modelling of beryllium erosion/deposition and local ... · bm11, „hdc‟: profile at y=-187mm ....

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Member of the Helmholtz Association D.Borodin | Institute of Energy Research Plasma Physics | Association EURATOM FZJ Modelling of Beryllium Erosion/Deposition and Local Transport at ITER First Wall Blanket Modules Using the ERO code D.Borodin 1 , A.Kirschner 1 , S.Carpentier-Chouchana 2 , R.Pitts 2 , C. Björkas 3 , P.C.Stangeby 4 , J.D. Elder 4 , A.Galonska 1 , D.Matveev 1 , V.Philipps 1 , U.Samm 1 1 Institute of Energy and Climate Research - Plasma Physics, Forschungszentrum Jülich GmbH, Association EURATOM-FZJ, Partner In the Trilateral Euregio Cluster, Jülich, Germany 2 ITER organization, Science Division, Route de Vinon sur Verdon 13115 St Paul Lez Durance France 3 EURATOM-Tekes, Department of Physics, P.O. Box 43, FI-00014 University of Helsinki, Finland 4 University of Toronto Institute Aerospace Studies, Ontario, Canada M3H 5T6

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Page 1: Modelling of Beryllium Erosion/Deposition and Local ... · BM11, „HDC‟: profile at y=-187mm . 12.05.2011 D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich No 11 -600

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D.Borodin | Institute of Energy Research – Plasma Physics | Association EURATOM – FZJ

Modelling of Beryllium Erosion/Deposition and

Local Transport at ITER

First Wall Blanket Modules Using the ERO code

D.Borodin1, A.Kirschner1, S.Carpentier-Chouchana2, R.Pitts2, C. Björkas3,

P.C.Stangeby4, J.D. Elder4, A.Galonska1, D.Matveev1, V.Philipps1, U.Samm1

1Institute of Energy and Climate Research - Plasma Physics, Forschungszentrum Jülich GmbH,

Association EURATOM-FZJ, Partner In the Trilateral Euregio Cluster, Jülich, Germany 2ITER organization, Science Division, Route de Vinon sur Verdon – 13115 St Paul Lez Durance – France

3EURATOM-Tekes, Department of Physics, P.O. Box 43, FI-00014 University of Helsinki, Finland 4University of Toronto Institute Aerospace Studies, Ontario, Canada M3H 5T6

Page 2: Modelling of Beryllium Erosion/Deposition and Local ... · BM11, „HDC‟: profile at y=-187mm . 12.05.2011 D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich No 11 -600

D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich 12.05.2011 No 2

ITER Be wall – BM erosion

• Blanket module (BM) shapes optimized for

heat loads (P.C.Stangeby)

Aim – predictive modelling of

ITER, including first wall life time

BM 15

BM11

FLFS close to 2nd separatrix =>

First PFC life time estimates assuming

limiter-like contact on outboard BM11

Be

+ low Z

- high erosion

Page 3: Modelling of Beryllium Erosion/Deposition and Local ... · BM11, „HDC‟: profile at y=-187mm . 12.05.2011 D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich No 11 -600

D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich 12.05.2011 No 3

(mmBe/h)

peak erosion

redeposition

toroidal

dist (m)

poloidal

dist (m)

(mmBe/h)peak erosion

toroidal

dist (m)

poloidal

dist (m)

High density case Low density case

<Yeff> ~ 7%, ~50% particles locally redeposited

Net peak erosion ~ 0.06 mm/h

PFC lifetime ~ 1500 shots

T-retention* ~ 0.083 gT/h for one module

~ 3 gT/h for 36 BM11-18

Limit ~ 1920 shots (assuming: 50:50 D:T plasma, maximum safety limit ~640g)

<Yeff> ~ 6%, ~10% particles locally redeposited

Net peak erosion ~0.0025 mm/h

PFC lifetime ~ 36 000 shots

T-retention* < 1.3 mgT/h for 36 BM11-18

* 2D estimation of (D+T)/Be = f(Tsurf, Eimp, ГD/ГBe) [PICSES-B scaling law, G. De Temmerman, R. Doerner]

2D Net erosion-redeposition patterns on BM11

LIM code results [S.Carpentier et.al, PSI-19,

J.Nucl.Mater. (2010), in press]

Important issue for ITER:

benchmark with ERO focusing on

life time

Page 4: Modelling of Beryllium Erosion/Deposition and Local ... · BM11, „HDC‟: profile at y=-187mm . 12.05.2011 D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich No 11 -600

D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich 12.05.2011 No 4

Background Plasma

EB

C, Be, …

CD4

Cx+,Bex+,…

CDz0,+

re-eroded/

reflected particles

PFC (substrate Be, C, W, Mo, …)

Input:

ne, Te,i,

geometry

ionisation, dissociation

friction (Fokker-Planck), thermal force

Lorentz force

cross-field diffusion

physical sputtering/reflection

chemical erosion (CD4)

(re-)erosion and (re-)deposition

HMM and SDTrimSP surface models

Local transport: Plasma-surface interaction:

3D MC impurity transport code ERO

Page 5: Modelling of Beryllium Erosion/Deposition and Local ... · BM11, „HDC‟: profile at y=-187mm . 12.05.2011 D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich No 11 -600

D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich 12.05.2011 No 5

ITER Be wall – plasma parameters

Aim – predictive modelling of

ITER first wall life time

Complications:

• Complex geometry e.g. leading

to shadowing

• Uncertainty in atomic and

surface data for Be

• Other uncertainties: enhanced

re-erosion, carbide and alloy

formation, Be-D molecules, etc.

high density case (HDC) BM11

LIM predicted life time due to transient

events is not a limiting factor – we

concentrate on steady state

Page 6: Modelling of Beryllium Erosion/Deposition and Local ... · BM11, „HDC‟: profile at y=-187mm . 12.05.2011 D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich No 11 -600

D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich 12.05.2011 No 6

Plasma parameters at limiter surface

Te = 10eV = const

Ti = 20eV = const

Te = 7.1eV = const

Ti = 18.6eV = const

High density case

(HDC)

Low density case

(LDC)

Page 7: Modelling of Beryllium Erosion/Deposition and Local ... · BM11, „HDC‟: profile at y=-187mm . 12.05.2011 D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich No 11 -600

D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich 12.05.2011 No 7

Shadowing patterns (LIM and ERO)

BM11, steady state BM15, start-up

shadowed

wetted shadowed

wetted

In shadowed areas we assume no BG erosion and re-deposition of intrinsic Be impurity

Modelling is in

progress, out of

the scope!

Page 8: Modelling of Beryllium Erosion/Deposition and Local ... · BM11, „HDC‟: profile at y=-187mm . 12.05.2011 D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich No 11 -600

D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich 12.05.2011 No 8

LIM and ERO overview

Code ERO LIM

Type Monte-Carlo impurity tracing (BG plasma import)

BM implementation Shape, shadowing, plasma parameter, etc. - SIMILAR

Geometry 3D 2D

Test-particle tracing resolving gyro-motion guiding centre

Intrinsic Be impurity concentration in D+ flux possible

Collisions with surface resolved angle and energy sheath potential

Multiple BM tiles periodic boundary particle "mirrors"

Many routines in ERO for ITER BM are “imported” from the LIM code.

Page 9: Modelling of Beryllium Erosion/Deposition and Local ... · BM11, „HDC‟: profile at y=-187mm . 12.05.2011 D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich No 11 -600

D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich 12.05.2011 No 9

Poloidal positions of toroidal profiles

Profile y=5mm

Profile y=-187mm

Profile y=-387mm

Maximal erosion

Background (BG) plasma erosion; BM11, HDC

For LDC the maximal erosion point is elsewhere . . .

[Be/cm-2]

Page 10: Modelling of Beryllium Erosion/Deposition and Local ... · BM11, „HDC‟: profile at y=-187mm . 12.05.2011 D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich No 11 -600

D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich 12.05.2011 No 10

-600 -400 -200 0 200 400 600

-0.08

-0.06

-0.04

-0.02

0

0.02

0.04

0.06

layer

evolu

tio

n [

mm

/h]

x (toroidal) [mm]

HDC, y=-187mm

LIM depos.

LIM BG eros.

LIM Be s-sputt.

LIM net eros.

ERO Be s-sputt.

ERO BG eros.

ERO net eros.

ERO depos.

Erosion/deposition profiles

Very good agreement between ERO and LIM

Deposition

Erosion by

background (BG)

plasma Layer

evolu

tion [

mm

/h]

BM11, „HDC‟: profile at y=-187mm

Page 11: Modelling of Beryllium Erosion/Deposition and Local ... · BM11, „HDC‟: profile at y=-187mm . 12.05.2011 D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich No 11 -600

D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich 12.05.2011 No 11

-600 -400 -200 0 200 400 600

-0.09

-0.08

-0.07

-0.06

-0.05

-0.04

-0.03

-0.02

-0.01

0

layer

evolu

tio

n [

mm

/h]

x (toroidal) [mm]

HDC, y=-187mm

LIM total eros.

LIM Be s-sputt.

ERO total eros.

ERO Be s-sputt.

Erosion profiles

Self-sputtering in ERO is larger and more concentrated near the ridge

Be self-sputtering

Total erosion

Small influence on total erosion . . .

Layer

evolu

tion [

mm

/h]

BM11, „HDC‟: profile at y=-187mm

Page 12: Modelling of Beryllium Erosion/Deposition and Local ... · BM11, „HDC‟: profile at y=-187mm . 12.05.2011 D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich No 11 -600

D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich 12.05.2011 No 12

-600 -400 -200 0 200 400 600

-0.08

-0.06

-0.04

-0.02

0

0.02

0.04

0.06

layer

evolu

tio

n [

mm

/h]

x (toroidal) [mm]

HDC, y=-187mm

LIM depos.

LIM BG eros.

LIM Be s-sputt.

LIM net eros.

ERO Be s-sputt.

ERO BG eros.

ERO net eros.

ERO depos.

The net erosion in LIM and ERO is in a very good agreement

Life time limiting erosion:

1[cm]/0.05[mm/h] = 200h

Net erosion

Net erosion profiles Layer

evolu

tion [

mm

/h]

BM11, „HDC‟: profile at y=-187mm

Page 13: Modelling of Beryllium Erosion/Deposition and Local ... · BM11, „HDC‟: profile at y=-187mm . 12.05.2011 D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich No 11 -600

D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich 12.05.2011 No 13

-600 -400 -200 0 200 400 600

-0.08

-0.06

-0.04

-0.02

0

0.02

0.04

0.06

layer

evolu

tio

n [

mm

/h]

x (toroidal) [mm]

HDC, y=-187mm

LIM depos.

LIM BG eros.

LIM Be s-sputt.

LIM net eros.

ERO Be s-sputt.

ERO BG eros.

ERO net eros.

ERO depos.

ERO uses in this case angle averaged W.Eckstein 2002 data for

sputtering yields from LIM and ADAS ‟93‟ Be ionization . . .

Life time limiting erosion:

1[cm]/0.05[mm/h] = 200h

Erosion/deposition profiles Layer

evolu

tion [

mm

/h]

BM11, „HDC‟: profiles at y=-187mm

Page 14: Modelling of Beryllium Erosion/Deposition and Local ... · BM11, „HDC‟: profile at y=-187mm . 12.05.2011 D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich No 11 -600

D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich 12.05.2011 No 14

Deposition in LDC is very low (in diffrence to HDC)

Life time limiting erosion:

1[cm]/1.5*10-4[cm/h] = 6600h

Maximal

erosion for

BM11, LDC is

at y=-367mm!..

Erosion profiles

BM11, „LDC‟: profiles at y=-187mm Layer

evolu

tion [

mm

/h]

Page 15: Modelling of Beryllium Erosion/Deposition and Local ... · BM11, „HDC‟: profile at y=-187mm . 12.05.2011 D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich No 11 -600

D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich 12.05.2011 No 15

Deposition: low vs. high density plasma

Be is ionized close to surface . . . Large redeposition.

Be is ionized far away from surface . . . Small redeposition.

Density of Be+[cm-2] – High density case (HDC)

Density of Be+[cm-2] – low density case (LDC)

In both LIM and ERO deposition dependence on plasma parameters is feasible!

Page 16: Modelling of Beryllium Erosion/Deposition and Local ... · BM11, „HDC‟: profile at y=-187mm . 12.05.2011 D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich No 11 -600

D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich 12.05.2011 No 16

ERO vs. LIM benchmark summary

• ERO in agreement with LIM . . .

a) Shadowing patterns, plasma parameters, etc.

implemented in a similar way.

b) Erosion, deposition and finally net erosion profiles are

in good agreement for BM11 (steady state).

c) Plasma conditions dependence is in agreement.

• ERO vs. LIM disagreements

a) Self-sputtering in ERO is larger and more concentrated

near the ridge. May indicate some difference in Be

transport assumptions . . .

Benchmark with existing experiments

would be useful!

Page 17: Modelling of Beryllium Erosion/Deposition and Local ... · BM11, „HDC‟: profile at y=-187mm . 12.05.2011 D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich No 11 -600

D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich 12.05.2011 No 17

Be sputtering yields – extreme assumptions

Normal incidence! Angle dependence should be taken into the account!

Only the ‘calculated’ data are included!

1) “maximum” – static TRIM + MD

2) “minimum” – SDTrimSP with 50% of D

(reasonable limit)

Experimental data too much scattered!

1) Large deviations: no sense to analyse

shape of curves

2) Various effects are difficult to separate

Be by D+ sputtering Be by D+ sputtering

„ERO-min“

„ERO-max“

Page 18: Modelling of Beryllium Erosion/Deposition and Local ... · BM11, „HDC‟: profile at y=-187mm . 12.05.2011 D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich No 11 -600

D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich 12.05.2011 No 18

Be sputtering yields – self sputtering

Estimation based on calculated data as for

Be by D+ sputtering Angular part is essential!

For following BM simulations ERO uses Eckstein 2007 fit.

Normal incidence Angular dependence

„ERO-max“ „ERO-min“

Page 19: Modelling of Beryllium Erosion/Deposition and Local ... · BM11, „HDC‟: profile at y=-187mm . 12.05.2011 D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich No 11 -600

D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich 12.05.2011 No 19

Sputtering by BG plasma (and intrinsic Be)

- “integration” produces effective sputter yields -

η (“B-angle”)

B=4.8T

Calculation of sputtering yield according to Eckstein’s fit 2007 for Y(E, α), using

angle and energy distribution as calculated by ERO (including gyration and sheath)

Injection of D+ or Be+ with Maxwell

energy around Ti and uniform initial

angle distribution

stagnation

α( angle of incidence)

ERO pre-calculation

normal

0 10 20 30 40 50 60 70 80 900

50

100

150

Angle of incidence [o]

En

erg

y [e

V]

D+ ions

"B-angle" = 1o

"B-angle" = 5o

"B-angle" = 20o

"B-angle" = 35o

0 10 20 30 40 50 60 70 80 900

50

100

150

200

250

300

Angle of incidence [o]

En

erg

y [e

V]

Be+, Be2+ ions

"B-angle" = 1o

"B-angle" = 5o

"B-angle" = 20o

"B-angle" = 35o

Page 20: Modelling of Beryllium Erosion/Deposition and Local ... · BM11, „HDC‟: profile at y=-187mm . 12.05.2011 D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich No 11 -600

D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich 12.05.2011 No 20

Be by D+ sputtering yields – assumptions

LIM data is ‘Eck2002’ averaged by incidence angle assuming uniform distribution

Incidence energy dependence Integrated yields

• HDC conditions (Te=10eV, Ti = 20eV)

BM11,HDC X

ELIM = 3Te+2Ti =70eV

Averaged by angle!

Normal

incidence

„Eck2002‟ is

[W.Eckstein,

IPP-report 2002]

Page 21: Modelling of Beryllium Erosion/Deposition and Local ... · BM11, „HDC‟: profile at y=-187mm . 12.05.2011 D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich No 11 -600

D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich 12.05.2011 No 21

Be self-sputtering yields – assumptions

Averaged by angle! BM11,HDC X

ELIM (Be+)= Z*3Te+2Ti =70eV

Normal

incidence

LIM data is ‘Eck2002’ averaged by incidence angle assuming uniform distribution

„Eck2002‟ is

[W.Eckstein,

IPP-report 2002]

Incidence energy dependence Integrated yields

• HDC conditions (Te=10eV, Ti = 20eV)

Page 22: Modelling of Beryllium Erosion/Deposition and Local ... · BM11, „HDC‟: profile at y=-187mm . 12.05.2011 D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich No 11 -600

D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich 12.05.2011 No 22

-600 -400 -200 0 200 400 600

-0.08

-0.07

-0.06

-0.05

-0.04

-0.03

-0.02

-0.01

0

0.01

layer

evolu

tio

n [

mm

/h]

x (toroidal) [mm]

ERO-max (0.081mm/h)

ERO-min (0.021mm/h)

Eck2002(LIM) (0.062mm/h)

Sputter yields assumptions and net erosion

BM11, „HDC‟: net erosion (deposition) profile at y=-187mm

In most pessimistic case life time about 30% less than in earlier LIM predictions

LIM predictions

4200 ITER shots

1500 ITER shots

1100 ITER shots

LIM predictions Layer

evolu

tion [

mm

/h]

Page 23: Modelling of Beryllium Erosion/Deposition and Local ... · BM11, „HDC‟: profile at y=-187mm . 12.05.2011 D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich No 11 -600

D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich 12.05.2011 No 23

-600 -400 -200 0 200 400 600

-0.08

-0.07

-0.06

-0.05

-0.04

-0.03

-0.02

-0.01

0

0.01

0.02

layer

evolu

tio

n [

mm

/h]

x (toroidal) [mm]

ERO-max (0.081mm/h)

ERO-max, 1% Be (BG) (0.074mm/h)

ERO-max, 3% Be (BG) (0.063mm/h)

ERO-max, 5% Be (BG) (0.051mm/h)

Intrinsic Be impurity influence on net erosion

BM11, „HDC‟: net erosion (deposition) profile at y=-187mm

Deposition of Be impurity from plasma dominates over additional Be self-sputtering

0 1 2 3 4 50

0.5

1

1.5

2

2.5

Intrinsic Be concentration

Su

rfa

ce e

volu

tio

n [

a.u

.]

BM11. HDC. 'ERO-max'

Total erosion

Deposition

Net erosion

Additional Be

self-sputtering

Deposition from

background

La

yer

evolu

tion

[m

m/h

]

Page 24: Modelling of Beryllium Erosion/Deposition and Local ... · BM11, „HDC‟: profile at y=-187mm . 12.05.2011 D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich No 11 -600

D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich 12.05.2011 No 24

Intrinsic Be impurity and sputter yields effect

BM11, „HDC‟: net erosion (deposition) profile at y=-187mm

Influence of enhanced Be re-erosion (typical ERO assumption) of is not yet studied!

LIM predictions

Sputering yield and intrinsic Be assumptions determine the outcome to a large extent!

Deposition (ERO-min +3%Be)

Layer

evolu

tion [

mm

/h]

Page 25: Modelling of Beryllium Erosion/Deposition and Local ... · BM11, „HDC‟: profile at y=-187mm . 12.05.2011 D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich No 11 -600

D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich 12.05.2011 No 25

Summary

1) ITER Organization requested a benchmark of LIM erosion-re-

deposition simulations made for steady state plasma exposure

on shaped, Be-armoured FW panels

ERO code

2) Using same input plasma parameters, shadowing geometry,

Be sputtering yields, ERO (3D) in excellent agreement with LIM

(2D)

LIM low limit for FW panel erosion lifetime reproduced

by ERO (~1500 ITER reference QDT = 10 discharges)

3) Large range of erosion lifetime dominated by uncertainties in

input plasma parameters and Be sputtering yields

inclusion of different sputtering models in ERO yields

variation of lower limit from 1100 4200 reference discharges

for BM11, HDC. This variation can also be influenced by other

assumptions e.g. intrinsic Be impurity.

Page 26: Modelling of Beryllium Erosion/Deposition and Local ... · BM11, „HDC‟: profile at y=-187mm . 12.05.2011 D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich No 11 -600

D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich 12.05.2011 No 26

To make progress now we require:

A) Experimental benchmarking of the impurity transport

codes in ITER-relevant geometry

IO planning dedicated benchmark on EAST (MAPES

manipulator with shaped tiles similar to ITER FW panel

profile

JET ILW the ideal location for a dedicated experiment

looking at erosion of Be tiles (e.g. upper part of the

vacuum vessel in the secondary X-point region)

Outlook – A

Page 27: Modelling of Beryllium Erosion/Deposition and Local ... · BM11, „HDC‟: profile at y=-187mm . 12.05.2011 D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich No 11 -600

D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich 12.05.2011 No 27

PISCES-B

Perfect for Be sputtering yields

benchmark

1. Spectroscopy

2. Target weight loss

3. Witness plate

The ERO was earlier applied for

modelling of PISCES-B

Outlook – B

B) Improvement in sputtering

yield uncertainty

model testing in PISCES-B

Page 28: Modelling of Beryllium Erosion/Deposition and Local ... · BM11, „HDC‟: profile at y=-187mm . 12.05.2011 D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich No 11 -600

D.Borodin | PFMC-13, Rosenheim | Forschungszentrum Jülich 12.05.2011 No 28

The End