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Regioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, Singapore 637371 E-mail: [email protected] Supporting Information: NMR spectra S1 Electronic Supplementary Material (ESI) for Chemical Communications This journal is © The Royal Society of Chemistry 2013

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Page 1: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

 

 

 

 

 

Regioselective Heck Reaction of Aliphatic Olefins and Aryl Halides

Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University,

21 Nanyang Link, Singapore 637371

E-mail: [email protected]

Supporting Information: NMR spectra        

 

 

 

 

 

 

S1

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 2: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S2

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 3: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S3

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 4: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S4

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 5: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S5

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 6: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S6

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 7: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S7

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 8: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S8

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 9: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S9

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 10: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S10

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 11: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S11

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 12: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S12

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 13: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S13

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 14: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S14

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 15: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S15

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 16: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S16

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 17: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S17

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 18: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S18

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 19: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

S19

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 20: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S20

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 21: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S21

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 22: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S22

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 23: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S23

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 24: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S24

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 25: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S25

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 26: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S26

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 27: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S27

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 28: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S28

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 29: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S29

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 30: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

S30

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 31: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S31

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 32: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S32

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 33: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S33

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 34: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S34

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 35: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S35

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 36: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S36

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 37: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S37

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013

Page 38: Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou* · PDF fileRegioselective Heck Reaction of Aliphatic Olefins and Aryl Halides Liena Qin, Hajime Hirao and Jianrong (Steve) Zhou*

 

S38

Electronic Supplementary Material (ESI) for Chemical CommunicationsThis journal is © The Royal Society of Chemistry 2013