density (ρ) (g /cm3) viscosity(η)/ mPa s speed of sound (u) / m s-1

Pure components Experimental Literature Experimental Literature Experimental Literature2-chloroaniline 1.20269 1.20270[9] 3.8256 3.8256[9] 1469.6 1471[10]Toluene 0.85762 0.85764[11] 0.527 0.526[13] 1272.5 1262[14]o-xylene 0.87132 0.87131[11] 0.708 0.708[13] 1337.5 1322[14]m-xylene 0.85575 0.85574[12] 0.553 0.552[13] 1302.5 1283[14]

Table 1 Mole fraction of 2-chloroaniline (x1), density (ρ), excess volumes (VE),viscosity (η), viscosity deviation(η) ,excess Gibbs free energy of

activation of viscous flow (G*E),Grunberg-Nissan interaction parameters(d12),Katti-Chaudhri interaction parameters (Wvis/RT), and Hind

interaction parameters (H12) , Tamura and Kurata (T12 ) and Heric-Brewer (∆12 ) equations for binary mixtures at 303.15 K , 308.15 K , 313.15

K, and 318.15 K.

2-chloroaniline+ Toluene 303.15 Kx1 ρ (g /cm3) VE/(cm3/mol1) η /mPa.s η/ mPa.s G*E J / mol1 W vis/ RT d12 H12 T12 ∆12

0.0000 0.85762 0.0000 0.5270 0.000 0.0000.0821 0.88553 -0.0561 0.8722 0.074 8.477 4.520 4.526 2.67 2.705 4.5760.1801 0.91895 -0.1063 1.2633 0.142 12.852 3.497 3.503 2.658 2.692 3.5520.2698 0.94963 -0.1379 1.6029 0.186 14.345 2.926 2.932 2.648 2.680 2.9800.3605 0.98074 -0.1574 1.9295 0.213 14.483 2.524 2.530 2.639 2.670 2.5770.4712 1.01885 -0.1656 2.3064 0.225 13.460 2.170 2.176 2.628 2.657 2.2220.5748 1.05465 -0.1592 2.6382 0.215 11.695 1.923 1.928 2.617 2.644 1.9740.6805 1.09129 -0.1394 2.9570 0.185 9.323 1.723 1.728 2.602 2.628 1.7730.7825 1.12676 -0.1080 3.2472 0.139 6.628 1.565 1.570 2.585 2.609 1.6140.8956 1.16620 -0.0590 3.5528 0.072 3.297 1.417 1.422 2.559 2.582 1.4651.0000 1.20269 0.0000 3.8256 0.000 0.000

2-chloroaniline+ Toluene 313.15 Kx1 ρ (g /cm3) VE/(cm3/mol1) η /mPa.s η/ mPa.s G*E J / mol1 W vis/ RT d12 H12 T12 ∆12

0.0000 0.84823 -0.0796 0.6855 0.006 0.0000.0821 0.87622 -0.1393 0.9984 0.064 5.882 3.036 3.045 1.801 1.826 3.0950.1801 0.90962 -0.1715 1.3029 0.136 10.801 2.845 2.853 1.982 2.008 2.9020.2698 0.94023 -0.1877 1.6038 0.202 13.302 2.626 2.634 2.109 2.137 2.6820.3605 0.97127 -0.1939 1.9376 0.249 14.256 2.405 2.412 2.202 2.228 2.4590.4712 1.00931 -0.1892 2.2042 0.247 13.767 2.149 2.155 2.263 2.288 2.2020.5748 1.04511 -0.1725 2.4307 0.199 12.074 1.922 1.928 2.268 2.291 1.9730.6805 1.08179 -0.1448 2.6191 0.123 9.483 1.697 1.703 2.221 2.243 1.7480.7825 1.11734 -0.0874 2.8258 0.036 6.479 1.481 1.488 2.125 2.145 1.5320.8956 1.15676 0.0000 3.0602 0.000 2.978 1.239 1.247 1.958 1.979 1.2891.0000 1.19302 -0.0796 0.6855 0.006 0.000

2-chloroaniline+ Toluene 308.15 Kx1 ρ (g /cm3) VE/(cm3/mol1) η /mPa.s η/ mPa.s G*E J / mol1 W vis/ RT d12 H12 T12 ∆12

0.0000 0.85295 0.0000 0.498 0.000 0.0000.0821 0.88092 -0.0696 0.7912 0.054 7.701 4.039 4.047 2.313 2.345 4.0970.1801 0.91435 -0.1251 1.1425 0.120 12.212 3.269 3.276 2.36 2.391 3.3250.2698 0.94500 -0.1561 1.4566 0.172 13.983 2.806 2.812 2.393 2.422 2.8610.3605 0.97608 -0.1732 1.7603 0.212 14.355 2.461 2.467 2.414 2.443 2.5150.4712 1.01416 -0.1794 2.1054 0.234 13.493 2.140 2.146 2.425 2.452 2.1930.5748 1.04997 -0.1737 2.3998 0.227 11.761 1.902 1.908 2.419 2.444 1.9530.6805 1.08666 -0.1565 2.6724 0.191 9.340 1.698 1.704 2.395 2.418 1.7480.7825 1.12218 -0.1273 2.9141 0.136 6.570 1.526 1.532 2.354 2.376 1.5760.8956 1.16164 -0.0748 3.1699 0.062 3.203 1.354 1.361 2.286 2.308 1.4041.0000 1.19802 0.0000 3.4122 0.000 0.000

2-chloroaniline+ Toluene 318.15 Kx1 ρ (g /cm3) VE/(cm3/mol1) η /mPa.s η/ mPa.s G*E J / mol1 W vis/ RT d12 H12 T12 ∆12

0.0000 0.84435 0.0000 0.4350 0.000 0.0000.0821 0.87235 -0.0907 0.6243 -0.002 5.369 2.771 2.781 1.587 1.609 2.8320.1801 0.90570 -0.1546 0.9099 0.056 10.380 2.734 2.743 1.787 1.812 2.7920.2698 0.93627 -0.1893 1.1915 0.129 13.044 2.575 2.583 1.925 1.950 2.6320.3605 0.96722 -0.2037 1.4682 0.194 14.099 2.379 2.386 2.02 2.044 2.4330.4712 1.00518 -0.2082 1.7687 0.237 13.625 2.127 2.134 2.074 2.097 2.1800.5748 1.04091 -0.2026 2.0001 0.228 11.865 1.888 1.895 2.064 2.085 1.9400.6805 1.07755 -0.1877 2.1894 0.171 9.169 1.640 1.648 1.991 2.011 1.6920.7825 1.11304 -0.1592 2.3453 0.089 6.096 1.393 1.401 1.861 1.881 1.4450.8956 1.15241 -0.1009 2.5281 0.009 2.663 1.108 1.117 1.647 1.668 1.1601.0000 1.18849 0.0000 2.7621 0.000 0.000

2-chloroaniline + o-xylene 303.15 Kx1 ρ (g /cm3) VE/(cm3/mol1) η /mPa.s η/ mPa.s G*E J / mol1 W vis/ RT d12 H12 T12 ∆12

0.0000 0.87132 0.0000 0.708 0.000 0.0000.0805 0.89432 0.0634 0.7832 -0.176 -0.837 -0.454 -0.471 1.080 1.121 4.2010.1856 0.92514 0.1336 0.9066 -0.380 -1.577 -0.419 -0.436 1.010 1.065 1.7320.2856 0.95537 0.1840 1.0592 -0.539 -1.879 -0.370 -0.387 0.946 1.017 1.1320.3751 0.98323 0.2135 1.2296 -0.648 -1.911 -0.328 -0.345 0.885 0.971 0.9090.4789 1.01657 0.2280 1.4758 -0.725 -1.718 -0.277 -0.294 0.814 0.92 0.8070.5761 1.04884 0.2217 1.7628 -0.741 -1.377 -0.227 -0.244 0.749 0.875 0.8070.6805 1.08469 0.1943 2.1386 -0.691 -0.963 -0.178 -0.196 0.678 0.827 0.8940.7859 1.12220 0.1464 2.5987 -0.559 -0.560 -0.134 -0.152 0.604 0.78 1.1360.8952 1.16256 0.0785 3.171 -0.328 -0.229 -0.098 -0.116 0.520 0.725 1.9641.0000 1.20269 0.0000 3.8256 0.000 0.000

2-chloroaniline + o-xylene 308.15 Kx1 ρ (g /cm3) VE/(cm3/mol1) η /mPa.s η/ mPa.s G*E J / mol1 W vis/ RT d12 H12 T12 ∆12

0.0000 0.86707 0.0000 0.664 0.000 0.0000.0805 0.88990 0.0795 0.7201 -0.165 -1.247 -0.666 -0.684 0.923 0.956 3.9870.1856 0.92061 0.1562 0.8262 -0.348 -2.088 -0.546 -0.564 0.887 0.935 1.6030.2856 0.95079 0.2051 0.9619 -0.487 -2.356 -0.456 -0.475 0.845 0.907 1.0450.3751 0.97863 0.2314 1.1153 -0.580 -2.305 -0.389 -0.407 0.802 0.878 0.8470.4789 1.01193 0.2435 1.3342 -0.646 -2.063 -0.327 -0.345 0.744 0.838 0.7570.5761 1.04415 0.2378 1.5879 -0.659 -1.684 -0.273 -0.291 0.688 0.8 0.7610.6805 1.07992 0.2134 1.9183 -0.616 -1.236 -0.225 -0.243 0.622 0.755 0.8460.7859 1.11737 0.1681 2.3224 -0.501 -0.787 -0.185 -0.204 0.548 0.705 1.0830.8952 1.15772 0.0965 2.8263 -0.298 -0.380 -0.160 -0.180 0.451 0.635 1.9011.0000 1.19802 0.0000 3.4122 0.000 0.000

2-chloroaniline + o-xylene 313.15 Kx1 ρ (g /cm3) VE/(cm3/mol1) η /mPa.s η/ mPa.s G*E J / mol1 W vis/ RT d12 H12 T12 ∆12

0.0000 0.86282 0.0000 0.623 0.000 0.0000.0805 0.88550 0.0910 0.6618 -0.157 -1.703 -0.085 -0.914 0.779 0.803 3.7570.1856 0.91596 0.1890 0.7507 -0.325 -2.723 -0.066 -0.721 0.768 0.808 1.4470.2856 0.94586 0.2630 0.8726 -0.446 -2.918 -0.053 -0.577 0.747 0.802 0.9430.3751 0.97351 0.3010 1.0117 -0.526 -2.761 -0.043 -0.479 0.721 0.788 0.7750.4789 1.00672 0.3106 1.2099 -0.580 -2.400 -0.035 -0.395 0.679 0.763 0.7070.5761 1.03890 0.2980 1.4351 -0.592 -1.992 -0.030 -0.338 0.630 0.73 0.7140.6805 1.07469 0.2610 1.7263 -0.555 -1.528 -0.026 -0.294 0.565 0.684 0.7960.7859 1.11219 0.2010 2.0824 -0.456 -1.045 -0.023 -0.262 0.487 0.628 1.0250.8952 1.15265 0.1100 2.5327 -0.272 -0.525 -0.021 -0.239 0.392 0.559 1.8421.0000 1.19302 0.0000 3.0602 0.000 0.000

2-chloroaniline + o-xylene 318.15 Kx1 ρ (g /cm3) VE/(cm3/mol1) η /mPa.s η/ mPa.s G*E J / mol1 W vis/ RT d12 H12 T12 ∆12

0.0000 0.85865 0.0000 0.595 0.000 0.0000.0805 0.88116 0.1086 0.6171 -0.152 -2.234 -1.156 -1.177 0.649 0.667 3.4940.1856 0.91164 0.1966 0.6950 -0.302 -3.306 -0.837 -0.858 0.679 0.713 1.3100.2856 0.94170 0.2435 0.8036 -0.410 -3.496 -0.656 -0.676 0.673 0.721 0.8440.3751 0.96947 0.2637 0.9289 -0.479 -3.287 -0.537 -0.556 0.657 0.717 0.6980.4789 1.00268 0.2699 1.1085 -0.524 -2.825 -0.433 -0.453 0.628 0.703 0.6490.5761 1.03478 0.2636 1.3094 -0.534 -2.374 -0.372 -0.392 0.585 0.675 0.6600.6805 1.07041 0.2421 1.5681 -0.502 -1.862 -0.328 -0.348 0.525 0.632 0.7420.7859 1.10773 0.1976 1.8851 -0.413 -1.301 -0.296 -0.317 0.451 0.579 0.9710.8952 1.14798 0.1251 2.2844 -0.251 -0.702 -0.286 -0.309 0.343 0.496 1.7711.0000 1.18849 0.0000 2.7621 0.000 0.000

2-chloroaniline + m-xylene 303.15 Kx1 ρ (g /cm3) VE/(cm3/mol1) η /mPa.s η/ mPa.s G*E J / mol1 W vis/ RT d12 H12 T12 ∆12

0.0000 0.85575 0.0000 0.553 0.000 0.0000.0896 0.88205 0.0866 0.6181 -0.228 -1.503 -0.740 -0.761 0.791 0.832 0.7430.1798 0.90935 0.1536 0.7127 -0.429 -2.267 -0.618 -0.638 0.736 0.793 0.6210.2798 0.94067 0.2008 0.8533 -0.615 -2.570 -0.512 -0.533 0.663 0.740 0.5150.3912 0.97683 0.2314 1.0642 -0.769 -2.417 -0.408 -0.428 0.575 0.677 0.4110.4951 1.01185 0.2407 1.3213 -0.852 -2.025 -0.326 -0.346 0.485 0.614 0.3290.5894 1.04477 0.2333 1.6137 -0.868 -1.593 -0.264 -0.285 0.396 0.550 0.2690.6812 1.07793 0.2101 1.9607 -0.822 -1.175 -0.217 -0.239 0.298 0.481 0.2220.7958 1.12093 0.1633 2.5006 -0.657 -0.665 -0.164 -0.186 0.168 0.391 0.1700.8925 1.15873 0.1038 3.0605 -0.413 -0.324 -0.136 -0.159 0.035 0.296 0.1431.0000 1.20269 0.0000 3.8256 0.000 0.000

2-chloroaniline + m-xylene 308.15 Kx1 ρ (g /cm3) VE/(cm3/mol1) η /mPa.s η/ mPa.s G*E J / mol1 W vis/ RT d12 H12 T12 ∆12

0.0000 0.85147 0.0000 0.523 0.000 0.0000.0896 0.87760 0.1033 0.5699 -0.212 -2.033 -0.985 -1.007 0.668 0.700 0.9900.1798 0.90485 0.1702 0.6488 -0.394 -2.997 -0.803 -0.825 0.633 0.681 0.8070.2798 0.93609 0.2190 0.7768 -0.555 -3.161 -0.620 -0.641 0.591 0.659 0.6240.3912 0.97220 0.2485 0.9679 -0.685 -2.862 -0.475 -0.496 0.529 0.620 0.4790.4951 1.00718 0.2567 1.1984 -0.755 -2.380 -0.376 -0.398 0.457 0.572 0.3810.5894 1.04004 0.2508 1.4582 -0.768 -1.894 -0.309 -0.331 0.381 0.519 0.3140.6812 1.07315 0.2291 1.7632 -0.728 -1.455 -0.265 -0.287 0.292 0.455 0.2710.7958 1.11610 0.1828 2.2368 -0.585 -0.900 -0.219 -0.242 0.166 0.365 0.2260.8925 1.15397 0.1140 2.73 -0.372 -0.485 -0.200 -0.224 0.031 0.265 0.2081.0000 1.19802 0.0000 3.4122 0.000 0.000

2-chloroaniline + m-xylene 318.15 Kx1 ρ (g /cm3) VE/(cm3/mol1) η /mPa.s η/ mPa.s G*E J / mol1 W vis/ RT d12 H12 T12 ∆12

0.0000 0.84318 0.0000 0.471 0.000 0.0000.0896 0.86899 0.1313 0.4874 -0.189 -3.142 -1.498 -1.523 0.459 0.476 1.5050.1798 0.89599 0.2132 0.5443 -0.339 -4.368 -1.152 -1.176 0.468 0.503 1.1590.2798 0.92706 0.2642 0.6455 -0.467 -4.499 -0.868 -0.892 0.459 0.511 0.8740.3912 0.96304 0.2893 0.8019 -0.565 -3.971 -0.649 -0.671 0.430 0.502 0.6540.4951 0.99788 0.2951 0.9885 -0.617 -3.310 -0.515 -0.538 0.383 0.475 0.5210.5894 1.03063 0.2868 1.1977 -0.624 -2.666 -0.429 -0.452 0.328 0.439 0.4350.6812 1.06359 0.2678 1.4394 -0.592 -2.126 -0.381 -0.405 0.253 0.385 0.3880.7958 1.10642 0.2187 1.8132 -0.481 -1.429 -0.342 -0.367 0.136 0.298 0.3510.8925 1.14419 0.1481 2.2097 -0.306 -0.780 -0.316 -0.344 0.021 0.213 0.3281.0000 1.18849 0.0000 2.7621 0.000 0.000

2-chloroaniline + m-xylene 313.15 Kx1 ρ (g /cm3) VE/(cm3/mol1) η /mPa.s η/ mPa.s G*E J / mol1 W vis/ RT d12 H12 T12 ∆12

0.0000 0.84718 0.0000 0.496 0.000 0.0000.0896 0.87309 0.1245 0.5277 -0.198 -2.550 -1.216 -1.240 0.564 0.588 1.2230.1798 0.90010 0.2140 0.5918 -0.365 -3.781 -0.997 -1.021 0.54 0.580 1.0040.2798 0.93112 0.2793 0.7065 -0.507 -3.873 -0.748 -0.771 0.52 0.580 0.754

0.3912 0.96704 0.3185 0.8813 -0.618 -3.376 -0.551 -0.575 0.481 0.562 0.5580.4951 1.00189 0.3285 1.0885 -0.677 -2.802 -0.436 -0.460 0.424 0.526 0.4430.5894 1.03470 0.3174 1.3182 -0.689 -2.293 -0.369 -0.393 0.354 0.478 0.3760.6812 1.06779 0.2879 1.5900 -0.653 -1.781 -0.319 -0.344 0.275 0.421 0.3270.7958 1.11083 0.2222 2.0072 -0.529 -1.184 -0.283 -0.309 0.149 0.328 0.2920.8925 1.14880 0.1365 2.4493 -0.335 -0.631 -0.256 -0.282 0.031 0.242 0.2661.0000 1.19302 0.0000 3.0602 0.000 0.000

2-chloroaniline + p-xylene 303.15 Kx1 ρ (g /cm3) VE/(cm3/mol1) η /mPa.s η/ mPa.s G*E J / mol1 W vis/ RT d12 H12 T12 ∆12

0.0000 0.85245 0.0000 0.573 0.000 0.0000.0895 0.87869 0.1142 0.5711 -0.293 -4.262 -2.102 -2.125 0.402 0.415 2.0990.1795 0.90606 0.1869 0.6466 -0.510 -5.389 -1.470 -1.493 0.467 0.510 0.7390.3125 0.94825 0.2435 0.8281 -0.761 -5.482 -1.025 -1.047 0.428 0.506 0.3730.4256 0.98574 0.2626 1.0515 -0.906 -4.868 -0.800 -0.822 0.347 0.456 0.3430.5169 1.01709 0.2658 1.3018 -0.953 -3.864 -0.622 -0.644 0.292 0.429 0.4290.6254 1.05567 0.2568 1.6443 -0.963 -3.182 -0.546 -0.568 0.144 0.317 0.4880.7145 1.08853 0.2362 1.9932 -0.904 -2.616 -0.515 -0.539 0.126 0.191 0.5910.8102 1.12514 0.1938 2.4333 -0.775 -2.197 -0.574 -0.599 0.100 0.157 0.7790.9012 1.16141 0.1239 2.9994 -0.505 -1.328 -0.599 -0.626 0.086 0.132 1.5531.0000 1.20269 0.0000 3.8256 0.000 0.000

2-chloroaniline + p-xylene 308.15 Kx1 ρ (g /cm3) VE/(cm3/mol1) η /mPa.s η/ mPa.s G*E J / mol1 W vis/ RT d12 H12 T12 ∆12

0.0000 0.84815 0.0000 0.542 0.000 0.0000.0895 0.87425 0.1275 0.5234 -0.276 -4.998 -2.424 -2.450 0.287 0.291 1.7750.1795 0.90153 0.2053 0.5823 -0.475 -6.453 -1.732 -1.756 0.365 0.398 0.476

0.3125 0.94364 0.2612 0.7616 -0.677 -5.816 -1.070 -1.093 0.401 0.47 0.3280.4256 0.98109 0.2772 0.9713 -0.792 -4.910 -0.794 -0.817 0.357 0.455 0.3480.5169 1.01242 0.2785 1.1738 -0.852 -4.367 -0.691 -0.714 0.271 0.393 0.3590.6254 1.05097 0.2688 1.4632 -0.874 -3.847 -0.649 -0.672 0.112 0.267 0.3840.7145 1.08379 0.2485 1.7593 -0.834 -3.346 -0.648 -0.673 0.066 0.121 0.4570.8102 1.12038 0.2059 2.1658 -0.702 -2.566 -0.660 -0.685 0.104 0.107 0.6930.9012 1.15665 0.1332 2.6739 -0.455 -1.508 -0.669 -0.697 0.277 0.093 1.4821.0000 1.19802 0.0000 3.4122 0.000 0.000

2-chloroaniline + p-xylene 313.15 Kx1 ρ (g /cm3) VE/(cm3/mol1) η /mPa.s η/ mPa.s G*E J / mol1 W vis/ RT d12 H12 T12 ∆12

0.0000 0.84379 0.0000 0.518 0.000 0.0000.0895 0.86967 0.1488 0.4759 -0.270 -6.208 -2.963 -2.991 0.135 0.128 1.2340.1795 0.89672 0.2480 0.5234 -0.451 -7.832 -2.068 -2.095 0.258 0.283 0.1370.3125 0.93852 0.3297 0.6957 -0.617 -6.544 -1.185 -1.211 0.354 0.415 0.2100.4256 0.97576 0.3579 0.8984 -0.702 -5.118 -0.814 -0.840 0.354 0.442 0.3250.5169 1.00698 0.3608 1.0884 -0.744 -4.350 -0.678 -0.703 0.300 0.409 0.3690.6254 1.04549 0.3436 1.3506 -0.757 -3.765 -0.625 -0.651 0.173 0.31 0.4050.7145 1.07835 0.3101 1.6113 -0.723 -3.311 -0.631 -0.658 0.117 0.182 0.4710.8102 1.11505 0.2481 1.9653 -0.612 -2.606 -0.659 -0.688 0.102 0.101 0.6900.9012 1.15148 0.1546 2.4085 -0.401 -1.576 -0.689 -0.718 0.080 0.021 1.4601.0000 1.19302 0.0000 3.0602 0.000 0.000

2-chloroaniline + p-xylene 318.15 Kx1 ρ (g /cm3) VE/(cm3/mol1) η /mPa.s η/ mPa.s G*E J / mol1 W vis/ RT d12 H12 T12 ∆12

0.0000 0.83964 0.0000 0.496 0.000 0.0000.0895 0.86548 0.1478 0.4527 -0.246 -6.345 -2.981 -3.008 0.119 0.111 1.2160.1795 0.89254 0.2396 0.4928 -0.410 -8.119 -2.110 -2.137 0.237 0.258 0.0950.3125 0.93437 0.3091 0.646 -0.558 -6.976 -1.243 -1.268 0.330 0.384 0.1520.4256 0.97161 0.3326 0.8259 -0.635 -5.612 -0.879 -0.904 0.331 0.409 0.261

0.5169 1.00278 0.3377 0.9937 -0.674 -4.870 -0.747 -0.772 0.280 0.378 0.3010.6254 1.04117 0.3294 1.2246 -0.689 -4.285 -0.700 -0.726 0.159 0.283 0.3310.7145 1.07392 0.3065 1.455 -0.660 -3.793 -0.712 -0.739 0.111 0.161 0.3910.8102 1.11049 0.2549 1.7702 -0.562 -2.992 -0.745 -0.774 0.198 0.101 0.6040.9012 1.14685 0.1652 2.1692 -0.369 -1.808 -0.777 -0.808 0.443 0.122 1.3701.0000 1.18849 0.0000 2.7621 0.000 0.000

Table 2 Mole fraction of 2-chloroaniline (x1), viscosity (η), Theoretical values of Grunberg and Nissan (Eq.10), Katti and Chaudhri (Eq.11) and

Hind et al., (Eq.12), and Heric Brewer (Eq.13) including standard deviation(SD) for binary mixtures at 303.15 K , 308.15 K , 313.15 K, and

318.15 K.

2-chloroaniline (1)+ toluene (2)

303.15 K 308.15 Kx1 η /mPa.s Eq.10 Eq.11 Eq.12 Eq.13 η /mPa.s Eq.10 Eq.11 Eq.12 Eq.13

0.0000 0.527 0.527 0.527 0.527 0.527 0.498 0.498 0.498 0.498 0.4980.0821 0.8722 0.758 0.757 0.873 0.758 0.7912 0.704 0.706 0.792 0.7040.1801 1.2633 1.115 1.116 1.263 1.115 1.1425 1.019 1.020 1.143 1.0190.2698 1.6029 1.519 1.518 1.602 1.519 1.4566 1.371 1.373 1.456 1.3710.3605 1.9295 1.988 1.981 1.929 1.988 1.7603 1.775 1.779 1.761 1.7750.4712 2.3064 2.602 2.601 2.305 2.601 2.1054 2.302 2.299 2.104 2.3010.5748 2.6382 3.155 3.159 2.639 3.153 2.3998 2.777 2.771 2.398 2.7750.6805 2.9570 3.621 3.630 2.956 3.619 2.6724 3.180 3.172 2.673 3.1790.7825 3.2472 3.909 3.922 3.246 3.907 2.9141 3.439 3.432 2.913 3.4370.8956 3.5528 3.989 4.006 3.552 3.988 3.1699 3.528 3.520 3.169 3.5271.0000 3.8256 3.826 3.826 3.826 3.826 3.4122 3.412 3.412 3.412 3.412

SD 0.3832 0.3895 0.0085 0.3822 0.2953 0.2909 0.0143 0.2945

2-chloroaniline (1)+ toluene (2)313.15 K 318.15 K

x1 η /mPa.s Eq.10 Eq.11 Eq.12 Eq.13 η /mPa.s Eq.10 Eq.11 Eq.12 Eq.130.0000 0.467 0.467 0.467 0.467 0.467 0.435 0.435 0.435 0.435 0.4350.0883 0.6855 0.645 0.647 0.684 0.645 0.6243 0.595 0.597 0.622 0.5950.1789 0.9984 0.912 0.913 0.997 0.912 0.9099 0.834 0.834 0.908 0.8340.2719 1.3029 1.206 1.207 1.303 1.206 1.1915 1.095 1.096 1.191 1.0940.3675 1.6038 1.542 1.545 1.603 1.542 1.4682 1.391 1.394 1.469 1.3910.4656 1.9376 1.979 1.977 1.936 1.979 1.7687 1.777 1.775 1.767 1.7770.5666 2.2042 2.379 2.374 2.206 2.379 2.0001 2.130 2.126 1.999 2.1290.6703 2.4307 2.732 2.725 2.432 2.731 2.1894 2.443 2.437 2.189 2.4430.7771 2.6191 2.977 2.972 2.619 2.976 2.3453 2.665 2.661 2.346 2.6640.8869 2.8258 3.101 3.095 2.824 3.100 2.5281 2.785 2.780 2.527 2.7841.0000 3.0602 3.060 3.060 3.060 3.060 2.7621 2.762 2.762 2.762 2.762

SD 0.1870 0.1831 0.0454 0.1865 0.1649 0.1616 0.0512 0.16442-chloroaniline (1)+ o-xylene (2)

303.15 K 308.15 Kx1 η /mPa.s Eq.10 Eq.11 Eq.12 Eq.13 η /mPa.s Eq.10 Eq.11 Eq.12 Eq.13

0.0000 0.708 0.708 0.708 0.708 0.708 0.664 0.664 0.664 0.664 0.6640.0805 0.7832 0.785 0.782 0.783 0.785 0.7201 0.731 0.734 0.721 0.7310.1856 0.9066 0.907 0.904 0.906 0.907 0.8262 0.836 0.839 0.825 0.8370.2856 1.0592 1.049 1.046 1.057 1.049 0.9619 0.960 0.964 0.962 0.9600.3751 1.2296 1.204 1.196 1.228 1.204 1.1153 1.096 1.102 1.117 1.096

0.4789 1.4758 1.424 1.417 1.474 1.424 1.3342 1.289 1.295 1.334 1.2890.5761 1.7628 1.682 1.674 1.762 1.682 1.5879 1.515 1.523 1.586 1.5150.6805 2.1386 2.030 2.023 2.136 2.029 1.9183 1.821 1.828 1.917 1.8210.7859 2.5987 2.477 2.476 2.597 2.477 2.3224 2.216 2.222 2.321 2.2160.8952 3.1710 3.077 3.082 3.172 3.077 2.8263 2.747 2.749 2.827 2.7471.0000 3.8256 3.826 3.826 3.826 3.826 3.4122 3.412 3.412 3.412 3.412

SD 0.1831 0.8137 0.0472 0.1687 0.2127 0.2461 0.0397 0.1994

2-chloroaniline (1)+ o-xylene (2)313.15 K 318.15 K

x1 η /mPa.s Eq.10 Eq.11 Eq.12 Eq.13 η /mPa.s Eq.10 Eq.11 Eq.12 Eq.130.0000 0.623 0.623 0.623 0.623 0.623 0.595 0.595 0.595 0.595 0.5950.0805 0.6618 0.681 0.684 0.662 0.681 0.6171 0.645 0.648 0.616 0.6450.1856 0.7507 0.773 0.776 0.752 0.773 0.6950 0.725 0.727 0.694 0.7250.2856 0.8726 0.881 0.884 0.872 0.881 0.8036 0.819 0.822 0.8044 0.8190.3751 1.0117 1.000 1.006 1.012 1.000 0.9289 0.923 0.929 0.927 0.9240.4789 1.2099 1.170 1.176 1.2081 1.170 1.1085 1.073 1.078 1.108 1.0730.5761 1.4351 1.370 1.377 1.433 1.370 1.3094 1.250 1.256 1.309 1.2500.6805 1.7263 1.641 1.647 1.729 1.640 1.5681 1.490 1.496 1.569 1.4900.7859 2.0824 1.991 1.997 2.084 1.991 1.8851 1.803 1.808 1.886 1.8030.8952 2.5327 2.465 2.467 2.533 2.464 2.2844 2.227 2.229 2.284 2.2261.0000 3.0602 3.060 3.060 3.060 3.060 2.7621 2.762 2.762 2.762 2.762

SD 0.216 0.2731 0.0337 0.2292 0.2702 0.3003 0.0291 0.2586

2-chloroaniline (1)+ m-xylene (2)313.15 K 318.15 K

x1 η /mPa.s Eq.10 Eq.11 Eq.12 Eq.13 η /mPa.s Eq.10 Eq.11 Eq.12 Eq.130.0000 0.496 0.496 0.496 0.496 0.496 0.471 0.471 0.471 0.471 0.4710.0896 0.5277 0.561 0.562 0.526 0.561 0.4874 0.527 0.528 0.487 0.5270.1798 0.5918 0.640 0.643 0.594 0.640 0.5443 0.595 0.598 0.543 0.5950.2798 0.7065 0.747 0.750 0.706 0.747 0.6455 0.688 0.692 0.647 0.6890.3912 0.8813 0.898 0.900 0.888 0.898 0.8019 0.821 0.823 0.802 0.8210.4951 1.0885 1.079 1.080 1.088 1.079 0.9885 0.980 0.981 0.987 0.9800.5894 1.3182 1.286 1.289 1.317 1.286 1.1977 1.163 1.166 1.196 1.163

2-chloroaniline (1)+ m-xylene (2)303.15 K 308.15 K

x1 η /mPa.s Eq.10 Eq.11 Eq.12 Eq.13 η /mPa.s Eq.10 Eq.11 Eq.12 Eq.130.0000 0.553 0.553 0.553 0.553 0.553 0.523 0.523 0.523 0.523 0.5230.0896 0.6181 0.637 0.636 0.617 0.637 0.5699 0.597 0.599 0.569 0.5970.1798 0.7127 0.740 0.737 0.713 0.740 0.6488 0.687 0.691 0.647 0.6870.2798 0.8533 0.879 0.876 0.852 0.879 0.7768 0.810 0.814 0.776 0.8100.3912 1.0642 1.075 1.073 1.063 1.076 0.9679 0.982 0.984 0.967 0.9820.4951 1.3213 1.309 1.307 1.322 1.309 1.1984 1.187 1.189 1.199 1.1870.5894 1.6137 1.576 1.573 1.615 1.575 1.4582 1.422 1.425 1.459 1.4220.6812 1.9607 1.900 1.894 1.961 1.900 1.7632 1.708 1.714 1.762 1.7070.7958 2.5006 2.421 2.427 2.501 2.421 2.2368 2.168 2.169 2.235 2.1680.8925 3.0605 2.995 2.998 3.061 2.995 2.730 2.675 2.679 2.729 2.6751.0000 3.8256 3.826 3.826 3.826 3.826 3.4122 3.412 3.412 3.412 3.412

SD 0.2231 0.2292 0.0672 0.2098 0.2540 0.2804 0.0555 0.2416

0.6812 1.5900 1.538 1.544 1.591 1.538 1.4394 1.388 1.393 1.436 1.3880.7958 2.0072 1.947 1.949 2.002 1.947 1.8132 1.754 1.755 1.812 1.7530.8925 2.4493 2.400 2.403 2.448 2.399 2.2097 2.162 2.165 2.208 2.1611.0000 3.0602 3.060 3.060 3.060 3.060 2.7621 2.762 2.762 2.762 2.762

SD 0.5609 0.5875 0.1097 0.5453 0.5856 0.6020 0.1026 0.5709

2-chloroaniline (1)+ p-xylene (2)303.15 K 308.15 K

x1 η /mPa.s Eq.10 Eq.11 Eq.12 Eq.13 η /mPa.s Eq.10 Eq.11 Eq.12 Eq.130.0000 0.573 0.573 0.573 0.573 0.573 0.542 0.542 0.542 0.542 0.5420.0895 0.5711 0.629 0.627 0.571 0.629 0.5234 0.586 0.588 0.521 0.5860.1795 0.6466 0.701 0.697 0.646 0.702 0.5823 0.645 0.649 0.584 0.6450.3125 0.8281 0.847 0.848 0.827 0.847 0.7616 0.767 0.765 0.764 0.7670.4256 1.0515 1.021 1.024 1.051 1.022 0.9713 0.915 0.911 0.971 0.9150.5169 1.3018 1.209 1.209 1.305 1.209 1.1738 1.076 1.073 1.176 1.0760.6254 1.6443 1.507 1.513 1.644 1.507 1.4632 1.336 1.330 1.468 1.3360.7145 1.9932 1.836 1.840 1.995 1.836 1.7593 1.625 1.621 1.753 1.6250.8102 2.4333 2.309 2.317 2.433 2.309 2.1658 2.044 2.041 2.163 2.0440.9012 2.9994 2.917 2.922 2.998 2.916 2.6739 2.588 2.588 2.673 2.5881.0000 3.8256 3.826 3.826 3.826 3.826 3.4122 3.412 3.412 3.412 3.412

SD 0.6060 0.6223 0.0752 0.5923 0.5889 0.6045 0.0719 0.5760

2-chloroaniline (1)+ p-xylene (2)313.15 K 318.15 K

x1 η /mPa.s Eq.10 Eq.11 Eq.12 Eq.13 η /mPa.s Eq.10 Eq.11 Eq.12 Eq.130.0000 0.518 0.518 0.518 0.518 0.518 0.496 0.496 0.496 0.496 0.4960.0895 0.4759 0.552 0.554 0.476 0.552 0.4527 0.523 0.525 0.453 0.5230.1795 0.5234 0.599 0.603 0.523 0.600 0.4928 0.563 0.566 0.493 0.5630.3125 0.6957 0.701 0.700 0.694 0.702 0.6460 0.650 0.649 0.648 0.6500.4256 0.8984 0.828 0.824 0.896 0.828 0.8259 0.761 0.758 0.824 0.7610.5169 1.0884 0.968 0.966 1.089 0.968 0.9937 0.885 0.882 0.997 0.8850.6254 1.3506 1.195 1.190 1.350 1.195 1.2246 1.086 1.082 1.224 1.0860.7145 1.6113 1.451 1.448 1.613 1.451 1.4550 1.314 1.311 1.458 1.3140.8102 1.9653 1.824 1.821 1.965 1.824 1.7702 1.648 1.646 1.774 1.6480.9012 2.4085 2.313 2.313 2.480 2.313 2.1692 2.088 2.088 2.169 2.0881.0000 3.0602 3.060 3.060 3.060 3.060 2.7621 2.762 2.762 2.762 2.762

SD 0.0464 0.0395 0.0311 0.0461 0.0605 0.0543 0.0363 0.0602

Table-3 Mole fraction of 2-chloroaniline (x1), density (ρ), speed of sound (u), deviation in ultrasonic speed (∆u), isentropic compressibility

(κs), intermolecular free length (Lf), acoustic impedance (Z), excess isentropic compressibility (κsE), excess intermolecular free length (Lf

E), deviation in acoustic impedance (Z) of the binary mixtures at 303.15 K, 308.15 K, 313.15and 318.15 K respectively.

2-chloroaniline(1) + toluene(2) 303.15 Kx1 ρ /(g /cm3) u/m sec-1 κs /TPa-1 Z ×10-3 /kgm-2s-1 Lf×10-9/m Z /kgm-2s-1 ∆u/m s-1 κs

E

/TPa-1 LfE×10-9/m

0.0000 857.62 1272.5 720.1 1091.3 225.03 0.000 0.000 0.000 0.0000.0821 885.53 1267.0 703.4 1122.0 219.82 1.447 0.208 -5.056 -1.4640.1801 918.95 1260.5 684.9 1158.4 214.02 2.902 0.458 -9.658 -2.7910.2698 949.63 1254.5 669.1 1191.4 209.09 3.949 0.662 -12.59 -3.6310.3605 980.74 1248.5 654.2 1224.4 204.43 4.716 0.831 -14.40 -4.1460.4712 1018.85 1240.9 637.4 1264.3 199.19 5.166 0.907 -15.10 -4.3350.5748 1054.65 1233.7 623.0 1301.1 194.68 5.114 0.874 -14.40 -4.1200.6805 1091.29 1226.3 609.4 1338.2 190.43 4.567 0.735 -12.43 -3.5450.7825 1126.76 1219.0 597.2 1373.5 186.64 3.564 0.519 -9.441 -2.6830.8956 1166.20 1211.0 584.8 1412.2 182.74 1.951 0.249 -5.019 -1.4211.0000 1202.69 1203.5 574.1 1447.4 179.39 0.000 0.000 0.000 0.000

2-chloroaniline(1) + toluene(2) 308.15 Kx1 ρ /(g /cm3) u/m sec-1 κs /TPa-1 Z ×10-3 /kgm-2s-1 Lf×10-9/m Z /kgm-2s-1 ∆u/m s-1 κs

E

/TPa-1 LfE×10-9/m

0.0000 852.95 1262.3 735.8 0.0000 1076.7 231.77 0.000 0.000 0.0000.0821 880.92 1258.6 716.7 0.0821 1108.7 225.75 2.554 1.518 -6.8550.1801 914.35 1252.8 696.8 0.1801 1145.5 219.49 4.201 2.055 -11.9710.2698 945.00 1246.9 680.6 0.2698 1178.3 214.40 4.808 1.870 -14.5630.3605 976.08 1240.7 665.6 0.3605 1211.0 209.65 4.953 1.469 -15.8040.4712 1014.16 1233.3 648.3 0.4712 1250.8 204.21 4.954 1.139 -16.0780.5748 1049.97 1226.7 632.9 0.5748 1288.0 199.36 5.062 1.228 -15.4650.6805 1086.66 1220.4 617.8 0.6805 1326.2 194.62 5.282 1.688 -14.0260.7825 1122.18 1214.4 604.3 0.7825 1362.8 190.34 5.237 2.164 -11.5910.8956 1161.64 1206.9 591.0 0.8956 1402.0 186.15 3.915 1.959 -6.9981.0000 1198.02 1198.3 581.3 1.0000 1435.6 183.11 0.000 0.000 0.000

2-chloroaniline(1) + toluene(2) 313.15 Kx1 ρ /(g /cm3) u/m sec-1 κs /TPa-1 Z ×10-3 /kgm-2s-1 Lf×10-9/m Z /kgm-2s-1 ∆u/m s-1 κs

E

/TPa-1 LfE×10-9/m

0.0000 848.23 1253.5 750.3 1063.3 238.22 0.000 0.000 0.000 0.0000.0821 876.22 1250.7 729.6 1095.9 231.66 3.093 2.174 -7.946 -2.3710.1801 909.62 1245.5 708.7 1132.9 225.01 4.924 2.977 -13.57 -4.0120.2698 940.23 1239.8 691.9 1165.7 219.68 5.447 2.741 -16.21 -4.7490.3605 971.27 1233.7 676.4 1198.3 214.76 5.417 2.192 -17.33 -5.0340.4712 1009.31 1226.5 658.6 1237.9 209.11 5.277 1.720 -17.46 -5.0340.5748 1045.11 1220.3 642.5 1275.4 204.00 5.444 1.821 -16.83 -4.8420.6805 1081.79 1214.5 626.7 1313.8 198.98 5.912 2.440 -15.47 -4.4640.7825 1117.34 1208.9 612.4 1350.8 194.43 6.167 3.069 -13.07 -3.7970.8956 1156.76 1201.7 598.6 1390.1 190.06 4.833 2.759 -8.131 -2.387

1.0000 1193.02 1192.6 589.3 1422.8 187.11 0.000 0.000 0.000 0.000

2-chloroaniline(1) + toluene(2) 318.15 Kx1 ρ /(g /cm3) u/m sec-1 κs /TPa-1 Z ×10-3 /kgm-2s-1 Lf×10-9/m Z /kgm-2s-1 ∆u/m s-1 κs

E

/TPa-1 LfE×10-9/m

0.0000 844.35 1235.7 775.6 1043.4 248.98 0.000 0.000 0.000 0.0000.0821 872.35 1234.3 752.4 1076.7 241.53 3.160 2.546 -8.989 -2.7240.1801 905.70 1230.4 729.4 1114.4 234.12 4.717 3.360 -15.02 -4.5070.2698 936.27 1225.6 711.1 1147.5 228.25 4.843 2.901 -17.60 -5.2270.3605 967.22 1220.4 694.1 1180.4 222.82 4.412 2.106 -18.52 -5.4480.4712 1005.18 1214.5 674.5 1220.8 216.52 4.003 1.470 -18.47 -5.3900.5748 1040.91 1209.6 656.6 1259.1 210.75 4.264 1.655 -17.87 -5.2050.6805 1077.55 1205.5 638.6 1299.0 205.00 5.199 2.577 -16.70 -4.8880.7825 1113.04 1201.6 622.3 1337.4 199.76 6.091 3.581 -14.46 -4.2700.8956 1152.41 1195.9 606.7 1378.2 194.76 5.279 3.395 -9.283 -2.7741.0000 1188.49 1187.5 596.7 1411.3 191.53 0.000 0.000 0.000 0.000

2-chloroaniline(1) + o-xylene(2) 303.15 Kx1 ρ /(g /cm3) u/m sec-1 κs /TPa-1 Z ×10-3 /kgm-2s-1 Lf×10-9/m Z /kgm-2s-1 ∆u/m s-1 κs

E

/TPa-1 LfE×10-9/m

0.0000 871.32 1337.5 0.0000 1165.4 200.49 0.000 0.000 0.000 0.0000.0805 894.32 1337.9 0.0805 1196.5 195.21 -17.34 -10.21 1.283 1.1780.1856 925.14 1338.4 0.1856 1238.2 188.58 -38.98 -23.66 4.384 2.9780.2856 955.37 1339.9 0.2856 1280.1 182.20 -57.25 -35.33 7.706 4.6080.3751 983.23 1343.2 0.3751 1320.7 176.17 -70.58 -43.87 10.23 5.7570.4789 1016.57 1350.2 0.4789 1372.6 168.61 -81.12 -50.52 12.03 6.5240.5761 1048.84 1360.9 0.5761 1427.4 160.87 -84.88 -52.69 12.28 6.5770.6805 1084.69 1377.6 0.6805 1494.3 151.80 -80.81 -49.76 10.88 5.8780.7859 1122.20 1400.8 0.7859 1572.0 141.91 -66.56 -40.49 7.966 4.434

0.8952 1162.56 1432.2 0.8952 1665.1 131.04 -39.31 -23.51 3.924 2.3281.0000 1202.69 1469.6 1.0000 1767.5 120.31 0.000 0.000 0.000 0.000

2-chloroaniline(1) + o-xylene(2) 308.15 Kx1 ρ /(g /cm3) u/m sec-1 κs /TPa-1 Z ×10-3 /kgm-2s-1 Lf×10-9/m Z /kgm-2s-1 ∆u/m s-1 κs

E

/TPa-1 LfE×10-9/m

0.0000 867.07 1314.2 667.76 1139.5 210.35 0.000 0.000 0.000 0.0000.0805 889.90 1314.3 650.53 1169.6 204.92 -18.33 -11.09 2.050 1.4830.1856 920.61 1314.5 628.67 1210.1 198.03 -41.05 -25.54 5.990 3.6210.2856 950.79 1316.4 606.97 1251.6 191.20 -59.74 -37.57 9.522 5.3710.3751 978.63 1320.1 586.36 1291.9 184.70 -73.26 -46.27 12.07 6.5620.4789 1011.93 1327.8 560.53 1343.6 176.57 -83.98 -53.03 13.83 7.3370.5761 1044.15 1339.0 534.15 1398.1 168.26 -87.94 -55.31 14.02 7.3730.6805 1079.92 1356.4 503.33 1464.8 158.55 -84.11 -52.49 12.56 6.6280.7859 1117.37 1380.4 469.69 1542.4 147.95 -69.90 -43.14 9.466 5.0800.8952 1157.72 1413.2 432.49 1636.1 136.23 -41.92 -25.49 4.941 2.7451.0000 1198.02 1453.3 395.21 1741.1 124.49 0.000 0.000 0.000 0.000

2-chloroaniline(1) + o-xylene(2) 313.15 Kx1 ρ /(g /cm3) u/m sec-1 κs /TPa-1 Z ×10-3 /kgm-2s-1 Lf×10-9/m Z /kgm-2s-1 ∆u/m s-1 κs

E

/TPa-1 LfE×10-9/m

0.0000 862.82 1297.5 688.44 1119.5 218.58 0.000 0.000 0.000 0.0000.0805 885.48 1297.6 670.76 1149.0 212.96 -18.23 -11.02 2.204 1.5760.1856 916.06 1297.8 648.13 1188.7 205.80 -40.78 -25.26 6.295 3.8130.2856 946.17 1299.0 626.36 1228.6 198.94 -60.14 -37.84 10.71 5.8830.3751 973.97 1302.7 605.00 1268.2 192.18 -73.62 -46.43 13.34 7.1230.4789 1007.21 1311.2 577.47 1320.0 183.44 -83.33 -52.22 14.30 7.6590.5761 1039.35 1322.5 550.09 1374.0 174.73 -87.00 -54.30 14.31 7.6380.6805 1075.03 1402.3 473.04 1440.5 164.45 -82.40 -50.86 12.26 6.6900.7859 1112.37 1361.6 484.90 1514.4 153.98 -70.97 -44.11 10.85 5.6430.8952 1152.66 1393.4 446.85 1606.1 141.88 -44.03 -27.39 6.496 3.307

1.0000 1193.02 1435.2 406.94 1712.2 129.20 0.000 0.000 0.000 0.000

2-chloroaniline(1) + o-xylene(2) 318.15 Kx1 ρ /(g /cm3) u/m sec-1 κs /TPa-1 Z ×10-3 /kgm-2s-1 Lf×10-9/m Z /kgm-2s-1 ∆u/m s-1 κs

E

/TPa-1 LfE×10-9/m

0.0000 858.65 1278.5 712.5 1097.8 228.71 0.000 0.000 0.000 0.0000.0805 881.16 1278.7 694.06 1126.8 222.79 -18.41 -11.08 2.373 1.6940.1856 911.64 1278.8 670.82 1165.8 215.33 -41.26 -25.80 6.980 4.1710.2856 941.70 1280.4 647.73 1205.8 207.92 -60.12 -38.19 11.13 6.2150.3751 969.47 1284.9 624.83 1245.6 200.57 -72.93 -46.31 13.25 7.3260.4789 1002.68 1292.8 596.73 1296.3 191.55 -83.39 -52.94 14.96 8.1230.5761 1034.78 1303.7 568.60 1349.0 182.52 -87.83 -55.70 15.55 8.2840.6805 1070.41 1320.4 535.85 1413.4 172.01 -84.94 -53.65 14.54 7.6430.7859 1107.73 1343.5 500.14 1488.2 160.54 -72.10 -45.34 11.86 6.1450.8952 1147.98 1376.1 460.01 1579.7 147.66 -44.93 -28.08 7.081 3.5981.0000 1188.49 1418.9 417.93 1686.3 134.15 0.000 0.000 0.000 0.000

2-chloroaniline(1) + m-xylene(2) 303.15 Kx1 ρ /(g /cm3) u/m sec-1 κs /TPa-1 Z ×10-3 /kgm-2s-1 Lf×10-9/m Z /kgm-2s-1 ∆u/m s-1 κs

E

/TPa-1 LfE×10-9/m

0.0000 855.75 1302.5 688.8 1114.6 215.25 0.000 0.000 0.000 0.0000.0896 882.05 1303.3 667.4 1149.6 208.58 -23.53 -14.16 2.215 1.8300.1798 909.35 1304.6 646.1 1186.4 201.91 -45.65 -27.93 5.257 3.7280.2798 940.67 1307.6 621.8 1230.0 194.31 -67.31 -41.69 8.732 5.6210.3912 976.83 1314.0 592.9 1283.5 185.29 -86.47 -53.89 11.84 7.1800.4951 1011.85 1324.1 563.7 1339.8 176.15 -98.03 -61.11 13.42 7.9030.5894 1044.77 1337.7 534.8 1397.6 167.14 -101.7 -63.23 13.44 7.847

0.6812 1077.93 1355.9 504.6 1461.6 157.68 -97.75 -60.40 12.12 7.1080.7958 1120.93 1386.7 463.9 1554.4 144.97 -79.71 -48.73 8.777 5.2730.8925 1158.73 1421.1 427.4 1646.6 133.55 -50.67 -30.58 4.856 3.0351.0000 1202.69 1469.6 385.0 1767.5 120.31 0.000 0.000 0.000 0.000

2-chloroaniline(1) + m-xylene(2) 308.15 Kx1 ρ /(g /cm3) u/m sec-1 κs /TPa-1 Z ×10-3 /kgm-2s-1 Lf×10-9/m Z /kgm-2s-1 ∆u/m s-1 κs

E

/TPa-1 LfE×10-9/m

0.0000 851.47 1285.7 710.5 1094.7 223.80 -19.88 0.000 0.000 0.0000.0896 877.60 1285.9 689.1 1128.5 217.06 -44.58 -14.78 3.041 2.1560.1798 904.85 1286.9 667.3 1164.4 210.21 -67.57 -28.96 6.584 4.2700.2798 936.09 1290.0 641.9 1207.6 202.21 -89.70 -42.56 9.989 6.1930.3912 972.20 1296.7 611.7 1260.7 192.70 -109.3 -54.56 12.96 7.7450.4951 1007.18 1306.8 581.4 1316.2 183.13 -121.6 -61.85 14.58 8.5010.5894 1040.04 1320.1 551.7 1373.0 173.79 -126.4 -64.33 14.85 8.5190.6812 1073.15 1337.8 520.7 1435.6 164.02 -123.7 -62.10 13.87 7.8670.7958 1116.10 1367.9 478.8 1526.7 150.83 -107.4 -51.17 10.78 6.0640.8925 1153.97 1402.3 440.7 1618.2 138.82 -79.10 -33.00 6.516 3.6521.0000 1198.02 1453.3 395.2 1741.1 124.49 -26.39 0.000 0.000 0.000

2-chloroaniline(1) + m-xylene(2) 313.15 Kx1 ρ /(g /cm3) u/m sec-1 κs /TPa-1 Z ×10-3 /kgm-2s-1 Lf×10-9/m Z /kgm-2s-1 ∆u/m s-1 κs

E

/TPa-1 LfE×10-9/m

0.0000 847.18 1266.5 735.9 1073.0 233.65 -41.66 0.000 0.000 0.0000.0896 873.09 1266.7 713.8 1105.9 226.64 -67.17 -14.92 3.430 2.3560.1798 900.10 1267.5 691.5 1140.9 219.56 -91.12 -29.32 7.465 4.6920.2798 931.12 1270.3 665.6 1182.8 211.33 -114.5 -43.44 11.60 6.9060.3912 967.04 1277.2 634.0 1235.1 201.28 -134.9 -55.32 14.55 8.4930.4951 1001.89 1288.1 601.6 1290.5 191.00 -147.3 -61.92 15.52 9.061

0.5894 1034.70 1302.0 570.1 1347.2 181.01 -152.2 -63.92 15.31 8.9230.6812 1067.79 1319.8 537.6 1409.3 170.70 -150.0 -61.60 14.17 8.1990.7958 1110.83 1349.2 494.6 1498.7 157.03 -135.4 -51.59 11.57 6.4950.8925 1148.80 1382.2 455.6 1587.8 144.67 -109.4 -34.88 8.018 4.2381.0000 1193.02 1435.2 406.9 1712.2 129.20 -55.25 0.000 0.000 0.000

2-chloroaniline(1) + m-xylene(2) 318.15 Kx1 ρ /(g /cm3) u/m sec-1 κs /TPa-1 Z ×10-3 /kgm-2s-1 Lf×10-9/m Z /kgm-2s-1 ∆u/m s-1 κs

E

/TPa-1 LfE×10-9/m

0.0000 843.18 1243.3 767.2 1048.3 246.28 -66.29 0.000 0.000 0.0000.0896 868.87 1243.7 744.1 1080.6 238.86 -92.53 -15.37 3.921 2.6260.1798 895.78 1244.3 721.0 1114.6 231.45 -117.3 -30.58 8.803 5.3320.2798 926.77 1247.8 693.0 1156.5 222.44 -140.8 -44.59 12.63 7.5340.3912 962.69 1255.5 659.0 1208.6 211.54 -161.3 -56.51 15.39 9.1240.4951 997.50 1266.7 624.8 1263.6 200.55 -174.2 -63.50 16.56 9.7790.5894 1030.23 1280.5 591.9 1319.3 190.01 -180.1 -66.25 16.92 9.8180.6812 1063.20 1298.7 557.6 1380.8 179.00 -178.5 -64.18 15.90 9.0990.7958 1106.08 1329.4 511.6 1470.4 164.21 -163.7 -53.63 12.81 7.1600.8925 1144.01 1364.6 469.4 1561.1 150.68 -136.1 -35.42 8.246 4.4751.0000 1188.49 1418.9 417.9 1686.3 134.15 -81.12 0.000 0.000 0.000

2-chloroaniline(1) + p-xylene(2) 303.15 Kx1 ρ /(g /cm3) u/m sec-1 κs /TPa-1 Z ×10-3 /kgm-2s-1 Lf×10-9/m Z /kgm-2s-1 ∆u/m s-1 κs

E

/TPa-1 LfE×10-9/m

0.0000 852.45 1287.8 707.35 1097.8 221.05 0.000 0.000 0.000 0.0000.0895 878.69 1288.3 685.75 1132.0 214.30 -25.75 -15.82 3.299 2.2650.1795 906.06 1289.9 663.36 1168.7 207.30 -49.29 -30.56 6.640 4.3360.3125 948.25 1295.5 628.35 1228.5 196.36 -78.60 -49.10 10.96 6.7920.4256 985.74 1304.5 596.14 1285.9 186.29 -96.91 -60.67 13.51 8.121

0.5169 1017.09 1315.5 568.18 1337.9 177.55 -106.0 -66.30 14.52 8.5790.6254 1055.67 1333.9 532.37 1408.2 166.37 -108.4 -67.58 14.27 8.3210.7145 1088.53 1354.5 500.73 1474.4 156.48 -101.8 -63.20 12.79 7.4090.8102 1125.14 1383.4 464.39 1556.5 145.12 -83.83 -51.67 9.863 5.6940.9012 1161.41 1419.1 427.54 1648.2 133.61 -53.13 -32.51 5.786 3.3441.0000 1202.69 1469.6 384.99 1767.5 120.31 0.000 0.000 0.000 0.000

2-chloroaniline(1) + p-xylene(2) 308.15 Kx1 ρ /(g /cm3) u/m sec-1 κs /TPa-1 Z ×10-3 /kgm-2s-1 Lf×10-9/m Z /kgm-2s-1 ∆u/m s-1 κs

E

/TPa-1 LfE×10-9/m

0.0000 848.15 1275.8 724.37 1082.1 228.18 0.000 0.000 0.000 0.0000.0895 874.25 1276.1 702.47 1115.6 221.28 -25.47 -15.63 3.497 2.3810.1795 901.53 1277.0 680.16 1151.3 214.25 -49.08 -30.62 7.435 4.6860.3125 943.64 1282.1 644.68 1209.9 203.07 -78.16 -49.16 12.09 7.2980.4256 981.09 1290.4 612.09 1266.0 192.81 -96.50 -60.90 14.97 8.7590.5169 1012.42 1300.7 583.83 1316.8 183.91 -105.8 -66.85 16.30 9.3260.6254 1050.97 1318.1 547.65 1385.3 172.51 -108.9 -68.68 16.43 9.1770.7145 1083.79 1337.8 515.53 1449.9 162.39 -103.0 -64.80 15.12 8.3000.8102 1120.38 1366.0 478.35 1530.4 150.68 -85.59 -53.62 12.06 6.5100.9012 1156.65 1401.5 440.14 1621.1 138.64 -54.89 -34.23 7.355 3.9101.0000 1198.02 1453.3 395.21 1741.1 124.49 0.000 0.000 0.000 0.000

2-chloroaniline(1) + p-xylene(2) 313.15 Kx1 ρ /(g /cm3) u/m sec-1 κs /TPa-1 Z ×10-3 /kgm-2s-1 Lf×10-9/m Z /kgm-2s-1 ∆u/m s-1 κs

E

/TPa-1 LfE×10-9/m

0.0000 843.79 1253.2 754.61 1057.4 239.59 0.000 0.000 0.000 0.0000.0895 869.67 1253.4 731.97 1090.0 232.40 -26.03 -16.13 4.161 2.6900.1795 896.72 1254.0 709.14 1124.5 225.15 -50.47 -31.85 9.036 5.3780.3125 938.52 1259.4 671.75 1182.0 213.28 -80.06 -50.64 14.01 8.187

0.4256 975.76 1268.8 636.65 1238.0 202.14 -98.11 -61.90 16.37 9.5280.5169 1006.98 1280.3 605.87 1289.2 192.36 -106.6 -67.00 16.83 9.8320.6254 1045.49 1298.6 567.17 1357.7 180.08 -109.2 -68.39 16.49 9.5220.7145 1078.35 1318.8 533.22 1422.1 169.30 -103.1 -64.47 15.09 8.5790.8102 1115.05 1346.1 494.93 1501.0 157.14 -86.96 -54.54 12.86 6.9850.9012 1151.48 1381.1 455.28 1590.3 144.55 -57.19 -36.08 8.612 4.4411.0000 1193.02 1435.2 406.94 1712.2 129.20 0.000 0.000 0.000 0.000

2-chloroaniline(1) + -xylene(2) 318.15 Kx1 ρ /(g /cm3) u/m sec-1 κs /TPa-1 Z ×10-3 /kgm-2s-1 Lf×10-9/m Z /kgm-2s-1 ∆u/m s-1 κs

E

/TPa-1 LfE×10-9/m

0.0000 839.64 1234.8 781.11 1036.8 250.74 0.000 0.000 0.000 0.0000.0895 865.48 1235.1 757.43 1068.9 243.14 -25.97 -16.18 4.292 2.8330.1795 892.54 1235.4 734.14 1102.6 235.66 -50.77 -32.47 9.907 5.8470.3125 934.37 1241.2 694.66 1159.8 222.99 -80.00 -51.09 14.66 8.6800.4256 971.61 1250.6 658.03 1215.1 211.23 -98.12 -62.51 17.15 10.100.5169 1002.78 1261.7 626.43 1265.2 201.09 -107.3 -68.24 18.18 10.600.6254 1041.17 1279.7 586.52 1332.4 188.27 -110.6 -70.26 18.34 10.440.7145 1073.92 1299.4 551.48 1395.5 177.03 -105.4 -66.92 17.31 9.5860.8102 1110.49 1327.5 510.96 1474.2 164.02 -88.84 -56.41 14.48 7.7370.9012 1146.85 1363.4 469.07 1563.6 150.57 -58.53 -37.29 9.598 4.8971.0000 1188.49 1418.9 417.93 1686.3 134.15 0.000 0.000 0.000 0.000