one man is another man treasure beneficially reusing
TRANSCRIPT
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One man’s trash,
is another man’s treasure
Beneficially Reusing Industrial Wastewaters & Waste By-products
presented by
Wes Ripple, NHDES for the
2013 North East Biosolids and Residuals Conference
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Pilgrim Foods – Greenville, NH n Medium size food processing facility n Produce mustards, vinegar and apple juice n Generate about 5,000 GPD of process wastewater
n Pretreat in aerated lagoons n Raw wastewater characteristics:
n BOD 24,000 mg/l n COD 54,000 mg/l n Acetic acid 34,000 mg/l
n Industrial discharge permit to town sewer: n Flow limit 14,600 GPD monthly average n BOD 300 mg/l n Acetic acid 100 mg/l
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Pilgrim Foods - Problems
n Pretreatment lagoons don’t always work very well n Discharge violations n Sludge accumulation n High flows
n Relationship with town difficult (on a good day) n Odor problems/complaints n Air permitting problems n Arsenic in groundwater problems n All leading to pressure to close the lagoons – What to
do with the process wastewater??? All options cost $$$$
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Great Bay Estuary n Tidal waters, deep channels, and mudflats n Fed by 7 rivers carrying pollution from 42 NH
towns and 10 Maine towns n Surface area of 17 sq miles, 1,023 sq miles of
watershed & 150 miles of tidal shoreline n At 10 miles inland, it is one of the largest and
most recessed estuaries on the east coast n Home to 162 bird, fish and plant species
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Sources of Nitrogen in Great Bay
n 68% from non-point sources n Atmospheric deposition n Septic systems n Lawn fertilizers n Animal wastes (mostly livestock)
n 32% from point sources n Wastewater treatment plants
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Regulate and Control Nitrogen at the Point Sources (WWTFs)
n NPDES permits will be written for 3 mg/l TN n The Limit of Technology, or LOT
n Administrative orders will be written for 8 mg/l n Time will be allowed for additional monitoring
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Nitrogen Removal is a Two Step Process
n First, ammonia is converted to nitrate via biological nitrification under aerobic conditions
n Second, nitrates are converted to nitrogen gas via denitrification under anoxic conditions (no air)
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So, what do nitrogen removal, Great Bay & Pilgrim Foods have in
common? n To meet low level nitrogen limits, a food source
(carbon) must usually be added during the anoxic denitrification stage.
n The bugs eat the food, and, if oxygen is not present, use nitrate (NO3) for respiration, leaving nitrogen gas stripped off to the atmosphere, completing the nitrogen removal process
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Methanol
n Methanol is typically used as the carbon source of choice
n It is high strength n COD of 1,888,000 mg/l n Easily consumed by bacteria
n Drawbacks n Highly flammable n Highly toxic in both liquid and vapor form n More money invested in methanol storage facilities
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Alternatives to Methanol
n Proprietary products n Micro C
n Pure chemical compounds n Concentrated acetic acid n High fructose corn syrup
n Brewery, soft drink, and fruit juice wastes n Glycerin
n Crude & various stages of refined
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Rochester WWTF
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Rochester Pilot Test for Nitrogen Removal
n First phase – Rectify over-aeration problems. n Aeration system is designed more for mixing and results in
excess D.O. n Excess D.O. interferes with denitrification and nitrogen
removal. n Floating mixers added to keep MLSS in suspension n Blower output reduced for energy savings and better D.O.
control
n First phase has resulted in some nitrogen reduction
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Phase 2
n Add methanol to get more nitrogen reduction
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Phase 2
Vinegar, fruit juice and mustard are ideal foods for bacteria – readily consumed in a short period of time Eliminates the hazards of methanol Meets both needs and solves 2 problems at once
Why not add Pilgrim Foods wastewater instead and treat it as an alternative carbon source?
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A win-win relationship has formed
n Pilot testing is about to get underway n Pilgrim Foods will be loaning Rochester two 5000
gallon storage tanks n Pilgrim Foods will cover transportation costs n If successful, Rochester will accept all of Pilgrim’s
wastewater on a year-round basis and get a free carbon source
n Pilgrim Foods will be able to close their lagoons and become part of the nitrogen solution to Great Bay
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Additional Benefits of Pilgrim Foods and Similar Types of Wastewater
n High acetic acid content makes it an ideal supplement for biological phosphorus removal n Acetic acid must be generated in a Bio-P plant in
order for PAOs to uptake phosphorus in the aeration zone
n Ideal food source for anaerobic digestion n Produce more methane, generate more electricity
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Glycerin – Another Carbon Source
n A waste by-product of biodiesel production n About 10% of biodiesel production results in
glycerin as a waste by-product n Too strong to discharge to the sewer n 2 big producers in NH
n White Mountain Biodiesel, Haverhill NH n Generates about 200,000 GPY of glycerin
n Granite State Biofuels, Bow NH (new) n Expected to generate 50,000 GPY of glycerin
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White Mountain Biodiesel
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In controlled doses, it becomes another inexpensive carbon source
for nitrogen removal systems
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Fixed film nitrification/denitrification
Fixed film denitrification tanks
Glycerin
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Pilot Total Nitrogen
0
5
10
15
20
25
30
35
40
45
50
Inlet
Outlet
May 28 October 9
Target 8 mg/l 3.8 mg/l
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Keep it local: Some industries can be a resource
n Maybe it’s time to rethink how we view industrial wastes
n Industrial wastewaters & waste by-products can: n Save money n Reduce carbon footprint n Eliminate hazardous chemicals n Satisfy a need
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…and this is what it’s all about.