material safety data sheet - farnell element14 · trade name: wlk (hardening agent) ......

Fischer Elektronik GmbH & Co. KG • Postfach 1590 • Nottebohmstr. 28 • D-58511 Lüdenscheid • Phone 02351/435-0

Material Safety Data Sheet in accordance with 91/155/EEC of 12

1.) Material / preparation and company name Product details Trade name: WLK (hardening agent) Supplier: Fischer Elektronik GmbH & Co. KG Postfach 1590 • D-58465 Lüdenscheid Nottebohmstr. 28 • 58511 Lüdenscheid Phone: + 49 (0) 2351/435-0 / Fax. + 49 (0) 2351/45754 Inquiry division: Technical Service Emergency service: National Information Centre, Berlin Emergency call: + 49 (0)30 19240 2.) Composition / Details of components Chemical analysis (recipe) Description: Aliphatic polyamine, Hazardous ingredients: CAS-no.: 4246-51-9 Designation according to EC Directive: 4,7,10-Trioxa-1, 13-tridecandiamin Content: 100 Unit: Weight % Code.: C R text: 34 Additional 4,7,10-Trioxa-1,13-tridecandiamine ( EINECS 224-207-2, UN 2735, information: RTECS ID 6475000, BRN 1760709 )


Material Safety Data Sheet in accordance with 91/155/EEC

Trade name: WLK (hardening agent) of 12 3.) Potential hazards Definition of hazard: caustic Special information on the danger to human beings and to the environment: Causes burns to eyes,

respiratory tract and skin. The product is incompatible with water 4.) First aid General information After inhaling: Breath fresh air, respiration if necessary. Seek medical assistance

immediately. Caution: Danger of burns After contact Rinse with plenty of water, remove contaminated clothing. Wash carefully with the skin: using water and soap. Avoid rubbing the skin. Contaminated clothing and shoes must be disposed of. After contact Keep eye lids open and rinse for at least 15 minutes with plenty of water. with eyes: Seek immediately advice of an eye specialist. Protect the eye which has not been in contact with the agent. After swallowing: Do not initiate vomiting. The patient should drink plenty of water, if

conscious. Get medical assistance immediately. Information for the Symptomatic treatment, see also safety specification sheet. physician: 5.) Fire fighting measures Suitable fire Carbon dioxide, extinguishing powder, foam (resistant to alcohol), extinguishers: water spray jet Extinguishers which are not recommended for safety reasons: N/A Particular danger from the agent, its products of combustion or gases produced: Carbon monoxide (CO), carbon dioxide (CO2), nitrogen oxides, pyrolysis products (smoke). In case of fire, closed containers may burst. Cool with water. Special protective equipment: protective clothing including a breathing mask with it's own air

supply.



Trade name: WLK (hardening agent) of 12 6.) Action to be taken in the event of accidental leakage Precautionary measures for personnel: Ventilate the area or suck the air off using mobile

equipment. Wipe or absorb the liquid using a 'vermiculite' type of material. Use protective clothing including goggles, gloves and shoes.

Precautionary measures for Seal off the area, close the source of the leak, if possible. the environment: Ventilate and suck the air off. Prevent the liquid from entering sewage systems, rivers, lakes and soil. Cleaning, removal: Collect spillage, remove residue using an absorbent.

Clean with soapy water. Collect the fluid in containers provided for this purpose.

Additional information: 7.) Handling and storage Handling Information on safe handling: Protection against fire and explosion: In the event of fire, containers should be cooled with

water! Storage Requirements for storage areas Store containers in a cool, dry and ventilated area. and containers: Containers must be tightly closed. Keep them off flames and away from sources of heat. Storage together with other materials: Do not store together with acids, oxydisers and

alkylating agents. For more details, see VCI directive. Further instructions on storage conditions: Storage class: 8; caustic substances (directive for storage together with

VCI chemicals)



Trade name: WLK (hardening agent) of 12 8.) Exposure limits and personal protective equipment Additional information for technical equipment: Ensure adequate ventilation and exhaust,

especially in case of high temperatures. Components, workplace-related limiting values which must be monitored: CAS-Nr. Designation Type Value Remark Unit The quoted values have been taken from the lists applicable at the time of preparation of the present specification sheet (e.g. TRGS 900 for the Federal Republic of Germany). Sp.kat = Max. limitation category. Additional information: The substance is not quoted in the list of limit values TRGS 90.

However, in view of its properties, concentration at the workplace should be minimised. Aerosol formation should be avoided.

Personal protective clothing: General protective and hygienic measures: Wash before breaks and after finishing work. Breathing mask: Breathing mask with it's own air supply is recommended if ventilation is

poor Gloves: Wear PVC gloves. Eye protection: Wear face protection and tightly fitting goggles. Body protection: Wear protective clothing. An emergency shower should be available.



Trade name: WLK (hardening agent) of 12 9.) Physical and chemical properties Form: liquid Odour: like amine Colour: amber Change of condition Values Unit Method (67/548) Type (1) Melting point/melting range: not determined Type (2) Boiling point/boiling range: 180 ° C and. 146°C / 4mm Hg, respectively Flash point: 138 °C Inflammability (solid, gaseous): °C Ignition temperature: not determined Self-ignition: The product is not self-igniting Explosion hazard: The product is not explosive Explosion limits: UEG OEG Steam pressure at (T1) 20 °C < 0,001 mmHg Density at (T1) 20 °C 1.0 cm³ Solubility: soluble T= °C in water T= °C mg/L ph value: T=20 °C 9.4 (alkaline) Distribution coefficient n -C8H17OH/H2O comp.: log Pow Viscosity dynamic: not determined Solvent content: 100 % Solvent separation test: no measurable separating layer Other information: no information



Trade name: WLK (hardening agent) of 12 10.) Stability and reactivity Conditions to be avoided: Heat, sources of ignition Materials to be avoided: Oxidisers, acids and alkylation agents Hazardous decomposition products: Carbon monoxide, carbon dioxide, nitrogen oxides, and other

organic decomposition products Additional information: When the product is used as intended, hazardous

decomposition products or undesirable reactions will not occur. Make sure that the products is handled and stored in an appropriate manner.

11.) Information on toxic effects Acute toxicity Values LD/LC50- relevant for classification: Type Values Species Method oral 4920 mg/kg rat LD50 dermal 2500 mg/kg rabbit LD50 Specific symptoms in animal experiments: no data available Primary cauterising / caustic effect: Causes burns to eyes, skin and respiratory tract. Sensitising effect: Respiratory tract is affected! Other information (concerning experimental toxicology): no indication.



Trade name: WLK (hardening agent) of 12 Subacute to chronic toxicity Investigations Species max. dose mg/kg Method Result: Experience with man: When in contact with the eyes, the product causes damage to the cornea and

burns. Permanent opacity or blindness may result. On the skin, the product may cause severe burns and blisters. Vapours or aerosols inhaled may cauterise the respiratory tract and cause nausea and headaches. Furthermore, symptoms such as tightness of the chest, asthma-like symptoms and difficulties in breathing may occur. The product is detrimental to health when swallowed and may cause burns in the mouth and in the gastro-intestinal tract. The product may aggravate existing cauterised areas of skin, eyes and respiratory tract.

Additional toxicological information (especially for preparation): none 12.) Ecological aspects: (If the degree of harm which the mixture causes to the environment is not known, the effects of individual components which are classified as damaging to the environment may be described). Elimination of the product (persistency and degradability) Method: Analyses: Degree of elimination: Classification: Evaluation text: Other information: none



Trade name: WLK (hardening agent) of 12 Behaviour in environmental compartments Component: Mobility and biological accumulation potential: Other information: none Ecotoxic effects aquatic toxicity: Kind of test Effective concentration Methode Evaluation Remark: no indication Behaviour in sewage treatment plants: Kind of test Effective concentration Method Evaluation Remark: no indication respiration inh., commun. activated sludge EC 20 = mg/l acc. to ISO 8192 B



Trade name: WLK (hardening agent) of 12 Other information: Other ecological information CSB value: mg/g Remark: no indication BSB5 value: mg/g Remark: no indication AOX information: Remark: no indication Contains the following heavy metals and bonds as per EC Directive no. 76/464/ EEC, as provided for in the recipe General information: Prevent it from entering rivers and lakes, sewage systems or soil. Hazard to

drinking water. The product is incompatible with water. 13.) Disposal of the product Product: Recommendation: Dispose of it in accordance with local regulations. Do not dispose of it together

with household rubbish. Waste subject to supervision, in accordance with § 41 of the law on recirculation of materials and waste (Kreislaufwirtschafts-/ Abfallgesetz).

Classification according to Directive 75/442/EEC: EWC code: EW designation: 070104 Other organic solvents Packaging: Cured material can be disposed into normal household waste in accordance with local legal regulations ( EWG-code: 200301 ) Uncleaned packages Recommendation: Packages must be completely emptied. Cleaned packages may be reused / recycled. Recommended cleaning agents: no indication



Trade name: WLK (hardening agent) of 12 14.) Transport regulations Road and rail transport ADR/RID nd GGVS/GGVE (international / national) Class as perADR/RID-GGVS/E: 8 Number/letter: 53c Warning sign: Hazard no.: 8 UN no.: 2735 Designation of goods: 2735 polyamine, liquid, caustic, n.o.s., 4,7,10-Trioxa- 1,13-tridecandiamin Remarks : Danger sheet no. 8 Inland sea transport ADN/ADR Class as per ADN/R: 8 Number/letter: 53 c Category: Designation of goods: 2735 polyamine, liquid, caustic, n.o.s., 4,7,10-Trioxa- 1,13-tridecandiamin Remark: Danger sheet no 8 Sea transport IMDG/GGVSee Class as per MDG/GGVSee: 8 UN no.: 2735 PG: III EMS no.: 8-05 MFAG: 320 Marine pollutant: yes, aliph. polyamine Correct technical designation: Polyalkylamines, liquid, corrosive, n.o.s., 4,7,10-Trioxa- 1,13-tridecanediamine Remark: Loading category A; IMDG code page 8103.



Trade name: WLK (hardening agent) of 12 Air transport ICAO-TI and IATA-DGR Class as per ICAO/IATA: 8 UN/ID no.: 2735 Packaging group: III Correct shipping designation: Polyamines, liquid, corrosive, n.o.s. (4,7,10-Trioxa- 1,13-tridecanediamine ) Remark: CAO 818, PAX 820 Transport/additional information Delivery by post is permitted. When using the designation 2801a, the product is completely

exempted from the provisions of appendices A and B of ADR. (Limited quantities) 15.) Prescriptions Marking in accordance with the EEC regulations /guideline ( GefStoffV ) Code letter and description of hazard: C, caustic Hazardous component(s) to be indicated on the label: 4,7,10-Trioxa-1,13-tridecandiamine R text: 34 S text: 26/36/37/39/45 Special marking of specific recipes: none (as per appendix II of the directive for preparation 88/379/EEC)


Material -Safety Data Sheet in accordance with 91/155/EEC

Trade name: WLK (hardening agent) of 12 National prescriptions Additional classification according to GefStoffV appendix II no.: none (only applicable in case of deviation from the EC classification) Information on restrictions imposed on occupation: see § 15b,c GefStoffV, pregnant women and young persons Prescriptions for cases of emergency: no indication Classification to VbF: N/A Protection against emission (TA Air): no indication Class: Number: Percentage m%: (in the case of liquids) Degree of water contamination: 2 (harmful to water, self-assessment) Other prescriptions, restrictions and bans: VBG 1; ZH 1/24.2, 132; TRGS 440,555; WHG TRGS 200, Classification of materials, recipes and products TRGS 220, Safety specification sheet for hazardous materials and recipes TRGS 900, Limit values in the atmosphere at the workplace 'Air limit values' Prescription on hazardous goods Law on recirculation of materials and waste (Kreislaufwirtschafts-/ Abfallgesetz) 16.) Other The information contained in this safety specification sheet reflects our present technical

knowledge and satisfies legal requirements at national and EC level. The users' working conditions, however, are not known to us and are beyond our control. Users are responsible for observing all applicable legal provisions. The information contained in this specification sheet describes the safety requirements applicable to our product and implies no guarantee of the properties of the product.

Revised: 2004-01-15 Printed: 2004-01-15

material safety data sheet - farnell element14 · trade name: wlk (hardening agent) ......

Documents