material. • to use temperature as a measure of hotness and … · 2020-04-08 · k. heat and...

38
K. Heat and Temperature Chapter Outline 1. Temperature and Thermal Equilibrium 2. Thermometers and Temperature Scales 3. Thermal Expansion 4. Quantity of Heat 2010 Herbert B. Domingo 5. Calorimetry and Phase Changes K. Heat and Temperature 1. Temperature & Thermal Equilibrium Concept of temperature rooted in qualitative ideas of “hot” and “cold” based on sense of touch. Many properties of matter we can measure depend on temperature . Temperature is also related to 2010 Herbert B. Domingo Temperature is also related to kinetic energies of molecules of material. To use temperature as a measure of hotness and coldness, we need to construct a temperature scale .

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Page 1: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

Ch

ap

ter

Ou

tlin

e

1.

Tem

pera

ture

and T

herm

al E

quili

brium

2.

Therm

om

ete

rs a

nd T

em

pera

ture

Scale

s

3.

Therm

al E

xpansio

n

4.

Quantity

of H

eat

�2

01

0 H

erb

ert

B. D

om

ing

o

5.

Calo

rim

etr

yand P

hase C

hanges

K. H

eat

an

d T

em

pera

ture

1. T

em

pe

ratu

re &

Th

erm

al

Eq

uil

ibri

um

•C

on

ce

pt o

f te

mp

era

ture

ro

ote

d in

q

ua

lita

tive

id

ea

s o

f “h

ot”

an

d “

co

ld”

ba

se

d o

n s

en

se

of

tou

ch

.

•M

an

y p

rop

ert

ies o

f m

atte

r w

e c

an

m

ea

su

re d

ep

en

d o

n te

mp

era

ture

.

•T

em

pe

ratu

re is a

lso

re

late

d to

�2

01

0 H

erb

ert

B. D

om

ing

o

•T

em

pe

ratu

re is a

lso

re

late

d to

kin

etic e

ne

rgie

so

f m

ole

cu

les o

f m

ate

ria

l.

•T

o u

se

te

mp

era

ture

as a

me

asu

re

of h

otn

ess a

nd

co

ldn

ess, w

e n

ee

d

to c

on

str

uct

a t

em

pe

ratu

re s

ca

le.

Page 2: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

1. T

em

pe

ratu

re &

Th

erm

al

Eq

uil

ibri

um

Th

erm

om

ete

r

•F

irst,

se

lect a

ny m

ea

su

rab

le p

rop

ert

y o

f a

syste

m

tha

t va

rie

s w

ith

its

“h

otn

ess”

an

d “

co

ldn

ess”.

•E

xa

mp

les: th

e le

ng

th o

f a

liq

uid

(m

erc

ury

, e

tha

no

l)

in a

tu

be

, p

ressu

re o

f g

as a

nd

th

e e

lectr

ica

l

�2

01

0 H

erb

ert

B. D

om

ing

o

in a

tu

be

, p

ressu

re o

f g

as a

nd

th

e e

lectr

ica

l

resis

tan

ce

of

a

co

nd

uctin

g w

ire

.

•E

ach

of th

e a

bo

ve

ca

n

be

use

d t

o m

ake

a th

erm

om

ete

r.

K. H

eat

an

d T

em

pera

ture

1. T

em

pe

ratu

re &

Th

erm

al

Eq

uil

ibri

um

Th

erm

al E

qu

ilib

riu

m

•W

e u

se

a t

he

rmo

me

ter

to m

ea

su

re t

he

te

mp

era

ture

of a

bo

dy.

•A

t th

e p

oin

t w

he

re t

he

re

ad

ing

on

th

e t

em

pe

ratu

re

rea

ch

es a

ste

ad

y v

alu

e, th

e c

on

ditio

n o

f th

erm

al

�2

01

0 H

erb

ert

B. D

om

ing

o

rea

ch

es a

ste

ad

y v

alu

e, th

e c

on

ditio

n o

f th

erm

al

eq

uili

bri

um

ha

s o

ccu

rre

d.

Insu

lato

r

•A

n in

su

lato

r re

du

ce

sth

e e

xch

an

ge

of

he

at

be

twe

en

tw

o s

yste

ms.

•E

xa

mp

les o

f in

su

lato

rs: w

oo

d,

pla

stic fo

am

, o

r

fib

erg

lass.

Page 3: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

1. T

em

pe

ratu

re &

Th

erm

al

Eq

uil

ibri

um

Insu

lato

r

•A

n id

ea

l in

su

lato

ris

a m

ate

ria

l th

at

pe

rmits n

o

inte

ractio

n a

t a

ll b

etw

ee

n t

wo

syste

ms, th

us

pre

ve

ntin

g th

erm

al e

qu

ilib

riu

m f

rom

be

ing

re

ach

ed

.

Ze

roth

La

w o

f T

he

rmo

dyn

am

ics

�2

01

0 H

erb

ert

B. D

om

ing

o

Ze

roth

La

w o

f T

he

rmo

dyn

am

ics

•It

is a

n im

po

rta

nt

pro

pe

rty

of th

erm

al e

qu

ilib

riu

m

•C

on

sid

er

thre

e s

yste

ms:

A,

Ba

nd

C.

K. H

eat

an

d T

em

pera

ture

1. T

em

pe

ratu

re &

Th

erm

al

Eq

uil

ibri

um

Ze

roth

La

w o

f T

he

rmo

dyn

am

ics

•S

yste

m A

an

d B

initia

lly s

ep

ara

ted

by id

ea

l

insu

latin

g w

all,

bu

t w

e le

t C

inte

ract w

ith

Aa

nd

B.

•T

he

id

ea

l in

su

latin

g w

all

is th

en

pla

ce

d b

etw

ee

n C

an

d A

an

d B

an

d a

co

nd

uctin

g w

all

is p

lace

d

�2

01

0 H

erb

ert

B. D

om

ing

o

an

d A

an

d B

an

d a

co

nd

uctin

g w

all

is p

lace

d

be

twe

en

Aa

nd

Bto

le

t th

em

in

tera

ct.

•E

xp

eri

me

nt

sh

ow

s t

ha

t n

oth

ing

ha

pp

en

s!

•T

ha

t is

, th

ere

is n

o a

dd

itio

na

l ch

an

ge

s t

o A

an

d B

.

•C

on

clu

sio

n:

If C

is in

itia

lly in

th

erm

al e

qu

ilib

riu

m

with

bo

th A

an

d B

, th

en

Aa

nd

Ba

re a

lso

in

th

erm

al

eq

uili

bri

um

with

ea

ch

oth

er.

Page 4: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

1. T

em

pe

ratu

re &

Th

erm

al

Eq

uil

ibri

um

Ze

roth

La

w o

f T

he

rmo

dyn

am

ics

•S

up

po

se

we

re

pla

ce

Cw

ith

a t

he

rmo

me

ter

an

d is in

co

nta

ct w

ith

Aa

nd

B.

•W

he

n th

erm

om

ete

r re

ach

es a

sta

ble

va

lue

, b

oth

A

an

d B

ha

s t

he

sa

me

te

mp

era

ture

.

�2

01

0 H

erb

ert

B. D

om

ing

o

an

d B

ha

s t

he

sa

me

te

mp

era

ture

.

•C

on

clu

sio

n:

Tw

o s

yste

ms a

re in

th

erm

al

eq

uili

bri

um

if a

nd

on

ly if th

ey h

ave

th

e s

am

e

tem

pe

ratu

re.

K. H

eat

an

d T

em

pera

ture

2. T

he

rmo

me

ters

an

d T

em

pe

ratu

re S

ca

les

Ce

lsiu

s te

mp

era

ture

sca

le/L

iqu

id-i

n-t

ub

e

the

rmo

me

ter

•T

o m

ake

th

e liq

uid

-in

-tu

be

de

vic

e in

to a

use

ful

the

rmo

me

ter,

we

ne

ed

to

ma

rk a

sca

le o

n t

he

tu

be

wa

ll w

ith

nu

mb

ers

on

it.

•T

he

nu

mb

ers

are

arb

itra

ry a

nd

ma

ny n

um

be

r

�2

01

0 H

erb

ert

B. D

om

ing

o

•T

he

nu

mb

ers

are

arb

itra

ry a

nd

ma

ny n

um

be

r sch

em

es w

ere

use

d in

th

e p

ast.

•S

up

po

se

we

la

be

l th

e t

he

rmo

me

ter’

s liq

uid

le

ve

l a

t th

e f

ree

zin

g t

em

pe

ratu

re o

f p

ure

wa

ter

“ze

ro”

an

d th

e le

ve

l a

t b

oili

ng

te

mp

era

ture

“1

00

”, a

nd

d

ivid

e th

e d

ista

nce

be

twe

en

th

e t

wo

pts

in

to 1

00

e

qu

al in

terv

als

ca

lled

de

gre

es.

Page 5: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

2. T

he

rmo

me

ters

an

d T

em

pe

ratu

re S

ca

les

Ce

lsiu

s te

mp

era

ture

sca

le/L

iqu

id-i

n-t

ub

e

the

rmo

me

ter

•W

e g

et a

Ce

lsiu

s t

em

pe

ratu

re s

ca

le (

form

erl

y

ca

lled

th

e c

en

tig

rad

e s

ca

le in

En

glis

h-s

pe

akin

g

co

un

trie

s).

�2

01

0 H

erb

ert

B. D

om

ing

o

•C

els

ius te

mp

era

ture

fo

r a

sta

te c

old

er

tha

n

fre

ezin

g w

ate

r is

a n

eg

ative

nu

mb

er.

K. H

eat

an

d T

em

pera

ture

2. T

he

rmo

me

ters

an

d T

em

pe

ratu

re S

ca

les

Bim

eta

llic s

trip

th

erm

om

ete

r

•A

no

the

r co

mm

on

th

erm

om

ete

r

use

s a

bim

eta

llic s

trip

, m

ad

e b

y

bo

nd

ing

tw

o d

iffe

ren

t m

eta

ls

tog

eth

er.

�2

01

0 H

erb

ert

B. D

om

ing

o

•W

he

n te

mp

era

ture

of co

mp

osite

str

ip in

cre

ase

s, o

ne

me

tal e

xp

an

ds

mo

re t

ha

n t

he

oth

er

an

d t

he

str

ip

be

nd

s.

•A

s s

ho

wn

th

e p

oin

ter

rota

tes in

resp

on

se

to

te

mp

era

ture

ch

an

ge

s.

Page 6: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

2. T

he

rmo

me

ters

an

d T

em

pe

ratu

re S

ca

les

Re

sis

tan

ce

th

erm

om

ete

r

•T

he

ch

an

gin

g e

lectr

ica

l re

sis

tan

ce

of a

co

il o

f fin

e

wir

e, a

ca

rbo

n c

ylin

de

r, o

r a

ge

rma

niu

m c

rysta

l is

m

ea

su

red

.

•S

ince

re

sis

tan

ce

ca

n b

e m

ea

su

red

ve

ry p

recis

ely

, re

sis

tan

ce

th

erm

om

ete

rs a

re m

ore

pre

cis

e th

an

�2

01

0 H

erb

ert

B. D

om

ing

o

resis

tan

ce

th

erm

om

ete

rs a

re m

ore

pre

cis

e th

an

o

the

r ty

pe

s o

f th

erm

om

ete

rs.

K. H

eat

an

d T

em

pera

ture

2. T

he

rmo

me

ters

an

d T

em

pe

ratu

re S

ca

les

Th

erm

op

ile

•A

n e

ar

the

rmo

me

ter

is a

typ

e o

f d

evic

e c

alle

d a

the

rmo

pile

.

•It

me

asu

res t

he

am

ou

nt

of in

fra

red

ra

dia

tio

n

em

itte

d b

y t

he

ea

rdru

m,

wh

ich

in

dic

ate

s th

e

�2

01

0 H

erb

ert

B. D

om

ing

o

em

itte

d b

y t

he

ea

rdru

m,

wh

ich

in

dic

ate

s th

e

ea

rdru

m’s

te

mp

era

ture

.

•A

dva

nta

ge

of

this

te

ch

niq

ue

is it

do

es n

ot

req

uir

e

a p

hysic

al co

nta

ct o

f th

e t

he

rmo

me

ter

with

th

e

ea

rdru

m.

Page 7: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

2. T

he

rmo

me

ters

an

d T

em

pe

ratu

re S

ca

les

Fa

hre

nh

eit t

em

pe

ratu

re s

ca

le

•T

his

te

mp

era

ture

sca

le is u

se

d in

da

ily life

in

th

e

Un

ite

d S

tate

s.

•T

he

fre

ezin

g t

em

pe

ratu

re o

f w

ate

r is

32

°F.

•T

he

bo

ilin

g t

em

pe

ratu

re o

f w

ate

r is

21

2°F

.

�2

01

0 H

erb

ert

B. D

om

ing

o

•T

he

bo

ilin

g t

em

pe

ratu

re o

f w

ate

r is

21

2°F

.

•B

oth

are

me

asu

red

at

sta

nd

ard

atm

osp

he

ric

pre

ssu

re.

•T

he

re a

re 1

80

de

gre

es b

etw

ee

n f

ree

zin

g a

nd

bo

ilin

g, co

mp

are

d t

o C

els

ius s

ca

le (

10

0 d

eg

ree

s).

K. H

eat

an

d T

em

pera

ture

17

.2 T

he

rmo

me

ters

an

d T

em

pe

ratu

re S

ca

les

Co

nve

rsio

n b

etw

ee

n F

ah

ren

he

it/C

els

ius t

em

pe

ratu

re

sca

les

•T

o c

on

ve

rt f

rom

Ce

lsiu

s t

o F

ah

ren

he

it

)1(3

259

°+

=C

FT

T

�2

01

0 H

erb

ert

B. D

om

ing

o

•T

o c

on

ve

rt f

rom

Fa

hre

nh

eit t

o C

els

ius

5

)2(

)3

2(

95°

−=

FC

TT

Page 8: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

2. T

he

rmo

me

ters

an

d T

em

pe

ratu

re S

ca

les

Te

mp

era

ture

in

terv

al

•It

is im

po

rta

nt

to d

iffe

ren

tia

te b

etw

ee

n a

n a

ctu

al

tem

pe

ratu

re a

nd

a t

em

pe

ratu

re in

terv

al.

•A

ctu

al te

mp

era

ture

of

20

°C is s

tate

d a

s 2

0°C

(tw

en

ty d

eg

ree

s C

els

ius).

�2

01

0 H

erb

ert

B. D

om

ing

o

(tw

en

ty d

eg

ree

s C

els

ius).

•A

te

mp

era

ture

in

terv

al o

f 2

0°is

20

C°(t

we

nty

Ce

lsiu

s d

eg

ree

s).

K. H

eat

an

d T

em

pera

ture

2. T

he

rmo

me

ters

an

d T

em

pe

ratu

re S

ca

les

Ke

lvin

te

mp

era

ture

sca

le

•It

wa

s n

am

ed

aft

er

Bri

tish

ph

ysic

ist L

ord

Ke

lvin

.

•T

he

un

its (

K)

are

th

e s

am

e s

ize

as t

ho

se

on

th

e

Ce

lsiu

s s

ca

le, b

ut

ze

ro is s

hifte

d s

o t

ha

t

0 K

= −

27

3.1

5°C

an

d 2

73

.15

K =

0°C

�2

01

0 H

erb

ert

B. D

om

ing

o

0 K

= −

27

3.1

5°C

an

d 2

73

.15

K =

0°C

)3(

15

.2

73

+=

CK

TT

Page 9: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

2. T

he

rmo

me

ters

an

d T

em

pe

ratu

re S

ca

les

•In

SI

no

me

ncla

ture

, “d

eg

ree

” is

no

t u

se

d w

ith

Ke

lvin

sca

le.

•2

93

K is r

ea

d a

s “

29

3 k

elv

ins”,

no

t “d

eg

ree

s

Ke

lvin

.

•W

e c

ap

ita

lize

Ke

lvin

wh

en

it re

fers

to

th

e

�2

01

0 H

erb

ert

B. D

om

ing

o

•W

e c

ap

ita

lize

Ke

lvin

wh

en

it re

fers

to

th

e

tem

pe

ratu

re s

ca

le.

•H

ow

eve

r, t

he

un

it o

f

tem

pe

ratu

re is th

e

ke

lvin

, w

hic

h is n

ot

ca

pita

lize

d.

K. H

eat

an

d T

em

pera

ture

Ex

am

ple

1. T

em

pe

ratu

re C

on

ve

rsio

n

Wh

at a

re t

he

eq

uiv

ale

nt

Ce

lsiu

s a

nd

Ke

lvin

tem

pe

ratu

res o

f 5

0.0

°F?

�2

01

0 H

erb

ert

B. D

om

ing

o

Page 10: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

Ex

am

ple

1. (S

OL

N)

�2

01

0 H

erb

ert

B. D

om

ing

o

K. H

eat

an

d T

em

pera

ture

Te

mp

era

ture

Co

nv

ers

ion

�2

01

0 H

erb

ert

B. D

om

ing

o

Page 11: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

2. T

he

rmo

me

ters

an

d T

em

pe

ratu

re S

ca

les

Re

latio

nsh

ip b

etw

ee

n d

iffe

ren

t sca

les

�2

01

0 H

erb

ert

B. D

om

ing

o

Eqn 1

7.5

K. H

eat

an

d T

em

pera

ture

2. T

he

rmo

me

ters

an

d T

em

pe

ratu

re S

ca

les

Ab

so

lute

te

mp

era

ture

sca

le

•T

he

Ke

lvin

te

mp

era

ture

sca

le is c

alle

d a

n

ab

so

lute

te

mp

era

ture

sca

le.

•It

s z

ero

po

int

(T=

0 K

= 2

73

.15

°C)

is c

alle

d a

n

ab

so

lute

ze

ro.

�2

01

0 H

erb

ert

B. D

om

ing

o

ab

so

lute

ze

ro.

Page 12: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

3. T

he

rma

l E

xp

an

sio

n

•M

ost m

ate

ria

ls e

xp

an

d w

he

n t

he

ir te

mp

era

ture

incre

ase

s.

•E

xa

mp

les o

f th

erm

al e

xp

an

sio

n:

–e

xp

an

din

g liq

uid

in

a liq

uid

-in

-tu

be

the

rmo

me

ter,

�2

01

0 H

erb

ert

B. D

om

ing

o

the

rmo

me

ter,

–b

en

din

g b

ime

talli

c s

trip

s,

–lo

ose

nin

g a

me

tal ja

r lid

by r

un

nin

g h

ot

wa

ter

ove

r it.

K. H

eat

an

d T

em

pera

ture

3. T

he

rma

l E

xp

an

sio

n

Lin

ea

r E

xp

an

sio

n

•A

ro

d o

f m

ate

ria

l h

as a

le

ng

th L

0a

t so

me

in

itia

l

tem

pe

ratu

re T

0.

•W

he

n te

mp

era

ture

ch

an

ge

s b

y �

T,

len

gth

ch

an

ge

s b

y �

L

�2

01

0 H

erb

ert

B. D

om

ing

o

ch

an

ge

s b

y �

L

•E

xp

eri

me

nts

sh

ow

th

at if �

Tis

no

t to

o la

rge

(le

ss

tha

n 1

00

°C o

r so

), �

Lis

dir

ectly p

rop

ort

ion

al to

�T

.

•If

tw

o r

od

s m

ad

e o

f sa

me

ma

teri

al h

ave

sa

me

tem

pe

ratu

re c

ha

ng

e,

bu

t o

ne

is tw

ice

as lo

ng

,

the

n c

ha

ng

e in

its

le

ng

th is a

lso

twic

e a

s g

rea

t.

Page 13: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

3. T

he

rma

l E

xp

an

sio

n

Lin

ea

r E

xp

an

sio

n

•T

he

refo

re, �

Lm

ust a

lso

be

pro

po

rtio

na

l to

L0.

•In

tro

du

ce

a p

rop

ort

ion

alit

y c

on

sta

nt

α(v

ari

es

acco

rdin

g to

typ

e o

f m

ate

ria

ls),

we

ge

t )4(

TL

L∆

=∆

α

�2

01

0 H

erb

ert

B. D

om

ing

o

)4(

0T

LL

∆=

∆α

()

)5(

10

00

0T

LT

LL

LL

L∆

+=

∆+

=∆

+=

αα

•If

a b

od

y h

as le

ng

th L

0a

t te

mp

era

ture

T0, th

en

its le

ng

th L

at te

mp

era

ture

T=

T0

+ �

Tis

K. H

eat

an

d T

em

pera

ture

3. T

he

rma

l E

xp

an

sio

n

Lin

ea

r E

xp

an

sio

n

•T

he

co

nsta

nt

αw

hic

h d

escri

be

s th

e t

he

rma

l

exp

an

sio

n p

rop

ert

ies o

f a

pa

rtic

ula

r m

ate

ria

l is

ca

lled

th

e c

oe

ffic

ien

t o

f lin

ea

r e

xp

an

sio

n.

•It

s u

nits a

re K

-1o

r (°

C)-

1.

�2

01

0 H

erb

ert

B. D

om

ing

o

•It

s u

nits a

re K

or

(°C

).

•T

hu

s L

co

uld

be

th

e t

hic

kn

ess o

f a

ro

d,

sid

e le

ng

th

of a

sq

ua

re s

he

et,

or

the

dia

me

ter

of a

ho

le.

Page 14: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

3. T

he

rma

l E

xp

an

sio

n

•If

a s

olid

ob

ject

ha

s a

ho

le in

it,

wh

at

ha

pp

en

s

to th

e s

ize

of

it w

he

n t

he

te

mp

era

ture

of

the

ob

ject in

cre

ase

s?

•C

om

mo

n m

isco

nce

ptio

n is th

at th

e m

ate

ria

l

will

exp

an

d in

to t

he

ho

le.

�2

01

0 H

erb

ert

B. D

om

ing

o

•T

he

fa

ct is

th

e h

ole

exp

an

ds a

lon

g w

ith

th

e

ob

ject.

•E

ve

ry lin

ea

r d

ime

nsio

n

of a

n o

bje

ct

ch

an

ge

s in

the

sa

me

wa

y w

he

n

tem

pe

ratu

re c

ha

ng

es.

K. H

eat

an

d T

em

pera

ture

Su

rfa

ce

Ex

pa

ns

ion

Do H

ole

s E

xpand o

r C

ontr

act

When t

he T

em

pera

ture

Incre

ases?

�2

01

0 H

erb

ert

B. D

om

ing

o

Page 15: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

3. T

he

rma

l E

xp

an

sio

n

Lin

ea

r E

xp

an

sio

n

•N

ote

th

e d

ire

ct p

rop

ort

ion

alit

y e

xp

resse

d in

Eq

n4

.

•It

is a

pp

roxim

ate

ly c

orr

ect o

nly

fo

r su

ffic

ien

tly s

ma

ll

tem

pe

ratu

re c

ha

ng

es.

�2

01

0 H

erb

ert

B. D

om

ing

o

K. H

eat

an

d T

em

pera

ture

3. T

he

rma

l E

xp

an

sio

n

Vo

lum

e E

xp

an

sio

n

•T

he

co

nsta

nt

βch

ara

cte

rize

s t

he

vo

lum

e

exp

an

sio

n p

rop

ert

ies o

f a

pa

rtic

ula

r m

ate

ria

l.

•It

is c

alle

d t

he

co

eff

icie

nt o

f vo

lum

e e

xp

an

sio

n

•It

s u

nits a

re K

-1o

r (°

C)-

1.

�2

01

0 H

erb

ert

B. D

om

ing

o

•It

s u

nits a

re K

-1o

r (°

C)-

1.

Page 16: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

3. T

he

rma

l E

xp

an

sio

n

Vo

lum

e E

xp

an

sio

n

•In

cre

asin

g te

mp

era

ture

usu

ally

ca

use

s a

n in

cre

ase

in v

olu

me

fo

r b

oth

so

lid a

nd

liq

uid

ma

teri

als

.

•E

xp

eri

me

nts

sh

ow

th

at if te

mp

era

ture

ch

an

ge

�T

is

no

t to

o g

rea

t (l

ess th

an

10

0°C

), t

he

in

cre

ase

in

�2

01

0 H

erb

ert

B. D

om

ing

o

no

t to

o g

rea

t (l

ess th

an

10

0°C

), t

he

in

cre

ase

in

vo

lum

e �

Vis

ap

pro

xim

ate

ly p

rop

ort

ion

al to

bo

th

tem

pe

ratu

re c

ha

ng

e �

Ta

nd

in

itia

l vo

lum

e V

0;

)6(

0T

VV

∆=

∆β

K. H

eat

an

d T

em

pera

ture

�2

01

0 H

erb

ert

B. D

om

ing

o

This

gap in t

he r

oadw

ay o

f a b

ridge is

calle

d a

n e

xpansio

n join

t; it

allo

ws t

he

bridge t

o e

xpand a

nd c

ontr

act.

Page 17: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

Ex

am

ple

2.

Le

ng

th c

ha

ng

e d

ue

to

te

mp

era

ture

ch

an

ge

I

A s

urv

eyo

r u

se

s a

ste

el m

ea

su

rin

g t

ap

e t

ha

t is

exa

ctly 5

0.0

00

m lo

ng

at a

te

mp

era

ture

of 2

0°C

.

Wh

at is

its

le

ng

th o

n a

ho

t su

mm

er

da

y w

he

n t

he

tem

pe

ratu

re is 3

5 °

C.

�2

01

0 H

erb

ert

B. D

om

ing

o

15

K1

02.

1−

−×

=st

eel

α

K. H

eat

an

d T

em

pera

ture

Ex

am

ple

2.

(SO

LN

)

Te

mp

era

ture

ch

an

ge

is �

T=

T−

T0

= 1

5C

°, s

o th

e

ch

an

ge

in

le

ng

th �

La

nd

th

e f

ina

l le

ng

th L

= L

0+

�L

are

()(

)()

mm

0.9

m1

00.

9

K1

5m

50

K1

02.

13

15

0

=

×=

∆=

∆−

−−

TL

�2

01

0 H

erb

ert

B. D

om

ing

o

Th

us th

e le

ng

th a

t 3

5°C

is 5

0.0

09

m.

m0

09

.5

0m

00

9.

0m

00

0.

50

mm

0.9

m1

00.

9

0=

+=

+=

=

LL

L

Page 18: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

Ex

am

ple

3.

Le

ng

th C

ha

ng

e D

ue

to

Te

mp

era

ture

Ch

an

ge

II

In e

xa

mp

le 2

, th

e s

urv

eyo

r u

se

s th

e m

ea

su

rin

g t

ap

e

to m

ea

su

re a

dis

tan

ce

wh

en

th

e te

mp

era

ture

is 3

5°C

;

the

va

lue

th

at sh

e r

ea

ds o

ff th

e t

ap

e is 3

5.7

94

m.

Wh

at is

th

e a

ctu

al d

ista

nce

? A

ssu

me

th

at th

e t

ap

e is

ca

libra

ted

fo

r u

se

at

20

°C.

�2

01

0 H

erb

ert

B. D

om

ing

o

K. H

eat

an

d T

em

pera

ture

Ex

am

ple

3. L

en

gth

Ch

an

ge

Du

e t

o T

em

pe

ratu

re C

ha

ng

e II

Th

e r

atio

L/L

0is

(5

0.0

09

m)/

(50

.00

0 m

), s

o t

he

tru

e

dis

tan

ce

is

()

mm

mm800

.35

794

.35

000

.50

009

.50

=

�2

01

0 H

erb

ert

B. D

om

ing

o

Page 19: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

Exam

ple

4. V

olu

me c

han

ge d

ue t

o t

em

pera

ture

ch

an

ge

A g

lass fla

sk w

ith

vo

lum

e 2

00

cm

3is

fill

ed

to

th

e b

rim

with

me

rcu

ry a

t 2

0°C

. H

ow

mu

ch

me

rcu

ry o

ve

rflo

ws

wh

en

th

e t

em

pe

ratu

re o

f th

e s

yste

m is r

ais

ed

to

10

0°C

? T

he

co

eff

icie

nt o

f lin

ea

r e

xp

an

sio

n o

f th

e

gla

ss is 0

.40

×1

0-5

K-1

.

�2

01

0 H

erb

ert

B. D

om

ing

o

βm

ercu

ry=

18

×1

0-5

K-1

K. H

eat

an

d T

em

pera

ture

Ex

am

ple

4.

(SO

LN

)

Incre

ase

in

vo

lum

e o

f g

lass f

lask

()(

) ()

3

31

5

0

20

10

02

00

10

2.1

CC

cm

K

=

°−

°×

=

∆=

−−

TV

Vg

lass

gla

ssβ

()

15

11

10

2.1

10

40

.0

33

−−

−−

×=

×=

=K

Kg

lass

gla

ssα

β

�2

01

0 H

erb

ert

B. D

om

ing

o

Incre

ase

in

vo

lum

e o

f m

erc

ury

is

31

9.

0cm

=

()(

) ()

3

31

5

0

9.2

20

10

02

00

10

18

cm

CC

cm

K

=

°−

°×

=

∆=

−−

TV

Vm

ercu

rym

ercu

ryβ

Page 20: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

Ex

am

ple

4.

(SO

LN

)

Vo

lum

e o

f m

erc

ury

th

at o

ve

rflo

ws

33

37.

21

9.

09.

2cm

cm

cm

=−

=∆

−∆

gla

ssm

ercu

ryV

V

�2

01

0 H

erb

ert

B. D

om

ing

o

K. H

eat

an

d T

em

pera

ture

3. T

he

rma

l E

xp

an

sio

n

Th

erm

al e

xp

an

sio

n o

f w

ate

r

•W

ate

r in

th

e t

em

pe

ratu

re r

an

ge

of

0°C

to

4°C

,

de

cre

ase

s in

vo

lum

e w

ith

in

cre

asin

g t

em

pe

ratu

re.

•In

th

e a

bo

ve

ra

ng

e,

its c

oe

ffic

ien

t o

f vo

lum

e

exp

an

sio

n is n

eg

ative

.

�2

01

0 H

erb

ert

B. D

om

ing

o

exp

an

sio

n is n

eg

ative

.

•A

bo

ve

4°C

, w

ate

r e

xp

an

ds w

he

n h

ea

ted

, h

en

ce

wa

ter

ha

s its

gre

ate

st

de

nsity a

t 4°C

.

•W

ate

r a

lso

exp

an

ds w

he

n it fr

ee

ze

s.

•T

his

an

om

alo

us b

eh

avio

r o

f w

ate

r h

as a

n

imp

ort

an

t e

ffe

ct o

n p

lan

t a

nd

wa

ter

life

in

la

ke

s,

pa

rtic

ula

rly d

uri

ng

win

ter.

Page 21: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

4. Q

ua

nti

ty o

f H

ea

t

Qu

an

tity

of

he

at

•E

ne

rgy tra

nsfe

r ta

ke

s p

lace

so

lely

be

ca

use

of a

tem

pe

ratu

re d

iffe

ren

ce

ca

lled

he

at

flo

w o

r h

ea

t

tra

nsfe

r.

•E

ne

rgy tra

nsfe

rre

d in

th

is w

ay is c

alle

d h

ea

t.

�2

01

0 H

erb

ert

B. D

om

ing

o

•E

ne

rgy tra

nsfe

rre

d in

th

is w

ay is c

alle

d h

ea

t.

•S

ir J

am

es J

ou

le

dis

co

ve

red

th

at

tem

pe

ratu

re r

ise

is

dir

ectly p

rop

ort

ion

al

to th

e a

mo

un

t o

f

wo

rk d

on

e.

K. H

eat

an

d T

em

pera

ture

Cats

, such a

s t

his

Bengal

tiger,

oft

en p

ant

to g

et

rid o

f

excess h

eat.

(P

hoto

Dis

c

�2

01

0 H

erb

ert

B. D

om

ing

o

Blu

e/P

hoto

Dis

c,

Inc./

Gett

y

Images)

Page 22: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

4. Q

ua

nti

ty o

f H

ea

t

•K

ee

p c

lea

rly in

min

d t

he

dis

tin

ctio

n b

etw

ee

n

tem

pe

ratu

re a

nd

he

at.

•T

em

pe

ratu

re d

ep

en

ds o

f th

e p

hysic

al sta

te o

f a

ma

teri

al a

nd

is a

qu

an

tita

tive

de

scri

ptio

n o

f its h

otn

ess o

r co

ldn

ess.

•H

ea

t a

lwa

ys r

efe

r to

en

erg

y in

tra

nsit fro

m o

ne

b

od

y o

r syste

m to

an

oth

er

be

ca

use

of a

�2

01

0 H

erb

ert

B. D

om

ing

obo

dy o

r syste

m to

an

oth

er

be

ca

use

of a

te

mp

era

ture

diffe

ren

ce

, n

eve

r to

th

e a

mo

un

t o

f e

ne

rgy c

on

tain

ed

with

in a

pa

rtic

ula

r syste

m.

•W

e c

ha

ng

e t

he

te

mp

era

ture

of a

bo

dy b

y

ad

din

g h

ea

t to

it o

r re

mo

vin

g h

ea

t a

wa

y f

rom

it.

K. H

eat

an

d T

em

pera

ture

4. Q

ua

nti

ty o

f H

ea

t

Qu

an

tity

of

he

at

•W

e d

efin

e a

un

it o

f q

ua

ntity

of h

ea

t b

ase

d o

n

tem

pe

ratu

re c

ha

ng

es o

f so

me

sp

ecific

ma

teri

al.

•T

he

ca

lori

e is d

efin

ed

as th

e a

mo

un

t o

f h

ea

t

req

uir

ed

to

ra

ise

th

e t

em

pe

ratu

re o

f o

ne

gra

m o

f

�2

01

0 H

erb

ert

B. D

om

ing

o

req

uir

ed

to

ra

ise

th

e t

em

pe

ratu

re o

f o

ne

gra

m o

f

wa

ter

by o

ne

C°.

•C

orr

esp

on

din

g u

nit o

f h

ea

t u

sin

g F

ah

ren

he

it

de

gre

es a

nd

Im

pe

ria

l u

nits is th

e B

ritish

th

erm

al

un

it (

Btu

).

•O

ne

Btu

is th

e q

ua

ntity

of h

ea

t re

qu

ire

d t

o r

ais

e th

e

tem

pe

ratu

re o

f o

ne

po

un

d o

f w

ate

r b

y o

ne

F°.

Page 23: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

4. Q

ua

nti

ty o

f H

ea

t

Qu

an

tity

of

he

at

•T

hu

s,

1 c

al =

4.1

86

J

1 k

ca

l =

41

86

J

1 B

tu =

25

2 c

al =

10

55

J

•T

he

ca

lori

e is n

ot

a f

un

da

me

nta

l S

I u

nit, in

ste

ad

�2

01

0 H

erb

ert

B. D

om

ing

o

•T

he

ca

lori

e is n

ot

a f

un

da

me

nta

l S

I u

nit, in

ste

ad

jou

le is u

se

d a

s th

e b

asic

un

it o

f e

ne

rgy in

all

form

s, in

clu

din

g h

ea

t.

K. H

eat

an

d T

em

pera

ture

4. Q

ua

nti

ty o

f H

ea

t

Sp

ecific

he

at

•Q

is u

se

d t

o r

ep

rese

nt

qu

an

tity

of

he

at.

•Q

ua

ntity

of

he

at

req

uir

ed

to

in

cre

ase

te

mp

era

ture

of a

ma

ss m

of

ce

rta

in m

ate

ria

l fr

om

T1

to T

2is

fou

nd

to

be

ap

pro

xim

ate

ly p

rop

ort

ion

al to

�2

01

0 H

erb

ert

B. D

om

ing

o

fou

nd

to

be

ap

pro

xim

ate

ly p

rop

ort

ion

al to

tem

pe

ratu

re c

ha

ng

e �

T=

T2

−T

1. It

is a

lso

pro

po

rtio

na

l to

ma

ss m

of th

e m

ate

ria

l. T

hu

s,

we

ha

ve

!

"#$

%&

"#c

as t

he

sp

ecific

he

at

of th

e m

ate

ria

l.

)7(

Tm

cQ

∆=

Page 24: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

4. Q

ua

nti

ty o

f H

ea

t

•H

ea

t is

alw

ays e

ne

rgy in

tra

nsit a

s a

re

su

lt o

f

tem

pe

ratu

re d

iffe

ren

ce

.

•T

he

re is n

o s

uch

th

ing

as “

the

am

ou

nt

of h

ea

t

in a

bo

dy”.

�2

01

0 H

erb

ert

B. D

om

ing

o

K. H

eat

an

d T

em

pera

ture

4. Q

ua

nti

ty o

f H

ea

t

Sp

ecific

he

at

•T

he

sp

ecific

he

at

of

a m

ate

ria

l a

lwa

ys d

ep

en

ds o

n

the

in

itia

l te

mp

era

ture

an

d t

he

te

mp

era

ture

in

terv

al.

•S

pe

cific

he

at

of w

ate

r is

ap

pro

xim

ate

ly

41

90

J/k

g·K

�2

01

0 H

erb

ert

B. D

om

ing

o

41

90

J/k

g·K

1 c

al/g

·C°

1 B

tu/lb

·F°

Page 25: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

Ex

am

ple

5.

Fe

ed

a c

old

, s

tarv

e a

fe

ve

r

Du

rin

g a

bo

ut

with

flu

, a

n 8

0-k

g m

an

ra

n a

fe

ve

r o

f

39

.0°C

(1

02

.2°F

) in

ste

ad

of th

e n

orm

al b

od

y

tem

pe

ratu

re o

f 3

7.0

°C (

98

.6°F

). A

ssu

min

g t

ha

t th

e

hu

ma

n b

od

y is m

ostly w

ate

r, h

ow

mu

ch

he

at

is

req

uir

ed

to

ra

ise

his

te

mp

era

ture

by th

at a

mo

un

t?

�2

01

0 H

erb

ert

B. D

om

ing

o

K. H

eat

an

d T

em

pera

ture

Ex

am

ple

5.

(SO

LN

) ()(

)()

JK

KJ/k

gkg

51

07.

60.

24

19

08

=⋅

=∆

=T

mc

Q

�2

01

0 H

erb

ert

B. D

om

ing

o

Page 26: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

Ex

am

ple

6.

Ov

erh

ea

tin

g e

lec

tro

nic

s

Yo

u a

re d

esig

nin

g a

n e

lectr

on

ic c

ircu

it e

lem

en

t m

ad

e

of 2

3 m

g o

f sili

co

n.

Th

e e

lectr

ic c

urr

en

t th

rou

gh

it

ad

ds e

ne

rgy a

t th

e r

ate

of 7

.4 ×

10

-3J/s

. If

yo

ur

de

sig

n d

oe

sn

’t a

llow

an

y h

ea

t tr

an

sfe

r o

ut o

f th

e

ele

me

nt,

at

wh

at

rate

do

es its

te

mp

era

ture

in

cre

ase

?

Sp

ecific

he

at

of sili

co

n is 7

05

J/k

g⋅K

.

�2

01

0 H

erb

ert

B. D

om

ing

o

Sp

ecific

he

at

of sili

co

n is 7

05

J/k

g⋅K

.

K. H

eat

an

d T

em

pera

ture

Ex

am

ple

6.

(SO

LN

)

In o

ne

se

co

nd

, Q

= (

7.4

×1

0-3

J/s

)(1

s)

= 7

.4 ×

10

-3J.

Fro

m Q

= m

c�T

,'"

&(")%

'*)"

#+,%$-"#.$#/

$"#0

"+/$1#.0

() (

)K

KJ/k

gkg

J4

6.

07

05

10

23

10

4.7 6

3

=⋅

×

×=

=∆

mc

QT

�2

01

0 H

erb

ert

B. D

om

ing

o

() (

)K

J/k

gkg

70

51

02

3⋅

×m

c

Page 27: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

4. Q

ua

nti

ty o

f H

ea

t

•T

he

te

rm “

he

at

ca

pa

city”

is u

nfo

rtu

na

te

be

ca

use

it g

ive

s t

he

err

on

eo

us im

pre

ssio

n

tha

t a

bo

dy c

on

tain

s a

ce

rta

in a

mo

un

t o

f h

ea

t.

•R

em

em

be

r th

e h

ea

t is

en

erg

y in

tra

nsit to

or

fro

m a

bo

dy,

no

t th

e e

ne

rgy r

esid

ing

in

th

e

�2

01

0 H

erb

ert

B. D

om

ing

obo

dy.

K. H

eat

an

d T

em

pera

ture

5. C

alo

rim

etr

ya

nd

Ph

as

e C

ha

ng

es

•C

alo

rim

etr

ym

ea

ns “

me

asu

rin

g h

ea

t”.

Ph

ase

ch

an

ge

s

•T

he

te

rm p

ha

se

is u

se

d t

o d

escri

be

a s

pe

cific

sta

te

of m

att

er,

su

ch

as s

olid

, liq

uid

or

ga

s.

•T

he

co

mp

ou

nd

H2O

exis

ts in

th

e s

olid

ph

ase

as

ice

, liq

uid

ph

ase

as w

ate

r, a

nd

ga

se

ou

s p

ha

se

as

�2

01

0 H

erb

ert

B. D

om

ing

o

ice

, liq

uid

ph

ase

as w

ate

r, a

nd

ga

se

ou

s p

ha

se

as

ste

am

(a

lso

kn

ow

n a

s s

tate

s o

f m

att

er)

.

•A

tra

nsitio

n fro

m o

ne

ph

ase

to

an

oth

er

is c

alle

d

ph

ase

ch

an

ge

or

ph

ase

tra

nsitio

n.

•A

ph

ase

ch

an

ge

ta

ke

s p

lace

at a

de

fin

ite

te

mp

era

ture

, a

cco

mp

an

ied

by a

bso

rptio

n/e

mis

sio

n

of h

ea

t a

nd

a c

ha

ng

e in

vo

lum

e a

nd

de

nsity.

Page 28: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

5. C

alo

rim

etr

ya

nd

Ph

as

e C

ha

ng

es

Ph

ase

ch

an

ge

s

•T

o c

ha

ng

e 1

kg

of ic

e a

t 0°C

to

1 k

g o

f liq

uid

wa

ter

at

0°C

at

no

rma

l a

tmo

sp

he

ric p

ressu

re r

eq

uir

es

3.3

4 ×

10

5J o

f h

ea

t.

•H

ea

t re

qu

ire

d p

er

un

it m

ass is c

alle

d t

he

he

at

of

�2

01

0 H

erb

ert

B. D

om

ing

o

•H

ea

t re

qu

ire

d p

er

un

it m

ass is c

alle

d t

he

he

at

of

fusio

n (

or

late

nt h

ea

t o

f fu

sio

n),

de

no

ted

by L

f.

•F

or

wa

ter

at n

orm

al a

tmo

sp

he

ric p

ressu

re,

the

he

at o

f fu

sio

n is L

f=

3.3

4 ×

10

5J =

79

.6 c

al/g

=

14

3 B

tu/lb

•G

en

era

lly,

Q =

mL

f

•N

ote

th

at th

e a

bo

ve

pro

ce

ss is r

eve

rsib

le.

K. H

eat

an

d T

em

pera

ture

5. C

alo

rim

etr

ya

nd

Ph

as

e C

ha

ng

es

Ph

ase

ch

an

ge

s

•W

e n

ee

d t

o r

em

ove

he

at

to fre

eze

liq

uid

wa

ter

to

ice

at

0°C

, th

e m

ag

nitu

de

is th

e s

am

e e

xce

pt

tha

t Q

is n

eg

ative

be

ca

use

he

at

is r

em

ove

d.

•T

o c

ove

r b

oth

po

ssib

ilitie

s a

nd

oth

er

kin

ds o

f p

ha

se

�2

01

0 H

erb

ert

B. D

om

ing

o

•T

o c

ove

r b

oth

po

ssib

ilitie

s a

nd

oth

er

kin

ds o

f p

ha

se

ch

an

ge

s, w

e w

rite

•H

ea

t o

f fu

sio

n is d

iffe

ren

t fo

r d

iffe

ren

t m

ate

ria

ls a

nd

als

o v

ari

es s

om

ew

ha

t w

ith

pre

ssu

re.

)8(

mL

=

Page 29: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

5. C

alo

rim

etr

ya

nd

Ph

as

e C

ha

ng

es

Ph

ase

eq

uili

bri

um

•F

or

a g

ive

n m

ate

ria

l a

t a

ny g

ive

n p

ressu

re,

the

fr

ee

zin

g te

mp

era

ture

is th

e s

am

e a

s t

he

me

ltin

g

tem

pe

ratu

re.

•T

he

co

nd

itio

n w

he

re liq

uid

an

d s

olid

ph

ase

s c

an

co

exis

t is

ca

lled

ph

ase

eq

uili

bri

um

.

�2

01

0 H

erb

ert

B. D

om

ing

o

co

exis

t is

ca

lled

ph

ase

eq

uili

bri

um

.

He

at o

f va

po

riza

tio

n

•T

he

pre

vio

us p

ha

se

ch

an

ge

ca

n a

lso

be

ap

plie

d t

o

bo

ilin

g o

r e

va

po

ratio

n,

a tra

nsitio

n b

etw

ee

n t

he

liq

uid

an

d g

ase

ou

s p

ha

se

s.

•T

he

he

at n

ee

de

d is c

alle

d t

he

he

at

of va

po

riza

tio

n,

Lv

= 2

.25

6 ×

10

6J/k

g =

53

9 c

al/g

= 9

70

Btu

/lb

K. H

eat

an

d T

em

pera

ture

5. C

alo

rim

etr

ya

nd

Ph

as

e C

ha

ng

es

He

at o

f va

po

riza

tio

n

•L

ike

me

ltin

g,

bo

ilin

g is a

re

ve

rsib

le t

ran

sitio

n.

•W

he

n h

ea

t is

re

mo

ve

d f

rom

a g

as a

t b

oili

ng

tem

pe

ratu

re,

the

ga

s r

etu

rns t

o th

e liq

uid

ph

ase

,

tha

t is

, it c

on

de

nse

s.

�2

01

0 H

erb

ert

B. D

om

ing

o

tha

t is

, it c

on

de

nse

s.

•L

va

nd

bo

ilin

g t

em

pe

ratu

re o

f a

ma

teri

al d

ep

en

d o

n

pre

ssu

re.

•T

he

gra

ph

sh

ow

s h

ow

te

mp

era

ture

va

rie

s w

he

n w

e

ad

d h

ea

t co

ntin

uo

usly

to

a s

pe

cim

en

of

ice

with

initia

l te

mp

era

ture

be

low

0°C

, w

he

n it

rea

ch

es

me

ltin

g b

oili

ng

po

ints

.

Page 30: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

5. C

alo

rim

etr

ya

nd

Ph

as

e C

ha

ng

es

Heat of vaporization

�2

01

0 H

erb

ert

B. D

om

ing

o

Fig

17.1

8

K. H

eat

an

d T

em

pera

ture

5. C

alo

rim

etr

ya

nd

Ph

as

e C

ha

ng

es

Heat of vaporization

�2

01

0 H

erb

ert

B. D

om

ing

o

Page 31: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

5. C

alo

rim

etr

ya

nd

Ph

as

e C

ha

ng

es

Su

blim

atio

n

•S

om

e s

ub

sta

nce

s c

an

so

me

tim

es c

ha

ng

e d

ire

ctly

fro

m s

olid

to

th

e g

ase

ou

s p

ha

se

, a

pro

ce

ss w

e

ca

lled

su

blim

atio

n.

•T

he

co

rre

sp

on

din

g h

ea

t n

ee

de

d is t

he

he

at

of

�2

01

0 H

erb

ert

B. D

om

ing

o

•T

he

co

rre

sp

on

din

g h

ea

t n

ee

de

d is t

he

he

at

of

su

blim

atio

n,

Ls.

Su

pe

rco

ole

d

•V

ery

pu

re w

ate

r ca

n b

e c

oo

led

to

se

ve

ral d

eg

ree

s

be

low

th

e f

ree

zin

g t

em

pe

ratu

re w

ith

ou

t fr

ee

zin

g,

this

sta

te is d

escri

be

d a

s s

up

erc

oo

led

.

K. H

eat

an

d T

em

pera

ture

5. C

alo

rim

etr

ya

nd

Ph

as

e C

ha

ng

es

Su

pe

rco

ole

d

•V

ery

pu

re w

ate

r ca

n b

e c

oo

led

to

se

ve

ral d

eg

ree

s

be

low

th

e f

ree

zin

g t

em

pe

ratu

re w

ith

ou

t fr

ee

zin

g.

•T

his

sta

te is d

escri

be

d a

s s

up

erc

oo

led

an

d t

he

pri

ncip

le is a

pp

lied

in

“se

ed

ing

” clo

ud

s.

�2

01

0 H

erb

ert

B. D

om

ing

o

pri

ncip

le is a

pp

lied

in

“se

ed

ing

” clo

ud

s.

Su

pe

rhe

ate

d

•S

imila

rly, a

liq

uid

ca

n a

lso

be

su

pe

rhe

ate

d a

bo

ve

its n

orm

al b

oili

ng

te

mp

era

ture

.

Page 32: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

5. C

alo

rim

etr

ya

nd

Ph

as

e C

ha

ng

es

Eva

po

rative

co

olin

g

•T

em

pe

ratu

re c

on

tro

l m

ech

an

ism

of

ma

ny a

nim

als

ma

ke

s u

se

of h

ea

t o

f va

po

riza

tio

n t

o r

em

ove

he

at

fro

m th

e b

od

y.

•B

y r

em

ovin

g w

ate

r fr

om

th

e t

on

gu

e (

pa

ntin

g)

or

�2

01

0 H

erb

ert

B. D

om

ing

o

•B

y r

em

ovin

g w

ate

r fr

om

th

e t

on

gu

e (

pa

ntin

g)

or

fro

m th

e s

kin

(sw

ea

tin

g)

by v

ap

ori

zin

g w

ate

r, a

n

op

tim

um

bo

dy t

em

pe

ratu

re c

an

be

ma

inta

ine

d.

•It

is a

lso

use

d t

o c

oo

l b

uild

ing

s in

ho

t, d

ry c

lima

tes

an

d to

re

cir

cu

late

“u

se

d”

ste

am

in

co

al-

fire

d o

r

nu

cle

ar-

po

we

red

ele

ctr

ic-g

en

era

tin

g p

lan

ts.

K. H

eat

an

d T

em

pera

ture

5. C

alo

rim

etr

ya

nd

Ph

as

e C

ha

ng

es

He

at o

f co

mb

ustio

n

•C

he

mic

al re

actio

ns (

e.g

., c

om

bu

stio

n)

tha

t a

re

sim

ilar

to p

ha

se

ch

an

ge

as t

he

y in

vo

lve

de

fin

ite

qu

an

titie

s o

f h

ea

t.

He

at ca

lcu

latio

ns

�2

01

0 H

erb

ert

B. D

om

ing

o

He

at ca

lcu

latio

ns

•L

aw

of

ca

lori

me

try:

Wh

en

he

at

flo

w o

ccu

rs

be

twe

en

tw

o b

od

ies t

ha

t a

re iso

late

d fro

m t

he

ir

su

rro

un

din

gs, a

mo

un

t o

f h

ea

t lo

st b

y o

ne

bo

dy

mu

st e

qu

al th

e a

mo

un

t g

ain

ed

by t

he

oth

er.

•In

oth

er

wo

rds,

the

co

nse

rva

tio

n o

f e

ne

rgy.

Page 33: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

�2

01

0 H

erb

ert

B. D

om

ing

o

This

hig

hly

magnifie

d im

age s

how

s a

fabric t

hat

has b

een c

oate

d

with m

icro

scopic

balls

of heat-

resis

tant

pla

stic. T

he b

alls

conta

in a

substa

nce k

now

n a

s a

“phase-c

hange m

ate

rial,”

the m

eltin

g a

nd

freezin

g o

f w

hic

h a

bsorb

s a

nd r

ele

ases h

eat.

Such f

abrics

auto

matically

adju

st

in r

eaction t

o y

our

body h

eat

to h

elp

main

tain

a

consta

nt te

mpera

ture

next

to y

our

skin

. (C

ourt

esy O

utlast

Technolo

gie

s,

Bould

er,

CO

)

K. H

eat

an

d T

em

pera

ture

Exam

ple

7. T

em

pera

ture

ch

an

ge w

ith

no

ph

ase c

han

ge

A 0

.05

0 k

g m

eta

l b

olt is h

ea

ted

to

an

un

kn

ow

n in

itia

l

tem

pe

ratu

re.

It is t

he

n d

rop

pe

d in

to a

be

ake

r

co

nta

inin

g 0

.15

kg

of w

ate

r w

ith

an

in

itia

l

tem

pe

ratu

re o

f 2

1.0

°C

. T

he

bo

lt a

nd

th

e w

ate

r th

en

rea

ch

a f

ina

l te

mp

era

ture

of 2

5.0

°C.

If th

e m

eta

l h

as

�2

01

0 H

erb

ert

B. D

om

ing

o

a s

pe

cific

he

at ca

pa

city o

f 8

99

J/k

g-C

°, f

ind

the

in

itia

l te

mp

era

ture

of th

e m

eta

l.

Page 34: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

Ex

am

ple

7. (S

OL

N)

�2

01

0 H

erb

ert

B. D

om

ing

o

K. H

eat

an

d T

em

pera

ture

Ex

am

ple

7. (S

OL

N)

�2

01

0 H

erb

ert

B. D

om

ing

o

Page 35: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

Ex

am

ple

7. (S

OL

N)

�2

01

0 H

erb

ert

B. D

om

ing

o

K. H

eat

an

d T

em

pera

ture

Ca

lori

me

try

(no

ph

as

e c

ha

ng

e)

�2

01

0 H

erb

ert

B. D

om

ing

o

Page 36: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

Ex

am

ple

8. C

ha

ng

es

in

bo

th t

em

pe

ratu

re a

nd

ph

as

e

Ho

w m

uch

en

erg

y is r

em

ove

d w

he

n 1

0.0

g o

f w

ate

r is

co

ole

d f

rom

ste

am

at 1

33

.0°C

to

liq

uid

at 5

3.0

°C?

�2

01

0 H

erb

ert

B. D

om

ing

o

K. H

eat

an

d T

em

pera

ture

Ex

am

ple

8.

Ch

an

ge

s in

bo

th t

em

pe

ratu

re a

nd

ph

as

e

�2

01

0 H

erb

ert

B. D

om

ing

o

Page 37: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

Ex

am

ple

8. (S

OL

N)

�2

01

0 H

erb

ert

B. D

om

ing

o

K. H

eat

an

d T

em

pera

ture

Ex

am

ple

8. (S

OL

N)

�2

01

0 H

erb

ert

B. D

om

ing

o

Page 38: material. • To use temperature as a measure of hotness and … · 2020-04-08 · K. Heat and Temperature 1. Temperature & Thermal Equilibrium Thermometer • First, select any measurable

K. H

eat

an

d T

em

pera

ture

Ex

am

ple

8. (S

OL

N)

�2

01

0 H

erb

ert

B. D

om

ing

o

K. H

eat

an

d T

em

pera

ture

Ca

lori

me

try

(wit

h p

os

sib

le p

ha

se

ch

an

ge

)

�2

01

0 H

erb

ert

B. D

om

ing

o