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    Dr.-Ing. Lothar Kallien. Sigma Engineering GmbH, Aachen.

    Optimization of the Injection Moulding Process for Thermoplasts With 3D Simulation

    Optimization of the

    Injection Moulding Process

    for Thermoplasts

    With 3D Simulation

    Dr.-Ing. Lothar Kallien

    Sigma Engineering GmbH, Aachen

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    Dr.-Ing. Lothar Kallien. Sigma Engineering GmbH, Aachen.

    Optimization of the Injection Moulding Process for Thermoplasts With 3D Simulation

    1

    Optimization of the

    Injection Moulding Process

    for Thermoplasts

    With 3D Simulation

    1. Introduction

    The use of innovative CAE technologies has made it possible

    to drastically reduce the time required for process and product

    development. A new simulation tool for optimization of ther-

    moset components has recently become available, and can be

    used for three-dimensional computation of the mould filling,

    cross-linking and internal stress buildup on a monitor.In contrast to conventional programs, the described program

    operates with volume elements deriving from the technology of

    injection moulding of plastics. The frequently three-dimension-

    al geometries of thermoset components are thus depicted in a

    physically correct sense.

    The flow algorithm for the filling simulation is based on the

    Navier-Stokes equations, i.e. kinetic effects such as independ-

    ent stream formation are predicted. Air inclusions that can re-

    sult from turbulent mould filling are thus detected at an early

    stage in mould design and eliminated by optimization.

    The mould is three-dimensionally networked and the local tem-perature distribution calculated in the new 3D program. Thus,

    inhomogeneous temperature zones such as corner effects and

    their influence on the local cross-linking behavior are taken in-

    to account. Multiple cycles can be simulated to determine the

    temperature distribution in the mould during production start-

    up up to the quasi-stationary state.

    After stripping, thermally induced internal stresses, particular-

    ly as a result of contraction constraints due to metallic inserts,

    can lead to cracking. The buildup of such internal stress can be

    calculated and the resultant cracking thus predicted.

    2. 2D and 3D Simulation

    In developing injection moulded components, simulation pro-

    grams are used that based on empirical data and mathemat-

    ical models - can compute mould filling, the holding and the

    cooling phase to the point of stripping, and the extent of com-

    ponent deformation /1,2/. Programs used to date for simula-

    tion of injection moulding processes rely on geometric informa-

    tion that approximately describes the upper, lower and middle

    planes of the actual geometry. This method of calculation is

    generally referred to as a 2?-dimensional shell model. The on-

    ly approximate description of the component geometry by a

    middle plane can have a negative effect on the quality of theresult. This particularly applies to calculation of components

    with irregular wall thickness /3,4,5,6/. Furthermore, three-

    dimensional flow effects cannot be resolved, since these

    programs always assume parallel laminar flow. Figure 2.1

    schematically illustrates zones in a plastic component in which

    three-dimensional flow effects develop /4/.

    Figure 2-1: Zones of three-dimensional melt flow in injection moulding /5/

    3. CAD Transference and Cross-Linking in 3D

    Including Mould and Inserts

    Presently, volume-oriented CAD data exist for the product to be

    calculated in most cases. These can be imported into SIGMA-

    SOFT as STL files. All types of FEM volume networks can sim-

    ilarly be transferred to SIGMASOFT. The geometry of the

    moulding can be expanded to include the injection points or

    the mould geometry using an integrated solid modeler.

    Separation into a three-dimensional volume network is fully au-

    tomatic. Depending on the complexity of the networking geom-

    etry, this operation takes only a few seconds to a maximum of

    2 3 minutes. In any case, the complete mould including all

    cooling and heating channels is networked.

    4. Simulation of a Thermoset Component

    A water circulation system produced at LM Plast for a French

    automobile was simulated in cooperation with the Vyncolit

    Company. The component is used in PSA-group cars such as

    the 106, 206 and 306 Peugeot models and the Saxo, Xsara

    and Berlingo Citroen models (Figure 4-1).

    Figure 4-1: Citroen Berlingo

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    Dr.-Ing. Lothar Kallien. Sigma Engineering GmbH, Aachen.

    Optimization of the Injection Moulding Process for Thermoplasts With 3D Simulation

    2

    This involved replacement of a die-cast aluminum component

    by a thermoset part. One of the reasons for this substitution

    was the major weight advantage: the aluminum component

    weighs 614 g, and the plastic part only 344 g. Figure 4-2

    shows a direct comparison of the aluminum component (left)

    and the new thermoset part (right).

    Figure 4-2: Comparison of an aluminum (left) andthermoset (right) component

    The design geometry was retained essentially unchanged in

    this simulation. The component is fabricated in a single-cavity

    mould. The data were adopted from a CAD System, and sim-

    ply imported into the preprocessor (Figure 4-3).

    Figure 4-3: Transfer of geometry to the simulation

    Networking in three-dimensional volume elements is fully au-

    tomatic. Figure 4-4 shows the networking geometry including

    the sprue.

    Figure 4-4: SIGMASOFT volume model

    After the geometry has been entered, the process and ma-

    terial data must be added. These include the filling time, the

    volume flow or filling pressure at the gate, the temperature of

    the thermoset material when injected, the preliminary cross-

    linking density, the mould temperature and information on the

    thermal conductivity coefficients of the involved groups of

    materials.

    The density, thermal conductivity, heat capacity as a function

    of the temperature and the cross-linking enthalpy of the ther-moset must be known. In order to calculate cross-linking as a

    function of the time, cross-linking curves at a minimum of

    three different temperatures must be entered into the program.

    Figure 4-5 illustrates a cross-linking curve for a temperature of

    160C. SIGMASOFT approximates this process fully automat-

    ically using the Deng-Isayev model. The actual results and

    the approximated cross-linking curve are directly compared in

    the figure.

    Figure 4-5: Cross-linking curve at a temperature of 160C

    The cross-linking reaction during mould filling is also calculat-ed in SIGMASOFT. This is accomplished using a Cross-

    Arrhenius formula that describes the viscosity as a function of

    the shear rate, the temperature and the local cross-linking den-

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    Dr.-Ing. Lothar Kallien. Sigma Engineering GmbH, Aachen.

    Optimization of the Injection Moulding Process for Thermoplasts With 3D Simulation

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    sity. If the cross-linking density exceeds a critical value in spe-

    cific zones, the viscosity rises sharply and flow is no longer

    possible. The following formulas describe this relationship.

    Alphagel is the cross-linking density at which flow is no longerpossible.

    For gel the following term

    describes the viscosity as a function of the cross-linking densi-

    ty, the temperature and the shear rate.

    In this case

    and

    If gel then

    Tb: Reference temperature [K]

    B: Arrhenius constant [Pas]

    *: Material constant [Pa]

    n: Cross exponent

    gel: Cross-linking density

    C1, C2: Constants

    The process parameters for the component were as follows:

    Filling time: 5s

    Bulk temperature: 110C

    Preliminary cross-linking density of the compound

    during filling: 5%

    Mould temperature: 170C

    Mould filling, the cross-linking reaction, cooling to ambient

    temperature and the resultant internal stresses were calculat-

    ed. Figure 4-6 shows the temperature distribution at 85 %

    mould fill. The compound enters the heated mould at 110C,

    and the temperature rises further. The local shear rate is high-

    est at the gate (Figure 4-7).

    Figure 4-6: Temperature distribution at 85 % mould fill

    Figure 4-7: Local shear rate distribution in the gate

    The flow phenomena can also be visualized using tracer parti-

    cles. The colors of these weightless particles in Figure 4-8

    show the ingress age of the particles, whereas the vectors de-

    scribe the directions and velocities of the particles. Figure 4-9

    shows the temperature distribution at the conclusion of mould

    filling. The coldest melt is located at the gate.

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    Dr.-Ing. Lothar Kallien. Sigma Engineering GmbH, Aachen.

    Optimization of the Injection Moulding Process for Thermoplasts With 3D Simulation

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    Figure 4-8: Tracer particles visualize the flows

    Figure 4-9: Temperature distribution at 100% mould fill

    The mould filling process can also be described by the local fill-

    ing time (Figure 4-10). The pressure required for filling is illus-

    trated in Figure 4-11. The value at the front flange (arrow)

    could be verified by an internal pressure sensor in the mould.

    A pressure of 230 bars was determined at this point.

    Figure 4-10: Local filling times in seconds

    Figure 4-11: Pressure distribution at conclusion of filling. The arrow shows

    the position of the internal pressure sensor in the mould.

    Since the compound is injected into the cavity at a preliminary

    cross-linking density of 5 %, the local cross-linking density has

    risen to 11% at the end of the filling operation (Figure

    4-12). Particularly in the vicinity of ribs, where the melt can

    no longer flow, the compound rapidly heats up and begins

    to cross-link (arrow). The local cross-linking density has

    increased to 55% after 16 seconds (Figure 4-13). The effect of

    mould filling is clearly apparent, since the zones that are

    farther away from the gate are more highly cross-linked by the

    elevated temperature.

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    Dr.-Ing. Lothar Kallien. Sigma Engineering GmbH, Aachen.

    Optimization of the Injection Moulding Process for Thermoplasts With 3D Simulation

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    Figure 4-12: Local cross-linking density at conclusion of mould filling.Zones such as ribs, which are not exposed to a continuous flow, heat upand cross-link more rapidly.

    Figure 4-13: Local cross-linking density after 16 seconds

    After 40 seconds, 7 % of the total compound is cross-linked

    (Figure 4-14). Zones with less than 70% cross-linking can be

    visualized in an X-ray view (Figure 4-15).

    Figure 4-14: Local cross-linking density after 40 seconds

    Figure 4-15: X-ray view of zones with less than 70% cross-linking density

    Following cross-linking in the mould, cooling in air to ambient

    temperature is calculated. The thermally induced internal

    stresses outside the mould can be calculated on the basis of a

    plastic-elastic material model in order to obtain data on de-

    formation. The stress calculation can be carried out for

    both isotropic materials and anisotropic, fiber-reinforced

    thermosets.

    The stress calculation assumes that the material is completely

    cross-linked when the mould is opened. The calculation is

    based on the following temperature-dependent, thermome-

    chanical parameters:

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    Dr.-Ing. Lothar Kallien. Sigma Engineering GmbH, Aachen.

    Optimization of the Injection Moulding Process for Thermoplasts With 3D Simulation

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    The isotropic elastic modulus or the elastic modulus length-

    wise and transverse to the fiber direction

    The isotropic coefficient of thermal expansion, or the param-

    eter lengthwise and transverse to the fiber direction

    The transverse contraction number

    In this case, the plastic is a short glass fiber-reinforced mate-

    rial. The elastic modulus in such a case depends very greatly

    on the fiber orientation. The fiber orientation can be three-di-

    mensionally calculated using SIGMASOF. Figure 4.16 shows

    the fiber orientation in a rib foot. Figure 4-17 shows the local

    distribution of the von-Mises internal stresses at ambient tem-

    perature. Because of the previously mentioned limitation, the

    results should be considered qualitative. Figure 4-18 shows

    the main stresses along the y-axis. The local shifts can be cal-

    culated on the basis of these values.

    Figure 4-16: Three-dimensionally calculated fiber orientation in a ribtransition area. The vectors indicate the direction of the fibers, and the

    colors show the degree of orientation in the pertinent element.

    Figure 4-17: Thermally induced internal (von-Mises) stresses

    Figure 4-18: Thermally induced main stresses along the y-axis

    Figure 4-19 shows the shifts along the y-axis. The depicted de-

    gree of deformation is exaggerated by a factor of 50.

    Figure 4-19: Shifts along the y-axis

    Figures 4.2x show a direct comparison of filling simulations.

    4 Export of Results to FE Networks

    Using a new interface, both the cross-linking reaction and fiber

    orientation results can also be exported to finite element net-

    works. Figure 4.20 shows the three-dimensionally calculated

    fiber orientation along the xaxis for a test component. This

    result can now be exported to a wide variety of finite elementnetworks. Figure 4.21 shows the fiber orientation after being

    exported to a finite element network for further processing in

    ABAQUS.

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    Dr.-Ing. Lothar Kallien. Sigma Engineering GmbH, Aachen.

    Optimization of the Injection Moulding Process for Thermoplasts With 3D Simulation

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    Figure 4-20: 3D-fiber orientation in SIGMASOFT

    Figure 4-21: 3D-fiber orientation in a finite element network for further pro-cessing in ABAQUS

    Figure 4.22 shows a direct comparison of the filling simulation

    with actual filling studies that were later performed. The simu-lation in the top picture offers an excellent view of the connect-

    ing seam in the component.

    Figure 4-22: Direct comparison of the simulation and the result of an experi-mental filling test shows very good agreement even in details (arrow).

    5. Thermoset Components With Inserts

    The stress calculations are of particular interest when inserts

    are to be embedded. Holec Holland NV in Hengelo manufac-

    tures thermoset components for high-tension engineering that

    are exposed to as much as 24 kV in later use. Metallic inserts

    are embedded in the thermoset of these components. The dif-

    ferent coefficients of thermal expansion of the thermoset and

    the metal can lead to stress cracking that affects the operation

    of the component. At Holec, the SIGMASOFT simulation pro-

    gram is used to predict filling, cross-linking and stress buildup

    during cooling. An optimized design for the component and the

    mould can thus be developed prior to actual component and

    mould construction. Figure 5-1 shows the thermoset compo-

    nent, and Figure 5-2 the insert. Figure 5-3 shows the temper-

    ature distribution at the conclusion of mould filling. The

    effect of mould filling on the temperature distribution is alsoapparent in this component.

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    Dr.-Ing. Lothar Kallien. Sigma Engineering GmbH, Aachen.

    Optimization of the Injection Moulding Process for Thermoplasts With 3D Simulation

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    Figure 5-1: High-tension component from Holec

    Figure 5-2: Metal insert

    Figure 5-3: The temperature distribution at the conclusion of mould fillingshows the effect of this operation

    6. Summary

    Mould filling, cross-linking, cooling and internal stress buildup

    during fabrication of thermoset components by casting or in-

    jection moulding can be three-dimensionally calculated using

    the new simulation tool. This permits optimization of the com-ponent design and mould prior to production. SIGMASOFT

    operates on the basis of three-dimensional volume elements.

    The advantages of this new 3D simulation method using volu-

    metric elements for simulation of thermoset components may

    be summarized as follows:

    Model preparation costs are eliminated since CAD data can

    be utilized and automatically networked.

    Flow phenomena such as backwater areas in thick-walled

    zones of mouldings or at points with different wall thickness

    are described in physically exact terms.

    Kinetic effects such as independent stream formation maybe predicted.

    Calculation of the cross-linking reaction takes account of the

    reaction enthalpy.

    Local cross-linking has an effect on mould filling.

    It is possible to take account of the back-pressure of air in

    the mould.

    The fiber orientation can be calculated in three dimensions,

    and used for stress analysis.

    The thermally induced buildup of internal stress during cool-

    ing can be calculated. Thermal effects on the flow and cross-linking processes are

    accounted for by the three-dimensionally coupled calcula-

    tion of the moulding, inserts and mould.

    The consideration of heating systems is three-dimensional;

    the local effect on the mould wall temperature is calculated.

    The cycle time can be predicted.

    References

    1. H. Bogensberger, Kunststoffe 85, 44 ff (1995).

    2. P.F. Filz, Kunststoffe 88, 954 ff (1998).

    3. B. Ohlsson, First International Thermoset Symposium in Iserlohn, Mrkische

    Fachhochschule Iserlohn

    4. P. Thienel, International Mould Construction Symposium 1999, Dr. Reinhold

    Hagen Stiftung, Bonn

    5. W. Michaeli, H. Findeisen, and T. Gossel, Kunststoffe 87, 462 ff (1997).

    6. O. Altmann and H.J. Wirth, Kunststoffe 87, 1670 ff (1997).

    7. A.J. van der Lelij, Kunststoffe 87, 51 ff (1997).