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    Introduction to Cement Manufacturing

    Table of Contents

    MILL GRINDING THEORY

    1. Introduction and Overview............................................................... 3

    1.1 Introduction to Grinding............................................................ 3

    1.2 Grinding Mill Circuits................................................................ 4

    1.2.1 Open - Circuit Grinding............................................... 4

    1.2.2 Closed - Circuit Grinding............................................ 41.2.3 Principles of Closed Circuit Grinding.......................... 8

    1.3 Types of Mills............................................................................ 8

    1.3.1 Ball Mills...................................................................... 9

    1.3.2 Roller Press Mills........................................................ 9

    1.3.3 Roller or Bowl Mills..................................................... 9

    2. Internal Ball Mill Parts....................................................................... 12

    2.1 Partitions................................................................................... 122.1.1 Purpose of Partitions.................................................. 12

    2.1.2 Double Wall Diaphragm Partitions.............................. 12

    2.1.3 Operation and Repair of the Diaphragm Partition...... 16

    2.2 Liners........................................................................................ 17

    2.2.1 Purpose of Liners....................................................... 17

    2.2.2 Types of Liners............................................................ 18

    2.2.3 Liner Quality................................................................ 24

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    3. Ball Mill Grinding and Related Topics 25

    3.1 Ball Milling Process (Basics and Fundamentals)..................... 25

    3.1.1 Size Reduction............................................................ 253.1.2 Bed Movement............................................................ 26

    3.1.3 Factors Influencing Size Reduction............................ 27

    3.1.4 Mill Critical Speed....................................................... 28

    3.1.5 Ball Size and Breakage Rates.................................... 29

    3.1.6 Ball Mill Liners............................................................. 31

    3.1.7 Mill Sweep Influence on Grinding............................... 31

    3.1.8 Mill Mass Transport and Bypass................................. 33

    3.2 Grinding Media......................................................................... 393.2.1 Ball Types and Wear................................................... 39

    3.2.2 Ball Coating................................................................ 41

    3.2.3 Ball Charge Design..................................................... 41

    3.3 Ball Mill and Circuit Evaluations and Tests.............................. 52

    3.3.1 Mill Material Levels..................................................... 52

    3.3.2 Fineness Evaluation................................................... 54

    3.3.3 Mill Retention Time..................................................... 54

    3.3.4 Circulating Load.......................................................... 57

    3.4 Ball Mill Control........................................................................ 58

    3.4.1 Basic Ball Mill Control Theory.................................... 58

    3.4.2 Mill Motor kW Control................................................. 58

    3.4.3 Mill Sound Control...................................................... 61

    3.4.4 Discharge Bucket Elevator Motor kW......................... 62

    3.4.5 Rejects Flowrate......................................................... 63

    3.4.6 Rule Base Mill Control................................................ 64

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    4. Air Separators 67

    4.1 Introduction............................................................................... 67

    4.2 Types........................................................................................ 67

    4.2.1 Static Grit Separator................................................... 68

    4.2.2 Sturtevant Separators................................................. 72

    4.2.3 Raymond Separators.................................................. 77

    4.2.4 High Efficiency Separators......................................... 79

    4.3 Separator Efficiency................................................................. 87

    4.3.1 Tromp Curve............................................................... 87

    4.3.2 Rosin-Rammler Number........................................................... 92

    4.4 Mill Circulating Loads............................................................... 93

    4.4.1 Definition..................................................................... 93

    4.4.2 Circulating Load and Production Rates...................... 94

    4.4.3 L/D Ratio and Circulating Load................................... 96

    4.4.4 Circulating Load Calculations..................................... 97

    4.5 Qf/Qa Principle......................................................................... 101

    4.5.1 Bypass and Qf/Qa...................................................... 102

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    3. MILL GRINDING THEORY

    Foreword

    The text of the following section on Mill Grinding was adapted from a larger

    document entitled:

    Lafarge Mill Grinding Reference, Edition 1

    Volume 1: Practical Fundamentals of Ball Milling and Separation

    Readers wishing to study the topic in greater depth and detail are encouraged to

    obtain a copy of this and other appropriate volumes which are available from CTS

    in hard copy or on diskette for Macintosh.

    Other volumes that will be available in the Lafarge Mill Grinding Reference series

    (all of which will be available before the end of 1992) are:

    Volume 2: Auxiliary Equipment in Mill Circuits

    Volume 3: Process Methods and Theory

    Volume 4: Roller Mills and Roller Presses

    Volume 5: Wet Process Grinding

    Volumes 1 & 2 were meant to be practical reference and idea books for plant

    people; to help solve the dizzy array of problems they encountered. The next

    three texts specialize and include more theory where appropriate.

    Reader should understand that the text presented here has been edited,

    substantially, to suit the time allotted in this course "Introduction to Process

    Engineering". Realistically we cannot present and teach this segment which

    normally requires 9 working days (for Production Supervisors). Quite simply

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    there is too much material. Recognize that the topic "Mill Grinding and

    Separation" is far more complex than most of us realize and in any short course

    one can only cover the highlights which never delves into the intricacies of this

    whole field. We can only encourage you to ask questions and discover.

    Sam Fujimoto Paul Ukrainetz

    Process Engineer Process Engineer

    Lafarge Canada Inc. Lafarge Canada Inc.

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    1. Introduction and !er!ie"

    1.1 Introduction to Grinding

    In the cement industry we spend a lot of effort and money into size

    reduction at various stages in the whole process. At each of these steps

    we try to grind materials very finely and within a specific size and surface

    area range. Why? A given particle's size (or mesh) and surface area (or

    blaine) significantly influences the speed and completeness of the

    chemical reaction with that particle. For example a pound of course

    particles will have a much smaller total surface area and will react slower

    than a pound of very fine particles which would have a much larger total

    surface area. Moreover with the larger particles, there is the chance thatthe reaction will not consume the whole particle, leaving the centers

    untouched. Grinding allows the cement manufacturer to influence and

    tailor the process to achieve the desired result.

    In raw mix grinding, the particle size has an important role in the ability

    and ease to produce clinker, the clinker quality and the efficiency with

    which we accomplish this in the kiln. Most plants use a % passing 200

    mesh (or 75 micron size) target as the index to determine, whether the

    product has been properly ground. See also "The Impact of Raw Grinding

    on Kiln Operation".

    For coal mills, most plants use the 200 mesh target as well. The particle

    size in fuels has a profound effect on the flame's shape, temperature and

    stability, which ultimately influences the clinker quality.

    For cement finish mills, we use both a 325 mesh (45 micron) and blaine

    (or surface area) targets. Different targets and different emphasis are

    used depending on the type of cement being produced and the desired

    performance. For example, ASTM Type 1 cements characteristically hasvery good early day strength gains but slows down at 28-days. The 325

    mesh in cements strongly influences late day strengths and therefore most

    plants focuses on this target closely. For ASTM Type 3 we typically raise

    the blaine or surface area (the amount of super fines) in order to

    dramatically raise the 1 and 3 day strength performance.

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    In short how we grind materials at the plants at each stage plays a very

    major role in our success in producing consistently high quality cements.

    Therefore we must all understand grinding thoroughly if we are to stay in

    business. We shall begin that process here.

    1.2 Grinding Mill Circuits

    A mill circuit is a combination and proper arrangement of one or more

    grinding mills and the auxiliaries required to convey, classify and to collect

    the ground product.

    Let us first look at the Ball Mill grinding circuits. Once a circuit is defined

    as either WET or DRY grinding, it need be further defined as OPEN or

    CLOSED circuit.

    1.2.1 Open-Circuit Grinding

    Where the mill product is sent to storage silos without sizing or returning

    the oversize to the mill for further grinding. Figure 4.1.2.1 is a sketch of an

    open circuit mill. Since size reduction must be accomplished in one pass,

    open circuit mills tend to be very long.

    1.2.2 Closed-Circuit Grinding

    Where the mill product is sent to the separator and the oversize returned

    to the mill for further grinding. The oversize material can be called

    REJECTS, TAILINGS or CIRCULATING LOAD. Figure 4.1.2.2 is a sketch

    of a closed circuit mill. Figure 4.1.2.3 is a variation showing flash drying.

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    1

    2

    3

    4

    5

    1.Clin

    kersilo

    2.Gyp

    sumsilo

    3.Mill

    feed

    4.Grin

    dingmill

    5.Groundcement

    Fig.1.2.1-OpenCircuitGrinding

    Sketchofanopencircuitmill

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    Fig. 1.2.2 - Closed Circuit Grinding

    Mill

    Separator Feed (A)

    Separator

    Rejects (R)

    Fresh Feed (K)

    Fines (F)

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    Fig. 1.2.3 - Closed Circuit Grinding

    With Drying of Feed

    Mill

    Separator Feed (A)

    Separator

    Rejects (R)

    Fresh Feed (K)

    Fines (F)

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    1.2.3 #rinciples o$ %losed %ircuit Grinding

    For most raw mix and cement grinding we used closed-circuit grinding.

    In a closed circuit system, the mill product is conveyed to a classifier

    (separator) and the material coarser than the required maximum size is

    returned to the mill feed. The separator removes the fine (Finish Product),

    which is then pumped to storage and the coarse particles (rejects) are

    returned to the mill. Sufficient new feed material is added as required to

    maintain the charge within the mill at the operating capacity.

    From the cost standpoint, it is less expensive to grind in open circuit if the

    required product does not exceed approximately 3300 Blaine. The mill

    system in open circuit is simpler, but it is not as efficient as closed circuit

    grinding. In general they tend to overgrind the product to maintain a

    certain mesh target.

    In the closed circuit, the mill has a greater capacity and the finish product

    contains little or no oversize, depending upon the adjustments made to the

    separator. Also for quality control, closed circuit systems offer more

    options to adjust the product particle size distributions for optimum

    performance.

    1.3 Types of Mills

    The grinding mill is the main piece of equipment used in the total finish

    grinding system. Grinding mills can be classified into the following

    categories:

    1.3.1 Ball Mills.

    1.3.2 Roller Press Mills.

    1.3.3 Roller or Bowl Mills.

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    1.3.1 Ball Mills

    A ball mill is a cylindrical drum with varying ratio of diameter to length,

    (also called tube mills). It has either one, or two compartments,(sometimes three compt.). The grinding media are usually steel or cast

    iron balls of different diameters. Within Lafarge, the vast majority of the

    grinding is accomplished with such mills and come in a variety of

    arrangements reflecting the technology of the time and what it is supposed

    to be grinding.

    1.3.2 Roller Press Mills

    A roller press as shown on the attached diagram is nothing more than a

    pair or rolls placed in opposing position with a small gap between the rolls.

    One of the rolls is stationary (fixed roll) and on (moveable roll) is mounted

    on sliding guide ways, with hydraulic cylinders applying force toward the

    fixed roll. The moveable roll of the roller press is under constant load from

    the hydraulic cylinders. It is an old idea, re-invented for a new application.

    Thus far installations have been applied to existing ball mills, to

    dramatically improve grinding rates. However they are difficult to balance

    and can be expensive to maintain.

    1.3.3 Roller or Bowl Mills

    Roller Mills consist of wheels (or rollers) mounted above a rotating table.

    Fresh feed is dropped into the table is ground between the wheels and

    table as the table turns. Often these mills are air swept and usually come

    with there own built in separator. Many of the installations in North

    America are for grinding coal, with a few grinding raw materials (eg.

    Balcones, Davenport and Demopolis). Installations are usually compactand are ideal for relatively soft materials, but normally have complex hot

    gas circuits associated with them.

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    Roller Press Configuration

    The basic configuration of the roller press consists of:

    2 rollers

    Frame

    Roller support bearings

    Hydraulic cylinders

    Hydraulic accumulator

    Moveable roll Fixed roll

    Tension member

    Frameend

    piece

    Tensionmember

    Bearing blocks

    Hydrauliccylinder

    Hydraulicaccumulator

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    Classifier shaftDriven byVariable speed drive

    ProductDischarge port

    Raw material

    Classifier

    Blade

    Totally enclosedhousing

    Loading rod(one of three)

    Gas intake port

    Hot gas(Reclaimed from kilnpreheater or cooler)

    Hydraulic loadingcylinder (one of three)

    Feed spout

    Roller support

    Roller housing

    Grinding roller

    Ported air ringGas plenium

    Wearing ring

    Rotating grinding table

    High speed shaft

    Speed reducer

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    2. Internal Ball Mill #arts

    2.1 Partitions

    2.1.1 Purpose of Partitions

    Their primary purpose is to separate the different sizes of the ball charge

    in order to roughly match the ball size to particle size being ground. For

    example, many open circuit mills were originally supplied with three

    compartments. However most compartmented mills in Lafarge today have

    just two. The material being ground in the first compartment passes

    through the grate slots in the partition to enter the second compartment,

    then leaves the mill through the discharge grate.

    A secondary purpose for a double intermediate partition is to retain the

    insufficiently ground material in the first compartment, by regulating the

    material level in it. Properly designed the partition determines the flow rate

    from one compartment to the next and thereby helps to maintain a good

    filling ratio.

    Of course it also roughly separates and retains the large material particles

    in the first compartment.

    2.1.2 Double Wall Diaphragm Partitions

    These partitions are equipped with lifters which regulate the flow rate of

    the material from the first to the second compartment. The back plates

    are blind.

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    Material

    Discharged

    Airfow

    As mill rotates, material is

    lited and dropped through

    the opening in the center hub.

    In the lower

    hal, material is

    pushed through

    the s lots, lling

    the empty liter

    chamber.

    Feed End View of Partition

    Slotted Grate Segment

    enter !ub or one

    Air Sweep enter ScreenSide View

    "lind #late

    $iter or Scoop

    Standard Liftered Partitions

    These are common and mostly suffer from the same problem. The

    porosity of the first compartment charge is high and with a fully-liftered

    partition (lifters right to the shell) the material filling ratio (U) is pulled down

    well below 0.9 and ball wear is accelerated. Usually it is below the 0.6

    point at which material breakage rates are reduced. (In other words the

    voids are too empty - see also section on Material Filling Ratio.) This is

    evidenced by no material visible on the balls at the partition, sometimes

    one must dig 18" or more to 'hit' cement.

    The French have attempted to overcome this through ball charge

    modifications (more smaller balls) and reducing the slot size. At

    Demopolis large holes have been cut in the lifters to reduce their

    efficiency. Neither method has been highly successful. Changing slot size

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    and cutting lifters are irreversible and plants have experienced very limited

    success. Adding small balls to increase the filling ratio is O.K. until the

    circulating load or material grindability changes, at which time you must

    start over.

    Other plants have installed partitions which are multi-segmented. These

    allow you to replace slotted segments with blind sections on the inlet side

    and thereby controlling the total slot area. The Group does not have a lot

    of experience with this type but it appears difficult to make changes and it

    also chokes off mill sweep.

    Adjustable Double Wall Diaphragm Partitions

    This is a double wall partition with adjustable scoops developed by

    SLEGTEN, and later offered by other manufacturers.

    The grinding efficiency of a mill depends directly on the time of retention of

    the material within the ball charge. This regulating partition thus permits

    adjustment of the material level in the first compartment by using scoops

    located between the slotted grates and the blind grates on the second

    compartment side.

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    SLEGTEN DOUBLE - DIAPHRAGM PARTITION

    Actual installations of the SLEGTEN regulating diaphragm on finish mills in

    the Group are:

    Boussens

    Val d'Azergues

    Port-la-Nouvelle

    Contes

    Le Havre

    Alpena

    Balcones

    Bath

    Whitehall

    Wossingen

    L.F.I. at Dunkerque, Fos, and Norfolk

    The Group strongly recommends SLEGTEN diaphragm partitions over all

    others. In addition, the SLEGTEN diaphragm partition is mechanically

    very well designed in that it has a simple structure, well adapted to

    stresses caused by the rotation of the mill shell, especially in large

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    diameter mills. However, recognize that the installation of a regulating

    diaphragm requires a long commissioning period, systematically making

    adjustments of the grinding charge and partition to see an improvement.

    2.1.3 Operation and Repair of the Diaphragm Partition

    The diaphragm and grates are a rather weak (perhaps the weakest)

    element inside the mill. If they are in poor shape, the mill will function

    poorly.

    Slots in bad shape block easily.

    High pressure loss causes poor ventilation.

    Holes, excessive play between the plates, worn and enlarged

    slots, all pass clinker particles (2, 5, 10 mm) which prevent the

    efficient action of the second compartment ball charge.

    It is therefore necessary to conduct a detailed inspection every time the

    mill is entered.

    The proper operation of the mill partition can be better understood by thefollowing two process elements:

    Fineness curves of samples taken along the ball charge,

    (granulometry). If they show too many large particles (2, 5, 10

    mm) in the second chamber, the partition needs attention.

    The level of the material in the first compartment. A well

    adjusted partition will keep a level of material equal to the level

    of the balls (even slightly higher) in the first compartment.

    If this is not the case, then you must play with:

    the position of the scoops, if installed

    the dimensions of the lifters, if possible

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    the number and/or the dimensions of the slots

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    2.2 &iners

    2.2.1 Purpose of Liners

    The purpose of mill liners is not only to protect the mill shell but they must

    also "grip" the grinding balls and release them at the right height to obtain

    the cascading or tumbling that maximizes the grinding rate. If the balls are

    carried too high they will get thrown against the mill liners on the opposite

    side where the balls or liners may break. In addition, the grinding action

    could be limited to the toe of the mill load. If the balls are not carried high

    enough then the impact energies while tumbling are greatly reduced, thus

    retarding the grinding action. In addition, recognize that some sliding

    contact will occur which increases liner wear.

    Many of us lose sight of the fact that the balls should not be sliding as they

    are being lifted up. Sliding between balls and liners increases wear and

    can lead to premature failures. Evidence of this can be seen in the form of

    "racing". Racing are the grooves or rings worn into liners and is a result of

    sliding contact between balls and liners. Excessive racing will in turn

    promote more sliding contact and thus accelerating the whole process.

    Recognize though that as the liner rotates around and enters into the toe

    of the ball charge some sliding contact will occur until the liner has gripped

    the ball charge, to lift it. Some manufacturers take advantage of this and

    market grooved liners which are designed to do extra grinding in the

    grooves themselves as the liners enter the ball charge. Examples are

    Manoir, Armco-Delloye, and Owen Corp.

    Liner design is critical to good grinding action and wear life. Careful

    consideration must also be given to ball charge design, material, material

    load and the grinding action required in that compartment in order to

    design the appropriate liner.

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    2.2.2 T'pes o$ &iners

    A) First Compartment

    The work done in this compartment is done by impact, thus some call this

    the crushing compartment. Therefore the liners must be lifting and are

    present in several forms, block, wedge bar, Lorraine and Duo-lift. Their

    job is simple. Lift the balls high to eject them from the charge so they fall

    farther and hit harder. This is shown in the following drawing showing the

    detachment point of the balls from the lining for a 0.75 m test mill, 75%

    critical speed, 25% volume load, 30 mm balls, material filling ratio 1.0,

    feed < 3.15 mm.

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    $iters

    %&'()Smooth

    %&*()

    Groo+ed

    %&()

    Therefore saturating is supported and the fracture mechanism enhanced.

    This means that breakage rates will be shifted towards the coarser particle

    sizes, at the expense of breakage rates on the finer ones.

    This is clearly shown by tests conducted by Rogers et al. ("..Effect of Liner

    Design on Performance of a...Wet Ball Mill") on a 0.91 m mill. The

    lifters move the peak breakage point to a coarser size, from 1.5 to 4 mm.

    The breakage of finer material is much lower with lifters than with

    corrugated lines. Therefore lifters don't belong in the second

    compartment.

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    .' ' '(

    .'

    '

    '(

    $ining -ype +s "reaage

    Material #article Diameter /mm0

    Sp

    ecifc

    "rea.age1

    ate,

    Si/'2m

    in0

    orrugated

    Spiral Angular

    Lifters

    Thus this is the type of liner which is the first choice many plants,

    (sometimes called shipload or wedge or stepped liner).

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    (!en so) t*ere are ot*er t'pes still in use in +ort* A,erica.

    For wedge bar, lorraine, block type liners the ratio of height to spacing in

    between (usually matches bolting patterns) is critical to achieving the

    correct trajectories. Surprisingly many suppliers do not have sophisticated

    methods to determine this. However this group of liner types seems to be

    ideal in SAG mills used in mining or for mills with very low % critical speed.

    Most single wave liners generally had good lift characteristics, however on

    the down slope side, media tended to slide which vastly accelerates wear.

    The new DuoLift liner developed by SLEGTEN could provide an

    interesting results.

    The Duolift is especially designed to maintain the same lift characteristics

    through 90% of it wear life by controlling the wear pattern. In doing so

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    Slegten claims that the absorbed power and grinding efficiency will remain

    more consistent, and wear life greatly extended. Presently this liner is

    being tried in Demopolis and Whitehall.

    B) Second Compartment

    Corrugated/Wave Linings

    These are the standard linings in North America that original come with

    most mills. As with lifters they come in all versions and perversions, wave,

    simple wave, double wave, etc. Their purpose is to assist in the cascading

    action of the balls. Therefore they assist in the attrition mechanisms,chipping and abrasion, on smaller sized particles. This means they do not

    belong in a first compartment, but rather in the second. They are,

    however, not the recommended second compartment liners.

    Classifying Linings

    This type of liner has several important advantages:

    ball size matches particle size along the mill;

    reverse and double-reverse classification is avoided.

    They have also been shown to increase material transport opposed to a

    non-classified charge. This is due to the increased porosity (big balls) in

    the areas where the particles are larger and less 'fluid'. This means it is

    theoretically possible to reduce the final ball size in the mill in comparison

    to an unclassified charge for better 'fit' between balls and material without

    material transport problems.

    This fit is obviously the best when 'plug-flow' is present. This means that

    material flows through the mill as though in a pipeline and isn't mixed too

    much. The longer L/D in the second compartment gives RTD's (residence

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    time distributions) which are closer to the plug flow limit than the short L/D

    first compartment.

    The advantages of a classified charge are greatest when it allows a widerange of ball sizes to be used. The fact that only 3 to 4 ball sizes are

    present in the more mixed first compartment reduces to benefits of this

    lining in that area.

    For each liner step for classifying liners in large mills over 4 metres (13

    feet) in diameter, use two liners per step, lengthwise of the mill.

    Large media, 50 to 70 mm (2 to 2 3/4 in) diameter, can be put in the samecompartment as small media, as small as 15 mm (5/8 in) diameter in an

    open-circuit mill. In such a compartment, the grinding charge can accept

    a very coarse feed. Classifying liners permit a deteriorating operation in

    the first compartment, or in the diaphragm partition. Furthermore, they

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    allow a better overall grinding performance in a mill whose partition

    diaphragm location is not ideal.

    Except in special cases, which must be examined with care, classifyinglinings are recommended for the second compartment, and long single-

    compartment mills with lower circulating loads, but not for first

    compartments.

    2.2.3 Liner Quality

    In North America, most liners today are white cast irons with high chrome

    contents although there seems to be a general movement to high carbon

    tool steel base. Different alloying elements as well as carbon and chrome

    contents are used, we suspect, to achieve desired properties and

    performance, but within the confines of the technology used at different

    foundries. This appears to vary even within the same company. The

    observation is unconfirmed mainly because none of the suppliers wish to

    divulge trade secrets, however none of our experience disputes this.

    In general, all liners attempt to produce grains of chromium carbide, which

    are extremely abrasion resistant, held in a martensitic steel (the hardestform of steel) matrix. Also the best performing liners generally have very

    fine grain microstructures (achieved through heat treatment and proper

    quenching) which increases overall hardness and abrasion resistance. By

    varying the carbide content, alloying elements, and microstructures

    suppliers can alter the liner performance with respect to abrasion and

    impact resistance to suit the application.

    However, foundry quality control is vital to good liner performance. This

    seems to vary more widely in North America than in Europe; to the pointwhere some plants will specify the foundry at which the liner is to be cast.

    CTS