msds frost protect

COMPO Frost Protect

Version: 1.2

Revision Date: 20.03.2012

1/8 Print Date: 03.05.2012

Material Safety Data Sheet according to Regulation (EC) No. 1907/2006

1. Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Trade name : COMPO Frost Protect

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the Substance/Mixture : Plant assistants

1.3 Details of the supplier of the safety data sheet

Company : COMPO GmbH & Co. KG Gildenstraße 38 D-48157 Münster

Telephone : +49-0251/3277-0 Telefax : +49 (0)251/326225 E-mail address : [email protected]

1.4 Emergency telephone number

Central Safety & Environment Telephone:+49-251-3277-0

2. Hazards identification

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Acute toxicity, Category 4 H302: Harmful if swallowed. Acute toxicity, Category 4 H332: Harmful if inhaled.

Classification(67/548/EEC,1999/45/EC)

Harmful R22: Harmful if swallowed.

2.2 Label elements

Labelling(REGULATION (EC) No 1272/2008)

Hazard pictograms :

Signal word : Warning

Hazard statements : H302 Harmful if swallowed.

H332 Harmful if inhaled.

Precautionary statements : P101 If medical advice is needed, have product container or label at hand.

P102 Keep out of reach of children. Prevention: P280 Wear protective gloves/ protective clothing/

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eye protection/ face protection. Response: P301 + P312 IF SWALLOWED: Call a POISON

CENTER or doctor/ physician if you feel unwell.

2.3 Other hazards

3. Composition/information on ingredients 3.2 Mixtures

Chemical nature : Plant assistants

Hazardous components

Chemical Name CAS-No. EC-No.

Registration number

Classification (67/548/EEC)

Classification (REGULATION (EC)

No 1272/2008)

Concentration [%]

Benzylalkohol 100-51-6

Xn; R20/22

Acute Tox. 4; H332 Acute Tox. 4; H302

>= 10 - <= 20

Ethylenglykol 107-21-1 203-473-3

Xn; R22

Acute Tox. 4; H302

>= 5 - <= 10

For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section 16.

4. First aid measures

4.1 Description of first aid measures

General advice : Take off immediately all contaminated clothing. Move the victim to fresh air.

If inhaled : If breathed in, move person into fresh air. If unconscious place in recovery position and seek medical advice. If breathing is irregular or stopped, administer artificial respiration.

In case of skin contact : Take off all contaminated clothing immediately. Wash off with soap and water.

In case of eye contact : Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed : Do NOT induce vomiting. If symptoms persist, call a physician.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms : No information available.

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Risks : No information available.

4.3 Indication of any immediate medical attention and special treatment needed

Treatment : Treat symptomatically.

5. Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media : ABC powder Carbon dioxide (CO2) Water spray jet Alcohol-resistant foam

Unsuitable extinguishing media : High volume water jet

5.2 Special hazards arising from the substance or mixture

Specific hazards during firefighting

: In the event of fire and/or explosion do not breathe fumes.

5.3 Advice for firefighters

Special protective equipment for firefighters

: Wear self-contained breathing apparatus and chemical-protective clothing.

Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Wear personal protective equipment. Keep container tightly closed.

6.2 Environmental precautions

Environmental precautions : Do not flush into surface water or sanitary sewer system.

6.3 Methods and materials for containment and cleaning up

Methods for cleaning up : Larger quantities evacuate. Remainders soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).

6.4 Reference to other sections

For personal protection see section 8.

7. Handling and storage

7.1 Precautions for safe handling

Advice on safe handling : Keep in a dry, cool and well-ventilated place. Smoking, eating and drinking should be prohibited in the application area.

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Advice on protection against fire and explosion

: Keep away from sources of ignition - No smoking.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers

: Keep in a well-ventilated place. Keep away from heat.

German storage class : 10 Combustible liquids

7.3 Specific end uses

: Always read the label and product information before use.

8. Exposure controls/personal protection

8.1 Control parameters

Components CAS-No. Value Control parameters Update Basis

Ethylenglykol 107-21-1 AGW 10 ppm 26 mg/m3

DE TRGS 900

STEL 40 ppm 104 mg/m3

TWA 20 ppm 52 mg/m3

8.2 Exposure controls

Personal protective equipment

Respiratory protection : Use the indicated respiratory protection if the occupational exposure limit is exceeded and/or in case of product release (dust). Gas filter EN141 Type A for gases/vapours of organic compounds (boiling point >65 °C).

Hand protection : butyl-rubber Glove thickness: 0,4 mm

: Fluorinated rubber Glove thickness: 0,4 mm

Eye protection : Tightly fitting safety goggles

Skin and body protection : Wearing of closed work clothing is recommended.

Environmental exposure controls

General advice : Do not flush into surface water or sanitary sewer system.

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Soil : Avoid subsoil penetration.

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance : liquid

Colour : product specific

Odour : characteristic

pH : ca. 6, 20 °C

Flash point : > 100 °C

Density : 1,05 g/cm³, ca. 20 °C

Water solubility : partly soluble

Autoignition temperature : no data available

Ignition temperature : not determined

Explosive properties : no data, Unspecified

Oxidizing properties : no data available

9.2 Other information

10. Stability and reactivity

10.1 Reactivity

None reasonably foreseeable.

10.2 Chemical stability

No decomposition if stored normally.

10.3 Possibility of hazardous reactions

Hazardous reactions : None known.

10.4 Conditions to avoid

Conditions to avoid : No decomposition if stored and applied as directed.

10.5 Incompatible materials

Materials to avoid : Incompatible with strong acids and oxidizing agents.

10.6 Hazardous decomposition products

Hazardous decomposition products

: Carbon dioxide (CO2) Carbon monoxide Biphenyls Benzoic acid

11. Toxicological information 11.1 Information on toxicological effects

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Product

Acute oral toxicity : no data available

Acute inhalation toxicity : no data available

Acute dermal toxicity : no data available

Skin corrosion/irritation : no data available

Serious eye damage/eye irritation

: no data available

Respiratory or skin sensitization

: None known.

Germ cell mutagenicity

Genotoxicity in vitro : no data available

Genotoxicity in vivo : no data available

Carcinogenicity : Contains no ingredient listed as a carcinogen

Reproductive toxicity : Contains no ingredient listed as toxic to reproduction

Components: Benzylalkohol : Acute oral toxicity : LD50: = 1.040 mg/kg, rabbit

Acute inhalation toxicity : LC50: >= 500 mg/l, rat

Acute dermal toxicity : LD50: = 2.000 mg/kg, rabbit

12. Ecological information

12.1 Toxicity

Components:

Benzylalkohol :

Toxicity to fish : LC50: 640 mg/l, 48 h, golden orfe

Toxicity to daphnia and other aquatic invertebrates.

: EC50: 400 mg/l, Daphnia magna

Toxicity to algae : EC50: = 640 mg/l, 96 h, Scenedesmus quadricauda (Green algae)

Toxicity to bacteria : EC50: > 658 mg/l, Pseudomonas putida

12.2 Persistence and degradability

Product:

Biodegradability : no data available

12.3 Bioaccumulative potential

Product:

Bioaccumulation :

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No bioaccumulation is to be expected . 12.4 Mobility in soil

Product:

Mobility : no data available 12.5 Results of PBT and vPvB assessment

Product:

Assessment : no data available

12.6 Other adverse effects

Product:

Additional ecological information

: Do not flush into surface water or sanitary sewer system., No information on ecology is available.

13. Disposal considerations

13.1 Waste treatment methods

Product : Incinerate in suitable incineration plant, observing local authority regulations.

Contaminated packaging : Observe all local regulations. Packs must be completely emptied. Uncleaned empties should be disposed of in the same manner as the contents.

14. Transport information

14.1 Land transport

ADR Remarks : Not classified as dangerous in the meaning of transport

regulations. 14.2 Sea transport

ADNR Remarks : Not classified as dangerous in the meaning of transport

regulations.

IMDG Remarks : Not classified as dangerous in the meaning of transport

regulations. 14.3 Air transport

IATA-DGR Remarks : Not classified as dangerous in the meaning of transport

regulations. 14.4 Special precautions for user

14.5 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

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15. Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Water contaminating class (Germany)

: WGK 1 slightly water endangering

15.2 Chemical Safety Assessment

16. Other information Full text of R-phrases referred to under sections 2 and 3

R20/22 Harmful by inhalation and if swallowed. R22 Harmful if swallowed.

Full text of H-Statements referred to under sections 2 and 3.

H302 Harmful if swallowed. H332 Harmful if inhaled.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

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