list of annexures sr. no. name of annexure€¦ · 4 mono butyl tin oxide 0.75 mt/month 2273-43-0...

LIST OF ANNEXURES

SR. NO. NAME OF ANNEXURE

I List of Products and Raw materials along with their Production Capacity

II Layout Map of the Plant

III Brief Manufacturing Process Description

IV Details of water consumption & waste water generation

V Details of Effluent Treatment Scheme

VI Details of Hazardous Waste Generation and Disposal

VII Details of Stacks and Vents, Fuel & Energy Requirements

VIII Details of Hazardous Chemicals Storage & Handling

IX Socio-economic Impacts

X Proposed Terms of Reference

XI Plot Allotment Letter

XII Copy of CC&A

ANNEXURE - I ____________________________________________________________________________ LIST OF PRODUCTS ALONG WITH THEIR PRODUCTION CAPACITY WITH RAW MATERIALS

SR. NO.

PRODUCT NAME Existing Capacity

(MT/Month)

Additional Capacity

(MT/Month)

Total Capacity

(MT/Month)

CAS Nos. LD50

1 BEES WAX 25 - 25 8012-89-3 --

2 PETROLIUM JELLY 100 - 100 8009-03-8 --

3 LIQUID PARAFIN 100 - 100 8012-95-1 --

4 EMULSIFYING WAX 50 - 50

8014-38-8 6772-27-0 68439-49-6 9004-99-3 123-94-4 25383-94-7 2197-63-9 9004-95-9

--

5 PETRO WAXES 23 - 23 6472-61-6 --

6 HARD PARAFFIN

WAX 30 - 30 8002-74-2 --

7 MICRO CRYSTALLINE

WAX 30 - 30 63231-60-7 --

8 GLYCERYL MONO

STEARATE 0 25 25 123-94-4 --

9 GLYCERYL COCOATE 0 25 25 8033-99-6 --

10 CEATO STEARYL

STEARATE 0 25 25 93820-97-4 --

11 STEARYL STEARATE 0 25 25 2778-96-3 --

12 CETYL RICINOELATE 0 25 25 --

13 CETYL PALMITATE 0 25 25 540-10-3 --

14 MYRISTRYL MYRISTATE

0 25 25 3234-85-3 --

15 CETYL OLEATE 0 25 25 22393-86-8 --

16

MYRISTYL STEARATE 0 25 25 177661-50-

56 --

17 SODIUM STEAROYL LACTYLATE

0 25 25 2583-94-7 --

18 CANDELILLA WAX 0 15 15 8006-44-8 --

19. COCOA BUTTER 0 10 10 8002-31-1 --

20. SHEA BUTTER 0 10 10 --

21 CARNAUBA WAX 0 15 15 --

22 VEGANCERAS NJ 0 15 15 --

23 VEGANCERAS SBW 0 25 25 --

24 VEGANCERAS DL 0 25 25 --

25 OZOKERITE WAX 0 25 25 --

26 CERESINE WAX 0 25 25 --

27 CHAPSTICK BASE 0 25 25 --

28 HARD FAT 0 25 25 --

29

EMULSIFYING OINTMENT

0 25 25

--

TOTAL 358 490 848

LIST OF RAW MATERIAL Existing Sr. No.

Name of the Raw Materials

Capacity QTY/M

Sr. No.


Quantity CAS No

1 BEES WAX IP 25 Crud Bees Wax 35 MT/Month --

2 PETROLIUM JELLY

100 1 Micro Crystalline Wax 10 MT/Month 63231-60-7

2 Paraffin Wax 16 MT/Month 8002-74-2

3 White Oil 75 MT/Month 8042-47-5

3 LIQUID PARAFIN

100 1 Mineral Oil 101 MT/Month 8042-47-5

4 EMULSIFYING WAX

50 1 Cetearyl Alcohol (Palm Oil Based)

30 MT/Month 8005-44-5

2 Sodium Laural Sulphate 1.6 MT/Month 151-21-3

3 Cetearyl Alcohol (Palm Oil Based) PS Grade

8 MT/Month 67762-27-0 / 8005-44-5

Ceto macrol-1000-500 5.5 MT/Month --

4 Poly ethiline Glycol – 20 Stearat

1.1 MT/Month 9004-99-3

5 Glyceryl mono stearate 2.6 MT/Month 31566-31-1

6 Poly ethiline Glycol-100 Stearate

2.6 MT/Month 9004-99-3

5 PETRO WAXES 23 1 Slack Wax 26 MT/Month 64742-61-6

6 HARD PARAFFIN WAX

30 2 Paraffin Wax 31 MT/Month 8002-74-2

7 MICRO CRYSTALLINE WAX

30 1 Micro crystalline wax 19 MT/Month 63231-60-7

2 Slack Wax 12 MT/Month 64742-61-6

Proposed Sr. No.

Name of the Products

Capacity QTY/M

Sr. No.


Quantity CAS No

8 GLYCERYL MONO STEARATE

25 1 Hydrogenated Palm Stearine

22 MT/Month 68514-74-9

2 Glycerine 3.5 MT/Month 56-81-5

3 Na(OH) Solution 5.0 LTR/MONTH 1310-73-2

9 GLYCERYL COCOATE

25 1 Coconut Fatty Acid

22 MT/Month 61788-47-4

2 Glycerin 3.5 MT/Month 56-81-5

3 Catalyst 0.75 MT/Month --

4 Na(OH) Solution 5.0 LTR/MONTH 1310-73-2

10 CEATO STEARYL STEARATE

25 1 Stearic Acid 12 MT/MONTH 57-11-4

2 Cetostearyl Alcohol

13 MT/MONTH 8005-44-5

3 Catalyst (Con. Sulphuric Acid)

1.25 MT/Month 7664-93-9

4 Mono Butyl Tin Oxide

0.75 MT/MONTH 2273-43-0

11 STEARYL STEARATE

25 1 Stearic Acid 13 MT/MONTH 57-11-4

2 Stearic Alcohol 12 MT/MONTH 112-92-5


1.25 LTR /Month 7664-93-9


0.75 MT/MONTH 2273-43-0

12 CTETYL RICINOELATE

25 1 Cetyl Alcohol 13.25 MT/MONTH 36653-82-4

2 Ricinoelic Acid 12.5 MT/MONTH 141-22-0


1.25 LTR /Month 7664-93-9


0.75 MT/MONTH 2273-43-0

13 CETYL PALMITATE

25 1 Cetyl Alcohol 12.5 MT/MONTH 36653-82-4

2 Palmitic Acid 12.5 MT/MONTH 57-10-3


1.25 LTR/Month 7664-93-9


0.75 MT/MONTH 2273-43-0

14 MYRISTRYL MYRISTATE

25 1 Myristryl Alcohol 12.5 MT/MONTH 112-72-1

2 Myristic Acid 12.5 MT/MONTH 544-63-8


1.25 LTR /Month 0.75 MT/MONTH

7664-93-9


2273-43-0

15 CETYL OLEATE 25 1 Cetyl Alcohol 12.5 MT/MONTH 36653-82-4

2 Oelic Acid 12.5 LTR /MONTH 112-80-1


1.25 LTR /Month 7664-93-9


0.75 MT/MONTH 2273-43-0

16 MYRISTYL STEARATE

25 1 STEARYL ALCOHOL 12.5 MT/MONTH 112-92-5

2 Myristic Acid 12.5 MT/MONTH 544-63-8

17 SODIUM 25

STEAROYL LACTYLATE

18 CANDELILLA WAX

25 1 Crude Candelilla wax

27.5MT/MONTH 8006-44-8

19 COCOA BUTTER

25 1 Crude Cocoa Butter

27.5MT/MONTH 8002-31-1

20 SHEA BUTTER 25 1 Crude Shea Butter 27.5MT/MONTH 194043-92-0

21 CARNAUBA WAX

25 1 Crude Carnauba wax

27.5MT/MONTH 8

0

1

5

-

8

6

-

9

22 VEGANCERAS NJ

15 1 Vegetable wax 7.5MT/MONTH 8001-39-6

2 Sunflower Oil 7.5MT/MONTH 8001-21-6

23 VEGANCERAS SBW

25 1 Ceto Steryl Alcohol

12.5 MT/MONTH 67762-27-0

Stearic Acid 12.5 MT/MONTH 57-11-4

Vegetable wax 5.0 MT/MONTH 8001-39-6

24 VEGANCERAS DL

25 1 Castor oil 12.5MT/MONTH 8001-79-4

2 SG 12.5MT/MONTH --

25 OZOKERITE WAX

25 1 Paraffin wax 12.5MT/MONTH 8002-74-2

2 Microcrystalline wax

12.5MT/MONTH 84136-31-2

26 CERESINE WAX 25 1 Paraffin wax 12.5MT/MONTH 8002-74-2

2 Microcrystalline wax

12.5MT/MONTH 63231-60-7

27 CHAPSTICK BASE

25 1 Coconut Oil 12.4 MT/MONTH 8001-31-8

2 Microcrystalline Slack Wax

12.4MT/MONTH 63231-60-7

3 Paraffin Wax 0.05 MT/MONTH 8002-74-2

4 Ozokerite Wax 0.05 MT/MONTH 84136-31-2

5 Candelilla wax 0.05 MT/MONTH 8006-44-8

6 Carnauba Wax 0.05 MT/MONTH 8015-86-9

7 Sunflower Wax 0.05 MT/MONTH 1286686-34-7

28 HARD FAT 25 1 GLYCERYL MONO STEARATE

22.5 MT/MONTH 123-94-4

2 CAPRILYC CAPRIC TRIGLYCERIDE

2.5 MT/MONTH 73398-61-5

29 EMULSIFYING OINTMENT

25 1 Emulsifying Wax 7.5 MT/MONTH --

2 White Soft Paraffin

12.5 MT/MONTH 8002-74-2

3 Liquid Paraffin 5.0 MT/MONTH 8012-95-1

ANNEXURE - II ___________________________________________________________________________ LAYOUT OF MAP OF THE PLANT

ANNEXURE - III ___________________________________________________________________________ MANUFACTURING PROCESS, CHEMICAL REACTION & MASS BALANCE Existing: 1. Manufacturing Process:

This is a simple blending process where selected waxes and oils are blended in the blending

vessel with continuous stirring for 2 hours.

Upon completion of the blending, new wax compound is formed.

There are no bye products or waste materials generated in this process.

Mass Balance:

Process Flow Diagram of Bees Wax:

Process Flow Diagram of Petroleum Jelly:

Process Flow Diagram of Liquid Paraffin:

Process Flow Diagram of Emulsifying Wax:

Process Flow Diagram of Petro wax:

Process Flow Diagram of Hard Paraffin wax:

Process Flow Diagram of Microcrystalline wax:

Proposed: 2. Esters (240 MT/Year i.e. 20 MT/Month) - Proposed

a. Manufacturing Process:

In Esters manufacturing process basic reaction involves substitution of a hydroxyl group with

an alkyl. Typically acids are organic acids like oleaic acid, linolic acid etc. and the alkyl group

is contributed by alcohols, phenols etc. The reactions are typically catalyzed.

Side stream generated in these processes are non toxic and biodegradable. The

biodegradability of esters is one of the main plus points. Side stream is generally glycerin.

The plant will be suited for multipurpose ester production. The volume expected is in the

range of 240 MT/Year of finished products.

List of Products

Cetyl Palmitate

Stearyl Stearate

Cetyl Oleate

Myristyl Myristate

Ceto Stearyl Stearate

Cetyl Recinoleate

Glycerol Mono Stearate

Glyceryl Cocoate

Myristyl Stearate

Sodium Stearoyl Lactylate

Process Type 1:

INPUT QTY (Kgs) OUTPUT QTY (Kgs) REMARK

Vegetable Oils 1564.00 Ester 1000.00 Product

Alcohols# 582.00 Recover alcohol 515.00 recycle

Process waste 631.00 To Incinerator/

co-processing

Total 2146.00 Total 2146.00

Process Type 2:


Fatty acid* 1089.00 Ester 1000.00 Product

Alcohols#

380.00 Recover alcohol 272.00 recycle

Process waste 51.00 To Incinerator/

co-processing Waste water 146.00 To ETP

Total 1469.00 Total 1469.00

Note: * Fatty acid can be anyone of Oleic acid, Lenolic acid, Palmitic acid, Stearic acid, Lauric

acid, Coconut fatty acid, Myristic acid, Caprylic Capric acid, 2-Ethyl hexanoic acid,

Trimellitic anhydride, Benzoic acid, Recinoleic acid

# Alcohol can be anyone of the list provided in Table below:

List of Alcohols

Sr. No.

Material Sr. No.

Material

1. Ethanol 2. Tridecanol

3. 2-Ethyl hexanol 4. Isotridecanol

5. Isopropanol 6. Cetyl alcohol

7. Trimethylolpropane 8. Stearyl alcohol

9. Pentaerythritol 10. Myristyl alcohol

11. Neopentyl glycol 12. Monoethylene glycol

13. Glycerol 14. Myristyl alcohol

15. Cetostearyl alcohol 16. C12-15 alcohol

17. Isodecanol

LIST OF RAW MATERIALS

Name of the product

Raw Materials

RM

Consumption (MT/MT)

RM

Consumption

(MT/Month)$

Esters (Proposed) (240 MT/Year)

Vegetable Oils 1.564 31.28

Fatty Acids 1.089 21.78

Alcohols# 0.582 11.64

$ Indicates the quantity of raw materials calculated based on annual production of the respective products. # indicates use of anyone alcohol from the list of alcohols.

CHEMICAL REACTIONS

C16H34O + C16H32O2 C32H64O2 + H2O Cetyl Alcohol Palmitic Acid Cetyl Palmitate Water C18H38O + C18H36O2 C36H72O2 + H2O Stearyl Alcohol Stearic Acid Stearyl Stearate Water C16H34O + C18H34O2 C34H66O2 + H2O Cetyl Alcohol Oleaic Acid Cetyl Oleate Water C14H30O + C14H28O2 C28H56O2 + H2O Myristyl Alcohol Myristic Acid Myristyl Myristate Water

CH3(CH2)nOH + C18H36O2 + H2O Ceto Stearyl Alcohol Stearic Acid Ceto Stearyl Stearate Water C16H34O + C18H34O3 C34H66O3 + H2O Cetyl Alcohol Ricinoleic Acid Cetyl Ricinoleate Water C3H8O3 + C18H36O2 C21H42O4 + H2O Glycerin Stearic Acid Glycerol Mono Stearate Water C3H8O3 + Coconut Fatty Acid + H2O Glycerin Glyceryl Cocoate Water C14H30O + C18H36O2 C32H64O2 + H2O Myristyl Alcohol Stearic Acid Myristyl Stearate Water 2C3H6O3 + C18H36O2 + NaOH C24H43NaO6 + 3H2O Lactic Acid Stearic Acid Sodium Hydroxide Sodium Stearoyl Lactylate Water

3. WAX BLENDS

b. Manufacturing Process:

This is a simple blending process where selected waxes and oils are blended in the

blending vessel with continuous stirring for 2 hours.

Upon completion of the blending, new wax compound is formed.

There are no bye products or waste materials generated in this process.

List of Products

Candelila Wax

Cocoa Butter

Shea Butter

Carnauba wax

Veganceras NJ

Veganceras SBW

Veganceras DL

Ozokerite wax

Ceresine wax

Chapstick Base

Hard Fat

Emulsifying Ointment

B. Process Flow Diagram

Waxes oils

Wax Blend

Reactor

Process Type 1:


Waxes and oils 1000 Wax Blend 950 Product

Process skinning loss

100 Handling loss

Total 1000 Total 1000

List of waxes and oils

LIST OF RAW MATERIALS

Name of the product

Raw Materials

RM

Consumption (MT/MT)

RM

Consumption

(MT/Month)$

WAX BLENDS(existing )(190mt/annum)

waxes 1.10 33.11

Sr. No.

Material Sr. No.

Material

1. Crude Candelilla wax 2. Crude Cocoa Butter

3. Crude Shea Butter 4. Crude Carnauba Wax

5. Vegetable Wax 6. Sunflower Wax

7. Cetostearyl Alcohol 8. Stearic Acid 9. Castor oil 10. Ester gum

11. Paraffin Wax 12. Microcrystalline Wax 13. Coconut Oil 14. Ozokerite wax

14 Glyceryl Monostearate 15. Caprilyc Capric Triglyceride

16 Emulsifying Wax 17. White Soft Paraffin

18. Liquid Paraffin

Annexure -4 ___________________________________________________________________________ Details of Water Consumption and Wastewater generation Water Consumption and Wastewater generation (Existing)

Note: No change in Water Consumption and Wastewater generation in proposed scenario. Industrial wastewater is treated in ETP and treated wastewater is used in gardening. Domestic waste water is treated in septic tank & disposed in soak pit.

SR. NO.

SECTION (m3/day)

WATER CONSUMPTION

WASTE WATER GENERATION

1. Domestic 1.7 0.7

2. Process 0.6 0.2

3. Boiler 2.1 0.4

4. Cooling & Chilling 1.1 0.3

5. Washing 1.7 1.5

6. Gardening 0.0 0.0

Total 5.5 3.1

Water Balance (KL/Day):

All figures are in KL/day

Fresh Water: 5.5 KL/Day

Domestic: 1.7 Industrial: 3.8

0.7 KL/Day Septic tank & soak pit

Process: 0.6 Washing: 1.7 Boiler: 2.1 Cooling: 1.1

Process: 0.2 Washing: 1.5 Boiler: 0.4 Cooling: 0.3

ETP

Reuse in Gardening

Annexure -5: ___________________________________________________________________________ Details of ETP PROCESS DESCRIPTION: ETP (EFFLUENT TREATMENT PLANT)

The details of ETP are as follows.

Wastewater is collected in Collection tank and Equalization cum Neutralization Tank (ENT-

01) where the continuous addition and stirring of Caustic solution is done to maintain

neutral pH of wastewater from Caustic Dosing Tank (LDT-01) as per requirement by gravity.

Mixer is provided at bottom of the ENT-01 to keep all suspended solids in suspension and to

provide proper mixing by Mixing Mechanism (M-01).

Then after, neutralized wastewater is pumped to Primary Settling tank (PST-01). Alum and

Polyelectrolyte is dosed from Alum Dosing Tank (ADT-01) and Polyelectrolyte Dosing Tank

(PEDT-1) respectively by gravity into PST-01 to carry out coagulation by using a Mixer. Then

after, coagulated wastewater is settled in Primary Settling tank (PST-01). Clear supernatant

from PST-01 shall be sent to aeration tank and then pass through filter press. Clear

supernatant is reused for gardening purpose.

Effluent Treatment Plant (Dimension): SIZE OF TANKS

SR. NO. NAME OF THE UNIT CAPACITY NUBER OF UNIT

01 COLLECTION TANK 5 KL 01

02 EQUILIZATION TANK 5 KL 01

03 AERATION MOTOR 7.5 HP (WITH GEAR BOX) 01

04 FEEDING PUMP 5 HP 01

05 FILTER PRESS 30 PLATE (CLOTH FILTER) 01

Annexure -6 ___________________________________________________________________________Details of hazardous waste generation, storage & disposal

Note: No change in hazardous waste in proposed scenario.

SR.

NO.

NAME OF

WASTE

WASTE

CATEGORY

EXISTING

CAPACITY

PROPOSED

CAPACITY

TOTAL QTY.

MODE OF DISPOSAL

1 ETP Waste 35.3 6 MTA 0 6 MTA Collection, Storage,

Transportation & disposal in

TSDF of M/s. BEIL.

2 Process Waste 26.1 4.8 MTA 0 4.8 MTA Collection, Storage,

Transportation & incineration

at CHWIF of M/s. BEIL or sent

for co-processing in cement

industries.

3 Discarded

Containers

33.1 12,000

No./Y

0 12,000 No./Y Collection, Storage,

Transportation,

Decontamination & reuse or

given to registered vendors.

Annexure -7 ___________________________________________________________________________

Details of flue gas & proposed pollution control equipment

1) Flue Gas Stack

Note: Existing utility sufficient for manufacturing additional new products. * Fuel will be changed from fire wood to agro waste briquette in baby boiler.

2) Process Stack

SR. NO.

PROCESS STACK

ATTACHED TO

HEIGHT FROM

GROUND (m)

DIAMETER (m)

AIR POLLUTION CONTROL SYSTEM

EXPECTED POLLUTANTS

N. A. No process vent is required in existing and proposed scenario.

SR. NO.

STACKS ATTACHED TO HEIGHT FROM

GROUND LEVEL (m)

CONSUMPTION OF FUEL

(KL/hr)

DIAMETER (m)

EXPECTED POLLUTANTS

1 Baby Boiler & Thermic Fluid Heater

11 4.58 SCM/Hr Natural Gas

0.2 PM 150 mg/NM3 SO2 100 ppm NOx 50 ppm

2 Baby Boiler 11 10.41 KG/Hr

Fire Wood* 0.2

3 85 KVA (Stand-by DG set) 9 0.625 Lit/Hr.

Diesel

0.12

Annexure -8

Storage Details of Hazardous Chemicals

Sr.

No.

Name of the

Material

Kind of Storage Max.

quantity to

be stored

(MT)

Storage

condition

i.e. temp.,

pressure

Tank

Dimensions in

(m)

Dyke

Dimensions

1. Glycerine Drum 7 MT Room

temperature

NA NA

2. Fatty Acid Drum 10 MT Room

temperature

NA NA

3. Alcohol Drum 10 MT Room

temperature

NA NA

Annexure – 9

Socio - Economic Impacts

1) Employment Opportunities

The manpower requirement for the proposed expansion project is being expected to

generate some permanent jobs and secondary jobs for the operation and maintenance of

plant. This will increase direct / indirect employment opportunities and ancillary business

development to some extent for the local population.

This phase is expected to create a beneficial impact on the local socio-economic

environment.

2) Industries

Required raw materials and skilled and unskilled laborers will be utilized maximum from the

local area. The increasing industrial activity will boost the commercial and economical status

of the locality, to some extent.

3) Public Health

The company regularly examines, inspects and tests its emission from sources to make sure

that the emission is below the permissible limit. Hence, there will not be any significant

change in the status of sanitation and the community health of the area, as sufficient

measures have been taken and proposed under the EMP.

4) Transportation and Communication

Since the existing factory is having proper linkage for the transport and communication, the

development of this project will not cause any additional impact.

In brief, as a result of the proposed there will be no adverse impact on sanitation,

communication and community health, as sufficient measures have been proposed to be

taken under the EMP. The proposed scenario is not expected to make any significant change

in the existing status of the socio - economic environment of this region.

Annexure-10 __________________________________________________________________________ Proposed Terms of Reference for EIA Studies

1. Project Description

Justification of project.

Promoters and their back ground

Project site location along with site map of 5 km area and site details providing various industries, surface water bodies, forests etc.

Project cost

Project location and Plant layout.

Existing infrastructure facilities

Water source and utilization including proposed water balance.

List of Products & their capacity

Details of manufacturing process of proposed products

List of hazardous chemicals

Mass balance of each product

Storage and Transportation of raw materials and products.

2. Description of the Environment and Baseline Data Collection

Micrometeorological data for wind speed, direction, temperature, humidity and rainfall in 10 km area.

Existing environmental status Vis a Vis air, water, noise, soil in 10 km area from the project site.

Ground water quality at 8 locations within 10 km.

Complete water balance

3. Socio Economic Data

Existing socio-economic status, land use pattern and infrastructure facilities available in the study area were surveyed.

4. Impacts Identification And Mitigatory Measures • Identification of impacting activities from the proposed project during construction and

operational phase. • Impact on air and mitigation measures including green belt • Impact on water environment and mitigation measures • Soil pollution source and mitigation measures • Noise generation and control. • Solid waste quantification and disposal. • Control of fugitive emissions 5. Environmental Management Plan • Details of pollution control measures • Environment management team • Proposed schedule for environmental monitoring including post project

6. Risk Assessment • Objectives, Philosophy and methodology of risk assessment • Details on storage facilities • Process safety, transportation, fire fighting systems, safety features and emergency

capabilities to be adopted. • Identification of hazards • Consequence analysis • Recommendations on the basis of risk assessment done • Disaster Management Plan. 7. Information for Control of Fugitive Emissions

8. Information on Rain Water Harvesting

9. Green Belt Development plan

Annexure-11 __________________________________________________________________________ Plot Allotment Letter

Annexure-12 __________________________________________________________________________ Copy of CC&A

list of annexures sr. no. name of annexure€¦ · 4 mono butyl tin oxide 0.75 mt/month 2273-43-0...

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