CH3

CH3

ClO4-

N+ N

S SO

ONaO

O

O

-O

Cl

1,1',3,3,3',3'-4,4',5,5'-Di-benzo-2,2'-indotricarbocyanine perchlorate

CAS No.GradeFormulaUVPL

: : : ::

23178-67-8 > 98% (HPLC)C37H37ClN2O4 609.15 g/mole781 nm (in MeOH)

N+ N

S SO

ONaO

O

O

-O

Cl



: : : ::

: : : ::

115970-66-6 > 90% (HPLC)C38H46ClN2NaO6S2 749.35 g/mole782 nm (in MeOH)

172616-80-7 > 80% (HPLC) C46H50ClN2NaO6S2 849.47 g/mole820 nm (in MeOH)

2-[2-[2-Chloro-3-[2-[1,3-dihydro-3,3-dimethyl-1-(4-sulfobutyl)-2H-indol-2-ylidene]-ethylidene]-1-cyclohexen-1-yl]-ethenyl]-3,3-dimethyl-1-(4-sulfobutyl)-3H-indolium hydroxide, inner salt sodium salt

2-[2-[2-Chloro-3-[[1,3-dihydro-1,1-dimethyl-3-(4-sulfobutyl)-2H-benzo[e]indol-2-ylidene]-ethylidene]-1-cyclohexen-1-yl]-ethenyl]-1,1-dimethyl-3-(4-sulfobutyl)-1H-benzo[e ]indolium hydroxide inner salt, sodium salt


: : : :: :

89846-21-9> 97% (HPLC)C19H23N2.ClO4


4-[4-(4-Dimethylaminophenyl)-1,3-butadienyl]-1- ethylpyridinium perchlorate

ClO4-

N

N+Et

LT-D1261 LT-D1264

LT-D1262

LT-D1263

HDITC perchlorate Pyridine 2

IR-783

IR-820



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Fluorescent ProbesContents

222

• Introduction --------------------------------------------------------------------223

• Popular Stains, Dyes and Fluorescent Probes (34) ----------------------------225

• pH Indicators (9) ---------------------------------------------------------------230

• Mitochondrial Staining (8) -----------------------------------------------------232

• ROS Probes (4) -----------------------------------------------------------------234

• Histological Staining (5) -------------------------------------------------------235

• Neurological Staining (4) ------------------------------------------------------236

• Intracellular Staining (3) -------------------------------------------------------237

• Protein and Antibody Labeling (9) --------------------------------------------238

• Peptide and Nucleotide Labeling (6) ------------------------------------------240

• Calcium Probes (4) -------------------------------------------------------------241

• Nucleus and Nucleolus Staining (5) -------------------------------------------242

• Fluorogenic Substrates (9) -----------------------------------------------------243

• Membrane Staining (4) --------------------------------------------------------245

• Bacterial Staining (2) -----------------------------------------------------------246

• Cytoskeleton Staining (2) ------------------------------------------------------246

• Protein Staining (4) ------------------------------------------------------------247

• Nucleic Acid Staining (2) -------------------------------------------------------248

• Lipid Labeling (2)---------------------------------------------------------------248

• Chromogenic Substrates (3) ---------------------------------------------------249

• Thiol-Reactive (4) --------------------------------------------------------------249

• Additional Stains, Dyes and Fluorescent Probes (54) -------------------------250



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Introduction

223

　A fluorophore is a fluorescent chemical compound that can re-emit light upon light excitation. Fluorophores typically contain several combined aromatic groups, or plane or cyclic molecules with several π bonds.

　Fluorophores are sometimes used alone, as a tracer in fluids, as a dye for staining of certain structures, as a substrate of enzymes, or as a probe or indicator, but more generally it is covalently bonded to a macromolecule, serving as a marker (or dye, or tag, or reporter) for affine or bioactive reagents (antibodies, peptides, nucleic acids). Fluorophores are notably used to stain tissues, cells, or materials in a variety of analytical methods, i.e. fluorescent imaging and spectroscopy.

　Labeling is one of the most common methodologies used for bioanalytical purposes, which can be carried out with radioactive materials or compounds with absorption and/or fluorescence from the ultraviolet to the near-infrared region of the electromagnetic spectrum.



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Fluorescent ProbesIntroduction

224

　Certain fluorescent reagents carry reactive groups for covalent attachment to target biomolecules and show minimal spectral sensitivity to environmental changes. These reagents are primary used to quantify the presence and distribution of probes and targets. The most well-known dyes of this type are derivatives of fluorescein and rhodamine (e.g., tetramethyl rhodamine, lissamine rhodamine, and sulforhodamine 101). A variety of reactive groups have been incorporated into these dyes permitting coupling of the dyes to different functionalities. Isothiocyanates, succinimidyl esters, and pentafluorophenyl esters couple with amino groups of target molecules, while haloacetamides, maleimides, and vinyl sulfones react with sulfhydryl groups. Dichlorotriazinyl (DCT) groups can couple effectively with both amines and alcohols,depending upon reaction pH and temperature. Reactivity and selectivity of the conjugation reactions can be manipulated by the reactive groups chosen and the conditions of the coupling reaction (e.g., reaction pH, solvent polarity, and temperature).



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Popular Stains, Dyes and Fluorescent Probes

225

LT-F0001

LT-F0005

LT-F0008

LT-F0006

LT-F0007

LT-F0002

LT-F0009

LT-F0004

Ru(bpy)2(mcbpy-O-Su-ester)(PF6)2

Fluorescein 5-isothiocyanate

N

N

N NH2

HCl

N+B-N

FF

NH

O

OO

NO

O

O

O

O

OO

OO

O

O

N

O

O

O

O

OHOHO

NCS

O NN

O

O

NCS


CAS No.FormulaM.W.

: : : :

: : :

553-24-2> 90%C15H17ClN4

288.78 g/mole

217190-09-5C24H29BF2N4O5

502.32 g/mole

3-Amino-7-dimethylamino-2-methylphenazine hydrochloride

3-Bodipy-propanoylaminocaproic acid,N-hydroxysuccinimide Ester


CAS No.FormulaM.W.UVPL


: : : :: :

: : : ::

: : : :: :

75168-11-5> 97%C26H38BrN3

472.50 g/mole496 nm in MeOH524 nm in MeOH

95197-95-8C25H21N3O3S443.52 g/mole529 nm in DMSO596 nm in DMSO

150347-59-4> 95% (HPLC)C29H19N2O11

557.46 g/mole492 nm in 0.1 M Tris pH 8.0 (esterase)517 nm in 0.1 M Tris pH 8.0 (esterase)

3,6-Bis(dimethylamino)-10-nonylacridinium bromide

Tetramethylrhodamine B isothiocyanate

5(6)-Carboxyfluorescein diacetate, NHS ester


: : : :: :

3326-32-7> 90% (HPLC)C21H11NO5S389.38 g/mole492 nm 518 nm

Fluorescein 5-isothiocyanate,with isomers

N+

C9H19

NNBr

N N

Ru N

N

N

N

OO

NO

O

Na+

O

OHO

OSO

OO-

CAS No.FormulaM.W.

: : :

130-22-3C14H7NaO7S342.26 g/mole

Sodium Alizarinesulfonate


: : : ::

136724-73-7C36H29N7O4Ru724.73 g/mole458 nm in 0.1 M phosphate pH 7.0628 nm in 0.1 M phosphate pH 7.0

Bis(2,2'-bipyridine)-4'-methyl-4-carboxybipyridine-ruthenium N-succinimidyl ester-bis(hexafluorophosphate)



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Fluorescent ProbesPopular Stains, Dyes and Fluorescent Probes

226

LT-F0012

LT-F0013

LT-F0014

LT-F0015

LT-F0010

LT-F0011


: : : :: :

26093-31-2> 98%C10H9NO2

175.18 g/mole365 nm in EtOH440 nm in EtOH

7-Amino-4-methylcoumarin

OO NH2


: : : :: :

90-33-5> 95%C10H8O3

176.17 g/mole372 nm in EtOH445 nm in EtOH

4-Methylumbelliferone

NH2


: : : :

72252-90-5> 95%C31H41N5O9

627.69 g/mole

Methyl 4-((S)-1-((S)-1-((S)-2-((S)-3-methyl-1-(4-methyl-2-oxo-2H-chromen-7-ylamino)-1-oxobutan-2-ylcarbamoyl)pyrrolidin-1-yl)-1-oxopropan-2-ylamino)-1-oxopropan-2-ylamino)-4-oxobutanoate

O

HN

O

ONH

ON

ONH

O

NHO

O O

O OHO


: : : :

93324-65-3> 95%C17H13N231.29 g/mole

1-Pyrenemethylamine hydrochloride


PL

: : : :: :

142978-18-5> 97%C16H16N2O2

268.31 g/mole433 nm in 50mM Tris pH 8.0 ;40% glycerol500 nm in 50mM Tris pH 8.0 ;40% glycerol

9-(2-Carboxy-2-cyanovinyl)julolidine

NC18H37

N+

C18H37ClO4


: : : :: :

41085-99-8> 97%C59H97Cl2N2O4


1,1'-Dioctadecyl-3,3,3',3'-tetramethylindocarbocyanine perchlorate

N

CN

O OH


: : : :: :

2044-85-1> 95%C24H14Cl2O7


2',7'-Dichlorofluorescein diacetate

O

O

O

ClCl

OO

O

O

LT-F0016



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227


: : : :: :

117464-70-7> 90%C42H40O21

880.75 g/mole505 nm in DMSO520 nm in DMSO

3',6'-Bis(acetyloxy)-5(or 6)-[[(acetyloxy)methoxy]carbonyl]-3 -oxo-spiro[isobenzofuran-1(3H ),9'-[9H ]xanthene]-2',7 '-dipropanoic acid 2',7'-bis[(acetyloxy)methyl] ester


: : : :

27072-45-3> 90% (HPLC)C21H11NO5S389.38 g/mole

3',6'-dihydroxy-5(6)-isothiocyanato-3H-spiro[isobenzofuran-1,9'-xanthen]-3-one

O

O

O N

OHHO

C S


PL

: : : :: :

75350-46-8> 90%C24H13NO7

427.36 g/mole492 nm in 0.1 M Tris pH 9.0,2-mercaptoethanol518 nm in 0.1 M Tris pH 9.0,2-mercaptoethanol

1-(3',6'-dihydroxy-3-oxo-3H-spiro[isobenzofuran-1,9'-xanthene]-5-yl)-1H-pyrrole-2,5-dione, with isomers

O

O

O OHHO

N

O

O




: : : :: :

: : : :: :

: : : :: :

76863-28-0> 80%C21H15N3O5S421.43 g/mole492 nm in 0.1 M Tris pH 9.0516 nm in 0.1 M Tris pH 9.0

23491-52-3> 98% (HPLC)C27H31Cl3N6O561.93 g/mole346 nm460 nm

157134-53-7> 95%C36H52N2O3S592.87 g/mole498 nm in DMSO713 nm in DMSO

5-(Hydrazinecarbothioamido)-2-(6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid, with isomers

2'-(4-Ethoxyphenyl)-5-(4-methylpiperazin-1-yl)-1H ,1'H-2,5'-bibenzo[d]imidazole

4-(2-[6-(Dioctylamino)-2-naphthalenyl]ethenyl)-1-(3-sulfopropyl)pyridinium inner salt

O OHO

HN S

HNNH2

COOH

N

NH

N

NH

N

NO

3HCl

N+ SO

O

O-

N

LT-F0019

LT-F0020

LT-F0021

LT-F0022

LT-F0017

LT-F0018

Fluorescein 5(6)-isothiocyanate

Fluorescein-5-thiosemicarbazide

Hoechst 33342 trihydrochloride

BCECF/AM

Fluorescein 5-Maleimide

O

O

O

OO

OO

O

O

O

O

O

O

O

O

O

O

O

O

O

O



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Fluorescent ProbesPopular Stains, Dyes and Fluorescent Probes

228


: : : ::

6226-79-5> 90%C22H12N4Na4O13S4

760.57 g/mole518-522 nm in H2O

3-Hydroxy-4-(2-sulfo-4-[4-sulfophenylazo]phenylazo)-2,7-naphthalenedisulfonic acid sodium salt

6,6-[(3,3'-Dimethyl[1,1'-biphenyl]-4, 4'-diyl)bis(azo)bis[4-amino- 5-hydroxy-1,3-naphthalenedisulphonic acid] tetrasodium salt


: : : :

314-13-6> 75%C34H24N6Na4O14S4

960.81 g/mole

H2NHO

S

S

NO

ONaO

OO

ONa

NNN

OHNH2

S

S

OO

ONa

OO

NaO

N

HO

N

SO3Na

SO3Na

NN

NaO3SSO3Na

LT-F0023

LT-F0026

LT-F0027

LT-F0028

LT-F0024

Evans Blue 7-Ethoxyresorufin


: : : :: :

5725-91-7> 98%C14H11NO3

241.24 g/mole464 nm in MeOH 540 nm in MeOH

7-Ethoxy-3H-phenoxazin-3-one



: : : :: :

: : : :: :

59323-54-5> 97%C16H9NaO3S304.30 g/mole314 nm in MeOH 376 nm in MeOH

59572-10-0> 98% (HPLC)C16H6Na4O12S4.XH2O610.43 g/mole454 nm in H2O511 nm in H2O

1-Pyrenesulfonic acid sodium salt

1,3,6,8-Pyrenetetrasulfonic acid tetrasodium salt hydrate

SO3Na

SO3Na

NaO3S

SO3Na

SO3Na

xH2O

OO

N

O


: : : :

109244-58-8> 95%C21H18N2O3

346.38 g/mole

Methyl 2-(3,6-diamino-9H-xanthen-9-yl)benzoate

FormulaM.W.UVPL

: : : :

C60H70N11O14S1201.33 g/mole546 nm575 nm

Phalloidin-tetramethylrhodamine Conjugate

H2N O NH2

O

O

ON N

COOH

ONH

HN

OHO NH

HN

OOH

NH

N

O

HO

SNH

NHO

O

NH

O

O

LT-F0029

LT-F0030

Dihydrorhodamine 123



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229



: : : :: :

: : : :

62669-70-9> 95%C21H17ClN2O3


989-38-8> 95%C28H31ClN2O3

479.01 g/mole

Methyl 2-(6-amino-3-imino-3H-xanthen-9-yl)benzoate hydrochloride

Eethyl 2-(6-(ethylamino)-3-(ethylimino)-2,7-dimethyl-3H-xanthen-9-yl)benzoate hydrochloride

O

O

O

H2N NH

HCl

O

OO

HN N

HCl



: : : :: :

: : :: :

81-88-9> 95% (HPLC)C28H31ClN2O3

479.01 g/mole554 nm in Acidic EtOH627 nm in Acidic EtOH

> 95%C29H38N2O3S494.69 g/mole498 nm (in DMSO)713 nm (in DMSO)

N-(9-(2-Carboxyphenyl)-6-(diethylamino)-3H-xanthen-3-ylidene)-N-ethylethanaminium chloride

1-(4-sulfonatobutyl)-4-[β-[2-(di-n-but ylamino)-6-naphthyl]vinyl]pyridinium betaineCAS No.



: : : :: :

: : : ::

60311-02-6> 98%C31H30N2O7S2

606.71 g/mole585 nm in H2O605 nm in H2O

116450-56-7C32H30N2O3


Sulforhodamine 101

Rhodamine 101 Inner Salt

O

SO

O-O

NN+

HO3S

O

CO

-O

NN+

O

OHO

N N+

Cl-

LT-F0032

LT-F0033

LT-F0034

LT-F0035

LT-F0103

LT-F0031

Rhodamine 6G

Sulforhodamine 101

Rhodamine B

Rhodamine 123

N N SO3



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Fluorescent ProbespH Indicators

230

N

N

N NH2

HCl


: : : :

553-24-2> 90%C15H17ClN4

288.78 g/mole

3-Amino-7-dimethylamino-2-methylphenazine hydrochloride

Na+

O

OHO

OSO

OO-

CAS No.FormulaM.W.

: : :

130-22-3C14H7NaO7S342.26 g/mole



: : : :: :

575-03-1> 99%C10H5F3O3


7-Hydroxy-4-(trifluoromethyl)coumarin

OO

FFF

OH


: : : :: :

117464-70-790%C42H40O21




: : : :: :

76823-03-5> 95% (HPLC)C21H12O7

376.32 g/mole492 nm in 0.1 M Tris pH 8.0517 nm in 0.1 M Tris pH 8.0

3',6'-Dihydroxy-3-oxo-3H-spiro[isobenzofuran-1,9'-xanthene]-5-carboxylic acid, with isomers

O

O

HO O OH

OHO


: : : ::

76-59-5> 95%C27H28Br2O5S624.38 g/mole420 nm

3',3'-Dibromothymolsulfonphthalein

OS O

O

HO

OH

Br

Br


: : : :

143-74-8> 95%C19H14O5S354.38 g/mole

Phenolsulfonphthalein

O S OO

HO

HO


: : : :: :

59572-10-0> 98% (HPLC)C16H6Na4O12S4 XH2O610.43 g/mole454 nm in H2O511 nm in H2O

1,3,6,8-Pyrenetetrasulfonic acid tetrasodium salt hydrate

SO3Na

NaO3S

SO3Na

SO3Na

xH2O

LT-F0001

LT-F0037

LT-F0027

LT-F0038

LT-F0039

LT-F0009

LT-F0036

LT-F0017

5-Carboxyfluorescein

Bromothymol Blue

Phenol Red

BCECF/AM

‧

O

O

O

OO

OO

O

O

O

O

O

O

O

O

O

O

O

O

O

O



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pH Indicators

231


: : : ::

27928-00-3C16H7Na3O10S3

524.39 g/mole454 nm in H2O 520 nm in H2O

8-Hydroxypyrene-1,3,6-trisulfonic acid, trisodium salt

OH

NaO3S

SO3Na

SO3Na

LT-F0040



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Fluorescent ProbesMitochondrial Staining

232


: : : :: :

75168-11-5> 97%C26H38BrN3


3,6-Bis(dimethylamino)-10-nonylacridinium bromide


: : : ::

2869-83-2> 65%C30H31ClN6

511.06 g/mole395, 660 nm

3-(Diethylamino)-7-((4-(dimethylamino)phenyl)diazenyl)-5-phenylphenazin-5-ium chloride

N+

N

NN

N

NCl-

3,6-Bis(diethylamino)-9-(2-((4-methyl-2-oxo-2H-chromen-7-yloxy)carbonyl)phenyl)xanthylium chloride


: : : ::

> 70% (HPLC)C38H37ClN2O5



: : : :: :

53213-82-4> 98%C29H37IN2O2


3,3'-Dihexyloxacarbocyanine Iodide

NO

N+

O

I-


: : : :

109244-58-8> 95%C21H18N2O3

346.38 g/mole

Methyl 2-(3,6-diamino-9H-xanthen-9-yl)benzoate

H2N O NH2

O

O


: : : :: :

62669-70-9> 95%C21H17ClN2O3


Methyl 2-(6-amino-3-imino-3H-xanthen-9-yl)benzoate hydrochloride

N+

C9H19

NNBr

O

O

O

H2N NH

HCl

O+

OO

O

NN

O

Cl-


: : : :

989-38-8> 95%C28H31ClN2O3

479.01 g/mole

Eethyl 2-(6-(ethylamino)-3-(ethylimino)-2,7-dimethyl-3H-xanthen-9-yl)benzoate hydrochloride

O

OO

HN N

HCl

LT-F0002

LT-F0029

LT-F0031

LT-F0032

LT-F0041

LT-F0042

LT-F0043

Dihydrorhodamine 123

Rhodamine 123

Rhodamine 6G

Janus Green B

Mito Red



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Mitochondrial Staining

233


: : : :: :

115532-52-0> 90% C26H27ClN2O7


3,6-Bis(dimethylamino)-9-(2-(ethoxycarbonyl)phenyl)xanthylium perchlorate

O+

OO

NN

ClO4-

LT-F0044



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Fluorescent ProbesROS Probes

234


: : : :

10510-77-7> 95%C16H20N2O4S336.41 g/mole

5-Ethyl-5,10-dihydrophenazin-5-ium ethyl sulfate

NH

NH

SO

O

O

O


: : : :: :

2044-85-1> 95%C24H14Cl2O7


2',7'-Dichlorofluorescein diacetate

O

O

O

ClCl

OO

O

O


: : : :: :

4091-99-0> 97%C24H16Cl2O7

487.29 g/mole502 nm523 nm

2-(3,6-Diacetoxy-2,7-dichloro-9H-xanthen-9-yl)benzoic acid

OH

O

O

ClCl

OO

O

O


: : : :: :

254109-22-3> 98% (HPLC)C25H18F2N2O7


4-Amino-2',7'-difluoro-5-(methylamino)-3-oxo-3H-spiro[isobenzofuran-1,9'-xanthene]-3',6'-diyl diacetate

O

O

O

O

O

O

O

FF

HN NH2

LT-F0045

LT-F0016

LT-F0046

LT-F0047 DAF-FM DA (cell permeable)



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Histological Staining

235

LT-F0041

LT-F0048

LT-F0009 LT-F0049

LT-F0039

Janus Green B

Naphthol Blue Black

Phenol Red


: : : ::

2869-83-2> 65%C30H31ClN6

511.06 g/mole395, 660 nm


N+

N

NN

N

NCl-

Na+

O

OHO

OSO

OO-

CAS No.FormulaM.W.

: : :

130-22-3C14H7NaO7S342.26 g/mole



: : : :

1064-48-8> 85%C22H14N6Na2O9S2

616.49 g/mole

Sodium 4-amino-5-hydroxy-3-((4-nitrophenyl)diazenyl)-6-(phenyldiazenyl)naphthalene-2,7-disulfonate

NH2 OHN N

NaO3S SO3Na

N

NO2N

CAS No.FormulaM.W.

: : :

71-67-0C20H8Br4Na2O10S2

838.00 g/mole

Sulfobromophthalein disodium salt hydrate

O

O

HO OH

Br

SO3NaSO3Na

Br

Br

BrXH2OH


: : : :

143-74-8> 95%C19H14O5S354.38 g/mole


O S OO

HO

HO



Fluo

rescent P

rob

es

Fluorescent ProbesNeurological Staining

236


: : : ::

2869-83-2> 65%C30H31ClN6

511.06 g/mole395, 660 nm


N+

N

NN

N

NCl-


: : : :

576-19-2> 98% (TLC)C16H28N4O4S372.48 g/mole

(S)-2-Amino-6-(5-((3aS,4S,6aR )-2-oxohexahydro-1H-thieno[3,4-d ]imidazol-4-yl)pentanamido)hexanoic acid

NHHN

S

O

NH

O

NH2

OHO

HHNC18H37

N+

C18H37ClO4


: : : :: :

41085-99-8> 97%C59H97Cl2N2O4




: : : :: :

60311-02-6> 98%C31H30N2O7S2


Sulforhodamine 101

O

SO

O-O

NN+

HO3S

LT-F0041

LT-F0014 LT-F0050

LT-F0033

Janus Green B

ε-Biotinoyl-L-lysine

Sulforhodamine 101



Fluo

rescent P

rob


Intracellular Staining

237

LT-F0005

LT-F0017

LT-F0039

BCECF/AM

Phenol Red

O

O

O

OO

OO

O

O

N

O

O


: : : :: :

150347-59-4> 95% (HPLC)C29H19N2O11


5(6)-Carboxyfluorescein diacetate, NHS ester


: : : :: :

117464-70-7> 90%C42H40O21




: : : :

143-74-8> 95%C19H14O5S354.38 g/mole


O S OO

HO

HO

O

O

O

OO

OO

O

O

O

O

O

O

O

O

O

O

O

O

O

O



Fluo

rescent P

rob

es

Fluorescent ProbesProtein and Antibody Labeling

238

N N

Ru N

N

N

N

OO

NO

O


: : : ::

136724-73-7C36H29N7O4Ru724.73 g/mole458 nm in 0.1 M phosphate pH 7.0628 nm in 0.1 M phosphate pH 7.0

Bis(2,2'-bipyridine)-4'-methyl-4-carboxybipyridine-ruthenium N-succinimidyl ester-bis(hexafluorophosphate)

: : : :: :

117548-22-8> 80% (HPLC)C25H15NO9

473.39 g/mole492 nm in DMF517 nm in DMF

O

O

N

O

O

HO

O

OH

O

O


PL

: : : :: :

142978-18-5> 97%C16H16N2O2



N

CN

O OH



: : : :: :

76823-03-5> 97% (HPLC)C21H12O7



1-(3',6'-dihydroxy-3-oxo-3a,4-dihydro-3H-spiro[isobenzofuran-1,9'-xanthene]-5-yl)-1H-pyrrole-2,5-dione

O

O

HO O OH

OHO


PL

: : : :: :

75350-46-8> 90%C24H13NO7


1-(3',6'-dihydroxy-3-oxo-3H -spiro[isobenzofuran-1,9'-xanthene]-5-yl)-1H -pyrrole-2,5-dione, with isomers

O

O

O OHHO

N

O

O


: : : :: :

5725-91-7> 98%C14H11NO3

241.24 g/mole464 nm in MeOH 540 nm in MeOH

7-Ethoxy-3H-phenoxazin-3-one

OO

N

O

LT-F0008 Ru(bpy)2(mcbpy-O-Su-ester)(PF6)2

LT-F0015

LT-F0018

LT-F0028

LT-F0037

LT-F0051


7-Ethoxyresorufin



: : : ::

53518-15-3> 98%C10H6F3NO2

229.16 g/mole207 nm

7-Amino-4-trifluoromethylcoumarin

OO

FFF

NH2

LT-F0052



Fluo

rescent P

rob


Protein and Antibody Labeling

239


: : : :: :

63368-54-7> 95% (HPLC)C22H14INO6

515.25 g/mole492 nm (Mercaptoethanol adduct)515 nm (Mercaptoethanol adduct)

N-(3',6'-dihydroxy-3-oxo-3H-spiro[isobenzofuran-1,9'-xanthene]-5-yl)-2-iodoacetamide, with isomers

O

O

HO O OH

O

HN

I


: : : ::


N-(Aminoethyl)-5-naphthylamine-1-sulfonic Acid

HN

SO

OHONH2

LT-F0053

LT-F0054

5-(Iodoacetamido)fluorescein



Fluo

rescent P

rob

es

Fluorescent ProbesPeptide and Nucleotide Labeling

240


: : : ::

194785-18-7C33H30N2O5


6-Carboxy-X-rhodamine

O+N N

-O

O

O

OH


PL

: : : ::

:

10199-89-0> 99% (HPLC)C6H2N3ClO3

199.55 g/mole336 nm in MeOH; 420 nm in EtOH (after derivatization with glycine)~540 nm in EtOH(after derivatization with glycine)

4-Chloro-7-nitrobenzofurazan

NO

N

NO2Cl


: : : :: :

72088-94-9> 95% (HPLC)C21H12O7


3',6'-Dihydroxy-3-oxo-3H-spiro[isobenzofuran-1,9'-xanthene]-5(6)-carboxylic acid

O

O

O

HO OH

HO O


: : : :: :

76823-03-5> 97% (HPLC)C21H12O7


3',6'-Dihydroxy-3-oxo-3H -spiro[isobenzofuran-1,9'-xanthene]-5-carboxylic acid, with isomers

O

O

HO O OH

OHO


: : : ::


N-(Aminoethyl)-5-naphthylamine-1-sulfonic acid

HN

SO

OHONH2


PL

: : : :: :

75350-46-8> 90%C24H13NO7



O

O

O OHHO

N

O

O

LT-F0018 LT-F0055

LT-F0056

LT-F0057

LT-F0037

LT-F0054


5(6)-Carboxyfluorescein




Fluo

rescent P

rob


Calcium Probes

241


: : : :

6409-77-4> 96%C14H8NNaO7S357.27 g/mole

4-Amino-9,10-dihydro-1,3-dihydroxy-9,10-dioxo-2-anthracenesulfonic acid sodium salt

SO

O

ONa

O

O

OH

OH

NH2

3,6-Bis((2-arsonophenyl)diazenyl)-4,5-dihydroxynaphthalene-2,7-disulfonic acid


: : : :

1668-00-4C22H18As2N4O14S2

776.37 g/mole530 nm

OH OHN N

HO3S SO3H

N

NAsO3H2

AsO3H2


: : : :

165660-27-5C20H12N2Na2O11S3

598.49 g/mole650 nm

Sodium(E)-3-hydroxy-4-((2-hydroxy-6-sulfo-3-sulfonatonaphthalen-1-yl)diazenyl)naphthalene-1-sulfonate

N

HO

N

S OHO

OOHNaO3S

SO3Na


: : : :: :

129787-64-0> 90%C52H59BrN4O19


N -(9-(4-(bis(2-(acetoxymethoxy)-2-oxoethyl)amino)-3-(2-(2-(bis(2-(acetoxymethoxy)-2-oxoethyl)amino)-5-methylphenoxy)ethoxy)phenyl)-6-(dimethylamino)-3H-xanthen-3-ylidene)-N-methylmethanaminium bromide

O NN+

NO

O

OOO

O

N

O

O

O O

O

O

O

O

O

OBr-

OO

LT-F0058 LT-F0061

LT-F0059

LT-F0060

RHOD 2/AM

Arsenazo III

Hydroxy naphthol blue disodium salt



Fluo

rescent P

rob

es

Fluorescent ProbesNucleus and Nucleolus Staining

242



: : : ::

: : : :

632-69-9> 85%C20H2NCl4I4Na2O5

1017.64 g/mole549 nm

76877-33-3> 95% (HPLC)C24H22N2O4

402.44 g/mole

Sodium 2,3,4,5-tetrachloro-6-(2,4,5,7-tetraiodo-6-oxido-3-oxo-3H-xanthen-9-yl)benzoate

1-(4-(7-(Diethylamino)-4-methyl-2-oxo-2H-chromen-3-yl)phenyl)-1H-pyrrole-2,5-dione

Na+

Na+

O

O-

O O-O

I

I I

I

ClCl

Cl

Cl


: : : :

6409-77-4> 96%C14H8NNaO7S357.27 g/mole


SO

O

ONa

O

O

OH

OH

NH2

OOO

O

NN


: : : :: :



N

NH

N

NH

N

NO

3HCl


: : : ::

76-59-5> 95%C27H28Br2O5S624.38 g/mole420 nm


OS O

O

HO

OH

Br

Br

LT-F0058

LT-F0038

LT-F0062

LT-F0063

LT-F0021

Bromothymol Blue

Rose Bengal Sodium Salt

Hoechst 33342 trihydrochloride



Fluo

rescent P

rob


Fluorogenic Substrates

243


: : : :

72252-90-5> 95%C31H41N5O9

627.69 g/mole

Methyl 4-((S)-1-((S)-1-((S)-2-((S)-3-methyl-1-(4-methyl-2-oxo-2H-chromen-7-ylamino)-1-oxobutan-2-ylcarbamoyl)pyrrolidin-1-yl)-1-oxopropan-2-ylamino)-1-oxopropan-2-ylamino)-4-oxobutanoate

O

HN

O

ONH

ON

ONH

O

NHO

O O

O OO

OHO

HOHO

NaO3SHN

4-Methylumbelliferyl 2-Sulfamino-2-deoxy-α-D-glucopyranoside Sodium Salt

CAS No.FormulaM.W.

: : :

460085-45-4C16H18NNaO10S439.37 g/mole


: : : :

133628-73-6> 98%C14H14N2O5

290.27 g/mole

L-Aspartic acid β-(7-amido-4-methylcoumarin)

OHNO

O

NH2

HO O


PL

: : : :: :

3368-04-5> 98%C10H9O6P256.15 g/mole319 nm (pH 9.1); 360 nm (Reaction product)384 nm (pH 9.1); 449 nm (Reaction product)

4-Methylumbelliferyl phosphate

PO

OOH

OHO O


PL

: : : :: :

62480-44-8C16H21ClN2O3

324.80 g/mole327 nm (pH 8.0); 380 nm (Reaction product)349 nm (pH 8.0); 440 nm (Reaction product)

L-Leucine 7-amido-4-methylcoumarin hydrochloride

O

NH

O

O

NH2HCl

3'-Butoxy-6'-hydroxy-3H-spiro[isobenzofuran-1,9'-xanthen]-3-one

CAS No.FormulaM.W.

: : :

335193-91-4C24H20O5

388.41 g/mole

O

O

O

HO O

LT-F0011 LT-F0067

LT-F0068

LT-F0069

LT-F0070

LT-F0064

LT-F0065

LT-F0066

N-Butylfluorescein

D-Luciferin sodium salt

C-6 NBD Ceramide


: : : :: :

103404-75-7> 95%C11H7N2NaO3S2


Sodium (S)-2-(6-hydroxybenzo[d]thiazol-2-yl)-4,5-dihydrothiazole-4-carboxylate

S

N

N

S

O

-OOH

Na+


: : : :: :

86701-10-2> 98%C30H49N5O6


N -((2S ,3S ,E )-1,3-dihydroxyoctadec-4-en-2-yl)-6-(7-nitrobenzo[c ][1,2,5]oxadiazol-4-ylamino)hexanamide

N

N

HN

O

NO2

HN

O

OH

OH



Fluo

rescent P

rob

es

Fluorescent ProbesFluorogenic Substrates

244


: : : :: :

101490-85-1> 90%C18H17NO8


7-((2S,3R ,4S,5S,6R )-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yloxy)-3H-phenoxazin-3-one

O O

N

O

OHHO

HOO

OH

LT-F0071 Resorufin β-D-glucopyranoside



Fluo

rescent P

rob


Membrane Staining

245

N

N+

SO

O-O

NC18H37

N+

C18H37ClO4



: : : :: :

: : : :: :

41085-99-8> 97 %C59H97Cl2N2O4


90134-00-2> 95% (HPLC)C28H36N2O3S480.66 g/mole497 nm in MeOH712 nm in MeOH


3-(4-(2-(6-(Dibutylamino)naphthalen-2-yl)vinyl)pyridinium-1-yl)propane-1-sulfonate


: : : :: :

53213-82-4> 98%C29H37IN2O2



NO

N+

O

I-


: : : :: :

157134-53-7> 95%C36H52N2O3S592.87 g/mole498 nm in DMSO713 nm in DMSO

4-(2-[6-(Dioctylamino)-2-naphthalenyl]ethenyl)-1-(3-sulfopropyl)pyridinium inner salt

N+ SO

O

O-

N

LT-F0014 LT-F0072

LT-F0022

LT-F0043

Di-4-ANEPPS



Fluo

rescent P

rob

es

Fluorescent ProbesBacterial Staining Cytoskeleton Staining

246


PL

: : : ::

:

905-96-4> 98%C21H21IN2O2

460.31 g/mole480 nm in EtOH; 444 nm in phosphate buffer/SDS 505 nm in EtOH; 512 nm in phosphate buffer/SDS

3,3'-Diethyloxacarbocyanine iodide

O

N+

N

O I


: : : ::

632-69-9> 85%C20H2NCl4I4Na2O5

1017.64 g/mole549 nm


Na+

Na+

O

O-

O O-O

I

I I

I

ClCl

Cl

Cl


: : : ::

635-78-9> 95%C12H7NO3

213.19 g/mole573 nm

7-Hydroxy-3H-phenoxazin-3-one

OO

N

OH

FormulaM.W.UVPL

: : : :

C60H70N11O14S1201.33 g/mole546 nm575 nm

Phalloidin-Tetramethylrhodamine Conjugate

ON N

COOH

ONH

HN

OHO NH

HN

OOH

NH

N

O

HO

SNH

NHO

O

NH

O

OLT-F0073

LT-F0074

LT-F0030LT-F0063

Resorufin




Fluo

rescent P

rob


Protein Staining

247


: : : ::

632-69-9> 85%C20H2NCl4I4Na2O5

1017.64 g/mole549 nm


Na+

Na+

O

O-

O O-O

I

I I

I

ClCl

Cl

Cl


: : : ::

6226-79-5> 90%C22H12N4Na4O13S4

760.57 g/mole518-522 nm in H2O

3-Hydroxy-4-(2-sulfo-4-[4-sulfophenylazo]phenylazo)-2,7-naphthalenedisulfonic acid sodium salt

N

HO

N

SO3Na

SO3Na

NN

NaO3SSO3Na


: : : :

1064-48-8> 85%C22H14N6Na2O9S2

616.49 g/mole


NH2 OHN N

NaO3S SO3Na

N

NO2N

CAS No.FormulaM.W.

: : :

71-67-0C20H8Br4Na2O10S2

838.00 g/mole


O

O

HO OH

Br

SO3NaSO3Na

Br

Br

BrXH2OH

LT-F0063 LT-F0049

LT-F0024

LT-F0048


Naphthol Blue Black



Fluo

rescent P

rob

es

Fluorescent ProbesNucleic Acid Staining Lipid Labeling

248


: : : :: :



N

NH

N

NH

N

NO

3HCl


: : : :

1064-48-8> 85%C22H14N6Na2O9S2

616.49 g/mole


NH2 OHN N

NaO3S SO3Na

N

NO2N

GradeFormulaM.W.


: : :

: : : ::

> 98%C45H70N4O5

747.06 g/mole

187099-99-6C74H117N4O14PS2


(3S,8S,9S,10R ,13R ,14S)-10,13-dimethyl-17-((R )-6-methylheptan-2-yl)-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a ]phenanthren-3-yl 12-(7-nitrobenzo[c ][1,2,5]oxadiazol-4-ylamino)dodecanoate

N

N

HN

O

O2N

O

OH3C H

H H

CH3

H3C

N-(Rhodamine 101 sulfonyl)-1,2-hexadecanoyl-sn-4-phosphoethanolamine, triethylammonium salt

O

N

N

SO

O OS

O

O

HN

OP

O O

OHO

O

C15H31

O

O C15H31

N

LT-F0021 LT-F0076

LT-F0077

LT-F0048

Hoechst 33342 trihydrochloride 3-dodecanoyl-NBD Cholesterol

Sulforhodamine 101 DHPE

Naphthol Blue Black



Fluo

rescent P

rob


Chromogenic Substrates Thiol-Reactive


: : : :

189950-66-1> 97% (HPLC)C26H34N6O13

638.58 g/mole

(4S,7S,10S,13S)-7-(2-carboxyethyl)-4-(carboxymethyl)-10-isopropyl-13-(4-nitrophenylcarbamoyl)-2,5,8,11-tetraoxo-3,6,9,12-tetraazapentadecan-15-oic acid

HN

ONH

NO2

O OH

O

HN

ONH

OHN

HO O

OH

O

O

HN NH

HNNH2

OHN

NO2

O

HCl


: : : :

146-68-9> 98% (TLC)C19H13ClIN5O2

505.70 g/mole

2-(4-Iodophenyl)-3-(4-nitrophenyl)-5-phenyl-2H-tetrazol-3-ium chloride

N+

N

N

N

O2N

I

Cl-


: : : :

911-77-3> 98%C19H23ClN6O4

434.88 g/mole

N -α-Benzoyl-DL-arginine 4-nitroanilide monohydrochloride

LT-F0078 LT-F0018

LT-F0007

LT-F0054

LT-F0081

LT-F0079

LT-F0080

Ac-DEVD-pNA Fluorescein 5-Maleimide

Iodonitrotetrazolium chloride

CAS No.FormulaM.W.

: : :

76809-63-7C15H12INO2

365.17 g/mole

4-(N-Iodoacetamide)benzophenone

NH

IO

O

O NN

O

O

NCS


: : : ::


Tetramethylrhodamine B isothiocyanate


: : : ::


N-(Aminoethyl)-5-naphthylamine-1-sulfonic Acid

HN

SO

OHONH2


PL

: : : :: :

75350-46-8> 90%C24H13NO7



O

O

O OHHO

N

O

O



Fluo

rescent P

rob

es

Fluorescent ProbesAdditional Stains, Dyes and Fluorescent Probes

250


PL

: : : :: :

142978-18-5> 97%C16H16N2O2



N

CN

O OH


: : : :

27072-45-3> 90% (HPLC)C21H11NO5S389.38 g/mole

3',6'-dihydroxy-5(6)-isothiocyanato-3H-spiro[isobenzofuran-1,9'-xanthen]-3-one

O

O

O N

OHHO

C S

LT-F0015

LT-F0019

LT-F0037

LT-F0036

LT-F0038

LT-F0039

LT-F0040

Fluorescein 5(6)-isothiocyanate


Bromothymol Blue

Phenol Red


: : : ::

76-59-5> 95%C27H28Br2O5S624.38 g/mole420 nm


OS O

O

HO

OH

Br

Br


: : : :

143-74-8> 95%C19H14O5S354.38 g/mole


O S OO

HO

HO


: : : ::

27928-00-3C16H7Na3O10S3

524.39 g/mole454 nm in H2O 520 nm in H2O

8-Hydroxypyrene-1,3,6-trisulfonic acid, trisodium salt

OH

NaO3S

SO3Na

SO3Na


: : : :: :

76823-03-5> 97% (HPLC)C21H12O7



O

O

HO O OH

OHO


: : : ::

2869-83-2> 65%C30H31ClN6

511.06 g/mole395, 660 nm


N+

N

NN

N

NCl-

LT-F0041 Janus Green B


: : : :: :

575-03-1> 99%C10H5F3O3


7-Hydroxy-4-(trifluoromethyl)coumarin

OO

FFF

OH



Fluo

rescent P

rob


Additional Stains, Dyes and Fluorescent Probes

251

LT-F0044

LT-F0049

LT-F0050

LT-F0043

LT-F0042

ε-Biotinoyl-L-lysine

Mito Red

CAS No.FormulaM.W.

: : :

71-67-0C20H8Br4Na2O10S2

838.00 g/mole


O

O

HO OH

Br

SO3NaSO3Na

Br

Br

BrXH2OH


: : : :: :

115532-52-0> 90% (HPCE)C26H27ClN2O7


3,6-Bis(dimethylamino)-9-(2-(ethoxycarbonyl)phenyl)xanthylium perchlorate

O+

OO

NN

ClO4-


: : : :: :

53213-82-4> 98%C29H37IN2O2



NO

N+

O

I-

O

O

N

O

O

HO

O

OH

O

O


: : : :: :

117548-22-8> 80% (HPLC)C25H15NO9

473.39 g/mole492 nm in DMF517 nm in DMF

2,5-Dioxopyrrolidin-1-yl 3',6'-dihydroxy-3-oxo-3H-spiro[isobenzofuran-1,9'-xanthene]-5(6)-carboxylate

LT-F0051


: : : :

10510-77-7> 95%C16H20N2O4S336.41 g/mole

5-Ethyl-5,10-dihydrophenazin-5-ium ethyl sulfate

NH

NH

SO

O

O

O

LT-F0045


: : : :

576-19-2> 98% (TLC)C16H28N4O4S372.48 g/mole

(S)-2-Amino-6-(5-((3aS,4S,6aR )-2-oxohexahydro-1H-thieno[3,4-d ]imidazol-4-yl)pentanamido)hexanoic acid

NHHN

S

O

NH

O

NH2

OHO

HH

3,6-Bis(diethylamino)-9-(2-((4-methyl-2-oxo-2H-chromen-7-yloxy)carbonyl)phenyl)xanthylium chloride


: : : ::

> 70% (HPLC)C38H37ClN2O5


O+

OO

O

NN

O

Cl-



Fluo

rescent P

rob

es


252


: : : :

6409-77-4> 96%C14H8NNaO7S357.27 g/mole


SO

O

ONa

O

O

OH

OH

NH2

LT-F0055

LT-F0053 LT-F0057

LT-F0058

LT-F0059

LT-F0060

5-(Iodoacetamido)fluorescein 5(6)-Carboxyfluorescein

Arsenazo III

Hydroxy naphthol blue disodium salt


: : : ::

194785-18-7C33H30N2O5


6-Carboxy-X-rhodamine

O+N N

-O

O

O

OH

LT-F0056


PL

: : : ::

:

10199-89-0> 99% (HPLC)C6H2N3ClO3

199.55 g/mole336 nm in MeOH; 420 nm in EtOH (after derivatization with glycine)~540 nm in EtOH(after derivatization with glycine)

4-Chloro-7-nitrobenzofurazan

NO

N

NO2Cl


: : : :: :

72088-94-9> 95% (HPLC)C21H12O7


3',6'-Dihydroxy-3-oxo-3H-spiro[isobenzofuran-1,9'-xanthene]-5(6)-carboxylic acid

O

O

O

HO OH

HO O


: : : :: :

63368-54-7> 95% (HPLC)C22H14INO6

515.25 g/mole492 nm (Mercaptoethanol adduct)515 nm (Mercaptoethanol adduct)

N-(3',6'-dihydroxy-3-oxo-3H-spiro[isobenzofuran-1,9'-xanthene]-5-yl)-2-iodoacetamide, with isomers

O

O

HO O OH

O

HN

I

3,6-Bis((2-arsonophenyl)diazenyl)-4,5-dihydroxynaphthalene-2,7-disulfonic acid


: : : :

1668-00-4C22H18As2N4O14S2

776.37 g/mole530 nm

OH OHN N

HO3S SO3H

N

NAsO3H2

AsO3H2


: : : :

165660-27-5C20H12N2Na2O11S3

598.49 g/mole650 nm

Sodium(E)-3-hydroxy-4-((2-hydroxy-6-sulfo-3-sulfonatonaphthalen-1-yl)diazenyl)naphthalene-1-sulfonate

N

HO

N

S OHO

OOHNaO3S

SO3Na



Fluo

rescent P

rob



253

O OO

OHO

HOHO

NaO3SHN

4-Methylumbelliferyl 2-Sulfamino-2-deoxy-α-D-glucopyranoside Sodium Salt

CAS No.FormulaM.W.

: : :

460085-45-4C16H18NNaO10S439.37 g/mole


: : : :

133628-73-6> 98%C14H14N2O5

290.27 g/mole

L-Aspartic acid β-(7-amido-4-methylcoumarin)

OHNO

O

NH2

HO O


PL

: : : :

:

62480-44-8C16H21ClN2O3

324.80 g/mole327 nm (pH 8.0); 380 nm (Reaction product)349 nm (pH 8.0); 440 nm (Reaction product)

L-Leucine 7-amido-4-methylcoumarin hydrochloride

O

NH

O

O

NH2HCl


: : : :

76877-33-3> 95% (HPLC)C24H22N2O4

402.44 g/mole

1-(4-(7-(Diethylamino)-4-methyl-2-oxo-2H-chromen-3-yl)phenyl)-1H-pyrrole-2,5-dione

OOO

O

NN

LT-F0062 LT-F0067

LT-F0068

LT-F0069

LT-F0070

LT-F0063

LT-F0064

LT-F0065

N-Butylfluorescein

D-Luciferin sodium salt

C-6 NBD Ceramide



: : : ::

632-69-9> 85%C20H2NCl4I4Na2O5

1017.64 g/mole549 nm


Na+

Na+

O

O-

O O-O

I

I I

I

ClCl

Cl

Cl

3'-Butoxy-6'-hydroxy-3H-spiro[isobenzofuran-1,9'-xanthen]-3-one

CAS No.FormulaM.W.

: : :

335193-91-4C24H20O5

388.41 g/mole

O

O

O

HO O


: : : :: :

103404-75-7> 95%C11H7N2NaO3S2


Sodium (S)-2-(6-hydroxybenzo[d]thiazol-2-yl)-4,5-dihydrothiazole-4-carboxylate

S

N

N

S

O

-OOH

Na+


: : : :: :

86701-10-2> 98%C30H49N5O6


N-((2S,3S,E)-1,3-dihydroxyoctadec-4-en-2-yl)-6-(7-nitrobenzo[c ][1,2,5]oxadiazol-4-ylamino)hexanamide

N

N

HN

O

NO2

HN

O

OH

OH



Fluo

rescent P

rob

es


254


PL

: : : ::

:

905-96-4> 98%C21H21IN2O2

460.31 g/mole480 nm in EtOH; 444 nm in phosphate buffer/SDS 505 nm in EtOH; 512 nm in phosphate buffer/SDS

3,3'-Diethyloxacarbocyanine iodide

O

N+

N

O I


: : : :: :

90134-00-2> 95% (HPLC)C28H36N2O3S480.66 g/mole497 nm in MeOH712 nm in MeOH

3-(4-(2-(6-(Dibutylamino)naphthalen-2-yl)vinyl)pyridinium-1-yl)propane-1-sulfonate

N

N+

SO

O-O

GradeFormulaM.W.

: : :

> 98%C45H70N4O5

747.06 g/mole

(3S,8S,9S,10R ,13R ,14S)-10,13-dimethyl-17-((R )-6-methylheptan-2-yl)-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a ]phenanthren-3-yl 12-(7-nitrobenzo[c ][1,2,5]oxadiazol-4-ylamino)dodecanoate

N

N

HN

O

O2N

O

OH3C H

H H

CH3

H3C


: : : ::

635-78-9> 95%C12H7NO3

213.19 g/mole573 nm

7-Hydroxy-3H-phenoxazin-3-one

OO

N

OH


: : : :: :

101490-85-1> 90%C18H17NO8


7-((2S ,3R ,4S ,5S ,6R )-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yloxy)-3H-phenoxazin-3-one

O O

N

O

OHHO

HOO

OH

LT-F0071 LT-F0076

LT-F0072

LT-F0073

LT-F0074

Resorufin β-D-glucopyranoside 3-dodecanoyl-NBD Cholesterol

Di-4-ANEPPS

Resorufin



: : : :

: : : ::

24782-64-7> 96%C14H9NO3

239.23 g/mole

52417-22-8> 99%C13H13ClIN2O248.71 g/mole400, 420 nm

9-Oxo-9,10-dihydroacridine-4-carboxylic acid

9-Aminoacridine hydrochloride hydrate

HN

O

OOH

N

NH2 HCl

H2O

LT-F0082

LT-F0083

4-Carboxy-9-acridanone


: : : :

100-10-7> 99% (HPLC)C9H11NO149.19 g/mole

4-(Dimethylamino)benzaldehyde

ON

LT-F0084



Fluo

rescent P

rob



255


: : : :: :

596-09-8> 97%C24H16O7

416.38 g/mole495 nm520 nm

3-oxo-3H-Spiro[isobenzofuran-1,9'-xanthene]-3',6'-diyl diacetate

O

O

O

O

O

O

O

518-47-8> 98%C20H12Na2O5



: : : :: :

Sodium 2-(3-hydroxy-6-oxido-9H-xanthen-9-yl)benzoate

NaO

O

ONaOHO

4',5'-Di(1,3,2-dithiarsolan-2-yl)-3',6'-dihydroxy-3H-spiro[isobenzofuran-1,9'-xanthen]-3-one


: : : ::

212118-77-9C24H18As2O5S4

664.50 g/mole508 nm 528 nm

O

O

O OHHOAs As

S S S S

CAS No.FormulaM.W.

: : :

1241912-74-2C31H29N3O11S651.64 g/mole

2,2'-(1-Carboxy-5-(3-(4-carboxy-3-(6-hydroxy-3-oxo-3H-xanthen-9-yl)phenyl)thioureido)pentylazanediyl)diacetic acid

O OHO

HN

HN

S

HOOC

HOOC

N

HOOC COOH

LT-F0088

LT-F0089

LT-F0090

LT-F0091

Fluorescein Diacetate

Fluorescein sodium salt

FlAsH-EDT2

NTA-FITC

LT-F0085

LT-F0086

LT-F0087

(2-Pyridyl)dithiobimane

Biotin (5-fluorescein) conjugate


: : : :: :

307554-62-7> 90%C22H18O8

410.37 g/mole380 nm in 0.1 M phosphate pH 7.0407 nm in 0.1 M phosphate pH 7.0

9,10-Anthracenediyl-bis(methylene)dimalonic acid

O

HO

OHO

OHO

O

OH

2,3,6-Trimethyl-5-((pyridin-2-yldisulfanyl)methyl)pyrazolo[1,2-a]pyrazole-1,7-dione


: : : ::

385398-64-1C15H15N3O2S2

333.43 g/mole406 nm in 0.1 M phosphate pH 7.0481 nm in 0.1 M phosphate pH 7.0

NN

O O

SS

N


: : : :::

957494-27-8> 90%C33H32N4O8S644.69 g/mole490 nm in 0.1 M Tris pH 8.0524 nm in 0.1 M Tris pH 8.0

2-(6-Hydroxy-3-oxo-3H-xanthen-9-yl)-5-(2-(5-((3aS,4S,6aR )-2-oxohexahydro-1H-thieno[3,4-d ]imidazol-4-yl)pentanamido)ethylcarbamoyl)benzoic acid

OHO O

O

HO

OHN

NH

OS

HN NH

O

H H



Fluo

rescent P

rob

es


256


: : : :

1658-56-6> 98%C20H13N2NaO4S400.38 g/mole

Sodium-4-((2-hydroxynaphthalen-1-yl)diazenyl)naphthalene-1-sulfonate

N

NaO3SN

HO


PL

:: : : :

:

7149-49-7> 98% (NMR)C12H8O2

184.19 g/mole420 nm in ~90 µM glycine, ~20 µM N-

480 nm in ~90 µM glycine, ~20 µM N-

Naphthalene-2,3-dicarboxaldehyde

5-(Dimethylamino)-N-(2-mercaptoethyl)naphthalene-1-sulfonamide


: : : ::

5354-61-0C14H18N2O2S2

310.43 g/mole335 nm526 nm

S

N

O NHO

SH

O

O

HH

(3R,8R,9R,10S,13S,17S)-10,13-dimethyl-17-((R)-6-methylheptan-2-yl)-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl 6-(7-nitrobenzo[c ][1,2,5]oxadiazol-4-ylamino)hexanoate

CAS No.FormulaM.W.

: ::

201731-19-3C39H58N4O5

662.90 g/mole

N

NO

NO2

HN

O

O

H3C

CH3

H3C

H

H

H

2-[(5-Fluoresceinyl)aminocarbonyl]ethyl methanethiosulfonate, with isomers


: : : ::

887355-30-8C24H19NO8S2

513.54 g/mole492 nm515 nm

SO

OS

O

HN

O

O

HO O OH

3-O-Methylfluorescein phosphate cyclohexylammonium salt

CAS No.FormulaM.W.

: : :

21233-09-0C27H28NO8P525.49 g/mole

O

O

O

OOP

OH

OHO

NH2

LT-F0092 LT-F0096

LT-F0097

LT-F0098

LT-F0093

LT-F0094

LT-F0095

3-hexanoyl-NBD Cholesterol

Acid Red 88

Dansylamidoethyl Mercaptan


: : : :

67000-89-9> 99% (HPLC)C20H18O274.36 g/mole

1-Pyrenebutanol

OH



Fluo

rescent P

rob



257

LT-F0100

LT-F0101

Tetramethylrhodamine methyl esterrate

Sulforhodamine B sodium salt


: : : :: :

115532-50-8> 95%C25H25ClN2O7


N-(6-(Dimethylamino)-9-(2-(methoxycarbonyl)phenyl)-3H-xanthen-3-ylidene)-N-methylmethanaminium perchlorate

ON N+

ClO4

O

O


: : : :: :

3520-42-1> 75%C27H29N2NaO7S2


Sodium 4-(6-(diethylamino)-3-(diethyliminio)-3H-xanthen-9-yl)benzene-1,3-disulfonate

O

SO

NN

SOO

O

OO

Na



Synth

etic Interm

ediates an

d R

eagents

Synthetic Intermediates and ReagentsContents

258

• Introduction -------------------------------------------------------------------259

• Arylamines (43) ----------------------------------------------------------------265

• Naphthalenes / Acenaphthenes (18) ------------------------------------------268

• Anthracenes / Phenanthracenes (20) ------------------------------------------269

• Fluorenes / Fluoranthenes (60) ------------------------------------------------270

• Pyrenes / Triphenylenes / Chrysenes (16) -------------------------------------273

• Carbazole Derivatives (54) ----------------------------------------------------274

• Heterocyclics (89) -------------------------------------------------------------277

• Iridium Complexes / Ligands (62) ---------------------------------------------282

• Silanes Derivatives (16) --------------------------------------------------------286

• Thiophenes Derivatives (271) ------------------------------------------------287

• Benzene Derivatives (57) ------------------------------------------------------301



Synth

etic Interm

ediates an

d R

eagents

Synthetic Intermediates and ReagentsIntroduction

259



Synthetic Intermediates and ReagentsContents

The development of organic materials for electronic applications has drawn much attention

over the last three decades. During this time, there have been significant advances made in

this field, leading to the use of organic materials in many present day applications such as

solar cells (OPV&DSSC),display technologies(OLED) and field effect transistors(OTFT).

Luminescence Technology Corp. (Lumtec) is an acknowledged world manufacturer in

organic chemicals company. Over ten years of abundant experiences developing innovative

organic optoelectronic materials in the market of OLED, OPV, OTFT, High polymer materials

and Pharmaceutical ,etc. Lumtec could provided more than two thousand synthetic

intermediates and reagents, most of the products are applied in the field of Solution-

Processed OLED, Flexible Printed Electronics.Organic Light Emitting Diode(OLED), Organic

Photovoltaic(OPV), Organic Thin-Film Transistor(OTFT), Photonic and Optical Device.

Arylamines of materials have been widely exploited as hole-transport layers in organic

light emitting diodes (OLEDs).

Naphthalenes / Acenaphthenes have been investigated as organic electroluminescence

materials for the applications in organic solar cells, biosensitizers and display devices such as

OLED(Organic Light Emiting Diode), OTFT(Organic Thin Film Transistor).

Arylamines

Naphthalenes / Acenaphthenes

S C10H21

SC10H21

S

S

C10H21

C10H21

HN NHN

Br

N N

N N



Synth

etic Interm

ediates an

d R

eagents


260

Anthracenes such intermediates are used in a wide range of made into organic light

emiting diode HOST, DOPANT related materials.

Fluorene-based conjugated oligomers can emit deep blue light at an efficiency of up to

99% in solution and 90% in neat solid films, These properties have been exploited extensively

in OLED, PLED, OPV and OTFT.

Anthracenes / Phenanthracenes / Tetracenes / Perylenes / Pentacenes

Fluorenes / Fluoranthenes

Reference: Av. Funct. Mater., 2006, 16, 667-674

Br

N

BO

ON

C8H17 C8H17

B BO

O O

O

C8H17 C8H17

Br Br

C8H17 C8H17

B BO

O O

O

S

S SBr Br

C8H17 C8H17

S

S

S

n



Synth

etic Interm

ediates an

d R

eagents


261

Pyrene derivatives have been turned out to be promising candidates for several

applications like blue-emitting materials in organic light-emitting diodes (OLEDs) due to its

desirable photophysical properties.

Carbazole-based compounds are used in a wide range of made into organic light emiting

diode host and dopant related materials.

Pyrenes / Triphenylenes / Chrysenes

Carbazoles

Reference: Organic electronics. 10,(2009), 877-882

Reference: Organic letters 2011 Vol. 13, No. 12 3146-3149

Reference: J. Matter. Chem., 2011, 21, 9546-9552

Br BO

O

NBr Br BO

ON

N

Br Br

N

P PO O

H2O2

P Cl

N

O

NN

N

BF3O(C2H5)2

On



Synth

etic Interm

ediates an

d R

eagents


262

Heterocyclics compound are the cyclic compound that has atoms of at least two different

elements as members of its ring(s) which used in a wide range of made into OLED, PLED, OPV

and OTFT materials.

Iridium dimer, Intermediate and ligands for Iridium complexe materials use.

Silane-based compounds are used in a wide range of made into OLED, PLED, OPV and

OTFT materials.

Heterocyclics

Iridium Complexes / Ligands

Silane Derivatives

Reference: Chem. Commun., 2013, 49, 1446-1448

Reference: J. Matter. Chem. 2010, 20, 8411-8416

NO

N

ON

Cl

B

N

OO

NIr

ClIr

Cl

N

2 2

N

F

F

NIr

2N

F

F

HNSi

Br

Br

Br

Br

Si

N

N

N

N



Synth

etic Interm

ediates an

d R

eagents


263

Thiophene -based compounds are used in a wide range of made into solar cells (OPV,

DSSC) and field effect transistors(OTFT) related materials.

Thiophene Derivatives

Reference: Appl. Phys. Lett. 92, 033307, 2008

Reference: J. Am. Chem. Soc. 2009, 131, 56-57

Reference: Organic Electronics, V 13, p1401-1408 (2012)

SiC8H17 C8H17

Br Br

NS

NS SBr Br

SiC8H17 C8H17

SN

SN

S

n

SiC8H17 C8H17

Sn Sn

SiC8H17 C8H17

Sn Sn

S

S

O

O

SnSn

C8H17

C8H17

S

S

Br

O OC12H25

BrS

S

O

O

C8H17

C8H17

S

S

O OC12H25 n

S

S

OR

OR

SnSn

S

S

Br

O OR

BrS

S

OR

OR

S

S

O OR n

F

F



Synth

etic Interm

ediates an

d R

eagents


264

The class of compounds, which contains benzene or substituted derivative of benzene with

functional groups.

Palladium catalysis has gained widesoread usd in industrial and academic synthetic

chemistry laboratories as a powerful methodology for the formation of C-C and C-H

heteroatiom bonds.

Benzene Derivatives

Metal Catalysts / Reductants

I

I

BrBrCl

Cl Cl

ClF

NH2

F

BrBr

Br O

OO

Me

Br

MeO

+ n-HexNH2

MeHN

MeO

HexPd2(dba)3

BINAP, NaOtBuPhCH3, 80OC

6 h 95% yield



Synth

etic Interm

ediates an

d R

eagents

Synthetic Intermediates and ReagentsArylamines

265

K0019

K0062

K0066

K0154

K0359

K0013

K0061

K0065

K0151

K0355

K0030

K0063

K0067

K0215

K0370

K0060

K0064

K0073

K0353

K0388

4181-20-8

36809-26-4

532-18-3

287937-02-4

603-34-9

42906-19-4

16292-17-4

4316-58-9

845526-91-2

20440-95-3

4181-05-9

202831-65-0

10311-61-2

1469780-16-2

534-85-0

531-91-9

81090-53-1

4669-06-1

101-70-2

287976-94-7

C18H12I3N623.01 g/mole> 98% (HPLC)

C18H14BrN324.21 g/mole> 98% (HPLC)

C20H15N269.34 g/mole> 98% (HPLC)

C21H19NO301.38 g/mole> 98% (HPLC)

C18H15N245.32 g/mole> 98% (HPLC)

C21H19NO301.38 g/mole> 98% (HPLC)

C12H9Br2N327.01 g/mole> 98% (HPLC)



C20H19N273.37 g/mole> 98% (HPLC)

C19H15NO273.33 g/mole> 98% (HPLC)


C26H24N2

364.48 g/mole> 98% (HPLC)

C19H13Br2NO431.12 g/mole> 98% (HPLC)

C12H12N2

184.24 g/mole> 98% (HPLC)

C24H20N2

336.43 g/mole> 98% (HPLC)


C20H15N269.34 g/mole> 98% (HPLC)

C14H15NO2

229.27 g/mole> 98% (HPLC)


FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

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FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

HN

NH

N

I

II

N

CHO

N

CHO

HN

BrBrN

Br

N Br N

Br Br

N

Br Br

Br

NH

HN

NH

HN

N

Br

N

CHO

N

Br Br

CHOHN

O O

N N NH NH2 N

Br Br



Synth

etic Interm

ediates an

d R

eagents


266

K0463

K0753

K0837

K0881

K0886

K0432

K0752

K0835

K0867

K0884

K0750

K0754

K0852

K0882

K0893

K0751

K0755

K0853

K0883

K0894

352359-42-3

34801-11-1

194416-45-0

6267-02-3

3282-99-3

308144-65-2

55389-75-8

499128-71-1

1467099-22-4

1548941-62-3

59131-00-9

626-13-1

78600-31-4

58751-07-8

1342892-15-2

352359-43-4

203710-89-8

854938-56-0

3661-49-2

71041-21-9


C14H15N197.28 g/mole> 98% (HPLC)

C20H18BrNO2

384.27 g/mole> 98% (HPLC)

C15H15N209.29 g/mole> 98% (HPLC)

C18H22N2

266.38 g/mole> 98% (HPLC)


C16H19N225.33 g/mole> 98% (HPLC)



C32H32IN557.51 g/mole> 98% (HPLC)

C26H24N2O2

396.48 g/mole > 98% (HPLC)

C14H15N197.28 g/mole> 98% (HPLC)


C14H15NO2

229.27 g/mole> 98% (HPLC)


C38H28N2

512.64 g/mole> 97% (HPLC)


C46H32N2O2

644.76 g/mole> 95% (HPLC)

C14H15NO2

229.27 g/mole> 98% (HPLC)

C18H12BrNO338.2 g/mole> 98% (HPLC)

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

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FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

Br N

N Br HN NH

O

O

N NH

NHNH NH

N

Br

N

Br

N

Br

O O

NBr

N N

O

O

Br

N

NH O

HN

O

O

HN O

IN

NH2H2N

N

Br

O

N

Br



Synth

etic Interm

ediates an

d R

eagents


267

K0916K0899 K0940152670-41-292-67-1 1241891-64-4

C32H24N2

436.55 g/mole> 98% (HPLC)

C12H11N169.22 g/mole> 98% (HPLC)

C31H20BrN486.40 g/mole > 98% (HPLC)

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

NH2 HN NHN

Br



Synth

etic Interm

ediates an

d R

eagents

Synthetic Intermediates and ReagentsNaphthalenes / Acenaphthenes

268

K0089

K0345

K0476

K0028

K0336

K0465

K0590

K0947

K0139

K0347

K0486

K0840

K0948

K0143

K0413

K0589

K0872 K0932

22856-30-0

580-13-2

1310197-76-2

4542-77-2

33626-98-1

1310197-70-6

245093-97-4

184027-05-2

13720-06-4

66-99-9

1292793-97-5

1310197-78-4

305798-02-1

18937-92-3

132178-78-0

71590-31-3 93655-02-8

C12H6N2

178.19 g/mole> 98% (HPLC)

C10H7Br207.07 g/mole> 98% (HPLC)

C22H32OS344.55 g/mole> 98% (HPLC)

C12H10Br2

314.02 g/mole> 98% (HPLC)

C12H9BrO2

265.10 g/mole> 98% (HPLC)

C21H30O298.46 g/mole> 98% (HPLC)

C14H14Br2O4

406.07 g/mole> 98% (HPLC)

C12H5FN2

196.18 g/mole> 98% (HPLC)

C10H6Br2

285.96 g/mole> 98% (HPLC)

C11H8O156.18 g/mole> 98% (HPLC)

C44H60S2

653.08 g/mole> 98% (HPLC)

C18H16OS280.38 g/mole> 98% (HPLC)

C12H5ClN2

212.63 g/mole> 98% (HPLC)

C11H8Br2

299.99 g/mole> 98% (HPLC)

C16H11Br283.16 g/mole> 98% (HPLC)

C10H6Br2O2

317.96 g/mole> 98% (HPLC)

C10H9BrClN258.54 g/mole> 98% (HPLC)

C18H14O2

262.3 g/mole> 98% (HPLC)

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BrBr

CN

CN Br

Br

Br

Br

BrO

O

Br OHC

Br

O

C10H21

O

SC10H21

S

C10H21

S

C10H21

OHBr

BrHO

Br

BrO

OO

OO

S

Br

H2N

HCl

O

O

FCN

CN

ClCN

CN



Synth

etic Interm

ediates an

d R

eagents

Synthetic Intermediates and ReagentsAnthracenes / Phenanthracenes

269

K0037

K0077

K0363

K0035

K0076

K0362

K0464

K0909

K0054

K0360

K0364

K0875

K0930

K0058

K0361

K0404

K0901

K0935

K0877

K0931

201731-79-5

7424-70-6

1564-64-3

572-83-8

400607-04-7

1055-23-8

23674-20-6

1092390-01-6

121848-75-7

523-27-3

573-17-1

937372-45-7

158902-11-5

474688-76-1

84-11-7

53348-05-3

474688-73-8

944801-33-6

23674-15-9

937372-45-7

C26H17Br409.32 g/mole> 97% (HPLC)

C24H16

304.38 g/mole> 98% (HPLC)


C14H7BrO2

287.11 g/mole> 98% (HPLC)

C24H15Br383.28 g/mole> 98% (HPLC)

C28H18

354.44 g/mole> 98% (HPLC)

C20H13Br333.22 g/mole> 98% (HPLC)

C30H19Br459.38 g/mole> 98% (HPLC)

C28H16Br2

512.23 g/mole> 98% (HPLC)

C14H8Br2

336.02 g/mole> 98% (HPLC)



C21H15BrO363.25 g/mole> 98% (HPLC)

C34H21Br509.43 g/mole> 97% (HPLC)

C14H8O2

208.21 g/mole> 98% (HPLC)

C14H6Br2O2

366.0 g/mole> 97% (HPLC)

C24H15Br383.28 g/mole> 98% (HPLC)

C30H19Br459.38 g/mole> 98% (HPLC)

C21H16O284.35 g/mole> 98% (HPLC)


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BrO

O

BrBr Br

Br

Br Br Br

O O

Br BrO O

Br Br

Br Br CN OCH3 Br

Br Br OMe Br CNBr



Synth

etic Interm

ediates an

d R

eagents

Synthetic Intermediates and ReagentsFluorenes / Fluoranthenes

270

K0002

K0006

K0012

K0024

K0050

K0001

K0005

K0011

K0023

K0033

K0003

K0009

K0014

K0025

K0086

K0004

K0010

K0020

K0032

K0087

171408-84-7

14348-75-5

357645-37-5

851478-90-5

302554-80-9

171408-76-7

16433-88-8

474918-33-7

28320-31-2

67665-45-6

128055-74-3

3096-56-8

15499-84-0

128406-10-0

198964-46-4

159-66-0

28320-32-3

486-25-9

790674-48-5

189367-54-2

C25H14Br2

474.19 g/mole> 98% (HPLC)

C13H6Br2O337.99 g/mole> 98% (HPLC)

C27H20Br2

504.26 g/mole> 98% (HPLC)

C45H38

578.78 g/mole> 98% (HPLC)

C29H41Br469.54 g/mole> 98% (HPLC)

C25H15Br395.29 g/mole> 98% (HPLC)

C13H8Br2

324.01 g/mole> 98% (HPLC)

C27H21Br425.36 g/mole> 98% (HPLC)

C15H13Br273.17 g/mole> 98% (HPLC)

C25H18N2

346.42 g/mole> 98% (HPLC)

C25H12Br4

631.98 g/mole> 98% (HPLC)


C25H20N2

348.44 g/mole> 98% (HPLC)

C25H16Br2

476.20 g/mole> 98% (HPLC)

C29H40Br2

548.44 g/mole> 98% (HPLC)

C25H16

316.39 g/mole> 98% (HPLC)

C15H12Br2

352.06 g/mole> 98% (HPLC)

C13H8O180.20 g/mole> 98% (HPLC)

C25H14I2

568.19 g/mole> 98% (HPLC)

C25H32Br2

492.33 g/mole> 98% (HPLC)

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Br Br Br Br

Br Br

Br

Br BrBr Br

O

Br

O

Br Br

Br BrBr

H2N NH2O

Br

Br Br

I

I

NH2

H2N C8H17C8H17

Br Br Br

C8H17 C8H17

Br Br

C6H13 C6H13



Synth

etic Interm

ediates an

d R

eagents


271

K0126

K0344

K0412

K0467

K0531

K0088

K0320

K0406

K0450

K0470

K0275

K0367

K0429

K0468

K0573

K0295

K0405

K0437

K0469

K0581

1133-80-8

1185855-21-3

50890-67-0

1186096-65-0

188200-93-3

175922-78-8

202831-64-9

198142-63-1

746-47-4

286438-45-7

86-73-7

673474-73-2

171856-25-0

438201-29-7

187148-75-0

937082-81-0

607739-64-0

738580-15-9

169169-89-5

C59H42Br2N2

938.79 g/mole> 98% (HPLC)


C29H16Br2

524.25 g/mole> 98% (HPLC)

C11H6N2O182.18 g/mole> 98% (HPLC)

C26H18O346.42 g/mole> 98% (HPLC)

C29H40Br2

548.44 g/mole> 98% (HPLC)

C33H48Br2

604.54 g/mole> 98% (HPLC)


C23H12Br2N2

476.16 g/mole> 98% (HPLC)

C26H16

328.41 g/mole> 98% (HPLC)

C37H56Br2

660.65 g/mole> 98% (HPLC)

C13H10

166.22 g/mole> 98% (HPLC)

C23H30Br2N2

494.31 g/mole> 98% (HPLC)

C23H14N2

318.37 g/mole> 98% (HPLC)

C25H31Br3

571.23 g/mole> 98% (HPLC)

C27H36Br2

520.38 g/mole> 98% (HPLC)

C25H17Br397.31 g/mole> 97% (HPLC)

C45H36Br2

736.58 g/mole> 97% (HPLC)

C26H32Br2

504.34 g/mole> 98% (HPLC)

C25H16Br2O2

508.2 g/mole> 98% (HPLC)

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Br Br

N N

Br Br

C10H21 C10H21

Br Br

Br

C12H25C12H25

BrBr Br

C6H13 C6H13

Br

Br

NBr

Br

BrN N

Br Br

NN

Br Br

Br Br

NN

O

NN

Br Br

C6H13C6H13

BrBr

Br

HO OH

BrBr

OHC



Synth

etic Interm

ediates an

d R

eagents


272

K0604

K0678

K0871 K0904K0895

K0933

K0582

K0627

K0761 K0867

K0609

K0759

K0866

K0874

K0907 K0934

K0626

K0760

K0868

1161009-88-6

325461-30-1

1260496-44-3 1262758-37-1865702-19-8

1173170-47-2

295796-56-4

1467099-22-4

216312-73-1

108714-73-4

1242570-65-5

1242570-65-5

1056884-35-5

295796-57-5

1175203-78-7

C25H15Br395.29 g/mole> 98% (HPLC)

C33H48Br2

604.54 g/mole> 98% (HPLC)

C53H52Br4N2

1036.61 g/mole> 97% (HPLC)


C15H12Br2

352.06 g/mole> 98% (HPLC)

C37H21Br545.47 g/mole> 98% (HPLC)

C57H40N2O2

784.94 g/mole> 98% (HPLC)

C27H38O2

394.59 g/mole> 98% (HPLC)




C15H15N209.29 g/mole> 98% (HPLC)

C29H16Br2

524.25 g/mole> 98% (HPLC)

C37H52Br2O2

688.62 g/mole> 97% (HPLC)

C27H19Br423.34 g/mole> 98% (HPLC)

C19H14Br2

402.12 g/mole> 98% (HPLC)

C27H34O2

390.56 g/mole> 98% (HPLC)

C20H18O274.36 g/mole> 98% (HPLC)

C29H17Br445.35 g/mole> 98% (HPLC)

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HO OH

NN

Br

O

Br Br

CHOOHC

C6H13 C6H13

HO OHC6H13 C6H13

NH2O

OBr

Br Br

BrBr Br

Br

N

NN

Br

Br

Br

Br

BrBr

O (CH 2) 6

O(H2C)6

BrBr

Br N

C8H17C8H17

BrBr

Br Br

K0941 2041-19-2


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O



Synth

etic Interm

ediates an

d R

eagents

Synthetic Intermediates and ReagentsPyrenes / Triphenylenes / Chrysenes

273

K0034

K0489

K0764

K0889 K0959

K0031

K0365

K0763

K0888 K0903

K0119

K0516

K0765

K0128

K0762

K0818

27973-29-1

1416893-92-9

3443-45-6 1015473-19-4

1714-29-0

129-00-0

1538574-70-7

7499-60-7 345924-29-0

38303-35-4

16391-62-1

131222-99-6

78751-74-3

187086-32-4

217-59-4

C16H8Br2

360.04 g/mole> 98% (HPLC)

C30H17Br457.36 g/mole> 97% (HPLC)


C20H16O2 288.34 g/mole> 98% (HPLC)

C40H41BrN2O4

693.67 g/mole> 97% (NMR)


C16H10

202.25 g/mole> 98% (HPLC)

C27H19Br423.34 g/mole> 98% (HPLC)

C20H14O3

302.32 g/mole> 98% (HPLC)

C22H13Br357.24 g/mole> 98% (HPLC)

C16H8Br2

360.04 g/mole> 97% (HPLC)

C32H20

404.50 g/mole> 97% (HPLC)

C18H10Br2

386.08 g/mole> 96% (HPLC)

C20H17Br337.25 g/mole> 95% (HPLC)

C32H19Br483.40 g/mole> 97% (HPLC)

C18H12

228.29 g/mole> 98% (HPLC)

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: ::

Br

Br

Br

Br

Br

Br

Br

Br

Br BrO BrBr

OH

O

O OH

O Br

N

N

O

O

O

O

C2H5

C4H9

C2H5

C4H9

Br



Synth

etic Interm

ediates an

d R

eagents

Synthetic Intermediates and ReagentsCarbazole Derivatives

274

K0074

K0113

K0325

K0378

K0499

K0068

K0112

K0324

K0328

K0480

K0075

K0125

K0326

K0433

K0510

K0093

K0152

K0327

K0449

K0565

57103-13-6

955964-73-5

1095570-49-2

173063-52-0

185112-61-2

57103-20-5

1256704-63-8

882066-02-6

951307-27-0

741293-42-5

136630-39-2

111296-90-3

1296229-23-6

110677-45-7

57102-42-8

882066-04-8

60511-85-5

109005-10-9

C22H21N299.41 g/mole> 98% (HPLC)


C50H74Br2N2

862.94 g/mole> 97% (HPLC)





C18H10Br2N2

414.09 g/mole> 98% (HPLC)

C34H42Br2N2

638.52 g/mole> 98% (HPLC)




C30H34Br2N2

582.41 g/mole> 98% (HPLC)

C18H12N2

256.30 g/mole> 98% (HPLC)

C30H19BrN2

487.39 g/mole> 98% (HPLC)

C19H13NO271.31 g/mole> 98% (HPLC)


C34H42Br2N2

638.52 g/mole> 97% (HPLC)

C18H12N2

256.30 g/mole> 98% (HPLC)

C24H15N3

345.4 g/mole> 98% (HPLC)

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N

BrBr

N N

Br

Br

NOHC

NH

Br Br NBrNBr Br

C6H13 C6H13

NBr Br

C8H17 C8H17

Br Br

HN

NH

Br Br

N

NC8H17

C6H13

C6H13

C8H17

N

N

BrBr

N

N

BrBr

N

Br Br

NH

NH

N

N

Br Br

NH

NH

Br

NNN

Br

NBr

HN

HN

NH



Synth

etic Interm

ediates an

d R

eagents


275

K0576

K0583

K0593

K0608

K0676

K0575

K0579 K0592

K0602

K0619

K0577

K0591

K0600

K0611

K0766

K0578

K0749

K0601

K0618

K0824

18628-07-4

37500-95-1

551951-04-3

1484-12-4

1268491-06-0

16807-13-9

56525-79-2 952308-18-8

750573-26-3

597570-65-5

6825-20-3

57103-02-3

1153-85-1

111296-91-4

5599-50-8

444796-09-2

728045-10-1

3652-90-2

C24H16N2

332.4 g/mole> 98% (HPLC)

C20H25N279.42 g/mole> 98% (HPLC)

C52H55N3

722.01 g/mole> 97% (HPLC)

C13H11N181.23 g/mole> 98% (HPLC)


C12H8IN293.1 g/mole> 98% (HPLC)

C24H17N319.4 g/mole> 98% (HPLC)

C18H10I3N620.99 g/mole> 98% (HPLC)


C38H24N2O2

540.61 g/mole> 98% (HPLC)


C12H7I2N419.0 g/mole> 98% (HPLC)

C17H17NO251.32 g/mole> 98% (HPLC)


C18H12N2

256.30 g/mole> 98% (HPLC)

C14H13N195.26 g/mole> 98% (HPLC)


C29H24N2O416.51 g/mole> 98% (HPLC)

C37H24N2O512.6 g/mole> 98% (HPLC)


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: : :

: ::

NH

I

NHN N

H

Br Br

NH

NH

NH

NH

I I

NBr Br

N

I

II

N

O

N

O

N

NH

NN

NN

Br

N

Br Br

N N

CHO

HN

HN

N N

CHO

OHC

N

BrBr

C8H17 C8H17HN

Br



Synth

etic Interm

ediates an

d R

eagents


276

K0850

K0897

K0936

K0829

K0871

K0908

K0956

K0851

K0906

K0949

K0838

K0896

K0922

K0961

750573-26-3

502161-03-7

1445416-81-8

1257220-47-5

1260496-44-3

57103-01-2

142116-85-6

1374147-31-5

1024598-06-8

1448296-00-1

150623-72-6

1592-95-6

1338919-70-2

606129-90-2


C18H12IN369.20 g/mole> 98% (HPLC)

C25H16N2S376.47 g/mole> 98% (HPLC)

C21H17N283.37 g/mole> 98% (HPLC)

C53H52Br4N2

1036.61 g/mole> 98% (HPLC)

C14H13NO2

227.26 g/mole> 98% (HPLC)

C20H15NO285.34 g/mole> 98% (HPLC)

C17H11BrN2

323.19 g/mole> 98% (HPLC)

C24H16N2

332.40 g/mole> 98% (HPLC)

C24H16N2

332.40 g/mole> 98% (HPLC)



C18H11NO257.29 g/mole> 98% (HPLC)

C36H23N3

497.59 g/mole> 98% (HPLC)

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HN

N

Br

Br NN

Br

N

Br Br

NN

Br

Br

Br

Br

NH

Br

N

I

NH

N

NH

MeO OMe

O NH

N

N

S NH

N

NO

NH

N N



Synth

etic Interm

ediates an

d R

eagents

Synthetic Intermediates and ReagentsHeterocyclics

277

K0052

K0218

K0333

K0346

K0387

K0026

K0153

K0331

K0342

K0386

K0085

K0267

K0334

K0349

K0392

K0141

K0310

K0340

K0369

K0430

5394-23-0

1159905-88-0

1236490-06-4

612-62-4

1810-71-5

866117-17-1

16567-18-3

221241-11-8

366-18-7

1134-35-6

148231-14-5

66-71-7

54-96-6

3922-40-5

6813-38-3

19493-44-8

108-31-6

1700-02-3

C12H6Cl2N2

249.10 g/mole> 97% (HPLC)

C20H27Br2NO2

473.24 g/mole> 97% (HPLC)

C28H44Br2N2

568.47 g/mole> 98% (HPLC)

C9H6ClN163.60 g/mole> 98% (HPLC)

C9H5BrClN242.50 g/mole> 98% (HPLC)

C11H8N6

224.22 g/mole> 98% (HPLC)


C5H5Br2N3

266.92 g/mole> 98% (HPLC)

C10H8N2

156.18 g/mole> 98% (HPLC)


C12H12N2

184.24 g/mole> 98% (HPLC)

C12H12Br2N2

344.05 g/mole> 98% (HPLC)

C12H8N2

180.21 g/mole> 99% (HPLC)

C5H7N3

109.13 g/mole> 97% (HPLC)

C12H8N2O2

212.20 g/mole> 98% (HPLC)

C12H8N2O4

244.20 g/mole> 98% (HPLC)

C14H15Br2NO2

389.08 g/mole> 97% (HPLC)


C4H2O3

98.06 g/mole> 98% (HPLC)

C9H5Cl2N3

226.06 g/mole> 98% (HPLC)

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N N

HOOC COOH

NBr

N N NN

NHN

NN

Cl Cl N N

NO O

C12H25

Br Br

NN

Br Br

NBr Br

NH2H2N

NO O

Br Br

C6H13

NN

C10H21 C10H21

Br Br N N

N

N

NCl

N

Cl

OO

O

N Cl

N

H2N NH2

N Cl

Br

N N

HO OH N

NN

Cl

Cl



Synth

etic Interm

ediates an

d R

eagents


278

K0441

K0477

K0567

K0605

K0639

K0439

K0455

K0530

K0603

K0638

K0446

K0490

K0571

K0606

K0645

K0452

K0529

K0584

K0628

K0677

2620-76-0

1314801-35-8

81167-60-4

86-76-0

1329114-94-4

3842-55-5

1030380-50-7

1147081-45-5

760212-58-6

1265637-81-7

1229012-68-3

30363-03-2

1424369-37-8

10016-52-1

498572-73-9

1147081-44-4

1147081-43-3

38922-71-3

1352743-87-3

863027-98-9

C19H13BrN2

349.22 g/mole> 98% (HPLC)

C22H34Br2N2O3

534.32 g/mole> 98% (HPLC)



C54H86Br2N2O2S4

987.08 g/mole> 98% (NMR)

C15H10ClN3

267.71 g/mole> 98% (HPLC)

C17H10Cl4N2

384.09 g/mole> 96% (HPLC)

C28H19BrN2O479.37 g/mole> 98% (HPLC)

C19H13BrN2

349.22 g/mole> 98% (HPLC)

C46H70Br2N2O2S4

874.87 g/mole> 98% (NMR)

C24H14Cl2N2

401.29 g/mole> 98% (HPLC)

C21H12Br3N3

546.05 g/mole> 98% (HPLC)

C11H6ClNO203.62 g/mole> 98% (HPLC)


C36H44Br2N2O2

696.55 g/mole> 98% (HPLC)

C28H19BrN2

463.37 g/mole> 98% (HPLC)

C27H17BrN2

449.34 g/mole> 98% (HPLC)

C17H12N2

244.29 g/mole> 98% (HPLC)

C32H54O4Sn2

740.19 g/mole> 98% (NMR)

C16H19Br2NO2

417.14 g/mole> 97% (HPLC)

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N

NN

Cl

N

NBr NN

Cl ClN

NBr

N NCl

Cl Cl

Cl

C8H17O OC8H17

NO

N

Br BrN

N

N

Br Br

Br

N

NBr

N

NBr

O

N

Cl

ON

ClN

N

N

N

Br

O

Br

O

BrBrO

O

O

O

SnSn

N

N

O

O

O

O

Br

Br

C8H17C6H13

C8H17C6H13

NN

BrBr

OO

N OO

BrBr

N

N

O

O

O

O

Br

Br

C10H21

C10H21

C8H17

C8H17



Synth

etic Interm

ediates an

d R

eagents


279

K0681

K0770

K0817

K0843 K0849

K0680

K0769

K0816

K0848

K0767

K0771

K0833 K0841

K0851

K0768

K0772

K0847

K0854 K0855

15862-19-8

1084334-28-0

6528-85-4 1097652-86-2

2677220-47-3

7089-68-1

1224430-28-7

1266389-17-6

10495-73-5

66318-88-5 1309387-42-5

1374147-31-5

29176-55-4

35989-02-7

2255-80-3 1457-92-7

C26H40O4

416.59 g/mole> 98% (HPLC)

C10H7BrN2

235.08 g/mole> 98% (HPLC)

C18H11BrS339.25 g/mole> 98% (HPLC)

C14H12N2O224.26 g/mole> 98% (HPLC)

C22H12Cl4N2

446.16 g/mole> 95% (HPLC)

C27H17BrN4

477.35 g/mole> 97% (HPLC)

C10H4O4

188.14 g/mole> 98% (HPLC)

C12H7ClN2

214.65 g/mole> 97% (HPLC)

C62H102Br2N2O2S2

1131.42 g/mole> 98% (NMR)

C15H9Cl2N3

302.16 g/mole> 98% (HPLC)

C10H7BrN2

235.08 g/mole> 98% (HPLC)

C15H11N205.25 g/mole> 98% (HPLC)

C46H53BrN2O4

777.83 g/mole> 96% (NMR)

C17H11BrN2

323.19 g/mole> 98% (HPLC)

C12H6Cl2N2

249.10 g/mole> 97% (HPLC)

C10H7BrN2

235.08 g/mole> 98% (HPLC)

C15H7BrCl2N4

394.05 g/mole> 97% (HPLC)

C7H5BrN2S229.1 g/mole> 98% (HPLC)

C7H6N2S150.2 g/mole> 98% (HPLC)

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: ::

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: : :

: : :

: : :

: : :

O

OO

O

O

OO

O

NN

N

Cl

ClN N

Cl Cl

N NCl

N NBr N N

Br N NBr

SBr N

N N

NN Cl

Cl

Br

N N

NN

Br

N

N

Cl Cl

Cl

Cl

NN

Br

Br

N N

O

O

O

O

N

HN

O

NSN

Br

NSN

N

NO

O

S

S

C12H25

C12H25

C10H21

C10H21

Br

Br

K0860 1424369-37-8

C11H6ClNO203.62 g/mole> 96% (HPLC)

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Cl



Synth

etic Interm

ediates an

d R

eagents


280

K0869

K0915

K0891

K0923

K0865

K0912

K0880

K0921

K0876

K0917

K0892

K0924

208124-25-8

1671-85-8

58536-46-2

65662-88-6

132141-40-3

1429119-69-6

864377-31-1

19654-19-4

1492917-86-8

29874-83-7

864377-28-6

23038-36-0

C20H13Br2N3

455.15 g/mole> 98% (HPLC)

C12H9N5

223.23 g/mole> 98% (HPLC)

C22H15BrN2

387.27 g/mole> 98% (HPLC)

C12H9BrO2S297.17 g/mole> 98% (HPLC)

C21H14N2

294.35 g/mole> 98% (HPLC)

C48H74Br2N2O2S2

935.05 g/mole> 98% (NMR)

C21H14BrN3

388.26 g/mole> 98% (HPLC)

C13H8BrNS290.18 g/mole> 98% (HPLC)

C16H11BrN2

311.18 g/mole> 98% (HPLC)

C14H9ClN2

240.69 g/mole> 98% (HPLC)

C22H15BrN2

387.27 g/mole> 98% (HPLC)


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NN

N N

NBr Br

K0862K0861 K0863 K0864

K0911

K0878

K0918

73025-93-1 37694-95-4 946147-12-2

20077-15-0

114415-25-7

103028-31-5

C15H9BrN2

297.15 g/mole> 98% (HPLC)

C18H21NS283.43 g/mole> 98% (HPLC)

C15H10N2

218.25 g/mole> 98% (HPLC)

C16H12N2

232.28 g/mole> 98% (HPLC)


C12H11NO4

233.22 g/mole> 98% (HPLC)

C10H8BrNO238.08 g/mole> 98% (HPLC)

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S

NC6H13

NN

Br

NN

NN

N

N

Br

NH

O

O

O O

N

NN

Br

NN

Br NN

Br

S

OBr

O O

N

N

O

O

S

S

H3C

CH3

C6H13

C8H17

C6H13

C8H17

Br

Br

HN N

NN

NNN

Cl

NO

Br

N

SBr

S

Br

S

Br

O O

K0925 846-85-8


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Br



Synth

etic Interm

ediates an

d R

eagents


281

K0937

K0951

K0936

K0950

K0938

K0955

1353724-76-1

1235872-86-2

1445416-81-8

909036-46-0

23449-08-3

83817-44-1

C34H46Br2N2O2S2

738.68 g/mole> 97% (NMR)

C11H5BrClNS298.59 g/mole> 98% (HPLC)

C25H16N2S376.47 g/mole> 98% (HPLC)

C5H4ClIN2

254.46 g/mole> 98% (HPLC)

C21H14BrN3

388.26 g/mole> 98% (HPLC)

C14H9BrN2O301.14 g/mole> 98% (HPLC)

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K0957

K0939

1429119-68-5

C48H76N2O2S2

777.26 g/mole> 97% (NMR)

C21H19NS317.45 g/mole> 98% (HPLC)

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N

N

S

N

N

O

O

S

S

C10H21

C10H21

Br

Br

NN

NBr

N

S

N

NH2I

Cl SN

Br

Cl N N

O

Br N

N

O

O

S

S

C6H13

C8H17

C8H17

C6H13



Synth

etic Interm

ediates an

d R

eagents

Synthetic Intermediates and ReagentsIridium Complexes / Ligands

282

K0039

K0045

K0144

K0149

K0473

K0036

K0044

K0055

K0148

K0440

K0042

K0046

K0145

K0390

K0474

K0043

K0047

K0147

K0403

K0484

4467-06-5

612-96-4

87065-50-7

4789-76-8

883129-97-3

562824-27-5

3297-72-1

39778-14-8

4373-61-9

603109-48-4

391604-55-0

889750-37-2

837-97-8

536753-86-3

1193263-65-8

38210-35-4

435277-99-9

33893-89-9

219508-27-7

1056874-43-1

C12H11N169.22 g/mole> 98% (HPLC)

C15H11N205.25 g/mole> 98% (HPLC)

C21H23N289.41 g/mole> 98% (HPLC)

C16H13N219.28 g/mole> 98% (HPLC)

C48H20Cl2F8Ir2N8

1316.05 g/mole> 75% (NMR)

C44H24Cl2Ir2N4F8

1216.02 g/mole> 98% (NMR)

C15H11N205.25 g/mole> 98% (HPLC)

C14H13IN2

336.17 g/mole> 97% (HPLC)

C12H11N169.22 g/mole> 98% (HPLC)

C44H32Cl2Ir2N4

1072.09 g/mole> 97% (HPLC)

C11H7F2N191.18 g/mole> 98% (HPLC)

C24H19N321.41 g/mole> 98% (HPLC)

C14H9NO2

223.23 g/mole> 98% (HPLC)

C17H12N2

244.29 g/mole> 98% (HPLC)

C52H28Cl2F20Ir2N4

1544.11 g/mole> 95% (NMR)

C13H9NS211.28 g/mole> 98% (HPLC)

C24H19N321.41 g/mole> 98% (HPLC)

C6H5N5

147.14 g/mole> 98% (HPLC)

C8H5F3N4

214.15 g/mole> 97% (HPLC)

C68H56Cl2Ir2N4

1384.54 g/mole> 95% (NMR)

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: : :

: : :

: : :

: : :

: : :

N

F

F

IrCl

Cl

N

F

F

Ir

2 2

NN

F

F

S

N

NN

N

N

NC6H13

N

N+ I-

N N NN

N

OO

N NN

HNN

N

N

N NH

F3C

NIr

ClIr

Cl

N

2 2N

F

F

IrCl

Cl

N

F

F

Ir

2 2

NC CN

N

F

F

IrCl

Cl

N

F

F

Ir

2 2

F3C CF3

NIr

Cl

ClIr

N

22



Synth

etic Interm

ediates an

d R

eagents


283

K0517

K0522

K0526

K0559

K0599

K0496

K0521

K0525

K0532

K0585

K0518

K0523

K0527

K0568

K0613

K0520

K0524

K0528

K0580

K0773

81820-65-7

75415-03-1

914306-50-6

435278-09-4

65039-06-7

458541-39-4

736928-20-4

1350748-60-5

18653-75-3

1314639-66-1

25364-47-0

1056451-44-5

3974-71-8

1353762-17-0

909405-17-0

1101187-10-3


C8H7N3

145.16 g/mole> 98% (HPLC)

C11H13IN2

300.14 g/mole> 97% (HPLC)

C21H24N2

304.43 g/mole> 98% (HPLC)

C19H17N259.34 g/mole> 98% (HPLC)

C21H23N289.41 g/mole> 98% (HPLC)

C24H22N2

338.44 g/mole> 98% (HPLC)

C10H11IN2

286.11 g/mole> 97% (HPLC)

C17H13N231.29 g/mole> 98% (HPLC)

C17H11IN2

370.19 g/mole> 98% (HPLC)

C17H17NS267.39 g/mole> 98% (HPLC)

C8H7N3

145.16 g/mole> 98% (HPLC)

C10H10FIN2

304.10 g/mole> 97% (HPLC)

C14H14F2N2

248.27 g/mole> 98% (HPLC)

C15H20N2

228.33 g/mole> 98% (HPLC)

C17H15N233.31 g/mole> 98% (HPLC)

C9H6F3N3

213.16 g/mole> 98% (HPLC)

C10H11N3

173.21 g/mole> 98% (HPLC)

C17H15N233.31 g/mole> 98% (HPLC)

C13H13N183.25 g/mole> 98% (HPLC)

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NC6H13 N

N

HN

NN NH N

N

NH NN N

H

F3C

NN

I

F NN NH

N

NN

I

NN

I

N N NF

N

F

N

N

N

I NN N N

N

S

N

S



Synth

etic Interm

ediates an

d R

eagents


284

K0775

K0779

K0783

K0774

K0778

K0782

K0786

K0776

K0780

K0784

K0777

K0781

K0785

1012310-87-0

25363-46-6

26274-35-1

851775-42-3

80635-92-3

156021-08-8

101893-57-6

64291-96-9

85237-71-4

15827-72-2

C13H13N183.25 g/mole> 98% (HPLC)

C13H13N183.25 g/mole> 98% (HPLC)

C17H13N231.29 g/mole> 98% (HPLC)

C13H13N183.25 g/mole> 98% (HPLC)

C13H13N183.25 g/mole> 98% (HPLC)

C18H15N245.32 g/mole> 98% (HPLC)

C52H48Cl2Ir2N4

1184.30 g/mole> 95% (NMR)

C13H13N183.25 g/mole> 98% (HPLC)

C13H13N183.25 g/mole> 98% (HPLC)

C52H48Cl2Ir2N4

1184.30 g/mole> 95% (NMR)

C13H13N183.25 g/mole> 98% (HPLC)

C17H13N231.29 g/mole> 98% (HPLC)

C52H48Cl2Ir2N4

1184.30 g/mole> 95% (NMR)

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N N N N

N N N

NN

IrCl

IrCl

N

2 2

N

N NIr

ClIr

Cl

N

2 2

NIr

ClIr

Cl

N

2 2

K0833

K0859 K0879K0873

K0856 K085766318-88-5

1361941-59-4 25700-11-21431374-74-1

512180-22-2 135838-04-9

C15H11N205.25 g/mole> 98% (HPLC)

C12H15N3

201.27 g/mole> 98% (HPLC)

C8H7N3

145.16 g/mole> 98% (HPLC)

C11H6F3N209.17 g/mole> 98% (HPLC)

C15H9F2N241.24 g/mole> 98% (HPLC)

C9H6FNO163.15 g/mole> 98% (HPLC)

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NN

F

F

NOH

F

NN

N

N

FF

FN

NN

K0913 1008-89-5

C11H9N155.20 g/mole> 98% (HPLC)

FormulaM.W.Grade

: : :

N



Synth

etic Interm

ediates an

d R

eagents


285

K0914 K094314996-61-3 391250-41-2

IrCl3 · xH2O298.58 (anhydrous basis)>99%> 52%

C12H9F2N205.20 g/mole> 98% (HPLC)

FormulaM.W.GradeIr Content

FormulaM.W.Grade

:: : :

: : :

IrCl3 xH2OFF

N



Synth

etic Interm

ediates an

d R

eagents

Synthetic Intermediates and ReagentsSilanes Derivatives

286

K0095

K0102

K0329

K0492

K0069

K0101

K0220

K0491

K0096

K0103

K0391

K0533

K0097

K0219

K0414

K0536

852138-90-0

1160106-14-8

1160106-12-6

207742-45-8

18737-40-1

188690-66-6

1207627-85-7

207742-50-5

891182-24-4

1089687-05-7

438546-40-8

1613310-44-3

906372-08-5

8981182-24-2

18733-91-0

C24H32Br2Si508.40 g/mole> 97% (HPLC)

C24H36Br2S2Si576.57 g/mole> 97% (HPLC)

C24H38S2Si418.77 g/mole> 97% (HPLC)


C24H19BrSi415.40 g/mole> 98% (HPLC)










C28H42Si406.72 g/mole> 97% (HPLC)


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Si BrSi

Br Br SiBr Br

SiBr Br

S S

Si

Br BrS S

Si

Br Br S S

Si

Br Br S S

Si

S

Si

S S S

SiSi

Br

Br

Br

Br

Si

Si

Br Br

Si BrBrSSSi Si

Br

Br

Si

S SBr Br



Synth

etic Interm

ediates an

d R

eagents

Synthetic Intermediates and ReagentsThiophenes Derivatives

287

K0094

K0101

K0105

K0110

K0117

K0092

K0100

K0104

K0108

K0116

K0098

K0102

K0106

K0111

K0122

K0099

K0103

K0107

K0115

K0123

288071-87-4

188690-66-6

1098102-93-2

359017-65-5

1057401-13-4

15155-41-6

365547-21-3

129415-75-5

853722-91-5

1214906-01-0

528570-55-0

1160106-14-8

1000623-95-9

1226782-13-3

1308671-90-0

478404-10-3

1089687-05-7

180729-93-5

655249-04-0

258527-25-2

C14H6Br2N2S3

458.21 g/mole> 98% (HPLC)


C19H26Br2O2S2

510.35 g/mole> 98% (HPLC)

C22H28Br2O2S2

548.39 g/mole> 98% (HPLC)

C30H38Br2N2O2S2

682.57 g/mole> 98% (NMR)

C6H2Br2N2S293.97 g/mole> 98% (HPLC)

C25H36Br2S2

560.49 g/mole> 98% (HPLC)

C26H36Br2O2S2

604.50 g/mole> 98% (HPLC)

C26H30Br2N2S4

658.60 g/mole> 98% (HPLC)

C26H30Br2N2O2S2

626.47 g/mole> 98% (NMR)

C21H28Br2S2

504.39 g/mole> 98% (HPLC)


C30H38Br2N2O2S2

682.57 g/mole> 98% (NMR)

C26H36Br2O2S2

604.50 g/mole> 98% (HPLC)

C30H39BrN2O2S2

603.68 g/mole> 98% (NMR)

C25H36Br2S2

560.49 g/mole> 98% (HPLC)


C18H26Br2N2S2

494.35 g/mole> 98% (HPLC)

C14H17BrS2

329.32 g/mole> 95% (HPLC)

C9H4Br2S2

336.07 g/mole> 98% (HPLC)

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NS

NS SBr Br

S SBr BrS SBr Br

NS

N

Br Br

S S

Si

Br BrS S

Si

Br Br S S

Si

Br BrS SBr Br

S

S

Br

O OC12H25

Br

N

NO

O

SSBr

BrS

SBr Br

O

O

N

SN

S

C6H13

C6H13

Br Br

N

SN

S

C6H13

C6H13

S

SBr

BrS

SO

O

Br BrS

SO

O

Br BrS SBr

N

NO

O

SSBr Br

N

NO

O

S

SBrBr

N

NS S

O

O

Br

SSBr Br



Synth

etic Interm

ediates an

d R

eagents


288

K0130

K0213

K0220

K0264

K0271

K0127

K0212

K0219

K0263

K0132

K0214

K0260

K0268

K0272

K0140

K0216

K0262

K0269

K0276

389-58-2

1160823-77-7

1207627-85-7

1185885-86-2

492-97-7

1693-86-3

359017-55-3

906372-08-5

852435-01-9

116971-11-0

1098102-94-3

566939-58-0

444177-63-3

173448-31-2

32281-36-0

333432-27-2

1057401-08-7

149703-84-4

250-84-0

C9H6S2

178.27 g/mole> 98% (HPLC)

C26H38O2S2

446.71 g/mole> 98% (HPLC)


C30H40N2O2S2

524.78 g/mole> 97% (NMR)

C8H6S2

166.26 g/mole> 97% (HPLC)

C10H16S168.30 g/mole> 98% (HPLC)

C22H30O2S2

390.60 g/mole> 98% (HPLC)


C26H32N2O2S2

468.67 g/mole> 97% (NMR)

C10H14Br2S326.09 g/mole> 98% (HPLC)

C26H38O2S2

446.71 g/mole> 98% (HPLC)

C14H17Br2NO2S423.16 g/mole> 98% (HPLC)


C14H18S2

250.42 g/mole> 98% (HPLC)

C10H4O2S2

220.27 g/mole> 98% (HPLC)

C5HBr2N3S294.95 g/mole> 98% (HPLC)

C30H40N2O2S2

524.78 g/mole> 97% (NMR)


C6H4S2

140.23 g/mole> 98% (HPLC)

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S

S S

S

C6H13

Br Br S

SO

O

S

SO

OS

SO

O

S

SO

O N

NS

N

Br Br

S

NO O

Br Br

S S

Si

S

Si

S

N

NS S

O

O

SBr BrN

N

S

S

O

ON

N

SS

O

O SBr Br

S S S S S S

K0277 251-41-2

C6H4S2

140.23 g/mole> 98% (HPLC)

FormulaM.W.Grade

: : :

S

S



Synth

etic Interm

ediates an

d R

eagents


289

K0278

K0282

K0286

K0290

K0297

K0281

K0285

K0289

K0293

K0279

K0283

K0287

K0291

K0298

K0280

K0284

K0288

K0292

K0305

4805-22-5

69249-61-2

145543-83-5

104934-52-3

566939-56-8

116971-10-9

1081-34-1

148256-63-7

162151-09-9

3593-75-7

211737-28-9

158956-23-1

139100-06-4

1231160-83-0

2404-89-9

98057-08-0

65016-55-9

132814-91-6

121134-38-1

C8H4Br2S2

324.06 g/mole> 98% (HPLC)



C16H28S252.46 g/mole> 98% (HPLC)



C12H8S3

248.39 g/mole> 98% (HPLC)


C40H58S4

667.15 g/mole> 97% (HPLC)

C8H4S3

196.31 g/mole> 97% (HPLC)





C8H6S2

166.26 g/mole> 96% (HPLC)

C12H6Br2S3

406.18 g/mole> 98% (HPLC)

C14H24S224.41 g/mole> 98% (HPLC)

C28H34S4

498.83 g/mole> 98% (HPLC)

C12H20S196.35 g/mole> 98% (HPLC)

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S SBr BrS

SS

S SSBr Br

S Br

SBrS

SSBr BrS

SS

S BrS

C10H21

Br Br S

C10H21

S Br

C12H25

Br

S

C12H25

S Br

C12H25

SS

S

SS

SSS

C12H25

C12H25

S

NO O

Br BrS

NO O

Br Br S

K0307 65016-62-8

C12H20S196.35 g/mole> 98% (HPLC)

FormulaM.W.Grade

: : :

S



Synth

etic Interm

ediates an

d R

eagents


290

K0308

K0314

K0329

K0376

K0382

K0313

K0317

K0368

K0381

K0309

K0315

K0330

K0379

K0383

K0312

K0316

K0343

K0380

K0393

303734-52-3

1000623-98-2

1160106-12-6

1134789-63-1

143746-72-9

942435-50-9

1352440-42-6

88-13-1

888491-16-5

144012-09-9

180729-92-4

1049034-71-0

182631-76-1

25143-53-5

609369-40-6

1024594-86-2

2536-91-6

753470-95-0

31574-87-5


C46H70Br2N2O2S2

907.00 g/mole> 98% (NMR)


C15H6Br3N3S3

564.14 g/mole> 98% (HPLC)

C18H8O2S2

320.38 g/mole> 98% (NMR)

C16H20S2

276.46 g/mole> 97% (HPLC)

C13H6Br2OS2

402.12 g/mole> 98% (HPLC)

C5H4O2S128.15 g/mole> 97% (HPLC)

C36H60Br2S2

716.80 g/mole> 98% (HPLC)


C18H28N2S2

336.56 g/mole> 98% (HPLC)

C64H72Br2S2

1065.19 g/mole> 98% (HPLC)

C18H12N2S2

320.43 g/mole> 98% (HPLC)

C8H2Br4S2

481.85 g/mole> 98% (HPLC)

C15H18OS2

278.43 g/mole> 98% (HPLC)

C7H2Br2O2S2

342.03 g/mole> 98% (HPLC)


C32H52Br2S2

660.69 g/mole> 98% (HPLC)


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S Br

S

C10H21

Br SS

SS

OHC

N

S

C6H13

N

S

C6H13N

NS S

O

O

BrBr

C6H13

C8H17

C6H13

C8H17

S

S

Br Br

O

S

S

C6H13 C6H13

C6H13 C6H13

Br

Br

S

S

Br Br

COOH

S S

Si

N

N

N

S

S

S

Br

Br

Br

S N N

SS

SBr Br

C12H25

C12H25

S

NH2N

SO

HO

SSBr Br

Br

BrS

Br Br

S

SO

O

SSBr Br

C14H29

C14H29

K0407 153312-86-8

C21H30S2

346.59 g/mole> 98% (HPLC)

FormulaM.W.Grade

: : :

S S



Synth

etic Interm

ediates an

d R

eagents


291

K0408

K0416

K0424

K0428

K0438

K0415

K0423

K0427

K0435

K0409

K0421

K0425

K0431

K0443

K0411

K0422

K0426

K0434

K0444

4282-29-5

6007-85-8

1262727-09-2

1086429-77-1

25792-77-4

165617-59-4

1202249-72-6

773881-47-3

936711-08-9

1286745-60-5

2160-62-5

1347736-74-6

1362678-15-6

120451-23-3

1286745-57-0

1160823-76-6

1295502-53-2



C20H17Br2NO2S3

559.36 g/mole> 98% (HPLC)


C25H39NS2

417.71 g/mole> 98% (HPLC)

C9H4OS2

192.26 g/mole> 98% (HPLC)

C28H32Br2N2S2

620.51 g/mole> 98% (HPLC)

C6Br2N4S2

352.03 g/mole> 98%

C14H15Br2FOS2

442.20 g/mole> 98% (HPLC)


C32H40Br2N2S2

676.61 g/mole> 98% (HPLC)

C22H21Br2NO2S3

587.4 g/mole> 98% (HPLC)

C5H2BrNS188.05 g/mole> 98% (HPLC)

C6HBr2FN2S311.96 g/mole> 98% (HPLC)

C40H56Br2N2S2

788.82 g/mole> 98% (HPLC)

C32H40Br2N2S2

676.61 g/mole> 98% (HPLC)

C22H21Br2NO2S3

587.41 g/mole> 98% (HPLC)

C15H17Br2FO2S2

472.23 g/mole> 98% (HPLC)

C6Br2F2N2S329.95 g/mole> 98% (HPLC)

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: : :

S

HOOC COOH

S

NO O

C12H25

Br Br

NN

C12H25 C12H25

S

S

Br

Br

S S

O

OS

O

O

NN

C8H17 C8H17

S

S

Br

BrNN

S

S

Br

Br

NN

C6H13 C6H13

S

S

Br

Br

N

S

O O

S

S

Br

Br

C6H13

N

S

O O

S

S

Br

Br

N

S

O O

S

S

Br

Br

C8H17

SBr CNS

S

F

BrBr

O OC8H17

NS

N

NS

N

Br Br

NS

N

Br Br

N N

N

S S

NN S

F

Br

Br

NN S

FF

Br

Br

S

S

Br Br

O

F

K0445 1260685-63-9

C54H86Br2N2O2S2

1019.21 g/mole> 98% (NMR)

FormulaM.W.Grade

: : :

N N

O

O

S

S

C8H17

C10H21

C8H17

C10H21

Br

Br



Synth

etic Interm

ediates an

d R

eagents


292

K0448 K0461

K0472

K0491

K0495

K0460

K0471

K0479

K0494

K0462

K0475

K0492

K0500

K0459

K0466

K0478

K0493

K0501

51751-44-1 1237479-39-8

943920-67-0

207742-50-5

1192352-10-5

1335150-10-1

1158270-38-2

1331742-86-9

365547-20-2

1314801-37-0

207742-45-8

1071224-34-4

89331-93-1

1283598-36-6

153312-87-9

C8H4Br2S2

324.06 g/mole> 98% (HPLC)

C15H17Br2FO2S2

472.23 g/mole> 98% (HPLC)

C25H39NS2

417.71 g/mole> 98% (HPLC)


C30H38Br2N2O2S3

714.64 g/mole> 98% (HPLC)


C21H31NS2

361.61 g/mole> 98% (HPLC)


C25H38S2

402.70 g/mole> 98% (HPLC)

C14H16Br2O2S2

440.21 g/mole> 98% (HPLC)

C30H38Br2N2O3S2

698.57 g/mole> 98% (HPLC)


C44H66S4

723.25 g/mole> 97% (HPLC)

C7H3BrN2OS243.08 g/mole> 98% (HPLC)

C18H17NS279.40 g/mole> 98% (HPLC)

C30H36Br2F2N2S3

718.62 g/mole> 98% (HPLC)

C25H38S2

402.70 g/mole> 98% (HPLC)

C34H46S4

582.99 g/mole> 97% (HPLC)

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

S

S

Br

BrN

N SOHC

Br

NN S

Br

NC

NC

S

SF

O O

Br Br

S

S

O OC7H15

Br Br

N

S

S

N

S

C8H17C8H17

C8H17O OC8H17

NO

NS

S Br

Br

FF

S

C8H17

S

C8H17

NS

NBr Br

S

N

S

C6H13C6H13

SSSi Si

Br

Br

Si

S SBr Br S S

C8H17 C8H17

NC

NS

N

Br

S SC8H17O OC8H17

NS

NS SBr Br

SS

SS

C14H29

C14H29

SS

SS

C9H19

C9H19

K0504 850583-75-4

C14H8N2O2S2

300.36 g/mole> 98% (NMR)

FormulaM.W.Grade

: : :

HN

NH

O

O

S S

K0505 133546-47-1

C10H4N4S2

244.30 g/mole> 98% (HPLC)

FormulaM.W.Grade

: : :

NS N

NSN



Synth

etic Interm

ediates an

d R

eagents


293

K0514

K0537

K0548

K0513

K0518

K0540 K0547

K0509

K0515

K0538

K0553

K0511

K0517

K0539

K0554

305800-44-6

1015071-23-4

1224709-68-5

1613310-44-3

1350748-60-5

1352642-35-3 217-19-6

1352743-83-9

339985-36-3

1421862-27-2

143367-56-0

153938-81-9

81820-65-7

1356371-05-5

1160823-78-8

C9H11BrOS247.15 g/mole> 98% (HPLC)

C18H6F2O2S2

356.37 g/mole> 97%

C38H54Br2N2O2S2

794.79 g/mole> 98% (HPLC)


C17H17NS267.39 g/mole> 98% (HPLC)

C34H42S4

578.96 g/mole> 98% (HPLC)

C14H8S2

240.34 g/mole> 98% (HPLC)

C14H15Br2FOS2

442.20 g/mole> 98% (HPLC)

C30H18Br3NS3

728.38 g/mole> 98% (HPLC)

C34H42O2S2

546.83 g/mole> 98% (HPLC)

C14H22S2Sn2

491.87 g/mole> 98% (NMR)

C24H26S4

442.72 g/mole> 98% (HPLC)


C16H14Br2O2S2

462.22 g/mole> 98% (HPLC)

C32H54O2S2Sn2

772.32 g/mole> 98% (NMR)

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

S

S

BrBr

F

O

SSS

S S

NC

CNBr SO

BrH

N

S

Br

S Br

S

Br

N

S

N

S

S

SO

O

F F

S

S

OO

O

O

SS

Br

Br

S

S

S

SS

S

S S SnSn

S

S

Sn

Sn

OONN

O

O

S

S

Br

Br

K0555 1049034-67-4

C64H74S2

907.4 g/mole> 98% (HPLC)

FormulaM.W.Grade

: : :

S

S

C6H13

C6H13

C6H13

C6H13

K0556 K0557 K0558851486-39-0 1192352-08-1 1267540-02-2


C22H34Br2N2O2S550.39 g/mole> 98% (HPLC)

C54H88N2O2S2

861.42 g/mole> 98% (NMR)

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

N N

BrBr

NS

N

OC8H17

BrBr

NS

N

C8H17ON

NO

O

SS

C8H17C10H21

C8H17C10H21

K0560 1352642-37-5

C40H58S4Sn2

904.57 g/mole> 98% (NMR)

FormulaM.W.Grade

: : :

S

S

S

S

Sn Sn



Synth

etic Interm

ediates an

d R

eagents


294

K0636 1270977-96-2

C58H86Br2N2O2S4

1131.38 g/mole> 98% (NMR)

FormulaM.W.Grade

: : :

K0562 K0616

K0622

K0629

K0594

K0621

K0625

K0617

K0623

K0630

K0572

K0620

K0624

K0631

1295502-20-3 143469-11-8

135831-08-2

1391764-83-2

190723-12-7

1264297-33-7

1044598-80-2

128032-22-4

155166-89-5

1098102-95-4

118726-30-0

86134-26-1

1354631-87-0

1044795-08-5

C29H46OS2

474.8 g/mole> 98% (HPLC)

C10H2BrF13S481.07 g/mole> 98% (HPLC)

C24H32S3

416.71 g/mole> 97% (HPLC)

C40H58O2S2Sn2

872.44 g/mole> 98% (NMR)

C6H2Br2O4S329.95 g/mole> 98% (HPLC)

C26H32N2O2S2

686.71 g/mole> 97% (HPLC)

C46H72N2O2S2

749.21 g/mole> 98% (NMR)

C10H3F13S402.18 g/mole> 98% (HPLC)

C28H40S3

472.81 g/mole> 97% (HPLC)

C32H54O2S2Sn2

772.32 g/mole> 98% (NMR)

C11H6ClNS219.69 g/mole> 98% (HPLC)

C10H20SSn2

409.75 g/mole> 98% (NMR)

C38H56N2O2S2

636.99 g/mole> 98% (NMR)

C40H70O2S2Sn2

884.53 g/mole> 98% (NMR)

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

O

S S

SN

Cl

S

HOO

OHO

Br BrS C6F13Br

S C6F13 SSn Sn S

SS

C10H21C10H21

Br

Br

S

SS

C8H17C8H17

S

SS

C6H13C6H13

N

NO

O

SS

C6H13

C4H9

C4H9

C6H13N

NO

O

SS

C8H17

C6H13

C6H13

C8H17

O

OSnSn

S

S

S

S

O

O

SnSn

C8H17

C8H17

S

S

O

O

SnSn

C12H25

C12H25

K0632 1160823-80-2

C32H54S2Sn2

740.32 g/mole> 98% (NMR)

FormulaM.W.Grade

: : :

S

SSnSn

C8H17

C8H17

K0633

K0634 K0635

1234306-33-2

215591-73-4 1369657-88-4

C40H70S2Sn2

852.53 g/mole> 98% (NMR)

C24H30Br2S3

574.50 g/mole> 97% (HPLC)

C50H70Br2N2O2S4

1019.17 g/mole> 98% (NMR)

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

S

SSnSn

C12H25

C12H25

N

N

O

O

S

SS

S

BrBr

C8H17

C6H13

C8H17 C6H13

S

SS

C6H13C6H13

Br

Br

K0637

C26H78Br4N2O2S2

784.26 g/mole> 98% (NMR)

FormulaM.W.Grade

: : :

N

N

O

O

S

S

Br

Br

Br

Br

N

N

O

O

S

S

C10H21

C10H21

C8H17

C8H17

S

S

BrBr



Synth

etic Interm

ediates an

d R

eagents


295

K0646

K0653

K0657

K0644

K0652

K0656

K0640

K0648

K0654

K0658

K0641

K0651

K0655

K0659

1383628-43-0

469912-82-1

1220888-35-6

1100761-34-9

1065645-75-1

1143585-35-6

1364488-29-8

1007347-63-8

1048694-54-7

1122708-93-3

1346837-43-1

C72H88Br2S2

1177.41 g/mole> 98% (HPLC)

C12H20S2Sn2

465.84 g/mole> 98%

C20H33NS2Sn2

589.03 g/mole> 98%

C44H48Br2N2O2S2

860.8 g/mole> 98% (HPLC)

C42H78S2Sn2

884.62 g/mole> 98% (NMR)

C26H45NS2Sn2

673.19 g/mole> 95% (NMR)

C54H74Br2N2O4S6

1071.25 g/mole> 98% (NMR)

C44H48Br2N2O2S2

860.8 g/mole> 98% (HPLC)

C38H70S2Sn2

828.51 g/mole> 98% (NMR)

C23H33Br2NS2

547.45 g/mole> 98% (HPLC)

C62H90Br2N2O4S6

1183.46 g/mole> 98% (NMR)

C38H70S2Sn2

828.51 g/mole> 98% (NMR)

C42H78S2Sn2

884.62 g/mole> 98% (NMR)

C25H37Br2NS2

575.51 g/mole> 98% (HPLC)

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

N

N

O

O

S

S

C8H17

C8H17

C6H13

C6H13

S

S

Br

Br

N

N

O

O

S

S

S

S

Br

Br

C10H21

C8H17

C10H21C8H17

NN

SS

OC8H17C8H17O

Br Br

S

SC8H17

C8H17

C8H17

C8H17 Br

Br

NN

SS

OO

Br BrS

S

C12H25

C12H25Sn

Sn SSn

S

C14H29

C14H29Sn

S

SSnSn

S

SC12H25

C12H25Sn

Sn

S

SC14H29

C14H29Sn

Sn N

SS SnSn

C12H25

N

SS SnSn

C6H13

N

SS

C6H13

BrBr

C8H17

N

SS BrBr

C8H17 C8H17

K0660 1346688-54-7

C16H19Br2NS2

449.27 g/mole> 98% (HPLC)

FormulaM.W.Grade

: : :

N

SS BrBr

C8H17

K0661

K0662 K0663

1250951-96-2

1346137-62-9 1382494-87-2

C16H19Br2NS2

449.27 g/mole> 98% (HPLC)

C20H27Br2NS2

505.37 g/mole> 98% (HPLC)

C14H15Br2NS2

421.21 g/mole> 98% (HPLC)

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

N

SS BrBr

N

SS BrBr

C12H25

N

SS BrBr

C6H13

K0664 1025451-57-3

C20H24N2S3Sn2

626.03 g/mole> 98% (HPLC)

FormulaM.W.Grade

: : :

NS

N

SSSn Sn

K0665 272-43-5


FormulaM.W.Grade

: : :

S

NN



Synth

etic Interm

ediates an

d R

eagents


296

K0689 345633-76-3

C32H54S2

502.9 g/mole> 98% (HPLC)

FormulaM.W.Grade

: : :

SS

C12H25

C12H25

K0669

K0673

K0682

K0668

K0672

K0679

K0666

K0674

K0683

K0667

K0671

K0675

K0684

1160823-85-7

1279083-60-1

1160823-81-3

1044795-04-1

1260224-09-6

25121-87-3

141029-75-6

1044795-06-3

124638-53-5

868173-44-8

C34H52Br2N4S2

740.74 g/mole> 98% (HPLC)

C15H18Br2O2S2

454.24 g/mole> 98% (HPLC)

C72H90S2

1019.62 g/mole> 98% (HPLC)

C10H4Br2N4S2

404.1 g/mole> 98% (HPLC)

C15H18Br2O2S2

454.24 g/mole> 98% (HPLC)

C34H54O2S2

558.92 g/mole> 98% (HPLC)

C26H36Br2N4S2

628.53 g/mole> 98% (HPLC)

C6H2Br2S2

298.02 g/mole> 98% (HPLC)

C16H21NS2

291.47 g/mole> 98% (HPLC)

C26H36Br2N4S2

628.53 g/mole> 98% (HPLC)

C34H52Br2O2S2

716.71 g/mole> 98% (HPLC)

C6Br4S2

455.81 g/mole> 98% (HPLC)

C16H21NS2

291.47 g/mole> 98% (HPLC)

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

N

NN

N

S

S

Br

Br N

NN

N

S

S

Br

Br

C8H17

C8H17 N

NN

N

S

S

Br

Br N

NN

N

S

S

Br

Br

C12H25

C12H25

S

SBrBr

O

O

C12H25

C12H25

S

S

BrBr

OO

S

S

BrBr

OOC8H17

S

SBrBr

S

SBrBr

Br

BrS

SO

OC12H25

C12H25

S

S C8H17

C8H17

C8H17

C8H17

N

SS

C8H17

N

SS

K0685

C24H37NS2

389.66 g/mole> 98% (HPLC)

FormulaM.W.Grade

: : :

N

SS

C6H13 C8H17

K0686 K0687

K0688

185350-30-5 135926-94-2

120762-66-5

C28H38Br2S3

630.6 g/mole> 98% (HPLC)

C20H30S2

334.58 g/mole> 98% (HPLC)

C24H38S2

390.69 g/mole> 98% (HPLC)

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

SS

C6H13

C6H13

SS

C8H17

C8H17

S

SS

C8H17C8H17

Br

Br

K0690 K06911327275-63-7 138058-53-4

C36H62S2

550.94 g/mole> 98% (HPLC)

C24H38S2

390.69 g/mole> 98% (HPLC)

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

SS

C14H25

C14H25

SS

C8H17

C8H17



Synth

etic Interm

ediates an

d R

eagents


297

K0694

K0698

K0702

K0693

K0697

K0701

K0695

K0699

K0703

K0692

K0696

K0700

K0704

211737-46-1

31486-86-9

95748-95-1

1357811-10-9

1260224-08-5

165190-76-1

40985-58-8

125607-30-9

59918-60-4

1279083-55-4

C20H30S2

334.58 g/mole> 98% (HPLC)

C7H4OS2

168.24 g/mole> 98% (HPLC)

C26H38N4S2

470.74 g/mole> 98% (HPLC)

C24H38S2

390.69 g/mole> 98% (HPLC)

C22H36S2

364.65 g/mole> 98% (HPLC)

C26H38N4S2

470.74 g/mole> 98% (HPLC)

C14H8N2S3

300.42 g/mole> 98% (HPLC)

C7H3NS2

165.24 g/mole> 98% (HPLC)

C34H54N4S2

582.95 g/mole> 98% (HPLC)

C20H30S2

334.58 g/mole> 98% (HPLC)

C18H28S2

308.54 g/mole> 98% (HPLC)

C10H6N4S2

246.31 g/mole> 98% (HPLC)

C22H30N4S2

414.63 g/mole> 98% (HPLC)

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

SS

C6H13

C6H13

SS

C8H17C8H17S

SC6H13C6H13

NS

N

SS

S

SC6H13 C6H13

S

SC8H17 C8H17

S

S CHO

S

S CN

N N

NN

S

S

N N

NN

S

S

N N

NN

S

SC8H17

C8H17N N

NN

S

SC12H25

C12H25

N N

NN

S

S

C6H13

C6H13

K0705

C26H38N4S2

470.74 g/mole> 98% (HPLC)

FormulaM.W.Grade

: : :

N N

NN

S

S

C8H17

C8H17

K0706 K0707

K0708 1057401-11-2

C26H38N4S2

470.74 g/mole> 98% (HPLC)

C34H54N4S2

582.95 g/mole> 98% (HPLC)

C38H44N2O2S4

689.03 g/mole> 98% (HPLC)

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

N N

NN

S

S

N N

NN

S

S

C12H25

C12H25

N

N

O

O

SS

SS

C8H17

C8H17

K0709 1269004-56-9

C38H44N2O2S4

689.03 g/mole> 98% (NMR)

FormulaM.W.Grade

: : :

N

N

O

O

SS

SS

K0710 K0711 1143585-34-5

C46H60N2O2S4

801.24 g/mole> 98% (NMR)

C54H76N2O2S4

913.45 g/mole> 98% (NMR)

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

N

N

O

O

SS

SS

C6H13C4H9

C4H9C6H13

N

N

O

O

SS

SS

C6H13

C6H13

C8H17

C8H17



Synth

etic Interm

ediates an

d R

eagents


298

K0714

K0718

K0722

K0713

K0717

K0721

K0715

K0719

K0723

K0712

K0716

K0720

K0724

1270977-94-0

1286745-49-0

13130-50-2

1632448-66-8

773881-44-0

7342-41-8

1231160-82-9

188917-41-1

100943-46-2

1474061-53-4

773881-43-9

188917-43-3

73792-02-6

C58H88N2O2S4

973.59 g/mole> 98% (NMR)

C22H23NO2S3

429.62 g/mole> 98% (HPLC)

C14H8O2S3

304.41 g/mole> 98% (HPLC)

C50H72N2O2S4

861.38 g/mole> 98% (NMR)

C18H27NO2S321.48 g/mole> 98% (HPLC)

C13H8OS3

276.4 g/mole> 98% (HPLC)


C24H32S3

416.71 g/mole> 98% (HPLC)

C11H16OS196.31 g/mole> 98% (HPLC)

C62H92N2O2S4

1025.67 g/mole> 98% (NMR)


C28H40S3

472.81 g/mole> 98% (HPLC)

C13H20OS224.36 g/mole> 98% (HPLC)

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

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FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

N

N

O

O

SS

SS

C10H21

C8H17

C8H17

C10H21

N

N

O

O

S

S

C6H13

C6H13

C8H17

C8H17

S

S N

N

O

O

S

S

C10H21

C10H21

C8H17

C8H17

S

S

N

S

OO

N

S

OO

C8H17

N

S

OO

C12H25

N

S

OO

C8H17

SS

S SSC6H13 C6H13

S SSC8H17 C8H17

S SSCHO

S SSCHOOHC

SC6H13 CHO

SC8H17 CHO

K0725 93164-73-9

C16H22S2

278.48 g/mole> 98% (HPLC)

FormulaM.W.Grade

: : :

SC8H17 S

K0726 K0731

K0732

172514-64-6 3779-27-9

32364-72-0

C16H21BrS2

357.37 g/mole> 98% (HPLC)

C9H6OS2

194.27 g/mole> 98% (HPLC)

C10H6O2S2

222.28 g/mole> 98% (HPLC)

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

SC8H17 S

BrS S

CHO

S SCHOOHC

K0733 945265-56-5

C17H22OS2

306.49 g/mole> 98% (HPLC)

FormulaM.W.Grade

: : :

S SCHOC8H17

K0734 K0735872-31-3 1003-09-4



FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

S

Br

S Br



Synth

etic Interm

ediates an

d R

eagents


299

K0738

K0742

K0737

K0741

K0745

K0739

K0743

K0736

K0740

K0744

3141-27-3

932-95-6

3141-26-2

98-03-3

52431-30-8

3598-03-0

16278-99-2

400713-59-9

3141-24-0

110230-97-2




C5H4OS112.15 g/mole> 98% (HPLC)

C4Br2N2O4S331.93 g/mole> 98% (HPLC)

C4Br4S399.72 g/mole> 98% (HPLC)

C9H5NS2

191.27 g/mole> 98% (HPLC)

C32H48S3

528.92 g/mole> 97% (HPLC)

C4HBr3S320.83 g/mole> 98% (HPLC)

C13H7NS3

273.4 g/mole> 98% (HPLC)

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

S

BrBrS

SS

C10H21C10H21 SBr Br

SBr Br

Br Br

SBr Br

Br

S CHO S CHOOHC S SCN

S SCN

S BrS

Br

O2N NO2

K0816 1224430-28-7

C62H102Br2N2O2S2

1131.42 g/mole> 98% (NMR)

FormulaM.W.Grade

: : :

K0820 1192352-09-2

C30H40N2O2S3

556.85 g/mole> 98% (HPLC)

FormulaM.W.Grade

: ::

OC8H17

NS

N

C8H17O

S

S

K0822K0821 K0823

K0825

207805-24-1 1234306-29-6

1359115-82-4

C22H14Br2N4O2S558.25 g/mole> 98% (HPLC)


C26H38S2

414.71 g/mole> 98% (HPLC)

C30H37Br2NO2S3

699.62 g/mole> 98% (HPLC)

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: ::

: ::

: ::

: ::

S

NN

Br Br

Br

BrN

NS N

N

O

O

S

S

S

N OO

C6H13

C8H17

SSBr Br

K0819 40985-58-8

C7H3NS2

165.24 g/mole> 98% (HPLC)

FormulaM.W.Grade

: : :

S

SN

K0826 1112384-50-5

C14H6Br2N2S4

490.28 g/moleFormulaM.W.

: :

N

S

S

N

S

SBr

Br

K0827 K0828 291535-21-2

C31H40N2O3S3

584.86 g/mole> 98% (HPLC)

C11H15BrOS275.21 g/mole> 98% (HPLC)

FormulaM.W.Grade

FormulaM.W.Grade

: ::

: ::

O OC8H17 C8H17

NS

NS

S

H

O

SBr O

H

N

NO

O

S

S

C12H25

C12H25

C10H21

C10H21

Br

Br



Synth

etic Interm

ediates an

d R

eagents


300

K0902

K0926

22439-61-8

1494614-27-5


C14H20S2

252.44 g/mole> 98% (HPLC)

FormulaM.W.Grade

FormulaM.W.Grade

: ::

: ::

K0870

K0960

K0836

K0905 K0927

1342311-48-1

636588-79-9

13640-78-3

34722-01-5 1494614-30-0

C29H39BrOS3

579.72 g/mole> 98% (HPLC)

C9H2Br2OS2

350.05 g/mole> 98% (HPLC)

C10H8S2

192.3 g/mole> 98% (HPLC)

C8H12S140.25 g/mole> 98% (HPLC)

C38H42S6

691.13 g/mole> 96% (HPLC)

FormulaM.W.Grade

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FormulaM.W.Grade

: : :

: : :

: : :

: : :

: : :

SS

S

C8H17

C8H17 O

H

Br

SS

K0854

K0910

K0958

2255-80-3

1283598-36-6

1190764-15-8


C30H36Br2F2N2S3

718.62 g/mole> 98% with isomers (HPLC)

C25H17Br2NOS539.28 g/mole> 98% (HPLC)

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

NN S

Br

S

Br

SN

SN

FF

S SBr Br

C8H17 C8H17 S

S

S

S

S

S

S

S

N

Br

Br

SCHO

S S

O

Br Br



Synth

etic Interm

ediates an

d R

eagents

Synthetic Intermediates and ReagentsBenzene Derivatives

301

K0008

K0079

K0118

K0146

K0338

K0007

K0078

K0109

K0142

K0337

K0059

K0090

K0129

K0211

K0339

K0072

K0091

K0131

K0335

K0350

17919-34-5

787-70-2

3268-21-1

129013-83-8

106-37-6

69571-02-4

1591-30-6

156682-52-9

13029-09-9

626-39-1

6942-99-0

146370-51-6

16400-50-3

91371-12-9

589-87-7

96761-85-2

209625-37-6

439797-69-0

643-79-8

936-59-4

C22H32O6P2

454.43 g/mole> 98% (HPLC)

C14H10O4

242.23 g/mole> 98% (HPLC)

C10H12I2

386.01 g/mole> 98% (HPLC)


C6H4Br2

235.90 g/mole> 98% (HPLC)

C14H12I2

434.05 g/mole> 98% (HPLC)

C14H8N2

204.23 g/mole> 98% (HPLC)

C6H2Br2F2

271.88 g/mole> 98% (HPLC)

C12H8Br2

312.00 g/mole> 98% (HPLC)

C6H3Br3

314.80 g/mole> 98% (HPLC)

C9H10Br2

277.98 g/mole> 98% (HPLC)

C15H24O2

236.35 g/mole> 98% (HPLC)

C12H6Br4

469.79 g/mole> 96% (HPLC)

C12H6Br2N2O4

402.00 g/mole> 98% (HPLC)

C6H4BrI282.90 g/mole> 98% (HPLC)

C24H15Br3

543.09 g/mole> 98% (HPLC)

C17H26Br2O2

422.20 g/mole> 97% (HPLC)

C12H7Br2NO2

357.00 g/mole> 98% (HPLC)

C8H6O2

134.13 g/mole> 97% (HPLC)

C9H9ClO168.62 g/mole> 97% (HPLC)

FormulaM.W.Grade

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II

CH3

H3C

POEtOOEt

PEtO

OEtO

BrBr

BrBr

Br

NC CN HOOC COOH

O

O

O

OBr

Br

Br Br

F FI I

Br

Br Br

Br

Br Br

NO2

Br

Br

BrN

Br Br

NO2

O2N

Br

Br

Br Br Br

CHOOHC

I Br

O

Cl



Synth

etic Interm

ediates an

d R

eagents


302

K0352

K0358

K0395

K0570

K0598

K0351

K0357

K0394

K0569

K0587

K0354

K0385

K0410

K0574

K0610

K0356

K0389

K0456

K0586

K0614

92-86-4

92-66-0

103068-20-8

84907-53-9

86949-86-2

3988-03-2

1122-91-4

500729-84-0

18869-30-2

1415633-83-8

611-97-2

852138-89-7

24239-82-5

1650594-31-2

15796-82-4

7511-49-1

1100761-32-7

93869-52-4

860815-31-2

C12H8Br2

312.00 g/mole> 98% (HPLC)


C18H13Br309.20 g/mole> 98% (HPLC)

C16H12O2

236.27 g/mole> 98% (HPLC)

C14H13Cl216.71 g/mole> 98% (HPLC)



C18H10Cl4368.08 g/mole> 98% (HPLC)

C14H10Br2

338.04 g/mole> 98% (HPLC)

C30H21Br2OP588.27 g/mole> 98% (HPLC)

C15H14O210.27 g/mole> 98% (HPLC)

C12H6Br2I2

563.79 g/mole> 96% (HPLC)

C6H2Br2N2O4

325.90 g/mole> 98% (HPLC)

C39H32O6S2

660.8 g/mole> 98% (HPLC)

C22H36O10

460.52 g/mole> 98% (HPLC)

C21H26O294.43 g/mole> 98% (HPLC)

C24H15Br3

543.09 g/mole> 98% (HPLC)

C30H42O4

466.65 g/mole> 98% (HPLC)

C18H13Br2OP436.08 g/mole> 98% (HPLC)

C18H27BrO3

371.31 g/mole> 98% (HPLC)

FormulaM.W.Grade

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: : :

O

Br Br

Br Br

OO

OBr Br BrBr

I

I

Br

Br Br

Cl

Cl

Cl

Cl

BrBr Br

O2N NO2

OC8H17

O O

C8H17O

BrBr

O

OH

H OTsTsO PO

Br

Br

PO

Br

BrCl

OO

O

OH

OO

OO

O

O

Br O

O O



Synth

etic Interm

ediates an

d R

eagents


303

K0647

K0758

K0615

K0757

K0649 K075669272-50-0

96392-77-7

746633-97-6

121623-97-0

498572-72-8 287919-00-0

C6H6Br2N2

265.93 g/mole> 98% (HPLC)

C16H14Br2

366.09 g/mole> 96% (HPLC)

C18H27BrO2

355.31 g/mole> 98% (HPLC)

C9H2F4N2

214.12 g/mole> 98% (HPLC)

C30H42O4

466.65 g/mole> 98% (HPLC)

C19H30Br2O2

450.25 g/mole> 98% (HPLC)

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

: : :

: : :

: : :

Br

O OBrBr

NH2H2N

OO

OO

BrBr

O

O

F F

F F

NCCN Br

Br

K0928

K0946

K0971

K0900

K0945

K0954

K0929 K094452827-70-0

2368-49-2

632-51-9

577-19-5

28342-75-8

203251-22-3

52331-02-9 160892-07-9


C6Br3F3

368.77 g/mole> 98% (HPLC)

C26H20

332.44 g/mole> 98%

C6H4BrNO2

202.01 g/mole> 98% (HPLC)

C6H2Br2F2

271.88 g/mole> 98% (HPLC)

C17H24O4

292.37 g/mole> 98% (HPLC)

C8H8Cl2175.06 g/mole> 98% (HPLC)

C8H3BrN2

207.03 g/mole> 98% (HPLC)

FormulaM.W.Grade

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: : :

K0839

K0952

K0887

K0953

117635-21-9

245731-57-1

13209-33-1

245731-58-2

C18H28Br2

404.22 g/mole> 98% (HPLC)

C21H32O6

380.48 g/mole> 98% (HPLC)

C8H4Cl2O2

203.02 g/mole> 98% (HPLC)

C17H28O4

296.4 g/mole> 98% (HPLC)

FormulaM.W.Grade

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FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

: : :

Br

Br

CHO

CHO

Cl

Cl

Br

O2N

NH2

Cl

Cl

Cl

Br

NC CN

FBr

FBr

BrF

BrF

Br F OO

OH

HO

OO

O

O

O

O

OO

OHC

CHO

*New

304

Synth

etic Interm

ediates an

d R

eagents

Synthetic Intermediates and ReagentsBoronic Acids / Boronic Esters

B0004

B0037

B0052

B0063

B0080

B0003

B0022

B0048

B0055

B0079

B0005

B0045

B0053

B0067

B0081

B0021

B0047

B0054

B0078

B0082

98-80-6

90002-36-1

156641-98-4

68572-87-2

175676-65-0

100622-34-2

151169-74-3

168267-99-0

127972-00-3

143418-49-9

4688-76-0

163517-62-2

163105-89-3

164461-18-1

139301-27-2

16152-51-5

166328-16-1

208399-66-0

182482-25-3

201802-67-7

C6H7BO2

121.92 g/mole> 97%

C8H11BO2

149.98 g/mole> 96%

C11H11BO3

202.01 g/mole> 97%

C14H11BO2

222.05 g/mole> 97%

C7H6BF3O3

205.93 g/mole> 98%

C14H11BO2

222.04 g/mole> 97%

C6H5BCl2O2

190.81 g/mole> 97%

C7H8BFO2

153.95 g/mole> 97%

C8H11BO3

165.98 g/mole> 97%

C6H4BF3O2

175.9 g/mole> 95%

C12H11BO2

198.02 g/mole> 97%

C7H8BFO2

153.95 g/mole> 96%

C6H8BNO3

152.94 g/mole> 98%

C16H11BO2

246.07 g/mole> 97%

C7H6BF3O3

205.93 g/mole> 97%

C9H13BO2

164.0 g/mole> 98%

C7H8BFO2

153.95 g/mole> 97%

C8H11BO3

165.98 g/mole> 97%

C6H4BF3O2

175.9 g/mole> 97%

C18H16BNO2

289.14 g/mole> 97%

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BHO OH

BOH

OH

BHO OH

BHO

HO

CH3

CH3

BHO

HOClCl

BHO

HO

BOH

OH

F

BOH

OHF

BHO

HOF

BHO

HO OCH3 NB

HO

HOOCH3 B

HO

HOH3C

OCH3

BOH

OH

H3C

OCH3

BHOOH

BOH

HO BOH

OHF

F

F

BHO

HOF

F

FB OH

HO

OCF3

BOH

OHF3CO B

OH

OHN

305

Synth

etic Interm

ediates an

d R

eagents


B0087

B0093

B1003

B1007

B1011

B0083

B0092

B1002

B1006

B1010

B0090

B0094

B1004

B1008

B1012

B0091

B1001

B1005

B1009

B1013

4151-80-8

1095570-51-6

101251-09-6

123088-59-5

98437-24-2

122775-35-3

711026-06-1

169760-16-1

206551-43-1

164014-95-3

172975-69-8

861455-18-7

204841-19-0

85006-23-1

268218-94-6

5980-97-2

78887-39-5

149104-90-5

98437-23-1

184000-11-1

C12H12B2O4

241.84 g/mole> 98%

C62H98B2N2O4

957.07 g/mole> 96%

C8H10BNO3

178.98 g/mole> 95%

C7H8BNO3

164.95 g/mole> 98%

C8H7BO3

161.95 g/mole> 97%

C8H11BO4

181.98 g/mole> 97%

C45H72B2O4

698.67 g/mole> 97%

C8H10BNO3

178.98 g/mole> 97%

C6H7BO3S169.99 g/mole> 96%

C8H9BO4

179.97 g/mole> 98%

C8H11BO2

149.98 g/mole> 98%

C37H38B2O4

568.32 g/mole> 97%

C8H9BO3

163.96 g/mole> 97%

C6H9BClNO2

173.41 g/mole> 95%

C13H11BO3

226.04 g/mole> 97%

C9H13BO2

164.01 g/mole> 98%

C8H10BNO3

178.98 g/mole> 98%

C8H9BO3

163.96 g/mole> 97%

C8H7BO2S178.02 g/mole> 97%

C14H13BO4

256.06 g/mole> 96%

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BHO

HOOCH3

OCH3

BHO

HOB

OH

OHB

OH

OHB

OH

OH

C10H21 C10H21

B BO

O O

OB B

N

N

C8H17

C6H13

C8H17

C6H13

O

O O

O B

B

O

O

O

O BOH

OH

O

NH

BHO OH

O

HN B

OH

OH

OHN B

OH

OH

O

BHO

HO

O

S BOH

OH

OB

HO

HO

O

NH2B

HO

HO

NH2 HClS

BOH

OH

O

O

BHO

HO OB

HO

HO

OB

HO

HOB

HO

OH

O

O

306

Synth

etic Interm

ediates an

d R

eagents


B1015

B1019

B1023

B1027

B1031

B1014

B1018

B1022

B1026

B1030

B1016

B1020

B1024

B1028

B1032

B1017

B1021

B1025

B1029

B1033

190661-29-1

73852-19-4

51323-43-4

162607-17-2

123324-71-0

133057-83-7

5122-94-1

135884-31-0

5467-74-3

4426-47-5

146631-00-7

380430-68-2

68162-47-0

105365-51-3

101084-81-5

5122-95-2

380430-49-9

244205-40-1

145240-28-4

85107-54-6

C13H13BO3

228.05 g/mole> 98%

C8H5BF6O2

257.93 g/mole> 98%

C7H8BBrO2

214.85 g/mole> 85%

C4H4BBrO2S206.85 g/mole> 95%

C10H15BO2

178.04 g/mole> 98%

C13H12BFO3

246.04 g/mole> 98%

C12H11BO2

198.03 g/mole> 98%

C9H14BNO4

211.02 g/mole> 98%

C6H6BBrO2

200.83 g/mole> 97%

C4H11BO2

101.94 g/mole> 95%

C13H13BO3

228.05 g/mole> 98%

C11H16BNO4

237.06 g/mole> 95%

C7H8BBrO2

214.85 g/mole> 85%

C10H15BO3

194.04 g/mole> 98%

C7H6BNO6

210.94 g/mole> 95%

C12H11BO2

198.03 g/mole> 97%

C11H16BNO4

237.06 g/mole> 95%

C6H6BBrO2

200.83 g/mole> 96%

C10H15BO2

178.04 g/mole> 97%

C7H6BNO6

210.94 g/mole> 96%

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BHO

HO

F

OB

OHHO

O BOH

OHO B

OH

HO

BOH

OH

BHO OH

F

FF

F

FF

BHO

OH HN

O

O BOH

OH

NH

O

O

N

BOHHO O

OB

HO

HO

Br

BHO

HO

Br

BHO

HO

Br

BHO

HOBr

SB

OH

OHBr BOH

OH

OB

OH

OH

BOH

OHB

HO

HO BOH

OH

O2N

OHO B

OHHO

O2N

OOH

307

Synth

etic Interm

ediates an

d R

eagents


B1035

B1039

B1043

B1048

B1052

B1034

B1038

B1042

B1046

B1051

B1036

B1040

B1044

B1049

B1053

B1037

B1041

B1045

B1050

B1054

14047-29-1

175883-63-3

3900-89-8

305832-67-1

151169-75-4

25487-66-5

219735-99-6

63503-60-6

150255-96-2

73852-17-2

144432-85-9

145349-62-8

1679-18-1

68716-47-2

67492-50-6

175883-60-0

148839-33-2

162607-18-3

135145-90-3

121219-16-7

C7H7BO4

165.94 g/mole> 97%

C7H8BClO2

170.4 g/mole> 97%

C6H6BClO2

156.37 g/mole> 98%

C5H4BNO2S152.97 g/mole> 97%

C6H5BCl2O2

190.82 g/mole> 96%

C7H7BO4

165.94 g/mole> 97%

C7H8BClO3

186.4 g/mole> 97%

C6H6BClO2

156.37 g/mole> 97%

C7H6BNO2

146.94 g/mole> 97%

C6H5BCl2O2

190.82 g/mole> 98%

C6H5BClFO2

174.37 g/mole> 98%

C7H8BClO2

170.4 g/mole> 98%

C6H6BClO2

156.37 g/mole> 97%

C6H5BCl2O2

190.82 g/mole> 98%

C6H5BCl2O2

190.82 g/mole> 97%

C7H8BClO3

186.4 g/mole> 96%

C7H8BClO2

170.4 g/mole> 97%

C4H4BClO2S162.4 g/mole> 97%

C6H5BCl2O2

190.82 g/mole> 98%

C6H5BF2O2

157.91 g/mole> 97%

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BOH

OH

O

HO BOH

OH

O

HO

BHO

HOF

Cl

BHO

HOO

Cl

BHO

HOO

Cl

BHO

HOCl

BHO

HOCl Cl

BOH

OH

BHO

HO

Cl

BHO

HO

Cl

BOH

OHCl

SB

OH

OHCl

BOH

OHNC S

NBOH

OH BHO

HOCl

Cl

BOH

OH

Cl

Cl

BOH

OH

Cl

Cl

BHO

HOCl

Cl

BHO

HO

Cl

Cl

BHO

HOFF

308

Synth

etic Interm

ediates an

d R

eagents


B1056

B1060

B1064

B1068

B1072

B1055

B1059

B1063

B1067

B1071

B1057

B1061

B1065

B1069

B1073

B1058

B1062

B1066

B1070

B1074

193353-34-3

133730-34-4

55499-43-9

100379-00-8

22237-13-4

144025-03-6

156545-07-2

221006-70-8

85199-06-0

4334-88-7

162101-25-9

107099-99-0

301699-39-8

4334-87-6

63139-21-9

168267-41-2

192182-54-0

183158-34-1

380430-53-5

178305-99-2

C6H5BF2O2

157.91 g/mole> 95%

C8H11BO4

181.98 g/mole> 95%

C8H11BO2

149.98 g/mole> 98%

C8H11BO2

149.98 g/mole> 98%

C8H11BO3

165.98 g/mole> 97%

C6H5BF2O2

157.91 g/mole> 98%

C6H5BF2O2

157.91 g/mole> 98%

C7H10BNO4

182.97 g/mole> 98%

C8H11BO2

149.98 g/mole> 98%

C9H11BO4

193.99 g/mole> 98%

C6H5BF2O2

157.91 g/mole> 98%

C8H11BO4

181.98 g/mole> 97%

C9H13BO3

180.01 g/mole> 97%

C9H11BO4

193.99 g/mole> 98%

C8H11BO2

149.98 g/mole> 97%

C6H5BF2O2

157.91 g/mole> 97%

C8H11BO4

181.98 g/mole> 97%

C8H11BO2

149.98 g/mole> 98%

C9H11BO4

193.99 g/mole> 96%

C12H10BFO2

216.02 g/mole> 98%

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BHO

HOF

F

BOH

OH

F

F

BOH

OH

F

F

BHO

HOF

F

BHO

HO

F

F

BHO

HOO

O

BHO

HO

O

O

BHO

HO

O

O

NB

OH

OHO

O

BHO

HOB

OH

OHO B

HO

HO

BOH

OHB

OH

OH

BOH

HO

O

OB OH

HO

O

O

BHO

HO O

OB

HO

HOO B

HO

HO BOH

OHF

309

Synth

etic Interm

ediates an

d R

eagents


B1076

B1080

B1084

B1088

B1092

B1075

B1079

B1083

B1087

B1091

B1077

B1081

B1085

B1089

B1093

B1078

B1082

B1086

B1090

B1094

179897-94-0

1993-03-9

27329-70-0

4347-31-3

87199-15-3

149507-26-6

768-35-4

351019-18-6

87199-17-5

13331-23-2

139911-29-8

1765-93-1

87199-16-4

17303-83-2

87199-14-2

139911-27-6

174669-73-9

40138-16-7

4347-33-5

59016-93-2

C7H8BFO3

169.95 g/mole> 97%

C6H6BFO2

139.92 g/mole> 98%

C5H5BO4

139.9 g/mole> 98%

C5H5BO3S155.97 g/mole> 95%

C7H9BO3

151.96 g/mole> 98%

C7H8BFO3

169.95 g/mole> 98%

C6H6BFO2

139.92 g/mole> 97%

C5H5BFNO2

140.91 g/mole> 98%

C7H7BO3

149.94 g/mole> 97%

C4H5BO3

111.89 g/mole> 97%

C7H8BFO2

153.95 g/mole> 97%

C6H6BFO2

139.92 g/mole> 98%

C7H7BO3

149.94 g/mole> 97%

C5H5BO3S155.97 g/mole> 95%

C7H9BO3

151.96 g/mole> 98%

C7H8BFO2

153.95 g/mole> 98%

C5H5BFNO2

140.91 g/mole> 98%

C7H7BO3

149.94 g/mole> 96%

C5H5BO3S155.97 g/mole> 98%

C7H9BO3

151.96 g/mole> 96%

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BHO

HOO

F

BHO

HOO

F

BHO

HOF B

HO

HOF

BHO

HO

F

BHO

HO

F

BOH

OHF N

BOH

OHF

NF B

OH

OH

OB

OH

OHOB

HO

HO

CHO

BHO

HO

OHC

BHO

HOCHO

OB

HO

HO

BOH

OHHO

SB

OH

OHCHO

SB

HO

HO

OHCS

BOH

OHOHC

BHO

HO

OH

BHO

HO OH

310

Synth

etic Interm

ediates an

d R

eagents


B1096

B1100

B1104

B1108

B1115

B1095

B1099

B1103

B1107

B1112

B1097

B1101

B1105

B1109

B1116

B1098

B1102

B1106

B1110

B1117

89466-08-0

192182-56-2

85107-55-7

10365-98-7

17933-03-8

87199-18-6

380427-38-3

117342-20-8

99768-12-4

94839-07-3

71597-85-8

148355-75-3

99769-19-4

5720-06-9

16419-60-6

89787-12-2

380430-57-9

374538-03-1

5720-07-0

5720-05-8

C6H7BO3

137.93 g/mole> 99%

C9H8BNO2

172.98 g/mole> 96%

C8H8BNO6

224.96 g/mole> 97%

C7H9BO3

151.96 g/mole> 98%

C7H9BO2

135.96 g/mole> 97%

C6H7BO3

137.93 g/mole> 95%

C9H13BO2S196.07 g/mole> 96%

C8H8BNO6

224.96 g/mole> 98%

C8H9BO4

179.97 g/mole> 97%

C7H7BO4

165.94 g/mole> 98%

C6H7BO3

137.93 g/mole> 98%

C7H10BNO4S215.03 g/mole> 95%

C8H9BO4

179.97 g/mole> 95%

C7H9BO3

151.96 g/mole> 97%

C7H9BO2

135.96 g/mole> 98%

C9H13BO2

164.01 g/mole> 97%

C7H10BNO4S215.03 g/mole> 95%

C8H9BO4

179.97 g/mole> 96%

C7H9BO3

151.96 g/mole> 97%

C7H9BO2

135.96 g/mole> 97%

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BHO

HO

OH

BHO

HO

HO

BOH

OHHO

BOH

OH

S BOH

OH N

BHO OH

BOH

OHHN

SO

O BOH

OHHNS

OO

BOH

HO

O

OB OH

HO

O

OBHO

OH

NO2O

O

BOH

HO

O2N

OO

BHO

HO O

OB

HO

HO

O

BHO

HO

OB

HO

HOO

BHO

HO

O

O BHO

HOB

HO

HOB

HO

HO

311

Synth

etic Interm

ediates an

d R

eagents


B1119

B1123

B1127

B1133

B1137

B1118

B1122

B1126

B1132

B1136

B1120

B1124

B1128

B1134

B1138

B1121

B1125

B1130

B1135

B1139

362045-65-6

32316-92-0

100124-07-0

191162-39-7

1423-26-3

84110-40-7

13922-41-3

24067-17-2

1692-15-5

6165-69-1

168618-42-6

13331-27-6

4612-26-4

86-58-8

128796-39-4

98546-51-1

5570-19-4

186497-67-6

6165-68-0

2156-04-9

C6H10BINO2

265.86 g/mole> 95%

C10H9BO2

171.99 g/mole> 98%

C12H9BO3S244.07 g/mole> 97%

C9H8BNO2

172.98 g/mole> 95%

C7H6BF3O2

189.93 g/mole> 97%

C4H11BO2

101.94 g/mole> 97%

C10H9BO2

171.99 g/mole> 98%

C6H6BNO4

166.93 g/mole> 95%

C5H6BNO2

122.95 g/mole> 98%

C4H5BO2S127.96 g/mole> 97%

C7H9BO2S168.02 g/mole> 98%

C6H6BNO4

166.93 g/mole> 95%

C6H8B2O4

165.75 g/mole> 96%

C9H8BNO2

172.98 g/mole> 98%

C7H6BF3O2

189.93 g/mole> 97%

C7H9BO2S168.02 g/mole> 98%

C6H6BNO4

166.93 g/mole> 97%

C9H13BO3

180.01 g/mole> 96%

C4H5BO2S127.96 g/mole> 95%

C8H9BO2

147.97 g/mole> 95%

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BHO

OH

BHO

HO

SB

HO

HOS

BHO OH

BOH

OHBOH

OHO2N

O

S

B OHHO

BHO

HOB

OH

OHB

OH

OHO

BOH

OH

NO2

BHO

HONO2

NBHO

HO

NB

HO

HO NB

HO OHS

BOH

OH

SB

HO

HO

BOH

OHFF

FB

HO

HO FF

FB

HO

HO

N BOH

OH

I

312

Synth

etic Interm

ediates an

d R

eagents


B1141

B1145

B1150

B1154

B1158

B1140

B1144

B1149

B1153 B1157

B1142

B1147

B1151

B1155

B1159

B1143

B1148

B1152

B1160

159624-15-4

444120-94-9

191171-55-8

248924-59-6

171364-83-3

552846-17-0

480424-71-3

380430-61-5

180516-87-4 190788-59-1

330793-09-4

195062-62-5

214360-73-3

269410-24-4

480425-36-3

330793-01-6

171364-80-0

269409-73-6

380430-60-4

C17H26BNO4

319.2 g/mole> 95%

C11H15BClNO2

239.51 g/mole> 96%

C12H18BNO2

219.09 g/mole> 96%

C10H15BO3

194.04 g/mole> 98%

C12H16BNO4

249.07 g/mole> 95%

C14H23BN2O4

294.15 g/mole> 98%

C17H25BO5

320.19 g/mole> 96%

C14H20BNO3

261.12 g/mole> 96%

C13H17BO4

248.08 g/mole> 98%

C12H16BNO4

249.07 g/mole> 95%

C17H26BNO4

319.2 g/mole> 95%

C15H21BO4

276.14 g/mole> 96%

C12H18BNO2

219.09 g/mole> 97%

C14H18BNO2

243.11 g/mole> 96%

C13H18BNO3

247.1 g/mole> 95%

C17H26BNO4

319.2 g/mole> 95%

C14H19BO4

262.11 g/mole> 96%

C13H17BO4

248.08 g/mole> 96%

C13H20BNO4S297.18 g/mole> 95%

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

NN

OBO

O

O HN

O

O

O BO

HNO

O OBO

NH

O

O

OBO

O

O

O

O BO

NOB

OCl

O

O

OB O

O

O

OB O

O

NH

OBO

NH2

OB

ONH2

OB

O

O

HO OBO

O

HO OB

O O

OB

OHN

OB

O OB

OO2N

OB

OO2N

O

NH

OB

O

SO

O

NH

OB

O

B1161 269410-08-4

C9H15BN2O2

194.04 g/mole> 96%

FormulaM.W.Grade

: : :

NHN

OB

O

313

Synth

etic Interm

ediates an

d R

eagents


B1184 1259931-19-5

C37H57B2NO4

601.5 g/mole> 97%

FormulaM.W.Grade

: : :

NBB

O

O O

O

B1162

B1167

B1172

B1177

B1181

B1165

B1171

B1176

B1180

B1163

B1168

B1174

B1178

B1182

B1164

B1170

B1175

B1179

B1183

329214-79-1

1073355-14-2

333432-28-3

254755-24-3

958293-23-7

214360-70-0

1706525-40-7

852475-03-7

852138-91-1

181219-01-2

236389-21-2

1222537-26-9

196207-58-6

1443551-29-8

485799-04-0

1193104-83-4

597553-98-5

357219-41-1

958261-51-3

C11H16BNO2

205.06 g/mole> 97%

C12H15BN2O3

246.07 g/mole> 95%

C15H15BO2

238.09 g/mole> 97%

C37H56B2O4

586.46 g/mole> 97%

C40H64B2O4Si658.64 g/mole> 97%

C10H15BO2S210.1 g/mole> 96%

C27H24B2O4

434.1 g/mole> 97%

C24H21BO2Si380.32 g/mole> 97%

C36H56B2O4Si602.53 g/mole> 97%

C11H16BNO2

205.06 g/mole> 97%

C25H17BO2

360.21 g/mole> 97%

C25H18B2O4

404.03 g/mole> 97%

C41H64B2O4

642.57 g/mole> 97%

C40H64B2O4Si658.64 g/mole> 97%

C15H23BN2O3

290.17 g/mole> 98%

C27H23BO2

390.28 g/mole> 97%

C26H19BO2

374.24 g/mole> 97%

C41H64B2O4

642.57 g/mole> 97%

C41H65B2NO4

657.58 g/mole> 97%

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

: : :

: : :

: : :

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: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

N

OB

ON

OB

ONO

N OB

O S

OB

O

NON

OB

O

B(OH)2

B(OH)2

H3C CH3

B(OH)2

H3C CH3

(HO)2B

CH3H3C

B(OH)2B(OH)2(HO)2B

(HO)2B

Si B(OH)2

BBO

O O

O BBO

O O

OBB

O

O O

O

SiBB

O

O O

O

SiBB

O

O O

O

SiBB

O

O O

ON

BBO

O O

O

314

Synth

etic Interm

ediates an

d R

eagents


B1185

B1189

B1195

B1199

B1203

B1188

B1194

B1198

B1202

B1186

B1190

B1196

B1200

B1204

B1187

B1193

B1197

B1201

B1205

1240488-30-5

1692-25-7

1507388-01-3

372963-49-0

762287-57-0

105365-50-2

882066-06-0

55552-70-0

452972-09-7

542504-04-3

134150-01-9

175361-81-6

870777-29-0

148493-34-9

128312-11-8

89466-07-9

313545-72-1

C41H65B2NO4

657.6 g/mole> 97%

C5H6BNO2

122.9 g/mole> 95%

C46H66B2N2O4

732.7 g/mole> 97%

C6H8BNO2

136.9 g/mole> 97%

C7H8BClO3

186.4 g/mole> 96%

C12H19BO2

206.1 g/mole> 97%

C46H66B2N2O4

732.7 g/mole> 97%

C4H5BO3

111.9 g/mole> 98%

C5H5BBrNO2

201.8 g/mole> 98%

C20H19BO2

302.2 g/mole> 97%

C9H13BO2

164.0 g/mole> 95%

C16H26B2O4S336.1 g/mole> 97%

C8H8BFO3

182.0 g/mole> 96%

C5H4BCl2NO2

191.8 g/mole> 98%

C71H66B2N2O4

1032.9 g/mole> 97%

C42H58B2N2O4

676.5 g/mole> 97%

C7H9BO2S168.0 g/mole> 97%

C6H7BN2O4

181.9 g/mole> 95%

C6H5BClFO2

174.4 g/mole> 98%

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

NBB

O

O O

O

(HO)2B

N N

BO

O B OO

C6H13(HO)2B

NB

HO

HOB

HO

HO N

NBO

OBO

O

N

NBO

OBO

O

N

NBO

OBO

O SB

B

O

O

O

OS B

OH

OH OB

HO

HO

NB

OH

OH

F

BHO

OH OB

OH

OH

H2N

O2NN

BHO

HO

Br

BHO

HOO

ClN

BOH

OHCl

Cl

BHO

HOF

Cl

B1206 223463-14-7

C5H5BBrNO2

201.8 g/mole> 96%

FormulaM.W.Grade

: : :

NB

OH

OHBr

315

Synth

etic Interm

ediates an

d R

eagents


B1226 153624-46-5

C9H13BO3

180.0 g/mole> 96%

FormulaM.W.Grade

: : :

BOH

OHO

B1207

B1211

B1215

B1219

B1223

B1210

B1214

B1218

B1222

B1208

B1212

B1216

B1220

B1224

B1209

B1213

B1217

B1221

B1225

452972-08-6

163105-90-6

89641-18-9

149105-19-1

153254-09-2

254993-59-4

854373-97-0

120153-08-4

1423-27-4

381248-04-0

308103-40-4

136496-72-5

138642-62-3

89598-96-9

182344-18-9

501435-91-2

216019-28-2

182163-96-8

91983-14-1

C5H5BBrNO2

201.8 g/mole> 98%

C6H8BNO3

152.9 g/mole> 98%

C6H9BN2O4

183.96 g/mole> 98%

C7H7BO4

165.9 g/mole> 95%

C8H5BF6O2

257.9 g/mole> 98%

C7H5BClF3O2

224.4 g/mole> 97%

C7H10BNO3

166.97 g/mole> 98%

C7H6BFO4

183.9 g/mole> 98%

C7H6BF3O2

189.9 g/mole> 97%

C5H5BClNO2

157.4 g/mole> 97%

C8H9BO3

164.0 g/mole> 97%

C7H6BClO4

200.4 g/mole> 95%

C7H6BNO2

146.9 g/mole> 95%

C6H6BBrO2

200.8 g/mole> 96%

C7H5BClF3O2

224.4 g/mole> 98%

C5H4BBrFNO2

219.8 g/mole> 98%

C9H13BO2

164.0 g/mole> 97%

C9H13BO5

212.0 g/mole> 96%

C7H8BBrO2

214.9 g/mole> 95%

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

NB

OH

OHBr

NB

OH

OHCl

BOH

OHF

F

F

ClB

HO

HO F

FF

Cl

NB

OH

OHO B

OH

OH

O

NB

OH

OH

F

Br

NB

OH

OH

O

N

N

OB

O

OH

OH

BHO

HOCl

O

OHBOH

OHB

OH

OHO

HO

F

BOH

OH

OHO

BHO

HO

NC

BHO

HOO

O

OB

HOOHF

FF

BHO

HO

F

FF

F

F F

BHO

HO

Br

BHO

HO

Br

316

Synth

etic Interm

ediates an

d R

eagents


B1227

B1231

B1235

B1239

B1243

B1230

B1234

B1238

B1242

B1228

B1232

B1236

B1240

B1244

B1229

B1233

B1237

B1241

B1245

121219-12-3

192182-55-1

109299-79-8

108238-09-1

156682-54-1

913836-03-0

220465-43-0

213211-69-9

913835-82-2

355386-94-6

936250-22-5

458532-96-2

351422-73-6

30418-59-8

182281-01-2

348098-29-3

572-06-9

90555-66-1

179113-90-7

C11H17BO2

192.1 g/mole> 97%

C9H10BNO2

175.0 g/mole> 98%

C12H23BN2O5

286.1 g/mole> 95%

C12H11BO3

214.0 g/mole> 97%

C13H13BO3

228.1 g/mole> 98%

C6H6BNO4

166.9 g/mole> 96%

C8H8BNO3

177.0 g/mole> 97%

C8H11BO3

166.0 g/mole> 97%

C11H15BO4

222.0 g/mole> 95%

C9H8BNO2

173.0 g/mole> 98%

C4H6BN3O2

138.9 g/mole> 95%

C5H5BClNO2

157.4 g/mole> 96%

C7H8BNO3

165.0 g/mole> 95%

C6H8BNO2

136.9 g/mole> 95%

C11H15BO4

222.0 g/mole> 97%

C5H7BN2O2S170 g/mole> 95%

C7H9BO3

152.0 g/mole> 97%

C8H11BO3

166.0 g/mole> 95%

C7H6BF3O3

205.9 g/mole> 97%

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

BHO

HO

N

BHO OH

BOH

OH

O

O

N

BOH

OH

O

HO

N

BOH

HON

NB

OH

OHH2N

N

NB

HO

HOS

HNB

O OH

OH

NN

BHOOH

O

O

HOH

N BOH

OHCl

BHO

HO

O

BHO

HOO

BHO

OHO BOH

OH

O

H2NB

OH

OHO

BHOOH

O

O

BOH

OHO B

HO

HO

NH2

BOH

OHOF

F F

B1246 145349-76-4

C8H11BO2S182.0 g/mole> 95%

FormulaM.W.Grade

: : :

BHO

HOS

317

Synth

etic Interm

ediates an

d R

eagents


B1266 226396-32-3

C6H4BF3O2

175.9 g/mole> 95%

FormulaM.W.Grade

: : :

BHO

HOF

FF

B1247

B1251

B1255

B1259

B1263

B1250

B1254

B1258

B1262

B1248

B1252

B1256

B1260

B1264

B1249

B1253

B1257

B1261

B1265

70799-12-1

259209-20-6

405520-68-5

5122-99-6

4612-28-6

89694-48-4

373384-14-6

80460-73-7

149104-88-1

947533-31-5

870774-25-7

832695-88-2

237429-33-3

55499-44-0

34420-17-2

173194-95-1

373384-18-0

162662-27-3

23112-96-1

C9H14BNO2

179.0 g/mole> 97%

C6H6BFO3

155.92 g/mole> 95%

C9H12BNO3

193.0 g/mole> 98%

C6H6BIO2

247.8 g/mole> 95%

C6H8B2O4

165.7 g/mole> 97%

C7H8BClO3

186.4 g/mole> 95%

C9H12BNO3

193.0 g/mole> 98%

C6H9BClNO2

173.4 g/mole> 95%


C8H13BN2O4

212.0 g/mole> 95%

C16H13BO2

248.1 g/mole> 97%

C8H10BNO3

179.0 g/mole> 95%


C8H11BO2

150.0 g/mole> 97%

C8H11BO2

150.0 g/mole> 95%

C10H9BO3

188.0 g/mole> 97%


C8H11BO3

166.0 g/mole> 98%

C8H11BO4

182.0 g/mole> 97%

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

BOH

OH

N NN

B OH

HO

O

OB

HO

HO

BHO

HOO

Cl

BHO

HOHO

F BOH

OH

BOH

OHHO BOH

HO

O

N

BHO

HO O

N BOH

HO

O

NH BOH

OHS

O

OB

OH

OHH2N HCl

BOH

OHI B

OH

OHHS B

HO

HO

OB

OH

OHSO

O

BOH

OHBOH

HO BHO

HOB

OH

OH

O

O

318

Synth

etic Interm

ediates an

d R

eagents


B1267

B1271

B1275

B1279

B1283

B1270

B1274

B1278

B1282

B1268

B1272

B1276

B1280

B1284

B1269

B1273

B1277

B1281

B1285

212779-19-6

73852-18-3

845551-44-2

313545-41-4

108847-20-7

247564-72-3

873566-75-7

160591-91-3

109299-78-7

247564-71-2

89694-46-2

505083-04-5

137504-86-0

148546-82-1

247564-73-4

503309-11-3

874219-35-9

176976-42-4

444120-91-6

C6H4BCl3O2

225.3 g/mole> 97%

C6H4BCl3O2

225.3 g/mole> 97%

C13H12BClO3

262.5 g/mole> 96%

C7H5BClF3O2

224.4 g/mole> 96%

C12H9BO2S228.1 g/mole> 98%

C6H4BF3O2

175.9 g/mole> 97%

C6H7BFNO2

154.9 g/mole> 95%

C6H5BClFO2

174.4 g/mole> 98%

C4H5BN2O2

123.9 g/mole> 98%

C6H4BF3O2

175.9 g/mole> 97%

C7H8BClO3

186.4 g/mole> 97%

C8H8BFO4

198.0 g/mole> 96%

C6H5BClFO2

174.4 g/mole> 98%

C6H8BNO2

136.9 g/mole> 98%

C6H4BF3O2

175.9 g/mole> 97%

C7H5BF4O2

207.9 g/mole> 98%

C8H8BFO4

198.0 g/mole> 96%

C7H5BClF3O2

224.4 g/mole> 98%

C5H5BClNO2

157.4 g/mole> 96%

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

BOH

OHCl

Cl Cl

BOH

OHF

F F

BOH

OHF

F F

BOH

OHF

F

F

BOH

OHCl

Cl

Cl

BOH

HOO

Cl

BHO

HO F

FF

F

BHO

HOF

NH2

BHO

HO

Cl

O BHO

HO

O

OF BHO

OH

O

O

F

BHO

HOF

Cl

BHO

HO F

FF

Cl

BHO

HOF

Cl BOH

OHF

FF

ClN

NB

OH

OH

SBOH

HO NB

HO

HO NB

OH

OHCl

B1286 872041-85-5

C5H5BClNO2

157.4 g/mole> 97%

FormulaM.W.Grade

: : :

NB

HO

HO

Cl

319

Synth

etic Interm

ediates an

d R

eagents


B1306 848779-87-3

C13H12BFO3

246.0 g/mole> 96%

FormulaM.W.Grade

: : :

BOH

OH

F O

B1287

B1291

B1295

B1299

B1303

B1290

B1294

B1298

B1302

B1288

B1292

B1296

B1300

B1304

B1289

B1293

B1297

B1301

B1305

4433-63-0

352535-96-7

179899-07-1

1582-24-7

70523-24-9

4441-56-9

78495-63-3

511295-01-5

40972-86-9

411235-57-9

352303-67-4

179923-32-1

243140-14-9

306935-93-3

80041-89-0

162101-31-7

511295-00-4

121219-20-3

852228-14-9

C2H7BO2

73.9 g/mole> 97%

C7H5BF4O2

207.9 g/mole> 98%

C7H8BFO3

169.9 g/mole> 96%

C6H2BF5O2

211.9 g/mole> 96%

C18H17BN2O4

336.1 g/mole> 95%

C6H13BO2

128.0 g/mole> 99%

C7H8BFO3

169.9 g/mole> 98%

C6H3BF4O2

193.9 g/mole> 96%

C8H11BO4

182 g/mole> 98%

C3H7BO2

85.9 g/mole> 95%

C7H8BFO3

169.9 g/mole> 98%

C6H3BF4O2

193.9 g/mole> 96%

C10H13BO4

208.0 g/mole> 96%

C12H21BN2O4

268.1 g/mole> 97%

C3H9BO2

87.9 g/mole> 95%

C7H8BFO3

169.9 g/mole> 98%

C6H3BF4O2

193.9 g/mole> 96%

C12H17BF2O3

258.1 g/mole> 96%

C5H4BBr2NO2

280.7 g/mole> 97%

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

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FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

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FormulaM.W.Grade

FormulaM.W.Grade

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FormulaM.W.Grade

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: : :

: : :

: : :

BOH

OHB

OH

OHB

OHHO B

OH

OH

BOH

OHF

F

F

F

BOH

OHO F

BHO

HOO

F

BOH

OH

O

F

BHO

HOO

FB

OH

OH

F

F

F F

BOH

OH

F

F

F F

BOH

OH

FF

F F

BOH

OH

FF

F

F F

BHO

OHOO B OH

HO

O F

FB

OH

OHO O

N

NB

HO

OH

O O NN

BHOOH

O

O

NB

OH

OHBr

Br

320

Synth

etic Interm

ediates an

d R

eagents


B1307

B1311

B1315

B1319

B1323

B1310

B1314

B1318

B1322

B1308

B1312

B1316

B1320

B1324

B1309

B1313

B1317

B1321

B1325

779331-47-4

313545-44-7

1150114-78-5

126617-98-9

170981-26-7

1003043-40-0

444666-39-1

867333-29-7

603122-84-5

1003043-34-2

1022922-16-2

957034-45-6

279263-10-4

352534-79-3

874290-62-7

936249-33-1

193353-35-4

904326-92-7

1072952-25-0

C13H12BFO3

246.0 g/mole> 96%

C8H10BClO3

200.4 g/mole> 97%

C7H6BClO3

184.4 g/mole> 97%

C8H11BO3

166.0 g/mole> 97%

C7H8BFO2

153.9 g/mole> 98%

C6H7BClNO2

171.4 g/mole> 98%

C6H5BClFO2

174.4 g/mole> 98%

C6H5BClNO4

201.4 g/mole> 97%

C8H8BFO4

198.0 g/mole> 98%

C6H7BBrNO2

215.8 g/mole> 98%

C7H5BClF3O3

240.4 g/mole> 98%

C8H8BF3O2

204.0 g/mole> 97%

C8H10BFO3

184.0 g/mole> 96%

C7H6BFO3

167.9 g/mole> 98%

C7H6BFO4

183.9 g/mole> 96%

C7H5BClNO2

181.4 g/mole> 97%

C7H8BClO2

170.4 g/mole> 97%

C6H7BFNO2

154.9 g/mole> 98%

C7H8BFO3

169.9 g/mole> 95%

FormulaM.W.Grade

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FormulaM.W.Grade

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FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

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FormulaM.W.Grade

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BHO OH

F

ON

BOH

OHBr B

HO

HO

F

OOH

NB

OH

OHCl

BHO

HOO

ClB

OH

OHOF

FFCl

BOH

OH

F

ClBOH

HOCN

Cl

BOH

HO O

Cl

BHO

HO F

FF B

OH

OHCl

B(OH)2

OMe

BOH

HO

Cl

NO2

B OHHO

F O NB

OH

OHF B

HO

HO

O

OF

BHO

HOF

BOH

HO O

F

BOH

HO OH

F

B1326 127972-02-5

C8H9BO4

180.0 g/mole> 96%

FormulaM.W.Grade

: : :

BHO

HO

O

O

321

Synth

etic Interm

ediates an

d R

eagents


B1346 159191-56-7

C12H21BO3Si252.2 g/mole> 97%

FormulaM.W.Grade

: : :

BOH

OHO

Si

B1327

B1331

B1335

B1339

B1343

B1330

B1334

B1338

B1342

B1328

B1332

B1336

B1340

B1344

B1329

B1333

B1337

B1341

B1345

419536-33-7

864377-33-3

874219-36-0

851335-12-1

389621-80-1

850568-78-4

279261-81-3

458532-97-3

159191-44-3

15016-42-9

352535-84-3

409108-13-0

603122-41-4

850568-12-6

850568-34-2

827300-04-9

609807-25-2

166386-48-7

389621-83-4

C18H14BNO2

287.1 g/mole> 97%

C18H14BNO2

287.1 g/mole> 97%

C9H10BFO4

212.0 g/mole> 97%

C8H9BO5

196.0 g/mole> 97%

C11H16BNO3

221.1 g/mole> 97%

C10H13BO4

208.0 g/mole> 97%

C8H10BClO3

200.4 g/mole> 97%

C5H5BFNO2

140.9 g/mole> 97%

C20H20BNO2

317.2 g/mole> 97%

C8H9BO2

148.0 g/mole> 95%

C6H4BBrF2O2

236.8 g/mole> 97%

C12H10BFO2

216.0 g/mole> 97%

C9H11BO5

210.0 g/mole> 98%

C9H12BNO3

193.0 g/mole> 97%

C12H16BNO3

233.1 g/mole> 97%

C11H15BO4

222.0 g/mole> 97%

C7H8BFO3

169.9 g/mole> 98%


C12H16BNO3

233.1 g/mole> 97%

FormulaM.W.Grade

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FormulaM.W.Grade

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: : :

N(HO)2BB

HO

HO

BHOOH

O

NBHO

OH

O

O

N

(HO)2B

BOH

OHF

FBr

BOH

OH

O

OB

HO

HOO

Cl

B OHHO

FO

O BOH

OHF

BOH

OH

O

F

N BOH

OHF

BHO

HO

O

OHO

BHO

HO

O

OO

BOH

OHSO

O

BOH

OHN

BHO

HO O

NB

HO

HO O

HN

BHO

HO

O

N

322

Synth

etic Interm

ediates an

d R

eagents


B1347

B1351

B1355

B1359

B1363

B1350

B1354

B1358

B1362

B1348

B1352

B1356

B1360

B1364

B1349

B1353

B1357

B1361

B1365

481725-35-3

338454-30-1

151169-67-4

91062-38-3

468718-30-1

1309980-72-0

209919-30-2

153624-38-5

352534-86-2

205672-21-5

130870-00-7

874288-38-7

380430-70-6

928053-97-8

847560-49-0

1162753-18-5

374538-01-9

654067-65-9

850991-69-4

C8H8BFO3

182.0 g/mole> 97%

C14H15BO3

242.1 g/mole> 96%

C6H5BClNO4

201.4 g/mole> 97%

C10H13BO4

208.0 g/mole> 96%

C7H5BFNO2

164.9 g/mole> 98%

C16H20BN3O3

313.2 g/mole> 96%

C7H8BClO2

170.4 g/mole> 98%

C10H15BO2

178.0 g/mole> 96%

C8H10BClO3

200.4 g/mole> 96%

C13H16BN3O3

273.1 g/mole> 97%

C8H10BBrO2

228.9 g/mole> 97%

C9H10BFO4

212.0 g/mole> 97%

C11H15BO5

238.0 g/mole> 96%

C7H5BF4O2

207.9 g/mole> 97%

C14H15BO3

242.1 g/mole> 97%

C20H20BNO2

317.2 g/mole> 97%

C7H6BFO3

167.9 g/mole> 98%

C20H20BNO2

317.2 g/mole> 97%

C6H8BNO3

152.9 g/mole> 96%

FormulaM.W.Grade

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: : :

BHO

HOF

O

N

NBOH

HO

NOB

HO

HOO

N

NB

HO

OH

NO

BHO

HOO B

OH

OHBr

N

B(OH)2

BHO

HOCl

BHO

HOF

O

OB

OH

OH

Cl

O2N BHO

HO

O

FB

OH

OH

BHO

HO

O

O BOH

OH

OO

OHN

B(OH)2

B OHHO

OCl

B OHHO

F

FFFB

OH

HO

F

CNN

BHO

HO

O

B1366 173999-18-3

C6H8BNO2

136.9 g/mole> 96%

FormulaM.W.Grade

: : :

NB

HO

HO

323

Synth

etic Interm

ediates an

d R

eagents


B1386 612833-41-7

C14H12BF3O3

296.05 g/mole> 98%

FormulaM.W.Grade

: : :

BHO

OH

FF

FO

B1367

B1371

B1375

B1379

B1383

B1370

B1374

B1378

B1382

B1368

B1372

B1376

B1380

B1384

B1369

B1373

B1377

B1381

B1385

16343-08-1

104376-24-1

147222-88-6

1263374-42-0

870779-02-5

852362-22-2

951677-39-7

957061-21-1

851756-54-2

4737-50-2

763120-58-7

170981-41-6

1072952-26-1

1072952-27-2

138900-55-7

376584-63-3

156684-91-2

897958-93-9

401816-16-8

C6H15BO2

130.0 g/mole> 95%

C5H11BO2

114.0 g/mole> 98%

C13H19BF2O3

272.1 g/mole> 99%

C5H4BF2NO2

158.9 g/mole> 97%

C7H7BF2O3

187.9 g/mole> 97%

C10H11BN2O2

202.0 g/mole> 96%

C5H4BCl2NO2

191.8 g/mole> 97%

C7H7BF2O3

187.9 g/mole> 98%

C7H7BCl2O2

204.8 g/mole> 98%

C5H13BO2

116.0 g/mole> 97%

C3H5BN2O2

111.9 g/mole> 98%

C7H7BF2O3

187.9 g/mole> 98%

C5H6BCl2NO3

209.8 g/mole> 95%

C5H6BF2NO3

176.9 g/mole> 95%

C13H26BNO2Si267.2 g/mole> 98%

C3H5BN2O2

111.9 g/mole> 96%

C11H15BF2O3

244.0 g/mole> 98%

C7H7BF2O3

187.9 g/mole> 95%

C5H4BF2NO2

158.9 g/mole> 97%

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

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FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

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FormulaM.W.Grade

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FormulaM.W.Grade

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: : :

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: : :

B OHHO

B OHHO

NBOH

HOSi

NN

BOH

OH

B OHHO

NHN

BHO

HO HN N

BHO

HON B

OH

OH

ClCl

B OHHO

O F

F BHO

HOO

FF BHO

OH

O F

F BOH

OHO

F F

N BOH

OH

FF

NB

OH

OH

Cl

ClH

OH

BOH

OHO

F

F

BOH

OHCl

Cl

BOH

OHO

F

F

NB

OH

OHF

FH

OH

N BOH

OHF

F

324

Synth

etic Interm

ediates an

d R

eagents


B1387

B1391

B1395

B1399

B1403

B1390

B1394

B1398

B1402

B1388

B1392

B1396

B1400

B1404

B1389

B1393

B1397

B1401

B1405

4540-87-8

330804-03-0

956283-09-3

868662-36-6

1072951-43-9

1072945-86-8

115377-94-1

947533-39-3

1072952-51-2

762263-92-3

579525-46-5

373384-12-4

870777-20-1

1072952-48-7

126617-98-9

85107-53-5

150691-04-6

1310384-22-5

874290-62-7

C10H14BNO4

223.03 g/mole> 98%

C7H9BO4S200.02 g/mole> 98%

C7H10BNO4S215.03 g/mole> 95%

C6H5BF3NO2

190.92 g/mole> 97%

C5H4BBrFNO2

219.8 g/mole> 95%

C7H8BNO4

180.95 g/mole> 98%

C11H16BNO4

237.06 g/mole> 97%

C6H5BF3NO2

190.92 g/mole> 98%

C5H4BBrClNO2

236.26 g/mole> 98%

C8H11BO4

181.98 g/mole> 98%

C7H13BN2O3

184 g/mole> 97%

C11H17BO3

208.06 g/mole> 97%

C14H14BBrO3

320.97 g/mole> 98%

C6H7BBrNO3

231.84 g/mole> 98%

C8H11BO3

165.98 g/mole> 95%

C9H14BNO2

179.02 g/mole> 98%

C10H16BNO4S257.11 g/mole> 97%

C14H13BO4

256.06 g/mole> 97%

C7H6BFO4

183.93 g/mole> 98%

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

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FormulaM.W.Grade

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: : :

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: : :

BOH

OH

HN

OO

BHO

HOO

OH

BHO

HO

ON

BHO

HO O

O

BHO

OH

SO

O

NB

HO

HON

HOH

BHO

HO

N BHO OH

HN

O

O

BOH

OHSO OHN

BHO OH

O

B OHHO

SO

ONH

N

BHOOH

FF

F

NB

OH

OHFF

F

BOH

HO

Br

OB OH

HO

OO

N BOH

OHCl

Br

N BOH

OHF

Br

NBHO

HOO

Br

BHO

HO

F

OOH

B1406 465515-31-5

C5H5BO4S171.97 g/mole> 98%

FormulaM.W.Grade

: : :

SB

HO

HO

O

OH

325

Synth

etic Interm

ediates an

d R

eagents


B1426 401815-98-3

C5H5BFNO2

140.91 g/mole> 98%

FormulaM.W.Grade

: : :

N BOH

OHF

B1407

B1411

B1415

B1419

B1423

B1410

B1414

B1418

B1422

B1408

B1412

B1416

B1420

B1424

B1409

B1413

B1417

B1421

B1425

957061-11-9

1003042-59-8

1003043-37-5

1003042-92-9

1072944-18-3

913835-92-4

957121-07-2

756817-82-0

871126-22-6

937595-71-6

851756-52-0

1003845-06-4

957062-87-2

406482-19-7

913836-08-5

1451392-26-9

128676-84-6

762287-58-1

313545-34-5

C7H5BClF3O2

224.37 g/mole> 98%

C7H8BClO3

186.4 g/mole> 95%

C8H11BClNO2

199.44 g/mole> 97%

C9H11BO4

193.99 g/mole> 98%

C6H7BFNO2

154.93 g/mole> 98%

C8H8BClO4

214.41 g/mole> 98%

C6H5BClFO3

190.36 g/mole> 98%

C6H10BN3O2

166.97 g/mole> 98%

C7H6BFO3

167.93 g/mole> 98%

C5H4BClFNO2

175.35 g/mole> 96%

C7H5BClF3O2

224.37 g/mole> 98%

C4H4BClN2O2

158.35 g/mole> 98%

C9H10BFO4

211.98 g/mole> 98%

C7H8BFO3

169.95 g/mole> 98%

C6H7BClNO2

171.39 g/mole> 98%

C8H9BClFO4

234.42 g/mole> 97%

C9H7BClNO2

207.42 g/mole> 98%

C7H8BFO2

153.95 g/mole> 97%

C7H5BF4O2

207.92 g/mole> 98%

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

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: : :

: : :

: : :

BOH

OHF

FFCl

N BOH

OH

FCl

NB

OH

OHCl

BOH

OH

O

O

Cl

BOH

HO OH

Cl

BHO OH

F

F

FCl BOH

OHOO

F

Cl

BOH

OH

HO

F

Cl

NB

OH

OH

Cl N

NB

OH

OHCl

N

BOH

OH

Cl

N

NB

HO

HON

B OHHO

OO

B

FO

O

OHHO

BHO

HOF

BHO

HO

O

F

NB

OH

OHF B

OH

HOO

F

BHO OH

F

FFF

326

Synth

etic Interm

ediates an

d R

eagents


B1427

B1431

B1435

B1439

B1443

B1430

B1434

B1438

B1442

B1428

B1432

B1436

B1440

B1444

B1429

B1433

B1437

B1441

B1445

94838-88-7

40138-17-8

290832-43-8

1260374-05-7

352525-94-1

40138-18-9

104116-17-8

628692-15-9

1015480-87-1

139962-95-1

1072944-17-2

240139-82-6

1072952-30-7

1256355-31-3

1218790-89-6

259209-22-8

762262-09-9

16114-47-9

850567-25-8

C8H7BO5

193.95 g/mole> 99%

C8H9BO3

163.97 g/mole> 97%

C8H8BF3O4

235.95 g/mole> 98%

C9H13BO4

196.01 g/mole> 97%

C7H11BClNO2

187.43 g/mole> 98%

C8H9BO4

179.97 g/mole> 96%

C11H11BO3

202.01 g/mole> 98%

C5H7BN2O3

153.93 g/mole> 98%

C6H9BN2O4

183.96 g/mole> 98%

C8H9BO4

179.97 g/mole> 97%

C7H6BF3O3

205.93 g/mole> 96%

C8H8BF3O3

219.95 g/mole> 98%

C6H10BNO3

154.96 g/mole> 97%

C14H15BO3

242.08 g/mole> 97%

C8H6BF3O4

233.94 g/mole> 98%

C7H9BO3

151.96 g/mole> 98%

C6H8BNO3

152.94 g/mole> 98%

C5H8BNO3

140.93 g/mole> 97%

C13H18BNO3

247.1 g/mole> 97%

FormulaM.W.Grade

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FormulaM.W.Grade

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FormulaM.W.Grade

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FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

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: : :

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: : :

BOH

OH

O

O

OB

HO

HOO

O

BHO

OHO F

F F

O

BHO

HO

O

O

BHO

HO

O

BOH

OHF

FFOH

BHO

HOHO B

OHHO

O

BHO

OHO F

F FO B OH

HO

F

FF O

N

BHO

OHO N

NB

HO

HOO

BHO

HOO

OON

BOH

OHN

NB

OH

OHO

O

NB

OH

OHH2O

BHO

OH

O BOH

HO

O

HNB

HO

HO

NH2HCl

B1447 723282-09-5

C11H16BNO3

221.06 g/mole> 98%

FormulaM.W.Grade

: : :

BOH

HO

O

HN

327

Synth

etic Interm

ediates an

d R

eagents


B1467 1072952-23-8

C5H5BO5

155.9 g/mole> 98%

FormulaM.W.Grade

: : :

OB

HO

HO

O OH

B1448

B1452

B1456

B1460

B1464

B1451

B1455

B1459

B1463

B1449

B1453

B1457

B1461

B1465

B1450

B1454

B1458

B1462

B1466

216443-40-2

625470-96-4

850689-36-0

913835-64-0

1072952-09-0

723281-57-0

99349-68-5

89488-24-4

379669-72-4

142273-84-5

199609-62-6

206658-89-1

458532-99-5

872460-12-3

178752-79-9

858364-78-0

1032231-32-5

101084-76-8

913836-12-1

C8H11BO4

181.98 g/mole> 98%

C14H14BNO3

255.08 g/mole> 98%

C6H7BClNO2

171.39 g/mole> 98%

C7H5BBrF3O2

268.82 g/mole> 98%

C7H6BFO4

183.93 g/mole> 98%

C9H12BNO4

209.01 g/mole> 98%

C9H10BNO3

190.99 g/mole> 98%

C6H6BBrO3

216.83 g/mole> 98%

C4H9BO2

99.92 g/mole> 97%

C8H11BO3

165.98 g/mole> 97%

C12H18BNO4

251.09 g/mole> 98%

C6H10BNO3

154.96 g/mole> 98%

C5H5BBrNO2

201.81 g/mole> 98%

C7H6BFO4

183.93 g/mole> 98%

C8H12BNO2

165 g/mole> 98%

C11H17BO3

208.06 g/mole> 97%

C7H5BBrNO2

225.84 g/mole> 98%

C4H4BBrO2S206.85 g/mole> 98%

C8H9BO5

195.97 g/mole> 98%

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

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FormulaM.W.Grade

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FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

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FormulaM.W.Grade

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: : :

: : :

BOH

OHOO B

OH

OH

OBOH

OHN

BHOOH

O

NO

BHOOH

O

HN

BOH

HO

HNO

O BOH

OHOB

OH

OH

O

NH

BHO

HOCl

NH2

BHO

HOHO Br

B OHHO

F

FF

Br

N BOH

OHBr

BHO

OH

CN

Br

BHO

HO

NH2H2O

SB

OH

OHBr

BOH

OH

BOH

OHFO

HOB

OH

OH

F

O

HOB

HO

HOO

OOH

328

Synth

etic Interm

ediates an

d R

eagents


B1468

B1472

B1476

B1480

B1484

B1471

B1475

B1479

B1483

B1469

B1473

B1477

B1481

B1485

B1470

B1474

B1478

B1482

B1487

519054-53-6

957060-88-7

458532-98-4

259209-24-0

1029880-18-9

951655-50-8

1072952-53-4

1315341-79-7

1031226-45-5

942438-89-3

324024-80-8

762287-59-2

1106869-99-1

352535-82-1

313545-20-9

214210-21-6

163517-61-1

4347-32-4

C5H5BO4S171.97 g/mole> 99%

C6H7BClNO3

187.39 g/mole> 98%

C5H7BClNO3

175.38 g/mole> 96%

C6H6BFO3

155.92 g/mole> 98%

C5H7BFNO3

158.92 g/mole> 98%

C6H6BClO3

172.37 g/mole> 98%

C7H6BClO3

184.38 g/mole> 96%

C9H11BO3

177.99 g/mole> 98%

C8H10BFO4

199.97 g/mole> 95%

C6H4BClF2O2

192.36 g/mole> 98%

C6H7BClNO3

187.39 g/mole> 98%

C4H4BClO2S162.4 g/mole> 95%

C7H8BFO3

169.95 g/mole> 95%

C8H9BO3

163.97 g/mole> 97%

C6H5BClFO2

174.37 g/mole> 98%

C7H8BClO2

170.4 g/mole> 97%

C7H5BFNO2

164.93 g/mole> 97%

C7H8BFO2

153.95 g/mole> 98%

C5H5BO3S155.97 g/mole> 96%

FormulaM.W.Grade

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: : :

: : :

: : :

BOH

OHF

FCl

BHO

HOF Cl

BHO

HOF Cl

SB

HO

HO

O OH

N

BOH

HOO

Cl NB

OH

OHO

Cl

BHO

HOCl

BHO

HO

O

Cl

N BOH

OHCl

H2OS

BHO

HO

Cl

BHO

HO

O

BHO

HOHO F

BHO

OH OF

BOH

OH

F

NC

BHO

HOF

BHO

HOO

O

F

BHO

HO

O

SB

OH

OH

O

N BOH

OHF

H2O

B1488 259209-17-1

C7H9BO4

167.95 g/mole> 98%

FormulaM.W.Grade

: : :

BOH

OHOHO

329

Synth

etic Interm

ediates an

d R

eagents


B1510 480996-05-2

C12H10BBrO2

276.92 g/mole> 98%

FormulaM.W.Grade

: : :

BBrOH

OH

B1489

B1493

B1498

B1502

B1507

B1492

B1497

B1501

B1506

B1490

B1494

B1499

B1503

B1508

B1491

B1495

B1500

B1505

B1509

1072952-50-1

252663-48-2

28611-39-4

489446-42-6

947533-41-7

75705-21-4

919496-59-6

252663-47-1

850568-14-8

177735-09-0

762262-07-7

1150114-73-0

121177-82-0

139962-97-3

1072952-49-8

1218790-88-5

179055-26-6

1024017-53-5

352535-81-0

C6H10BNO4

170.96 g/mole> 98%

C11H16BNO3

221.06 g/mole> 98%

C8H12BNO2

165 g/mole> 97%

C12H18BNO4

251.09 g/mole> 97%

C6H7BF3NO3

208.93 g/mole> 95%

C7H11BClNO2

187.43 g/mole> 98%

C9H14BNO2

179.02 g/mole> 96%

C14H14BNO3

255.08 g/mole> 98%

C11H16BNO3

221.06 g/mole> 98%

C5H7BO2S141.98 g/mole> 99%

C13H18BNO3

247.1 g/mole> 97%

C8H13BClNO2

201.46 g/mole> 98%

C8H10BNO3

178.98 g/mole> 98%

C14H13BO4

256.06 g/mole> 97%

C10H13BO6

240.02 g/mole> 98%

C8H11BO3

165.98 g/mole> 97%

C9H12BNO4

209.01 g/mole> 97%

C11H17BO3

208.06 g/mole> 98%

C6H4BBrF2O2

236.81 g/mole> 98%

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

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FormulaM.W.Grade

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: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

SB

HO

HO

B OHHO

O

OO

O

N BOH

OHO

H2O BHO

HO NH2

HCl

BHO

HO

O

HNB

HO

HO O

HNB

HO

HO

OHB

HO

HON

BOH

OHN B

OH

OHN

HCl

BHO

HO

O

NO B

HO

OH

O

HN

BOH

OHNHO

O BHO

HO O

NHB

OH

OHOB

HO

HO

O

HN

N

BHO

OHF

FF

HOH

BHO

HO

O

OB

OH

OHF

F

Br

330

Synth

etic Interm

ediates an

d R

eagents


B1511

B1515

B1519

B1523

B1527

B1514

B1518

B1522

B1526

B1512

B1516

B1520

B1524

B1528

B1513

B1517

B1521

B1525

B1529

263368-72-5

156428-81-8

162607-15-0

850864-59-4

488713-34-4

1310384-23-6

355004-67-0

1032231-30-3

1072952-42-1

182344-16-7

62306-78-9

51067-38-0

957060-94-5

1256355-30-2

874219-21-3

175883-62-2

1215281-20-1

730971-32-1

1246633-53-3

C8H7BO2

145.95 g/mole> 98%

C8H9BO3

163.97 g/mole> 98%

C5H7BO2S141.98 g/mole> 96%

C6H7BBrNO3

231.84 g/mole> 97%

C8H10BFO4

199.97 g/mole> 97%

C8H8BFO3

181.96 g/mole> 96%

C6H10BNO4

170.96 g/mole> 97%

C7H5BBrNO2

225.84 g/mole> 98%

C7H7BClFO2

188.39 g/mole> 98%

C7H5BF4O2

207.92 g/mole> 98%

C5H5BO4

139.9 g/mole> 97%

C12H11BO3

214.02 g/mole> 97%

C6H7BBrNO3

231.84 g/mole> 97%

C7H6BFO3

167.93 g/mole> 96%

C10H13BFNO3

225.02 g/mole> 98%

C8H11BO3

165.98 g/mole> 98%

C9H11BO4

193.99 g/mole> 98%

C8H9BO5

195.97 g/mole> 98%

C7H8BFO3

169.95 g/mole> 98%

FormulaM.W.Grade

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FormulaM.W.Grade

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: : :

: : :

: : :

: : :

B OHHO

F

FF

F

BOH

HOHN

OF

BHO

HO

O

FB

HO

HOCN

BHO

HO

O

OB

OH

OH

O BHO

HOO

SB

HO

HO

NB

HO

HO

OH2O

BOH

OH

O

BHO

OH

OO

NB

OH

OH

O

Br

N

BOH

HOO

Br

BOH

HO

NC Br

BHO

OH

OO

HO BOH

OH

F

Cl

B OHHO

OO

F

BHO

OH

OF

BHO

OH

OHF

B1530 871329-62-3

C8H8BFO4

197.96 g/mole> 98%

FormulaM.W.Grade

: : :

BOH

HO

F

O

O

331

Synth

etic Interm

ediates an

d R

eagents


B1550 899438-92-7

C9H8BNO2

172.98 g/mole> 98%

FormulaM.W.Grade

: : :

NB

OH

OH

B1531

B1535

B1539

B1543

B1547

B1534

B1538

B1542

B1546

B1532

B1536

B1540

B1544

B1548

B1533

B1537

B1541

B1545

B1549

1043869-98-2

162607-20-7

203927-98-4

63076-51-7

147621-18-9

62306-79-0

916336-19-1

27762-64-7

144104-59-6

1072952-28-3

913836-11-0

258865-48-4

100124-06-9

98139-72-1

175592-59-3

867333-04-8

426268-09-9

3088-79-7

371766-08-4

C6H7BFNO3

170.93 g/mole> 98%

C5H7BO2S141.98 g/mole> 97%

C25H36B2O4

422.17 g/mole> 98%

C5H11BO2

113.95 g/mole> 96%

C8H8BNO2

160.97 g/mole> 95%

C5H7BO3

125.92 g/mole> 97%

C27H40B2O4

450.23 g/mole> 98%

C7H15BO2

142 g/mole> 98%

C8H8BNO2

160.97 g/mole> 98%

C6H7BO3S169.99 g/mole> 98%

C6H6BNO4

166.93 g/mole> 98%

C29H44B2O4

478.28 g/mole> 98%

C12H9BO3

212.01 g/mole> 97%

C5H13BO2

115.97 g/mole> 95%

C5H5BO3S155.97 g/mole> 97%

C7H7BClFO3

204.39 g/mole> 98%

C6H5BN2O3

163.93 g/mole> 97%

C12H27BO2

214.15 g/mole

C9H8BNO2

172.98 g/mole> 96%

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

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FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

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FormulaM.W.Grade

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: : :

: : :

: : :

: : :

: : :

: : :

: :

: : :

N

BOH

HOO

F

SB

HO

HO

O

SB

OH

OH

O

OB

OH

OH

SB

OH

OH NB

OH

OH

O

HO

BOH

OHO

F

Cl BHO

HOB

OH

OH

BHO

HOB

OH

OH

BHO

HOB

OH

OHON

N

BOH

OHBOH

OH

BHO

HO

OBOH

HOHN B

OH

OH

HN

BHO

HO BOH

HO

BHO OH

N

BHO OH

332

Synth

etic Interm

ediates an

d R

eagents


B1551

B1555

B1559

B1563

B1567

B1554

B1558

B1562

B1566

B1552

B1556

B1560

B1564

B1568

B1553

B1557

B1561

B1565

B1569

1092790-21-0

475102-13-7

4445-09-4

728911-52-2

374790-93-9

850568-05-7

701261-35-0

70523-22-7

476004-81-6

721401-43-0

213318-44-6

371764-64-6

476004-79-2

193978-23-3

13061-96-6

17745-45-8

1072952-46-5

214360-77-7

388116-27-6

C9H8BNO2

172.98 g/mole> 95%

C13H15BBrNO4

339.98 g/mole> 97%

C18H39BO2

298.31 g/mole

C37H38B2O4

568.32 g/mole> 97%

C10H15BO3

194.04 g/mole> 97%

C14H24BNO6

313.15 g/mole> 95%

C5H13BO2

115.97 g/mole> 96%

C4H5BN2O4

155.9 g/mole> 97%

C14H18BNO2

243.11 g/mole> 97%

C9H8BNO2

172.98 g/mole> 98%

C13H16BNO4

261.08 g/mole> 97%

C9H8BNO2

172.98 g/mole> 98%

C10H16BNO2

193.05 g/mole> 97%

C10H15BO2S210.1 g/mole> 97%

CH5BO2

59.86 g/mole> 98%

C3H9BO2

87.91 g/mole> 97%

C5H11BO3

129.95 g/mole> 95%

C19H36BNO2Si349.39 g/mole> 97%

C14H18BNO2

243.11 g/mole> 97%

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

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: : :

: :

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: : :

: : :

N

BHO

HON

BHO OH

BHO

OHN B

OH

OHO

O

OO

NB

OH

OH

Br

OO

NB

OH

OH

OO

BOH

OHB

HO

OH

N

BHO OH

O BOH

OH

C18H37B

OHHOHN

OHN

O

BOH

OH

BBO

O O

O

NH

B

O

O

N BO

OSiNH

BO

O

HN

BO

OSB

O

O

OB

O

O

B1570 402960-38-7

C10H16BN3O2

221.06 g/mole> 98%

FormulaM.W.Grade

: : :

N

NBH2N

O

O

333

Synth

etic Interm

ediates an

d R

eagents


B1591 73183-34-3

C12H24B2O4

253.9 g/mole> 99%

FormulaM.W.Grade

: : :

O

OB B

O

O

B1571

B1575

B1579

B1584

B1588

B1574

B1578

B1583

B1587

B1572

B1576

B1580

B1585

B1589

B1573

B1577

B1582

B1586

B1590

777061-36-6

264925-45-3

286961-14-6

864772-18-9

210907-84-9

325129-69-9

884336-44-1

929203-04-3

87100-28-5

837392-62-8

302554-81-0

262444-42-8

908350-80-1

195062-57-8

569343-09-5

740812-14-0

1009033-87-7

24388-23-6

138500-85-3

C19H26BNO4

343.23 g/mole> 98%

C31H45BO2

460.5 g/mole> 97%

C16H28BNO4

309.21 g/mole> 98%

C18H21BO3

296.17 g/mole> 97%

C12H18BNO2

219.1 g/mole> 95%

C27H36B2O4

446.19 g/mole> 97%

C31H27BO2

442.36 g/mole> 97%

C17H20BNO2

281.16 g/mole> 97%

C13H19BO2

218.1 g/mole> 97%

C15H20BNO2

257.14 g/mole> 97%

C35H53BO2

516.61 g/mole> 97%

C17H25BFNO4

337.19 g/mole> 95%

C17H20BNO2

281.16 g/mole> 97%

C13H19BO2

218.1 g/mole> 98%

C21H25BO2

320.23 g/mole> 97%

C35H53BO2

516.61 g/mole> 97%

C17H20BNO2

281.16 g/mole> 97%

C12H17BO2

204.1 g/mole> 97%

C13H18BBrO2

297.0 g/mole> 95%

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

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: : :

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: : :

: : :

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: : :

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: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

N

B

O

O

O

O BO

OBB

O

O O

O

BO

O BO

OB

O

O

N

OB

O

BO

O

N

B

O

O

O

ONH

OB

OF

OO

BNO

OB

N

O

O

B

O

O

O BN

O

O

OBO

OBO

BH2NO

O

OBO

B

Br

O

O

334

Synth

etic Interm

ediates an

d R

eagents


B1592

B1596

B1600

B1605

B1609

B1595

B1599

B1604

B1608

B1593

B1597

B1602

B1606

B1610

B1594

B1598

B1603

B1607

B1611

761446-44-0

214360-62-0

138500-86-4

141091-37-4

239075-02-6

452972-12-2

396131-82-1

287944-13-2

847818-74-0

1073371-78-4

269409-70-3

1046832-21-6

287944-10-9

479719-88-5

377780-72-8

349666-24-6

1011460-68-6

885698-94-2

1025707-98-5

C10H17BN2O2

208.1 g/mole> 97%

C11H15BBrNO2

284.0 g/mole> 97%

C14H18BNO2

243.1 g/mole> 98%

C12H21BO2

208.1 g/mole> 98%

C20H28B2O4S2

418.2 g/mole> 98%

C11H15BBrNO2

284.0 g/mole> 97%

C14H18BNO2

243.1 g/mole> 98%

C13H23BO2

222.1 g/mole> 96%

C10H17BN2O2

208.1 g/mole> 98%

C11H14BCl2NO2

274.0 g/mole> 95%

C12H17BO3

220.1 g/mole> 97%

C11H19BN2O2

222.1 g/mole> 97%

C11H19BO2

194.1 g/mole> 98%

C14H17BO2S2

292.2 g/mole> 98%

C13H18BBrO2

297.0 g/mole> 96%

C22H21BO2

328.2 g/mole> 97%

C9H14BF3O2

222.0 g/mole> 99%

C14H19BN2O2

258.1 g/mole> 98%

C13H17BF2O2

254.1 g/mole> 98%

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

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: : :

: : :

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: : :

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: : :

: : :

: : :

: : :

: : :

NN

OB

O

N

B

Cl Cl

O

O B

BrO

O

N

B

Br

O

O

NBBr

O

OB

HO

O

OB

O

O

BNC

O

O

NN

BO

O BF

FF

O

O BO

OB

CN

O

O

BO

OBO

O

NN

BO

O NN

BO

O

S SB

B

O

OO

O S SB

O

OB

F

FO

O

B1612 883741-17-1

C22H36B2O4

386.1 g/mole> 98%

FormulaM.W.Grade

: : :

BO

O

B O

O

335

Synth

etic Interm

ediates an

d R

eagents


B1634 765916-91-4

C13H15BFNO2

247.1 g/mole> 98%

FormulaM.W.Grade

: : :

B FCNO

O

B1613

B1618

B1622

B1627

B1631

B1617

B1621

B1626

B1630

B1614

B1619

B1624

B1628

B1632

B1616

B1620

B1625

B1629

B1633

1218790-41-0

876316-33-5

940284-18-4

1015242-08-6

1256360-64-1

957198-30-0

957065-99-5

852228-08-1

1218790-42-1

627526-35-6

1009307-13-4

956229-73-5

1015242-07-5

1010836-19-7

942922-07-8

1056904-43-8

945863-21-8

956229-69-9

883899-03-4

C16H26BNO4

307.2 g/mole> 97%

C17H26BNO3

303.2 g/mole> 98%

C11H17BN2O2S252.1 g/mole> 97%

C15H24BN3O2

289.2 g/mole> 98%

C12H17BBrNO2

298.0 g/mole> 97%

C14H22BN3O3

291.2 g/mole> 98%

C13H18BNO4

263.1 g/mole> 98%

C16H25BN2O2

288.2 g/mole> 98%

C15H20BNO3

273.1 g/mole> 98%

C16H18BFO2

272.1 g/mole> 96%

C11H19BO4

226.1 g/mole> 98%

C15H22BNO3

275.2 g/mole> 97%

C14H22BN3O2

275.2 g/mole> 98%

C11H15BO4S254.1 g/mole> 98%

C15H25BN4O2

304.2 g/mole> 98%

C16H22BNO3

287.2 g/mole> 98%

C13H19BN2O3

262.1 g/mole> 98%

C17H25BO4

304.2 g/mole> 97%

C13H13BF3NO2

283.1 g/mole> 98%

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

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: : :

: : :

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: : :

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: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

NO

O

B O

O

OB

OF N

NB N N

O

O N

NB N O

O

O

NO

BOO

B O

OO

O

BO

NHO

O NB

O

O

O

O

N

NB

S

O

OB

OO

N

ON

BO

HN O

O

NBN

O

O

N

NBN

O

ON

NBN

O

O

B

OO

O

O

BO

NHO

O

NBBr

O

O

SBO

OH

O

O BF

F FCNO

O

336

Synth

etic Interm

ediates an

d R

eagents


B1635

B1639

B1643

B1648

B1652

B1638

B1642

B1647

B1651

B1636

B1640

B1644

B1649

B1653

B1637

B1641

B1646

B1650

B1654

883899-02-3

883898-97-3

1032759-30-0

61676-62-8

1204580-79-9

463335-96-8

1025708-31-9

1073354-14-9

1189746-27-7

1073355-21-1

868944-75-6

1073371-96-6

532391-31-4

1012084-56-8

461451-63-8

741709-63-7

846023-58-3

885698-95-3

660867-80-1

C13H16BNO3

245.1 g/mole> 98%

C13H16BNO3

245.1 g/mole> 98%

C12H20BN3O2

249.1 g/mole> 98%

C9H19BO3

186.05 g/mole> 96%

C14H19BN2O2

258.12 g/mole> 98%

C13H15BFNO2

247.1 g/mole> 98%

C11H14BN3O2

231.1 g/mole> 98%

C12H16BNO3

233.07 g/mole> 98%

C14H19BN2O2

258.12 g/mole> 98%

C14H15BF3NO2

297.1 g/mole> 97%

C11H13BN2O2

216.0 g/mole> 98%

C12H17BFNO2

237.1 g/mole> 98%

C12H18BNO3

235.08 g/mole> 97%

C12H18BNO2

219.08 g/mole> 97%

C13H15BFNO2

247.1 g/mole> 97%

C12H15BN2O2

230.1 g/mole> 96%

C12H17BO4

236.07 g/mole> 99%

C14H19BN2O2

258.12 g/mole> 98%

C12H18BNO2

219.08 g/mole> 98%

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

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: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

B OCNO

OB

F

F

F

CNO

O B

F

CNO

O B

CN

OO

F

N

B

N

O

OB

CNO

O

O N

B

NC

O

O

N

NB

NC

O

O

N

NB

N

O

ON

B

F

O

OO

OBO

ON

B

O

H

O

O

OB

OO N

B

O

O

ON

N

BO

ON

N

BO

O

NNBO

ON

BO

O NBO

O

B1655 610768-32-6

C12H18BNO2

219.08 g/mole> 98%

FormulaM.W.Grade

: : :

NB

O

O

337

Synth

etic Interm

ediates an

d R

eagents


B1676 486422-05-3

C14H22BNO4S311.20 g/mole> 98%

FormulaM.W.Grade

: : :

BSO

ONO

O

B1656

B1660 B1664

B1668

B1673

B1659

B1663

B1667

B1672

B1657

B1661

B1665

B1669

B1674

B1658

B1666

B1670

B1675

1073354-54-7

940284-98-0 944392-68-1

862129-81-5

916326-10-8

496786-98-2

1025707-93-0

287944-16-5

212127-71-4

1073355-13-1

153737-25-8

832114-00-8

843646-72-0

134892-18-5

1073354-59-2

919197-88-9

852227-95-3

1036991-19-1

C21H34BN3O4

403.32 g/mole> 98%

C19H31BN4O4

390.28 g/mole> 98%

C16H21BO6

320.14 g/mole> 98%

C11H19BO2S226.14 g/mole> 98%

C14H20BNO4

277.12 g/mole> 95%

C20H32BN3O4

389.29 g/mole> 98%

C11H19BO3

210.07 g/mole> 98%

C11H19BO3

210.07 g/mole> 97%

C12H21BO3

224.10 g/mole> 98%

C21H34BN3O4

403.32 g/mole> 98%

C13H25BO4

256.14 g/mole> 95%

C11H18BNO3

223.07 g/mole> 98%

C14H20BNO3

261.12 g/mole> 98%

C11H22BNO3

227.10 g/mole> 98%

C21H33BN2O4

388.30 g/mole> 98%

C10H13BCl2N2O2

274.93 g/mole> 97%

C16H24BNO3

289.17 g/mole> 98%

C15H25BClNO2

297.62 g/mole> 97%

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

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: : :

: : :

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: : :

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: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

NN NB

O

O

O

O NN NB

O

O

O

O N NO

O

B OO

NN NB

O

O

O

O

N

NN NB

O

O

O

O B

O

OO

O

O BO

O B

OO

OO

O

O

ON

BO

ONN

B

Cl

Cl O

O

O

BO

OS

BO

O

B O

OO

NH2

BO

NO

O B

O

O

O

NB

OO

O

O

BO

NO

OB

N

HCl

O

O

B1677 1257554-93-0

C17H27BN2O4

334.21 g/mole> 95%

FormulaM.W.Grade

: : :

N

BNH

O

O O

O

338

Synth

etic Interm

ediates an

d R

eagents


B1681

B1685

B1689

B1693

B1680

B1684

B1688

B1692

B1678

B1682

B1686

B1690

B1694

B1679

B1683

B1687

B1691

B1695

957198-28-6

775351-57-0

719268-92-5

4627-10-5

883899-07-8

153724-93-7

445303-67-3

207611-87-8

903895-48-7

883899-06-7

402718-29-0

445264-60-8

944591-57-5

850568-69-3

1245524-02-0

957198-29-7

540752-87-2

887757-48-4

C15H22BClN2O3

324.61 g/mole> 98%

C13H15BFNO2

247.07 g/mole> 98%

C11H15BFNO2

223.05 g/mole> 98%

C8H15BO2

154.01 g/mole90~95%

C12H13BBrNO2

293.95 g/mole> 98%

C9H16BClO2

202.48 g/mole> 98%

C13H15BF4O2

290.06 g/mole> 98%

C24H32B2O4

406.13 g/mole> 98%

C17H25BO4

304.18 g/mole> 98%

C12H13BClNO2

249.50 g/mole> 95%

C12H15BN2O2

230.07 g/mole> 98%

C12H18BNO3

235.08 g/mole> 98%

C17H27BClNO3

339.66 g/mole> 98%

C17H25BO4

304.18 g/mole> 98%

C12H15BClFO2

256.50 g/mole> 97%

C15H22BFN2O3

308.15 g/mole> 98%

C21H33BN2O4

388.30 g/mole> 97%

C13H17BF2O3

270.08 g/mole> 97%

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

BO O

OOBO

O

O

O

N B

O

N Cl

O

O

F

ClOB O

BCN

BrO

O

BCN

ClO

O BCl O

O

N B

O

N F

O

O

B

F

NCO

O

N

BNCO

OB

F

F

F

FO

ON

B

F

O

O

NB

O

O

O

N N

BO

OO

O

BBO

OO

OOB

O

NO

B O

OHCl

B

O

F

F

O

O

B1696 473596-87-1

C15H21BO4

276.13 g/mole> 98%

FormulaM.W.Grade

: : :

B

O

O

O

O

B1697 616880-14-9

C13H20BNO4S297.17 g/mole> 98%

FormulaM.W.Grade

: : :

BS

OO

HNO

O

339

Synth

etic Interm

ediates an

d R

eagents


B1716 1073354-91-2

C13H16BNO2S261.15 g/mole> 98%

FormulaM.W.Grade

: : :

S

N BO

O

B1701

B1705

B1709

B1713

B1700

B1704

B1708

B1712

B1698

B1702

B1706

B1710

B1714

B1699

B1703

B1707

B1711

B1715

914610-50-7

648905-63-9

452972-15-5

928664-98-6

330794-35-9

850568-72-8

1072944-28-5

1073354-66-1

878197-87-6

1073353-47-5

1073354-94-5

868944-72-3

470478-90-1

486422-04-2

1092390-02-7

445303-09-3

445303-14-0

1073371-92-2

C15H22BNO4S323.21 g/mole> 98%

C16H26BNO4S339.26 g/mole> 98%

C11H15BClNO2

239.51 g/mole> 98%

C9H14BNO3

195.02 g/mole> 98%

C18H28BNO4

333.23 g/mole> 98%

C17H25BO4

304.18 g/mole> 98%

C17H22B2ClNO4

361.44 g/mole> 98%

C14H19BO3

246.11 g/mole> 98%

C15H25BClNO2

297.62 g/mole> 98%

C13H20BNO4S297.17 g/mole> 98%

C11H15BO5

238.04 g/mole> 97%

C11H13BN2O2

216.04 g/mole> 98%

C21H33BN2O4

388.31 g/mole> 98%

C14H22BNO4S311.20 g/mole> 98%

C22H23BO2

330.22 g/mole> 98%

C13H15BClF3O2

306.52 g/mole> 98%

C13H15BF4O2

290.06 g/mole> 98%

C16H23BN2O4

318.18 g/mole> 98%

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: : :

: : :

HClB

N

O

O B

SO

O

N

O

OB

HN

O

O

O

O BSO

OO

OHN

BSO

OO

OHN B

O

O B

O

O

O

O BSO

OHN

O

O

O

B O

OH

O

O BF

FF

Cl

O

O

N

BCl O

O

BF

FF

F

O

O

CN

B

B

ClO

O

O

O

NB

NCO

OB

O

O

OH

ON

BO

O

N NBO

O

O

O

N

B

O

N

O OO

B1717 942069-51-4

C12H15BBrFO2

300.96 g/mole> 97%

FormulaM.W.Grade

: : :

B

F

Br

O

O

340

Synth

etic Interm

ediates an

d R

eagents


B1721

B1725

B1729

B1733

B1720

B1724

B1728

B1732

B1718

B1722

B1726

B1730

B1734

B1719

B1723

B1727

B1731

B1735

1083168-95-9

865350-17-0

1000160-75-7

928773-42-6

706820-96-4

1310383-99-3

214360-51-7

331958-92-0

1073354-65-0

848093-29-8

72824-04-5

201733-56-4

87100-15-0

883898-93-9

1171891-42-1

486422-08-6

166330-03-6

126689-01-8

C12H17BFNO3

253.08 g/mole> 98%

C9H15BO2

166.03 g/mole> 98%

C14H17BO2S260.16 g/mole> 98%

C15H17BO4

272.1 g/mole> 98%

C14H18BNO3

259.11 g/mole> 97%

C16H18BNO3

283.13 g/mole

C12H18BNO4S283.15 g/mole> 98%

C10H19BO2

182.07 g/mole> 98%

C12H14BClF2O2

274.5 g/mole> 97%

C12H16BNO3

233.07 g/mole> 98%

C9H17BO2

168.04 g/mole> 98%

C10H20B2O4

225.89 g/mole> 98%

C12H23BO2

210.12 g/mole> 95%

C12H13BClNO2

249.5 g/mole> 98%

C12H18BNO2

219.09 g/mole> 98%

C12H18BNO4S283.15 g/mole> 98%

C7H14BBrO2

220.9 g/mole> 97%

C9H17BO2

168.04 g/mole> 98%

FormulaM.W.Grade

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: : :

: : :

B

F

F

Cl

O

O B

NC

Cl

O

O

N

B

O

FO

O

N

BO

H O

O

N

BO

O

CB O

O

B O

O SO

O

NH2BO

O

B

O

CN

O

O

N

BO

OO

SO

OH2N B

O

OS B

O

O

OB

OB

O

O

BBr

OO

B O

O

O

O BO

O

BO

OBO

O

B1736 1025708-01-3

C15H20BBrO4

355.03 g/mole> 97%

FormulaM.W.Grade

: : :

OO

BBrO

O

B1737 302577-73-7

C11H21BO4

228.09 g/mole> 98%

FormulaM.W.Grade

: : :

O

OOBO

341

Synth

etic Interm

ediates an

d R

eagents


B1756 214360-65-3

C13H16BF3O2

272.07 g/mole> 97%

FormulaM.W.Grade

: : :

BFF

F O

O

B1741

B1745

B1749

B1753

B1740

B1744

B1748

B1752

B1738

B1742

B1746

B1750

B1754

B1739

B1743

B1747

B1751

B1755

1025707-92-9

66080-23-7

1150654-77-5

1131912-76-9

1073354-51-4

797755-07-8

1073372-05-0

134892-19-6

642494-37-9

69190-62-1

849677-21-0

662138-96-7

943899-12-5

1150561-77-5

797755-05-6

1021186-08-2

1167418-13-4

1269004-46-7

C20H26BNO5

371.24 g/mole> 98%

C13H19BO2S250.16 g/mole> 98%

C6H7BF3KN2O2+

246.04 g/mole

C11H21BO3

212.09 g/mole> 99%

C21H24BNO4S397.3 g/mole> 98%

C14H19BO4

262.11 g/mole> 98%

C18H29BClNO2

337.69 g/mole

C13H25BO4

256.15 g/mole> 98%

C14H18BNO2

243.11 g/mole> 98%

C10H21BO2

184.08 g/mole> 98%

C14H15BO5

274.08 g/mole> 98%

C18H25BN2O3

328.21 g/mole

C18H16BNO2

289.1 g/mole> 97%

C10H19BO4

214.07 g/mole> 98%

C14H19BO4

262.11 g/mole> 98%

C18H29BClNO2

337.69 g/mole> 97%

C14H17BN2O2

256.11 g/mole> 97%

C42H62B2N2O6S2

776.7 g/mole> 96%

FormulaM.W.Grade

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: :

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: : :

: : :

: : :

NHBO

O

O

OOBO

N

B

SO

O

OO

N

B

O

O

O

H

O

O

B O

O

O

HO B O

O O

HO

BO

OB

S

O

O

O

O

OB

O

O N

N

BF3

O

O

K+

BO N

ON

OHN

N

BO

O

B

N

HCl O

O

N

BO

O

HCl

O

OO

BO

O

BO

O

N

(HO)2B

N

N

O

O

S

SB

B

OO

OO

B1757 890042-13-4

C24H23BO2

354.25 g/mole> 97%

FormulaM.W.Grade

: : :

BO

O

342

Synth

etic Interm

ediates an

d R

eagents


B1761

B1765

B1769

B1773

B1760

B1764

B1768

B1772

B1758

B1762

B1766

B1770

B1774

B1759

B1763

B1767

B1771

B1775

1030020-61-1

528610-01-7

1268491-07-1

1126522-69-7

474918-37-1

792909-35-4

99770-93-1

219834-95-4

1334549-69-7

267221-88-5

1189126-37-1

1637564-11-4

452972-14-4

1017967-97-3

618442-57-2

947533-51-9

C31H43BBr2O2

618.29 g/mole> 97%

C28H28BNO2

421.34 g/mole> 97%

C41H65B2NO4

657.58 g/mole> 97%

C24H24BNO2

369.26 g/mole> 97%

C39H44B2O4

598.39 g/mole> 97%

C34H32BNO2

497.43 g/mole> 97%

C18H28B2O4

330.03 g/mole> 97%

C11H11BO3

202.01 g/mole> 97%

C38H56B2O4

598.47 g/mole> 97%

C24H26BNO2

371.28 g/mole> 97%

C20H25BO2

308.22 g/mole> 97%

C6H6BF3N2O2

205.93 g/mole> 98%

C28H25BO2

404.31 g/mole> 96%

C11H15BFNO2

223.05 g/mole> 97%

C42H51B3O6

684.28 g/mole> 97%

C30H35B2NO4

495.23 g/mole> 97%

C6H5BF3NO2

190.92 g/mole> 98%

C32H27BO2

454.37 g/mole> 96%

FormulaM.W.Grade

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: ::

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: : :

: ::

: : :

C6H13C6H13

B BO

O O

ON F

BO

OBB

O

O O

O

BrBr

BO

O

BO

ON

B

B

B O

O

O O

O

O

N

B O

O

N

B O

O

N

BBO

O OO

B BO

O O

ON

B BOO O

O

BO

O

B(OH)2

ON

B OO

BO

OB

O

O

N

BF3C

H2N

OH

OH

N

F3C BOH

OH

B1776 1146340-38-6

C25H25BN2O2

396.29 g/mole> 97%

FormulaM.W.Grade

: : :

BN

NO

O

B1777 879291-27-7

C17H20BNO2

281.16 g/mole> 97%

FormulaM.W.Grade

: : :

NB

O

O

343

Synth

etic Interm

ediates an

d R

eagents


B1781B1780B1778

B1782

B1779

B1783 B1784

929103-40-2562098-24-2912844-88-3

1224430-81-2

1487428-49-8

939430-30-5 226396-32-3

C30H34B2O4

480.21 g/mole> 97%

C16H19BN2O2

282.15 g/mole> 97%

C18H21BO2

280.17 g/mole> 98%

C58H94B2N2O6S2

1001.13 g/mole> 98%

C24H31B2NO4

419.13 g/mole> 97%

C17H20BNO2

281.16 g/mole> 97%

C6H4BF3O2

175.9 g/mole> 97%

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

: : :

: : :

: : :

: : :

N NB

O

OB O

O

NH

B BO

O O

O

BBO

O O

O

B1788

B1792 B1793 B1794

B1798

B1785

B1791B1789 B1790214360-48-2

1224881-17-7 1030024-65-7 374934-77-7

747413-21-4

875667-84-8

378223-65-5108847-20-7 1398398-12-3

C13H16BNO2

229.08 g/mole> 98%

C24H32BNO2

377.33 g/mole> 98%

C36H42B2O4Si588.42 g/mole> 98%

C30H52B2O4

498.35 g/mole> 98%

C17H27BN2O2

302.22 g/mole> 98%

C26H30BNO4

431.33 g/mole> 98%

C20H33BO2

316.29 g/mole> 98%

C12H9BO2S228.07 g/mole> 97%

C24H41BO2

372.39 g/mole> 98%

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

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: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

CNB

OO SBHO

OH

B

C12H25

O

O B

C8H17

O

O

NC6H13

BO

O

F

FF

B(OH)2 N

H3CO OCH3

BO O

B1795

B1796 B17971643935-09-4 1647121-47-8

C49H76B2O6

782.75 g/mole> 98%

C27H30BNO2

411.34 g/mole> 98%

C24H24BNO3

385.26 g/mole> 98%

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

N O

NOS

S

C8H17

C6H13

C6H13

C8H17

B

B

O

O

O

ON

BO

O

SiB BO

O O

O

C6H13

C6H13B

BO

O

O

OBB

O (CH 2) 6

O(H2C)6

O

O O

O

N

BOO

O

N

BOO

N N BO

O

B1799 1028729-05-6

C22H23BO2

330.23 g/mole> 98%

FormulaM.W.Grade

: : :

BO

O



Synth

etic Interm

ediates an

d R

eagents


344

B1800 B1801196212-27-8 1030834-61-7

C57H78B4N2O8

962.48 g/mole> 98%

C47H62BNO2

683.81 g/mole> 98%

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

B BO

O O

O

C8H17 C8H17

BNO

O



Synth

etic Interm

ediates an

d R

eagents

Synthetic Intermediates and ReagentsMetal Catalysts / Reductants

345

K0787

K0791

K0795

K0799

K0803

K0545

K0790

K0794

K0798

K0802

K0788

K0792

K0796

K0800

K0804

K0789

K0793

K0797

K0801

603-35-0

224311-51-7

13782-33-7

19978-61-1

7647-10-1

14221-01-3

247940-06-3

134620-00-1

14220-64-5

10025-98-6

6002-40-0

53199-31-8

12107-56-1

59831-02-6

14024-61-4

13716-12-6

14592-56-4

13965-03-2

95464-05-4

(C6H5)3P 262.29 g/mole> 99%

C6H5C6H4P[C(CH3)3]2 298.40 g/mole> 97%

Pd(NH3)2Cl2 211.39 g/mole> 99%

[(C6H5)2PCH2CH2P(C6H5)2]PdCl2

575.74 g/mole> 98%

PdCl2177.33 g/mole59-60% palladium (Pd) basis

Pd[(C6H5)3P]4 1155.56 g/mole> 99%

C24H31P 350.48 g/mole> 97%

C2H14N4O6Pd 296.58 g/mole> 99%

(C6H5CN)2PdCl2 383.57 g/mole> 95%

K2PdCl4 326.43 g/mole> 98%

[(CH3)3C]2PCH3 160.24 g/mole> 97%

C24H54P2Pd 511.05 g/mole

C8H12Cl2Pd 285.51 g/mole> 99%

C27H26P2 · PdCl2

589.77 g/mole

Pd(C5H7O2)2

304.64 g/mole> 98%

(CH3)3C]3P 202.32 g/mole> 98%

PdCl2 · (CH3CN)2 259.43 g/mole> 99%

[(C6H5)3P]2PdCl2 701.90 g/mole> 98%

C35H30Cl4FeP2Pd 816.64 g/mole

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

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FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.

FormulaM.W.Grade

FormulaM.W.

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.

: : :

: : :

: : :

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: : :

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: : :

: : :

: : :

: : :

: : :

: :

: : :

: :

: : :

: : :

: : :

: : :

: :

P

P P

P

PdP

PP t-But-Bu

Pd NN C CH3CH3CCl

ClOHO

O

2Pd2+ 4NH3

P

P Pd PP

PdNH3Cl

ClH3NPd

Cl

Cl

PdCl

ClP P Pd

Cl

ClN N CC Pd

Cl

Cl

P

P PPdP

PhPh

ClCl

PhPh

FeP

P

PhPh

PhPd

PdClCl

CH2Cl2Pd2Cl

ClCl

ClK+

K+ H3C CH3

O O

2Pd2+PdCl2

K0552 51364-51-3

(C6H5CH=CHCOCH=CHC6H5)3Pd2

915.72 g/mole> 97%

FormulaM.W.Grade

: : :

O

3

Pd2



Synth

etic Interm

ediates an

d R

eagents

Synthetic Intermediates and ReagentsMetal Catalysts / Reductants

346

K0807

K0811

K0806

K0810

K0814

K0808

K0812

K0809

K0813

29934-17-6

3375-31-3

14588-08-0

32005-36-0

12112-67-3

72287-26-4

1295-35-8

12012-95-2

14264-16-5

[(C6H11)3P]2PdCl2 738.18 g/mole> 95%

Pd(OCOCH3)2 224.51 g/mole> 98%

[(C6H5)3P]2Pd(CH3COO)2

749.08 g/mole> 98%

(C6H5CH=CHCOCH=CHC6H5)2Pd

575.00 g/mole

C16H24Cl2Ir2

671.70 g/mole> 97%

(C17H14P)2Fe · PdCl2 731.70 g/mole

C16H24Ni 275.06 g/mole> 98%

C6H10Cl2Pd2 365.89 g/mole> 98%

[(C6H5)3P]2NiCl2

654.17 g/molesynthesis grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.

FormulaM.W.Grade

FormulaM.W.

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

: :

: : :

: :

: : :

: : :

: : :

P

2

PdO

O

CH3

CH3

O

O

PdCl

ClPP Fe

P

P

PhPh

PhPd

PdClCl

PdCH2

CH2Pd

H2C

H2C

Cl

Cl

O

O

Pd

H3C O

O

2

Pd2+ Ni

Ir IrCl

Cl

P Ni PCl

Cl



Synth

etic Interm

ediates an

d R

eagents

Synthetic Intermediates and ReagentsOthers

347

K0041

K0451

K0549

K0070

K0842

K0040

K0057

K0535

K0747

K0840

K0055

K0498

K0550

K0488

K0843

K0056

K0534

K0597 K0817

K0845

33985-71-6

58519-06-5

1187-42-4

1090-13-7

312924-97-3

216978-79-9

479-59-4

6239-48-1

1310197-78-4

39778-14-8

910324-13-9

527-31-1

3029-32-1

6528-85-4

28286-88-6

1080-74-6

250734-47-5 1084334-28-0

856650-39-0

C13H15NO201.26 g/mole> 98% (HPLC)

C20H17N3

299.37 g/mole> 98% (HPLC)

C4H4N4

108.10 g/mole> 97% (HPLC)

C18H10O2

258.27 g/mole> 98% (HPLC)

C19H20BrNOS390.34 g/mole> 98% (HPLC)

C17H23NO257.37 g/mole> 98% (HPLC)

C12H15N173.25 g/mole> 98% (HPLC)

C15H17NO227.30 g/mole> 97% (HPLC)

C8H6Se2

260.05 g/mole> 99% (HPLC)

C18H16OS280.38 g/mole> 98% (HPLC)

C14H13IN2

336.17 g/mole> 97% (HPLC)

C20H11I3

632.01 g/mole> 98% (HPLC)

C6H16O14

312.18 g/mole> 98% (HPLC)

C22H12O2

308.33 g/mole> 97% (HPLC)

C14H12N2O224.26 g/mole> 98% (HPLC)

C10H8N2O172.18 g/mole> 98% (HPLC)

C12H6N2O194.19 g/mole> 98% (HPLC)

C19H18BF2IN2

450.07 g/mole> 97% (HPLC)


C15H15NO2

241.29 g/mole> 98% (HPLC)

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

: : :

: : :

: : :

: : :

: : :

: : :

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N

O H

NO

HN

N I

O

CNNC

N

H2N

H2N

NH2

I

I

I

O

NCCN

H2N CN

CNH2N

NB

N

I

FF

Se Se

NO

O

O

O

O

OO

OO

O

O8H2O S

Br

O

SS

NC6H13

OBr N

HN

O NH

COOEt



Synth

etic Interm

ediates an

d R

eagents

Synthetic Intermediates and ReagentsOthers

348

K0846

C11H15NO2

193.24 g/mole> 98% (HPLC)

FormulaM.W.Grade

: : :

NH

COOEt

K0890K0885 89827-45-2146823-30-5


C18H18I2488.14 g/mole> 98% (HPLC)

FormulaM.W.Grade

FormulaM.W.Grade

: : :

: : :

O

SS

NC6H13

OBr

K0942 39655-12-4

C12H8BrI359.00 g/mole> 98% (HPLC)

FormulaM.W.Grade

: : :

I

Br



Electrod

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Electrode / Substrate and SealingContents

349

• Electron Injection Layer(EIL) Materials / Metal (5) ----------------------------- 351

• ITO Glass / Bare Glass ---------------------------------------------------------- 352

• Sealing Materials --------------------------------------------------------------- 354



Electrod

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Electrode / Substrate and SealingITO Glass / Bare Glass

350

CAS No.GradeFormulaM.W.Melting PointBoiling Point





: : : :::

: : : ::

: : : ::

: : : ::

: : :::

7789-24-4 > 99.99%LiF25.94 g/mole848 °C1681 °C

534-17-8> 99.994%Cs2CO3

325.82 g/mole610 °C

1313-27-5> 99.998%MoO3

143.94 g/mole795 °C

13400-13-0> 99%CsF151.90 g/mole682 °C

7429-90-5> 99.999%Al26.98 g/mole660 °C

Lithium fluoride

Cesium carbonate

Molybdenum(VI) Oxide

Cesium fluoride

Aluminium

LT-E001

LT-E002

LT-E003

LT-E004

LT-E005

LiF

Cs2CO3

MoO3

CsF

Al



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351

We can supply OLED, OPV grade ITO, Indium Tin Oxide, transparent conductive coated glass. The ITO is deposited onto polished soda lime float glass in two standard smooth thicknesses giving 9~15 ohms per square and 4~6 ohms per square. Then SiO2 barrier coating is deposited between the ITO and glass.

Including custom photomask, we can supply the ITO glass cutting, cleaning and patterning service to customer requirements. The specialized pattern masking process is used which allows us to offer quantities ranging from small scale prototyping of re-search requirements to full scale production volumes.

• ITO glass specification and patterning process

Product No. LT-G001 LT-G002ITO Thickness : 1200~1600Å : 3100~3700Å ITO Resistance : 9~15 Ω/sq : 4~6 Ω/sq ITO Transparency : >84% (at 550nm) : >78% (at 550nm) Material : Polished soda lime glass Size : 370*470 mm or Customize Glass Thickness : 0.7 or 1.1 mm : 0.7 mmSiO2 Thickness : ≥ 200Å Ra : Less than 6 nm Rmax : Less than 35 nm



Electrod

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352

We also provide cleaning service of bare and sandlasted glass for the use of cover. Smaller pieces ofthe cover glasses can be cut and based on customers requirements.

• Glass cover specification and cleaning process

(Bare glass / Sandblasted glass)

• W Boat

LT-M310 : 100×10×0.3mm

Product No. LT-CoverSize : 370*470 mm or CustomizeThickness : 0.7 or 1.1 mm Mohs Hardness : 6.5Thermal Expansion : 85-90 (at 20 ~ 350 oC)Specific Heat : 0.19 cal/g oC (at 0 ~ 50 oC)Transmittance : > 90% Resistivity : 15.3 Log Ω-cm (at 25 oC), 7.3 Log Ω-cm (at 250 oC)



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Electrode / Substrate and SealingSealing Materials

353

UV curing adhesives not only bond materials together but they can also be used to seal and coat products. Also, it adheres well to glass surfaces. This product is cured after exposing to UV radiation. To obtain full cure on surfaces exposed to air, radiating wavelength at 365nm is effective.

UV Curing Adhesives for Sealing Application

Application Data

Curing Type UV

Coating System / Type Dispense / Edge sealing

Product LT-U001

Main contents Epoxy resin / Polymer

Store in 0~4oC

Before

Appearance Milky white

Density @25C 1.4 g/cm3

Viscosity @25C 200 Pa.s

After hardening

WVTRCup method

4 g/m2‐24h(JIS Z 0208) 40C/90%RH

Outgas Head space GC‐MS < 20 ug/resin

Tensile Shear Strength Autograph Glass/Glass sub. Material failure

Tg DSC 120oC

Low coefficientof linear expansion TMA < 6.0 X 10‐5/oC

Hardening condition (std.) 6 J/cm2 + 80 oC/1h



Cu

stom

Synth

esis Services

Custom Synthesis Services

354

Lumtec provides custom synthesis tailored to customers' specific needs in research and study. With the certification of ISO 9001 and 14001, Lumtec aims to provide our customers the best service. All inquiries of custom synthesis will be submitted to our technicians for thorough evaluations. The specification of custom products (product volume, purity, Mw, etc.) will be confirmed and agreed before the production proceeds. If necessary, non-disclosure agreements or other business agreements could be arranged and signed.

During the production we will keep our customers well-informed about the synthesis status. Analysis reports of the custom products such as HPLC, Ms, COA, etc. can be provided upon request.

Capacity and Equipment• Capacity

– 500 kg/month (production line)

– 100 kg/month (sublimation line)• Production Equipment

– 30-500 L reactors• Sublimation Equipment

– 6-8 inch quartz tubes• Analysis Equipment

– HPLC, NMR, LC-Ms, GPC, TGA, UV, PL, etc.• Device Evaluation

– Lithographically Patterned ITO Equipment (Clean Room: Class 100)

– Vacuum Deposition Equipment (Clean Room: Class 1000)

• Ullmann reaction• Cyanation reaction• Elimination reaction• Friedel-Crafts reaction• Alkylation/Acylation• Grignard reaction• Wittig reaction• Sandmeyer reaction

• Sonogashira reaction• Suzuki reaction• Baeyer-Villiger Oxidation• Vilsmeier reaction• Williamson reaction• Catalytic hydrogenation• Knoevenagel condensation

Specific Reaction

www.lumtec.com.tw

Head office : 2F, NO. 17, R&D Road II, Science-Based Industrial Park, Hsin-Chu 30076, Taiwan, TEL : +886-3-666-3188, FAX : +886-3-666-9288E-mail : [email protected] ; Web : http://www.lumtec.com.tw

[email protected]

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