lewis theory of chemical bonding 51...lewis theory of chemical bonding • in lewis theory, a...
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Ch 10: Chemical Bonding Lewis Dot Structures: dots represent valence electrons
Octet Rule: In chemical bonding, atoms transfer or share electrons to obtain outer shells with eight electrons. Exceptions: H, Li, Be & B (6)
Hmwk: 2, 6, 23, 31, 37, 43, 47, 49, 57, 65, 79, 89, 95 & 105
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Lewis Theory of Chemical Bonding • In Lewis theory, a chemical bond involves
the sharing or transfer of electrons to attain stable electron configurations for the bonding atoms.
• If the electrons are transferred, the bond is an ionic bond.
• If the electrons are shared, the bond is a covalent bond.
• In either case, the bonding atoms attain stable electron configurations.
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Lewis Structures for
• Ionic Compounds: e- transferred • Covalent Compounds: e- shared
• Atom Arrangement: • Hydrogens are terminal • Molecules tend towards symmetry • Multiple identical atoms- terminal
• Bonding & Lone-pair electrons • Bonds: single, double & triple • Polyatomic ions • Exceptions: NO, BF3, SF6 & PCl5 • Resonance: O3 & CO3
2-
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VSEPR Theory & Molecular Geometry
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Electronegativity, Polar Bonds & Polar Molecules
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The degree of bond polarity is a continuous function. The guidelines given here are approximate.
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© 2012 Pearson Education, Inc.
© 2012 Pearson Education, Inc.
Highlight Problem 10.113 • Draw the Lewis structure
for each of these free radicals, which have been implicated in theories of aging.
• O2−
• O− • OH • CH3OO(unpaired electron
on terminal oxygen)