nano‐porous cellulose: a new fiber · even mercerization! to produce soft higherdrynesswith...

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NanoPorous Cellulose: A New Fiber 1. Simple to Produce 2. Reduced Crystallinity Much More Open Structure 1. XRay 2. Staining 3. Generates Sheets With: 1. Higher Bulk 2. Higher Porosity 3 Lower Strength 3. Lower Strength 4. Especially Effective With Recycled Fiber R R CSI Treatment Exceeds the Bulk Potential of Eucalyptus fiber, i ti ! Extremely Large Bulk Gains in Recycled Fibers at High Freeness and Strength Levels! We Believe a High Potential to Produce Soft Recycled Fiber sheets 1. Reduce Drying Costs Add Treated Fibers to Furnish Increase Wet Pressing Higher Dryness with No Bulk Loss even mercerization! Levels! We Believe a High Potential to Produce Soft Recycled Fiber sheets at or nearly equivalent to those made with Eucalyptus. Higher Dryness with No Bulk Loss Maintain Target Tensile Values Wide Crescent Former Running at 39% Post Pressure Consistency Install Shoe Press, Raise Consistency to 45 to 50% Reduce Drying Load 22% to 36% Or Increase Production! 2. Increase Sheet Porosity Add Treated Recycled Fiber to Premium Sheets Bonding of Recycled Reduced More Uniform Drying, especially with Through Air Drying Process While Strengths Are Considerably Reduced by 1/3 or more, Bulks increase Treatment yields up to a 5fold increase in air flow rates through the pressed handsheets! The high porosities and bulks will not only increase sheet quality levels Through Air Drying Process More Effective Creping since Sheet Density Reduced Premium Quality with Relatively Large Amounts of Recycle Fiber! by 50% or more! Treated NSWK should be a great towel bulking fiber! handsheets! The high porosities and bulks will not only increase sheet quality levels but also ease of through air drying strong towel and high recycled fiber sheets! PaperCon 2011 Page 2945

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Nano‐Porous Cellulose: A New Fiber

1. Simple to Produce2. Reduced CrystallinityMuch More 

Open Structure1. X‐Ray2. Staining

3. Generates Sheets With:1. Higher Bulk2. Higher Porosity 3 Lower Strength3. Lower Strength

4. Especially Effective With Recycled Fiber R

RCSI Treatment Exceeds the Bulk Potential of Eucalyptus fiber, 

i ti !Extremely Large Bulk Gains in Recycled Fibers at High Freeness and Strength Levels! We Believe a High Potential to Produce Soft Recycled Fiber sheets

1. Reduce Drying Costs Add Treated Fibers to Furnish Increase Wet Pressing 

Higher Drynesswith No Bulk Losseven mercerization! Levels!  We Believe a High Potential to Produce Soft Recycled Fiber sheets at or nearly equivalent to those made with Eucalyptus.

Higher Dryness with No Bulk Loss  Maintain Target Tensile Values

Wide Crescent Former Running at 39% Post Pressure Consistency

Install Shoe Press, Raise Consistency to 45 to 50%

Reduce Drying Load 22% to 36%  Or Increase Production!

2. Increase Sheet Porosity Add Treated Recycled Fiber to Premium 

Sheets Bonding of Recycled Reduced More Uniform Drying, especially with 

Through Air Drying Process

While Strengths Are Considerably Reduced by 1/3 or more, Bulks increase  Treatment yields up to a 5‐fold increase in air flow rates through the pressed 

handsheets! The high porosities and bulks will not only increase sheet quality levels

Through Air Drying Process More Effective Creping since Sheet Density 

Reduced Premium Quality with Relatively Large 

Amounts of Recycle Fiber! 

by 50% or more!  Treated NSWK should be a great towel bulking fiber!handsheets!  The high porosities and bulks will not only increase sheet quality levels but also ease of through air drying strong towel  and high recycled fiber sheets!  

PaperCon 2011 Page 2945

What’s Different About These Fibers?1 Simple to Produce1. Simple to Produce

2. Reduced CrystallinityMuch More Open Structurey y p1. X‐Ray2. Staining

3. Generates Sheets With:1. Higher Bulk  Even Under High Wet Pressing Loads!

2. Higher Porosity Increase Drying Uniformity and Speeds!2. Higher Porosity  Increase Drying Uniformity and Speeds!

3. Lower Strength  Reversible by Wet Pressing Without Bulk Loss!

4. Especially Effective With Recycled Fiber

PaperCon 2011 Page 2946

CSI Treatment Process

NaOH in Cosolvent

Cosolvent Wash

Water WashCosolvent Wash Wash

Bleached Fiber

Mixer ConsistencyUp to 15%

WasherUp to 15%

Treated Fiber

NaOH in Cosolvent

Cosolvent + NaOH + WaterRR

Recycle Cosolvents + WaterRRCosolvents + 

NaOH

PaperCon 2011 Page 2947

X‐ray Diffractogram gShows Much 

Less Crystalline Structure in CSIStructure in CSI Treated Kraft 

Fiber

X‐ray diffractogram of bleached Kraft pulp before and after CSI Decrystallization treatment

PaperCon 2011 Page 2948

Dark Staining of CSI Treated Avicel ShowsTh M O S f Thi C ll lThe More Open Structure of This Cellulose

Avicel microcrystalline cellulose after staining with Graff’s C‐Stain.

Avicel microcrystalline cellulose pretreated with CSI process after staining with Graff’s C‐stain.

PaperCon 2011 Page 2949

mlk, cc/gram

ndsheet B

uressed

 Han

NHWK Fibers NSWK Portion 

Pr Refined to 560 ml 

Freeness, CSF

Percentage of Hardwood Fiber in Sheets

CSF

PaperCon 2011 Page 2950

PaperCon 2011 Page 2951

PaperCon 2011 Page 2952

Examples of Potential Uses1 R d D i C1. Reduce Drying Costs Add Treated Fibers to Furnish

Increase Wet Pressing g Higher Dryness with No Bulk Loss 

Maintain Target Tensile Values

Wide Crescent Former Running at 39% Post Pressure Consistency

Install Shoe Press, Raise Consistency to 45 to 50%

Reduce Drying Load 22% to 36%  Or Increase Production!

2. Increase Sheet Porosity Add Treated Recycled Fiber to Premium Sheets

Bonding of Recycled Reduced

More Uniform Drying, especially with Through Air Drying Process

More Effective Creping since Sheet Density Reducedp g y

Premium Quality with Relatively Large Amounts of Recycle Fiber! 

PaperCon 2011 Page 2953

No Treated Fibers

PaperCon 2011 Page 2954

Treated Fiber Blends

PaperCon 2011 Page 2955

No Treated Fibers

PaperCon 2011 Page 2956

Treated Fiber Blends

PaperCon 2011 Page 2957