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www.VeoliaES.com

Welcome to Marquette University’s Hazardous Waste

and Emergency Procedures Awareness Training

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www.VeoliaES.comNORTH AMERICATECHNICAL SOLUTIONS www.VeoliaES.com

Why am I here?

• Handle or generate hazardous materials

• Formal personnel training program is a requirement for large quantity generators (49 CFR 265.16)

• To be trained on the proper procedures of accumulating and storing hazardous materials to ensure compliance with the law

• To prevent personal injury, property damage, or a major spill

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Agenda

• Marquette’s Classification & History

• Hazardous Waste Characteristics

• Recognizing Hazardous Materials

• Handling Hazardous Materials & Proper Personal Protective Equipment

• Satellite Accumulation Procedures

• 90-Day Storage Area Procedures

• Spill Response, Clean-Up, Emergency Response and Preparedness

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Acronyms

• EPA = Environmental Protection Agency» Determines what is a hazardous waste

• DOT = Department of Transportation» Regulates transportation of hazardous materials

• RCRA = Resource Conservation & Recovery Act» Governs the disposal of solid and hazardous wastes

• DNR = Department of Natural Resources» Governs over the generators of hazardous waste

• OSHA = Occupational Safety and Health Administration

» Regulates hazardous materials in the workplace

• PPE = Personal Protective Equipment» Last line of defense against hazardous materials


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Marquette’s History and Classification

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Marquette’s Hazardous Waste History

• In 2010:– 8,281 pounds of Hazardous Waste– 1,204 pound of Non-Hazardous Waste

• In 2009: – 20,157 pounds of Hazardous Waste– 13,413 pounds of Non-Hazardous Waste

• In 2008: – 8,623 pounds of Hazardous Waste– 2,198 pounds of Non-Hazardous Waste

• In 2007:– 12,397 pounds of Hazardous Waste– 8,018 pounds of Non-Hazardous Waste

• Halogenated Solvents and Non-Halogenated Solvents

• Veolia ES Technical Solutions disposes of materials

• Small Quantity Generator to a Large Quantity Generator

• Developing procedures and plans to comply with new regulations from this transition

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Three Categories of Generators

Very Small Quantity Generator (VSQG)– < 220 lbs/month generation or < 2205 lbs total accumulation

Small Quantity Generator (SQG)– 220 - 2205 lbs/month generation or < 13,230 lbs total accumulation

Large Quantity Generator (LQG)– > 2205 lbs generation/month or > 13,230 lbs total accumulation

Acute Waste– >2.2 lbs/month generation or > 2.2 lbs accumulation at any time makes you a LQG

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How much is that?

2200 lbs. (1000 kg) is about five 55-gallon drums


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Hazardous Waste Determination

Characteristic versus Listed Wastes

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Hazardous Waste Determination

• Characteristic Wastes– Ignitability– Corrosivity– Toxicity– Reactivity

•EPA Listed Wastes–P Listed: Unused acutely Hazardous Waste

–U Listed: Unused non-acutely hazardous waste

–K Listed: Waste from Specific Sources

–F Listed: Waste from Non-Specific Sources

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Ignitable WastesFlashpoint <140° F, or solids that easily catch fire. - Examples: acetone, xylene, and acetonitrile and other solvents

Compressed flammable gases, such as propane

Flammable solids, such as road flares or carbon. Ignitable materials are represented by a D001 waste code.

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Potassium Tert-butoxide, a flammable solid

Corrosive Wastes

- pH <2 or >12.5

- Capable of corroding steel at a rate greater than 0.25 inches per year.

Examples: nitric acid, aqueous sodium hydroxide, hydrochloric acid.

Corrosive materials are represented by a D002 waste code.

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Reactive Wastes

Materials that undergo violent change: - react violently with water or air- capable of detonation- create toxic gases when exposed to pH extremes

Examples: sodium metal, extremely dry picric acid, and organic peroxides.

Reactive materials are represented by a D003 waste code.

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Toxic Wastes

- Materials that are poisonous, harmful and potentially deadly- Examples: lead acetate, mercuric chloride, benzene.

The wastes are represented by codes from D004 – D043. These codes are specific to material types. For example: Mercury has a D009 code, Benzene has D018.

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Examples of Toxic Contaminants

Heavy Metals:arsenic, barium, cadmium, chromium, lead, mercury, selenium, silver

Pesticides:Chlordane, 2,4-D, Endrin, Lindane, Heptachlor, Methoxychlor, Silvex (2,4,5-TP), Toxaphene.

Organics:benzene, carbon tetrachloride, chlorobenzene, chloroform,

Organics, continued: cresol, 1,4-dichlorobenzene,

1,2-dichloroethane, 1,1-dichloroethylene, 2,4-dinitrotoluene, hexachlorobenzene, hexachlorobutadiene, hexachloroethane, methyl ethyl ketone, nitrobenzene, pentachlorophenol, pyridine, tetrachloroethylene, trichloroethylene, 2,4,5-trichlrophenol, 2,4,6-trichlorophenol, vinyl chloride.

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Contact Dennis Daye (414) 288-8411 if you have questions about the status of your

waste.

Hazardous Waste Management can be very confusing and we are here to help

you! Aaron Walters, Veolia Environmental Services

On campus Wednesday from 2-4 PM


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Recognizing Hazardous Materials

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Recognizing Hazardous Materials

• Read Material Safety Data Sheets (MSDS)– A document provided by the

manufacturer– Contain ingredients and lists the hazards

of materials– Lists routes of exposure and proper PPE

that should be worn when handling– Has spill response, disposal and other

environmental information– Contains contacts if further information is

needed

Material Material

Safety Data Safety Data

SheetsSheets

MMSSDDSS

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http://cispro.mu.edu/

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National Fire Protection Association (NFPA) Label

Flammability Hazard

Reactivity Hazard

SpecificHazards

HealthHazard

•NFPA –Colors and numbers are used to communicate the potential hazards of a material.

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Number Rating Word Rating Description ofDegree of Danger

0 minimal Little or no damage, evenwith heavy exposures.

1 slight Irritation or minor injurythat can be cured.

2 moderate May cause temp. or perm.minor injury or make youunable to function.

3 serious Short exposure may causeserious injury and requiresquick medical attention.

4 severe Short exposure may causedeath or serious injury.

NFPA: Health Hazard

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NFPA: Flammability Hazard

Number Rating Word Rating Description of Degree of Danger

0 minimal Does not normally burn even when heated to 1500 deg F

1 slight Will burn but must be heated, FP200°F

2 moderate Must be heated somewhat before burning or may form harmful gases if heated. FP=100°-200°F

3 serious Can be ignited easily, burns rapidly or ignites on exposure to air. FP=<100°F

4 severe Gives off explosive vapors at room temperature (73°F)

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NFPA: Reactivity Hazard

Number Rating Word Rating Description of Degree ofDanger

0 minimal Usually does not change evenduring conditions of fire.

1 slight Usually does not change, butmay release some energy at hightemperatures and pressures.

2 moderate Usually changes easily, mayundergo strong changes (notreleasing energy suddenly/notexploding) although it may beexplosive in water.

3 serious May explode but needs a strongstart (example - hightemperature, pressure, or shock).

4 severe Slight shock, pressure, ortemperature may cause anexplosion.

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NFPA: Specific Hazards

Hazard Abbreviation

Oxidizer OX

Acid ACID

Alkali ALK

Use No Water W Radioactive

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Hazardous Materials Identification System(HMIS) Label

HEALTH

FLAMMABILITY

REACTIVITY

PERSONAL PROTECTION

0-4

0-4

0-4

letter

Colors, numbers, and letters are used to communicate the potential hazards of a material as well as what kind of protective equipment should be worn.

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HMIS: Personal Protection

A Safety glasses

B Safety glasses/gloves

C Safety glasses/gloves/apron

D Face shield/gloves/apron

E Safety glasses/gloves/dust respirator

F Safety glasses/gloves/dust respirator/apron

G Safety glasses/gloves /vapor respirator

H Goggles/gloves/apron/ vapor respirator

I Safety glasses/gloves/dust and vapor respirator

J Goggles/gloves/apron/dust and vapor respirator

K Airline hood or mask/gloves/protective coveralls/boots

X Ask your supervisor

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DOT Hazard Classes

• Class 1 – Explosives

• Class 2 – Gases

• Class 3 – Flammable Liquids

• Class 4 – Flammable Solids

• Class 5 – Oxidizers and Organic Peroxides

• Class 6 – Toxic Materials and Infectious Substances

• Class 7 – Radioactive Materials

• Class 8 – Corrosive Materials

• Class 9 – Miscellaneous Hazardous Materials

Department of Transportation (DOT) Hazard Class Diamonds and Placards

–Containers and trucks are marked with diamonds to inform you of the material’s hazard class

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DOT Labels


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Hazardous Material Handling and Proper Personal Protective Equipment

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Considerations when Handling Hazardous Materials

• Use common sense!

• Think before you act

• Follow good housekeeping procedures– Clean-up after yourself

• Always wear the proper PPE

• Know the hazards of the materials you are working with!• Create and use chemical specific SOP’s (Safe Operating Procedures)

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Controlling Hazards

1. Engineering Controls• Eliminate the hazard from the workplace

2. Administrative Controls• Limit worker contact with the hazard• Training/Procedures, Good Housekeeping

3. PPE • LAST RESORT

Material Handling and Proper PPE

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PPE = Last Resort

• When PPE is the primary control measure, the hazard is still present in the environment

• Failure of the PPE or improper usage can expose the worker to the full effect of the hazards present in the environment

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Types of PPE

• Head Protection• Eye/Face Protection• Hearing Protection• Foot Protection• Respiratory Protection• Hand and Arm Protection• Electrical Protective Devices• Special Work Clothing

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Considerations for PPE Selection:

• The types of hazards you will be in contact with– Physical Hazards– Chemical Hazards

• The specific chemicals you will be in contact with

• The concentration of these chemicals

• The length of time the PPE is to be worn

• The durability of the PPE

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PPE continued

• PPE Limitations– Degradation– Permeation/Breakthrough– Penetration– Tears/Rips– Location

• PPE Failure– Knowing how to recognize PPE failure is crucial since PPE is the last line

of protection between you and the chemical

– Limit contact time with the chemical/hazard and inspect and change PPE frequently


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Satellite Accumulation Procedures

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Satellite Accumulation

• “A generator may accumulate as much as 55 gallons of hazardous waste…in containers at or near any point of generation…which is under the control of the operator…”

• Up to 1 quart of acutely hazardous waste (P-coded) can be

collected in a satellite accumulation area

• Your research labs, student labs or other rooms where materials are collected and accumulated are considered to be Satellite Accumulation Areas

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Satellite Accumulation

• Containers must remain closed when not adding waste

• Must be leak-proof and in good condition

• Containers must be compatible with contents– No corrosive materials in metal containers

• Store liquid wastes in secondary containers– Must be able to hold 110% of the largest containers volume

• Containers must be moved to storage location within 3 days after being filled

•Material name must be on label –NO CHEMICAL FORMULAS OR

ABBREVIATIONS!!!•The container must have the words “hazardous waste”

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Accumulation Start Date

There are two (2) Regulations to follow:

1. Material can not be stored / accumulated in satellite accumulation area for more than one year.

2. Material can not be stored for more than 90 days in 90-Day Storage Area.

So, please put the date that you start accumulating material on the Hazardous Waste Tag.

Before submitting for disposal, please cross-out and initial by the old date and write in the current date

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Example of Inadequate Labeling

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Container Management

• Attach label BEFORE adding waste

• Container must be closed when not adding waste– Lids must be on – no funnels

• Containers should be kept in their designated areas

• Keep the outsides of containers free of waste

• Do not use the top of the container as a storage shelf

• Free access to containers must be maintained at all times!

• Segregate Chemicals according to compatibility

Hazard Storage Class Storage Type Examples

Inorganic Acids Corrosives Cabinet Do not store acids and bases in same cabinet

Conc. Hydrochloric Acid (37%), Phosphoric Acid Less than concentrated: Sulfuric Acid, Nitric Acid

Organic Acids Corrosives Cabinet Dichloroacetic Acid, EDTA (ethylenedinitrilo tetraacetic acid), Thimerosal

Bases Corrosives Cabinet Do not store acids and bases in same cabinet

Ammonium Hydroxide, Calcium Oxide, Potassium Hydroxide, Sodium Hydroxide

Oxidizing / Special Handling Inorganic Acids

Corrosives Cabinet Cabinet labeled ‘Oxidizing / Special Handling Inorganic Acids’Separate secondary containment for each (& label)

Bromine, Hydrofluoric Acid

Concentrated: Nitric Acid (70%) , Perchloric Acid (60%), Sulfuric Acid (96%)

Oxidizers General Storage Cabinet Cabinet labeled ‘Oxidizers’

Sodium Hypochlorite. The following are generally considered oxidizing substances: Peroxides, Perchlorates, Chlorates, Nitrates, Nitrites and less than concentrated Perchloric Acid.

Toxics Designated Storage Cabinet Cabinet labeled ‘Toxics’ , use secondary containment

Chloroform, Ethidium Bromide, Lead, Mercury Compounds, Potassium Cyanide, Phenol

Flammables Flammable Storage Cabinet Only keep flammables in a flammable cabinet

Acetone, Acetic Acid, Benzene, Ethyl Ether, Formaldehyde, Heptane, Hexane, Methanol, Pentane, Picric Acid, Toluene, Xylene

NONE General Storage Cabinet Double check NFPA Ratings to ensure general storage is appropriate

MARQUETTE UNIVERSITY CHEMICAL COMPATIBILITY IN STORAGEKeep stored incompatible chemicals apart from each other. Keep incompatible chemicals apart by cabinet, drawer, shelving unit or shelf. For liquid and high hazard chemicals, secondary containers are effective tools to prevent reactions between incompatible chemicals. When storing reactive chemicals, secondary containment can prevent degradation and reactions that occur during storage. It is best to use secondary containers made of materials that are non-reactive (i.e., polyethylene, polypropylene). Refer to Marquette’s Guidelines for Preventing Chemical Incompatibility Hazards.

If there is an asterisk with the hazard storage class number (6*), the chemical is considered to be a particularly hazardous substance by Marquette University. A Standard Operating Procedure (SOP) is required for all particularly hazardous substances.


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90-Day Hazardous Waste Accumulation Area Procedures

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90-Day Storage Area

• Full, labeled and dated containers should be brought here for storage until the next waste pickup

• Accumulation date is the date it is brought into storage area

• Containers labeled and label is facing forwards

• Containers must be clean, closed and intact

• Incompatible materials must be segregated

• There must be at least 3 feet of aisle space at all times

• The area must be free of debris and spills

These parameters above are federal & state regulations that must be followed or fines will be incurred!!

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• The 90-day storage area is inspected weekly to ensure that all of these regulations are complied with

• Waste can only be stored in the accumulation area for 90 days

• Any waste brought into the storage area must be marked on the waste generation form that is to be sent to Dennis

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Dept.

Date: Page of

Person(s) doing inventory / Contact Person(s) Phone Ext.

(S)olid, (L)iquid or

(G)as

Container Size

Total Estimated

Quality Wgt./Vol.

Container Type

No. of Containers

Chemical Name / Description Comments

Chemical Waste Inventory DisposalMarquette University

Location / Room #11/05/08 1 1

Jon Pipkorn

Olin Engineering 126

Toluene Liquid 4 L 2 L Glass 1

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Your Responsibilities

• You must fill out an inventory of material generated or discarded and send it to Dennis

– State and Federal Regulations State:“The identity and location of all stored hazardous waste shall be known

throughout the entire accumulation period.”

– To maintain documentation of hazardous waste that is currently being stored, in case of an emergency

– Makes waste shipment easier

– Aids in determining waste generation rate

– Helps identify waste minimization opportunities

• Please fill out sheet for materials to be disposed of on a regular basis

• Inspect your work area to ensure proper procedures and practices are being followed

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90-Day Hazardous Waste Storage

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What happens when an Acid and Oxidizer are mixed?


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Spill Response, Clean-Up, and Emergency Response

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Please reference the Marquette University Emergency Procedures Guide and

Contingency Plan for further details on what to do in case of an emergency.

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Mercury Thermometer Exchange Program

• Replace mercury thermometers with alcohol thermometers for FREE

• The new alcohol thermometers will be paid for by EHS

• Eliminates the possibility of mercury spills occurring

• Please fill out the “Mercury Thermometer Exchange Request” Form and send to Dennis Daye

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Causes of chemical spills are as follows:

• Inappropriate handling techniques;

• Inappropriate storage containers;

• Damaged storage containers;

• Uncontrolled access to chemical storage;

• Lack of chemical-related training; and

• Lack of supervision.

Causes of a Spill

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Dangers of Chemical Spills

• Slip, trip, fall hazard

• Contamination of other materials

• Risk of Fire

• Possible Release to the Environment

• Routes of Exposure to Hazardous Materials– Inhalation– Injection– Ingestion– Absorption

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Why chemicals are dangerous?

• Chemicals can cause:- Burns- Adverse health effects

- Permanent disabilities- Death

• Sometimes problems occur immediately (Acute effect)

• Others may happen after years of exposure (Chronic effect).

Dangerous to you…

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Spill Prevention Planning

• Only buy and store amount of material needed

• Buy the least hazardous materials possible

• Use non-hazardous materials when possible

• Minimize traffic in the area

• Store liquid wastes in secondary containers

• Regularly inspect containers to ensure their integrity

• Be aware of evacuation routes and emergency equipment

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Managing A Spill

What type and size of spills am I capable of managing?

You should only be cleaning up small spills (less than 1 gallon) of known materials that you work with on a regular basis after you have had attended a hands-on training session given by the EHS department.

Small spill clean-up kits are located in the 90-day storage area and in “all” laboratories.

Notify the Public Safety Department (x8-1911) for larger spills, or spills containing reactive or highly toxic materials. Public Safety will notify the proper authorities.

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Spill Kits

These spill kits contain everything you need to properly manage a small spill in your labs.

These are available for $48 each.

Please contact Dennis Daye to place an order and purchase.

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• In the event of a chemical spill, first decide if you are trained, knowledgeable and equipped to handle the incident.

• Prepare a plan of action (e.g. waiting for help, attend to injured, shutting off the valve, turn off ignition sources in presence of flammables if safe to do so)

• Immediately evacuate the lab and notify Public Safety if there is a possibility of an acute respiratory hazard present or if you need assistance to clean up the spill. – Never proceed to clean up a spill if you do not know the hazards associated with the chemical

or if you are unsure of how to clean up the spill.

• If anyone is injured or contaminated, immediately notify Public Safety and begin decontamination measures or first aid, if trained.

• Make sure to wear the proper PPE.– Apron, Gloves, Goggles, etc.

Managing A Spill…

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Contain the spill (Stopping the source and stopping the spread)

• stopping the source includes:– Closing a valve;– Shutting down a pump to stop flow;– Putting “bandage” around a leaking hose;– Positioning of leaking container.

• stopping the spread includes:– Building a barrier around the spill;– Make a flow channel;– Use of absorbent or spill pads;

Managing A Spill…

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• Absorbent should be distributed over the entire spill area, working

from the outside, circling to the inside. – This stops the spread of the spilled chemical.

• When spilled materials have been absorbed, use brush and scoop to place materials in an appropriate container (bag is provided in spill kits).

– Dispose of any contaminated PPE used during cleanup.

• Complete hazardous waste sticker, identifying the material as Spill Debris involving XYZ Chemical, and affix onto the container. Arrange for pick-up by EH&S Dept. as soon as possible.

Managing A Spill…

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• When managing a spill of a flammable liquid…

– Turn off all sources of ignition

– Lay the chemical spill pads over the spill• Pads are designed to suppress flammable vapors

– Allow pads to completely absorb the liquid

– Place the pads in plastic disposal bag

– Wipe up any remaining liquid with paper towel

– Dispose of the paper towel in plastic bag

– Seal bag and attach a completed hazardous waste sticker

Flammable Liquids

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• Remember that absorbed materials have the same properties and hazards as the original spilled materials.

• Safely dispose all disposable coveralls, gloves and respirators.

• Decontaminate all non-disposable items (brooms, shovels, thongs, protective clothing) using a mild detergent and water.

• Arrange for pick up by EH&S Dept. as soon as possible.

After the spill…

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• Review what happened to prevent reoccurrence.

• No matter how small the spill, keep a record of what happened.

• Make sure that supplies (e.g. first aid, spill control kit) are replaced immediately. (Contact EH&S)

ONLY HANDLE SPILLS OF A GALLON OR LESS OF A KNOWN MATERIAL. FOR LARGE SPILLS OR REACTIVE MATERIALS CONTACT PUBLIC SAFETY (x8-1911) .

After the spill…

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What to do when an emergency occurs…

• TAKE CARE OF THE SAFETY OF YOURSELF AND OTHERS!

• Activate the building’s fire alarm system.

• If you have bodily contact with material:– immediately remove any contaminated clothing – flush the area with copious amounts of water

• Call Public Safety at 288-1911– Identify yourself and why you are calling– Identify the exact location and nature of the emergency– Identify any injuries of symptoms involved– Identify all hazardous materials involved (if known)

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What to do when an emergency occurs…

• Evacuate building to a safe distance (at least 100 feet)

• leave clear access for emergency personnel

• Keep all persons exposed in the same area. They should not leave until they are cleared by proper authorities.

• If you have time to do so safely– Close, but do not lock, doors behind you to isolate the area– Turn off, unplug, or remove potential sources of ignition– Contain the spill material with berms or other means– Post a sign to warn others not to enter the area

YOUR SAFETY AND THE SAFETY OF OTHERS SHOULD BE YOUR TOP PRIORITY!

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This is a general awareness training. You are not trained as an emergency responder and should not attempt to manage

emergencies. Emergency agencies such as the Fire Department, Police Department and Haz Mat Response

Teams will be responsible for situations other than easily contained spills or incidental situations.

ALWAYS CALL 288-1911 ON CAMPUS TO REPORT AN EMERGENCY


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Questions or Suggestions?

Feel free to contact Dennis Daye (414) 288-8411 or Aaron Walters with questions, concerns, or suggestions.


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Thank you for participating in Hazardous Waste Generator Requirements Training

north america technical solutions welcome to marquette university’s hazardous waste and emergency...

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