monitoring report - mdeq

TestAmericaTHE LEADER IN ENVIRONMENTAL TESTING

ANALYTICAL REPORT

Job Number: 680-42572-1

Job Description: Hercules Hattiesburg 4Q08

For:Hercules Inc.

Research Center- Bldg 8139/15500 Hercules Road

Wilmington, DE 19808-1599

Attention: Mr. Timothy Hassett

L Approved for releaseLolyc GuIiz,aProject Menager I1211512008 504 PM

cc: Mr. Charles Coney

Lidya GuliziaProject Manager I

[email protected]/15/2008

The test results in this report meet NELAP requirements for parameters for which accreditation is required or available.Any exceptions to the NELAP requirements are noted. Results pertain only to samples listed in this report. This reportmay not be reproduced, except in full, without the written approval of the laboratory. Questions should be directed to theperson who signed this report.

Savannah Certifications and ID #s: A2LA: 0399.01; AL: 41450; ARDEQ: 88-0692; ARDOH; CA: 03217CA; Cc; CT:PHOI61; DE; FL: E87052; GA: 803; Guam; HI; IL: 200022; IN; IA: 353; KS: F-i 0322; KY EPPC: 90084; KY UST; LA

L DEQ: 30690; LA DHH: LA080008; ME: 2008022; MD: 250; MA: M-GAOO6; MI: 9925; MS; NFESC: 249; NV: GA00006;NJ: GA769; NM; NY: 10842; NC DWQ: 269; NC DHHS: 13701; PA: 68-00474; PR: GA00006; RI: LA000244; SC:98001001; TN: TN0296; TX: Ti 04704185; USEPA: GA00006; VT: VT-87052; VA: 00302; WA; WV DEP: 094; WVDHHR: 9950 C; WI DNR: 999819810; WY/EPAR8: 8TMS-Q

TestAmerica Laboratories, Inc.

TestAmerica Savannah 5102 LaRoche Avenue, Savannah, GA 31404

Tel (912) 354-7858 Fax (912) 352-0165 www.testamericpinc.com

8 ACC0,

(ePage 1 of 119

Job Narrative680-J42572-1

OReceiptL Method(s) 8260B: The following sample(s) was received with headspace in the sample vial: HER-MWO5-1 11908 (680-42572-15),

HER-MW14-112008(680-42572-25). Three of three vials contain headspace for both IDs,

All other samples were received in good condition within temperature requirements.

GCIMSVOANo analytical or quality issues were noted

CommentsNo additional comments.

Page 2 of 119

LIL

METHOD SUMMARY

0 Client Hercules Inc. Job Number 680-42572-1

LI Description Lab Location Method Preparation Method

Matrix Water

[j Volatile Organic Compounds (GC/MS) TAL SAV SW846 82608Purge and Trap TAL SAV SW846 5030B

U Lab References:

TAL SAV = TestAmerica Savannah

El Method References:

SW846 = Test Methods For Evaluating Solid Waste, Physical/Chemical Methods, Third Edition, November 1986 And ItsUpdates.

0UEl[0

Lici

LiLI

TestAmerica Savannah

Page 3 of 119

I

UCi

cD METHOD I ANALYST SUMMARY

U Client: Hercules Inc Job Number: 680-42572-1

[ Method Analyst

SW846 8260B Bearden, Robert RBSW846 8260B Lui, Chung CL

[] SW846 826DB Sokolin, Eleina ES

UCiU[0

UF::!UUEl


Page 4 of 119

Ii

SAMPLE SUMMARY

Client: Hercules Inc. Job Number: 680-42572-1

Lab Sample ID Client Sample ID Client MatrixDate/Time

SampledDate/TimeReceived

680-42572-1 RB

680-42572-2

680-42572-3

680-42572-4

680-42572-5

680-42572-6

680-42572-7

680-42572-8

680-42572-9

680-42572-9MS

flU 680-42572-1 ORB

680-42572-11

ci680-42572-12

680-42572-13

680-42572-1 4FD680-42572-15

rO 680-42572-16

[j,680-42572-18

680-42572-19

680-42572-2OFD

680-42572-21

680-42572-22

U680-42572-22MS

680-42572-22MSD

680-42572-23

680-42572-24

fl 680-42572-25

Li 680-42572-26

680-42572-27

680-42572-28

[1 680-42572-29

680-42572-3OTB

HER-RS1-1 11808

HER-CMO5-1 11808HER-CMO4-1 11808HER-CMO3-1 11808

HER-CMO2-1 11808HER-CMO1-1 11808

HER-CMOO-1 11808

HER-MWO3-1 11908HER-MWO2-1 11908

HER-MWO2-1 11908

HER-MWO2-1 11908HER-RS2-1 11908

HER-MW1 0-111908

HER-MW1 1-111908

HER-MWO4-1 11908HER-FDO1 -111908

HER-MWO5-1 11908

HER-MW1 2-112008

HER-RSO3-1 12008HER-MWO6-1 12008

HER-MW1 8-112008

HER-FDO2-1 12008

HER-MW1 9-112008

HER-MWO7-1 12008HER-MWO7-1 12008

HER-MWO7-1 12008

HER-MW1 6-112008

HER-MW1 5-112008

HER-MW14-112008

HER-MW1 3-112008HER-MWO9-1 12108

HER-MWO8-1 12108

HER-MW17-112108

TRIP BLANK

Water

Water

Water

Water

Water

Water

Water

Water

Water

Water

Water

Water

Water

Water

Water

Water

Water

Water

WaterWater

Water

Water

Water

Water

Water

Water

Water

Water

Water

Water

Water

Water

Water

Water

11/19/2008 1034

11/19/2008 1034

11/19/2008 1057

11/19/2008 1221

11/19/2008 1428

11/19/2008 1515

11/19/2008 1515

11/19/2008 1639

11/20/2008 090611/20/2008 0925

11/20/2008 0953

11/20/2008 1037

11/20/2008 0000

11/20/2008 1129

11/20(2008 1323

11/20/2008 1323

11/20/2008 132311/20/2008 1415

11/20/2008 1455

11/20/2008 1529

11/20/2008 1629

11/21/2008 0908

11/21/2008 0957

11/21/2008 1040

11/21/2008 0000

11/22/2008 0950

11/22/2008 095011/22/2008 0950

11/22/2008 095011/22)2008 095011/22/2008 0950

11/22/2008 095011/22/2008 0950

11/22/2008 0950

11/22/2008 0950

11/22/2008 095011/22/2008 0950

11(22/2008 0950

11/22/2008 095011/22/2008 095011/22/2008 0950

11/22/2008 0950

11/22/2008 095011/22/2008 095011/22/2008 095011/22/2008 0950

11/22/2008 095011/22/2008 095011/22/2008 0950

11/22/2008 095011/22/2008 095011/22/2008 095011/22/2008 0950

11/22/2008 095011/22/2008 0950

11/22/2008 095011/22/2008 095011/22)2008 095011/22)2008 0950


ciiEl

11/18/2008

11/18/2008

11/18/2008

11/18/2008

11/18/2008

11/18/2008

11/18/2008

11/19/2008

11/19/2008

1325

1330

1350

1410

1425

1437

1455

0927

1034

Page 5 of 119

0

00

0ci

SAMPLE RESULTS

n00

I

El

U


Page 6 of 119

Analytical Data


Client Sample ID: HER-RSI-111808

Lab Sample ID: 680-42572-1 RB Date Sampled: 11/18/2008 1325Client Matrix: Water Date Received: 11/22/2008 0950

8260B Volatile Organic Compounds (GCIMS)[ Method: 82608 Analysis Batch: 680-1 23846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a384.dDilution: 1.0 Initial Weight/Volume: 5 mLDate Analyzed: 11/25/2008 1237 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1237

UAnalyte Result (ug/L) Qualifier RLAcetone <25 25Acetonitrile <40 40Acrolein . <20 20

O Acrytonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0[ Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0Carbon tetrachloride <1.0 1.0

U Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.0ri 2-Chloro-1,3-butadiene <1.0 1.0

I 3-Chloro-1-propene <1.0 1.0Chlorodibromomethane <1.0 1.0

U1 2-Dibrorno-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i 4-Dichloro-2-butene <2.0 2.0

UDichlorodifluoromethane <1.0 1.0i,1-Dichloroethane <1.0 1.0i,2-Dichloroethane <1.0 1.0li-Dichloroethene <1.0 1.0cis-i ,2-Dichloroethene <1.0 1.0trans-i 2-Dichloroethene <1.0 1.0i ,2-Dichloropropane <1.0 1.0cis-i,3-Dichloropropene <1.0 1.0[ trans-i 3-Dichloropropene <1.0 i .0Ethylbenzene <1.0 i.0Ethyl melhacrylate <1.0 1.02-Hexanone <10 iO

U lodomethane <5.0 5.0Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.0

fl Methyl methacrylate <1.0 1.0

__

4-Methyl-2-pentanone (MIBK) <10 10

( Pentachtoroethane <5.0 5.0‘-.) Propionitrile <20 20

1 Styrene <1.0 1.0

J ii, 1 2-Tetrachloroethane <1.0 1.0

TestAmerica Savannah Page 7 of 119

Analytical Data

Client: Hercules inc. Job Number: 680-42572-1

Client Sample ID: HER-RSI-111808

Lab Sample ID: 680-42572-1 RB Date Sampled: 11/18/2008 1325Client Matrix: Water Date Received: 11/22/2008 0950

8260B Volatile Organic Compounds (GCIMS)

Method: 8260B Analysis Batch: 680-1 23846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a384.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11125/2008 1237 Final WeightNolume: 5 mLDate Prepared. 11125)2008 1237

Analyte Result (ugIL) Qualifier RL1,1 2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.01,1,1-Trichloroethane <1.0 1.01,1,2-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.0

L 1,2,3-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0

Surrogate %Rec Acceptance Limits4-Bromofluorobenzene 100 75- 120Dibromofluoromethane 102 75- 121Toluene-d8 (Surr) 96 75-120


Analytical Data


Client Sample ID: HER-CMO5-111808

Lab Sample ID: 680-42572-2 Date Sampled: 11/18/2008 1330Client Matrix: Water Date Received: 11/22/2008 0950

826DB Volatile Organic Compounds (GCIMS)

Method: 8260B Analysis Batch: 680-1 23846 Instrument ID: GC/MS Volatiles - A C2Preparation: 503DB Lab File ID: a386.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/25/2008 1307 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1307

OAnalyte Result (ug/L) Qualifier RLAcetone <25 25Acetonitrile <40 40Acrolein <20 20Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0Carbon tetrachloride <1.0 1.0

Q Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-1 3-butadiene <1 .0 1.03-Chloro-i-propene <1.0 1.0Chlorodibromomethane <1.0 1.0

U1,2-Dibromo-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i ,4-Dichloro-2-butene <20 2.0

UDichlorodifluoromethane <1.0 1.0ii-Dichloroethane <1.0 1.012-Dichloroethane <1.0 1.0li-Dichloroethene <1.0 1.0cis-i,2-Dichloroethene <1.0 1.0

H trans-i,2-Dichloroethene <1.0 1.01 ,2-Dichloropropane <1.0 1.0cis-1 ,3-Dichloropropene <1.0 1.0trans-1,3-Dichloropropene <1.0 1.0

J Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10lodomethane <5.0 5 0

J Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.0Methyl methacrylate <1.0 1.0J 4-Methyl-2-pentanone (MIBK) <10 10

O Pentachloroethane <5 0 5 0Propionitrile <20 20Styrene <1.0 1.01,1,1 2-Tetrachloroethane <1.0 1.0


Analytical Data


Client Sample ID: HER-CMO5-1 11808


8260B Volatile Organic Compounds (GC/MS)

U Method: 8260B Analysis Batch: 680-1 23846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a386.dDilution: 1.0 Initial WeightfVolume: 5 mLDate Analyzed: 11/25/2008 1307 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1307

Analyte Result (ugIL) Qualifier RL1,1 2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.0

O 1,11-Trichloroethane <1.0 1.01,1,2-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.0

U 1,2,3-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0

Surrogate %Rec Acceptance Limits4-Bromofluorobenzene 98 75- 120Dibromofluoromethane 104 75 - 121Toluene-d8 (Surr) 98 75- 120


Analytical Data


Client Sample ID: HER-CM041 11808

Lab Sample ID: 680-42572-3 Date Sampled: 11/18/2008 1350Client Matrix: Water Date Received: 11/2212008 0950


U Method: 8260B Analysis Batch: 680-123846 Instrument ID: GC/MS Volatiles -A C2Preparation: 5030B Lab File ID: a388.dDilution: 1.0 Initial WeightNolume. 5 mLDate Analyzed: 11/25/2008 1336 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1336

fl Analyte Result (ug/L) Qualifier RLAcetone <25 25Acetonitrile <40 40Acrolein <20 20fl Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0Carbon tetrachloride <1.0 1.0

fl Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-1 3-butadiene <1.0 1.0r 3-Chloro-1-propene <1.0 1.0Chlorodibromomethane <1.0 1.01 ,2-Dibromo-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i ,4-Dichloro-2-butene <2.0 2.0

UDichlorodifluoromethane <1.0 1.011-Dichloroethane <1.0 1.01,2-Dichloroethane <1.0 1.01,1-Dichloroethene <1.0 1.0cis-1 2-Dichloroethene <1.0 1.0trans-i,2-Dichloroethene <1.0 1.01 2-Dichloropropane <1.0 1.0cis-i,3-Dichloropropene <1.0 1.0trans-1,3-Dichloropropene <1.0 1.0Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10lodomethane <5.0 5.0

J Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.07 Methyl methacrylate <1 0 1.0J

Q4-Methyl-2-pentanone (MIBK) <10 10Pentachloroethane <5 0 5.0Propionitrile <20 20Styrene <1.0 1.01,1 1 2-Tetrachloroethane <1.0 1.0


Analytical Data



Lab Sample ID: 680-42572-3 Date Sampled: 11/1812008 1350Client Matrix: Water Date Received: 11/22/2008 0950


L Method: 8260B Analysis Batch: 680-1 23846 Instrument ID: GCIMS Volatiles - A C2Preparation: 5030B Lab File ID: a388.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/25/2008 1336 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1336

Analyte Result (ugIL) Qualifier RL1,1 2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.01,1,1-Trichloroethane <1.0 1.01,1,2-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.01 ,2,3-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0

Surrogate %Rec Acceptance Limits4-Bromofluorobenzene 95 75- 120Dibromofluoromethane 104 75- 121Toluene-d8 (Surr) 97 75- 120


Analytical Data



Lab Sample ID: 680-42572-4 Date Sampled: 11/18/2008 1410

Client Matrix: Water Date Received: 11)22/2008 0950


O Method: 8260B Analysis Batch: 680-1 23846 Instrument ID: GC/MS Volatiles - A C2

Preparation: 5030B Lab File ID: a390.dDilution: 1.0 Initial Weight/Volume: 5 mLDate Analyzed: 11/25/2008 1405 Final Weight/Volume: 5 mLDate Prepared: 11/25/2008 1405

fl Analyte Result (ug/L) Qualifier RL

U Acetone <25 25Acetonitrile <40 40Acrolein <20 20Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0Carbon tetrachloride <1.0 1.0Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-1 ,3-butadiene <1.0 1.03-Chloro-1-propene <1.0 1.0Chlorodibromomethane <1.0 1.01,2-Dibromo-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i 4-Dichloro-2-butene <2.0 2.0

UDichlorodifluoromethane <1.0 1.0li-Dichloroethane <1.0 1.01 2-Dichloroethane <1.0 1.01 ,i-Dichloroethene <1.0 1.0cis-i2-Dichloroethene <1.0 1.0

[j trans-12-Dichloroethene <1.0 1.0i,2-Dichloropropane <1.0 1.0cis-i,3-Dichloropropene <1.0 1.0

Utrans-i 3-Dichloropropene <1.0 1.0Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10lodomethane <5.0 5.0Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5 0 5.0

U Methyl methacrylate <1.0 1.04-Methyl-2-pentanone (MIBK) <10 10

Q Pentachloroethane <5 0 5,0Propionitrile <20 20

L Styrene <1.0 1.01,1 1 ,2-Tetrachloroethane <1.0 1.0


Analytical Data





Method: 8260B Analysis Batch: 680-123846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a390.dDilution: 1.0 Initial Weight/Volume: 5 mLDate Analyzed: 11/25/2008 1405 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1405

Analyte Result (ug/L) Qualifier RL

LI 1,1 2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.01,1,1-Trichloroethane <1.0 1.01,1 ,2-Trichloroetharie <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 . 1.0

O 1,2,3-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0

Surrogate %Rec Acceptance Limits4-Bromofluorobenzene 99 75- 120Dibromotluoromethane 102 75- 121Toluene-d8 (Sun) 98 75- 120


Analytical Data





U Method: 826DB Analysis Batch: 680-123846 Instrument ID: GC/MS Volatiles -A C2Preparation: 503DB Lab File ID: a392.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/25/2008 1435 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1435

J Analyte Result (ug/L) Qualifier RLAcetone <25 25Acetonitrile <40 40Acrolein <20 20

fl Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0

U Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0Carbon tetrachloride <1.0 1.0

U Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-1,3-butadiene <1.0 1.03-Chloro-1-propene <1.0 1.0Chlorodibromomethane <1.0 1.0

U1 2-Dibromo-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i ,4-Dichloro-2-butene <2.0 2.0

ODichlorodifluoromethane <1.0 1.0i,i-Dichloroethane <1.0 1.01 2-Dichloroethane <1.0 1.01,1-Dichloroethene <1.0 1.0cis-i,2-Dichloroethene <1.0 1.0

Li trans-1,2-Dichloroethene <1.0 1.0i,2-Dichloropropane <1.0 1.0cis-1,3-Dichloropropene <1.0 1.0trans-i 3-Dichloropropene <1.0 1.0Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10lodomethane <5.0 5.0Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.07 Methyl methacrylate <1.0 1.0J 4-Methyl-2-pentanone (MIBK) <10 10Q Pentachloroethane <5.0 5.0Propionitrile <20 20Styrene <1.0 1.01,112-Tetrachloroethane <1.0 1.0


Analytical Data

Chent: Hercules Inc. Job Number: 680-42572-1




Method: 8260B Analysis Batch: 680-1 23846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a392.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/25/2008 1435 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1435

Analyte Result (ug/L) Qualifier RL1,1 ,2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.0

fl 11,1-Trichloroethane <1.0 1.01,1,2-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.01,2,3-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xy)enes, Total <2.0 2.0

Surrogate %Rec Acceptance Limits4-Bromofluorobenzene 97 75 - 120Dibromofluoromethane 100 75- 121Toluene-dS (Surr) 97 75- 120

TestAnierica Savannah Page 16 of 119

Analytical Data


Client Sample ID: HER-CMOI.111808



Method: 8260B Analysis Batch: 680-123846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a394.dDilution; 1.0 Initial Weight/Volume: 5 mLDale Analyzed: 11/25/2008 1504 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1504

O Analyle Result (ug/L) Qualifier RLAcetone <25 25Acetonitrile <40 40Acrolein <20 20

O Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0[ Bromomelhane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0Carbon tetrachloride <1.0 1.0

Q Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-1 3-butadiene <1.0 1.03-Chloro-1-propene <1.0 1.0Chlorodibromomethane <1.0 1.01 2-Dibromo-3-Chloropropane <1 .0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i ,4-Dichloro-2-butene <2.0 2.0

JDichlorodilluoromethane <1.0 1.01,1-Dichloroethane <1.0 1.0i,2-Dichloroethane <1.0 1.01,1-Dichloroethene <1.0 1.0cis-i ,2-Dichloroelhene <1.0 1.0

[j trans-12-Dichloroethene <1.0 1.0i,2-Dichloropropane <1.0 1.0cis-1 .3-Dichloropropene <1.0 1.0trans-i,3-Dichloropropene <1.0 1.0Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 101 lodomethane <5.0 5.0J Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.0Methyl methacrylate <1.0 1.0J 4-Methyl-2-pentanone (MIBK) <10 10Q Pentachloroethane <5.0 5.0Propionitrile <20 20Styrene <1.0 1.01,1,1,2-Tetrachloroethane <1.0 1.0


Analytical Data


Client Sample ID: HER-CMOI-111808


826DB Volatile Organic Compounds (GCIMS)

fl Method: 8260B Analysis Batch: 680-1 23846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a394.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 1112512008 1504 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1504

Analyte Result (ug/L) Qualifier RL1,1 ,2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.01,1,1-Trichloroethane <1.0 1.01,1 2-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.0


Surrogate %Rec Acceptance Limits4-Bromofluorobenzene 95 75- 120Dibromofluoromethane 101 75 121Toluene-d8 (Surr) 97 75- 120


Analytical DataClient: Hercules Inc.

Job Number: 680-42572-1

Client Sample ID: HER-CMQD-111808


8260B Volatile Organic Compounds (GCIMS)[ Method: 8260B Analysis Batch: 680-1 23846 Instrument ID: GCIMS Volatiles - A C2Preparation: 50308 Lab File ID: a396.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/25/2008 1534 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1534

fl Analyte Result (ug/L) QualifierAcetone <25 25Acetonitrile <40 40Acrolein <20 20fl Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0[ Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0Carbon tetrachloride <1.0 1.0Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-1,3-butadiene <1,0 1.03-Chloro-1-propene <1.0 1.0Chlorodibromomethane <1.0 1.0


UDichlorodifluoromethane <1.0 1.01,1-Dichloroethane <1.0 1.01,2-Dichloroethane <1.0 1.01,1-Dichloroethene <1.0 1.0[ cis-1,2-Dichloroethene <1.0 1.0trans-i ,2-Dichloroethene <1.0 1.01,2-Dichloropropane <1.0 1.0cis-1,3-Dichloropropene <1.0 1.0fl trans-i ,3-Dichloropropene <1.0 1.0J Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 101 lodomethane <5.0 5.0J Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.01 Methyl methacrylate <1.0 1.0J 4-Methyl-2-pentanone (MIBK) <10 10Q Pentachloroethane <5.0 5.0Propionitrile <20 201 Styrene <1.0 1.0J i,i,1,2-Tetrachloroethane <1 0 1.0


Analytical Data

Client: Hercules Inc. Job Number 680-42572-1

Client Sample ID: HER-CMOO-111808



Method: 8260B Analysis Batch: 680-1 23846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a396.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11125/2008 1534 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1534

Analyte Result (ugIL) Qualifier RL1,1 ,22-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.0fl 1,1,1-Thchloroethane <1.0 1.0

U 1,1,2-Tiichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.0

O 1 ,23-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0

Surrogate %Rec Acceptance Limits4-Bromofluorobenzene 94 75- 120Dibromofluoromethane 100 75- 121Toluene-d8 (Surr) 99 75 - 120


Analytical Data


Client Sample ID: HER-MWO3-111908



U Method: 8260B Analysis Batch: 680-1 23846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a398.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/25/2008 1603 Final Weight/Volume: 5 mLDate Prepared: 11/25/2008 1603

Analyte Result (ug/L) Qualifier RLAcetone <25 25Acetonitrile <40 40Acrolein <20 20

O Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disultide <2.0 2.0Carbon teirachloride <1.0 1.0Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-1,3-butadiene <1.0 1.03-Chloro-1-propene <1.0 1.0Chlorodibromomethane <1.0 1.0

U1 ,2-Dibromo-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i ,4-Dichloro-2-butene <2.0 2.0Dichlorodifluoromethane <1.0 1.0i,1-Dichloroethane <1.0 1.0i,2-Dichloroethane <1.0 1.0i,i-Dichloroethene <1.0 1.0cis-i,2-Dichloroethene <1.0 1.0trans-12-Dichloroethene <1.0 1.01,2-Dichloropropane <1.0 1.0cis-i,3-Dichloropropene <1.0 1.0trans-i ,3-Dichloropropene <1.0 1.0Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10lodomethane <5.0 5.0Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.0Methyl methacrylate <1.0 1.0

J 4-Methyl-2-pentanone (MIBK) <10 10Pentachloroethane <5.0 5.0Propionilrile <20 20Styrene <1,0 1.01,1,1 ,2-Tetrachloroethane <1.0 1.0


Analytical DataClient: Hercules Inc. Job Number: 680-42572-1

Client Sample ID; I-IER-MWO3-111908


8260B Volatile Organic Compounds (GCIMS)[ Method: 8260B Analysis Batch: 680-123846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a398.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/25/2008 1603 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1603

Analyte Result (ug/L) Qualifier RL1,1 2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.0

fl 1,1,1-Trichloroethane <1.0 1.0U 1,1,2-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.0


Surrogate %Rec Acceptance Limits4-Bromofluorobenzene 97 75- 120Dibromofluoromethane 101 75- 121Toluene-d8 (Surr) 98 75 - 120


Analytical Data





fl Method: 8260B Analysis Batch: 680-123846 Instrument ID: GC/MS Volatiles -A C2LI Preparation: 5030B Lab File ID: a400.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/25)2008 1632 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1632

Analyte Result (ug/L) Qualifier RLAcetone <25 25Acetonitrile <40 40Acrolein <20 20Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0Carbon tetrachloride <1.0 1.0

D Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-1 3-butadiene <1.0 1.03-Chloro-i-propene <1.0 1.0Chlorodibromomethane <1.0 1,0


UDichlorodifluoromethane <1.0 1.01,1-Dichloroethane <1.0 1.01,2-Dichloroethane <1.0 1.0i,1-Dichloroethene <1.0 1 0

fjcis-1,2-Dichloroethene <1.0 1 0trans-i ,2-Dichloroethene <1.0 1.0i,2-Dichloropropane <1.0 1.0cis-i ,3-Dichloropropene <1.0 1.0trans-i .3-Dichloropropene <1.0 1.0Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10lodomethane <5.0 5.0Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.0Methyl methacrylate <1.0 1.0J 4-Methyl-2-pentanone (MIBK) <10 10Q Pentachloroethane <5.0 5.0Propionitrile <20 20Styrene <1.0 1 01,1,1 ,2-Tetrachloroethane <1.0 1 0




Lab Sample ID: 680-42572-9 Date Sampled: 11/19/2008 1034Client Matrix: Water Date Received: 11/2212008 0950


Method: 8260B Analysis Batch: 680-1 23846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a400.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/2512008 1632 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1632

UAnalyte Result (ug/L) Qualifier RL1,1 ,2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.0fl ill-Trichloroethane <1,0 1.01,12-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.0

E l ,2,3-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0



Analytical Data


Client Sample ID: HER-RS2-111908

Lab Sample ID: 680-42572-1 ORB Date Sampled: 1111912008 1057Client Matrix: Water Date Received: 11/22/2008 0950


Method: 8260B Analysis Batch: 680-1 23846 Instrument ID: GO/MS Volatiles - A 02Preparation: 5030B Lab File ID: a402.dDilution: 1.0 Initial WeightfVolume: 5 mLDate Analyzed: 1112512008 1702 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1702


U Acetone <25 25Acetonitrile <40 40Acrolein <20 20

O Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0Carbon tetrachloride <1.0 1.0Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-1,3-butadiene <1.0 1.03-Chtoro-1-propene <1.0 1.0Chlorodibromomethane <1.0 1.0

Ui ,2-Dibromo-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i ,4-Dichloro-2-butene <2.0 2.0Dichlorodifluoromethane <1.0 1.01,1-Dichloroethane <1.0 1.01,2-Dichloroethane <1.0 1.01,1-Dichloroethene <1.0 1.0cis-1,2-Dichloroethene <1.0 1.0trans-i ,2-Dichloroethene <1.0 1.01,2-Dichloropropane <1.0 1.0cis-i ,3-Dichloropropene <1.0 1.0r trans-i ,3-Dichloropropene <1.0 1.0

U Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10lodomethane <5.0 5 0J Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.0Methyl methacrylate <1.0 1.04-Methyl-2-pentanone (MIBK) <10 10Q Pentachloroethane <5.0 5,0Propionitrile <20 20Styrene <1.0 1.01.1,1 ,2-Tetrachloroethane <1.0 1.0


Analytical Data


Client Sample ID: HER-RS2.111908

Lab Sample ID: 680-42572-1 ORB Date Sampled: 11/19)2008 1057Client Matrix: Water Date Received: 11/22/2008 0950

8260B Volatile Organic Compounds (GCIMS)[ Method: 8260B Analysis Batch: 680-123846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a402.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/25/2008 1702 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1702

fl Analyte Result (ugIL) Qualifier RL11 ,2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.0111-Trichloroethane <1.0 1.0

U 1,1,2-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.0[ 1 ,2,3-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0

Surrogate %Rec Acceptance Limits4-Bromofluorobenzene 98 75- 120Dibromofluoromethane 102 75 - 121Toluene-d8 (Surr) 98 75- 120

TestAmericaSavannah Page 26 of 119

Analytical Data


Client Sample ID: HER-MWIO-111908



D Method: 8260B Analysis Batch: 680-123846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a404.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/25/2008 1731 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1731

Analyte Result (ug/L) Qualifier RLAcetone <25 25Acetonitrile <40 40Acrolein <20 20Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0

U Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0Carbon tetrachloride <1.0 1.0Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-i ,3-butadiene <1.0 1.03-Chloro-i-propene <1.0 1.0Chlorodibromomethane <1.0 1.0i,2-Dibromo-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i ,4-Dichloro-2-butene <2.0 2.0

UDichlorodifluoromethane <1.0 1.0i,i-Dichloroethane <1.0 1.01 ,2-Dichloroethane <1.0 1.0i,i-Dichloroethene <1.0 1.0cis-i,2-Dichloroethene <1.0 1.0

[I trans-i 2-Dichloroethene <1.0 1.0i,2-Dichloropropane <1.0 1.0cis-i ,3-Dichloropropene <1.0 1.0trans-i 3-Dichloropropene <1.0 1.0Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10lodomethane <5.0 5.0Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.0Methyl methacrylate <1.0 1.04-Methyl-2-pentanone (MIBK) <10 10Pentachloroethane <5.0 5.0Propionitrile <20 20Styrene <1.0 1.01,1.1 2-Tetrachloroethane <1.0 1.0


Analytical Data


Client Sample ID: HER-MWIO-111908



U Method: 8260B Analysis Batch: 680-123846 Instrument ID: GC/MS Volatiles -A C2Preparation: 5030B Lab File ID: a404,dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/25/2008 1731 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1731

Analyte Result (ug/L) Qualifier RL1,1 ,2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.0fl 1,1,1-Trichloroethane <1.0 1.0

LI 1,1 ,2-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.01 ,2,3-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0

Surrogate %Rec Acceptance Limits4-Bromofluorobenzene 97 75- 120Dibromofluoromethane 102 75- 121Toluene-d8 (Surr) . 97 75- 120


Analytical Data


Client Sample ID: HER-MW1I-111908

Lab Sample ID: 680-42572-12 Date Sampled: 1111912008 1428Client Matrix: Water Date Received: 11/22/2008 0950


Method: 8260B Analysis Batch: 680-123846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a406.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/25/2008 1800 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1800

fl Analyte Result (ug/L) Qualifier RLAcetone <25 25Acetonitrile <40 40Acrolein <20 20fl Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0

U Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0Carbon tetrachloride <1.0 1.0

U Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-1 3-butadiene <1.0 1.03-Chloro-1-propene <1.0 1.0Chlorodibromomethane <1.0 1.0

IJ1 ,2-Dibromo-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i ,4-Dichloro-2-butene <2.0 2,0

UDichlorodifluoromethane <1.0 1.01,1-Dichloroethane <1.0 1.01,2-Dichloroethane <1.0 1.0i,1-Dichloroethene <1.0 1.0cis-i,2-Dichloroethene <1.0 1.0

U trans-i ,2-Dichloroethene <1.0 1.01,2-Dichloropropane <1.0 1.0cis- 1 ,3-Dichloropropene <1.0 1.0

Dtrans-i,3-Dichloropropene <1.0 1.0Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10lodomethane <5.0 5.0

] Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.0Methyl methacrylate <1.0 1.0

2 4-Methyl-2-pentanone (MIBK) <10 10

Q Pentachloroethane <5.0 5.0Propionitrile <20 20Styrene <1.0 1.01,1,1 ,2-Tetrachloroethane <1.0 1.0



Client Sample ID: HER-MWII-111908



Method: 8260B Analysis Batch: 680-123846 Instrument ID: GC/MS Volatiles -A C2Preparation: 5030B Lab File ID: a406.dDilution: 1.0 Initial Weight/Volume: 5 mLDate Analyzed: 11/25/2008 1800 Final Weight/Volume: 5 mLDate Prepared: 11/25/2008 1800

UAnalyte Result (ug/L) Qualifier RL1,1 2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.0

fl 1,1,1-Trichloroethane <1.0 1 01,1 ,2-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.01 ,2,3-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0




Job Number: 680-42572-1




O Method: 8260B Analysis Batch: 680-1 23846 Instrument ID: GC!MS Volatiles - A C2Preparation: 50308 Lab File ID: a408.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/25/2008 1830 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1830

UAnalyte Result (ug/L) Qualifier RLAcetone <25 25Acetonitrile <40 40Acrolein <20 20

fl Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobrornomethane <1.0 1.0Bromoform <1.0 1.0Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0Carbon tetrachloride <1.0 1.0

O Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-1 3-butadiene <1.0 1.03-Chloro-i-propene <1.0 1.0Chlorodibromomethane <1.0 1.01 ,2-Dibromo-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i ,4-Dichloro-2-butene <2.0 2.0

UDichlorodifluoromethane <1.0 1.0li-Dichloroethane <1.0 1.0i,2-Dichloroethane <1.0 1.01,1-Dichloroethene <1.0 1.0

Dcis-i,2-Dichloroethene <1.0 1.0trans-i 2-Dichloroethene <1.0 1.01 2-Dichloropropane <1.0 1.0cis-i ,3-Dichloropropene <1.0 1.0trans-i 3-Dichloropropene <1.0 1.0Ethylbenzene <i.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 iDlodornethane <5.0 5.0J Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.0Methyl melhacrylate <1.0 1.0

j 4-Methyl-2-pentanone (MIBK) <10 10Q Pentachloroethane <5.0 50Propionitrile <20 20Styrene <1.0 1.01,i,i,2-Tetrachloroethane <1.0 1 0


Analytical Data





U Method: 826GB Analysis Batch: 680-1 23846 Instrument ID: DC/MS Volatiles - A C2Preparation: 503DB Lab File ID: a408.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/25/2008 1830 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1830

Analyte Result (ug)L) Qualifier RL1,1 ,2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.0

1,1,1-Trichloroethane

<1.0 1.011,2-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.0





Job Number: 680-42572-1

Client Sample ID: HER-FDOI-111908

Lab Sample ID: 680-42572-14FD Date Sampled: 11/19/2008 1515Client Matrix: Water Date Received: 11122/2008 0950

8260B Volatile Organic Compounds (GCIIVIS)

U Method: 8260B Analysis Batch: 680-123846 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a410.dDilution: 1.0 Initial Weight/Volume: 5 mLDateAnalyzed: 11/25/2008 1859 Final WeightNolume: 5 mLDate Prepared: 11/25/2008 1859

Analyte Result (ug/L) Qualifier RLAcetone <25 25Acetonitrile <40 40Acrolein <20 20

U Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0Carbontetrachloride <1.0 1.0Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-13-butadiene <1.0 1.03-Chloro-1-propene <1.0 1.0Chlorodibromomethane <1.0 1.01 2-Dibromo-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i ,4-Dichloro-2-butene <2.0 2.0Dichlorodifluoromethane <1.0 1.01,1-Dichloroethane <1.0 1.01,2-Dichloroethane <1.0 1.01,1-Dichloroethene <1.0 1.0cis-1,2-Dichloroethene <1.0 1.0lrans-1 ,2-Dichloioethene <1.0 1.01 ,2Dichloropropane <1.0 1.0cis-1,3-Dichloropropene <1.0 1.0trans-i ,3-Dichloropropene <1.0 1.0Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10lodomethane <5.0 5.0J Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.0

Methylmethacrylate <1 0 1.0

4-Methyl-2-pentanone (MIBK) <10 10Pentachloroethane <5.0 5.0Propionitrile <20 20Styrene <1 0 1.01,1,1 ,2-Tetrachloroethane <1.0 1.0



Job Number: 680-42572-1

Client Sample ID:

Lab Sample ID:Client Matrix.

HER-FDOI -111908

580-42572-1 4FDWater

Date Sampled:Date Received:

11/19/2008 151511/22/2008 0950

8260B Volatile Organic Compounds (GC1MS)

826DB

503DB

1.011/25/2008 185911/25/2008 1859

U Analyte

1,1 ,2,2-TetrachloroethaneTetrachloroetheneToluene

fl 1,1 1-Trichloroethane

Lj 1,1,2-TrichloroethaneTrichloroetheneTrichiorofluoromethane1 ,2,3-TrichloropropaneVinyl acetateVinyl chlorideXylenes, Total

Result (ug/L) Qualifier<1.0<1.0<1.0<1.0<1.0<1.0<1.0<1.0<2.0<1.0<2.0

Instrument ID: GC/MS Volatiles - A C2Lab File ID: a410.dInitial WeightNolume: 5 mLFinal WeightNolume: 5 mL

RL

1.01.01.01.01.01.01.01.02.01.02.0

Surrogate4-BromofluorobenzeneDibromofluoromethaneToluene-d8 (Surr)

%Rec

10010399

Acceptance Limits75- 12075- 12175-120

U Method:Preparation:Dilution:

Date Analyzed:Date Prepared:

Analysis Batch: 680-1 23846


Analytical Data



Lab Sample ID: 680-42572-15 Date Sampled: 11(19/2008 1639Client Matrix: Water Date Received: 11/22/2008 0950


U Method: 8260B Analysis Batch: 680-124082 Instrument ID: GC/MS Volatiles - A C2Preparation: 5030B Lab File ID: a425.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 11/26/2008 1523 Final WeightNolume: 5 mLDate Prepared: 11/26/2008 1523

Analyte Result (ugIL) Qualifier RLAcetone 85 25Acetonitrile <40 40Acrolein <20 20Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0

U Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0

OCarbon tetrachlonde <1.0 1.0

O Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-i 3-butadiene <1.0 1.03-Chloro-1-propene <1.0 1.0Chlorodibromomethane <1.0 1.0

Ui 2-Dibromo-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i ,4-Dichloro-2-butene <2.0 2.0Dichlorodifluoromethane <1.0 1.0ii-Dichloroethane <1.0 1.0i,2-Dichloroethane <1.0 1.0i,i-Dichloroethene <1.0 1.0cis-i,2-Dichloroethene <1.0 1.0

fl trans-i ,2-Dichloroethene <1.0 1.0I—I i,2-Dichloropropane <1.0 1.0

cis-1 ,3-Dichloropropene <1.0 1.0trans-i ,3-Dichloropropene <1.0 1.0Lthylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10lodomethane <5.0 5.0Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.0Methyl methacrylate <1.0 1.0

JO4-Methyl-2-pentanone (MIBK) <10 10Pentachloroethane <5.0 5.0Propionitrile <20 20nStyrene <1.0 1.0

J i,1i,2-Tetrachloroethane <1 0 1.0


Analytical Data




826DB Volatile Organic Compounds (GC/MS)

O Method: 826DB Analysis Batch: 680-1 24082 Instrument ID: GC/MS Volatiles - A C2Preparation: 503DB Lab File ID: a425.dDilution: 1.0 Initial WeighlNolume: 5 mLDate Analyzed: 11/26/2008 1523 Final WeightNolume: 5 mLDate Prepared: 11/26/2008 1523

Analyte Result (ugiL) Qualifier RL1,1 2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.0ill-Trichloroethane <1,0 1.01,1 2-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.01 23-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0



Analytical Data


Client Sample ID: HER-MWI2-1 12008

Lab Sample ID: 680-42572-16 Date Sampled: 11120/2008 0906

Client Matrix: Water Date Received: 11/22/2008 0950


fl Method: 82608 Analysis Batch: 680-1 241 64 Instrumenl ID: GCIMS Volatiles - APreparation: 50308 Lab File ID: a485.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 12/01/2008 1716 Final WeightNolume: 5 mLDate Prepared: 12/01/2008 1716

Analyte Result (ug/L) Qualifier RLAcetone 32 25Acetonitrile <40 40Acrolein <20 20

h Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <10 1.0Bromoform <1.0 1.0

J Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0Carbon tetrachloride <1.0 1.0

I Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-1,3-butadiene <1.0 1.03-Chloro-1-propene <1.0 1.0Chlorodibromomethane <1.0 1.01 ,2-Dibromo-3-Chloropropane <1.0 1.0

Ethylene Dibromide <1.0 1.0jijJ Dibromomethane <1.0 1.0

trans-i ,4-Dichloro-2-butene <2.0 2.0

U. Dichlorodifluoromethane <1.0 1.0

1,1-Dichloroethane <1.0 1.01,2-Dichloroethane <1.0 1.011-Dichloroethene <1.0 1.0cis-1,2-Dichloroethene <1.0 1.0trans-1,2-Dichloroethene <1.0 1.01,2-Dichloropropane <1.0 1.0cis-13-Dichloropropene <1.0 1.0

Otrans-1,3-Dichloropropene <1.0 1.0Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10

U lodomethane <5.0 5.0Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.0Methyl methacrylate <1.0 1.04-Methyl-2-pentanone (MIBK) <10 10Pentachloroethane <5.0 5.0Propionitrile <20 20

D Styrene <1.0 1.0111,2-Tetrachloroethane <1 0 1.0


Analytical Data


Client Sample ID: HER-MWI2-112008



Method: 8260B Analysis Batch: 680-1 24164 Instrument ID: GC/MS Volatiles - APreparation: 50308 Lab File ID: a485.dDilution: 1.0 Initial WeightNolume: 5 mLDate Analyzed: 12/01/2008 1716 Final WeightNolume: 5 mLDate Prepared: 12101/2008 1716

fl Analyte Result (ugIL) Qualifier RL1,1 2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.01,1,1-Trichloroethane <1.0 1.01,1,2-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.0[ 1,2,3-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0

Surrogate %Rec Acceptance Limits4-Bromofluorobenzene 100 75- 120Dibromofluoromethane 96 75- 121Toluene-d8 (Surr) 95 75-120


Analytical Data


Client Sample ID: HER-RSO3-112008

Lab Sample ID: 680-42572-17RB Date Sampled: 11/20/2008 0925



U Method: 8260B Analysis Batch: 680-124164 Instrument ID: GC/MS Volatiles -APreparation: 5030B Lab File ID: a487.d

Dilution: 1.0 Initial WeightlVolume: 5 mL

Date Analyzed: 12/01/2008 1746 Final WeightNolume: 5 mLDate Prepared: 12/01/2008 1746

Analyte Result (ugIL) Qualifier RLAcetone <25 25Acetonitrile <40 40Acrolein <20 20

E] Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0

QCarbon tetrachloride <1.0 1.0

fl Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-1 ,3-butadiene <1.0 1.03-Chloro-1-propene <1.0 1.0Chlorodibromomethane <1.0 1.0

Ui ,2-Dibromo-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i ,4-Dichloro-2-butene <2.0 2.0Dichlorodifluoromethane <1.0 1.01,1-Dichloroethane <1.0 1.0

LJ 1,2-Dichloroethane <1.0 1.01,1-Dichloroethene <1.0 1.0cis-i,2-Dichloroethene <1.0 1.0

IJ trans-i,2-Dichloroethene <1.0 1.01 ,2-Dichloropropane <1.0 1.0cis-i ,3-Dichloropropene <1.0 1.0

Utrans-i 3-Dichloropropene <1.0 1.0Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10

U lodomethane <5.0 5.0lsobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.0

U Methyl methacrylate <1.0 1.0

O4-Methyl-2-pentanone (MIBK) <10 10Pentachloroethane <5.0 5 0Propionitrile <20 20Styrene <1.0 1.01,1.1 ,2-Tetrachloroethane <1.0 1.0


Analytical Data


Client Sample ID: HER-RSO3-1 12008

Lab Sample ID: 680-42572-17RB Date Sampled: 11/20/2008 0925



Method: 8260B Analysis Batch: 680-124164 Instrument ID: GC/MS Volatiles -A

Preparation: 503DB Lab File ID: a487.d

Dilution: 1.0 Initial Weight/Volume: 5 mL

Date Analyzed: 12/01/2008 1746 Final WeightNolume: 5 mL

Date Prepared: 12/01/2008 1746

Analyte Result (ugIL) Qualifier RL

1,1 2,2-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1,0 1.01,1,1-Trichloroethane <1.0 1.01,1,2-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.0

fl 1,2,3-Trichloropropane <1.0 1.0

U Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0

Surrogate %Rec Acceptance Limits

4-Bromofluorobenzene 99 75- 120Dibromofluoromethane 98 75- 121Toluene-d8 (Surr) 96 75 - 120


Analytical Data






O Method: 8260B Analysis Batch: 680-1 241 64 Instrument ID: GC/MS Volatiles - A

Preparation: 5030B Lab File ID: a493.d

Dilution: 2.0 Initial WeightNolume: 5 mL




Acetone 490 50Acetonitrile <80 80Acrolein <40 40Acrylonitrile <40 40Benzene <2.0 2.0Dichlorobromomethane <2.0 2.0Bromoform <2.0 2.0

fl Bromomethane <2.0 2.02-Butanone (MEK) <20 20Carbon disulfide <4.0 4.0

OCarbon tetrachloride <2.0 2.0

O Chlorobenzene <2.0 2.0Chloroethane <2.0 2.0Chloroform <2.0 2.0Chloromethane <2.0 2.02-Chloro-13-butadiene <2.0 2.03-Chloro-1-propene <2.0 2.0Chlorodibromomethane <2.0 2.0

U1,2-Dibromo-3-Chloropropane <2.0 2.0Ethylene Dibromide <2.0 2.0Dibromomethane <2.0 2,0trans-i ,4-Dichloro-2-butene <4.0 4.0Dichlorodifluoromethane <2.0 2.0

U 1,1-Dichloroethane <2.0 2.01 ,2-Dichloroethane <2.0 2.01,1-Dichloroethene <2.0 2.0cis-1,2-Dichloroethene <2.0 2.0

U trans-i 2-Dichloroethene <2.0 2.01 ,2-Dichloropropane <2.0 2.0cis-1,3-Dichloropropene <2.0 2.0trans-i 3-Dichloropropene <2.0 2.0Ethylbenzene <2.0 2.0Ethyl methacrylate <2.0 2.02-Hexanone <20 20lodomethane <10 10Isobutyl alcohol <80 80Methacrylonitrile <40 40Methylene Chloride <10 10

D Methyl methacrylate <2.0 2.0

Q4-Methyl-2-pentanone (MIBK) <20 20Pentachloroethane <10 10Propionitrile <40 40Styrene <2.0 2.01,1,1 2-Tetrachloroethane <2.0 2.0


Analytical Data


Client Sample ID: HERMWO6-1120O8

Lab Sample ID: 680-42572-18 Date Sampled 11/20/2008 0953



O Method: 82608 Analysis Batch: 680-124164 lnstwment ID: GC/MS Volatiles -A

Preparation: 5030B Lab File ID: a493.d

Dilution: 2.0 Initial WeighliVolume: 5 mL

Date Analyzed: 12/01/2008 1914 Final Weight/Volume: 5 mL



U 11,2,2-Tetrachloroethane <2.0 2.0

Tetrachloroethene <2.0 2.0

Toluene <2.0 2.0

fl 11,1-Trichloroethane <2.0 2.0

LI 1,1,2-Trichloroethane <2.0 2.0

Trichloroethene <2.0 2.0

Trichlorofluoromethane <2.0 2.0[ 12,3-Trichloropropane <2.0 2.0

Vinyl acetate <4.0 4 0

Vinyl chloiide <2.0 2.0

Xylenes, Total <4.0 4.0


4-Bromofluorobenzene 99 75- 120

Dibromofluoromethane 97 75- 121

Toluene-d8 (Surr) 95 75- 120


Analytical Data


Client Sample ID: HER-MWI8-112008

Lab Sample ID: 680-42572-19 Date Sampled; 11/20/2008 1037


8260B Volatile Organic Compounds (GC1MS)

O Method: 826DB Analysis Batch: 680-1 23846 Instrument ID: GC/MS Volatiles - A C2

Preparation: 503DB Lab File ID: a412 d


Date Analyzed: 11/25/2008 1929 Final WeightNolume. 5 mL



U Acetone <25 25

Acetonitrile <40 40

Acrolein <20 20

O Acrylonitrile <20 20

Benzene <1.0 1.0

Dichlorobromomethane <1.0 1.0

Bromoform <1.0 1.0

L Bromomethane <1.0 1.0

2-Butanone (MEK) <10 10

Carbon disulfide <2.0 2.0


L Chlorobenzene 23 1.0

Chloroethane <1.0 1.0

Chloroform <1.0 1.0

Chloromethane <1.0 1.0

2-Chloro-13-butadiene <1.0 1.0

3-Chloro-1-propene <1.0 1.0

Chlorodibromomethane <1.0 1.0

Ui ,2-Dibrorno-3-Chloropropane <1.0 1.0

Ethylene Dibromide <1.0 1.0

Dibromomethane <1.0 1.0

trans-i 4-Dichloro-2-butene <2.0 2.0

UDichlorodifluoromethane <1.0 1.0

ii-Dichloroethane <1.0 1.0

i2-Dichloroethane <1.0 1.0

1,1-Dichloroethene 1.0 1.0

cis-i,2-Dichloroethene <1.0 1.0trans-i ,2-Dichloroethene <1.0 1.0

1,2-Dichloropropane <1.0 1.0

cis-i ,3-Dichloropropene <1.0 1.0

Utrans-i ,3-Dichloropropene <1.0 1.0

Ethylbenzene <1.0 1.0

Ethyl methacrylate <1.0 1.0

2-Hexanone <10 10

r lodomethane <5.0 5.0

[j Isobutyl alcohol <40 40

Methacrylonitrile <20 20

Methylene Chloride <5.0 5.0

fl Methyl methacrylate <1.0 1.0

jQ4-Methyl-2-pentanone (MIBK) <10 10

Pentachloroethane <5.0 5.0Propionitrile <20 20

Styrene <1.0 1.0

1 1 1 2-Tetrachloroethane <1.0 1.0


Analytical Data

Client: Hercules Inc. Job Number 680-42572-1


Method:

Li Preparation:

Dilution:

Date Analyzed:

Date Prepared:

8260B

5030B

1.011/25/2008 1929

11/25/2008 1929

Analysis Batch: 680-1 23846 Instrument ID: GC/MS Volatiles - A C2

Lab File ID: a412.d

Initial WeightNolume: 5 mL

Final WeightNolume: 5 mL

OAnalyte

1,1 ,22-TetrachloroethaneTetrachloroetheneToluene1,1,1-Trichloroethane1,1 2-TrichloroethaneTrichloroetheneTrichiorofluoromethane

[J 1 2,3-TrichloropropaneVinyl acetateVinyl chlorideXylenes, Total

Result (ug/L)

<1.0<1.0<1.0<1.0<1.0<1.0<1.0<1.0<2.0<1.0<2.0

Surrogate

4-BromofluorobenzeneDibromofluoromethaneToluene-d8 (Surr)

%Rec

101105101

Acceptance Limits

75- 12075- 12175- 120

Client Sample ID:

Lab Sample ID:

Client Matrix:

HER-MWI 8-1 12008

680-42572-19

Water

Date Sampled:

Date Received:

11/20/2008 1037

11/22/2008 0950

Qualifier RL

1.01.01.01.01.01.01.01.02.01.02.0


Analytical Data


Client Sample ID: HER-FDO2-112008

Lab Sample ID: 680-42572-2OFD Date Sampled: 11/20/2008 0000



O Method: 8260B Analysis Batch: 680-124115 Instrument ID: GC/MS Volatiles -0 C2

Preparation: 5030B Lab File ID: o6496.d

Dilution: 1.0 Initial Weight/Volume: 5 mL

Date Analyzed: 11/28/2008 1244 Final Weight/Volume: 5 mL



U Acetone <25 25

Acetonitrile <40 40

Acrolein <20 20

fl Acrylonitrile <20 20

U Benzene 1.1 1.0

Dichlorobromomethane <1 0 1.0

Bromoform <1.0 1.0

Bromomethane <1.0 1.0




fl Chlorobenzene 28 1.0

U Chloroethane <1.0 1.0

Chloroform <1.0 1.0

Chloromethane <1.0 1.0

2-Chloro-1,3-butadiene <1.0 1.0



1 ,2-Dibromo-3-Chloropropane <1.0 1.0

Ethylene Dibromide <1.0 1.0

U Dibromomethane <1.0 1.0


Dichlorodifluoromethane <1.0 1.0

i,i-Dichloroethane <1.0 1.0

i,2-Dichloroethane <1.0 1.0

1,i-Dichloroethene 1.2 1.0

cis-i,2-Dichloroethene <1.0 1.0

U trans-i2-Dichloroethene <1.0 1.0

i,2-Dichloropropane 1.1 1.0

cis-13-Dichloropropene <1.0 1.0

Ltrans-1,3-Dichloropropene <1.0 1.0

Ethylbenzene <1.0 1.0

Ethyl methacrylate <1.0 1.0

2-Hexanone <10 10

L lodomethane <5.0 5.0

Isobutyl alcohol <40 40

Methacrylonitrile <20 20

Methylene Chloride <5.0 5.0

fl Methyl methacrylate <1 0 1 0

O4-Methyl-2-pentanone (MIBK) <10 10

Pentachloroethane <5.0 5.0

Propionitrile <20 20

Styrene <1 0 1.0

L 1,1,1 .2-Tetrachloroethane <1.0 1.0


Analytical Data


Client Sample ID: HER-FDO2-112008

Lab Sample ID: 680-42572-2OFD Date Sampled: 11/20/2008 0000



Method: 8260B Analysis Batch: 680-124115 Instrument ID. GC/MS Volatiles -0 C2


Dilution: 1.0 Initial WeightfVolume: 5 mL




U 112,2-Tetrachloroethane <1.0 1.0

Tetrachloroethene <1.0 1.0

Toluene <1.0 1.0

O1,1,1-Trichloroethane <1.0 1.0

1,1,2-Trichloroethane <1.0 1.0

Trichloroethene <1.0 1.0

Trichlorofluoromethane <1.0 1.0

O 1,2,3-Trichloropropane <1.0 1.0

Vinyl acetate <2.0 2.0

Vinyl chloride <1.0 1.0

Xylenes, Total <2.0 2.0


4-Bromofluorobenzene 103 75- 120

Dibromofluoromethane 95 75 121

Toluene-d8 (Surr) 104 75- 120


Analytical Data


Client Sample ID; HER-MWI9-112008




Method: 8260B Analysis Batch: 680-124115 Instrument ID: GC/MS Volatiles -0 C2






LI Acetone <25 25

Acetonitrile <40 40

Acrolein <20 20

fl Acrylonitrile <20 20

U Benzene 58 1.0

Dichlorobromomethane <1.0 1.0

Bromoform <1.0 1.0

L Bromomethane <1.0 1.0



OCarbon tetrachloride <1 0 1.0

L Chlorobenzene 9.7 1.0

Chloroethane <1.0 1.0

Chloroform 1.1 1.0

Chloromethane <1.0 1.02-Chloro-i,3-butadiene <1.0 1.0



U12-Dibromo-3-Chloropropane <1.0 1.0

Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0


UDichlorodifluoromethane <1.0 1.0

ii-Dichloroethane <1.0 1.012-Dichloroethane <1.0 1.0

li-Dichloroethene <1.0 1.0

cis-i,2-Dichloroethene <1.0 1.0

U trans-i 2-Dichloroethene <1.0 1.0

12-Dichloropropane <1.0 1.0

cis-i,3-Dichloropropene <1.0 1.0[ trans-1,3-Dichloropropene <1.0 1.0

Ethylbenzene 2.4 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10

U lodomelhane <5.0 5.0

Isobutyl alcohol <40 40

Methacrylonitrile <20 20Melhylene Chloride <5.0 5.0

Methyl methacrylate <1.0 1.0

Li 4-Methyl-2-pentanone (MIBK) <10 10

Pentachloroelhane <5.0 5.0Propionitrile <20 20

Styrene <1.0 1.0

11,1 2-Tetrachloroethane <1.0 1.0


Analytical Data


Client Sample ID: HER-MW07-1 12008



8260B Volatile Organic Compounds (GCIrV1S)

r Method: 8260B Analysis Batch: 680-124115 Instrument ID: GC/MS Volatiles - 0 C2

[j Preparation: 5030B Lab File ID: o6500.dDilution: 1.0 Initial WeightNolume: 5 mL




Acetone <25 25Acetonitrile <40 40Acrolein <20 20

Acrylonitrile <20 20Benzene <1.0 1.0Dichlorobromomethane <1.0 1.0Bromoform <1.0 1.0Bromomethane <1.0 1.02-Butanone (MEK) <10 10Carbon disulfide <2.0 2.0

OCarbon tetrachloride <1.0 1.0[ Chlorobenzene <1.0 1.0Chloroethane <1.0 1.0Chloroform <1.0 1.0Chloromethane <1.0 1.02-Chloro-1 ,3-butadiene <1.0 1.03-Chloro-i-propene <1.0 1.0Chlorodibromomethane <1.0 1.0

Ui ,2-Dibromo-3-Chloropropane <1.0 1.0Ethylene Dibromide <1.0 1.0Dibromomethane <1.0 1.0trans-i 4-Dichloro-2-butene <2.0 2.0Dichlorodifluoromethane <1.0 1.01,1-Dichloroethane <1.0 1.01,2-Dichloroethane <1.0 1.0i,i-Dichloroethene <1,0 1.0cis-i,2-Dichloroethene <1.0 1.0

U trans-1,2-Dichloroethene <1.0 1.01,2-Dichloropropane <1.0 1.0cis-i,3-Dichloropropene <1.0 1.0trans-i ,3-Dichloropropene <1.0 1.0Ethylbenzene <1.0 1.0Ethyl methacrylate <1.0 1.02-Hexanone <10 10lodomethane <5.0 5.0Isobutyl alcohol <40 40Methacrylonitrile <20 20Methylene Chloride <5.0 5.0Methyl methacrylate <1.0 1.04-Methyl-2-pentanone (MIBK) <10 10Pentachloroethane <5.0 5.0Propionitrile <20 20Styrene <1.0 10i,1,1,2-Tetrachloroethane <1.0 1 0

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Analytical Data


Client Sample ID: HER-MWO7-1 12008


Client Matiix: Water Date Received: 11/22/2008 0950

826DB Volatile Organic Compounds (GC/MS)

Method: 8260B Analysis Batch: 680-124115 Instrument ID: GC/MS Volatiles -0 C2






1,1 ,22-Tetrachloroethane <1.0 1.0Tetrachloroethene <1.0 1.0Toluene <1.0 1.01,1 1 -Trichloroethane <1.0 1.01,1 2-Trichloroethane <1.0 1.0Trichloroethene <1.0 1.0Trichlorofluoromethane <1.0 1.0

fl 12,3-Trichloropropane <1.0 1.0Vinyl acetate <2.0 2.0Vinyl chloride <1.0 1.0Xylenes, Total <2.0 2.0


4-Bromofluorobenzene 102 75- 120Dibromofluoromethane 96 75- 121Toluene-d8 (Surr) 104 75- 120

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monitoring report - mdeq

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