mr. jon horler - · pdf filea chartered chemical engineer, mr. jon horler has worked for bp...
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Mr. Jon Horler
Acetyls Project & Engineering ManagerBP
A Chartered Chemical Engineer, Mr. Jon Horler has worked for BP for 25years and leads a team responsible for the delivery of technology andengineering in support of BP’s proprietary package for the manufactureof Acetic Acid.
Part of his role is also to provide project management during conceptselection and early stage development for licensing opportunitiesworldwide.
Mr. Jon has previously worked on major projects in the UK, China,Taiwan, Malaysia, Korea and India.
Overview of Acetic acid Production
Through Petcoke Gasification
IOCL Petrochemicals Conclave
18th
March 2013
Jon Horler, Projects and Engineering Manager
Acetyls and Aromatics Technology
© 2013 BP Chemicals Limited All rights reserved
Outline
• Overview:
− What is Acetic Acid
− Key Uses of Acetic Acid
− Chemistry
• Feedstock Choices
• Acetic Acid Technology
• Sources of Project Value
© 2013 BP Chemicals Limited All rights reserved
3
What is Acetic Acid?
• A very important chemical
• A key raw material for the production of a wide
number of products we use in our everyday
lives
• Do you know that acetic acid in its very dilute
form is vinegar that is consumed or used in the
manufacture of food products?
• Acetic acid is involved in the manufacture of
other items you'll find in your shopping basket,
such as washing powder, drink bottles and food
packaging
With just 1 tonne
of acetic acid our
customers can
make 38,000 jars
of pickles*
*BP Internal Data
© 2013 BP Chemicals Ltd All rights reserved
4
Key uses of Acetic Acid
• Vinyl Acetate Monomer (VAM)
− Paint, adhesives in furniture or floor covering, manufacture
of clothes, shoe soles, juice cartons and cheese packaging,
manufacture of safety glass for car windscreens
• Purified Terephthalic Acid (PTA)
− Plastic containers for beverages, food and electronics,
apparel, home textiles, carpets and industrial fibre products,
audio and video recording tapes, photographic films and
labels
• Acetate Esters (Ethyl Acetate, Butyl Acetate…)
− Solvent in printing inks, laminating adhesive in flexible
packaging and plastic films. Also used as solvent in paint,
varnishes, resin coatings and nail polish remover
• Acetic Anhydride
− More than 75% made into cellulose acetate found in filter
tow, textiles, photographic and x-ray films
− Also used in pharmaceuticals such as aspirin and
paracetamol
© 2013 BP Chemicals Ltd All rights reserved
Acetic Acid Technology Evolution
CATIVA® gives advantages across all
key project criteria:
• Capital - simplification of flowsheet
results in lower project costs for new
build plants
• Variable Cost - patented catalyst
technology and subsequent reduced
energy requirements result in lower
operating costs
• Cash Cost / Reliability - less
equipment items to maintain mean
lower annual maintenance spends
and less downtime
• Scale - potential to build at scale to
suit market demands improves
capital efficiency
• Fully Built-up Cost - all of the above
have a positive impact on overall
project economics and long term
sustainable operations
Feedstock
changes
Process
changes
Time
Methanol carbonylation Hydrocarbon oxidations
Cost estimates are based on generic models
0
20
40
60
80
100
120
Ethylene Naphtha Rhodium Rhodium / lithium Iridium
Pro
duct
ion c
ost
[in
dex
ed t
o e
thyle
ne
pro
cess
to
tal
cost
= 1
00
]
Cash cost = variable + fixed Capital-related costs=depreciation + return on investment
© 2013 BP Chemicals Ltd All rights reserved
Methanol Carbonylation:
A C1 route to Acetic Acid
Natural Gas
Coal
Pet Coke
Naphtha
Light HC’s
Heavy HC’s
Biomass
……….
Syngas
(CO + H2)
Purify CO Compress
CO
Pure
CO
Methanol Distribution Methanol
(CH3OH)
Acetic Acid
(CH3COOH)
CO must be generated locally
MeOH purchased as a globally traded commodity
6
© 2013 BP Chemicals Ltd All rights reserved
Feedstock Selection In India
• Main issues associated with accessing attractive CO economics are:
− High energy costs. Investment in lower capital Nat Gas/Fuel Oil based
Syngas plants (eg SMR/POX) have higher variable costs
− Investment in Coal/Petcoke based Syngas plants (Gasification) delivers
much lower energy / variable cost but carries a much higher capital
cost burden and is dependent on scale and integration opportunity
• For a methanol carbonylation
production, feedstock access
for competitive CO
production cost is key to the
Acetic Acid value chain
Re
lativ
e E
ne
rg
y C
ost
Feedstock Options
© 2013 BP Chemicals Ltd All rights reserved
8
Ulsan, South Korea
SSBP: AA , 51%
Nanjing, China
Byaco: AA , 50%
Shanghai
Head office
Kertih, Malaysia
BPPA: AA, 70%
Chongqing, China
Yaraco: AA &
Esters , 51%
Kuala Lumpur
Commercial office,
Rest of Asia
Taiwan
FBPC: AA, 50%
Naperville/Cantera
Commercial Office USA
Hull, UK
Europe Commercial Office and
Production
AA and Anhydrides
Texas City
AA
Acetyls sites
Commercial/Sales offices
% BP share of JVs
BP Acetyls – Global Experience
© 2013 BP Chemicals Limited All rights reserved
CATIVA® Process Flow Diagram
Vent Gases
To Flare
Acetic Acid
Product
Lights
Removal
Column Heavy Ends Column
Cativa®
SCHEMATIC PROCESS FLOW DIAGRAM
Off-gas Recovery Area
Reactor
(Mixed acid
For disposal)
CO and
methanol
9
© 2013 BP Chemicals Limited All rights reserved
Internal Infrastructure
Keys to Project Value
• Build at scale
• Locate near market
• Locate close to
petcoke feedstock
• Integrate common
infrastructure
• Lever the
strengths of both
parties
Value Levers: Project Integration
ASU AA Purification
Petcoke Gasification
External Infrastructure
© 2013 BP Chemicals Limited All rights reserved
• Acetic Acid is a petrochemical building block for products associated
with a sophisticate growing modern economy
• BP has developed world leading technology for the manufacture of
acetic acid.
• Feedstock choice is critical
• Integration opportunities help to lever value
Thank You
Summary
© 2013 BP Chemicals Limited All rights reserved